(311) Method for preparing perovskite titanate material with crystal plane preferred growth and application thereof

By using density premixing and homogenizing, perovskite titanate materials with preferential growth of (311) crystal planes were prepared, solving the problems of uniform mixing and crystal plane growth of titanate materials, improving the safety and energy density of lithium-ion batteries, and achieving high-efficiency electrochemical performance.

CN122235834APending Publication Date: 2026-06-19HUAZHONG UNIV OF SCI & TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUAZHONG UNIV OF SCI & TECH
Filing Date
2026-03-05
Publication Date
2026-06-19

AI Technical Summary

Technical Problem

Traditional preparation processes make it difficult to achieve uniform mixing and selective growth of specific crystal planes in perovskite titanate materials, which limits the improvement of the material's electrochemical performance. Furthermore, existing anode materials have shortcomings in terms of safety and energy density.

Method used

Perovskite titanate material with (311) crystal plane preferential growth was prepared by using density premixing and homogenizer mixing, through "core-shell" predispersion structure and three-dimensional uniform dispersion, combined with Bravais law of crystal growth and the principle of preferred crystal growth.

Benefits of technology

It improves the lithium-ion diffusion rate and rate performance of the material, enhances the compaction density and energy density of the electrode, improves the cycle life of the material and the battery, and reduces the complexity and cost of the manufacturing process.

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Abstract

This invention provides a method for preparing perovskite titanate materials with preferred growth on the (311) crystal plane and its application. The structural formula of the perovskite titanate material is A. x B y TiO4, wherein element A is at least one of Na, Ca, and La, and element B is at least one of Y, Ni, and Sr, and 0 < x ≤ 1, 0 < y ≤ 1. The perovskite titanate material prepared by this invention has a low crystal defect content, and the (311) crystal plane is the dominant crystal plane. The (311) direction is the direction of rapid diffusion of lithium ions in the bulk structure of the perovskite titanate material. The perovskite titanate material dominated by the (311) crystal plane has a short ion diffusion distance and a fast overall lithium ion diffusion rate, thereby improving the rate performance of the material.
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