An alloy component on-line monitoring system with accurate phosphorus content regulation

Abstract

The utility model relates to alloy production technical field, and disclose a kind of alloy component on-line monitoring system of phosphorus content accurate regulation and control, solve the problem of current inconvenience to the quick replacement of phosphorus probe, it includes laser-induced breakdown spectroscopy detection unit and high-temperature solid electrolyte phosphorus probe, the high-temperature solid electrolyte phosphorus probe includes signal transmission section, electrolyte section and electrode section, electrolyte section is fixed in the bottom end of signal transmission section, electrode section is located in the bottom end of electrolyte section, and connecting mechanism is equipped between electrode section and electrolyte section, connecting mechanism includes the outer disc one fixed in the outside of electrolyte section, the outside fixed mounting of electrode section has outer disc two, and two side grooves one are symmetrically equipped on outer disc two;The utility model, electrode section can be fixed with outer disc two and outer disc one, then electrode section can be fixed in the bottom end of electrolyte section, otherwise the fixing of outer disc two and outer disc one can be removed, to facilitate the quick replacement of electrode section.

Description

Technical Field

[0001] This utility model belongs to the field of alloy production technology, specifically an online monitoring system for alloy composition with precise control of phosphorus content. Background Technology

[0002] In the field of alloy production, phosphorus has a significant impact on alloy performance. Appropriate amounts of phosphorus can improve wear resistance, but excessive amounts can easily cause problems such as cold brittleness. Especially in high-end manufacturing such as aerospace and nuclear power, the precise control of phosphorus content is extremely important, requiring an accuracy of ±0.002%.

[0003] High-temperature solid electrolyte phosphorus determination probes are key detection components, but they face the technical bottleneck of inconvenient replacement. Traditional phosphorus determination probes adopt an integrated structure. In alloy melts above 1600℃, the electrolyte is prone to aging and the electrodes are prone to wear. The service life is usually only 4-8 hours, and frequent replacement is required to maintain detection accuracy. However, due to its deep coupling with the sealing structure of the melting furnace, replacement requires disassembling complex flanges, cleaning high-temperature residues, and recalibrating, which makes the operation cumbersome. Utility Model Content

[0004] In view of the above situation and to overcome the shortcomings of the existing technology, this utility model provides an online monitoring system for alloy composition with precise control of phosphorus content, which effectively solves the problem of the inconvenience of quickly replacing the phosphorus determination probe.

[0005] To achieve the above objectives, this utility model provides the following technical solution: an online monitoring system for alloy composition with precise phosphorus content control, comprising a laser-induced breakdown spectroscopy detection unit and a high-temperature solid electrolyte phosphorus determination probe, wherein the high-temperature solid electrolyte phosphorus determination probe comprises a signal transmission section, an electrolyte section and an electrode section, the electrolyte section is fixed at the bottom end of the signal transmission section, the electrode section is located at the bottom end of the electrolyte section, and a connecting mechanism is provided between the electrode section and the electrolyte section;

[0006] The connecting mechanism includes an outer disk 1 fixed to the outside of the electrolyte section, an outer disk 2 fixedly installed on the outside of the electrode section, two side grooves 1 symmetrically arranged on the outer disk 2, an inner shaft rotatably connected to the inner side of each of the two side grooves 1, a rotating plate fixedly sleeved on the outer side of each of the two inner shafts, a side block fixedly connected to the side of each of the two rotating plates that are close to each other, a slot provided at the bottom of each of the two side blocks, a fixed ring fixedly sleeved on the outside of the electrolyte section located above the outer disk 1, a lifting ring provided between the fixed ring and the outer disk 1, a cylinder fixedly installed between the lifting ring and the fixed ring, the lifting ring being located between the two rotating plates and at the bottom of the two side blocks, two insert blocks symmetrically fixedly connected to the top of the lifting ring, and the two insert blocks being inserted into the two slots respectively.

[0007] Preferably, the fixing ring and the outer plate are symmetrically fixedly connected by two columns, and the lifting ring is movably sleeved on the outside of the two columns.

[0008] Preferably, the outer disk has two symmetrical side grooves, and the two rotating plates are respectively inserted into the two side grooves.

[0009] Preferably, two positioning blocks are symmetrically fixedly connected to the outer side of the second outer disk, and two positioning rods are symmetrically fixedly connected to the bottom of the first outer disk, with the two positioning blocks respectively sleeved on the outer side of the two positioning rods.

[0010] Preferably, the top of the outer plate is symmetrically and fixedly connected to two L-shaped round rods, and a sliding plate is movably sleeved between the two L-shaped round rods. The top of the sliding plate is symmetrically and rotatably connected to two movable rods, the top ends of which are rotatably connected to a lifting ring. The top of the sliding plate is symmetrically and fixedly connected to two limiting rods.

[0011] Preferably, the top of the outer disc is symmetrically fixedly connected with two limiting cylinders, the two rotating plates abut against the two limiting cylinders respectively, each of the two rotating plates is provided with a through hole, the two limiting rods pass through the two through holes respectively, and the two through holes are inserted into the two limiting cylinders respectively.

[0012] Compared with the prior art, the beneficial effects of this utility model are:

[0013] 1. The positioning block, positioning rod, outer disk two, outer disk one, inner shaft, rotating plate and side groove two can be used to position the electrolyte section and the electrode section. The outer disk two and outer disk one can be fixed by the cylinder, lifting ring, column, insert block, slot and side block. Then the electrode section can be fixed to the bottom of the electrolyte section. Conversely, the outer disk two and outer disk one can be released, so as to facilitate the quick replacement of the electrode section.

[0014] 2. Through the cooperation of the cylinder, lifting ring, column, sliding plate, L-shaped rod, limiting rod, through hole and limiting cylinder, the two rotating plates can be limited, so that the outer plate two is fixedly connected to the outer plate one, thereby facilitating the stability of the electrode section after installation. Attached Figure Description

[0015] The accompanying drawings are provided to further understand the present invention and form part of the specification. They are used together with the embodiments of the present invention to explain the present invention and do not constitute a limitation thereof.

[0016] In the attached diagram:

[0017] Figure 1 This is a schematic diagram of the online monitoring system for precise phosphorus content control of alloy composition according to this utility model;

[0018] Figure 2 This is a schematic diagram of the connection mechanism of this utility model;

[0019] Figure 3 This is a schematic diagram of the rotating plate structure of this utility model;

[0020] Figure 4 This is a schematic diagram of the lifting ring structure of this utility model.

[0021] In the diagram: 1. Laser-induced breakdown spectroscopy detection unit; 2. Connecting mechanism; 201. Outer disk one; 202. Positioning rod; 203. Positioning block; 204. Outer disk two; 205. Limiting cylinder; 206. Side groove one; 207. Side groove two; 208. Rotating plate; 209. Fixing ring; 2010. Lifting ring; 2011. Slot; 2012. Side block; 2013. Through hole; 2014. Inner shaft; 2015. Cylinder; 2016. Insert block; 2017. Limiting rod; 2018. L-shaped round rod; 2019. Slide plate; 2020. Movable rod; 2021. Column; 3. Signal transmission section; 4. Electrolyte section; 5. Electrode section. Detailed Implementation

[0022] The technical solutions of the present utility model will be clearly and completely described below with reference to the accompanying drawings of the embodiments of the present utility model. Obviously, the described embodiments are only some embodiments of the present utility model, and not all embodiments. All other embodiments obtained by those skilled in the art based on the embodiments of the present utility model without creative effort are within the protection scope of the present utility model.

[0023] Example 1, by Figure 1 This invention relates to an online monitoring system for alloy composition with precise phosphorus content control. It includes a laser-induced breakdown spectroscopy detection unit 1 and a high-temperature solid electrolyte phosphorus determination probe. The high-temperature solid electrolyte phosphorus determination probe includes a signal transmission section 3, an electrolyte section 4, and an electrode section 5. The electrolyte section 4 is fixed to the bottom end of the signal transmission section 3, and the electrode section 5 is located at the bottom end of the electrolyte section 4. A connecting mechanism 2 is provided between the electrode section 5 and the electrolyte section 4. The laser-induced breakdown spectroscopy detection unit 1 is arranged next to the alloy melting furnace. Its high-energy laser emitter emits pulsed laser light onto the surface of the molten metal. The laser interacts with the melt to generate high-temperature plasma. When the plasma de-excites, it releases... The characteristic spectra of the emitted phosphorus are acquired by a fiber optic spectrometer. By analyzing the intensity distribution of the characteristic spectral lines of phosphorus, and combining it with a partial least squares calibration model, the phosphorus content of the melt is inverted in real time. At the same time, a high-temperature solid electrolyte phosphorus determination probe is used. It adopts a sandwich structure of ZrO2-based composite electrolyte and 4CaO·P2O5 phosphorus ion conductive layer. After being inserted into the melt, it forms an electrochemical cell. Based on the Nernst equation, the phosphorus activity is calculated in real time and converted into mass fraction by measuring the potential difference between the reference electrode and the working electrode. It forms a dual-redundant sensing architecture with LIBS detection data. The data is fused by Kalman filtering algorithm to control the detection uncertainty within ±0.0015%.

[0024] Specifically, by Figure 2-4 The connecting mechanism 2 includes an outer disk 201 fixed to the outside of the electrolyte section 4, and an outer disk 204 fixedly mounted on the outside of the electrode section 5. Two side grooves 206 are symmetrically arranged on the outer disk 204. Inner shafts 2014 are rotatably connected to the inner sides of both side grooves 206. Rotating plates 208 are fixedly sleeved on the outer sides of both inner shafts 2014. Side blocks 2012 are fixedly connected to the sides of the two rotating plates 208 that are close to each other. Slots 2011 are provided at the bottom of both side blocks 2012. A fixing ring 209 located above the outer disk 201 is fixedly sleeved on the outside of the electrolyte section 4. A lifting ring 2010 is provided between the fixing ring 209 and the outer disk 201. A cylinder 2015 is fixedly mounted between the lifting ring 2010 and the fixing ring 209. Located between two rotating plates 208, and with the lifting ring 2010 located at the bottom of two side blocks 2012, two insert blocks 2016 are symmetrically fixedly connected to the top of the lifting ring 2010. The two insert blocks 2016 are respectively inserted into two slots 2011. Two columns 2021 are symmetrically fixedly connected between the fixing ring 209 and the outer plate 201. The lifting ring 2010 is movably sleeved on the outside of the two columns 2021. Two side grooves 207 are symmetrically provided on the outer plate 201. The two rotating plates 208 are respectively inserted into the two side grooves 207. Two positioning blocks 203 are symmetrically fixedly connected to the outside of the outer plate 204. Two positioning rods 202 are symmetrically fixedly connected to the bottom of the outer plate 201. The two positioning blocks 203 are respectively sleeved on the outside of the two positioning rods 202.

[0025] In use, first place electrode segment 5 at the bottom of electrolyte segment 4, so that the two positioning blocks 203 are respectively fitted onto the outside of the two positioning rods 202. Then rotate the two rotating plates 208 until the two rotating plates 208 are respectively inserted into the two side slots 207. At this time, the two insert blocks 2016 are respectively located directly below the two slots 2011. Then start the cylinder 2015 to drive the lifting ring 2010 to slide upward along the two columns 2021 and drive the two insert blocks 2016 to rise until the lifting ring 2010 abuts against the two side blocks 2012. At the same time, the two insert blocks 2016 are respectively inserted into the two slots 2011, fixing the outer disk 204 and the outer disk 1 201, and fixing the electrode segment 5 and electrolyte segment 4. When the two insert blocks 2016 descend and are removed from the two slots 2011, the fixing of the outer disk 204 and the outer disk 1 201 can be released, and finally the electrode segment 5 can be quickly replaced.

[0026] Specifically, by Figure 4As shown, the top of the outer disk 201 is symmetrically and fixedly connected to two L-shaped round rods 2018, and a sliding plate 2019 is movably sleeved between the two L-shaped round rods 2018. The top of the sliding plate 2019 is symmetrically and rotatably connected to two movable rods 2020, and the top of the two movable rods 2020 is rotatably connected to the lifting ring 2010. The top of the sliding plate 2019 is symmetrically and fixedly connected to two limiting rods 2017, and the top of the outer disk 201 is symmetrically and fixedly connected to two limiting cylinders 205. Two rotating plates 208 abut against the two limiting cylinders 205 respectively. Both rotating plates 208 are provided with through holes 2013. The two limiting rods 2017 pass through the two through holes 2013 respectively, and the two through holes 2013 are inserted into the two limiting cylinders 205 respectively.

[0027] In operation, when the cylinder 2015 drives the lifting ring 2010 to slide upward along the two columns 2021, the two movable rods 2020 drive the slide plate 2019 to slide along the two L-shaped round rods 2018, and drive the two limiting rods 2017 to move, so that the two limiting rods 2017 pass through the two through holes 2013 respectively. When the two inserts 2016 are inserted into the two slots 2011 respectively, the two limiting rods 2017 are inserted into the two limiting cylinders 205 respectively, limiting the two rotating plates 208, so that the outer disk 204 is fixedly connected to the outer disk 1 201, and finally ensuring the stability of the electrode segment 5 after installation.

Claims

1. An alloy composition on-line monitoring system with accurate phosphorus content regulation, comprising a laser-induced breakdown spectroscopy detection unit (1) and a high-temperature solid electrolyte phosphorus determination probe, characterized in that: The high-temperature solid electrolyte phosphorus determination probe includes a signal transmission section (3), an electrolyte section (4) and an electrode section (5). The electrolyte section (4) is fixed at the bottom of the signal transmission section (3), the electrode section (5) is located at the bottom of the electrolyte section (4), and a connecting mechanism (2) is provided between the electrode section (5) and the electrolyte section (4). The connecting mechanism (2) includes an outer disk one (201) fixed to the outside of the electrolyte section (4), an outer disk two (204) fixedly installed on the outside of the electrode section (5), two side grooves one (206) symmetrically provided on the outer disk two (204), an inner shaft (2014) rotatably connected to the inner side of each of the two side grooves one (206), a rotating plate (208) fixedly sleeved on the outer side of each of the two inner shafts (2014), a side block (2012) fixedly connected to the side of each of the two rotating plates (208) that are close to each other, and a slot (2011) provided at the bottom of each of the two side blocks (2012), the outer side of the electrolyte section (4) A fixed ring (209) is fixedly connected to the side of the outer plate (201) and a lifting ring (2010) is provided between the fixed ring (209) and the outer plate (201). A cylinder (2015) is fixedly installed between the lifting ring (2010) and the fixed ring (209). The lifting ring (2010) is located between the two rotating plates (208) and at the bottom of the two side blocks (2012). Two inserts (2016) are symmetrically fixedly connected to the top of the lifting ring (2010). The two inserts (2016) are respectively inserted into the two slots (2011).

2. The online monitoring system of alloy composition with precise control of phosphorus content according to claim 1, characterized in that: The fixed ring (209) and the outer plate (201) are symmetrically fixedly connected by two columns (2021), and the lifting ring (2010) is movably sleeved on the outside of the two columns (2021).

3. The alloy composition online monitoring system with precise control of phosphorus content according to claim 1, characterized in that: The outer disk (201) is symmetrically provided with two side grooves (207), and two rotating plates (208) are respectively inserted into the two side grooves (207).

4. The alloy composition online monitoring system with precise control of phosphorus content according to claim 1, characterized in that: Two positioning blocks (203) are symmetrically fixedly connected to the outer side of the second outer disc (204), and two positioning rods (202) are symmetrically fixedly connected to the bottom of the first outer disc (201). The two positioning blocks (203) are respectively sleeved on the outer side of the two positioning rods (202).

5. The online monitoring system for precise phosphorus content control of alloy composition according to claim 1, characterized in that: The top of the outer disc (201) is symmetrically and fixedly connected to two L-shaped round rods (2018), and a sliding plate (2019) is movably sleeved between the two L-shaped round rods (2018). The top of the sliding plate (2019) is symmetrically and rotatably connected to two movable rods (2020), and the top of the two movable rods (2020) is rotatably connected to the lifting ring (2010). The top of the sliding plate (2019) is symmetrically and fixedly connected to two limiting rods (2017).

6. The online monitoring system of alloy composition with precisely controlled phosphorus content according to claim 1, characterized in that: The top of the outer disc (201) is symmetrically fixedly connected to two limiting cylinders (205). Two rotating plates (208) abut against the two limiting cylinders (205) respectively. Both rotating plates (208) are provided with through holes (2013). Two limiting rods (2017) pass through the two through holes (2013) respectively, and the two through holes (2013) are inserted into the two limiting cylinders (205) respectively.

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