Aging-resistant composite material for automobiles and method for preparing the same

By combining modified glass fiber and halloysite nanotubes, the problem of insufficient aging resistance of polypropylene materials in automotive applications was solved, and the stability under thermal-oxidative and photo-oxidative aging environments was improved, thus constructing a multi-layered antioxidant protection system.

CN122404853APending Publication Date: 2026-07-17SHIYAN BOXING AUTOMOBILE DECORATIVE PROD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHIYAN BOXING AUTOMOBILE DECORATIVE PROD
Filing Date
2026-06-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polypropylene materials have insufficient aging resistance in automotive applications, especially under ultraviolet light and heat-oxidation environments, where they are prone to aging. Furthermore, existing reinforcing agents and antioxidants suffer from migration, precipitation, and volatilization losses.

Method used

Modified glass fiber and modified halloysite nanotubes are composited with polypropylene. Epoxy groups are introduced onto the surface of the glass fiber by treatment with γ-glycidoxypropyltrimethoxysilane, and then covalently grafted with 4-amino-2,2,6,6-tetramethylpiperidine. The modified halloysite nanotubes are then aminated with γ-aminopropyltriethoxysilane and then grafted with lipoic acid and syringic acid using a DCC/DMAP activation system to form covalent bonds that fix functional molecules, achieving multiple antioxidant protections.

Benefits of technology

It improves the mechanical properties and aging resistance of composite materials, especially their stability under thermo-oxidative and photo-oxidative aging environments, avoids the migration and volatilization of functional molecules, and constructs a comprehensive protection system covering different aging causes.

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Abstract

本发明公开了一种汽车用耐老化复合材料及其制备方法,按重量份计,包括以下原料:聚丙烯80‑90份、POE 10‑14份、改性玻璃纤维10‑15份、改性埃洛石5‑8份、相容剂4‑7份、抗氧剂0.4‑0.8份、润滑剂0.2‑0.4份。该汽车用耐老化复合材料,通过将改性玻璃纤维与改性埃洛石复合引入PP / POE基体,同时实现力学性能增强与热氧‑光氧耐老化防护,改性玻璃纤维提供宏观载荷承载骨架,改性埃洛石作为增强相兼具抗氧化功能,两者与相容剂协同作用,使复合材料在力学性能与耐老化性能上均得到提升,适用于对长期服役稳定性要求较高的汽车结构与功能零部件。
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