A process for removing color from keratin fibers previously colored with two alkoxysilanes, a film-forming polymer, a nonionic cellulosic polymer, and a coloring agent.

Abstract

Method for removing color from keratin fibers previously colored with two alkoxysilanes, a film-forming polymer, a nonionic cellulosic polymer, and a coloring agent. The present invention relates to a method for removing color from keratin fibers, such as hair, comprising applying at least one color-removing composition to said keratin fibers, which have been previously colored using at least one keratin fiber coloring composition A comprising at least one alkoxysilane selected from compounds of formula (I) or formula (I') and at least one alkoxysilane of formula (II), and at least one keratin fiber coloring composition B comprising at least one film-forming polymer. Said composition A and / or composition B comprise at least one nonionic cellulosic polymer, different from the film-forming polymers.Composition A and / or composition B comprise at least one coloring agent selected from pigments, direct dyes, and mixtures thereof. The color-removing composition comprises at least one surfactant.

Description

Title of the invention: A method for removing color from keratin fibers previously colored with two alkoxysilanes, a film-forming polymer, a nonionic cellulosic polymer, and a coloring agent Technical field of the invention

[0001] The present invention relates to a method for removing color from keratin fibers, such as hair, comprising applying at least one color-removing composition to said keratin fibers, having been previously colored with at least one keratin fiber coloring composition A comprising at least one alkoxysilane selected from compounds of formula (I) or formula (1') and at least one alkoxysilane of formula (II), and at least one keratin fiber coloring composition B comprising at least one film-forming polymer. Said composition A and / or composition B comprise at least one nonionic cellulosic polymer, other than film-forming polymers. Said composition A and / or composition B comprise at least one coloring agent selected from pigments, direct dyes, and mixtures thereof. Said color-removing composition comprises at least one surfactant. Context of the invention

[0002] In the field of staining keratin fibers, particularly human fibers, it is already known to stain keratin fibers by different techniques from direct dyes or pigments for non-permanent staining or from dye precursors for permanent staining.

[0003] There are essentially three types of hair coloring processes:

[0004] a) so-called permanent coloring which has the function of bringing about a significant change in the natural color and which uses oxidation dyes which penetrate the hair fiber and form the dye by a process of oxidative condensation;

[0005] b) non-permanent, semi-permanent or direct coloring, which does not implement the oxidative condensation process and resists 4 or 5 shampoos; consists of dyeing the keratin fibers with dyeing compositions containing direct dyes.

[0006] c) Temporary hair coloring that results in a change to the natural hair color that lasts from one shampoo to the next and serves to enhance or correct a previously achieved shade. It can also be considered a "makeup" process.

[0007] For this latter type of coloring, it is known to use pigments. Indeed, The use of pigment on the surface of keratin fibers generally allows for visible coloring on dark hair, since the surface pigment masks the fiber's natural color. This coloring method also allows for the creation of coloring compositions that offer the advantage of achieving a homogeneous colored coating on keratin fibers, particularly hair, while forming a coating that resists shampooing and various aggressions to which hair can be subjected, such as brushing and / or friction, without damaging the hair.

[0008] However, there are no processes using compositions to effectively remove color with this type of temporary color composition that is residual with shampoos.

[0009] There therefore remains a need for a process enabling the efficient removal of color from keratin fibers such as hair that has been previously colored using said residual coloring compositions in shampoos.

[0010] Thus, the object of the present invention is to develop a process for removing color from keratin fibers, such as hair, with good efficiency. Summary of the invention

[0011] The present invention relates to a method for removing color from keratin fibers, such as hair, previously colored, comprising applying at least one color-removing composition to said keratin fibers previously colored using: a) of at least one composition A for coloring keratinous fibers, such as hair, comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described below, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described below, its oligomers and / or mixtures thereof, and b) of at least one composition B for coloring keratinous fibers, such as hair, comprising: - at least one film-forming polymer, composition A and / or composition B comprising at least one coloring agent selected from pigments, direct colorants, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulosic polymer, different from film-forming polymers, and said composition for removing color comprising at least one surfactant.

[0012] The present invention also relates to the use of the composition for removing color according to the invention, or as it is used in the process According to the invention, to remove the color from keratin fibers, such as hair, that have been previously colored using: a) of at least one composition A for coloring keratinous fibers, such as hair, comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described below, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described below, its oligomers and / or mixtures thereof, and b) of at least one composition B for coloring keratinous fibers, such as hair, comprising: - at least one film-forming polymer, composition A and / or composition B comprising at least one coloring agent selected from pigments, direct colorants, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulosic polymer, different from film-forming polymers.

[0013] The present invention also relates to a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers, comprising several compartments containing: - in a first compartment, a composition A for coloring keratin fibers, such as hair, comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (I') as described below, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described below, its oligomers and / or mixtures thereof, - in a second compartment, composition B comprising: - at least one film-forming polymer, composition A and / or composition B comprising at least one coloring agent selected from pigments, direct colorants, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulosic polymer, different from film-forming polymers, and - in a third compartment, a composition for removing color comprising at least one surfactant.

[0014] By using this process to remove color from previously colored keratin fibers, such as hair, effective color removal is obtained from a strand of hair or an entire head of hair that has been previously colored from the keratin fiber coloring compositions A and B as described above.

[0015] The expression "at least one" means one or more.

[0016] Unless otherwise indicated, the bounds of a range of values ​​are included in that range, in particular in the expressions "between" and "ranging from ... to ...".

[0017] By "keratin fibers", we mean particularly human keratin fibers such as hair, eyelashes, eyebrows, and body hair, preferably hair, eyebrows and eyelashes, even more preferably hair.

[0018] For the purposes of the present invention, "hair" means the hair on the head. This term does not include body hair, eyebrows, or eyelashes.

[0019] For the purposes of this invention, "silicone" means any organosilicon polymer or oligomer with a linear or cyclic, branched or cross-linked structure of variable molecular weight, obtained by polymerization and / or polycondensation of suitably functionalized silanes, and consisting essentially of a repetition of principal motifs in which silicon atoms are linked together by oxygen atoms (siloxane bond -Si-O-Si-), with optionally substituted hydrocarbon radicals being directly linked via a carbon atom to said silicon atoms.

[0020] For the purposes of the present invention and unless otherwise indicated, - an "alkyl" radical refers to a linear or branched, saturated radical, containing for example from 1 to 30 carbon atoms; - an "aminoalkyl" radical refers to an alkyl radical as defined above, said alkyl radical comprising an NH2 group; - a "hydroxyalkyl" radical refers to an alkyl radical as defined above, said alkyl radical comprising an OH group; - an "alkylene" radical refers to a divalent saturated hydrocarbon group in Ci-CiO, linear or branched, such as methylene, ethylene, or propylene; - A "cycloalkyl" or "alicycloalkyl" radical designates a mono- or bicyclic saturated cyclic hydrocarbon group, preferably monocyclic, comprising from 1 to 3 rings, preferably 2 rings, and comprising from 3 to 40 carbon atoms, in particular comprising from 3 to 24 carbon atoms, more particularly from 3 to 20 carbon atoms, even more particularly from 3 to 12 carbon atoms, preferably between 5 and 10 carbon atoms, such as cyclopropyl, cyclopentyl, cyclohexyl, cycloheptyl, norbornyl, or isobotyl, in particular cyclopropyl, cyclopentyl, or a cyclohexyl. It being understood that the cycloalkyl radical may be substituted by one or more (Ci-C4)alkyl groups such as methyl; preferably, the cycloalkyl radical is then an isobotyl group. - an "aryl" radical is an unsaturated and aromatic hydrocarbon cyclic radical, comprising from 6 to 30 carbon atoms, preferably between 6 and 14 carbon atoms, more preferably between 6 and 12 carbon atoms, mono / bi / or tri /

[0021]

[0022]

[0023] cyclic, fused or not, preferably the aryl group comprises 1 ring with 6 carbon atoms such as phenyl, naphthyl, anthryl, phenanthryl and biphenyl, it being understood that the aryl radical may be substituted by one or more (CrC4)alkyl groups such as methyl, preferably tolyl, xylyl, or methylnaphthyl, preferably the aryl group represents a phenyl; - an "aryloxy" radical refers to an aryl-oxy radical with "aryl" as defined previously; - an "alkoxy" radical refers to an alkyl-oxy radical with "alkyl", as defined previously. Unless otherwise indicated, when compounds are mentioned in this application, this also includes their optical isomers, their geometric isomers, their tautomers, their salts, alone or in mixtures. The invention is not limited to the illustrated examples. The features of the different examples can, in particular, be combined within non-illustrated variants. Detailed description of the invention Method according to the invention Composition A of coloring Alkoxysilane of formula (I) or of formula (!'): Composition A according to the invention comprises at least one alkoxysilane selected from the following compounds of formula (I) or formula (!'), their oligomers and / or mixtures thereof: (D in which: - Ra represents an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 10 carbon atoms, more preferably from 1 to 4 carbon atoms, and in particular from 1 to 2 carbon atoms such as a methyl group, said alkyl group being even actually substituted by an aryl group; an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as an ethoxy; or an aryl group having from 6 to 12 carbon atoms; Rb and Rc, identical or different, represent a hydrogen atom; an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 6 carbon atoms and in particular from 1 to 4 carbon atoms, in particular an ethyl group, it being understood that if Ra does not represent an alkoxy group, then Rb and Rc cannot simultaneously represent a hydrogen atom; Rd and Re, identical or different, represent a hydrogen atom; an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 6 carbon atoms and especially from 1 to 4 carbon atoms; a cycloalkyl group having from 3 to 20 carbon atoms; an aryl group having from 6 to 12 carbon atoms; an aminoalkyl group having from 1 to 20 carbon atoms; - A independently represents an alkylene group having from 1 to 10 linear or branched carbon atoms, which may be interrupted by at least one heteroatom chosen from O, S, NH or a carbonyl group (CO), preferably NH - Q represents a carbonyl group (CO); - r denotes an integer ranging from 0 to 1.

[0024] Among the alkoxysilanes of formula (I), their oligomers and / or mixtures, we may mention in particular 3-aminopropyltriethoxysilane (APTES), 3-aminopropylmethyldiethoxysilane (APMDES), 3-ureidopropyltrimethoxysilane and N-cyclohexylaminomethyl triethoxysilane.

[0025] APTES can, for example, be purchased from the company DOW CORNING under the name XIAMETER OFS-6011 SILANE or with the company MOMENTIVE PERFORMANCE MATERIALS under the name SILSOFT A-1100 or with the company SHIN ETSU under the name KBE-903.

[0026] The compounds of formula (I) may also refer to DYNASYLAN SIVO 210 or DYNASYLAN 1505 sold by the company EVONIK.

[0027] 3-ureidopropyltrimethoxysilane can for example be purchased from the company Gelest under the name SIU9058.0.

[0028] N-cyclohexylaminomethyl triethoxysilane can for example be purchased from the company WACKER under the name GENIOSIL XL 926.

[0029] Among the alkoxysilanes of formula (T), their oligomers and / or mixtures, we may mention in particular N,N-Bis[3-(trimethoxysilyl)propyl]ethylenediamine (CAS RN: 74956-86-8), Nl,Nl-Bis[3-(triethoxysilyl)propyl]-l,2-ethanediamine (CAS RN: 457065-96-2), 1,2-ethanediamine, Nl-[3-(triethoxysilyl)propyl]-Nl-[3-(trimethoxysilyl)propyl]- (CAS RN: 1638528-78-5), and their mixtures.

[0030] Preferably, the alkoxysilane(s), their oligomers and / or mixtures thereof are chosen from the compounds of the following formula (I): in which: - Ra represents an alkyl group having from 1 to 10 carbon atoms, in particular from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms, preferably a methyl, or an alkoxy group having from 1 to 4 carbon atoms, preferably from 1 to 2 carbon atoms, preferably an ethoxy; - Rb and Rc, identical or different, represent an alkyl group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms like an ethyl; - Rd and Re, identical, represent a hydrogen atom or Rd designates a hydrogen atom and Re designates a C5-C6 cycloalkyl radical such as cyclohexyl; - A independently represents an alkylene group having from 1 to 10 linear or branched carbon atoms, which can be interrupted by at least one heteroatom chosen from O, S, NH or a carbonyl group (CO), preferably NH; - r denotes an integer equal to 0.

[0031] Preferably, the alkoxysilane(s), their oligomers and / or mixtures are chosen from compounds of formula (I) in which Ra represents an ethoxy group, Rb and Rc are identical and represent an ethyl, Rd and Re represent a hydrogen atom, A represents a propyl and r denotes an integer equal to 0.

[0032] According to a preferred embodiment, alkoxysilane of formula (I), its oligomers and / or mixtures thereof, is 3-aminopropyltriethoxysilane (APTES).

[0033] The alkoxysilane(s) of formula (I) or of formula (!'), their oligomers and / or mixtures thereof may be present in a total quantity of 0.1 to 40% by weight, preferably 0.5 to 30% by weight, preferably 0.75 to 25% by weight, better 1 to 20% by weight, even better 1.5 to 15% by weight relative to the total weight of composition A.

[0034] According to a preferred embodiment, the alkoxysilane(s) of formula (I), their oligomers and / or mixtures thereof is (are) present in a total quantity ranging from 0.1 to 40% by weight, preferably from 0.5 to 30% by weight, preferably from 0.75 to 25% by weight, better from 1 to 20% by weight, even better from 1.5 to 15% by weight relative to the total weight of composition A. Alkoxysilane of formula (II):

[0035] Composition A according to the invention comprises at least one alkoxysilane of the following formula (II), its oligomers and / or mixtures thereof: in which: - Ra represents an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 10 carbon atoms, more preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methyl, said alkyl group possibly being substituted by an aryl group; an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as an ethoxy; or an aryl group having from 6 to 12 carbon atoms; - Rb represents a hydrogen atom or an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 6 carbon atoms and in particular from 1 to 4 carbon atoms, in particular an ethyl group; - Rc represents an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 10 carbon atoms, more preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methyl, said alkyl group possibly being substituted by an aryl group; an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as an ethoxy; or an aryl group having from 6 to 12 carbon atoms; it being understood that if Ra and Rc do not represent an alkoxy group, then Rb cannot represent a hydrogen atom; - k denotes an integer ranging from 0 to 5, preferably ranging from 0 to 3; - Rf represents a hydrogen atom; an alkyl group having from 1 to 10 carbon atoms and in particular from 1 to 4 carbon atoms; or a group with the following formula (lia): R. z (Ha) in which Rn represents a hydroxyl group (OH); an alkyl group having from 1 to 10 carbon atoms, preferably a methyl.

[0036] Among the alkoxysilanes of formula (II), their oligomers and / or mixtures thereof, the following may be mentioned in particular: tetraethoxysilane (TEOS), methyltrimethoxysilane (MTMS), methyltriethoxysilane (MTES), dimethyldiethoxysilane (DMDES), diethyldiethoxysilane, dipropyldiethoxysilane, propyltriethoxysilane, isobutyltriethoxysilane, phenyltriethoxysilane, phenylmethyldiethoxysilane, diphenyldiethoxysilane, benzyltriethoxysilane, benzylmethyldiethoxysilane, dibenzyldiethoxysilane, acetoxymethyltriethoxysilane and mixtures thereof.

[0037] TEOS can for example be purchased from the company EVONIK under the name Dynasylan® A or Dynasylan® A SQ.

[0038] MTES can for example be purchased from the company EVONIK under the name Dynasylan® MTES.

[0039] The DMDES can for example be purchased from the company GELEST under the reference SID3404.0.

[0040] Preferably, the alkoxysilane(s) of formula (II), their oligomers and / or mixtures thereof are such that: - Ra represents an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methoxy or an ethoxy; or an alkyl group having from 1 to 10 carbon atoms possibly substituted by an aryl group, preferably 1 to 2 carbon atoms possibly substituted by an aryl group; - Rb represents an alkyl group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms, in particular from 1 to 2 carbon atoms such as a methyl or an ethyl; - Rc represents an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methoxy or an ethoxy - k denotes an integer from 0 to 3, preferably equal to 0; - Rf represents a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms and in particular from 1 to 4 carbon atoms such as a methyl or an ethyl.

[0041] More preferably, the alkoxysilane(s) of formula (II), their oligomers and / or mixtures thereof are such that: - Ra represents an alkyl group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms, in particular from 1 to 2 carbon atoms such as a methyl or an ethyl; - Rb represents an alkyl group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms, in particular from 1 to 2 carbon atoms such as a methyl or an ethyl; - Rc represents an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methoxy or an ethoxy - k denotes an integer equal to 0; - Rf represents an alkyl group having from 1 to 10 carbon atoms and in particular of 1 to 4 carbon atoms such as a methyl or an ethyl.

[0042] According to a preferred embodiment, alkoxysilane of formula (II), its oligomers and / or mixtures thereof, is methyltrimethoxysilane (MTMS) or methyltriethoxysilane (MTES).

[0043] The alkoxysilane(s) of formula (II), its oligomers and / or mixtures thereof may be present in a total quantity of 0.5 to 90% by weight, preferably 1 to 75% by weight, preferably 3 to 45% by weight, better 5 to 40% relative to the total weight of composition A. Organic solvents:

[0044] Composition A according to the invention may comprise one or more organic solvents.

[0045] Examples of organic solvents include lower CrC4 alkanols such as ethanol and isopropanol; polyols and polyol ethers such as glycerol, 2-butoxyethanol, propylene glycol, propylene glycol monomethyl ether, diethylene glycol monoethyl ether and monomethyl ether, as well as aromatic alcohols such as benzyl alcohol or phenoxyethanol, and mixtures thereof.

[0046] Preferably, composition A according to the invention comprises ethanol.

[0047] The organic solvent(s) may be present in a total quantity from 1 to 70% by weight, preferably from 5 to 55% by weight, more preferably from 10 to 50% by weight relative to the total weight of composition A according to the invention. Composition B of the coloring agent: Film-forming polymer:

[0048] Composition B according to the invention comprises at least one film-forming polymer.

[0049] Preferably, the film-forming polymer(s) are chosen from among the polymers hydrophilic film-forming polymers, hydrophobic film-forming polymers, and their mixtures.

[0050] For the purposes of this invention, "polymer" means a compound consisting of the repetition of one or more motifs (these motifs being derived from compounds called monomers). This motif or these motifs are repeated at least twice and preferably at least three times.

[0051] By "hydrophobic polymer" is meant a polymer having a solubility in water at 25°C of less than 1% by weight.

[0052] By "hydrophilic polymer" is meant a polymer having a solubility in water at 25°C greater than or equal to 1% by weight.

[0053] By "film-forming" polymer, we mean a polymer capable of forming, on its own or in the presence of an auxiliary film-forming agent, a macroscopically continuous film on a support, in particular on keratinous materials, and preferably a cohesive film.

[0054] According to a preferred embodiment, the film-forming polymer(s) are chosen among hydrophobic film-forming polymers.

[0055] In a particularly preferred embodiment, the hydrophobic film-forming polymer is a polymer selected from the group comprising: - film-forming polymers soluble in an organic solvent medium, in particular liposoluble polymers; this means that the polymer is soluble or miscible in the organic medium and will form a single homogeneous phase when incorporated into the medium. - Film-forming polymers dispersible in an organic solvent medium; this means that the polymer forms an insoluble phase in the organic medium, the polymer remaining stable and / or compatible once incorporated into this medium. In particular, such polymers can be in the form of non-aqueous dispersions of polymer particles, preferably dispersions in silicone or hydrocarbon oils; in one embodiment, the non-aqueous polymer dispersions comprise polymer particles stabilized on their surface by at least one stabilizing agent; these non-aqueous dispersions are often called "NADs (non-aqueous dispersions)". - Film-forming polymers in the form of aqueous dispersions of polymer particles mean that the polymer forms a water-insoluble phase. The polymer remains stable and / or compatible once incorporated into water, and the polymer particles can be stabilized on their surface by at least one stabilizing agent. These polymer particles are often called "latex"; in this case, the composition must include an aqueous phase.

[0056] Among the hydrophobic film-forming polymers that can be used in the composition of the present invention, we can mention synthetic polymers, of radical type or of polycondensate type, polymers of natural origin and their mixtures.

[0057] Examples of hydrophobic film-forming polymers include acrylic polymers, polyurethanes, polyesters, polyamides, polyureas, cellulosic polymers such as nitrocellulose, silicone polymers, acrylamide-type polymers, and polyisoprenes.

[0058] Non-ionic, amphoteric, anionic or cationic hydrophobic film-forming polymers may be used.

[0059] Preferably, the hydrophobic film-forming polymer(s) according to the invention are selected from acrylic acid copolymers, methacrylic acid copolymers, acrylic acid ester homopolymers or copolymers, methacrylic acid ester homopolymers or copolymers, acrylic acid amide homopolymers or copolymers, methacrylic acid amide homopolymers or copolymers, vinylpyrrolidone copolymers, vinyl alcohol copolymers, vinyl acetate copolymers, homopolymers or copolymers ethylene, propylene homopolymers or copolymers, styrene homopolymers or copolymers, polyurethanes, polyesters and / or polyamides.

[0060] The hydrophobic film-forming polymer can be selected from homopolymers and copolymers of olefins such as cycloolefins; butadiene; isoprene; styrene; vinyl ethers, esters or amides; (meth)acrylic acid esters or amides containing a linear, branched or cyclic Ci-C20 alkyl group, a C6-Ci0 aryl group or a C2-C6 hydroxyalkyl group.

[0061] The hydrophobic film-forming polymer can in particular be chosen from homopolymers and copolymers that can be obtained from monomers chosen from the group consisting of isooctyl (meth)acrylate, isononyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, lauryl (meth)acrylate, isopentyl (meth)acrylate, n-butyl (meth)acrylate, isobutyl (meth)acrylate, ethyl (meth)acrylate, methyl (meth)acrylate, tert-butyl (meth)acrylate, tridecyl (meth)acrylate, stearyl (meth)acrylate, hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, benzyl or phenyl acrylate, or mixtures thereof.

[0062] One can cite for example the ethylene / sodium acrylate copolymer marketed under the trade name ECOSMOOTH SATIN® by the company Dow.

[0063] The hydrophobic film-forming polymer can in particular be chosen from among the homopolymers and copolymers that can be obtained from amides of acid monomers, we can mention (meth)acrylamides, and in particular N-alkyl (meth)acrylamides, in particular of alkyl in C2-Ci2 such as N-ethyl acrylamide, Nt-butyl acrylamide, N-octyl acrylamide; N-dialkyl (C1-C4) (meth)acrylamides, perfluoroalkyl (meth)acrylates.

[0064] We can also mention copolymers whose CTFA designation (4th Ed., 1991) is Octylacrylamide / acrylates / butylaminoethyl-methacrylate copolymer, such as the products sold under the name AMPHOMER® or LOVOCRYL® 47 by the company NATIONAL STARCH as well as copolymers whose CTFA designation is Acrylates / octylacrylamide copolymer, such as the products sold under the name DERMACRYL® LT or DERMACRYL® 79 by the company NATIONAL STARCH.

[0065] According to a preferred embodiment, the hydrophobic film-forming polymer(s) according to the invention are chosen from anionic copolymers.

[0066] Preferably, the anionic copolymers according to the invention are copolymers of acrylic acid, methacrylic acid or (meth)acrylic acid esters containing a linear, branched or cyclic Ci-C6 alkyl group, as described under the INCI name Acrylates.

[0067] Such copolymers are marketed by the company ROHM AND HAAS under the Aculyn®33 designation.

[0068] Copolymers of unsaturated ethylenic acid esters and alkoxylated fatty alcohols can also be used according to the invention. Such unsaturated ethylenic acid esters are in particular acrylic acid, methacrylic acid and itaconic acid, and such alkoxylated fatty alcohols are in particular steareth-20 and ceteth-20.

[0069] We will cite, for example, Aculyn®22 (Acrylates / Steareth-20 Methacrylate Copolymer), Aculyn®28 (Acrylates / Beheneth-25 Methacrylate Copolymer), Structure 2001® (Acrylates / Steareth-20 Itaconate Copolymer), Structure 3001® (Acrylates / Ceteth-20 Copolymer Itaconate), Structure Plus® (Copolymer Acrylates / Amino-acrylates C10-30 Alkyl PEG-20 Itaconate), Carbopol® 1342, 1382, Ultrez 20, Ultrez 21 (Crosspolymer Acrylates / C 10-30 Alkyl acrylate Crosspolymer), Synthalen W2000® (Copolymer Acrylates / Palmeth-25 Acrylate) or SOLTEX OPT (acrylates / C 12-22 alkyl methacrylate copolymer) marketed by the company ROHM AND HAAS.

[0070] The hydrophobic film-forming polymer can also be chosen from homopolymers and copolymers that can be obtained from vinyl monomers. Examples include homopolymers or copolymers of N-vinylpyrrolidone, vinylca-prolactam, vinyl N-alkyl(Cl-C6)pyrroles, vinyl-oxazoles, vinyl-thiazoles, vinyl-pyrimidine, or vinylimidazole.

[0071] Examples of vinylpyrrolidone copolymers that can be used in the invention include VP / vinyl laurate copolymer, VP / vinyl stearate copolymer, butylated polyvinylpyrrolidone (PVP), VP / hexadecene marketed by ISP under the name Ganex V216, VP / eicosene marketed by ISP under the name Ganex V220, VP / triacontene or VP / acrylic acid / lauryl methacrylate.

[0072] The hydrophobic film-forming polymer can also be chosen from homopolymers and copolymers that can be obtained from olefins such as ethylene, propylene, butenes, isoprene, butadienes.

[0073] In one embodiment, the hydrophobic film-forming polymer according to the invention is a block copolymer comprising at least one block made of styrene or styrene derivative units (for example, methylstyrene, chlorostyrene, or chloromethylstyrene). The copolymer comprising at least one styrene block may be a diblock or triblock copolymer, or even a multiblock, star, or radial copolymer. The copolymer comprising at least one styrene block may further comprise, for example, an alkylstyrene block (AS), an ethylene / butylene block (EB), an ethylene / propylene block (EP), a butadiene block (B), an isoprene block (I), an acrylate block (A), a methacrylate block (MA), or a combination of these blocks. The copolymer comprising at least one block made up of styrene motifs or styrene derivatives may be a diblock or triblock copolymer, and in particular of the polystyrene / polyisoprene or polystyrene / polybutadiene type, such as those marketed or manufactured under the name "Luvitol HSB" by BASF SE.

[0074] Preferably, the hydrophobic film-forming polymer(s) according to the invention are chosen from vinylpyrrolidone (co)polymers, vinylalcohol (co)polymers, vinylacetate (co)polymers, vinyl carboxy (co)polymers, acrylic acid (co)polymers, methacrylic acid (co)polymers, acrylic acid ester (co)polymers, ethylene (co)polymers, acrylamide (co)polymers and mixtures thereof.

[0075] More preferably, the hydrophobic film-forming polymer(s) are chosen from vinylpyrrolidone copolymers, acrylamide copolymers, acrylic acid ester homopolymers or copolymers, ethylene homopolymers or copolymers and mixtures thereof.

[0076] According to another preferred embodiment, the film-forming polymer(s) are chosen from among hydrophilic film-forming polymers.

[0077] Non-ionic, anionic or cationic hydrophilic film-forming polymers may be used.

[0078] The hydrophilic film-forming polymer can be selected from vinylpyrrolidone (co)polymers, vinyl alcohol (co)polymers, vinyl acetate polymers, carboxyvinyl (co)polymers, acrylic acid (co)polymers, methacrylic acid (co)polymers, natural gums, polysaccharides and / or acrylamide (co)polymers.

[0079] Preferably, the hydrophilic film-forming polymer is chosen from vinylpyrrolidone (PVP) homopolymers and / or vinylpyrrolidone copolymers, more preferably vinylpyrrolidone (PVP) homopolymers.

[0080] Examples include vinylpyrrolidone (PVP) homopolymers marketed under the name Luviskol® K by BASF SE, in particular Luviskol® K 90 or Luviskol® K 85 by BASF SE.

[0081] The PVP K30 polymer marketed by Ashland Inc. (ISP, POI Chemical) can also be used. PVP K30 is a cold-water soluble polyvinylpyrrolidone polymer with CAS number 9003-39-8 and a molecular weight of 40.000 g / mol.

[0082] Other polyvinylpyrrolidone homopolymers suitable for the invention are marketed under the trade name LUVITEC K 17, LUVITEC K 30, LUVITEC K 60, LUVITEC K 60, LUVITEC K 80, LUVITEC K 85, LUVITEC K 90 and LUVITEC K 115 by BASF SE.

[0083] We can also mention vinylpyrrolidone / vinyl ester copolymers marketed under the name Luviskol® by BASF SE, in particular the non-ionic polymers Luviskol® VA64 and Luviskol® VA73 (vinylpyr-rolidone / vinyl acetate copolymers).

[0084] We can also mention styrene / vinylpyrrolidone copolymers, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / DMAPA acrylates copolymers, vinylpyrrolidone / vinyl caprolactam / DMAPA acrylates copolymers.

[0085] Vinylpyrrolidone / vinyl caprolactam / DMAPA acrylates copolymers may be marketed by Ashland Inc. under the trade name Aquaflex® SF-40.

[0086] Vinylpyrrolidone / DMAPA acrylates copolymers may be marketed by Ashland Inc. under the trade name Styleze CC-10.

[0087] As copolymers of vinylpyrrolidone, mention may be made of copolymers obtained by reaction of N-vinylpyrrolidone with at least one monomer chosen from N-vinylformamide, vinyl acetate, ethylene, propylene, acrylamide or vinylca-prolactam.

[0088] According to a preferred embodiment, the hydrophilic film-forming polymer(s) are selected from vinylpyrrolidone (PVP) homopolymers, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / styrene copolymers, vinylpyrrolidone / ethylene copolymers, vinylpyrrolidone / propylene copolymers, vinylpyrrolidone / vinyl caprolactam copolymers, vinylpyrrolidone / vinylformamide copolymers, vinylpyrrolidone / vinyl alcohol copolymers, and mixtures thereof.

[0089] Preferably, the film-forming polymer(s) are chosen from vinylpyrrolidone (PVP) homopolymers, vinylpyrrolidone / vinyl acetate copolymers, vinylpyrrolidone / styrene copolymers, vinylpyrrolidone / ethylene copolymers, vinylpyrrolidone / propylene copolymers, vinylpyrrolidone / vinyl caprolactam copolymers, vinylpyrrolidone / vinylformamide copolymers, vinylpyrrolidone / vinylalcohol copolymers, acrylamide copolymers, acrylic acid ester homopolymers or copolymers, ethylene homopolymers or copolymers and mixtures thereof.

[0090] More preferably, the film-forming polymer(s) are chosen from vinylpyrrolidone (PVP) homopolymers, acrylamide copolymers, acrylic acid ester homopolymers or copolymers, ethylene homopolymers or copolymers and mixtures thereof.

[0091] The film-forming polymer(s) may be present in a total quantity ranging from 0.1 to 30% by weight, preferably from 0.5 to 25% by weight, even better from 1 to 20% by weight, relative to the total weight of composition B. Colour composition A and / or B Non-ionic, non-associative cellulose polymer

[0092] Composition A and / or composition B according to the invention comprises (include) at least one non-ionic cellulosic polymer.

[0093] The non-ionic cellulosic polymer is different from the film-forming polymers mentioned previously.

[0094] Preferably, the non-ionic cellulosic polymer according to the invention is non-associative.

[0095] By "cellulosic polymer", according to the invention, any polysaccharide polymer having in its structure chains of glucose residues joined by beta-1,4 bonds.

[0096] By "non-associative cellulosic polymer", it is understood according to the invention that the cellulosic polymers do not have a C8-C30 fatty chain.

[0097] Non-associative non-ionic cellulosic polymers may be selected from alkyl(Ci-C4)celluloses, such as methylcelluloses and ethylcelluloses (e.g., Ethocel Standard 100 Premium from DOW CHEMICAL); hydroxyalkyl(Ci-C4)celluloses, such as hydroxymethylcelluloses, hydroxyethylcelluloses and hydroxypropylcelluloses; mixed hydroxyalkyl(Ci-C4)-alkyl(Ci-C4)celluloses, such as hydroxypropyl methylcelluloses (e.g., Methocel E4M from DOW CHEMICAL), hydroxyethyl methylcelluloses, hydroxyethyl ethylcelluloses (e.g., Bermocoll E 481 FQ from AKZO NOBEL), and hydroxybutyl methylcelluloses, and mixtures thereof.

[0098] Preferably, the non-ionic cellulosic polymer(s) are non-associative.

[0099] Preferably, the non-ionic non-associative cellulosic polymer(s) are chosen from among the hydroxyalkyl(Ci-C4)celluloses.

[0100] More preferably, the non-ionic non-associative cellulosic polymer(s) are hydroxyethylcellulose and / or hydroxypropylcellulose.

[0101] More preferably, composition A and / or composition B comprises (include) hydroxyethylcellulose and / or hydroxypropylcellulose.

[0102] In particular, hydroxyethylcellulose sold by Ashland Inc. under the trade name NATROSOL 250 HHR PC.

[0103] The non-ionic cellulosic polymer(s) may be present in a total quantity preferably from 0.01 to 10% by weight, preferably from 0.05 to 5% by weight, better from 0.1 to 3% by weight relative to the total weight of composition A and / or composition B. Amino silicone:

[0104] Composition A and / or composition B may include at least one silicone.

[0105] Preferably, composition A and / or composition B comprises(s) at least one amino silicone.

[0106] The term “amino silicone” means any silicone comprising at least one primary, secondary, tertiary amine or one quaternary ammonium group.

[0107] The average molecular masses by weight of these amino silicones can be measured by Gel Permeation Chromatography (GPC) at room temperature (25°C) in polystyrene equivalents. The columns used are Styragel p-columns. The eluent is THF, and the flow rate is 1 ml / min. 200 µL of a 0.5% by weight silicone solution is injected into the THF. Detection is performed by refractometry and UV measurement.

[0108] Preferably, the amine-based silicone(s) that may be used in the context of the invention are chosen from: a) Polysiloxanes corresponding to formula (A): HO--- CH, 1 Si O CH, x' OH 1 — Si---O - (CH,}, i NH 4¾ -H y

[0109] in which x' and y' are integers such that the average molecular weight by weight (Mw) is between approximately 5,000 and 500,000; b) Amino silicones corresponding to formula (B): R'aG3a-Si(OSiG2)n-(OSiGbR'2b)mO-SiG3a-R'a (B) in which:

[0110] - G, identical or different, designates a hydrogen atom, a phenyl group, OH, alkyl in CrC8, for example methyl, or alkoxy in CrC8, for example methoxy, - a, same or different, denotes 0 or an integer from 1 to 3, in particular 0, - b denotes 0 or 1, in particular 1,

[0111] - m and n are numbers such that the sum (n + m) varies from 1 to 2000, in particular from 50 to 150, n being able to designate a number from 0 to 1999, and in particular from 49 to 149 and m being able to designate a number from 1 to 2000, and in particular from 1 to 10; - R', identical or different, denotes a monovalent radical of formula -CqH2qL in which q is a number from 2 to 8, and L is an amine group possibly quaternized chosen from the groups: -N(R")2; -N+(R")3 A-; -NR"-QN(R")2 and -NR"-Q-N+(R")3 A-, in which R", identical or different, denotes hydrogen, phenyl, benzyl, or a monovalent saturated hydrocarbon radical, for example a Ci-C2O alkyl radical; Q denotes a group of formula CrH2r, linear or branched, r being an integer ranging from 2 to 6, preferably 2 to 4; and A- represents a cosmetically acceptable union, in particular a halide such as fluoride, chloride, bromide or iodide.

[0112] Preferably, the amine silicone(s) are chosen from among the amine silicones of formula (B).

[0113] Preferably, the amino silicones of formula (B) are chosen from among the amino silicones corresponding to the following formulas (C), (D), (E), (F), (G) and / or the amino silicones comprising at least one formula unit (L), in particular the following amino silicones of formula (N).

[0114] According to a first embodiment, the amino silicones corresponding to formula (B) are chosen from the silicones called "trimethylsilylamodi-methicone" corresponding to formula (C): X Qi ■CH, 1 n. has:? CH, 1 3 A 1 CH, (CH2)3 1 -U / ? " n NH (CH^ 1 - ~ mh2 m in which m and n are numbers such that the sum (n + m) varies from 1 to 2000, in particular from 50 to 150, n being able to designate a number from 0 to 1999, and in particular from 49 to 149 and m being able to designate a number from 1 to 2000, and in particular from 1 to 10.

[0115] According to a second embodiment, the amino silicones corresponding to formula (B) are chosen from the silicones of the following formula (D): GH. CH, in which: - m and n are numbers such that the sum (n + m) varies from 1 to 1000, in particular from 50 to 250 and more particularly from 100 to 200; n can represent a number from 0 to 999 and in particular from 49 to 249 and more particularly from 125 to 175 and m can designate a number from 1 to 1000, in particular from 1 to 10, more particularly from 1 to 5; - Rb R2, R3, identical or different, represent a hydroxy or alkoxy radical in Ci-C4, at least one of the radicals Ri to R3 designating an alkoxy radical.

[0116] Preferably the alkoxy radical is a methoxy radical.

[0117] The hydroxy / alkoxy molar ratio preferably ranges from 0.2:1 to 0.4:1 and preferably from 0.25:1 to 0.35:1 and more particularly is equal to 0.3:1.

[0118] The average molecular mass by weight (Mw) of these silicones preferably ranges from 2000 to 1,000,000, more particularly from 3500 to 200,000.

[0119] According to a third embodiment, the amino silicones corresponding to formula (B) are chosen from the following silicones of formula (E): in which: - p and q are numbers such that the sum (p+q) varies from 1 to 1000, in particular from 50 to 350, and more particularly from 150 to 250; p can designate a number from 0 to 999 and in particular from 49 to 349 and more particularly from 159 to 239 and q can designate a number from 1 to 1000, in particular from 1 to 10 and more particularly from 1 to 5; - Rb R2, different, represent a hydroxy or alkoxy radical in Ci-C4, at least one of the radicals Ri or R2 designating an alkoxy radical.

[0120] Preferably the alkoxy radical is a methoxy radical.

[0121] The hydroxy / alkoxy molar ratio generally ranges from 1:0.8 to 1:1.1 and preferably from 1:0.9 to 1:1 and more particularly is equal to 1:0.95.

[0122] The average molecular mass by weight (Mw) of silicone is preferably from 2000 to 200000 and even more particularly from 5000 to 100000 and more particularly from 10000 to 50000.

[0123] Commercial products comprising structural silicones (D) or (E) may include in their composition one or more other amino silicones whose structure is different from formulas (D) or (E).

[0124] A product containing structure-amino silicones (D) is offered by the company WACKER under the name BELSIL® ADM 652.

[0125] A product containing structural amino silicones (E) is offered by WACKER under the name Fluid WR 1300® or under the name Belsil ADM Log 1.

[0126] When these amino silicones are implemented, a particularly interesting embodiment is their use in the form of an oil-in-water emulsion. The oil-in-water emulsion may comprise one or more surfactants. The surfactants may be of any type, but preferably cationic and / or nonionic. The average number size of the silicone particles in the emulsion generally ranges from 3 nm to 500 nanometers. Preferably, particularly for amino silicones of formula (E), microemulsions are used with an average particle size ranging from 5 nm to 60 nanometers (inclusive), and more particularly from 10 nm to 50 nanometers (inclusive). Thus, according to the invention, amino silicone microemulsions of formula (E) offered under the names FINISH CT 96 E® or SLM 28020® by WACKER can be used.

[0127] According to a fourth embodiment, the amino silicones corresponding to formula (B) are chosen from the silicones of the following formula (F): (CHz)2

[0128] in which:

[0129] - m and n are numbers such that the sum (n + m) varies from 1 to 2000 and in by particular from 50 to 150, n can designate a number from 0 to 1999 and in particular from 49 to 149 and m can designate a number from 1 to 2000, and in particular from 1 to 10;

[0130] - A denotes a linear or branched alkylene radical having from 4 to 8 carbon atoms and preferably 4 carbon atoms. This radical is preferably linear.

[0131] The average molecular mass by weight (Mw) of these amino silicones preferably ranges from 2000 to 1000000 and even more particularly from 3500 to 200000.

[0132] Another silicone meeting formula (B) is for example XIAMETER MEM 8299 EMULSION from DOW CORNING (INCI name amodimethicone and trideceth-6 and cetrimonium chloride).

[0133]

[0134]

[0135]

[0136]

[0137]

[0138] According to a fifth embodiment, the amino silicones corresponding to formula (B) are chosen from the silicones of the following formula (G): CH, I O —If — i HAS I NH I (CH2)2 - in which: - m and n are numbers such that the sum (n + m) varies from 1 to 2000 and in particular from 50 to 150, n being able to designate a number from 0 to 1999 and in particular from 49 to 149 and m being able to designate a number from 1 to 2000, and in particular from 1 to 10; - A designates a linear or branched alkylene radical having from 4 to 8 carbon atoms and preferably 4 carbon atoms. This radical is preferably branched. The average molecular weight (Mw) of these amino silicones preferably ranges from 500 to 1,000,000 and even more particularly from 1,000 to 200,000. One silicone that meets this formula is, for example, DOW CORNING's DC2-8566 Amino Fluid. c) Amino silicones conforming to formula (H): CH OH—CH Si-(R5)3 (H)

[0139]

[0140]

[0141] in which: - R5 represents a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical in CrCi8, or alkenyl in C2-Ci8, for example methyl; - R6 represents a divalent hydrocarbon radical, in particular a C1-C18 alkylene radical or a divalent CrCi8 alkyleneoxy radical, for example CrC8 linked to Si by a SiC bond; - Q is an anion such as a halide ion, in particular chloride or an acid salt organic, in particular acetate;

[0142] - r represents an average statistical value ranging from 2 to 20, in particular from 2 to 8; - s represents an average statistical value ranging from 20 to 200, in particular from 20 to 50.

[0143] Such amino silicones are described in particular in US patent 4,185,087.

[0144] d) quaternary ammonium silicones of formula (I): R, OH w- FU-CK-CHOH-GIU-N — R. 0) R, in which: - R7, identical or different, represent a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical in CrCi8, an alkenyl radical in C2-C[8 or a ring comprising 5 or 6 carbon atoms, for example methyl; - R6 represents a divalent hydrocarbon radical, in particular an alkylene radical in CrCi8 or a divalent alkyleneoxy radical in CrCi8, for example in CrC8 linked to Si by a SiC bond; - R8, identical or different, represent a hydrogen atom, a monovalent hydrocarbon radical having from 1 to 18 carbon atoms, and in particular an alkyl radical in CrCi8, an alkenyl radical in C2-Ci8, an -R6-NHCOR7 radical; - X is an anion such as a halide ion, in particular chloride or a salt of organic acid, in particular acetate; - r represents an average statistical value ranging from 2 to 200, in particular from 5 to 100.

[0145] These silicones are described for example in application EP-A-0530974.

[0146] e) Amino silicones of formula (J): HJN z. (CK Hl-Si — O 1 in as' s zrr Si----O: Si--R in which: - Ri, R2, R2 and R4, whether identical or different, denote a C1-C4 alkyl radical or a phenyl group, - R5 designates a C1-C4 alkyl radical or a hydroxyl group,

[0147] - n is an integer ranging from 1 to 5,

[0148] - m is an integer ranging from 1 to 5, and - x is chosen such that the amine index varies from 0.01 to 1 meq / g.

[0149] f) multiblock polyoxyalkylened amine silicones, of type (AB)n, A being a polysiloxane block and B being a polyoxyalkylened block comprising at least one amine group.

[0150] Said silicones are preferably made up of repeating units of the following general formulas: [-(SiMe2O)xSiMe2 - R -N(R")- R'-O(C2H4O)a(C3H6O)b -R'-N(H)-R-] or else [-(SiMe2O)xSiMe2 - R -N(R")- R' - O(C2H4O)a(C3H6O)b -] in which: - a is an integer greater than or equal to 1, preferably from 5 to 200, more particularly from 10 to 100; - b is an integer between 0 and 200, preferably from 4 to 100, more particularly between 5 and 30; - x is an integer ranging from 1 to 10000, more specifically from 10 to 5000; - R" is a hydrogen atom or a methyl atom;

[0151] - R, identical or different, represent a divalent hydrocarbon radical in C2-Ci2, linear or branched, possibly comprising one or more heteroatoms such as oxygen; preferably, R denotes an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a CH2CH2CH2OCH2 CH(OH)CH2- radical; preferably R denotes a CH2CH2CH2OCH2CH(OH)CH2 radical - R', identical or different, represent a divalent hydrocarbon radical in C2-Ci2, linear or branched, possibly comprising one or more heteroatoms such as oxygen; preferably, R' designates an ethylene radical, a linear or branched propylene radical, a linear or branched butylene radical, or a CH2CH2CH2OCH2 CH(OH)CH2- radical; preferably R' designates -CH(CH3)-CH2-.

[0152] The siloxane blocks preferably represent 50 and 95% by moles of the total weight of the silicone, more particularly 70 to 85% by moles.

[0153] The amine content is preferably between 0.02 and 0.5 meq / g of copolymer in a 30% solution in dipropylene glycol, more particularly between 0.05 and 0.2.

[0154] The average molecular mass by weight (Mw) of silicone is preferably between 5000 and 1000000, more particularly between 10000 and 200000.

[0155] We can cite in particular the silicones marketed under the names Silsoft A-843 or Silsoft A+ by Momentive.

[0156] g) Amino silicones of formula (K): in which: - A represents a hydroxyl group, -O-Si(CH3)3, -O-Si(CH3)2OH, or -O-Si(CH3)2 och3, - D represents a hydrogen atom, a -Si(CH3)3, -Si(CH3)2OH, or -Si(CH3)2OCH3 group - b, n and c, independent of each other, are integers between 0 and 100 with n>0 and b+c>0, and at least one of the following conditions is met: A represents a hydroxyl group (OH) or D represents a hydrogen atom.

[0157] In formula (K), the siloxane units bearing the indices b, c and n are randomly distributed, i.e. they are not necessarily block copolymers.

[0158] h) Amino silicones comprising at least one formula unit (L): According to a preferred embodiment, the amino silicone according to the invention comprises at least one unit of the following formula (L):

[0159] According to a more preferred embodiment, the amino silicone according to the invention comprises at least one formula unit (L) and at least one formula unit (M) as follows:

[0160] Preferably, the amino silicone according to the invention is a substituted amino silicone by at least one 4-Morpholinomethyl group.

[0161] One can cite for example the amodimethicone / morpholinomethyl silses-quioxane copolymer marketed under the trade name Belsil ADM 8301E by the company Wacker.

[0162] The amine-substituted silicone containing at least one 4-Morpholinomethyl group that can be used according to the invention has the following formula (N): in which: - Ri represents a group -CH3, OH, -OCH3, -O-CH2CH3, -O-CH2CH2CH3, or -O-CH(CH3)2, - R2 represents a -CH3, OH, or -OCH3 group - B represents a hydroxyl group, -O-Si(CH3)3, -O-Si(CH3)2OH, or -O-Si(CH3)2 och 3j - D represents a hydrogen atom, a -Si(CH3)3, -Si(CH3)2OH, or -Si(CH3)2OCH3 group - a, b and c, independent of each other, are integers between 0 and 1000 with a+b+b >0, - m and n, independent of each other, are integers between 1 and 1000, with at least one of the following conditions being met: B represents a hydroxyl group (OH) or D represents a hydrogen atom.

[0163] Preferably, a>0 or b>0, more preferably a>0 and b>0.

[0164] Amino silicone of formula (N) may have trimethylsilyl (D or B = -Si(CH3)3) terminations or dimethylsilylhydroxy terminations or trimethylsilyl terminations on one side and dimethylsilylhydroxy terminations on the other side.

[0165] According to a preferred embodiment, the amino silicone according to the invention is an amino silicone substituted by at least one 4-Morpholinomethyl group of formula (N) selected from: B= -O-Si(CH3)2OH and D= -Si(CH3)3 B=-O-Si(CH3)2OH and D= -Si(CH3)2OH B=-O-Si(CH3)2OH and D= -Si(CH3)2OCH3 B = -Si(CH3)3 and D = -Si(CH3)2OH B=-Si(CH3)2OCH3and D= -Si(CH3)2OH

[0166] i) and their mixtures.

[0167] Preferably, the amino silicones of formula (B) are chosen from among the amino silicones corresponding to formula (D) or the amino silicones comprising at least one unit of formula (L), in particular the amino silicones of formula (N).

[0168] Preferably, composition A and / or composition B comprises (include) at least one amino silicone selected from amino silicones of formula (D) or amino silicones comprising at least one formula unit (L), in particular amino silicones of formula (N).

[0169] The amine silicone(s) may be present in a total quantity varying from 0.1% to 35%, preferably from 1 to 25%, more preferably from 3 to 20%, more preferably still from 5 to 17% by weight relative to the total weight of composition A and / or composition B. Coloring agent:

[0170] Composition A and / or composition B according to the invention comprises (include) at least one coloring agent selected from pigments, direct colorants and their mixtures.

[0171] Preferably, composition A according to the invention comprises at least one coloring agent selected from pigments, direct colorants and their mixtures.

[0172] Preferably, composition A and / or composition B according to the invention comprises (include) one or more pigments.

[0173] Preferably, the colouring agent(s) are chosen from pigments.

[0174] The term "pigment" means all pigments that impart color to keratinous materials. Their solubility in water at 25 °C and atmospheric pressure (760 mmHg) is less than 0.05% by weight, and preferably less than 0.01% by weight.

[0175] The pigments that can be used are in particular chosen from among the organic and / or mineral pigments known in the art, in particular those described in Kirk-Othmer's Encyclopedia of Chemical Technology and in Ullmann's Encyclopedia of Industrial Chemistry.

[0176] They may be natural, of natural origin, or not.

[0177] These pigments may be in the form of a powder or pigment paste. They may be coated or uncoated.

[0178] Pigments can, for example, be chosen from mineral pigments, organic pigments, lacquers, special effect pigments such as mother-of-pearl or Glitter, and their mixtures.

[0179] The pigment may be a mineral pigment. By mineral pigment, we mean any pigment that meets the definition in the Ullmann Encyclopedia in the chapter on inorganic pigments. Examples of mineral pigments useful in the present invention include iron or chromium oxides, manganese violet, ultramarine blue, chromium hydrate, ferric blue, and titanium dioxide.

[0180] The pigment may be an organic pigment. By "organic pigment" is meant any pigment that meets the definition in the Ullmann encyclopedia in the chapter on organic pigment.

[0181] The organic pigment may in particular be selected from the following compounds: nitroso, nitro, azo, xanthene, pyrene, quinoline, quinoline, anthraquinone, triphenylmethane, fluorane, phthalocyanine, metal complex type, isoindolinone, isoindoline, qui-nacridone, perinone, perylene, diketopyrrolopyrrole, indigo, thioindigo, dioxazine, triphenylmethane, quinophthalone.

[0182] In particular, the white or colored organic pigments may be selected from carmine, carbon black, aniline black, azo yellow, quinacridone, phthalocyanine blue, the blue pigments coded in the Color Index under references Cl 42090, 69800, 69825, 74100, 74160, the yellow pigments coded in the Color Index under references Cl 11680, 11710, 19140, 20040, 21100, 21108, 47000, 47005, the green pigments coded in the Color Index under references Cl 61565, 61570, 74260, the orange pigments coded in the Color Index under references CI 11725, 45370, 71105, the red pigments coded in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 26100, 45380, 45410, 58000, 73360, 73915, 75470, the pigments obtained by oxidative polymerization of indole, phenolic derivatives as described in patent FR 2 679 771.

[0183] By way of example, one can also cite organic pigment pastes such as the products sold by the company HOECHST under the name: - COSMENYL YELLOW IOG: Pigment YELLOW 3 (Cl 11710); - COSMENYL YELLOW G: Pigment YELLOW 1 (Cl 11680); - ORANGE COSMENYL GR: Pigment ORANGE 43 (Cl 71105); - COSMENYL RED R: Pigment RED 4 (Cl 12085); - CARMIN COSMENYL FB: Pigment RED 5 (Cl 12490); - VIOLET COSMENYL RL: Pigment VIOLET 23 (Cl 51319); - COSMENYL BLUE A2R: Pigment BLUE 15.1 (Cl 74160); - VERT COSMENYL GG: Pigment GREEN 7 (Cl 74260); - COSMENYL BLACK R: Pigment BLACK 7 (Cl 77266).

[0184] The pigments according to the invention may also be in the form of pigments composites as described in patent EP 1 184 426. These composite pigments may be composed in particular of particles comprising an inorganic core, at least one binder ensuring the fixation of organic pigments on the core, and at least one organic pigment covering at least partially the core.

[0185] The organic pigment can also be a lake. By lake, we mean colorants adsorbed onto insoluble particles, the whole thus obtained remaining insoluble during use.

[0186] The inorganic substrates on which the dyes are adsorbed are, for example, alumina, silica, calcium sodium borosilicate or calcium aluminium borosilicate, and aluminium.

[0187] Among the colorants, we can mention carminic acid. We can also mention the colorants known under the following names: D & C Red 21 (CI 45 380), D & C Orange 5 (CI 45 370), D & C Red 27 (CI 45 410), D & C Orange 10 (CI 45 425), D & C Red 3 (CI 45 430), D & C Red 4 (CI 15 510), D & C Red 33 (CI 17 200), D & C Yellow 5 (CI 19 140), D & C Yellow 6 (CI 15 985), D & C Green (CI 61 570), D & C Yellow 1 O (CI 77 002), D & C Green 3 (CI 42 053), D & C Blue 1 (CI 42 090).

[0188] As examples of lacquers, we can cite the product known under the following name: D & C Red 7 (CI 15 850 :1).

[0189] The pigment can also be a special effects pigment. Special effects pigments are defined as pigments that generally create a non-uniform and changing colored appearance (characterized by a certain shade, vibrancy, and clarity) depending on the viewing conditions (light, temperature, viewing angles, etc.). They are thus distinct from colored pigments that provide a uniform opaque, semi-transparent, or conventionally transparent tint.

[0190] There are several types of special effect pigments, those with a low refractive index such as fluorescent or photochromic pigments, and those with a higher refractive index such as mother-of-pearl, interference pigments or glitter.

[0191] Examples of special effect pigments include pearlescent pigments such as titanium-coated mica or bismuth oxychloride, colored pearlescent pigments such as titanium-coated mica with iron oxides, iron oxide-coated mica, titanium-coated mica, particularly with ferric blue or chromium oxide, titanium-coated mica with an organic pigment as defined above, and bismuth oxychloride-based pearlescent pigments. Examples of pearlescent pigments include Cellini pearlescent pigments marketed by BASF (Mica-TiO2-lacquer), Prestige pearlescent pigments marketed by Eckart (Mica-TiO2), Prestige Bronze pearlescent pigments marketed by Eckart (Mica-Fe2O3), and Colorona pearlescent pigments marketed by Merck (Mica-TiO2-Fe2O3).

[0192] We can also mention gold-colored mother-of-pearl, notably marketed by BASF under the names Brilliant Gold 212G (Timica), Gold 222C (Cloisonne), Sparkle Gold (Timica), Gold 4504 (Chromalite) and Monarch Gold 233X (Cloisonne); bronze mother-of-pearl, notably marketed by MERCK under the names Bronze Fine (17384) (Colorona) and Bronze (17353) (Colorona) and by BASF under the name Super Bronze (Cloisonne); orange mother-of-pearl, notably marketed by BASF under the names Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by MERCK under the names Passion Orange (Colorona) and Matte Orange (17449) (Microna); brown-tinted mother-of-pearl, notably marketed by BASF under the names Nu-antique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite); copper-tinted mother-of-pearl, notably marketed by BASF under the name Copper 340A (Timica);red-tinted mother-of-pearl, notably marketed by MERCK under the name Sienna fine (17386) (Colorona); yellow-tinted mother-of-pearl, notably marketed by BASF under the name Yellow (4502) (Chromalite); red-tinted mother-of-pearl with a gold sheen, notably marketed by BASF under the name Sunstone G012 (Gemtone); pink mother-of-pearl, notably marketed by BASF under the name Tan opale G005 (Gemtone);black mother-of-pearl with a gold sheen, notably marketed by BASF under the name Nu antique bronze 240 AB (Timica); blue mother-of-pearl, notably marketed by MERCK under the name Matte blue (17433) (Microna); white mother-of-pearl with a silver sheen, notably marketed by MERCK under the name Xirona Silver; and orange-pink-green-gold mother-of-pearl, notably marketed by MERCK under the name Indian summer (Xirona), and their mixtures.

[0193] As further examples of nacres, we can also mention particles comprising a borosilicate substrate coated with titanium oxide.

[0194] Particles with a glass substrate coated with titanium oxide are notably sold under the name METASHINE MC1080RY by the company TOYAL.

[0195] Finally, examples of mother-of-pearl include polyethylene terephthalate flakes, particularly those marketed by Meadowbrook Inventions under the name Silver IP 0.004X0.004 (silver flakes). Multilayer pigments based on synthetic substrates such as alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate, and aluminum can also be considered.

[0196] Special effect pigments can also be chosen from reflective particles, that is to say, in particular, particles whose size, structure, in particular the thickness of the layer or layers that constitute them and their physical nature Their chemical composition and surface condition allow them to reflect incident light. This reflection can, where appropriate, have sufficient intensity to create visible highlights on the surface of the composition or mixture when applied to the makeup base; these are brighter spots that contrast with their surroundings, appearing to shine.

[0197] Reflective particles can be selected so as not to significantly alter the coloring effect generated by the coloring agents associated with them, and more particularly so as to optimize this effect in terms of color rendering. They may, in particular, have a yellow, pink, red, bronze, orange, brown, gold, and / or copper color or reflection.

[0198] These particles can have various shapes, including being platelet-shaped or globular, particularly spherical.

[0199] Reflective particles, whatever their shape, may or may not have a multilayer structure and, in the case of a multilayer structure, for example at least one layer of uniform thickness, in particular of a reflective material.

[0200] When reflective particles do not have a multilayer structure, they can be composed, for example, of metal oxides, in particular titanium or iron oxides obtained by synthesis.

[0201] When reflective particles have a multilayer structure, they may, for example, comprise a natural or synthetic substrate, in particular a synthetic substrate at least partially coated by at least one layer of a reflective material, in particular at least one metal or metallic material. The substrate may be monomaterial, multimaterial, organic and / or inorganic.

[0202] More specifically, it may be selected from glasses, ceramics, graphite, metal oxides, aluminas, silicas, silicates, in particular aluminosilicates and borosilicates, synthetic mica and mixtures thereof, this list not being exhaustive.

[0203] The reflective material may include a layer of metal or a metallic material.

[0204] Reflective particles are described in particular in documents JP-A-09188830, JP-A-10158450, JP-A-10158541, JP-A-07258460 and JP-A-05017710.

[0205] As further examples of reflective particles comprising a mineral substrate coated with a layer of metal, one can also mention particles comprising a borosilicate substrate coated with silver.

[0206] Silver-coated glass substrate particles in the form of wafers are sold under the name MICROGLASS METASHINE REFSX 2025 PS by the company TOYAL. Nickel / chromium / molybdenum alloy-coated glass substrate particles are sold under the name CRYSTAL STAR GF 550, GF 2525 by the same company.

[0207] Particles comprising a metallic substrate such as silver, aluminum, iron, chromium, nickel, molybdenum, gold, copper, zinc, tin, magnesium, steel, bronze, titanium may also be used, said substrate being coated with at least one layer of at least one metallic oxide such as titanium oxide, aluminum oxide, iron oxide, cerium oxide, chromium oxide, silicon oxides and mixtures thereof.

[0208] An example can be cited as aluminium, bronze or copper powders coated with SiO2 marketed under the name VISIONAIRE by the company ECKART.

[0209] Other examples include non-substrate interference pigments such as liquid crystals (Wacker's Helicones HC) and interference holographic glitter (Spectratek's Geometry Pigments or Spectra f / x). Special effect pigments also include fluorescent pigments, whether daylight fluorescent or ultraviolet fluorescent, phosphorescent pigments, photochromic pigments, thermochromic pigments, and quantum dots, marketed, for example, by Quantum Dots Corporation.

[0210] The variety of pigments that can be used in the present invention makes it possible to obtain a rich palette of colors, as well as particular optical effects such as metallic, interference effects.

[0211] The size of the pigment used in the composition according to the present invention is generated typically between 5 nm and 200 µm, preferably between 7 nm and 80 µm, and more preferably between 10 nm and 50 µm.

[0212] The pigments can be dispersed within the composition by means of a dispersing agent.

[0213] The dispersing agent serves to protect the dispersed particles from agglomeration or flocculation. This dispersing agent may be a surfactant, an oligomer, a polymer, or a mixture of several of these, possessing one or more functionalities with a strong affinity for the surface of the particles to be dispersed. In particular, they may adhere physically or chemically to the surface of the pigments. These dispersants also have at least one functional group that is compatible with or soluble in the continuous medium.In particular, esters of 12-hydroxystearic acid are used, especially C8 to C20 fatty acids and polyols such as glycerol and diglycerin, such as poly(12-hydroxystearic acid) stearate with a molecular weight of approximately 750g / mol, such as that sold under the name Solsperse 21 000 by Avecia, polyglyceryl-2 dipolyhydroxystearate (name CTFA) sold under the reference Dehymyls PGPH by Henkel, or polyhydroxystearic acid such as that sold under the reference Arlacel P100 by Uniqema and their mixtures.

[0214] As another dispersant that can be used in the compositions of the invention, we can mention quaternary ammonium derivatives of polycondensed fatty acids such as Solsperse 17 000 sold by Avecia, poly dimethylsiloxane / oxypropylene mixtures such as those sold by Dow Corning under the references DC2-5185, DC2-5225 C.

[0215] The pigments used in the composition can be surface treated with an organic agent.

[0216] Thus, the pigments previously surface-treated useful within the framework of the invention are pigments which have undergone totally or partially a surface treatment of a chemical, electronic, electro-chemical, mechano-chemical or mechanical nature, with an organic agent such as those described in particular in Cosmetics and Toiletries, February 1990, Vol. 105, pp. 53-64 before being dispersed in the composition according to the invention.These organic agents can be chosen, for example, from waxes, such as carnauba wax and beeswax; fatty acids, fatty alcohols and their derivatives, such as stearic acid, hydroxystearic acid, stearyl alcohol, hydroxystearyl alcohol, lauric acid and their derivatives; anionic surfactants; lecithins; sodium, potassium, magnesium, iron, titanium, zinc or aluminum salts of fatty acids, for example aluminum stearate or laurate; polyethylene; (meth)acrylic polymers, for example polymethylmethacrylates; polymers and copolymers containing acrylate motifs; alkanoamines; fluorinated organic compounds, for example perfluoroalkyl ethers; fluorosilicone compounds.

[0217] The surface-treated pigments useful in the composition may also have been treated by a mixture of these compounds and / or have undergone several surface treatments.

[0218] The surface-treated pigments useful in the context of the present invention can be prepared using surface treatment techniques well known to those skilled in the art or found as such in the commercial market.

[0219] Preferably, the surface-treated pigments are covered by an organic layer.

[0220] The organic agent with which the pigments are treated can be deposited on the pigments by solvent evaporation, chemical reaction between the molecules of the surfactant or creation of a covalent bond between the surfactant and the pigments.

[0221] Surface treatment can thus be achieved, for example, by a chemical reaction of a surfactant with the surface of the pigments and the creation of a covalent bond between the surfactant and the pigments or fillers. This method is described in particular in US patent 4,578,266.

[0222] Preferably, an organic agent bound to the pigments will be used in such a way covalent.

[0223] The surface treatment agent may represent from 0.1 to 50% by weight of the total weight of the pigment treated on the surface, preferably from 0.5 to 30% by weight, and even more preferably from 1 to 20% by weight of the total weight of the pigment treated on the surface.

[0224] Preferably, the surface treatments of the pigments are chosen from the following treatments: - a PEG-Silicone treatment such as the AQ surface treatment marketed by LCW; - a Methicone treatment such as the SI surface treatment marketed by LCW; - a Dimethicone treatment such as the Covasil 3.05 surface treatment marketed by LCW; - a Dimethicone / Trimethylsiloxysilicate treatment such as the Covasil 4.05 surface treatment marketed by LCW; - a Magnesium Myristate treatment such as the MM surface treatment marketed by LCW; - a Dimyristate Aluminium treatment such as the MI surface treatment marketed by Miyoshi; - a Perfluoropolymethylisopropyl ether treatment such as the FHC surface treatment marketed by LCW; - an Isostearyl Sebacate treatment such as the HS surface treatment marketed by Miyoshi; - a Perfluoroalkyl Phosphate treatment such as the PF surface treatment marketed by Daito; - an acrylate / dimethicone copolymer and perfluoalkyl phosphate treatment such as the FSA surface treatment marketed by Daito; - a Polymethylhydrogen siloxane / Perfluoroalkyl Phosphate treatment such as the FS01 surface treatment marketed by Daito; - an Acrylate / Dimethicone Copolymer treatment such as the ASC surface treatment marketed by Daito; - an Isopropyl Titanium Triisostearate treatment such as the ITT surface treatment marketed by Daito; - an Acrylate copolymer treatment such as the APD surface treatment marketed by Daito; - a Perfluoroalkyl Phosphate / Isopropyl Titanium Triisostearate treatment such as the PF + ITT surface treatment marketed by Daito.

[0225] According to a particular embodiment of the invention, the dispersing agent is present with organic or inorganic pigments in submicron-sized particulate form in the colouring composition.

[0226] By "sub-micronic" or in English "sub-micronic" is meant pigments whose particle size has been micronized by micronization method and whose average particle size is less than one micrometer (pm), in particular between 0.1 and 0.9 pm, and preferably between 0.2 and 0.6 pm.

[0227] According to one embodiment, the dispersing agent and the pigment(s) are present in an amount (dispersant: pigment) between 1:4 and 4:1, particularly between 1.5:3.5 and 3.5:1 or better between 1.75:3 and 3:1.

[0228] The dispersing agent(s) may therefore have a silicone skeleton, such as silicone polyether and amino-silicone dispersants, other than the amino silicones or alkoxysilanes of formula (I) or formula (T) previously described in the application. Suitable dispersing agents include: - amino-silicones, i.e. silicones comprising one or more amino groups, such as those marketed under the names and references: BYK LPX 21879, by BYK, GP-4, GP-6, GP-344, GP-851, GP-965, GP-967 and GP-988-1, marketed by Genesee les polymers, - silicone acrylates such as Tego ® RC 902, Tego ® RC 922, Tego ® RC 1041, and Tego ® RC 1043, marketed by Evonik, - polydimethylsiloxane (PDMS) silicones with carboxylic groups such as X-22162 and X-22370 by Shin-Etsu, silicone epoxy such as GP-29, GP-32, GP-502, GP-504, GP-514, GP-607, GP-682, and GP-695, by Genesee Polymers, or Tego ® RC 1401, Tego ® RC 1403, Tego ® RC 1412, by Evonik.

[0229] According to a particular embodiment, the dispersing agent(s) are of the amino-silicone type, different from the amino silicones or alkoxysilanes of formula (I) or formula (T) previously described in the application and are cationic.

[0230] Preferably, the pigment(s) is / are chosen from mineral, mixed mineral-organic or organic pigments.

[0231] In one embodiment of the invention, the pigment(s) according to the invention are organic pigments. In another embodiment of the invention, the pigment(s) according to the invention are mineral pigments.

[0232] Composition A and / or composition B according to the invention may (can) comprise one or more direct dye(s).

[0233] By "direct dye" we mean natural and / or synthetic dyes, different from oxidation dyes. These are dyes that will diffuse superficially onto the fiber.

[0234] They can be ionic or non-ionic, preferably anionic, cationic or non-ionic.

[0235] Examples of suitable direct dyes that may be mentioned include azo direct dyes; (poly)methine dyes such as cyanines, hemicyanines and styryls; carbonyl dyes; azine dyes; nitro(hetero)aryl dyes; tri(hetero)arylmethane dyes; porphyrin dyes; phthalocyanine dyes and natural direct dyes, alone or in mixtures.

[0236] Direct dyes are preferably cationic direct dyes. Examples include the hydrazono cationic dyes of formulas (III) and (IV), and the azo cationic dyes (V) and (VI) below: (III) Her-C(Ra)=^-N(Rb)-MQ Het+-N(Ra)-N=C <rb)-ars q- Her-N=N-Ai; Q- + (VI) Ai'*-N=i\-Ar , Q- formulas (III) to (VI) in which: - Het+ represents a cationic heteroaryl radical, preferably with endocyclic cationic charge such as imidazolium, indolium, or pyridinium, possibly preferentially substituted by at least one (CrC8)alkyl group such as methyl; - Ar+ represents an aryl radical, such as phenyl or naphthyl, with an exocyclic cationic charge, preferably ammonium, particularly tri(Ci-C8)alkyl-ammonium such as trimethylammonium; - Ar represents an aryl group, in particular phenyl, possibly substituted, preferably by one or more electron-donating groups such as i) (Ci-C8)alkyl possibly substituted, ii) (Ci-C8)alkoxy possibly substituted, iii) (di)(Ci-C8)(alkyl)amino possibly substituted on the alkyl group(s) by a hydroxyl group, iv) aryl(Ci-C8)alkylamino, v) N-(Ci-C8)alkyl-N-aryl(Ci-C8)alkylamino possibly substituted or else Ar represents a julolidine group; - Ar” represents a (hetero)aryl group possibly substituted such as phenyl or pyrazolyl possibly substituted, preferably by one or more (CrC8)alkyl, hydroxyl, (di)(Ci-C8)(alkyl)amino, (CrC8)alkoxy or phenyl groups; - Ra and Rb, identical or different, representing a hydrogen atom or a (CrC8)alkyl group possibly substituted, preferably by a hydroxyl group; or the Ra substituent with a Het+ substituent and / or Rb with a substituent of Ar together with the atoms that bear them form a (hetero)cycloalkyl; particularly Ra and Rb, representing a hydrogen atom or a (CrC4)alkyl group possibly substituted by a hydroxyl group; - Q- represents an organic or mineral anionic counter-ion such as a halide or an alkyl sulfate.

[0237] In particular, one may cite the endo-cyclic cationic direct dyes of azo and hydrazono of formula (III) to (VI) as defined above. More particularly, the endo-cyclic cationic direct dyes described in patent applications WO 95 / 15144, WO 95 / 01772 and EP-714954.

[0238] Preferably the following direct dyes: formulas (VII) and (VIII) in which: - R1 represents an (Ci-C4)alkyl group such as methyl; - R2 and R3, whether identical or different, represent a hydrogen atom or an (Ci-C4)alkyl group such as methyl; and - R4 represents a hydrogen atom or an electron-donating group such as (Ci-C8)alkyl possibly substituted, (Ci-C8)alkoxy possibly substituted, (di)(CrC8)(alkyl)amino possibly substituted on the alkyl group(s) by a hydroxyl group; particularly R4 is a hydrogen atom, - Z represents a CH group or a nitrogen atom, preferably CH, - Q- is an anionic counter ion as defined previously, particularly a halide such as chloride or an alkyl sulfate such as methyl sulfate or mesytyl.

[0239] Particularly the colorants of formula (VII) and (VIII) are selected from Basic Red 51, Basic Yellow 87 and Basic Orange 31 or their derivatives with Q' an anionic counter ion as defined above, particularly a halide such as chloride or an alkyl sulfate such as methyl sulfate or mesytyl.

[0240] Direct dyes may be selected from anionic direct dyes. The The anionic direct dyes of the invention are dyes commonly called "acid" direct dyes because of their affinity for alkali substances. Anionic direct dyes are defined as any direct dye having in its structure at least one CO2R or SO3R substituent, where R designates a hydrogen atom, a cation from a metal or amine, or an ammonium ion. Anionic dyes can be selected from among acidic nitro direct dyes, acidic azo dyes, acidic azinic dyes, acidic triarylmethanic dyes, acidic indoamine dyes, acidic anthraquinone dyes, indigoids, and acidic natural dyes.

[0241] By way of acid dyes according to the invention, the following dyes of formulas (IX), (IX'), (X), (X'), (XI), (XI'), (XII), (XII'), (XIII), (XIV), (XV) and (XVI) may be cited: a) Diaryl anionic azo dyes of formula (IX) or (IX'): formulas (IX) and (IX') in which: R7, Rs, R9, Rio, R'7, R's, R'9 and R'1O, whether identical or different, represent a hydrogen atom or a group chosen from: - alkyl; - alkoxy, alkylthio; - hydroxy, mercapto; - nitro, nitroso; - R°-C(X)-X'-, R°-X'-C(X)-, R°-X'-C(X)-X”- with R° representing a hydrogen atom, an alkyl or aryl group; X, X' and X”, identical or different, representing an oxygen, sulfur or NR atom with R representing a hydrogen atom or an alkyl group; - (0)2S(0-)-, M+ with M+ representing a hydrogen atom or a cationic counter-ion; - (O)CO—, M+ with M+ as defined previously; - R”-S(O)2-, with R” representing a hydrogen atom, an alkyl group, an aryl group, (di)(alkyl)amino, aryl(alkyl)amino; preferably a phenylamino or phenyl group; - R”'-S(O)2-X'- with R'” representing an alkyl group, possibly substituted aryl, X' as defined previously; - (di)(alkyl)amino; - aryl(alkyl)amino possibly substituted by one or more groups chosen from i) nitro; ii) nitroso; iii) (O)2S(O-)-, M+ and iv) alkoxy with M+ as defined above; - heteroaryl possibly substituted; preferably a benzo-thiazolyl group; - cycloalkyl; in particular cyclohexyl, - Ar-N=N- with Ar representing an aryl group possibly substituted; preferably a phenyl possibly substituted by one or more alkyl groups, (O)2S(O-)-, M+ or phenylamino; - or two contiguous groups R7 with R8 or R8 with R9 or R9 with Rio together form a fused benzo group A'; and R'7 with R'8 or R'8 with R'9 or R'9 with R'10 together form a fused benzo group B'; with A' and B' possibly substituted by one or more groups chosen from i) nitro; ii) nitroso; iii) (O)2S(O-)-, M+; iv) hydroxy; v) mercapto; vi) (di)(alkyl)amino; vii) R°-C(X)-X'-; vüi) R°-X'-C(X)-; ix) R°-X'-C(X)-X”-; x) Ar-N=N- and xi) aryl(alkyl)amino possibly substituted; with M+, R°, X, X', X” and Ar as defined above; - W represents a sigma bond, an oxygen atom, a sulfur atom, or a divalent radical i) -NR- with R as defined previously, or ii) methylene -C(Ra)(Rb)- with Ra and Rb identical or different, representing a hydrogen atom or an aryl group, or Ra and Rb together with the carbon atom bearing them form a spiro cycloalkyl; preferably W represents a sulfur atom or Ra and Rb together form a cyclohexyl; provided that formulas (IX) and (IX') comprise at least one sulfonate radical (O)2S(O-)-, M+ or one carboxylate radical (O)CO-, M+ on one of the rings A, A', B, B' or C; preferably sodium sulfonate;

[0242] Examples of colorants of formula (IX) include: Acid Red 1, Acid Red 4, Acid Red 13, Acid Red 14, Acid Red 18, Acid Red 27, Acid Red 28, Acid Red 32, Acid Red 33, Acid Red 35, Acid Red 37, Acid Red 40, Acid Red 41, Acid Red 42, Acid Red 44, Pigment red 57, Acid Red 68, Acid Red 73, Acid Red 135, Acid Red 138, Acid Red 184, Food Red 1, Food Red 13, Acid Orange 6, Acid Orange 7, Acid Orange 10, Acid Orange 19, Acid Orange 20, Acid Orange 24, Yellow 6, Acid Yellow 9, Acid Yellow 36, Acid Yellow 199, Food Yellow 3; Acid Violet 7, Acid Violet 14, Acid Bine 113, Acid Bine 117, Acid Black 1, Acid Brown 4, Acid Brown 20, Acid Black 26, Acid Black 52, Food Black 1, Food Black 2; Food yellow 3 or sunset yellow; and as an example of dyes of formula (IX') we can cite: Acid Red 111, Acid Red 134, Acid yellow 38.

[0243] b) the azo anionic pyrrazolone dyes of formula (X) and (X'): (X') formulas (X) and (X') in which: - Ru, Rn and Ri3, whether identical or different, represent a hydrogen atom, a halogen atom, an alkyl group or -(O)2S(O-), M+ with M+ as defined previously; - Rm represents a hydrogen atom, an alkyl group or a -C(O)O- group, M+ with M+ as defined previously; - Ru represents a hydrogen atom; - Ris represents an oxo group in which case R' i6 is absent, or else Ri5 with Ri6 together form a double bond; - Ru and Ri, identical or different, represent a hydrogen atom, or a group chosen from: - (O)2S(O-)-, M+ with M+ as defined previously; - Ar-OS(O)2- with Ar representing an aryl group possibly substituted; preferably a phenyl possibly substituted by one or more alkyl groups; - R19 and R20 together form either a double bond or a benzo D' group, possibly substituted; - R'i6, R'19 and R'20, identical or different, represent a hydrogen atom or an alkyl or hydroxy group; - R2i represents a hydrogen atom, an alkyl group, or alkoxy; Ra and Rb, whether identical or different, are as defined previously, preferably Ra represents a hydrogen atom and Rb represents an aryl group; - Y represents either a hydroxy group or an oxo group; - _ _ _ _ represents a simple bond when Y is an oxo group; and represents a double bond when Y represents a hydroxy group; provided that the formulas (X) and (X') include at least one sulfonate radical (O)2S(O-)-, M+ or one carboxylate radical -C(O)O-, M+ on one of the rings D or E; preferably sodium sulfonate;

[0244] Examples of colorants of formula (X) include: Acid Red 195, Acid Yellow 23, Acid Yellow 27, Acid Yellow 76, and examples of colorants of formula (X') include: Acid Yellow 17;

[0245] c) the anthraquinone dyes of formula (XI) and (XI'): formulas (XI) and (XI') in which: - R22, R23, R24, R25, R26 and R27, whether identical or different, represent a hydrogen atom, a halogen atom, or a group chosen from: - alkyl; - hydroxy, mercapto; - alkoxy, alkylthio; - aryloxy or arylthio possibly substituted, preferably substituted by one or more groups chosen from alkyl and (O)2S(O-)-, M+ with M+ as defined above; - aryl(alkyl)amino possibly substituted by one or more groups chosen from alkyl and (O)2S(O-)-, M+ with M+ as defined previously; - (di)(alkyl)amino; - (di)(hydroxyalkyl)amino - (O)2S(O-)-, M+ with M+ as defined previously; -Z' represents a hydrogen atom or a group NR28R29 where R28 and R29, identical or different, represent a hydrogen atom or a group chosen from: - alkyl; - polyhydroxyalkyl such as hydroxyethyl; - aryl possibly substituted by one or more particularly i) alkyl groups such as methyl, n-dodecyl, n-butyl; ii) (O)2S(O-)-, M+ with M+ as defined previously; iii) R°-C(X)-X'-, R°-X'-C(X)-, R°-X'-C(X)-X”- with R°, X, X' and X” as defined previously, preferably R° represents an alkyl group; - cycloakyl; in particular cyclohexyl; - Z, represents a group chosen from hydroxy and NR'28R'29 with R'28 and R'29, identical or different, represent the same atoms or groups as R28 and R29 as defined previously; provided that formulas (XI) and (XI') comprise at least one sulfonate radical (O)2S(O-)-, M+ or one carboxylate radical -C(O)O-, M+; preferably sodium sulfonate;

[0246] Examples of colorants of formula (XI) include: Acid Blue 25, Acid Blue 43, Acid Blue 62, Acid Blue 78, Acid Blue 129, Acid Blue 138, Acid Blue 140, Acid Blue 251, Acid Green 25, Acid Green 41, Acid Violet 42, Acid Violet 43, Mordant Red 3; EXT violet No. 2; and examples of colorants of formula (XI') include: Acid Black 48;

[0247] d) Nitrated dyes of formula (XII), (XII'): (XII) formulas (XII) and (XII') in which: - R30, R31 and R32, whether identical or different, represent a hydrogen atom, a halogen atom, or a group chosen from: - alkyl; - alkoxy possibly substituted by one or more hydroxy groups, alkylthio possibly substituted by one or more hydroxy groups; - hydroxy, mercapto; - nitro, nitroso; - polyhalogenoalkyl; - R°-C(X)-X'-, R°-X'-C(X)-, R°-X'-C(X)-X”- with R° ; X, X' and X” as defined previously; - (0)2S(0-)-, M+ with M+ as defined previously; - (0)C0—, M+ with M+ as defined previously; - (di)(alkyl)amino; - (di)(hydroxyalkyl)amino; - heterocycloalkyl such as piperidino, piperazino or morpholino; particularly R30, R3i and R32 represent a hydrogen atom; Rc and Rd, whether identical or different, represent a hydrogen atom or an alkyl group; - W is as defined previously; W particularly represents a -NH- group; - ALK represents a linear or branched divalent alkylene group, in Ci-C6; particularly ALK represents a -CH2-CH2- group; - n is equal to 1 or 2; - p represents an integer between 1 and 5 inclusive; - q represents an integer between 1 and 4 inclusive; - u is equal to 0 or 1; - when n equals 1, J represents a nitro or nitroso group; particularly nitro - when n equals 2, J represents an oxygen atom, a sulfur atom, or a divalent radical -S(O)m- with m representing an integer 1 or 2; preferably J represents a radical -SO2-; - M' represents a hydrogen atom or a cationic counter-ion; The presence or absence of a benzo group may represent a benzo group. substituted by one or more R30 groups as defined above, it being understood that formulas (XII) and (XII') comprise at least one sulfonate radical (O)2S(O-)-, M+ or one carboxylate radical -C(O)O-, M+; preferably sodium sulfonate.

[0248] By way of example of colorants of formula (XII) the following may be cited: Acid Brown 13; Acid Orange 3; by way of example of colorants of formula (XII') the following may be cited: Acid Yellow 1, Sodium salt of 2,4-dinitro-1-naphthol-7-sulfonic acid, 2-piperidino-5-nitrobenzenesulfonic acid, 2(4'-N,N(2'-hydroxyethyl)amino-2'-nitro)aniline ethanesulfonic acid, 4-[3-hydroxyethylamino-3-nitrobenzenesulfonic acid; EXT D&C yellow 7;

[0249] e) triarylmethane dyes of formula (XIII): (XIII) formula (XIII) in which: - R33, R34, R35 and R36, identical or different, represent a hydrogen atom or a group chosen from alkyl, possibly substituted aryl and possibly substituted arylalkyl; particularly an alkyl and benzyl group possibly substituted by an (O)mS(O-)-, M+ group with M+ and m as defined previously; - R37, R38, R39, R40, R41, R42, R43 and R44, whether identical or different, represent a hydrogen atom or a group chosen from: - alkyl; - alkoxy, alkylthio; - (di)(alkyl)amino; - hydroxy, mercapto; - nitro, nitroso; - R°-C(X)-X'-, R°-X'-C(X)-, R°-X'-C(X)-X”- with R° representing a hydrogen atom, an alkyl or aryl group; X, X' and X”, identical or different, representing an oxygen, sulfur or NR atom with R representing a hydrogen atom or an alkyl group; - (O)2S(O-)-, M+ with M+ representing a hydrogen atom or a cationic counter-ion; - (O)CO—, M+ with M+ as defined previously; - or two contiguous groups R4[ with R42 or R42 with R41 or R43 with R44 together form a fused benzo group: I'; with I' possibly substituted by one or more groups chosen from i) nitro; ii) nitroso; iii) (O)2 S(O-)-, M+; iv) hydroxy; v) mercapto; vi) (di)(alkyl)amino; vii) R°-C(X)-X'-; viii) R°-X'-C(X)-; ix) R°-X'-C(X)-X”-; with M+, R°, X, X', X” as defined previously; particularly R37 to R^ represent a hydrogen atom, and R4i to R^, identical or different, represent a hydroxyl group or (O)2S(O-)-, M+; and when R4i together with R44 form a benzo group, it is preferentially substituted by an (O)2S(O-)- group; provided that at least one of the rings G, H, I or I' includes at least one sulfonate radical (O)2S(O-)- or one carboxylate radical -C(O)O-; preferably sulfonate;

[0250] Examples of colorants of formula (XIII) include: Acid Blue 1; Acid Blue 3; Acid Blue 7; Acid Blue 9; Acid Violet 49; Acid green 3; Acid green 5; Acid Green 50;

[0251] f) xanthene-derived dyes of formula (XIV): formula (XIV) in which: - R45, R46, R47 and R48, whether identical or different, represent a hydrogen atom or a halogen atom; - R49, R5o, R5i and R52, whether identical or different, represent a hydrogen atom, a halogen atom, or a group chosen from: - alkyl; - alkoxy, alkylthio; - hydroxy, mercapto; - nitro, nitroso; - (O)2S(O-)-, M+ with M+ representing a hydrogen atom or a cationic counter-ion; - (O)CO—, M+ with M+ as defined previously; Specifically, R53, R54, R55 and R48 represent a hydrogen or halogen atom - G represents an oxygen atom, sulfur atom, or an NRe group with Re as defined previously; particularly G represents an oxygen atom; - L represents an O-, M+ alkoxide; an S-, M+ thioalkoxide or an NRf group, with Rf representing a hydrogen atom or an alkyl group, and M+ as defined previously; M+ is particularly sodium or potassium; - The ' represents an oxygen atom, a sulfur atom, or an ammonium group: N+RfRg, with Rf and Rg, identical or different, representing a hydrogen atom, an alkyl group, possibly substituted aryl; L' particularly represents an oxygen atom or a phenylamino group possibly substituted by one or more alkyl groups or (O)mS(O-)-, M+ with m and M+ as defined previously; - Q and Q', whether identical or different, represent an oxygen or sulfur atom; particularly Q and Q' represent an oxygen atom; - M+ is as defined previously;

[0252] As an example of colorants of formula (XIV) we can cite: Acid Yellow 73; Acid Red 51; Acid Red 52, Acid Red 87; Acid Red 92; Acid Red 95; Acid Violet 9;

[0253] g) dyes derived from indole of formula (XV): - R53, R54, R55, R56, R57, Rss, R59 and R60, whether identical or different, represent a hydrogen atom or a group chosen from: - alkyl; - alkoxy, alkylthio; - hydroxy, mercapto; - nitro, nitroso; - R°-C(X)-X'-, R°-X'-C(X)-, R°-X'-C(X)-X”- with R° representing a hydrogen atom, an alkyl or aryl group; X, X' and X”, identical or different, representing an oxygen, sulfur or NR atom with R representing a hydrogen atom or an alkyl group; - (O)2S(O-)-, M+ with M+ representing a hydrogen atom or a cationic counter-ion; - (O)CO—, M+ with M+ as defined previously; - G represents an oxygen atom, sulfur atom, or an NRe group with Re as defined previously; particularly G represents an oxygen atom; - Ri and Rh, whether identical or different, represent a hydrogen atom or an alkyl group; provided that formula (XV) comprises at least one sulfonate radical (O)2 S(O-)-, M+ or one carboxylate radical -C(O)O-, M+; preferably sodium sulfonate

[0254] As an example of colorants of formula (XV) we can cite: Acid Blue 74.

[0255] h) quinoline-derived dyes of formula (XVI) - R61 represents a hydrogen atom, a halogen atom, or an alkyl group; - R62, R63, and R64, identical or different, represent a hydrogen atom or a (O)2S(O-)- group, M+ with M+ representing a hydrogen atom or a cationic counter-ion; or R6[ with R62, or R6[ with R64, together form a benzo group possibly substituted by one or more (O)2S(O-)- groups, M+ with M+ representing a hydrogen atom or a cationic counter-ion; it being understood that formula (XVI) includes at least one sulfonate radical (O)2 S(O-)-, M+ preferably sodium sulfonate.

[0256] Examples of colorants of formula (XVI) include: Acid Yellow 2, Acid Yellow 3 and Acid Yellow 5.

[0257] Among the natural direct dyes that can be used according to the invention are lawsone, juglone, alizarin, purpurin, carminic acid, kermesic acid, purpurogallin, protocatechaldehyde, indigo, isatin, curcumin, spinulosin, apigenidine, and orceins. Extracts or decoctions containing these natural dyes, and in particular henna-based poultices or extracts, can also be used.

[0258] Preferably, the direct dyes are chosen from anionic direct dyes.

[0259] The colouring agent(s) may be present in a total quantity from 0.001 to 20%, preferably from 0.005 to 15% by weight, better from 0.005 to 10% by weight relative to the total weight of composition A and / or composition B.

[0260] The pigments may be present in a total quantity ranging from 0.05 to 20% by weight, preferably from 0.1 to 15% by weight, better from 0.5 to 10% by weight relative to the total weight of composition A and / or composition B.

[0261] The direct colorant(s) may be present in a total quantity ranging from 0.001 to 10% by weight of the total weight of the composition, preferably from 0.005 to 5% by weight of the total weight of composition A and / or composition B. Solvent:

[0262] Composition A and / or composition B according to the invention may comprise water. Preferably, the water is present in a content ranging from 0.1% to 95% by weight, more preferably from 1% to 90% by weight, better from 10% to 85% by weight relative to the total weight of composition A and / or composition B.

[0263] When composition A and / or composition B according to the invention comprises (include) water, the pH of composition A and / or composition B is preferably alkaline.

[0264] In order to adjust the pH, composition A and / or composition B may include an alkaline agent.

[0265] Preferably, composition A and / or composition B according to the invention comprises an alkaline agent.

[0266] The pH of the compositions is measured at room temperature.

[0267] Examples of alkaline agents include ammonia, alkanolamines, and / or basic amino acids.

[0268] Preferably, the alkanolamine(s) are selected from monoethanolamine,

[0269] triethanolamine, monoisopropanolamine, diisopropanolamine, N-dimethylaminoethanolamine, 2-amino-2-methyl-l-propanol, triisopropanolamine, 2-amino-2-methyl-l,3-propanediol, 3-amino-l,2-propanediol, 3-dimethylamino-l,2-propanediol, and trishydroxymethylaminomethane. More preferably, the alkanolamine(s) are selected from monoethanolamine and / or 2-amino-2-methyl-l-propanol.

[0270] For the purposes of this invention, "amino acid" means organic compounds having two functional groups: both a carboxyl group -COOH or car-boxylate and an amine group -NH2, the amine group optionally being methylated, i.e. in the form -NR2 or N+R3, where at least one R=CH3.

[0271] Preferably, the amino acid or acids are chosen from aminocarboxylic acids such as alpha-aminocarboxylic acid.

[0272] By "basic amino acid" is meant amino acids having an isoelectric point greater than 7.

[0273] Preferably, the basic amino acid(s) are chosen from arginine, lysine, ornithine and / or histidine, more preferably arginine and / or lysine.

[0274] According to a particular embodiment, composition A may include an inorganic alkali agent, preferably selected from ammonium hydroxide, sodium hydroxide, potassium hydroxide, calcium hydroxide, barium hydroxide, sodium phosphate, potassium phosphate, sodium silicate, sodium metasilicate, potassium silicate, sodium carbonate and / or potassium carbonate.

[0275] Preferably, composition A and / or composition B comprises(s) a alkaline agent chosen from ammonia, monoethanolamine, 2-amino-2-methyl-l-propanol, arginine and / or lysine.

[0276] Composition A and / or composition B may also include acidifying agents to adjust the pH.

[0277] Preferably, the acidifying agents are chosen from citric acid, lactic acid, acetic acid and / or mineral acids such as hydrochloric acid, sulfuric acid, phosphoric acid and mixtures thereof. Additives:

[0278] Composition A and / or composition B according to the invention may also contain any adjuvant or additive usually used.

[0279] Among the additives that may be contained in the composition, we can mention reducing agents, thickening agents other than the polymers previously described, softeners, anti-foaming agents, moisturizing agents, UV filters, peptizers, dispersants, perfumes, anionic, cationic, non-ionic or amphoteric surfactants, proteins, vitamins, preservatives, waxes and mixtures thereof.

[0280] Composition A and / or composition B may be in particular in the form of a suspension, dispersion, gel, emulsion, in particular an oil-in-water (O / W) or water-in-oil (W / O) emulsion, or multiple emulsion (W / O / W or polyol / O / W or O / W / O), in the form of a cream, foam, stick, vesicle dispersion in particular of ionic or non-ionic lipids, bi-phase or multi-phase lotion, an anhydrous liquid or an anhydrous gel.

[0281] According to a particular embodiment, composition A according to the invention is an anhydrous liquid or an anhydrous gel.

[0282] According to a particular embodiment, composition B according to the invention is a dispersion.

[0283] A person skilled in the art will be able to choose the appropriate galenic form, as well as its method of preparation, on the basis of their general knowledge, taking into account on the one hand the nature of the constituents used, in particular their solubility in the support, and on the other hand the application envisaged for composition A and / or composition B.

[0284] According to a preferred embodiment, composition A according to the invention comprises at least one alkoxysilane of formula (I) as described above, at least one al-coxysilane of formula (II) as described above, and at least one pigment.

[0285] According to a more preferred embodiment, composition A according to the invention comprises 3-aminopropyltriethoxysilane (APTES), methyltrimethoxysilane (MTMS) or methyltriethoxysilane (MTES) and at least one pigment.

[0286] According to a preferred embodiment, composition B according to the invention comprises at least one film-forming polymer selected from vinylpyrrolidone (PVP) homopolymers, vinylpyrrolidone copolymers, acrylamide copolymers, acrylic acid ester homopolymers or copolymers, ethylene homopolymers or copolymers and mixtures thereof, and hydroxyethylcellulose and / or hydroxypropylcellulose.

[0287] According to a more preferred embodiment, composition B according to the invention comprises at least one film-forming polymer selected from vinylpyrrolidone (PVP) homopolymers, acrylamide copolymers, acrylic acid ester homopolymers or copolymers, ethylene homopolymers or copolymers and mixtures thereof, and hydroxyethylcellulose and / or hydroxypropylcellulose. Composition for removing color

[0288] As previously stated, the process for removing color from keratin fibers, in particular hair, comprises applying at least one color-removing composition to said hair keratin fibers which have been previously colored using at least one keratin fiber coloring composition A as defined previously and at least one keratin fiber coloring composition B as defined previously, said color-removing composition comprising at least one surfactant.

[0289] Preferably, the color removal composition comprises one or more surfactants selected from anionic surfactants, non-ionic surfactants, cationic surfactants, amphoteric surfactants and mixtures thereof, more preferably selected from anionic surfactants, amphoteric surfactants and mixtures thereof.

[0290] The surfactant(s) may be present in a total quantity ranging from 0.1% to 40%, preferably from 1 to 30%, more preferably from 5 to 25%, more preferably still from 7 to 20% by weight relative to the total weight of the composition for removing color.

[0291] According to a preferred embodiment, the anionic surfactant(s) is / are present in a total quantity ranging from 0.1% to 30%, preferably from 1 to 20%, more preferably from 3 to 17%, more preferably still from 5 to 15% by weight relative to the total weight of the composition for removing color.

[0292] According to a preferred embodiment, the amphoteric surfactant(s) is / are present in a total quantity ranging from 0.01% to 20%, preferably from 0.1% to 15%, more preferably from 0.5% to 10%, more preferably still from 1% to 8% by weight relative to the total weight of the composition for removing color. Anionic surfactant:

[0293] The color removal composition according to the invention may comprise one or several anionic surfactants.

[0294] The term "anionic surfactant" means a surfactant comprising only anionic groups as ionic or ionizable groups.

[0295] In the present description, an entity is qualified as "anionic" when it has at least one permanent negative charge or when it can be ionized into a negatively charged entity, under the conditions of use of the composition of the invention (medium, pH for example) and not comprising a cationic charge.

[0296] A distinction is made between anionic surfactants having at least one negative charge, amphoteric or zwitterionic surfactants having both a negative charge and a positive charge, cationic surfactants having at least one positive charge, and non-ionic surfactants which do not have any charges.

[0297] Anionic surfactants can be sulfate, sulfonate and / or carboxylic (or carboxylate) surfactants. A mixture of these surfactants can obviously be used.

[0298] It is understood in this description that: - Anionic carboxylate surfactants include at least one carboxylic or carboxylate function (-COOH or -COO-), and may optionally include in addition one or more sulfate and / or sulfonate functions; - Anionic sulfonate surfactants comprise at least one sulfonate function (-SO3H or -SO3-), and may optionally also comprise one or more sulfate functions, but do not comprise a carboxylate function; and - Anionic sulfate surfactants include at least one sulfate function but do not include a carboxylate or sulfonate function.

[0299] Carboxylic anionic surfactants that may be used therefore include at least one carboxylic or carboxylate function (-COOH or -COO-).

[0300] They may be selected from the following compounds: acylglycinates, acyl-lactylates, acylsarcosinates, acylglutamates; alkyl-D-galactoside-uronic acids, alkylethercarboxylic acids, alkyl(C6-3O-aryl)ethercarboxylic acids, alkylamidoethercarboxylic acids; as well as the salts of these compounds; the alkyl and / or acyl groups of these compounds having from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably designating a phenyl or benzyl group; these compounds can be polyoxyalkylated, in particular polyoxyethylated and then preferably comprising from 1 to 50 ethylene oxide motifs, better from 2 to 10 ethylene oxide motifs.

[0301] C6-C24 alkyl monoesters and polyglycoside-polycarboxylic acids such as C6-C24 alkyl polyglycoside citrates, can also be used C6-C24 alkyl polyglycoside tartrates and C6-C24 alkyl polyglycoside sulfosuccinates, and their salts.

[0302] Among the carboxylic surfactants above, special mention may be made of polyoxyalkylened alkyl(amido)ether carboxylic acids and their salts, in particular those comprising 2 to 50 alkylene oxide groups, in particular ethylene, such as the compounds offered by the company KAO under the names AKYPO.

[0303] The polyoxyalkylened alkyl(amido)ether carboxylic acids that may be used are preferably chosen from those of formula (1): (1) R s—(O C2H 4)~— OCHjCQOA in which: - Ri represents a linear or branched C6-C24 alkyl or alkenyl radical, an alkyl(C8-C9)phenyl radical, an R2CONH-CH2-CH2- radical with R2 designating a linear or branched C9-C2i alkyl or alkenyl radical; preferably Ri is an alkyl radical in the C8-C20 range, preferably in the C8-Ci8 range, and aryl preferably designates phenyl, - n is an integer or decimal number (average value) ranging from 2 to 24, preferably from 2 to 10, - A denotes H, ammonium, Na, K, Li, Mg or a monoethanolamine or triethanolamine residue.

[0304] Mixtures of compounds of formula (1) can also be used, in particular mixtures of compounds having different Ri groups.

[0305] Particularly preferred polyoxyalkylened alkyl(amido)ether carboxylic acids are those of formula (1) in which: - Ri designates an alkyl radical in the form Ci2-CM, cocoyl, oleyl, nonylphenyl or octylphenyl, - A designates a hydrogen or sodium atom, and - n varies from 2 to 20, preferably 2 to 10.

[0306] Even more preferably, compounds of formula (1) are used in which R designates a C12 alkyl radical, A designates a hydrogen or sodium atom and n varies from 2 to 10.

[0307] Preferably, the carboxylic anionic surfactants are selected from, alone or in mixtures: - acylglutamates, especially in C6-C24, or even in Ci2-C20, such as stearoylglutamates, and in particular disodium stearoylglutamate; - acylsarcosinates, particularly in C6-C24, or even in Ci2-C20, such as palmitoyl-sarcosinates, and in particular sodium palmitoylsarcosinate; - acyllactylates, particularly in C[2-C28, or even C[4-C24], such as behenoyl- lactylates, and in particular sodium behenoyllactylate; - C6-C24 acylglycinates, particularly in Ci2-C2o; - alkyl(C6-C24)ethercarboxylates, and in particular alkyl(C12-C20) ethercarboxylates; - polyoxyalkylened alkyl(C6-C24) (amido) ether carboxylic acids, in particular those containing 2 to 50 ethylene oxide groups; in particular in the form of alkali or alkaline earth metal salts, ammonium, or amino alcohol.

[0308] The anionic sulfonate surfactants that may be used comprise at least one sulfonate function (-SO3H or -SO3-).

[0309] They may be selected from the following compounds: alkylsulfonates, alkylamidesulfonates, alkylarylsulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide sulfosuccinates, alkylsulfoacetates, N-acyltaurates, acylisethionates; alkylsulfosulfolaurates; as well as salts of these compounds; the alkyl groups of these compounds having from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably designating a phenyl or benzyl group; these compounds can be polyoxyalkylated, in particular polyoxyethylated and then preferably comprising from 1 to 50 ethylene oxide motifs, better from 2 to 10 ethylene oxide motifs.

[0310] Preferably, the anionic sulfonate surfactants are selected from, alone or in mixtures: - C6-C24 alkylsulfosuccinates, especially C12-C20 alkylsulfosuccinates, particularly laurylsulfosuccinates. - C6-C24 alkyl ether sulfosuccinates, particularly Ci2-C20; - (C6-C24)acylisethionates, preferably (Ci2-Ci8)acylisethionates, particularly in the form of alkali or alkaline earth metal salts, ammonium, or amino alcohol.

[0311] The anionic sulfate surfactants that may be used have at least one sulfate function (-OSO3H or -OSO3).

[0312] They may be selected from the following compounds: alkyl sulfates, alkyl ether sulfates, alkylamido ether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates; as well as the salts of these compounds; the alkyl groups of these compounds comprising from 6 to 30 carbon atoms, in particular from 12 to 28, even better from 14 to 24, or even from 16 to 22, carbon atoms; the aryl group preferably designating a phenyl or benzyl group; these compounds being able to be polyoxyalkylated, in particular polyoxyethylated and then preferably comprising from 1 to 50 ethylene oxide motifs, better from 2 to 10 ethylene oxide motifs.

[0313] Preferably, anionic sulfate surfactants are selected from, alone or in blend : - alkyl sulfates, particularly in the C6-C24 and even Ci2-C2O ranges, - alkyl ether sulfates, especially in C6-C24, or even in Ci2-C20, preferably comprising 2 to 20 ethylene oxide motifs; in particular in the form of alkali or alkaline earth metal salts, ammonium, or amino alcohol.

[0314] When the anionic surfactant is in salt form, said salt may be selected from alkali metal salts such as sodium or potassium salt, ammonium salts, amine salts and in particular amino alcohols, and alkaline earth metal salts such as magnesium salt.

[0315] Examples of amino alcohol salts include mono-, di- and tri-ethanolamine salts, mono-, di- or tri-isopropanolamine salts, 2-amino 2-methyl 1-propanol salts, 2-amino 2-methyl 1,3-propanediol and tris(hydroxymethyl)aminomethane salts.

[0316] Salts of alkali or alkaline earth metals are preferably used, and in particular salts of sodium or magnesium.

[0317] Preferably, anionic surfactants are chosen from, alone or in mixtures, - C6-C24 alkyl sulfates, particularly C12-C20, - C6-C24 alkyl ether sulfates, especially C12-C20; preferably comprising 2 to 20 ethylene oxide motifs; - C6-C24 alkylsulfosuccinates, especially C12-C20 alkylsulfosuccinates, particularly laurylsulfosuccinates. - C6-C24 alkyl ether sulfosuccinates, particularly Ci2-C20; - (C6-C24)acylisethionates, preferably (Ci2-Ci8)acylisethionates, - C6-C24 acylsarcosinates, particularly C12-C20; especially palmitoylsarcosinates; - alkyl(C6-C24)ethercarboxylates, preferably alkyl(Ci2-C20)ethercarboxylates; - polyoxyalkylened alkyl(C6-C24) (amido) ether carboxylic acids and their salts, in particular those containing 2 to 50 alkylene oxide groups, in particular ethylene; - acylglutamates in C6-C24, particularly in Ci2-C20; - C6-C24 acylglycinates, particularly Ci2-C20; in particular in the form of alkali or alkaline earth metal salts, ammonium, or amino alcohols.

[0318] More preferably, anionic surfactants are chosen from, alone or in mixtures, - C6-C24 alkyl sulfates, particularly C12-C20, and their salts, - C6-C24 alkyl ether sulfates, especially Ci2-C2o; preferably comprising 2 to 20 ethylene oxide motifs and their salts; - polyoxyalkylened alkyl(C6-C24) (amido) ether carboxylic acids and their salts, in particular those comprising 2 to 50 alkylene oxide groups, especially ethylene, even better, anionic surfactants are chosen from, alone or in mixture, C6-C24 alkyl ether sulfates, especially Ci2-C20; preferably comprising 2 to 20 ethylene oxide motifs and their salts.

[0319] Among the C6-C24 alkyl ethersulfates in the form of sodium lauryl ether sulfate and sodium myristyl ether sulfate are found.

[0320] One can cite for example sodium lauryl ether sulfate marketed under the name Texapon® N70 by the company BASF.

[0321] Among the polyoxyalkylened alkyl(C6-C24) (amido) ether carboxylic acids and their salts, we can mention sodium laureth-6 carboxylate marketed under the trade name Akypo Soft 45 HP by the company KAO. Amphoteric surfactant

[0322] The color removal composition according to the invention may comprise one or more amphoteric surfactants.

[0323] Amphoteric surfactants that may be used in the invention may be secondary or tertiary aliphatic amine derivatives, possibly quatemized, in which the aliphatic group is a linear or branched chain comprising 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate, sulfonate, sulfate, phosphate or phosphonate group.

[0324] Examples include betaines and sulfobetaines (or sultaines) and their mixtures, and in particular, alone or in mixtures: - Betaine, - alkyl(C8-C2o)betaines, and in particular cocobetaine; - alkyl(C8-C2O)amidoalkyl(Ci-C6)betaines, and in particular alkyl(C8-C2O)amidopropylbetaines such as cocoamidopropylbetaine, - alkyl(C8-C20)sulfobetaines.

[0325] Among the secondary or tertiary aliphatic amine derivatives possibly quaternized that could be used, the following products with respective structures (Al) and (A2) may also be mentioned: (Al) Ra-CON(Z)CH2-(CH2)m-N+(Rb)(Rc)(CH2COO ) in which: - Ra represents an alkyl or alkenyl group in C10-C30 derived from an acid Ra-COOH preferably present in hydrolyzed coconut oil, a heptyl, nonyl or undecylinder, - Rb represents a beta-hydroxyethyl group, - Rc represents a carboxymethyl group; - m is equal to 0.1 or 2, - Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group; (A2) Ra -CON(Z)CH2-(CH2)m -N(B)(B') in which: - B represents -CH2CH2OX', with X' representing -CH2-COOH, CH2-COOZ', -CH2CH2-COOH, -CH2CH2-COOZ', or a hydrogen atom, - B' represents -(CH2)Z-Y', with z = 1 or 2, and Y' representing -COOH, -COOZ', -CH2 -CHOH-SO3H or -CH2-CHOH-SO3Z', - m' is equal to 0, 1 or 2, - Z represents a hydrogen atom or a hydroxyethyl or carboxymethyl group, - Z' represents an ion from an alkali or alkaline earth metal, such as sodium, potassium or magnesium; an ammonium ion; or an ion from an organic amine and in particular from an amino alcohol, such as mono-, di- and triethanolamine, mono-, di- or tri-isopropanol-amine, 2-amino 2-methyl 1-propanol, 2-amino 2-methyl 1,3-propanediol and tris(hydroxymethyl)aminomethane. - Ra represents an alkyl or alkenyl group in Ci0-C30 of an acid Ra COOH preferably present in coconut oil or in hydrolyzed linseed oil, an alkyl group, especially in Cp and its iso form, an unsaturated Cp group.

[0326] Among the compounds of formula (A2) for which X' represents a hydrogen atom, we can cite the compounds known under the names (CTFA) sodium co-coamphoacetate, sodium lauroamphoacetate, sodium caproamphoacetate and sodium capryloamphoacetate.

[0327] Other compounds of formula (A2) are known under the (CTFA) names disodium co-coamphodiacetate, disodium lauroamphodiacetate, disodium caproamphodiacetate, disodium capryloamphodiacetate, disodium cocoamphodipropionate, disodium lauroamphodipropionate, disodium caproamphodipropionate, disodium capryloamphodipropionate, lauroamphodipropionic acid and cocoamphodipropionic acid.

[0328] Examples of compounds of formula (A2) include cocoamphodiacetate marketed by RHODIA under the trade name MIRANOL® C2M concentrated, sodium cocoamphoacetate marketed under the trade name MIRANOL ULTRA C 32 and the product marketed by CHIMEX under the trade name CHIMEXANE HA.

[0329] Compounds of formula (A3) can also be used: (A3)Ra-NH-CH(Y”)-(CH2)nC(O)-NH-(CH2)n'-N(Rd)(Re) in which: - Ra” represents a C10-C30 alkyl or alkenyl group of an acid Ra”-C(O)OH, preferably present in coconut oil or hydrolyzed linseed oil; - Y” represents the group -C(O)OH, -C(O)OZ”, -CH2-CH(OH)-SO3H or the group -CH2-CH(OH)-SO3-Z” with Z” representing a cation derived from an alkali or alkali-o-earth metal, such as sodium, an ammonium ion or an ion derived from an organic amine; - Rd and Re, independently of each other, represent a Ci-C4 alkyl or hydroxyalkyl radical; and - n and n', independently of each other, denote an integer from 1 to 3.

[0330] Among the compounds of formula (A3), we can notably mention the compound classified in the CTFA dictionary under the name sodium diethylaminopropyl cocoas-partamide, and in particular that marketed by the company CHIMEX under the name CHIMEXANE HB.

[0331] Preferably, amphoteric surfactants are selected from alkyl(C8-C20)betaines, alkyl(C8-C2o)amidoalkyl(Ci-C6)betaines, alkyl(C8-C20)amphoacetates and alkyl(C8-C20)amphodiacetates, and mixtures thereof, more preferably from alkyl(C8-C2o)betaines, alkyl(C8-C2o)amidoalkyl(Ci-C6)betaines, and in particular from cocobetaine and cocoamidopropylbetaine. Non-ionic surfactant

[0332] The color removal composition according to the invention may comprise one or more non-ionic surfactants.

[0333] They may be selected from alcohols, alpha-diols and alkyl(Ci-20)phenols, these compounds being polyethoxylated and / or polypropoxylated and / or polyglycerolated, the number of ethylene oxide and / or propylene oxide groups being from 1 to 100, and the number of glycerol groups being from 2 to 30; or these compounds comprising at least one fatty chain having from 8 to 30 carbon atoms, in particular from 16 to 30 carbon atoms.

[0334] We can also mention ethylene oxide and propylene oxide condensates on fatty alcohols; polyethoxylated fatty amides preferably having 2 to 30 ethylene oxide motifs, polyglycerol fatty amides having on average 1 to 5 glycerol groups and in particular 1.5 to 4; ethoxylated sorbitan fatty acid esters preferably having 2 to 40 ethylene oxide motifs, sucrose fatty acid esters, polyoxyalkylated fatty acid esters, preferably polyoxyethylated having 2 to 150 moles of ethylene oxide including oxyethylated vegetable oils, N-(C6-24 alkyl)glucamine derivatives, amine oxides such as (C10-14 alkyl)amine oxides or N-(C10-14 acyl)-aminopropylmorpholine oxides.

[0335] We can also mention non-ionic surfactants of the alkyl(poly)glycoside type, in particular represented by the following general formula: RiO-(R2O)t-(G)v in which: - Ri represents a linear or branched alkyl or alkenyl radical comprising 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms, or an alkylphenyl radical whose linear or branched alkyl radical comprises 6 to 24 carbon atoms, in particular 8 to 18 carbon atoms; - R2 represents an alkylene radical with 2 to 4 carbon atoms, - G represents a sugar motif containing 5 to 6 carbon atoms, -1 denotes a value ranging from 0 to 10, preferably from 0 to 4, - v denotes a value from 1 to 15, preferably from 1 to 4.

[0336] Preferably, the alkyl(poly)glycoside surfactants are compounds of the formula described above in which: - Ri designates a saturated or unsaturated, linear or branched alkyl radical comprising 8 to 18 carbon atoms, - R2 represents an alkylene radical with 2 to 4 carbon atoms, -1 denotes a value ranging from 0 to 3, preferably equal to 0, - G designates glucose, fructose or galactose, preferably glucose; - the degree of polymerization, i.e. the value of v, which can range from 1 to 15, preferably from 1 to 4; the average degree of polymerization being more particularly between 1 and 2.

[0337] The glycosidic bonds between the sugar motifs are generally of type 1-6 or 1-4, preferably of type 1-4.

[0338] Preferably, non-ionic surfactants are chosen from polyethoxylated C8-C30 fatty alcohols, polyoxyethylenated C8-C30 fatty acid esters, these compounds preferably having 2 to 150 moles of ethylene oxide, and mixtures thereof. Cationic surfactant:

[0339] The color removal composition according to the invention may comprise one or more cationic surfactants.

[0340] They are advantageously chosen from primary, secondary or tertiary fatty amine salts, possibly polyoxyalkylated; quaternary ammonium salts, and mixtures thereof.

[0341] Preferably, the cationic surfactants are chosen from cetyltrimethylammonium salts, behenyltrimethylammonium salts, dipalmitoylethylhydroxyethylmethylammonium salts and mixtures thereof.

[0342] Preferably, the surfactant(s) is / are selected from C6-C24 alkyl sulfates, in particular Ci2-C20 and their salts, C6-C24 alkyl ether sulfates and their salts, in particular Ci2-C20; preferably comprising 2 to 20 ethylene oxide motifs; alkyl(C6-C24) (amido) polyoxyalkylened carboxylic ether acids and their salts, in particularly those containing 2 to 50 alkylene oxide groups, in particular ethylene, alkyl(C8-C2o)betaines, alkyl(C8-C2o)amidoalkyl(Ci-C6)betaines and their mixtures.

[0343] Preferably, the color-removing composition comprises one or more surfactants selected from C6-C24 alkyl sulfates, in particular Ci2-C20 and their salts, C6-C24 alkyl ether sulfates and their salts, in particular Ci2-C20; preferably comprising 2 to 20 ethylene oxide motifs; polyoxyalkylened alkyl(C6-C24) (amido) ether carboxylic acids and their salts, in particular those comprising 2 to 50 alkylene oxide groups, in particular ethylene, alkyl(C8-C20)betaines, alkyl(C8-C20)amidoalkyl(Ci-C6)betaines and mixtures thereof.

[0344] According to a preferred embodiment, the composition for removing the color comprises one or more anionic surfactants and one or more amphoteric surfactants.

[0345] According to a more preferred embodiment, the color-removing composition comprises one or more anionic surfactants selected from C6-C24 alkyl ethersulfates, in particular Ci2-C20; preferably comprising 2 to 20 ethylene oxide motifs, and their salts, and one or more amphoteric surfactants selected from alkyl(C8-C2o)betaines, alkyl(C8-C2o)amidoalkyl(Ci-C6)betaines, and in particular from cocobetaine and cocoamidopropylbetaine. Water-soluble organic solvents

[0346] The color removal composition used in the process according to the invention may further comprise at least one water-soluble organic solvent selected from monoalcohols having 1 to 5 carbon atoms such as ethanol, isopropanol and butanol.

[0347] The composition for removing the color used in the process according to the invention may include water.

[0348] According to another particular embodiment, the composition for removing the color does not include water.

[0349] Furthermore, the additives mentioned above may be included in the composition to remove the color used in the process according to the invention. Process for treating keratin fibers

[0350] The present invention relates to a method for removing color from keratin fibers, such as hair, previously colored, comprising applying at least one color-removing composition to said keratin fibers previously colored using: a) of at least one composition A for coloring keratinous fibers, such as hair, comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, and b) of at least one composition B for coloring keratinous fibers, such as hair, comprising: - at least one film-forming polymer as described above, composition A and / or composition B comprising at least one coloring agent selected from pigments, direct colorants, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulosic polymer, different from film-forming polymers, as described above, and said composition for removing color comprising at least one surfactant as described above.

[0351] Composition A and composition B can be applied simultaneously or sequentially. Preferably, composition A and composition B are applied sequentially.

[0352] Thus, preferably, composition A is first applied to the keratin fibers followed by composition B in a second step.

[0353] According to a preferred embodiment, the process for removing color from previously colored keratin fibers, such as hair, comprises: (i) the application to said keratin fibers of composition A according to the invention comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (I') as described above, their oligomers and / or mixtures thereof, - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, and - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, ii) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application to said keratin fibers of composition B according to the invention comprising: - at least one film-forming polymer as described above, and - at least one non-ionic cellulosic polymer, different from the polymers film-forming, as described previously, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0354] According to another preferred embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the application to said keratin fibers of composition A according to the invention comprising: - at least one alkoxysilane chosen from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, and - at least one non-ionic cellulosic polymer, different from film-forming polymers, as described previously, ii) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0355] According to another preferred embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the application to said keratin fibers of composition A according to the invention comprising: - at least one alkoxysilane chosen from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, and - at least one non-ionic cellulosic polymer, different from film-forming polymers, as described previously, ii) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above, and - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, (viii) optionally a waiting time of 1 minute to several days, including 1 from one to 30 days, more preferably from 1 to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0356] According to another preferred embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the application to said keratin fibers of composition A according to the invention comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, ii) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above, - at least one non-ionic cellulosic polymer, different from the film-forming polymers described above, and - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0357] According to another preferred embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the application to said keratin fibers of composition A according to the invention comprising: - at least one alkoxysilane chosen from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, and - at least one non-ionic, non-associative cellulosic polymer, distinct from film-forming polymers, as described previously, ii) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above, and

[0358] - at least one non-ionic, non-associative cellulosic polymer, different from film-forming polymers, as described previously, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0359] According to another preferred embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the application to said keratin fibers of composition A according to the invention comprising: - at least one alkoxysilane chosen from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, and - at least one non-ionic, non-associative cellulosic polymer, distinct from film-forming polymers, as described previously, ii) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above,

[0360] - at least one non-ionic non-associative cellulosic polymer, different from film-forming polymers, as described previously, and - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0361] The term "rinsing step" refers to the application of water to the keratin fibers.

[0362] Compositions A and B according to the invention can be implemented on fibers dry or wet keratin, as well as on all types of fibers, light or dark, natural or colored, permed, bleached or straightened.

[0363] According to a particular embodiment of the process of the invention, the fibers are washed before application of compositions A and B according to the invention.

[0364] The application of compositions A and B according to the invention on keratin fibers can be carried out by any conventional means, in particular by means of a comb, a brush, a brush or the fingers.

[0365] The coloring process, i.e. the application of compositions A and B according to the invention on the keratin fibers, is generally carried out at room temperature (between 15 and 25°C).

[0366] After application of composition A or composition B to the keratin fibers, it is preferable to have a setting time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes of composition A or composition B on said fibers.

[0367] According to a particular embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the preparation of composition A according to the invention by mixing a first composition A' and a second composition A” wherein the first composition A' comprises: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof and The second composition A' ' comprises: - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, ii) the application of composition A according to the invention to said keratin fibers, ii) optionally a leave-on time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes, of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above, and - at least one non-ionic cellulosic polymer, different from film-forming polymers, as described previously, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0368] In order to allow better preservation of composition A', it preferably comprises a low water content or is anhydrous.

[0369] Preferably, composition A' comprises a water content of between 0.001 and 10% by weight, better between 0.5 and 10% by weight, more preferably between 1 and 8% by weight relative to the weight of composition A'.

[0370] Composition A' ' may also contain water.

[0371] According to another particular embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the preparation of composition A according to the invention by mixing a first composition A' and a second composition A” wherein the first composition A' comprises: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof and The second composition A' ' comprises: - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, and - at least one non-ionic cellulosic polymer, different from film-forming polymers, as described previously, ii) the application of composition A according to the invention to said keratin fibers, ii) optionally a leave-on time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0372] According to a particular embodiment, the process for removing color from keratin fibers such as previously colored hair comprises: (i) the preparation of composition A according to the invention by mixing a first composition A', a second composition A” and a third composition A'” wherein the first composition A' comprises: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, and The second composition A' ' comprises: - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, and The third composition A'” includes: - at least one non-ionic cellulosic polymer, different from film-forming polymers, as described previously, ii) the application of composition A according to the invention to said keratin fibers, ii) optionally a leave-on time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition A on said fibers, iii) optionally a washing, rinsing, spinning or drying step for said fibres, (iv) the application of composition B according to the invention comprising: - at least one film-forming polymer as described above, (v) optionally an exposure time of 10 seconds to 20 minutes, in particular from 20 seconds to 10 minutes, preferably from 30 seconds to 5 minutes of composition B according to the invention on said fibers, vi) optionally a washing, rinsing, spinning and vii) optionally a drying and / or heating step of the keratin fibers, for example at a temperature greater than or equal to 30°C, viii) optionally a waiting period of 1 minute to several days, in particular 1 hour to 30 days, more preferably from 1 day to 15 days before application of the composition to remove the color from said colored fibers, ix) the application to said colored fibers of the color-removing composition comprising at least one surfactant as described above, x) optionally a processing time of 10 seconds to 20 minutes, in particular 20 seconds to 10 minutes, preferably 30 seconds to 5 minutes, of the composition to remove the color from said colored fibers, xi) optionally a washing, rinsing, and spinning step.

[0373] After application of compositions A and B according to the invention and before any possible step of applying heat to the keratin fibers, the keratin fibers can be subjected to a drying step, using for example a hair dryer.

[0374] The drying step can be carried out for a period of between 20 seconds and 5 minutes.

[0375] The drying step can be carried out using absorbent paper, a hair dryer, a hair dryer helmet or in the open air.

[0376] Preferably, the drying step is carried out using a hairdryer at a temperature of 30°C or higher, more particularly at a temperature above 30°C and below 110°C

[0377] After applying compositions A and B according to the invention to the keratin fibers, one can wait at least 10 seconds, preferably at least 30 seconds before the drying step of the keratin fibers.

[0378] After application of compositions A and B according to the invention and optionally a drying step of the keratin fibers, the process according to the invention may include a step of applying heat to the keratin fibers using a heating tool.

[0379] Preferably, the process according to the invention does not include a step of applying heat to the keratin fibers using a heating tool in addition to the possible drying step.

[0380] The heat application step of the process of the invention can be carried out using a helmet, a hair dryer, a straightener or curling iron, a clozazon,...

[0381] Preferably, the heat application step of the process of the invention is carried out using a hair dryer and / or a straightener, more preferably using a hair dryer.

[0382] During the heat application step on the keratin fibers, a mechanical action on the strands can be exerted such as combing, brushing, passing with fingers.

[0383] When the heat application step on the keratin fibers is carried out using a helmet or a hair dryer, the temperature is preferably between 30 and 110°C, preferably between 50 and 90°C.

[0384] When the heat application step on the keratin fibers is carried out using a hair straightener, the temperature is preferably between 110 and 240°C, preferably between 110 and 200°C.

[0385] Then, as indicated above, the process for removing the color from keratin fibers according to the invention comprises the application of at least one color removal composition as defined above, on keratin fibers which have been previously colored using at least one hair keratin fiber coloring composition A as defined above and at least one hair keratin fiber coloring composition B as defined above.

[0386] The composition for removing the color can be applied using any suitable medium such as a brush, comb or glove.

[0387] Before applying the composition to remove the color, the colored keratin fibers can be subjected to a temperature of 25 to 70°C, preferably 25 to 60°C, more preferably 30 to 55°C.

[0388] Preferably, the colour removal composition is then rinsed after a possible waiting period, possibly followed by shampooing.

[0389] Preferably, the colour removal composition is left on for 30 seconds to 60 minutes, preferably 1 to 30 minutes, more preferably 1 to 15 minutes, better still 2 to 10 minutes, before being rinsed.

[0390] According to a particular embodiment, the process according to the invention further includes a step of kneading the keratin fibers, after the application of the composition to remove the color.

[0391] During this kneading step, a special tool such as an exfoliating glove may be used.

[0392] Preferably, during a kneading step, 6 finger strokes are performed along the strand. The duration of all 6 strokes can vary from 30 seconds to 2 minutes, for example, for 1g of strand.

[0393] The step of kneading the capillary keratin fibers can be repeated several times, for example 2 times, possibly with an intermediate rest time.

[0394] The step of applying the composition to remove the color can be repeated several times, possibly with an intermediate rinse.

[0395] The time between the step of applying the keratin fiber coloring compositions and the step of applying the composition to remove the color can vary from a few minutes to several days, for example several tens of days.

[0396] Preferably, the time between the step of applying the keratin fiber coloring compositions and the step of applying the composition to remove the color varies from 1 hour to 30 days, more preferably from 1 day to 15 days.

[0397] The optional kneading step can then be followed by a washing step of the keratin fibers, for example using shampoo. The hair keratin fibers can then be kneaded, rinsed, and dried. Multi-compartment device (kit)

[0398] The present invention also relates to a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers, comprising several compartments containing: - in a first compartment, a composition A for coloring keratin fibers, such as hair, comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, - in a second compartment, composition B comprising: - at least one film-forming polymer as described above, composition A and / or composition B comprising at least one coloring agent selected from pigments, direct colorants, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulosic polymer as described above, distinct from film-forming polymers, and - in a third compartment, a colour removal composition comprising at least one surfactant as described above.

[0399] According to a preferred embodiment of the invention, the coloring device according to the invention is a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers comprising several compartments containing: - in a first compartment, a composition A comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, - in a second compartment, a composition B according to the invention comprising: - at least one film-forming polymer as described above, and - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, composition A and / or composition B comprising at least one non-ionic cellulosic polymer as described above, different from film-forming polymers.

[0400] According to a preferred embodiment of the invention, the coloring device according to the invention is a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers, comprising several compartments containing: - in a first compartment, a composition A comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (I') as described above, their oligomers and / or mixtures thereof, - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof, and - at least one coloring agent chosen from pigments, direct dyes, and their mixtures; - in a second compartment, a composition B according to the invention comprising: - at least one hydrophobic film-forming polymer as described above, and composition A and / or composition B comprising at least one non-ionic cellulosic polymer as described above, different from the film-forming polymers.

[0401] The present invention also relates to a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers, comprising several compartments containing: - in a first compartment, a composition A' comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (I') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof; - in a second compartment, a composition A” comprising: - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, - in a third compartment, a composition B comprising: - at least one film-forming polymer as described above, composition A' and / or composition A” and / or composition B comprising at least one non-ionic cellulosic polymer as described above, distinct from film-forming polymers, and - in a fourth compartment, a color removal composition comprising at least one surfactant, as described previously.

[0402] According to a preferred embodiment of the invention, the coloring device according to the invention is a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers, comprising several compartments containing: - in a first compartment, a composition A' comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof; - in a second compartment, a composition A” comprising: - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, - in a third compartment, a composition B according to the invention comprising: - at least one film-forming polymer as described above, and - at least one non-ionic cellulosic polymer, different from the film-forming polymers described above, and - in a fourth compartment, a color removal composition comprising at least one surfactant.

[0403] According to another preferred embodiment of the invention, the coloring device according to the invention is a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers, comprising several compartments containing: - in a first compartment, a composition A' comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (I') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof; - in a second compartment, a composition A” comprising: - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, - at least one non-ionic cellulosic polymer, different from the film-forming polymers described above, and - in a third compartment, a composition B according to the invention comprising: - at least one film-forming polymer as described above, and - in a fourth compartment, a color removal composition comprising at least one surfactant.

[0404] According to a particular embodiment of the invention, the coloring device according to the invention is a device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers, comprising several compartments containing: - in a first compartment, a composition A' comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (!') as described above, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described above, its oligomers and / or mixtures thereof; - in a second compartment, a composition A” comprising: - at least one coloring agent chosen from pigments, direct dyes, and their mixtures, - in a third compartment, a composition A'” comprising: - at least one non-ionic cellulosic polymer, different from film-forming polymers, as described previously and - in a fourth compartment, a composition B according to the invention comprising: - at least one film-forming polymer as described above, and - in a fifth compartment, a colour removal composition comprising at least one surfactant.

[0405] Use of the composition to remove color

[0406] The present invention also relates to the use of the color-removing composition according to the invention, or as used in the process according to the invention, for removing color from keratin fibers, such as hair, that have been previously colored using: a) of at least one composition A for coloring keratinous fibers, such as hair, comprising: - at least one alkoxysilane selected from the compounds of formula (I) or formula (I') as described below, their oligomers and / or mixtures thereof, and - at least one alkoxysilane of formula (II) as described below, its oligomers and / or mixtures thereof, and b) of at least one B composition for staining keratin fibers, such as hair, including: - at least one film-forming polymer, composition A and / or composition B comprising at least one coloring agent selected from pigments, direct colorants, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulosic polymer, different from film-forming polymers.

[0407] The present invention will now be described more specifically by means of examples, which are in no way limiting of the scope of the invention. However, the examples allow for the support of specific features, variants, and preferred embodiments of the invention. Examples

[0408] In the examples, the temperature is given in degrees Celsius, and corresponds to the ambient temperature (20-25°C), unless otherwise stated, and the pressure is atmospheric pressure, unless otherwise stated.

[0409] The following compositions are prepared (in g / lOOg of raw material as is, MA: Active ingredient):

[0410] [Tables 1] Composition Al' 3-aminopropyltriethoxysilane (APTES)(1) 24 Methyltriethoxysilane (MTES) 72 Ethanol Qsp 100

[0411] [Tables2] Composition Al” Pigment® 10 Ethanol Qsp 100

[0412] [Tables3] Composition A2 3-aminopropyltriethoxysilane (APTES) ® 2 Methyltriethoxysilane (MTES) 7 Lactic acid Qs pH= 9.5 Water 45.5 Ethanol Qsp 100

[0413] [Tables4] Compositions B1 B2 Ethylene / sodium acrylate copolymer (3) 3.8 MA - Hydroxyethylcellulose 2 0.5 Pigment® - 5 Polyvinylpyrrolidone (4) 4.5 Acrylates / octyla-crylamide copolymer (5) - 4.4 MA Ammonia - Qs pH= 10 Water Qsp 100 Qsp 100

[0414] [Tables5] Composition for removing color C: Sodium laureth sulfate (6) 14 MA, Coco-betaine (7) 4.5 MA, Ethanol Qsp 100 1. Sold under the trade name KBE-903 by the company Shin Etsu 2. SYNTHETIC FLUORPHLOGOPITE (and) TITANIUM DIOXIDE (and) TIN OXIDE sold under the trade name SYNCRYSTAL SILK SILVER by the company ECKART 3. Sold under the trade name ECOSMOOTH SATIN by Dow Corning, 4. Sold under the trade name PVP K30L by the company ISP (Ashland). 5. Sold under the trade name DERMACRYL 79 by the company AKZO NOBEL. 6. Sold under the trade name TEXAPON N 70 by BASF (with 70% active ingredient in water), 7. Sold under the trade name DEHYTON AB30 by the company BASF (with 30% active ingredient in water), Protocol:

[0415] The compositions Al' and Al” according to the invention are mixed in a 50 / 50 ratio to obtain composition AL

[0416] The composition Al according to the invention is applied with a finger to strands of dry brown hair (HT4), at a rate of 1 g of composition per gram of strand.

[0417] The hair strands are left at room temperature for 2 minutes.

[0418] Composition B1 according to the invention is then applied to the hair strands treated with composition Al, at a rate of 1 g of composition per gram of strand.

[0419] The hair strands are left at room temperature for 5 minutes.

[0420] Composition A2 according to the invention is applied with a finger to strands of dry brown hair (HT4), at a rate of 1 g of composition per gram of strand.

[0421] The hair strands are left at room temperature for 5 minutes.

[0422] Composition B2 according to the invention is then applied to the hair strands treated with composition A2, at a rate of 1 g of composition per gram of strand

[0423] The hair strands are left at room temperature for 2 minutes.

[0424] The hair strands are then dried with a hairdryer for 2 minutes.

[0425] The hair strands are left at room temperature for 24 hours.

[0426] Some colored hair strands will be subjected to the removal protocol of the color of previously colored hair strands described below and others only to a shampooing protocol described below.

[0427] Protocol for removing color from previously colored hair strands:

[0428] The composition for removing color C is applied to the strands of hair colored by compositions Al + B1 and A2+ B2 respectively, using a brush, at a rate of 3g of composition per g of strand.

[0429] After a 2-minute processing time, the hair strands are rinsed (15 passes under water).

[0430] The strands are then washed using a standard shampoo (Garnier Ultra Doux).

[0431] The strands of hair are kneaded (6 passes of the fingers along the strand) then the strands of hair are rinsed and dried using a hair dryer. Shampooing protocol:

[0432] The hair strands are washed using a standard shampoo (Garnier Ultra Doux).

[0433] The hair strands are then rinsed, combed, and blow-dried. Results:

[0434] The persistence of the color of the highlights was evaluated in the CIE L*a*b* system, using a Minolta Spectrophotometer CM3600A colorimeter (illuminant D65, angle 10°, specular component included).

[0435] In this L*a*b* system, L* represents the intensity of the color, a* indicates the green / red color axis and b* the blue / yellow color axis.

[0436] The permanence of the color is assessed by the color difference AE between the colored strands before shampooing or before the color removal step, and then after one shampooing according to the protocol described above or after undergoing the color removal protocol for the previously colored hair strands described above. The lower the AE value, the more resistant the color is to shampoos or the color removal formula.

[0437] The value of AE is calculated according to the following equation:

[0438] [Math.l] «£ = - C + ss''- s*')a t(tr- bs

[0439] In this equation, L*a*b* represent the values ​​measured after hair coloring and after shampooing or after the color removal step, and L0*a0*b0* represent the values ​​measured after hair coloring but before shampooing or before the color removal step.

[0440] [Tableauxô] Coloring compositions Protocols L* a* b* AE Compositions Al + B1 Colored control strands 38.1 1.2 -1.2 - After 1 shampoo 37.2 1.5 -1.0 1.0 After application Composition C 21.6 3.0 3.3 17.2 Compositions A2 + B2 Colored control strands 47.2 0.9 -1.9 - After 1 shampoo 28.0 2.2 1.1 19.5 After application Composition C 21.2 3.1 3.6 26.7

[0441] It is observed that the composition for removing color C according to the invention has excellent color removal power on fibers.

[0442] Thus, the process for removing color from keratin fibers according to the invention enables the effective removal of color from a strand of hair that has been previously colored using a keratin fiber coloring composition A and a keratin fiber coloring composition B comprising two alkoxysilane compounds, a film-forming polymer, a non-ionic cellulosic polymer and a coloring agent selected from pigments, direct dyes and their mixtures.

Claims

1. Claims A method for removing color from previously colored keratin fibers, such as hair, comprising the application of at least one composition for removing color from said previously colored keratin fibers using: a) at least one composition A for coloring keratin fibers, such as hair, comprising: - at least one alkoxysilane chosen from the compounds of formula (I) or of formula (!) following, their oligomers and / or their mixtures: in which: - Ra represents an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 10 carbon atoms, more preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methyl, said alkyl group being optionally substituted by an aryl group; an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as an ethoxy; or an aryl group having from 6 to 12 carbon atoms; Rb and Rc,; identical or different, represent a hydrogen atom; an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 6 carbon atoms and in particular from 1 to 4 carbon atoms, in particular an ethyl group, it being understood that if Ra does not represent an alkoxy group, then Rb and Rc cannot simultaneously represent a hydrogen atom; Rd and Re, identical or different, represent a hydrogen atom; an alkyl group having from 1 to 20 carbon atoms, preferably from 1 with 6 carbon atoms and in particular from 1 to 4 carbon atoms; a cycloalkyl group having from 3 to 20 carbon atoms; an aryl group having from 6 to 12 carbon atoms; an aminoalkyl group having from 1 to 20 carbon atoms; - A independently represents an alkylene group having from 1 to 10 linear or branched carbon atoms, which may be interrupted by at least one heteroatom chosen from O, S, NH or a carbonyl group (CO), preferably NH - Q represents a carbonyl group (CO); - r denotes an integer ranging from 0 to 1., and - at least one alkoxysilane of the following formula (II), its oligomers and / or their mixtures: in which: - Ra represents an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 10 carbon atoms, more preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methyl, said alkyl group being optionally substituted by an aryl group; an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as an ethoxy; or an aryl group having from 6 to 12 carbon atoms; - Rb represents a hydrogen atom or an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 6 carbon atoms and in particular from 1 to 4 carbon atoms, in particular an ethyl group; - Rc represents an alkyl group having from 1 to 20 carbon atoms, preferably from 1 to 10 carbon atoms, more preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as a methyl, said alkyl group being optionally substituted by an aryl group; an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as an ethoxy; or an aryl group having from 6 to 12 carbon atoms; it being understood that if Ra and Rc do not represent an alkoxy group, then Rb cannot represent a hydrogen atom - k denotes an integer ranging from 0 to 5, preferably ranging from 0 to 3; - Rf represents a hydrogen atom; an alkyl group having from 1 to 10 carbon atoms and in particular from 1 to 4 carbon atoms; or a group of formula (IIa) below: G in which Rn represents a hydroxy group (OH);an alkyl group having from 1 to 10 carbon atoms, preferably a methyl, and b) at least one composition B for coloring keratin fibers, such as hair, comprising: - at least one film-forming polymer, composition A and / or composition B comprising at least one coloring agent chosen from pigments, direct dyes, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulose polymer, different from the film-forming polymers, and said composition for removing color comprising at least one surfactant, at least one of which is an amphoteric surfactant.;

2. Process according to claim 1, in which the alkoxysilane(s), their oligomers and / or their mixtures are chosen from the compounds of formula (I) in which Ra represents an ethoxy group, Rb and Rc are identical and represent an ethyl, Rd and Re represent a hydrogen atom, A represents a propyl and r denotes an integer equal to 0

3. Process according to any one of the preceding claims, in which the alkoxysilane(s) of formula (I) or of formula (I'), their oligomers and / or their mixtures is (are) present in a total amount ranging from 0.1 to 40% by weight, preferably from 0.5 to 30% by weight, preferentially from 0.75 to 25% by weight, better still from 1 to 20% by weight, even better still from 1.5 to 15% by weight, relative to the total weight of composition A.

4. A method according to any one of the preceding claims, wherein the alkoxysilane(s) of formula (II), their oligomers and / or their mixtures are such that: - Ra represents an alkyl group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms, in particular from 1 to 2 carbon atoms such as methyl or ethyl; - Rb represents an alkyl group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms, in particular from 1 to 2 carbon atoms such as methyl or ethyl; - Rc represents an alkoxy group having from 1 to 10 carbon atoms, preferably from 1 to 4 carbon atoms and in particular from 1 to 2 carbon atoms such as methoxy or ethoxy - k denotes an integer equal to 0; - Rf represents an alkyl group having from 1 to 10 carbon atoms and in particular from 1 to 4 carbon atoms such as a methyl or an ethyl, preferably methyltrimethoxysilane (MTMS) or methyltriethoxysilane (MTES).

5. Process according to any one of the preceding claims, in which the alkoxysilane(s) of formula (II), its oligomers and / or their mixtures is (are) present in a total amount ranging from 0.5 to 90% by weight, preferably from 1 to 75% by weight, preferentially from 3 to 45% by weight, better still from 5 to 40% by weight, relative to the total weight of composition A.

6. A method according to any one of the preceding claims, wherein the film-forming polymer(s) are chosen from vinylpyrrolidone (PVP) homopolymers, acrylamide copolymers, acrylic acid ester homopolymers or copolymers, ethylene homopolymers or copolymers and mixtures thereof.

7. Process according to any one of the preceding claims, in which the film-forming polymer(s) is (are) present in a total amount ranging from 0.1 to 30% by weight, preferably from 0.5 to 25% by weight, even better from 1 to 20% by weight, relative to the total weight of composition B.

8. A method according to any preceding claim, wherein the non-ionic cellulosic polymer(s) are non-associative.

9. A method according to claim 8, wherein the non-associative non-ionic cellulose polymer(s) is (are) chosen from hydroxyalkyl(Ci-C4)celluloses, preferably hydroxyethylcellulose and / or hydroxypropylcellulose.

10. Process according to any one of the preceding claims, in which the non-ionic cellulose polymer(s) is (are) present in a total amount ranging from 0.01 to 10% by weight, preferably from 0.05% to 5% by weight, better still from 0.1 to 3% by weight relative to the total weight of composition A and / or composition B.

11. A method according to any one of the preceding claims, wherein the color removing composition comprises one or more surfactants chosen from anionic surfactants, non-ionic surfactants, cationic surfactants and mixtures thereof, more preferably chosen from anionic surfactants and mixtures thereof.

12. Process according to any one of the preceding claims, in which the surfactant(s) is (are) chosen from C6-C24 alkyl sulfates, in particular C12-C20 and their salts, C6-C24 alkyl ether sulfates and their salts, in particular C12-C20; preferably comprising from 2 to 20 ethylene oxide units; polyoxyalkylenated alkyl(C6-C24) (amido) ether carboxylic acids and their salts, in particular those comprising from 2 to 50 alkylene oxide groups, in particular ethylene oxide, alkyl(C8-C20)betaines, alkyl(C8-C20)amidoalkyl(C1-C6)betaines and mixtures thereof.

13. A method according to any one of the preceding claims, wherein the surfactant(s) is (are) present in a total amount ranging from 0.1% to 40%, preferably from 1 to 30%, more preferably from 5 to 25%, even more preferably from 7 to 20% by weight relative to the total weight of the composition for removing the color.

14. Device for coloring keratin fibers such as hair, and for removing the color from said previously colored keratin fibers comprising several compartments containing: - in a first compartment, a composition A for coloring keratin fibers, such as hair, comprising: - at least one alkoxysilane chosen from the compounds of formula (I) or of formula (!') as described according to any one of claims 1 to 3, their oligomers and / or their mixtures, and - at least one alkoxysilane of formula (II) as described according to any one of claims 1, 4 or 5, its oligomers and / or their mixtures, - in a second compartment, a composition B comprising: - at least one film-forming polymer as described according to any one of claims 6 or 7, composition A and / or composition B comprising at least one coloring agent chosen from pigments, direct dyes, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulose polymer, different from the film-forming polymers, as described according to any one of claims 8 to 10, and - in a third compartment, a composition for removing color comprising at least one surfactant as described according to any one of claims 1, and 11 to 13.

15. Use of the composition for removing color as used in the process according to any one of claims 1 to 13, for removing color from keratin fibers, such as hair, having been previously colored using: a) at least one composition A for coloring keratin fibers, such as hair, comprising: - at least one alkoxysilane chosen from the compounds of formula (I) or of formula (!') as described according to any one of claims 1 to 3, their oligomers and / or their mixtures, and - at least one alkoxysilane of formula (II) as described according to any one of claims 1, 4 or 5, its oligomers and / or their mixtures, and b) at least one composition B for coloring keratin fibers, such as hair, comprising: - at least one film-forming polymer as described according to any one of claims 6 or 7, composition A and / or composition B comprising at least one coloring agent chosen from pigments, direct dyes, and mixtures thereof, and composition A and / or composition B comprising at least one non-ionic cellulose polymer, different from the film-forming polymers, as described according to any one of claims 8 to 10.