Cr-si co-doped dlc protective coating and method for producing the same

By constructing a Cr-Si dual-element synergistic doped DLC protective coating in surface engineering, the stability and wear resistance of the coating under high load or fretting wear conditions were improved, the friction coefficient was reduced, and the film-substrate bonding strength was increased.

CN122406154APending Publication Date: 2026-07-17NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
Filing Date
2026-06-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing diamond-like carbon films tend to accumulate extremely high internal stress during deposition, resulting in limited film-substrate bonding strength and difficulty in maintaining stability under high load or fretting wear conditions. Traditional doping modification methods are unable to achieve synergistic optimization between reducing internal stress, improving bonding strength, and low friction characteristics.

Method used

A Cr-Si dual-element synergistic doped DLC protective coating is adopted. By constructing a single-layer micro-composite structure in which a rigid CrC nanophase and a flexible Si-C amorphous network coexist, combined with a Cr/CrC gradient transition layer and a Cr/Si-DLC functional layer, the internal residual stress is released and the film-substrate bonding strength is improved.

Benefits of technology

This study improved the stability and wear resistance of the coating under high load or fretting wear conditions, reduced the coefficient of friction, and increased the film-substrate bonding strength.

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Abstract

本发明涉及表面工程与功能薄膜技术领域,具体而言,涉及一种Cr‑Si双元素协同掺杂DLC防护涂层及其制备方法。所述防护涂层自基体向外依次包括Cr / CrC梯度过渡层和Cr / Si‑DLC功能层;Cr / Si‑DLC功能层为含CrC纳米相与Si‑C非晶网络的多元复合结构;Cr元素参与形成所述CrC纳米相;Si元素参与形成Si‑C非晶网络。本防护涂层利用Cr / CrC过渡层夯实结合基础,并在单层功能层内构建CrC纳米相与Si‑C非晶网络的复合微观结构。通过刚性CrC相提升结构强度与结合力,协同柔性Si‑C网络释放内应力并降低摩擦,彻底避免了界面失效,实现了高结合力与优异摩擦学性能的综合优化。
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