Method for controlling harmful arthropods using heterocyclic compounds

Abstract

To provide a method for controlling harmful arthropods.SOLUTION: A compound represented by the formula (I) in the figure [where the symbols are as described in the specification] or an N-oxide thereof can control harmful arthropods.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a method for controlling arthropod pests using a heterocyclic compound. [Background technology]

[0002] Various compounds have been investigated so far for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that certain compounds have pest control effects. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] International Publication No. 2016 / 129684 Summary of the Invention [Problem to be solved by the invention]

[0004] An object of the present invention is to provide a method for controlling arthropod pests. [Means for solving the problem]

[0005] The present invention is as follows. [1] Formula (I)

[0006] [ka] [During the ceremony, Q expressed by the following formula

[0007] [ka] (wherein # represents a bonding site to a sulfur atom, and ● represents a bonding site to Het) represents a group represented by formula Q1 or a group represented by formula Q2,

[0008] [ka] A 1 is a nitrogen atom or CR 8 represents R 8 represents a halogen atom or a hydrogen atom, R 2 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a cyclopropyl group, or a cyclopropylmethyl group, n represents 0, 1 or 2; G 1 is a nitrogen atom or CR 3a represents G 2 is a nitrogen atom or CR 3b represents G 3 is a nitrogen atom or CR 3c represents G 4 is a nitrogen atom or CR 3d represents R 3a , R 3b , R 3c and R 3d are the same or different and each represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group L, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group E, a phenyl group optionally substituted with one or more substituents selected from Group H, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group H, OR 12 , N.R. 11 R 12 , N.R. 11a R 12a , N.R. 24 NR 11 R 12 , N.R. 24 OR 11 , N.R. 11 C(O)R 13 , N.R. 24 NR 11 C(O)R 13 , N.R. 11 C(O)OR 14 , N.R. 24 NR 11 C(O)OR 14 , N.R.11 C(O)NR 31 R 32 , N.R. 24 NR 11 C(O)NR 31 R 32 , N=CHNR 31 R 32 , N=S(O) p R 15 R 16 , C(O)R 13 , C(O)OR 17 , C(O)NR 31 R 32 , C(O)NR 11 S(O)2R 23 , C.R. 30 =NOR 17 , N.R. 11 CR 24 =NOR 17 , S(O) m R 23 , a cyano group, a nitro group, a halogen atom, or a hydrogen atom; p represents 0 or 1; m represents 0, 1 or 2; R 30 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 35 , N.R. 36 R 37 or a hydrogen atom, R 35 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, R 17 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, or a hydrogen atom; R 11 , R 24 , R 36 and R 37 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 12represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J, a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from group J, a phenyl group optionally substituted with one or more substituents selected from group D, a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, S(O)R 23 or a hydrogen atom, R 23 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a phenyl group optionally substituted with one or more substituents selected from Group D, R 11a and R 12a together with the nitrogen atom to which they are bonded form a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group E, R 13 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, or a hydrogen atom; R 14 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D}, R 15 and R 16 are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, R 31represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, R 32 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J, S(O)R 23 or a hydrogen atom, R 4 is the group L 2 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group E 2 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group H 2 a phenyl group optionally substituted with one or more substituents selected from group H 2 a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of OR 42 , N.R. 41 R 42 , N.R. 41a R 42a , N.R. 54 NR 41 R 42 , N.R. 54 OR 41 , N.R. 41 C(O)R 43 , N.R. 54 NR 41 C(O)R 43 , N.R. 41 C(O)OR 44 , N.R. 54 NR 41 C(O)OR 44 , N.R. 41 C(O)NR 61 R 62 , N.R. 54 NR 41 C(O)NR 61 R 62 , N=CHNR 61 R 62 , N=S(O) r R 45 R 46 , C(O)R 43 , C(O)OR 47 , C(O)NR 61 R 62, C(O)NR 41 S(O)2R 53 , C.R. 60 =NOR 47 , N.R. 41 CR 54 =NOR 47 , S(O) t R 53 , a cyano group, a nitro group, or a halogen atom; r represents 0 or 1; t represents 0, 1 or 2; R 60 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 65 , N.R. 66 R 67 or a hydrogen atom, R 65 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, R 47 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms; Group D 2 represents a phenyl group optionally substituted by one or more substituents selected from the group consisting of: R 41 , R 54 , R 66 and R 67 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 42 is the group F 2 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 2 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J 2 a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from Group D 2 a phenyl group optionally substituted with one or more substituents selected from Group D 2 a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of a hydrogen atom and S(O)R 53 represents R 53represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a group D 2 represents a phenyl group optionally substituted with one or more substituents selected from the group consisting of R 41a and R 42a together with the nitrogen atom to which they are attached form group E 2 and forming a 3- to 7-membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from the group consisting of R 43 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, group D 2 a phenyl group optionally substituted with one or more substituents selected from Group D 2 a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the group consisting of: R 44 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group is selected from the group D 2 and optionally substituted with one or more substituents selected from the following: R 45 and R 46 are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, R 61 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, R 62 is the group F 2 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 2 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of S(O)R53 or a hydrogen atom, k represents 0, 1, 2, or 3, and when k is 2 or 3, two or three R 4 may be the same or different, The Two R's 4 When R are bonded to adjacent carbon atoms, the two R 4 together with the two carbon atoms to which they are bonded, form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, or a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring are each selected from the group H 2 or a triazole ring optionally substituted with one or more substituents selected from group P; Het represents a group of formula Het1 or a group of formula Het2,

[0009] [ka] A 2 is -NR 5a - or -CR 7a R 7b - represents A 3 -CR 7c R 7d -, -CR 7e R 7f -CR 7g R 7h -* 1 , or -CR 7i R 7j -CR 7k R 7l -CR 7m R 7n -* 1 represents * 1 is A 2represents the bonding position with A 4 is -NR 5b -, -CR 7o R 7p -, -CR 7q R 7r -CR 7s R 7t -* 2 , -NR 5c -CR 7u R 7v -* 2 , -CR 7w R 7x -CR 7y R 7z -CR 7aa R 7bb -* 2 , or -NR 5d -CR 7cc R 7dd -CR 7ee R 7ff -* 2 represents * 2 is A 2 represents the bonding position with R 5a , R 5b , R 5c , and R 5d are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group K, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 7a , R 7b , R 7c , R 7d , R 7e , R 7f , R 7g , R 7h , R 7i , R 7j , R 7k , R 7l , R 7m , R 7n , R 7o , R 7p , R 7q , R7r , R 7s , R 7t , R 7u , R 7v , R 7w , R 7x , R 7y , R 7z , R 7aa , R 7bb , R 7cc , R 7dd , R 7ee , and R 7ff are the same or different and are each a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a nitro group, OR 69 , N.R. 69 R 70 , a cyano group, a halogen atom, or a hydrogen atom; R 7a and R 7b , R 7c and R 7d , R 7e and R 7f , R 7g and R 7h , R 7i and R 7j , R 7k and R 7l , R 7m and R 7n , R 7o and R 7p , R 7q and R 7r , R 7s and R 7t , R 7u and R 7v , R 7w and R 7x , R 7y and R 7z , R 7aa and R 7bb , R 7cc and R 7dd , and R 7ee and R 7ffmay each be taken together with the carbon atom to which they are attached to form a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; R 69 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group T, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group U, a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from Group U, a phenyl group optionally substituted with one or more substituents selected from Group V, a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group V, or a hydrogen atom; R 70 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; W represents an oxygen atom or a sulfur atom; B 1 is CR 6a or a nitrogen atom, B 2 is CR 6b or a nitrogen atom, B 3 is CR 6c or a nitrogen atom, R 6a , R 6b , and R 6c are the same or different, and the group L 3 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from Group E 3 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group H 3 a phenyl group optionally substituted with one or more substituents selected from group H 3 a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of OR 72 , N.R. 71 R 72 , N.R. 71a R 72a , N.R. 84 NR 71 R 72 , N.R. 84 OR71 , N.R. 71 C(O)R 73 , N.R. 84 NR 71 C(O)R 73 , N.R. 71 C(O)OR 74 , N.R. 84 NR 71 C(O)OR 74 , N.R. 71 C(O)NR 91 R 92 , N.R. 84 NR 71 C(O)NR 91 R 92 , N=CHNR 91 R 92 , N=S(O) q R 75 R 76 , C(O)R 73 , C(O)OR 77 , C(O)NR 91 R 92 , C(O)NR 71 S(O)2R 83 , C.R. 90 =NOR 77 , N.R. 71 CR 84 =NOR 77 , S(O) v R 83 , a cyano group, a nitro group, a halogen atom, or a hydrogen atom; q represents 0 or 1; v represents 0, 1 or 2; R 90 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 95 , N.R. 96 R 97 or a hydrogen atom, R 95 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, R 77 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms; Group D 3 represents a phenyl group optionally substituted by one or more substituents selected from the group consisting of: R71 , R 84 , R 96 and R 97 are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 72 is the group F 3 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 3 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J 3 a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from Group D 3 a phenyl group optionally substituted with one or more substituents selected from Group D 3 a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of S(O)R 83 or a hydrogen atom, R 83 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a group D 3 represents a phenyl group optionally substituted with one or more substituents selected from the group consisting of R 71a and R 72a together with the nitrogen atom to which they are attached form group E 3 and forming a 3- to 7-membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from the group consisting of R 73 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, group D 3 a phenyl group optionally substituted with one or more substituents selected from Group D 3 a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the group consisting of: R 74represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group is selected from the group D 3 and optionally substituted with one or more substituents selected from the following: R 75 and R 76 are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms, R 91 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, R 92 is the group F 3 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 3 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of S(O)R 83 , or a hydrogen atom. Group L: a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group M: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, and halogen atoms. Group D: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 ,OC(O)R 21 , C(O)OR 21 The group consisting of , a cyano group, a nitro group, and a halogen atom. R 21 and R 22 are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms. Group E: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, halogen atoms, oxo groups, hydroxy groups, cyano groups, and nitro groups. Group F: a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group M, an amino group, NHR 21 , N.R. 21 R 22 , a halogen atom, and a cyano group. Group H: C1-C6 alkyl groups optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 ,OC(O)R 9 ,OC(O)OR 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group W. R 9 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, R 10 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom. Group P: C2-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C3-C6 cycloalkyl groups optionally substituted with one or more halogen atoms, Group D 2 a phenyl group optionally substituted with one or more substituents selected from Group D 2 the group consisting of a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the above, a C2-C6 alkylcarbonyl group optionally substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group optionally substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group optionally substituted by one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group optionally substituted by one or more halogen atoms. Group J: A group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. Group K: a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, and a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group M. Group T: a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group M, an amino group, NHR 21 , N.R. 21 R 22 , a halogen atom, and a cyano group. Group U: A group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. Group V: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 ,OC(O)R 21 , C(O)OR 21 The group consisting of , a cyano group, a nitro group, and a halogen atom. Group W: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 ,OC(O)R 21 , C(O)OR 21 The group consisting of , a cyano group, a nitro group, and a halogen atom. Group L 2 The group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group D 2: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 ,OC(O)R 21 , C(O)OR 21 The group consisting of , a cyano group, a nitro group, and a halogen atom. Group E 2 The group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group. Group F 2 C1-C6 alkoxy group optionally substituted with one or more halogen atoms, phenyl group optionally substituted with one or more substituents selected from group D, 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, amino group, NHR 21 , N.R. 21 R 22 , a halogen atom, and a cyano group. Group H 2 : a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R10 , C(O)NR 9 R 10 ,OC(O)R 9 ,OC(O)OR 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group W. Group J 2 : The group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. Group L 3 The group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group D 3 : a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21,OC(O)R 21 , C(O)OR 21 The group consisting of , a cyano group, a nitro group, and a halogen atom. Group E 3 The group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group. Group F 3 C1-C6 alkoxy group optionally substituted with one or more halogen atoms, phenyl group optionally substituted with one or more substituents selected from group D, 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, amino group, NHR 21 , N.R. 21 R 22 , a halogen atom, and a cyano group. Group H 3 : a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 ,OC(O)R 9 ,OC(O)OR 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group W. Group J 3 The group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. or an N-oxide thereof (hereinafter, the compound represented by formula (I) or the N-oxide thereof will be referred to as the present compound) to harmful arthropods, habitats of harmful arthropods, plants, or cultivation carriers of plants. [2] The method for controlling arthropod pests according to [1], wherein the plant cultivation carrier is soil. [3] A composition containing the compound represented by formula (I) according to [1] or an N-oxide or an agriculturally acceptable salt thereof, and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i), and group (j): Group (a): A group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): Fungicidally active ingredients; Group (c): Plant growth regulating components; Group (d): phytotoxicity-reducing components; Group (e): synergists; Group (f): repellent components; Group (g): molluscicidal ingredients; Group (h): Signal transducers consisting of pheromones and allelochemicals used by insects; Group (i): herbicidal active ingredients; Group (j): Biological control materials. [4] A method for controlling arthropod pests, comprising the step of applying an effective amount of the composition according to [3] to arthropod pests, habitats of arthropod pests, plants, or cultivation carriers of plants. [5] The method for controlling arthropod pests according to [4], wherein the plant cultivation carrier is soil. [6] A seed or a vegetative reproductive organ containing an effective amount of the compound represented by formula (I) according to [1], or an N-oxide or an agriculturally acceptable salt thereof, or the composition according to [3]. [Effects of the Invention]

[0010] According to the present invention, arthropod pests can be controlled. DETAILED DESCRIPTION OF THE INVENTION

[0011] First, the present compound will be explained.

[0012] The substituents in the present invention will be explained. A halogen atom means a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom. When a substituent is substituted with two or more halogen atoms or substituents, the halogen atoms or substituents may be the same or different. In this specification, the notation "CX-CY" means that the number of carbon atoms is X to Y. For example, the notation "C1-C6" means that the number of carbon atoms is 1 to 6. The chain hydrocarbon group represents an alkyl group, an alkenyl group, or an alkynyl group. Examples of alkyl groups include methyl, ethyl, propyl, isopropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-ethylpropyl, butyl, sec-butyl, tert-butyl, pentyl, and hexyl groups. Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl groups. Examples of the alkynyl group include an ethynyl group, a 1-propynyl group, a 2-propynyl group, a 1-methyl-2-propynyl group, a 1,1-dimethyl-2-propynyl group, a 1-ethyl-2-propynyl group, a 2-butynyl group, a 4-pentynyl group, and a 5-hexynyl group. Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, and hexyloxy groups. Examples of the alkenyloxy group include a 2-propenyloxy group, a 2-butenyloxy group, and a 5-hexenyloxy group. Examples of the alkynyloxy group include a 2-propynyloxy group, a 2-butynyloxy group, and a 5-hexynyloxy group.

[0013] Examples of cycloalkyl groups include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and cycloheptyl groups. Examples of cycloalkenyl groups include cyclopropenyl, cyclobutenyl, cyclopentenyl, cyclohexenyl, and cycloheptenyl groups.

[0014] Examples of the 3- to 7-membered non-aromatic heterocyclic group include an aziridinyl group, an oxiranyl group, a thiiranyl group, an azetidinyl group, an oxetanyl group, a thietanyl group, a pyrrolidinyl group, a tetrahydrofuranyl group, a tetrahydrothienyl group, a piperidyl group, a pyranyl group, a dihydropyranyl group, a tetrahydropyranyl group, a tetrahydrothiopyranyl group, an azepanyl group, an oxepanyl group, a thiepanyl group, a pyrazolinyl group, a pyrazolidinyl group, an imidazolinyl group, an imidazolidinyl group, an oxazolinyl group, a thiazolinyl group, an oxazolidinyl group, a thiazolidinyl group, an isoxazolinyl group, an isoxazolidinyl group, an isothiazolinyl group, an isothiazolidinyl group, a dioxolyl group, a dioxolanyl group, a dioxanyl group, a morpholinyl group, a thiomorpholinyl group, and a piperazinyl group. Examples of the 5- or 6-membered aromatic heterocyclic group include a pyrrolyl group, a furyl group, a thienyl group, a pyrazolyl group, an imidazolyl group, a triazolyl group, a tetrazolyl group, an oxazolyl group, an isoxazolyl group, a thiazolyl group, an isothiazolyl group, an oxadiazolyl group, a thiadiazolyl group, a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group. Examples of the 6-membered aromatic heterocyclic group include a pyridyl group, a pyridazinyl group, a pyrimidinyl group, a pyrazinyl group, a triazinyl group, and a tetrazinyl group. Examples of the (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms include a cyclopropylmethyl group, a (2-fluorocyclopropyl)methyl group, a cyclopropyl(fluoro)methyl group, and a (2-fluorocyclopropyl)(fluoro)methyl group. The (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms refers to a group in which a (C3-C7 cycloalkyl) and / or a (C1-C6 alkyl) is optionally substituted with one or more halogen atoms, and examples thereof include a (2,2-difluorocyclopropyl)methyl group, a 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, a 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl group, a (2,2-difluorocyclopropyl)propyl group, a (2,2-difluorocyclopropyl)butyl group, a (2,2-difluorocyclopropyl)pentyl group, and a (2,2-difluorocyclopropyl)hexyl group. Examples of the phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D}, the phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D2}, and the phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D3} include a benzyl group, a 2-fluorobenzyl group, a 4-chlorobenzyl group, a 4-(trifluoromethyl)benzyl group, and a 2-[4-(trifluoromethyl)phenyl]ethyl group. Examples of the alkylsulfanyl group include a methylsulfanyl group, an ethylsulfanyl group, a propylsulfanyl group, and an isopropylsulfanyl group. Examples of the alkylsulfinyl group include a methylsulfinyl group, an ethylsulfinyl group, a propylsulfinyl group, and an isopropylsulfinyl group. Examples of alkylsulfonyl groups include methylsulfonyl groups, ethylsulfonyl groups, propylsulfonyl groups, and isopropylsulfonyl groups. Examples of the alkylcarbonyl group include an acetyl group, a propanoyl group, a 2-methylpropanoyl group, and a hexanoyl group. Examples of the alkoxycarbonyl group include a methoxycarbonyl group, an ethoxycarbonyl group, an isopropoxycarbonyl group, and a pentyloxycarbonyl group. Examples of the (C1-C6 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms include a methylaminocarbonyl group, a trifluoromethylaminocarbonyl group, an isopropylaminocarbonyl group, and a hexylaminocarbonyl group. Examples of the di(C1-C4 alkyl)aminocarbonyl group optionally substituted with one or more halogen atoms include a dimethylaminocarbonyl group, a methylethylaminocarbonyl group, a trifluoromethylethylaminocarbonyl group, and a diisopropylaminocarbonyl group.

[0015] Examples of the N-oxide of the compound represented by formula (I) include the compounds represented by the following formula:

[0016] [ka] (wherein the symbols have the same meanings as defined above.)

[0017] The present compound may exist in one or more stereoisomers. Stereoisomers include enantiomers, diastereomers, and geometric isomers. The present compound includes each stereoisomer and a mixture of stereoisomers in any ratio.

[0018] The present compound may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. The acid addition salt can be obtained by mixing the present compound with an acid.

[0019] Next, the method for producing the present compound will be explained.

[0020] Manufacturing method 1 A compound represented by formula (Ib) (hereinafter referred to as compound (Ib)) or a compound represented by formula (Ic) (hereinafter referred to as compound (Ic)) can be produced by reacting a compound represented by formula (Ia) (hereinafter referred to as compound (Ia)) with an oxidizing agent.

[0021] [ka] [In the formula, the symbols have the same meanings as defined above.]

[0022] First, a method for producing compound (Ib) from compound (Ia) will be described. The reaction is usually carried out in a solvent, such as halogenated hydrocarbons (hereinafter referred to as halogenated hydrocarbons) such as dichloromethane and chloroform, nitriles (hereinafter referred to as nitriles) such as acetonitrile, alcohols (hereinafter referred to as alcohols) such as methanol and ethanol, acetic acid, water, and mixtures of two or more of these. Examples of the oxidizing agent include sodium periodate, m-chloroperbenzoic acid (hereinafter referred to as mCPBA), and hydrogen peroxide. When hydrogen peroxide is used as the oxidizing agent, a base or a catalyst may be used as necessary. An example of the base is sodium carbonate. When a base is used in the reaction, the base is usually used in a proportion of 0.01 to 1 mole per mole of compound (Ia). Examples of the catalyst include tungstic acid and sodium tungstate. When a catalyst is used in the reaction, the catalyst is usually used in a proportion of 0.01 to 0.5 moles per mole of compound (Ia). In the reaction, the oxidizing agent is usually used in a proportion of 1 to 1.2 moles per mole of compound (Ia). The reaction temperature is usually in the range of −20° C. to 80° C. The reaction time is usually in the range of 0.1 to 12 hours. After the reaction is complete, water is added to the reaction mixture, which is then extracted with an organic solvent. The organic layer is washed with an aqueous solution of a reducing agent (e.g., sodium sulfite or sodium thiosulfate) and an aqueous solution of a base (e.g., sodium bicarbonate) as needed. The organic layer is dried and concentrated to obtain compound (Ib).

[0023] Next, a method for producing compound (Ic) from compound (Ib) will be described. The reaction is usually carried out in a solvent, such as halogenated hydrocarbons, nitriles, alcohols, acetic acid, water, or a mixture of two or more of these. Oxidizing agents include, for example, mCPBA and hydrogen peroxide. When hydrogen peroxide is used as the oxidizing agent, a base or a catalyst may be used as necessary. An example of the base is sodium carbonate. When a base is used in the reaction, the base is usually used in a proportion of 0.01 to 1 mole per mole of compound (Ib). An example of the catalyst is sodium tungstate. When a catalyst is used in the reaction, the catalyst is usually used in a proportion of 0.01 to 0.5 moles per mole of compound (Ib). In the reaction, the oxidizing agent is usually used in a ratio of 1 to 2 moles per mole of compound (Ib). The reaction temperature is usually in the range of −20° C. to 120° C. The reaction time is usually in the range of 0.1 to 12 hours. After the reaction is complete, water is added to the reaction mixture, which is then extracted with an organic solvent. The organic layer is washed with an aqueous solution of a reducing agent (e.g., sodium sulfite or sodium thiosulfate) and an aqueous solution of a base (e.g., sodium bicarbonate) as needed. Compound (Ic) can be obtained by drying and concentrating the organic layer.

[0024] Compound (Ic) can also be produced in a one-step reaction (one-pot) by reacting compound (Ia) with an oxidizing agent. The reaction can be carried out in accordance with the method for producing compound (Ic) from compound (Ib) using an oxidizing agent usually in a proportion of 2 to 5 moles per mole of compound (Ia).

[0025] Manufacturing method 2 The compound represented by formula (IS-1) (hereinafter referred to as compound (IS-1)) can be produced by reacting a compound represented by formula (IO-1) (hereinafter referred to as compound (IO-1)) with a sulfurizing agent.

[0026] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is carried out in a solvent or in the absence of a solvent. Examples of the solvent include ethers (hereinafter referred to as ethers) such as tetrahydrofuran (hereinafter referred to as THF), methyl tert-butyl ether (hereinafter referred to as MTBE), ethylene glycol dimethyl ether, 1,4-dioxane, and cyclopentyl methyl ether; halogenated hydrocarbons; aromatic hydrocarbons (hereinafter referred to as aromatic hydrocarbons) such as toluene and xylene; nitriles; nitrogen-containing aromatic compounds (hereinafter referred to as nitrogen-containing aromatic compounds) such as pyridine, picoline, lutidine, and quinoline; and mixtures of two or more of these. Examples of the sulfurizing agent include diphosphorus pentasulfide and Lawesson's reagent (2,4-bis(4-methoxyphenyl)-1,3-dithia-2,4-diphosphetane-2,4-disulfide). In the reaction, the sulfurizing agent is usually used in a proportion of 1 mole to 3 moles per mole of compound (IO-1). The reaction temperature is usually in the range of 0° C. to 200° C. The reaction time is usually in the range of 1 to 24 hours. After the reaction is complete, the compound (IS-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatments such as drying and concentrating the organic layer.

[0027] Manufacturing method 3 The compound represented by formula (IS-2) (hereinafter referred to as compound (IS-2)) can be produced by reacting a compound represented by formula (IO-2) (hereinafter referred to as compound (IO-2)) with a sulfiding agent.

[0028] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IS-2) can be produced according to Production Method 2, using compound (IO-2) instead of compound (IO-1).

[0029] Manufacturing method 4 Compound (IO-1) can be produced by reacting a compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) with a compound represented by formula (M-2) (hereinafter referred to as compound (M-2)) in the presence of a base.

[0030] [ka] [In the formula, Xa represents a leaving group such as a fluorine atom, a chlorine atom, a bromine atom, or an iodine atom, and the other symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents (hereinafter referred to as aprotic polar solvents) such as N,N-dimethylformamide (hereinafter referred to as DMF), N-methylpyrrolidone (hereinafter referred to as NMP), and dimethyl sulfoxide (hereinafter referred to as DMSO), and mixtures of two or more of these solvents. Examples of the base include organic bases such as triethylamine, N,N-diisopropylethylamine, pyridine, and 4-(dimethylamino)pyridine (hereinafter referred to as organic bases); alkali metal carbonates such as sodium carbonate, potassium carbonate, and cesium carbonate (hereinafter referred to as alkali metal carbonates); and alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides). The reaction can also be carried out using a metal catalyst, if necessary. Examples of metal catalysts include copper catalysts such as copper(I) iodide, copper(I) bromide, copper(I) chloride, copper(I) oxide, copper(I) trifluoromethanesulfonate benzene complex, tetrakis(acetonitrile)copper(I) hexafluorophosphate, and copper(I) 2-thiophenecarboxylate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), and tris(dibenzylideneacetone)dipalladium(0). When a metal catalyst is used in the reaction, the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-1). The reaction can also be carried out using a ligand, if necessary. Examples of the ligand include triphenylphosphine, 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (hereinafter referred to as Xantphos), 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When a ligand is used in the reaction, the ligand is usually used in a proportion of 0.01 to 0.5 moles per mole of compound (M-1). In the reaction, the compound (M-2) is usually used in a proportion of 0.8 to 1.2 moles and the base is usually used in a proportion of 1 to 3 moles per mole of the compound (M-1). The reaction temperature is usually in the range of −20° C. to 150° C. The reaction time is usually in the range of 0.5 to 24 hours. After the reaction is complete, the compound (IO-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer. Compound (M-1) is a commercially available compound, or can be produced, for example, according to the method described in WO 2013 / 192346.

[0031] Manufacturing method 5 Compound (IO-2) can be produced by reacting a compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) with compound (M-2) in the presence of a base.

[0032] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction can be carried out according to Production Method 4, using compound (M-3) instead of compound (M-1). Compound (M-3) is a commercially available compound or can be prepared using known methods.

[0033] Manufacturing method 6 The compound represented by formula (I-n0-1) (hereinafter referred to as compound (I-n0-1)) can be produced according to the following scheme.

[0034] [ka] [In the formula, Xd represents a chlorine atom, a bromine atom, or an iodine atom, and the other symbols have the same meanings as defined above.] First, a method for producing the compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) will be described. Compound (M-5) can be produced in accordance with Production Method 4, using a compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) instead of compound (M-2).

[0035] Next, a method for producing the compound represented by formula (M-6) (hereinafter referred to as compound (M-6)) will be described. The compound (M-6) can be produced by reacting the compound (M-5) with a halogenating agent. The reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these. Examples of halogenating agents include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, and N-iodosuccinimide. In the reaction, the halogenating agent is usually used in a proportion of 1 to 20 moles per mole of compound (M-5). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is complete, the compound (M-6) can be obtained by post-treatment such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

[0036] Next, a method for producing compound (I-n0-1) from compound (M-5) will be described. Compound (I-n0-1) can be produced by reacting compound (M-5), a compound represented by formula (R-1) (hereinafter referred to as compound (R-1)), and a halogenating agent. The reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these. Examples of halogenating agents include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, and N-iodosuccinimide. In the reaction, the compound (R-1) is usually used in a proportion of 1 to 20 moles and the halogenating agent is usually used in a proportion of 1 to 20 moles per mole of the compound (M-5). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is complete, compound (I-n0-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer. Compound (R-1) is a commercially available compound or can be prepared using known methods.

[0037] Next, a method for producing compound (I-n0-1) from compound (M-6) will be described. Compound (I-n0-1) can also be produced by reacting compound (M-6) with compound (R-1) in the presence of a metal catalyst and a base. The reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these. Examples of the metal catalyst include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and copper catalysts such as copper(I) iodide and copper(I) chloride. Examples of the base include alkali metal hydrides, alkali metal carbonates, and organic bases. A ligand can also be used in the reaction. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline. When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 1 mole per mole of compound (M-6). In the reaction, compound (R-1) is usually used in a proportion of 1 to 20 moles, metal catalyst is usually used in a proportion of 0.01 to 0.5 moles, and base is usually used in a proportion of 0.1 to 5 moles, relative to 1 mole of compound (M-6). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is complete, compound (I-n0-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0038] Manufacturing method 7 The compound represented by formula (I-n0-2) (hereinafter referred to as compound (I-n0-2)) can be produced according to the following scheme.

[0039] [ka] [In the formula, the symbols have the same meanings as defined above.] The compound represented by formula (M-7) (hereinafter referred to as compound (M-7)) can be produced according to Production Method 6, using compound (M-3) instead of compound (M-1).

[0040] The compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) can be produced in accordance with the method for producing compound (M-6) from compound (M-5) in Production Method 6, using compound (M-7) instead of compound (M-5).

[0041] Compound (I-n0-2) can be produced in accordance with the method for producing compound (I-n0-1) from compound (M-5) in Production Method 6, using compound (M-7) instead of compound (M-5).

[0042] Compound (I-n0-2) can also be produced by using compound (M-8) instead of compound (M-6) in accordance with the method for producing compound (I-n0-1) from compound (M-6) in Production Method 6.

[0043] Manufacturing method 8 Compound (IO-1) can also be produced by reacting a compound represented by formula (M-9-X) (hereinafter referred to as compound (M-9-X)) with a base.

[0044] [ka] [In the formula, XA represents a chlorine atom, a bromine atom, or an iodine atom, and the other symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these. Examples of the base include organic bases; alkali metal carbonates; and alkali metal hydrides. The reaction can also be carried out using a metal catalyst, if necessary. Examples of metal catalysts include copper catalysts such as copper(I) iodide, copper(I) bromide, copper(I) chloride, copper(I) oxide, copper(I) trifluoromethanesulfonate benzene complex, tetrakis(acetonitrile)copper(I) hexafluorophosphate, and copper(I) 2-thiophenecarboxylate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), and tris(dibenzylideneacetone)dipalladium(0). When a metal catalyst is used in the reaction, the metal catalyst is typically used in a ratio of 0.01 to 0.5 moles per mole of compound (M-9-X). The reaction can also be carried out using a ligand, if necessary. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When a ligand is used in the reaction, the ligand is typically used in a ratio of 0.01 to 0.5 moles per mole of compound (M-9-X). In the reaction, the base is usually used in a proportion of 1 to 5 moles per mole of compound (M-9-X). The reaction temperature is usually in the range of −20° C. to 150° C. The reaction time is usually in the range of 0.5 to 24 hours. After the reaction is complete, the compound (IO-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0045] Manufacturing method 9 Compound (IO-1) can also be produced by intramolecular condensation of a compound represented by formula (M-9-OH) (hereinafter referred to as compound (M-9-OH)) in the presence of a condensing agent.

[0046] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters such as ethyl acetate and butyl acetate (hereinafter referred to as esters), nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these. The condensing agent used in the reaction may be, for example, a mixture of triphenylphosphine and an azodiester compound, such as diethyl azodicarboxylate. In the reaction, the condensing agent is usually used in a proportion of 1 to 5 moles per mole of the compound (M-9-OH). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the compound (IO-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0047] Manufacturing method 10 Compound (IO-1) can also be produced by reacting a compound represented by formula (M-10-X) (hereinafter referred to as compound (M-10-X)) with a base.

[0048] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1) can also be produced according to Production Method 8, using compound (M-10-X) instead of compound (M-9-X).

[0049] Manufacturing method 11 Compound (IO-1) can also be produced by intramolecular condensation of a compound represented by formula (M-10-OH) (hereinafter referred to as compound (M-10-OH)) in the presence of a condensing agent.

[0050] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1) can also be produced according to Production Method 9, using compound (M-10-OH) instead of compound (M-9-OH).

[0051] Manufacturing method 12 The compound represented by formula (Ibp) (hereinafter referred to as compound (Ibp)) or the compound represented by formula (Icp) (hereinafter referred to as compound (Icp)) can be produced by reacting a compound represented by formula (Iap) (hereinafter referred to as compound (Iap)) with an oxidizing agent.

[0052] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (Ibp) can be produced according to Production Method 1, using compound (Iap) instead of compound (Ia). Compound (Icp) can be produced according to Production Method 1, using compound (Ibp) instead of compound (Ib). Compound (Icp) can also be produced according to Production Method 1, using compound (Iap) instead of compound (Ia).

[0053] Manufacturing method 13 The compound represented by formula (IS-1p) (hereinafter referred to as compound (IS-1p)) can be produced by reacting a compound represented by formula (IO-1p) (hereinafter referred to as compound (IO-1p)) with a sulfurizing agent.

[0054] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IS-1p) can be produced according to Production Method 2, using compound (IO-1p) instead of compound (IO-1).

[0055] Manufacturing method 14 The compound represented by formula (IS-2p) (hereinafter referred to as compound (IS-2p)) can be produced by reacting a compound represented by formula (IO-2p) (hereinafter referred to as compound (IO-2p)) with a sulfiding agent.

[0056] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IS-2p) can be produced according to Production Method 2, using compound (IO-2p) instead of compound (IO-1).

[0057] Manufacturing method 15 Compound (IO-1p) can be produced by reacting compound (M-1) with a compound represented by formula (M-11) (hereinafter referred to as compound (M-11)) in the presence of a base.

[0058] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 4, using compound (M-11) instead of compound (M-2).

[0059] Manufacturing method 16 Compound (IO-2p) can be produced by reacting compound (M-3) with compound (M-11) in the presence of a base.

[0060] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2p) can be produced according to Production Method 5, using compound (M-11) instead of compound (M-2).

[0061] Manufacturing method 17 The compound represented by formula (I-n0-1p) (hereinafter referred to as compound (I-n0-1p)) can be produced according to the following scheme.

[0062] [ka] [In the formula, the symbols have the same meanings as defined above.] The compound represented by formula (M-13) (hereinafter referred to as compound (M-13)) can be produced according to Production Method 6, using compound (M-12) instead of compound (M-4). Compound (M-12) is a commercially available compound or can be prepared using known methods.

[0063] The compound represented by formula (M-14) (hereinafter referred to as compound (M-14)) can be produced in accordance with the method for producing compound (M-6) from compound (M-5) in Production Method 6, using compound (M-13) instead of compound (M-5).

[0064] Compound (I-n0-1p) can also be produced by using compound (M-13) instead of compound (M-5) in accordance with the method for producing compound (I-n0-1) from compound (M-5) in Production Method 6.

[0065] Compound (I-n0-1p) can also be produced by using compound (M-14) instead of compound (M-6) in accordance with the method for producing compound (I-n0-1) from compound (M-6) in Production Method 6.

[0066] Manufacturing method 18 The compound represented by formula (I-n0-2p) (hereinafter referred to as compound (I-n0-2p)) can be produced according to the following scheme.

[0067] [ka] [In the formula, the symbols have the same meanings as defined above.] The compound represented by formula (M-15) (hereinafter referred to as compound (M-15)) can be produced according to Production Method 7, using compound (M-12) instead of compound (M-4).

[0068] The compound represented by formula (M-16) (hereinafter referred to as compound (M-16)) can be produced by using compound (M-15) instead of compound (M-7) in accordance with the method for producing compound (M-8) from compound (M-7) in Production Method 7.

[0069] Compound (I-n0-2p) can also be produced by using compound (M-15) instead of compound (M-7) in accordance with the method for producing compound (I-n0-2) from compound (M-7) in Production Method 7.

[0070] Compound (I-n0-2p) can also be produced by using compound (M-16) instead of compound (M-8) in accordance with the method for producing compound (I-n0-2) from compound (M-8) in Production Method 7.

[0071] Manufacturing method 19 Compound (IO-1p) can also be produced by reacting a compound represented by formula (M-17-X) (hereinafter referred to as compound (M-17-X)) with a base.

[0072] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 8, using compound (M-17-X) instead of compound (M-9-X).

[0073] Manufacturing method 20 Compound (IO-1p) can also be produced by intramolecular condensation of a compound represented by formula (M-17-OH) (hereinafter referred to as compound (M-17-OH)) in the presence of a condensing agent.

[0074] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 9, using compound (M-17-OH) instead of compound (M-9-OH).

[0075] Manufacturing method 21 Compound (IO-1p) can also be produced by reacting a compound represented by formula (M-18-X) (hereinafter referred to as compound (M-18-X)) with a base.

[0076] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can be produced according to Production Method 10, using compound (M-18-X) instead of compound (M-10-X).

[0077] Manufacturing method 22 Compound (IO-1p) can also be produced by intramolecular condensation of a compound represented by formula (M-18-OH) (hereinafter referred to as compound (M-18-OH)) in the presence of a condensing agent.

[0078] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-1p) can also be produced according to Production Method 11, using compound (M-18-OH) instead of compound (M-10-OH).

[0079] Manufacturing method 23 The N-oxide of the compound represented by formula (I) can be produced by reacting the compound represented by formula (I) with an oxidizing agent. The reaction can be carried out, for example, in accordance with Production Method 1, the method described in U.S. Patent Application Publication No. 2018 / 0009778, or WO 2016 / 121970.

[0080] Manufacturing method 24 The compound represented by formula (IO-1ph) (hereinafter referred to as compound (IO-1ph)) can be produced by reacting a compound represented by formula (IO-1pp) (hereinafter referred to as compound (IO-1pp)) with a compound represented by formula (Ph-BOH) (hereinafter referred to as compound (Ph-BOH)) or a compound represented by formula (Ph-Bpin) (hereinafter referred to as compound (Ph-Bpin)) in the presence of a metal catalyst and a base.

[0081] [ka] [In the formula, R 4p represents a chlorine atom, a bromine atom, or an iodine atom, and R 4h is the group H 2 represents a substituent selected from the group consisting of: y represents 0, 1, 2, 3, 4, or 5; and other symbols have the same meanings as defined above. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, or a mixture of two or more of these. Examples of the base used in the reaction include organic bases; alkali metal carbonates; alkali metal hydrides; and alkali metal phosphates such as potassium phosphate (hereinafter referred to as alkali metal phosphates). Examples of the metal catalyst used in the reaction include nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II). The reaction can also be carried out using a ligand, if necessary. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When a ligand is used in the reaction, the ligand is typically used in a ratio of 0.01 to 0.5 moles per mole of compound (IO-1pp). In the reaction, the compound (Ph-BOH) or the compound (Ph-Bpin) is usually used in a ratio of 1 to 5 moles, the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles, and the base is usually used in a ratio of 1 to 5 moles, relative to 1 mole of the compound (IO-1pp). The reaction temperature is usually in the range of −20° C. to 150° C. The reaction time is usually in the range of 0.5 to 24 hours. After the reaction is complete, the compound (IO-1ph) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0082] Manufacturing method 25 The compound represented by formula (IO-2ph) (hereinafter referred to as compound (IO-2ph)) can be produced by reacting a compound represented by formula (IO-2pp) (hereinafter referred to as compound (IO-2pp)) with compound (Ph-BOH) or compound (Ph-Bpin) in the presence of a metal catalyst and a base.

[0083] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2ph) can be produced according to Production Method 24, using compound (IO-2pp) instead of compound (IO-1pp).

[0084] Manufacturing method 26 The compound represented by formula (IO-1Ar) (hereinafter referred to as compound (IO-1Ar)) can be produced according to the following scheme.

[0085] [ka] [In the formula, A1a represents CR1a or a nitrogen atom, R1a represents a hydrogen atom or a substituent selected from the group H2, Xh represents a halogen atom, and the other symbols have the same meanings as defined above.] First, a method for producing a compound represented by formula (IO-1-Bpin) (hereinafter referred to as compound (IO-1-Bpin)) from a compound represented by formula (IO-1pa) (hereinafter referred to as compound (IO-1pa)) will be described. Compound (IO-1-Bpin) can be produced by reacting compound (IO-1pa) with Bis(pinacolato)diboron in the presence of a metal catalyst and a base. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these. Examples of the base used in the reaction include organic bases, alkali metal carbonates, alkali metal hydrides, and alkali metal phosphates. Examples of the metal catalyst used in the reaction include palladium catalysts such as [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II). In the reaction, Bis(pinacolato)diboron is usually used in a ratio of 1 to 3 moles, the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles, and the base is usually used in a ratio of 1 to 5 moles, relative to 1 mole of compound (IO-1pa). The reaction temperature is usually in the range of −20° C. to 150° C. The reaction time is usually in the range of 0.5 to 24 hours. After the reaction is complete, the compound (IO-1-Bpin) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0086] Next, a method for producing the compound (IO-1Ar) from the compound (IO-1-Bpin) will be described. Compound (IO-1Ar) can be produced by reacting compound (IO-1-Bpin) with a compound represented by formula (Ar-hal) (hereinafter referred to as compound (Ar-hal)) in the presence of a metal catalyst and a base. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, or a mixture of two or more of these. Examples of the base used in the reaction include organic bases, alkali metal carbonates, alkali metal hydrides, and alkali metal phosphates. Examples of the metal catalyst used in the reaction include palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II). The reaction can also be carried out using a ligand, if necessary. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When a ligand is used in the reaction, the ligand is usually used in a proportion of 0.01 to 0.5 moles per mole of the compound (IO-1-Bpin). In the reaction, the compound (Ar-hal) is usually used in a ratio of 1 to 5 moles, the metal catalyst is usually used in a ratio of 0.01 to 0.5 moles, and the base is usually used in a ratio of 1 to 5 moles, relative to 1 mole of the compound (IO-1-Bpin). The reaction temperature is usually in the range of −20° C. to 150° C. The reaction time is usually in the range of 0.5 to 24 hours. After the reaction is complete, the compound (IO-1Ar) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0087] Manufacturing method 27 The compound represented by formula (IO-2Ar) (hereinafter referred to as compound (IO-2Ar)) can be produced according to the following scheme.

[0088] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2Ar) can be produced from compound (IO-2-Bpin) produced according to Production Method 26, using compound (IO-2pa) instead of compound (IO-1pa), in accordance with Production Method 26.

[0089] Manufacturing method 28 The compound represented by formula (IO-1NBoc) (hereinafter referred to as compound (IO-1NBoc)) can be produced by reacting compound (IO-1pp) with tert-butyl carbamate in the presence of a metal catalyst and a base.

[0090] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these. Examples of the base used in the reaction include organic bases, alkali metal carbonates, alkali metal hydrides, and alkali metal phosphates. Examples of the metal catalyst used in the reaction include nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and palladium catalysts such as palladium(II) acetate, tetrakis(triphenylphosphine)palladium(0), tris(dibenzylideneacetone)dipalladium(0), and [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(II). The reaction can also be carried out using a ligand, if necessary. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When a ligand is used in the reaction, the ligand is typically used in a ratio of 0.01 to 0.5 moles per mole of compound (IO-1pp). In the reaction, tert-butyl carbamate is usually used in a proportion of 1 to 5 moles, the metal catalyst is usually used in a proportion of 0.01 to 0.5 moles, and the base is usually used in a proportion of 1 to 5 moles, relative to 1 mole of compound (IO-1pp). The reaction temperature is usually in the range of −20° C. to 150° C. The reaction time is usually in the range of 0.5 to 24 hours. After the reaction is complete, the compound (IO-1NBoc) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0091] Manufacturing method 29 The compound represented by formula (IO-2NBoc) (hereinafter referred to as compound (IO-2NBoc)) can be produced by reacting compound (IO-2pp) with tert-butyl carbamate in the presence of a metal catalyst and a base.

[0092] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2NBoc) can be produced according to Production Method 28, using compound (IO-2pp) instead of compound (IO-1pp).

[0093] Manufacturing method 30 The compound represented by the formula (IO-1NH2) (hereinafter referred to as the compound (IO-1NH2)) can be produced by reacting the compound (IO-1NBoc) with an acid.

[0094] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as halogenated hydrocarbons, ethers, alcohols, water, or a mixture of two or more of these. The acid used in the reaction includes, for example, mineral acids such as hydrochloric acid; and carboxylic acids such as trifluoroacetic acid. In the reaction, the acid is usually used in a proportion of 1 to 50 moles per mole of compound (IO-1NBoc). The reaction temperature is usually in the range of 0° C. to 120° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the reaction mixture is extracted with an organic solvent, and the organic layer is dried, concentrated, and other post-treatment procedures are carried out to obtain the compound (IO-1NH2).

[0095] Manufacturing method 31 The compound represented by the formula (IO-2NH2) (hereinafter referred to as the compound (IO-2NH2)) can be produced by reacting the compound (IO-2NBoc) with an acid.

[0096] [ka] [In the formula, the symbols have the same meanings as defined above.] The compound (IO-2NH2) can be produced according to Production Method 30, using the compound (IO-2NBoc) instead of the compound (IO-1NBoc).

[0097] Manufacturing method 32 The compound represented by formula (IO-1-NHamide) (hereinafter referred to as compound (IO-1-NHamide)) can be produced by reacting compound (IO-1NH2) with a compound represented by formula (R-13) (hereinafter referred to as compound (R-13)).

[0098] [ka] [In the formula, R Alkyl represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, group D 2 a phenyl group optionally substituted with one or more substituents selected from the group D 2 and the other symbols have the same meanings as above.] The reaction is usually carried out in a solvent, such as ethers, aliphatic hydrocarbons such as hexane, heptane, and octane (hereinafter referred to as aliphatic hydrocarbons), aromatic hydrocarbons, halogenated hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these. A base can be used in the reaction as needed. Examples of the base used in the reaction include alkali metal carbonates; alkali metal hydroxides such as sodium hydroxide and potassium hydroxide (hereinafter referred to as alkali metal hydroxides); and organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 2 moles per mole of compound (IO-1NH2). In the reaction, the compound (R-13) is usually used in a proportion of 0.8 to 2 moles per mole of the compound (IO-1NH2). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the compound (IO-1-NHamide) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer. Compound (R-13) is a commercially available compound or can be prepared using known methods.

[0099] Manufacturing method 33 The compound represented by the formula (IO-2-NHamide) (hereinafter referred to as compound (IO-2-NHamide)) can be produced by reacting compound (IO-2NH2) with compound (R-13).

[0100] [ka] [In the formula, the symbols have the same meanings as defined above.] The compound (IO-2-NHamide) can be produced according to Production Method 32, using the compound (IO-2NH2) instead of the compound (IO-1NH2).

[0101] Manufacturing method 34 The compound represented by formula (IO-1-amide) (hereinafter referred to as compound (IO-1-amide)) can be produced by reacting compound (IO-1-NHamide) with compound (R-14) in the presence of a base.

[0102] [ka] [In the formula, L2 represents a leaving group such as a chlorine atom, a bromine atom, or an iodine atom, Ramide represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, and the other symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these. Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases. In the reaction, the compound (R-14) is usually used in a proportion of 1 to 5 moles, and the base is usually used in a proportion of 1 to 5 moles, relative to 1 mole of the compound (IO-1-NHamide). The reaction temperature is usually in the range of 0° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the compound (IO-1-amide) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer. Compound (R-14) is a commercially available compound or can be prepared using known methods.

[0103] Manufacturing method 35 The compound represented by formula (IO-2-amide) (hereinafter referred to as compound (IO-2-amide)) can be produced by reacting compound (IO-2-NHamide) with compound (R-14) in the presence of a base.

[0104] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (IO-2-amide) can be produced according to Production Method 34, using compound (IO-2-NHamide) instead of compound (IO-1-NHamide).

[0105] Manufacturing method 36 The compound represented by formula (IO-1-OH) (hereinafter referred to as compound (IO-1-OH)) can be produced by reacting compound (IO-1-OBn) with hydrogen in the presence of a catalyst.

[0106] [ka] [In the formula, the symbols have the same meanings as defined above.] Hydrogen gas is used in the reaction, and the pressure of the hydrogen gas is usually 1 to 100 atmospheres. The reaction is usually carried out in a solvent, such as ethers, esters, alcohols, water, or a mixture of two or more of these. Examples of catalysts used in the reaction include transition metal compounds such as palladium on carbon, palladium (II) hydroxide, Raney nickel, and platinum oxide. In the reaction, the catalyst is usually used in a proportion of 0.001 to 0.5 moles per mole of compound (IO-1-OBn). The reaction can be carried out using an acid, a base, etc., if necessary. Examples of the acid include acetic acid and hydrochloric acid, and examples of the base include tertiary amines such as triethylamine. When an acid is used in the reaction, the acid is usually used in a ratio of 0.001 to 0.5 moles per mole of compound (IO-1-OBn). When a base is used in the reaction, the base is usually used in a ratio of 0.1 to 5 moles per mole of compound (IO-1-OBn). The reaction temperature is usually in the range of −20° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the reaction mixture is filtered, and if necessary, extracted with an organic solvent, and the organic layer is dried, concentrated, and other post-treatment procedures are carried out to obtain the compound (IO-1-OH).

[0107] Manufacturing method 37 The compound represented by the formula (IO-2-OH) (hereinafter referred to as compound (IO-2-OH)) can be produced by reacting compound (IO-2-OBn) with hydrogen in the presence of a catalyst.

[0108] [ka] [In the formula, the symbols have the same meanings as defined above.] The compound (IO-2-OH) can be produced according to Production Method 36, using the compound (IO-2-OBn) instead of the compound (IO-1-OBn).

[0109] Manufacturing method 38 The compound represented by formula (IO-1-OAlkyl) (hereinafter referred to as compound (IO-1-OAlkyl)) can be produced by reacting compound (IO-1-OH) with a compound represented by formula (R-15) (hereinafter referred to as compound (R-15)) in the presence of a base.

[0110] [ka] [In the formula, L3 represents a leaving group such as a chlorine atom, a bromine atom, or an iodine atom; R OH is the group F 2 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 2 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from Group J 2 a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from Group D 2 a phenyl group optionally substituted with one or more substituents selected from the group D 2 and the other symbols have the same meanings as above.] The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these. Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases. In the reaction, the compound (R-15) is usually used in a proportion of 1 to 5 moles, and the base is usually used in a proportion of 1 to 5 moles, relative to 1 mole of the compound (IO-1-OH). The reaction temperature is usually in the range of 0° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the compound (IO-1-OAlkyl) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer. Compound (R-15) is a commercially available compound or can be prepared using known methods.

[0111] Manufacturing method 39 The compound represented by the formula (IO-2-OAlkyl) (hereinafter referred to as compound (IO-2-OAlkyl)) can be produced by reacting compound (IO-2-OH) with compound (R-15) in the presence of a base.

[0112] [ka] [In the formula, the symbols have the same meanings as defined above.] The compound (IO-2-OAlkyl) can be produced according to Production Method 38, using the compound (IO-2-OH) instead of the compound (IO-1-OH).

[0113] The methods for producing intermediates are described below.

[0114] Reference manufacturing method 1 The compound represented by formula (M-2-n1) and the compound represented by formula (M-2-n2) can be produced by reacting the compound represented by formula (M-2-n0) with an oxidizing agent.

[0115] [ka] [In the formula, the symbols have the same meanings as defined above.] These reactions can be carried out according to Production Method 1.

[0116] Reference manufacturing method 2 The compound represented by formula (M-2-d) (hereinafter referred to as compound (M-2-d)) can be produced according to the following scheme.

[0117] [ka] [In the formula, Xc represents a chlorine atom or a bromine atom, R52 represents a hydrogen atom, a methyl group, or an ethyl group, and the other symbols have the same meanings as defined above.] The compound represented by formula (M-20) (hereinafter referred to as compound (M-20)) can be produced by reacting a compound represented by formula (M-19) (hereinafter referred to as compound (M-19)) with a compound represented by formula (R-6) (hereinafter referred to as compound (R-6)). The reaction is usually carried out in a solvent, such as aromatic hydrocarbons, alcohols, nitriles, and mixtures of two or more of these. In the reaction, the compound (M-19) is usually used in a proportion of 1 to 10 moles per mole of the compound (R-6). The reaction temperature is usually in the range of 0° C. to 200° C. The reaction time is usually in the range of 0.1 to 48 hours. After completion of the reaction, compound (M-20) can be obtained by carrying out a usual post-treatment. Compound (R-6) and compound (M-19) are commercially available compounds or can be prepared using known methods.

[0118] The compound represented by formula (M-21) (hereinafter referred to as compound (M-21)) can be produced by reacting compound (M-20) with a compound represented by formula (R-7) (hereinafter referred to as compound (R-7)). The reaction is usually carried out in a solvent, such as aromatic hydrocarbons, nitriles, and mixtures of two or more of these. In the reaction, the compound (R-7) is usually used in a proportion of 1 to 10 moles per mole of the compound (M-20). The reaction temperature is usually in the range of 60° C. to 120° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is complete, the compound (M-21) can be obtained by carrying out a usual post-treatment. Compound (R-7) is a commercially available compound or can be prepared using known methods.

[0119] The compound represented by formula (M-22) (hereinafter referred to as compound (M-22)) can be produced by reacting compound (M-21) with N-iodosuccinimide. The reaction can be carried out in accordance with the method for producing compound (M-6) from compound (M-5) in Production Method 6.

[0120] Compound (M-2-d) can be produced by reacting compound (M-21) or compound (M-22) with compound (R-1). This reaction can be carried out in accordance with the method for producing compound (I-n0-1) from compound (M-5) or compound (M-6) in Production Method 6.

[0121] Reference manufacturing method 3 The compound represented by formula (M-2-f) can be produced by reacting a compound represented by formula (M-2-e) (hereinafter referred to as compound (M-2-e)) with silver fluoride in the presence of a metal catalyst.

[0122] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction can be carried out, for example, according to the method described in Journal of the American Chemical Society, 2014, 136, 3792.

[0123] Reference manufacturing method 4 The compound represented by formula (M-2-g) can be produced by reacting the compound (M-2-e) with sodium iodide in the presence of a metal catalyst.

[0124] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction can be carried out, for example, according to the method described in Journal of the American Chemical Society, 2002, 124, 14844.

[0125] Reference manufacturing method 5 Compound (M-9-X) can be produced by reacting a compound represented by formula (M-23) (hereinafter referred to as compound (M-23)) with a compound represented by formula (M-24) (hereinafter referred to as compound (M-24)) in the presence of a condensing agent.

[0126] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these. The condensing agent used in the reaction includes, for example, carbodiimide compounds such as 1-ethyl-3-[3-(dimethylamino)propyl]carbodiimide hydrochloride and 1,3-dicyclohexylcarbodiimide. A catalyst can be used in the reaction if necessary. Examples of the catalyst used in the reaction include 1-hydroxybenzotriazole. When a catalyst is used in the reaction, the catalyst is usually used in a ratio of 0.01 to 0.5 moles per mole of compound (M-24). A base can be used in the reaction as needed. Examples of the base include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 2 moles per mole of compound (M-24). In the reaction, the compound (M-23) is usually used in a proportion of 1 to 2 moles, and the condensing agent is usually used in a proportion of 1 to 2 moles, relative to 1 mole of the compound (M-24). The reaction temperature is usually in the range of 0° C. to 200° C. The reaction time is usually in the range of 0.1 to 12 hours. After the reaction is complete, the compound (M-9-X) can be obtained by post-treatment such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

[0127] Reference manufacturing method 6 Compound (M-23) can be produced by hydrolyzing a compound represented by formula (M-25) (hereinafter referred to as compound (M-25)).

[0128] [ka] [In the formula, R A represents a C1-C3 alkyl group such as a methyl group or an ethyl group, and the other symbols have the same meanings as above.] When hydrolysis is carried out with an acid, the reaction is usually carried out using an aqueous solution of the acid as a solvent. The acid used in the reaction includes, for example, mineral acids such as hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, etc.; and carboxylic acids such as acetic acid, trifluoroacetic acid, etc. The reaction temperature is usually in the range of 0° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, compound (M-23) can be obtained by carrying out post-treatments such as extraction with an organic solvent, drying and concentrating the organic layer.

[0129] When hydrolysis is carried out with a base, the reaction is usually carried out in the presence of a solvent. Examples of the solvent used in the reaction include ethers, alcohols, water, and mixtures of two or more of these. The base used in the reaction includes, for example, alkali metal hydroxides. In the reaction, the base is usually used in a proportion of 1 to 10 moles per mole of compound (M-25). The reaction temperature is usually in the range of 0° C. to 120° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the reaction mixture is acidified, and the reaction mixture is extracted with an organic solvent. The organic layer is then dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (M-23).

[0130] Reference manufacturing method 7 Compound (M-25) can be produced by reacting a compound represented by formula (M-26) (hereinafter referred to as compound (M-26)) with a compound represented by formula (R-8) (hereinafter referred to as compound (R-8)) in the presence of a condensing agent.

[0131] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, halogenated hydrocarbons, aromatic hydrocarbons, esters, nitriles, aprotic polar solvents, nitrogen-containing aromatic compounds, and mixtures of two or more of these. The condensing agent used in the reaction may be, for example, a mixture of triphenylphosphine and an azodiester compound, such as diethyl azodicarboxylate. In the reaction, the compound (R-8) is usually used in a proportion of 1 to 5 moles and the condensing agent is usually used in a proportion of 1 to 5 moles per mole of the compound (M-26). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, compound (M-25) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer. Compound (M-26) is a commercially available compound or can be prepared using known methods. Compound (R-8) is a commercially available compound or can be prepared using known methods.

[0132] Reference manufacturing method 8 The compound (M-24) can be produced by reacting the compound (M-2-h) with ammonia.

[0133] [ka] [In the formula, Xe represents a fluorine atom or a chlorine atom, and the other symbols have the same meanings as above.] The reaction is usually carried out in a solvent, such as ethers, nitriles, aprotic polar solvents, alcohols, water, and mixtures of two or more of these. A base can be used in the reaction as needed. Examples of the base used in the reaction include organic bases and alkali metal carbonates. When a base is used in the reaction, the base is usually used in a ratio of 0.1 to 5 moles per mole of compound (M-2-h). Ammonia can also be used as a solution such as aqueous ammonia and ammonia methanol solution. In the reaction, ammonia is usually used in a proportion of 1 to 100 moles per mole of compound (M-2-h). The reaction temperature is usually in the range of −20° C. to 100° C. The reaction time is usually in the range of 0.1 to 48 hours. After the reaction is complete, the compound (M-24) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0134] Reference manufacturing method 9 Compound (M-9-X) can also be produced by reacting a compound represented by formula (M-27) (hereinafter referred to as compound (M-27)) with compound (M-24).

[0135] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, aliphatic hydrocarbons, aromatic hydrocarbons, halogenated hydrocarbons, esters, nitriles, aprotic polar solvents, and mixtures of two or more of these. A base can be used in the reaction as needed. Examples of the base used in the reaction include alkali metal carbonates, alkali metal hydroxides, and organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 2 moles per mole of compound (M-24). In the reaction, compound (M-27) is usually used in a proportion of 0.8 to 1.2 moles per mole of compound (M-24). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the compound (M-9-X) can be obtained by post-treatment such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

[0136] Reference manufacturing method 10 The compound (M-27) can be produced by reacting the compound (M-23) in the presence of a chlorinating agent.

[0137] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, halogenated hydrocarbons, and mixtures of two or more of these. The chlorinating agent used in the reaction includes, for example, thionyl chloride, oxalyl dichloride, phosphorus oxychloride and the like. In the reaction, the chlorinating agent is usually used in a proportion of 1 to 5 moles per mole of compound (M-23). The reaction temperature is usually in the range of 0° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the solvent can be distilled off to obtain compound (M-27).

[0138] Reference manufacturing method 11 Compound (M-9-OH) can be produced by reacting a compound represented by formula (M-9-P) (hereinafter referred to as compound (M-9-P)) with an acid.

[0139] [ka] [where, X B represents ORB, RB represents a protecting group such as a tetrahydropyranyl group, a methoxymethyl group, a 2-methoxyethoxymethyl group, a tert-butyldimethylsilyl group, or a tribenzylsilyl group, and the other symbols have the same meanings as above. The reaction is usually carried out in a solvent, such as ethers, alcohols, water, or a mixture of two or more of these. The acid used in the reaction includes, for example, mineral acids such as hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, etc.; and carboxylic acids such as acetic acid, trifluoroacetic acid, etc. The reaction temperature is usually in the range of 0° C. to 120° C. The reaction time is usually in the range of 0.1 to 24 hours. In the reaction, the acid is usually used in a proportion of 1 to 10 moles per mole of compound (M-9-P). After the reaction is complete, the reaction mixture is extracted with an organic solvent, and the organic layer is dried, concentrated, and other post-treatment procedures are carried out to obtain the compound (M-9-OH).

[0140] Reference manufacturing method 12 Compound (M-9-P) can be produced by reacting a compound represented by formula (M-28) (hereinafter referred to as compound (M-28)) with compound (M-24) in the presence of a condensing agent.

[0141] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-9-P) can be produced according to Reference Production Method 5, using compound (M-28) instead of compound (M-23).

[0142] Reference manufacturing method 13 Compound (M-28) can be produced by hydrolyzing a compound represented by formula (M-29) (hereinafter referred to as compound (M-29)) in the presence of a base.

[0143] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, alcohols, water, or a mixture of two or more of these. The base used in the reaction includes, for example, alkali metal hydroxides. In the reaction, the base is usually used in a proportion of 1 to 10 moles per mole of compound (M-29). The reaction temperature is usually in the range of 0° C. to 120° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the reaction mixture is acidified, and the reaction mixture is extracted with an organic solvent. The organic layer is then dried and concentrated, and other post-treatment procedures can be carried out to obtain compound (M-28).

[0144] Reference manufacturing method 14 Compound (M-29) can be produced by reacting compound (M-26) with a compound represented by formula (R-9) (hereinafter referred to as compound (R-9)) in the presence of a condensing agent.

[0145] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-29) can be produced according to Reference Production Method 7, using compound (R-9) instead of compound (R-8). Compound (R-9) is a commercially available compound or can be prepared using known methods.

[0146] Reference manufacturing method 15 Compound (M-10-X) can be produced by reacting compound (M-10-OH) in the presence of a halogenating agent.

[0147] [ka] [In the formula, the symbols have the same meanings as defined above.] The reaction is usually carried out in a solvent, such as ethers, alcohols, aromatic hydrocarbons, halogenated hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these. Examples of the halogenating agent used in the reaction include hydrogen halides such as hydrogen chloride; phosphorus halides such as phosphorus tribromide; thionyl halides such as thionyl chloride; a mixture of triphenylphosphine and carbon tetrachloride; and a mixture of triphenylphosphine and carbon tetrabromide. In the reaction, the halogenating agent is usually used in a proportion of 1 to 10 moles per mole of the compound (M-10-OH). A base can be used in the reaction as needed. Examples of the base used in the reaction include organic bases. When a base is used in the reaction, the base is usually used in a ratio of 1 to 2 moles per mole of the compound (M-10-OH). The reaction temperature is usually in the range of −20° C. to 150° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the compound (M-10-X) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0148] Reference manufacturing method 16 Compound (M-10-OH) can be produced by reacting a compound represented by formula (M-10-P) (hereinafter referred to as compound (M-10-P)) with an acid.

[0149] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-10-OH) can be produced according to Reference Production Method 11, using compound (M-10-P) instead of compound (M-9-P).

[0150] Reference manufacturing method 17 Compound (M-10-P) can be produced by reacting a compound represented by formula (M-30) (hereinafter referred to as compound (M-30)) with a compound represented by formula (M-33) (hereinafter referred to as compound (M-33)) in the presence of a condensing agent.

[0151] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-10-P) can be produced according to Reference Production Method 5, using compound (M-30) instead of compound (M-23) and compound (M-33) instead of compound (M-24). Compound (M-30) is a commercially available compound or can be prepared using known methods.

[0152] Reference manufacturing method 18 Compound (M-10-P) can also be produced by reacting a compound represented by formula (M-32) (hereinafter referred to as compound (M-32)) with compound (M-33).

[0153] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-10-P) can be produced according to Reference Production Method 9, using compound (M-32) instead of compound (M-27) and compound (M-33) instead of compound (M-24). Compound (M-32) is a commercially available compound or can be prepared using known methods.

[0154] Reference manufacturing method 19 Compound (M-33) can be produced by reacting compound (M-24) with a compound represented by formula (R-12) (hereinafter referred to as compound (R-12)) in the presence of a base.

[0155] [ka] [In the formula, L represents a leaving group such as a chlorine atom or a bromine atom, and the other symbols have the same meanings as above.] The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these. Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases. In the reaction, the compound (R-12) is usually used in a proportion of 1 to 5 moles and the base is usually used in a proportion of 1 to 2 moles per mole of the compound (M-24). The reaction temperature is usually in the range of 0° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, the compound (M-33) can be obtained by post-treatment such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer. Compound (R-12) is a commercially available compound or can be prepared using known methods.

[0156] Reference manufacturing method 20 The compound (M-2-n0) can be produced according to the following scheme.

[0157] [ka] [In the formula, Xb represents SR2 or a hydrogen atom, Xf represents a chlorine atom, a bromine atom, or an iodine atom, and the other symbols have the same meanings as above.] First, the process for producing a compound represented by formula (M-4-f) (hereinafter referred to as compound (M-4-f)) from compound (M-4) will be described. The compound (M-4-f) can be produced by reacting the compound (M-4) with a halogenating agent. The reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, halogenated hydrocarbons, water, and mixtures of two or more of these. Examples of halogenating agents include chlorine, bromine, iodine, N-chlorosuccinimide, N-bromosuccinimide, and N-iodosuccinimide. In the reaction, the halogenating agent is usually used in a proportion of 1 to 20 moles per mole of compound (M-4). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is complete, compound (M-4-f) can be obtained by post-treatment such as adding water to the reaction mixture, extracting with an organic solvent, and drying and concentrating the organic layer.

[0158] Next, the process for producing compound (M-2-n0) from compound (M-4-f) will be described. The compound (M-2-n0) can be produced by reacting the compound (M-4-f) with the compound (R-1) in the presence of a metal catalyst and a base. The reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these. Examples of the metal catalyst used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(0), [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(0), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(0) and nickel(II) chloride; and copper catalysts such as copper(I) iodide and copper(I) chloride. Examples of the base used in the reaction include alkali metal hydrides, alkali metal carbonates, and organic bases. A ligand can also be used in the reaction. Examples of the ligand include triphenylphosphine, xantphos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline. When a ligand is used in the reaction, the ligand is usually used in a ratio of 0.01 to 1 mole per mole of compound (M-4-f). In the reaction, compound (R-1) is usually used in a proportion of 1 to 20 moles, a metal catalyst is usually used in a proportion of 0.01 to 0.5 moles, and a base is usually used in a proportion of 0.1 to 5 moles, relative to 1 mole of compound (M-4-f). The reaction temperature is usually in the range of −20° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is complete, the compound (M-2-n0) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer.

[0159] Next, the process for producing the compound (M-2-n0) from the compound (M-4) will be described. Compound (M-2-n0) can also be produced by reacting compound (M-4) with a compound represented by formula (R-3) (hereinafter referred to as compound (R-3)) in the presence of a halogenating agent. The reaction is usually carried out in a solvent, such as alcohols, nitriles, ethers, aromatic hydrocarbons, aprotic polar solvents, water, and mixtures of two or more of these. Examples of halogenating agents include bromine, iodine, sodium bromide, potassium bromide, sodium iodide, and potassium iodide. An oxidizing agent can be used in the reaction as needed. Examples of the oxidizing agent used in the reaction include hydrogen peroxide, tert-butyl hydroperoxide, DMSO, etc. When an oxidizing agent is used in the reaction, the oxidizing agent is usually used in a ratio of 1 to 20 moles per mole of compound (M-4). In the reaction, the compound (R-3) is usually used in a proportion of 0.5 to 10 moles and the halogenating agent is usually used in a proportion of 0.05 to 10 moles per mole of the compound (M-4). The reaction temperature is usually in the range of 0° C. to 200° C. The reaction time is usually in the range of 0.1 to 72 hours. After the reaction is complete, the compound (M-2-n0) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment such as drying and concentrating the organic layer. Compound (R-3) is known or can be produced according to a known method. Compound (M-4) is known or can be produced according to the methods described in WO 2015 / 157093, WO 2016 / 109706, Organic & Biomolecular Chemistry, 2017, 15, 4199, and European Journal of Medicinal Chemistry, 2016, 123, 916, etc.

[0160] Reference manufacturing method 21 The compound represented by formula (M-11-n1) (hereinafter referred to as compound (M-11-n1)) or the compound represented by formula (M-11-n2) (hereinafter referred to as compound (M-11-n2)) can be produced by reacting compound (M-11-n0) with an oxidizing agent. Compound (M-11-n2) can also be produced by reacting compound (M-11-n1) with an oxidizing agent.

[0161] [ka] [In the formula, the symbols have the same meanings as defined above.] These reactions can be carried out according to Production Method 1.

[0162] Reference manufacturing method 22 Compound (M-17-X) can be produced by reacting compound (M-23) with a compound represented by formula (M-34) (hereinafter referred to as compound (M-34)) in the presence of a condensing agent.

[0163] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-X) can be produced according to Reference Production Method 5, using compound (M-34) instead of compound (M-24).

[0164] Reference manufacturing method 23 Compound (M-17-X) can also be produced by reacting compound (M-27) with compound (M-34).

[0165] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-X) can be produced according to Reference Production Method 9, using compound (M-34) instead of compound (M-24).

[0166] Reference manufacturing method 24 Compound (M-34) can be produced by reacting a compound represented by formula (M-11-h) (hereinafter referred to as compound (M-11-h)) with ammonia.

[0167] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-34) can be produced according to Reference Production Method 8, using compound (M-11-h) instead of compound (M-2-h).

[0168] Reference manufacturing method 25 The compound (M-11-n0) can be produced according to the following scheme.

[0169] [ka] [In the formula, the symbols have the same meanings as defined above.] These reactions can be carried out according to Reference Production Method 20.

[0170] Reference manufacturing method 26 Compound (M-17-OH) can be produced by reacting a compound represented by formula (M-17-P) (hereinafter referred to as compound (M-17-P)) with an acid.

[0171] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-OH) can be produced according to Reference Production Method 11, using compound (M-17-P) instead of compound (M-9-P).

[0172] Reference manufacturing method 27 Compound (M-17-P) can be produced by reacting a compound represented by formula (M-28) (hereinafter referred to as compound (M-28)) with compound (M-34) in the presence of a condensing agent.

[0173] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-17-P) can be produced according to Reference Production Method 12, using compound (M-34) instead of compound (M-24).

[0174] Reference manufacturing method 28 Compound (M-18-OH) can be produced by reacting a compound represented by formula (M-18-P) (hereinafter referred to as compound (M-18-P)) with an acid.

[0175] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-18-OH) can be produced according to Reference Production Method 11, using compound (M-18-P) instead of compound (M-9-P).

[0176] Reference manufacturing method 29 Compound (M-18-P) can be produced by reacting compound (M-30) with a compound represented by formula (M-35) (hereinafter referred to as compound (M-35)) in the presence of a condensing agent.

[0177] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-18-P) can be produced according to Reference Production Method 5, using compound (M-30) instead of compound (M-23) and compound (M-35) instead of compound (M-24).

[0178] Reference manufacturing method 30 Compound (M-18-P) can also be produced by reacting compound (M-32) with compound (M-35).

[0179] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-18-P) can be produced according to Reference Production Method 9, using compound (M-32) instead of compound (M-27) and compound (M-35) instead of compound (M-24).

[0180] Reference manufacturing method 31 The compound (M-35) can be produced by reacting the compound (M-34) with the compound (R-12) in the presence of a base.

[0181] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-35) can be produced according to Reference Production Method 19, using compound (M-34) instead of compound (M-24).

[0182] Reference manufacturing method 32 Compound (M-18-X) can be produced by reacting compound (M-18-OH) in the presence of a halogenating agent.

[0183] [ka] [In the formula, the symbols have the same meanings as defined above.] Compound (M-18-X) can be produced according to Reference Production Method 15, using compound (M-18-OH) instead of compound (M-10-OH).

[0184] Compound (M-2) can also be produced, for example, according to the method described in WO 2020 / 158889.

[0185] Reference manufacturing method 33 Compound (M-1) can also be produced according to the following scheme.

[0186] [ka] [In the formula, XP represents a protecting group such as a tert-butoxycarbonyl group, and the other symbols have the same meanings as above.] First, a method for producing a compound represented by formula (M-29-N) (hereinafter referred to as compound (M-29-N)) from a compound represented by formula (M-29-N-PG) (hereinafter referred to as compound (M-29-N-PG)) will be described. Compound (M-29-N) can be produced by reacting compound (M-29-N-PG) with an acid. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, and mixtures of two or more of these. The acid used in the reaction includes, for example, mineral acids such as hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, etc.; and carboxylic acids such as acetic acid, trifluoroacetic acid, etc. In the reaction, the acid is usually used in a proportion of 1 to 30 moles per mole of the compound (M-29-N-PG). The reaction temperature is usually in the range of 0° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, compound (M-29-N) can be obtained by carrying out post-treatment such as concentrating the reaction mixture.

[0187] Next, a method for producing compound (M-1) from compound (M-29-N) will be described. Compound (M-1) can be produced by reacting compound (M-29-N) with a base. The reaction is usually carried out in a solvent, such as ethers, aromatic hydrocarbons, nitriles, aprotic polar solvents, water, or a mixture of two or more of these. The base used in the reaction includes, for example, alkali metal carbonates. In the reaction, the base is usually used in a proportion of 1 to 30 moles per mole of compound (M-29-N). The reaction temperature is usually in the range of 0° C. to 100° C. The reaction time is usually in the range of 0.1 to 24 hours. After the reaction is complete, compound (M-1) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatments such as drying and concentrating the organic layer.

[0188] This compound can be mixed or used in combination with one or more components (hereinafter referred to as this component) selected from the group consisting of the following groups (a), (b), (c), (d), (e), (f), (g), (h), (i), and (j): The term "mixed or combined use" means that the present compound and the present ingredient are used simultaneously, separately or with an interval of time. When the present compound and the present ingredient are used simultaneously, the present compound and the present ingredient may be contained in separate preparations or may be contained in a single preparation. One aspect of the present invention is a composition (hereinafter sometimes referred to as Composition A) containing one or more components selected from the group consisting of Group (a), Group (b), Group (c), Group (d), Group (e), Group (f), Group (g), Group (h), Group (i), and Group (j) (i.e., the present component), and the present compound.

[0189] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABA-activated chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-activated chloride channel allosteric modulators (e.g., macrolide insecticides), The group consists of juvenile hormone mimics, multisite inhibitors, chordotonal organ TRPV channel modulators, acarid growth inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, mitochondrial electron transport chain complex I, II, III, and IV inhibitors, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chordotonal organ modulators, and other insecticidal, acaricidal, and nematicidal active ingredients. These are described in the IRAC mechanism-based classification.

[0190] Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acylamino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiration inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid synthesis and protein synthesis inhibitors (e.g., anilinopyrimidine fungicides), signal transduction inhibitors, lipid synthesis and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multisite contact-active fungicides, microbial fungicides, and other fungicidal active ingredients. These are described in the FRAC classification based on the mechanism of action.

[0191] Group (c) is a group of plant growth regulators.

[0192] Group (d) is a group of safeners.

[0193] Group (e) is a group of synergists.

[0194] Group (f) is a group of repellent components consisting of bird repellent components, insect repellent components and animal repellent components.

[0195] Group (g) is the group of molluscicidal ingredients.

[0196] Group (h) is a group of signaling substances consisting of pheromones and allelochemicals used by insects.

[0197] Group (i) consists of acetyl-CoA carboxylase (ACCase) inhibitors, acetolactate synthase (ALS) inhibitors, photosynthesis (photosystem II) inhibitors, photosystem I electron converters, protoporphyrinogen oxidase (PPO) inhibitors, phytoene desaturase system (PDS) inhibitors, 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitors, carotenoid biosynthesis inhibitors, EPSP synthase inhibitors, glutamine synthase inhibitors, dihydropteroic acid (DHP) synthase inhibitors, microtubule polymerization inhibitors, mitosis / microtubule formation inhibitors, very long-chain fatty acid (VLCFA) inhibitors, cellulose synthesis inhibitors, uncoupling agents, lipid synthesis inhibitors, indoleacetic acid-like active agents, auxin transport inhibitors, and other herbicidal active ingredients. These are listed in the HRAC classification based on the mechanism of action.

[0198] Group (j) is a group of biological control agents consisting of bacteria, fungi, yeasts, protozoa, viruses, natural products, insects, mites, and mollusks that have pest control effects (e.g., insecticidal, acaricidal, nematicidal, fungicidal, herbicidal, etc.) or plant growth-regulating effects such as rhizobia and mycorrhizal fungi. Specifically, group (j) is divided into subgroups (j-1): bacteria, subgroup (j-2): fungi and yeast, subgroup (j-3): protozoa, subgroup (j-4): viruses, subgroup (j-5): nematodes, subgroup (j-6): natural products, subgroup (j-7): insects, subgroup (j-8): mites, and subgroup (j-9): mollusks.

[0199] Examples of combinations of the present ingredients and compounds are listed below: For example, alanycarb + SX means a combination of alanycarb and SX. The abbreviation SX means any one of the present compounds selected from the compound group SX1 to SX1840 described below. The present components described below are all known components and can be obtained from commercially available preparations or produced by known methods. When the present component is a microorganism, it can also be obtained from a bacterial depository. The number in parentheses indicates the CAS RN (registered trademark).

[0200] Combinations of the present components and the present compounds in group (a) above: Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetic acid + SX, acetoprole + SX, acrinathrin + SX, acinonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide + SX, Amitraz + SX, azamethiphos + SX, azinphos-ethyl + SX, azinphos-methyl + SX, azocyclotin + SX, bendiocarb + SX, benfluthrin + SX, benfuracarb + SX, bensultap + SX, bentiofluorin + SX, benzoic acid + SX, benzoximate + SX, benzpyrimoxan + SX, beta-cyfluthrin + SX, beta-cypermethrin + SX, Bifenazate + SX, bifenthrin + SX, bilobalide + SX, bioallethrin + SX, bioresmethrin + SX,Bistrifluron + SX, bisulfurfen + SX, borax + SX, boric acid + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butyric acid + SX, butocarboxim + SX, butoxycarboxim + SX, cadusafos + SX, calcium phosphide + SX, carbaryl + SX, carbofuran + SX, carbosulfan + SX, cartap hydrochloride + SX, Cartap + SX, chinomethionate + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos-methyl + SX, chromafenozide + SX, citric acid + SX, clofentezine + SX, Clothianidin + SX, coumaphos + SX, cryolite + SX, cyanophos + SX,Cyantraniliprole + SX, cybenzoxasulfyl + SX, cyclaniliprole + SX, cyclobutrifluram + SX, cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyetpyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + SX, cyhexatin + SX, cypermethrin + SX, cyphenothrin + SX, cyproflanilide + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX, diafenthiuron + SX, diatomaceous earth + SX, diazinon + SX, dichlorvos + SX, dichloromezotiaz + SX, dicofol + SX, dicrotophos + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX Dimethoate + SX, dimethylvinphos + SX, dimpropyridaz + SX, dinotefuran + SX, disodium octaborate + SX,Disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, doramectin + SX, emamectin benzoate + SX, empenthrin + SX, endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, epsilon-metofluthrin + SX, epsilon-momfluorothrin + SX, esfenvalerate + SX, ethiofencarb + SX, ethion + SX, ethiprole + SX, ethoprophos + SX, Etofenprox + SX, etoxazole + SX, famphur + SX, fenamiphos + SX, fenazaquin + SX, fenbutatin oxide + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, flometoquin + SX, flonicamid + SX, fluacrypyrim + SX, fluazaindolizine + SX,Fluazuron + SX, flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX, fluensulfone + SX, flufenprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupyradifurone + SX, flupyrimin + SX, flupyroxystrobin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, fumaric acid + SX, furamethrin + SX, furathiocarb + SX, gamma-cyhalothrin + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, Potassium salt of hop beta acid + SX, hydramethylnon + SX, imicyafos + SX, imidacloprid + SX,Imidaclothiza + SX, imiprothrin + SX, indazapyroxamet + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoflualanam + SX, isoprocarb + SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate + SX, isoxathion + SX, kadethrin + SX, kappa-tefluthrin + SX, kappa-bifenthrin + SX Lactic acid + SX, lambda-cyhalothrin + SX, lavandulyl senecioate + SX, ledprona + SX, lenoremycin + SX, lepimectin + SX, lime sulfur + SX, lotilaner + SX, lufenuron + SX, machine oil + SX, malathion + SX, malic acid + SX, mecarbam + SX, meperfluthrin + SX, metaflumizone + SX, metam + SX, methamidophos + SX, methidathion + SX, methiocarb + SX, methomyl + SX, methoxychlor + SX,Methoxyfenozide + SX, methyl bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycin oxime + SX, mivorilaner + SX, modoflaner + SX, momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, naled + SX, nicofluprole + SX, nicotine + SX Nicotine sulfate + SX, nitenpyram + SX, novaluron + SX, noviflumuron + SX, omethoate + SX, organic acid + SX, oxalic acid + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, parathion + SX, parathion-methyl + SX, permethrin + SX, phenothrin + SX, phenthoate + SX, phorate + SX, phosalone + SX. Phosmet + SX, phosphamidon + SX, phosphine + SX, phoxim + SX, pioxaniliprole + SX,Piperflanilide + SX, pirimicarb + SX, pirimiphos-methyl + SX, prallethrin + SX, profenofos + SX, profluthrin + SX, propionic acid + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, Pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, pyriminostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, Sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spirobudifen + SX,Spirodiclofen + SX, spiromesifen + SX, spiropidione + SX, spirotetramat + SX, sulfiflumin + SX, sulfluramid + SX, sulfotep + SX, sulfoxaflor + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic +, SX, tartaric acid + SX, tau-fluvalinate + SX, tebufenozide + SX, tebufenpyrad + SX, tebupirimfos + SX, teflubenzuron + SX, tefluthrin + SX, temephos + SX, terbufos + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX, tetramethrin + SX, tetramethylfluthrin + SX, Tetraniliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosultap disodium + SX, thiosultap monosodium + SX, tigolaner + SX, thioantraniliprole + SX, tioxazafen + SX, tolfenpyrad + SX, Tralomethrin + SX, transfluthrin + SX, triazamate + SX, triazophos + SX, trichlorfon + SX,Trifluenfuronate + SX, triflumezopyrim + SX, triflumuron + SX, trimethacarb + SX, tyclopyrazoflor + SX, umifoxolaner + SX, vadescana + SX, vamidothion + SX, 3,5-dimethylphenyl N-methylcarbamate (XMC) + SX, xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluoropropanesulfinyl)propanamide (1477923-37-7) + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, 2-({2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolidin-4-one (1445683-71-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, 4-[5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, (S)-2-chloro-N-(3-ethylpentan-2-yl)furan-3-carboxamide + SX。,

[0201] Combinations of the present components and the present compounds in group (b) above: Acibenzolar-S-methyl + SX, aldimorph + SX, ametoctradin + SX, aminopyrifen + SX, amisulbrom + SX, anilazine + SX, azaconazole + SX, azoxystrobin + SX, basic copper sulfate + SX, benalaxyl + SX, benalaxyl-M + SX, benodanil + SX, benomyl + SX, benthiavalicarb + SX, benthiavalicarb-isopropyl + SX, Benzovindiflupyr + SX, bifemetstrobin + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin S + SX, Bordeaux mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, Carpropamid + SX, chinomethionate + SX, chloroinconazide + SX, chloroneb + ​​SX,Chlorothalonil + SX, chlozolinate + SX, copper(II) acetate + SX, copper(II) hydroxide + SX, copper oxychloride + SX, copper(II) sulfate + SX, coumoxystrobin + SX, cyazofamid + SX, cyflufenamid + SX, cymoxanil + SX, cyproconazole + SX, cyprodinil + SX, dichlobentiazox + SX, dichlofluanid + SX Diclocymet + SX, diclomezine + SX, dicloran + SX, diethofencarb + SX, difenoconazole + SX, diflumetorim + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, diniconazole-M + SX, dinocap + SX, dipotassium hydrogenphosphite + SX, dipymetitrone + SX, dithianon + SX, dodecylbenzenesulphonic acid bisethylenediamine copper(II) salt + SX,Dodemorph + SX, dodine + SX, edifenphos + SX, enoxastrobin + SX, epoxiconazole + SX, etaconazole + SX, ethaboxam + SX, ethirimol + SX, etridiazole + SX, famoxadone + SX, fenamidone + SX, fenaminstrobin + SX, fenarimol + SX, fenbuconazole + SX, feneptamidoquin + SX, fenfuram + SX, Fenhexamid + SX, fenopyramid + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, triphenyltin acetate + SX, triphenyltin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX, florylpicoxamid + SX, fluazinam + SX, Flubeneteram + SX, Fludioxonil + SX, Flufenoxadiazam + SX, Flufenoxystrobin + SX,Fluindapyr + SX, flumetylsulforim + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxapiprolin + SX, fluoxastrobin + SX, fluoxytioconazole + SX, fluquinconazole + SX, fluquinometoate + SX, flusilazole + SX, flusulfamide + SX, flutianil + SX, Flutolanil + SX, flutriafol + SX, fluxapyroxad + SX, folpet + SX, fosetyl + SX, fosetyl-aluminium + SX, fuberidazole + SX, furalaxyl + SX, furametpyr + SX, galquin + SX, guazatine + SX, hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, Iminoctadine triacetate + SX, iminoctadine trialbesilate + SX, inpyrfluxam + SX, iodocarb + SX,Ipconazole + SX, ipfentrifluconazole + SX, ipflufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX, isofetamide + SX, isofleucine + SX, isofleucine + SX, isofleucine + SX, isopyrazam + SX, isotianil + SX, kresoxim-methyl + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, Maneb + ​​SX, mefentrifluconazole + SX, mepanipyrim + SX, mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metarylpicoxamid + SX, metconazole + SX, methasulfocarb + SX, metiram + SX, metominostrobin + SX, metrafenone + SX, metyltetraprole + SX, mineral oils + SX Myclobutanil + SX, Naftifine + SX, Nuarimol + SX, Octilinone + SX, Ofurace + SX, Orysastrobin + SX,Oxadixyl + SX, oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, Picarbutrazox + SX, picoxystrobin + SX, piperalin + SX, potassium hydrogencarbonate + SX, potassium dihydrogenphosphite + SX, probenazole + SX, prochloraz + SX, procymidone + SX, propamidine + SX, propamocarb + SX, propiconazole + SX, propineb + ​​SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, Pyraclostrobin + SX, Pyrametostrobin + SX,Pyraoxystrobin + SX, pyrapropoyne + SX, pyraziflumid + SX, pyrazophos + SX, pyribencarb + SX, pyributicarb + SX, pyridaclomethyl + SX, pyrifenox + SX, pyrimethanil + SX, pyrimorph + SX, pyriophenone + SX, pyrisoxazole + SX, pyroquilon + SX, quinconazole + SX, quinofumelin + SX, Quinoxyfen + SX, quintozene + SX, saccharin + SX, saccharin sodium + SX, saccharin potassium + SX, saccharin calcium + SX, saccharin ammonium + SX, saccharin salt + SX, seboctylamine + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium carbonate peroxhydrate + SX, sodium hydrogencarbonate + SX, spiroxamine + SX, sulfur + SX, Tebuconazole + SX, Tebufloquin + SX, Teclofthalam + SX,Tecnazene + SX, terbinafine + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, tiadinil + SX, tolclofos-methyl + SX, tolfenpyrad + SX, tolprocarb + SX, tolylfluanid + SX, triadimefon + SX, triadimenol + SX, triazoxide + SX SX, triclopyricarb + SX, tricyclazole + SX, tridemorph + SX, trifloxystrobin + SX, triflumizole + SX, triforine + SX, triticonazole + SX, validamycin + SX, valifenalate + SX, vinclozolin + SX, zinc thiazole + SX, zineb + ​​SX, ziram + SX, zoxamide + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1R)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-48-7) + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1S)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-49-8) + SX, 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide (141573-94-6) + SX, 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide (1513466-73-3) + SX, N'-[4-({3-[(4-c, hlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX,2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, α-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229605-96-2) + SX, (αS)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-46-5) + SX, (αR)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-02-3) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol ( 1801930-07-3) + SX, (1R,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-53-8) + SX, (1S,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-54-9) + SX, (1R,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-55-0) + SX, (1S,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-56-1) + SX, (1R,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-57-2) + SX, (1S,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-58-3) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (1791398-02-1) + SX, methyl (1R,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-90-2) + SX, methyl (1S,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-91-3) + SX, methyl (1R,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-92-4) + SX, methyl (1S,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-93-5) + SX, methyl (1R,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-94-6) + SX, methyl (1S,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-95-7) + SX, methyl (1R,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-22-3) + SX, methyl (1S,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-23-4) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S,2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, (1R,2R,3R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-08-4) + SX, (1S,2S,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-10-8) + SX, (1R,2R,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-13-1) + SX, (1S,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-16-4) + SX, (1R,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-20-0) + SX, (1S,2R,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-24-4) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX,2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-33-8) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952305-97-3) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, 2-(difluoromethyl)-N-[(3R)-3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952306-00-1) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX,5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide + SX, N-[(1R)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide (2132414-06-1) + SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N,2-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX,N'-ethyl-N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX, 3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX,(1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropanecarboxamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide + SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propanamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butanamide + SX,N-methoxy-N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-diethyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-methyl-N'-({ 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-ox, adiazol-3-yl]phenyl}methyl)isoxazolidin-3-one + SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one + SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one + SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azepan-2-one + SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, 5-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidin-2-one + SX, ethyl 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylate + SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N-methoxy-N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide + SX, N,N-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX,5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxyprop-2-enoate + SX, methyl (Z)-2-[(3-isopropyl-1H-pyrazol-1-yl)-2-methylphenoxy]-3-methoxyprop-2-enoate + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, rel-N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[2-(pyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX,N-[(2S)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2R)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-(2-{6-[(1E)-(methoxyimino)ethyl]pyridin-2-yl}-2-(1-methylpyrazol-4-yl)propyl)-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(5-methylpyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-dichlorophenyl)isoxazole-3-carboxamide + SX, methyl 6-(2-{[5-(2,4-difluorophenyl)isoxazole-3-carbonyl]amino}-1-methyl-1-(1-methylpyrazol-4-yl)ethyl)pyridine-3-carboxylate + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-3-(2,4-difluorophenyl)-1,2,4-oxadiazole-5-carboxamide + SX,N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(5-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX.,

[0202] Combination of this component of group (c) and this compound: 1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 1,3,5-triazinane-2,4,6-trithione + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, cyprosulfamide + SX, daminozide + SX, Decane-1-ol + SX,Dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, gibberellin A + SX, gibberellin A3 + SX, inabenfide + SX, kinetin + SX, lipochitooligosaccharide MOR116 + SX, lipochitooligosaccharide SP104 + SX SX, maleic hydrazide + SX, mefluidide + SX, mepiquat chloride + SX, methyl-alpha-D-mannopyranoside + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, pyroglutamic acid + SX, sintophen + SX, sodium 1-naphthaleneacetate 1-naphthaleneacetate + SX, sodium cyanate + SX, thidiazuron + SX, titanium apatite + SX,Triapenthenol + SX, tribufos + SX, trinexapac-ethyl + SX, uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, strigolactone + SX, (1E)-1-[[1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-5-oxo-2H-pyrrol-2-yl]oxymethylene]-3,3a,4,8b-tetrahydroindeno[2,1-b]pyrrol-2-one + SX, as described in WO 2018 / 145979; (2R)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX, as described in WO 2018 / 145979; (2S)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX, as described in WO 2018 / 145979.

[0203] Combinations of the present component and the present compound in group (d) above: Allidochlor + SX, benoxacor + SX, cloquintocet + SX, cloquintocet-mexyl + SX, cyometrinil + SX, cyprosulfamide + SX, dichlormid + SX, dicyclonone + SX, dimepiperate + SX, disulfoton + SX, dymron + SX, fenchlorazole + SX, fenchlorazole-ethyl + SX, fenclorim + SX, flurazole + SX, Furilazole + SX, fluxofenim + SX, hexim + SX, isoxadifen + SX, isoxadifen-ethyl + SX, Jiecaowan + SX, Jiecaoxi + SX, mecoprop + SX, mefenpyr + SX, mefenpyr-ethyl + SX, mefenpyr-diethyl + SX, mephenate + SX, metcamifen + SX, oxabetrinil + SX, 1,8-naphthalic anhydride + SX, Octane-1,8-diamine + SX, AD-67 (4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl)sulfonyl]benzene) + SX, DKA-24 (2,2-dichloro-N-[2-oxo-2-(2-propenylamino)ethyl]-N-(2-propenyl)acetamide) + SX, MG191 (2-(dichloromethyl)-2-methyl-1,3-dioxolane) + SX, MG-838 (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N-(1,3-dioxan-2-ylmethyl)-N-(2-propenyl)acetamide) + SX, R-28725 (3-(dichloroacetyl)-2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3-(dichloroacetyl)-2,2,5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1-(dichloroacetyl)azepane) + SX。

[0204] Combination of this component of group (e) and this compound: 1-dodecyl-1H-imidazole + SX, N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide + SX, bucarpolate + SX, N,N-dibutyl-4-chlorobenzenesulfonamide + SX, dietholate + SX, diethylmaleate + SX, Jiajizengxiaolin + SX, octachlorodipropyl ether + SX, perbutin + SX, piperonyl butoxide butoxide + SX, piperonyl cyclonene + SX, piprotal + SX, propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, verbutin + SX, DMC (1,1-bis(4-chloro) phenyl)ethanol) + SX, FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol) + SX, ETN (1,2-epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S,S,S-tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX.

[0205] Combinations of the present component and the present compound in group (f) above: Anthraquinone + SX, chloralose + SX, acrep + SX, butopyronoxyl + SX, camphor + SX, d-camphor + SX, carboxide + SX, dibutyl phthalate + SX, deet + SX, dimethyl carbate + SX, dimethyl phthalate + SX, dibutyl succinate + SX, dibutyl adipate + SX, ethohexadiol + SX, hexamide + SX, icaridin + SX, Methoquin-butyl + SX, methylneodecanamide + SX, 2-(octylthio)ethanol + SX, butoxypolypropylene glycol + SX, oxamate + SX, quwenzhi + SX, quyingding + SX, zengxiaon + SX, rebemide + SX, copper naphthenate + SX, zinc naphthenate + SX.

[0206] Combination of the present component and the present compound in group (g) above: Bis(tributyltin) oxide + SX, allicin + SX, bromoacetamide + SX, calcium arsenate + SX, cloethocarb + SX, copper sulfate + SX, fentin + SX, ferric phosphate + SX, metaldehyde + SX, niclosamide + SX, Paris green + SX, pentachlorophenol + SX, sodium ferric EDTA + SX, sodium pentachlorophenoxide + SX, tazimcarb + SX, Tralopyril + SX, tributyltin oxide + SX, trifenmorph + SX.

[0207] Combinations of the present component and the present compound in group (h) above: (4Z,7Z)-deca-4,7-dien-1-yl acetate + SX, (2E)-dec-2-en-1-ol + SX, (4Z)-dec-4-en-1-yl acetate + SX, (5Z)-dec-5-en-1-ol + SX, +-5Z a-ceta-1-dec (8Z)-dec-8-en-1-ol + SX, (7Z,13Z,16Z,19Z)-docosa-7,13,16,19-tetraen-1-ly isobutylate + SX, (7Z)-dodec-7-en-1-yl acetate + SX-,1-ol +8)-endo (8E)-dodec-8-en-1-yl acetate + SX, (8Z)-dodec-8-en-1-yl acetate + SX, (9E)-dodec-9-en-1-yl acetate + SX, (9Z)-dodec-9-en-1-yl acetate-Z3-Z-endo, (de (2E)-but-2-enoate + SX, (7E,9E)-dodeca-7,9-diene-1-yl acetate + SX, (7E,9Z)-dodeca-7,9-diene-1-yl acetate + SX, (7Z,9E)-dodeca-7,9-dien-te +1-yl (8E,10E)-dodeca-8,10-diene-1-ol + SX, (8E,10E)-dodeca-8,10-diene-1-yl acetate + SX, (6Z)-henicos-6-en-1-one + SX, (9Z)-hexadec-9-enal-9l- SX, + SX, (10Z)-hexadec-10-en-1-yl acetate + SX, (11Z)-hexadec-11-enal + SX, (11Z)-hexadec-11-en-1-ol + SX, (11Z)-hexadec-11-en-1-yl acetate (13Z)-hexadec-13-en-11-yn-1-yl acetate + SX, (7Z,11Z)-hexadeca-7,11-dienal + SX, (7E,11E)-hexadeca-7,11-dien-1-yl acetate + SX, (7E,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (7Z,11E)-hexadeca,ta-7,1-Xcel-dien (7Z,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (10E,12E)-hexadeca-10,12-dienal + SX, (11Z,13Z)-hexadeca-11,13-dienal + SX, (7Z,1caZ-37-Z + SX, (7Z,11Z,13E)-hexadeca-7,11,13-trienal + SX, (13Z)-icos-13-en-10-one + SX, (2E)-6-methylhept-2-en-4-ol + SX, (11Z)-ol-octadec,1-11 (11Z)-octadec-11-enal + SX, (13Z)-octadec-13-enal + SX, (2E,13Z)-octadeca-2,13-diene-1-ol + SX, (2E,13Z)-octadeca-2,13-dienete-1-1-yl acetate (2Z,13Z)-octadeca-2,13-diene-1-yl acetate + SX, (3E,13Z)-octadeca-3,13-dien-1-ol + SX, (3E,13Z)-octadeca-3,13-diene-1-yl acetate + SX, (3Z,13Z)-octadeca-3,13-dien-1-ol + SX, (3Z,13Z)-octadeca-3,13-diene-1-yl acetate + SX, (7Z)-tetradec-7-enal + SX, (7Z)-tetradec-1c-Z-7-en-X-en-9-ol + SX, (9Z)-tetradec-9-en-1-yl acetate + SX, (11Z)-tetradec-11-enal + SX,(11E)-tetradec-11-en-1-yl acetate + SX, (11Z)-tetradec-11-en-1-yl acetate + SX, (3E,8Z)-tetradeca-3,8-dien-1-yl acetate + SX, (4E,10Z)-tetradeca-4,10-dien-1-yl acetate + SX, (8E,10Z)-tetradeca-8,10-dienal + SX, (9E,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,12E)-tetradeca-9,12-dien-1-yl acetate + SX, (3E,8Z,11Z)-tetradeca-3,8,11-trien-1-yl acetate + SX, (9E)-tricos-9-ene + SX, (4E)-tridec-4-en-1-yl acetate + SX, (4Z)-tridec-4-en-1-yl acetate + SX, allyl isothiocyanate + SX, 4-allylanisole + SX, 3-carene + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + eugenol + 2-phenylethyl propionate + SX, hexyl butyrate + (E)-2-hexenyl butyrate + (E)-4-oxo-2-hexenal + SX, phenylacetaldehyde + SX,(Z)-2-(3,3-dimethylcyclohexylidene)ethanol + SX, (4R,8R)-4,8-dimethyldecanal + SX, (4R,8S)-4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3,2,1]octane + SX, 1,7-dioxaspiro[5,5]undecane + SX, dodecan-1-ol + SX, dodecyl acetate + SX, ethyl (2E,4Z)-deca-2,4-dienoate + SX, ethyl 4-methyloctanoate + SX, (2R,5R)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (2R,5S)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (E)-β-farnesene + SX, farnesyl alcohol + SX, ferrugineol + SX, geranyl hexanoate + SX, jasmone + SX, 3-ketopetromyzonol-24-sulfate ammonium salt + SX, methyl 2,6,10-trimethyldodecanoate + SX, methyl (2E,4E)-hepta-2,4-dienoate + SX, 2-methylbut-3-en-1-ol + SX, 2-(1-methyl-2-prop-1-en-2-ylcyclobutyl)ethanol + SX, 3-methylcyclohex-2-en-1-one + SX, (-)-4-methylheptan-3-ol + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 14-methyloctadec-1-ene + SX, nepetalactone + SX, ocimene + SX, 1,2-octanediol + SX, oct-1-en-3-ol + SX, (R)-oct-1-en-3-ol + SX, olean + SX, 4-(3-oxobutyl)phenyl acetate + SX, pentacosane + SX, penta-termanone + SX, putrescine + SX, tetradecan-1-ol + SX, tetradecyl acetate + SX, tricosane + SX, tridecan-2-one + SX, 1,2,4-trimethoxybenzene + SX,Trimethylamine + SX, trimethylamine hydrochloride + SX, 2-(undecyloxy)ethanol + SX, querciverol + SX, alpha-terpinene + SX, alpha-terpineol + SX, alpha-terpinoline + SX, animal tissue hydrolysate + SX, beet molasses-urea hydrolysate + SX, camphene + SX, capilure + SX, ceralure + SX, chalcogran + SX, codlelure + SX, codlemone + SX, copaene + SX, cosmolure + SX Cucujolide VIII + SX, cuelure + SX, cyclotene + SX, disparlure + SX, dominicalure + SX, endobrevicomin + SX, eugenol + SX, exitlure + SX, exobrevicomin + SX, farnesol + SX, ferrolure + SX, frontalin + SX, German cockroach pheromone + SX, gossyplure + SX, gossyplure HF + SX Grand Lure (Grandlure) + SX, Grand Lure I (Grandlure I) + SX, Grand Lure II (Grandlure II) + SX, Grand Lure III (Grandlure III) + SX,Grandlure IV + SX, Hexalure + SX, Ipsdienol + SX, Ipsenol + SX, Japonilure + SX, Lavandin Oil + SX, Lineatin + SX, Litlue + SX, Looplure + SX, Medlure + SX, Megatomoic Acid + SX, Methyl Eugenol + SX, Multistriatin + SX, Muscalure + SX, Nerolidol + SX, Orfralure + SX, Oryctalure + SX, ostramone + SX, peachflure + SX, prodenialure B + SX, rescalure + SX, rhyncolure + SX, siglure + SX, sordidin + SX, sulcatol + SX, trimedlure + SX, trimedlure A + SX, trimedlure B1 + SX, trimedlure B2 + SX, trimedlure C + SX, trunc-call + SX, (E)-verbenol + SX, (Z)-verbenol + SX, trans-verbenol + SX, S-verbenone + SX.

[0208] Combinations of the present components of group (i) above with the present compounds: 2,3,6-TBA (2,3,6-trichlorobenzoic acid) + SX, 2,3,6-TBA-dimethylammonium + SX, 2,3,6-TBA-lithium + SX, 2,3,6-TBA-potassium + SX, 2,3,6-TBA-sodium + SX, 2,4-D + SX, 2,4-D choline salt + SX, 2,4-D-biproamine + SX, 2,4-D-doboxyl + SX, 2,4-D 2,4-D-2-ethylhexyl + SX, 2,4-D-3-butoxypropyl + SX, 2,4-D-ammonium + SX, 2,4-D-butotyl + SX, 2,4-D-butyl + SX, 2,4-D-diethylammonium + SX, 2,4-D-dimethylammonium + SX, 2,4-D-diolamine + SX, 2,4-D-dodecylammonium + SX, 2,4-D-ethyl + SX, 2,4-D-heptylammonium + SX, 2,4-D-isobutyl + SX, 2,4-D-isooctyl + SX, 2,4-D-isopropyl + SX, 2,4-D-isopropylammonium + SX, 2,4-D-lithium + SX, 2,4-D-meptyl + SX, 2,4-D-methyl4-D-methyl + SX, 2,4-D-octyl + SX, 2,4-D-pentyl + SX, 2,4-D-propyl + SX, 2,4-D-sodium + SX, 2,4-D-tefuryl + SX, 2,4-D-tetradecylammonium + SX, 2,4-D-triethylammonium + SX, 2,4-D-tris(2-hydroxypropyl)ammonium + SX, 2,4-D-trolamine + SX, 2,4-DB + SX, 2,4-DB choline salt + SX, 2,4-DB biproamine + SX, 2,4-DB butyl + SX, 2,4-DB dimethylammonium + SX, 2,4-DB isoctyl + SX, 2,4-DB potassium + SX, 2,4-DB sodium + SX, acetochlor + SX, acifluorfen + SX, acifluorfen sodium + SX, aclonifen + SX, ACN (2-amino-3-chloronaphthalene-1,4-dione) + SX, alachlor + SX, alloxydim + SX, ametryn + SX, amicarbazone + SX, amidosulfuron + SX, aminocyclopyrachlor + SX,Aminocyclopyrachlor-methyl + SX, aminocyclopyrachlor-potassium + SX, aminopyralid + SX, aminopyralid choline salt + SX, aminopyralid-potassium + SX, aminopyralid-tripromine + SX, amiprophos-methyl + SX, amitrole + SX, anilofos + SX, asulam + SX, atrazine + SX, azafenidin + SX, azimsulfuron + SX, beflubutamid + SX Benazolin-ethyl + SX, bencarbazone + SX, benfluralin + SX, benfuresate + SX, benquitrione + SX, bensulfuron + SX, bensulfuron-methyl + SX, bensulide + SX, bentazon + SX, benthiocarb + SX, benzfendizone + SX, benzobicyclon + SX, benzofenap + SX, benzthiazuron + SX, bialaphos + SX, Bicyclopyrone + SX, Bifenox + SX, Bipyrazone + SX, Bispyribac + SX,Bispyribac-sodium + SX, bixlozone + SX, bromacil + SX, bromobutide + SX, bromofenoxim + SX, bromoxynil + SX, bromoxynil octanoate + SX, butachlor + SX, butafenacil + SX, butamifos + SX, butroxydim + SX, butyrate + SX, cafenstrole + SX, carbetamide + SX, carfentrazone + SX, Carfentrazone-ethyl + SX, chlomethoxyfen + SX, chloramben + SX, chloridazon + SX, chlorimuron + SX, chlorimuron + SX, chlorimuron-ethyl + SX, chlorbromuron + SX, chlorotoluron + SX, chloroxuron + SX, chlorpropham + SX, chlorsulfuron + SX, chlorthal-dimethyl + SX, chlorthiamid + SX, cinflubrolin + SX, cinidon + SX, cinidon-ethyl + SX, Cinmethylin + SX, Cinosulfuron + SX, Clethodim + SX, Clodinafop + SX,Clodinafop-propargyl + SX, clomazone + SX, clomeprop + SX, clopyralid + SX, clopyralid choline salt + SX, clopyralid-methyl + SX, clopyralid-olamine + SX, clopyralid-potassium + SX, clopyralid-tris(2-hydroxypropyl)ammonium + SX, cloransulam + SX, cloransulam-methyl + SX, cumyluron + SX, cyanazine + SX, Cycloate + SX, cyclopyranil + SX, cyclopyrimorate + SX, cyclosulfamuron + SX, cycloxydim + SX, cyhalofop + SX, cyhalofop-butyl + SX, cypyrafluone + SX, dalapon + SX, dazomet + SX, desmedipham + SX, desmetryn + SX, di-allate + SX, dicamba + SX, dicamba choline salt + SX, dicamba-biproamine + SX, Dicambatrolamine + SX, Dicamba-diglycolamine + SX,Dicamba dimethylammonium + SX, dicamba diolamine + SX, dicamba isopropylammonium + SX, dicamba methyl + SX, dicamba olamine + SX, dicamba potassium + SX, dicamba sodium + SX, dichlobenil + SX, dichlorprop choline + SX, dichlorprop biproamine + SX, dichlorprop 2-ethylhexyl + SX, dichlorprop butotyl + SX, Dichlorprop-dimethylammonium + SX, dichlorprop-ethylammonium + SX, dichlorprop-isoctyl + SX, dichlorprop-methyl + SX, dichlorprop-P + SX, dichlorprop-P choline salt + SX, dichlorprop-P-biproamine + SX, dichlorprop-P-etexyl + SX, dichlorprop-P-dimethylammonium + SX, dichlorprop-potassium + SX, dichlorprop-sodium + SX, Diclofop + SX,Diclofop-methyl + SX, diclosulam + SX, difenoxuron + SX, difenzoquat + SX, difenzoquat methylsulfate + SX, diflufenican + SX, diflufenzopyr + SX, diflufenzopyr sodium + SX, dimefuron + SX, dimepiperate + SX, dimesulfazet + SX, dimethachlor + SX, dimethametryn + SX, dimethenamid + SX SX, dimethenamid P + SX, dinitramine + SX, dinoseb + SX, dinoterb + SX, dioxopyritrione + SX, diphenamid + SX, diquat-dibromide + SX, disodium methylarsonate (DSMA) + SX, dithiopyr + SX, diuron + SX, 2-methyl-4,6-dinitrophenol (DNOC) + SX, epirifenacil + SX, esprocarb + SX, ethalfluralin + SX, Ethametsulfuron + SX, ethametsulfuron-methyl + SX, ethidimuron + SX, ethofumesate + SX, ethoxyfen-ethyl + SX,Ethoxysulfuron + SX, etobenzanid + SX, fenoxaprop + SX, fenoxaprop-ethyl + SX, fenoxaprop-P + SX, fenoxaprop-P-ethyl + SX, fenoxasulfone + SX, fenpyrazone + SX, fenquinotrione + SX, fentrazamide + SX, fenuron + SX, feproxydim + SX, flamprop-M + SX, flazasulfuron + SX, florasulam + SX, florpyrauxifen + SX, florpyrauxifen-benzyl + SX, fluazifop + SX, fluazifop-butyl + SX, fluazifop-P + SX, fluazifop-P-butyl + SX, fluazolate + SX, flucarbazone + SX, flucarbazone-sodium + SX, flucetosulfuron + SX, fluchloraminopyr + SX, fluchloraminopyr-tefuryl + SX, flufenacet + SX, flufenoximacil + SX, flufenpyr + SX, flufenpyr-ethyl + SX, flumetsulam + SX,Flumetsulam + SX, Flumiclorac + SX, Flumiclorac-pentyl + SX, Flumioxazin + SX, Fluometuron + SX, Fluoroglycofen-ethyl + SX, Flupoxam + SX, Flupropanate + SX, Flupyl, Sulfuron + SX, flupyrsulfuron-methyl-sodium + SX, flurenol + SX, fluridone + SX, flurochloridone + SX, fluroxypyr + SX, fluroxypyr-butometyl + SX, fluroxypyr-meptyl + SX, flurtamone + SX, flusulfinam + SX, fluthiacet + SX, fluthiacet-methyl + SX, fomesafen + SX, fomesafen-sodium + SX Foramsulfuron + SX, fosamine + SX, glufosinate + SX, glufosinate-ammonium + SX, glufosinate-P + SX, glufosinate-P-ammonium + SX, glufosinate-P-sodium + SX, glyphosate + SX, glyphosate-choline + SX, glyphosate-isopropylammonium + SX, glyphosate-biproamine + SX, glyphosate-ammonium + SX SX, glyphosate-diammonium salt (glyphosate-diammonium) + SX, glyphosate-potassium salt (glyphosate-potassium) + SX,Glyphosate sodium + SX, glyphosate trimesium + SX, halauxifen + SX, halauxifen-benzyl + SX, halauxifen-methyl + SX, halosafen + SX, halosulfuron + SX, halosulfuron-methyl + SX, haloxyfop + SX, haloxyfop-ethotyl + SX, haloxyfop-methyl + SX, haloxyfop-P + SX, haloxyfop-P-ethotyl + SX Haloxyfop-P-methyl + SX, hexazinone + SX, icafolin + SX, icafolin-methyl + SX, imazamethabenz + SX, imazamethabenz-methyl + SX, imazamox + SX, imazamox-ammonium + SX, imazamox-sodium + SX, imazapic + SX, imazapic-ammonium + SX, imazapyr + SX, imazapyr-ammonium + SX, imazapyr-isopropylammonium + SX Imazaquin + SX, Imazaquin-ammonium + SX, Imazethapyr + SX,Imazethapyr ammonium salt + SX, imazosulfuron + SX, indanofan + SX, indaziflam + SX, indolauxipyr + SX, indolauxipyr-cyanomethyl + SX, iodosulfuron + SX, iodosulfuron-methyl-sodium + SX, iofensulfuron + SX, iofensulfuron sodium + SX, ioxynil + SX, ioxynil-octanoate + SX, ipfencarbazone + SX, Iptriazopyrid + SX, isoproturon + SX, isouron + SX, isoxaben + SX, isoxachlortole + SX, isoxaflutole + SX, lactofen + SX, lenacil + SX, linuron + SX, maleic hydrazide + SX, MCPA choline salt + SX, MCPA-biproamine + SX, MCPA-etexyl + SX, MCPA-butotyl + SX, MCPA-butyl + SX, MCPA-dimethylammonium + SX, MCPA-diolamine + SX, MCPA-ethyl + SX,MCPA-isobutyl + SX, MCPA-isoctyl + SX, MCPA-isopropyl + SX, MCPA-methyl + SX, MCPA-olamine + SX, MCPA-sodium + SX, MCPA-trolamine + SX, MCPB (4-(4-chloro-2-methylphenoxy)butanoic acid) + SX, MCPB-choline + SX, MCPB-biproamine + SX, MCPB-ethyl + SX, MCPB-methyl + SX, MCPB-sodium + SX, mecoprop choline + SX Mecoprop-biproamine + SX, mecoprop-2-ethylhexyl + SX, mecoprop-dimethylammonium + SX, mecoprop-diolamine + SX, mecoprop-ethadyl + SX, mecoprop-isoctyl + SX, mecoprop-methyl + SX, mecoprop-potassium + SX, mecoprop-sodium + SX, mecoprop-trolamine + SX, mecoprop-P + SX, mecoprop-P choline + SX SX, mecoprop-P-2-ethylhexyl + SX,Mecoprop-P-dimethylammonium + SX, mecoprop-P-isobutyl + SX, mecoprop-P-potassium + SX, mefenacet + SX, mesosulfuron + SX, mesosulfuron-methyl + SX, mesotrione + SX, metam + SX, metamifop + SX, metamitron + SX, metazachlor + SX, metazosulfuron + SX, methabenzthiazuron + SX, methiozolin + SX Methyldymron + SX, metobromuron + SX, metolachlor + SX, metoxuron + SX, metosulam + SX, metproxybicyclone + SX, metribuzin + SX, metsulfuron + SX, metsulfuron-methyl + SX, molinate + SX, monolinuron + SX, naproanilide + SX, naproxen + SX, napropamide + SX, nappropamide M + SX, naptalam + SX, neburon + SX, nicosulfuron + SX, norflurazon + SX, oleic acid + SX, orbencarb + SX,Orthosulfamuron + SX, Oryzalin + SX, Oxadiargyl + SX, Oxadiazon + SX, Oxasulfuron + SX, Oxaziclomefone + SX, Oxyfluorfen + SX, Paraquat + SX, Paraquat-dichloride + SX, Pebulate + SX, Pelargonic acid + SX, Pendimethalin + SX, Penoxsulam + SX, Pentanochlor + SX, Pentoxazone + SX Pethoxamid + SX, phenisopham + SX, phenmedipham + SX, picloram, picolinafen + SX, picolinafen + SX, pinoxaden + SX, piperophos + SX, pretilachlor + SX, primisulfuron + SX, primisulfuron-methyl + SX, prodiamine + SX, profluazol + SX, profoxydim + SX, prometon + SX, prometryn + SX, propachlor + SX, propanil + SX, propaquizafop + SX, propazine + SX, propham + SX, propisochlor + SX,Propoxycarbazone + SX, propoxycarbazone-sodium + SX, propyrisulfuron + SX, propyzamide + SX, prosulfocarb + SX, prosulfuron + SX, pyraclonil + SX, pyraquinate + SX, pyrasulfotole + SX, pyrazolinate + SX, pyrazosulfuron + SX, pyrazosulfuron-ethyl + SX, pyrazoxyfen + SX, pyribenzoxim + SX, Pyributicarb + SX, pyridafol + SX, pyridate + SX, pyriflubenzoxim + SX, pyriftalid + SX, pyriminobac + SX, pyriminobac-methyl + SX, pyrimisulfan + SX, pyrithiobac + SX, pyrithiobac-sodium + SX, pyroxasulfone + SX, pyroxsulam + SX, quinclorac + SX, quinmerac + SX, quizalofop + SX, Quizalofop-ethyl + SX, quizalofop-tefuryl + SX, quizalofop-P + SX, quizalofop-P-ethyl + SX,Quizalofop-P-tefuryl + SX, rimisoxafen + SX, rimsulfuron + SX, saflufenacil + SX, sethoxydim + SX, EPTC (S-ethyl N,N-dipropylcarbamothioate) + SX, siduron + SX, simazine + SX, simetryn + SX, S-metolachlor + SX, MSMA (sodium hydrogen methylarsonate) + SX, sulcotrione + SX, sulfentrazone + SX, sulfometuron + SX, Sulfometuron methyl + SX, sulfosulfuron + SX, swep + SX, 2,2,2-trichloroacetic acid (TCA) + SX, ammonium TCA + SX, calcium TCA + SX, ethadyl TCA + SX, magnesium TCA + SX, sodium TCA + SX, tebutam + SX, tebuthiuron + SX, tefuryltrione + SX, tembotrione + SX, tepraloxydim + SX, terbacil + SX, terbumeton + SX SX, terbuthylazine + SX, terbutryn + SX, tetflupyrolimet + SX, thaxtomin A + SX,Thenylchlor + SX, thiazopyr + SX, thidiazimin + SX, thiencarbazone + SX, thiencarbazone-methyl + SX, thifensulfuron + SX, thifensulfuron-methyl + SX, thifensulfuron + SX, thiafenacil + SX, tiocarbazil + SX, tolpi, Tolpyralate + SX, topramezone + SX, tralkoxydim + SX, triafamone + SX, tri-allate + SX, triasulfuron + SX, triaziflam + SX, tribenuron + SX, tribenuron-methyl + SX, triclopyr + SX, triclopyr-butotyl + SX, triclopyr-ethyl + SX, triclopyr-triethylammonium + SX, tridiphane + SX, trietazine + SX, Trifloxysulfuron + SX, trifloxysulfuron sodium + SX, trifludimoxazin + SX, trifluralin + SX, triflusulfuron + SX, triflusulfuron-methyl + SX, tripyrasulfone + SX, tritosulfuron + SX, vernolate + SX, 4-(4-fluorophenyl)-6-[(2-hydroxy-6-oxo-1-cyclohexen-1-yl)carbonyl]-2-methyl-1,2,4-triazine-3,5(2H,4H)-dione + SX, 2-chloro-N-(1-methyl-1H-tetrazol-5-yl)-3-(methylthio)-4-(trifluoromethyl)benzamide + SX, 2-methyl-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-(methanesulfonyl)-4-(trifluoromethyl)benzamide + SX, 1-{2-chloro-6-[(5-chloropyrimidin-2-yl)oxy]phenyl}-4,4,4-trifluorobutan-1-one (2052297-97-7) + SX. ,

[0209] Combinations of the present component and the present compound in group (j) above:

[0210] Subgroup (j-1): Combination of the present bacterial component and the present compound: Acidovorax wautersii + SX, Agrobacterium radiobacter strain K1026 + SX, Agrobacterium radiobacter strain K84 + SX, Agrobacterium vitis strain VAR03-1 + SX, Azorhizobium spp. + SX, Azorhizobium caulinodans strain ZB-SK-5 + SX, Azospirillum amazonense + SX, Azospirillum brasilense + SX, Azospirillum brasilense strain XOH + SX, Azospirillum brasilense strain Ab-V5 + SX, Azospirillum brasilense strain Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Azotobacter + SX, Azotobacter chroococcum Azotobacter chroococcum strain H23 + SX,Azotobacter salinestris strain CECT9690 + SX, Azotobacter vinelandii strain ATCC12837 + SX, Bacillus acidocaldarius + SX, Bacillus acidoterrestris + SX, Bacillus agri + SX, Bacillus albolactis + SX, Bacillus alcalophilus + SX, Bacillus alvei + SX, Bacillus aminoglucosidicus + SX, Bacillus aminovorans + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo™ EZ nematicide) + SX, Bacillus amyloliquefaciens strain AH2 + SX, Bacillus amyloliquefaciens strain AT79 + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX, Bacillus amyloliquefaciens strain BV03 + SX,Bacillus amyloliquefaciens strain CECT7657 + SX, Bacillus amyloliquefaciens strain D203 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain ENV503 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain IT-45 + SX, Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain R6-CDX + SX,Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens subsp. Plantarum strain D747 + SX, Bacillus amylolyticus + SX, Bacillus aneurinolyticus + SX, Bacillus atrophaeus + SX, Bacillus atrophaeus strain Abi05 + SX, Bacillus azotoformans + SX, Bacillus badius + SX, Bacillus cereus strain Ar56 + SX, Bacillus cereus strain B4 + SX, Bacillus cereus strain BP01 + SX, Bacillus cereus strain bromelia + SX, Bacillus cereus strain CIL + SX, Bacillus cereus CNCM strain I-1562 + SX, Bacillus cereus strain DGA34 + SX, Bacillus cereus strain N6 + SX, Bacillus cereus strain N7 + SX, Bacillus cereus strain peumo + SX,Bacillus cereus strain UW85 + SX, Bacillus chitinosporus strain AQ746 + SX, Bacillus chitinosporus strain CM-1 + SX, Bacillus circulans + SX, Bacillus coagulans strain TQ33 + SX, Bacillus fastidiosus + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus lacticola + SX, Bacillus lactimorbus + SX, Bacillus lactis + SX, Bacillus lautus + SX, Bacillus lentimorbus + SX, Bacillus lentus + SX, Bacillus licheniformis strain copihue + SX, Bacillus licheniformis strain B000106 + SX, Bacillus licheniformis strain DSM17236 + SX, Bacillus licheniformis strain FMCH001 + SX,Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus maroccanus + SX, Bacillus medusa + SX, Bacillus megaterium strain ATCC10778 + SX, Bacillus megaterium strain NCIM2087 + SX, Bacillus megaterium strain YFM3.25 + SX, Bacillus methylotrophicus strain BAC-9912 + SX methylotrophicus strain BAC-9912 + SX, Bacillus methylotrophicus strain C1 + SX, Bacillus methylotrophicus isolate UFPEDA20 + SX, Bacillus metiens + SX, Bacillus mojavensis strain R3 + SX, Bacillus mojavensis strain SR11 + SX, Bacillus mycoides strain AQ726 + SX, Bacillus mycoides isolate J + SX, Bacillus nematocida + SX, Bacillus nigrificans + SX, Bacillus nigrum + SX,Bacillus popilliae + SX, Bacillus psychrosaccharolyticus + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain CCTB05 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus safensis strain HCX-01 + SX, Bacillus siamensis strain KCTC 13613 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus smithii + SX, Bacillus sp. strain AQ175 + SX, Bacillus sp. strain AQ177 + SX, Bacillus sp. strain AQ178 + SX, Bacillus sphaericus strain 2362 serotype H5a5b + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus subtilis strain AFS032321 + SX, Bacillus subtilis strain antumavida + SX,Bacillus subtilis strain AP-01 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain B246 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain BV02 + SX, Bacillus subtilis strain BV09 + SX, Bacillus subtilis strain C-3102 subtilis strain C-3102 + SX, Bacillus subtilis strain CCTB04 + SX, Bacillus subtilis strain CX-9060 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain DB102 + SX, Bacillus subtilis strain FMCH002 + SX, Bacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX,Bacillus subtilis strain IAB / BS03 + SX, Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain DSM17231 + SX, Bacillus subtilis strain N5 + SX, Bacillus subtilis strain NCIM2063 + SX, Bacillus subtilis strain NCIM8872 + SX, Bacillus subtilis strain NSRS89-24 + SX, Bacillus subtilis strain PAH17 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 +, SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis strain RTI477 + SX, Bacillus subtilis strain S1 + SX, Bacillus subtilis strain S2 + SX, Bacillus subtilis strain SEIBS23 + SX, Bacillus subtilis strain UFPEDA764 + SX, Bacillus subtilis strain Y1336 subtilis strain Y1336 + SX, Bacillus subtilis strain YL13 + SX, Bacillus subtillis subsp. natto + SX, Bacillus subtilis var. amyloliquefaciens FZB24 + SXAmyloliquefaciens strain FZB24 + SX, Bacillus tequilensis strain 10b + SX, Bacillus tequilensis strain NII-0943 + SX, Bacillus thuringiensis strain 4042 + SX, Bacillus thuringiensis strain anemophila + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 + SX, Bacillus thuringiensis strain CR-371 + SX thuringiensis strain CR-371 + SX, Bacillus thuringiensis strain EX297512 + SX, Bacillus thuringiensis subsp. aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. aizawai strain GC-91 + SX, Bacillus thuringiensis subsp. aizawai strain NB200 + SX, Bacillus thuringiensis subsp. aizawai serotype H-7 + SX, Bacillus thuringiensis subsp. galleriae SDS-502 strain (Bacillus thuringiensis subsp.galleriae strain SDS-502 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 serotype H-14 + SX, Bacillus thuringiensis subsp. israelensis strain BMP144 + SX, Bacillus thuringiensis subsp. israelensis strain D142 + SX, Bacillus thuringiensis subsp. israelensis strain EG2215 + SX, Bacillus thuringiensis subsp. israelensis strain SA3A + SX, Bacillus thuringiensis subsp. israelensis strain SUM-6218 + SX, Bacillus thuringiensis subsp. israelensis strain VCRC B17 serotype 11-14 + SX, Bacillus thuringiensis subsp. israelensis strain VCRC B17 serotype 11-14 + SX, Bacillus thuringiensis subsp. israelensis strain VCRC B17 serotype 11-14 + SX, Bacillus thuringiensis subsp. japonensis) + SX, Bacillus thuringiensis kurstaki subsp. CrylA delta endotoxins (Bacillus thuringiensis subsp.Kurstaki CrylA delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki CrylC delta endotoxins + SX, Bacillus thuringiensis subsp. Kurstaki strain 3A3B + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306 + SX thuringiensis subsp. Kurstaki strain CCT1306 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2371 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2424 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7673 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7826 + SX thuringiensis subsp.Kurstaki strain EG7826 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain M-200) + SX,. Bacillus thuringiensis subsp. Kurstaki strain NCIM2514 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Kurstaki strain VBTS-2546 + SX, Bacillus thuringiensis subsp. Kurstaki strain Z-52, serotype H-3a, 3b + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis subsp. tenebriosis strain NB 176 + SX, Bacillus thuringiensis subsp. tenebriosis strain SA-10 + SX, Bacillus thuringiensis subsp. thuringiensis strain MPPL002 + SX MPPL002) + SX, Bacillus thuringiensis subsp. var. colmeri + SX,Bacillus thuringiensis subsp. var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis subsp. var. dendrolimus + SX, Bacillus thuringiensis subsp. var. galleriae + SX, Bacillus thuringiensis subsp. var. japonensis strain buibui + SX, Bacillus thuringiensis subsp. var. aegypti + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. sandiego strain M-7 + SX, Bacillus thuringiensis var. T36 + SX, Bacillus velezensis + SX, Bacillus velezensis isolate CNPSo3602 + SX, Bacillus velezensis strain ABi19 + SX, Bacillus velezensis strain FZB42 + SX, Bacillus velezensis strain FZB45 + SX, Bacillus velezensis strain NRRL B-41580 + SX,Bacillus velezensis strain RTI301 + SX, Bradyrhizobium spp. + SX, Bradyrhizobium elkanii + SX, Bradyrhizobium elkanii strain SEMIA 587 + SX, Bradyrhizobium elkanii strain SEMIA 5019 + SX, Bradyrhizobium japonicum + SX, Bradyrhizobium japonicum strain TA-11 + SX SX, Bradyrhizobium japonicum strain USDA 110 + SX, Bradyrhizobium japonicum strain WB74 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Bradyrhizobium lupini strain LL13 + SX, Bradyrhizobium spp. (Arachis) + SX, Bradyrhizobium spp. (Vigna) + SX, Brevibacillus brevis strain maguellines I + SX, Brevibacillus brevis strain 2904 + SX, Brevibacillus brevis strain SS86-3 + SX,Brevibacillus brevis strain SS86-4 + SX, Brevibacillus brevis strain SS86-5 + SX, Brevibacillus laterosporus strain ATCC64 + SX, Brevibacillus laterosporus strain BPM3 + SX, Brevibacillus laterosporus strain G4 + SX, Brevibacillus laterosporus strain NCIMB 41419 + SX, Brevibacillus laterosporus strain NRS1111 + SX, Brevibacillus laterosporus strain NRS1645 + SX, Brevibacillus laterosporus strain NRS1647 + SX, Burkholderia ambifaria strain AMMD + SX, Burkholderia cenocepacia strain A396 + SX, Burkholderia cenocepacia strain Ral-3 + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX,Burkholderia cepacia + SX, Burkholderia gladii strain BA-7 + SX, Burkholderia rinojensis strain A396 + SX, Chromobacterium subtsugae strain PRAA4-1T + SX, Corynebacterium flavescens strain B2575 + SX, Corynebacterium glutamicum + SX, Delftia acidovorans + SX, Delftia acidovorans strain RAY209 acidovorans strain RAY209 + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Gluconacetobacter diazotrophicus strain IMI504853 + SX, Klebsiella variicola 137 + SX, Kosakonia cowanii strain SYM00028 + SX, Lactobacillus acidophilus + SX, Lactobacillus brevis + SX, Lactobacillus casei strain LPT-111 + SX, Lactobacillus plantarum + SX, Lactobacillus spp. + SX,Lysobacter antibioticus strain 13-1 + SX, Lysobacter enzymogenes strain B25 + SX, Lysobacter enzymogenes strain C3 + SX, Metylobacterium spp. + SX, Methylobacterium isolate ISO01 + SX, Methylobacterium isolate ISO02 + SX, Methylobacterium isolate ISO03 + SX, Methylobacterium isolate ISO04 + SX, Methylobacterium isolate ISO07 + SX, Methylobacterium isolate ISO09 + SX, Methylobacterium isolate ISO10 + SX, Methylobacterium isolate ISO11 + SX, Methylobacterium symbioticum + SX, Mesorhizobium spp. + SX, Mesorhizobium ciceri + SX, Mesorhizobium huakii + SX, Mesorhizobium loti + SX, Paenibacillus alvei strain 2771 + SX, Paenibacillus alvei strain 46C3 + SX,Paenibacillus alvei strain III2E + SX, Paenibacillus alvei strain III3DT-1A + SX, Paenibacillus alvei strain T36 + SX, Paenibacillus macerans + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Paenibacillus polymyxa strain H-5 + SX, Paenibacillus popilliae + SX, Pantoea agglomerans strain E325 + SX, Pantoea vagans strain C9-1 + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria ramose + SX, Pasteuria usgae + SX, Pectobacterium carotovorum + SX, Pasteuria thornei + SX, Pseudomonas aeruginosa strain PN1 + SX, Pseudomonas aeruginosa strain WS-1 + SX,Pseudomonas aureofaciens strain TX-1 + SX, Pseudomonas alcaligenes + SX, Pseudomonas cepacia type Wisconsin strain J82 + SX, Pseudomonas cepacia type Wisconsin strain M54 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX chlororaphis strain MA342 + SX, Pseudomonas entomophila strain 1257 + SX, Pseudomonas fluorescens isolate Pf-5 + SX, Pseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain ACK55 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain D7 + SX,Pseudomonas fluorescens strain G7090 + SX, Pseudomonas fluorescens biover B strain XJ3 + SX, Pseudomonas fluorescens biover B strain XS18 + SX, Pseudomonas fluorescens biover A strain LRS12 + SX, Pseudomonas proradix + SX, Pseudomonas putida strain CECT8538 (Pseudomonas, as putida strain CECT8538 + SX, Pseudomonas reactans + SX, Pseudomonas resinovorans + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas sp. strain DSMZ13134 + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain ESC-10 + SX SX, Pseudomonas syringae strain ESC-11 + SX, Pseudomonas syringae strain MA-4 + SX, Pseudomonas trivialis + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium leguminosarum bv. Phaseoli + SX, Rhizobium leguminosarum bv. Trifolii + SX, Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Rhodococcus globerulus strain AQ719 + SX,Saccharopolyspora spinosa + SX, Serratia entomophila strain 626 + SX, Serratia marcescens strain 35 + SX, Serratia marcescens strain SRM + SX, Serratia nematodiphila strain S-CSR-0024 + SX, Sphingobacterium nematocida strain ZY-71-1 + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti meliloti + SX, Streptomyces acidiscabies strain RL-110T + SX, Streptomyces candidus strain Y21007-2 + SX, Streptomyces colombiensis + SX, Streptomyces galbus strain QST6047 + SX, Streptomyces globosus strain LZH-48 + SX, Streptomyces goshikiensis + SX, Streptomyces griseofuscus strain 200101 + SX, Streptomyces griseoviridis strain K61 + SX,Streptomyces jalisciencis isolate CM-CNRG0001 + SX, Streptomyces jofer isolate CM-CNRG0002 + SX, Streptomyces lavendulae + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Streptomyces microflavus strain AQ6121 + SX, Streptomyces prasinus + SX, Streptomyces rimosus + SX, Streptomyces saraceticus + SX, Streptomyces sp. strain NRRL No. B-30145 + SX, Streptomyces sp. strain WYE20 + SX, Streptomyces sp. strain WYE 324 + SX, Streptomyces venezuelae + SX, Thiobacillus spp. + SX, Variovorax paradoxus strain GF4526 + SX, Virgibacillus pantothenticus strain ATCC14576 + SX,Virgibacillus pantothenticus strain DSM491 + SX, Wolbachia pipientis + SX, Xanthomonas campestris pv poae + SX, Xanthomonas campestris + SX, Xenorhabdus luminescens + SX, Xenorhabdus nematophila + SX.

[0211] Subgroup (j-2): Combination of this compound with the component of fungi and yeast Acaulospora spp. + SX, Acaulospora longula + SX, Alternaria destruens + SX, Alternaria destruens strain 59 + SX, Ambispora spp. + SX, Ambispora leptoticha + SX, Ampelomyces quisqualis strain AQ10 + SX, Ampelomyces quisqualis strain RSAQ7690 + SX, Ampelomyces quisqualis strain M-10 + SX SX, Archaeospora spp. + SX, Arkansas Fungus 18 + SX, Arthrobotrys dactyloides + SX, Arthrobotrys superba + SX, Aschersonia aleyrodis + SX, Aspergillus flavus strain AF36 + SX, Aspergillus flavus strain MUCL54911 + SX, Aspergillus flavus strain NRRL21882 + SX, Aureobasidium pullulans strain DSM14940 + SX, Aureobasidium pullulans strain DSM14941 + SX,Aureobasidium pullulans strain YBCA5 + SX, Beauveria bassiana isolate B21 + SX, Beauveria bassiana isolate B33 + SX, Beauveria bassiana isolate CBMAI1306 + SX, Beauveria bassiana strain 147 + SX, Beauveria bassiana strain 203 + SX, Beauveria bassiana strain 447 + SX, Beauveria bassiana strain ANT-03 ANT-03 + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain ATP02 + SX, Beauveria bassiana strain CFL-A + SX, Beauveria bassiana strain CG716 + SX, Beauveria bassiana strain ESALQ PL63 + SX, Beauveria bassiana strain GHA + SX, Beauveria bassiana strain HF23 + SX, Beauveria bassiana strain IBCB66 + SX, Beauveria bassiana strain IMI389521 + SX,Beauveria bassiana strain J25 + SX, Beauveria bassiana strain NCIM1216 ATCC26851 + SX, Beauveria bassiana strain NPP111B005 + SX, Beauveria bassiana strain PL63 + SX, Beauveria bassiana strain PPRI 5339 + SX, Beauveria bassiana strain R444 + SX, Beauveria bassiana strain ZJU435 + SX ZJU435 + SX, Beauveria brongniartii + SX, Beauveria brongniartii isolate IMBST95.031 + SX, Beauveria brongniartii isolate IMBST95.041 + SX, Candida oleophila strain O + SX, Candida oleophila isolate I-182 + SX, Candida saitoana + SX, Candida spp. + SX, Cell walls of Saccharomyces cerevisiae strain LAS117 + SX, Chaetomium cupreum + SX, Chlorella + SX, Chondrostereum purpureum + SX,Cladosporium cladosporioides strain H39 + SX, Claroideoglomus spp. (formerly Glomus spp.) + SX, Claroideoglomus claroideum (formerly Glomus claroideum) + SX, Claroideoglomus etunicatum (formerly Glomus etunicatum) + SX, Claroideoglomus luteum + SX, Clonostachys rosea strain ACM941 + SX, Clonostachys rosea strain CR-7 CR-7 + SX, Clonostachys rosea strain IDAC 040913-01 + SX, Clonostachys rosea strain J1446 + SX, Colletotrichum gloeosporioides + SX, Conidiobolus obscurus + SX, Conidiobolus thromboide + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-08 CON / M / 91-08) + SX, Cryphonectria parasitica + SX, Cryptococcus albidus + SX,Cryptococcus flavescens + SX, Cylindrobasidium laeve + SX, Dactyllela ellipsospora + SX, Decylaria thaumasia + SX, Dilophosphora alopecuri + SX, Diversispora spp. + SX, Enterococcus faecium + SX, Entomophthora virulenta + SX, Entrophospora spp. + SX, Entyloma ageratinae ageratinae + SX, Epicoccum nigrum + SX, Funneliformis spp. (formerly Glomus spp.) + SX, Funneliformis mosseae (formerly Glomus mosseae) + SX, Fusarium oxysporum strain Fo47 + SX, Fusarium oxysporum strain RS-21 + SX, Fusarium oxysporum strain RS-25 + SX, Fusarium proliferatum strain NCIM1101 + SX, Geosiphon spp. + SX, Gigaspora spp. + SX, Gigaspora margarita + SX, Gigaspora rosea + SX,Gliocladium catenulatum strain J1446 + SX, Gliocladium roseum + SX, Gliocladium virens strain GL-21 + SX, Glomus spp. + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus etunicatum + SX, Glomus iranicum + SX, Glomus monosporum + SX, Hirsutella minnesotensis minnesotensis + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Isaria fumosorosea isolate B3 + SX, Isaria fumosorosea strain Isfm-CPF + SX, Isaria tenuipes + SX, Laccaria bicolor + SX, Laccaria laccata + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 + SX, Lecanicillium lecanii conidia of strain DAOM198499 + SX, Lecanicillium lecanii conidia of strain DAOM216596 + SX,Lecanicillium muscarium (formerly Verticillium lecanii) strain 1 / 1 + SX, Lecanicillium muscarium (formerly Verticillium lecanii) strain Ve6 + SX, Metarhizium anisopliae isolate D1 + SX, Metarhizium anisopliae isolate IBCB425 + SX, Metarhizium anisopliae strain CQMa421 + SX, Metarhizium anisopliae strain ESALQ E9 + SX, Metarhizium anisopliae strain ESF1 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae strain FI-985 + SX, Metarhizium anisopliae strain FI-1045 + SX, Metarhizium anisopliae strain ICIPE30 + SX, Metarhizium anisopliae strain ICIPE62 + SX, Metarhizium anisopliae strain ICIPE69 + SX anisopliae strain ICIPE69 + SX, Metarhizium anisopliae strain ICIPE78 + SX,Metarhizium anisopliae strain NCIM1311 + SX, Metarhizium anisopliae var. acridum strain EVCH077 + SX, Metarhizium anisopliae var. acridum isolate IMI 330189 + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium brunneum strain Cb15-III Cb15-III + SX, Metarhizium flavoviride strain F001 + SX, Metarhizium rileyi strain PHP1705 + SX, Metschnikowia fructicola strain NRRLY-27328 + SX, Metschnikowia fructicola strain NRRLY-30752 + SX, Microdochium dimerum strain L13 + SX, Microsphaeropsis ochracea + SX, Monacrosporium phymatopagum + SX, Mucor hiemalis + SX, Muscodor albus strain 620 + SX, Muscodor albus strain QST 20799 + SX,Muscodor albus strain SA13 + SX, Muscodor roseus strain A3-5 + SX, Myrothecium verrucaria strain AARC-0255 + SX, Nomuraea rileyi strain CG128 + SX, Nomuraea rileyi strain GU87401 + SX, Nomuraea rileyi strain SA86101 + SX, Nomuraea rileyi strain SR86151 + SX, Nomuraea lily VA9101 strain (Nomurae, a rileyi strain VA9101 + SX, Ophiostoma piliferum strain D97 + SX, Pacispora spp. + SX, Paecilomyces fumosoroseus Apopka 97 (now known as Isaria fumosorosea Apopka strain 97) + SX, Paecilomyces fumosoroseus strain FE9901 (now known as Isaria fumosorosea FE9901) + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paecilomyces variotii strain Q-09 + SX, Pandora delphacis + SX, Paraglomus spp. + SX, Paraglomus brasilianum (formerly Glomus brasilianum) + SX, Penicillium bilaiae strain ATCC22348 + SX, Penicillium citrinum strain VFI-51 VFI-51 + SX, Penicillium vermiculatum + SX, Phlebiopsis gigantea strain FOC PG410.3 + SX,Phlebiopsis gigantea strain VRA1835 + SX, Phlebiopsis gigantea strain VRA1984 + SX, Phlebiopsis gigantea strain VRA1985 + SX, Phlebiopsis gigantea strain VRA1986 + SX, Phlebiopsis gigantea strain VRA1992 + SX, Phlebiopsis spp. + SX, Phoma macrostroma 94-44B strain strain 94-44B + SX, Phytophthora palmivora + SX, Pichia anomala strain WRL-076 + SX, Pichia guilliermondii strain Z1 + SX, Pichia guilliermondii strain Z8 + SX, Pisolithus tinctorius + SX, Pochonia chlamydosporia isolate strain PC10 + SX, Pochonia chlamydosporia + SX, Pseudozyma flocculosa strain ATTC64874 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Puccinia thlaspeos strain woad + SX,Purpureocillium lilacinum strain 251 + SX, Purpureocillium lilacinum strain PL11 + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Racocetra spp. + SX, Rhizophagus spp. (formerly Glomus spp.) + SX, Rhizophagus clarus (formerly Glomus clarum) + SX, Rhizophagus intraradices, (formerly Glomus intraradices) + SX, Rhizophagus intraradices strain RTI-801 + SX, Rhizophagus irregularis (formerly Glomus intraradices) + SX, Rhizophagus irregularis strain DAOM 197198 + SX, Scutellospora spp. + SX, Rhizopogon amylopogon + SX, Rhizopogon fulvigleba + SX, Rhizopogon luteolus + SX, Rhizopogon villosullus + SX, Saccharomyces cerevisiae strain LAS02 + SX,Saccharomyces cerevisiae strain DDSF623 + SX, Saccharomyces cerevisiae strain SP.1026 + SX, Scleroderma cepa + SX, Scleroderma citrinum + SX, Sclerotinia minor strain IMI34414 + SX, Sporothrix insectorum + SX, Suillus granulatus + SX, Suillus punctatapies + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma afroharzianum + SX, Trichoderma album + SX, Trichoderma asperelloides strain JM41R + SX, Trichoderma asperellum strain CBMAI840 + SX, Trichoderma asperellum strain CBMAI1622 + SX, Trichoderma asperellum strain BV09 + SX, Trichoderma asperellum strain BV10 + SX,Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum strain kd + SX, Trichoderma asperellum strain M103 + SX, Trichoderma asperellum strain RNCIM F-1323 + SX, Trichoderma asperellum strain T11 + SX, Trichoderma asperellum strain T25 + SX, Trichoderma asperellum strain T34 + SX Trichoderma asperellum strain SKT-1 + SX, Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain 77B + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain I-1237 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain K4 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride strain LU132 + SX,Trichoderma atroviride strain SC1 + SX, Trichoderma atroviride strain SKT-1 + SX, Trichoderma atroviride strain T11 + SX, Trichoderma atroviride strain TV1 + SX, Trichoderma atroviride strain WW10TC4 + SX, Trichoderma gamsii strain ICC080 + SX, Trichoderma harmatum strain 382 + SX, Trichoderma harmatum strain TH382 + SX, Trichoderma harzianum strain 21 + SX, Trichoderma harzianum strain AP-001 + SX, Trichoderma harzianum strain BK-Th001 + SX, Trichoderma harzianum strain CBS101525 + SX, Trichoderma harzianum strain DB 104 + SX, Trichoderma harzianum strain DSM 14944 + SX harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX,Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain F11Bab + SX, Trichoderma harzianum strain Gomorteka + SX, Trichoderma harzianum strain IB19 / 17 + SX, Trichoderma harzianum strain IBLF006 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain K2 + SX, Trichoderma harzianum strain kd + SX, Trichoderma harzianum strain KRL-AG2 + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain queule + SX, Trichoderma harzianum strain RR17Bc + SX, Trichoderma harzianum strain SF harzianum strain SF) + SX, Trichoderma harzianum strain T5) + SX,Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T24 + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma harzianum strain TH315 + SX, Trichoderma harzianum rifai + SX, Trichoderma koningii + SX, Trichoderma lignorum strain TL-0601 + SX, Trichoderma lignorum + SX, Trichoderma longibrachiatum strain T-397 + SX, Trichoderma polysporum strain IMI206039 + SX, Trichoderma parceramosum + SX, Trichoderma reesei + SX, Trichoderma strain SKT-1 + SX, Trichoderma spp. + SX, Trichoderma saturnisporium strain PBP-TH-001 + SX, Trichoderma stromaticum + SX,Trichoderma virens strain chagual + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 (formy Gliocladium virens GL-21) + SX, Trichoderma virens strain nire + SX, Trichoderma virens strain sherwood + SX, Trichoderma viride strain (NRRL B-50520) + SX, Trichoderma viride strain K5 + SX, Trichoderma viride strain T111 + SX, Tsukamurella paurometabola strain C-924 + SX, Tsukamurella paurometabola, Tsukamurella paurometabola + SX, Typhula phacorrhiza strain 94671 + SX, Ulocladium oudemansii strain HRU3 + SX, Ulocladium oudemansii strain U3 + SX, Verticillium alboatrum strain WCS850 + SX, Verticillium chlamydosporium + SX, Verticillium dahliae + SX, Verticillium lecanii strain ID05-F0117 ID05-F0117 + SX, Verticillium lecanii strain NCIM1312 + SX, Verticillium lecanii strain SZWL7 + SX, Zoophtora radicans + SX.

[0212] Subgroup (j-3): Combination of the present component of protozoa with the present compound: Nosema locustae + SX, Thelohania solenopsis + SX, Vairimorpha spp. strain Q-09 + SX.

[0213] Subgroup (j-4): Combination of this component of the virus with this compound: Adoxophyes orana granulovirus BV-0001 (GV (granulovirus) strain BV-0001) + SX, Agrotis segetum nucleopolyhedrovirus NPV (nucleopolyhedrovirus) + SX, Anagraoha falcifera NPV (NPV) + SX, Anticarsia gemmatalis MNPV (multiple nucleocapsid nucleopolyhedrovirus) + SX, Autographa californica MNPV strain FV11 (MNPV) + SX, Autographa californica MNPV strain R3 (MNPV) + SX SX, Bacteriophage of Clavibacter michiganesis + SX, Bacteriophage active against Clavibacter michiganensis subsp. michiganensis + SX, Bacteriophage active against Erwinia amylovora + SX, Bacteriophage active against Pseudomonas syringae pv. tomato + SX, Bacteriophage active against Xanthomonas campestris pv. vesicatoria + SX, Bacteriophage active against Xanthomonas citri subsp. citri + SX, Bacteriophage against Xylella fastidiosa + SX, Biston suppressaria NPV + SX, Bombyx mori NPV + SX,Chrysodeixis includens nucleopolyhedrovirus isolate 460 + SX, Cryptophlebia leucotreta granulosis virus (GV) + SX, Cydia pomonella granulosis virus (GV) + SX, Cydia pomonella granulosis virus M (GV M) + SX, Cydia pomonella granulosis virus CP4 (GV strain CP4) + SX, Cydia pomonella granulosis virus R5 (GV strain R5) + SX, Cydia pomonella granulosis virus V15 (GV strain V15) + SX Cydia pomonella granulosis virus V22 + SX, Douglas fir tussock moth NPV + SX, Dendrolimus punctatus cypovirus + SX, Ectropis obliqua picorna-like virus + SX, Helicoverpa armigera NPV + SX, Helicoverpa armigera NPV strain BV-0003 + SX, Helicoverpa zea NPV + SX, Indian meal moth granulosis virus GV) + SX, Leucoma salicis NPV + SX, Lymantria dispar MNPV + SX, Mamestra brassicae NPV + SX,Mamestra configurata nucleopolyhedrosis virus (NPV) + SX, Neodiprion abietis nucleopolyhedrosis virus (NPV) + SX, Neodiprion lecontei nucleopolyhedrosis virus (NPV) + SX, Neodiprion sertifer nucleopolyhedrosis virus (NPV) + SX, Orgyia pseudotsugata nucleopolyhedrosis virus (NPV) + SX, pepino mosaic virus strain CH2 isolate 1906 + SX, pepino mosaic virus strain CH2 isolate Abp1 + SX Pepino mosaic virus strain CH2 isolate Abp2 + SX, Pepino mosaic virus isolate VC1 + SX, Pepino mosaic virus isolate VX1 + SX, Phthorimaea operculella GV isolate DSMZ GV-0019 + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Plutella xylostella GV + SX Spodoptera albula MNPV + SX, Spodoptera exempta MNPV + SX,Spodoptera exigua MNPV strain BV-0004 + SX, Spodoptera frugiperda MNPV + SX, Spodoptera littoralis MNPV isolate DSMZ BV-0005 + SX, Spodoptera litura NPV + SX, Tobacco mild tobamovirus strain U2 + SX, Zucchini Yellow Mosaic Virus weak strain + SX.

[0214] Subgroup (j-5): Combination of the present component of nematodes and the present compound: Abreviata caucasica + SX, Acuaria spp. + SX, Agamermis decaudata + SX, Allantonema spp. + SX, Amphimermis spp. + SX, Deladenus siricidicola + SX, Bovienema spp. + SX, Cameronia spp. + SX, Chitwoodiella ovofilamenta + SX, Contortylenchus spp. + SX, Culicimermis spp. + SX, Diplotriaena spp. + SX, Empidomermis spp. + SX, Filipjevimermis leipsandra + SX, Gastromermis spp. + SX, Gongylonema spp.) + SX, Gynopoecilia pseudovipara + SX, Heterorhabditis bacteriophora + SX, Heterorhabditis baujardi + SX, Heterorhabditis downesi + SX, Heterorhabditis heliothidis + SX, Heterorhabditis indica + SX, Heterorhabditis marelatus + SX, Heterorhabditis megidis + SX, Heterorhabditis zealandica zealandica + SX, Hexamermis spp. + SX, Hydromermis spp. + SX, Isomermis spp. + SX, Limnomermis spp. + SX, Maupasina weissi + SX, Mermis nigrescens + SX, Mesomermis spp. + SX, Neomesomermis spp. + SX, Neoparasitylenchus rugulosi + SX, Octomyomermis spp. spp.) + SX, Parasitaphelenchus spp.) + SX, Parasitorhabditis spp.) + SX, Parasitylenchus spp.) + SX, Perutilimermis culicis + SX, Phasmarhabditis hermaphrodita isolate DDT M1 + SX, Physaloptera spp. + SX, Protrellatus spp. + SX, Pterygodermatites spp. + SX, Romanomermis spp. + SX, Seuratum cadarachense + SX, Sphaerulariopsis spp. + SX, Spirura guianensis + SX, Steinernema bibionis + SX, Steinernema carpocapsae + SX, Steinernema feltiae isolate DDT D2 + SX, Steinernema glaseri + SX, Steinernema indica + SX, Steinernema kraussei + SX, Steinernema riobrave + SX, Steinernema scapterisci + SX, Steinernema scarabaei + SX, Steinernema siamkayai + SX, Steinernema thailandse + SX, Steinernema spp.) + SX, Strelkovimermis peterseni + SX, Subulura spp. + SX, Sulphuretylenchus elongatus + SX, Tetrameres spp. + SX.

[0215] Subgroup (j-6): Combination of the present component of natural products and the present compound: (2S,3R,4R,5S)-2,5-bis(hydroxymethyl)pyrrolidine-3,4-diol + SX, 1,4-dimethylnapthalene + SX, 2-methyl-1-butanol + SX, 2-phenylethyl propionate + SX, 9,21-didehydroryanodine + SX, alizarin 2-glucoside + SX, dihydroazadirachtin + SX, ethyl 3-[acetyl(butyl)amino]propanoate + SX, glycerol monocaprate + SX, glycerol monocaprylate + SX, glycerol monolaurate + SX, heptyl butyrate + SX, methyl anthranilate + SX, methyl nonyl ketone + SX, methyl Salicylate + SX, N-(3-methyl-2-buten-1-yl)-9H-purin-6-amine + SX, N,N'-diformylurea + SX, octanal + SX, oxypurinol + SX, p-cymene + SX, p-menthane-3,8-diol + SX, phenazine-1-carboxylic acid + SX, propylene glycol monocaprylate + SX, propylene glycol monolaurate + SX, sorbitol octanoate + SX, sucrose octanoate + SX, terpinen-4-ol + SX, balsam of fir oil (Abies balsamea oil) + SX, α-ionone + SX, β-citronellol + SX, gamma-Terpinene + SX, ammonium bicarbonate + SX, anabasine + SX, anise oil + SX,Ascaridole + SX, azadirachtin + SX, Celastrus angulatus bark + SX, Brassica juncea (mustard) + SX, brassinolide + SX, Bacillus thuringiensis Cry1Ab protein + SX, Bacillus thuringiensis Cry1Ac protein + SX, Bacillus thuringiensis Cry1Fa protein + SX, Bacillus thuringiensis Cry1A.105 protein + SX, Bacillus Cry2Ab protein from Bacillus thuringiensis (Bacillus thuringiensis Cry2Ab protein) + SX, Vip3A protein from Bacillus thuringiensis (Bacillus thuringiensis Vip3A protein) + SX, mCry3A protein from Bacillus thuringiensis (Bacillus thuringiensis mCry3A protein) + SX, Cry3Ab protein from Bacillus thuringiensis (Bacillus thuringiensis Cry3Ab protein) + SX, Cry3Bb protein from Bacillus thuringiensis (Bacillus thuringiensis Cry3Bb protein) + SX,Bacillus thuringiensis Cry34Ab1 / Cry35Ab1 protein + SX, insecticidal protein Tma12 derived from the fern Tectaria macrodonata + SX, insecticidal protein IPD083 derived from the fern Adiantum spp. + SX, insecticidal protein IPD113 derived from the fern Pteris cretica cv. albolineata or Pteris umbrosa + SX, calcium acetate + SX, calcium lactate + SX, calcium polysulfide + SX, canola oil + SX, capsaicin + SX, capsicum oleoresin + SX, castor oil + SX, cedarwood oil + SX, cevadine + SX, chitin + SX, chitosan + SX, chlorophyllin + SX, chlortetracycline + SX, cinerin I + SX, cinerin II + SX, cinnamaldehyde + SX, cis-jasmone + SX, citral + SX, citric acid + SX,Citronella oil + SX, Citrus bergamia fruit oil + SX, clarified hydrophobic extract of neem oil + SX, clove oil + SX, collagen protein hydrolysate + SX, colletochlorin B + SX, concanamycin A + SX, cottonseed oil + SX, cytokinin + SX, cow's milk + SX, deguelin + SX, diallyl sulfide + SX, d-limonene + SX, dried leaves of Dryopteris filix-mas + SX, Ea peptide 91398 + SX, eucalyptol + SX, black wattle extract (extract of Acacia mearnsii) + SX, Achillea fragrantissima extract (extract of Achillea fragrantissima) + SX, onion extract (extract of Allium cepa) + SX, garlic extract (extract of Allium sativum) + SX, dill extract (extract of Anethum graveolens) + SX, sugar apple extract (extract of Annona squamosa) + SX, burdock extract (extract of Arctium lappa) + SX, wormwood extract (extract of Artemisia absinthium) + SX, jackfruit extract (extract of Artocarpus heterophyllus) + SX,Neem extract (extract of Azadirachta indica) + SX, Calendula extract (extract of Calendula officinalis) + SX, Tea plant extract (extract of Camelia sinensis) + SX, Capsicum annum extract (extract of Capsicum annum) + SX, Cassia nigricans extract (extract of Cassia nigricans) + SX, Chenopodium ambrosioides extract (extract of Chenopodium quinoa) + SX, Cinnamon extract (extract of Cinnamomum verum) + SX, Clitoria ternatea extract (extract of the cotyledons of lupine plantlets ("BLAD")) + SX, Daphne gnidium extract (extract of Daphne gnidium) + SX, extract of Equisetum arvense + SX, extract of Equisetum giganteum + SX, extract of Galenia africana + SX, extract of green tea + SX, extract of Liliaceae plant Liliaceae) + SX, extract of Macleaya + SX, extract of Matricaria chamomilla + SX, extract of Melaleuca alternifolia + SX, extract of Millettia pinnata + SX,Opuntia lindheimeri extract (extract of Opuntia lindheimeri) + SX, Oregano extract (extract of Origanum vulgare) + SX, Piper auritum extract (extract of Piper auritum) + SX, Pyrethrum extract (extract of Pyrethrum), Southern red oak extract (extract of Quercus falcata) + SX, Quillaja extract (extract of Quillaja saponaria) + SX, Giant knotweed extract (extract of Reynoutria sachalinensis) + SX, Siebold tree extract (extract of Rhamnus utilis) + SX, Sumac extract (extract of Rhus aromatica) + SX, Rheum officinale extract (extract of Rhizophora mangle) + SX, Rosemary extract (extract of Rosmarinus officinalis + SX, Ruta chalepensis extract + SX, Sabadilla seed extract + SX, Sweet lupin seed extract + SX, Swinglea glutinosa extract + SX, Comfrey extract + SX, Sweet lupinseed extract + SX, Tagetes erecta extract + SX, Tansy extract + SX, Thymus vulgaris extract + SX,Nasturtium extract (Tropaeolum majus extract) + SX, Stinging nettle extract (Urtica dioica extract) + SX, Mistletoe extract (Viscum album extract) + SX, Yucca schidigera extract (Yucca schidigera extract) + SX, Fenugreek seed powder + SX, Fish oil + SX, Formic acid + SX, Geraniol + SX, Ginkgolide A + SX, Ginkgolide B + SX, Ginkgolide C + SX, Ginkgolide J + SX, Ginkgolide M + SX, Gougerotin + SX GS-omega / kappa HXTX-Hv1a peptide + SX, Harpin protein + SX, hydrogenated castor oil + SX, hydroprene + SX, Illicium verum oil + SX, ivermectin + SX, jasmolin I + SX, jasmolin II + SX, jojoba oil + SX, karanjin + SX, kasugamycin + SX, kinoprene + SX, laminarin + SX, L-ascorbic acid + SX, Oak leaves and bark of Quercus + SX, Lemongrass oil + SX, L-glutamic acid + SX, Linalool + SX,Linseed oil + SX, Alyssum (Lobularia maritima) + SX, Lysophosphatidylethanolamine + SX, Maltodextrin + SX, Matrine + SX, Matrine N-oxide + SX, Menthol + SX, Methoprene + SX, Milbemycin A4 + SX, Mildiomycin + SX, Natamycin + SX, Nemadectin + SX, Nepeta cataria oil + SX, Nootkatone + SX, Chenopodium oil anthelminticum + SX, orange oil + SX, Pelargonium odoratissimum oil + SX, pellitorine + SX, piperine + SX, Piper nigrum seed oil + SX, polyoxin B + SX, polyoxorim + SX, potassium phosphonate + SX, potassium silicate + SX, precocene II + SX, putrescent whole egg solids + SX, pyrethrin I + SX, pyrethrin II + SX, Quillaja extract + SX, rotenone + SX, rapeseed oil + SX, rhamnolipid + SX,Ryanodine + SX, Rosemary oil + SX, Sabadilla + SX, Salicylic acid + SX, Sanguinarine + SX, Saponins of Chenopodium quinoa + SX, Sesame oil + SX, Soy lecithin + SX, Soybean oil + SX, Spinosad + SX, Squamocin + SX, Streptomycin + SX, Sunflower oil + SX, Tagetes oil + SX, Terpene constituents of the extract of Chenopodium Ambrosioides near ambrosioides, Brand name: Terpenoid blend QRD 460) + SX, Thyme oil + SX, Thymol + SX, Trypsin modulating oostatic factor + SX, Veratrine + SX, Veratridine + SX, Quassia amara wood extract + SX, Xanthine + SX, Yellow mustard powder + SX.

[0216] Subgroup (j-7): Combination of the present component of insects with the present compound: Adalia bipunctata + SX, Amitus hesperidum + SX, Amitus spiniferus + SX, Anagrus atomus + SX, Anagrus epos + SX, Anagyrus fusciventris + SX, Anagyrus fusciventris + SX, Anagyrus pseudococci + SX, Anaphes flavipes + SX, Anaphes iole + SX, Anaphes nitens + SX, Anastatus tenuipes + SX, Anthocoris nemoralis + SX, Aphelinus abdominalis + SX, Aphelinus asychis + SX, Aphelinus mali + SX, Aphelinus semiflavus + SX, Aphidius colemani + SX, Aphidius ervi + SX, Aphidius gifuensis + SX, Aphidius matricariae + SX, Aphidius smithi + SX, Aphidius aphidimyza + SX, Aphytis holoxanthus + SX, Aphytis lepidosaphes + SX, Aphytis lignanensis + SX, Aphytis melinus + SX, Aphytis mytilaspidis + SX, Apion fuscirostre + SX, Apion ulicis + SX, Aprostocetus hagenowii + SX, Avetianella longoi + SX, Bangasternus orientalis + SX, Bathyplectes anurus + SX, Bathyplectes curculionis + SX, Bracon cushmani + SX,Bracon gelechiae + SX, Bracon hebetor + SX, Cales noacki + SX, Calosoma sycophanta + SX, Carcinops pumillio + SX, Catolaccus grandis + SX, Cephalonomia tarsalis + SX, Chilocorus baileyi + SX, Chilocorus bipustulatus + SX, Chilocorus circumdatus + SX, Chilocorus kuwanae + SX, Chilocorus nigritus + SX, Chilocorus stigma + SX, Chrysoperla carnea + SX, Chrysoperla rufilabris + SX, Clitostethus arcuatus + SX, Coccidoxenoides perminutus + SX, Coccophagus cowperi + SX, Coccophagus lycimnia + SX, Coenosia attenuata + SX, Coleomegilla maculata + SX, Comperia merceti + SX, Comperiella bifascita + SX, Copidosoma floridanum + SX, Copidosoma truncatellum + SX, Cotesia flavipes + SX, Cotesia glomerata + SX, Cotesia marginiventris + SX, Cotesia medicaginis + SX, Cotesia melanoscela + SX, Cotesia plutellae + SX, Cotesia ruficrus + SX, Cryptolaemus montrouzieri + SX, Cybocephalus nipponicus + SX,Dacnusa sibirica + SX, Dalotia coriaria + SX, Delphastus catalinae + SX, Delphastus pusillus + SX, Dendrolimus punctatus + SX, Deraeocoris brevis + SX, Diaeretiella rapae + SX, Dicyphus hesperus + SX, Diglyphus isaea + SX, Encarsia aurantii + SX, Encarsia formosa + SX, Encarsia inaron + SX, Encarsia opulenta + SX, Encarsia perplexa + SX, Ephedrus cerasicola + SX, Episyrphus balteatus + SX, Eretmocerus eremicus + SX SX, Eretmocerus mundus + SX, Feltiella acarisuga + SX, Franklinothrips megalops + SX, Franklinothrips orizabensis + SX, Franklinothrips vespiformis + SX, Geocoris punctipes + SX, Glyptapanteles liparidis + SX, Goniozus legneri + SX, Harmonia axyridis + SX, Hippodamia convergens + SX, Hyposoter exiguae + SX, Hyposoter fugitivus + SX, Lariophagus distinguendus + SX, Leptomastidea abnormis + SX, Leptomastix algirica + SX, Leptomastix dactylopii + SX,Leptomastix epona + SX, Lydella thompsoni + SX, Lysiphlebus testaceipes + SX, Macrocentrus ancylivorus + SX, Macrocentrus iridescens + SX, Macrolophus pygmaeus + SX, Mallada signata + SX, Metaphycus bartletti + SX, Metaphycus californicus + SX, Metaphycus flavus + SX, Metaphycus funicularis + SX, Metaphycus helvolus + SX, Metaphycus luteolus + SX, Metaphycus stanleyi + SX, Meteorus autographae + SX, Meteorus laphygmae + SX, Meteorus pulchricornis + SX, Meteorus trachynotus + SX, Metoecus paradoxus + SX, Microctonus aethiopoides + SX, Red-bellied toad (Micromus angulatus) + SX, Micromus tasmaniae + SX, Micromus variegatus + SX, Microplitis brassicae + SX, Microplitis plutellae + SX, Microterys flavus + SX, Muscidifurax raptor + SX, Muscidifurax raptorellus + SX, Nabis kinbergii + SX, Necremnus artynes ​​+ SX, Neochrysocharis formosa + SX, Neodryinus typhlocybae + SX, Nesidiocoris tenuis + SX, Orius albidipennis + SX, Orius armatus + SX, Orius insidiosus + SX, Orius laevigatus + SX,Orius majusculus + SX, Orius niger + SX, Orius strigicollis + SX, Orygia pseudotsugata + SX, Pediobius foveolatus + SX, Pentalitomastix plethorica + SX, Pnigalio flavipes + SX, Podisus maculiventris + SX, Praon volucre + SX, Pseudaphycus maculipennis + SX, Psyllaephagus pilosus + SX, Rhapalosiphum padi + SX, Rhizophagus grandis + SX, Rhyzobius forestieri + SX, Rhyzobius lophantae + SX, Bedariia tentacles (Rodolia cardinalis) + SX, Scolothrips sexmaculatus + SX, Serangium parcesetosum + SX, Spalangia cameroni + SX, Spalangia endius + SX, Stethorus punctillum + SX, Sympiesis stigmata + SX, Telenomus podisi + SX, Tenodera sinensis + SX, Tetrastichus brevistigma + SX, Tetrastichus gallerucae + SX, Tetrastichus howardi + SX, Tetrastichus setifer + SX, Thripobius semiluteus + SX, Torymus sinensis + SX, Trichogramma achaeae + SX, Trichogramma brassicae + SX, Trichogramma evanescens + SX, Trichogramma minutum + SX, Trichogramma ostriniae + SX, Trichogramma platneri + SX,Trichogramma pretiosum + SX, Trichogramma semifumatum + SX, Trichogrammatoidea bactrae + SX, Trichopoda pennipes + SX, Trioxys complanatus + SX, Trioxys curvicaudus + SX, Trioxys pallidus + SX, Trioxys tenuicaudus + SX, Trissolcus bathos + SX, Vairimorpha necatrix + SX, Volucella inanis + SX, Voria ruralis + SX, Squid (Xylocoris flavipes) + SX, Zelus renardii + SX.

[0217] Material (j-8): Details and designs of the fish: Amblydromalus limonicus + SX, Amblyseius andersoni + SX, Amblyseius barkeri + SX, Amblyseius californicus + SX, Amblyseius cucumeris + SX, Amblyseius degenerans + SX, Amblyseius montdorensis + SX, Amblyseius swirskii + SX, Amblyseius womersleyi + SX, Anystis agilis + SX, Cheyletus eruditus + SX, Euseius gallicus + SX, Euseius stipulatus + SX, Euseius tularensis + SX, Gaeolaelaps gillespiei + SX, Galendromus annectens + SX, Galendromus helveolus + SX, Galendromus occidentalis + SX, Hypoaspis aculeifer + SX, Hypoaspis miles + SX, Macrocheles robustulus + SX, Mesoseiulus longipes + SX, Neoseiulus fallacis + SX, Phytoseiulus macropilis + SX, Phytoseiulus persimilis + SX, Thyreophagus entomophagus + SX, Typhlodromus pyri + SX。

[0218] Subgroup (j-9): Combination of the present component of the mollusk and the present compound: Rumina decollata + SX。

[0219] Components selected from group (j) are typically prepared by methods known in the art. For example, in the case of (j-1) bacteria or (j-2) fungi or yeast, they are prepared using media and fermentation methods known in the art. When the component is (j-1) bacteria or (j-2) fungi or yeast, the preparation contains 1×10 to 1×10 CFU (colony forming units), preferably 1×10 to 1×10 CFU, of the component per gram. When the component is (j-4) a virus, the preparation contains 1×10 to 1×10 occlurion bodies (sometimes referred to as Obs), preferably 1×10 to 1×10 occlurion bodies (sometimes referred to as Obs) of the component per gram. When the component is (j-5) a nematode, the preparation contains 1×10 4 to 1×10 13 individuals, preferably 1×10 8 to 1×10 12 individuals of the component per 1 g.

[0220] This compound can be mixed with or used in combination with chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.).

[0221] The weight ratio of the application amount of the present compound to the application amount of the present component in Composition A is not particularly limited, and can be appropriately adjusted to an optimal weight ratio depending on the type of plant to be protected, the type and frequency of occurrence of harmful arthropods, harmful nematodes, harmful mollusks, plant pathogenic microorganisms or weeds to be controlled, the formulation form, application time, application method, application location, weather conditions, etc. For example, in the agricultural field, when applied to plants (particularly, stems and leaves, seeds, and vegetative reproductive organs) or to a cultivation carrier for cultivating plants (particularly, soil), the following weight ratios can be mentioned. The weight of the present component selected from group (j) refers to the weight of the preparation. For example, a weight ratio of 1:500 means that the application amount of the preparation of one or more components selected from group (j) is 500 parts by weight per 1 part by weight of the present compound.

[0222] Weight ratio [(this compound):(this component)] = 1:10^15 to 10^15:1, specifically, for example, approximately 1:10^15, 1:10^14, 1:10^13, 1:10^12, 1:10^11, 1:10^10, 1:10^9, 1:10^8, 1:10^7, 1:10^6, 1:10^5, 1:10000, 1:9000, 1:8000, 1:7000, 1:6000, 1:5000, 1:4000, 1:3000, 1:2000, 1:1000, 1:900, 1:800, 1:700, 1:600, 1:500 , 1:400, 1:350, 1:300, 1:250, 1:200, 1:150, 1:100, 1:90, 1:80, 1:70, 1:60, 1:50, 1:40, 1:30, 1:20, 1:19, 1:18, 1:17, 1:16, 1:15, 1:14, 1:13, 1:12, 1:11, 1:10, 1:9, 1:8, 1:7, 1:6, 1:5, 2:9, 1:4, 2:7, 3:10, 1:3, 3:8, 2:5, 3:7, 4:9, 1:2, 5:9, 4:7, 3:5, 5:8, 2:3, 7:10, 5:7, 3:4, 7:9, 4:5, 5:6, 6:7, 7:8, 8:9, 9:10, 1:1, 10:9, 9:8, 8:7, 7:6, 6:5, 5:4, 9:7, 4:3, 7:5, 10:7, 3:2, 8:5, 5:3, 7:4, 9:5, 2:1, 9:4, 7:3, 5:2, 8:3, 3:1, 10:3, 7:2, 4:1, 9:2, 5:1, 6:1, 7:1, 8:1, 9:1, 10:1, 11:1, 12:1, 13:1, 14:1, 15:1, 16:1, 17:1, 18:1, 19:1, 20:1, 30:1, 40:1, 50:1, 60:1, 70:1 , 80:1, 90:1, 100:1, 150:1, 200:1, 250:1, 300:1, 400:1, 500:1, 600:1, 700:1, 800:1, 900:1, 1000:1, 2000:1, 3000:1, 4000:1, 5000:1, 6000:1, 7000:1, 8000:1, 9000:1, 10000:1, 10^5:1, 10^6:1, 10^7:1, 10^8:1, 10^9:1, 10^10:1, 10^11:1, 10^12:1, 10^13:1, 10^14:1, 10^15:1. Here, the caret symbol "^" is an operator that indicates exponentiation, and for example, "10^5" means "105" (i.e., 10 to the fifth power).In the preceding paragraph, "approximately" includes a range of 10% by weight increase or decrease from the specified ratio. For example, approximately 1:2 includes a range of 1:1.8 to 1:2.2.

[0223] The present compound or composition A is usually used as a composition further containing an inert carrier (hereinafter referred to as composition B). Composition B is usually prepared by mixing the present compound or composition A with a solid carrier, a liquid carrier, a surfactant, etc., and adding formulation adjuvants such as binders, dispersants, stabilizers, and gases as necessary to prepare aqueous suspensions, oily suspensions, emulsifiable concentrates, emulsions, microemulsions, microcapsules, wettable powders, water dispersible granules, dusts, granules, tablets, aerosols, resin formulations, etc. The present compound or composition A is usually used as a composition further containing an inert carrier, such as a solid carrier, a liquid carrier, a surfactant, etc. Composition B is usually prepared by mixing the present compound or composition A with a solid carrier, a liquid carrier, a surfactant, etc., and adding formulation adjuvants such as binders, dispersants, stabilizers, and gases as needed to prepare aqueous suspensions, oily suspensions, emulsifiable concentrates, emulsions, microemulsions, microcapsules, wettable powders, water dispersible granules, dusts, granules, tablets, aerosols, resin formulations, etc. The present compound or composition B can be formulated into the dosage forms described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271 to 276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN: 0259-2517. Composition B may also be processed into, for example, sprays (aerosols, pump sprays, ultrasonic vibration preparations, electrostatic spray preparations, etc.), poison baits, combustibles (incense sticks, etc.), heat-transmitting agents (electric mosquito mats, liquid mosquito preparations, etc.), air-blowing transmitting agents (fan-type mosquito preparations, etc.), fumigants (self-combustion fumigants, chemical reaction fumigants, porous ceramic plate fumigants, etc.), fumigants, aerosols, ULV agents, mists, foams, paste-like preparations, paints, wood protective coatings, sealants, carbon dioxide preparations, sheet preparations, tape preparations, paper preparations, nonwoven fabric preparations, animal collars, animal ear tags, shampoos, spot-on preparations, pour-on preparations, suppositories, injections, oral treatments (capsules, tablets, chewable preparations, feed, etc.), sublimable tablets, mosquito nets, attractants, gardening poles, and screen doors, and then used. These preparations contain the present compound in an amount of usually 0.0001 to 99%, preferably 0.1 to 99%, and more preferably 0.2 to 90% by weight.

[0224] When the present compound or Composition A is formulated into an aqueous suspension, oil suspension, wettable powder, or water dispersible granule, the particle size of the present compound or Composition A is usually in the range of 0.1 to 20 μm, preferably 0.2 to 15 μm. When the present compound or Composition A is formulated into a granule, the particle size of the present compound or Composition A is usually in the range of 0.1 to 200 μm, preferably 0.5 to 100 μm. The particle size of the present compound or Composition A refers to the particle size (volume median diameter) that corresponds to 50% cumulative frequency in the volume-based frequency distribution, and can be determined by wet measurement using a laser diffraction particle size analyzer. An example of a laser diffraction particle size analyzer is the Mastersizer 3000 manufactured by Malvern Instruments. The cumulative frequency in the volume-based frequency distribution can be expressed based on any percentage other than the median (50%), and a preferred range can be expressed as "40% volume diameter of 2.5 μm to 60% volume diameter of 2.5 μm", etc. Furthermore, instead of the volume median diameter, it can also be expressed by the weight median diameter, which can then be expressed by any percentage.

[0225] Examples of solid supports include the following: Inorganic substances: minerals (natural silicates, marble, pumice, limestone, rare earth minerals, cryolite, activated clay, lime, activated carbon, talc, attapulgite, sodium montmorillonite, calcium montmorillonite, kaolinite, calcite, dolomite, diatomite, bentonite, zeolite, sepiolite, pyrophyllite, vermiculite, crystalline silica, amorphous silica, etc.), silicon dioxide, calcium sulfate, magnesium sulfate, barium sulfate, magnesium oxide, aluminum oxide, ammonium sulfate, ammonium phosphate, ammonium nitrate, calcium phosphate, sulfur, calcium carbonate, sodium bicarbonate, sodium carbonate, synthetic silicates, and their crushed products; Organic matter: Grain powders (rice bran, rice flour, corn flour, wheat flour, etc.), sugars (cellulose, starch, lactose, glucose, fructose, sucrose, etc.), plant-derived powders (ground nut shells (ground nut shells of coconut, walnut, peanut, etc.)), tree-derived powders (bark powder and sawdust, etc.), other plant powders (tobacco stalks, soybeans, cottonseed husks, etc.)), lignin, wax, shells, urea, polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resin, melamine resin, epoxy resin. The above solid carrier can also be used as an adsorption carrier.

[0226] Examples of liquid carriers include water, aliphatic hydrocarbons (hexane, 1-hexene, cyclohexane, octane, isooctane, 1-heptene, d-limonene, pinene, hexadecane, etc.), Aromatic hydrocarbons (alkylbenzenes (toluene, xylene, isopropylbenzene, p-diethylbenzene, etc.), alkylbenzene derivatives, alkylnaphthalenes, alkylnaphthalene derivatives, tetrahydronaphthalene, etc.), chlorinated hydrocarbons (monochloroethylene, dichloroethylene, trichloroethylene, tetrachloroethylene, dichloromethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,2-dichloropropane, etc.), ketones (cyclohexanone, acetone, 2-heptanone, isophorone, mesityl oxide, methyl isoamyl ketone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, diacetone alcohol, methylcyclohexanone, etc.), esters (fatty acid esters (ethyl acetate, butyl acetate, amyl acetate, isoamyl acetate, isobornyl acetate, hexyl acetate, heptyl acetate, octyl acetate, isopropyl myristate, methyl octanoate, methyl oleate, methyl laurate, Dibutyl adipate, tributyl citrate, dibutyl phthalate, etc.), lactate esters (ethyl lactate, propyl lactate, etc.), carbonate esters (ethylene carbonate, propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, etc.), esterified polyols (glycerol acetate, glycol acetate, glycerin monoacetate, glycerin diacetate, glycerin triacetate, diethylene glycol abietate, dipropylene glycol dibenzoate, dipropylene glycol monomethyl ester, etc.), lactones (γ-butyl lactone, etc.), ethers (1,4-dioxane, tetrahydrofuran, dipropylene glycol methyl ether, ethylene glycol methyl ether, propylene glycol methyl ether, etc.), amides (N-octyl-caprolactam, N-dodecyl-caprolactam, N,N-dimethylformamide, fatty acid dimethylamides (N,N-dimethylacetamide, N,N-dimethyldecanamide, N,N-dimethyloctanamide, etc.), alkylpyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone, N-dodecylpyrrolidone, etc.), lactams (α-lactam, β-lactam, γ-lactam, δ-lactam, etc.), amines (octylamine, octylamine acetate, oleylamine, diethanolamine, laurylamine, etc.), alcohols (methanol, ethanol, butanol, propanol, isopropanol, butanol, amyl alcohol, hexanol, heptanol, octanol, 2-ethylhexanol, etc.), hexylene glycol, cyclohexanol, phenol, benzyl alcohol, methoxypropanol (1-methoxy-2-propanol), tetrahydrofurfuryl alcohol, furfuryl alcohol, polyethylene glycol, ethylene glycol, diethylene glycol, hexylene glycol, ethylene glycol methyl ether, diethylene glycol Examples of suitable oils include glycol methyl ether, diethylene glycol butyl ether, triethylene glycol, propylene glycol methyl ether, dipropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, dipropylene glycol monomethyl ether, glycerin, etc.), mineral oils (naphtha, petroleum ether, kerosene, diesel oil, paraffin, olefin, etc.), oils derived from animals and plants, oils derived from plants (palm oil, rapeseed oil, castor oil, coconut oil, soybean oil and derivatives thereof, etc.), oils derived from animals (sardine oil, saury oil, whale oil and derivatives thereof, etc.), dimethyl sulfoxide, silicone oil, acetonitrile, propanenitrile, acid anhydrides (such as acetic anhydride), triethyl phosphate, oleic acid, propionic acid, lactic acid, and xylene sulfonic acid.

[0227] Examples of gaseous carriers include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide gas.

[0228] Examples of anionic surfactants include carboxylic acids, sulfonic acids, sulfates, and phosphates, and specific examples thereof include the following: Carboxylic acids: fatty acid salts (octanoate, decanoate, laurate, myristate, palmitate, stearate, behenate, oleate, polyoxyethylene alkyl ether carboxylates (laureth-3-carboxylate, α-(carboxymethyl)-ω-(dodecyloxy)poly(oxyethylene) salt, etc.), N-acyl sarcosinate (N-lauroyl sarcosinate, etc.), N-acyl glutamate (N-lauroyl glutamate, etc.), polycarboxylates (polyacrylates, polyvinyl acetates, comb polymers of polyacid salts, and their derivatives, etc.), sulfonic acids: alkyl sulfonic acids and their salts (dodecyl sulfonate, etc.), alpha olefins alkene sulfonates (alkene (C14-18) hydroxysulfonates, alkapolyene (C12-20) hydroxysulfonates, alkene (C14-18) hydroxysulfonates, alkene (C12-20) hydroxysulfonates, tetradecene-1-sulfonates, α-olefin (C14-16) sulfonates, etc.), alkyl benzene sulfonates (decyl benzene sulfonates, dodecyl benzene sulfonates, tridecyl benzene sulfonates, diphenyl sulfonates, etc.), alkyl naphthalene sulfonates (naphthalene sulfonates, 6-methyl-2-naphthalene sulfonates, dibutyl naphthalene sulfonates, 2,2'-dinaphthylmethane-6,6'-disulfonate, diisopropyl naphthalene sulfonate, triisopropyl naphthalene sulfonate, 1-isopropyl 2-naphthalene sulfonate, etc.), sulfosuccinic acid, monoalkyl sulfosuccinate, dialkyl sulfosuccinate, (di(2-ethylhexyl) sulfosuccinate, etc.), N-methyl-N-acyltaurate (oleoyl methyl taurate, etc.), lignin sulfonate, alkylphenol sulfonate, naphthalene sulfonate-formaldehyde condensate, benzimidazole sulfonate and its derivatives, sulfate esters such as alkyl sulfates (hexyl sulfate, heptyl sulfate, octyl sulfate, lauryl sulfate, diethanolamine lauryl sulfate, etc.), salts, hexadecyl sulfate, octadecyl sulfate, etc.), polyoxyethylene alkyl ether sulfates and their salts (laureth-3 sulfate, polyoxyethylene monotridecyl ether sulfate, α-sulfo-ω-hydroxyalkyl (C6-10) ether poly(oxyethylene) salts, etc.), polyoxyethylene alkyl phenyl ether sulfates (poly(oxyethylene) 2-decylphenyl ether sulfate, poly(oxyethylene) 3-decylphenyl ether sulfate, α-sulfo-ω-[2,4-bis(1,1,3,3-tetramethylbutyl)phenoxy]poly(oxyethylene) salts, etc.), polyoxypropylene alkyl ether sulfates, lignosulfite waste liquor, and derivatives thereof; Phosphate esters: alkyl phosphates (propyl phosphate, hexadecyl phosphate, lauryl phosphate, dioctyl phosphate, etc.), polyoxyethylene alkyl ether phosphates (polyoxyethylene decyl phosphate, α-phosphono-ω-butoxypoly(oxyethylene), etc.), polyoxyethylene alkyl phenyl ether phosphates (α-(dinonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(dodecylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(nonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, etc.), polyoxypropylene alkyl ether phosphates, and derivatives thereof.

[0229] Examples of cationic surfactants include amine salts and quaternary ammonium salts, and specific examples include the following: Amine salts: alkylamine salts (monomethylamine salts, dimethylamine salts, trimethylamine salts, etc.), fatty acid amidoamine salts (stearamidopropyldimethylamine, behenamidopropyldimethylamine, etc.), polyamine salts (polyvinylamine, polyethyleneimine, etc.), and derivatives thereof; Quaternary ammonium salts: lauryltrimethylammonium salt, cetyltrimethylammonium salt, dodecyltrimethylammonium salt, stearyltrimethylammonium salt, benzalkonium chloride, benzethonium chloride, benzylbis(2-chloroethyl)ethylammonium bromide salt.

[0230] Examples of zwitterionic surfactants include betaine, alkyl betaine, alkyl dimethyl betaine, imidazoline, taurine, alkyl taurine, dodecyl dimethyl ammonio acetate, 4-carboxy-N,N,N-trimethyl-1-butanaminium, 1-carboxy-N,N,N-2-tetramethyl-1-propanaminium, N-alkyl (or alkenyl) (C12-18) glycine and salts thereof, N-dodecyl glycine and salts thereof, and derivatives thereof.

[0231] Examples of nonionic surfactants include alcohols, amides, amines, esters, ethers, ether esters, and carboxylic acids, and specific examples thereof include the following: Alcohols: aromatic alcohols (alkylphenols (allylphenol, octylphenol, nonylphenol, octylcresol, etc.), acylphenols, etc.), aliphatic alcohols (isotridecyl alcohol, oleyl alcohol, cetyl alcohol, etc.), polyhydric alcohols (polysaccharides, starch, starch derivatives, sucrose, alkyl polyglucosides, sorbitan, ethoxylated sorbitan, cellulose derivatives, gum arabic, etc.), synthetic polymers (polyvinyl alcohol, polyethylene glycol, etc.); Amides: alkanolamides (fatty acid alkanolamides (lauric acid diethanolamide, etc.), fatty acid glucamides (alkoxylated propylene oxide fatty acid glucamides, etc.), alkoxylated amides (polyoxyethylene oleic acid amide, polyoxyethylene stearic acid amide, etc.), synthetic polymers (polyvinylpyrrolidone, etc.), Amines: alkoxylated amines (polyoxyethylene oleylamine, α,α'-[(9-octadecenylimino)di2,1-ethanedyl]bis(ω-hydroxy)polyoxyethylene, etc.); Esters: fatty acid esters (fatty acid esters of polyols, monoglycerides, phospholipids, etc.), sugar-derived esters (sucrose fatty acid esters (sucrose stearate diester, etc.), sorbitan fatty acid esters (sorbitan oleate monoester, etc.), glucose esters, cellulose esters, etc.), synthetic polymers (vinyl acetate copolymers, polymethacrylic acid, copolymers of methacrylic acid and methacrylic acid esters, etc.); Ethers: alcohol ethoxylates (fatty alcohol ethoxylates (tridecyl alcohol ethoxylate, isooctyl alcohol ethoxylate, lauryl alcohol ethoxylate, hexadecyl alcohol ethoxylate, stearyl alcohol ethoxylate, etc.)), alkylphenol ethoxylates (nonylphenol ethoxylate, tristyrylphenol ethoxylate, tributylphenol ethoxylate, octylphenol ethoxylate, etc.), arylalkylphenol ethoxylates, arylphenol ethoxylates (monobenzyl biphenol alcohol ethoxylate, etc.), alcohol propoxylates (fatty alcohol propoxylates, alkylphenol propoxylates, arylalkylphenol propoxylates, etc.), block polymers (block polymers of polyethylene oxide and polypropylene oxide, polyethylene oxide block polymers, polypropylene oxide block polymers, block polymers of alkanol, polyethylene oxide and polypropylene oxide, etc.); Ether esters: polyoxyethylene fatty acid esters (polyoxyethylene castor oil esters, polyoxyethylene stearic acid esters, polyoxyethylene beef tallow fatty acid esters, etc.), polyoxyethylene sorbitan fatty acid esters (polyoxyethylene sorbitan monooleate esters, polyoxyethylene sorbitan trioleate esters, polyoxyethylene sorbitan monolaurate esters, polyoxyethylene sorbitan stearate esters, etc.), polyoxyethylene fatty acid amine esters, polyoxyethylene rosin esters, polyoxypropylene fatty acid esters (polyoxypropylene castor oil esters, etc.), polyoxypropylene fatty acid amine esters; Carboxylic acids: undecafluorohexanoic acid.

[0232] Other formulation adjuvants include, for example, thickeners, antifreeze agents / humectants, antifoaming agents, antioxidants, pH adjusters, colorants, preservatives / disinfectants, binders, adhesives / spreaders, lubricants / lubricants, anti-caking agents, light stabilizers, fragrances, propellants, fertilizers, film-forming agents, deodorizers, plasticizers, desiccants / moisture-proofing agents, fumigation aids, attractants, inclusion agents, and efficacy enhancers.Specific examples include the following. Thickeners: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose and its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, carrageenan, etc.), clays (organic clays, organically modified clays, inorganic clays, inorganically modified clays, etc.), minerals (bentonite, attapulgite, silica, silicates, etc.), synthetic polymers (polycarboxylates, polyacrylic acid derivatives, polyvinylpyrrolidone, polyvinyl alcohol, etc.); Antifreeze agents and humectants: alcohols (ethylene glycol, propylene glycol, dipropylene glycol, triethylene glycol, ethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol butyl ether, glycerin, polyethylene glycol, etc.), esters (dipropylene glycol dibenzoate, glycerol acetate, glycerol diacetate, glycerol triacetate, gamma-butyrolactone, etc.), ethers (1,4-dioxane, etc.), urea; Antifoaming agents: silicones (polysiloxane, diblock ethoxyl siloxane, triblock ethoxyl siloxane, etc.), alkyl sulfosuccinates, higher alcohols, higher alcohol derivatives, salts of fatty acids, fatty acid derivatives; Antioxidants: phenols (2,6-di-t-butyl-p-cresol, 2,2'-methylenebis(4-methyl-6-t-butylphenol), etc.), amines (p,p'-dioctyldiphenylamine, N,N'-diphenyl-p-phenylenediamine, etc.), dibutylhydroxytoluene, butylhydroxyanisole, sodium erythorbate, sodium sulfite, potassium sulfite, potassium pyrosulfite, catechin, propyl gallate, sulfur compounds (didodecyl thiodipropionate, etc.), phosphoric acids (trisnonylphenyl phosphite, etc.), vitamins (alpha tocopherol, L-ascorbic acid, sodium ascorbate, ascorbyl palmitate, etc.); pH adjusters: sulfuric acid, nitric acid, hydrochloric acid, acetic acid, carbonic acid, oxalic acid, lactic acid, succinic acid, gluconic acid, citric acid, phosphoric acid, sorbic acid, and their salts, sodium bicarbonate, sodium hydroxide, potassium hydroxide, calcium hydroxide, aluminum hydroxide, copper hydroxide, magnesium hydroxide; Colorants: Monoazo (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, Cl Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazos (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinones (Pigment Red 83, etc.), dioxazines (Pigment Blue 80, etc.), xanthenes (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethanes (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium dioxide, titanium oxide, zinc oxide, zinc sulfide, iron hexacyanoate, chrome vermilion, yellow lead, calcium carbonate, baryte powder, aluminum powder; Preservatives and disinfectants: phenols (orthophenylphenol, thymol, 3,5-dimethyl-4-chlorophenol, etc.), isothiazolinone derivatives (methylisothiazolinone (2-methyl-4-isothiazolin-3-one), chloromethylisothiazolinone (5-chloro-2-methyl-4-isothiazolin-3-one), octylisothiazolinone (2-n-octyl-4-isothiazolin-3-one), dichlorooctylisothiazolinone (4,5-dichloro-2-octyl-4-isothiazolin-3-one), benzisothiazolinone (1,2-benzisothiazolin-3-one), etc.), bronopolysaccharides alcohol derivatives (bronopol (2-bromo-2-nitropropane-1,3-diol), etc.), benzyl alcohol hemiformal, isopropyl methylphenol, parabens (methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, heptylparaben, benzylparaben), imidazoles (thiabendazole), benzalkonium chloride, glyceryl caprylate, glyceryl caprate, glycerin fatty acid esters, sodium dehydroacetate, hinokitiol, acids (citric acid, phosphoric acid, sorbic acid, salicylic acid, benzoic acid, and their salts, etc.); Binders: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clays, organically modified clays, inorganic clays, inorganically modified clays), minerals (bentonite), synthetic polymers (polycarboxylic acids or their salts, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salts), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefin, etc.); Fixing agents and spreading agents: surfactants and liquid carriers as described above (esters (alkyl fatty acid esters, sorbitan fatty acid esters, ethoxylated fatty acid esters, ethoxysorbitan fatty acids, etc.), alcohols (ethoxylated fatty alcohols, ethoxysorbitan fatty alcohols, etc.), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefin, etc.), vegetable oils (alkylated vegetable oils, etc.), mineral oils (mineral oil, etc.), silicone emulsions, synthetic polymers (styrene-butadiene copolymers, methyl methacrylate-butadiene copolymers, polyacrylic acid or its salts, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), natural polymers (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, etc.); Lubricants and lubricants: Alcohols, fatty acid esters, sucrose fatty acid esters, glycerin fatty acid esters, hydrocarbons, paraffin, ethylene wax, aliphatic amides, erucic acid amide, stearic acid amide, oleic acid amide, methylene bisstearic acid amide, ethylene bisstearic acid amide, metal soaps, lead stearate, zinc stearate, calcium stearate, magnesium stearate, mineral oil, vegetable oil, kerosene, diesel oil, as listed in the liquid carriers and surfactants above; Anti-caking agents: solid and liquid carriers as described above, calcium phosphate, sodium phosphate, sodium carbonate, sodium silicate, calcium silicate, magnesium silicate, potassium aluminum silicate, silicon dioxide, talc, sodium aluminosilicate, calcium aluminosilicate, bentonite, stearic acid, dimethylpolysiloxane, powdered cellulose; Light stabilizers: titanium dioxide, zinc oxide, activated carbon, carbon black, ethylhexyl methoxycinnamate, tert-butyl methoxydibenzoylmethane, hindered amines, ferulic acid, phenyl hydroxybenzoate, ethyl para-aminobenzoate, octyl salicylate, t-butylphenyl salicylate, 4-tert-octylphenyl salicylate, 2-cyano-3,3-diphenylprop-2-enoic acid-2-ethylhexyl ester (octocrylene), drometrizole trisiloxane, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine (octyltriazone, TEAT), 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol] (MBP), 2-ethylhexyl paradimethylaminobenzoate (EDB), homomenthyl salicylate (HS), phenylbenzimidazole sulfonic acid (PBS), hydroxymethoxybenzophenone sulfonic acid (oxybenzone 4, OXB4), sodium hydroxymethoxybenzophenone sulfonate (oxybenzone 5, OXB5), sodium dihydroxydimethoxybenzophenone disulfonate (oxybenzone 9, OXB9), tetrahydroxybenzophenone, dihydroxybenzophenone, dihydroxydimethoxybenzophenone, 2-hydroxy-4-methoxybenzophenone, dimethoxybenzylidene dioxoimidazolidine-2-ethylhexyl propionate, 2,4-dihydroxybenzophenone, bis(2-methoxy-4-hydroxy-5-benzoylphenyl)methane; Fragrance: Hydrocarbons, α-limonene, β-caryophyllene, alcohols, cis-3-hexenol, linalool, farnesol, β-phenylethyl alcohol, aldehydes, 2,6-nonadenal, citral, α-hexyl cinnamic aldehyde, ketones, β-ionone, L-carvone, cyclopentadecanone, esters, linalyl acetate, benzyl benzoate, lactones, γ-undecalactone, phenols, eugenol, oxides, rose oxide, acetals, phenylacetaldehyde dimethyl acetal, α-pinene, β-pinene; Propellant: liquefied petroleum gas, aliphatic hydrocarbons having 3 to 5 carbon atoms such as propane, normal butane, isobutane, normal pentane, isopentane, etc., hydrofluoroolefins such as trans-1,3,3,3-tetrafluoroprop-1-ene, trans-2,3,3,3-tetrafluoroprop-1-ene, etc., dimethyl ether, nitrogen gas, carbon dioxide gas, nitrous oxide gas, compressed air, and mixtures thereof; Fertilizer: Nitrogenous fertilizer components (urea, ammonium nitrate, magnesium ammonium nitrate, ammonium chloride, ammonium sulfate, ammonium phosphate, sodium nitrate, calcium nitrate, potassium nitrate, lime nitrogen, formaldehyde-modified urea (UF), acetaldehyde-modified urea (CDU), isobutyraldehyde-modified urea (IBDU), guanylated urea (GU)), phosphate fertilizer components (superphosphate, triple superphosphate, fused phosphorus, humic acid phosphorus, calcined phosphorus, double calcined phosphorus, magnesium superphosphate, ammonium polyphosphate, potassium metaphosphate, calcium metaphosphate, magnesium phosphate, sulfur Ammonium phosphate, potassium ammonium phosphate nitrate, ammonium chloride, etc.), potassium fertilizer ingredients (potassium chloride, potassium sulfate, potassium soda sulfate, magnesium sulfate, potassium bicarbonate, potassium phosphate, etc.), silicate fertilizer ingredients (calcium silicate, etc.), magnesium fertilizer ingredients (magnesium sulfate, magnesium chloride, etc.), calcium fertilizer ingredients (quicklime, slaked lime, calcium carbonate, etc.), manganese fertilizer ingredients (manganese sulfate, manganese sulfate, manganese slag, etc.), boron fertilizer ingredients (boric acid, borates, etc.), iron-containing fertilizer ingredients (steel slag, etc.), other fertilizer ingredients (copper, cobalt, zinc, etc.); Film-forming agents: natural rubber, synthetic rubber, resins (styrene butadiene copolymer, polyacrylonitrile, polyester, polyamide, polyurethane, polyurea, polyether, rosin, melamine, etc.), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefin, etc.), polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethyl cellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tylose, starch xanthate, carrageenan, etc.), proteins (gelatin, etc.); Deodorants: organic clay, organic modified clay, unmodified clay, zinc silicate, silica gel; Plasticizers: triethyl phosphate, citrate esters, phthalates, adipates, sebacates, phosphate esters; Desiccants and moisture-proofing agents: silica gel, calcium chloride, quicklime, aluminum oxide, zeolite, allophane; Fumigant additives: nitrocellulose, potassium chlorate, calcium oxide, melamine, potassium nitrate, azodicarbonamide; Attractants: starch, cellulose, dextrin, vinegar, alcohol, yeast extract; Inclusion agents: cyclodextrins, α-cyclodextrin, β-cyclodextrin, γ-cyclodextrin; Efficacy enhancers: Liquid carriers and surfactants as described above.

[0233] When the present compound or Composition A is formulated into an aqueous suspension or an oil suspension, an antifreeze agent and / or a preservative is usually added.Preferably, the antifreeze agent includes ethylene glycol, propylene glycol, and glycerin.Preferably, the preservative includes an isothiazolinone derivative (e.g., 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one) and Proxel (1,2-benzisothiazolin-3-one). Ethylene glycol (EG), propylene glycol (PG), glycerin (GL), 2-methyl-4-isothiazolin-3-one (MIT), 5-chloro-2-methyl-4-isothiazolin-3-one (CMIT), 2-n-octyl-4-isothiazolin-3-one (OIT), 4,5-dichloro-2-octyl-4-isothiazolin-3-one (DCOIT), 1,2-benzisothiazolin-3-one (BIT), and 2-bromo-2-nitropropane-1,3-diol (BNPD), which are used as antifreezes and preservatives, are commercially available.

[0234] Examples of combinations of the present compound or composition A with the above antifreeze agents or preservatives are given below. SX + EG, SX + PG, SX + GL, SX + MIT, SX + CMIT, SX + OIT, SX + DCOIT, SX + BIT, SX + BNPD, Composition A + EG, Composition A + PG, Composition A + GL, Composition A + MIT, Composition A + CMIT, Composition A + OIT, Composition A + DCOIT, Composition A + BIT, composition A+ BNPD.

[0235] The weight ratio of the present compound or composition A to the antifreeze agent or preservative is in the range of 1:0.0001 to 1:100, for example, 1:0.0001 to 1:1, 1:0.005 to 1:0.01, 1:0.15 to 1:0.35, or 1:0.125 to 1:0.25. Specific weight ratios are 1:0.0001, 1:0.0002, 1:0.0003, 1:0.0004, 1:0.0005, 1:0.0006, 1:0.0007, 1:0.0008, 1:0.0009, 1:0.001, 1:0.002, 1:0.003, 1:0.004, 1:0.005, 1:0.006, 1:0.007, 1:0.008, 1:0.009, 1:0.01, 1:0.02, 1:0.03, 1:0.04, 1:0.05, 1:0.06 Examples of suitable ratios include 1:0.06, 1:0.07, 1:0.08, 1:0.09, 1:0.1, 1:0.125, 1:0.15, 1:0.2, 1:0.25, 1:0.3, 1:0.4, 1:0.5, 1:0.6, 1:0.7, 1:0.8, 1:0.9, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:30, 1:40, 1:50, 1:60, 1:70, 1:80, 1:90, and 1:100. These weight ratios can also be expressed as "approximate." Approximately means plus or minus 10%. For example, "approximately 1:2" means 1:1.8 to 1:2.2.

[0236] Examples of combinations of the present compound or composition A with the above antifreeze agents and preservatives are given below. SX + EG + MIT, SX + EG + CMIT, SX + EG + OIT, SX + EG + DCOIT, SX + EG + BIT, SX + EG + BNPD, SX + PG + MIT, SX + PG + CMIT, SX + PG + OIT, SX + PG + DCOIT, SX + PG + BIT, SX + PG + BNPD, SX + GL + MIT, SX + GL + CMIT, SX + GL + OIT, SX + GL + DCOIT, SX + GL + BIT, SX + GL + BNPD, Composition A + EG + MIT, Composition A + EG + CMIT, Composition A + EG + OIT, Composition A + EG + DCOIT, Composition A + EG + BIT, Composition A + EG + BNPD, composition A + PG + MIT, composition A + PG + CMIT, Composition A + PG + OIT, Composition A + PG + DCOIT, Composition A + PG + BIT, Composition A + PG + BNPD, Composition A + GL + MIT, Composition A + GL + CMIT, Composition A + GL + OIT, Composition A + GL + DCOIT, Composition A + GL + BIT, Composition A + GL + BNPD. When combining this compound or composition A with the above-mentioned antifreeze and preservative, the mixing ratio of this compound or composition A to the antifreeze, and this compound or composition A to the preservative can be used within the same range as the ratio described above.

[0237] In the case of granules or microgranules, a coloring agent may be added to make it easier to identify the granules or microgranules during or after application. Also, when applying Composition B to plant seeds or vegetative reproductive organs, a coloring agent may be added to make it easier to identify that the composition has been applied.

[0238] Examples of substrates for resin formulations include polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resin, melamine resin, and epoxy resin. These substrates may contain, as needed, plasticizers such as phthalates (dimethyl phthalate, dioctyl phthalate, etc.), adipic acid esters, and stearic acid. The resin formulations can be molded into various forms, such as plates, films, tapes, threads, nets, cloths, strings, and blocks, as needed. Specifically, they can be used in the form of animal collars, animal ear tags, clothing, protective hats, arm / leg covers, attractants, gardening poles, screen doors, and mosquito nets. The resins can also be obtained by molding and processing the resins and then post-treating them with Composition B. Examples of base materials for poison bait include grain flour, vegetable oil, sugar, and crystalline cellulose, and, if necessary, may also contain antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, preservatives such as dehydroacetic acid, agents to prevent accidental ingestion by children and pets such as chili pepper powder, and pest-attracting flavors such as cheese flavoring, onion flavoring, and peanut oil.

[0239] Harmful arthropods can be controlled by applying an effective amount of the present compound, Composition A, or Composition B directly to them or to their habitats. The term "habitat" as used herein refers not only to places where harmful arthropods live, but also to places where they are expected to live. Specific examples include plants, plant cultivation areas, plant cultivation carriers, indoor and outdoor buildings, building materials, food, daily necessities, wood, vehicles, and animal bodies.

[0240] In the present invention, plants include whole plants and specific parts of plants, such as stems, leaves, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative reproductive organs, and seedlings.

[0241] Vegetative reproductive organs refer to plant roots, stems, leaves, and other parts that can grow when separated from the main body and placed in soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and propagules are also called bulbils and are divided into broad buds and bulbils. Vines refer to shoots (a collective term for leaves and stems) of plants such as sweet potatoes and Japanese yams. Bulbs are a collective term for bulbs, corms, tubers, rhizomes, stem fragments, rhizophores, or tuberous roots. Potato cultivation begins by planting the tubers in soil, and the tubers used are generally called seed potatoes.

[0242] Seedlings include seedlings and saplings.

[0243] Examples of areas where plants are grown include agricultural land such as fields, rice paddies, and orchards, and non-agricultural land such as lawns and forests.

[0244] A plant cultivation carrier is a support for plants and may be made of any material that allows plants to grow, such as soil, a seedling raising mat, or water. Specific examples of materials for soil and seedling raising mats include sand, pumice, vermiculite, diatomaceous earth, gel-like substances, polymeric substances, rock wool, glass wool, wood chips, and bark.

[0245] Examples of buildings include houses, commercial facilities, train stations, airports, hospitals, factories, offices, schools, accommodation facilities, waste treatment facilities, livestock barns, and warehouses. Examples of interior spaces of buildings include closets, storage areas, dressers, cupboards, toilets, bathrooms, storage rooms, living rooms, bedrooms, and dining rooms.

[0246] Examples of outdoors include the ground, exterior walls, fences, ditches, spaces, water jars, water tanks, wells, puddles, rainwater catch basins, gutters, septic tanks, old tires, reservoirs, rivers, waterways, forests, and lakes.

[0247] Examples of building materials include wood, concrete, brick, plastic, glass, wallpaper, heat insulating materials, packing, piping, electric wires and cables, paint, and sealants.

[0248] Examples of foods include agricultural products (grains, fruits, spices, and processed products thereof), livestock and marine products (meat, fish, eggs, milk, and processed products thereof), and daily necessities include plant-derived products (cotton, paper, tobacco, and processed products thereof), animal-derived products (leather, hair, wool, feathers, silk, and processed products thereof), electrical appliances, and other products (furniture, stationery, toys, tableware).

[0249] Examples of wood include wood processed for construction (high-density wood, laminated wood, plywood and fiberboard, hardboard, MDF, insulation board, particle board, insulation hardboard, OSB, LSL, glued laminated lumber, cross-laminated lumber, flooring, composite flooring, etc.).

[0250] Examples of vehicles include bicycles, cars (private cars, buses, taxis, luggage carriers, etc.), trains, airplanes, and ships.

[0251] Examples of animals include livestock (cows, horses, pigs, sheep, goats, chickens, etc.) and small animals (dogs, cats, rats, mice, etc.).

[0252] When Composition B is used to control arthropod pests in the agricultural field, the application rate can vary over a wide range depending on the type of plant to which it is applied, the type and frequency of arthropod pests to be controlled, the formulation, application time, application method, application location, weather conditions, etc. Typically, the application rate of the present compound or one of the present components is 1 to 10,000 g per hectare, preferably 5 to 5,000 g, and more preferably 50 to 2,000 g (specifically, for example, 100 g, 200 g, 300 g, or 500 g). When Composition B is formulated as an emulsifiable concentrate, wettable powder, flowable powder, or the like, it is typically diluted with water to a concentration of the present compound or one of the present components of 0.01 to 10,000 ppm, preferably 0.1 to 5,000 ppm, and more preferably 1 to 1,000 ppm (specifically, for example, 10 ppm, 100 ppm, or 500 ppm) before application. When composition B is formulated as granules, dust or the like, it is usually applied as is.

[0253] These formulations or water dilutions of the formulations may be sprayed directly onto harmful arthropods or onto plants to be protected from harmful arthropods, or may be applied to cultivation carriers to control harmful arthropods that infest the cultivation carriers.

[0254] Alternatively, composition B, which is a resin preparation processed into a sheet or string shape, can be wrapped around the plant, stretched near the plant, or laid on a cultivation carrier.

[0255] When applying Composition B to a plant or a plant cultivation area, it may be applied once or multiple times. The plant or plant cultivation area may already be infested with arthropod pests, or may not yet be infested with arthropod pests.

[0256] Examples of the application method for Composition B include foliage application, soil application, root application, shower application, mist spray application, fumigation application, water surface application, hydroponic solution application, and seed application.

[0257] Examples of foliar treatment include a method in which Composition B is applied to the surface of foliage, tree trunks, fruits, flowers, or spikes. Examples of root treatment include a method of immersing the roots in a chemical solution containing Composition B, and a method of attaching a solid preparation containing Composition B to the roots of the plant. Examples of soil treatment include soil spraying, soil incorporation, and soil drenching. The location of soil treatment includes, for example, planting holes, rows, areas near planting holes, areas near rows, and areas in the cultivation area. Examples of suitable treatment locations include the entire area, the plant's soil edge, between plants, under the trunk, in the main ridge, in the soil, in seedling boxes, seedling trays, and seedling beds. Treatment times include, for example, before sowing, at the time of sowing, after sowing, during the seedling raising period, before planting, at the time of planting, and during the growth period after planting. In the above-mentioned soil treatment, Composition B may be simultaneously applied to the plants, or a paste fertilizer, liquid fertilizer, solid fertilizer, or the like containing Composition B may be applied to the soil. Composition B may also be mixed with an irrigation solution, for example, by injection into irrigation equipment (irrigation tubes, irrigation pipes, sprinklers, etc.), by mixing into inter-row flooding solution, or by mixing into a hydroponic solution. Alternatively, the active ingredient may be mixed with the irrigation solution in advance, and then treated using the above-mentioned irrigation method or other appropriate irrigation methods, such as sprinkling or flooding. An example of the shower treatment is a method in which a diluted solution of composition B is showered onto the fruit after harvest. Examples of mist spray treatments include a method in which a diluted solution of composition B is made into a mist and dispersed into the air, allowing the mist to adhere to the stems, leaves, or fruits of plants. Examples of smoking treatments include a method in which a solid preparation containing composition B is heated to form smoke, which is then suspended in the air and allowed to adhere to the stems, leaves, or fruits of plants. An example of a water surface treatment is a method in which a liquid drug containing Composition B or a solid formulation containing Composition B is sprayed onto a flooded paddy field. Examples of hydroponic solution treatment include methods in which a chemical solution containing composition B or a solid formulation containing composition B is mixed or incorporated into a hydroponic solution (hydroponic solution mixing treatment, hydroponic solution mixing treatment, etc.).

[0258] Seed treatment Seed treatment refers to the treatment of seeds or vegetative reproductive organs with Composition B. Seed treatment methods using Composition B include, for example, spraying, in which a suspension of Composition B is sprayed in mist form onto the surface of seeds or vegetative reproductive organs, smearing, in which Composition B is applied to seeds or vegetative reproductive organs, immersion, in which seeds are immersed in a solution of Composition B for a certain period of time, and methods of coating seeds or vegetative reproductive organs with a carrier containing Composition B (film coating, pellet coating, etc.). The vegetative reproductive organs mentioned above particularly include seed potatoes. When applying Composition A to seeds or vegetative reproductive organs, Composition A can be applied to the seeds or vegetative reproductive organs as a single formulation, or Composition A can be applied to the seeds or vegetative reproductive organs in multiple separate applications as multiple different formulations. Examples of the method of applying Composition A in multiple separate applications include a method of applying a formulation containing only the present compound as an active ingredient, air-drying the seeds or vegetative reproductive organs, and then applying a formulation containing this component; and a method of applying a formulation containing the present compound and this component as active ingredients, air-drying the seeds or vegetative reproductive organs, and then applying a formulation containing the present component other than the component that has already been applied. After seed treatment, the active ingredient may completely or partially cover the seeds or vegetative reproductive organs, may be scattered on their surface, and / or may be present inside them. For treatment, it is preferable to use a composition containing one or more present ingredients having fungicidal activity selected from group (b) and group (j) among composition B. In this case, the present compound may be applied to commercially available seeds or vegetative reproductive organs that have been treated with one or more present ingredients having fungicidal activity selected from group (b) and group (j). When applying Composition B to seeds or vegetative reproductive organs, manganese, copper, zinc, etc. may also be applied at the same time. When Composition B is used for seed treatment, the application amount of Composition B is usually 0.001 to 100 g, and preferably 0.02 to 50 g, per 1 kg of seeds or vegetative reproductive organs, and the application amount of each active ingredient contained in Composition B is usually 0.001 to 100 g, preferably 0.01 to 50 g, and more preferably 0.1 to 10 g, per 1 kg of seeds or vegetative reproductive organs. Specific examples of the application amounts are as follows: 0.05g of active ingredient per 1kg of seeds or vegetative reproductive organs; 0.5g of active ingredient per 1kg of seeds or vegetative reproductive organs; 5g of active ingredient per 1kg of seeds or vegetative reproductive organs. In the present invention, a seed or vegetative reproductive organ carrying the present compound or composition A refers to a seed or vegetative reproductive organ having the present compound or composition A attached to its surface. The seeds or vegetative reproductive organs carrying the present compound or composition A may have materials other than the present compound or composition A attached to them before or after the present compound or composition A is attached to the seeds or vegetative reproductive organs. When composition A is attached to the surface of a seed or vegetative reproductive organ in the form of a layer, the layer may consist of one or more layers. When the composition consists of multiple layers, each layer may contain one or more active ingredients, or may consist of a layer containing one or more active ingredients and a layer containing no active ingredients. Seeds or vegetative reproductive organs carrying the present compound or composition A can be obtained, for example, by applying composition B containing the present compound or composition A to seeds or vegetative reproductive organs by the seed treatment method described above.

[0259] Commonly known seed treatment formulations include DS, ES, FS, LS, WS, CF, GF, and SS. However, CS, EG, EW, GW, ME, OD, OF, SC, SE, SG, SL, SP, ST, WG, WP, WT, ZC, ZE, and ZW formulations can also be used. These formulations contain one of the present compounds or components at a weight ratio of 0.01 to 70%, preferably 0.1 to 50%. Furthermore, when treating seeds or vegetative reproductive organs, these formulations may be used as is or diluted with water. When treating seeds or vegetative reproductive organs with a diluted formulation, the formulation can be diluted as needed depending on the active ingredient content and the amount of active ingredient desired to be retained in the seeds or vegetative reproductive organs. However, the formulation is generally diluted 2 to 1000 times. When seeds are treated, the seeds may be treated before sowing or after germination. When the present compound or composition A is used for seed treatment, adjuvants such as colorants and binders may be mixed in when the compound or composition A is formulated, or may be further mixed in when the formulated composition B is used for seed treatment. The coloring agent makes it easy to confirm whether Composition B has been applied to each seed or vegetative reproductive organ. A binder can also be added to improve adhesion of the active ingredient to the seeds or vegetative reproductive organs. Specific examples of coloring agents and binders are shown below. Colorants: For example, monoazos (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, Cl Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazos (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinones (Pigment Red 83, etc.), dioxazines (Pigment Blue 80, etc.), xanthenes (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethanes (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium dioxide, titanium oxide, zinc oxide, zinc sulfide, iron hexacyanoate, chrome vermilion, yellow lead, calcium carbonate, baryte powder, aluminum powder; Binders: polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clays, organically modified clays, inorganic clays, inorganically modified clays, etc.), minerals (bentonite, etc.), synthetic polymers (polycarboxylic acids or salts thereof, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or salts thereof, styrene-butadiene copolymer, methyl methacrylate-butadiene copolymer, polyacrylic acid or salts thereof, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), waxes (vegetable oils and fats, animal oils and fats, and derivatives thereof, paraffin, olefin, etc.). When Composition B is applied to seeds or vegetative reproductive organs, Composition B may be mixed with an adjuvant, if necessary. The seeds or vegetative reproductive organs treated with Composition B are sown or planted in a field in the usual manner.

[0260] The present compound and the present component may be applied separately at the same time to a plant, the soil in which the plant is grown, or the site of occurrence of harmful arthropods, or the present compound and the present component may be applied separately at different times to a plant, a cultivation carrier, or the site of occurrence of harmful arthropods. Specifically, for example, before or after planting seeds or vegetative reproductive organs treated with either the present compound or the present component into a cultivation carrier (e.g., soil, etc.), the other may be applied to the cultivation carrier.

[0261] Composition B can be applied to plants whose seeds have been previously treated with one or more components selected from the present components, or to cultivation carriers for such plants. Application methods include, for example, foliage treatment, soil treatment, root treatment, shower treatment, mist spray treatment, smoke treatment, water surface treatment, and hydroponic solution treatment.

[0262] Examples of seed treatment agents that are applied to soybeans in advance include the following. STANDAK-TOP 500FS (Fipronil / Pyraclostrobin / Thiophanate-m), DERMACOR 625FS (Chlorantraniliprole), CRUISER 350FS (Thiamethoxam), CROPSTAR 600FS (Imidacloprid / Thiodicarb), FORTENZA 600FS (Cyantraniliprole), S-UNSPEC-INS-WHEAT, NEMAT 300WP (Verticillium), FIPRONIL-ALTA 250FS (Fipronil), MAXIM-ADVANCED 195FS (Fludioxonil / Metalaxyl-M / Thiabendazole), SHELTER 250SC (Fipronil), MAXIM-XL 035FS (Fludioxonil / Metalaxyl-M), DEROSAL Plus(Carbendazim / Thirum), Vitavax - THIRAM (Carboxin / Thiram).

[0263] Examples of seed treatment agents that are applied to corn in advance include the following. PONCHO-VOTIVO 601EC (Bacillus-firmus / Clothianidin), ACCELERON-IC-609 600EC (Clothianidin), CRUISER 600FS (Thiamethoxam), ACCELERON-D-342 480FS (Prothioconazole), PONCHO 600FS (Clothianidin), MAXIM-QUATTRO 382.5FS (Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole), AVICTA-COMPLETE-CORN-250 280FS, Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), AVICTA-COMPLETE-CORN-500 423FS, (Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), LUMIVIA 625FS (Chlorantraniliprole), ACCELERON-D-281 480FS (Fluoxastrobin), ACCELERON-DC-309 312FS (Metalaxyl).

[0264] Examples of seed potato treatment agents that are used to treat potatoes in advance include the following: Maxim 4FS (fludioxonil), Maxim MZ (fludioxonil + mancozeb), Cruiser MAXX Vibrance Potato (fludioxonil + difenoconazole + sedaxane + thiamethoxam), Emesto Silver (penflufen + prothioconazole), MonCoatMZ (flutolanil + mancozeb), Moncut (flutolanil), Elatus (azoxystrobin + benzovindiflupyr), Quadris (azoxystrobin), Serenade ASO (Bacillus subtillis), DoubleNickel LC (Bacillus amyloliquefaciens), Atackin (streptomycin, thiophanate M), Furonside (fluazinam), Basidac (mepronil), Moncut (flutolanil), Lovral (iprodione), Moncut (flutolanil), Benlate (benomyl).

[0265] A spraying device can be used when applying Composition B. Examples of devices used for application include a hand-cranked sprayer, a power sprayer, a punkul sprayer, a manned aircraft (such as a manned helicopter), an unmanned aircraft (such as a radio-controlled helicopter or drone), a tractor, a planter, etc. Alternatively, the composition may be applied by hand without using a spraying device.

[0266] When applying Composition B using a sprayer, the spray pressure is not particularly limited, but is usually 30 to 120 PSI, preferably 40 to 80 PSI. The spray pressure here is the setting before introduction into the nozzle.

[0267] When applying composition B using a sprayer, the spray nozzle is not particularly limited, but examples include a flat spray nozzle, a conical nozzle, a rotary nozzle, a hollow cone nozzle, a deflector nozzle, and a straight nozzle.

[0268] When Composition B is applied in the form of a solution, the pH and hardness of the solution are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500. The time of day when Composition B is applied is not particularly limited, but is generally between 5:00 AM and 9:00 PM. The photon flux at the canopy level in the area where Composition B is applied is usually 10 to 2500 micromoles / m2 / sec. The weather conditions when Composition B is applied are not particularly limited, but the air temperature is usually 0 to 30°C, preferably 10 to 20°C, the soil temperature is usually 0 to 30°C, preferably 10 to 20°C, the relative humidity is 50 to 90%, preferably 40 to 80%, and the wind speed is 0 to 2 MPH.

[0269] Composition B is usually sprayed by mixing it with water to obtain a spray solution, which can be prepared by directly diluting it with the amount of water needed to spray it, or by mixing Composition B with a small amount of water, homogenizing it, and then adding water to adjust the amount to the specified volume. The amount of spray solution is not particularly limited, but is usually in the range of 5 to 5,000 L / ha, preferably 20 to 1,000 L / ha, and more preferably 140 to 300 L / ha. Specific spraying liquid volume is 10L / ha, 30L / ha, 50L / ha, 70L / ha, 90L / ha, 100L / ha, 120L / ha, 150L / ha, 180L / ha, 20 Examples include 0L / ha, 250L / ha, 300L / ha, 400L / ha, 500L / ha, 700L / ha, 900L / ha, 2000L / ha, and 4000L / ha.

[0270] When Composition B is sprayed using a manned or unmanned aircraft, the spray height is not particularly limited, but is usually 0.5 to 30 m, preferably 1 to 10 m.

[0271] Composition B may be mixed with an adjuvant when applying it to foliage, soil, roots, showers, smoke, water surface, seeds, or hydroponic solutions. The adjuvants may be mixed in advance of formulation (premix) or immediately before use (tank mix). The type of adjuvant is not particularly limited, but examples include mineral oil-derived COC (crop oil concentrate), vegetable oil-derived MSO (methylated seed oil), alcohol-based solvents, nonionic surfactants, anionic surfactants, cationic surfactants, silicone-based surfactants, nitrogen fertilizers, and mixtures thereof. Specifically, AgriDex (registered trademark), Induce (registered trademark), Gramin S (registered trademark), Genamin T 200BM (registered trademark), Silwet L77 (registered trademark), Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol Gold (registered trademark), BreakThru (registered trademark), Sundance II (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), BANOLE (registered trademark), Ochima (registered trademark), Agris (registered trademark), AMS (Ammonium Sulfate), UAN (Urea Ammonium Sulfate), Examples of suitable adjuvants include urea ammonium nitrate (urea ammonium nitrate), AdGreen (registered trademark), Mees (trademark), Rumba (registered trademark), Strides (registered trademark), Partner, Orix (registered trademark), and Penetrator. Furthermore, a drift-reducing agent such as Intact (registered trademark) may also be used. The weight ratio of Composition B to the adjuvant or drift-reducing agent is not particularly limited, but may be, for example, in the range of 1:100 to 100:1.

[0272] Composition B and a fertilizer can be mixed or used together. When mixed, they can be mixed in advance when preparing a formulation (premix) or just before application (tank mix). Examples of fertilizers include substances containing various elements such as nitrogen (N), phosphorus (P), potassium (K), silicon, magnesium, calcium, manganese, boron, iron, copper, zinc, sulfur, molybdenum, and cobalt. Examples of substances containing nitrogen, phosphorus, and potassium include urea, ammonium nitrate, ammonium chloride, ammonium sulfate, sodium nitrate, magnesium nitrate, nitric acid, anhydrous ammonia, urea ammonium nitrate, lime nitrate, lime nitrogen, phosphoric acid, superphosphate, calcium triphosphate, potassium sulfate, potassium chloride, potassium silicate, caustic potassium, potassium nitrate, potassium phosphate, MAP (ammonium phosphate), and DAP (diammonium phosphate). Fertilizers can be used in any form, such as granular, powdered, bulk, or liquid. Examples of application locations include the soil surface, in the soil, and on plants. Examples of equipment used for application include hand sprayers, power sprayers, pancras sprayers, manned aircraft (such as manned helicopters), unmanned aircraft (such as radio-controlled helicopters and drones), tractors, planters, broadcasters, sowers, and seeders. Application may also be done by hand without using a spraying device. A specific application method includes, for example, applying Composition B and a fertilizer together to seeds, vegetative reproductive organs, or seedlings at the time of sowing or planting, or around the time of sowing or planting (e.g., 0, 1, 2, 3, 4, or 5 days after sowing) (this method is sometimes called in-furrow application). The fertilizer applied at the time of sowing or planting, or around the time of sowing or planting, may be a solid fertilizer and / or a liquid fertilizer, including, for example, a fertilizer having an N:P:K ratio (sometimes called a starter fertilizer, pop-up fertilizer, etc.). Composition B and the fertilizer may be mixed immediately before application, or may be applied separately and simultaneously. The application location is not particularly limited as long as it is near the seed, vegetative reproductive organ, or seedling, but it may be in the planting furrow of the seed, vegetative reproductive organ, or seedling, or a location several inches away from the planting furrow of the seed, vegetative reproductive organ, or seedling, for example, 2 inches to the side and 2 inches below the planting furrow of the seed, vegetative reproductive organ, or seedling (sometimes referred to as a 2-by-2 band). Crops suitable for application include corn, soybean, sugarcane, potato, wheat, barley, rye, oats, rice, and the like. The ratio of the weight of one active ingredient contained in Composition B to the total weight of NPK contained in the fertilizer is not particularly limited, but may be, for example, in the range of 1:1 to 1:10,000.

[0273] Composition B can be applied by spot treatment. Spot treatment is a concept that is opposite to uniform application of Composition B, and refers to selective spraying of Composition B to a location where harmful arthropods are present or where there is a risk of harmful arthropods appearing. "Applying to a location" means applying to a plant or soil where harmful arthropods are present or where there is a risk of harmful arthropods appearing, preferably when applying to a plant. When applying to a plant, this includes applying only to individuals in a plant population where harmful arthropods are present or where there is a risk of harmful arthropods appearing, and also includes applying to parts of individual plants where harmful arthropods are present or where there is a risk of harmful arthropods appearing. Even when Composition B is sprayed in small amounts in areas where no harmful arthropods have occurred or where there is no risk of harmful arthropods occurring due to scattering, transpiration, etc., it is considered a spot treatment as long as it is not a uniform area treatment. Furthermore, spot treatment is not only considered when all areas where harmful arthropods have occurred or where there is a risk of harmful arthropods occurring in a continuous cultivation area are selectively treated. In other words, even if only part of the cultivation area is treated in an area, or even if some areas where harmful arthropods have occurred or where there is a risk of harmful arthropods occurring are not treated with Composition B, it is still considered a spot treatment as long as there are areas in the continuous cultivation area that have been spot-treated.

[0274] Specific examples of spot treatment methods are given below. Spot treatment may be performed in a plant cultivation area by an applicator visually spraying composition B using a handheld nozzle or robotic arm nozzle while walking or aboard a ground-based or flying device. Furthermore, spot treatment may be performed by mapping in advance areas where pest arthropods are present or likely to be present, and spraying composition B based on the map information. In spraying based on map information, in addition to the above-mentioned methods, spot treatment may be performed by automatically or manually opening and closing a boom nozzle or robotic arm nozzle while the sprayer is traveling or flying, based on the sprayer's position information (obtained by GPS, etc.) and the map information. The map information may be created based on image information captured by a manned or unmanned flying object, or may be created visually by an observer walking on the ground, riding on a ground-based or flying device, or by an observer aboard a flying device. Furthermore, a mobile or flying sprayer may be equipped with the function of detecting areas where harmful arthropods are present or likely to be present, and spot treatment may be carried out using the boom or robotic arm while performing real-time mapping.

[0275] In addition to visual recognition by applicators or observers, locations where pest arthropods are present can be identified through image analysis using visible light, or through image analysis using specific wavelengths of hyperspectral images. Image analysis can be performed by visually recognizing pest arthropod infestations on a screen, or by image recognition using artificial intelligence (e.g., OPTiM Corporation, press release, December 26, 2017). These images can be taken by manned or unmanned flying objects, or by photographers walking on the ground, riding on ground-traveling devices, or flying devices. Locations where pest arthropods may be present can be estimated based on patchy occurrences of the pests in previous crop growing seasons, or from the distribution of pest arthropods in the soil. The distribution of pest arthropods in the soil can be investigated by soil sampling or estimated using remote sensing. Furthermore, image analysis can be used to detect and estimate the presence of pest arthropods hiding in plants. This technology is known as a form of emerging agriculture, also known as precision agriculture, smart agriculture, or digital agriculture, and the uneven spraying pattern caused by spot treatment is sometimes called VRA (Variable Rate Application) in the emerging agriculture terminology.

[0276] Methods for spot treatment with Composition B include spraying the soil in areas where harmful arthropods are present or where there is a risk of harmful arthropod infestation (soil treatment), and spraying Composition B on plants where harmful arthropods are present or where there is a risk of harmful arthropod infestation (foliage treatment). Spraying is typically carried out using a spray solution prepared by mixing Composition B with water. The amount of spray solution is not particularly limited, but is typically 50 to 1,000 L / ha, preferably 100 to 500 L / ha, and more preferably 140 to 300 L / ha within the area to be spot-treated. The proportion of the...

Claims

1. Formula (I) 【Chemistry 1】 [During the ceremony, Q expressed by the following formula 【Chemistry 2】 (wherein # represents a bonding site with a sulfur atom, and ● represents a bonding site with Het) represents a group represented by formula Q1 or a group represented by formula Q2, 【Chemistry 3】 A 1 is a nitrogen atom or CR 8 represents R 8 represents a halogen atom or a hydrogen atom, R 2 represents a C1-C6 alkyl group optionally substituted by one or more halogen atoms, a cyclopropyl group, or a cyclopropylmethyl group; n represents 0, 1 or 2; G 1 is a nitrogen atom or CR 3a represents G 2 is a nitrogen atom or CR 3b represents G 3 is a nitrogen atom or CR 3c represents G 4 is a nitrogen atom or CR 3d represents R 3a , R 3b , R 3c and R 3d are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group L, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group E, a phenyl group optionally substituted with one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group H, OR 12 , N.R. 11 R 12 , N.R. 11a R 12a , N.R. 24 N.R. 11 R 12 , N.R. 24 OR 11 , N.R. 11 C(O)R 13 , N.R. 24 N.R. 11 C(O)R 13 , N.R. 11 C(O)OR 14 , N.R. 24 N.R. 11 C(O)OR 14 , N.R. 11 C(O)NR 31 R 32 , N.R. 24 N.R. 11 C(O)NR 31 R 32 , N=CHNR 31 R 32 , N=S(O) p R 15 R 16 , C(O)R 13 , C(O)OR 17 , C(O)NR 31 R 32 , C(O)NR 11 S (O) 2 R 23 , C.R. 30 = NOR 17 , N.R. 11 CR 24 = NOR 17 , S(O) m R 23 , a cyano group, a nitro group, a halogen atom, or a hydrogen atom; p represents 0 or 1; m represents 0, 1 or 2; R 30 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 35 , N.R. 36 R 37 or a hydrogen atom, R 35 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, R 17 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group D, or a hydrogen atom; R 11 , R 24 , R 36 and R 37 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 12 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J, a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from group J, a phenyl group optionally substituted with one or more substituents selected from group D, a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, S(O) 2 R 23 or a hydrogen atom, R 23 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a phenyl group optionally substituted with one or more substituents selected from group D, R 11a and R 12a form, together with the nitrogen atom to which they are bonded, a 3- to 7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from Group E; R 13 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, or a hydrogen atom, R 14 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from group D}, R 15 and R 16 are the same or different and represent a C1-C6 alkyl group optionally substituted by one or more halogen atoms, R 31 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 32 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group F, a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J, S(O) 2 R 23 or a hydrogen atom, R 4 is group L 2 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group E 2 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group H 2 a phenyl group which may be substituted with one or more substituents selected from group H 2 a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the group consisting of: OR 42 , N.R. 41 R 42 , N.R. 41a R 42a , N.R. 54 N.R. 41 R 42 , N.R. 54 OR 41 , N.R. 41 C(O)R 43 , N.R. 54 N.R. 41 C(O)R 43 , N.R. 41 C(O)OR 44 , N.R. 54 N.R. 41 C(O)OR 44 , N.R. 41 C(O)NR 61 R 62 , N.R. 54 N.R. 41 C(O)NR 61 R 62 , N=CHNR 61 R 62 , N=S(O) r R 45 R 46 , C(O)R 43 , C(O)OR 47 , C(O)NR 61 R 62 , C(O)NR 41 S (O) 2 R 53 , C.R. 60 = NOR 47 , N.R. 41 CR 54 = NOR 47 , S(O) t R 53 , a cyano group, a nitro group, or a halogen atom; r represents 0 or 1; t represents 0, 1 or 2; R 60 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 65 , N.R. 66 R 67 or a hydrogen atom, R 65 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, R 47 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms; 2 represents a phenyl group which may be substituted by one or more substituents selected from the following, or a hydrogen atom; R 41 , R 54 , R 66 and R 67 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 42 is the group F 2 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 2 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J 2 a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from group D 2 a phenyl group which may be substituted with one or more substituents selected from group D 2 a 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from the group consisting of a hydrogen atom and S(O) 2 R 53 represents R 53 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a group D 2 represents a phenyl group which may be substituted by one or more substituents selected from R 41a and R 42a together with the nitrogen atom to which they are attached, form a group E 2 forming a 3- to 7-membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from R 43 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, Group D 2 a phenyl group which may be substituted with one or more substituents selected from group D 2 a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from the following, or a hydrogen atom; R 44 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group is a group selected from group D 2 and optionally substituted with one or more substituents selected from the following: R 45 and R 46 are the same or different and represent a C1-C6 alkyl group optionally substituted by one or more halogen atoms, R 61 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 62 is the group F 2 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 2 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of S(O) 2 R 53 or a hydrogen atom, k represents 0, 1, 2, or 3, and when k is 2 or 3, two or three R 4 may be the same or different, Two R's 4 When R are bonded to adjacent carbon atoms, the two R 4 together with the two carbon atoms to which they are bonded, form a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, or a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring are each selected from the group H 2 or a triazole ring which may be substituted with one or more substituents selected from group P; Het represents a group of the formula Het1 or a group of the formula Het2, 【Chemistry 4】 A 2 is -NR 5a - or -CR 7a R 7b - represents A 3 is -CR 7c R 7d -, -CR 7e R 7f -CR 7g R 7h -* 1 , or -CR 7i R 7j -CR 7k R 7l -CR 7m R 7n -* 1 represents * 1 A 2 represents the bonding position with A 4 is -NR 5b -, -CR 7o R 7p -, -CR 7q R 7r -CR 7s R 7t -* 2 , -NR 5c -CR 7u R 7v -* 2 , -CR 7w R 7x -CR 7y R 7z -CR 7aa R 7bb -* 2 , or -NR 5d -CR 7cc R 7dd -CR 7ee R 7ff -* 2 represents * 2 A 2 represents the bonding position with R 5a , R 5b , R 5c , and R 5d are the same or different and represent a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group K, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 7a , R 7b , R 7c , R 7d , R 7e , R 7f , R 7g , R 7h , R 7i , R 7j , R 7k , R 7l , R 7m , R 7n , R 7o , R 7p , R 7q , R 7r , R 7s , R 7t , R 7u , R 7v , R 7w , R 7x , R 7y , R 7z , R 7aa , R 7bb , R 7cc , R 7dd , R 7ee , and R 7ff are the same or different and each represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group which may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom, a nitro group, OR 69 , N.R. 69 R 70 , a cyano group, a halogen atom, or a hydrogen atom; R 7a and R 7b , R 7c and R 7d , R 7e and R 7f , R 7g and R 7h , R 7i and R 7j , R 7k and R 7l , R 7m and R 7n , R 7o and R 7p , R 7q and R 7r , R 7s and R 7t , R 7u and R 7v , R 7w and R 7x , R 7y and R 7z , R 7aa and R 7bb , R 7cc and R 7dd , and R 7ee and R 7ff each may be taken together with the carbon atom to which they are attached to form a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom; R 69 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group T, a C3-C7 cycloalkyl group which may be substituted with one or more substituents selected from group U, a C3-C7 cycloalkenyl group which may be substituted with one or more substituents selected from group U, a phenyl group which may be substituted with one or more substituents selected from group V, a 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group V, or a hydrogen atom; R 70 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; W represents an oxygen atom or a sulfur atom; B 1 is CR 6a or a nitrogen atom, B 2 is CR 6b or a nitrogen atom, B 3 is CR 6c or a nitrogen atom, R 6a , R 6b , and R 6c are the same or different, and the group L 3 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group E 3 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group H 3 a phenyl group which may be substituted with one or more substituents selected from group H 3 a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the group consisting of: OR 72 , N.R. 71 R 72 , N.R. 71a R 72a , N.R. 84 N.R. 71 R 72 , N.R. 84 OR 71 , N.R. 71 C(O)R 73 , N.R. 84 N.R. 71 C(O)R 73 , N.R. 71 C(O)OR 74 , N.R. 84 N.R. 71 C(O)OR 74 , N.R. 71 C(O)NR 91 R 92 , N.R. 84 N.R. 71 C(O)NR 91 R 92 , N=CHNR 91 R 92 , N=S(O) q R 75 R 76 , C(O)R 73 , C(O)OR 77 , C(O)NR 91 R 92 , C(O)NR 71 S (O) 2 R 83 , C.R. 90 = NOR 77 , N.R. 71 CR 84 = NOR 77 , S(O) v R 83 , a cyano group, a nitro group, a halogen atom, or a hydrogen atom; q represents 0 or 1; v represents 0, 1 or 2; R 90 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a halogen atom, OR 95 , N.R. 96 R 97 or a hydrogen atom, R 95 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, R 77 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms; 3 represents a phenyl group which may be substituted by one or more substituents selected from the group consisting of phenyl, ... R 71 , R 84 , R 96 and R 97 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 72 is the group F 3 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 3 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from group J 3 a C3-C7 cycloalkenyl group optionally substituted with one or more substituents selected from group D 3 a phenyl group which may be substituted with one or more substituents selected from group D 3 a 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the group consisting of S(O) 2 R 83 or a hydrogen atom, R 83 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, or a group D 3 represents a phenyl group which may be substituted by one or more substituents selected from R 71a and R 72a together with the nitrogen atom to which they are attached, form a group E 3 forming a 3- to 7-membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from R 73 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, Group D 3 a phenyl group which may be substituted with one or more substituents selected from group D 3 a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from the following, or a hydrogen atom; R 74 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group optionally substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group is a group selected from group D 3 and optionally substituted with one or more substituents selected from the following: R 75 and R 76 are the same or different and represent a C1-C6 alkyl group optionally substituted by one or more halogen atoms, R 91 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom; R 92 is the group F 3 a C1-C6 chain hydrocarbon group optionally substituted with one or more substituents selected from group J 3 a C3-C7 cycloalkyl group optionally substituted with one or more substituents selected from the group consisting of S(O) 2 R 83 or a hydrogen atom. Group L: a group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group M: a group consisting of C1-C6 chain hydrocarbon groups optionally substituted with one or more halogen atoms, C1-C6 alkoxy groups optionally substituted with one or more halogen atoms, C3-C6 alkenyloxy groups optionally substituted with one or more halogen atoms, C3-C6 alkynyloxy groups optionally substituted with one or more halogen atoms, and halogen atoms. Group D: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 , O.C.(O)R 21 , C(O)OR 21 The group consisting of a cyano group, a nitro group, and a halogen atom. R 21 and R 22 are the same or different and represent a C1-C6 alkyl group optionally substituted with one or more halogen atoms. Group E: a group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group. Group F: a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, an amino group, NHR 21 , N.R. 21 R 22 , halogen atoms, and cyano groups. Group H: a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 , O.C.(O)R 9 , O C (O) O R 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group W. R 9 represents a C1-C6 alkyl group optionally substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, R 10 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. Group P: C2-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, Group D 2 a phenyl group which may be substituted with one or more substituents selected from group D 2 the group consisting of a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from the above, a C2-C6 alkylcarbonyl group optionally substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group optionally substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group optionally substituted by one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group optionally substituted by one or more halogen atoms. Group J: a group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. Group K: a group consisting of a C1-C6 alkoxy group optionally substituted by one or more halogen atoms, a phenyl group optionally substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted by one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted by one or more halogen atoms, and a 3- to 7-membered non-aromatic heterocyclic group optionally substituted by one or more substituents selected from Group M. Group T: a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from Group M, an amino group, NHR 21 , N.R. 21 R 22 , halogen atoms, and cyano groups. Group U: a group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. Group V: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 , O.C.(O)R 21 , C(O)OR 21 The group consisting of a cyano group, a nitro group, and a halogen atom. Group W: a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 , O.C.(O)R 21 , C(O)OR 21 The group consisting of a cyano group, a nitro group, and a halogen atom. Group L 2 The group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group D 2 : a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 , O.C.(O)R 21 , C(O)OR 21 The group consisting of a cyano group, a nitro group, and a halogen atom. Group E 2 The group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group. Group F 2 a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, an amino group, NHR 21 , N.R. 21 R 22 , halogen atoms, and cyano groups. Group H 2 : a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 , O.C.(O)R 9 , O C (O) O R 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group W. Group J 2 The group consisting of C1-C6 alkyl groups which may be substituted with one or more halogen atoms, halogen atoms, and cyano groups. Group L 3 The group consisting of a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, a cyano group, a hydroxy group, and a halogen atom. Group D 3 : a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a hydroxy group, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a sulfanyl group, a C1-C6 alkylsulfanyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfinyl group optionally substituted with one or more halogen atoms, a C1-C6 alkylsulfonyl group optionally substituted with one or more halogen atoms, an amino group, NHR 21 , N.R. 21 R 22 , C(O)R 21 , O.C.(O)R 21 , C(O)OR 21 The group consisting of a cyano group, a nitro group, and a halogen atom. Group E 3 The group consisting of a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a C3-C6 alkenyloxy group optionally substituted with one or more halogen atoms, a C3-C6 alkynyloxy group optionally substituted with one or more halogen atoms, a halogen atom, an oxo group, a hydroxy group, a cyano group, and a nitro group. Group F 3 a C1-C6 alkoxy group optionally substituted with one or more halogen atoms, a phenyl group optionally substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group D, a C3-C7 cycloalkyl group optionally substituted with one or more halogen atoms, a 3- to 7-membered non-aromatic heterocyclic group optionally substituted with one or more substituents selected from group M, an amino group, NHR 21 , N.R. 21 R 22 , halogen atoms, and cyano groups. Group H 3 : a C1-C6 alkyl group optionally substituted with one or more halogen atoms, OR 10 , N.R. 9 R 10 , C(O)R 10 , C(O)NR 9 R 10 , O.C.(O)R 9 , O C (O) O R 9 , N.R. 10 C(O)R 9 , N.R. 10 C(O)OR 9 , C(O)OR 10 a halogen atom, a nitro group, a cyano group, an amino group, and a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from group W. Group J 3 The group consisting of a C1-C6 alkyl group optionally substituted with one or more halogen atoms, a halogen atom, and a cyano group. A method for controlling arthropod pests, which comprises the step of applying an effective amount of a compound represented by the formula:

2. 2. The method for controlling arthropod pests according to claim 1, wherein the cultivation carrier for the plant is soil.

3. A composition comprising the compound represented by formula (I) according to claim 1, or an N-oxide or an agriculturally acceptable salt thereof, and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i) and group (j): Group (a): A group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): bactericidal active ingredient; Group (c): plant growth regulating ingredients; Group (d): phytotoxicity-safening components; Group (e): synergists; Group (f): repellent components; Group (g): molluscicidal components; Group (h): Signal transduction substances consisting of pheromones and allelochemicals used by insects; Group (i): herbicidal active ingredients; Group (j): biological control materials.

4. A method for controlling arthropod pests, which comprises the step of applying an effective amount of the composition according to claim 3 to arthropod pests, their habitats, plants, or cultivation carriers for plants.

5. The method for controlling arthropod pests according to claim 4, wherein the support for cultivating plants is soil.

6. A seed or vegetative reproductive organ carrying an effective amount of a compound of formula (I) as defined in claim 1, or an N-oxide or an agriculturally acceptable salt thereof, or a composition as defined in claim 3.

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