STRONG BINDERS

Description

Technical field

[0001] The present invention relates to oil-based binders and optionally pitch-based binders, solid when cold and in divided form, and their use as a rejuvenating agent for the production of coatings from recycled asphalt aggregates. It also relates to a method for transporting and / or storing and / or handling binders that are solid when cold and in divided form. State of the prior art

[0002] The invention aims to facilitate and improve the use of recycled bituminous mix aggregates during the manufacture of new bituminous mixes. Recycled bituminous mix aggregates are materials resulting from the operation of repairing a bituminous surfacing layer, such as road surfaces, sidewalks, sports fields, which are essentially composed of a bituminous binder and aggregates. More specifically, recycled bituminous mix aggregates are derived from the operation of repairing bituminous surfacing which can be either the wearing course or one of the structural layers. Recycled bituminous mix aggregates are essentially composed of aggregates and bituminous binder residues adhering to these aggregates. Bituminous binder residues are also called aged bituminous binders.The formulation of new bituminous mixes from these recycled materials poses challenges: the presence of solidified bituminous residues, of varied origins and / or compositions, provides inhomogeneous compositions, with mixtures of bituminous materials that have inhomogeneous softening temperatures and penetrabilities. The size distribution of recycled aggregates can be wide and constitutes an obstacle to obtaining a homogeneous regenerated material. The aging of the bituminous binder also leads to a modification of its properties compared to a freshly prepared bituminous binder composition, in particular a lower penetrability and a higher softening temperature than that of the original material.

[0003] The rejuvenator must allow both the consistency and chemical composition of the bituminous binder present in the recycled asphalt aggregates to be adjusted. It facilitates the remobilization of aged bituminous binders present in the bituminous aggregates, i.e. it mixes easily with the aged bituminous binder and the aggregates both forming the recycled asphalt aggregates. This mixture produces asphalts in which the bituminous binder once again has a consistency and chemical composition allowing it to have the expected mechanical properties. The rejuvenator must allow the formulation of a composition whose binder has a satisfactory softening temperature and penetrability.

[0004] Recycled asphalt aggregates and oil-based binder compositions, possibly with added pitch, are usually used as rejuvenators.

[0005] These binders are currently transported in insulated tanker trucks or in iso-containers that allow heating using a heat transfer fluid or a steam network. The user must be equipped with storage tanks that are also kept hot until the binder is used. These constraints result in significant energy and equipment costs, both for the binder supplier and for its customer. In addition, maintaining the binder at temperature for a given period can affect the binder's properties, particularly its aging properties, and thus change the final performance of the products in which the binder is incorporated.

[0006] It is known that low molecular weight organogelators allow liquids to be gelled thermoreversibly. However, it is not possible to predict which organogelator is capable of solidifying which liquid. Furthermore, the presence of an organogelator in a liquid has an influence on the properties of this liquid and the invention aims to formulate a binder based on oil and possibly pitch, solid at room temperature, without its usage properties, in particular its properties as a rejuvenating agent in the production of coatings from recycled asphalt aggregates, being modified by the presence of additives allowing its solidification.

[0007] WO 2008 / 107551 teaches bitumen compositions comprising an organogelator-type additive and having thermoreversible viscosity and hardness characteristics. It is known, in particular from WO 2016 / 016320, to use organogelators to condition bitumens in cold solid and divided form. However, the composition of a bitumen is very different from that of an oil-based binder and possibly pitch, and the intended applications are very different.

[0008] JP 02 169669 discloses the preparation of bituminous compositions whose odor intensity and the amount of smoke released upon heating are reduced. The bituminous compositions comprise bitumen, a styrene-based thermoplastic elastomer and dibenzylidene sorbitol.

[0009] The aim of the present invention is to provide an oil-based binder and optionally a pitch, which can be used as a rejuvenating agent in the production of coatings from recycled bituminous mix aggregates, which is in divided and solid form at room temperature and which can be made fluid by simple heating. In particular, an aim of the invention is to provide an oil-based binder and optionally a pitch, which is in divided and solid form at room temperature, and which can be mixed with recycled bituminous mix aggregates in order to produce bituminous coatings.In particular, an attempt has been made to develop a binder based on oil and possibly pitch, in solid form and in divided form, comprising an organogelator whose presence does not significantly modify the usage properties of the rejuvenating composition or the rejuvenating binder, nor those of the bituminous coating compositions in which it is incorporated.

[0010] The invention also aims to propose a method for transporting and / or storing and / or handling at room temperature a binder in solid form and in divided form.

[0011] Another objective of the invention is to propose a method allowing easy handling of the binder during handling operations.

[0012] Another objective of the invention is to propose an ecological and economical method for transporting a binder and to avoid the use of additional means for maintaining the temperature of this binder during its transport and / or its storage and / or its handling. Summary of the invention

[0013] The invention relates to a binder which is solid at room temperature comprising: at least one hydrocarbon oil chosen from aromatic oils having an aromatic compound content of between 30 and 95% by mass, at least one pitch, at least one organogelating chemical additive.

[0014] According to a preferred embodiment, the hydrocarbon oil is chosen from hydrocarbon oils of petroleum origin.

[0015] According to a first preferred variant, the hydrocarbon oil is chosen from aromatic oils having an aromatic compound content of between 50 and 95% by mass, more advantageously between 60 and 95% by mass relative to the total mass of the aromatic oil.

[0016] According to a preferred embodiment of this variant, the aromatic oil has a kinematic viscosity at 100°C of between 0.1 and 150 mm 2 < / s, advantageously of between 5 and 120 mm 2 < / s, more advantageously of between 7 and 90 mm 2 < / s.

[0017] According to a preferred embodiment, the pitch has a penetrability at 25°C ranging from 0 to 20 1 / 10 mm, it being understood that the penetrability is measured according to standard EN 1426.

[0018] According to a first variant, the pitch has a ring and ball softening temperature (RBT), measured according to standard EN 1427, ranging from 115°C to 175°C.

[0019] According to a preferred embodiment of this first variant, the pitch is an oxidized pitch.

[0020] According to a second variant, the pitch has a ring and ball softening temperature (RBT), measured according to standard EN 1427, ranging from 55°C to 110°C.

[0021] According to a preferred embodiment of this second variant, the pitch comes from a deasphalting operation by the addition of a C 3 -C 4 aliphatic solvent.

[0022] According to a preferred embodiment, the organogelating compound has a molar mass less than or equal to 2000 g.mol -1< .

[0023] According to a preferred embodiment, the binder comprises from 0.2% to 5% by mass, more preferably from 0.5% to 3.5% by mass of organogelling additive relative to the total mass of the binder.

[0024] According to a preferred embodiment, the binder is in the form of granules or loaves.

[0025] The invention also relates to a kit comprising at least: a binder solid at room temperature as defined above and in detail below or a solid binder consisting of a hydrocarbon oil of petroleum or synthetic origin and their mixtures, and a capsule comprising at least one additive.

[0026] The invention also relates to a process for preparing a binder which is solid at room temperature as defined above and in detail below, comprising: (i) Mixing the oil and pitch and heating to a temperature between 140 and 200°C, (ii) Adding the organogelating compound, mixing and heating to a temperature between 140 and 200°C, (iii) Optionally adding one or more other additives, mixing and heating to a temperature between 140 and 200°C, (iv) Shaping the composition, for example in the form of granules or cakes. (v) Cooling to room temperature.

[0027] The invention also relates to a method for transporting and / or storing and / or handling a binder which is solid at room temperature and in divided form as defined above and in detail below, or to a kit comprising such a binder, the binder being transported and / or stored and / or handled in the form of loaves or granules which are solid at room temperature.

[0028] The invention also relates to the use of a binder which is solid at room temperature and in divided form comprising: at least one hydrocarbon oil chosen from aromatic oils having an aromatic compound content of between 30 and 95% by mass, at least one organogelating chemical additive,

[0029] for the manufacture of bituminous mixes comprising recycled bituminous mix aggregates.

[0030] According to a preferred embodiment, the binder which is solid at room temperature and in divided form further comprises at least one pitch, preferably having a penetrability at 25°C ranging from 0 to 20 1 / 10 mm, and advantageously chosen from: a pitch resulting from a deasphalting operation by the addition of a C 3 -C 4 aliphatic solvent and having a ring and ball softening temperature (RBT) ranging from 55°C to 110°C; a pitch an oxidized pitch having a ring and ball softening temperature (RBT) ranging from 115°C to 175°C, it being understood that penetrability is measured according to EN 1426 and TBA is measured according to EN 1427.

[0031] According to a preferred embodiment of the use, the binder which is solid at room temperature and in divided form is as defined above or in detail below or in the form of a kit. Detailed description

[0032] The expression "consists essentially of" followed by one or more characteristics means that, in addition to the components or steps explicitly listed, components or steps which do not significantly modify the properties and characteristics of the invention may be included in the process or material of the invention.

[0033] The expression "between X and Y" includes the limits, unless explicitly stated otherwise. This expression therefore means that the interval in question includes the values ​​X, Y and all values ​​from X to Y.

[0034] For the purposes of the present invention, the term "binder" means a composition comprising at least one oil and optionally at least one pitch, said composition being usable in a mixture with aggregates, as a substitute for bitumen-based binders, for the preparation, for example, of bituminous coatings.

[0035] By "binder solid at room temperature" is meant a binder having a solid appearance at room temperature under transport and / or storage and / or handling conditions. More specifically, it means a solid binder which retains its solid appearance throughout transport and / or storage and / or handling at room temperature, i.e. a solid binder which does not flow at a temperature of up to 80°C, advantageously from 5°C to 70°C, preferably from 10°C to 70°C, more preferably from 10°C to 60°C, even more preferably from 15°C to 50°C, and at pressure forces resulting from the transport and / or storage and / or handling conditions.

[0036] By "binder solid at room temperature and in divided form" is meant a binder solid at room temperature which is packaged in divided form, i.e. in the form of units distinct from each other, which are called granules or loaves.

[0037] The binder according to the invention is also referred to indifferently in the present description as “solid binder” or “solid composition”.

[0038] The binder according to the invention is designated indifferently in the present description by “cold solid binder in divided form” or “additive binder”.

[0039] The binder according to the invention is also referred to in the present invention as “rejuvenating binder”.

[0040] By "penetrability" is meant here the measurement known as "needle penetrability" which is carried out using a standardized test NF EN 1426 at 25°C (P25). This penetrability characteristic is expressed in tenths of a millimeter (dmm or 1 / 10 mm). Needle penetrability, measured at 25°C, according to the standardized test NF EN 1426, represents the measurement of the penetration into a sample of bitumen, after a time of 5 seconds, of a needle whose weight with its support is 100g. The NF EN 1426 standard replaces the approved standard NF T 66-004 of December 1986 with effect from December 20, 1999 (decision of the Director General of AFNOR dated November 20, 1999). The oil

[0041] The oil can be of any type, it is chosen depending on the conditions of the subsequent application, in particular the origin of the recycled bituminous aggregates. It can be a hydrocarbon oil of petroleum origin, a hydrocarbon oil of synthetic origin or their mixture.

[0042] Preferably the oil is a hydrocarbon oil of petroleum origin. It can be aromatic or paraffinic.

[0043] According to a first embodiment, the oil is composed of 90 to 100% by mass of at least one hydrocarbon oil of petroleum origin, advantageously 95 to 100%, even better 98 to 100%, by mass of at least one hydrocarbon oil of petroleum origin. Even more advantageously, the oil is composed of one hydrocarbon oil or a mixture of hydrocarbon oils of petroleum origin.

[0044] In a first embodiment of the invention, the hydrocarbon oil of petroleum origin is chosen from aromatic oils.

[0045] Aromatic oils have an aromatic compound content of between 30 and 95% by mass, advantageously between 50 and 95% by mass, more advantageously between 60 and 95% by mass relative to the total mass of the aromatic oil (SARA method: Saturates / Aromatics / Resins / Asphaltenes).

[0046] More preferably, the aromatic oils have a content of saturated compounds of between 1 and 20% by mass, advantageously between 3 and 15% by mass, more advantageously between 5 and 10% by mass (SARA method: Saturates / Aromatics / Resins / Asphaltenes).

[0047] More preferably, the aromatic oils have a resin compound content of between 1 and 10% by mass, advantageously between 3 and 5% by mass (SARA method: Saturates / Aromatics / Resins / Asphaltenes).

[0048] The contents of saturated, resinous and aromatic compounds mentioned in this application are determined according to ASTM D2140, in % by mass relative to the mass of the oil.

[0049] More preferably, the aromatic oils have a kinematic viscosity at 100°C of between 0.1 and 150 mm 2 < / s, advantageously of between 5 and 120 mm 2 < / s, more advantageously of between 7 and 90 mm 2 < / s (ASTM Method D 445).

[0050] More preferably, the aromatic oils have a Cleveland flash point greater than or equal to 150°C, advantageously between 150°C and 600°C, more advantageously between 200°C and 400°C (Method EN ISO 2592).

[0051] More preferably, aromatic oils have an aniline point between 20°C and 120°C, advantageously between 40°C and 120°C (ASTM D611 Method).

[0052] More preferably, the aromatic oils have a density at 15°C of between 400 kg / m 3< and 1500 kg / m 3<, advantageously of between 600 kg / m 3< and 1200 kg / m 3<, more advantageously of between 800 kg / m 3< and 1000 kg / m 3< (ASTM Method D4052).

[0053] According to this advantageous embodiment, the aromatic oil comprises aromatic extracts of petroleum residues, obtained by extraction or dearomatization of residues from distillations of petroleum cuts.

[0054] Aromatic extracts are by-products of the crude oil refining process, obtained in particular from the products of vacuum distillation of atmospheric residues. They result from a single or double extraction of the raffinate that can be used in lubricants, using a polar solvent. The different extracts are classified into different categories depending on their production process and are as follows: DAE (Distillate Aromatic Extract), MES (Mild Extract Solvate), TDAE (Treated Distillate Aromatic Extract), RAE (Residual Aromatic Extract), TRAE (Treated Residual Aromatic Extract)

[0055] For example, the aromatic oils that can be used according to the invention can be chosen from the following products marketed by the company TOTAL under the names: Plaxolene 50 ®< (also sold under the brand name Régénis 50 ®< ), Plaxolene TD346 ®< and Plaxolene MS132 ®< .

[0056] The respective contents of paraffinic, naphthenic and aromatic compounds depend to some extent on the nature of the crude oil from which the aromatic oil is derived and the refining process used.

[0057] For example, Plaxolene 50 ®< or Régénis 50 ®< is a RAE (Residual Aromatic Extract) which presents: a density at 15°C between 980 kg / m 3< and 1010 kg / m 3< (ASTM D4052 Method), a flash point (Cleveland) of approximately 230°C (EN ISO 2592 Method), a kinematic viscosity at 100°C between 60 and 85 mm 2< / s (ASTM D 445 Method), an aniline point between 53 and 65°C (ASTM D611 Method).

[0058] For example, Plaxolene TD346 ®< is a TDAE (Treated Distillates Aromatic Extract) which presents: a density at 15°C between 940 kg / m 3< and 970 kg / m 3< (ASTM D4052 Method), a flash point (Cleveland) of approximately 220°C (EN ISO 2592 Method), a kinematic viscosity at 100°C between 16 and 23 mm 2< / s (ASTM D 445 Method), an aniline point between 64 and 72°C (ASTM D611 Method).

[0059] For example, Plaxolene MS132 ®< is a MES (Mild Extract Solvate) which presents: a density at 15°C between 895 kg / m 3< and 925 kg / m 3< (ASTM D4052 Method), a flash point (Cleveland) of approximately 230°C (EN ISO 2592 Method), a kinematic viscosity at 100°C between 13 and 17 mm 2< / s (ASTM D 445 Method), an aniline point between 85 and 100°C (ASTM D611 Method).

[0060] According to a second embodiment of the present disclosure, the oil is a paraffinic oil comprising predominantly paraffinic extracts of petroleum residues. According to this specific embodiment, advantageously, the oil comprises a total content of paraffinic compounds of at least 50% by mass, preferably at least 60% by mass, for example between 50% and 90%, preferably between 60% and 90%, more preferably between 50% and 80% and in particular between 55% and 75% or in particular between 60% and 75%.

[0061] In a more specific embodiment, the oil further contains a total content of naphthenic compounds which does not exceed 25%, for example between 5% and 25%, and in particular between 10% and 25%.

[0062] In a more specific embodiment, the oil further contains a total content of aromatic compounds which does not exceed 25%, for example between 5% and 25%, and in particular between 8% and 18%.

[0063] In a particularly preferred embodiment, the oil is a paraffinic oil, comprising the respective contents: (i) a total content of paraffinic compounds of between 50% and 90%; (ii) a total content of naphthenic compounds of between 5% and 25%; and (iii) a total content of aromatic compounds of between 5% and 25%.

[0064] In a more particularly preferred embodiment, the oil is a paraffinic oil, comprising the respective contents: (i) a total content of paraffinic compounds of between 60% and 75%; (ii) a total content of naphthenic compounds of between 5% and 25%; and (iii) a total content of aromatic compounds of between 5% and 25%.

[0065] In a further preferred embodiment, the oil is a paraffinic oil, comprising the respective contents: (i) a total content of paraffinic compounds of between 60% and 75%; (ii) a total content of naphthenic compounds of between 15% and 25%; and (iii) a total content of aromatic compounds of between 10% and 15%.

[0066] In a preferred embodiment of this variant, the paraffinic oils are derived from the deasphalting cuts of reduced pressure distillation (vacuum residue, RSV) of crude oil (hereinafter referred to as "DAO oil"). The principle of deasphalting is based on separation by precipitation of a petroleum residue into two phases: i) a phase called "deasphalted oil", also called "oil matrix" or "oil phase" or DAO (DeAsphalted Oil in English); and ii) a phase called "asphalt".

[0067] Oils meeting the characteristics below and usable according to the invention are obtained by the processes for deasphalting vacuum residues (VRR) from petroleum refining, for example by deasphalting using a C3 to C6 solvent, preferably propane. Deasphalting processes are well known to those skilled in the art and are described for example in FR3014111, US 2004 / 0069685, US 4,305,812 and US 4,455,216 or in Lee et al., 2014, Fuel Processing Technology 119: 204-210.

[0068] In Lee et al., 2014, Fuel Processing Technology 119: 204-210, vacuum distillation residues (VDR) are separated according to their molecular weight in the presence of C3 to C6 solvents (e.g., propane). The resulting DAO oil is rich in paraffin, has a very low asphaltene content, an evaporation temperature between 440°C and 750°C, and an API gravity much higher than that of vacuum residues.

[0069] The API gravity or API density of an oil (in English "API gravity" for "American Petroleum Institute gravity") can be obtained from the following formula (1): G API = 141 , 5 d − 131 , 5 with : G API, the API gravity of the oil considered (expressed without units), and d, the density at 16°C (60°F) of the oil considered (expressed without units) taking water as the reference.

[0070] The respective contents of paraffinic, naphthenic and aromatic compounds depend to a certain extent on the nature of the crude oil from which the DAO oil originates and on the refining process used. A person skilled in the art knows how to determine the respective contents of paraffinic, naphthenic and aromatic compounds in a DAO oil, for example, using the SARA fractionation method also described in Lee et al 2014, Fuel Processing Technology 119: 204-210, and thus select the appropriate DAO oil for the preparation of the gelled oil composition according to the invention.

[0071] The contents of paraffinic, naphthenic and aromatic compounds mentioned in this application are determined according to ASTM D2140, in % by mass relative to the mass of the oil.

[0072] In a third embodiment of the invention, the hydrocarbon oil of petroleum origin is a mixture of aromatic oils as described above and paraffinic oils as described above.

[0073] According to another embodiment, the binder may further comprise an oil of vegetable origin.

[0074] For example, oils of vegetable origin can be chosen from rapeseed, sunflower, soybean, linseed, olive, palm, castor, wood, corn, pumpkin, grapeseed, jojoba, sesame, walnut, hazelnut, almond, shea, macadamia, cottonseed, alfalfa, rye, safflower, peanut, coconut and copra oils, and mixtures thereof. The pitch :

[0075] Pitch is optionally used in a mixture with oil in the binder.

[0076] According to the French dictionary, "pitch" means a residue from the distillation of tars from petroleum, oil, coal, wood or other organic molecules.

[0077] The pitch used in the invention is chosen from petroleum distillation residues, also called “petroleum pitch”.

[0078] In the description, the terms "pitch", "petroleum pitch" and "deasphalting pitch" will be used independently of each other.

[0079] Pitch can be obtained by conventional refinery manufacturing processes. The manufacturing process consists of a succession of atmospheric distillation and vacuum distillation. First, the crude oil is subjected to distillation at atmospheric pressure, which results in a gaseous phase, various distillates, and an atmospheric distillate residue. Then, the atmospheric distillation residue itself undergoes distillation under reduced pressure, called vacuum distillation, which separates a heavy diesel oil, various distillate cuts, and a vacuum distillation residue. This vacuum distillation residue contains "petroleum pitch" in varying concentrations.

[0080] It is possible to obtain “petroleum pitch” using two processes: 1 ère< process: The vacuum distillation residue is subjected to a deasphalting operation by adding a suitable solvent, such as propane, which thus allows the pitch to precipitate and separate it from the light fractions such as deasphalted oil. 2nd< Process: The vacuum distillation residue is subjected to solvent extraction, more specifically furfural. This heterocyclic aldehyde has the particularity of selectively solubilizing aromatic and polycyclic compounds. This process thus makes it possible to eliminate aromatic extracts and recover the “petroleum pitch”.

[0081] According to one embodiment of the invention, the pitch is in the form of granules before its introduction into the heated oil. Such an embodiment facilitates the handling of the components and the implementation of the method.

[0082] The mechanical qualities of pitches are generally assessed by determining a series of mechanical characteristics by standardized tests, the most used of which are needle penetrability expressed in 1 / 10 mm and the softening point determined by the ring and ball test, also called ring and ball softening temperature (RBT).

[0083] According to one embodiment of the invention, the pitch has a needle penetrability at 25°C of 0 to 20 1 / 10 mm, preferably of 5 to 20 1 / 10 mm, it being understood that the penetrability is measured according to standard EN 1426.

[0084] According to a first variant, the pitch has a softening point of between 115°C and 175°C. Among examples of pitches used in the invention, there are pitches having respectively a softening point of between 115°C and 125°C, between 135 and 145°C or between 165 and 175°C.

[0085] According to a preferred embodiment of this first variant, the pitch is a blown pitch, also called an oxidized pitch. For the purposes of the invention, the terms "blown pitch" and "oxidized pitch" will be used independently of each other.

[0086] Preferably, the oxidized pitch used according to the invention is obtained by oxidation of a mixture comprising pitch and a diluent, such as a light gasoline, also called "fluxant" subjected to an oxidation operation in a blowing tower in the presence of a catalyst, at a fixed temperature and at a given pressure.

[0087] For example, oxidized pitches can be produced in a blowing unit, by passing a stream of air and / or oxygen through a starting pitch. This operation can be carried out in the presence of an oxidation catalyst, for example phosphoric acid. Generally, oxidation is carried out at high temperatures, in the order of 200 to 300°C, for relatively long periods of time typically between 30 minutes and 2 hours, continuously or in batches. The oxidation time and temperature are adjusted according to the desired properties of the oxidized pitch and the quality of the starting pitch.

[0088] According to a second variant, the pitch has a ring and ball softening temperature (RBT), measured according to standard EN 1427, ranging from 55°C to 110°C.

[0089] According to a preferred embodiment of this second variant, the pitch is obtained from a deasphalting operation by the addition of a C 3 -C 4 aliphatic solvent, preferably directly obtained after a deasphalting operation by the addition of a C 3 -C 4 aliphatic solvent.

[0090] Preferably, according to this preferred embodiment, the deasphalting solvent is chosen from propane, butane and their mixtures.

[0091] The addition of a pitch with the mechanical characteristics presented above in an oil makes it possible to obtain a rejuvenating binder suitable for all types of recycled bituminous coating aggregates.

[0092] The binder of the invention can be prepared by a process comprising at least the steps of: Heating the oil to a temperature ranging from 140 to 180°C, Introducing the pitch into the oil, Stirring the mixture at a temperature ranging from 140 to 180°C until a homogeneous mixture is obtained.

[0093] It has been found that pitch mixes perfectly with oil.

[0094] Advantageously, the pitch does not require heating before being added to the oil. Although pitch usually has a melting temperature above 220°C, it dissolves in oils at the usual temperatures for preparing binders. The process for manufacturing the binder of the invention is easy to implement and does not require the pitch to be hot transported over long distances to be added to the oil.

[0095] According to one embodiment of the invention, the pitch is used in cold solid and divided form, preferably in the form of granules, in the process for producing binders. This form facilitates the handling of the pitch for its use in the manufacture of the binder of the invention.

[0096] Cold-solid pitch in divided form means pitch that is solid at room temperature and is packaged in divided form, i.e. in the form of separate units, for example granules.

[0097] The pitch granules may have, within the same population of granules, one or more shapes chosen from a cylindrical, spherical or ovoid shape. More specifically, the pitch granules preferably have a cylindrical or spherical or even semi-spherical shape.

[0098] Advantageously, the size of the pitch granules is such that the longest average dimension is preferably less than or equal to 50 mm, more preferably 2 to 30 mm. For example, the use of a die makes it possible to control the production of granules of a chosen size. Sieving makes it possible to select granules according to their size.

[0099] To enable the formation of pitch granules that do not adhere to each other and resist compression during storage, it may be advantageous to use pitch granules coated in whole or in part on their surface with an anti-caking compound. Pitch, in the form of granules possibly coated with an anti-caking compound, is easy to handle after prolonged transport and / or storage. The anti-caking compound is then found in the composition forming the core of the granules. The organogelating compound

[0100] The binder which is solid at room temperature and in divided form according to the invention comprises at least one chemical additive chosen from organogelating compounds.

[0101] In particular, the binder which is solid at room temperature and in divided form comprises at least one organogelling chemical additive in an amount suitable for this composition to be solid at room temperature and in divided form.

[0102] In one embodiment of the invention, the organogelating chemical additive is an organic compound. Advantageously, the organogelating compound has a molar mass less than or equal to 2000 gmol -1< , preferably a molar mass less than or equal to 1000 gmol -1< .

[0103] In this first embodiment, according to a first variant, the organogelling compound is a compound of general formula (I): Ar1-R-Ar2 (I), in which: Ar1 and Ar2 represent, independently of each other, a benzene ring or a system of condensed aromatic rings of 6 to 20 carbon atoms, substituted by at least one hydroxyl group and optionally substituted by one or more C 1 -C 20 alkyl groups, and R represents an optionally substituted divalent radical, the main chain of which comprises from 6 to 20 carbon atoms and at least one group chosen from the amide, ester, hydrazide, urea, carbamate, anhydride functions.

[0104] Preferably, Ar1 and / or Ar2 are substituted by at least one alkyl group of 1 to 10 carbon atoms, advantageously in one or more positions ortho with respect to the hydroxyl group(s), more preferably Ar1 and Ar2 are 3,5-dialkyl-4-hydroxyphenyl groups, advantageously 3,5-di-tert-butyl-4-hydroxyphenyl groups.

[0105] Preferably, R is in position para relative to a hydroxyl group of Ar1 and / or Ar2.

[0106] An example of a compound of formula (I) is 2',3-bis[(3-[3, 5-di- tert -butyl-4-hydroxyphenyl]propionyl)]propionohydrazide.

[0107] According to a second variant of this embodiment, the organogelling compound is a compound of general formula (II): R-(NH) n CONH-(X) m -(NHCO) p (NH) n -R' (II), in which, the groups R and R', which may be identical or different, represent a saturated or unsaturated, linear, branched or cyclic hydrocarbon chain comprising from 1 to 22 carbon atoms, optionally substituted by one or more hydroxyl groups or amine groups, and optionally comprising heteroatoms such as N, O, S, C 5 -C 24 hydrocarbon rings and / or C 4 -C 24 hydrocarbon heterocycles comprising one or more heteroatoms such as N, O, S, and R' may be H; the group X represents a saturated or unsaturated, linear, cyclic or branched hydrocarbon chain comprising from 1 to 22 carbon atoms, optionally substituted, and optionally comprising heteroatoms such as N, O, S, C 5 -C 24 hydrocarbon rings and / or C 4 -C 24 hydrocarbon heterocycles comprising one or more heteroatoms such as N, O, S; n, m and p are integers having a value of 0 or 1 independently of each other.

[0108] According to this variant, when the integer m has a value of 0 and when the integer p has a value of 1, then the groups R-(NH) n CONH and NHCO(NH) n -R' are covalently linked and together form a hydrazide bond CONH-NHCO. The group R, or the group R', then represents at least one group chosen from: a hydrocarbon chain of at least 4 carbon atoms, an aliphatic cycle of 3 to 8 atoms, an aliphatic, partially aromatic or entirely aromatic condensed polycyclic system, each cycle comprising 5 or 6 atoms.

[0109] Still according to this variant, when the integer m has a value of 1, then the group R, the group R' and / or the group X, represent at least one group chosen from: a hydrocarbon chain of at least 4 carbon atoms, an aliphatic cycle of 3 to 8 atoms, an aliphatic, partially aromatic or entirely aromatic condensed polycyclic system, each cycle comprising 5 or 6 atoms.

[0110] Preferably, the group R and / or the group R' represent an aliphatic hydrocarbon chain of 4 to 22 carbon atoms, in particular, chosen from the groups C 4 H 9 , C 5 H 11 , C 9 H 19 , C 11 H 23 , C 12 H 25 , C 17 H 35 , C 18 H 37 , C 21 H 43 , C 22 H 45 .

[0111] According to a first preferred embodiment, the group X represents a linear, saturated hydrocarbon chain comprising from 1 to 22 carbon atoms, advantageously from 1 to 12 carbon atoms, even better from 1 to 10 carbon atoms. Preferably, the group X is chosen from the groups C 2 H 4 , C 3 H 6 .

[0112] According to a second preferred embodiment, the group X can also be a cyclohexyl group or a phenyl group, the radicals R-(NH) n CONH- and - NHCO(NH) n -R' can then be in the ortho, meta or para position. Furthermore, the radicals R-(NH) n CONH- and -NHCO(NH) n -R' can be in the cis or trans position relative to each other. In addition, when the radical X is cyclic, this cycle can be substituted by groups other than the two main groups R-(NH) n CONH- and -NHCO(NH) n -R'.

[0113] According to a third preferred embodiment, the group X represents two 6-carbon cycles, optionally substituted, linked by a CH 2 group, these cycles being aliphatic or aromatic. In this case, the group X is, for example

[0114] Advantageously, according to this variant, the organogelling compound is a compound of general formula (II) chosen from hydrazide derivatives such as the compounds C 5 H 11 -CONH-NHCO-C 5 H 11 , C 9 H 19 -CONH-NHCO-C 9 H 19 , C 11 H 23 -CONH-NHCO-C 11 H 23 , C 17 H 35 -CONH-NHCO-C 17 H 35 , or C 21 H 43 -CONH-NHCO-C 21 H 43 ; diamides such as N,N'-ethylenedi(laurylamide) of formula C 11 H 23 -CONH-CH 2 -CH 2 -NHCO-C 11 H 31 , N,N'-ethylenedi(myristylamide) of formula C 13 H 27 -CONH-CH 2 -CH 2 -NHCO-C 13 H 27 , N,N'-ethylenedi(palmitamide) of formula C 15 H 31 -CONH-CH 2 -CH 2 -NHCO-C 15 H 31 , N,N'-ethylenedi(stearamide) of formula C 17 H 35 -CONH-CH 2 -CH 2 -NHCO-C 17 H 35 ; and ureide derivatives such as 4,4'-bis(dodecylaminocarbonylamino)diphenylmethane of formula C 12 H 25 -NHCONH-C 6 H 4 -CH 2 -C 6 H 4 -NHCONH-C 12 H 25 .

[0115] Preferably, the compound of general formula (II) is chosen from those which satisfy the condition n = 0.

[0116] Preferably, the compound of general formula (II) is chosen from those which satisfy the condition: the sum of the numbers of carbon atoms of R, X and R' is greater than or equal to 10, advantageously greater than or equal to 14, preferably greater than or equal to 18.

[0117] Preferably, the compound of general formula (II) is chosen from those which satisfy the condition: the number of carbon atoms of at least one of R and R' is greater than or equal to 10, advantageously greater than or equal to 12, preferably greater than or equal to 14.

[0118] Preferably, according to a first variant, the compound of general formula (II) is chosen from those of formula (IIA): R-CONH-(X) m -NHCO-R' (IIA) in which R, R', m and X have the same definition as above.

[0119] Preferably, in formula (IIA) when m= 1, the group X represents a linear, saturated hydrocarbon chain comprising from 1 to 22 carbon atoms, advantageously X represents a linear, saturated hydrocarbon chain comprising from 1 to 12 carbon atoms, even better from 1 to 4 carbon atoms. Preferably, the group X is chosen from the groups C 2 H 4 , C 3 H 6 .

[0120] Preferably, the compound of general formula (IIA) is chosen from those which satisfy the condition: the sum of the numbers of carbon atoms of R, X and R' is greater than or equal to 10, advantageously greater than or equal to 14, preferably greater than or equal to 18.

[0121] Preferably, the compound of general formula (IIA) is chosen from those which satisfy the condition: the number of carbon atoms of at least one of R and R' is greater than or equal to 10, advantageously greater than or equal to 12, preferably greater than or equal to 14.

[0122] More preferably, according to this variant, the compound of general formula (IIA) is chosen from hydrazide derivatives such as the compounds C 5 H 11 -CONH-NHCO-C 5 H 11 , C 9 H 19 -CONH-NHCO-C 9 H 19 , C 11 H 23 -CONH-NHCO-C 11 H 23 , C 17 H 35 -CONH-NHCO-C 17 H 35 , or C 21 H 43 -CONH-NHCO-C 21 H 43 ; diamides such as N,N'-ethylenedi(laurylamide) of formula C 11 H 23 -CONH-CH 2 -CH 2 -NHCO-C 11 H 31 , N,N'-ethylenedi(myristylamide) of formula C 13 H 27 -CONH-CH 2 -CH 2 -NHCO-C 13 H 27 , N,N'-ethylenedi(palmitamide) of formula C 15 H 31 -CONH-CH 2 -CH 2 -NHCO-C 15 H 31 , N,N'-ethylenedi(stearamide) of formula C 17 H 35 -CONH-CH 2 -CH 2 -NHCO-C 17 H 35 ; monoamides such as laurylamide of formula C 11 H 23 -CONH 2 , myristylamide of formula C 13 H 27 -CONH 2 , palmitamide of formula C 15 H 31 -CONH 2 , stearamide of formula C 17 H 35 -CONH 2 .Even more advantageously, the compound of general formula (IIA) is N,N'-ethylenedi(stearamide) of formula C 17 H 35 -CONH-CH 2 -CH 2 -NHCO-C 17 H 35 .

[0123] Preferably, according to a second variant, the compound of general formula (II) is chosen from those of formula (IIB): R-CONH-R' (IIB) in which R and R' have the same definition as above.

[0124] Advantageously, according to this variant, the sum of the numbers of carbon atoms of R and R' is greater than or equal to 10, advantageously greater than or equal to 14, preferably greater than or equal to 18.

[0125] Even more advantageously, according to this variant, the number of carbon atoms of R is greater than or equal to 10, advantageously greater than or equal to 12, preferably greater than or equal to 14, and R' = H.

[0126] Advantageously, the compound of general formula (II) is chosen from hydrazide derivatives such as the compounds C 5 H 11 -CONH-NHCO-C 5 H 11 , C 9 H 19 -CONH-NHCO-C 9 H 19 , C 11 H 23 -CONH-NHCO-C 11 H 23 , C 17 H 35 -CONH-NHCO-C 17 H 35 , or C 21 H 43 -CONH-NHCO-C 21 H 43 ; diamides such as N,N'-ethylenedi(laurylamide) of formula C 11 H 23 -CONH-CH 2 -CH 2 -NHCO-C 11 H 31 , N,N'-ethylenedi(myristylamide) of formula C 13 H 27 -CONH-CH 2 -CH 2 -NHCO-C 13 H 27 , N,N'-ethylenedi(palmitamide) of formula C 15 H 31 -CONH-CH 2 -CH 2 -NHCO-C 15 H 31 , N,N'-ethylenedi(stearamide) of formula C 17 H 35 -CONH-CH 2 -CH 2 -NHCO-C 17 H 35 ; monoamides such as laurylamide of formula C 11 H 23 -CONH 2 , myristylamide of formula C 13 H 27 -CONH 2 , palmitamide of formula C 15 H 31 -CONH 2 , stearamide of formula C 17 H 35 -CONH 2 .

[0127] Even more advantageously, the compound of general formula (II) is N,N'-ethylenedi(stearamide) of formula C 17 H 35 -CONH-CH 2 -CH 2 -NHCO-C 17 H 35 .

[0128] Preferably, when the chemical additive is chosen from organic compounds of formula (II), it is used in combination with at least one other chemical additive chosen from organic compounds of formula (I), (III), (V), (VI) and (VII) and / or the reaction products of at least one C3-C12 polyol and at least one C2-C12 aldehyde, in particular those comprising a group of formula (IV).

[0129] According to a third variant, the organogelating compound is a compound of formula (III): (R-NHCO) x -Z-(NHCO-R') y (III), in which, R and R', identical or different, represent a saturated or unsaturated, linear, branched or cyclic hydrocarbon chain comprising from 1 to 22 carbon atoms, optionally substituted, and optionally comprising heteroatoms such as N, O, S, C 5 -C 24 hydrocarbon rings and / or C 4 -C 24 hydrocarbon heterocycles comprising one or more heteroatoms such as N, O, S, Z represents a tri-functionalized group chosen from the following groups: x and y are different integers with values ​​ranging from 0 to 3 and such that x+y=3.

[0130] Preferably, when x is 0 and Z represents Z 2 , the compound of formula (III) is N2,N4,N6-tridecylmelamine having the following formula with R' representing the group C 9 H 19 :

[0131] Other preferred compounds corresponding to formula (III) are such that x is equal to 0, Z represents Z 2 and R' represents a saturated, linear hydrocarbon chain of 1 to 22 carbon atoms, preferably of 2 to 18 carbon atoms, preferably of 5 to 12 carbon atoms.

[0132] Other preferred compounds corresponding to formula (III) are such that: y is equal to 0 and Z represents Z 1 , the compounds then have the formula: with R chosen from the following groups, taken alone or in mixtures:

[0133] Other preferred compounds corresponding to formula (III) are such that: y is equal to 0, Z represents Z 1 and R represents a saturated, linear hydrocarbon chain of 1 to 22 carbon atoms, preferably of 8 to 12 carbon atoms.

[0134] According to a fourth variant, the organogelating compound is a reaction product of at least one C 3 -C 12 polyol and at least one C 2 -C 12 aldehyde. Among the polyols which may be used, mention may be made of sorbitol, xylitol, mannitol and / or ribitol. Preferably, the polyol is sorbitol.

[0135] Advantageously, according to this variant, the organogelating compound is a compound which comprises at least one function of general formula (IV): with : x is an integer, R is chosen from a C 1 -C 12 alkyl, C 2 -C 12 alkenyl, C 6 -C 12 aryl, or C 7 -C 12 aralkyl radical, optionally substituted by one or more halogen atoms, one or more C 1 -C 6 alkoxy groups.

[0136] According to this variant, the organogelating compound is advantageously a sorbitol derivative. By "sorbitol derivative" is meant any reaction product obtained from sorbitol. In particular, any reaction product obtained by reacting an aldehyde with D-sorbitol. This condensation reaction produces sorbitol acetals, which are sorbitol derivatives. 1,3:2,4-Di-O-benzylidene-D-sorbitol is obtained by reacting 1 mole of D-sorbitol and 2 moles of benzaldehyde and has the formula:

[0137] Sorbitol derivatives can thus be all condensation products of aldehydes, in particular aromatic aldehydes with sorbitol. We will then obtain sorbitol derivatives with the general formula: where Ar 1 and Ar 2 are optionally substituted aromatic rings.

[0138] Among the derivatives of sorbitol, other than 1,3:2,4-Di-O-benzylidene-D-sorbitol, we can find for example 1,3:2,4:5,6-tri-O-benzylidene-D-sorbitol, 2,4-mono-O-benzylidene-D-sorbitol, 1,3:2,4-bis(p-methylbenzylidene) sorbitol, 1,3:2,4-bis(3,4-dimethylbenzylidene) sorbitol, 1,3:2,4-bis(p-ethylbenzylidene) sorbitol, 1,3:2,4-bis(p-propylbenzylidene) sorbitol, 1,3:2,4-bis(p-butylbenzylidene) sorbitol, 1,3:2,4-bis(p-ethoxylbenzylidene) sorbitol, 1,3:2,4-bis(p-chlorobenzylidene) sorbitol, 1,3:2,4-bis(p-bromobenzylidene) sorbitol, 1,3:2,4-Di-O-methylbenzylidene-D-sorbitol, 1,3:2,4-Di-O-dimethylbenzylidene-D-sorbitol, 1,3:2,4-Di-O-(4-methylbenzylidene)-D-sorbitol, 1,3:2,4-Di-O-(4,3-dimethylbenzylidene)-D-sorbitol. Preferably, according to this variant, the organogelating compound is 1,3:2,4-Di-O-benzylidene-D-sorbitol.

[0139] According to a fifth variant, the organogelling compound is a compound of general formula (V): R''-(COOH) z (V), in which R'' represents a linear or branched, saturated or unsaturated chain comprising from 4 to 68 carbon atoms, preferably from 4 to 54 carbon atoms, more preferably from 4 to 36 carbon atoms and z is an integer ranging from 2 to 4.

[0140] Preferably, the group R'' is a saturated linear chain of formula C w H 2w with w an integer ranging from 4 to 22, preferably from 4 to 12.

[0141] According to this variant of the invention, the organogelling compounds corresponding to formula (V) can be diacids (z = 2), triacids (z = 3) or tetraacids (z = 4). The preferred organogelling compounds according to this variant are diacids with z = 2.

[0142] Preferably, according to this variant, the diacids (V) have the general formula HOOC-C w H 2w -COOH with w an integer ranging from 4 to 22, preferably from 4 to 12.

[0143] Advantageously, according to this variant, the organogelating compound is a diacid chosen from adipic acid or 1,6-hexanedioic acid with w = 4, pimelic acid or 1,7-heptanedioic acid with w = 5, suberic acid or 1,8-octanedioic acid with w = 6, azelaic acid or 1,9-nonanedioic acid with w = 7, sebacic acid or 1,10-decanedioic acid with w = 8, undecanedioic acid with w = 9, 1,2-dodecanedioic acid with w = 10 or tetradecanedioic acid with w = 12. More advantageously, the organogelating compound is sebacic acid or 1,10-decanedioic acid with w = 8.

[0144] Diacids can also be diacid dimers of unsaturated fatty acid(s), i.e. dimers formed from at least one unsaturated fatty acid, for example from a single unsaturated fatty acid or from two different unsaturated fatty acids. Diacid dimers of unsaturated fatty acid(s) are conventionally obtained by intermolecular dimerization reaction of at least one unsaturated fatty acid (Diels Alder reaction for example).

[0145] Preferably, only one type of unsaturated fatty acid is dimerized. They are derived in particular from the dimerization of an unsaturated fatty acid, in particular C 8 to C 34 , in particular C 12 to C 22 , in particular C 16 to C 20 , and more particularly C 18 . A preferred fatty acid dimer is obtained by dimerization of linoleic acid, which can then be partially or totally hydrogenated.

[0146] Another preferred fatty acid dimer has the formula HOOC-(CH 2 ) 7 -CH=CH-(CH 2 ) 7 -COOH. Another preferred fatty acid dimer is obtained by dimerization of methyl linoleate. Similarly, fatty acid triacids and fatty acid tetraacids may be found, obtained respectively by trimerization and tetramerization of at least one fatty acid.

[0147] According to a sixth variant, the organogelating compound is a compound of general formula (VI): in which, the groups Y and Y' represent, independently of one another, an atom or group chosen from: H, -(CH 2 ) q -CH 3 , -(CH 2 ) q -NH 2 , -(CH 2 ) q -OH, - (CH 2 ) q -COOH or with q an integer varying from 2 to 18, preferably from 2 to 10, preferably from 2 to 4 and p an integer greater than or equal to 2, preferably having a value of 2 or 3.

[0148] Among the preferred organogelating compounds corresponding to formula (VI), the following compounds may be mentioned:

[0149] Preferably, according to this variant, the organogelating compound of general formula (VI) is:

[0150] According to a seventh variant of this embodiment, the organogelling compound is a compound of general formula (VII): R-NH-CO-CO-NH-R' (VII) in which, R and R', identical or different, represent a saturated or unsaturated, linear, branched or cyclic hydrocarbon chain, comprising from 1 to 22 carbon atoms, preferably from 8 to 12 carbon atoms, optionally substituted, and optionally comprising heteroatoms, such as N, O, S, C 5 -C 24 hydrocarbon cycles and / or C 4 -C 24 hydrocarbon heterocycles comprising one or more heteroatoms such as N, O, S.

[0151] It will not be outside the scope of the invention to combine several different chemical additives such as different organogelling compounds of formula (I), (II), (III), (V), (VI) and (VII), the reaction products of at least one C 3 -C 12 polyol and at least one C 2 -C 12 aldehyde, in particular those comprising a group of formula (IV), in the binder.

[0152] Advantageously, the binder comprises at least one organogelling additive chosen from the compounds of formula (I), the compounds of formula (II) and the compounds of formula (V).

[0153] More advantageously, the binder comprises at least one organogelling additive chosen from the compounds of formula (I) or the compounds of formula (II).

[0154] Preferably, the binder comprises an organogelling additive wherein the additive is 2',3-bis[(3-[3, 5-di- tert -butyl-4-hydroxyphenyl]propionyl)]propionohydrazide.

[0155] According to an advantageous embodiment, the binder according to the invention comprises at least two organogelling compounds.

[0156] According to a first variant of this embodiment, the binder according to the invention comprises at least one first organogelling compound of formula (V) and at least one second organogelling compound chosen from: the organogelling compounds of formula (I); the organogelling compounds of formula (II); the organogelling compounds of formula (III); the organogelling compounds of formula (V); the organogelling compounds of formula (VI); the organogelling compounds of formula (VII) and the reaction products of at least one C 3 -C 12 polyol and at least one C 2 -C 12 aldehyde, in particular those comprising a group of formula (IV), the second organogelling compound being distinct from the first organogelling compound.

[0157] Preferably, and according to this first variant, the binder according to the invention comprises at least one first organogelling compound of formula (V) and at least one second organogelling compound chosen from: the organogelling compounds of formula (I) and the organogelling compounds of formula (II).

[0158] When the second organogelating compound is chosen from organogelating compounds of formula (II), it is preferably chosen from organogelating compounds of formula (IIA).

[0159] Preferably, and still according to this first variant, the first organogelating compound of formula (V) is chosen from diacids (z=2), triacids (z=3) and tetracids (z=4), preferably from diacids (z=2).

[0160] More preferably, and still according to this first variant, the first organogelating compound of formula (V) is chosen from adipic acid or 1,6-hexanedioic acid with w = 4, pimelic acid or 1,7-heptanedioic acid with w = 5, suberic acid or 1,8-octanedioic acid with w = 6, azelaic acid or 1,9-nonanedioic acid with w = 7, sebacic acid or 1,10-decanedioic acid with w = 8, undecanedioic acid with w = 9, 1,2-dodecanedioic acid with w = 10 or tetradecanedioic acid with w = 12.

[0161] Advantageously, and according to this first variant, the first organogelating compound of formula (V) is sebacic acid or 1,10-decanedioic acid with w = 8.

[0162] According to a second variant of this embodiment, the binder according to the invention comprises at least one first organogelling compound of formula (II) and at least one second organogelling compound chosen from: the organogelling compounds of formula (I); the organogelling compounds of formula (II); the organogelling compounds of formula (III); the organogelling compounds of formula (V); the organogelling compounds of formula (VI); the organogelling compounds of formula (VII) and the reaction products of at least one C 3 -C 12 polyol and at least one C 2 -C 12 aldehyde, in particular those comprising a group of formula (IV), the second organogelling compound being distinct from the first organogelling compound.

[0163] Preferably, and according to this second variant, the first organogelling compound of formula (II) is chosen from the organogelling compounds of formula (IIA).

[0164] More preferably, and according to this second variant, the binder according to the invention comprises at least one first organogelling compound of formula (IIA) and at least one second organogelling compound chosen from: organogelling compounds of formula (I); organogelling compounds of formula (IIB); organogelling compounds of formula (III); organogelling compounds of formula (V); organogelling compounds of formula (VI); organogelling compounds of formula (VII) and the reaction products of at least one C 3 -C 12 polyol and at least one C 2 -C 12 aldehyde, in particular those comprising a group of formula (IV), the second organogelling compound being distinct from the first organogelling compound.

[0165] Even more preferably, and according to this second variant, the binder according to the invention comprises at least one first organogelling compound of formula (IIA) and at least one second organogelling compound chosen from: the organogelling compounds of formula (I) and the organogelling compounds of formula (V).

[0166] Preferably, and according to this second variant, the first organogelling compound of formula (II) is N,N'-ethylenedi(stearamide).

[0167] When the second organogelating compound is selected from organogelating compounds of formula (V), it is preferably selected from adipic acid or 1,6-hexanedioic acid with w = 4, pimelic acid or 1,7-heptanedioic acid with w = 5, suberic acid or 1,8-octanedioic acid with w = 6, azelaic acid or 1,9-nonanedioic acid with w = 7, sebacic acid or 1,10-decanedioic acid with w = 8, undecanedioic acid with w = 9, 1,2-dodecanedioic acid with w = 10 or tetradecanedioic acid with w = 12.

[0168] According to a third preferred variant of this embodiment, the binder according to the invention comprises at least sebacic acid or 1,10-decanedioic acid and at least N,N'-ethylenedi(stearamide).

[0169] According to a fourth variant of this embodiment, the binder according to the invention comprises at least one first organogelling compound of formula (I) and at least one second organogelling compound chosen from: the organogelling compounds of formula (I); the organogelling compounds of formula (II); the organogelling compounds of formula (III); the organogelling compounds of formula (V); the organogelling compounds of formula (VI); the organogelling compounds of formula (VII) and the reaction products of at least one C 3 -C 12 polyol and at least one C 2 -C 12 aldehyde, in particular those comprising a group of formula (IV), the second organogelling compound being distinct from the first organogelling compound.

[0170] Preferably, and according to this fourth variant, the second organogelling compound is chosen from the organogelling compounds of formula (II) and the organogelling compounds of formula (V).

[0171] Preferably, and according to this fourth variant, when the second organogelling compound is chosen from the organogelling compounds of formula (II), it is chosen from the organogelling compounds of formula (IIA).

[0172] More preferably, and according to this fourth variant, the second organogelating compound of formula (II) is N,N'-ethylenedi(stearamide).

[0173] Preferably, and still according to this fourth variant, when the second organogelating compound is chosen from the organogelating compounds of formula (V), it is chosen from the diacids (z=2), the triacids (z=3) and the tetracids (z=4), preferably from the diacids (z=2).

[0174] Even more preferably, and still according to this fourth variant, the second organogelating compound of formula (V) is chosen from adipic acid or 1,6-hexanedioic acid with w = 4, pimelic acid or 1,7-heptanedioic acid with w = 5, suberic acid or 1,8-octanedioic acid with w = 6, azelaic acid or 1,9-nonanedioic acid with w = 7, sebacic acid or 1,10-decanedioic acid with w = 8, undecanedioic acid with w = 9, 1,2-dodecanedioic acid with w = 10 or tetradecanedioic acid with w = 12.

[0175] Advantageously, and still according to this fourth variant, the second organogelating compound of formula (V) is sebacic acid or 1,10-decanedioic acid.

[0176] Preferably, and according to this fourth variant, the first organogelating compound of formula (I) is 2',3-bis[(3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide.

[0177] Preferably, and according to this embodiment, the mass ratio of the first organogelating compound relative to the second organogelating compound is from 1:99 to 99:1, preferably from 1:9 to 9:1, even more preferably from 1:5 to 5:1.

[0178] Advantageously, the binder comprises from 0.1% to 10% by mass, preferably from 0.2% to 5% by mass, more preferably from 0.5% to 3.5% by mass of organogelating compound relative to the total mass of the binder. Solid binder at room temperature and in divided form

[0179] The binder is solid at room temperature and in divided form. It includes the oil, possibly the pitch and the organogelling additive(s) and, if applicable, other additives.

[0180] According to a first embodiment, the binder does not comprise pitch: Advantageously, according to this embodiment, the binder comprises, or is essentially composed of: 80% to 99.9% by mass of at least one oil chosen from: hydrocarbon oils of petroleum or synthetic origin, 0.1% to 10% by mass of at least one organogelling chemical additive, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder.

[0181] Preferably, the binder comprises, or is essentially composed of: 85% to 99.8% by mass of at least one oil, chosen from: hydrocarbon oils of petroleum or synthetic origin, 0.2% to 5% by mass of at least one organogelling chemical additive, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder.

[0182] More preferably, the binder comprises, or is essentially composed of: 86.5% to 99.5% by mass of at least one oil chosen from: hydrocarbon oils of petroleum or synthetic origin, 0.5% to 3.5% by mass of at least one organogelling chemical additive, 0% to 10% by mass of one or more other additives relative to the total mass of the binder.

[0183] According to a preferred variant, the organogelating compound is chosen from those corresponding to formula (I), in particular 2',3-bis[(3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide.

[0184] Advantageously, the binder comprises, or is essentially composed of: 85% to 99.9% by mass of at least one hydrocarbon oil of petroleum origin, 0.1% to 5% by mass of at least one organogelling chemical additive of formula (I), advantageously 2',3-bis[(3-[3, 5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder.

[0185] Preferably, the binder comprises, or is essentially composed of: 86.5% to 99.8% by mass of at least one hydrocarbon oil of petroleum origin, 0.2% to 3.5% by mass of at least one organogelling chemical additive of formula (I), advantageously 2',3-bis[(3-[3, 5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder.

[0186] According to a second embodiment, the composition comprises pitch: Advantageously, according to this embodiment, the binder comprises, or is essentially composed of: 90% to 10% by mass of at least one oil chosen from: hydrocarbon oils of petroleum or synthetic origin, 10% to 90% by mass of at least one pitch 0.1% to 10% by mass, of at least one organogelling chemical additive, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder.

[0187] Preferably, the binder comprises, or is essentially composed of: 10% to 70% by mass of at least one oil, chosen from: hydrocarbon oils of petroleum or synthetic origin, 90% to 30% by mass of at least one pitch, 0.2% to 5% by mass of at least one organogelling chemical additive, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder.

[0188] More preferably, the binder comprises, or is essentially composed of: 15% to 50% by mass of at least one oil chosen from: hydrocarbon oils of petroleum or synthetic origin, 50% to 85% by mass of at least one pitch, 0.5% to 3.5% by mass of at least one organogelling chemical additive, 0% to 10% by mass of one or more other additives relative to the total mass of the binder.

[0189] According to a preferred variant, the organogelating compound is chosen from those corresponding to formula (I), in particular 2',3-bis[(3-[3,5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide.

[0190] Advantageously according to this variant, the binder comprises, or is essentially composed of: 10% to 70% by mass of at least one hydrocarbon oil of petroleum origin, 30% to 90% by mass of at least one pitch, 0.1% to 5% by mass of at least one organogelling chemical additive of formula (I), advantageously 2',3-bis[(3-[3, 5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder.

[0191] Preferably, the binder comprises, or is essentially composed of: 15% to 50% by mass of at least one hydrocarbon oil of petroleum origin, 50% to 85% by mass of at least one pitch 0.2% to 3.5% by mass, of at least one organogelling chemical additive of formula (I), advantageously 2',3-bis[(3-[3, 5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide, 0% to 10% by mass of one or more other additives, relative to the total mass of the binder. Other additives

[0192] According to a variant of the invention, it is possible to incorporate into the binder all kinds of additives usually used for the formulation, depending on the intended application, provided that these additives do not hinder the solidification of the binder composition.

[0193] The amount of additive in the binder is calculated based on the amount of oil and pitch that will be used for the intended application and the amount of additive expected in that application. Typically, additives are incorporated in amounts ranging from 0.1 to 10% by mass relative to the total mass of the binder. Process for preparing the solid binder

[0194] The binders solid at room temperature according to the invention can be prepared for example according to the following process comprising the steps of: (i) Mixing the oil, for example DAO or RAE oil, and heating to a temperature of between 140-200°C, for example from 10 minutes to 30 minutes, (ii) Optionally, introducing the pitch into the oil, and stirring the mixture at a temperature of between 140 and 180°C until a homogeneous mixture is obtained, (iii) Adding the organogelling compound, mixing and heating to a temperature of between 140-200°C, for example from 30 minutes to 2 hours, (iv) Optionally adding one or more other additives, mixing and heating to a temperature of between 140-200°C, for example, from 5 minutes to 20 minutes, (v) Shaping the binder, for example in the form of granules or cakes, (vi) Cooling to room temperature.

[0195] The order of steps (i) to (iv) may be changed. Binder granules solid at room temperature

[0196] For the purposes of the invention, the term "binder granules" may also be defined as a binder that is solid at room temperature and packaged in a divided form, i.e. in the form of small units called balls, granules or particles.

[0197] The binder granules according to the invention are obtained by shaping a binder as described above according to any known method, for example according to the manufacturing method described in document US 3,026,568, document WO 2009 / 153324 or document WO 2012 / 168380. According to a particular embodiment, the shaping of the granules can be carried out by draining, in particular using a drum.

[0198] Other techniques may be used in the process for manufacturing the solid binder granules at room temperature according to the invention, in particular molding, extrusion, etc.

[0199] Preferably, the binder granules according to the invention may have, within the same population of granules, one or more shapes chosen from a cylindrical, spherical or ovoid shape. The size of the binder granules according to the invention is such that the longest average dimension is preferably less than or equal to 50 mm, more preferably from 3 to 30 mm, even more preferably from 5 to 20 mm. The size and shape of the binder granules solid at room temperature may vary depending on the manufacturing process used. For example, the use of a die makes it possible to control the manufacture of granules of a chosen size. Sieving makes it possible to select granules according to their size.

[0200] The binder granules are preferably transported and / or stored in bulk in bags of 1 kg to 30 kg or 500 kg to 1000 kg commonly called “Big Bags”, said bags preferably being made of hot-melt material or in cartons of 5 kg to 30 kg or in drums of 100 kg to 200 kg.

[0201] According to one embodiment of the invention, the binder granules according to the invention are covered on at least part of their surface with an anti-caking agent, preferably on their entire surface. Solid binder block at room temperature

[0202] According to one embodiment of the invention, the binder, which is solid at room temperature and in divided form, is in the form of a loaf. For the purposes of the invention, the binder in the form of a loaf is also referred to as a "binder loaf".

[0203] By solid binder block at room temperature is meant a block of binder according to the invention having a mass of between 1 kg and 1000 kg, preferably between 1 kg and 200 kg, more preferably between 1 kg and 50 kg, even more preferably between 5 kg and 25 kg, even more preferably between 10 kg and 30 kg, said block being advantageously parallelepiped, preferably being a paving stone.

[0204] The binder block according to the invention preferably has a volume of between 1000 cm 3 and 50000 cm 3 , preferably between 5000 cm 3 and 25000 cm 3 , more preferably between 10000 cm 3 and 30000 cm 3 , even more preferably between 14000 cm 3 and 25000 cm 3 .

[0205] When the binder block according to the invention is handled manually by one person, the mass of the oil block can vary from 1 to 20 kg, and from 20 to 50 kg in the case of handling by two people. When handling is carried out by mechanical equipment, the mass of the binder block according to the invention can vary from 50 to 1000 kg.

[0206] The binder block according to the invention is manufactured from the binder as described above according to any industrially known process, for example by extrusion, by molding, or according to the manufacturing process described in document US2011 / 0290695.

[0207] The binder block according to the invention is advantageously packaged in a hot-melt film according to any known method, preferably by a film made of polypropylene, polyethylene or a mixture of polyethylene and polypropylene. The binder according to the invention packaged in a block wrapped in a hot-melt film has the advantage of being ready to use, that is to say that it can be directly heated in the melter without prior unpacking, for example for the manufacture of new bituminous mixes obtained from recycled bituminous mix aggregates. The hot-melt material which melts with the binder according to the invention does not affect the properties of said binder.

[0208] The binder block according to the invention can also be covered with an anti-caking compound as defined below.

[0209] In this variant, the preferences, advantages, and different embodiments described for the anti-caking compounds also apply.

[0210] The binder block according to the invention can also be packaged in a cardboard box using any known method.

[0211] In particular, the binder block according to the invention is packaged in a cardboard by hot-pouring the binder according to the invention into a cardboard whose inner wall is silicone-coated and then cooled, the dimensions of the cardboard being adapted to the mass and / or volume of the desired binder block.

[0212] When the binder block according to the invention is wrapped in a hot-melt film or is packaged in a cardboard box, the applicant has demonstrated that the deterioration of said hot-melt film or said cardboard box during transport and / or storage and / or handling at room temperature of said binder block according to the invention does not cause the binder to flow. Consequently, the binder blocks according to the invention retain their initial shape and do not stick together during their transport and / or storage and / or handling at room temperature despite the fact that the hot-melt film or the cardboard box is damaged. The absence of flow of the binder according to the invention in the form of a block during its transport and / or storage and / or handling at room temperature is due to the presence of the organogelling additive(s) within the binder. The anti-caking compound:

[0213] Optionally, as set out above, the binder according to the invention in divided form which is solid at room temperature, such as for example in the form of granules or blocks of binder which is solid at room temperature, may be partially coated with one or more anti-caking compounds.

[0214] The anti-caking compound is of mineral or organic origin. By "anticaking agent" or "anticaking compound" is meant any compound that limits, reduces, inhibits, delays, the agglomeration and / or adhesion of granules or loaves to each other during their transport and / or storage and / or handling at room temperature and which, in the case of granules, also ensures their fluidity during their handling.

[0215] More preferably, the anti-caking compound is chosen from: talc; fines, also called "fillers", generally with a diameter of less than 125 µm, such as siliceous fines, with the exception of calcareous fines; ultrafines; sand such as Fontainebleau sand; cement; carbon; wood residues such as lignin, lignosulfonate, conifer needle powders, conifer cone powders, in particular pine; rice husk ash; glass powder; clays such as kaolin, bentonite, vermiculite; alumina such as alumina hydrates; silica; silica derivatives such as silicates, silicon hydroxides and other silicon oxides; silica fumes; plastic powder; lime; plaster; rubber crumb;polymer powder, such as styrene-butadiene (SB) copolymers, styrene-butadiene-styrene (SBS) copolymers and mixtures of these materials.;

[0216] Advantageously, the anti-caking compound is chosen from: fines, generally with a diameter of less than 125 µm; wood residues such as lignin, conifer needle powders and conifer cone powders; silica fumes; mixtures thereof.

[0217] Preferably, the anti-caking compound is chosen from silica fumes.

[0218] For the purposes of the invention, the compounds "silica fume" and "pyrogenic silica" have the same chemical definition and are registered under the same CAS number 112 945-52-5. Consequently, for the purposes of the invention, these compounds can be used interchangeably. By "pyrogenic silica" is meant either a pyrogenic silica or a pyrogenic silica derivative.

[0219] "Fumed silica" means a compound obtained by the vapor-phase hydrolysis of chlorosilanes such as silicon tetrachloride, in an oxygen and hydrogen flame. Such processes are generally referred to as pyrogenic processes, the overall reaction of which is: SiCl 4 + H 2 + O 2 → SiO 2 + 4 HCl.

[0220] Fumed silicas differ from other silicon dioxides in that they have an amorphous structure. They are highly pure (> 99.8% silica) and have low hydrophilicity (no microporosity).

[0221] Preferably, the fumed silica compound is fumed silica.

[0222] According to one embodiment of the invention, the pyrogenic silica compound has a specific surface area of ​​between 25 and 420 m 2 < / g, preferably between 90 and 330 m 2 < / g, more preferably between 120 and 280 m 2 < / g.

[0223] The specific surface area of ​​fumed silica defined in m 2 < / g commonly called "surface area" or "SA" is measured according to the method of S. Brunauer, PH Emmet and I. Teller, J. Am. Chemical Society, 60: 309 (1938) (BET).

[0224] According to one embodiment of the invention, the fumed silica compound has an average particle size of between 5 and 50 nm.

[0225] According to one embodiment of the invention, the fumed silica compound has a pH of between 3 and 10 when it is in aqueous phase.

[0226] According to one embodiment of the invention, the fumed silica compound has a carbon content of between 0.1 and 10% by weight relative to the total weight of the fumed silica compound.

[0227] According to one embodiment of the invention, the fumed silica compound is chosen from a hydrophilic fumed silica compound, a hydrophobic fumed silica compound and mixtures thereof.

[0228] Preferably, the fumed silica compound is a hydrophilic fumed silica compound.

[0229] By "hydrophilic" is meant a compound that is miscible with water in all proportions.

[0230] The fumed silica compound, or fumed silica derivative, used in the sense of the invention may be chemically modified.

[0231] Different types of fumed silica compounds are described in the following patent applications and can be used in the present invention: silanized fumed silicas, as described in WO 2004 / 020532, or in WO 2007 / 128636, hydrophilic fumed silicas, as described in WO 2009 / 071467, WO 2011 / 000133 filed in the name of Degussa AG or Degussa Gmbh, silica fumes rendered hydrophobic by treatment with polysiloxanes as described in WO 2008 / 141932, or by silanization as described in WO 2008 / 141930, silicas doped with potassium oxide as described in WO 2008 / 043635, WO 2008 / 022836, silicas in the form of aggregates of primary particles as described in WO 2009 / 015969 filed in the name of Evonik Degussa Gmbh or in WO 2010 / 028261 filed in the name of Cabot Corporation.

[0232] The fumed silica compound can be implemented alone or in the form of a mixture within a coating composition.

[0233] Whether used alone or as a mixture in a composition, the fumed silica compound can be used in the process according to the invention in the form of a powder or in dispersion in a solvent which evaporates after application.

[0234] Preferably, when the coating composition comprises at least one fumed silica compound and at least one solvent, the coating composition comprises from 5 to 70% by weight of fumed silica compound relative to the total weight of the coating composition, more preferably from 20 to 40% by weight.

[0235] Preferably, the solvent is an organic solvent or water. By organic solvent is meant any solvent immiscible with a bitumen, such as an alcohol, for example ethanol.

[0236] The silica fumes used in the invention are commercially available and for example can be sold by Evonik Degussa under the brand name AEROSIL ®< , such as for example AEROSIL ®< 200, by Cabot Corporation under the brands CAB-O-SIL ®< and CAB-O-SPERSE ®< or by Wacker Chemie AG under the brand name HDK ®< .

[0237] Preferably, the mass of the anti-caking agent covering at least part of the surface of the granules or the binder loaves is between 0.2% and 10% by mass, preferably between 0.5% and 8% by mass, more preferably between 0.5% and 5% relative to the total mass of binder according to the invention, in said granules or said loaves or said balls.

[0238] The layer of anti-caking agent covering the granules or binder blocks according to the invention is preferably continuous so that at least 90% of the surface of the granule or binder block according to the invention is covered with at least one anti-caking agent, preferably at least 95%, more preferably at least 99%. The layer of anti-caking agent must be sufficiently thick so that it is continuous.

[0239] The granules or blocks of binder solid at room temperature are coated with the anti-caking agent according to any known method, for example according to the method described in document US 3,026,568. Cold and split solid binder kit

[0240] Another object of the invention relates to a kit comprising at least: a cold-solid binder in divided form as defined above, a capsule comprising at least one additive as defined above.

[0241] According to one embodiment of the invention, the binder which is solid when cold and in divided form is in the form of a cake.

[0242] According to one embodiment of the invention, the binder in the form of a block comprises on one of its faces, a cavity allowing all or part of the capsule to be housed.

[0243] According to one embodiment of the invention, the capsule is housed in whole or in part in the cavity in a removable manner.

[0244] According to this embodiment, the capsule may be a soft-shell capsule, in particular a sachet, or a hard-shell capsule.

[0245] Preferably, the capsule is made of heat-melting plastic film, particularly polyethylene, or silicone.

[0246] Another object of the invention relates to the use of the kit as defined above in the process for preparing a binder ready for application according to the invention.

[0247] According to one embodiment of the invention, the binder in the form of a cake and the capsule forming the kit as defined above are used in the process for preparing a binder simultaneously or consecutively.

[0248] In a variant, when the binder in the form of a bar and the capsule forming the kit as defined above are used consecutively in the process for preparing a binder, said binder in the form of a bar is heated beforehand and then the capsule is added. In this variant, before heating the binder bar, the capsule is dislodged from the cavity present on one of the faces of the bar.

[0249] In another variant, the binder in the form of a cake and the capsule forming the kit as defined above are used simultaneously in the process for preparing a binder. Method of transporting and / or storing and / or handling the solid binder at room temperature and in divided form

[0250] Another subject of the invention also relates to a method for transporting and / or storing and / or handling the binder which is solid at room temperature and in divided form, the binder being transported and / or stored and / or handled in the form of binder loaves or granules which are solid at room temperature. The binder which is solid at room temperature and in divided form is as described above.

[0251] Preferably, the additive binder of the invention is transported and / or stored at room temperature for a period greater than or equal to 2 months, preferably 3 months.

[0252] According to one embodiment of the invention, the solid binder at room temperature of the invention is transported and / or stored at a temperature below 80°C. In particular, the transport and / or storage temperature corresponds to room temperature. Room temperature is understood to mean the temperature which is reached during the transport and / or storage of the binder according to the invention without said binder being heated by any type of process. Thus, the room temperature can reach high temperatures, below 80°C during summer periods, in particular in geographical regions with a hot climate.

[0253] Advantageously, the ambient temperature is from 5°C to 70°C, preferably from 10°C to 70°C, more preferably from 10°C to 60°C, even more preferably from 15°C to 50°C.

[0254] The solid binders at room temperature and in divided form according to the present invention are remarkable in that they allow the transport and / or storage and / or handling of binders at room temperature under optimal conditions, in particular without there being any creep of said solid binders during their transport and / or storage and / or handling, even when the room temperature is high and without degrading the properties of the binder, or even improving them.

[0255] The binder granules are preferably transported and / or stored and / or handled in bulk in bags of 1 kg to 100 kg or 500 kg to 1000 kg commonly referred to in the field of road bitumens as "Big Bags", said bags preferably being made of hot-melt material. They can also be transported and / or stored in bulk in boxes of 5 kg to 30 kg or in drums of 100 kg to 200 kg. Use of solid binders at room temperature as a rejuvenator for bituminous coatings

[0256] Bituminous mixes are used as materials for the construction and maintenance of road surfaces and their coverings, as well as for carrying out all road works. Examples include surface dressings, hot mixes, cold mixes, cold-poured mixes, emulsified gravel, base, bonding, tack and surface courses, and other combinations of a bituminous binder and road aggregate with specific properties, such as anti-rutting layers, draining mixes, or asphalts (a mixture of a bituminous binder and sand-type aggregates).

[0257] As is known, the layers of bituminous mixes that have been removed from roads or pavements, for example, are crushed before being reused. They are called recycled bituminous mix aggregates. The solid binders according to the invention can be used for the manufacture of new bituminous mixes from recycled bituminous mix aggregates. The solid binders according to the invention have the property of fluidifying the aggregated bituminous residues around the aggregates forming the recycled bituminous mix aggregates, of increasing the adhesiveness of the bituminous composition composed of binder and bituminous residues and their cohesion around the aggregates. The solid binders according to the invention make it possible to reduce the application temperature of bituminous mixes formed from asphalt aggregates.By facilitating the mixing and homogenization of the compositions resulting from the asphalt aggregates, they make it possible to form a bituminous asphalt with a substantially homogeneous composition and mechanical properties substantially identical to those of bituminous asphalts obtained solely with bitumen that has never been used to form bituminous asphalts.

[0258] Another subject of the invention relates to a method for manufacturing bituminous coatings from recycled bituminous coating aggregates, this method comprising at least the steps of: heating the recycled bituminous mix aggregates to a temperature ranging from 100°C to 180°C, preferably from 120°C to 160°C in a tank such as a mixer or a mixer drum, introducing and mixing the solid binder according to the invention, obtaining bituminous mixes.

[0259] The method of the invention has the advantage of being able to be implemented without a prior step of heating the solid binder granules.

[0260] The process for manufacturing asphalt mixes according to the invention does not require a step of heating the solid binder granules before mixing with the recycled asphalt aggregates because upon contact with the hot aggregate mix, the solid binder melts at room temperature.

[0261] The binder solid at room temperature according to the invention as described above has the advantage of being able to be added directly to the hot recycled bituminous mix aggregates, without having to be melted prior to mixing with the recycled bituminous mix aggregates.

[0262] The solid binder in divided form according to the present invention is remarkable in that it allows the transport and / or storage of the binder at room temperature under optimal conditions, in particular without there being agglomeration and / or adhesion of the solid binder during its transport and / or storage and / or handling, even when the room temperature is high. Furthermore, the presence of organogelling additives in the mixture of binder and recycled bituminous mix aggregates does not degrade the properties of the bituminous mixes obtained for a road application, compared to a non-additive binder.

[0263] The various embodiments, variations, preferences and advantages described above for each of the objects of the invention apply to all of the objects of the invention and may be taken separately or in combination.

[0264] The invention is illustrated by the following examples given without limitation. Experimental part:

[0265] In these Examples, parts and percentages are by weight unless otherwise indicated. I- Raw materials Oil :

[0266] Régénis 50 ®<: RAE oil, i.e. an aromatic oil, marketed by the company TOTAL under the brand Régénis 50 ®<. Organogelator : We used:

[0267] Compound A1: 2',3-bis[(3-[3, 5-di-tert-butyl-4-hydroxyphenyl]propionyl)]propionohydrazide (CAS 32687-78-8) marketed by BASF under the brand name Irganox MD 1024 Brai: We used:

[0268] A pitch resulting from a deasphalting operation by the addition of propane and having a ring and ball softening temperature (RBT) of 59.6°C and a penetrability at 25°C of 14 1 / 10 mm. II- Characterization methods

[0269] Penetrability: standard NF EN 1426 at 25°C. Ring and ball softening temperature (RBT): standard EN 1427. III- Preparation of binder according to the invention

[0270] The binders according to the invention are prepared according to the following general process: (i) The oil is heated to 170°C; (ii) The pitch is introduced into the oil and mixed for 30 minutes at a stirring speed of 400 rpm while maintaining the temperature of the mixture at 170°C; (ii) The organogelator compound is added and mixed for 1 hour at 170°C at a stirring speed of 400 rpm; (iii) When the organogelator additive is completely dissolved, stirring is stopped and the liquid is poured into molds and then left to cool to room temperature.

[0271] Solid binder compositions at room temperature C 0 , C 1 And C 2 according to the invention are prepared according to the protocol described above with constituents and proportions (in mass percentage relative to the total mass of the binder compositions prepared) indicated in the following Table 1: Table 1 Composition C 0 C 1 C 2 Oil 17% 17% 17% Pitch 83% 82,2% 81% Compound A1 - 0,8% 2%

[0272] The compositions C 1 And C 2 are according to the invention. The composition C 0 is comparative. IV- Preparation of solid binder blocks

[0273] The binder compositions prepared above are poured directly into a mold while hot and then left to cool to room temperature. After observing the solidification of the compositions in the mold, the compositions are removed from the mold and the compositions are obtained in the form of a solid block at room temperature. V- Preparation of solid binder granules

[0274] The granules G 0 , G 1 And G 2 are prepared respectively from the compositions C 0 , C 1 And C 2 according to one of the two equivalent protocols described below. 5.1 General method for the preparation of solid binder granules at room temperature

[0275] Solid binder compositions C 0 , C 1 And C 2 , prepared previously, are heated to 160°C for two hours in an oven before being poured into a silicone mold with various spherical holes to form binder granules. After observing the solidification of the binder in the mold, the excess is leveled with a blade heated with a Bunsen burner. After 30 minutes, the solid binder in the form of granules is removed from the mold and stored in a tray covered with silicone paper. The granules are then left to cool at room temperature for 10 to 15 minutes. 5.2 General method for the preparation of solid binder granules at room temperature using an industrial process

[0276] For the implementation of this method, a device and a method as described in great detail in US patent 4,279,579 can be used. Different models of this device are commercially available from the Sandvik company under the trade name Rotoform.

[0277] Solid binder granules can also be obtained from the binder compositions C 0 , C 1 And C 2 poured into the tank of such a device and maintained at a temperature between 130 and 180°C.

[0278] One or more injection nozzles allow(s) the transfer of the binder composition C 0 , C 1 Or C 2 inside the double pelletizing drum comprising a rotating outer drum, the two drums being equipped with slots, nozzles and orifices allowing the pelletization of binder drops through the first fixed drum and the orifices having a diameter between 2 and 8 mm of the rotating outer drum. The binder drops are deposited on the upper face of a horizontal rolling belt, driven by rollers. VI- Storage stability

[0279] This test is carried out to assess the load resistance of binder granules G 0 , G 1 And G 2 prepared above at a temperature of 65°C under a compressive force. In fact, this test makes it possible to simulate the temperature and compression conditions of the granules on each other to which they are subjected during transport and / or bulk storage in bags of 10 to 100 kg or in Big Bags of 500 to 1000 kg or in drums of 200 kg and to evaluate their resistance under these conditions.

[0280] The load resistance test is carried out according to the following protocol: 5 mL of granules are placed in a 20 mL syringe then the piston is placed on the granules as well as a mass of 208g, representing a force applied as in a Big Bag. The whole is placed in an oven at 65°C for at least 4 hours. The observations are listed in Table 2 below. Table 2 Granules G 0 G 1 G 2 Store at room temperature at 65°C -- + ++ +++: The granules retain their original shape and do not adhere to each other. ++: The granules do not adhere to each other but are slightly deformed. + The granules adhere slightly to each other. -: The granules are partially melted. -: The granules are melted.

[0281] The granules G 1 And G 2 have very good resistance to an ambient temperature of 60°C since they adhere very little or not at all to each other. The granules G 2 are advantageous in that they do not adhere to each other at all. Thus, the handling and transport / storage of said granules G 1 And G 2 will be easy since the granules clump very little, if at all, at high room temperature.

Claims

1. A binder solid at ambient temperature, comprising: • at least one hydrocarbon oil chosen from among aromatic oils having a content of aromatic compounds between 30 and 95 weight %, • at least one pitch, • at least one chemical organogelator additive.

2. The binder according to claim 1, wherein the hydrocarbon oil is chosen from among hydrocarbon oils of petroleum origin.

3. The binder according to any of the preceding claims, wherein the hydrocarbon oil is chosen from aromatic oils having a content of aromatic compounds between 50 and 95 weight %, more advantageously between 60 and 95 weight % relative to the total weight of the aromatic oil.

4. The binder according to claim 3, wherein the aromatic oil has kinematic viscosity at 100 °C between 0.1 and 150 mm2 / s, advantageously between 5 and 120 mm2 / s, more advantageously between 7 and 90 mm2 / s.

5. The binder according to any of the preceding claims, wherein the pitch has a penetration value at 25°C ranging from 0 to 20 1 / 10, on the understanding that penetration is measured according to standard EN 1426.

6. The binder according to claim 5, wherein the pitch has a Ring-and-Ball softening point measured according to standard EN 1427 ranging from 55°C to 110°C.

7. The binder according to any of the preceding claims, wherein the organogelator compound has a molar mass lower than or equal to 2000 gmol-1.

8. The binder according to any of the preceding claims comprising from 0.2 to 5 weight %, more preferably from 0.5 to 3.5 weight % of organogelator additive relative to the total weight of the binder.

9. The binder according to any of the preceding claims, in the form of granules or blocks.

10. A kit comprising at least: - a binder solid at ambient temperature according to any of claims 1 to 9, - a capsule comprising at least one additive.

11. A process to prepare a binder solid at ambient temperature according to any of claims 1 to 9, comprising: i. mixing the oil and pitch, and heating to a temperature of between 140 and 200°C; ii. adding the organogelator compound, mixing and heating to a temperature of between 140 and 200°C; iii. optionally adding one or more other additives, mixing and heating to a temperature of between 140 and 200°C; iv. forming the composition for example in the form of granules or blocks; v. cooling to ambient temperature.

12. A method for transporting and / or storing and / or handling a binder solid at ambient temperature and in divided form according to any of claims 1 to 9, or a kit comprising said binder according to claim 10, said binder being transported and / or stored and / or handled in the form of blocks or granules solid at ambient temperature.

13. Use of a binder solid at ambient temperature and in divided form comprising: • at least one oil chosen from hydrocarbon oils chosen from among aromatic oils having a content of aromatic compounds between 30 and 95 weight %; • at least one chemical organogelator additive, for the manufacture of bituminous asphalts comprising recycled bituminous asphalt aggregates.

14. The use according to claim 13, wherein the binder solid at ambient temperature and in divided form is according to any of claims 1 to 9, or in the form of a kit according to claim 10.