The invention provides a double-layer glass curtain wall structure and an intelligent control method and belongs to the field of construction. An intelligent control system with a plurality of control modes is arranged on a double-layer glass curtain wall. Electric opening degree adjusting devices are arranged at a ventilation opening in an inner glass curtain wall body and at a ventilation opening in an outer glass curtain wall body. Ventilating grill sealing devices are arranged on ventilating grills. A temperature and humidity sensor and smoke probes are arranged in a ventilating channel and in a building correspondingly. Flexible sunshade fabric blinds capable of being rolled are arranged on the inner side of the outer glass curtain wall body. The double-layer glass curtain wall structure is provided with a power generation device. According to the double-layer glass curtain wall structure, indoor temperature adjustment can be conducted automatically through the intelligent control system, natural wind is sufficiently utilized for driving the rotary power generation device to generate power, and flexible solar cells are utilized for generating power, so that green energy resources are generated, carbon emission can be reduced, the greenhouse effect is avoided, and green ecology of the building is achieved.