A mass solid waste-based low-carbon concrete maintenance-free agent and a preparation method thereof

By generating calcium-aluminum layered double hydroxide intercalated alkali-resistant hydrogel composite microparticles and compounding them with high-calcium solid waste micropowder, silicon-aluminum solid waste micropowder and modified porous carbon materials, the problems of early water loss, cracking and insufficient strength of low-carbon concrete based on bulk solid waste were solved. The water storage, water retention and slow-release water supply functions were realized in a high-alkali environment, and the engineering applicability of concrete was improved.

CN122403833APending Publication Date: 2026-07-17HENGSHUI JITU TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HENGSHUI JITU TECH CO LTD
Filing Date
2026-05-11
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing curing-free concrete technologies for low-carbon concrete based on bulk solid waste suffer from problems such as rapid early water loss, insufficient strength development, and plastic shrinkage cracking. In particular, the water absorption ratio decreases significantly in high-alkali, high-calcium, and high-sulfate pore solutions, making it difficult to match with solid waste-based cementitious systems.

Method used

The calcium-aluminum layered double hydroxide intercalation structure is generated by in-situ reaction of calcium and aluminum sources with acrylamide, acrylic acid, and 2-acrylamide-2-methylpropanesulfonic acid, forming an alkali-resistant controlled-release hydrogel network. The composite microparticles are combined with high-calcium solid waste powder, silica-alumina solid waste powder, and modified porous carbon materials to achieve continuous internal water supply, promote gelation reaction, and CO2 mineralization and densification.

Benefits of technology

Without watering or covering, it reduces early water loss and shrinkage cracking, improves compressive strength and strength retention rate, and enhances the utilization rate of bulk solid waste. It has the advantages of low carbon, alkali resistance, controlled release and strong engineering adaptability.

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Abstract

本发明公开了一种大宗固废基低碳混凝土免养护剂及其制备方法。该方法先将钙源、铝源、丙烯酰胺、丙烯酸、2‑丙烯酰胺‑2‑甲基丙磺酸、交联剂和过硫酸铵加入水中,在碱性条件下原位生成钙铝层状双氢氧化物插层耐碱水凝胶复合微粒;再将高钙固废和硅铝质固废粉磨成微粉,将多孔碳材料经氢氧化钙悬浮液浸渍改性,并将复合微粒经CO2预碳化处理;最后将复合微粒、高钙固废微粉、硅铝质固废微粉、改性多孔碳材料、保水增稠组分、减水组分、碳酸盐调节组分和消泡组分混合,得到免养护剂。本发明制得的免养护剂具有耐碱储水、缓释供水、水化成核和矿化致密协同作用,可降低混凝土免洒水条件下的早期失水、收缩开裂和强度损失。
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