A titanium-based catalyst, a titanium-based composite catalyst and its preparation method

By pyrolyzing a titanium-based MOF framework and loading it with single-atom Cu and Pt-Cu alloys, the problems of low visible light absorption and low photogenerated carrier separation efficiency of TiO2 nanomaterials were solved, achieving efficient utilization of visible light and improved photocatalytic performance.

CN122298409APending Publication Date: 2026-06-30NORTHEAST GASOLINEEUM UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NORTHEAST GASOLINEEUM UNIV
Filing Date
2026-05-12
Publication Date
2026-06-30

AI Technical Summary

Technical Problem

Existing TiO2 nanomaterials have poor absorption of visible light and low separation efficiency of photogenerated carriers, resulting in low solar energy utilization and photogenerated electron utilization.

Method used

A porous rutile TiO2 nanomaterial was constructed by pyrolyzing a high specific surface area titanium-based MOF framework under an inert atmosphere and achieving in-situ rearrangement and directional phase transformation of titanium-oxygen clusters through a topological confinement pyrolysis strategy. Single-atom Cu and Pt-Cu alloys were then loaded onto the nanomaterial to construct a heterojunction to optimize electron transport channels.

Benefits of technology

It improves the material's response to visible light and photocatalytic performance, exhibits good adsorption and photocatalytic degradation effects on Rhodamine B, enhances the spatial separation efficiency of photogenerated carriers, and improves photocatalytic reaction activity.

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Abstract

This invention relates to a titanium-based catalyst, a titanium-based composite catalyst, and their preparation method, belonging to the field of catalyst technology. The titanium-based catalyst is obtained by pyrolysis of a titanium-based MOF framework under an inert atmosphere; the pyrolysis temperature is 700-850℃. This titanium-based catalyst exhibits intrinsic visible light response and excellent adsorption and photocatalytic performance, showing good adsorption and photocatalytic degradation effects on Rhodamine B.
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