Cellulose-based packaging material, products, machines
A multilayer cellulose-based packaging material with a welded rim addresses the need for structurally robust, compostable capsules with enhanced sealing and barrier properties, ensuring efficient brewing and rapid decomposition.
Patent Information
- Application Number
- DE202025102844
- Authority / Receiving Office
- DE · DE
- Patent Type
- Utility models
- Current Assignee / Owner
- Filing Date
- 2025-05-22
- Publication Date
- 2025-12-24
- Estimated Expiration
- 2035-05-31
AI Technical Summary
There is a need for a biodegradable, compostable capsule material that maintains structural integrity and barrier properties under mechanical stress, while also being suitable for high-speed production and rapid decomposition in industrial composting conditions.
A multilayer packaging material composed of cellulose-based layers, including a moisture barrier varnish, adhesive, film, and metallized paper, designed for capsules that ensures structural integrity, barrier properties, and rapid compostability, with a welded rim for enhanced sealing and mechanical strength.
The material achieves high mechanical flexibility, rapid compostability, and effective sealing, ensuring consistent brewing performance and environmental sustainability, meeting ISO 14855-1 standards for decomposition and being fully recyclable.
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Abstract
Description
AREA AND BACKGROUND OF THE INVENTION
[0001] The present invention relates generally to a cellulose-based packaging material made from pulp and / or paper, products and related machinery.
[0002] There has long been a need for a biodegradable, compostable capsule material suitable for the high mechanical demands of capsule manufacturing. The material must be elongated without tearing, maintain sufficient structural integrity during use, and decompose rapidly under industrial composting conditions. Furthermore, the manufacturing process should allow for efficient capsule production while preserving the capsules' barrier properties, particularly in beverage or food preparation systems. SUMMARY OF THE INVENTION
[0003] According to an object of the invention, a manufactured product and a machine for manufacturing such a product with home-compostable and recyclable multilayer packaging paper and products thereof, material made of cellulose and / or pulp designed to hold edible foodstuffs, is to be disclosed, wherein the material comprises the following groups: a layer with a moisture barrier varnish selected from group B, a layer comprising an adhesive selected from group D, a layer comprising a film selected from group E, and an innermost layer comprising metallized paper cellulose selected from group F.
[0004] According to a further object of the invention, the packaging paper material defined above is to be disclosed, wherein the packaging material further comprises one or more of the following layers: a layer comprising a printing ink selected from group A, a layer comprising printing inks selected from group C.
[0005] According to a further object of the invention, the packaging paper material defined above is to be disclosed, wherein the material comprises a first layer comprising a printing ink selected from group A, a second layer comprising a moisture barrier varnish selected from group B, a third layer comprising printing inks selected from group C, a fourth layer comprising an adhesive selected from group D, a fifth layer comprising a film selected from group E, and a sixth and innermost layer comprising metallized paper cellulose selected from group F. BRIEF DESCRIPTION OF THE FIGURES Fig. Figure 1 shows the perforation force measurements for dry and wet capsules compared to a reference. The data show increased perforability with wet capsules, which require lower average forces for both partial and complete perforation. In particular, it shows Fig. 1. Perforation force measurements for dry and wet capsules compared to a reference. Dry capsules required an average force of 12.2 ± 0.5 kg for partial perforation (A and C) and 13.1 ± 0.5 kg for complete perforation (positions B and D). In contrast, wet capsules showed an increased tendency to perforate, requiring lower forces of 8.1 ± 1 kg for partial perforation (position F) and 10.1 ± 1 kg for complete perforation (position E). These results demonstrate that moisture content significantly influences the mechanical perforation resistance of the capsules. Fig. Figure 2 shows a tensile force-displacement curve of a welded two-layer paper strand under dry conditions with a peak tensile force of 16.5 N / mm. In particular, it shows Fig. 2. A tensile force-displacement curve obtained during a strain test on a single strand of welded two-layer paper. The test yielded a peak force of 16.5 N / mm. Fig. Figure 3 shows a tensile force-displacement curve of the welded two-layer paper strand after a soaking time of 30 seconds in 90°C warm water, which shows a reduced peak force of 4.6 N / mm. In particular, it shows Fig. 3. A tensile force-displacement curve for a single strand of welded two-layer paper after a soaking time of 30 seconds in 90°C warm water. The test yielded a peak force of 4.6 N / mm. Fig. Figure 4 shows a tensile force-displacement curve for an unwelded, single-layer paper tensile strand under dry conditions with a measured peak force of 14.4 N / mm. In particular, it shows Fig. 4. A tensile force-displacement curve obtained during a strain test on a tensile member made of unwelded single-layer paper. The test yielded a peak force of 14.4 N / mm. Fig. Figure 5 shows a tensile force-displacement curve of the unwelded single-layer paper tensile strand after a soaking time of 30 seconds in 90°C warm water, during which a peak force of 14.4 N / mm² was maintained. In particular, it shows Fig. 5. A tensile force-displacement curve obtained during a tensile test on a tensile strand of unwelded single-layer paper after a soaking time of 30 seconds in 90°C warm water. The test yielded a peak force of 14.4 N / mm. Fig. Figure 6 shows Fourier-transform infrared spectroscopy (FTIR) spectra for the internal compositions of the multilayer structure. Characteristic absorption peaks are identified, providing confirmation of the material composition at the molecular level using µ-ATR techniques. In particular, Fig. 6, that the internal composition has characteristic Fourier-transform infrared spectroscopy peaks (FTIR peaks) at the following wavenumbers: 528.76 cm -1 , 598.75 cm -1 , 656.17 cm -1 893.00 cm -1 , 1016.01 cm -1 , 1234.94 cm -1 , 1359.84 cm -1 , 1409.39 cm -1 , 1655.06 cm -1 , 1737.53 cm -1 , 2853.02 cm -1 , 2922.65 cm -1 and 3231.62 cm -1 The sample was analyzed using µ-ATR technology with crystal diamond and FT-IR investigations in the range of 4000 to 400 cm. -1 subjected to. Fig. Figure 7 shows the Fourier-transform infrared spectroscopy (FTIR) spectra for the outer compositions of the multilayer structure. Characteristic absorption peaks are identified, providing confirmation of the material composition at the molecular level using µ-ATR techniques. In particular, Fig. 7, that the external composition has characteristic Fourier-transform infrared spectroscopy peaks (FTIR peaks) at the following wavenumbers: 506.28 cm -1 , 556.40 cm -1 , 982.88 cm -1 , 1159.69 cm -1 , 1313.31 cm -1 , 1429.02 cm -1 , 1735.13 cm -1 , 2853.23 cm -1 , 2922.05 cm -1 and 3325.49 cm -1 The sample was analyzed using µ-ATR technology with crystal diamond and FT-IR investigations in the range of 4000 to 400 cm. -1 subjected to. DETAILED DESCRIPTION OF PREFERRED EXECUTION FORMS
[0006] The present invention addresses this unmet need with a novel compostable paper material intended for use in the manufacture of capsules, particularly those compatible with coffee machines. The capsule consists of two layers of multilayer paper processed to form both the capsule body and a cavity for holding beverage or food ingredients such as roasted and ground coffee. A key feature is the rim, created by welding the two layers together, which exhibits a treated area with reduced porosity and improved physical properties such as increased stiffness and brittleness. Crucially, the paper material possesses a unique degree of elongation—approximately 15% in the grain direction and 5% in the transverse direction—enabling the production of clearly defined capsule shapes without compromising structural integrity.This mechanical flexibility, combined with compatibility with forming processes, improves barrier properties by reducing water absorption and enhancing sealing performance during brewing. In addition to its structural advantages, the capsule meets the ISO 14855-1:2012 standard for compostability, achieving over 90% decomposition within six months and being fully recyclable, thus offering a comprehensive solution for both functional and environmental requirements.
[0007] It will now be referred to as Fig. Reference is made to Figures 1 to 7. The figures shown herein are examples of embodiments illustrating products and compositions as a series of approaches to implementing the described systems of various embodiments of the present invention. Variants and equivalent methods for achieving the same objectives are conceivable and may be applied, reflecting different adaptations within the scope of the embodiments.
[0008] Fig. Figure 1 shows the perforation force measurements for dry and wet capsules compared to a reference. The data show increased perforability with wet capsules, which require lower average forces for both partial and complete perforation. In particular, it shows Fig. 1. Perforation force measurements for dry and wet capsules compared to a reference. Dry capsules required an average force of 12.2 ± 0.5 kg for partial perforation (A and C) and 13.1 ± 0.5 kg for complete perforation (positions B and D). In contrast, wet capsules showed an increased tendency to perforate, requiring lower forces of 8.1 ± 1 kg for partial perforation (position F) and 10.1 ± 1 kg for complete perforation (position E). These results demonstrate that moisture content significantly influences the mechanical perforation resistance of the capsules. Fig. Figure 2 is a tensile force-displacement curve of a welded two-layer paper strand under dry conditions with a peak tensile force of 16.5 N / mm. In particular, it shows Fig. 2. A tensile force-displacement curve obtained during a strain test on a single strand of welded two-layer paper. The test yielded a peak force of 16.5 N / mm. Fig. Figure 3 shows a tensile force-displacement curve of the welded two-layer paper strand after a soaking time of 30 seconds in 90°C warm water, where a reduced peak force of 4.6 N / mm was observed. In particular, it shows Fig. 3. A tensile force-displacement curve for a single strand of welded two-layer paper after a soaking time of 30 seconds in 90°C warm water. The test yielded a peak force of 4.6 N / mm. Fig. Figure 4 shows a tensile force-displacement curve for an unwelded, single-layer paper tensile strand under dry conditions with a measured peak force of 14.4 N / mm. In particular, it shows Fig. 4. A tensile force-displacement curve obtained during a strain test on a tensile member made of unwelded single-layer paper. The test yielded a peak force of 14.4 N / mm. Fig. Figure 5 shows a tensile force-displacement curve of the unwelded single-layer paper tensile strand after a soaking time of 30 seconds in 90°C warm water, maintaining a peak force of 14.4 N / mm. In particular, it shows Fig. 5. A tensile force-displacement curve obtained during a tensile test on a tensile strand of unwelded single-layer paper after a soaking time of 30 seconds in 90°C warm water. The test yielded a peak force of 14.4 N / mm. Fig. Figure 6 shows Fourier-transform infrared spectroscopy (FTIR) spectra for the internal compositions of the multilayer structure. Characteristic absorption peaks are identified, providing confirmation of the material composition at the molecular level using µ-ATR techniques. In particular, Fig. 6, that the internal composition has characteristic Fourier-transform infrared spectroscopy peaks (FTIR peaks) at the following wavenumbers: 528.76 cm -1 , 598.75 cm -1 , 656.17 cm -1 893.00 cm -1 , 1016.01 cm -1 , 1234.94 cm -1 , 1359.84 cm -1 , 1409.39 cm -1 , 1655.06 cm -1 , 1737.53 cm -1 , 2853.02 cm -1 , 2922.65 cm -1 and 3231.62 cm -1 The sample was analyzed using µ-ATR technology with crystal diamond and FT-IR investigations in the range of 4000 to 400 cm. -1 subjected to. Fig. Figure 7 shows Fourier-transform infrared spectroscopy (FTIR) spectra for the outer compositions of the multilayer structure. Characteristic absorption peaks were identified, providing confirmation of the material composition at the molecular level using µ-ATR techniques. In particular, Fig. 7, that the external composition has characteristic Fourier-transform infrared spectroscopy peaks (FTIR peaks) at the following wavenumbers: 506.28 cm -1 , 556.40 cm -1 , 982.88 cm -1 , 1159.69 cm -1 , 1313.31 cm -1 , 1429.02 cm -1 , 1735.13 cm -1 , 2853.23 cm -1 , 2922.05 cm -1 and 3325.49 cm -1 The sample was analyzed using µ-ATR technology with crystal diamond and FT-IR investigations in the range of 4000 to 400 cm. -1 subjected to.
[0009] In this production process, particular attention is paid to the formation of the weld seam during the stretching process. This seam is crucial for both the strength and impermeability of the packaging. During stretching, the edges of the paper are melted to form a uniform seam that bonds the fibers and ensures a strong weld that is resistant to moisture and air. The seam increases mechanical strength and prevents tearing and deformation during handling, transport, and storage. It also improves impermeability, preventing the penetration of moisture, air, and contaminants, which is essential for packaging sensitive products.
[0010] The welded rim also plays a crucial role in improving the capsule's seal when inserted into the coffee machine. By ensuring a particularly secure seal, the rim prevents air from escaping during the coffee extraction process. This tight seal guarantees optimal pressure retention, resulting in a more controlled and consistent brewing process. Consequently, the coffee is extracted more efficiently, leading to a richer, fuller flavor and a superior brewing experience.
[0011] The following section describes a multi-layered packaging system consisting of compostable and food-grade materials, with each layer selected from an approved group of commercially available products with proven environmental compatibility. The structure is designed to balance printability, barrier properties, adhesion, and mechanical integrity, while maintaining compliance with international standards for compostability and food contact.
[0012] It will now be on Fig. 1. Referenced. To evaluate the mechanical perforation resistance of capsule structures, a series of tests were conducted under dry and wet conditions. In the dry state, the capsules required an average force of 12.2 ± 0.5 kg for partial perforation (positions A and C) and 13.1 ± 0.5 kg for complete perforation (positions B and D). In contrast, wet capsules exhibited lower resistance, with partial perforation occurring at 8.1 ± 1 kg (position F) and complete perforation at 10.1 ± 1 kg (position E). These results demonstrate that moisture content significantly reduces the mechanical strength of the capsule, a critical factor for applications requiring structural integrity under humid conditions.
[0013] It will now be referred to as Fig. Reference is made to Figures 2 to 5, which illustrate the properties of various paper configurations under tensile stress. The present invention relates to a multilayer paper product designed to have controlled tensile elongation properties in both the grain direction (MD) and the cross direction (CD). In particular, the paper has an elongation at break of approximately 15% in MD and 5% in CD, enabling it to withstand directed mechanical loads without loss of structural integrity. These properties are achieved through precise fiber alignment, bonding techniques, and multilayer compositions.
[0014] It will now be on Fig. Reference is made to Figure 6, which shows an FT-IR spectral analysis of the inner and outer layers of the multilayer paper. This analysis confirms the chemical composition of the material by means of µ-ATR testing between 4000 and 400 cm⁻¹. -1The paper product according to the invention is over 90% compostable and recyclable and, unlike prior art solutions such as those disclosed in WO2024100283A1, combines high elongation with ecological sustainability. The result is a structurally robust and environmentally friendly material that is ideally suited for packaging applications requiring flexibility, durability, and compliance with environmental standards. Group A - Printing ink layer
[0015] The first optional layer comprises compostable inks selected from an approved group of environmentally friendly formulations. These include the FLEXO UV LED FP 285 ink series (Colorgraf SpA, Italy), REVALUX® 156-3 food-contact approved inks from Rezino (Israel), certified under reference number TA8012004452 according to OK Compost INDUSTRIAL, SunUno Solvent Flexo inks (Sun Chemical, USA), compostable flexo inks (Siegwerk, Germany), Bio-Flexo inks (Flisnt Group, USA), environmentally friendly water-based inks (Toyo Ink SC Holdings Co., Ltd., Japan), plant-based inks (Eco-Products, USA), NatureFlex inks (Futamura, Japan), GreenPrint inks (BioPak, Australia), Vegware inks (Vegware, UK), and Earthlnks (Earthpack, USA).These printing inks contain compostable polymers and dyes with various CAS numbers depending on the specific formulations and may include natural resins, plant-based solvents, or biodegradable acrylic resins. They are applied at a dry weight concentration of approximately 0.75% to 1.25%, based on the total packaging material, with the total concentration of all printing inks limited to 3.75% to 6.25%. All Group A printing inks are certified for industrial composting and approved for food contact applications in accordance with applicable local standards (e.g., FDA, EU Regulation 10 / 2011). Group B - Moisture barrier coating
[0016] The second layer comprises a compostable moisture barrier lacquer selected from a group that includes WATER REPELLENT LAQUER LAC500 (Chemiprint LLP, Israel), BioBarrier WB-100 (EcoCoat Technologies, USA), CompostCoat MB-200 (GreenPack Solutions, Germany), AquaShield 3000 (BioLacquer Inc., Canada), EcoSeal 500 (NatureCoat Ltd., UK), PlantGuard Lacquer (Swisspac, India), GreenShield Coating (Pouchmakers, Canada), EcoBarrier Lacquer (Footprint, USA), NatureCoat Aqua (Vegware, UK), and BioLac 100 (BioPak, Australia). These coatings typically contain biodegradable acrylic emulsions, water-based dispersions, and natural waxes or starches, with active barrier agents present at concentrations of approximately 0.35% by weight. The application weights range from 0.375 g / m² 2 up to 0.625 g / m² 2. All coatings in this group A are certified as compostable and designed according to ASTM D6400, EN 13432 or equivalent standards for food-safe barrier properties.
[0017] OPV overprint varnish is particularly suitable as a varnish for use in controlling water penetration into paper, especially when a pigment-free (transparent) varnish is used that is approved for contact with food, such as overprint varnish certified for direct contact with food on rigid or flexible food packaging made from the following materials: commercially available products, e.g., JONCRYL® DFC 3025 from Ultrus (USA) for cardboard, MDF, PE (polyethylene), PP (polypropylene) and PET (polyethylene terephthalate), VARNIPACK FOODGRADE, VARNIPflex FOODGRADE from Fakolith Chemical Systems (Spain), water-based OPV ECO-1630 from Camprint (Israel). Group C - Secondary ink layer
[0018] The third layer comprises a second ink application consisting of black, yellow, red, and blue inks selected from the same color groups listed in Group A. These are applied at a weight of approximately 0.375 g / m². 2 up to 0.625 g / m² 2 Applied and used for functional or decorative purposes, such as branding or instructions for use, the printing inks remain compostable and meet food contact safety requirements with common formulations of natural pigments or biodegradable resin-based dyes. They comply with compostability and migration limits according to ISO 17088 and the legal requirements for food packaging in the USA, the EU, and Japan. Group D - Adhesive layer
[0019] The fourth layer comprises a compostable adhesive, selected from Herberts-1K-LF 190 X3 (Bostik SA, France), compostable adhesives from Sun Chemical (USA), BioAdhesive 2100 (GreenBond Adhesives, USA), EcoGlue 500 (NatureAdhesives Ltd., UK), CompostBond 300 (BioStick GmbH, Germany), AquaBond 100 (EcoAdhere Inc., Canada), PlantStick Adhesive (Swisspac, India), GreenHold Adhesive (Pouchmakers, Canada), EcoGrip 200 (Footprint, USA), NatureBond Adhesive (Vegware, UK), and BioSeal 400 (BioPak, Australia). These adhesives are typically water-based or bio-based polyurethane, starch, or dextrin formulations whose biodegradability has been demonstrated according to ISO 14855-1:2012 or ASTM D6866. For an application with a coating weight of approximately 3.75 g / m² 2 up to 6.25 g / m² 2 They are certified as compostable and suitable for direct contact with food. Group E - Foil layer
[0020] The fifth layer comprises a biodegradable film selected from cellulose-based products, such as NatureFlex NKME (Futamura, Japan) or NatureFlex NK (Futamura, Japan), certified under reference number TA8021601613 according to OK Compost HOME, with a thickness of approximately 63.75 µm to 106.25 µm. Other suitable alternatives include Cellophane MST (Futamura), BioFilm CF-100 (GreenWrap Films, USA), EcoCell Film (NatureFilms Ltd., UK), CompostFilm 200 (BioPack GmbH, Germany), Plantmade™ Film (Swisspac, India), GreenWrap Film (Pouchmakers, Canada), EcoFiber Film (Footprint, USA), Vegware Film (Vegware, UK), and BioFlex Film (BioPak, Australia). Additionally, cellulose films coated on the inside and outside with polyvinylidene chloride (PVDC) can be used. PVDC has the CAS number 25014-34-6 and the IUPAC name poly(1,1-dichloroethylene).These films offer oxygen and moisture barrier properties and are certified for compostability and food contact in accordance with applicable standards such as EN 13432, ASTM D6400 and FDA 21 CFR Part 177. Group F - Metallized paper layer (sixth and innermost layer)
[0021] The sixth and innermost layer consists of a metallized paper substrate selected from a group that includes the home-compostable Advantage Formable (Mondi Group, Austria), METIVO VB and METIVO (Nissha Metallizing Solutions, Belgium), EcoMetallized Paper (GreenPack Solutions, Germany), BioMetal Paper (BioWrap Inc., Canada), CompostMetal 100 (BioPack GmbH, Germany), NatureMetal Foil (EcoFoil Ltd., UK), Barrier Paper (Nissha Metallizing Solutions), Biowrap Kraft (APL Packaging, France), and Timber Wrap (Biowrap, New Zealand). These materials typically contain vacuum-metallized aluminum or alternative coatings with vapor permeability barriers (MVTR < 1 g / m²). 2 / day) and are applied to kraft paper or fiber-based substrates. Depending on the specific formulation, they can meet compostability or recycling standards, including DIN CERTCO or FSC chain-of-custody certifications. Many options comply with global food safety regulations and are suitable for flexible packaging applications with direct or indirect food contact.
[0022] All trademarks and brand names refer to commercially available products. Although the present invention has been described here in connection with certain disclosed embodiments, many modifications and changes can be made to these embodiments. For example, different types of end effectors can be used. Furthermore, materials other than those disclosed for certain components can be used. The preceding description and the following claims are intended to cover all such modifications and changes.
[0023] All patents, publications, or other disclosure materials that are to be incorporated herein, in whole or in part, by reference, are incorporated herein only to the extent that the incorporated materials do not conflict with existing definitions, statements, or other disclosure materials set forth in this disclosure. As such, and to the extent necessary, the disclosure expressly set forth herein supersedes all conflicting materials incorporated herein by reference. All materials or parts thereof that are to be incorporated herein by reference but conflict with existing definitions, statements, or other disclosure materials set forth herein are incorporated only to the extent that there is no conflict between the incorporated material and the existing disclosure material. QUOTES INCLUDED IN THE DESCRIPTION
[0000] This list of documents cited by the applicant was automatically generated and is included solely for the reader's convenience. The list is not part of the German patent or utility model application. The DPMA accepts no liability for any errors or omissions. Cited patent literature
[0000] WO 2024100283A1
[0014] Cited non-patent literature
[0000] ISO 14855-1:2012
[0006]
Claims
[1] Manufactured product comprising (i) home compostable and / or (ii) recyclable or otherwise non-toxic multilayer packaging material made of paper, pulp or cellulose-based materials designed to hold edible foodstuffs, the material comprising the following groups: a layer comprising a moisture barrier lacquer selected from group B, a layer comprising an adhesive selected from group D, a layer comprising a film selected from group E, and an innermost layer of metallized paper selected from group F. [2] Packaging paper material according to claim 1 and any of the dependent claims, wherein the packaging material further comprises one or more of the following layers: a layer comprising a printing ink selected from group A, a layer comprising printing inks selected from group C. [3] Packaging paper material according to claim 1 and any of the dependent claims, wherein the material comprises: a first layer comprising a printing ink selected from group A, a second layer comprising a moisture barrier lacquer selected from group B, a third layer comprising printing inks selected from group C, a fourth layer comprising an adhesive selected from group D, a fifth layer comprising a film selected from group E, a sixth and innermost layer comprising metallized paper selected from group F. [4] Packaging paper material according to claim 1 and any of the dependent claims, wherein the fifth layer comprises a cellulose film coated on its inner and outer surfaces with polyvinylidene chloride (PVDC). [5] Packaging paper material according to claim 4, wherein the polyvinylidene chloride coating (PVDC coating) constitutes between 0.01% and 1.0% of the dry weight of the total weight of the fifth layer. [6] Packaging paper material according to claim 4, wherein the polyvinylidene chloride coating (PVDC coating) constitutes between 1.0% and 10.0% of the dry weight of the total weight of the fifth layer. [7] Packaging paper material according to claim 4, wherein the polyvinylidene chloride coating (PVDC coating) constitutes between 10.0% and 30.0% of the dry weight of the total weight of the fifth layer. [8] Packaging paper material according to claim 1 and any dependent claim, wherein the sixth and innermost layer comprises metallized paper consisting of an element selected from the group consisting of the home compostable, commercially available Advantage Formable from Mondi Group (Austria), the commercially available METIVO VB from Nissha Metallizing Solutions (Belgium), the EcoMetallized Paper from GreenPack Solutions (Germany), the commercially available BioMetal Paper from BioWrap Inc. (Canada), the commercially available CompostMetal 100 from BioPack GmbH (Germany), the NatureMetal Foil from EcoFoil Ltd. (Great Britain), the commercially available METIVO from Nissha Metallizing Solutions (Belgium), the Barrier Paper from Nissha Metallizing Solutions (Belgium), the commercially available Biowrap Kraft from APL Packaging (France), the commercially available Timber Wrap from Biowrap (New Zealand) and any combination thereof. [9] Packaging paper material according to claim 1 and any of the dependent claims, wherein the first layer comprises a 15-25 µm thick film consisting of 21.5% commercially available NatureFlex™ NKME from Futamura, certified under reference number TA8021601613 according to OK compost HOME, with a maximum certified thickness of 85 µm. [10] Packaging paper material according to claim 1 and any of the dependent claims, wherein the first layer comprises a 15-50 µm thick film consisting of 21.5% NatureFlex™ NK from Futamura. [11] Packaging paper material according to claim 1 and any of the dependent claims, wherein a 5 g / m² layer is placed between the first and second layers 2 A thick adhesive layer is arranged, comprising 3.7% Herberts-1K-LF 190 X3 from Bostik SA, which is suitable for laminating paper onto plastic films. [12] Packaging paper material according to claim 1 and any of the dependent claims, wherein the second layer weighs 100 g / m² 2 The paper consists of 74.1% home compostable Advantage Formable from Mondi, which is characterized by its thermoformability and suitability for food packaging applications. [13] Packaging paper material according to claim 1 and any of the dependent claims, wherein the second layer further comprises a total of 0.5 g / m² 2 Printing inks containing 0.35% black, yellow, red and blue printing inks. [14] Packaging paper material according to claim 1 and any of the dependent claims, wherein the second layer has a density of 0.5 g / m² 2 coated with a thick layer of lacquer containing 0.35% commercially available WATER REPELLENT LAQUER LAC500 from Chemiprint LLP. [15] Packaging paper material according to claim 1 and any of the dependent claims, wherein the printing inks applied to the second layer comprise the commercially available FLEXO UV LED FP 285 INKS SERIES from Colorgraf SpA, which are certified under reference number TA8012004452 according to OK compost INDUSTRIAL, with a maximum concentration of each color pigment not exceeding 1.0% of the dry weight based on the total packaging, and a total printing ink concentration not exceeding 5% of the dry weight based on the total packaging, as specified in report no. 65003462-2024-AG-0339pre. [16] Packaging paper material according to claim 1 and any of the dependent claims, wherein the paper has an elongation of up to 15% in the milling direction (MD), thereby improving its ability to adapt to different shapes during processing and in end applications. [17] Packaging paper material according to claim 1 and any of the dependent claims, wherein the paper has an elongation of up to 10% in the transverse direction (CD), which contributes to its overall flexibility and formability. [18] Packaging paper material according to claim 1 and any of the dependent claims, wherein it is compatible with both modified atmosphere packaging (MAP) and vacuum packaging systems. [19] Packaging paper material according to claim 1 and any of the dependent claims, wherein the increased MD extensibility is achieved by mechanical processes such as the Clupak process. [20] Packaging paper material according to claim 1 and any of the dependent claims, wherein the improved CD stretchability is achieved by the use of techniques such as the Papermorphosis system. [21] Packaging paper material according to claim 1 and any of the dependent claims, wherein the combined MD and CD elongabilities contribute to a total biaxial elongation of up to 25%, which simplifies its use in applications requiring high conformability and durability. [22] Packaging paper material according to claim 1 and any of the dependent claims, wherein the packaging paper material has compostability properties according to DIN EN 13432:2002, including a solids residue of 92.67 ± 0.78 g / 100 g, an ash content at 550°C of 1.02 ± 0.18 g / 100 g and a volatile solids content of 91.65 ± 0.80 g / 100 g. [23] Packaging paper material according to claim 1 and any dependent claim, wherein the heavy metal concentrations of the packaging paper material do not exceed the following limits: arsenic undetectable, cadmium 0.091 ± 0.024 mg / kg, cobalt 0.057 ± 0.030 mg / kg, chromium 0.46 ± 0.14 mg / kg, mercury undetectable, molybdenum 0.068 ± 0.032 mg / kg, nickel 0.266 ± 0.083 mg / kg, lead 0.296 ± 0.074 mg / kg, copper 7.9 ± 2.2 mg / kg, selenium 0.078 ± 0.034 mg / kg and zinc 12.9 ± 3.1 mg / kg, determined according to method MP 1664 rev June 2022. [24] Packaging paper material according to claim 1 and any of the dependent claims, wherein the material has compostability according to DIN EN 13432:2002, wherein seed trays were prepared with 25% and 50% sample compost mixed with reference soil, 100 seeds of Lepidium sativum and Triticum aestivum were sown per tray, and the trays were kept under controlled conditions at a temperature of 22°C ± 3°C, a relative humidity of 60% ± 10%, a minimum photoperiod of 16 hours, and a light intensity of 7000 lux, with periodic relocation to minimize fluctuations. [25] Packaging paper material according to claim 1 and any of the dependent claims, wherein, after a 14-day observation period following 50% plant emergence in control plants, the test results showed that for Lepidium sativum the germination rates were 102.8% and 102.1% respectively and the biomass fractions were 103.0% and 104.7% respectively for sample compost concentrations of 50% and 25%, and for Triticum aestivum the germination rates were 107.9% and 111.4% respectively and the biomass fractions were 103.1% and 93.6% respectively for sample compost concentrations of 50% and 25%, wherein all values exceeded the threshold of >90% specified in DIN EN 13432:2002, indicating the absence of phytotoxic effects. [26] Packaging paper material according to claim 1 and any of the dependent claims, wherein the oxygen permeability (O2TR), measured at 23 ± 1°C and a relative humidity of 30 ± 5% and determined according to ASTM F1307-20, is less than 0.001 cm 3 / (Packaging × 24 h × Area) is. [27] Packaging paper material according to claim 1 and any of the dependent claims, wherein the oxygen permeability (O2TR), measured at 23 ± 1°C and a relative humidity of 30 ± 5% and determined according to ASTM F1307-20, is less than 0.01 cm 3 / (Packaging × 24 h × Area) is. [28] Packaging paper material according to claim 1 and any of the dependent claims, wherein the oxygen permeability (O2TR), measured at 23 ± 1 °C and a relative humidity of 30 ± 5 % and determined according to ASTM F1307-20, is less than 0.1 cm 3 / (Packaging × 24 h × Area) is. [29] Packaging paper material according to claim 1 and any of the dependent claims, wherein the first layer has a nominal thickness of 19 ± 1 µm and a basis weight of 29 ± 1.5 g / m² 2 has. [30] Packaging paper material according to claim 1 and any of the dependent claims, wherein the adhesive layer comprises commercially available Herberts-1 K-LF 190 X3 from Bostik SA (France) having a weight of 5 ± 5 g / m² 2 has been applied. [31] Packaging paper material according to claim 1 and any of the dependent claims, wherein the second layer has a nominal thickness of 100 ± 5 g / m² 2 has, with printing inks weighing 0.5 ± 0.025 g / m² 2 and varnish with a weight of 0.5 ± 0.025 g / m² 2 are applied. [32] Packaging paper material according to claim 1 and any of the dependent claims, wherein the total dry solids content is 92.67% and the moisture content is 7.33%. [33] Packaging paper material according to claim 1 and any of the dependent claims, wherein the disintegration rate is more than 98.0% w / w dry matter by weight. [34] Packaging paper material according to claim 1 and any of the dependent claims, wherein the organic matter content is 92.67 ± 0.78 g / 100 g. [35] Packaging paper material according to claim 1 and any of the dependent claims, wherein the single surface thickness is 138 ± 6 µm and the edge thickness is 259 ± 5 µm. [36] Packaging paper material according to claim 1 and any of the dependent claims, wherein the basis weight is 133 ± 7 g / m² 2 amounts. [37] Packaging paper material according to claim 1 and any of the dependent claims, wherein the color is brown with black prints. [38] Packaging paper material according to claim 1 and any of the dependent claims, wherein the color is white with black prints. [39] Packaging paper material according to claim 1 and any of the dependent claims, wherein the colour is a natural colour with black prints. [40] Packaging paper material according to claim 1 and any of the dependent claims, wherein the color is brown with colored prints. [41] Packaging paper material according to claim 1 and any of the dependent claims, which is designed as a coffee capsule. [42] Packaging paper material according to claim 1 and any of the dependent claims, which is used to manufacture capsules by adding coffee and sealing the two layers with heat, and then cutting the capsule into an original Nespresso capsule shape. [43] Packaging paper material according to claim 1 and any of the dependent claims, wherein the capsule is produced by welding together an upper and a lower laminateable paper layer in a matrix-shaped form, creating an edge which reinforces the structure of the capsule and can withstand a tensile tensile force in the range of 13.2 N / mm to 19.8 N / mm. [44] Packaging paper material according to claim 1 and any of the dependent claims, wherein the welded edge provides improved airtightness, thereby ensuring a secure seal for coffee machines. [45] Packaging paper material according to claim 1 and any of the dependent claims, wherein the capsule exhibits a partial perforation force of 12.2 ± 0.5 kg and a full perforation force of 13.1 ± 0.5 kg when dry. [46] Packaging paper material according to claim 1 and any of the dependent claims, wherein the capsule exhibits a partial perforation force of 8.0 ± 1.0 kg and a full perforation force of 10.0 ± 1.0 kg after immersion in 90°C warm water for 30 seconds. [47] Packaging paper material according to claim 1 and any of the dependent claims, wherein the outer composition has characteristic Fourier transform infrared spectroscopy peaks (FTIR peaks) at the following wavenumbers: 506.28 cm -1 , 556.40 cm -1 , 982.88 cm -1 , 1159.69 cm -1 , 1313.31 cm -1 , 1429.02 cm -1 , 1735.13 cm -1 , 2853.23 cm -1 , 2922.05 cm -1 and 3325.49 cm -1 . [48] Packaging paper material according to claim 1 and any of the dependent claims, wherein the internal composition has characteristic Fourier transform infrared spectroscopy peaks (FTIR peaks) at the following wavenumbers: 528.76 cm -1 598.75 cm -1 , 656.17 cm -1 893.00 cm -1 , 1016.01 cm -1 , 1234.94 cm -1 , 1359.84 cm -1 , 1409.39 cm -1 , 1655.06 cm -1 , 1737.53 cm -1 , 2853.02 cm -1, 2922.65 cm -1 and 3231.62 cm -1 . [49] Packaging paper material according to claim 1 and any of the dependent claims, wherein a tensile test carried out in accordance with ISO 1924-3:2005 using a constant strain rate of 100 mm / min on specimens with a length of 100 mm and a width of 10 mm shows that at a strain of 8 mm the welded laminate has a tensile strength of 165 N, while the non-welded laminate has a tensile strength of 110 N, and furthermore, after a soaking time of 30 seconds in 90°C warm tap water, the welded laminate has a tensile strength of 28 N and the non-welded laminate has a tensile strength of 24 N. [50] Packaging paper material according to claim 1 and any of the dependent claims, wherein a tensile test carried out in accordance with ISO 1924-3:2005 using a constant strain rate of 100 mm / min on specimens with a length of 100 mm and a width of 10 mm shows that at a strain of 8 mm the welded laminate has a tensile strength of 165 N, while the non-welded laminate has a tensile strength of 110 N, and furthermore, after a soaking time of 30 seconds in 90°C warm tap water, the welded laminate has a tensile strength of 28 N and the non-welded laminate has a tensile strength of 24 N. [51] Packaging paper material according to claim 1 and any of the dependent claims, wherein the brewing time of a coffee capsule made from the material does not differ by more than ± 5% from the brewing time of a standard Nespresso capsule when brewed under identical conditions, including, inter alia, machine model, water temperature, pressure, coffee grind size and capsule fill weight, thereby ensuring that the alternative capsule has a brewing performance comparable to conventional Nespresso capsules. [52] Packaging paper material according to claim 1 and any of the dependent claims, wherein the oxygen permeability (O2TR), measured at 23 ± 1°C and a relative humidity of 30 ± 5%, is less than 0.001 cm 3 / (Packaging × 24 h × Area) is the value, which ensures extended shelf life for oxygen-sensitive foods. [53] Packaging paper material according to claim 1 and any of the dependent claims, wherein the carbon dioxide transmittance (CO2TR), measured at 23 ± 1°C and a relative humidity of 30 ± 5%, is less than 0.001 cm 3 / (Packaging × 24 h × Area) is achieved, which improves the preservation of foods that are sensitive to carbon dioxide loss. [54] Packaging paper material according to claim 1 and any of the dependent claims, wherein the moisture transmittance (MTR), measured at 23 ± 1°C and a relative humidity of 60 ± 5%, is less than 0.01 g / (m²). 2 × 24 h), which provides excellent moisture retention and excellent protection for moisture-sensitive foods. [55] Packaging paper material according to claim 1 and any of the dependent claims, wherein the material has a moisture retention capacity of at least 95% under controlled storage conditions over a period of 30 days, ensuring that the packaged food retains its desired moisture content during long-term storage. [56] Packaging paper material according to claim 1 and any of the dependent claims, wherein the barrier layer is designed to have a specific water vapor permeability (MVTR) of less than 0.05 g / (m²). 2 × 24 h), which prevents excessive moisture loss or absorption and thus extends the shelf life of packaged foods. [57] Packaging paper material according to claim 1 and any of the dependent claims, wherein the material has a moisture retention of 98% over 90 days at 25°C and a relative humidity of 60%, thereby ensuring long-term moisture protection for foodstuffs that require stable storage conditions. [58] Packaging paper material according to claim 1 and any of the dependent claims, wherein the material retains at least 98% of its moisture content under controlled temperature and humidity conditions for a period of 60 days, thereby ensuring the freshness and quality of moisture-sensitive packaged food products. [59] Packaging paper material according to claim 1 and any of the dependent claims, wherein the barrier layer is designed to provide an oxygen barrier performance with a permeability rate of less than 0.0005 cm². 3 / (m 2× 24 h), which extends the shelf life of oxygen-sensitive products such as fresh produce. [60] Packaging paper material according to claim 1 and any of the dependent claims, wherein the first layer is biodegradable and the biodegradability test according to ISO 14855-1:2012 is achieved with a biodegradability rate of at least 90% within 6 months in a composting environment. [61] Packaging paper material according to claim 1 and any of the dependent claims, wherein the second layer further comprises a UV-curable varnish to increase its moisture resistance and to improve the print quality of the material. [62] Packaging paper material according to claim 1 and any of the dependent claims, wherein the third layer comprises printing inks which are free from heavy metals and hazardous chemicals, thereby ensuring compliance with EU Regulation No. 1907 / 2006 (REACH). [63] Packaging paper material according to claim 1 and any of the dependent claims, wherein the adhesive layer has a shear strength of at least 25 N / cm, thereby ensuring durability under conditions of high stress during use. [64] Packaging paper material according to claim 1 and any of the dependent claims, wherein the metallized paper layer is designed to form a barrier against oxygen, moisture and light, thereby extending the shelf life of the packaged food. [65] Packaging paper material according to claim 1 and any of the dependent claims, wherein the film layer has a high tear strength of at least 30 N in the running direction (MD) and 25 N in the transverse direction (CD), thereby improving the structural integrity of the packaging. [66] Packaging paper material according to claim 1 and any of the dependent claims, wherein the total weight of the multilayer packaging material is 200 g / m² 2 does not exceed the limit, thus providing a lightweight solution while maintaining functionality. [67] Packaging paper material according to claim 1 and any of the dependent claims, wherein the film layer is made of a biodegradable plastic material, thereby ensuring complete compostability without leaving any toxic residues in the environment. [68] Packaging paper material according to claim 1 and any of the dependent claims, wherein the metallized paper layer includes an additional antimicrobial coating to prevent the growth of microorganisms on the packaging material and to ensure food safety. [69] Packaging paper material according to claim 1 and any of the dependent claims, wherein the packaging paper material has a coefficient of friction (COF) of less than 0.4, thereby ensuring easy handling and transport during the manufacturing process. [70] Packaging paper material according to claim 1 and any of the dependent claims, wherein the third layer contains pigments from renewable raw materials, making the material suitable for sustainable packaging applications. [71] Packaging paper material according to claim 1 and any of the dependent claims, wherein the adhesive layer is water-based, making it environmentally friendly and non-toxic for direct contact with food. [72] Packaging paper material according to claim 1 and any of the dependent claims, wherein the fifth layer is formed from a transparent material, allowing consumers to see the contents of the packaged product while maintaining the barrier properties. [73] Packaging paper material according to claim 1 and any of the dependent claims, wherein the packaging paper material has a low shrinkage factor of no more than 3% during the heat sealing processes, ensuring that the packaging retains its shape after sealing. [74] Packaging paper material according to claim 1 and any of the dependent claims, wherein the packaging paper material has a biodegradability rate of at least 90% under composting conditions according to ASTM D6400-19, ensuring that the material is completely decomposed in industrial composting facilities. [75] Machine for producing a home compostable and recyclable multilayer packaging paper material designed to hold edible foodstuffs and comprising laminating the material according to claim 1 and any of the dependent claims. [76] Machine for stretching a home-compostable and recyclable multilayer packaging paper material designed to hold edible foodstuffs into a form for producing packaging, comprising: a continuous paper feed system designed to roll a top paper layer and a base paper layer, a gas exchange system for introducing an edible substance into the paper during the stretching process, thereby improving the interaction between the paper and the mold, a vacuum and pressure control system for applying a vacuum and high internal pressure during the stretching process, thereby promoting a uniform interaction between the paper and the form and improving the quality and structural integrity of the manufactured packaging, a stretching mechanism for stretching the paper while maintaining edge melting, resulting in improved structural integrity for packaging manufacturing, a heating system to regulate the heat input at the edges of the paper to ensure uniform stretching while maintaining the integrity of the paper center, a control system with adjustable speed for winding and unwinding the paper to regulate the thickness and uniformity of the stretching, a gas supply system for distributing coffee particles or other edible substances in the air surrounding the paper during the stretching process, thereby facilitating absorption into the paper fibers, a temperature and pressure control system for adjusting the gas exchange process, optimizing the soaking of the paper with coffee, and improving the mechanical properties of the paper during stretching. [77] Machine according to one of claims 75 or 76, wherein the gas exchange system is designed to introduce coffee particles into the air surrounding the paper, thereby facilitating the absorption of the coffee into the fibers of the paper during the stretching process. [78] Machine according to one of claims 75 or 76, wherein the continuous paper feed system is designed to guide the paper into the mold under tension in order to promote uniform elongation and improve the interaction between paper and mold. [79] Machine according to one of claims 75 or 76, further comprising a control system for adjusting the temperature and pressure of the gas exchange process in order to optimize the soaking of the paper with coffee and to improve the mechanical properties of the paper when stretched. [80] Machine according to one of claims 75 or 76, wherein the stretching mechanism comprises a two-stage process: a first stage to lengthen the paper and a second stage to produce the final packaging shape. [81] Machine according to one of claims 75 or 76, wherein the vacuum and pressure control system is designed to maintain a constant internal pressure and a constant vacuum throughout the entire stretching process, thereby ensuring a uniform interaction between the paper and the form. [82] Machine according to one of claims 75 or 76, wherein the heating system is designed to selectively apply heat to the edges of the paper in such a way as to facilitate the melting of the edges while maintaining the integrity of the paper center. [83] Machine according to one of claims 75 or 76, further comprising a gas filter system to ensure that the edible substance introduced during the gas exchange process does not impair the quality of the paper or introduce impurities. [84] Machine according to one of claims 75 or 76, wherein the control system comprises a variable speed motor to adjust the speed at which the paper is unwound and thus control the thickness of the paper and the uniformity of the stretching. [85] Machine according to one of claims 75 or 76, wherein the gas exchange system is adjustable to regulate the gas flow rate, thereby enabling precise control of the rate at which coffee or other edible substances are absorbed into the paper fibers. [86] Machine according to one of claims 75 or 76, wherein the stretching mechanism can stretch the paper both in the forward direction and in the transverse direction to improve the uniformity and mechanical properties of the paper for packaging production. [87] Capsule for receiving a solid, liquid or gaseous manufactured product, including beverage, food, cosmetic composition or medical composition, comprising a material according to claim 1 or any of the dependent claims, wherein the paper material is produced by a process comprising rolling and stretching and is able to withstand the mechanical forces required for capsule manufacture, wherein the paper material is stretchable in the running direction to an elongation of at least 15% and in the transverse direction to an elongation of at least 5% and has a compostability of over 90% within six months under the conditions specified in ISO 14855-1:2012. [88] A capsule for receiving a solid, liquid, or gaseous manufactured product, including a beverage, food, cosmetic composition, or medicinal composition, comprising a material according to claim 1 or any of the dependent claims, manufactured by a machine designed for continuously rolling a top layer and a base layer of biodegradable paper material, for introducing an edible substance into the paper by gas exchange during the stretching process, for applying a vacuum and high internal pressure during the stretching process to ensure uniform interaction between the paper and a mold, and for stretching the paper while maintaining edge melting to enhance the structural integrity of the manufactured capsule.wherein the paper material is stretchable by at least 15% in the grain direction and at least 5% in the transverse direction and has a compostability of over 90% within six months under the conditions according to ISO 14855-1:2012.
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Patent Citations
Nutritional container and beverage preparation system
WO2024100283A1