A method for starting and debugging an oscillation type electric adsorption based wastewater treatment system

By injecting a microampere-level broadband AC excitation current signal and impedance imaginary part feedback into the electroadsorption system, combined with a piezoelectric ceramic pulsating water pump and digital phase-locked loop control, the problem of electrolyte penetration into the microporous structure of porous carbon electrodes was solved, achieving efficient wetting and stable operation of the system.

CN122403589APending Publication Date: 2026-07-17HUANENG (DALIAN) THERMAL POWER CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUANENG (DALIAN) THERMAL POWER CO LTD
Filing Date
2026-04-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the initial startup and commissioning phases, existing electroadsorption systems face resistance during the penetration process of the electrolyte into the microporous structure of the porous carbon electrode, resulting in the formation of unwetted dead zones, which affects adsorption efficiency and system stability. Furthermore, they lack precise monitoring of the physical state of the micro-interface and coordinated control of macro-fluid-driven processes.

Method used

A wastewater treatment system based on oscillating electroadsorption is adopted. By injecting a microampere-level broadband AC excitation current signal, combined with in-situ microcurrent broadband impedance detection and impedance imaginary part feedback, and using a piezoelectric ceramic pulsed water pump and digital phase-locked loop control, the physical wetting state of the porous carbon electrode micropore network is quantitatively monitored and precisely controlled. With the help of high-frequency asymmetric commutation pulse voltage and acoustic cleaning, the mechanical balance of the air blockage inside the micropores is broken, ensuring the deep penetration of wastewater electrolyte.

Benefits of technology

It enables precise monitoring and control of the physical wetting state of the microporous network of porous electrodes, ensuring that the system operates under optimal wetting conditions, improving initial desalination efficiency and system stability, and avoiding the problem of excessively rapid local polarization of the electrodes.

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Abstract

本发明公开了一种基于振荡式电吸附的废水处理系统启动与调试方法,属于电化学水处理领域,该方法主要步骤包括:首先通过原位微电流宽频阻抗探查提取特征角频率,所述特征角频率随润湿进程降低并最终趋于稳定;随后依据特征角频率输出高频非对称换向脉冲电压,并通过相位补偿实现压力波峰与毛细阻力极小值时刻重合,实现液电相干推进及气液置换;接着监控相位角变化率判定微孔润湿饱和状态;最后平滑过渡至低频电吸附模式。本发明解决了多孔电极润湿困难及气泡堵塞问题,实现高效离子传质。
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