Method for purifying semiconductor-grade quartz sand without acid

The purification system, which combines acid-free complexation scrubbing, neutral reverse flotation, and gradient chlorination roasting, solves the problems of equipment corrosion and environmental pollution in existing quartz sand purification processes, achieving efficient quartz sand purification and obtaining high-purity semiconductor-grade quartz sand.

CN122403458APending Publication Date: 2026-07-17KAISEN QUARTZ MATERIALS (TAIHU) CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
KAISEN QUARTZ MATERIALS (TAIHU) CO LTD
Filing Date
2026-04-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing quartz sand purification processes rely on volatile acids and fluorine-containing inhibitors, leading to equipment corrosion, environmental pollution, and occupational health risks, and cannot meet the high purity requirements of semiconductor-grade quartz sand.

Method used

A purification system consisting of acid-free complexing scrubbing, neutral reverse flotation, and gradient chlorination roasting is employed. The complexing scrubbing agent, a mixture of aminotrimethylene phosphonic acid and hydroxyethylidene diphosphonic acid, is used to remove metallic impurities under alkaline conditions. The neutral flotation system achieves efficient separation of quartz and gangue through hydroxypropyl oxidized starch and a composite amphoteric collector. Gradient chlorination roasting removes impurities.

Benefits of technology

Efficient separation of quartz and gangue was achieved under neutral conditions, and metallic impurities in quartz were deeply removed, resulting in semiconductor-grade quartz sand with a purity of 99.9992%. This solved the problems of equipment corrosion and environmental pollution, and met the requirements of semiconductor-grade applications.

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Abstract

The application discloses a kind of purification methods of acidless semiconductor grade quartz sand, belong to material purification field.This method is prepared semiconductor grade quartz sand by raw material pretreatment, acidless complex scrubbing, neutral fluoride-free acid reverse flotation, gradient chlorination roasting whole-process procedure, core uses hydroxypropyl oxidized starch as quartz inhibitor, amino polycarboxy compound and sulfobutyric acid methyl ester sodium compound amphoteric collector of compounding, realize the efficient separation of quartz and gangue mineral under the neutral condition of pH6.5~7.5.The application does not use hydrofluoric acid, sulfuric acid and other strong acid throughout, realizes the efficient purification of quartz sand by the synergistic effect of physical and chemical methods, product purity can reach more than 99.9992%, meet the requirement of semiconductor grade, and environment-friendly, process safety.
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