An organic soil amendment suitable for use in poor soils and a method of making the same

By using a hydrochloric acid-ethanol confined dispersion system and a precise reaction process, the problems of low grafting rate and insufficient active sites of humic acid in the aminosilane modification process were solved, and an organic amendment that can be stably retained in barren soil and retain biological activity was prepared, thus achieving synergistic enhancement of soil fertility.

CN122445366APending Publication Date: 2026-07-24HUNAN SOIL & FERTILIZER INST
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUNAN SOIL & FERTILIZER INST
Filing Date
2026-06-26
Publication Date
2026-07-24

AI Technical Summary

Technical Problem

In existing technologies, the effective grafting rate of humic acid in aminosilane modification is low due to silane self-polymerization, excessive consumption of active sites, and competition for multi-step reaction windows, resulting in insufficient retention of natural activity and making it difficult to achieve long-term improvement in barren soils.

Method used

By constructing a hydrochloric acid-ethanol confined dispersion system, and employing a partial carboxyl activation strategy and a three-step precision reaction process involving pre-hydrolyzed silane, simultaneous dropwise addition, and pH program control, an organic amendment suitable for infertile soil was prepared, ensuring that humic acid remains stably on the soil particle surface and retains its biological activity.

Benefits of technology

It significantly improves the soil conditioner's adhesion and biological activity, while simultaneously increasing soil pH, organic matter content, cation exchange capacity, field water holding capacity, and nitrogen, phosphorus, and potassium nutrient availability, thus improving soil physical structure and chemical fertility and achieving an organic combination of short-term improvement effects and long-term effects.

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Abstract

The present application relates to the technical field of soil improvement, and particularly relates to an organic improver suitable for infertile soil and a preparation method thereof. The improver takes sodium humate as a basic raw material, constructs a water / ethanol suspension dispersion system through hydrochloric acid-ethanol, activates part of carboxyl groups of the sodium humate under the action of carbodiimide / N-hydroxysuccinimide, carries out grafting reaction with pre-hydrolyzed 3-aminopropyl triethoxysilane, and realizes condensation by adjusting the liquid through triethylamine and accurately controlling pH through ammonia water. The method can effectively inhibit silane self-polymerization and improve grafting efficiency, retains natural active sites of the sodium humate while enhancing the adhesion capacity of the sodium humate on the surface of soil particles. The obtained improver can significantly improve soil structure, improve water and fertilizer retention performance, and promote seed germination, and has excellent comprehensive improvement effect.
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