ENVIRONMENTALLY FRIENDLY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE

Abstract

ENVIRONMENTALLY FRIENDLY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE This disclosure relates to environmentally friendly compositions including 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: bis-ethylhexyloxyphenol methoxyphenyl triazine) and an environmentally friendly carrier, as well as processes for manufacturing and using such compositions. Figure for the abstract: none

Description

Title of the invention: ENVIRONMENTALLY FRIENDLY COMPOSITIONS CONTAINING BIS- ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE FIELD OF INVENTION

[0001] This disclosure relates to environmentally friendly compositions comprising 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: bis-ethylhexyloxyphenol me-thoxyphenyl triazine) and an environmentally friendly vector, as well as processes for manufacturing and using such compositions. DISCUSSION OF THE CONTEXT

[0002] Many cosmetic compositions contain ingredients of animal origin or natural beeswax to achieve a desired texture or properties. Due to growing concerns about how these ingredients are obtained, many consumers prefer to avoid cosmetics containing such ingredients, opting instead for products that do not rely on them.

[0003] Similarly, many customers prefer to avoid cosmetics containing non-biodegradable ingredients such as microplastics because of the potential environmental effects that such ingredients may have.

[0004] However, without these ingredients, it may be difficult to obtain a desired texture for cosmetic compositions containing UV filters, or it may be difficult to obtain other desirable properties such as, for example, improved application properties in such compositions, particularly in compositions containing bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0005] Radiation with wavelengths between 290 nm and 400 nm allows the human epidermis to tan, while radiation with wavelengths between 290 and 320 nm, called UVB rays, hinders the development of a natural tan. Exposure is also likely to cause a detrimental alteration of the biomechanical properties of the epidermis, resulting in the appearance of wrinkles leading to premature skin aging (i.e., photoaging).

[0006] UVA rays with a wavelength between 320 and 400 nm penetrate the skin more deeply than UVB rays. UVA rays cause immediate and persistent tanning of the skin. Daily exposure to UVA rays, even for a short period, under normal conditions, can cause this. damaging collagen and elastin fibers, resulting in a change in the skin's microrelief, the appearance of wrinkles and uneven pigmentation (spots, lack of uniformity of complexion).

[0007] Numerous studies show the need for effective protection against UVA and UVB to prevent sunburn, photoaging, and the like.

[0008] In order to obtain a high protection product, it is generally necessary to combine a large number of sunscreens and / or a large quantity of UV filters to achieve high levels of filtration efficiency.

[0009] However, high levels of UV filters do not in themselves lend themselves to the easy development of stable environmentally friendly compositions having a pleasant texture.

[0010] There remains a need in art for improved environmentally friendly compositions which have organic UV filters and have pleasant application properties (e.g. a non-greasy feel) and UV protection properties.

[0011] Therefore, one aspect of this disclosure relates to environmentally friendly compositions which have organic UV filters and pleasant application properties (e.g., a non-greasy feel) and UV protection properties. Summary of the invention

[0012] This disclosure relates to environmentally friendly compositions comprising bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT or bemo-trizinol) and an environmentally friendly carrier. Preferably, the compositions contain minimal amounts of ingredients of animal origin and / or microplastics, or are free of such ingredients.

[0013] This disclosure also relates to processes for the treatment, care, protection, enhancement of appearance and / or makeup of keratinous material, including the application of compositions of this disclosure to keratinous material in sufficient quantity to treat the keratinous material, care for it, enhance its appearance and / or make it up.

[0014] This disclosure also relates to processes for manufacturing environmentally friendly compositions comprising the combination of bis-ethylhexyloxyphenol methoxyphenyl triazine and ingredient(s) that form an environmentally friendly carrier during the formation of the compositions. Preferably, the compositions contain minimal amounts of ingredients of animal origin and / or microplastics, or are free of such ingredients.

[0015] It must be understood that both the preceding general description and the des The detailed description that follows is only exemplary and explanatory and does not limit disclosure. DETAILED DESCRIPTION OF THE INVENTION

[0016] In the following description and the claims annexed thereto, it shall be understood that the terms used have their ordinary and usual meanings in the art, unless otherwise specified.

[0017] “Approximately” as used here means to within 10% of the number indicated (for example "approximately 10%" means from 9% to 11% and "approximately 2%" means from 1.8% to 2.2%.

[0018] “A” or “an” as used here means “at least one”

[0019] “At least one” means one or more and thus includes components in individual products as well as mixtures / combinations.

[0020] As used herein, all proposed ranges are intended to include each specific point and range within the given ranges, as well as combinations of intermediate sub-ranges. Thus, a range from 1 to 5 specifically includes the integers within the range 1, 2, 3, 4, and 5, as well as sub-ranges such as 2 to 5, 3 to 5, 2 to 3, 2 to 4, 1 to 4, etc., and all fractional numbers within the range such as 1, 2, 2, 3, 3, 4, etc., and sub-ranges including such fractional numbers, such as 1.5 to 3.8, 2 to 4.3, 4.2 to 4.9, etc.

[0021] “Film-forming”, “film-forming polymer” or “film-forming agent” as used herein means a polymer or resin that is capable of leaving a film on the substrate to which it is applied, for example, after a solvent accompanying the film-forming agent has evaporated, been absorbed into the substrate and / or dissipated on it.

[0022] “Substitute” as used herein means comprising at least one substitute. Non-limiting examples of substituents include atoms, such as hydrogen or chlorine atoms, as well as functional groups, such as hydroxyl groups, ether groups, alkoxy groups, acyloxyalkyl groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide groups, halogen-containing groups, ester groups, thiol groups, sulfonate groups, thiosulfate groups, siloxane groups, and polysiloxane groups. The substituent(s) may also be substituted.

[0023] “Volatile”, as used here, means having a flash point less than about 115 °C.

[0024] “Non-volatile”, as used here, means having a flash point greater than approximately 115 °C.

[0025] “Polymer” as used herein means a compound that is made up of at least two monomers.

[0026] “Exempt” or “substantially exempt” or “devoid of” as used herein This means that although it is preferable for no quantity of the specific component to be present in the composition, it is possible for very small quantities of it to be present in the compositions of the disclosure, provided that these quantities do not materially affect at least one, preferably most, of the advantageous properties of the compositions of the disclosure. Thus, for example, "microplastic-free" means that an effective quantity (i.e., greater than trace amounts) of microplastic(s) is omitted from the composition (i.e., about 0% by weight), "substantially free of microplastics" means that one or more microplastics are present in quantities not exceeding 0.1% by weight, and "microplastic-free" means that one or more microplastics are present in quantities not exceeding 0.25% by weight, based on the total weight of the composition.The same nomenclature applies to all other ingredients identified throughout the application and in this paragraph, such as, for example, specific UV filters and / or surfactants (the compositions in the disclosure that are "free of oxybenzone and / or octinoxate," "substantially free of oxybenzone and / or octinoxate," and "devoid of oxybenzone and / or octinoxate," as well as "free of surfactants," "substantially free of surfactants," and "devoid of surfactants" have meanings consistent with the discussion in this paragraph), even if they are not specifically mentioned for each identified ingredient. The examples of the use of such language, such as those in this paragraph, are intended to be provided by way of example, not limitation.

[0027] “UV filters” as used herein means the active protective agents sunscreens approved by a government regulatory agency such as the Food and Drug Administration (FDA) in the United States or the European Commission in Europe and include organic UV filters such as avobenzone, octocrylene, benzophenones, benzotriazoles and merocyanines, as well as mineral UV filters such as iron oxide, zinc oxide (ZnO) and titanium dioxide (TiO2).

[0028] “Anhydrous” as used here means that the compositions of the disclosure contain less than 3% water, which means that compositions may also contain less than 2% water, and less than 1% water, as well as being "water-free", "substantially water-free" and "water-free" as defined above.

[0029] "Keratinous materials" means nails (fingernails and / or toenails), skin such as that of the body, face and around the eyes, scalp, keratinous fibers such as eyelashes, eyebrows and hair, and mucous membranes such as lips.

[0030] “Physiologically acceptable” means compatible with keratinous materials and having a pleasant color, smell and feel, and which does not cause unacceptable discomfort (tingling or pulling) likely to discourage a consumer from using the composition.

[0031] “Environmentally friendly vector” means the ingredients of a com Cosmetic ingredients other than active agents, colorants, and / or UV filters that are "environmentally friendly." "Environmentally friendly" means that the ingredients in the carrier are not resistant to biodegradation and / or are renewable. Preferably, "environmentally friendly" ingredients are not derived from animals. "Environmentally friendly carrier" means that the composition contains less than 3%, less than 2%, and less than 1% of non-environmentally friendly ingredients, and also that it is "free from non-environmentally friendly ingredients," "substantially free from non-environmentally friendly ingredients," and "devoid of non-environmentally friendly ingredients," as defined above.

[0032] “UV protection efficiency” or “filtration efficiency” in the context of the this disclosure is evaluated from one or more elements among FPS, FPUVA, critical wavelength and UVA-I / UV ratio.

[0033] The "SPF" (Sun Protection Factor) measures the level of protection against erythema provided by a composition. The SPF value corresponds to the ratio between the minimum erythematous dose (MED) measured on skin covered with the composition and the MED measured on bare skin. The term "SPF" is known in the art of sunscreens and is defined, for example, in "A new substrate to measure sunscreen protection factors throughout the ultraviolet spectrum," J. Soc. Cosmet. Chem., 40, 127-133 (May / June 1989).

[0034] The evaluation of the SPF (Sun Protection Factor) can be carried out, for example, in vitro with a spectrophotometer from Labsphere (North Sutton, NH, USA). In such an evaluation, the plate is the material onto which the composition under test is applied. For such an evaluation, polymethyl methacrylate (PMMA) plates can be used. An example of an acceptable protocol is currently undergoing ISO accreditation under the name ISO Committee Draft 23675.

[0035] The evaluation of the sun protection factor (SPF) can also be performed in vivo in accordance with ISO 24444:2019 “Cosmetics-Sun protection test methods-In-vivo determination of the sun protection factor (SPF).” It can also be determined in accordance with FDA protocols, as described in the document “Labeling and Effectiveness Testing; Sunscreen Drug Products for Over-the-Counter Human Use” published in the US Federal Register on 07 / 05 / 2011. (https: / / www.federalregister.gov / d / 2011-14766); 21 CFR Part 352 Subpart D § 352.72, updated and revised by the 2011 publication in the Federal Register.

[0036] “UVA protection factor” refers to a characteristic index assessing the UVA protection provided by a composition. For example, the UVA protection factor (UPPF) can be measured in vivo according to the "PPD" (Persistent Pigment Darkening) method of the ISO-24442:2022 protocol, measuring the skin color observed 2 to 4 hours after UVA exposure. It can also be determined according to FDA protocols, as described again in 21 CFR Part 352 Subpart D § 352.72 as mentioned above in relation to SPF.

[0037] UVA protection can also be assessed in vitro using the Labsphere® spectrophotometer under conditions such as those mentioned above in relation to the SPF. ISO 24443:2021 describes such an in vitro procedure.

[0038] FDA broad-spectrum test procedures, particularly "critical wavelength" test procedures, are also available in 21 CFR Part 352 Subpart D § 352.72. In addition, broad-spectrum test procedures include the determination of the UVA1 / UV ratio as described in "Sunscreen Drug Products for Over-the-Counter-Human-Use" published in the Federal Register https: / / www.federalregister.gov / documents / 2019 / 02 / 26 / 2019-03019 / sunscreen-drug-products-for-over-the-counter-human-use. "In the assay described in the monograph, known as the Boots adaptation of the Diffey / Robson test method, a ratio is generated between the protection offered by the sunscreen product against UVA1 (340-400 nm) and the protection against total UV radiation (UVB and UVA at 290-400 nm) calculated from the absorbance curve. This UVA1 / UV ratio would represent the product's score in the in vitro test."

[0039] According to this disclosure, the compositions in this disclosure preferably have one or more of the following properties:

[0040] The compositions have a critical wavelength as determined by FDA critical wavelength procedures of at least 370 nm;

[0041] The compositions have an FPS value of at least 15, preferably at least 30, preferably at least 50 and preferably at least 70;

[0042] The compositions have an FPUVA / FPS ratio of at least 1 / 3, and preferably of at least 2 / 5 and / or

[0043] The compositions have a UVA1 / UV ratio of 0.7 or more, preferably 0.75 or more, and preferably 0.8 or more.

[0044] The "makeup result" as used herein refers to the visual impact of a composition when applied to a keratinous material such as skin. Makeup result may relate to the apparent color of the product after application to keratinous material or an optical effect such as shine, blurring of fine lines and imperfections, or a concealing effect on pores or skin defects after application of the product to keratinous material.

[0045] "Longevity," as used here, refers to compositions where the color or other apparent properties remain the same or substantially the same as at the time of application, as seen with the naked eye, after a prolonged period or after a particular stress event such as immersion in water or rubbing. "Longevity" can be assessed by evaluating the longevity properties using any method known in the art for evaluating such properties. For example, longevity can be assessed by a test involving the application of a composition to a keratinous material such as skin and evaluating the color of the composition after a prolonged period. For example, the color of a composition can be evaluated immediately after application to a keratinous material such as skin, and these characteristics can then be re-evaluated and compared after a certain time.Furthermore, these characteristics can be evaluated against other compositions, such as commercially available ones. "Longevity" can also be assessed using in vitro processes on non-keratinous substrates such as polymethyl methacrylate (PMMA), in which properties such as color, transparency, or in vitro FPS can be evaluated before and after a period or stress factor such as immersion in water, incubation at high temperatures, or the application of an abrasive technique.

[0046] “Natural” as in the expression “natural compound” means any compound derived directly from a natural substance such as a plant without having undergone chemical modification.

[0047] “Compound of natural origin” means any compound derived from a natural compound which has undergone one or more chemical modifications, for example by organic synthesis reaction, without the properties of the natural compound having been modified.

[0048] “Synthetic compound” means any compound that is neither a natural compound nor a composed of natural origin.

[0049] “Room temperature” means approximately 20 to 25 °C.

[0050] “Atmospheric pressure” means approximately 760 mmHg, i.e. approximately 105 pascals.

[0051] “UV filter” and “sunscreen agent” are used interchangeably in the present request.

[0052] The expressions "effectiveness against UV", "UV protection" and "UV effectiveness" are used interchangeably in this application.

[0053] The compositions and processes of this disclosure may include, consist of, or essentially consist of, the essential elements and limitations of the disclosure described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful. For example, the UV (ultraviolet) absorbing system of the compositions in the disclosure may "consist essentially of" bis-ethylhexyloxyphenol methoxyphenyl triazine and one or more additional organic UV filters identified herein.

[0054] For the purposes of this disclosure, the "fundamental novel property" associated with the compositions, components and processes that "consist essentially of" identified ingredients or actions is "environmental friendliness".

[0055] The compositions of this disclosure may be in any form suitable for use as a personal care composition, such as a stick, paste, cream, anhydrous composition, emulsion (oil-in-water, water-in-oil, multiple emulsion such as oil-in-water-in-oil), nanoemulsion, gel, liquid, solid, etc. These compositions may be used for any personal care purpose in cosmetic and / or dermatological products such as, for example, sunscreen, foundation, lip balms, lipsticks, concealers, mascaras, leave-in hair products, eyeshadows, powders, etc.

[0056] Reference is made herein to trade names of materials including, but not limited to, materials such as polymers and optional components. Materials are not intended to be limited by the materials described and referenced herein by a particular trade name. Equivalent materials (for example, those obtained from a different source under a different name or catalogue (reference) number) to those referenced by a trade name may be substituted for and used in the processes described and claimed herein.

[0057] Unless otherwise stated, all percentages and ratios are calculated by weight. Unless otherwise stated, all percentages are calculated on the basis of the total weight of a composition. All component or composition levels refer to the active level of that component or composition and are understood to exclude impurities, for example, residual solvents or by-products, which may be present in commercially available sources.

[0058] All US patents or patent applications disclosed herein are expressly incorporated by reference in their entirety. Composition

[0059] Bis-ethylhexyloxyphenol methoxyphenyl triazine

[0060] According to this disclosure, compositions comprising a UV (ultraviolet) absorbing system comprising 4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (name INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) are offered.

[0061] According to preferred embodiments, the UV-absorbing system comprises at least 5% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 15% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 20% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 30% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 40% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 50% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 70% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 80% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, and preferably at least 90% by weight of the bis-ethylhexyloxyphenol methoxyphenyl triazine, all weights being based on the total weight of the UV-absorbing system.The "UV absorbing system" contains all the organic and / or mineral UV filters present in the composition.

[0062] According to preferred embodiments, bis-ethylhexyloxyphenol methoxyphenyl triazine is present in compositions of the present disclosure in an effective UV absorption amount such as about 0.1% to about 10% by weight relative to the total weight of the composition, about 1% to about 10% by weight, about 2.5% to about 8%, and about 4% to about 6% by weight, including all intermediate ranges and sub-ranges such as, for example, about 4.5% to about 10% by weight, and about 1% to about 8% by weight, about 1% to about 6% by weight, about 5.5% to about 8% by weight, about 5.7% to about 9% by weight, etc., all weights being based on the total weight of the composition. Additional sunscreen agents

[0063] According to preferred embodiments of this disclosure, compositions optionally further comprising at least one additional UV filter (in addition to bis-ethylhexyloxyphenol methoxyphenyl triazine) selected from the group consisting of organic UV filters and mineral UV filters such as zinc oxides, cerium oxides, titanium oxides, and mixtures thereof are proposed. Preferably, the at least one mineral UV filter is coated, for example, with a silicone-based coating. An example of such a silicone-based coating is hydrogen dimethicone, an exemplary product being hydrogen dimethicone-coated zinc oxide such as ZNO-C-DMC2, available from Kobo Products. Passivated mineral UV filters, such as passivated zinc oxide, are suitable for use in the compositions of this disclosure.

[0064] The additional organic UV filter(s) may be hydrophilic or lipophilic. “Hydrophilic organic UV filter” means an organic UV filter water-soluble or a water-dispersible organic UV filter (in colloidal form). "Lipophilic organic UV filter" refers to a UV filter that is dissolved or dispersed in colloidal form in a liquid oil phase.

[0065] Suitable organic UV filters may be selected from the following non-exhaustive list of compounds: cinnamic compounds; anthranilate compounds; para-aminobenzoic acid compounds; salicylic compounds; dibenzoylmethane compounds; camphor compounds; benzophenone compounds; [3,[3-diphenylacrylate] compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; benzalmalonate compounds, including those cited in US patent 5,624,663; benzimidazole derivatives; imidazoline compounds; bis-benzoazolyl compounds as described in patents EP669323 and US 2,463,264; the compounds methylene bis(hydroxyphenylbenzotriazole) as described in applications US 5 237 071, US 5 166 355, GB2303549, DE197 26 184 and EP893119; the compounds benzoxazole as described in patent applications EP0832642, EP1027883, EP1300137 and DE10162844;Polymer filters and silicone filters such as those described in particular in application WO 93 / 04665; alkylstyrene-derived dimers such as those described in patent application DE19855649; 4,4-diarylbutadiene compounds such as those described in applications EP0967200, DE19746654, DE19755649, EP-A-1008586, EPI 133980 and EP133981, and mixtures thereof. Preferably, lipophilic organic UV filters are selected from salicylic compounds, dibenzoylmethane compounds, benzylidene camphor compounds; benzophenone compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; as well as other categories of compounds identified herein; and mixtures thereof.

[0066] Specific reference may be made to suitable salicylate compounds including Homosalate (homomentyl salicylate), for example marketed under the brand name "Eusolex HMS" by Rona / EM Industries; and ethylhexyl salicylate, for example marketed under the brand name "Neo Heliopan OS" by Symrise; and glycol salicylate. Other examples of salicylate compounds include phenyl salicylate; dipropylene glycol salicylate, for example marketed under the brand name "Dipsal" by Scher; and TEA salicylate, for example marketed under the brand name "Neo Heliopan TS" by Symrise.

[0067] Examples of suitable [3,[3-diphenylacrylate compounds include Octocrylene, for example marketed under the brand name "Uvinul N539" by BASF; and Etocrylene, for example marketed under the brand name "Uvinul N35" by BASF.

[0068] Suitable anthranilic compounds may include methyl anthranilates, marketed for example under the brand name "Neo Heliopan MA" by Symrise.

[0069] Examples of dibenzoylmethane compounds include butyl methoxydiben-zoylmethane, for example marketed under the brand name "Parsol 1789" by DSM; and isopropyl dibenzoylmethane.

[0070] Suitable cinnamyl compounds include ethylhexyl methoxycinnamate, marketed for example under the brand name "Parsol MCX" by DSM; isopropyl methoxycinnamate; isopropoxyl methoxycinnamate; isoamyl methoxycinnamate, marketed for example under the brand name "Neo Heliopan E 1000" by Symrise; cinoxate (2-ethoxyethyl-4-methoxycinnamate); DEA methoxycinnamate; diisopropyl methylcinnamate; and glyceryl dimethoxycinnamate ethylhexanoate.

[0071] Examples of camphor compounds include benzylidenecamphor derivatives: 3-benzylidenecamphor, for example marketed under the brand name "Mexoryl SD" by Chimex; 4-methylbenzylidenecamphor, for example marketed under the brand name "Eusolex 6300" by Merck; benzylidenecamphor sulfonic acid, for example marketed under the brand name "Mexoryl SL" by Noveal; benzalconium camphor methosulfate, for example marketed under the brand name "Mexoryl SO" by Noveal; dicamphor sulfonic acid terephthalylidene, for example marketed under the brand name "Mexoryl SX" by Noveal; and polyacrylamidomethylbenzylidenecamphor, for example marketed under the brand name "Mexoryl SW" by Noveal.

[0072] Suitable benzophenone compounds include benzophenone-1 (2,4-dihydroxybenzophenone), such as that marketed under the brand name "Uvinul 400" by BASF; benzophenone-2 (tetrahydroxybenzophenone), such as that marketed under the brand name "Uvinul D50" by BASF; benzophenone-3 (2-hydroxy-4-methoxybenzophenone) or oxybenzone, such as that marketed under the brand name "Uvinul M40" by BASF; benzophenone-4 (hydroxymethoxybenzophonene sulfonic acid), such as that marketed under the brand name "Uvinul MS40" by BASF; benzophenone-5 (sodium hydroxymethoxybenzophenone sulfonate); benzophenone-6 (dihydroxy dimethoxy benzophenone), such as that marketed under the brand name "Helisorb 11" by Norquay; benzophenone-8, such as that marketed under the brand name "Spectra-Sorb UV-24" by American Cyanamid;benzophenone-9 (disodium dihydroxy dimethoxy benzophenonedisulfonate), such as that marketed under the brand name "Uvinul DS-49" by BASF; and benzophenone-12, and n-hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (such as that marketed under the brand name "UVINUL A+" by BASF).

[0073] Examples of triazine compounds include diethylhexyl butamido triazone, such that marketed under the brand name "Uvasorb HEB" by the company Sigma 3V; 2,4,6-tris(dineopentyl 4'-aminobenzalmalonate)-s-triazine, bis-ethylhexyloxyphenol methoxyphenyl triazine, such as that marketed under the brand name “TINOSORB S” by BASF and ethylhexyl triazone, such as that marketed under the brand name “UVTNUL T150” by BASF.

[0074] Suitable benzotriazole compounds include phenylbenzotriazole derivatives: 2-(2H-benzotriazole-2-yl)-6-dodecyl-4-methylpheno, branched and linear, and those described in USP 5240975.

[0075] Suitable benzalmalonate compounds include dineopentyl 4'-methoxybenzalmalonate and polyorganosiloxane comprising benzalmalonate functional groups, such as polysilicone-15, such as that marketed under the brand name "Parsol SLX" by Hoffmann-LaRoche.

[0076] Examples of benzimidazole compounds include, in particular, phenylbenzimidazole derivatives such as phenylbenzimidazole sulfonic acid, such as that marketed, in particular, under the brand name "Eusolex 232" by Merck, and phenyl dibenzimidazole tetrasulfonate disodium, such as that marketed under the brand name "Neo Heliopan AP" by Symrise.

[0077] Suitable imidazoline compounds include ethylhexyl dimethoxybenzylidene propionate dioxoimidazoline.

[0078] Examples of bis-benzoazolyl compounds include the compounds described in EP-669 323 and US patent no. 2 463 264.

[0079] Suitable para-aminobenzoic acid compounds include PABA (p-aminobenzoic acid), ethyl PABA, ethyl dihydroxypropyl PABA, pentyl dimethyl PABA, ethylhexyl dimethyl PABA, such as that marketed under the brand name "Escalol 507" by ISP, glyceryl PABA, and PEG-25 PABA, such as that marketed under the brand name "Uvinul P25" by BASF.

[0080] Suitable methylene bis-(hydroxyphenylbenzotriazole) compounds include 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-methylphenol], such as that marketed under the brand name "Mixxim BB / 200" by Fairmount Chemical, 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol], such as that marketed in micronized aqueous dispersion form under the brand name "Tinosorb M" by BASF or under the brand name "Mixxim BB / 100" by Fairmount Chemical, and derivatives as described in US patents Nos. 5,237,071 and 5,166,355, GB-2,303,549, DE-197,26184 and EP-893,119, and drometrizole tri-siloxane, such as that marketed under the brand name "Silatrizole" by Rhodia Chimie or - "Mexoryl XL" by L'Oréal.

[0081] Examples of benzoxazole compounds include the 2,4-bis[5-l(dimethylpropyl)benzoxazol-2-yl-(4-phenyl)imino]-6-(2-ethylhexyl)imino- 1,3,5-triazine, such as that marketed under the brand name Uvasorb K2A by Sigma 3V.

[0082] Suitable examples of protective polymers and protective silicones include the silicones described in WO 93 / 04665.

[0083] Suitable α-alkylstyrene derived dimers include the dimers described in DE-19855649.

[0084] Examples of 4,4-diarylbutadiene compounds include l,l-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene.

[0085] According to preferred embodiments, the compositions of this disclosure further comprise at least one additional organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate, Octocrylene, and mixtures thereof. In such embodiments, the UV-absorbing system may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine and (2) at least one organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate, Octocrylene, and mixtures thereof.

[0086] According to other preferred embodiments, however, the compositions of this disclosure are "free", "substantially free" or "devoid", as defined above, of one or more additional organic UV filter(s) selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate and Octocrylene, preferably with two or more, preferably three or more, preferably four or more, or preferably all five of these sunscreen agents.

[0087] According to preferred embodiments, the compositions of this disclosure are "free", "substantially free" or "devoid", as defined above, of one or more additional organic UV filters selected from the group consisting of OXYBENZONE (benzophenone-3), OCTINOXATE (ethylhexyl methoxycinnamate), ETHYLHEXYL TRIAZONE, DROMETRIZOLE TRISILOXANE, METHYLENE BIS-BENZOTRIAZOLYL TETRAMETHYLBUTYL PHENOL, DIE-THYLAMINO HYDROXYBENZOYL HEXYL BENZOATE, DIETHYLHEXYL BUTAMIDO TRIAZONE, ISOAMYL P-METHOXYCINNAMATE, POLY-SILICONE-15, 4-METHYLBENZYLIDENE CAMPHOR, PHENYL DIBENZL MIDAZOLE DISODIUM TETRASULFONATE, METHOXYETHYLACYA-NOACETATE OF METHOXYPROPYLAMINO CYCLOHEXENYLIDENE, preferably two or more, preferably three or more, preferably four or plus, etc., and preferably "free", "significantly free" or "devoid" of all these sunscreen agents.

[0088] According to preferred embodiments, the compositions of this disclosure are "free", "substantially free" or "devoid", as defined above, of OXYBENZONE (benzophenone-3) and / or OCTINOXATE (ethylhexyl methoxy cinnamate).

[0089] If present in the compositions of this disclosure, at least one additional UV filter is preferably present in the compositions of this disclosure in an amount of at least about 5% by weight, preferably at least about 10% by weight, preferably at least about 12% by weight, preferably at least about 14% by weight, and preferably at least about 15% by weight, the upper end of the range of the additional UV filter present preferably being about 40% by weight (e.g. about 5 to 40%, about 10 to 40%, about 12 to 40%, etc.), preferably about 30% by weight (e.g. about 5 to 30%, about 10 to 30%, about 12 to 30%, etc.), preferably about 25% by weight (e.g. about 5 to 25%, about 10 to 25%, about 12 to 25%, etc.), and preferably about 20% by weight (for example about 5 to 20%, about 10 to 20%, about 12 to 20%, etc.), all weights being based on the total weight of the composition.

[0090] According to preferred embodiments, the compositions of this disclosure comprise 10% or less by weight relative to the total weight of the composition of additional UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight relative to the total weight of the composition.

[0091] According to preferred embodiments, the compositions of this disclosure comprise 10% or less by weight relative to the total weight of the composition of additional organic UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight relative to the total weight of the composition.

[0092] According to preferred embodiments, the UV-absorbing system of the compositions of this disclosure may "consist of" or "consist essentially of" bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0093] According to preferred embodiments, the UV-absorbing system of the compositions of this disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) zinc oxides, titanium oxides and / or cerium oxides.

[0094] According to preferred embodiments, the UV-absorbing system of the compositions of this disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) additional organic UV filter(s).

[0095] According to preferred embodiments, the present disclosure envisages omitting one or more of the specific UV filters mentioned above from the UV-absorbing system of the compositions of this disclosure. By way of example, octocrylene and / or octinoxate may be omitted from the compositions. A similar omission of one or more of the specific UV filters mentioned is thus envisaged. Oil

[0096] According to preferred embodiments of this disclosure, compositions further comprising at least one oil are proposed. “Oil” means a substance that is hydrophobic and lipophilic, and is a liquid at approximately room temperature (20 to 25 °C) and approximately atmospheric pressure (760 mm Hg).

[0097] Suitable oils include volatile and / or non-volatile oils. These oils may be any acceptable oil, including, but not limited to, silicone oils and / or hydrocarbon oils.

[0098] According to certain embodiments, the compositions of this disclosure preferably comprise one or more volatile silicone oils. Examples of such volatile silicone oils include linear or cyclic silicone oils having from 2 to 7 silicon atoms, these silicones being optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms. Specific oils that may be used in the disclosure include octamethyltetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and mixtures thereof. Other volatile oils that may be used include KF 96A with a viscosity of 6 cSt, a commercial product from Shin Etsu with a flash point of 94 °C. Preferably, volatile silicone oils have a flash point of at least 40°C.

[0099] Non-limiting examples of volatile silicone oils are listed in Table 1 below.

[0100] [Tables] Compound Flash Point (°C) Viscosity (cSt) Octyltrimethicone 93 1.2 Hexyltrimethicone 79 1.2 Decamethylcyclopentasiloxane 72 4.2 (cyclopentasiloxane or D5) 55 2.5 Octamethylcyclotetrasiloxane 93 7 (cyclotetramethylsiloxane or D4) 63 1.7 Dodecamethylcyclohexasiloxane (D6) 94 6 Decamethyltetrasiloxane (L4) 56 1.5 KF-96 A from Shin Etsu PDMS (polydimethylsiloxane) DC 200 (1.5 cSt) from Dow Corning PDMS DC 200 (2 cSt) from Dow Corning 87 2

[0101] In addition, a volatile linear silicone oil may be used in this disclosure. Suitable volatile linear silicone oils include those described in US Patent No. 6,338,839 and in WO03 / 042221, the contents of which are incorporated herein by reference. In one embodiment, the volatile linear silicone oil is decamethyltetrasiloxane. In another embodiment, decamethyltetrasiloxane is further combined with another solvent that is more volatile than decamethyltetrasiloxane.

[0102] According to certain embodiments of this disclosure, the composition preferably comprises one or more non-silicone volatile oils and may be selected from volatile hydrocarbon oils, volatile esters, and volatile ethers. Examples of such volatile non-silicone oils include, but are not limited to, volatile hydrocarbon oils having 8 to 16 carbon atoms and mixtures thereof, and in particular, C8-Ci6 branched alkanes such as C8-Ci6 isoalkanes (also known as isoparaffins), isohexadecane, isododecane, isodecane, and, for example, oils sold under the trade names Isopar or Permethyl. Preferably, the volatile non-silicone oils have a flash point of at least 40 °C.

[0103] Non-limiting examples of volatile non-silicone oils are given in Table 2 below.

[0104] [Tables2] Compound Flash Point (°C) Isododecane 43 N-butyl propylene glycol ether 60 Ethyl 3-Ethoxypropionate 58 Propylene glycol acetate methyl ether 46 Isopar L (Cn-Cu isoparaffin) 62 Isopar H (Cn-Cl2 isoparaffin) 56

[0105] According to certain embodiments of this disclosure, the composition comprises at least one non-volatile oil. Examples of non-volatile oils that may be used in this disclosure include, but are not limited to, polar oils such as, for example:

[0106] - esters and ethers, in particular fatty acids, such as oils of formula R1COOR2, in which RI represents the remainder of a fatty acid having from 8 to 29 carbon atoms, and R2 represents a hydrocarbon chain, branched or unbranched, containing from 3 to 30 carbon atoms, such as, for example, Purcellin oil, isononyl isononanoate, isopropyl myristate, ethyl-2-hexyl palmitate, octyl-2-dodecyl stearate, octyl-2-dodecyl erucate, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, octylhydroxystearate, octyldodecyl hydroxystearate, diisostearylmalate, triisocetyl citrate, heptanoates, octanoates, fatty alcohol decanoates; polyol esters, such as propylene glycol dioctanoate, neopentyl glycol diheptanoate and diethylene glycol diiso-nonanoate;triglycerides such as caprylic / capric acid triglycerides, for example those sold by Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by Dynamit Nobel; and pentaerythritol esters such as pentaerythrityl tetraisostearate or dipentaerythrityl pentaisononanoate;

[0107] - ethers containing 10 to 40 carbon atoms;

[0108] - liquid C8 to C26 fatty alcohols, for example oleyl alcohol, alcohol cetyl alcohol, stearyl alcohol and cetearyl alcohol;

[0109] - hydrocarbon oils of animal origin, such as perhydrosqualene;

[0110] - vegetable hydrocarbon oils, such as liquid triglycerides of fatty acids having 4 to 10 carbon atoms such as heptanoic or octanoic acid triglycerides, for example, sunflower, corn, soybean, cucurbit, grapeseed, sesame, hazelnut, apricot, macadamia, ara, sunflower oil, castor oil, avocado oil, caprylic / capric acid triglycerides, such as those sold by the company Stéarineries Dubois or those sold under the names Miglyol 810, 812, and 818, by the Dynamit Nobel Company, coco-caprylate / caprate (esterified coconut oil), jojoba oil, shea butter oil; and [YES] - their mixture.

[0112] In addition, examples of non-volatile oils that may be used in this disclosure include, but are not limited to, non-polar oils such as branched and unbranched hydrocarbons, in particular Vaseline (petrolatum), paraffin oil, squalane, squalene, hydrogenated polyisobutene, hydrogenated polydecene, polybutene, mineral oil, pentahydrosqualene and mixtures thereof.

[0113] According to certain embodiments of this disclosure, the compositions of this disclosure include at least one non-volatile silicone oil. Appropriate examples of such silicone oils include, but are not limited to, non-volatile silicone fluids such as, for example, polyalkyl (aryl) siloxanes. Appropriate polyalkyl siloxanes include, but are not limited to, polydimethyl siloxanes, which are designated CTFA dimethicone, polydiethyl siloxane, phenyl trimethicone, trimethyl pentaphenyl trisiloxane, phenyldimethicone, phenyltrimethylsi-loxydiphenylsiloxane, diphenyldimethicone, and diphenylmethyldiphenyltrisiloxane, and the siloxanes disclosed in the U.S. patent application publication No. 2004 / 0126350, the full disclosure of which is incorporated herein by reference. Specific examples of suitable high-viscosity silicone oils include, but are not limited to, PCR 15 M 30 (500 cSt) or Wacker Belsil PDM 1000 (1000 cSt) and Dow Corning 200 (350 cSt) (values ​​in parentheses represent viscosities at 25 °C).

[0114] Particularly preferred oils include, but are not limited to, one or more of the following: diisopropyl sebacate, C12-15 alkyl benzoate, isopropyl lau-roylsarcosinate, dicaprylyl carbonate, dicaprylate / dicaprate, coco glycerides, caprylic / capric triglyceride, isopropyl myristate, isopropyl palmitate, coco caprylate / caprate, ethylhexyl palmitate, isononyl isononanoate, octyldodecanol, dicaprylyl ether, C15-19 alkane, diisopropyl adipate, dicaprylyl ether and mixtures thereof.

[0115] According to preferred embodiments, the compositions of this disclosure include a system for solubilizing bis-ethylhexyloxyphenol methoxyphenyl triazine comprising at least one solvent that is present in the system in an amount effective for solubilizing bis-ethylhexyloxyphenol methoxyphenyl triazine such that the composition is suitable for use as a composition containing effective amounts of bis-ethylhexyloxyphenol methoxyphenyl triazine and can be used as such. Preferably, the at least one solvent is chosen among the oils mentioned in the previous paragraph.

[0116] According to preferred embodiments, the oil system of the compositions of this disclosure may "consist of" or "consist essentially of" C12-15 alkyl benzoate and / or caprylic / capric triglyceride and / or dii-sopropyl sebacate and / or isopropyl palmitate.

[0117] According to preferred embodiments, C12-15 alkyl benzoate and / or caprylic / capric triglyceride and / or diisopropyl sebacate and / or isopropyl palmitate are present in compositions of this disclosure in an amount, individually or collectively, preferably of at least 10% by weight, preferably of at least 20% by weight, preferably of at least 30% by weight, preferably of at least 40% by weight, preferably of at least 50% by weight (collectively), preferably of at least 60% by weight (collectively) and preferably of at least 70% by weight (collectively), all weights being relative to the total weight of the composition.

[0118] According to preferred embodiments, the compositions of this disclosure may further optionally include at least one natural oil. The natural oil or oils are oils recovered or extracted from foods, and / or preferably oils recovered from plants or other forms of plant life (as opposed to oils that are derived from natural sources by reactions and are not "natural oils" as used herein). For example, vegetable oils include glyceride triesters, which are generally triesters of fatty acids and glycerol, the fatty acids of which may have chain lengths ranging from C4 to C24, these chains being saturated or unsaturated and linear or branched.

[0119] Non-limiting examples of suitable natural oil(s) include olive oil, sweet almond oil, coconut oil, avocado oil, wheat germ oil, sunflower oil, grapeseed oil, sesame oil, corn oil, apricot oil, castor oil, shea oil, soybean oil, palm oil, rapeseed oil, cottonseed oil, hazelnut oil, macadamia oil, jojoba oil, alfalfa oil, poppy oil, pumpkin seed oil, cucurbit oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, oil of Rye, safflower oil, candlenut oil, passionflower oil, rosehip oil, etc., including oils from the aforementioned seeds and mixtures thereof. Castor (seed) oil is particularly preferred.

[0120] Preferably, where applicable, at least one natural oil is present in an amount of approximately 0.1% to approximately 20% by weight, preferably 0.25% to approximately 15% by weight, preferably approximately 0.5% to approximately 10% by weight, and preferably approximately 1% to approximately 5% by weight, relative to the total weight of the product position, including all intermediate ranges and sub-ranges.

[0121] According to preferred embodiments, at least one oil is present in the compositions of this disclosure in an amount ranging from about 10% to about 80% by weight, more preferably from about 25% to about 75% by weight, and preferably from about 40% to about 70% by weight, based on the total weight of the composition, including all ranges and sub-ranges within those ranges such as, for example, 50% to 75%, 35% to 67%, etc.

[0122] According to preferred embodiments, the compositions of this disclosure are anhydrous. Aqueous Phase

[0123] The compositions of this disclosure may also optionally contain water. When the compositions of this disclosure contain water, they are preferably in the form of an emulsion. Preferably, when the compositions of this disclosure contain water, they are in the form of an emulsion containing an external aqueous phase such as an oil-in-water (O / W) emulsion or a water-in-oil-in-water (W / O / W) emulsion, or an emulsion containing an external oil phase such as a water-in-oil (W / O) emulsion or an oil-in-water-in-oil (W / O / O) emulsion. Preferably, when in the form of an emulsion, the oil phase may contain silicone oils (for example, Si / O or W / Si emulsion) or hydrocarbon oils.Where appropriate, water is preferably present in an amount of about 10% to about 80% by weight, preferably about 20% to about 70% by weight, preferably about 35% to about 65% by weight, including all intermediate ranges and sub-ranges, all weights being based on the total weight of the composition.

[0124] However, according to preferred embodiments, the compositions of this disclosure are water-free, substantially water-free, or water-free as defined herein. Preferably, the compositions of this disclosure are anhydrous.

[0125] If present in compositions of this disclosure, the aqueous phase may include at least one water-soluble organic solvent that is liquid at room temperature and atmospheric pressure. For example, such at least one water-soluble organic solvent may include:

[0126] - triethyl citrate;

[0127] - C1-C5 monoalcohols having a C1-C5 alkane chain and a single functional group hydroxyl (OH). Suitable C1-C5 monoalcohols include methanol, ethanol, propanol, isopropanol, butanol, and mixtures thereof;

[0128] - polyols (compounds having 2 or more hydroxyl groups) having, for example, 2 with 20 carbon atoms, preferably from 2 to 6 carbon atoms, such that, by for example, glycerol, diglycerol, propylene glycol, isoprene glycol, dipropylene glycol, butylene glycol, hexylene glycol, 1,3-propanediol, pentylene glycol, simple sugars and water-soluble polyalkylene glycols;

[0129] - and mixtures thereof.

[0130] According to preferred embodiments, at least one water-soluble organic solvent is chosen from the group consisting of ethanol, dipropylene glycol, butylene glycol, propanediol and propylene glycol, and mixtures thereof.

[0131] Where appropriate, the water-soluble organic solvent(s) is / are preferably present in the compositions of this disclosure in a total amount ranging from 0.5% to about 40% by weight, preferably from about 3% to about 30% by weight, and preferably from about 5% to about 20% by weight, relative to the total weight of the composition, including all intermediate ranges and sub-ranges, such as 2% to 15%, 2% to 25%, 7.5% to 30%, etc. Optional additional ingredients

[0132] The compositions of this disclosure may also optionally further include at least one additive or auxiliary commonly used in cosmetic compositions and known to a person skilled in the art as being capable of being incorporated into such compositions.These additives or auxiliaries may be selected from sugar fatty acid ester-based gelling agents, lipophilic acrylate-based thickening agents, water-soluble gums, film-forming agents, coloring agents (e.g., dyes and pigments), waxes, thixotropic agents (e.g., clays), fillers, preservatives, perfumes, surfactants, antioxidants, free radical scavengers, spreading agents, dispersing agents, antifoaming agents, neutralizing agents, stabilizing agents, active ingredients selected from essential oils, moisturizing agents, vitamins, active ingredients, proteins, ceramides, plant extracts, fibers and the like, wetting agents, and mixtures thereof. However, preferably, the compositions in this disclosure are "free," "substantially free," or "devoid" of such additives.

[0133] According to preferred embodiments, compositions optionally further comprising at least one sugar fatty acid ester-based gelling agent are proposed. Any sugar-based compound esterified with at least one fatty acid may be used in accordance with this disclosure.

[0134] Sugar-based compounds include, but are not limited to, compounds containing at least one monomer of glucose and / or fructose, including sucrose. These compounds include not only sugar monomers (e.g., glucose and fructose), but also polymeric forms of such monomers such as, for example, dextrin and fructo-oligosaccharides.

[0135] Suitable fatty acids for the production of an esterified compound include, but are not limited to, acidic compounds containing at least C8 (8 carbon atoms) (e.g., octanoic acid). Preferably, suitable fatty acids for the esterification of sugar-based compounds contain from 8 to 32 carbon atoms, preferably from 10 to 26 carbon atoms, preferably from 12 to 22 carbon atoms, and preferably from 16 to 18 carbon atoms, including saturated and unsaturated, branched and unbranched fatty acids, such as, for example, octanoic acid, ethylhexyl acid, stearic acid, palmitic acid, oleic acid, palmitoleic acid, etc.

[0136] Appropriate specific examples of fatty acid ester-based gelling agents suitable for use in accordance with this disclosure include, but are not limited to, dextrin fatty acid esters such as dextrin palmitate, dextrin stearate and dextrin 2-ethylhexanoate / palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; and fructo-oligosaccharide fatty acid esters such as fructo-oligosaccharide stearate and fructo-oligosaccharide 2-ethylhexanoate.

[0137] According to preferred embodiments, at least one sugar fatty acid ester-based gelling agent, if any, is present in the compositions of this disclosure in an amount such as, for example, about 0.1% to about 30% by weight relative to the total weight of the composition, about 1% to about 25% by weight, about 5% to about 20% by weight, and about 7.5% to about 17.5% by weight, including all intermediate ranges and sub-ranges such as, for example, about 4.5% to about 10% by weight, about 12% to about 18% by weight, about 11% to about 16% by weight, about 5.5% to about 18% by weight, about 7.7% to about 19% by weight, etc., all weights being based on the total weight of the composition. Lipophilic acrylate-based thickening agent

[0138] According to this disclosure, compositions optionally further comprising at least one lipophilic acrylate-based thickening agent are proposed. Preferably, if present, the at least one lipophilic acrylate-based thickening agent comprises a monomer containing a crystallizable chain selected from the group consisting of C8 to C36 alkyl (meth)acrylates, preferably C10 to C1 alkyl (meth)acrylates, and preferably C14 to C22 alkyl (meth)acrylates, such as, for example, poly(stearyl acrylate) and poly(behenyl acrylate).

[0139] Suitable examples of lipophilic acrylate-based thickening agents include, but are not limited to, polymers with the INCI name "Poly C10-C30 alkyl acrylate," for example, Intelimer™ products from Air Products, such as Intelimer H4. Other examples include Intelimer™ IPA 13-1 or the product Intelimer (TM) IPA 13-6. More generally, at least one lipophilic acrylate-based thickening agent may be a polymer disclosed in US patent application 2007 / 0264204, the entirety of which is incorporated herein by reference. A particularly preferred lipophilic acrylate-based thickening agent is the C12-22 alkyl acrylate / hydroxyethyl acrylate copolymer.

[0140] According to preferred embodiments, at least one lipophilic acrylate-based thickening agent, if any, is preferably present in the compositions of this disclosure in an amount ranging from about 0.1% to about 10% by weight, preferably from about 0.25% to about 5% by weight, preferably from about 0.5% to about 4% by weight, and preferably from about 0.75% to about 3% by weight, all weights being based on the total weight of the composition, including all intermediate ranges and sub-ranges such as, for example, from 0.05, 0.06, 0.07, 0.08, 0.09, 1.0, 2.0, 3.0, 4.0 to 5.0 percent by weight, including sub-ranges including any of these amounts. Water-soluble gum

[0141] According to preferred embodiments, the compositions of this disclosure may optionally further comprise at least one water-soluble natural gum. Preferred water-soluble natural gums include, but are not limited to, guar gum, acacia gum (Senegal), xanthan gum, gum arabic, tragacanth gum, locust bean gum, agar-agar, and mixtures thereof. Acacia gum (Senegal) is preferred.

[0142] Preferably, where appropriate, at least one water-soluble natural gum is present in an amount ranging from about 0.1% to about 20% by weight, preferably from about 0.5% to about 10% by weight, preferably from about 0.75% to about 7.5% by weight, and preferably from about 1% to about 5% by weight, relative to the total weight of the composition, including all intermediate ranges and sub-ranges.

[0143] A person skilled in the art shall ensure that the optional additional additives are chosen and / or their quantity so that the advantageous properties of the composition as disclosed are not, or are not substantially, compromised by the envisaged addition.

[0144] It goes without saying that the composition of the disclosure must be cosmetically or dermatologically acceptable, that is, it must contain a physiologically acceptable, non-toxic carrier. The composition may be in any pharmaceutical form normally used in the cosmetic and dermatological fields that is suitable for topical administration as mentioned above.

[0145] These auxiliary additives may be present in the composition in a proportion of 0% to 99% (such as 0.01% to 90%) by weight of the total composition and furthermore such as 0.1% to 50% by weight (where applicable), including all beaches and intermediate sub-beaches.

[0146] In accordance with this disclosure, the compositions of this disclosure may be a standalone product (for use alone), or they may be a product for use in conjunction with another composition, for example, a base coat composition (makeup base), a color coat composition, or a top coat composition (overcoat). It should be understood that when compositions of this disclosure are applied to keratinous materials in the form of any such composition, such application may comprise one or more coats of the product.Thus, for example, the application of at least one color layer composition may include one or more color layers; the application of at least one topcoat composition may include one or more topcoats; the application of at least one basecoat composition may include one or more basecoats. Preferably, such basecoat, color layer, and topcoat compositions contain three or fewer layers of compositions, preferably two or fewer layers of compositions, and preferably only one layer of compositions.

[0147] During the application of the compositions of this disclosure, the base coat (if any) is typically applied directly to the keratinous material, the color coat is typically applied either directly to the keratinous material (if no base coat is present), or to a previously applied base coat, and the top coat (if any) is typically applied to a color coat.

[0148] According to preferred embodiments of this disclosure, methods for treating, protecting, improving the appearance, caring for and / or making up a keratinous material by applying compositions of this disclosure to the keratinous material in a quantity sufficient to treat the keratinous material, improve its appearance, care for it and / or make it up, are proposed.

[0149] Preferably, the "makeup" of the keratinous material includes the application of a composition comprising at least one coloring agent to the keratinous material in sufficient quantity to provide color and / or an optical effect to the keratinous material.

[0150] Preferably, the "protection" of the keratinous material includes the application of a composition of this disclosure to protect the keratinous material from damage resulting from exposure to UV rays.

[0151] According to the preceding embodiments, the compositions of this disclosure are applied topically to the keratinous material in a sufficient quantity to treat the keratinous material, improve its appearance, care for it and / or to cover it with makeup. The compositions can be applied to the desired area as needed, preferably once or twice a day, more preferably once a day, and then preferably allowed to dry before being subjected to contact such as with clothing or other objects (e.g., clothing or a top coat). Preferably, the composition is allowed to dry for about 1 minute or less, more preferably for about 45 seconds or less.

[0152] According to preferred embodiments of this disclosure, manufacturing processes for environmentally friendly compositions comprising the combination of bis-ethylhexyloxyphenol methoxyphenyl triazine and ingredient(s) that form an environmentally friendly carrier during the formation of the compositions are proposed. Preferably, the compositions contain minimal amounts of ingredients of animal origin and / or microplastics, or are free of such ingredients.

[0153] This disclosure also considers pre-packaged kits and / or materials suitable for consumer use containing one or more composition(s) as described herein, alone or in combination with makeup products such as primers, top coats, makeup removers, etc. The packaging and application device for any subject of this disclosure may be selected and manufactured by persons skilled in the art based on their general knowledge and adapted according to the nature of the composition to be packaged. Indeed, the type of device to be used may be particularly related to the consistency of the composition, especially its viscosity; it may also depend on the nature of the constituents present in the composition, for example, the presence of volatile compounds.

[0154] Unless otherwise stated, all numbers expressing quantities of ingredients, reaction conditions, and so forth used in the patent specification and claims are to be understood as modified in all cases by the term "approximately." Accordingly, unless otherwise stated, the numerical parameters presented in the following patent specification and the attached claims are approximations that may vary depending on the desired properties that are sought to be obtained through this disclosure.

[0155] Although the numerical ranges and parameters defining the general scope of disclosure are approximations, the numerical values ​​shown in the specific examples are reported as accurately as possible. However, every numerical value inherently contains some errors necessarily resulting from the standard deviation found in its respective measurements. The following examples are intended to illustrate disclosure without, however, limiting its scope. Percentages are given on a weighted basis. Example 1

[0156] [Tables3] ENVIRONMENTALLY FRIENDLY LOTION EPS 50 ISOPROPYL MYRISTATE 7.00 TOCOPHEROL 0.10 DENATURED ALCOHOL 5.00 WATER QS XANTHAN GUM 0.20 AVOBENZONE 3.00 SODIUM HYALURONATE 0.02 GLYCERIN 3.00 OCTISALATE 5.00 CROSS-CUT POLYMER ACRYLATES / C10-30 ALKYL ACRYLATE 0.20 TRIETHANOL AMINE QS C12-15 ALKYL BENZOATE 5.00 CAPRYLYL GLYCOL 0.50 CAPRYLIC / CAPRIC TRIGLYCERIDE 4.00 DIISOPROPYL SEBACATE 3.00 ACRYLATES COPOLYMER 2.00 BEMOTRIZINOL 6.00 PROPANEDIOL 3.00 TRISODIUM ETHYLENEDIAMINE DL SUCCINATE 0.31 STARCH ACETATE OXIDE 1.00 COPERNICIA CERIFERA (CARNAUBA) WAX 1.00 C12-22 ALKYL ACRYLATE / HYDROXYETHYLACRYLATE COPOLYMER 1.00 Example 2

[0157] [Tables4] ENVIRONMENTALLY FRIENDLY OIL SPF30 TOCOPHEROL 0.25 ISOPROPYL PALMITATE QS FRAGRANCE 0.50 ALCOHOL DENATURE 8.00 OCTISALATE 22.00 AVOBENZONE 4.50 DIISOPROPYL SEBACATE 8.00 ETHYLENEDIAMINE DILINOLEATE / STEARYL DIMER COPOLYMER 1.50 BEMOTRIZINOL 5.00 DICAPRYLYL CARBONATE 2.00 C12-15 ALKYL BENZOATE 2.00 SQUALANE 1.00 HOMOSALATE 10.00

Claims

Demands

1. Composition comprising bemotrizinol and an environmentally friendly vector.

2. Composition according to claim 1, wherein the composition has: - a critical wavelength of at least 370 nm; and / or - an FPUVA / FPS ratio of at least 1 / 3; and / or - a UVA1 / UV ratio of 0.7 or more.

3. Composition according to any one of the preceding claims, wherein the composition also has an FPS value of at least 30.

4. Composition according to any one of the preceding claims, wherein the composition is free from mineral UV filters and / or microplastics.

5. Composition according to any one of the preceding claims, wherein the environmentally friendly carrier comprises an oil system comprising C12-15 alkyl benzoate, caprylic / capric triglyceride, diisopropyl sebacate, isopropyl palmitate or a mixture thereof.

6. Composition according to any one of the preceding claims, wherein Cl2-15 alkyl benzoate and / or caprylic / capric triglyceride and / or diisopropyl sebacate and / or isopropyl palmitate are present in an amount from about 25% to about 75% by weight relative to the total weight of the composition.

7. Composition according to any one of the preceding claims, further comprising at least one passivated mineral UV filter.

8. Composition according to any one of the preceding claims, wherein the composition is free of oxybenzone and / or octinoxate.

9. Composition according to any one of the preceding claims, wherein the composition is anhydrous.

10. Composition according to any one of the preceding claims, further comprising at least one coloring agent and / or at least one active agent.