Composition of dyes and / or lightening agents for keratin fibers, and their processes

Abstract

KERATIN FIBER DYEING AND / OR BRIGHTENING COMPOSITION AND METHODS This disclosure proposes a composition comprising sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer agent, and an oxidative dye and / or at least one alkaline agent. The composition is stable at various temperatures and provides long-lasting color and improved cosmetic appeal. This disclosure also proposes a keratin fiber dyeing kit comprising said composition and a keratin fiber dyeing method. Figure for abstract: none

Description

Title of the invention: Composition for dyeing and / or lightening keratin fibers, and their methods FIELD OF INVENTION

[0001] This disclosure relates, in general, to personal care products, and more specifically, to compositions for dyeing and / or bleaching keratin fibers. This disclosure further relates to a process for dyeing and / or bleaching keratin fibers. CONTEXT OF THE INVENTION

[0002] Dyeing keratin fibers, particularly human hair, is a well-known practice and commonly involves the use of coloring compositions, which include oxidation dye precursors, generally called oxidation bases and couplers. These dye precursors are colorless or weakly colored compounds. When combined with an oxidizing agent, they give rise, through a process of oxidative condensation, to colored compounds.

[0003] Typically, the oxidation dyeing process involves the application, on keratin fibers, of oxidation bases, or a mixture of oxidation bases and couplers, with an oxidizing agent, which is added at the time of use.

[0004] Generally, this process is carried out at an alkaline pH and produces dyeing and, at the same time, lightening of the fiber by decolorizing the melanin pigment in the hair. In this way, the dyes develop in the hair cortex and a uniform color development is obtained.

[0005] The formulation of environmentally friendly cosmetic products, which are designed and developed taking environmental issues into account, is becoming a major objective in the context of efforts to address global challenges.

[0006] It is therefore essential to offer more sustainable compositions, preparation processes, and ingredients to address these environmental concerns. In this context, it is important to develop new cosmetic compositions with a better carbon footprint, in particular by promoting the use of renewable raw materials and / or materials with a high naturalness index and / or materials of natural origin, and more specifically, materials of plant origin, while reducing the use of petrochemical compounds.

[0007] However, the addition of materials of natural or plant origin to hair dye compositions tends to reduce the shelf life of such compositions, because they are often unstable when stored for long periods, especially when stored at higher temperatures.

[0008] Thus, there is a need for more durable hair dye compositions that achieve superior performance benefits such as long-lasting color, improved revitalization, protection against hair damage, while having a long shelf life. Summary of the invention

[0009] In one aspect of this disclosure, a composition is proposed comprising sunflower oil; at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer, and at least one oxidative dye and / or at least one alkali agent.

[0010] In another aspect of this disclosure, a kit is proposed comprising a composition (A) including sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer, and at least one oxidative dye and / or at least one alkali agent; and a composition (B) including at least one oxidizing agent, and optionally at least one nonionic polyoxyalkylated fatty alcohol ether, the mixture of composition (A) and composition (B) resulting in a ready-to-use composition.

[0011] In another aspect of this disclosure, a process for dyeing keratin fibers, preferably hair, is proposed, comprising mixing a composition (A) comprising sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer, and at least one oxidative dye and / or at least one alkali agent; and a composition (B) comprising at least one oxidizing agent, and optionally at least one nonionic polyoxyalkylated fatty alcohol ether, to obtain a mixture and applying the mixture to said fibers.

[0012] In another aspect of this disclosure, it is proposed to use a composition comprising sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer and at least one oxidative dye, and / or at least one alkali agent; or a kit comprising a composition (A) which includes sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer, at least one oxidative dye and / or at least one alkali agent, and a composition (B) comprising at least one oxidizing agent, and optionally at least one nonionic polyoxyalkylated fatty alcohol ether, the mixture of composition (A) and composition (B) resulting in a ready-to-use composition for dyeing and / or lightening keratin fibers, such as hair.

[0013] These features, aspects, and advantages, as well as others, of the present subject matter will be better understood with reference to the following description and the attached claims. This summary is provided to present a selection of concepts in a simplified form. This summary is not intended to identify key features or essential features of the claimed subject matter, nor to be used to limit the scope of the claimed subject matter. DESCRIPTION OF THE INVENTION

[0014] The person skilled in the art will be aware that this disclosure is subject to variations and modifications other than those specifically described. It should be understood that this disclosure includes all such variations and modifications. The disclosure also includes all such steps, features, compositions, and compounds designated or indicated in this specification, individually or collectively, and any combination of one or more of these steps or features.

[0015] Definitions

[0016] For convenience, before describing this disclosure in more detail, certain terms used in the descriptive document and examples are defined here. These definitions should be read in light of the rest of the disclosure and understood as by a person skilled in the art. The terms used here have meanings recognized and known to persons skilled in the art; however, for convenience and completeness, specific terms and their meanings are set out below.

[0017] The articles "un", "une", "la", "le" and "les" are used to designate one or more of one (i.e. at least one) grammatical object of the article.

[0018] The terms "understand" and "comprising" are used in an inclusive and open sense, meaning that additional elements may be included. It is not intended to be interpreted as "consists solely of".

[0019] The expression "at least one" is used to mean one or more and therefore includes individual components as well as mixtures / combinations.

[0020] Throughout this descriptive document, unless the context otherwise requires, the term "include", and variations such as "includes" and "including", shall be understood as implying the inclusion of any element or step or group of elements or steps stated, but not the exclusion of any other element or step or group of elements or steps.

[0021] The term "including" is used to mean "including, but not limited to". "Including" and "including, but not limited to" are used interchangeably.

[0022] The term “INCI” is an abbreviation for International Nomenclature of Cosmetic Ingredients, which is a system of names provided by the International Nomenclature Committee of the Personal Care Products Council to describe the ingredients of personal care products.

[0023] All percentages, parts, and ratios are based on the total weight of the compositions in this disclosure, unless otherwise stated. Ratios, concentrations, quantities, and other numerical data may be presented herein in a range format. It should be understood that such a range format is used solely for convenience and conciseness and should be interpreted flexibly as including not only the numerical values ​​explicitly cited as the range limits, but also as including all individual numerical values ​​or subranges encompassed within that range as if each numerical value and subrange were explicitly cited.For example, a percentage range of about 0.1% to 20% should be interpreted as including not only the explicitly quoted limits of about 0.1% to about 20%, but also as including sub-ranges, such as 0.5% to 15%, 1% to 12%, and so on, as well as individual quantities, including fractional quantities, within the specified ranges, such as 2.8%, 3%, 6%, and 17.25%, for example.

[0024] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as that commonly understood by a person skilled in the art to which this disclosure relates. Although all processes and materials similar or equivalent to those described herein may be used in the practice or testing of the disclosure, preferred processes and materials are now described.

[0025] This disclosure shall not be limited in scope by the specific embodiments described herein, which are intended for illustrative purposes only. Functionally equivalent products, compositions, and processes are clearly within the scope of this disclosure, as described herein.

[0026] The embodiments presented herein provide a composition that offers superior performance benefits such as intense color, chromatic color, uniform color, long-lasting color, improved cosmetic appeal, and hair revitalization. In particular, the composition, according to the embodiments presented herein, includes sunflower oil, which nourishes, protects, and repairs hair damage. The composition has good usability qualities, such as ease of application along the hair shaft and ease of rinsing. The composition overcomes the drawbacks associated with natural oils, such as rancidity, and is stable after storage even at high temperatures, such as 45°C, for extended periods. It also provides improved smoothness and detangling effects to the hair. It also imparts shine to the hair.The embodiments presented here provide a kit comprising a ready-to-use composition. The ready-to-use composition results from a mixture comprising a composition (A), as described herein, comprising sunflower oil, at least one. polyol, at least one cationic polysaccharide, at least one nonionic associative polymer, and at least one oxidative dye and / or at least one alkali metal, and a composition (B) comprising at least one oxidizing agent, and optionally at least one nonionic polyoxyalkylated fatty alcohol ether. Compositions (A) and (B) are intended to be mixed together and then applied to keratin fibers to dye and / or lighten the keratin fibers.Accordingly, the embodiments herein further include a method for dyeing keratin fibers, preferably hair, in which a composition (A) comprising sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer, and at least one oxidative dye and / or at least one alkali metal, and a composition (B) comprising at least one oxidizing agent, and optionally at least one nonionic polyoxyalkylated fatty alcohol ether, as proposed in the embodiments herein, are mixed and applied to said fibers. Furthermore, the embodiments herein also include the use of the composition or kit according to the present invention for dyeing and / or lightening keratin fibers, such as hair. Composition

[0027] The embodiments presented herein propose a composition, according to the present invention, comprising sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one nonionic associative polymer, and at least one oxidative dye and / or at least one alkaline agent. The composition, according to the present invention, is used to dye and / or lighten keratin fibers, such as hair.

[0028] The composition, according to the embodiments presented herein, demonstrates the advantages associated with the use of sunflower oil, such as improved smooth texture and nourishment. The product according to the invention, in particular, effectively revitalizes keratin fibers, notably by providing them with improved cosmetic properties, especially by giving them a softer and more even feel, as well as increased suppleness and shine.

[0029] Furthermore, the incorporation of sunflower oil into the composition, according to the embodiments herein, replaces the need for synthetic ingredients, such as mineral oil.

[0030] Moreover, the composition, according to the embodiments presented herein, overcomes the drawbacks associated with the use of other natural oils, such as rancidity, and demonstrates increased stability and a longer shelf life. The composition is stable with respect to storage over time, across a wide temperature range, including ambient temperatures (25 °C), higher temperatures, particularly 45 °C, and also at lower temperatures, particularly 4 °C.

[0031] Overall, the combination of sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one non-ionic associative polymer and at least one oxidative dye and / or at least one alkaline agent in the composition, according to the embodiments herein, works synergistically to contribute to the superior dyeing and / or lightening performance of keratin fibers, such as hair. Sunflower oil

[0032] Embodiments of the present invention include sunflower oil. The sunflower oil of the present invention is obtained from sunflower seeds, i.e., Helianthus annuus. In particular, the sunflower oil of the present invention is obtained from Helianthus annuus of European origin. More specifically, the sunflower oil used in the present invention is sold under the name of refined sunflower oil by ADM Speciality Oils and Fats (Société Industrielle des Oléagineux).

[0033] Sunflower oil is a liquid fatty acid triglyceride and according to the embodiments herein, sunflower oil is a fatty acid triglyceride comprising palmitic acid in an amount from 5% to 8% by weight, stearic acid in an amount from 3% to 6% by weight, oleic acid in an amount from 15% to 40% by weight and / or linoleic acid in an amount from 48% to 75% by weight, relative to the total fatty acid content of said oil.

[0034] In some embodiments, sunflower oil further comprises myristic acid in an amount of less than 0.2% by weight, palmitoleic acid in an amount of less than 0.3% by weight, palmitic acid in an amount of 5% to 7.6% by weight, linolenic acid in an amount of less than 0.3% by weight, arachidic acid in an amount of 0.1% to 0.6% by weight, gadoleic acid in an amount of less than 0.3% by weight, behenic acid in an amount of 0.3% to 1.5% by weight, erucic acid in an amount of less than 0.3% by weight, and / or lignoceric acid in an amount of less than 0.5% by weight, relative to the total fatty acid content of said oil.

[0035] Preferably, the sunflower oil according to the invention is refined sunflower oil.

[0036] Sunflower oil, according to the embodiments here, may be present in a total quantity of at least 0.1% by weight, preferably at least 2% by weight, and more preferably at least 3% by weight, relative to the total weight of the composition.

[0037] Sunflower oil, according to the embodiments herein, is present in an amount ranging from 0.1% to 20% by weight, preferably from 0.5% to 15% by weight, more preferably from 1% to 12% by weight, better from 2% to 10%, and even better from 3% to 8% by weight, relative to the total weight of the composition. Polyols

[0038] The composition according to the present invention comprises one or more polyols.

[0039] For the purposes of the present invention, the term "polyol" means an organic compound consisting of a hydrocarbon-based chain optionally interrupted by one or more oxygen atoms and bearing at least two free hydroxyl groups (-OH) on different carbon atoms, this compound being optionally cyclic or acyclic, linear or branched and saturated or unsaturated.

[0040] Polyols comprise from 2 to 30 hydroxyl groups, preferably from 2 to 10 hydroxyl groups, more preferably from 2 to 3 hydroxyl groups, even more preferably 2 hydroxyl groups.

[0041] In one embodiment, the polyols are chosen from among the diols, preferably from among the C3-C6 diols.

[0042] In some embodiments, the polyols are selected from propylene glycol, propane-1,3-diol, 1,3-butylene glycol, pentane-1,2-diol, dipropylene glycol, hexylene glycol, ethylene glycol, or mixtures thereof, preferably from propylene glycol, propane-1,3-diol, or mixtures thereof.

[0043] Preferably, the polyols are selected from propylene glycol, propane-1,3-diol, 1,3-butylene glycol, pentane-1,2-diol, dipropylene glycol, hexylene glycol, ethylene glycol, or mixtures thereof, more preferably from propylene glycol, propane-1,3-diol, or mixtures thereof. Most preferably, the polyol is propylene glycol.

[0044] The polyol(s), according to the embodiments here, are in a total quantity ranging from 0.5% to 15% by weight, preferably from 1% to 10% by weight, and more preferably from 2% to 8% by weight, relative to the total weight of the composition.

[0045] Preferably, the polyol(s) are chosen from C3-C6 diols and are in a total quantity ranging from 0.5% to 15% by weight, preferably from 1% to 10% by weight, and more preferably from 2% to 8% by weight, relative to the total weight of the composition.

[0046] Preferably, the polyol(s) are selected from propylene glycol, propane-1,3 diol, or mixtures thereof and are in a total quantity of 0.5% to 15% by weight, preferably 1% to 10% by weight, and more preferably 2% to 8% by weight, relative to the total weight of the composition. Cationic polysaccharide

[0047] The composition according to the present invention comprises one or more cationic polysaccharides.

[0048] For the purposes of the present invention, the expression "cationic polysaccharide" means any polysaccharide comprising cationic groups and / or groups that can be ionized to form cationic groups, and not comprising anionic groups and / or groups that can be ionized into anionic groups.

[0049] In one embodiment, the cationic polysaccharide is chosen from cationic cellulose derivatives, cationic galactomannan gums, or mixtures thereof, preferably is chosen from cationic cellulose derivatives comprising quaternary ammonium groups, cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer, cationic galactomannan gums or mixtures thereof.

[0050] Examples of cellulose derivatives comprising quaternary ammonium groups are described in particular in French patent 1,492,597, and mention can be made of the polymers sold under the name UCARE POLYMER “JR” (JR 400 LT, JR 125 and JR 30M) or “LR” (LR 400 and LR 30M) by Dow Chemical. These polymers are also defined in the CTFA dictionary as quaternary ammonium compounds of hydroxyethylcellulose that have reacted with an epoxide substituted with a trimethylammonium group. Polyquaternium-10 is, for example, one of these polymers.

[0051] Cationic cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer are described, in particular, in US patent 4,131,576, and hydroxyalkylcelluloses, for example, hydroxymethyl-, hydroxyethyl-, or hydroxypropylcelluloses grafted, in particular, with a salt of methacryloylethyltrimethylammonium, methacrylamidopropyltrimethylammonium, or dimethyldiallylammonium, may be mentioned. Commercial products corresponding to this definition are, more particularly, those marketed under the names CELQUAT L 200 and CELQUAT H 100 by National Starch.

[0052] Cationic galactomannan gums are described more particularly in US patents 3,589,578 and 4,031,307, and guar gums comprising cationic trialkylammonium groups, preferably tri-kylammonium groups in the C1-C6 form, may be mentioned. For example, guar gums modified with a salt of 2,3-epoxypropyltrimethylammonium (e.g., the chloride) may be used. Such products are sold under the names JAGUAR C13 S, JAGUAR C 15, JAGUAR C 17, and JAGUAR C162 by the Rhodia company.

[0053] In some embodiments, the cationic polysaccharides are selected from cationic cellulose derivatives comprising quaternary ammonium groups, cationic galactomannan gums comprising cationic trialkylammonium groups, or combinations thereof.

[0054] Preferably, the cationic polysaccharides are chosen from ga- gums Cationic lactomannan containing cationic trialkylammonium groups, and preferably from among guar gums containing cationic trialkylammonium groups. More preferably, the cationic polysaccharides are chosen from polymers bearing INCI names, such as hydroxypropyltrimonium guar chloride, hydroxypropyltrimonium guar chloride, or mixtures thereof, preferably hydroxypropyltrimonium guar chloride.

[0055] The cationic polysaccharide(s), according to the embodiments herein, are in a total quantity ranging from 0.01% to 8% by weight, preferably from 0.05% to 5% by weight, more preferably from 0.1% to 4%, and better from 0.2% to 3% by weight, relative to the total weight of the composition.

[0056] Preferably, the cationic polysaccharide(s) are selected from cationic galactomannan gums comprising cationic trialkylammonium groups and are in a total quantity ranging from 0.01% to 8% by weight, preferably from 0.05% to 5% by weight, more preferably from 0.1% to 4%, and better from 0.2% to 3% by weight, relative to the total weight of the composition.

[0057] More preferably, the cationic polysaccharide(s) are selected from guar gums comprising cationic trialkylammonium groups and are in a total quantity ranging from 0.01% to 8% by weight, preferably from 0.05% to 5% by weight, more preferably from 0.1% to 4%, and better from 0.2% to 3% by weight, relative to the total weight of the composition. Alkaline agents

[0058] The composition according to the present invention may comprise one or more alkaline agents.

[0059] In a preferred embodiment, the composition according to the present invention comprises one or more alkaline agents.

[0060] In one embodiment, the alkali agents are chosen from mineral, organic or hybrid alkali agents, or mixtures thereof.

[0061] Mineral alkali agents are preferably chosen from ammonium hydroxide, alkali metal carbonates or bicarbonates such as sodium (hydrogen)carbonate and potassium (hydrogen)carbonate, alkali metal or alkaline earth metal silicates or metasilicates such as sodium metasilicate, or mixtures thereof.

[0062] Organic alkali agents are preferably chosen from alkanolamines. In one embodiment, the alkanolamines are chosen from monoalkanolamines, dialkanolamines or trialkanolamines comprising one to three identical or different hydroxyalkyl radicals in the C1-C10 group.

[0063] In some embodiments, the alkanolamines are selected from monoethanolamine (MEA), diethanolamine, triethanolamine, monoisopropa- nolamine, diisopropanolamine, N,N-dimethylethanolamine, 2-amino-2-methyl-l-propanol, triisopropanolamine, 2-amino-2-methyl-l,3-propanediol, 3-amino-l,2-propanediol, 3-dimethylamino-l,2-propanediol, tris(hydroxymethyl)arninomethane or mixtures thereof.

[0064] In one embodiment, the alkali agents are chosen from alkanolamines such as monoethanolamine, diethanolamine, triethanolamine, ammonium hydroxide, carbonates or bicarbonates such as sodium (hydrogen)carbonate and potassium (hydrogen)carbonate, alkali metal or alkaline earth metal silicates or metasilicates such as sodium metasilicate or mixtures thereof.

[0065] Preferably, the alkali agents are chosen from alkanolamines and ammonium hydroxide. More preferably, the alkali agent is chosen from alkanolamines, such as monoethanolamine.

[0066] The alkaline agent(s), according to the embodiments herein, are in a total quantity ranging from 0.1% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 2% to 25% by weight, and better from 4% to 20% by weight, relative to the total weight of the composition.

[0067] Preferably, the alkali agent(s) are chosen from alkanolamines, ammonium hydroxide or mixtures thereof and are in a total quantity ranging from 0.1% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 2% to 25% by weight, and better from 4% to 20% by weight, relative to the total weight of the composition.

[0068] Preferably, the alkaline agent(s) chosen from the alkanolamines are in a total quantity ranging from 0.1% to 40% by weight, preferably from 1% to 30% by weight, more preferably from 2% to 25% by weight, and better from 4% to 20% by weight, relative to the total weight of the composition. Non-ionic associative polymers

[0069] The composition according to the present invention comprises one or more non-ionic associative polymers.

[0070] For the purposes of the present invention, the term "associative polymers" refers to water-soluble polymers that are capable, in an aqueous medium, of reversibly combining with each other or with other molecules. The chemical structure of one or more associative polymers comprises at least one hydrophilic region and at least one hydrophobic region characterized by at least one C8-C30 fatty acid chain.

[0071] In one embodiment, the non-ionic associative polymers are selected from: 1. Cellulose modified by groups comprising at least one chain fat. Examples that can be cited include: • Hydroxyethylcelluloses modified by groups comprising at least one fatty chain, such as linear or branched alkyl, linear or branched arylalkyl, or linear or branched alkylaryl groups, or mixtures thereof, and in which the linear or branched alkyl groups are preferentially C8-C22, for example, the product Natrosol Plus Grade 330 CS® (alkyl in C16) sold by Aqualon, the product Polysurf 67 CS (cetylhydroxyethylcellulose) sold by Ashland, or the product Bermocoll EHM 100® sold by Berol Nobel, • Hydroxyethylcelluloses modified with alkylphenyl polyalkylene glycol ether groups, such as the Amercell Polymer HM-1500® product (polyethylene glycol (15) nonylphenyl ether) sold by the Amerchol company, • Hydroxypropyl methylcelluloses modified by linear or branched C8-C22 alkyl groups, for example the product Sangelose 60L (INCI name: hydroxypropyl methylcellulose stearoxy ether) sold by Daido Chemical. 1. Hydroxypropyl guars modified by groups comprising at least one fatty chain, such as the product Esaflor HM 22® (C22 alkyl chain) sold by the company Lamberti, and the products RE210-18® (Cl4 alkyl chain) and RE205-1® (C20 alkyl chain) sold by the company Rhone-Poulenc, 2. Copolymers of vinylpyrrolidone and hydrophobic fatty-chain monomers; examples that may be cited include: • the products Antaron V216® and Ganex V216® (vinylpyrrolidone / hexadecene copolymer) sold by the company ISP. • the products Antaron V220® and Ganex V220® (vinylpyrrolidone / eicosene copolymer) sold by the company ISP, 1. Copolymers of methacrylates or alkyl acrylates in Ci-C6 and amphiphilic monomers comprising at least one fatty chain, for example the oxyethylenated methyl acrylate / stearyl acrylate copolymer sold by the Goldschmidt company under the name Antil 208®, 2. Copolymers of hydrophilic methacrylates or acrylates and hydrophobic monomers comprising at least one fatty chain, for example polyethylene glycol methacrylate / lauryl methacrylate copolymer, 3. Polyurethane polyethers comprising in their chain both hydrophilic blocks, usually of a polyoxyethylenated nature, and hydrophobic blocks, which may be aliphatic sequences alone and / or cycloaliphatic and / or aromatic sequences, 4. Polymers with an aminoplast ether skeleton containing at least one fatty chain, such as Pure Thix® compounds sold by Sud-Chemie.

[0072] Preferably, the polyether polyurethanes comprise at least two lipophilic hydrocarbon-based chains containing 6 to 30 carbon atoms, separated by a hydrophilic block. The hydrocarbon-based chains may be dangling chains or chains at the ends of the hydrophilic block. In particular, one or more dangling chains may be included. Furthermore, the polymer may comprise a hydrocarbon-based chain at one or both ends of a hydrophilic block.

[0073] Polyurethane polyethers can be multi-sequenced, particularly in tri-sequenced form. The hydrophobic blocks can be at each end of the chain (e.g., a tri-sequenced copolymer with a central hydrophilic block) or distributed both at the ends and throughout the chain (e.g., a multi-sequenced copolymer). These polymers can also be grafted polymers or star polymers.

[0074] Nonionic fatty-chain polyurethane polyethers can be tri-sequenced copolymers, in which the hydrophilic block is a polyoxyethylene chain comprising 50 to 1000 oxyethylene groups. Nonionic polyurethane polyethers include a urethane linkage between the hydrophilic blocks, hence the name.

[0075] In one embodiment, the nonionic fat chain polyurethane polyethers include hydrophilic blocks that are linked to the lipophilic blocks via other chemical bonds.

[0076] Examples of nonionic fat chain polyether polyurethanes that can be used include Rheolate 205® containing a urea function, sold by the Rheox company, or Rheolate® 208, 204 or 212, and also Acrysol RM 184®.

[0077] We can also mention the product Elfacos T210® containing a C 12-14 alkyl chain, and the product Elfacos T212® containing a C[8] alkyl chain, from Akzo.

[0078] Rohm & Haas product DW 1206B® containing a C20 alkyl chain and a urethane bond, comprising a total quantity of 20% by weight in water, can also be used.

[0079] It is also possible to use solutions or dispersions of these polymers, particularly in water or in aqueous-alcoholic media. Examples of such polymers include Rheolate® 255, Rheolate® 278, and Rheolate® 244, sold by Rheox. Products DW 1206F and DW 1206J, sold by Rohm & Haas, can also be used.

[0080] We can also mention Luvigel Star (polyurethane-39) sold by BASF, which is a copolymer of polyethylene glycol-140 (PEG-140) and hexamethylene di- socyanate terminated by C12-14 pareth-10, C16-18 pareth-11 and C18-20 pareth-11.

[0081] Polyurethane polyethers that can be used according to the invention are in particular those described in the article by G. Fonnum, J. Bakke and Fk. Hansen - Colloid Polym. Sci. 271, 380-389 (1993).

[0082] In certain embodiments, the polyether polyurethane can be obtained by polycondensation of at least three compounds comprising: i. at least one polyethylene glycol comprising 150 to 180 moles of ethylene oxide, ii. stearyl alcohol or decyl alcohol, and iii. at least one diisocyanate.

[0083] Such polyurethane polyethers are sold in particular by the company Rohm & Haas under the names Aculyn 46® and Aculyn 44® [Aculyn 46® is a polyethylene glycol polycondensate containing 150 or 180 moles of ethylene oxide, stearyl alcohol and methylenebis(4-cyclohexyl isocyanate) (SMDI), at 15% by weight in a matrix of maltodextrin (4%) and water (81%); Aculyn 44® is a polyethylene glycol polycondensate containing 150 or 180 moles of ethylene oxide, decyl alcohol and methylenebis(4-cyclohexyl isocyanate) (SMDI), at 35% by weight in a mixture of propylene glycol (39%) and water (26%)].

[0084] In certain preferred embodiments, the nonionic associative polymers are selected from cellulose derivatives, preferably from hydroxyethylcelluloses modified by groups comprising at least one fatty chain. More preferably, the nonionic associative polymer is cetylhydroxyethylcellulose.

[0085] The non-ionic associative polymer(s), according to the embodiments herein, are in a total quantity ranging from 0.005% to 5% by weight, and preferably from 0.01% to 2% by weight, relative to the total weight of the composition.

[0086] Preferably, the non-ionic associative polymer(s) are selected from celluloses modified by groups comprising at least one fatty chain, according to the embodiments herein, and are in a total quantity ranging from 0.005% to 5% by weight, and preferably from 0.01% to 2% by weight, relative to the total weight of the composition. Oxidative dye

[0087] The composition according to the present invention may comprise one or more oxidative dyes.

[0088] Preferably, the composition according to the present invention comprises one or more oxidative dyes.

[0089] The oxidative dye, according to the embodiments herein, includes at least one oxidation base and / or at least one oxidation coupler. Preferably, the composition according to the invention comprises one or more oxidation bases in combination with one or more couplers.

[0090] Oxidation bases are generally colorless or faintly colored compounds which, when mixed with oxidizing compounds, give rise to colored compounds or a dye. Furthermore, the color shades obtained with these oxidation bases can be varied by combining them with oxidation couplers or color modifiers.

[0091] In one embodiment, the oxidation bases are selected from a group consisting of para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts.

[0092] The addition salts of the oxidation bases are preferably chosen from addition salts with an acid, such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates, and addition salts with a base, such as sodium hydroxide, potassium hydroxide, aqueous ammonia, amines or alkanolamines.

[0093] The para-phenylenediamines that can be used include, for example, para-phenylenediamine, para-toluenediamine, 2-chloro-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,5-dimethyl-para-phenylenediamine, N,N-dimethyl-para-phenylenediamine, N,N-diethyl-para-phenylenediamine, N,N-dipropyl-para-phenylenediamine, 4-amino-N,N-diethyl-3-methylaniline, N,N-bis([3-hydroxyethyl)-para-phenylenediamine, 4-N,N-bis([3-hydroxyethyl)amino-2-methylaniline, 4-N,N-bis([3-hydroxyethyl)amino-2-chloroaniline, 2-[3-hydroxyethyl-para-phenylenediamine, 2-γ-hydroxypropyl-para-phenylenediamine, 2-methoxymethyl-para-phenylenediamine, 2-fluoro-para-phenylenediamine, 2-isopropyl-para-phenylenediamine, N-([3-hydroxypropyl)-para-phenylenediamine, 2-hydroxymethyl-para-phenylenediamine, N,N-dimethyl-3-methyl-para-phenylenediamine, N,N-(ethyl-[3-hydroxyethyl)-para-phenylenediamine, N-([3,γ-dihydroxypropyl)-para-phenylenediamine, N-(4'-aminophenyl)-para-phenylenediamine, N-phenyl-para-phenylenediamine, 2-[3-hydroxyethyloxy-para-phenylenediamine, 2-[3-acetylaminoethyloxy-para-phenylenediamine, N-(γ-methoxyethyl)-para-phenylenediamine, 2-thienyl-para-phenylenediamine, 2-[3-hydroxyethylamino-5-aminotoluene, 4-aminophenylpyrrolidine, 3-hydroxy-γ-(4'-aminophenyl)pyrrolidine, and / or their addition salts with an acid.

[0094] In one embodiment, the para-phenylenediamines are selected from para-phenylenediamine, para-toluenediamine, 2-isopropyl-para-phenylenediamine, 2-[3-hydroxyethyl-para-phenylenediamine, 2-y-hydroxyethyl-para-phenylenediamine, 2-methoxymethyl-para-phenylenediamine, 2-[3-hydroxyethyloxy-para-phenylenediamine, 2,6-dimethyl-para-phenylenediamine, 2,6-diethyl-para-phenylenediamine, 2,3-dimethyl-para-phenylenediamine, N,N-bis([3-hydroxyethyl)-para-phenylenediamine, 2-chloro-para-phenylenediamine, 2-[3-acetylaminoethyloxy-para-phenylenediamine, or, preferably, their addition salts with an acid, or mixtures thereof.

[0095] The bis(phenyl)alkylenediamines that may be used include, for example, N,N'-bis(P-hydroxyethyl)-N,N'-bis(4'-aminophenyl)-1,3-diaminopropanol, N,N'-bis-([3-hydroxyethyl)-N,N'-bis(4'-aminophenyl)ethylenediamine, N,N'-bis(4-aminophenyl)tetramethylenediamine, N,N'-bis([3-hydroxyethyl)-N,N'-bis(4-aminophenyl)tetramethylenediamine, N,N'-bis(4-methylaminophenyl)tetramethylenediamine, N,N'-bis(ethyl)-N,N'bis(4'-amino-3'-methylphenyl)ethylenediamine, 1,8,bis(2,5-diaminophenoxy-3,6-dioxaoctane, and / or their addition salts.

[0096] Para-aminophenols that can be used include, for example, para-aminophenol, 4-amino-3-methylphenol, 4-amino-3-fluorophenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethylphenol, 4-amino-2-methylphenol, 4-amino-2-hydroxymethylphenol, 4-amino-2-methoxymethylphenol, 4-amino-2-aminomethylphenol, 4-amino-2-([3-hydroxyethylaminomethyl)phenol and 4-amino-2-fluorophenol, and / or their addition salts with an acid. In one example, the addition salt is a sulfurous acid salt or a sodium metabisulfite salt.

[0097] Ortho-aminophenols that may be used include, for example, 2-aminophenol, 2-amino-5-methylphenol, 2-amino-6-methylphenol and 5-acetamido-2-aminophenol, and / or their addition salts.

[0098] Various heterocyclic bases are known and can be used in the embodiments presented herein. Examples of such heterocyclic bases include pyridine derivatives, pyrimidine derivatives, and pyrazole derivatives.

[0099] Pyridine derivatives may be selected from compounds as described, for example, in patents GB 1 026 978 and / or GB 1 153 196, including 2,5-diaminopyridine, 2-(4-methoxyphenyl)amino-3-aminopyridine, 3,4-diaminopyridine, and / or their addition salts.

[0100] In one embodiment, the pyridine derivatives may be chosen from the oxidation bases of 3-aminopyrazolo[l,5-a]pyridine, or their described addition salts, for example, in patent application FR 2 801 308. Examples of such bases include pyrazolo[l,5-a]pyrid-3-ylamine, 2-acetylaminopyrazolo[l,5-a]pyrid-3-ylamine, 2-morpholin-4-ylpyrazolo[l,5-a]pyrid-3-ylamine, 3-aminopyrazolo[l,5-a]pyridine-2-carboxylic acid, 2-methoxypyrazolo[l,5-a]pyrid-3-ylamine, (3-aminopyrazolo[l,5-a]pyrid-7-yl)methanol, 2-(3-aminopyrazolo[l,5-a]pyrid-5-yl)ethanol, 2-(3-aminopyrazolo[l,5-a]pyrid-7-yl)ethanol, the (3-aminopyrazolo[l,5-a]pyrid-2-yl)methanol, 3,6-diaminopyrazolo[l,5-a]pyridine, 3,4-diaminopyrazolo[l,5-a]pyridine, pyrazolo[l,5-a]pyridine-3,7-diamine, 7-morpholin-4-ylpyrazolo[l,5-a]pyrid-3-ylamine, pyrazolo[l,5-a]pyridine-3,5-diamine, 5-morpholin-4-ylpyrazolo[l,5-a]pyrid-3-ylamine, 2-[(3-aminopyrazolo[l,5-a]pyrid-5-yl)(2-hydroxyethyl)amino]ethanol, 2-[(3-aminopyrazolo[l,5-a]pyrid-7-yl)(2-hydroxyethyl)amino]ethanol, the 3-aminopyrazolo[l,5-a]pyridin-5-ol, 3-aminopyrazolo[l,5-a]pyridin-4-ol,3-aminopyrazolo[l,5-a]pyridin-6-ol and 3-aminopyrazolo[l,5-a]pyridin-7-ol, 2-(3-aminopyrazolo[l,5-a]pyridin-2-yl)oxyethanol, and / or their addition salts.

[0101] Pyrimidine derivatives may be selected from the compounds described, for example, in patents DE 2359399; JP 88-169571; JP 05-63124; EP 0770375, or patent application WO 96 / 15765, including 2,4,5,6-tetraaminopyrimidine, 4-hydroxy-2,5,6-triaminopyrimidine, 2-hydroxy-4,5,6-triaminopyrimidine, 2,4-dihydroxy-5,6-diaminopyrimidine, 2,5,6-triaminopyrimidine, and their addition salts and their tautomeric forms, where a tautomeric equilibrium exists.

[0102] Pyrazole derivatives may be selected from, for example, the compounds described in patents DE 3843892, DE 4133957 and patent applications WO 94 / 08969, WO 94 / 08970, FR-A-2 733 749 and DE 195 43 988, including 4,5-diamino-l-methylpyrazole, 4,5-diamino-l-([3-hydroxyethyl)pyrazole, 3,4-diaminopyrazole, 4,5-diamino-l-(4'-chlorobenzyl)pyrazole, 4,5-diamino-l,3-dimethylpyrazole, 4,5-diamino-3-methyl-l-phenylpyrazole, 4,5-diamino-l-methyl-3-phenylpyrazole, 4-amino-1,3-dimethyl-5-hydrazinopyrazole, l-benzyl-4,5-diamino-3-methylpyrazole, 4,5-diamino-3-tert-butyl-l-methylpyrazole, 4,5-diamino-l-tert-butyl-3-methylpyrazole, 4,5-diamino-l-([3-hydroxyethyl)-3-methylpyrazole, 4,5-diamino-l-ethyl-3-methylpyrazole, 4,5-diamino-l-ethyl-3-(4'-methoxyphenyl)pyrazole, the 4,5-diamino-l-ethyl-3-hydroxymethylpyrazole, the 4,5-diamino-3-hydroxymethyl-l-methylpyrazole, the 4,5-diamino-3-hydroxymethyl-l-isopropylpyrazole, the 4,5-diamino-3-methyl-1-isopropylpyrazole, the 4-Amino-5-(2'-aminoethyl)amino-l,3-dimethylpyrazole, 3,4,5-triaminopyrazole, l-methyl-3,4,5-triaminopyrazole, 3,5-diamino-l-methyl-4-methylaminopyrazole, 3,5-diamino-4-([3-hydroxyethyl)amino-l-methylpyrazole, and their addition salts. 4,5-Diamino-l-([3-methoxyethyl)pyrazole may also be used.

[0103] Preferably, 4,5-diaminopyrazole and even more preferably 4,5-diamino-l-([3-hydroxyethyl)pyrazole, and / or its salts may be cited.

[0104] In one embodiment, pyrazole derivatives that may also be used include diamino-N,N-dihydropyrazolopyrazolones, and in particular those described in patent application FR-A-2 886 136, such as the following compounds and their addition salts: 2,3-diamino-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 2-amino-3-éthylamino-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 2-amino-3-isopropylamino-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 2-amino-3-(pyrrolidin-l-yl)-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 4,5-diamino-1,2-diméthyl-1,2-dihydropyrazol-3-one, 4,5-diamino-1,2-diéthyl-1,2-dihydropyrazol-3-one, 4,5-diamino-1,2-di-(2-hydroxyéthyl)-1,2-dihydropyrazol-3-one, 2-amino-3-(2-hydroxyéthyl)amino-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 2-amino-3-diméthylamino-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 2,3-diamino-5,6,7,8-tétrahydro-lH,6H-pyridazino[l,2-a]pyrazol-l-one, 4-amino-1,2-diéthyl-5-(pyrrolidin-1 -yl)-1,2-dihydropyrazol-3-one, 4-amino-5-(3-diméthylaminopyrrolidin-1 -yl)-1,2-diéthyl-1,2-dihydropyrazol-3-one, 2,3-diamino-6-hydroxy-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 2,3-Diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one and / or, preferably, one of their salts, or mixtures thereof. Preferably, 2,3-diamino-6,7-dihydro-1H,5H-pyrazolo[1,2-a]pyrazol-1-one, and / or its salts, may be specified.

[0105] The heterocyclic base can be chosen from the 4,5-diamino- l-([3-hydroxyethyl)pyrazole, 2,3-diamino-6,7-dihydro-lH,5H-pyrazolo[l,2-a]pyrazol-l-one, 2-(3-aminopyrazolo[l,5-a]pyridin-2-yl)oxyethanol, and / or one of their salts.

[0106] In certain embodiments, the oxidation bases are chosen from para-phenylenediamines, bis(phenyl)alkylenediamines, para-aminophenols, ortho-aminophenols, heterocyclic bases, the corresponding addition salts, or mixtures thereof, preferably from 2-methoxymethyl-para-phenylenediamine, the 2- [3-hydroxyethyl-para-phenylenediamine, the 2-γ-Hydroxypropyl-para-phenylenediamine, their addition salts, or mixtures thereof.

[0107] In one embodiment, the oxidation couplers may be selected from a group consisting of meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene-based couplers, heterocyclic couplers and / or their addition salts.

[0108] In certain embodiments, the oxidation couplers are selected from 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene, 1-hydroxy-3-aminobenzene, 1-methyl-2-hydroxy-4-[3-hydroxyethylaminobenzene, 4-amino-2-hydroxytoluene, 5-amino-6-chloro-2-methylphenol, 2,4-diamino-1-([3-hydroxyethyloxy)benzene, 2-amino-4-([3-hydroxyethylamino)-1-methoxybenzene, 1,3-diaminobenzene, 1,3-bis(2,4-diaminophenoxy)propane, 3-ureidoaniline, 3-ureido-1-dimethylaminobenzene, sesamol, the l-[3-hydroxyethylamino-3,4-methylenedioxybenzene, α-naphtol, 2-methyl-1-naphtol, 6-hydroxyindole, 4-hydroxyindole, 4-hydroxy-N-methylindole, 5-methoxy-6-hydroxyindole, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 2-amino-4-hydroxyethylaminoanisole, 3-amino-6-methoxy-2-methylaminopyridine, 3,5-diamino-2,6-dimethoxypyridine, lN-([3-hydroxyethyl)amino-3,4-methylenedioxybenzene, 2,6-bis-([3-hydroxyethylamino)toluene, 6-hydroxyindole, 2,6-dihydroxy-4-methylpyridine, 2-chloro-3,5-diaminopyridine, 2-chloro-3,5-diamino-6-methoxypyridine, 2-chloro-3,5-diamino-6-methylpyridine, 1H-3-methylpyrazol-5-one, 1-phenyl-3-methylpyrazol-5-one, 4-(3,5-diaminopyridin-2-yl)-1-(2-hydroxyethyl)-1-methylpiperiazine-1-ium chloride, 2,6-dimethylpyrazolo[1,5-b]-1,2,4-triazole, 2,4,6-trimethoxyaniline hydrochloride, 2,6-dimethyl[3,2-c]-1,2,4-triazole, the 6-Methylpyrazolo[l,5-a]benzimidazole and 2,6-diaminopyrazine, their acid salts, or mixtures thereof.

[0109] In various embodiments, the oxidation couplers are selected from 1,3-dihydroxybenzene, 1,3-dihydroxy-2-methylbenzene, 4-chloro-1,3-dihydroxybenzene, 1-hydroxy-3-aminobenzene, 1-methyl-2-hydroxy-4-[3-hydroxyethylaminobenzene, 4-amino-2-hydroxytoluene, 5-amino-6-chloro-2-methylphenol, 2,4-diamino-1-([3-hydroxyethyloxy)benzene, α-naphthol, 6-hydroxyindole, 2-amino-3-hydroxypyridine, 6-hydroxybenzomorpholine, 3-amino-6-methoxy-2-methylaminopyridine, 2-amino-4-hydroxyethylaminoanisole, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino-5-ethylphenol, their salts of addition or their mixtures.

[0110] The oxidation couplers, in certain embodiments, are further selected from 3-amino-6-methoxy-2-methylaminopyridine, 6-hydroxybenzomorpholine, 2,4-diamino-l-([3-hydroxyethyloxy)benzene, 2-amino-3-hydroxypyridine, 5-amino-6-chloro-2-methylphenol, l-methyl-2-hydroxy-4-[3-hydroxyethylaminobenzene, 2-amino-4-hydroxyethylaminoanisole, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino-5-ethylphenol and l-hydroxy-3-aminobenzene, their addition salts and mixtures thereof.

[0111] In general, the addition salts of the oxidation couplers used in the present invention are chosen from addition salts with an acid, such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates, and addition salts with a base, such as sodium hydroxide, potassium hydroxide, aqueous ammonia, amines or alkanolamines.

[0112] In some embodiments, the oxidation couplers are chosen from 6-hydroxybenzomorpholine, 2,4-diamino-l-([3-hydroxyethyloxy)benzene, 2-amino-3-hydroxypyridine, 5-amino-6-chloro-2-methylphenol, l-methyl-2-hydroxy-4-[3-hydroxyethylaminobenzene, 2-amino-4-hydroxyethylaminoanisole, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino-5-ethylphenol, l-hydroxy-3-aminobenzene, α-naphthol, their addition salts, their salts, the solvates of their salts, or mixtures thereof.

[0113] Preferably, the oxidation couplers are chosen from 6-hydroxybenzomorpholine, hydroxyethyl-3,4-methylenedioxyaniline, 2-amino-5-ethylphenol, their addition salts or mixtures thereof.

[0114] In a particular embodiment, the composition according to the present invention is free from oxidation couplers selected from resorcinol, 2-methylresorcinol, 4-chlororesorcinol and their addition salts.

[0115] The oxidation base(s), according to the embodiments here, are preferably in a total quantity ranging from 0.0001% to 10% by weight, relative to the total weight of the composition.

[0116] The oxidation coupler(s), according to the embodiments herein, are preferably in a total quantity ranging from 0.0001% to 10% by weight, relative to the total weight of the composition.

[0117] The oxidation bases and couplers may be in suitable quantities so that the total amount of oxidative dye, according to the embodiments herein, is in the range of 0.0002% to 20% by weight, relative to the total weight of the composition. Fatty Acids

[0118] The composition, according to the present invention, may further include one or more fatty acids.

[0119] In one embodiment, the fatty acids comprise from 6 to 40 carbon atoms, preferably from 12 to 22 carbon atoms. They may optionally be hydroxylated.

[0120] In some embodiments, the fatty acids may comprise at least one carboxylic acid group and a linear or branched alkyl chain, saturated or unsaturated, in particular unsaturated, comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms, and more preferably from 10 to 30 carbon atoms.

[0121] Preferably, the fatty acids may include at least one carboxylic acid group and a linear or branched alkyl chain, saturated or unsaturated, in particular unsaturated, comprising from 10 to 30 carbon atoms, in particular from 12 to 22 carbon atoms.

[0122] In some embodiments, the fatty acids are chosen from compounds of RC(O)OH structure in which R represents a linear or branched alkyl group, saturated or unsaturated including from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms, preferably from 12 to 24 carbon atoms, better still from 14 to 22 carbon atoms.

[0123] For the purposes of the present invention, the term "fatty acids" means free fatty acids, for example fatty acids according to the invention which are not esterified.

[0124] Fatty acids may be selected from solid fatty acids, liquid fatty acids or mixtures thereof.

[0125] For the purposes of the present invention, the expression "solid fatty acid" means a fatty acid having a melting point above 25 °C, preferably above or equal to 28 °C, more preferably above or equal to 30 °C at atmospheric pressure (1.013 x 0.5 Pa).

[0126] In one embodiment, the solid fatty acids are selected from myristic acid, palmitic acid, arachidic acid, stearic acid, lauric acid, behenic acid, 12-hydroxystearic acid or mixtures thereof.

[0127] For the purposes of the present invention, the expression "liquid fatty acid" means a fatty acid with a melting point less than or equal to 25 °C, preferably less than or equal to 20 °C at atmospheric pressure (1.013 x 0.5 Pa).

[0128] In one embodiment, the liquid fatty acids are selected from oleic acid, linoleic acid, arachidonic acid, isostearic acid, isopalmitic acid or mixtures thereof.

[0129] In some embodiments, the fatty acids are selected from lauric acid, oleic acid, linoleic acid, linolenic acid, undecylenic acid, isocetyl acid, isostearic acid, myristic acid, palmitic acid, acid stearic acid, cetylstearic acid or mixtures thereof, preferably from myristic acid, palmitic acid, stearic acid or mixtures thereof.

[0130] Preferably, the fatty acids present in the composition according to the present invention are solid fatty acids, in particular chosen from fatty acids including at least one carboxylic acid group and a linear or branched unsaturated alkyl chain comprising from 10 to 30 carbon atoms, in particular from 14 to 22 carbon atoms.

[0131] More preferably, the fatty acids present in the present composition according to the present invention are solid fatty acids, in particular selected from myristic acid, palmitic acid, stearic acid or mixtures thereof.

[0132] Where appropriate, the fatty acid(s) are preferably present in the composition in a total quantity of 0.1% to 15% by weight, preferably 0.2% to 10%, more preferably 0.4% to 5% by weight, and better 0.5% to 3% by weight, relative to the total weight of the composition. Additional fatty compounds

[0133] The composition, according to the present invention, may further include one or more additional fatty compounds. The additional fatty compound is different from sunflower oil and fatty acids.

[0134] The additional fatty compounds that may be used in the present invention are neither (poly)oxyalkylated nor (poly)glycerolated.

[0135] The additional fatty compounds that can be used according to the present invention are non-silicone fatty compounds.

[0136] The expression "non-silicone fatty compound" refers to a fatty compound not containing Si-O bonds and the expression "silicone fatty compound" refers to a fatty compound containing at least one Si-O bond.

[0137] The additional fatty compounds that are useful in an embodiment may be liquid fatty compounds (or oils) and / or solid fatty compounds. The term "liquid fatty compound" refers to a fatty compound with a melting point less than or equal to 25 °C at atmospheric pressure (1.013 x 10⁵ Pa) and the term "solid fatty compound" refers to a fatty compound with a melting point greater than 25 °C at atmospheric pressure (1.013 x 10⁵ Pa).

[0138] The term 'melting point' refers to the temperature of the most endothermic peak observed in thermal analysis (differential scanning calorimetry or DSC) as described in ISO 11357-3; 1999. The melting point can be measured using a differential scanning calorimeter (DSC), for example, the calorimeter sold under the name "MDSC 2920" by TA Instruments. In the present invention, all melting points are determined at atmospheric pressure (1.013 x 1.05 Pa).

[0139] Liquid fatty compounds are selected from liquid hydrocarbons in the C6 to Ci6 range, liquid hydrocarbons comprising more than 16 carbon atoms, non-silicone oils of animal origin, fluorinated oils, liquid fatty alcohols, liquid esters of fatty acids and / or fatty alcohols other than triglycerides, or mixtures thereof.

[0140] Liquid hydrocarbons in the C6 to C16 range may be linear, branched, or optionally cyclic, and are preferably chosen from among the alkanes. Examples that may be cited include hexane, cyclohexane, undecane, dodecane, isododecane, tridecane, or isoparaffins, such as isohexadecane or isodecane, or mixtures thereof.

[0141] Liquid hydrocarbons comprising more than 16 carbon atoms may be linear or branched, and of mineral or synthetic origin, and are preferably selected from liquid paraffins or liquid petroleum jelly (or mineral oil), polydecenes, hydrogenated polyisobutene such as Parleam®, and mixtures thereof.

[0142] One oil based on hydrocarbons of animal origin that may be cited is perhydrosqualene.

[0143] Fluorinated oils may be selected from perfluoromethylcyclopentane and perfluoro-1,3-dimethylcyclohexane, sold under the names Flutec® PCI and Flutec® PC3 by BNFL Fluorochemicals, perfluoro-1,2-dimethylcyclobutane, per-fluoroalkanes such as dodecafluoropentane and tetradecafluorohexane, sold under the names PF 5050® and PF 5060® by 3M, or bromoperfluorooctyl sold under the name Foralkyl® by Atochem, nonafluoromethoxybutane and nonafluoroethoxyisobutane, perfluoromorpholine derivatives such as 4-trifluoromethyl perfluoromorpholine sold under the name PF 5052® by 3M.

[0144] The liquid fatty alcohols that may be used are selected from linear or branched, saturated or unsaturated alcohols, preferably unsaturated or branched alcohols, comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms. These fatty alcohols are neither oxyalkylated nor glycerolated. Examples that may be cited include octyldodecanol, 2-butyloctanol, 2-hexyldecanol, 2-undecylpentadecanol, isostearyl alcohol, oleyl alcohol, linolenylic alcohol, ricinoleyl alcohol, undecylenyl alcohol, and linoleyl alcohol, or mixtures thereof. Preferably, the liquid fatty alcohol is oleyl alcohol.

[0145] With regard to liquid esters of fatty acids and / or fatty alcohols, other than triglycerides, particular examples may be given of esters of saturated or unsaturated aliphatic mono- or polyacids, linear in Cl to C26 or branched in C3 to C26 and of saturated or unsaturated aliphatic mono- or polyalcohols, linear in Cl to C26 or branched in C3 to C26, the total number of carbons of the esters being greater than or equal to 6 and more advantageously greater than or equal to 10.

[0146] In some embodiments, for monoalcohol esters, at least one of the alcohol and the acid is branched.

[0147] In various embodiments, monoesters of fatty acids and / or fatty alcohols other than triglycerides are selected from dihydroabietyl behenate, isostearyl lactate, lauryl lactate, linoleyl lactate, oleyl lactate, isostearyl octanoate, isocetyl octanoate, isocetyl isostearate, isocetyl laurate, isocetyl stearate, isodecyl octanoate, isodecyl oleate, isononyl isononanoate, isostearyl palmitate, methyl acetyl ricinoleate, octyl isononanoate, 2-ethylhexyl isononanoate, octyldodecyl erucate, oleyl erucate, ethyl palmitate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as 2-octyldodecyl isopropyl myristate, isobutyl stearate, 2-hexyldecyl laurate, or mixtures thereof.

[0148] Preferably, monoesters of monoacids and monoalcohols are selected from ethyl palmitate and isopropyl palmitate, alkyl myristates such as isopropyl myristate or ethyl myristate, isocetyl stearate, 2-ethylhexyl isononanoate, isodecyl neopentanoate and isostearyl neopentanoate, or mixtures thereof.

[0149] In some embodiments, esters of dicarboxylic or tricarboxylic acids in C4 to C22 and of alcohols in Cl to C22 and esters of monocarboxylic, dicarboxylic or tricarboxylic acids and of dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy alcohols in C2 to C26 may also be used.

[0150] In various embodiments, the following may be mentioned in particular: diethyl sebacate, diisopropyl sebacate, diisopropyl adipate, di-n-propyl adipate, dioctyl adipate, diisostearyl adipate, dioctyl maleate, glyceryl undecylenate, octyldodecyl stearoyl stearate, pentaerythrityl monoricinoleate, pentaerythrityl tetraisononanoate, pentaerythrityl tetrapelargonate, pentaerythrityl tetraisostearate, pentaerythrityl tetraoctanoate, propylene glycol dicaprylate, propylene glycol dicaprate, tridecyl erucate, triisopropyl citrate, citrate of triisostearyl, glyceryl trilactate, glyceryl trioctanoate, trioctyldodecyl citrate, trioleyl citrate, propylene glycol dioctanoate, neopentyl glycol diheptanoate, diethylene glycol diisononanoate and polyethylene glycol distearates, or mixtures thereof.

[0151] In one embodiment, the fatty acid esters and / or fatty alcohols other than triglycerides are selected from sugar esters and fatty acid diesters in C6 to C30 and preferably in C12 to C22.

[0152] The term "sugar" refers to compounds based on oxygen-bearing hydrocarbons bearing several alcohol functional groups, with or without aldehyde or ketone functional groups, and comprising at least 4 carbon atoms. These sugars may be monosaccharides, oligosaccharides or polysaccharides other than anionic polysaccharides.

[0153] In some embodiments, examples of suitable sugars that may be mentioned include sucrose, glucose, galactose, ribose, fucose, maltose, fructose, mannose, arabinose, xylose, and lactose and their derivatives, including alkyl derivatives, such as methyl derivatives, for example methylglucose.

[0154] In various embodiments, the sugar esters of fatty acids are chosen from the group comprising the esters or mixtures of esters of sugars described above and linear or branched fatty acids, saturated or unsaturated at C6 to C30 and preferably at C12 to C22. In some embodiments, if unsaturated, these compounds may comprise one to three conjugated or non-conjugated carbon-carbon double bonds.

[0155] In some embodiments, the esters can also be chosen from monoesters, diesters, triesters, tetraesters and polyesters, or mixtures thereof.

[0156] These esters may be, for example, oleates, laurates, palmitates, myristates, behenates, cocoates, stearates, linoleates, linolenates, caprates, arachidonates or mixtures thereof, in particular such as mixed esters of oleopalmitate, oleostearate and palmitostearate.

[0157] Preferably, the esters are chosen from among monoesters and diesters and in particular mono- or dioleates, stearates, behenates, oleopalmitates, linoleates, linolenates and oleostearates of sucrose, glucose or methylglucose, or mixtures thereof.

[0158] One example that can be mentioned is the product sold under the name Glucate® DO by the company Amerchol, which is a methylglucose dioleate.

[0159] In one embodiment, the fatty esters of fatty acids and / or fatty alcohols other than triglycerides are preferably chosen from a liquid ester of a monoacid and a monoalcohol.

[0160] Preferably, the additional fatty compounds are chosen from solid fatty compounds.

[0161] Solid fatty compounds preferentially have a viscosity greater than 2 Pa.s, measured at 25 °C and at a shear rate of 1 s1.

[0162] In one embodiment, the solid fatty compound(s) are chosen from solid fatty alcohols, solid esters of fatty acids and / or fatty alcohols, waxes, ceramides, or mixtures thereof.

[0163] The term "fatty alcohol" is intended to designate a long-chain aliphatic alcohol comprising from 6 to 40 carbon atoms, preferably from 8 to 30 carbon atoms, and comprising at least one hydroxyl group OH. These fatty alcohols are neither oxy-alkylated nor glycerolated.

[0164] Solid fatty alcohols may be saturated or unsaturated, and linear or branched, and include from 8 to 40 carbon atoms, preferably from 10 to 30 carbon atoms. Preferably, solid fatty alcohols have the structure R'-OH with R' denoting a linear alkyl group, optionally substituted by one or more hydroxyl groups, comprising from 8 to 40, preferably from 10 to 30 carbon atoms, better still from 10 to 30, or even from 12 to 24 atoms, and even better from 14 to 22 carbon atoms.

[0165] The solid fatty alcohols in various embodiments, which can be used, are chosen from saturated or unsaturated, linear or branched (mono)alcohols, preferably linear and saturated, including from 8 to 40 carbon atoms, better still from 10 to 30, or even from 12 to 24 atoms, and even better from 14 to 22 carbon atoms.

[0166] In one embodiment, the solid fatty alcohols that can be used, alone or in mixture, can be selected from myristyl alcohol (or 1-tetradecanol), cetyl alcohol (or 1-hexadecanol), stearyl alcohol (or 1-octadecanol), arachidyl alcohol (or 1-eicosanol), behenyl alcohol (or 1-docosanol), lignoceryl alcohol (or 1-tetracosanol), ceryl alcohol (or 1-hexacosanol), montanylic alcohol (or 1-octacosanol), and myricyl alcohol (or 1-triacontanol).

[0167] In some embodiments, the solid fatty alcohol is selected from cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, arachidyl alcohol, or mixtures thereof, such as cetylstearyl or cetearyl alcohol.

[0168] Preferably, the solid fatty alcohol is chosen from cetyl alcohol, stearyl alcohol or mixtures thereof such as cetylstearyl alcohol or cetearyl alcohol.

[0169] The solid esters of a fatty acid and / or a fatty alcohol may be selected from esters derived from a C9-C30 carboxylic fatty acid and / or a C9-C30 fatty alcohol*

[0170] In certain embodiments, the solid fatty esters are the esters of a linear or branched saturated carboxylic acid, comprising at least 9 carbon atoms, preferably 10 to 30 carbon atoms and more particularly 12 to 24 carbon atoms, and of a linear or branched saturated monoalcohol, comprising at least 9 carbon atoms, preferably 10 to 30 carbon atoms and more particularly 12 to 24 carbon atoms. The saturated carboxylic acids may optionally be hydroxylated and are preferably monocarboxylic acids.

[0171] In some embodiments, C4-C22 dicarboxylic or tricarboxylic acid esters and C1-C22 alcohol esters and C2-C26 monocarboxylic, dicarboxylic or tricarboxylic acid esters and dihydroxy, trihydroxy, tetrahydroxy or pentahydroxy alcohols may also be used.

[0172] In an additional embodiment, octyldodecyl behenate, the isocetyl behenate, cetyl lactate, stearyl octanoate, octyl octanoate, cetyl octanoate, decyl oleate, hexyl stearate, octyl stearate, myristyle stearate, cetyl stearate, stearyl stearate, octyl pelargonate, cetyl myristate, myristyle myristate, stearyl myristate, octyl palmitate, myristyle palmitate, cetyl palmitate, stearyl palmitate, or mixtures thereof are preferred.

[0173] In certain embodiments, the solid esters of a fatty acid and / or a fatty alcohol are selected from C9-C26 alkyl palmitates, in particular myristyle palmitate, cetyl palmitate or stearyl palmitate; C9-C26 alkyl myristates, such as cetyl myristate, stearyl myristate and myristyle myristate; C9-C26 alkyl stearates, in particular myristyle stearate, cetyl stearate and stearyl stearate, or mixtures thereof.

[0174] Preferably, the additional fatty compound(s) are chosen from solid fatty alcohols, in particular from cetyl alcohol, stearyl alcohol or mixtures thereof, such as cetylstearyl alcohol or cetearyl alcohol.

[0175] Where appropriate, the additional fatty compound(s) other than sunflower oil and fatty acids, according to the embodiments herein, are present in a total quantity of 0.5 to 40% by weight, preferably 1% to 30% by weight, more preferably 5% to 25% by weight, better 10% to 20% by weight, relative to the total weight of the composition.

[0176] Preferably, the additional fatty compound(s) other than sunflower oil and fatty acids are chosen from solid fatty compounds, according to the embodiments herein, and are present in a total quantity of 0.5% to 40% by weight, preferably 1% to 30% by weight, more preferably 5% to 25% by weight, better 10% to 20% by weight, relative to the total weight of the composition.

[0177] Preferably, the additional fatty compound(s), other than sunflower oil and fatty acids, are chosen from solid fatty alcohols, according to the embodiments herein, and are present in a total quantity of 0.5 to 40% by weight, preferably 1% to 30% by weight, more preferably 5% to 25% by weight, better 10% to 20% by weight relative to the total weight of the composition. Additives

[0178] The composition according to the present invention optionally comprises one or more additives, different from the compounds of the invention, and among which may be mentioned mineral thickening agents, non-ionic, anionic, cationic and amphoteric surfactants, sequestrants, solvents other than polyols, anti-dandruff agents, anti-seborrheic agents, agents to prevent hair loss and / or to promote hair regrowth, vitamins and provitamins, sunscreens, mineral or organic pigments, plasticizers, solubilizers, opacifiers or pearlescent agents, antioxidants, hydroxy acids, perfumes and preservatives.

[0179] Each of the additives, in various embodiments herein, may be present in an amount ranging from 0.01% to 20% by weight, relative to the total weight of the composition.

[0180] Solvents other than the polyols mentioned herein in the composition according to the present invention may include water and / or one or more organic solvents.

[0181] In one embodiment, the organic solvents are chosen from linear or branched and preferably saturated monoalcohols, comprising from 2 to 10 carbon atoms, such as ethanol, isopropanol, aromatic alcohols such as benzyl alcohol or phenylethyl alcohol, polyol ethers, for example ethylene glycol monomethyl, monoethyl or monobutyl ether, propylene glycol or its ethers, for example propylene glycol monomethyl ether, and also diethylene glycol alkyl ethers, in particular Ci-C4 alkyl ethers, for example diethylene glycol monoethyl ether or monobutyl ether, alone or in mixture.

[0182] Organic solvents, according to the embodiments here, when present, are in an amount ranging from 0.1% to 20% by weight, preferably ranging from 0.4% to 10% by weight, relative to the total weight of the composition.

[0183] The composition, according to the present invention, is preferably aqueous. In one embodiment, the water in the composition, according to the embodiments here, is in an amount from 30% to 99% by weight, preferably in an amount from 40% to 95% by weight, and more preferably in an amount from 50% to 90% by weight, relative to the total weight of the composition.

[0184] In one embodiment, the composition of the invention may include at least one oxidizing agent as disclosed below. According to this embodiment, the composition of the invention is a ready-to-use composition comprising at least one oxidizing agent.

[0185] In another embodiment, the composition of the invention is free of oxidizing agent. According to this embodiment, the composition is preferably mixed with a composition comprising at least one oxidizing agent as disclosed below immediately before use. Kit

[0186] The embodiments provided herein also include a kit comprising a composition (A) as described in the above embodiments comprising sunflower oil, at least one polyol, at least one cationic polysaccharide, at least one non-ionic associative polymer, and at least one oxidative dye and / or at least one alkali agent, and a composition (B) comprising at least one oxidizing agent, and optionally at least one nonionic polyoxyalkylated fatty alcohol ether. Compositions (A) and (B) are intended to be mixed together at the time of use to obtain a ready-to-use composition which is then applied to keratin fibers to dye and / or lighten the keratin fibers. Preferably, the pH of the ready-to-use composition is between 8 and 11, preferably between 9.0 and 10.5.

[0187] Compositions (A) and (B) may be in separate sachets or containers or in a single double-compartment sachet, optionally accompanied by one or more suitable applicators, which may be identical or different, such as fine brushes, coarse brushes, or sponges. The kit mentioned above may also be equipped with a means of distributing the desired mixture onto the hair, for example, the devices described in French patent FR 2586913. Oxidizing agent

[0188] Embeddings of composition (B) of the kit supplied herein include at least one oxidizing agent.

[0189] Oxidizing agents may be selected from hydrogen peroxide, urea peroxide, alkali metal bromates or ferricyanides, peroxygenated salts such as persulfates, perborates, peracids and / or their precursors, or alkali metal or alkaline earth metal percarbonates.

[0190] In one embodiment, the oxidizing agent is hydrogen peroxide.

[0191] The oxidizing agent(s), according to the embodiments herein, are in an amount ranging from 0.1% to 40% by weight, and preferably from 0.5% to 20% by weight, relative to the total weight of the composition.

[0192] Nonionic ether of a polyoxyalkylated fatty alcohol

[0193] Embodiments of composition (B) of the kit proposed herein include at least one nonionic ether of a polyoxyalkylated fatty alcohol. The nonionic ether of a polyoxyalkylated fatty alcohol, according to the embodiments herein, comprises at least one nonionic ether of a polyoxyalkylated fatty alcohol including those of formula (IV):

[0194] Rr(O-Alk)n-OR2

[0195] Formula (IV),

[0196] and / or their optical isomers and / or geometric isomers,

[0197] wherein, Ri denotes a linear or branched hydrocarbon-based radical, saturated or unsaturated with Cio-C3o; R2 denotes a linear or branched hydrocarbon-based radical, saturated or unsaturated with Cio-C3o, which may be substituted by a hydroxyl radical, preferably the hydroxyl being [3 on the ether function; n is an integer between 1 and 100 inclusive; and Alk represents a linear or branched (Ci-C6) alkylene group, preferably linear, such as ethylene or propylene, preferably ethylene.

[0198] In a particular embodiment, the Alk radical of formula (IV) represents the -CH2-CH2- group.

[0199] The nonionic ether of formula (IV) is such that Ri and R2, independently of each other, denote a linear or branched, preferably linear, saturated or unsaturated, preferably saturated, hydrocarbon-based radical in the form of Ci2-C2o and preferably in the form of CM-Ci8; R2 being optionally substituted by at least one hydroxyl radical and n denotes an integer greater than or equal to 20, for example from 20 to 100 and preferably from 40 to 80. Preferably, Ri and R2 denote an alkyl radical.

[0200] In some embodiments, the nonionic ether of formula (IV) is such that: Ri denotes a Ci6-Ci8 alkyl radical, which is preferably linear, and R2 denotes a CM alkyl radical, which is preferably linear, substituted by an OH group, and n is equal to 60.

[0201] In various embodiments, the nonionic ether of a polyoxy-alkylated fatty alcohol has the formula (V): OH

[0202] Formula (V)

[0203] in which R is a cetyl or stearyl group with n = 60.

[0204] Such nonionic ethers of a polyoxyalkylated fatty alcohol are known, for example, in the CTFA dictionary as Ceteareth 60 myristyl glycol or hydrogenated talloweth 60 myristyl glycol. Examples include commercially available ceteareth 60 myristyl glycol, such as those sold under the reference Elfacos GT 282 S by Akzo.

[0205] The non-ionic ether(s) of a polyoxyalkylated fatty alcohol, according to the embodiments herein, are present in an amount ranging from 0.001% to 5% by weight, and preferably from 0.01% to 1% by weight, relative to the total weight of the composition (B). Process

[0206] The composition of the present invention can be manufactured using known processes that are generally used in cosmetics or dermatology. Typically, the process for preparing the composition includes mixing sunflower oil, polyol, cationic polysaccharide, nonionic associative polymer, and oxidative dye and / or alkaline agent with a suitable solvent, and optionally with the additive to obtain the composition.

[0207] The embodiments herein also include methods for manufacturing composition (A) and composition (B) of the kit supplied herein. In one embodiment, the method for preparing composition (A) is according to the method described below. The process for preparing composition (A) comprises mixing sunflower oil, polyol, cationic polysaccharide, nonionic associative polymer, and oxidative dye, and optionally an alkali metal, with a suitable solvent, and optionally an additive to obtain composition (A). The process for preparing composition (B) comprises mixing an oxidizing agent and optionally a nonionic polyoxyalkylated fatty alcohol ether with a suitable solvent and optionally an additive to obtain composition (B).

[0208] The embodiments herein further include a method for dyeing keratin fibers. The method includes dyeing and / or lightening keratin fibers, in particular hair. In one embodiment, the method includes mixing composition (A) and composition (B) of the kit as supplied herein to obtain a mixture and applying the mixture to said fiber. In some embodiments, the mixture is left to stand for a processing time in the range of 5 to 45 minutes. In some embodiments, the mixture is left to stand for a processing time in the range of 5 to 15 minutes.

[0209] The temperature during the process is conventionally between ambient temperature (15 to 25 °C) and 80 °C and preferably between ambient temperature and 60 °C. Use

[0210] Embodiments herein include the use of the composition and / or kit of the present invention.

[0211] The composition and / or kit, according to the embodiments herein, can be used to dye and / or lighten or color keratin fibers, in particular hair. The composition can be used for the purposes of color changing, color lightening / bleaching hair and / or covering gray hair.

[0212] The composition and / or kit can be used on natural hair and / or artificial hair, including hair extensions.

[0213] The composition and / or kit can be used at different temperatures, including conventionally at room temperature (between 15 °C and 25 °C) and 80 °C and preferably between room temperature and 60 °C.

[0214] Although the subject has been described in great detail with reference to certain examples and implementations thereof, it is understood that other implementations are possible and included within the scope of the present invention. EXAMPLES

[0215] Disclosure will now be illustrated by practical examples, which are intended to illustrate how disclosure works and are not intended to impose in a way Restrictive limitations on the scope of this disclosure apply. Unless otherwise defined, all technical and scientific terms used in this document have the same meaning as that commonly understood by a person skilled in the art of making this disclosure. Although processes and materials similar or equivalent to those described herein may be used in the practice of the disclosed processes and compositions, examples of such processes, devices, and materials are described herein. It should be understood that this disclosure is not limited to the particular processes and experimental conditions described, as these processes and conditions may be applicable. Example 1

[0216] Composition for dyeing and / or lightening keratin fibres

[0217] Composition A (according to the present invention) for dyeing and / or lightening keratin fibers was prepared using 6% by weight of Helianthus Annuus (sunflower) seed oil, polyol i.e. 5% by weight of propylene glycol, cationic polysaccharide i.e. 0.5% by weight of hydroxypropyltrimonium guar chloride, non-ionic associative polymer i.e. 0.05% by weight of cetyl hydroxyethylcellulose, 0.24% by weight of chelator i.e. tetrasodium glutamate diacetate, oxidative dyes, i.e. p-aminophenol, 2-amino-3-hydroxypyridine, hydroxybenzomorpholine, N,N-bis(2-hydroxyethyl)-p-phenylenediamine sulfate, m-aminophenol, 2,4-Diaminophenoxyethanol HCl, hydroxyethyl-3,4-methylenedioxyaniline HCl, toluene-2,5-diamine, surfactants i.e. 1.50% by weight of laureth-12, 3% by weight of laureth-4, 1.50% by weight of oleth-20 and 2.40% by weight of polysorbate 21,of fatty compounds, i.e. 17% by weight of cetearyl alcohol, of alkali agents, i.e. 7.83% by weight of ethanolamine, of fatty acids, i.e. 0.32% by weight of stearic acid, 0.02% by weight of myristic acid, 0.26% by weight of palmitic acid, of reducing agent / antioxidant, i.e. 0.25% by weight of ascorbic acid, 0.75% by weight of sodium metabisulfite, and water (up to 100% by weight).

[0218] The sunflower seed oil used in the composition, according to the embodiments herein, was commercially purchased from Europe ADM Speciality Oil and Fats (Société Industrielle des Oléagineux).

[0219] Composition A1 (comparative), composition A2 (comparative), composition A3 (comparative) and composition A4 (comparative) were prepared in the same way as composition A, however, sunflower oil was replaced by coconut oil in composition A1, rapeseed oil in composition A2 and caprylic / capric triglyceride in composition A3. Composition A4 was prepared without the addition of natural or synthetic oils.

[0220] The coconut oil used in composition Al was purchased commercially Primarily from Cargill under the name Agripure AP-20 MB in Europe. Rapeseed oil of composition A2 was commercially purchased from Gustav Heess under the name Rapeseed Oil Refined Solvent Extracted PH. Eur in Europe.

[0221] Table 1 below provides the ingredients used to prepare composition A (according to the present invention) and the comparative compositions A1, A2, A3 and A4, expressed as % by weight:

[0222] [Table 1] Table 1 Ingredient No. (INCI) Composition A Al A2 A3 A4 1 Ethanolamine 7.83 7.83 7.83 7.83 6.33 2 Ascorbic acid 0.25 0.25 0.25 0.25 0.25 3 Tetrasodium glutamate diacetate 0.24 0.24 0.24 0.24 0.24 4 Myristic acid 0.02 0.02 0.02 0.02 0.02 5 Palmitic acid 0.26 0.26 0.26 0.26 0.26 6 Stearic acid 0.32 0.32 0.32 0.32 0.32 7 Propylene glycol 5.00 5.00 5.00 5.00 5.00 8 Guar chloride hydroxypropyltrimonium 0.5 0.5 0.5 0.5 0.5 9 Cetearyl alcohol 17.00 17.00 17.00 17.00 17.00 10 Laureth-12 1.50 1.50 1.50 1.50 1.50 11 Laureth-4 3.00 3.00 3.00 3.00 3.00 12 Oleth-20 1.50 1.50 1.50 1.50 1.50 1.50 13 Polysorbate 21 2.40 2.40 2.40 2.40 2.40 14 Cetylhydroxyethylcellulose 0.05 0.05 0.05 0.05 0.05 15 Grain oil (sunflower) Helianthus annuus 6.00 - - - - 16 Coconut oil - 6.00 - - - 17 Rapeseed oil - - 6.00 - - 18 Caprylic / capric triglyceride - - - 6.00 - 19 Sodium metabisulfite 0.75 0.75 0.75 0.75 0.75 20 p-Aminophenol 0.08 0.08 0.08 0.08 0.08 21 2-Amino-3-Hydroxypyridine 0.07 0.07 0.07 0.07 0.07 22 Hydroxybenzomorpholine 0.68 0.68 0.68 0.68 0.68 23 N,N-bis(2-hydroxyethyl)-p-phenylenediamine sulfate 0.23 0.23 0.23 0.23 0.23 24 2,4-Diaminophenoxyethano 1HCl 0.02 0.02 0.02 0.02 0.02 25 Hydroxyethyl-3,4-methylenedioxyaniline HCl 0.32 0.32 0.32 0.32 0.32 26 m-aminophenol 0.26 0.26 0.26 0.26 0.26 27 Toluene-2,5-diamine 0.89 0.89 0.89 0.89 0.89 28 Water qs 100 qs 100 qs 100 qs 100 qs 100

[0223] Oxidizing composition B was prepared from the ingredients whose content is indicated in Table 2 below, expressed as % by weight:

[0224] [Table 2] Table 2 Ingredients Composition B Stabilizing and chelating agents qs Hydrogen peroxide 6.00 Cetearyl alcohol 2.28 Ceteareth-25 0.57 Trideceth-2 carboxamide MEA 0.85 Glycerol 0.50 Phosphoric acid qs pH 2.2 Water qs 100

[0225] Example 2: Stability assessment

[0226] Each of the compositions A (according to the present invention) and the comparative compositions A1, A2 and A3 was stored for 2 months at 4°C, room temperature (or ambient temperature), 37°C and 45°C.

[0227] The amount of oil retained in each composition was measured by HPLC-CAD method (HPLC with charged aerosol detection).

[0228] Results: The results of the stability of the oils after storage at different temperatures for 2 months in composition A and the comparative compositions A1, A2 and A3 are provided in Table 3 below, in which the percentages of oil retained in the compositions are indicated. Composition A, comprising sunflower oil, was the most stable at all temperatures; in particular, at a high storage temperature of 45 °C, 86.27% of the sunflower oil was stable, i.e., it was preserved in its original state, compared to only 37.50% for rapeseed oil in composition A2, for example.

[0229] [Table 3]Table 3 Stability of sunflower oil in Composition A; Stability of coconut oil in Composition A1; Stability of rapeseed oil in Composition A2; Stability of caprylic / capric triglyceride in Composition A3: 2 months at 4°C: 97.27%, 93.71%, 86.80%, 90.05%; 2 months at room temperature: 92.45%, 89.15%, 84.71%, 86.99%; 2 months at 37°C: 89.96%, 77.95%, 38.31%, 68.89%; 2 months at 45°C: 86.27%, 79.59%, 37.50%, 65.49%

[0230] Furthermore, no rancid odor was observed for the compositions after 2 months at all temperatures.

[0231] Furthermore, the assessment of the physical characteristics of the compositions determined that a color change was observed in the comparative composition A2 comprising rapeseed oil, whereas no color change was observed in composition A of the present invention.

[0232] The results have therefore demonstrated that the specific combination of ingredients in composition A (according to the present invention) works in synergy and reduces the hydrolysis of sunflower oil, confers stability and thus provides the composition with a long shelf life even when stored at high temperatures.

[0233] Example 3: Evaluation of slip in the wet state

[0234] The expression "wet glide", as used here, refers to the ease with which a comb moves through keratin fibers, particularly hair, after the application of a composition or product to keratin fibers, in particular a dyeing and / or lightening composition for keratin fibers, in particular human hair, as disclosed herein.

[0235] The ease of movement of the comb in the keratin fibers was measured in terms of force (Fmax) in Newtons (N) required for the comb to move in the keratin fibers, for example, the greater the ease of movement of the comb through the keratin fibers, the lower the Fmax, which indicates a higher level of revitalization and smoothing of the keratin fibers.

[0236] Compositions A (according to the present invention) and A4 (comparative) were each independently mixed with oxidizing composition B in a weight ratio of 1 / 1.

[0237] Each of the mixtures was applied to natural human hair, in a proportion of 5 g of mixture to 1 g of hair, 27 cm long. After a processing time of 35 minutes, the hair was rinsed. This was repeated twice, i.e., the mixtures were applied, left on for 35 minutes, and rinsed three times.

[0238] For each of the compositions, wet slip was measured using a slip bench instrument.

[0239] Results: As shown in Table 4 below, composition A, comprising 6% sunflower oil, as proposed herein, showed the best wet glide as it demonstrated the least resistance to slippage, while composition A4, which was without sunflower oil, demonstrated the least wet glide as the force required for wet glide (Fmax) on composition A4 was significantly higher than that required for composition A. The results indicated that the compositions according to the present invention, comprising sunflower oil, demonstrated the best wet glide performance, thus providing a more nourishing and revitalizing effect on the hair.

[0240] [Table 4] Table 4 Wet slip resistance Compositions A A4 Fmax (N) 0.72 0.96 BENEFITS OF THIS DISCLOSURE

[0241] The composition of the present invention provides improved wet glide and hair nourishment. In particular, the composition of the present invention includes sunflower oil, which contributes to the superior properties of a smoother and more even feel on the hair, as well as improved shine and re- It repairs damaged hair without leaving a perceived greasy feeling. Furthermore, the composition of the present invention is stable, particularly at higher temperatures. The composition also achieves long-lasting color and improved cosmetic appeal.

Claims

Demands

1. Composition comprising: sunflower oil; at least one polyol; at least one cationic polysaccharide; at least one non-ionic associative polymer; and at least one oxidative dye and / or at least one alkali agent.

2. Composition according to claim 1, wherein sunflower oil is in an amount from 0.1% to 20% by weight, preferably from 0.5% to 15% by weight, more preferably from 1% to 12% by weight, better from 2% to 10%, and even better from 3% to 8% by weight, relative to the total weight of the composition.

3. Composition according to claim 1, wherein the polyol is selected from diols, preferably from C3-C6 diols, and more preferably is propylene glycol.

4. Composition according to any one of the preceding claims, wherein the polyol(s) are in a total amount from 0.5% to 15% by weight, preferably from 1% to 10% by weight, and more preferably from 2% to 8% by weight, relative to the total weight of the composition.

5. Composition according to any one of the preceding claims, wherein the cationic polysaccharide is selected from cationic cellulose derivatives, cationic galactomannan gums, or combinations thereof, preferably from cationic cellulose derivatives comprising quaternary ammonium groups, cationic galactomannan gums comprising cationic trialkylammonium groups, or combinations thereof, more preferably from cationic galactomannan gums comprising cationic trialkylammonium groups, and better from guar gums comprising cationic trialkylammonium groups.

6. Composition according to any one of the preceding claims, wherein the cationic polysaccharide(s) are in a total amount from 0.01% to 8% by weight, preferably from 0.05% to 5% by weight, more preferably from 0.1% to 4%, and better from 0.2% to 3% by weight of the total weight of the composition.

7. A composition according to any one of the preceding claims, wherein the alkali agent is selected from alkanolamines, ammonium hydroxide, metal carbonates, metal bicarbonates, alkali metal silicates, alkaline earth metal silicates, alkali metal metasilicates, alkaline earth metal metasilicates, or combinations thereof, preferably among the alkanolamines, ammonium hydroxide or their combinations, more preferably among the alkanolamines, and best is monoethano-nolamine.

8. Composition according to any one of the preceding claims, wherein the nonionic associative polymer is selected from celluloses modified by groups comprising at least one fatty chain, preferably from hydroxyethylcelluloses modified by groups comprising at least one fatty chain, and more preferably is cetylhydroxyethylcellulose.

9. Composition according to any one of the preceding claims, wherein the non-ionic associative polymer(s) are in a total amount from 0.005% to 5% by weight, and preferably from 0.01% to 2% by weight, relative to the total weight of the composition.

10. Kit comprising: (a) a composition (A) as claimed in any of the preceding claims; and (b) a composition (B) comprising at least one oxidizing agent; and optionally at least one nonionic polyoxy-alkylated fatty alcohol ether, the mixture of composition (A) and composition (B) resulting in a ready-to-use composition.