Carboxylate, carboxylic acid generator, resin, resist composition, and method for producing resist pattern

Abstract

To provide a resist composition and the like which allow a resist pattern having good CD uniformity to be produced.SOLUTION: There are provided: a carboxylic acid generator containing a carboxylate represented by formula (I) or a structural unit derived from the carboxylate represented by formula (I); and a resist composition. [In the formula, X represents an S or I atom; m10 represents 1 when X is S, and m10 represents 0 when X is I; and R1A-R1D each represent a group represented by formula (4a).]SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a carboxylate, a carboxylic acid generator, a resin, a resist composition, and a method for producing a resist pattern. [Background technology]

[0002] Patent Document 1 describes a resist composition that contains a resin that includes a structural unit derived from a carboxylate represented by the following formula. TIFF2025017356000001.tif2454 [Prior art documents] [Patent documents]

[0003] [Patent Document 1] JP 2011-037835 A Summary of the Invention [Problem to be solved by the invention]

[0004] The present invention provides a carboxylate that forms a resist pattern that has better CD uniformity (CDU) than a resist pattern formed using a resist composition that uses the above-mentioned carboxylate. [Means for solving the problem]

[0005] The present invention includes the following inventions. [1] A carboxylic acid generator containing a carboxylate represented by formula (I) or a structural unit derived from a carboxylate represented by formula (I). TIFF2025017356000002.tif52101 [In formula (I), X represents a sulfur atom or an iodine atom. m10 represents 0 or 1. When X is a sulfur atom, m10 is 1, and when X is an iodine atom, m10 is 0. R 1A , R 1B , R 1C and R1D each independently represents a group represented by formula (4a). R 4 represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, and the -CH 2 - is -O-, -S-, -CO-, -SO- or -SO 2 It may be replaced with -. R 7 , R 8 and R 9 each independently represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, and -CH 2 - is -O-, -S-, -CO-, -SO- or -SO 2 When X is a sulfur atom, R 7 and R 8 or R 8 and R 9 Combined, S + The R forming the ring may form a ring containing 7 and R 8 or R 8 and R 9 is S + The —CH 2 - is -O-, -S-, -CO-, -SO- or -SO 2 It may be replaced with -. m1A, m1C, and m1D each independently represent an integer of 0 to 5. When m1A, m1C, and m1D each represent 2 or more, a plurality of R 1A , R 1C and R 1D may be the same or different from each other. m1B represents an integer of 0 to 4, and when m1B is 2 or more, a plurality of R 1B may be the same or different from each other. However, at least one of m1A, m1B, m1C, and m1D is an integer of 1 or more. m4 represents an integer of 0 to 5, and when m4 is 2 or more, a plurality of R4 may be the same or different, and satisfy the relationship 0≦m1A+m4≦5. m7 represents an integer of 0 to 4, and when m7 is 2 or more, a plurality of R 7 may be the same or different, and satisfy the relationship 0≦m1B+m7≦4. m8 represents an integer of 0 to 5, and when m8 is 2 or more, a plurality of R 8 may be the same or different, and satisfy the relationship 0≦m1C+m8≦5. m9 represents an integer of 0 to 5, and when m9 is 2 or more, a plurality of R 9 may be the same or different, and satisfy 0≦m1D+m9≦5. X 0 represents a hydrocarbon group having 2 to 72 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced.] TIFF2025017356000003.tif4145[In formula (4a), R 10 represents a hydrogen atom or a methyl group. X 10 represents *-O-**, *-CO-O-**, *-O-CO-O-** or *-Ax-Ph-Ay-**. Ph represents a phenylene group which may have a substituent. Ax and Ay each independently represent one or more bond types selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate bond. *R 10 represents the bond site with the carbon atom to which it is attached, and ** represents L 10 represents the binding site with L 10 represents a single bond or a hydrocarbon group having 1 to 36 carbon atoms which may have a substituent, and -CH 2 -, -O-, -S-, -SO 2 It may be replaced by - or -CO-. *10 indicates the bonding site with the benzene ring.] [2] The carboxylic acid generator according to [1], which contains a resin containing a structural unit derived from a carboxylate represented by formula (I), wherein the structural unit derived from the carboxylate represented by formula (I) is a structural unit represented by formula (IP). TIFF2025017356000004.tif50128[In expression (IP), X, R 4 , R 7 , R 8 , R 9 , m1A, m1B, m1C, m1D, m4, m7, m8, m9, m10, X 0 has the same meaning as in formula (I). R 1a , R 1b , R 1c and R 1d each independently represents a group represented by formula (4a) or formula (4a-1), R 1a , R 1b , R 1c and R 1d At least one of represents a group represented by formula (4a-1). TIFF2025017356000005.tif4163 [In formula (4a-1), all symbols have the same meaning as in formula (4a)] [3]X 10 is a single bond or a group represented by the formula (X 10 -1)~Formula(X 10 -10): The carboxylic acid generator according to [1] or [2], wherein the carboxylic acid generator is a group represented by any one of the following formulas: TIFF2025017356000006.tif46170[expression(X 10 -1)~Formula(X 10 -10) Medium, *, ** are binding sites, * is R 10 represents the bonding site with the carbon atom to which it is bonded. Rx represents a halogen atom, a hydroxy group, a fluorinated alkyl group having 1 to 6 carbon atoms, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms. mx represents an integer of 0 to 4. X 20 is -O- or -NR 3- represents. R 3 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.] [4]X 0 is an alicyclic hydrocarbon group having 3 to 36 carbon atoms; an aromatic hydrocarbon group having 6 to 36 carbon atoms, or a group consisting of a combination of a chain hydrocarbon group having 1 to 18 carbon atoms and an alicyclic hydrocarbon group having 3 to 36 carbon atoms or an aromatic hydrocarbon group having 6 to 36 carbon atoms, The alicyclic hydrocarbon group, the chain hydrocarbon group and the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms or a hydroxy group. 2 - is -O-, -S-, -CO- or -SO 2 The carboxylic acid generator according to any one of [1] to [3], wherein - may be replaced by. [5]X 0 is a group represented by formula (aa): The carboxylic acid generator according to any one of [1] to [4]. TIFF2025017356000007.tif1572[In formula (aa), X a and X b each independently represents -O- or -S-. X 1a represents a hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. X 2a represents a hydrocarbon group having 1 to 48 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. * -COO - represents the bonding site with the carbon atom of [6]X 0is a phenyl group which may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms, or a hydroxy group. [7] A resist composition comprising the carboxylic acid generator according to any one of [1] to [6] and an acid generator other than the carboxylic acid generator. [8] A carboxylate represented by formula (I), and a resin including a structural unit having an acid labile group. [9] A resin containing a structural unit derived from a carboxylate represented by formula (I), The resist composition according to [7], wherein the resin containing a structural unit derived from a carboxylate represented by formula (I) further contains a structural unit having an acid labile group.

[10] The composition further comprises a resin having a structural unit having an acid labile group, The resist composition according to any one of [7] to [9], wherein the structural unit having an acid labile group includes at least one selected from the group consisting of a structural unit represented by formula (a1-0), a structural unit represented by formula (a1-1), a structural unit represented by formula (a1-2), a structural unit represented by formula (a1-4), a structural unit represented by formula (a1-5), and a structural unit represented by formula (a1-6). TIFF2025017356000008.tif43143 [In formula (a1-0), formula (a1-1) and formula (a1-2), L a01 , L a1 and L a2 are each independently -O- or *-O-(CH 2 ) k1 represents --CO--O--, k1 represents an integer of 1 to 7, and * represents a bonding site with --CO--. R a01 , R a4 and R a5 each independently represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R a02 , R a03 and R a04each independently represents an alkyl group having 1 to 8 carbon atoms, an alicyclic hydrocarbon group having 3 to 18 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or a combination thereof, and the alkyl group, alicyclic hydrocarbon group and aromatic hydrocarbon group may have a halogen atom. R a6 and R a7 each independently represents an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alicyclic hydrocarbon group having 3 to 18 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or a group formed by combining these, and the alkyl group, alkenyl group, alicyclic hydrocarbon group and aromatic hydrocarbon group may have a halogen atom. m1' represents an integer of 0 to 14. n1 represents an integer of 0 to 10. n1' represents an integer of 0 to 3. TIFF2025017356000009.tif31118[In formula (a1-4), R a1 represents a hydrogen atom, a halogen atom, or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R a17 represents a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 6 carbon atoms, an alkoxyalkyl group having 2 to 12 carbon atoms, an alkoxyalkoxy group having 2 to 12 carbon atoms, an alkylcarbonyl group having 2 to 4 carbon atoms, an alkylcarbonyloxy group having 2 to 4 carbon atoms, an acryloyloxy group or a methacryloyloxy group. A a11 represents a single bond or an alkanediyl group having 1 to 12 carbon atoms, and the -CH 2 - is -O-, -CO- or -NR a18 - may be replaced. R a18 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. X a1 represents a single bond or -CO-. R a34 and R a35each independently represents a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms; R a36 represents a hydrocarbon group having 1 to 20 carbon atoms, or R a35 and R a36 are bonded to each other to form a divalent hydrocarbon group having 2 to 20 carbon atoms together with the -CO- to which they are bonded, and the -CH 2 - may be replaced by -O- or -S-. na1 represents an integer of any one of 1 to 5, and when na1 is 2 or more, the groups in the multiple parentheses may be the same or different. na11 represents an integer of 0 to 4. When na11 is 2 or more, multiple R a17 may be the same or different from each other. mc represents an integer from 0 to 2. TIFF2025017356000010.tif4558[In formula (a1-5), R a8 represents an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, a hydrogen atom, or a halogen atom. Z a1 is a single bond or *-(CH 2 ) h3 -CO-L 54 -, h3 represents an integer of 1 to 4, * represents L 51 represents the binding site with L 51 , L 52 , L 53 and L 54 each independently represents -O- or -S-. s1 represents an integer of 1 to 3. s1' represents an integer of 0 to 3. TIFF2025017356000011.tif3479[In formula (a1-6), R a61 represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R a62 , R a63 and R a64each independently represents an alkyl group having 1 to 6 carbon atoms or a cyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent, or R a62 and R a63 are bonded to each other to form a ring having 3 to 20 carbon atoms together with the carbon atoms to which they are attached. X a61 is a single bond, -CO-O-* or -CO-NR 5 -*, where * represents the bonding site with Ar, and R 5 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. X a62 is a single bond, *-OL a61 -or*-CO-OL a62 -, * represents the bonding site with Ar, L a61 and L a62 each independently represents an alkanediyl group having 1 to 4 carbon atoms. Ar represents an aromatic hydrocarbon group having 6 to 20 carbon atoms which may have a substituent.]

[11] The resist composition according to any one of [7] to

[10] , which contains a resin containing a structural unit represented by formula (a2-A). TIFF2025017356000012.tif30128[In formula (a2-A), R a2 represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R a27 represents a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 6 carbon atoms, an alkoxyalkyl group having 2 to 12 carbon atoms, an alkoxyalkoxy group having 2 to 12 carbon atoms, an alkylcarbonyl group having 2 to 4 carbon atoms, an alkylcarbonyloxy group having 2 to 4 carbon atoms, an acryloyloxy group or a methacryloyloxy group. A a21 represents a single bond or an alkanediyl group having 1 to 12 carbon atoms, and the -CH 2 - is -O-, -CO- or -NR a28 - may be replaced. R a28represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. X a2 represents a single bond or -CO-. nA2 represents an integer of 1 to 5. When nA2 is 2 or more, the groups in the multiple parentheses may be the same or different. na21 represents an integer of 0 to 4. When na21 is 2 or more, a plurality of R a27 may be the same or different from each other. mc represents an integer from 0 to 2.

[12] The resist composition according to any one of [7] to

[11] , wherein the acid generator comprises a salt represented by formula (B1) or a salt represented by formula (B2). TIFF2025017356000013.tif1391[In formula (B1), L b1 represents a single bond or a (nb1+1)-valent hydrocarbon group which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. L b2 represents a single bond or a divalent hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced with -. Y b1 represents a methyl group which may have a substituent or a cyclic hydrocarbon group having 3 to 24 carbon atoms which may have a substituent, and -CH 2 -, -O-, -S-, -SO 2 It may be replaced by - or -CO-. nb1 represents an integer of 1 to 6. When nb1 is 2 or more, the groups in the multiple parentheses may be the same or different. Z1 + represents an organic cation. TIFF2025017356000014.tif13100[In formula (B2), A 1represents a nitrogen atom or a carbon atom. L b2 represents a single bond or a divalent hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced with -. Y b1’ represents a methyl group which may have a substituent or a cyclic hydrocarbon group having 3 to 24 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced with -. nb5 represents an integer of 2 or 3. When nb5 is 2, A 1 is a nitrogen atom, and when nb5 is 3, A 1 A is a carbon atom. The groups in the parentheses may be the same or different from each other, and two groups in the parentheses are bonded to form A 1 may form a ring comprising: Z2 + represents an organic cation.

[13] (1) A step of applying the resist composition according to any one of [7] to

[12] onto a substrate; (2) A step of drying the applied resist composition to form a composition layer; (3) exposing the composition layer to light; (4) heating the composition layer after exposure; and (5) A method for producing a resist pattern, comprising the step of developing the composition layer after heating.

[14] A carboxylate represented by the above formula (I).

[15] X 10 is a single bond or the above formula (X 10 -1)~Formula(X 10 -10).

[16] X 0 is an alicyclic hydrocarbon group having 3 to 36 carbon atoms; an aromatic hydrocarbon group having 6 to 36 carbon atoms, or a group consisting of a combination of a chain hydrocarbon group having 1 to 18 carbon atoms and an alicyclic hydrocarbon group having 3 to 36 carbon atoms or an aromatic hydrocarbon group having 6 to 36 carbon atoms, The alicyclic hydrocarbon group, the chain hydrocarbon group and the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms or a hydroxy group. 2 - is -O-, -S-, -CO- or -SO 2 The carboxylate according to

[14] or

[15] , which may be replaced by -.

[17] X 0 is a group represented by the above formula (aa).

[18] X 0 is a fluorine atom, an iodine atom, a fluoroalkyl group having 1 to 4 carbon atoms, or a phenyl group which may have a hydroxyl group.

[19] A resin comprising a structural unit represented by the above formula (IP). Effect of the Invention

[0006] By using the resist composition of the present invention, a resist pattern with good CD uniformity (CDU) can be produced. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0007] In this specification, the term "(meth)acrylic monomer" means "at least one of an acrylic monomer and a methacrylic monomer." The terms "(meth)acrylate" and "(meth)acrylic acid" have the same meaning. In the groups described in this specification, those that can have both a straight-chain structure and a branched structure may have either one. -CH contained in a hydrocarbon group, etc. 2 - is -O-, -S-, -CO- or -SO 2When replaced with -, the same example applies to each group, and the number of carbon atoms before replacement is the number of carbon atoms of the hydrocarbon group, etc. "Combined group" means a group in which two or more of the exemplified groups are bonded, and the valence of the group may be appropriately changed depending on the bond form. "Derived from" or "derived from" means that the polymerizable C=C bond contained in the molecule becomes a -CC- group (single bond) by polymerization. When stereoisomers exist, all stereoisomers are included. Each group may have any position and number of hydrogen atoms contained in the group that are substituted for the bond site depending on the number of substituents, etc. The number of carbon atoms in the substituent is not included in the number of carbon atoms of the substituted group. An acid labile group means a group that, when contacted with an acid (e.g., trifluoromethanesulfonic acid, etc.), the leaving group is eliminated to form a hydrophilic group (e.g., a hydroxyl group or a carboxyl group, etc.). By base labile group is meant a group which, upon contact with a base (eg, trimethylamine, etc.), is eliminated to form a hydrophilic group (eg, a carboxy group or a hydroxy group, etc.). In this specification, the term "solids content of a resist composition" refers to the sum of the components excluding the solvent (E), which will be described later, from the total amount of the resist composition.

[0008] [Carboxylic acid generator] The carboxylic acid generator of the present invention is a carboxylic acid generator containing a carboxylate represented by formula (I) (hereinafter may be referred to as "carboxylate (I)" or "salt (I)") or a structural unit derived from salt (I) (hereinafter may be referred to as "structural unit (IP)"). The carboxylic acid generator of the present invention may contain one type of carboxylate (I), or may contain two or more types of carboxylate (I), or may contain one or more types of structural units (IP); that is, it may contain a compound or resin containing one type of structural unit (IP), or may contain a resin containing two or more different structural units (IP), or may contain a resin containing the structural unit (IP) and a structural unit derived from a compound (monomer) different from the carboxylate (I), or may contain both the carboxylate (I) and a compound or resin containing the structural unit (IP). The carboxylic acid generator of the present invention may contain, in addition to the salt (I), one or more known compounds which act as a carboxylic acid generator in the resist field.

[0009] [Carboxylic acid salt represented by formula (I)] The present invention relates to a carboxylate represented by formula (I) (hereinafter sometimes referred to as "salt (I)" or "carboxylate (I)"). In a salt (I), the side having a positive charge is sometimes called a "cation (I)" and the side having a negative charge is sometimes called an "anion (I)". TIFF2025017356000015.tif52101 [wherein all symbols have the same meanings as defined above.]

[0010] [Cation (I)] The cation (I) of the salt represented by formula (I) is a cation represented by formula (IC). TIFF2025017356000016.tif63126 [In formula (IC), all symbols have the same meaning as in formula (I)]

[0011] R 1A , R 1B , R 1C and R 1D X included in formula (4a) 10 is a group represented by *-Ax-Ph-Ay-**, it is preferably a linking group represented by the following formula (X10). TIFF2025017356000017.tif3449[In formula (X10), Ax is R 10 represents a bond type bonding to the carbon atom to which is bonded, and represents one or more bond types selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate ester bond. Ay is L 10 and represents one or more bond types selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate bond. Rx represents a halogen atom, a hydroxy group, a fluorinated alkyl group having 1 to 6 carbon atoms, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms. mx represents an integer of 0 to 4, and when mx is an integer of 2 or more, multiple Rx's may be the same or different. When either Ax or Ay is a single bond, the other is preferably one selected from the group consisting of an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate ester bond. When either Ax or Ay is an amide bond, -CO-NR 3 A bond represented by - is preferred. Among these, Rx is preferably a fluorine atom, an iodine atom, a trifluoromethyl group, a methyl group or an ethyl group. mx is preferably 0, 1 or 2. The bonding position of Ay in the phenylene group is preferably the m-position or p-position relative to the bonding position of Ax, and more preferably the p-position. X 10 For example, the following formula (X 10 -1)~Formula(X 10 -10). * and ** represent a bonding site, * represents -R 10 represents the bonding site with the carbon atom to which it is bonded. TIFF2025017356000018.tif45170[expression(X 10 -1)~Formula(X 10 -10) Medium, *, ** are binding sites, * is R 10 represents the bonding site with the carbon atom to which it is bonded. Rx represents a halogen atom, a hydroxy group, a fluorinated alkyl group having 1 to 6 carbon atoms, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms. mx represents an integer of 0 to 4. X 20 is -O- or -NR 3 - represents. R 3 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.] R3 Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a tert-butyl group, a pentyl group, and a hexyl group. The number of carbon atoms in the alkyl group is preferably 1 to 4, and more preferably 1 to 3. 10 -1)~Formula(X 10 Specific examples of the group represented by -10) include the following groups. TIFF2025017356000019.tif87163 Among them, X 10 is a single bond or a group of the formula (X 10 -1') and formula (X 10 -3')~expression(X 10 -10'), a single bond or a group represented by the formula (X 10 -1'), expression (X 10 -4'), expression (X 10 -5'), expression (X 10 -6') and formula (X 10 -10'), and more preferably a single bond, a group represented by the formula (X 10 -1'), a group represented by the formula (X 10 -5') or a group represented by the formula (X 10 -6') is more preferable.

[0012] L included in formula (4a) 10 Examples of the hydrocarbon group having 1 to 36 carbon atoms include divalent aliphatic hydrocarbon groups (divalent chain hydrocarbon groups and divalent alicyclic hydrocarbon groups such as alkanediyl groups, alkenediyl groups, and alkynediyl groups), divalent aromatic hydrocarbon groups, and the like, and may be divalent hydrocarbon groups formed by combining two or more of these groups.

[0013] Examples of the alkanediyl group include linear alkanediyl groups such as a methylene group, an ethylene group, a propane-1,3-diyl group, a butane-1,4-diyl group, a pentane-1,5-diyl group, a hexane-1,6-diyl group, a heptane-1,7-diyl group, an octane-1,8-diyl group, a nonane-1,9-diyl group, a decane-1,10-diyl group, an undecane-1,11-diyl group, and a dodecane-1,12-diyl group; Examples of branched alkanediyl groups include ethane-1,1-diyl group, propane-1,1-diyl group, propane-1,2-diyl group, propane-2,2-diyl group, pentane-2,4-diyl group, 2-methylpropane-1,3-diyl group, 2-methylpropane-1,2-diyl group, pentane-1,4-diyl group, and 2-methylbutane-1,4-diyl group. Examples of the alkenediyl group include an ethenediyl group, a propenediyl group, an isopropenediyl group, a butenediyl group, an isobutenediyl group, a tert-butenediyl group, a pentenediyl group, a hexenediyl group, a heptenediyl group, an octenediyl group, an isooctenediyl group, and a nonenediyl group. Examples of the alkynediyl group include an ethynediyl group, a propynediyl group, an isopropynediyl group, a butynediyl group, an isobutynediyl group, a tert-butynediyl group, a pentynediyl group, a hexynediyl group, an octynediyl group, and a nonynediyl group. The chain hydrocarbon group preferably has 1 to 12 carbon atoms, more preferably 1 to 9 carbon atoms, even more preferably 1 to 6 carbon atoms, still more preferably 1 to 4 carbon atoms, and even more preferably 1 to 3 carbon atoms. The divalent alicyclic hydrocarbon group may be any of monocyclic, polycyclic, and spirocyclic. Examples of the divalent alicyclic hydrocarbon group include the groups shown below. The bonding site can be any position. TIFF2025017356000020.tif47167Specific examples of the monocyclic divalent alicyclic hydrocarbon group include monocyclic cycloalkanediyl groups such as cyclobutane-1,3-diyl group, cyclopentane-1,3-diyl group, cyclohexane-1,4-diyl group, cyclohexene-3,6-diyl group, and cyclooctane-1,5-diyl group.Specific examples of the polycyclic divalent alicyclic hydrocarbon group include norbornane-1,4-diyl group, Examples of the cycloalkyl group include norbornane-2,5-diyl group, 5-norbornene-2,3-diyl group, adamantane-1,5-diyl group, adamantane-2,6-diyl group, spirocyclohexane-1,2'-cyclopentane group, and spiroadamantane-2,3'-cyclopentane group; and polycyclic cycloalkanediyl groups such as a spiro ring having a cycloalkyl group bonded to a norbornyl group or an adamantyl group via a spiro bond. The alicyclic hydrocarbon group preferably has 3 to 18 carbon atoms, more preferably 3 to 16 carbon atoms, and further preferably 3 to 12 carbon atoms. Examples of the divalent aromatic hydrocarbon group include a phenylene group, a naphthylene group, an anthrylene group, a biphenylene group, a phenanthrylene group, etc. The aromatic hydrocarbon group preferably has 6 to 18 carbon atoms, more preferably 6 to 14 carbon atoms, and further preferably 6 to 10 carbon atoms. Examples of hydrocarbon groups in which two or more types are combined include groups in which an alkanediyl group is combined with an alicyclic hydrocarbon group and / or an aromatic hydrocarbon group, such as -alicyclic hydrocarbon group-alkanediyl group-, -alkanediyl group-alicyclic hydrocarbon group-, -alkanediyl group-alicyclic hydrocarbon group-alkanediyl group-, -alkanediyl group-aromatic hydrocarbon group-, -aromatic hydrocarbon group-alkanediyl group-, and the like.

[0014] L 10 -CH contained in the hydrocarbon group having 1 to 36 carbon atoms 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. L 10 When the hydrocarbon group having 1 to 36 carbon atoms has a substituent, or when the hydrocarbon group contains -CH2 - is -O-, -S-, -CO- or -SO 2 When it is replaced with -, the number of carbon atoms before the replacement is regarded as the number of carbon atoms of the hydrocarbon group. -CH contained in the hydrocarbon group 2 -, -O-, -S-, -SO 2 The group substituted for - or -CO- is a hydroxy group (-CH 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), thiol group (-CH 2 - is replaced by -S-), alkoxy group (-CH 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), oxy group (-CH 2 - is replaced by -O-), carbonyl group (-CH 2 - is replaced by -CO-), thio group (-CH 2 - is replaced by -S-), sulfonyl group (-CH 2 -But-SO 2 -), alkanediyloxy group (groups in which -CH at any position in the alkanediyl group is replaced by -), 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2- is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 - is replaced by -CO-O-), alkylthio group (-CH 2 - is replaced by -S-), alkylsulfonyl group (-CH 2 -But-SO 2 -), alkanediylthio group (groups in which -CH at any position in the alkanediyl group is replaced with -CH 2 - is replaced by -S-), alkanediylsulfonyl group (-CH at any position contained in the alkanediyl group) 2 -But-SO 2 -substituted), cycloalkoxy groups, cycloalkylalkoxy groups, alkoxycarbonyloxy groups, aromatic hydrocarbon group-carbonyloxy groups, aromatic hydrocarbon group-carbonyl groups, aromatic hydrocarbon group-oxy groups, and combinations of two or more of these groups. Examples of the alkoxy group include alkoxy groups having 1 to 35 carbon atoms, such as a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentyloxy group, a hexyloxy group, an octyloxy group, a 2-ethylhexyloxy group, a nonyloxy group, a decyloxy group, an undecyloxy group, etc. The number of carbon atoms in the alkoxy group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. Examples of the alkoxycarbonyl group include alkoxycarbonyl groups having 2 to 35 carbon atoms, such as methoxycarbonyl, ethoxycarbonyl, and butoxycarbonyl groups. Examples of the alkylcarbonyl group include alkylcarbonyl groups having 2 to 36 carbon atoms, such as acetyl, propionyl, and butyryl groups. Examples of the alkylcarbonyloxy group include alkylcarbonyloxy groups having 2 to 35 carbon atoms, such as acetyloxy, propionyloxy, and butyryloxy groups. The number of carbon atoms in the alkoxycarbonyl group, alkylcarbonyl group, and alkylcarbonyloxy group is preferably 2 to 11, more preferably 2 to 6, even more preferably 2 to 4, and even more preferably 2 to 3. The alkanediyloxy group includes an alkanediyloxy group having 1 to 35 carbon atoms, such as a methyleneoxy group, an ethyleneoxy group, a propanediyloxy group, a butanediyloxy group, a pentanediyloxy group, etc. The number of carbon atoms in the alkanediyloxy group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. Examples of the alkanediyloxycarbonyl group include alkanediyloxycarbonyl groups having 2 to 35 carbon atoms, such as methyleneoxycarbonyl group, ethyleneoxycarbonyl group, propanediyloxycarbonyl group, butanediyloxycarbonyl group, etc. Examples of the alkanediylcarbonyl group include alkanediylcarbonyl groups having 2 to 36 carbon atoms, such as methylenecarbonyl group, ethylenecarbonyl group, propanediylcarbonyl group, butanediylcarbonyl group, pentanediylcarbonyl group, etc. Examples of the alkanediylcarbonyloxy group include alkanediylcarbonyloxy groups having 2 to 35 carbon atoms, such as methylenecarbonyloxy group, ethylenecarbonyloxy group, propanediylcarbonyloxy group, butanediylcarbonyloxy group, etc. The alkanediyloxycarbonyl group, alkanediylcarbonyl group, and alkanediylcarbonyloxy group preferably have 2 to 11 carbon atoms, more preferably 2 to 6 carbon atoms, further preferably 2 to 4 carbon atoms, and even more preferably 2 to 3 carbon atoms. The alkylthio group includes an alkylthio group having 1 to 35 carbon atoms, such as a methylthio group, an ethylthio group, a propylthio group, etc. The number of carbon atoms in the alkylthio group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkylsulfonyl group includes alkylsulfonyl groups having 1 to 35 carbon atoms, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, etc. The number of carbon atoms in the alkylsulfonyl group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkanediylthio group includes an alkanediylthio group having 1 to 35 carbon atoms, such as a methylenethio group, an ethylenethio group, a propylenethio group, etc. The number of carbon atoms in the alkanediylthio group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkanediylsulfonyl group includes an alkanediylsulfonyl group having 1 to 35 carbon atoms, such as a methylenesulfonyl group, an ethylenesulfonyl group, a propylenesulfonyl group, etc. The number of carbon atoms in the alkanediylsulfonyl group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. Examples of the cycloalkoxy group include a cycloalkoxy group having 3 to 35 carbon atoms, such as a cyclohexyloxy group. Examples of the cycloalkylalkoxy group include a cycloalkylalkoxy group having 4 to 35 carbon atoms, such as a cyclohexylmethoxy group. Examples of the alkoxycarbonyloxy group include an alkoxycarbonyloxy group having 2 to 34 carbon atoms, such as a butoxycarbonyloxy group. The number of carbon atoms in the cycloalkoxy group and the cycloalkylalkoxy group is preferably 3 to 11, more preferably 3 to 6. The number of carbon atoms in the alkoxycarbonyloxy group is preferably 2 to 11, more preferably 2 to 6, even more preferably 2 to 4, and even more preferably 2 to 3. Examples of the aromatic hydrocarbon group-carbonyloxy group include an aromatic hydrocarbon group-carbonyloxy group having 7 to 35 carbon atoms, such as a benzoyloxy group. Examples of the aromatic hydrocarbon group-carbonyl group include an aromatic hydrocarbon group-carbonyl group having 7 to 36 carbon atoms, such as a benzoyl group. The aromatic hydrocarbon group-oxy group includes an aromatic hydrocarbon group-oxy group having 6 to 35 carbon atoms, such as a phenyloxy group. In addition, -CH contained in alicyclic hydrocarbon groups 2 - is -O-, -S-, -CO- or -SO 2 Examples of the group substituted with - include the groups shown below. -O- or -CO- in the groups shown below can be replaced with -S- or -SO 2 The binding site may be at any position. TIFF2025017356000021.tif46168

[0015] L 10Examples of the substituent that the hydrocarbon group may have include a halogen atom, a cyano group, a nitro group, and the like. L 10 contains a group in which an alicyclic hydrocarbon group or an aromatic hydrocarbon group is combined with a chain hydrocarbon group, the chain hydrocarbon group bonded to the alicyclic hydrocarbon group or aromatic hydrocarbon group can be regarded as substantially a substituent of the alicyclic hydrocarbon group or aromatic hydrocarbon group. 10 -CH contained in the hydrocarbon group 2 - is replaced by -O- or -CO-, 10 can substantially have a substituent such as a hydroxy group, a carboxy group, an alkoxy group, an alkoxycarbonyl group, an alkylcarbonyl group, or an alkylcarbonyloxy group. Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. L 10 The hydrocarbon group having 1 to 36 carbon atoms may have one or more substituents.

[0016] L 10 represents a single bond, an alkanediyl group having 1 to 6 carbon atoms (provided that the -CH 2 - may be replaced by -O- or -CO-), a cyclic hydrocarbon group having 3 to 18 carbon atoms (however, the cyclic hydrocarbon group may have a substituent, and the -CH 2 -, -O-, -S-, -SO 2 - or -CO- may be substituted.) or a group formed by combining an alkanediyl group having 1 to 6 carbon atoms with a cyclic hydrocarbon group having 3 to 18 carbon atoms (provided that the cyclic hydrocarbon group may have a substituent, and the -CH 2 - may be replaced by -O- or -CO-, and -CH contained in the cyclic hydrocarbon group 2 -, -O-, -S-, -SO 2 - or -CO-) is preferable, and a single bond, an alkanediyl group having 1 to 4 carbon atoms (with the proviso that the -CH 2may be replaced by -O- or -CO-), an alicyclic hydrocarbon group having 3 to 18 carbon atoms (provided that the -CH 2 -, -O-, -S-, -SO 2 - or -CO-), an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent, a group formed by combining an alkanediyl group having 1 to 4 carbon atoms and an alicyclic hydrocarbon group having 3 to 18 carbon atoms (with the proviso that -CH 2 - may be replaced by -O- or -CO-, and -CH contained in the alicyclic hydrocarbon group 2 -, -O-, -S-, -SO 2 - or -CO-) or a group formed by combining an alkanediyl group having 1 to 4 carbon atoms with an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent (with the proviso that the -CH 2 - may be replaced by -O- or -CO-.) is more preferred, and a single bond, an alkanediyl group having 1 to 4 carbon atoms (with the proviso that -CH 2 may be replaced by -O- or -CO-), an alicyclic hydrocarbon group having 3 to 18 carbon atoms (provided that the -CH 2 - may be replaced by -O- or -CO-), a phenylene group which may have a substituent, a group formed by combining an alkanediyl group having 1 to 4 carbon atoms with an alicyclic hydrocarbon group having 3 to 18 carbon atoms (with the proviso that -CH 2 - may be replaced by -O- or -CO-, and -CH contained in the alicyclic hydrocarbon group 2 - may be replaced by -O- or -CO-; or a group formed by combining an alkanediyl group having 1 to 4 carbon atoms with a phenylene group which may have a substituent (provided that the -CH 2 - may be replaced by -O- or -CO-.) is more preferable, and a single bond or an alkanediyl group having 1 to 4 carbon atoms (with the proviso that -CH 2- may be replaced by -O- or -CO-.

[0017] m1A, m1C, and m1D are each independently preferably an integer from 0 to 4, more preferably an integer from 0 to 3, even more preferably an integer from 1 to 3, even more preferably 1 or 2, and even more preferably 1. m1B is preferably an integer of 0 to 3, more preferably an integer of 0 to 2, even more preferably 0 or 1, and even more preferably 0. R 1A The bonding position of to the benzene ring is X + The position may be any of o-position, m-position, and p-position with respect to the bonding position of the benzene ring to which X is bonded. + At least one of them is preferably bonded to the o-position or p-position with respect to the bonding position of the benzene ring to which is bonded. R 1C and R 1D The bonding position of to the benzene ring is X + The bonding position of X may be either o-position, m-position or p-position. + It is preferable that at least one of the bonding positions is bonded to the o-position or p-position. R 1B The bonding position of to the benzene ring is X + The bonding position of X may be either o-position, m-position or p-position. + It is preferable that at least one of the bonding positions is bonded to the o-position or m-position.

[0018] R 4 , R 7 , R 8 and R 9 Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. R 4 , R 7 , R 8 and R 9Examples of the hydrocarbon group having 1 to 36 carbon atoms include chain hydrocarbon groups such as alkyl groups and alkanediyl groups, alicyclic hydrocarbon groups, aromatic hydrocarbon groups, and groups formed by combining these. The number of carbon atoms in the hydrocarbon group is preferably 1 to 30, more preferably 1 to 24, and even more preferably 1 to 18. The alkyl group is a straight-chain or branched alkyl group, and examples thereof include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, a 2-ethylhexyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, and a dodecyl group. The alkanediyl group is a linear or branched alkanediyl group, such as a methylene group, an ethylene group, a propane-1,3-diyl group, a butane-1,4-diyl group, a pentane-1,5-diyl group, or a hexane-1,6-diyl group; and Examples of branched alkanediyl groups include ethane-1,1-diyl group, propane-1,1-diyl group, propane-1,2-diyl group, propane-2,2-diyl group, pentane-2,4-diyl group, 2-methylpropane-1,3-diyl group, 2-methylpropane-1,2-diyl group, pentane-1,4-diyl group, and 2-methylbutane-1,4-diyl group. The chain hydrocarbon group has preferably 1 to 18 carbon atoms, more preferably 1 to 12, even more preferably 1 to 9, still more preferably 1 to 6, even more preferably 1 to 4, and even more preferably 1 to 3. The alicyclic hydrocarbon group may be either monocyclic or polycyclic, and examples thereof include the groups shown below. The bonding site may be any position. TIFF2025017356000022.tif46168Specifically, the monocyclic alicyclic hydrocarbon group includes monocyclic cycloalkyl groups such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl, and cyclododecyl. The polycyclic alicyclic hydrocarbon group includes polycyclic cycloalkyl groups such as decahydronaphthyl, adamantyl, and norbornyl, cycloalkyl groups such as spirocyclohexane-1,2'-cyclopentane, and spiroadamantane-2,3'-cyclopentane, and spiro rings having cycloalkyl groups bonded to norbornyl or adamantyl groups by spiro. The number of carbon atoms in the alicyclic hydrocarbon group is preferably 3 to 18, more preferably 3 to 16, and even more preferably 3 to 12. Examples of the aromatic hydrocarbon group include a phenyl group, a naphthyl group, a biphenyl group, an anthryl group, a phenanthryl group, a binaphthyl group, etc. The number of carbon atoms in the aromatic hydrocarbon group is preferably 6 to 18, more preferably 6 to 14, and further preferably 6 to 10.

[0019] Among chain hydrocarbon groups, alicyclic hydrocarbon groups, and aromatic hydrocarbon groups, groups formed by combining two or more of these groups include groups formed by combining an aromatic hydrocarbon group with a chain hydrocarbon group (for example, an aromatic hydrocarbon group-alkanediyl group-*, an alkyl group-aromatic hydrocarbon group-*, an alkyl group-aromatic hydrocarbon group-alkanediyl group-*, the -CH 2 - is -O-, -CO-, -S- or -SO 2 -), a group combining an alicyclic hydrocarbon group and a chain hydrocarbon group (for example, an alicyclic hydrocarbon group-alkanediyl group-*, an alkyl group-alicyclic hydrocarbon group-*, an alkyl group-alicyclic hydrocarbon group-alkanediyl group-*, -CH contained in the alicyclic hydrocarbon group, the alkanediyl group, and the alkyl group 2 - is -O-, -CO-, -S- or -SO 2-), a group in which an aromatic hydrocarbon group and an alicyclic hydrocarbon group are combined (for example, an aromatic hydrocarbon group-alicyclic hydrocarbon group-*, an alicyclic hydrocarbon group-aromatic hydrocarbon group-*, -CH 2 - is -O-, -CO-, -S- or -SO 2 - may be substituted. * represents a binding site. The aromatic hydrocarbon group -alkanediyl group-* includes aralkyl groups such as benzyl group and phenethyl group. Examples of the alkyl group-aromatic hydrocarbon group-* include a tolyl group, a xylyl group, and a cumenyl group. Examples of the alicyclic hydrocarbon group -alkanediyl group-* include cycloalkylalkyl groups such as a cyclohexylmethyl group, a cyclohexylethyl group, a 1-(adamantan-1-yl)methyl group, and a 1-(adamantan-1-yl)-1-methylethyl group. Examples of the alkyl group-alicyclic hydrocarbon group-* include cycloalkyl groups having an alkyl group such as a methylcyclohexyl group, a dimethylcyclohexyl group, and a 2-alkyladamantan-2-yl group. Examples of the aromatic hydrocarbon group-alicyclic hydrocarbon group-* include a phenylcyclohexyl group. Examples of the alicyclic hydrocarbon group-aromatic hydrocarbon group-* include a cyclohexylphenyl group. In addition, in the combination, two or more types of alicyclic hydrocarbon groups, aromatic hydrocarbon groups, and chain hydrocarbon groups may be combined, and any of the groups may be bonded to a benzene ring.

[0020] R 4 , R 7 , R 8 and R 9 The -CH 2 - is -O-, -CO-, -S-, -SO- or -SO 2 When it is replaced with -, the number of carbon atoms before the replacement is regarded as the total number of carbon atoms in the hydrocarbon group. In addition, the number may be 1 or 2 or more. -CH contained in the hydrocarbon group2 - is -O-, -CO-, -S-, -SO- or -SO 2 The group substituted for - is a hydroxy group (-CH 2 - is replaced by -O-), thiol group (-CH 2 - is replaced by -S-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), alkoxy group (-CH 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), alkylthio group (-CH 2 - is replaced by -S-), alkylsulfur group (-CH at any position in the alkyl group) 2 - is replaced by -SO-), alkylsulfonyl group (-CH 2 -But-SO 2 - substituted), oxy group (-CH contained in methylene group 2 - is replaced by -O-), carbonyl group (-CH 2 - is replaced by -CO-), thio group (-CH 2 - is replaced by -S-), sulfyl group (-CH 2 - is replaced by -SO-), sulfonyl group (-CH 2 -But-SO 2 -), alkanediyloxy group (groups in which -CH at any position in the alkanediyl group is replaced by -),2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 - is replaced by -CO-O-), alkanediylthio group (-CH at any position in the alkanediyl group) 2 - is replaced by -S-), alkanediylsulfyl group (-CH at any position contained in the alkanediyl group) 2 - is replaced by -SO-), alkanediylsulfonyl group (-CH at any position contained in the alkanediyl group) 2 -But-SO 2 -substituted), cycloalkoxy groups, cycloalkylalkoxy groups, alkoxycarbonyloxy groups, aromatic hydrocarbon group-carbonyloxy groups, aromatic hydrocarbon group-carbonyl groups, aromatic hydrocarbon group-oxy groups, and combinations of two or more of these groups. Examples of the alkoxy group include alkoxy groups having 1 to 35 carbon atoms, such as a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentyloxy group, a hexyloxy group, an octyloxy group, a 2-ethylhexyloxy group, a nonyloxy group, a decyloxy group, an undecyloxy group, etc. The number of carbon atoms in the alkoxy group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkoxycarbonyl group, alkylcarbonyl group and alkylcarbonyloxy group represent groups in which a carbonyl group or a carbonyloxy group is bonded to the above-mentioned alkyl group or alkoxy group. Examples of the alkoxycarbonyl group include an alkoxycarbonyl group having 2 to 35 carbon atoms, such as a methoxycarbonyl group, an ethoxycarbonyl group, and a butoxycarbonyl group. Examples of the alkylcarbonyl group include an alkylcarbonyl group having 2 to 36 carbon atoms, such as an acetyl group, a propionyl group, and a butyryl group. Examples of the alkylcarbonyloxy group include an alkylcarbonyloxy group having 2 to 35 carbon atoms, such as an acetyloxy group, a propionyloxy group, and a butyryloxy group. The number of carbon atoms in the alkoxycarbonyl group is preferably 2 to 11, more preferably 2 to 6, even more preferably 2 to 4, and even more preferably 2 or 3. The number of carbon atoms in the alkylcarbonyl group is preferably 2 to 12, more preferably 2 to 6, even more preferably 2 to 4, and even more preferably 2 or 3. The alkylcarbonyloxy group preferably has 2 to 11 carbon atoms, more preferably 2 to 6 carbon atoms, further preferably 2 to 4 carbon atoms, and even more preferably 2 or 3 carbon atoms. The alkylthio group includes an alkylthio group having 1 to 35 carbon atoms, such as a methylthio group, an ethylthio group, a propylthio group, a butylthio group, a pentylthio group, a hexylthio group, an octylthio group, a 2-ethylhexylthio group, a nonylthio group, a decylthio group, an undecylthio group, etc. The number of carbon atoms in the alkylthio group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkylsulfyl group includes alkylsulfyl groups having 1 to 35 carbon atoms, such as methylsulfyl group, ethylsulfyl group, propylsulfyl group, butylsulfyl group, pentylsulfyl group, hexylsulfyl group, octylsulfyl group, 2-ethylhexylsulfyl group, nonylsulfyl group, decylsulfyl group, undecylsulfyl group, etc. The number of carbon atoms in the alkylsulfyl group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. Examples of the alkylsulfonyl group include alkylsulfonyl groups having 1 to 35 carbon atoms, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, a butylsulfonyl group, a pentylsulfonyl group, a hexylsulfonyl group, an octylsulfonyl group, a 2-ethylhexylsulfonyl group, a nonylsulfonyl group, a decylsulfonyl group, an undecylsulfonyl group, etc. The number of carbon atoms in the alkylsulfonyl group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkanediyloxy group includes an alkanediyloxy group having 1 to 35 carbon atoms, such as a methyleneoxy group, an ethyleneoxy group, a propanediyloxy group, a butanediyloxy group, a pentanediyloxy group, etc. The number of carbon atoms in the alkanediyloxy group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. Examples of the alkanediyloxycarbonyl group include alkanediyloxycarbonyl groups having 2 to 35 carbon atoms, such as methyleneoxycarbonyl group, ethyleneoxycarbonyl group, propanediyloxycarbonyl group, butanediyloxycarbonyl group, etc. Examples of the alkanediylcarbonyl group include alkanediylcarbonyl groups having 2 to 36 carbon atoms, such as methylenecarbonyl group, ethylenecarbonyl group, propanediylcarbonyl group, butanediylcarbonyl group, pentanediylcarbonyl group, etc. Examples of the alkanediylcarbonyloxy group include alkanediylcarbonyloxy groups having 2 to 35 carbon atoms, such as methylenecarbonyloxy group, ethylenecarbonyloxy group, propanediylcarbonyloxy group, butanediylcarbonyloxy group, etc. The number of carbon atoms in the alkanediyloxycarbonyl group is preferably 2 to 11, more preferably 2 to 6, still more preferably 2 to 4, and even more preferably 2 or 3. The number of carbon atoms in the alkanediylcarbonyl group is preferably 2 to 12, more preferably 2 to 6, still more preferably 2 to 4, and even more preferably 2 or 3. The number of carbon atoms in the alkanediylcarbonyloxy group is preferably 2 to 11, more preferably 2 to 6, still more preferably 2 to 4, and even more preferably 2 or 3. The alkanediylthio group includes an alkanediylthio group having 1 to 35 carbon atoms, such as a methylenethio group, an ethylenethio group, a propylenethio group, etc. The number of carbon atoms in the alkanediylthio group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkanediylsulfyl group includes an alkanediylsulfyl group having 1 to 35 carbon atoms, such as a methylenesulfyl group, an ethylenesulfyl group, a propylenesulfyl group, etc. The number of carbon atoms in the alkanediylsulfyl group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkanediylsulfonyl group includes an alkanediylsulfonyl group having 1 to 35 carbon atoms, such as a methylenesulfonyl group, an ethylenesulfonyl group, a propylenesulfonyl group, etc. The number of carbon atoms in the alkanediylsulfonyl group is preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. Examples of the cycloalkoxy group include a cycloalkoxy group having 3 to 35 carbon atoms, such as a cyclohexyloxy group. Examples of the cycloalkylalkoxy group include a cycloalkylalkoxy group having 4 to 35 carbon atoms, such as a cyclohexylmethoxy group. Examples of the alkoxycarbonyloxy group include an alkoxycarbonyloxy group having 2 to 34 carbon atoms, such as a butoxycarbonyloxy group. Examples of the aromatic hydrocarbon group-carbonyloxy group include an aromatic hydrocarbon group-carbonyloxy group having 7 to 36 carbon atoms, such as a benzoyloxy group. Examples of the aromatic hydrocarbon group-carbonyl group include an aromatic hydrocarbon group-carbonyl group having 7 to 36 carbon atoms, such as a benzoyl group. Examples of the aromatic hydrocarbon group-oxy group include an aromatic hydrocarbon group-oxy group having 6 to 35 carbon atoms, such as a phenyloxy group.

[0021] In addition, -CH contained in alicyclic hydrocarbon groups 2 -, -O-, -S-, -SO 2 Examples of the group replaced with - or -CO- include the groups shown below. In addition, among the groups shown below, when -O- is -S-, and -CO- is -SO- or -SO 2 Also included are groups each replaced with -. The binding site may be at any position. TIFF2025017356000023.tif46168

[0022] R 4 , R 7 , R 8 and R 9Examples of the substituent that the hydrocarbon group may have include a halogen atom, a cyano group, a nitro group, and the like. Examples of the halogen atom include the same groups as those mentioned above. R 4 , R 7 , R 8 and R 9 When R is a hydrocarbon group having a halogen atom, 4 , R 7 , R 8 and R 9 Examples of the hydrocarbon group having a halogen atom include a chain hydrocarbon group having a halogen atom (such as a haloalkyl group), an alicyclic hydrocarbon group having a halogen atom, and an aromatic hydrocarbon group having a halogen atom. Examples of the alkyl group having a halogen include haloalkyl groups having 1 to 12 carbon atoms, such as fluorinated alkyl groups having 1 to 12 carbon atoms, chlorinated alkyl groups having 1 to 12 carbon atoms, brominated alkyl groups having 1 to 12 carbon atoms, and iodinated alkyl groups having 1 to 12 carbon atoms. Examples of the haloalkyl groups include perfluoroalkyl groups having 1 to 12 carbon atoms (trifluoromethyl group, pentafluoroethyl group, heptafluoropropyl group, nonafluorobutyl group, etc.), 2,2,2-trifluoroethyl group, 3,3,3-trifluoropropyl group, 4,4,4-trifluorobutyl group, 3,3,4,4,4-pentafluorobutyl group, chloromethyl group, bromomethyl group, and iodomethyl group. The number of carbon atoms in the haloalkyl group is preferably 1 to 9, more preferably 1 to 6, even more preferably 1 to 4, and even more preferably 1 to 3. Haloalkyl group contains -CH 2 - may be replaced by -O- or -CO-, etc., and examples thereof include a haloalkoxy group, a haloalkoxycarbonyl group, a haloalkylcarbonyl group, a haloalkylcarbonyloxy group, etc. Specific examples thereof include a haloalkoxy group having 1 to 11 carbon atoms, a haloalkoxycarbonyl group having 2 to 11 carbon atoms, a haloalkylcarbonyl group having 2 to 12 carbon atoms, a haloalkylcarbonyloxy group having 2 to 11 carbon atoms, etc., and examples thereof include groups in which one or more hydrogen atoms of the above-exemplified groups are replaced with halogen atoms. The hydrocarbon group may have one substituent or multiple substituents. R 4 is a halogen atom or an alkyl group having 1 to 12 carbon atoms which may have a halogen atom (-CH contained in the alkyl group) 2 - may be replaced by -O- or -CO-.) is preferably a halogen atom, a fluorinated alkyl group having 1 to 6 carbon atoms, or an alkyl group having 1 to 6 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-.) is more preferred, and a halogen atom, a fluorinated alkyl group having 1 to 4 carbon atoms or an alkyl group having 1 to 4 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-), and a fluorine atom, a bromine atom, an iodine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or an alkyl group having 1 to 4 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-.) is more preferable, and a fluorine atom, an iodine atom, a trifluoromethyl group, a hydroxy group, a methoxy group, a methyl group or a t-butyl group is even more preferable. R 7 , R 8 and R 9 each independently represents a halogen atom or an alkyl group having 1 to 12 carbon atoms which may have a halogen atom (-CH 2 - may be replaced by -O- or -CO-.) is preferably a halogen atom, a fluorinated alkyl group having 1 to 6 carbon atoms, or an alkyl group having 1 to 6 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-.) is more preferred, and a halogen atom, a fluorinated alkyl group having 1 to 4 carbon atoms or an alkyl group having 1 to 4 carbon atoms (the -CH 2- may be replaced by -O- or -CO-), and a fluorine atom, a bromine atom, an iodine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or an alkyl group having 1 to 4 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-.) is more preferable, and a fluorine atom, an iodine atom, a trifluoromethyl group, a hydroxy group, a methoxy group, a methyl group or a t-butyl group is even more preferable.

[0023] m4 is preferably 0, 1, 2, 3 or 4, more preferably 0, 1, 2 or 3, and even more preferably 0, 1 or 2. R 4 The bonding position of to the benzene ring is X + may be at the о-position, m-position, or p-position relative to the bonding position of the benzene ring to which m4 is bonded. When m4 is 1 or 2, at least one R 4 X + is preferably bonded to the p-position or m-position with respect to the bonding position of the benzene ring to which R is bonded. 4 X + is preferably bonded to the o-position or m-position with respect to the bonding position of the benzene ring to which it is bonded. R 1A and R 4 The bonding position of the benzene ring to which X can be bonded is + In the benzene ring to which X is attached, + The bonding position of R may be either o-position, m-position or p-position. 1A and R 4 The benzene ring to which X can be attached is + It is preferably bonded to the p-position or m-position, and more preferably bonded to the p-position, relative to the bonding position of the above. m7 is preferably 0, 1, 2 or 3, more preferably 0, 1 or 2, and even more preferably 0 or 1. R 7 The bonding position of to the benzene ring is X +The bonding position of R may be any of o-position, m-position, or p-position. 7 But X + It is preferably bonded to the o-position or m-position, and more preferably bonded to the m-position, with respect to the bonding position of the above. m8 is preferably 0, 1, 2, 3 or 4, more preferably 0, 1, 2 or 3, even more preferably 0, 1 or 2, and even more preferably 0 or 1. m9 is preferably 0, 1, 2, 3 or 4, more preferably 0, 1, 2 or 3, even more preferably 0, 1 or 2, and even more preferably 0 or 1. When at least one of m8 and m9 is an integer of 1 or more, R 8 and / or R 9 The bonding position of to the benzene ring is X + The bonding position of R may be any of o-position, m-position, or p-position. 8 and / or R 9 But X + It is preferably bonded to the m-position or p-position, and more preferably bonded to the p-position, relative to the bonding position of the above.

[0024] Specific examples of the cation represented by formula (IC) include cations represented by formula (IC-1) or formula (IC-2) (hereinafter, these may be referred to as "cation (IC-1)" and "cation (IC-2)", respectively). TIFF2025017356000024.tif48147 [wherein all symbols have the same meanings as defined above.] When X is a sulfur atom and m10=1, R 7 and R 8 or R 8 and R 9 Combined, S + In particular, R 8 and R 9 Combined, S + It is preferable that the cation is a cation represented by the formula (IC'). TIFF2025017356000025.tif5295[where, X 7 The symbols other than the above have the same meanings as above. X 7 is a single bond, -CH 2 -, -O-, -CO-, -SO-, -SO 2 - or -S-.] X 7 is a single bond, -CH 2 - or -O- is preferred.

[0025] Examples of the cation of the salt (I) include the cations represented by the following formulae (Ic-1) to (Ic-52). JPEG2025017356000026.jpg124168

[0026] TIFF2025017356000027.tif254159

[0027] TIFF2025017356000028.tif230165

[0028] TIFF2025017356000029.tif123166

[0029] [Anion (I)] In formula (I), X 0 Examples of the hydrocarbon group represented by the formula include aliphatic hydrocarbon groups (chain hydrocarbon groups such as alkyl groups, alkenyl groups, and alkynyl groups, and alicyclic hydrocarbon groups), aromatic hydrocarbon groups, and combinations of these groups. 2 - is -O-, -S-, -CO- or -SO 2 In the hydrocarbon group, CO 2 - The atom adjacent to is preferably a carbon atom, and in the aliphatic hydrocarbon group, 2 -The number of carbon atoms in the hydrocarbon group may be 2 to 48, preferably 2 to 36, more preferably 2 to 30, even more preferably 2 to 24, still more preferably 2 to 18, and even more preferably 2 to 12. The alkyl group may be a linear or branched alkyl group, such as an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a tert-butyl group, a pentyl group, a hexyl group, an octyl group, a nonyl group, etc. The number of carbon atoms in the alkyl group is preferably 2 to 18, more preferably 2 to 12, still more preferably 2 to 9, still more preferably 2 to 6, and still more preferably 2 to 4. Examples of the alkenyl group include ethenyl, propenyl, isopropenyl, butenyl, isobutenyl, tert-butenyl, pentenyl, hexenyl, heptenyl, octenyl, isooctenyl, and nonenyl groups. Examples of the alkynyl group include an ethynyl group, a propynyl group, an isopropynyl group, a butynyl group, an isobutynyl group, a tert-butynyl group, a pentynyl group, a hexynyl group, an octynyl group, and a nonynyl group. The chain hydrocarbon group preferably has 2 to 18 carbon atoms, more preferably 2 to 12 carbon atoms, even more preferably 2 to 9 carbon atoms, still more preferably 2 to 6 carbon atoms, and even more preferably 2 to 4 carbon atoms. -CH contained in chain hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 The group substituted for - is a hydroxy group (-CH 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), thiol group (-CH 2 - is replaced by -S-), carbonyl group (-CH 2 - is replaced by -CO-), thio group (-CH 2- is replaced by -S-), sulfonyl group (-CH 2 -But-SO 2 - substituted), oxy group (-CH contained in methylene group 2 - is replaced by -O-), alkoxy group (-CH 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), alkylthio group (-CH 2 - is replaced by -S-), alkylsulfonyl group (-CH 2 -But-SO 2 -), alkanediyloxy group (groups in which -CH at any position in the alkanediyl group is replaced by -), 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 - is replaced by -CO-O-), alkanediylsulfonyl group (-CH at any position contained in the alkanediyl group) 2 -But-SO 2 -), alkanediylthio group (groups in which -CH at any position in the alkanediyl group is replaced with -CH 2 - is replaced with -S-. Examples of the alkoxy group include alkoxy groups having 1 to 71 carbon atoms, such as a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentyloxy group, a hexyloxy group, an octyloxy group, a 2-ethylhexyloxy group, a nonyloxy group, a decyloxy group, an undecyloxy group, a phenyloxy group, etc. The number of carbon atoms in the alkoxy group is, for example, 1 to 36, and may be 1 to 17, preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and even more preferably 1 to 3. Examples of the alkoxycarbonyl group include alkoxycarbonyl groups having 2 to 71 carbon atoms, such as a methoxycarbonyl group, an ethoxycarbonyl group, and a butoxycarbonyl group. Examples of the alkylcarbonyl group include alkylcarbonyl groups having 2 to 72 carbon atoms, such as an acetyl group, a propionyl group, and a butyryl group. Examples of the alkylcarbonyloxy group include alkylcarbonyloxy groups having 2 to 71 carbon atoms, such as an acetyloxy group, a propionyloxy group, and a butyryloxy group. The number of carbon atoms in the alkoxycarbonyl group, the alkylcarbonyl group, and the alkylcarbonyloxy group is, for example, 2 to 36, and may be 2 to 17, preferably 2 to 11, more preferably 2 to 6, further preferably 2 to 4, and even more preferably 2 to 3. The alkylthio group includes an alkylthio group having 1 to 71 carbon atoms, such as a methylthio group, an ethylthio group, a propylthio group, etc. The number of carbon atoms in the alkylthio group is, for example, 1 to 36, and may be 1 to 17, preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and even more preferably 1 to 3. The alkylsulfonyl group includes alkylsulfonyl groups having 1 to 71 carbon atoms, such as a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, etc. The number of carbon atoms in the alkylsulfonyl group is, for example, 1 to 36, and may be 1 to 17, preferably 1 to 11, more preferably 1 to 6, further preferably 1 to 4, and even more preferably 1 to 3. Examples of the alkanediyloxy group, the alkanediyloxycarbonyl group, the alkanediylcarbonyl group, the alkanediylcarbonyloxy group, the alkanediylsulfonyl group, and the alkanediylthio group include an alkoxy group, an alkoxycarbonyl group, an alkylcarbonyl group, an alkylcarbonyloxy group, an alkylthio group, and an alkylsulfonyl group in which one hydrogen atom at any position is replaced with a bonding site. The substitution in the alkenyl group or alkynyl group may be any of the substitutions in the alkyl group exemplified above that include a carbon-carbon double bond or a carbon-carbon triple bond at any position.

[0030] The alicyclic hydrocarbon group may be any of monocyclic, polycyclic and spiro rings, and may be any of saturated and unsaturated. Examples of the alicyclic hydrocarbon group include monocyclic cycloalkyl groups such as cyclopropyl group, cyclobutyl group, cyclopentyl group, cyclohexyl group, cyclooctyl group, cyclononyl group, cyclodecyl group, cyclododecyl group, etc., polycyclic cycloalkyl groups such as norbornyl group, adamantyl group, etc., and spiro rings having a cycloalkyl group bonded to a cycloalkyl group, norbornyl group or adamantyl group via a spiro bond. Examples of the alicyclic hydrocarbon group include the following groups: The bonding site may be any position. TIFF2025017356000030.tif58166 The alicyclic hydrocarbon group preferably has 3 to 36 carbon atoms, more preferably 3 to 24 carbon atoms, even more preferably 3 to 18 carbon atoms, still more preferably 3 to 16 carbon atoms, and even more preferably 3 to 12 carbon atoms. -CH contained in alicyclic hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 The group substituted with - may form an ether ring, a ketone ring, a lactone ring, a sultone ring or an acetal ring, and specific examples thereof include the following groups: The bonding site may be at any position. TIFF2025017356000031.tif82167The alicyclic hydrocarbon group is preferably a group represented by any one of formulas (y1) to (y11), (y44) to (y48), and (y59) to (y61), and more preferably a group represented by formula (y3), (y4), (y9), or (y11). -CH contained in alicyclic hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 The group substituted with - is preferably a group represented by any one of formulas (y12) to (y20), (y26), (y27), (y30), (y31), (y39) to (y43), and (y49) to (y71), and more preferably a group represented by any one of formulas (y14), (y15), (y16), (y20), (y26), (y27), (y30), (y31), (y39), (y40), (y42), (y43), (y49) to (y58), and (y62) to (y71).

[0031] Examples of the aromatic hydrocarbon group include aryl groups such as a phenyl group, a naphthyl group, a biphenyl group, an anthryl group, a phenanthryl group, a binaphthyl group, etc. The number of carbon atoms in the aromatic hydrocarbon group is preferably 6 to 36, more preferably 6 to 24, still more preferably 6 to 18, still more preferably 6 to 14, and still more preferably 6 to 10. In the case of a combined group, the above groups may contain groups having different valences (such as an alkanediyl group, an alkanetriyl group, an alkanetetrayl group, a cycloalkanediyl group, a cycloalkanetriyl group, or a cycloalkanetetrayl group).

[0032] The combined groups are: A group that combines an alicyclic hydrocarbon group with a chain hydrocarbon group (the -CH contained in the chain hydrocarbon group and the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 -), A group combining a chain hydrocarbon group and an aromatic hydrocarbon group (the -CH2 - is -O-, -S-, -CO- or -SO 2 -), and A group that combines an alicyclic hydrocarbon group with an aromatic hydrocarbon group (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - (which may be replaced by ). In addition, in the combination, two or more types of each of the alicyclic hydrocarbon groups, the chain hydrocarbon groups and the aromatic hydrocarbon groups may be combined. Specifically, the combined groups are Alicyclic hydrocarbon groups such as adamantylmethylene group, cyclohexylmethylene group, etc. - Chain hydrocarbon groups -* (alicyclic hydrocarbon groups) 2 - Acyclic hydrocarbon group -* (-CH contained in the acyclic hydrocarbon group and the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 -), Methyladamantyl group, dimethyladamantyl group, and other chain hydrocarbon groups - Alicyclic hydrocarbon groups - * (chain hydrocarbon groups) 2 -Alicyclic hydrocarbon group-* (-CH contained in the chain hydrocarbon group and the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 -), Aromatic hydrocarbon groups such as tolyl and xylyl groups - (-CH 2 - is -O-, -S-, -CO- or -SO 2 -), Methylcyclohexylmethylene group and other chain hydrocarbon groups - Alicyclic hydrocarbon groups - Chain hydrocarbon groups -* (chain hydrocarbon groups) 2 -Alicyclic hydrocarbon group-open chain hydrocarbon group-*, (open chain hydrocarbon group-alicyclic hydrocarbon group) 2 - Acyclic hydrocarbon group -* (-CH contained in the acyclic hydrocarbon group and the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 -), Aromatic hydrocarbon groups such as benzyl groups - Chain hydrocarbon groups -* (-CH contained in the chain hydrocarbon groups) 2 - is -O-, -S-, -CO- or -SO 2 -), Aromatic hydrocarbon groups such as tolylmethyl groups - Aromatic hydrocarbon groups - Aromatic hydrocarbon groups - Aromatic hydrocarbon groups -* (-CH contained in the aromatic hydrocarbon groups) 2 - is -O-, -S-, -CO- or -SO 2 -), Methyladamantane methylene adamantyl group, di(methyladamantane methylene) adamantyl group, etc. Chain hydrocarbon group-alicyclic hydrocarbon group-chain hydrocarbon group-alicyclic hydrocarbon group-*, (chain hydrocarbon group-alicyclic hydrocarbon group-chain hydrocarbon group) 2 -Alicyclic hydrocarbon group-*, (chain hydrocarbon group-alicyclic hydrocarbon group) 2 -Open chain hydrocarbon group-Alicyclic hydrocarbon group-*, (Open chain hydrocarbon group) 2 -Alicyclic hydrocarbon group-Open chain hydrocarbon group-Alicyclic hydrocarbon group-* (-CH contained in the open chain hydrocarbon group and the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 -), Alicyclic hydrocarbon group-Acyclic hydrocarbon group-Acyclic hydrocarbon group-Acyclic hydrocarbon group-*, (Alicyclic hydrocarbon group) 2 -Open chain hydrocarbon group-alicyclic hydrocarbon group-open chain hydrocarbon group-*, (alicyclic hydrocarbon group-open chain hydrocarbon group) 2 -Alicyclic hydrocarbon group-open chain hydrocarbon group-*, (alicyclic hydrocarbon group-open chain hydrocarbon group-alicyclic hydrocarbon group) 2 - Acyclic hydrocarbon group -* (-CH contained in the acyclic hydrocarbon group and the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 -), Acyclic hydrocarbon group-alicyclic hydrocarbon group-acyclic hydrocarbon group-acyclic hydrocarbon group-acyclic hydrocarbon group-*, (acyclic hydrocarbon group) 2 -Alicyclic hydrocarbon group-Open chain hydrocarbon group-Alicyclic hydrocarbon group-Open chain hydrocarbon group-*, (Open chain hydrocarbon group-Alicyclic hydrocarbon group)2 -Open chain hydrocarbon group-alicyclic hydrocarbon group-open chain hydrocarbon group-*, (open chain hydrocarbon group-alicyclic hydrocarbon group-open chain hydrocarbon group) 2 -Alicyclic hydrocarbon group-Open chain hydrocarbon group-*, (Open chain hydrocarbon group-Alicyclic hydrocarbon group-Open chain hydrocarbon group-Alicyclic hydrocarbon group) 2 - Acyclic hydrocarbon group -* (-CH contained in the acyclic hydrocarbon group and the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 -), Here, * represents the bonding site with the carbon atom of the carbonyl group.

[0033] X 0 The -CH 2 - is -O-, -S-, -CO- or -SO 2 When X is replaced with -, the number of carbon atoms before the replacement is the total number of carbon atoms in the hydrocarbon group. 0 When a substituent is bonded to a hydrocarbon group represented by the following formula (I), the number of carbon atoms before substitution is regarded as the total number of carbon atoms in the hydrocarbon group. X 0 The hydrocarbon group represented by the following formula may have one or more substituents. Examples of the substituent include a hydroxy group, a halogen atom, a cyano group, and a nitro group. 0 is a group in which an alicyclic hydrocarbon group or an aromatic hydrocarbon group is combined with a chain hydrocarbon group, the chain hydrocarbon group may be regarded as substantially a substituent possessed by the alicyclic hydrocarbon group or the aromatic hydrocarbon group. 0 The -CH chain hydrocarbon group contained in the hydrocarbon group 2 - is -O-, -CO-, -S- or -SO 2 By replacing with -, the hydrocarbon group can substantially have a substituent such as a hydroxy group, a carboxy group, an alkoxy group, an alkylcarbonyl group, an alkoxycarbonyl group, an alkylcarbonyloxy group, a thiol group, or a sulfonyl group. Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.

[0034] X 0 The hydrocarbon group represented by the formula (I) is preferably an aliphatic hydrocarbon group having 2 to 72 carbon atoms which may have a substituent (-CH 2 - is -O-, -S-, -CO- or -SO 2 -), a hydrocarbon group having 6 to 72 carbon atoms including an aromatic hydrocarbon group having 6 to 36 carbon atoms which may have a substituent, a group represented by formula (aa) or a group represented by formula (bb), More preferably, it is an alicyclic hydrocarbon group which may have a halogen atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxyl group (the —CH 2 - is -O-, -S-, -CO- or -SO 2 -), a group consisting of a combination of an alicyclic hydrocarbon group and a chain hydrocarbon group (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by -, and -CH 2 - may be replaced by -O- or -CO-, and the alicyclic hydrocarbon group and the chain hydrocarbon group may have a halogen atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group.), an aromatic hydrocarbon group which may have a halogen atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group, a group in which an aromatic hydrocarbon group and a chain hydrocarbon group are combined (the -CH contained in the chain hydrocarbon group 2 - may be replaced by -O- or -CO-, and the aromatic hydrocarbon group and the chain hydrocarbon group may have a halogen atom, a perfluoroalkyl group having 1 to 4 carbon atoms or a hydroxy group.), a group represented by formula (aa) or a group represented by formula (bb), More preferably, *-alicyclic hydrocarbon group (-CH contained in the alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 The alicyclic hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group. -represents the bonding site with the carbon atom of the alicyclic hydrocarbon group. 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by -, and -CH 2 - may be replaced by -O- or -CO-, and the alicyclic hydrocarbon group and the chain hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group. * is -COO - ), *-chain hydrocarbon group-alicyclic hydrocarbon group (-CH 2 - may be replaced by -O- or -CO-, and -CH contained in the alicyclic hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 The chain hydrocarbon group and the alicyclic hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group. - represents a bonding site with a carbon atom of the formula (I), *-aromatic hydrocarbon group (the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxyl group. * represents -COO - )*-aromatic hydrocarbon group-chain hydrocarbon group (-CH 2 - may be replaced by -O- or -CO-, the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a perfluoroalkyl group having 1 to 4 carbon atoms or a hydroxyl group, and the chain hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms or a hydroxyl group. * is -COO - ), *-chain hydrocarbon group-aromatic hydrocarbon group (the -CH 2- may be replaced by -O- or -CO-, the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a perfluoroalkyl group having 1 to 4 carbon atoms or a hydroxyl group, and the chain hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms or a hydroxyl group. * is -COO - represents a bonding site with a carbon atom of More preferably, the polycyclic alicyclic hydrocarbon group (the -CH contained in the polycyclic alicyclic hydrocarbon group) 2 - is -O-, -S-, -CO- or -SO 2 The polycyclic alicyclic hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group. - represents the bonding site with the carbon atom of the 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by -, and -CH 2 - may be replaced by -O- or -CO-, and the polycyclic alicyclic hydrocarbon group and the chain hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group. * is -COO - ), *-chain hydrocarbon group-polycyclic alicyclic hydrocarbon group (-CH 2 - may be replaced by -O- or -CO-, and -CH contained in the polycyclic alicyclic hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 The chain hydrocarbon group and the polycyclic alicyclic hydrocarbon group may have a fluorine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group. - represents a bonding site with a carbon atom of the formula (I), *-aromatic hydrocarbon group (the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxyl group. * represents -COO- represents a bonding site with a carbon atom of Particularly preferred are an adamantyl group, an adamantanone group, a hydroxyadamantyl group, and a group combining an adamantyl group with an alkyl group (wherein the alkyl group contains —CH 2 - may be replaced by -O- or -CO-), a group represented by formula (Y30F), a fluorine atom, an iodine atom, a perfluoroalkyl group having 1 to 4 carbon atoms or a phenyl group having a hydroxyl group, a group represented by formula (aa) or a group represented by formula (bb). Also, X 0 is an aliphatic hydrocarbon group having 2 to 72 carbon atoms which may have a substituent (-CH contained in the aliphatic hydrocarbon group). 2 - is -O-, -S-, -CO- or -SO 2 -) or a hydrocarbon group having 6 to 72 carbon atoms including an aromatic hydrocarbon group having 6 to 36 carbon atoms which may have a substituent (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by .) is preferred, X 0 is a halogen atom, an alkyl group having 1 to 4 carbon atoms, a perfluoroalkyl group having 1 to 4 carbon atoms, or an alicyclic hydrocarbon group having 3 to 36 carbon atoms which may have a hydroxy group (the -CH 2 - is -O-, -S-, -CO- or -SO 2 -), a group formed by combining an alicyclic hydrocarbon group having 3 to 36 carbon atoms with a chain hydrocarbon group having 1 to 18 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by -, and -CH 2The - may be replaced by -O- or -CO-, and the alicyclic hydrocarbon group and the chain hydrocarbon group may have a halogen atom, an alkyl group having 1 to 4 carbon atoms, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group.), an aromatic hydrocarbon group having 6 to 36 carbon atoms which may have a halogen atom, an alkyl group having 1 to 4 carbon atoms, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group, or a group combining an aromatic hydrocarbon group having 6 to 36 carbon atoms and a chain hydrocarbon group having 1 to 18 carbon atoms (the -CH contained in the chain hydrocarbon group 2 - may be replaced by -O- or -CO-, and the aromatic hydrocarbon group and the chain hydrocarbon group may have a halogen atom, an alkyl group having 1 to 4 carbon atoms, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group.) is more preferable. Among them, X 0 represents an alicyclic hydrocarbon group having 3 to 36 carbon atoms, an aromatic hydrocarbon group having 6 to 36 carbon atoms, or a group in which a chain hydrocarbon group having 1 to 18 carbon atoms is combined with an alicyclic hydrocarbon group having 3 to 36 carbon atoms or an aromatic hydrocarbon group having 6 to 36 carbon atoms (the alicyclic hydrocarbon group, the chain hydrocarbon group, and the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms, or a hydroxy group, and the -CH contained in the alicyclic hydrocarbon group and the chain hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by .) is preferred. In the above groups, the number of carbon atoms in the alicyclic hydrocarbon group is preferably 3 to 36, more preferably 3 to 24, even more preferably 3 to 18, still more preferably 3 to 16, and even more preferably 3 to 12. The number of carbon atoms in the chain hydrocarbon group is preferably 1 to 18, more preferably 1 to 12, even more preferably 1 to 9, still more preferably 1 to 6, and even more preferably 1 to 4. The number of carbon atoms in the aromatic hydrocarbon group is preferably 6 to 36, more preferably 6 to 24, even more preferably 6 to 18, still more preferably 6 to 14, and even more preferably 6 to 10. TIFF2025017356000032.tif27136[In formula (aa), X a and X b each independently represents -O- or -S-. X 1a represents a hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. X 2a represents a hydrocarbon group having 1 to 48 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. * -COO - represents the bonding site with the carbon atom of [In formula (bb), L A represents an alkanediyl group having 1 to 6 carbon atoms which may have a fluorine atom, or an aromatic hydrocarbon group having 6 to 14 carbon atoms which may have a halogen atom or a perfluoroalkyl group having 1 to 4 carbon atoms. L B represents a single bond or an alkanediyl group having 1 to 6 carbon atoms, and the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. R A represents a hydrocarbon group having 1 to 36 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. * -COO - represents the bonding site with the carbon atom of

[0035] X a and X b are preferably the same atom, and more preferably both are oxygen atoms.

[0036] X 1a and X 2aExamples of the hydrocarbon group represented by the formula include an aliphatic hydrocarbon group, an aromatic hydrocarbon group, or a group in which two or more of these are combined. These hydrocarbon groups may have a substituent. In addition, the -CH 2 - is -O-, -S-, -CO- or -SO 2 Here, the number of carbon atoms in the hydrocarbon group means the number of carbon atoms in the hydrocarbon group that does not have a substituent and is not substituted.

[0037] X 1a Examples of the aliphatic hydrocarbon group include chain hydrocarbon groups such as alkanetriyl groups, alicyclic hydrocarbon groups, and combinations thereof. Specific examples of the alkanetriyl group include a methine group, an ethanetriyl group, a propanetriyl group, a butanetriyl group, a pentanetriyl group, a hexanetriyl group, a heptanetriyl group, an octanetriyl group, a nonanetriyl group, a decanetriyl group, an undecanetriyl group, and a dodecanetriyl group.

[0038] The alicyclic hydrocarbon group may be either monocyclic or polycyclic. Examples of the monocyclic alicyclic hydrocarbon group include a cyclobutanetriyl group, a cyclopentanetriyl group, a cyclohexanetriyl group, and a cyclooctanetriyl group. Examples of the polycyclic alicyclic hydrocarbon group include a norbornanetriyl group and an adamantanetriyl group. Examples of the aromatic hydrocarbon group include a benzenetriyl group, a naphthalenetriyl group, and an anthracenetriyl group. In the case of a combination of groups, the above groups may contain groups having different valences (such as an alkyl group, an alkanediyl group, an alkanetetrayl group, a cycloalkyl group, a cycloalkanediyl group, or a cycloalkanetetrayl group).

[0039] X 1aThe hydrocarbon group represented by the formula (I) has 1 to 24 carbon atoms and may further have one or more substituents. Examples of the substituents include a hydroxy group, a halogen atom, a cyano group, an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 12 carbon atoms, an alkoxycarbonyl group having 2 to 13 carbon atoms, an alkylcarbonyl group having 2 to 13 carbon atoms, an alkylcarbonyloxy group having 2 to 13 carbon atoms, an alicyclic hydrocarbon group having 3 to 12 carbon atoms, an aromatic hydrocarbon group having 6 to 10 carbon atoms, or a combination of these groups. Examples of the halogen atom, alkyl group, alkoxy group, alkoxycarbonyl group, alkylcarbonyl group, alkylcarbonyloxy group, alicyclic hydrocarbon group, aromatic hydrocarbon group, and combinations thereof include the same groups as described above.

[0040] X 1a The hydrocarbon group represented by the formula (i) is preferably an alkanetriyl group having 1 to 6 carbon atoms which may have a substituent or an alicyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent, more preferably an alkanetriyl group having 1 to 6 carbon atoms or a group represented by formula (w1-1) to formula (w1-11), and even more preferably an alkanetriyl group having 1 to 6 carbon atoms, a polycyclic hydrocarbon group such as an alkanetriyl group having 1 to 6 carbon atoms, a group represented by formula (w1-1) or a group represented by formula (w1-3), or a monocyclic hydrocarbon group such as a group represented by formula (w1-2) or a group represented by formula (w1-6). TIFF2025017356000033.tif22154 [Formula (w1-1) to formula (w1-11), The ring may have a hydroxy group, a halogen atom, a cyano group, an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 12 carbon atoms, an alkoxycarbonyl group having 2 to 13 carbon atoms, an alkylcarbonyl group having 2 to 13 carbon atoms, an alkylcarbonyloxy group having 2 to 13 carbon atoms, an alicyclic hydrocarbon group having 3 to 12 carbon atoms, an aromatic hydrocarbon group having 6 to 10 carbon atoms, or a combination of these groups. * denotes a binding site.]

[0041] X 2aThe hydrocarbon group represented by the following formula (I) preferably has 2 to 48 carbon atoms, more preferably 4 to 48 carbon atoms, even more preferably 6 to 44 carbon atoms, even more preferably 8 to 40 carbon atoms, and even more preferably 10 to 38 carbon atoms. X 2a Examples of the substituent that the hydrocarbon group in the formula (I) may have include a hydroxy group, a halogen atom, a cyano group, an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 12 carbon atoms, an alkoxycarbonyl group having 2 to 13 carbon atoms, an alkylcarbonyl group having 2 to 13 carbon atoms, an alkylcarbonyloxy group having 2 to 13 carbon atoms, an alicyclic hydrocarbon group having 3 to 12 carbon atoms, an aromatic hydrocarbon group having 6 to 10 carbon atoms, or a combination of these. Examples of the halogen atom, alkyl group, alkoxy group, alkoxycarbonyl group, alkylcarbonyl group, alkylcarbonyloxy group, alicyclic hydrocarbon group, aromatic hydrocarbon group, and combinations thereof include the same groups as those mentioned above. X 2a The hydrocarbon group having 1 to 48 carbon atoms represented by the following formula may have one or more substituents. X 2a The substituent that the hydrocarbon group in the formula (I) may have is preferably a fluorine atom, an alkyl group having 1 to 4 carbon atoms, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group. X 2a Examples of the hydrocarbon group in include linear or branched chain hydrocarbon groups (e.g., alkanediyl groups, etc.), monocyclic or polycyclic alicyclic hydrocarbon groups, and aromatic hydrocarbon groups, and may be a combination of two or more of these groups. Specific examples of such alkyl groups include linear alkanediyl groups such as a methylene group, an ethylene group, a propane-1,3-diyl group, a butane-1,4-diyl group, a pentane-1,5-diyl group, a hexane-1,6-diyl group, a heptane-1,7-diyl group, and an octane-1,8-diyl group; branched alkanediyl groups such as ethane-1,1-diyl, propane-1,1-diyl, propane-1,2-diyl, propane-2,2-diyl, pentane-2,4-diyl, 2-methylpropane-1,3-diyl, 2-methylpropane-1,2-diyl, pentane-1,4-diyl, and 2-methylbutane-1,4-diyl; monocyclic alicyclic hydrocarbon groups such as monocyclic cycloalkanediyl groups, such as cyclobutane-1,3-diyl, cyclopentane-1,3-diyl, cyclohexane-1,4-diyl, and cyclooctane-1,5-diyl groups; polycyclic alicyclic hydrocarbon groups such as norbornane-1,4-diyl, norbornane-2,5-diyl, adamantane-1,5-diyl, and adamantane-2,6-diyl groups; Examples of the aromatic hydrocarbon groups include a phenylene group, a naphthylene group, a biphenylene group, an anthrylene group, a phenanthrylene group, and a binaphthylene group. In the case of a combination of groups, the above groups may contain groups having different valences (such as an alkyl group, an alkanetriyl group, an alkanetetrayl group, a cycloalkyl group, a cycloalkanetriyl group, or a cycloalkanetetrayl group). Examples of the combined group include a group in which a chain hydrocarbon group and an alicyclic hydrocarbon group are combined, a group in which a chain hydrocarbon group and an aromatic hydrocarbon group are combined, and a group in which an alicyclic hydrocarbon group and an aromatic hydrocarbon group are combined. Specifically, a group in which one or more alicyclic hydrocarbon groups are bonded to a chain hydrocarbon group (for example, -chain hydrocarbon group-alicyclic hydrocarbon group, -chain hydrocarbon group-(alicyclic hydrocarbon group) 2 etc.), groups in which one or more chain hydrocarbon groups are bonded to an alicyclic hydrocarbon group (for example, -alicyclic hydrocarbon group-chain hydrocarbon group, -alicyclic hydrocarbon group-(chain hydrocarbon group) 2 etc.), groups in which one or more alicyclic hydrocarbon groups and a chain hydrocarbon group are bonded to a chain hydrocarbon group (for example, -chain hydrocarbon group-alicyclic hydrocarbon group-chain hydrocarbon group, -chain hydrocarbon group-(alicyclic hydrocarbon group-chain hydrocarbon group) 2 etc.)

[0042] X2a As the hydrocarbon group in A chain hydrocarbon group having 2 to 18 carbon atoms (-CH contained in the chain hydrocarbon group) 2 - may be replaced by -O- or -CO-, and the chain hydrocarbon group may have a substituent. Alicyclic hydrocarbon groups having 3 to 18 carbon atoms (-CH contained in the alicyclic hydrocarbon groups) 2 - is -O-, -S-, -CO- or -SO 2 -, and the alicyclic hydrocarbon group may have a substituent.), or A chain hydrocarbon group having 1 to 12 carbon atoms (-CH contained in the chain hydrocarbon group) 2 - may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 3 to 18 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - (which may be substituted with -), A chain hydrocarbon group having 4 to 18 carbon atoms (-CH contained in the chain hydrocarbon group) 2 - may be replaced by -O- or -CO-, and the chain hydrocarbon group may have a substituent. A chain hydrocarbon group having 1 to 12 carbon atoms (-CH contained in the chain hydrocarbon group) 2 - may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 3 to 16 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - (which may be substituted with -), A chain hydrocarbon group having 6 to 14 carbon atoms (-CH contained in the chain hydrocarbon group) 2 - may be replaced by -O- or -CO-, and the chain hydrocarbon group may have a substituent. A chain hydrocarbon group having 1 to 12 carbon atoms (-CH contained in the chain hydrocarbon group) 2- may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 5 to 14 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - which may be replaced by -.) is more preferable (the group may have a substituent).

[0043] Specifically, X 2a Examples of the hydrocarbon group in An alkanediyl group having 2 to 18 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-, and the alkanediyl group may have a substituent. Alicyclic hydrocarbon groups having 3 to 18 carbon atoms (-CH contained in the alicyclic hydrocarbon groups) 2 - is -O-, -S-, -CO- or -SO 2 -, and the alicyclic hydrocarbon group may have a substituent. An alkanediyl group having 1 to 12 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 3 to 18 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be substituted.) (the group may have a substituent); or An alkanediyl group having 1 to 12 carbon atoms (the —CH 2 may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 3 to 18 carbon atoms and an alkyl group having 1 to 12 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-; and the group may have a substituent. An alkanediyl group having 4 to 18 carbon atoms (the —CH 2- may be replaced by -O- or -CO-, and the alkanediyl group may have a substituent. An alkanediyl group having 1 to 12 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 3 to 16 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be substituted.) (the group may have a substituent); or An alkanediyl group having 1 to 12 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 3 to 16 carbon atoms and an alkyl group having 1 to 12 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-; and An alkanediyl group having 6 to 14 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-, and the alkanediyl group may have a substituent. An alkanediyl group having 1 to 12 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-.) and an adamantanediyl group (-CH 2 - may be replaced by -O- or -CO-; and the group may have a substituent; or An alkanediyl group having 1 to 12 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-.) and an adamantanediyl group and an alkyl group having 1 to 12 carbon atoms (the -CH 2 -may be replaced by -O- or -CO-; and the group (which may have a substituent) is more preferable.

[0044] More specifically, X 2a is the formula (X 2 -1), a group represented by the formula (X 2 -2), a group represented by the formula (X 2 -3) or a group represented by the formula (X 2 -4) is preferred. TIFF2025017356000034.tif33158[expression(X 2 -1)~Formula(X 2 -4) Medium, R 1x , R 2x , R 3x , R 4x , R 5x and R 6x each independently represents an alkyl group having 1 to 6 carbon atoms, an alicyclic hydrocarbon group having 5 to 12 carbon atoms, or a group combining two or more of these groups, and -CH contained in the alkyl group and the alicyclic hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 The alkyl group and the alicyclic hydrocarbon group may each have a substituent. * is X a and X b represents the binding site for The combined group may be a combination of one each of the above-mentioned alkyl groups and alicyclic hydrocarbon groups, or a combination of two or more of either or both of them. In this case, the number of carbon atoms in the combined group is 39 or less, and preferably 37 or less.

[0045] Among them, R 1x , R 2x , R 3x , R 4x , R 5x and R 6x As the alkyl group, an alkyl group having 1 to 6 carbon atoms (including —CH 2 may be replaced by -O- or -CO-, and the alkyl group may have a substituent.), an alicyclic hydrocarbon group having 5 to 12 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2-, and the alicyclic hydrocarbon group may have a substituent.) or an alkyl group having 1 to 6 carbon atoms (the -CH 2 - may be replaced by -O- or -CO-.) and an alicyclic hydrocarbon group having 5 to 12 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by -.) (the group may have a substituent). 2 - may be replaced by -O- or -CO-, and the adamantyl group may have a substituent.) or an alkyl group having 1 to 6 carbon atoms (the -CH 2 -may be replaced by -O- or -CO-) and an adamantyl group (which may have a substituent). The group represented by formula (aa) is more preferably a group represented by any one of the following formulas (aa1), (aa2), (aa3) and (aa4). TIFF2025017356000035.tif34155 [Formula (aa1) to formula (aa4), W 1a represents an alicyclic hydrocarbon group having 3 to 18 carbon atoms. X a and X b Each independently represents -O- or -S-. a and X b is W 1a It bonds to the same carbon atom contained in R 1x , R 2x , R 3x , R 4x , R 5x and R 6x Each independently represents a formula (X 2 -1), formula (X 2 -2), formula (X 2 -3) and the formula (X 2 -4) has the same meaning. * -COO -represents the bonding site with the carbon atom of In formulae (aa1) to (aa4), W 1a The alicyclic hydrocarbon group is more preferably a group represented by formula (w1-1) to formula (w1-11), and further preferably a polycyclic hydrocarbon group such as a group represented by formula (w1-1) or a group represented by formula (w1-3), or a monocyclic hydrocarbon group such as a group represented by formula (w1-2) or a group represented by formula (w1-6).

[0046] In formula (bb), L A and L B In the above formula, examples of the alkanediyl group having 1 to 6 carbon atoms include linear alkanediyl groups such as methylene, ethylene, propane-1,3-diyl, butane-1,4-diyl, pentane-1,5-diyl, and hexane-1,6-diyl groups; and branched alkanediyl groups such as propane-1,2-diyl, 1-methylpropane-1,3-diyl, 2-methylpropane-1,3-diyl, 2-methylpropane-1,2-diyl, 1-methylbutane-1,4-diyl, and 2-methylbutane-1,4-diyl groups. The number of carbon atoms in the alkanediyl group is preferably 1 to 4, and more preferably 1 to 3. Examples of the alkanediyl group which may have a fluorine atom include perfluoroalkanediyl groups such as a difluoromethylene group, a perfluoroethylene group, a perfluoropropanediyl group, a perfluorobutanediyl group, and a perfluoropentanediyl group. The alkanediyl group contains -CH 2 - is -O-, -S-, -CO- or -SO 2 When the alkanediyl group is replaced with -, the number of carbon atoms before the replacement is the total number of carbon atoms in the alkanediyl group. 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), thiol group (-CH 2- is replaced by -S-), alkoxy group (-CH 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), alkylthio group (-CH 2 - is replaced by -S-), alkylsulfonyl group (-CH 2 -But-SO 2 -) an alkanediyloxy group (a group where -CH is substituted at any position in the alkanediyl group) 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 - is replaced by -CO-O-), alkanediylthio group (-CH at any position in the alkanediyl group) 2 - is replaced by -S-), alkanediylsulfonyl group (-CH at any position contained in the alkanediyl group) 2 -But-SO 2 -substituted group). Examples of the alkoxy group, alkoxycarbonyl group, alkylcarbonyl group, alkylcarbonyloxy group, alkylthio group and alkylsulfonyl group include the same as those mentioned above. Examples of the alkanediyloxy group include a methyleneoxy group, an ethyleneoxy group, a propanediyloxy group, a butanediyloxy group, and a pentanediyloxy group. Examples of the alkanediyloxycarbonyl group include a methyleneoxycarbonyl group, an ethyleneoxycarbonyl group, a propanediyloxycarbonyl group, and a butanediyloxycarbonyl group. Examples of the alkanediylcarbonyl group include a methylenecarbonyl group, an ethylenecarbonyl group, a propanediylcarbonyl group, a butanediylcarbonyl group, and a pentanediylcarbonyl group. Examples of the alkanediylcarbonyloxy group include a methylenecarbonyloxy group, an ethylenecarbonyloxy group, a propanediylcarbonyloxy group, and a butanediylcarbonyloxy group. Examples of the alkanediylthio group include a methylenethio group, an ethylenethio group, a propanediylthio group, a butanediylthio group, and a pentanediylthio group. Examples of the alkanediylsulfonyl group include a methylenesulfonyl group, an ethylenesulfonyl group, a propanediylsulfonyl group, a butanediylsulfonyl group, and a pentanediylsulfonyl group. L A Examples of the aromatic hydrocarbon group having 6 to 14 carbon atoms include aromatic hydrocarbon groups such as arylene groups such as a phenylene group, a naphthylene group, an anthrylene group, a biphenylene group, and a phenanthrylene group. The number of carbon atoms in the aromatic hydrocarbon group is preferably 6 to 10, and more preferably 6. L A Examples of the halogen atom that may be contained in include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. L A Examples of the perfluoroalkyl group having 1 to 4 carbon atoms that may be contained in the ring include a trifluoromethyl group, a pentafluoroethyl group, a heptafluoropropyl group, and a nonafluorobutyl group. L Ais preferably an alkanediyl group having 1 to 4 carbon atoms which may have a fluorine atom, or an aromatic hydrocarbon group having 6 to 10 carbon atoms which may have a halogen atom or a perfluoroalkyl group having 1 to 4 carbon atoms, and more preferably an alkanediyl group having 1 to 3 carbon atoms which has a fluorine atom, or a phenylene group which may have a fluorine atom, an iodine atom, or a perfluoroalkyl group having 1 to 3 carbon atoms. L B is a single bond or an alkanediyl group having 1 to 3 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-, and a single bond, a methylene group or an ethylene group is more preferable.

[0047] R A Examples of the hydrocarbon group in include aliphatic hydrocarbon groups (chain hydrocarbon groups such as alkyl groups, alkenyl groups, and alkynyl groups, and alicyclic hydrocarbon groups), aromatic hydrocarbon groups, and groups formed by combining these. Examples of the alkyl group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, an n-hexyl group, an n-heptyl group, a 2-ethylhexyl group, an n-octyl group, an n-nonyl group, an n-decyl group, an n-undecyl group, an n-dodecyl group, etc. The number of carbon atoms in the alkyl group is preferably 1 to 18, more preferably 1 to 12, still more preferably 1 to 9, still more preferably 1 to 6, and still more preferably 1 to 4. Examples of the alkenyl group include ethenyl, propenyl, isopropenyl, butenyl, isobutenyl, tert-butenyl, pentenyl, hexenyl, heptenyl, octenyl, isooctenyl, and nonenyl groups. Examples of the alkynyl group include an ethynyl group, a propynyl group, an isopropynyl group, a butynyl group, an isobutynyl group, a tert-butynyl group, a pentynyl group, a hexynyl group, an octynyl group, and a nonynyl group. -CH contained in chain hydrocarbon group 2- is -O-, -S-, -CO- or -SO 2 Examples of the group substituted for - include a hydroxy group, a carboxy group, an alkoxy group, an alkoxycarbonyl group, an alkylcarbonyl group, an alkylcarbonyloxy group, an alkylsulfonyl group, and an alkylthio group. Examples of the alkoxy group, alkoxycarbonyl group, alkylcarbonyl group, alkylcarbonyloxy group, alkylsulfonyl group and alkylthio group include an alkoxy group having 1 to 17 carbon atoms, an alkoxycarbonyl group having 2 to 17 carbon atoms, an alkylcarbonyl group having 2 to 18 carbon atoms, an alkylcarbonyloxy group having 2 to 17 carbon atoms, an alkylsulfonyl group having 1 to 17 carbon atoms and an alkylthio group having 1 to 17 carbon atoms, and examples of the same groups as those mentioned above. The alicyclic hydrocarbon group may be any of monocyclic, polycyclic and spirocyclic, and may be any of saturated and unsaturated. Examples of the monocyclic alicyclic hydrocarbon group include monocyclic cycloalkyl groups such as cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cyclooctyl, cyclononyl, cyclodecyl and cyclododecyl. Examples of the polycyclic alicyclic hydrocarbon group include polycyclic cycloalkyl groups such as decahydronaphthyl, adamantyl and norbornyl. Alicyclic hydrocarbon groups and -CH contained in alicyclic hydrocarbon groups 2 - is -O-, -S-, -CO- or -SO 2 Specific examples of the group substituted with - include the groups represented by the above formulae (y1) to (y71). The number of carbon atoms in the alicyclic hydrocarbon group is preferably 3 to 36, more preferably 3 to 24, still more preferably 3 to 18, even more preferably 3 to 16, and still more preferably 3 to 12. Examples of the aromatic hydrocarbon group include aryl groups such as a phenyl group, a naphthyl group, a biphenyl group, an anthryl group, a phenanthryl group, a binaphthyl group, etc. The number of carbon atoms in the aromatic hydrocarbon group is preferably 6 to 36, more preferably 6 to 24, still more preferably 6 to 18, still more preferably 6 to 14, and still more preferably 6 to 10. In the case of a combination of groups, the above groups may contain groups having different valences (such as an alkanediyl group, an alkanetriyl group, a cycloalkanediyl group, and a cycloalkanetriyl group). Groups formed by combination include groups that combine an aromatic hydrocarbon group with a chain hydrocarbon group (e.g., aromatic hydrocarbon group-alkanediyl group-*, alkyl group-aromatic hydrocarbon group-*), groups that combine an alicyclic hydrocarbon group with a chain hydrocarbon group (e.g., alicyclic hydrocarbon group-alkanediyl group-*, alkyl group-alicyclic hydrocarbon group-*), and groups that combine an aromatic hydrocarbon group with a alicyclic hydrocarbon group (e.g., aromatic hydrocarbon group-alicyclic hydrocarbon group-*, alicyclic hydrocarbon group-aromatic hydrocarbon group-*). * represents a bonding site. The aromatic hydrocarbon group -alkanediyl group-* includes aralkyl groups such as benzyl group and phenethyl group. Examples of the alkyl group-aromatic hydrocarbon group-* include a tolyl group, a xylyl group, and a cumenyl group. Examples of the alicyclic hydrocarbon group -alkanediyl group-* include cycloalkylalkyl groups such as a cyclohexylmethyl group, a cyclohexylethyl group, a 1-(adamantan-1-yl)methyl group, and a 1-(adamantan-1-yl)-1-methylethyl group. Examples of the alkyl group-alicyclic hydrocarbon group-* include cycloalkyl groups having an alkyl group such as a methylcyclohexyl group, a dimethylcyclohexyl group, and a 2-alkyladamantan-2-yl group. Examples of the aromatic hydrocarbon group-alicyclic hydrocarbon group-* include a phenyladamantyl group. Examples of the alicyclic hydrocarbon group-aromatic hydrocarbon group-* include an adamantylphenyl group. In addition, in the combination, two or more of the alicyclic hydrocarbon groups, aromatic hydrocarbon groups, and chain hydrocarbon groups may be combined. B may be bound to -CH contained in the hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2In addition to the groups mentioned above, examples of the group substituted with - include a cycloalkoxy group, a cycloalkylalkoxy group, an alkoxycarbonyloxy group, an aromatic hydrocarbon group-carbonyloxy group, and a group formed by combining two or more of these groups. Examples of the cycloalkoxy group include cycloalkoxy groups having 3 to 17 carbon atoms, such as a cyclohexyloxy group. Examples of the cycloalkylalkoxy group include cycloalkylalkoxy groups having 4 to 17 carbon atoms, such as a cyclohexylmethoxy group. Examples of the alkoxycarbonyloxy group include alkoxycarbonyloxy groups having 2 to 16 carbon atoms, such as a butoxycarbonyloxy group. Examples of the aromatic hydrocarbon group-carbonyloxy group include aromatic hydrocarbon group-carbonyloxy groups having 7 to 17 carbon atoms, such as a benzoyloxy group. -CH contained in the hydrocarbon group 2 -, -O-, -S-, -SO 2 When the carbon atom is replaced by - or -CO-, the number of carbon atoms before the replacement is regarded as the total number of carbon atoms in the hydrocarbon group.

[0048] R A The substituent that the hydrocarbon group may have is, for example, a halogen atom, a cyano group, an alkyl group having 1 to 12 carbon atoms (including the —CH 2 - is -O-, -S-, -CO- or -SO 2 - may be substituted). Examples of the halogen atom include the same groups as those mentioned above. Examples of the alkyl group having 1 to 12 carbon atoms include the same groups as those mentioned above. -CH in the alkyl group 2 Examples of the group in which - is replaced by -O- or -CO- include a hydroxy group, a carboxy group, an alkoxy group, an alkoxycarbonyl group, an alkylcarbonyl group, and an alkylcarbonyloxy group. Examples of the alkoxy group, alkoxycarbonyl group, alkylcarbonyl group and alkylcarbonyloxy group include an alkoxy group having 1 to 11 carbon atoms, an alkoxycarbonyl group having 2 to 11 carbon atoms, an alkylcarbonyl group having 2 to 12 carbon atoms, and an alkylcarbonyloxy group having 2 to 11 carbon atoms, and examples thereof include the same groups as those described above. R A The hydrocarbon group in may have one or more substituents.

[0049] R A The hydrocarbon group in the formula (I) is an alkyl group having 1 to 12 carbon atoms which may have a substituent (provided that the —CH 2 - is -O-, -S-, -CO- or -SO 2 -) or a cyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent (provided that the -CH 2 - is -O-, -S-, -CO- or -SO 2 -), and a cyclic hydrocarbon group having 3 to 18 carbon atoms which may have a fluorine atom, a hydroxy group, an alkyl group having 1 to 6 carbon atoms, or a perfluoroalkyl group having 1 to 6 carbon atoms (with the proviso that the -CH 2 - is -O-, -S-, -CO- or -SO 2 It is more preferable that the formula is ##STR1##

[0050] Examples of the cyclic hydrocarbon group include cyclic hydrocarbon groups such as monocyclic or polycyclic alicyclic hydrocarbon groups having 3 to 18 carbon atoms and aromatic hydrocarbon groups having 6 to 18 carbon atoms, or combinations of these groups. Examples of the alicyclic hydrocarbon group, aromatic hydrocarbon group, and combined group include the same groups as those described above. In the combination, two or more types of alicyclic hydrocarbon groups and aromatic hydrocarbon groups may be combined. B may be bound to

[0051] A cyclic hydrocarbon group having 3 to 18 carbon atoms (the cyclic hydrocarbon group may have a fluorine atom, a hydroxyl group, an alkyl group having 1 to 6 carbon atoms, or a perfluoroalkyl group having 1 to 6 carbon atoms, and the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by . An alicyclic hydrocarbon group having 3 to 18 carbon atoms which may have a fluorine atom, a hydroxyl group, an alkyl group having 1 to 4 carbon atoms, or a perfluoroalkyl group having 1 to 4 carbon atoms (the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by ), or It is preferably an aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a fluorine atom, a hydroxy group, an alkyl group having 1 to 4 carbon atoms or a perfluoroalkyl group having 1 to 4 carbon atoms. The group represented by formula (bb) is more preferably a group represented by formula (bb1). TIFF2025017356000036.tif1577[In formula (bb1), L A and L B has the same meaning as formula (bb). W 2a represents an alicyclic hydrocarbon group having 3 to 18 carbon atoms, which may have a fluorine atom, an alkyl group having 1 to 4 carbon atoms, a perfluoroalkyl group having 1 to 4 carbon atoms, or a hydroxy group, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. * -COO - represents the bonding site with the carbon atom of In formula (bb1), W 2a is an alicyclic hydrocarbon group having 3 to 18 carbon atoms which may have a fluorine atom, a hydroxyl group, an alkyl group having 1 to 4 carbon atoms or a perfluoroalkyl group having 1 to 4 carbon atoms (the -CH 2 - is -O-, -CO- or -SO 2It is more preferable that the formula is ##STR1## In formula (bb1), W 2a The alicyclic hydrocarbon group is preferably a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, a norbornyl group, an adamantyl group, or the following groups (the bonding site may be any position): TIFF2025017356000037.tif1687

[0052] Examples of the carboxylate anion in the carboxylate salt represented by formula (I) include the carboxylate anions described below. TIFF2025017356000038.tif243165

[0053] TIFF2025017356000039.tif251168

[0054] TIFF2025017356000040.tif233167

[0055] Specific examples of the carboxylate (I) include salts of any combination of the above-mentioned cations and anions. Specific examples of the carboxylate (I) are shown in the table below. In the following table, each symbol represents the symbol attached to the structure representing the above-mentioned anion or cation, and "~" indicates that the carboxylate (I) corresponds to the anion (I). For example, the carboxylate (I-1) is a salt consisting of an anion represented by formula (Ia-1) and a cation represented by formula (Ic-1), the carboxylate (I-2) is a salt consisting of an anion represented by formula (Ia-2) and a cation represented by formula (Ic-1), and the carboxylate (I-101) is a salt consisting of an anion represented by formula (Ia-1) and a cation represented by formula (Ic-2). TIFF2025017356000041.tif5157 [Table 1] TIFF2025017356000043.tif125157 Among these, the carboxylate (I) is preferably a salt obtained by combining an anion represented by any one of Formulae (Ia-1) to (Ia-5), (Ia-10) to (Ia-21), and (Ia-57) to (Ia-66) with a cation represented by any one of Formulae (Ic-1) to (Ic-52).

[0056] <Method for producing carboxylate (I)> The carboxylate (I) can be produced by reacting a salt represented by the formula (Ia) with a salt represented by the formula (Ib) in a solvent. TIFF2025017356000044.tif57163 [wherein all symbols have the same meanings as defined above. R A , R B and R C each independently represents a hydrocarbon group having 1 to 12 carbon atoms, or R A , R B and R C may combine together to form an aromatic ring. D represents a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms.] Examples of the solvent used in this reaction include chloroform, acetonitrile, and ion-exchanged water. The reaction temperature is usually 15° C. to 80° C., and the reaction time is usually 0.5 to 24 hours.

[0057] The salt represented by formula (Ib) can be synthesized with reference to the methods described in JP-A-2011-39502 and JP-A-2014-88367, and examples thereof include salts represented by the following formula (Ib). TIFF2025017356000045.tif142165

[0058] A salt (Ia) in which m1A is an integer of 1 or more, and m1B, m1C and m1D are each 0 (salt represented by formula (I-a1)) can be produced by reacting a salt represented by formula (Ic) with a compound represented by formula (Id) in a solvent in the presence of a catalyst. TIFF2025017356000046.tif55151 [wherein all symbols have the same meanings as defined above.] The catalyst includes carbonyldiimidazole, potassium hydroxide, and the like. Examples of the solvent include chloroform, monochlorobenzene, dimethylformamide, acetonitrile, ethyl acetate, and water. The reaction temperature is usually 15° C. to 80° C., and the reaction time is usually 0.5 to 24 hours.

[0059] Examples of the compound represented by formula (Id) include the compounds represented by the following formulas, which are readily available on the market and can also be readily produced by known methods. TIFF2025017356000047.tif38131

[0060] The salt represented by formula (Ic) can be produced by passing the salt represented by formula (I-c') through an ion exchange resin. TIFF2025017356000048.tif50138 [wherein all symbols have the same meanings as defined above.] The ion exchange resin may be, for example, ion exchange resin (No. 6, 100-200 mesh, manufactured by Wako Pure Chemical Industries, Ltd.). The solvent may be methanol or the like.

[0061] When X is a sulfur atom, the salt represented by formula (I-c') can be produced by reacting a compound represented by formula (Ie) with a compound represented by formula (If) in the presence of trifluoroacetic anhydride and trifluoromethanesulfonic acid in a solvent, followed by treatment with a base. TIFF2025017356000049.tif48159 [wherein all symbols have the same meanings as defined above.] Examples of the solvent include chloroform, monochlorobenzene, and acetonitrile. The reaction temperature is usually 15° C. to 100° C., and the reaction time is usually 0.5 to 24 hours.

[0062] Examples of the compound represented by formula (Ie) include compounds represented by the following formula, and are readily available on the market. TIFF2025017356000050.tif79144

[0063] Examples of the compound represented by formula (If) include compounds represented by the following formula, and are readily available on the market. TIFF2025017356000051.tif23123

[0064] The salt represented by formula (Ic) in which X is an iodine atom (salt represented by formula (I-c1)) can be produced by reacting a compound represented by formula (Ig) with a compound represented by formula (If) in a solvent in the presence of potassium peroxymonosulfate and sulfuric acid, followed by treatment with hydrochloric acid. TIFF2025017356000052.tif41155 [wherein all symbols have the same meanings as defined above.] Examples of the solvent include chloroform, monochlorobenzene, and acetonitrile. The reaction temperature is usually 15° C. to 100° C., and the reaction time is usually 0.5 to 24 hours.

[0065] Examples of the compound represented by formula (Ig) include compounds represented by the following formula, and are readily available on the market. TIFF2025017356000053.tif15139

[0066] In salt (Ia), a salt in which at least one of m1A, m1B, m1C, and m1D is an integer of 1 or greater can be prepared by replacing the salt represented by formula (1-c) with the salt represented by formula (I-c'') below and replacing the salt represented by formula (I-c') with the salt represented by formula (I-c''') in the reaction scheme used in the example of the production method for a salt in which m1A is an integer of 1 or greater, and m1B, m1C, and m1D are each 0. TIFF2025017356000054.tif51146 [wherein all symbols have the same meanings as defined above.]

[0067] [Structural unit derived from a carboxylate represented by formula (I)] The structural unit derived from the carboxylate represented by formula (I) is CH 2 =CR 10 An example of the structural unit is a structural unit represented by the formula (IP) (hereinafter sometimes referred to as "structural unit (IP)"). TIFF2025017356000055.tif62152 [wherein all symbols have the same meanings as defined above.] Among these, the structural unit (IP) is preferably a structural unit represented by the structural unit (IP-A), the structural unit (IP-B) or the structural unit (IP-C). TIFF2025017356000056.tif167154 [wherein all symbols have the same meanings as defined above.] The structural unit (IP) functions as a carboxylic acid generator like the carboxylate (I), and also functions as a structural unit constituting a compound or resin. The structural unit (IP) is R 1a , R 1b , R 1c and R 1d may be a structural unit in which all are cleaved, 1a , R 1b , R 1c and R 1d It is not necessary that all of R 1a , R 1b , R 1c and R 1d It is sufficient that at least one of the groups is cleaved like the group represented by formula (4a-1), and among them, R 1a is preferably a cleaved structural unit (IP-A).

[0068] [Resin containing structural units derived from a carboxylate represented by formula (I)] The resin of the present invention is a resin containing a structural unit (IP) derived from a carboxylate represented by formula (I) (hereinafter, may be referred to as "resin (Ap)"). The resin (Ap) may be a homopolymer containing one type of structural unit (IP) or a copolymer containing two or more types of structural units (IP). The resin (Ap) may also contain a structural unit other than the structural unit (IP). As the structural unit other than the structural unit (IP), as described below, there may be mentioned a structural unit having an acid labile group (hereinafter, sometimes referred to as "structural unit (a1)") and a structural unit other than the structural unit (a1). As the structural unit other than the structural unit (a1), there may be mentioned a structural unit not having an acid labile group (hereinafter, sometimes referred to as "structural unit (s)"), other structural units (hereinafter, sometimes referred to as "structural unit (t)"), and structural units known in the art. Here, the "acid labile group" means a group having a leaving group, which is released by contact with an acid, and the structural unit is converted into a structural unit having a hydrophilic group (e.g., a hydroxyl group or a carboxyl group). The content of the structural unit (IP) is 0.1 mol% or more, preferably 0.5 mol% or more, more preferably 0.8 mol% or more, and even more preferably 1 mol% or more, based on the total structural units of the resin (Ap). Also, it is 100 mol% or less, preferably 50 mol% or less, more preferably 30 mol% or less, and even more preferably 10 mol% or less. Specifically, it is 0.1 to 100 mol%, preferably 0.5 to 50 mol%, more preferably 0.8 to 30 mol%, and even more preferably 1 to 10 mol%. In particular, when the resin (Ap) is used in a resist composition, as described below, it is preferable that the resin (Ap) further contains the structural unit (a1) in addition to the structural unit (IP). Furthermore, as described below, when the resin (Ap) is used in a resist composition, regardless of whether it contains the structural unit (a1), it may be used in combination with a resin containing the structural unit (a1) (hereinafter sometimes referred to as "resin (A)"). Hereinafter, the resin (Ap) and / or the resin (A) may be referred to as "resin (A), etc." The resin (Ap) and the resin (A) preferably further contain a structural unit other than the structural unit (a1).

[0069] <Structural unit (a1)> The structural unit (a1) is derived from a monomer having an acid labile group (hereinafter sometimes referred to as "monomer (a1)"). The acid labile group contained in the resin (A) etc. is preferably a group represented by formula (1) (hereinafter also referred to as group (1)) and / or a group represented by formula (2) (hereinafter also referred to as group (2)). TIFF2025017356000057.tif1988[In formula (1), R a1 , R a2 and R a3 each independently represents an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alicyclic hydrocarbon group having 3 to 20 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or a combination thereof, or R a1 and R a2 are bonded to each other to form, together with the carbon atom to which they are bonded, an alicyclic hydrocarbon group having 3 to 20 carbon atoms, and the alkyl group, the alkenyl group, the alicyclic hydrocarbon group and the aromatic hydrocarbon group may have a halogen atom. ma and na each independently represent 0 or 1, and at least one of ma and na represents 1. * denotes a binding site.] TIFF2025017356000058.tif2171[In formula (2), R a1’ and R a2’ each independently represents a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms; R a3’ represents a hydrocarbon group having 1 to 20 carbon atoms, or R a2’ and R a3’ are bonded to each other to form a heterocyclic group having 3 to 20 carbon atoms together with the carbon atom to which they are bonded and X, and the —CH 2 - may be replaced by -O- or -S-, and the hydrocarbon group and the heterocyclic group may have a halogen atom. X represents an oxygen atom or a sulfur atom. na′ represents 0 or 1. * denotes a binding site.]

[0070] R a1 , R a2 and R a3 Examples of the alkyl group in include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, and an octyl group. R a1 , R a2 and R a3 Examples of the alkenyl group in include an ethenyl group, a propenyl group, an isopropenyl group, a butenyl group, an isobutenyl group, a tert-butenyl group, a pentenyl group, a hexenyl group, a heptenyl group, an octenyl group, an isooctenyl group, and a nonenyl group. R a1 , R a2 and R a3 The alicyclic hydrocarbon group in may be either monocyclic or polycyclic. Examples of monocyclic alicyclic hydrocarbon groups include cycloalkyl groups such as cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl. Examples of polycyclic alicyclic hydrocarbon groups include decahydronaphthyl, adamantyl, and norbornyl groups, as well as the following groups (* indicates a bonding site). R a1 , R a2 and R a3 The alicyclic hydrocarbon group preferably has 3 to 16 carbon atoms. TIFF2025017356000059.tif10150R a1 , R a2 and R a3 Examples of the aromatic hydrocarbon group in include aryl groups such as a phenyl group, a naphthyl group, an anthryl group, a biphenyl group, and a phenanthryl group. Examples of the combined group include a group in which the above-mentioned alkyl group and an alicyclic hydrocarbon group are combined (for example, an alkylcycloalkyl group or a cycloalkylalkyl group such as a methylcyclohexyl group, a methylnorbornyl group, a cyclohexylmethyl group, an adamantylmethyl group, an adamantyldimethyl group, or a norbornylethyl group), an aralkyl group such as a benzyl group, an aromatic hydrocarbon group having an alkyl group (a p-methylphenyl group, a p-tert-butylphenyl group, a tolyl group, a xylyl group, a cumenyl group, a mesityl group, a 2,6-diethylphenyl group, a 2-methyl-6-ethylphenyl group, or the like), an aromatic hydrocarbon group having an alicyclic hydrocarbon group (a p-cyclohexylphenyl group, a p-adamantylphenyl group, or the like), and an aryl-cycloalkyl group such as a phenylcyclohexyl group. Preferably, ma is 0 and na is 1. R a1 and R a2 When they are bonded to each other to form an alicyclic hydrocarbon group, -C(R a1 )(R a2 )(R a3 ) includes the following groups. The alicyclic hydrocarbon group preferably has 3 to 12 carbon atoms. * represents the bonding site with -O-. TIFF2025017356000060.tif30138

[0071] R a1’ , R a2’ and R a3’ Examples of the hydrocarbon group in include an alkyl group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, and a group formed by combining these groups. Alkyl groups, alicyclic hydrocarbon groups, aromatic hydrocarbon groups, and groups formed by combining these groups are R a1 , R a2 and R a3 Examples of the groups include the same groups as those listed in the above. R a2’ and R a3’ When they are bonded to each other to form a heterocyclic group together with the carbon atom to which they are bonded and X, -C(R a1’ )(R a2’)-XR a3’ Examples of the group include the following: * represents a binding site. TIFF2025017356000061.tif18130R a1’ and R a2’ At least one of these is preferably a hydrogen atom. na' is preferably 0. R a1 , R a2 , R a3 , R a1 , R a2’ and R a3’ The halogen atom which may be contained includes a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom.

[0072] Examples of the group (1) include the following groups. In formula (1), R a1 , R a2 and R a3 is an alkyl group, ma = 0, and na = 1. As the group, a tert-butoxycarbonyl group is preferable. In formula (1), R a1 , R a2 together with the carbon atom to which they are attached form an adamantyl group, R a3 is an alkyl group, ma=0, and na=1. In formula (1), R a1 and R a2 are each independently an alkyl group; R a3 is an adamantyl group, ma=0, and na=1. Specific examples of the group (1) include the following groups: * represents a binding site. TIFF2025017356000062.tif150164

[0073] Specific examples of the group (2) include the following groups: * represents a bonding site. TIFF2025017356000063.tif55153

[0074] The monomer (a1) is preferably a monomer having an acid labile group and an ethylenically unsaturated bond, more preferably a (meth)acrylic monomer having an acid labile group. Of the (meth)acrylic monomers having an acid labile group, preferred are those having an alicyclic hydrocarbon group having 5 to 20 carbon atoms. By using a resin (A) or the like having a structural unit derived from a monomer (a1) having a bulky structure such as an alicyclic hydrocarbon group in a resist composition, the resolution of the resist pattern can be improved.

[0075] Examples of the structural unit derived from the (meth)acrylic monomer having the group (1) include a structural unit represented by formula (a1-0) (hereinafter, sometimes referred to as structural unit (a1-0)), a structural unit represented by formula (a1-1) (hereinafter, sometimes referred to as structural unit (a1-1)), or a structural unit represented by formula (a1-2) (hereinafter, sometimes referred to as structural unit (a1-2)). Preferably, it is at least one structural unit selected from the group consisting of the structural unit (a1-0), the structural unit (a1-1) and the structural unit (a1-2), more preferably at least one structural unit selected from the group consisting of the structural unit (a1-1) and the structural unit (a1-2). These may be used alone or in combination of two or more. TIFF2025017356000064.tif43144 [In formula (a1-0), formula (a1-1) and formula (a1-2), all symbols have the same meaning as defined above.]

[0076] R a01 , R a4 , R a5 The halogen atom in the formula (I) includes a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. R a01 , R a4 , R a5Examples of the alkyl group which may have a halogen atom in the above formula include a trifluoromethyl group, a difluoromethyl group, a methyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, an ethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a propyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4-octafluorobutyl group, a butyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, a pentyl group, a hexyl group, a perfluorohexyl group, a chloromethyl group, a bromomethyl group, and an iodomethyl group. The number of carbon atoms in the alkyl group is preferably 1 to 4, more preferably 1 to 3, and even more preferably 1 or 2. The alkyl group is preferably a methyl group or an ethyl group, and more preferably a methyl group. R a01 , R a4 and R a5 is preferably a hydrogen atom or a methyl group, and more preferably a methyl group. L a01 , L a1 and L a2 is preferably an oxygen atom or -O-(CH 2 ) k01 It is -CO-O- (wherein k01 is preferably an integer of any one of 1 to 4, more preferably 1), and more preferably an oxygen atom. R a02 , R a03 and R a04 The alkyl group, alicyclic hydrocarbon group, aromatic hydrocarbon group and combinations thereof in the formula (1) are R a1 , R a2 and R a3 Examples of the groups include the same groups as those listed in the above. R a6 and R a7 The alkyl group, alkenyl group, alicyclic hydrocarbon group, aromatic hydrocarbon group, and combinations thereof in the formula (1) include R a1 , R a2 and R a3 Examples of the groups include the same groups as those listed in the above. R a02, R a03 , and R a04 The alkyl group in the formula (I) is preferably an alkyl group having 1 to 6 carbon atoms, more preferably a methyl group or an ethyl group, and even more preferably a methyl group. R a6 and R a7 The alkyl group in the formula (I) is preferably an alkyl group having 1 to 6 carbon atoms, more preferably a methyl group, an ethyl group, an isopropyl group, or a t-butyl group, and even more preferably an ethyl group, an isopropyl group, or a t-butyl group. R a6 and R a7 The alkenyl group in is preferably an alkenyl group having 2 to 6 carbon atoms, and more preferably an ethenyl group, a propenyl group, an isopropenyl group, or a butenyl group. R a02 , R a03 , R a04 , R a6 and R a7 The alicyclic hydrocarbon group preferably has 5 to 12 carbon atoms, and more preferably 5 to 10 carbon atoms. R a02 , R a03 , R a04 , R a6 and R a7 The aromatic hydrocarbon group preferably has 6 to 12 carbon atoms, and more preferably 6 to 10 carbon atoms. In the group in which an alkyl group and an alicyclic hydrocarbon group are combined, the total number of carbon atoms in the combination of the alkyl group and the alicyclic hydrocarbon group is preferably 18 or less. In the group in which an alkyl group and an aromatic hydrocarbon group are combined, the total number of carbon atoms in the combination of the alkyl group and the aromatic hydrocarbon group is preferably 18 or less. R a02 and R a03 is preferably an alkyl group having 1 to 6 carbon atoms which may have a halogen atom or an aromatic hydrocarbon group having 6 to 12 carbon atoms which may have a halogen atom, and more preferably a methyl group, an ethyl group, a phenyl group or a naphthyl group which may have a halogen atom. R a04is preferably an alkyl group having 1 to 6 carbon atoms which may have a halogen atom or an alicyclic hydrocarbon group having 5 to 12 carbon atoms which may have a halogen atom, and more preferably a methyl group, an ethyl group, a cyclohexyl group or an adamantyl group which may have a halogen atom. R a6 and R a7 is preferably an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, an alkenyl group having 2 to 6 carbon atoms which may have a halogen atom, or an aromatic hydrocarbon group having 6 to 12 carbon atoms which may have a halogen atom, more preferably a methyl group, ethyl group, isopropyl group, t-butyl group, ethenyl group, phenyl group or naphthyl group which may have a halogen atom, and even more preferably an ethyl group, isopropyl group, t-butyl group, ethenyl group or phenyl group which may have a halogen atom. m1' is preferably an integer of 0 to 3, and more preferably 0 or 1. n1 is preferably an integer of 0 to 3, and more preferably 0 or 1. n1' is preferably 0 or 1.

[0077] Examples of the structural unit (a1-0) include a structural unit represented by any one of formulas (a1-0-1) to (a1-0-24) and R a01 and structural units in which the methyl group corresponding to the formula (a1-0-1) is replaced with a hydrogen atom, a halogen atom, a haloalkyl group (an alkyl group having a halogen atom) or another alkyl group. Structural units represented by any of formulas (a1-0-1) to (a1-0-10), (a1-0-13), (a1-0-14) and (a1-0-19) to (a1-0-24) are preferred. TIFF2025017356000065.tif119160

[0078] Examples of the structural unit (a1-1) include structural units derived from monomers described in JP 2010-204646 A. Among them, structural units represented by any one of formulas (a1-1-1) to (a1-1-7) and R in the structural unit (a1-1) area4 In the above formula (a1-1-1), a methyl group is replaced with a hydrogen atom, a halogen atom, a haloalkyl group or another alkyl group. In the above formula (a1-1-2), a methyl group is replaced with a hydrogen atom, a halogen atom, a haloalkyl group or another alkyl group. In the above formula (a1-1-3), a methyl group is replaced with a hydrogen atom, a halogen atom, a haloalkyl group or another alkyl group. In the above formula (a1-1-4), a structural unit is more preferred. TIFF2025017356000066.tif38168

[0079] The structural unit (a1-2) includes a structural unit represented by any one of formulas (a1-2-1) to (a1-2-20) and R a5 and structural units in which a methyl group corresponding to the formula (a1-2-2), (a1-2-5), (a1-2-6), and (a1-2-10) to (a1-2-20) are replaced with a hydrogen atom, a halogen atom, a haloalkyl group, or another alkyl group. TIFF2025017356000067.tif91163

[0080] When the resin (A) etc. contains the structural unit (a1-0) and / or the structural unit (a1-1) and / or the structural unit (a1-2), the total content of these units is 10 mol% or more, preferably 15 mol% or more, more preferably 20 mol% or more, even more preferably 25 mol% or more, even more preferably 30 mol% or more, even more preferably 40 mol% or more, and even more preferably 50 mol% or more, based on the total structural units of the resin (A) etc. Also, 95 mol% or less is mentioned, preferably 90 mol% or less, more preferably 85 mol% or less, even more preferably 70 mol% or less, and even more preferably 65 mol% or less. Specifically, 10 to 95 mol% is mentioned, preferably 15 to 90 mol%, more preferably 20 to 85 mol%, even more preferably 25 to 70 mol%, and even more preferably 30 to 70 mol%. When the resin (A) or the like contains the structural unit (a1-0), the content thereof is 5 mol% or more, preferably 10 mol% or more, more preferably 15 mol% or more, even more preferably 20 mol% or more, even more preferably 25 mol% or more, even more preferably 30 mol% or more, and even more preferably 35 mol% or more, based on the total structural units of the resin (A) or the like. Also, the content is 80 mol% or less, preferably 75 mol% or less, more preferably 70 mol% or less, even more preferably 65 mol% or less, and even more preferably 60 mol% or less. Specifically, the content is 5 to 80 mol%, preferably 5 to 75 mol%, and more preferably 10 to 70 mol%. When the resin (A) etc. contains the structural unit (a1-1) and / or the structural unit (a1-2), the total content of these units is 10 mol% or more, preferably 15 mol% or more, more preferably 20 mol% or more, even more preferably 25 mol% or more, even more preferably 30 mol% or more, even more preferably 40 mol% or more, and even more preferably 50 mol% or more, based on the total structural units of the resin (A) etc. Also, 95 mol% or less is included, preferably 90 mol% or less, more preferably 85 mol% or less, even more preferably 80 mol% or less, even more preferably 75 mol% or less, even more preferably 70 mol% or less, and even more preferably 65 mol% or less. Specifically, 10 to 90 mol% is included, preferably 15 to 85 mol%, more preferably 15 to 80 mol%, even more preferably 20 to 80 mol%, even more preferably 20 to 75 mol%, and even more preferably 20 to 70 mol%.

[0081] An example of the structural unit (a1) having a group (2) is a structural unit represented by formula (a1-4) (hereinafter, sometimes referred to as "structural unit (a1-4)"). TIFF2025017356000068.tif31118 [In formula (a1-4), all symbols have the same meaning as defined above.] R a1 and Ra17 Examples of the halogen atom in include a fluorine atom, a chlorine atom, and a bromine atom. R a1 and R a17 Examples of the alkyl group having 1 to 6 carbon atoms, which may have a halogen atom, include a trifluoromethyl group, a difluoromethyl group, a methyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, an ethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a propyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4-octafluorobutyl group, a butyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, a pentyl group, a hexyl group, a perfluorohexyl group, a chloromethyl group, a bromomethyl group, and an iodomethyl group. The number of carbon atoms in the alkyl group is preferably 1 to 4, more preferably 1 to 3, and even more preferably 1 or 2. R a1 is preferably a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, more preferably a hydrogen atom, a methyl group or an ethyl group, and further preferably a hydrogen atom or a methyl group. R a17 Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a sec-butoxy group, a tert-butoxy group, a pentyloxy group, and a hexyloxy group. The number of carbon atoms in the alkoxy group is preferably 1 to 4, and more preferably 1 to 3. The alkoxy group is preferably an alkoxy group having 1 to 4 carbon atoms, more preferably a methoxy group or an ethoxy group, and even more preferably a methoxy group. R a17 Examples of the alkoxyalkyl group include a methoxymethyl group, an ethoxyethyl group, a propoxymethyl group, an isopropoxymethyl group, a butoxymethyl group, a sec-butoxymethyl group, and a tert-butoxymethyl group. The number of carbon atoms in the alkoxyalkyl group is preferably 2 to 8, and more preferably 2 to 4. The alkoxyalkyl group is preferably an alkoxyalkyl group having 2 to 8 carbon atoms, more preferably a methoxymethyl group or an ethoxyethyl group, and even more preferably a methoxymethyl group. R a17 Examples of the alkoxyalkoxy group include a methoxymethoxy group, a methoxyethoxy group, an ethoxymethoxy group, an ethoxyethoxy group, a propoxymethoxy group, an isopropoxymethoxy group, a butoxymethoxy group, a sec-butoxymethoxy group, and a tert-butoxymethoxy group. The number of carbon atoms in the alkoxyalkoxy group is preferably 2 to 8, and more preferably 2 to 4. The alkoxyalkoxy group is preferably an alkoxyalkoxy group having 2 to 8 carbon atoms, and more preferably a methoxyethoxy group or an ethoxyethoxy group. R a17 Examples of the alkylcarbonyl group include an acetyl group, a propionyl group, and a butyryl group. The number of carbon atoms in the alkylcarbonyl group is preferably 2 to 4, and more preferably 2 to 3. The alkylcarbonyl group is preferably an alkylcarbonyl group having 2 to 3 carbon atoms, and more preferably an acetyl group. R a17 Examples of the alkylcarbonyloxy group include an acetyloxy group, a propionyloxy group, and a butyryloxy group. The number of carbon atoms in the alkylcarbonyloxy group is preferably 2 to 4, and more preferably 2 to 3. The alkylcarbonyloxy group is preferably an alkylcarbonyloxy group having 2 to 3 carbon atoms, and more preferably an acetyloxy group. R a17 is preferably a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 4 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 4 carbon atoms, or an alkoxyalkoxy group having 2 to 8 carbon atoms, more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, an ethoxy group, an ethoxyethoxy group, or an ethoxymethoxy group, and even more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, or an ethoxyethoxy group.

[0082] A a11Examples of the alkanediyl group include straight-chain alkanediyl groups such as methylene, ethylene, propane-1,3-diyl, propane-1,2-diyl, butane-1,4-diyl, pentane-1,5-diyl, hexane-1,6-diyl, heptane-1,7-diyl, octane-1,8-diyl, nonane-1,9-diyl, decane-1,10-diyl, undecane-1,11-diyl, and dodecane-1,12-diyl groups. Examples of branched alkanediyl groups include branched alkanediyl groups such as butane-1,3-diyl group, 2-methylpropane-1,3-diyl group, 2-methylpropane-1,2-diyl group, pentane-1,4-diyl group, 2-methylbutane-1,4-diyl group, heptane-1,6-diyl group, octane-1,7-diyl group, nonane-1,8-diyl group, decane-1,9-diyl group, and undecane-1,10-diyl group. The number of carbon atoms in the alkanediyl group is preferably 1 to 10, more preferably 1 to 8, still more preferably 1 to 6, even more preferably 1 to 4, still more preferably 1 to 3, and even more preferably 1 or 2. In addition, A a11 is also preferably a methylene group or an ethylene group. R a18 Examples of the alkyl group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, and a tert-butyl group. A a11 -CH contained in the alkanediyl group 2 - is -O-, -CO- or -NR a18 When it is replaced with -, the number of carbon atoms before the replacement is regarded as the number of carbon atoms of the alkanediyl group. A a11 -CH contained in the alkanediyl group 2 - is -O-, -CO- or -NR a18 The group substituted for - is a hydroxy group (-CH 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), carbonyl group (-CH 2- is replaced by -CO-), oxy group (-CH 2 - is replaced by -O-), amino group (-CH 2 -But -NR a18 - substituted), alkoxy group (-CH at any position in the alkyl group) 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylamino group (-CH at any position in the alkyl group) 2 -But -NR a18 -substituted group), peptide group (-CH contained in ethylene group) 2 -CH 2 -But-CO-NR a18 -), alkanediyloxy group (groups in which -CH at any position in the alkanediyl group is replaced by -), 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 - is replaced by -CO-O-), alkanediylsulfonyl group (-CH at any position contained in the alkanediyl group) 2 -But-SO 2 -), alkanediylthio group (groups in which -CH at any position in the alkanediyl group is replaced with -CH 2 - is replaced by -S-), alkanediylamino group (-CH at any position contained in the alkanediyl group) 2 -But -NR a18These substituted groups include the same groups as those exemplified in this specification, within the range permitted by the upper limit of the number of carbon atoms. The alkylamino group includes alkylamino groups having 1 to 11 carbon atoms, such as a methylamino group, an ethylamino group, a propylamino group, a butylamino group, a pentylamino group, a hexylamino group, an octylamino group, etc. The number of carbon atoms in the alkylamino group is preferably 1 to 8, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkanediylamino group includes an alkanediylamino group having 1 to 11 carbon atoms, such as a methyleneamino group, an ethyleneamino group, a propyleneamino group, etc. The number of carbon atoms in the alkanediylamino group is preferably 1 to 8, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. For example, A a11 -CH contained in the alkanediyl group 2 - is -O-, -CO- or -NR a18 Groups substituted with - include *-O-, *-CO-O-, *-O-CO-, *-CO-OA a12 -CO-O-, *-O-CO-A a12 -O-, *-OA a12 -CO-O-, *-CO-OA a12 -O-CO-, *-O-CO-A a12 -O-CO-, *-CO-NR a18 Among them, *-CO-O- and *-CO-OA a12 -CO-O-, *-OA a12 -CO-O-, *-CO-NR a18 - is preferred, where A a12 represents an alkanediyl group having 1 to 8 carbon atoms, and * represents R a1 A represents the bonding site with the carbon atom to which it is attached. a12 The alkanediyl group of A is as follows, within the upper limit of the carbon number. a11 Examples of the alkanediyl groups include those shown above. A a11 is a single bond, *-CO-O- or *-CO-OAa12 -CO-O- is preferred, and a single bond, *-CO-O- or *-CO-O-CH 2 It is more preferably -CO-O-, and further preferably a single bond or *-CO-O-. na1 is preferably 1, 2, 3 or 4, more preferably 1, 2 or 3, and even more preferably 1 or 2. na11 is preferably 0, 1, 2 or 3, more preferably 0, 1 or 2, and further preferably 0 or 1. mc is preferably 0 or 1. R a34 , R a35 and R a36 Examples of the hydrocarbon group in include an alkyl group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, and a group consisting of a combination thereof. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, and an octyl group. The alicyclic hydrocarbon group may be either monocyclic or polycyclic. Examples of the monocyclic alicyclic hydrocarbon group include cycloalkyl groups such as cyclopentyl, cyclohexyl, cycloheptyl, and cyclooctyl. Examples of the polycyclic alicyclic hydrocarbon group include decahydronaphthyl, adamantyl, and norbornyl groups, as well as the following groups (* indicates a bonding site): TIFF2025017356000069.tif10151 Examples of the aromatic hydrocarbon group include aryl groups such as a phenyl group, a naphthyl group, an anthryl group, a biphenyl group, and a phenanthryl group. Examples of the combined group include a group in which the above-mentioned alkyl group and alicyclic hydrocarbon group are combined (e.g., alkylcycloalkyl groups or cycloalkylalkyl groups such as methylcyclohexyl group, dimethylcyclohexyl group, methylnorbornyl group, cyclohexylmethyl group, adamantylmethyl group, adamantyldimethyl group, and norbornylethyl group), aralkyl groups such as benzyl group, aromatic hydrocarbon groups having an alkyl group (p-methylphenyl group, p-tert-butylphenyl group, tolyl group, xylyl group, cumenyl group, mesityl group, 2,6-diethylphenyl group, 2-methyl-6-ethylphenyl group, etc.), aromatic hydrocarbon groups having an alicyclic hydrocarbon group (p-cyclohexylphenyl group, p-adamantylphenyl group, etc.), and aryl-cycloalkyl groups such as phenylcyclohexyl group. In particular, R a36 Examples of the alkyl group include an alkyl group having 1 to 18 carbon atoms, an alicyclic hydrocarbon group having 3 to 18 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or a group formed by combining these groups. R a35 and R a36 Examples of the divalent hydrocarbon group having 2 to 20 carbon atoms that is formed by bonding together with the -CO- to which they are bonded include the following groups. * represents a bonding site, and one of the groups is R a34 This is the binding site for TIFF2025017356000070.tif15105R a34 is preferably a hydrogen atom. R a35 is preferably a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, or an alicyclic hydrocarbon group having 3 to 12 carbon atoms, and more preferably a methyl group or an ethyl group. R a36 The hydrocarbon group in R is preferably an alkyl group having 1 to 18 carbon atoms, an alicyclic hydrocarbon group having 3 to 18 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or a group formed by combining these, and more preferably an alkyl group having 1 to 18 carbon atoms, an alicyclic hydrocarbon group having 3 to 18 carbon atoms, or an aralkyl group having 7 to 18 carbon atoms. a36 The alkyl group and the alicyclic hydrocarbon group in R are preferably unsubstituted.a36 The aromatic hydrocarbon group in is preferably an aromatic ring having an aryloxy group having 6 to 10 carbon atoms.

[0083] -OC(R a34 )(R a35 )-OR a36 is eliminated on contact with an acid (e.g., p-toluenesulfonic acid) to form a hydroxy group or a carboxy group, respectively. -X a1 -OC(R a34 )(R a35 )-OR a36 In the case of a benzene ring, A a11 It is preferable that at least one of them is bonded to the o-position or the m-position, and more preferable that it is bonded to the p-position. In the case of a naphthalene ring, A a11 When the bonding position of A is the 1st position, it may be bonded to any of the 2nd to 8th positions. a11 When the bonding position of A is the 2-position, it may be bonded to any of the 1-position and the 3-8-positions. a11 When the bonding position of A is the 1st position, at least one of them is preferably bonded to the 3rd to 6th positions, and more preferably bonded to the 3rd or 4th position. a11 When the bonding position is the 2-position, it is preferably bonded to the 4- to 7-positions, and more preferably bonded to the 5- or 6-position. Examples of the structural unit (a1-4) include structural units derived from monomers described in JP 2010-204646 A. Preferably, the structural units represented by formulas (a1-4-1) to (a1-4-42) and R in the structural unit (a1-4) are a1 and more preferably, the structural units represented by formulae (a1-4-1) to (a1-4-5), (a1-4-10), (a1-4-13), (a1-4-14), (a1-4-19), and (a1-4-20), respectively. TIFF2025017356000071.tif227163

[0084] When the resin (A) or the like contains the structural unit (a1-4), the content thereof is 10 mol% or more, preferably 15 mol% or more, more preferably 20 mol% or more, even more preferably 25 mol% or more, even more preferably 30 mol% or more, even more preferably 40 mol% or more, and even more preferably 50 mol% or more, based on the total of all structural units in the resin (A) or the like. Also, the content is 95 mol% or less, preferably 90 mol% or less, more preferably 85 mol% or less, even more preferably 80 mol% or less, even more preferably 75 mol% or less, even more preferably 70 mol% or less, and even more preferably 65 mol% or less. Specifically, the content is preferably 10 to 95 mol%, more preferably 15 to 90 mol%, even more preferably 20 to 85 mol%, even more preferably 20 to 70 mol%, and even more preferably 20 to 65 mol%.

[0085] An example of a structural unit derived from a (meth)acrylic monomer having the group (2) is a structural unit represented by formula (a1-5) (hereinafter, may be referred to as "structural unit (a1-5)"). TIFF2025017356000072.tif4558 [In formula (a1-5), all symbols have the same meaning as defined above.]

[0086] R a8 Examples of the halogen atom in include a fluorine atom, an iodine atom, a chlorine atom, and a bromine atom. Of these, a fluorine atom is preferred. R a8Examples of the alkyl group having 1 to 6 carbon atoms which may have a halogen atom in the formula (I) include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a fluoromethyl group, a difluoromethyl group, a trifluoromethyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4-octafluorobutyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, and a perfluorohexyl group. In formula (a1-5), R a8 is preferably a hydrogen atom, a methyl group, or a trifluoromethyl group. L 51 is preferably an oxygen atom. L 52 and L 53 Of these, it is preferred that one is -O- and the other is -S-. It is preferable that s1 is 1. s1' is preferably an integer of 0 to 2. Z a1 is a single bond or -CH 2 -CO-O- is preferred.

[0087] Examples of the structural unit (a1-5) include structural units derived from monomers described in JP 2010-61117 A. Among them, the structural units represented by formulae (a1-5-1) to (a1-5-4) are preferred, and the structural unit represented by formula (a1-5-1) or (a1-5-2) is more preferred. TIFF2025017356000073.tif33133

[0088] When the resin (A) or the like contains the structural unit (a1-5), the content thereof is 1 mol% or more, preferably 2 mol% or more, more preferably 3 mol% or more, even more preferably 5 mol% or more, even more preferably 10 mol% or more, even more preferably 20 mol% or more, and even more preferably 25 mol% or more, based on the total structural units of the resin (A) or the like. Also, the content is 80 mol% or less, preferably 70 mol% or less, more preferably 60 mol% or less, even more preferably 50 mol% or less, even more preferably 45 mol% or less, even more preferably 40 mol% or less, and even more preferably 30 mol% or less. Specifically, the content is preferably 1 to 50 mol%, more preferably 3 to 45 mol%, even more preferably 5 to 40 mol%, and even more preferably 5 to 30 mol%.

[0089] An example of the structural unit (a1) having a group (1) is a structural unit represented by formula (a1-6) (hereinafter, sometimes referred to as "structural unit (a1-6)"). TIFF2025017356000074.tif3580 [In formula (a1-6), all symbols have the same meaning as defined above.] R a61 Examples of the halogen atom in include a fluorine atom, an iodine atom, a chlorine atom, and a bromine atom. Of these, a fluorine atom is preferred. R a61 Examples of the alkyl group having 1 to 6 carbon atoms which may have a halogen atom in the formula (I) include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a fluoromethyl group, a difluoromethyl group, a trifluoromethyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4-octafluorobutyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, and a perfluorohexyl group. R a61is preferably a hydrogen atom, a methyl group, or a trifluoromethyl group. R a62 , R a63 and R a64 Examples of the alkyl group in include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, etc. The alkyl group is preferably an alkyl group having 1 to 4 carbon atoms, more preferably an alkyl group having 1 to 3 carbon atoms, and further preferably a methyl group or an ethyl group. R a62 , R a63 and R a64 The cyclic hydrocarbon group in the formula (I) includes an alicyclic hydrocarbon group and an aromatic hydrocarbon group. The alicyclic hydrocarbon group may be either monocyclic or polycyclic. Examples of the monocyclic alicyclic hydrocarbon group include a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group. Examples of the polycyclic alicyclic hydrocarbon group include a decahydronaphthyl group, an adamantyl group, and a norbornyl group. The number of carbon atoms in the alicyclic hydrocarbon group is preferably 3 to 16, and more preferably 3 to 12. Examples of the aromatic hydrocarbon group include a phenylene group and a naphthylene group. Examples of the substituent that the cyclic hydrocarbon group may have include a halogen atom, a hydroxy group, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkoxyalkyl group having 2 to 12 carbon atoms, an alkoxyalkoxy group having 2 to 12 carbon atoms, an alkylcarbonyl group having 2 to 4 carbon atoms, an alkylcarbonyloxy group having 2 to 4 carbon atoms, an acryloyloxy group, or a methacryloyloxy group. R a62 and R a63 Examples of the ring formed by bonding with each other include an adamantane ring, a cyclopentane ring, and a cyclohexane ring. a62 and R a63 When they are bonded to each other to form a ring, -C(R a62 )(R a63 )(R a64 ) includes the following groups. * represents a bonding site with an oxygen atom. The number of carbon atoms in the ring is preferably 3 to 16, and more preferably 3 to 12. TIFF2025017356000075.tif33110

[0090] L a61 and L a62 Examples of the alkanediyl group having 1 to 4 carbon atoms include a methylene group, an ethylene group, a propane-1,3-diyl group, a propane-1,2-diyl group, a butane-1,4-diyl group, a butane-1,3-diyl group, a 2-methylpropane-1,3-diyl group, and a 2-methylpropane-1,2-diyl group. L a61 and L a62 is preferably each independently a methylene group or an ethylene group. X a61 is preferably a single bond or -CO-O-*, and more preferably a single bond. X a62 is preferably a single bond or *-OL a61 -, and more preferably a single bond.

[0091] Examples of the aromatic hydrocarbon group having 6 to 20 carbon atoms for Ar include a phenylene group, a 1-naphthylene group, a 2-naphthylene group, a 1-anthrylene group, a 9-anthrylene group, a biphenylene group, a 1-phenanthrylene group, and a 2-phenanthrylene group. Examples of the substituent that the aromatic hydrocarbon group may have include a halogen atom, a hydroxy group, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkoxyalkyl group having 2 to 12 carbon atoms, an alkoxyalkoxy group having 2 to 12 carbon atoms, an alkylcarbonyl group having 2 to 4 carbon atoms, an alkylcarbonyloxy group having 2 to 4 carbon atoms, an acryloyloxy group, or a methacryloyloxy group. Examples of the halogen atom include a fluorine atom, an iodine atom, a chlorine atom, and a bromine atom. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group. The alkyl group is preferably an alkyl group having 1 to 4 carbon atoms, more preferably a methyl group or an ethyl group, and further preferably a methyl group. Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a sec-butoxy group, a tert-butoxy group, a pentyloxy group, and a hexyloxy group. The alkoxy group is preferably an alkoxy group having 1 to 4 carbon atoms, more preferably a methoxy group or an ethoxy group, and further preferably a methoxy group. Examples of the alkoxyalkyl group include a methoxymethyl group, an ethoxyethyl group, a propoxymethyl group, an isopropoxymethyl group, a butoxymethyl group, a sec-butoxymethyl group, and a tert-butoxymethyl group. The alkoxyalkyl group is preferably an alkoxyalkyl group having 2 to 8 carbon atoms, more preferably a methoxymethyl group or an ethoxyethyl group, and further preferably a methoxymethyl group. Examples of the alkoxyalkoxy group include a methoxymethoxy group, a methoxyethoxy group, an ethoxymethoxy group, an ethoxyethoxy group, a propoxymethoxy group, an isopropoxymethoxy group, a butoxymethoxy group, a sec-butoxymethoxy group, and a tert-butoxymethoxy group. The alkoxyalkoxy group is preferably an alkoxyalkoxy group having 2 to 8 carbon atoms, and more preferably a methoxyethoxy group or an ethoxyethoxy group. Examples of the alkylcarbonyl group include an acetyl group, a propionyl group, a butyryl group, etc. The alkylcarbonyl group is preferably an alkylcarbonyl group having 2 to 3 carbon atoms, and more preferably an acetyl group. Examples of the alkylcarbonyloxy group include an acetyloxy group, a propionyloxy group, and a butyryloxy group. The alkylcarbonyloxy group is preferably an alkylcarbonyloxy group having 2 to 3 carbon atoms, and more preferably an acetyloxy group. The substituent is preferably a halogen atom, a hydroxy group, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or an alkoxyalkoxy group having 2 to 8 carbon atoms, more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, an ethoxy group, an ethoxyethoxy group, or an ethoxymethoxy group, and even more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, or an ethoxyethoxy group. Ar is preferably a phenylene group which may have a substituent, and more preferably a phenylene group which may have a hydroxy group.

[0092] Examples of the structural unit (a1-6) include structural units represented by formulas (a1-6-1) to (a1-6-44), preferably structural units represented by formulas (a1-6-1) to (a1-6-9), more preferably structural units represented by formulas (a1-6-1), (a1-6-2), (a1-6-4), (a1-6-5), (a1-6-7) or (a1-6-8), and still more preferably structural units represented by formulas (a1-6-1) or (a1-6-2). TIFF2025017356000076.tif226161

[0093] In the structural units represented by formulae (a1-6-1) to (a1-6-9), (a1-6-16) to (a1-6-21), (a1-6-28) to (a1-6-30), and (a1-6-37) to (a1-6-44), R a61 In the structural units represented by formulae (a1-6-10) to (a1-6-15), (a1-6-22) to (a1-6-27), and (a1-6-31) to (a1-6-36), R a61 The structural unit (a1-6) also includes a structural unit in which the methyl group corresponding to the following formula is replaced with a hydrogen atom, a halogen atom, a haloalkyl group, or the like.

[0094] When the resin (A) or the like contains the structural unit (a1-6), the content thereof is 3 mol% or more, preferably 5 mol% or more, more preferably 7 mol% or more, even more preferably 10 mol% or more, even more preferably 20 mol% or more, even more preferably 30 mol% or more, and even more preferably 40 mol% or more, based on the total structural units of the resin (A) or the like. Also, the content is 80 mol% or less, preferably 75 mol% or less, more preferably 70 mol% or less, and even more preferably 65 mol% or less. Specifically, the content is preferably 3 to 80 mol%, more preferably 5 to 75 mol%, even more preferably 7 to 70 mol%, even more preferably 7 to 65 mol%, and particularly preferably 10 to 65 mol%.

[0095] Further, examples of the structural unit (a1) include the following structural units. TIFF2025017356000077.tif32168

[0096] When the resin (A) etc. contains the structural units represented by the formulas (a1-3-1) to (a1-3-7), the content thereof is 10 mol% or more, preferably 15 mol% or more, more preferably 20 mol% or more, even more preferably 25 mol% or more, even more preferably 30 mol% or more, even more preferably 40 mol% or more, and even more preferably 50 mol% or more, based on the total structural units of the resin (A) etc. Also, the content is 95 mol% or less, preferably 90 mol% or less, more preferably 85 mol% or less, even more preferably 80 mol% or less, even more preferably 75 mol% or less, even more preferably 70 mol% or less, and even more preferably 60 mol% or less. Specifically, 10 to 95 mol% is preferred, 15 to 90 mol% is more preferred, 20 to 85 mol% is even more preferred, 20 to 70 mol% is even more preferred, and 20 to 60 mol% is particularly preferred.

[0097] Further, examples of the structural unit (a1) include the following structural units. TIFF2025017356000078.tif51105 When the resin (A) etc. contains structural units represented by formulas (a1-7-1) to (a1-7-3), the content thereof is 10 mol% or more, preferably 15 mol% or more, more preferably 20 mol% or more, even more preferably 25 mol% or more, even more preferably 30 mol% or more, even more preferably 40 mol% or more, and even more preferably 50 mol% or more, based on the total structural units of the resin (A) etc. Also, 95 mol% or less is mentioned, preferably 90 mol% or less, more preferably 85 mol% or less, even more preferably 80 mol% or less, even more preferably 75 mol% or less, even more preferably 70 mol% or less, and even more preferably 60 mol% or less. Specifically, it is preferably 10 to 60 mol %, more preferably 15 to 55 mol %, even more preferably 20 to 50 mol %, even more preferably 20 to 45 mol %, and particularly preferably 20 to 40 mol %.

[0098] Structural unit(s) The structural unit (s) is derived from a monomer having no acid labile group (hereinafter, may be referred to as "monomer (s)"). As the monomer from which the structural unit (s) is derived, a monomer having no acid labile group known in the resist field can be used. The structural unit (s) preferably has a hydroxy group, a carboxy group, or a lactone ring. If a resin containing a structural unit having a hydroxy group or a carboxy group and no acid labile group (hereinafter sometimes referred to as "structural unit (a2)") and / or a structural unit having a lactone ring and no acid labile group (hereinafter sometimes referred to as "structural unit (a3)") is used in the resist composition of the present invention, the resolution of the resist pattern and adhesion to the substrate can be improved. In addition to the above-mentioned structural units, the structural unit (s) may also include a structural unit having a halogen atom (hereinafter sometimes referred to as "structural unit (a4)"), a structural unit having a non-leaving hydrocarbon group (hereinafter sometimes referred to as "structural unit (a5)"), a structural unit having a sultone structure (hereinafter sometimes referred to as "structural unit (a6)"), or a structural unit that decomposes upon exposure to generate an acid (hereinafter sometimes referred to as "structural unit (a7)").

[0099] <Structural unit (a2)> The structural unit (a2) is a structural unit represented by formula (a2) and has an alcoholic hydroxy group, a phenolic hydroxy group, a carboxy group, or the like. TIFF2025017356000079.tif4194[In formula (a2), R a2 represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. A a21 represents a single bond or an alkanediyl group having 1 to 12 carbon atoms, and the -CH 2 - is -O-, -CO- or -NR a28 - may be replaced. R a28 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. L a21 represents a single bond or a hydrocarbon group having 1 to 28 carbon atoms, the hydrocarbon group optionally having a substituent, and the -CH 2 - is -O-, -CO-, -S- or -SO 2 - may be replaced. La22 represents a single bond or a chain hydrocarbon group having 1 to 12 carbon atoms which may have a fluorine atom, and -CH 2 - may be replaced by -O- or -CO-. na2 represents an integer of 1 to 5. When na2 is 2 or more, a plurality of L a22 may be the same or different.

[0100] R a2 Examples of the halogen atom in include a fluorine atom, an iodine atom, a chlorine atom, and a bromine atom. R a2 Examples of the alkyl group having 1 to 6 carbon atoms, which may have a halogen atom, include a trifluoromethyl group, a difluoromethyl group, a methyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, an ethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a propyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4-octafluorobutyl group, a butyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, a pentyl group, a hexyl group, a perfluorohexyl group, a chloromethyl group, a bromomethyl group, and an iodomethyl group. The number of carbon atoms in the alkyl group is preferably 1 to 4, more preferably 1 to 3, and even more preferably 1 or 2. R a2 is preferably a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, more preferably a hydrogen atom, a methyl group or an ethyl group, and further preferably a hydrogen atom or a methyl group.

[0101] A a21Examples of the alkanediyl group include straight-chain alkanediyl groups such as methylene, ethylene, propane-1,3-diyl, propane-1,2-diyl, butane-1,4-diyl, pentane-1,5-diyl, hexane-1,6-diyl, heptane-1,7-diyl, octane-1,8-diyl, nonane-1,9-diyl, decane-1,10-diyl, undecane-1,11-diyl, and dodecane-1,12-diyl groups. branched alkanediyl groups such as butane-1,3-diyl group, 2-methylpropane-1,3-diyl group, 2-methylpropane-1,2-diyl group, pentane-1,4-diyl group, 2-methylbutane-1,4-diyl group, heptane-1,6-diyl group, octane-1,7-diyl group, nonane-1,8-diyl group, decane-1,9-diyl group, and undecane-1,10-diyl group. The number of carbon atoms in the alkanediyl group is preferably 1 to 10, more preferably 1 to 8, still more preferably 1 to 6, even more preferably 1 to 4, still more preferably 1 to 3, and still more preferably 1 or 2. In addition, Aa21 is also preferably a methylene group or an ethylene group. R a28 Examples of the alkyl group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, and a tert-butyl group. A a21 The -CH2- in the alkanediyl group is -O-, -CO- or -NR a28 When it is replaced with -, the number of carbon atoms before the replacement is regarded as the number of carbon atoms of the alkanediyl group. A a21 -CH contained in the alkanediyl group 2 - is -O-, -CO- or -NR a28 The group substituted for - is a hydroxy group (-CH 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), carbonyl group (-CH 2- is replaced by -CO-), oxy group (-CH 2 - is replaced by -O-), amino group (-CH 2 -But -NR a28 - substituted), alkoxy group (-CH at any position in the alkyl group) 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (a group in which -CH2- at any position in the alkyl group is replaced by -CO-), alkylamino group (a group in which -CH 2 -But -NR a28 -substituted group), peptide group (-CH contained in ethylene group) 2 -CH 2 -But-CO-NR a28 -), alkanediylamino group (groups in which -CH at any position in the alkanediyl group is replaced with -CH 2 -But -NR a28 These substituted groups include those exemplified in this specification, within the range permitted by the upper limit of the carbon number. The alkylamino group includes alkylamino groups having 1 to 11 carbon atoms, such as a methylamino group, an ethylamino group, a propylamino group, a butylamino group, a pentylamino group, a hexylamino group, an octylamino group, etc. The number of carbon atoms in the alkylamino group is preferably 1 to 8, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. The alkanediylamino group includes an alkanediylamino group having 1 to 11 carbon atoms, such as a methyleneamino group, an ethyleneamino group, a propyleneamino group, etc. The number of carbon atoms in the alkanediylamino group is preferably 1 to 8, more preferably 1 to 6, further preferably 1 to 4, and further more preferably 1 to 3. Among them, A a21-CH contained in the alkanediyl group 2 - is -O-, -CO- or -NR a28 Groups substituted with - include *-O-, *-CO-O-, *-O-CO-, *-CO-OA a22 -CO-O-, *-O-CO-A a22 -O-, *-OA a22 -CO-O-, *-CO-OA a22 -O-CO-, *-O-CO-A a22 -O-CO-, *-CO-NR a28 Among them, *-CO-O- and *-CO-OA a22 -CO-O-, *-OA a22 -CO-O-, *-CO-NR a28 - is preferred, where A a22 represents an alkanediyl group having 1 to 8 carbon atoms, and * represents R a2 A represents the bonding site with the carbon atom to which it is attached. a22 The alkanediyl group of A is as follows, within the upper limit of the carbon number. a21 Examples of the alkanediyl groups include those shown above. A a21 is a single bond, *-CO-O- or *-CO-OA a22 -CO-O- is preferred, and a single bond, *-CO-O- or *-CO-O-CH 2 It is more preferably -CO-O-, and further preferably a single bond or *-CO-O-. L a21 The hydrocarbon group in is a (na2+1)-valent hydrocarbon group, and examples of such cyclic hydrocarbon groups include linear or branched chain hydrocarbon groups, monocyclic or polycyclic (including spiro rings, fused rings or bridged rings) alicyclic hydrocarbon groups, and aromatic hydrocarbon groups, and may be groups formed by combining two or more of these groups (for example, a hydrocarbon group formed from an alicyclic hydrocarbon group or an aromatic hydrocarbon group and a chain hydrocarbon group). L a21 Examples of the chain hydrocarbon group include divalent to hexavalent chain hydrocarbon groups such as an alkanediyl group, an alkanetriyl group, an alkanetetrayl group, an alkanepentyl group, and an alkanehexyl group. Examples of the alkanediyl group include Aa21 Examples of the alkanediyl groups include those shown above. Examples of the alkanetriyl group include a methanetriyl group, an ethanetriyl group, a propanetriyl group, a butanetriyl group, a pentanetriyl group, a hexanetriyl group, a heptanetriyl group, an octanetriyl group, a nonanetriyl group, a decanetriyl group, an undecanetriyl group, a dodecanetriyl group, a tridecanetriyl group, a tetradecanetriyl group, a pentadecanetriyl group, a hexadecanetriyl group, and a heptadecanetriyl group. Examples of the alkanetetrayl group include a methanetetrayl group, an ethanetetrayl group, a propanetetrayl group, a butanetetrayl group, a pentanetetrayl group, a hexanetetrayl group, a heptanetetrayl group, an octanetetrayl group, a nonanetetrayl group, a decanetetrayl group, an undecanetetrayl group, a dodecanetetrayl group, a tridecanetetrayl group, a tetradecanetetrayl group, a pentadecanetetrayl group, a hexadecanetetrayl group, and a heptadecanetetrayl group. Examples of the alkanol groups include a methane pentaylene group, an ethane pentaylene group, a propane pentaylene group, a butane pentaylene group, a pentane pentaylene group, and a hexane pentaylene group. Examples of the alkanehexyl group include a methanehexyl group, an ethanehexyl group, a propanehexyl group, a butanehexyl group, a pentanehexyl group, and a hexanehexyl group. Further examples include groups in which one or more hydrogen atoms of the above groups are replaced with bonding sites. The number of carbon atoms in the chain hydrocarbon group is preferably 1 to 18, more preferably 1 to 12, even more preferably 1 to 10, still more preferably 1 to 9, even more preferably 1 to 8, even more preferably 1 to 6, even more preferably 1 to 5, and particularly preferably 1 to 4. L a21 Examples of the monocyclic and polycyclic alicyclic hydrocarbon groups in the formula (I) include the following alicyclic hydrocarbon groups: The binding site may be any position. TIFF2025017356000080.tif45168For example, divalent to hexavalent alicyclic hydrocarbon groups such as a cycloalkanediyl group, a cycloalkanetriyl group, a cycloalkanetetrayl group, a cycloalkanepentyl group, and a cycloalkanehexyl group are exemplified. Specifically, monocyclic alicyclic hydrocarbon groups such as cyclobutane-1,3-diyl group, cyclopentane-1,3-diyl group, cyclohexane-1,4-diyl group, cyclooctane-1,5-diyl group, cyclopropanetriyl group, cyclobutanetriyl group, cyclopentanetriyl group, cyclohexanetriyl group, cycloheptanetriyl group, cyclooctanetriyl group, cyclodecanetriyl group, cyclopropanetetrayl group, cyclobutanetetrayl group, cyclopentanetetrayl group, cyclohexanetetrayl group, cycloheptanetetrayl group, cyclooctanetetrayl group, and cyclodecanetetrayl group; Examples of polycyclic alicyclic hydrocarbon groups include norbornane-1,4-diyl group, norbornane-2,5-diyl group, adamantane-1,5-diyl group, adamantane-2,6-diyl group, decahydronaphthalenediyl group, bicyclo[3.3.0]octanediyl group, norbornanetriyl group, adamantanetriyl group, decahydronaphthalenetriyl group, bicyclo[3.3.0]octanetriyl group, norbornanetetrayl group, adamantanetetrayl group, decahydronaphthalenetetrayl group, and bicyclo[3.3.0]octanetetrayl group. Further examples include groups in which one or more hydrogen atoms of the above groups are replaced with bonding sites. The alicyclic hydrocarbon group preferably has 3 to 20 carbon atoms, more preferably 3 to 18 carbon atoms, further preferably 3 to 16 carbon atoms, and further preferably 3 to 12 carbon atoms. L a21 Examples of the aromatic hydrocarbon group in include divalent to hexavalent aromatic hydrocarbon groups such as an arylene group, an arenetriyl group, an arenettetrayl group, an arenetyl group, and an arenethexyl group. Specific examples of aromatic hydrocarbon groups include a phenylene group, a naphthylene group, an anthrylene group, a biphenylene group, a phenanthrylene group, a benzenetriyl group, a naphthalenetriyl group, an anthracenetriyl group, a biphenylenetriyl group, a phenanthrenetriyl group, a benzenetetrayl group, a naphthalenetetrayl group, an anthracenetetrayl group, a biphenylenetetrayl group, and a phenanthrenetetrayl group. Further examples include groups in which one or more hydrogen atoms of the above groups are replaced with bonding sites. The aromatic hydrocarbon group preferably has 6 to 20 carbon atoms, more preferably 6 to 18 carbon atoms, further preferably 6 to 14 carbon atoms, and even more preferably 6 to 10 carbon atoms. Examples of groups that combine two or more of these groups include a group that combines an alicyclic hydrocarbon group with a chain hydrocarbon group, a group that combines an aromatic hydrocarbon group with a chain hydrocarbon group, a group that combines an alicyclic hydrocarbon group with an aromatic hydrocarbon group, and a group that combines an alicyclic hydrocarbon group with a chain hydrocarbon group and an aromatic hydrocarbon group. In the combination, two or more of each of the alicyclic hydrocarbon group, aromatic hydrocarbon group, and chain hydrocarbon group may be combined. In addition, when any of the groups is A a21 and L a22 may be bound to -CH contained in the hydrocarbon group 2 -, -O-, -S-, -SO 2 The group substituted for - or -CO- is a hydroxy group (-CH 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), thiol group (-CH 2 - is replaced by -S-), alkoxy group (-CH 2 - is replaced by -O-), alkylthio group (-CH 2 - is replaced by -S-), alkoxycarbonyl group (-CH 2 -CH2 - is replaced by -O-CO-), alkylsulfonyl group (-CH at any position in the alkyl group) 2 -But-SO 2 - substituted), alkylcarbonyl group (-CH at any position in the alkyl group) 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), oxy group (-CH 2 - is replaced by -O-), carbonyl group (-CH 2 - is replaced by -CO-), thio group (-CH 2 - is replaced by -S-), sulfonyl group (-CH 2 -But-SO 2 -), alkanediyloxy group (groups in which -CH at any position in the alkanediyl group is replaced by -), 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 - is replaced by -CO-O-), alkanediylsulfonyl group (-CH at any position contained in the alkanediyl group) 2 -But-SO 2 -), alkanediylthio group (groups in which -CH at any position in the alkanediyl group is replaced with -CH 2Examples of the substituted groups include a cycloalkoxy group, a cycloalkylalkoxy group, an alkoxycarbonyloxy group, an aromatic hydrocarbon group-carbonyloxy group, an aromatic hydrocarbon group-carbonyl group, an aromatic hydrocarbon group-oxy group, and a group combining two or more of these groups. Examples also include groups in which one or more hydrogen atoms of these groups are replaced with a bonding site. Examples of these substituted groups include the same as those exemplified in this specification. In addition, -CH contained in alicyclic hydrocarbon groups 2 - is -O-, -S-, -CO- or -SO 2 Groups replaced with - include the same as those exemplified in this specification. -CH in the combined group 2 - is -O-, -S-, -CO- or -SO 2 Examples of groups substituted with - include the following groups: The binding site may be at any position. TIFF2025017356000081.tif27164L a21 The hydrocarbon group in may have one or more substituents. Examples of the substituent include a halogen atom, a haloalkyl group having 1 to 12 carbon atoms, an alkyl group having 1 to 16 carbon atoms (including the —CH 2 - may be replaced by -O- or -CO-), an acryloyloxy group or a methacryloyloxy group. Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. L a21The hydrocarbon group in the formula (I) can have a halogen atom as a substituent, and thus can have a substituent such as a haloalkyl group. Examples of the haloalkyl group include a fluorinated alkyl group, a chlorinated alkyl group, a brominated alkyl group, and an iodinated alkyl group, and examples thereof include a chloromethyl group, a bromomethyl group, an iodomethyl group, a fluoromethyl group, a difluoromethyl group, a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, and a perfluorobutyl group. The number of carbon atoms in the haloalkyl group is preferably 1 to 8, more preferably 1 to 6, even more preferably 1 to 4, and even more preferably 1 to 3. L a21 The hydrocarbon group of L a21 can substantially have a substituent such as an alkyl group. Examples of the alkyl group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, a 2-ethylhexyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, and a dodecyl group. The number of carbon atoms in the alkyl group is preferably 1 to 12, more preferably 1 to 10, still more preferably 1 to 8, still more preferably 1 to 6, still more preferably 1 to 4, and still more preferably 1 to 3. L a21 -CH contained in the hydrocarbon group 2 - is replaced by -O- or -CO-, etc., a21can substantially have a substituent such as a hydroxy group, a carboxy group, an alkoxy group, a thiol group, a sulfonyl group, an alkoxycarbonyl group, an alkylcarbonyl group, an alkylcarbonyloxy group, an alkoxyalkyl group, an alkoxyalkoxy group, an acryloyloxy group, or a methacryloyloxy group. The number of carbon atoms in the alkoxy group is preferably 1 to 12, more preferably 1 to 6, even more preferably 1 to 4, and even more preferably 1 to 3. The number of carbon atoms in the alkoxycarbonyl group, the alkylcarbonyl group, or the alkylcarbonyloxy group is preferably 2 to 12, more preferably 2 to 6, even more preferably 2 to 4, and even more preferably 2 to 3. The number of carbon atoms in the alkoxyalkyl group or the alkoxyalkoxy group is preferably 2 to 12, more preferably 2 to 8, even more preferably 2 to 6, and even more preferably 2 to 4. The above groups also include the same groups as those exemplified in this specification. L a21 The substituent that the hydrocarbon group in the formula (I) may have is, for example, a halogen atom, a haloalkyl group having 1 to 8 carbon atoms, or an alkyl group having 1 to 12 carbon atoms (including —CH 2 is preferably a halogen atom, a haloalkyl group having 1 to 6 carbon atoms, or an alkyl group having 1 to 10 carbon atoms (-CH2- contained in the alkyl group may be replaced by -O- or -CO-), more preferably a halogen atom, a haloalkyl group having 1 to 4 carbon atoms, an alkyl group having 1 to 4 carbon atoms, a hydroxy group, an alkoxy group having 1 to 4 carbon atoms, or an alkoxyalkoxy group having 2 to 8 carbon atoms, still more preferably a fluorine atom, an iodine atom, a trifluoromethyl group, a methyl group, a hydroxy group, a methoxy group, an ethoxy group, an ethoxyethoxy group, or an ethoxymethoxy group, and still more preferably a fluorine atom, an iodine atom, a trifluoromethyl group, a methyl group, a hydroxy group, a methoxy group, or an ethoxyethoxy group. Also, L a21 In the case where the alkanediyl group is replaced by -O- or -CO-, for example, *-L a23 -X a21-(L a23 represents an alkanediyl group having 1 to 8 carbon atoms; X a21 represents -O-, -O-CO-, -CO-O-, or -O-CO-O-, and * represents A a21 It is also preferred that the bond is L a21 represents a single bond, a chain hydrocarbon group having 1 to 12 carbon atoms which may have a substituent (provided that the —CH 2 - may be replaced by -O- or -CO-), a cyclic hydrocarbon group having 3 to 20 carbon atoms which may have a substituent (provided that the -CH 2 - is -O-, -S-, -CO- or -SO 2 -) or a group formed by combining a chain hydrocarbon group having 1 to 8 carbon atoms which may have a substituent and a cyclic hydrocarbon group having 3 to 20 carbon atoms which may have a substituent (with the proviso that the -CH 2 - may be replaced by -O- or -CO-, and -CH contained in the cyclic hydrocarbon group 2 -, -O-, -S-, -SO 2 - or -CO-), and a chain hydrocarbon group having 1 to 10 carbon atoms which may have a substituent (with the proviso that the -CH 2 - may be replaced by -O- or -CO-), a cyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent (provided that -CH 2 - is -O-, -S-, -CO- or -SO 2 -) or a group formed by combining a chain hydrocarbon group having 1 to 6 carbon atoms which may have a substituent and a cyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent (with the proviso that the -CH 2 - may be replaced by -O- or -CO-, and -CH contained in the cyclic hydrocarbon group 2 -, -O-, -S-, -SO 2 - or -CO- may be substituted.) is more preferable.

[0102] L a22 Examples of the chain hydrocarbon group having 1 to 12 carbon atoms include linear alkanediyl groups such as methylene group, ethylene group, propane-1,3-diyl group, propane-1,2-diyl group, butane-1,4-diyl group, pentane-1,5-diyl group, hexane-1,6-diyl group, heptane-1,7-diyl group, octane-1,8-diyl group, nonane-1,9-diyl group, decane-1,10-diyl group, undecane-1,11-diyl group, and dodecane-1,12-diyl group. Examples of branched alkanediyl groups include ethane-1,1-diyl, propane-1,1-diyl, propane-1,2-diyl, propane-2,2-diyl, 1-methylpropane-1,3-diyl, 2-methylpropane-1,3-diyl, 2-methylpropane-1,2-diyl, 1-dimethylpropane-1,3-diyl, pentane-2,4-diyl, pentane-1,4-diyl, and 2-methylbutane-1,4-diyl groups. The number of carbon atoms in the chain hydrocarbon group is preferably 1 to 10, more preferably 1 to 8, even more preferably 1 to 6, and even more preferably 1 to 4. -CH contained in chain hydrocarbon group 2 Examples of the group in which - is replaced by -O- or -CO- include the same as those exemplified in this specification. L a22 may have one fluorine atom or two or more fluorine atoms. na2 is preferably an integer of 1 to 4, and more preferably an integer of 1 to 3. L a21 In the case where R is a single bond or a chain hydrocarbon group, examples of the structural unit (a2) include the following structural units. a2 In the same manner as the following structural unit, a structural unit in which a methyl group corresponding to the following formula is replaced with a hydrogen atom or the like is also a suitable structural unit of the structural unit (a2). TIFF2025017356000082.tif69169

[0103] When a resist pattern is produced from the resist composition of the present invention, in the case where a high energy ray such as a KrF excimer laser (248 nm), an electron beam, or EUV (extreme ultraviolet light) is used as an exposure light source, the structural unit (a2) having a phenolic hydroxyl group is preferred, and the structural unit (a2-A) described below is more preferred. In addition, in the case where an ArF excimer laser (193 nm) or the like is used, the structural unit (a2) having an alcoholic hydroxyl group is preferred, and the structural unit (a2-C) described below is more preferred. The structural unit (a2) may contain one type alone or two or more types.

[0104] In the structural unit (a2), L a21 In the case where is a cyclic hydrocarbon group, an example of the structural unit having a phenolic hydroxy group or a carboxy group is a structural unit represented by formula (a2-A) (hereinafter sometimes referred to as "structural unit (a2-A)"). TIFF2025017356000083.tif31128 [In formula (a2-A), all symbols have the same meaning as defined above.] R a2 and A a21 The groups include the same groups as those exemplified in formula (a2). R a27 Examples of the halogen atom include a fluorine atom, a chlorine atom, an iodine atom, and a bromine atom. R a27Examples of the alkyl group having 1 to 6 carbon atoms, which may have a halogen atom, include a trifluoromethyl group, a difluoromethyl group, a methyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, an ethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a propyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4-octafluorobutyl group, a butyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, a pentyl group, a hexyl group, a perfluorohexyl group, a chloromethyl group, a bromomethyl group, and an iodomethyl group. The number of carbon atoms of the alkyl group is preferably 1 to 4, more preferably 1 to 3, further preferably a methyl group or an ethyl group, and even more preferably a methyl group. R a27 Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, a sec-butoxy group, and a tert-butoxy group. The number of carbon atoms in the alkoxy group is preferably 1 to 4, and more preferably 1 to 3. The alkoxy group is preferably a methoxy group or an ethoxy group, and more preferably a methoxy group. R a27 Examples of the alkoxyalkyl group include a methoxymethyl group, an ethoxyethyl group, a propoxymethyl group, an isopropoxymethyl group, a butoxymethyl group, a sec-butoxymethyl group, and a tert-butoxymethyl group. The number of carbon atoms in the alkoxyalkyl group is preferably 2 to 8, and more preferably 2 to 4. The alkoxyalkyl group is preferably an alkoxyalkyl group having 2 to 8 carbon atoms, more preferably a methoxymethyl group or an ethoxyethyl group, and even more preferably a methoxymethyl group. R a27Examples of the alkoxyalkoxy group include a methoxymethoxy group, a methoxyethoxy group, an ethoxymethoxy group, an ethoxyethoxy group, a propoxymethoxy group, an isopropoxymethoxy group, a butoxymethoxy group, a sec-butoxymethoxy group, and a tert-butoxymethoxy group. The number of carbon atoms in the alkoxyalkoxy group is preferably 2 to 8, and more preferably 2 to 4. The alkoxyalkoxy group is preferably an alkoxyalkoxy group having 2 to 8 carbon atoms, and more preferably a methoxyethoxy group or an ethoxyethoxy group. R a27 Examples of the alkylcarbonyl group include an acetyl group, a propionyl group, and a butyryl group. The number of carbon atoms in the alkylcarbonyl group is preferably 2 to 4, and more preferably 2 to 3. The alkylcarbonyl group is preferably an alkylcarbonyl group having 2 to 3 carbon atoms, and more preferably an acetyl group. R a27 Examples of the alkylcarbonyloxy group include an acetyloxy group, a propionyloxy group, and a butyryloxy group. The number of carbon atoms in the alkylcarbonyloxy group is preferably 2 to 4, and more preferably 2 to 3. The alkylcarbonyloxy group is preferably an alkylcarbonyloxy group having 2 to 3 carbon atoms, and more preferably an acetyloxy group. R a27 is preferably a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 4 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 4 carbon atoms, or an alkoxyalkoxy group having 2 to 8 carbon atoms, more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, an ethoxy group, an ethoxyethoxy group, or an ethoxymethoxy group, and even more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, or an ethoxyethoxy group. nA2 is preferably 1, 2, 3 or 4, more preferably 1, 2 or 3, and even more preferably 1 or 2. na21 is preferably 0, 1, 2 or 3, more preferably 0, 1 or 2, and further preferably 0 or 1. mc is preferably 0 or 1. -X a2 -OH is a benzene ring, Aa21 It is preferable that at least one of them is bonded to the m-position or p-position, and more preferable that it is bonded to the m-position. In the case of a naphthalene ring, A a21 When the bonding position of A is the 1st position, it may be bonded to any of the 2nd to 8th positions. a21 When the bonding position of A is the 2-position, it may be bonded to any of the 1-position and the 3-8-positions. a21 When the bonding position of A is the 1st position, at least one of them is preferably bonded to the 3rd to 6th positions, and more preferably bonded to the 3rd or 4th position. a21 When the bonding position is the 2-position, it is preferably bonded to the 4- to 7-positions, and more preferably bonded to the 5- or 6-position.

[0105] Examples of the structural unit (a2-A) include structural units derived from monomers described in JP-A-2010-204634 and JP-A-2012-12577. The structural unit (a2-A) includes structural units represented by formulae (a2-2-1) to (a2-2-32) and (a2-3-1) to (a2-3-24), and in these structural units, R in the structural unit (a2-A) a2 and the like, in which the methyl group corresponding to the following formula (I) is replaced with a hydrogen atom, a halogen atom, a haloalkyl group or another alkyl group. TIFF2025017356000084.tif188170

[0106] When the structural unit (a2-A) is contained in the resin (A) or the like, the content of the structural unit (a2-A) is preferably 5 mol% or more, more preferably 10 mol% or more, even more preferably 15 mol% or more, and even more preferably 20 mol% or more, based on the total structural units. Also, it is preferably 80 mol% or less, more preferably 70 mol% or less, even more preferably 65 mol% or less, even more preferably 60 mol% or less, even more preferably 50 mol% or less, even more preferably 45 mol% or less, and even more preferably 40 mol% or less. Specifically, it is preferably 5 to 80 mol%, more preferably 10 to 70 mol%, even more preferably 15 to 65 mol%, and even more preferably 20 to 65 mol%. The structural unit (a2-A) may be a compound from which the structural unit (a2-A) is derived (e.g., the -CH 2 -C(-R a2 )- is the CH of the double bond before cleavage. 2 =C(-R a2 ) can be polymerized to incorporate the structural unit (a2-A') into the resin (A) or the like. The structural unit (a2-A) can be polymerized using the structural unit (a1-4), for example, and then treated with an acid such as p-toluenesulfonic acid, to incorporate the structural unit (a2-A) into the resin (A) or the like. The structural unit (a2-A) can be polymerized using acetoxystyrene, for example, and then treated with an alkali such as tetramethylammonium hydroxide, to incorporate the structural unit (a2-A) into the resin (A) or the like.

[0107] In the structural unit (a2), L a21 is a cyclic hydrocarbon group, examples of the structural unit having an alcoholic hydroxy group or a carboxy group include a structural unit represented by formula (a2-B) (hereinafter may be referred to as "structural unit (a2-B)"), a structural unit represented by formula (a2-C) (hereinafter may be referred to as "structural unit (a2-C)"), and a structural unit represented by formula (a2-D) (hereinafter may be referred to as "structural unit (a2-D)"). TIFF2025017356000085.tif46102 [In formula (a2-B) and formula (a2-C), R a2 has the same meaning as formula (a2). R a27 has the same meaning as formula (a2-A). L a25 is -O- or *-O-(CH 2 ) k2 represents -CO-O-, k2 represents an integer of any one of 1 to 7. * represents a bonding site with -CO-. X a2 represents a single bond or -CO-. R a25 and R a26 each independently represents a hydrogen atom, a methyl group, or a hydroxy group. nB2 represents an integer of 1 to 5. When nB2 is 2 or more, a plurality of X a2 may be the same or different from each other. nB22 represents an integer of 0 to 8. When nB22 is 2 or more, a plurality of R a27 may be the same or different from each other. nC22 represents an integer of 0 to 10. When nC22 is 2 or more, multiple R a27 may be the same or different. L a25 is preferably -O-, -O-(CH 2 ) f1 It is -CO-O- (wherein f1 represents an integer of 1 to 4), and more preferably -O-. R a2 is preferably a methyl group. X a2 is preferably a single bond. R a25 is preferably a hydrogen atom. R a26 is preferably a hydrogen atom or a hydroxy group. R a27is preferably a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 4 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 4 carbon atoms, or an alkoxyalkoxy group having 2 to 8 carbon atoms, more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, an ethoxy group, an ethoxyethoxy group, or an ethoxymethoxy group, and even more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, or an ethoxyethoxy group. nB2 is preferably 1, 2, 3 or 4, more preferably 1, 2 or 3, and even more preferably 1 or 2. nB22 is preferably an integer of 0 to 3, more preferably 0, 1 or 2, and further preferably 0 or 1. nC22 is preferably an integer of 0 to 6, more preferably an integer of 0 to 3, and further preferably 0 or 1.

[0108] Examples of the structural unit (a2-B) and the structural unit (a2-C) include structural units derived from monomers described in JP-A-2010-204646, the following structural units, and R a2 In particular, structural units represented by any one of formulae (a2-B-1) to (a2-B-5) and formulae (a2-C-1) to (a2-C-9) are preferred. TIFF2025017356000086.tif80164 When the resin (A) or the like contains the structural unit (a2-B) or the structural unit (a2-C), the content thereof is 1 mol% or more, preferably 2 mol% or more, based on the total structural units of the resin (A) or the like. Also, 45 mol% or less is mentioned, preferably 40 mol% or less, more preferably 35 mol% or less, even more preferably 20 mol% or less, and even more preferably 10 mol% or less. Specifically, 1 to 45 mol% is mentioned, preferably 1 to 40 mol%, more preferably 1 to 35 mol%, even more preferably 1 to 20 mol%, and even more preferably 1 to 10 mol%.

[0109] TIFF2025017356000087.tif51105[In formula (a2-D), R a2 and A a21 have the same meaning as in formula (a2). R a27 has the same meaning as formula (a2-A). R a21 and R a22 each independently represents a fluorinated alkyl group having 1 to 4 carbon atoms. L a24 represents a single bond or an alkanediyl group having 1 to 3 carbon atoms, and the alkanediyl group may be substituted with a fluorine atom. nD2 represents an integer of 1 to 5. When nD2 is 2 or more, the groups in the multiple parentheses may be the same or different. nD22 represents an integer of 0 to 4. When nD22 is 2 or more, a plurality of R a27 may be the same or different from each other. However, 1≦nD2+nD22≦5. R a21 and R a22 Examples of the fluorinated alkyl groups are each independently a trifluoromethyl group, a 2,2,2-trifluoroethyl group, a 3,3,3-trifluoropropyl group, a 4,4,4-trifluorobutyl group, and the like. R a21 and R a22 As the alkyl group, a trifluoromethyl group is preferable. L a24 Examples of the alkanediyl group include a methylene group, an ethane-1,1-diyl group, a propane-1,1-diyl group, and a propane-2,2-diyl group. L a24 is preferably a single bond or a methylene group. R a27is preferably a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 4 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 4 carbon atoms, or an alkoxyalkoxy group having 2 to 8 carbon atoms, more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, an ethoxy group, an ethoxyethoxy group, or an ethoxymethoxy group, and even more preferably a fluorine atom, an iodine atom, a hydroxy group, a methyl group, a methoxy group, or an ethoxyethoxy group. nD2 is preferably 1, 2, 3 or 4, more preferably 1, 2 or 3, even more preferably 1 or 2, and even more preferably 1. Also preferably, nD2 is 1 and the group in parentheses is bonded to the para position. nD22 is preferably an integer of 0 to 3, more preferably an integer of 0 to 2, further preferably 0 or 1, and even more preferably 0.

[0110] The structural unit (a2-D) is more preferably a structural unit represented by the following formula (a2-D1) (hereinafter, sometimes referred to as "structural unit (a2-D1)"). TIFF2025017356000088.tif51108[In formula (a2-D1), R a2 , A a21 , R a27 , nD2 and nD22 each have the same meaning as in formula (a2-D). In formula (a2-D1), R a2 is preferably a hydrogen atom or a methyl group. A a21 is preferably a single bond.

[0111] Examples of the structural unit (a2-D) include the structural units shown below. TIFF2025017356000089.tif62168

[0112] In the structural units represented by formulae (a2-D-1) to (a2-D-8), R a2In the structural units represented by formulae (a2-D-9) to (a2-D-16), the hydrogen atom corresponding to R a2 Specific examples of the structural unit (a2-D) include structural units in which the methyl group corresponding to the following formula is replaced with a hydrogen atom, etc. Among these, the structural units represented by formulae (a2-D-1) to (a2-D-8) are preferred, the structural units represented by formulae (a2-D-1) to (a2-D-4) are more preferred, and the structural unit represented by formula (a2-D-1) is even more preferred. When the resin (A) etc. contains the structural unit (a2-D), the content thereof is preferably 3 mol% or more, more preferably 5 mol% or more, and even more preferably 10 mol% or more, based on the total structural units of the resin (A) etc. Also, it is preferably 80 mol% or less, more preferably 75 mol% or less, even more preferably 70 mol% or less, and even more preferably 65 mol% or less. Specifically, it is preferably 3 to 80 mol%, more preferably 5 to 75 mol%, even more preferably 10 to 70 mol%, and even more preferably 10 to 65 mol%.

[0113] <Structural unit (a3)> The lactone ring of the structural unit (a3) ​​may be a monocyclic ring such as a β-propiolactone ring, a γ-butyrolactone ring, or a δ-valerolactone ring, or may be a condensed ring of a monocyclic lactone ring and another ring. Preferred examples include a γ-butyrolactone ring, an adamantane lactone ring, or a bridged ring containing a γ-butyrolactone ring structure (for example, a structural unit represented by the following formula (a3-2)).

[0114] The structural unit (a3) ​​is preferably a structural unit represented by formula (a3-1), formula (a3-2), formula (a3-3) or formula (a3-4). One of these may be contained alone, or two or more of them may be contained. TIFF2025017356000090.tif48155[In formula (a3-1), formula (a3-2), formula (a3-3) and formula (a3-4), L a4 , L a5 and L a6are each independently -O- or *-O-(CH 2 ) k3 It represents a group represented by -CO-O- (k3 represents an integer of any of 1 to 7). L a7 , -O-, *-OL a8 -O-, *-OL a8 -CO-O-, *-OL a8 -CO-OL a9 -CO-O- or *-OL a8 -O-CO-L a9 Represents -O-. L a8 and L a9 each independently represents an alkanediyl group having 1 to 6 carbon atoms. * indicates the bonding site with the carbonyl group. R a18 , R a19 , R a20 and R a24 each independently represents an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, a hydrogen atom, or a halogen atom. X a3 -CH 2 - or an oxygen atom. R a21 represents an aliphatic hydrocarbon group having 1 to 4 carbon atoms. R a22 , R a23 and R a25 each independently represents a carboxy group, a cyano group, or an aliphatic hydrocarbon group having 1 to 4 carbon atoms. p1 represents an integer of 0 to 5. q1 represents an integer of 0 to 3. r1 represents an integer of 0 to 3. w1 represents an integer of 0 to 8. When p1, q1, r1 and / or w1 are 2 or more, multiple R a21 , R a22 , R a23 and / or R a25 may be the same or different.]

[0115] R a21 , Ra22 , R a23 and R a25 Examples of the aliphatic hydrocarbon group in include alkyl groups such as a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a sec-butyl group, and a tert-butyl group. R a18 , R a19 , R a20 and R a24 Examples of the halogen atom in include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. R a18 , R a19 , R a20 and R a24 Examples of the alkyl group in include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group, and preferably includes an alkyl group having 1 to 4 carbon atoms, and more preferably includes a methyl group or an ethyl group. R a18 , R a19 , R a20 and R a24 Examples of the alkyl group having a halogen atom in the formula (I) include a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluorosec-butyl group, a perfluorotert-butyl group, a perfluoropentyl group, a perfluorohexyl group, a trichloromethyl group, a tribromomethyl group, and a triiodomethyl group. L a8 and L a9 Examples of the alkanediyl group in the formula (I) include a methylene group, an ethylene group, a propane-1,3-diyl group, a propane-1,2-diyl group, a butane-1,4-diyl group, a pentane-1,5-diyl group, a hexane-1,6-diyl group, a butane-1,3-diyl group, a 2-methylpropane-1,3-diyl group, a 2-methylpropane-1,2-diyl group, a pentane-1,4-diyl group, and a 2-methylbutane-1,4-diyl group. In formulas (a3-1) to (a3-3), L a4 ~L a6are each independently preferably -O- or *-O-(CH 2 ) k3 In the -CO-O- group, k3 is an integer of 1 to 4, and more preferably -O- and *-O-CH 2 It is preferably an oxygen atom. R a18 ~R a21 is preferably a methyl group. R a22 and R a23 are each independently preferably a carboxy group, a cyano group, or a methyl group. p1, q1 and r1 each independently represent an integer of preferably 0 to 2, and more preferably 0 or 1. In formula (a3-4), R a24 is preferably a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, more preferably a hydrogen atom, a methyl group, or an ethyl group, and even more preferably a hydrogen atom or a methyl group. R a25 is preferably a carboxy group, a cyano group or a methyl group. L a7 is preferably -O- or *-OL a8 -CO-O-, more preferably -O-, -O-CH 2 -CO-O- or -OC 2 H 4 -CO-O-. w1 is preferably an integer of 0 to 2, and more preferably 0 or 1. In particular, the formula (a3-4) is preferably the formula (a3-4)'. TIFF2025017356000091.tif3848 (in the formula, R a24 , L a7 has the same meaning as above.)

[0116] Examples of the structural unit (a3) ​​include structural units derived from monomers described in JP 2010-204646 A, JP 2000-122294 A, and JP 2012-41274 A. Examples of the structural unit (a3) ​​include structural units represented by any one of formulas (a3-1-1), (a3-1-2), (a3-2-1), (a3-2-2), (a3-3-1), (a3-3-2), and (a3-4-1) to (a3-4-12), and in the structural unit, R in formulas (a3-1) to (a3-4) a18 , R a19 , R a20 and R a24 A structural unit in which a methyl group corresponding to the following formula is replaced with a hydrogen atom is preferred. TIFF2025017356000092.tif108164

[0117] When the resin (A) or the like contains the structural unit (a3), the total content thereof is 1 mol% or more, preferably 3 mol% or more, more preferably 5 mol% or more, and even more preferably 10 mol% or more, based on the total structural units of the resin (A) or the like. Also, 70 mol% or less is mentioned, preferably 65 mol% or less, more preferably 60 mol% or less, even more preferably 50 mol% or less, even more preferably 40 mol% or less, even more preferably 30 mol% or less, even more preferably 25 mol% or less, and even more preferably 20 mol% or less. Specifically, 1 to 70 mol% is mentioned, preferably 3 to 70 mol%, more preferably 3 to 65 mol%, even more preferably 5 to 65 mol%, even more preferably 5 to 60 mol%, and even more preferably 10 to 60 mol%. The content of the structural unit (a3-1), the structural unit (a3-2), the structural unit (a3-3) or the structural unit (a3-4) relative to the total structural units of the resin (A) is, It is preferably 1 mol% or more, more preferably 3 mol% or more, even more preferably 5 mol% or more, and even more preferably 10 mol% or more. It is also preferably 60 mol% or less, more preferably 55 mol% or less, even more preferably 50 mol% or less, still more preferably 40 mol% or less, even more preferably 30 mol% or less, still more preferably 25 mol% or less, and even more preferably 20 mol% or less. Specifically, it is preferably 1 to 60 mol%, more preferably 3 to 60 mol%, even more preferably 3 to 55 mol%, even more preferably 5 to 55 mol%, even more preferably 5 to 50 mol%, and even more preferably 10 to 50 mol%.

[0118] <Structural unit (a4)> The structural unit represented by formula (a4) is shown below. TIFF2025017356000093.tif3254[In formula (a4), R 41 represents a hydrogen atom or a methyl group. R 42 represents a saturated hydrocarbon group having 1 to 24 carbon atoms and containing a halogen atom, and -CH 2 - may be replaced by -O- or -CO-.

[0119] R 42 Examples of the saturated hydrocarbon group represented by the formula (I) include linear or branched chain saturated hydrocarbon groups, monocyclic or polycyclic alicyclic saturated hydrocarbon groups, and groups formed by combining these groups. Examples of the chain saturated hydrocarbon group include linear alkyl groups such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a decyl group, a dodecyl group, a pentadecyl group, a hexadecyl group, a heptadecyl group, and an octadecyl group, and branched alkyl groups such as an isopropyl group and an isobutyl group. Examples of the monocyclic or polycyclic alicyclic saturated hydrocarbon group include monocyclic alicyclic saturated hydrocarbon groups which are monocyclic cycloalkyl groups, such as a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group; and polycyclic alicyclic saturated hydrocarbon groups which are polycyclic cycloalkyl groups, such as a decahydronaphthyl group, an adamantyl group, a norbornyl group, and the following groups (* represents a bonding site): TIFF2025017356000094.tif10146 Examples of groups formed by combinations include groups formed by combining one or more alkyl groups or one or more alkanediyl groups with one or more alicyclic saturated hydrocarbon groups, such as -alkanediyl group-alicyclic saturated hydrocarbon group, -alicyclic saturated hydrocarbon group-alkyl group, and -alkanediyl group-alicyclic saturated hydrocarbon group-alkyl group. Examples of the alkanediyl group include linear alkanediyl groups such as methylene, ethylene, propane-1,3-diyl, butane-1,4-diyl, pentane-1,5-diyl, and hexane-1,6-diyl groups, and branched alkanediyl groups such as propane-1,2-diyl, butane-1,3-diyl, 2-methylpropane-1,2-diyl, 1-methylbutane-1,4-diyl, and 2-methylbutane-1,4-diyl groups. The terminal of the branched alkanediyl group may be a methyl group. R 42 Examples of the halogen atom contained in the saturated hydrocarbon group include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. R 42 -CH of saturated hydrocarbon groups contained in 2 Examples of groups in which - is replaced by -O- or -CO- include a hydroxy group (-CH contained in a methyl group). 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), carbonyl group (-CH 2 - is replaced by -CO-), oxy group (-CH 2- is replaced by -O-), alkoxy group (-CH 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), alkanediyloxy group (-CH at any position in the alkanediyl group) 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 Examples of the substituted groups include a group in which - is replaced by -CO-O-, a cycloalkoxy group, a cycloalkylalkoxy group, and a group in which two or more of these groups are combined. Examples of these substituted groups include the same groups as those exemplified in this specification, within the range permitted by the upper limit of the number of carbon atoms.

[0120] The structural unit (a4) is R 42 is preferably a saturated hydrocarbon group having a fluorine atom. 42 However, examples of the structural unit (a4) which is a saturated hydrocarbon group having a fluorine atom include a structural unit represented by formula (a4-1) (hereinafter may be referred to as "structural unit (a4-1)"), a structural unit represented by formula (a4-2) (hereinafter may be referred to as "structural unit (a4-2)"), and a structural unit represented by formula (a4-3) (hereinafter may be referred to as "structural unit (a4-3)"). The structural unit represented by formula (a4-1) is a structural unit represented by the following formula: TIFF2025017356000095.tif4873[In formula (a4-1), R 41 represents a hydrogen atom or a methyl group. L 41 represents a single bond or an alkanediyl group having 1 to 4 carbon atoms. L 42f represents a fluorine atom-containing alkanediyl group having 1 to 8 carbon atoms or a fluorine atom-containing cycloalkanediyl group having 3 to 12 carbon atoms. R 42f represents a fluorine atom or a hydrogen atom.

[0121] L 41 Examples of the alkanediyl group in the formula (I) include linear alkanediyl groups such as methylene, ethylene, propane-1,3-diyl, and butane-1,4-diyl, and branched alkanediyl groups such as ethane-1,1-diyl, propane-1,2-diyl, butane-1,3-diyl, 2-methylpropane-1,3-diyl, and 2-methylpropane-1,2-diyl. The terminal of the branched alkanediyl group may be a methyl group.

[0122] L 42f Examples of the alkanediyl group having a fluorine atom in the formula (I) include linear alkanediyl groups having a fluorine atom, such as a methylene group having a fluorine atom, an ethylene group having a fluorine atom, a propane-1,3-diyl group having a fluorine atom, a butane-1,4-diyl group having a fluorine atom, a pentane-1,5-diyl group having a fluorine atom, a hexane-1,6-diyl group having a fluorine atom, a heptane-1,7-diyl group having a fluorine atom, and an octane-1,8-diyl group having a fluorine atom; Examples of branched alkanediyl groups having fluorine atoms include ethane-1,1-diyl groups having fluorine atoms, propane-1,1-diyl groups having fluorine atoms, propane-1,2-diyl groups having fluorine atoms, propane-2,2-diyl groups having fluorine atoms, pentane-2,4-diyl groups having fluorine atoms, 2-methylpropane-1,3-diyl groups having fluorine atoms, 2-methylpropane-1,2-diyl groups having fluorine atoms, pentane-1,4-diyl groups having fluorine atoms, and 2-methylbutane-1,4-diyl groups having fluorine atoms. The terminal of the branched alkanediyl group may be a methyl group which may have a fluorine atom. L 42f Examples of the cycloalkanediyl group having a fluorine atom in the formula (I) include monocyclic cycloalkanediyl groups having a fluorine atom, such as a cyclobutane-1,3-diyl group having a fluorine atom, a cyclopentane-1,3-diyl group having a fluorine atom, a cyclohexane-1,4-diyl group having a fluorine atom, a cyclohexene-3,6-diyl group having a fluorine atom, a cycloheptane-1,4-diyl group having a fluorine atom, and a cyclooctane-1,5-diyl group having a fluorine atom; Examples of polycyclic cycloalkanediyl groups having a fluorine atom include a norbornane-1,4-diyl group having a fluorine atom, a norbornane-2,5-diyl group having a fluorine atom, a 5-norbornene-2,3-diyl group having a fluorine atom, an adamantane-1,5-diyl group having a fluorine atom, and an adamantane-2,6-diyl group having a fluorine atom. L 42f The number of fluorine atoms contained in the alkanediyl group and cycloalkanediyl group having a fluorine atom in the above formula may be 1 or more, and is preferably 2 or more. L 42f The alkanediyl group and cycloalkanediyl group having a fluorine atom in the above formula (I) are preferably a perfluoroalkanediyl group and a perfluorocycloalkanediyl group, respectively. L 42fExamples of the perfluoroalkanediyl group in the formula (I) include a difluoromethylene group, a perfluoroethylene group, a perfluoroethylfluoromethylene group, a perfluoropropane-1,3-diyl group, a perfluoropropane-1,2-diyl group, a perfluoropropane-2,2-diyl group, a perfluorobutane-1,4-diyl group, a perfluorobutane-2,2-diyl group, a perfluorobutane-1,2-diyl group, a perfluoropentane-1,5-diyl group, a perfluoropentane-2,2-diyl group, a perfluoropentane-3 ,3-diyl group, perfluorohexane-1,6-diyl group, perfluorohexane-2,2-diyl group, perfluorohexane-3,3-diyl group, perfluoroheptane-1,7-diyl group, perfluoroheptane-2,2-diyl group, perfluoroheptane-3,4-diyl group, perfluoroheptane-4,4-diyl group, perfluorooctane-1,8-diyl group, perfluorooctane-2,2-diyl group, perfluorooctane-3,3-diyl group, and perfluorooctane-4,4-diyl group. L 42f Examples of the perfluorocycloalkanediyl group in the formula (I) include a perfluorocyclohexanediyl group, a perfluorocyclopentanediyl group, a perfluorocycloheptanediyl group, and a perfluoroadamantanediyl group.

[0123] L 41 is preferably a single bond or an alkanediyl group having 1 to 3 carbon atoms, more preferably a single bond, a methylene group, or an ethylene group, and even more preferably a single bond or a methylene group. L 42f is preferably a perfluoroalkanediyl group having 1 to 8 carbon atoms or a perfluorocycloalkanediyl group having 3 to 12 carbon atoms, more preferably a perfluoroalkanediyl group having 1 to 6 carbon atoms, and even more preferably a perfluoroalkanediyl group having 1 to 3 carbon atoms.

[0124] The structural unit (a4-1) may be any of the structural units shown below and R in the structural unit (a4-1) in the structural unit shown below. 41In the structural unit, a methyl group corresponding to the above formula is replaced with a hydrogen atom. TIFF2025017356000096.tif99159

[0125] The structural unit represented by formula (a4-2) is a structural unit shown below. TIFF2025017356000097.tif6545[In formula (a4-2), R 41 represents a hydrogen atom or a methyl group. L 43f represents a saturated hydrocarbon group having 1 to 20 carbon atoms which may have a fluorine atom, and -CH 2 - may be replaced by -O- or -CO-. R 43f represents a saturated hydrocarbon group having 1 to 20 carbon atoms which may have a fluorine atom, and -CH 2 - may be replaced by -O- or -CO-. However, L 43f and R 43f At least one of L has a fluorine atom. 43f and R 43f The total number of carbon atoms in the molecule is limited to 21.

[0126] L 43f and R 43f Examples of the saturated hydrocarbon group in include linear or branched chain saturated hydrocarbon groups, monocyclic or polycyclic alicyclic saturated hydrocarbon groups, and groups formed by combining these groups. 43f and R 43f Examples of saturated hydrocarbon groups in the formula are L 43f and R 43f As long as the upper limit of the total number of carbon atoms in 42 Examples of the saturated hydrocarbon group include the same groups as the saturated hydrocarbon groups exemplified above. L 43f The saturated hydrocarbon group is preferably an alkanediyl group having 1 to 6 carbon atoms or a group represented by the formula (L43f-1). TIFF2025017356000098.tif14120[In formula (L43f-1), s represents 0 or 1. L 45f and L 46f each independently represents a divalent saturated hydrocarbon group having 1 to 5 carbon atoms which may contain a fluorine atom. L 47f represents a single bond or a divalent saturated hydrocarbon group having 1 to 5 carbon atoms which may contain a fluorine atom. X 46f and X 47f each independently represents -O-, -CO-, -CO-O- or -O-CO-. However, L 45f , L 46f , L 47f , X 46f and X 47f The total number of carbon atoms is 7 or less. * and ** are binding sites, ** is -O-CO-R 43f This is the binding site for

[0127] L in the group represented by formula (L43f-1) 45f , L 46f and L 47f Examples of the divalent saturated hydrocarbon group represented by include a linear or branched alkanediyl group, a monocyclic or polycyclic divalent alicyclic saturated hydrocarbon group, and a divalent saturated hydrocarbon group formed by combining an alkanediyl group and a divalent alicyclic saturated hydrocarbon group, etc. Specific examples include a methylene group, an ethylene group, a propane-1,3-diyl group, a propane-1,2-diyl group, a butane-1,4-diyl group, a 1-methylpropane-1,3-diyl group, a 2-methylpropane-1,3-diyl group, a 2-methylpropane-1,2-diyl group, etc. It is preferred that s is 0. Examples of the group represented by formula (L43f-1) include the following groups. In the following examples, * and ** each represent a bonding site, and ** represents -O-CO-R 43f This is the binding site for TIFF2025017356000099.tif47140R 43fis preferably a saturated hydrocarbon group having a fluorine atom. In this case, examples of the structural unit represented by formula (a4-2) include structural units represented by formula (a4-2A) or (a4-2B). TIFF2025017356000100.tif70102 [In formula (a4-2A) and formula (a4-2B), R 41 and L 43f represents the same as in formula (a4-2). R 43fA represents a saturated hydrocarbon group having 1 to 20 carbon atoms and containing a fluorine atom. A 43f represents a divalent saturated hydrocarbon group having 1 to 17 carbon atoms which may have a fluorine atom, and -CH 2 - may be replaced by -O- or -CO-. X 43 represents **-O-CO- or **-CO-O-, and ** represents A 43f represents the binding site with R 43fB represents a saturated hydrocarbon group having 1 to 17 carbon atoms which may contain a fluorine atom. However, in formula (a4-2A), L 43f and R 43fA The total number of carbon atoms in formula (a4-2B) is 21 or less, and in formula (a4-2B), L 43f , A 43f , X 43 and R 43fB The total number of carbon atoms in A is 21 or less. 43f and R 43fB At least one of them has at least one fluorine atom. R 43fA The saturated hydrocarbon group represented by R in formula (a4) is as large as possible within the upper limit of the number of carbon atoms. 42 Examples of the saturated hydrocarbon groups include the saturated hydrocarbon groups exemplified by the above. R 43fA is preferably an alkyl group having 1 to 13 carbon atoms and containing a fluorine atom, a cycloalkyl group having 3 to 12 carbon atoms and containing a fluorine atom, or a group combining these, and *-(CF 2 ) n43f-R 42’ (* represents the bonding site with the carbonyl group. n43f represents an integer of 1 to 6. R 42’ represents a hydrogen atom or a fluorine atom.) or a perfluorocycloalkyl group having 3 to 12 carbon atoms is more preferable. A 43f and R 43fB The saturated hydrocarbon group represented by R in formula (a4) is as large as possible within the upper limit of the number of carbon atoms. 42 Examples of the saturated hydrocarbon groups include the saturated hydrocarbon groups exemplified by the above. A 43f is preferably a divalent chain saturated hydrocarbon group which may have a fluorine atom, a divalent alicyclic saturated hydrocarbon group, or a combination thereof, more preferably a divalent chain saturated hydrocarbon group which has a fluorine atom, and further preferably a fluorinated alkanediyl group having 1 to 6 carbon atoms. R 43fB The saturated hydrocarbon group which may have a fluorine atom is preferably a chain saturated hydrocarbon group which may have a fluorine atom, an alicyclic saturated hydrocarbon group or a group combining these, more preferably an alkyl group having 1 to 12 carbon atoms which may have a fluorine atom, a cycloalkyl group having 3 to 12 carbon atoms or a group combining these, and more preferably a trifluoromethyl group, a difluoromethyl group, a methyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, an ethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a propyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4- More preferred are fluorinated alkyl groups such as an octafluorobutyl group, a butyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, a pentyl group, a hexyl group, a perfluorohexyl group, a heptyl group, a perfluoroheptyl group, an octyl group, and a perfluorooctyl group; a cyclopropylmethyl group, a cyclopropyl group, a cyclobutylmethyl group, a cyclopentyl group, a cyclohexyl group, a perfluorocyclohexyl group, an adamantyl group, an adamantylmethyl group, an adamantyldimethyl group, a norbornyl group, a norbornylmethyl group, a perfluoroadamantyl group, and a perfluoroadamantylmethyl group. In formula (a4-2B), *-A 43f -X 43 -R 43fB An example of a structure that the group represented by the formula (I) can take is the following structure (* indicates the bonding site with the carbonyl group). TIFF2025017356000101.tif15170

[0128] The structural unit represented by formula (a4-2A) includes the structural units shown below and R in the structural unit represented by formula (a4-2A) in the structural units shown below. 41 In the structural unit, a methyl group corresponding to the above formula is replaced with a hydrogen atom. TIFF2025017356000102.tif99167

[0129] The structural unit represented by formula (a4-2B) includes the structural units shown below and R in the structural unit represented by formula (a4-2B) in the structural units shown below. 41 In the structural unit, a methyl group corresponding to the above formula is replaced with a hydrogen atom. TIFF2025017356000103.tif111163

[0130] The structural unit (a4-3) is a structural unit represented by the following formula (a4-3). TIFF2025017356000104.tif6545[In formula (a4-3), R 41 represents a hydrogen atom or a methyl group. L 44f represents a saturated hydrocarbon group having 1 to 20 carbon atoms which may have a fluorine atom, and -CH 2 - may be replaced by -O- or -CO-. R 44f represents a saturated hydrocarbon group having 1 to 20 carbon atoms which may have a fluorine atom, and -CH 2 - may be replaced by -O- or -CO-. However, L 44f and R 44f At least one of L has a fluorine atom.44f and R 44f The total number of carbon atoms in the molecule is limited to 21.

[0131] L 44f and R 44f Examples of the saturated hydrocarbon group in include linear or branched chain saturated hydrocarbon groups, monocyclic or polycyclic alicyclic saturated hydrocarbon groups, and groups formed by combining these groups. 44f and R 44f Examples of saturated hydrocarbon groups in the formula are L 43f and R 43f As long as the upper limit of the total number of carbon atoms in 42 Examples of the saturated hydrocarbon group include the same groups as the exemplified saturated hydrocarbon groups. L 44f is an alkanediyl group having 1 to 14 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-.) is preferred, and -(CH 2 ) j1 -, -(CH 2 ) j2 -O-(CH 2 ) j3 -or-(CH 2 ) j4 -CO-O-(CH 2 ) j5 - (j1 to j5 each independently represent an integer of 1 to 6). 2 - may be replaced by -O-, and one -CH 2 -CH 2 It is further preferred that - may be replaced by -CO-O- or -O-CO-. R 44fis preferably a saturated hydrocarbon group having 1 to 10 carbon atoms and having a fluorine atom, more preferably an alkyl group having 1 to 10 carbon atoms and having a fluorine atom, an alicyclic saturated hydrocarbon group having 3 to 10 carbon atoms and having a fluorine atom, or a group combining these, further preferably an alkyl group having 1 to 10 carbon atoms and having a fluorine atom, and even more preferably an alkyl group having 1 to 6 carbon atoms and having a fluorine atom.

[0132] Examples of the structural unit represented by formula (a4-3) include the following structural units and structural units represented by the following formulas: 41 In the structural unit, a methyl group corresponding to the above formula is replaced with a hydrogen atom. TIFF2025017356000105.tif85165

[0133] When the resin (A) or the like contains the structural unit (a4), the content thereof is preferably 1 to 20 mol %, more preferably 2 to 15 mol %, and even more preferably 3 to 10 mol %, based on all structural units in the resin (A) or the like.

[0134] <Structural unit (a5)> The non-leaving hydrocarbon group contained in the structural unit (a5) may be a group containing a linear, branched or cyclic hydrocarbon group. Among these, the structural unit (a5) is preferably a group containing an alicyclic hydrocarbon group. An example of the structural unit (a5) is a structural unit represented by the formula (a5-1). TIFF2025017356000106.tif3971[In formula (a5-1), R 51 represents a hydrogen atom or a methyl group. R 52 represents an alicyclic hydrocarbon group having 3 to 18 carbon atoms, and a hydrogen atom contained in the alicyclic hydrocarbon group may be substituted with an aliphatic hydrocarbon group having 1 to 8 carbon atoms. L 55 represents a single bond or a divalent saturated hydrocarbon group having 1 to 18 carbon atoms, and the -CH 2 - may be replaced by -O- or -CO-.

[0135] R 52 The alicyclic hydrocarbon group in may be either monocyclic or polycyclic. Examples of the monocyclic alicyclic hydrocarbon group include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, and a cyclohexyl group. Examples of the polycyclic alicyclic hydrocarbon group include an adamantyl group, a norbornyl group, and the like. Examples of the aliphatic hydrocarbon group having 1 to 8 carbon atoms include alkyl groups such as a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, a hexyl group, an octyl group, and a 2-ethylhexyl group. An example of the alicyclic hydrocarbon group having a substituent is a 3-methyladamantyl group. R 52 is preferably an unsubstituted alicyclic hydrocarbon group having 3 to 18 carbon atoms, and more preferably an adamantyl group, a norbornyl group, or a cyclohexyl group. L 55 Examples of the divalent saturated hydrocarbon group in include a divalent chain saturated hydrocarbon group and a divalent alicyclic saturated hydrocarbon group, and a divalent chain saturated hydrocarbon group is preferred. Examples of the divalent chain saturated hydrocarbon group include alkanediyl groups such as a methylene group, an ethylene group, a propanediyl group, a butanediyl group, and a pentanediyl group. The divalent alicyclic saturated hydrocarbon group may be either monocyclic or polycyclic. Examples of the monocyclic alicyclic saturated hydrocarbon group include cycloalkanediyl groups such as cyclopentanediyl and cyclohexanediyl. Examples of the polycyclic divalent alicyclic saturated hydrocarbon group include adamantanediyl and norbornanediyl.

[0136] L 55 -CH contained in the divalent saturated hydrocarbon group represented by 2 Examples of the group in which - is replaced by -O- or -CO- include groups represented by formulae (L1-1) to (L1-4). In the following formulae, * and ** each represent a bonding site, and * represents a bonding site with an oxygen atom. TIFF2025017356000107.tif18165[In formula (L1-1), X x1 represents *-O-CO- or *-CO-O- (* represents L x1 ) which represents the binding site with L x1 represents a divalent aliphatic saturated hydrocarbon group having 1 to 16 carbon atoms. L x2 represents a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 15 carbon atoms. However, L x1 and L x2 The total number of carbon atoms is 16 or less. In formula (L1-2), L x3 represents a divalent aliphatic saturated hydrocarbon group having 1 to 17 carbon atoms. L x4 represents a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 16 carbon atoms. However, L x3 and L x4 The total number of carbon atoms is 17 or less. In formula (L1-3), L x5 represents a divalent aliphatic saturated hydrocarbon group having 1 to 15 carbon atoms. L x6 and L x7 each independently represents a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 14 carbon atoms. However, L x5 , L x6 and L x7 The total number of carbon atoms is 15 or less. In formula (L1-4), L x8 and L x9 represents a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 12 carbon atoms. W x1 represents a divalent alicyclic saturated hydrocarbon group having 3 to 15 carbon atoms. However, L x8 , L x9 and W x1 The total number of carbon atoms is 15 or less. L x1is preferably a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms, more preferably a methylene group or an ethylene group. L x2 is preferably a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms, and more preferably a single bond. L x3 is preferably a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms. L x4 is preferably a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms. L x5 is preferably a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms, more preferably a methylene group or an ethylene group. L x6 is preferably a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms, and more preferably a methylene group or an ethylene group. L x7 is preferably a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms. L x8 is preferably a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms, and more preferably a single bond or a methylene group. L x9 is preferably a single bond or a divalent aliphatic saturated hydrocarbon group having 1 to 8 carbon atoms, and more preferably a single bond or a methylene group. W x1 is preferably a divalent alicyclic saturated hydrocarbon group having 3 to 10 carbon atoms, and more preferably a cyclohexanediyl group or an adamantanediyl group. Examples of the group represented by formula (L1-1) include the divalent groups shown below. TIFF2025017356000108.tif37147 Examples of the group represented by formula (L1-2) include the divalent groups shown below. TIFF2025017356000109.tif23130 Examples of the group represented by formula (L1-3) include the divalent groups shown below. TIFF2025017356000110.tif16147Examples of the group represented by formula (L1-4) include the divalent groups shown below. TIFF2025017356000111.tif13168L 55 is preferably a single bond or a group represented by formula (L1-1).

[0137] The structural unit (a5-1) may be any of the structural units shown below and R in the structural unit (a5-1) in the structural unit shown below. 51 In the structural unit, a methyl group corresponding to the above formula is replaced with a hydrogen atom. TIFF2025017356000112.tif111150 When the resin (A) or the like contains the structural unit (a5), the content thereof is preferably from 1 to 30 mol %, more preferably from 2 to 20 mol %, and even more preferably from 3 to 15 mol %, based on all structural units in the resin (A) or the like.

[0138] <Structural unit (a6)> The structural unit (a6) is -SO 2 - group, -SO 2 It is preferred that the aryl group has a - group in the side chain. -SO 2 The structural unit having a - group is -SO 2 - groups, or may have a linear structure having -SO 2 - groups, or may have a branched structure having -SO 2 It may have a cyclic structure (monocyclic or polycyclic structure) having a - group. 2 A structural unit having a cyclic structure having a - group, more preferably, -SO 2 It is a structural unit having a ring structure (sultone ring) containing -O-.

[0139] The sultone ring may be represented by the following formula (T 1 -1), formula (T 1 -2), formula (T 1 -3) and the formula (T 1The binding site can be any position. The sultone ring may be monocyclic, but is preferably polycyclic. A polycyclic sultone ring is one in which the atomic group constituting the ring is -SO 2 It means a bridged ring containing -O-, and has the formula (T 1 -1) and the formula (T 1 The sultone ring is represented by the formula (T 1 -2) The ring is made up of -SO 2 In addition to -O-, the ring may further contain a heteroatom, such as an oxygen atom, a sulfur atom, or a nitrogen atom, and preferably an oxygen atom. TIFF2025017356000113.tif3286 The sultone ring may have a substituent. Examples of the substituent include an alkyl group having 1 to 12 carbon atoms which may have a halogen atom or a hydroxy group, a halogen atom, a hydroxy group, a cyano group, an alkoxy group having 1 to 12 carbon atoms, an aryl group having 6 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, a glycidyloxy group, an alkoxycarbonyl group having 2 to 12 carbon atoms, and an alkylcarbonyl group having 2 to 4 carbon atoms. Examples of halogen atoms include fluorine, chlorine, bromine and iodine atoms. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, an octyl group, and a decyl group, and preferably an alkyl group having 1 to 6 carbon atoms, and more preferably a methyl group. Examples of the alkyl group having a halogen atom include a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluorosec-butyl group, a perfluorotert-butyl group, a perfluoropentyl group, a perfluorohexyl group, a trichloromethyl group, a tribromomethyl group, and a triiodomethyl group, and preferably a trifluoromethyl group. Examples of the alkyl group having a hydroxy group include a hydroxymethyl group and a 2-hydroxyethyl group. Examples of the alkoxy group include a methoxy group, an ethoxy group, a propoxy group, a butoxy group, a pentyloxy group, a hexyloxy group, a heptyloxy group, an octyloxy group, a decyloxy group, and a dodecyloxy group. Examples of the aryl group include a phenyl group, a naphthyl group, an anthryl group, a p-methylphenyl group, a p-tert-butylphenyl group, a p-adamantylphenyl group, a tolyl group, a xylyl group, a cumyl group, a mesityl group, a biphenyl group, a phenanthryl group, a 2,6-diethylphenyl group, and a 2-methyl-6-ethylphenyl group. Aralkyl groups include benzyl, phenethyl, phenylpropyl, naphthylmethyl and naphthylethyl groups. Examples of the alkoxycarbonyl group include groups in which an alkoxy group, such as a methoxycarbonyl group or an ethoxycarbonyl group, is bonded to a carbonyl group, and preferably, an alkoxycarbonyl group having 6 or less carbon atoms is used, and more preferably, a methoxycarbonyl group is used. Alkylcarbonyl groups include acetyl, propionyl and butyryl groups. From the viewpoint of ease of production of the monomer from which the structural unit (a6) is derived, a sultone ring having no substituent is preferred.

[0140] The sultone ring is preferably a ring represented by the following formula (T1'). TIFF2025017356000114.tif3271[In formula (T1'), X 11 represents an oxygen atom, a sulfur atom, or a methylene group. R 41 represents an alkyl group having 1 to 12 carbon atoms which may have a halogen atom or a hydroxy group, a halogen atom, a hydroxy group, a cyano group, an alkoxy group having 1 to 12 carbon atoms, an aryl group having 6 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, a glycidyloxy group, an alkoxycarbonyl group having 2 to 12 carbon atoms, or an alkylcarbonyl group having 2 to 4 carbon atoms. ma represents an integer of 0 to 9. When ma is 2 or more, multiple R 41may be the same or different. The binding site is at any position.] X 11 is preferably an oxygen atom or a methylene group, and more preferably a methylene group. R 41 Examples of the substituent include the same ones as the substituents on the sultone ring, and an alkyl group having 1 to 12 carbon atoms which may have a halogen atom or a hydroxyl group is preferred. ma is preferably 0 or 1, and more preferably 0.

[0141] Examples of the ring represented by formula (T1') include the following rings. The binding site may be any position. Among them, the binding site is preferably the 1st or 3rd position. TIFF2025017356000115.tif47148-SO 2 The structural unit having a - group preferably further has a group derived from a polymerizable group, such as a vinyl group, an acryloyl group, a methacryloyl group, an acryloyloxy group, a methacryloyloxy group, an acryloylamino group, a methacryloylamino group, an acryloylthio group, or a methacryloylthio group. Among these, the monomer from which the structural unit (a6) is derived is preferably a monomer having an ethylenically unsaturated bond, and more preferably a (meth)acrylic monomer.

[0142] The structural unit (a6) is preferably a structural unit represented by the formula (a6-0). TIFF2025017356000116.tif4863[In formula (a6-0), R x represents an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, a hydrogen atom, or a halogen atom. A xx is an oxygen atom, -N(R c )- or a sulfur atom. A x represents a single bond or a divalent saturated hydrocarbon group having 1 to 18 carbon atoms, and the -CH 2- is -O-, -CO- or -N(R d )- may also be replaced. X 11 represents an oxygen atom, a sulfur atom, or a methylene group. R 41 represents an alkyl group having 1 to 12 carbon atoms which may have a halogen atom or a hydroxy group, a halogen atom, a hydroxy group, a cyano group, an alkoxy group having 1 to 12 carbon atoms, an aryl group having 6 to 12 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, a glycidyloxy group, an alkoxycarbonyl group having 2 to 12 carbon atoms, or an alkylcarbonyl group having 2 to 4 carbon atoms. ma represents an integer of 0 to 9. When ma is 2 or more, multiple R 41 may be the same or different. R c and R d each independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.] R x Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom and an iodine atom. R x Examples of the alkyl group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, an n-pentyl group, and an n-hexyl group. An alkyl group having 1 to 4 carbon atoms is preferred, and a methyl group or an ethyl group is more preferred. R x Examples of the alkyl group having a halogen atom include a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluorosec-butyl group, a perfluorotert-butyl group, a perfluoropentyl group, a perfluorohexyl group, a trichloromethyl group, a tribromomethyl group, and a triiodomethyl group. R x is preferably a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, more preferably a hydrogen atom, a methyl group, or an ethyl group, and even more preferably a hydrogen atom or a methyl group. A xExamples of the divalent saturated hydrocarbon group include a linear alkanediyl group, a branched alkanediyl group, and a monocyclic or polycyclic divalent alicyclic saturated hydrocarbon group, and may be a combination of two or more of these groups. Specifically, methylene group, ethylene group, propane-1,3-diyl group, propane-1,2-diyl group, butane-1,4-diyl group, pentane-1,5-diyl group, hexane-1,6-diyl group, heptane-1,7-diyl group, octane-1,8-diyl group, nonane-1,9-diyl group, decane-1,10-diyl group, undecane-1,11-diyl group, linear alkanediyl groups such as a dodecane-1,12-diyl group, a tridecane-1,13-diyl group, a tetradecane-1,14-diyl group, a pentadecane-1,15-diyl group, a hexadecane-1,16-diyl group, a heptadecane-1,17-diyl group, an ethane-1,1-diyl group, a propane-1,1-diyl group, and a propane-2,2-diyl group; branched alkanediyl groups such as butane-1,3-diyl, 2-methylpropane-1,3-diyl, 2-methylpropane-1,2-diyl, pentane-1,4-diyl, and 2-methylbutane-1,4-diyl; monocyclic divalent alicyclic saturated hydrocarbon groups such as cycloalkanediyl groups, such as cyclobutane-1,3-diyl, cyclopentane-1,3-diyl, cyclohexane-1,4-diyl, and cyclooctane-1,5-diyl; Examples of the polycyclic divalent alicyclic saturated hydrocarbon groups include norbornane-1,4-diyl group, norbornane-2,5-diyl group, adamantane-1,5-diyl group, and adamantane-2,6-diyl group. A x The bonding position of to the sultone ring may be any position, but is preferably the 1-position.

[0143] Examples of the structural unit (a6-0) include the following structural units. TIFF2025017356000117.tif93150Of these, structural units represented by formulae (a6-1), (a6-2), (a6-6), (a6-7), (a6-8) and (a6-12) are preferred, and structural units represented by formulae (a6-1), (a6-2), (a6-7) and (a6-8) are more preferred. When the resin (A) or the like contains the structural unit (a6), the content thereof is preferably 1 to 50 mol %, more preferably 2 to 40 mol %, and even more preferably 3 to 30 mol %, based on all structural units in the resin (A) or the like.

[0144] <Structural unit (a7)> The resin may further contain a structural unit that decomposes upon exposure to generate an acid (hereinafter, sometimes referred to as "structural unit (a7)", except for the structural unit represented by formula (IP). Specific examples of the structural unit (a7) include structural units described in JP 2016-79235 A, and the structural unit is preferably a structural unit having a sulfonate group or carboxylate group and an organic cation in the side chain, or a structural unit having a sulfonio group and an organic anion in the side chain. The structural unit having a sulfonate group or carboxylate group and an organic cation in the side chain is preferably a structural unit represented by formula (a7-A). TIFF2025017356000118.tif26124[In formula (a7-A), R a7 represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. X a71 is a single bond, *-O-**, *-CO-O-**, *-O-CO-O-**, *-CO-NR a71 -**, *-NR a71 -CO-O-**, *-O-CO-NR a71 -** or *-Ax-Ph-Ay-**. R a71 represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. Ph represents a phenylene group which may have a substituent. Ax and Ay each independently represent one type of bond selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate bond. * and ** represent binding sites, * represents R a7 represents the bonding site with the carbon atom to which it is bonded. L a71 and L a72 each independently represents a hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced. X a72 represents ***-CO-O-, ***-O-CO-, ***-O-CO-O-, ***-O-, and *** represents L a71 represents the binding site with na7 represents an integer of 0 to 2. When na7 is 2, the groups in the parentheses may be the same or different. RA - represents a sulfonate anion or a carboxyl anion. Z.A. + represents an organic cation.

[0145] R a7 and R a71 Examples of the alkyl group having 1 to 6 carbon atoms in the formula include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group. R a7 Examples of the halogen atom in include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. R a7Examples of the alkyl group having 1 to 6 carbon atoms and having a halogen atom in the formula (I) include a trifluoromethyl group, a difluoromethyl group, a perfluoroethyl group, a 2,2,2-trifluoroethyl group, a 1,1,2,2-tetrafluoroethyl group, a perfluoropropyl group, a 2,2,3,3,3-pentafluoropropyl group, a perfluorobutyl group, a 1,1,2,2,3,3,4,4-octafluorobutyl group, a perfluoropentyl group, a 2,2,3,3,4,4,5,5,5-nonafluoropentyl group, a perfluorohexyl group, a trichloromethyl group, a dichloromethyl group, a triiodomethyl group, a diiodomethyl group, a tribromomethyl group, and a dibromomethyl group. R a7 is preferably a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, more preferably a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, still more preferably a hydrogen atom, a methyl group or an ethyl group, and even more preferably a hydrogen atom or a methyl group.

[0146] X a71 is a group represented by *-Ax-Ph-Ay-**, it is preferably a linking group represented by the following formula (X10). TIFF2025017356000119.tif3251[In formula (X10), Ax is R a7 represents a bond type bonded to the carbon atom to which is bonded, and represents one type of bond selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, a carbonate bond, and an amide bond. Ay is L a71 represents a bond type that bonds with, and represents one type of bond selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, a carbonate bond, and an amide bond. Rx represents a halogen atom, a hydroxy group, a fluorinated alkyl group having 1 to 6 carbon atoms, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms. mx represents an integer of 0 to 4, and when mx is an integer of 2 or more, multiple Rx's may be the same or different. When either Ax or Ay is a single bond, the other is preferably one selected from the group consisting of an ether bond, a thioether bond, an ester bond, a carbonate ester bond, and an amide bond. When either Ax or Ay is an amide bond, -CO-NR a71 A bond represented by - is preferred. The bonding position of Ay in the phenylene group is preferably the m-position or p-position relative to the bonding position of Ax, and more preferably the p-position. Among these, Rx is preferably a fluorine atom, an iodine atom, a trifluoromethyl group, a methyl group or an ethyl group. mx is preferably 0, 1 or 2. X a71 Examples of the substituent include a single bond and a substituent represented by the following formula (X 10 -1)~Formula(X 10 -10) is a group represented by * -R a7 represents the bonding site with the carbon atom to which L is bonded. a71 It represents the binding site with X 20 is -O- or -NR a71 - represents. TIFF2025017356000120.tif43161 expression (X 10 -1)~Formula(X 10 Specific examples of the group represented by -10) include the following groups. TIFF2025017356000121.tif88162 Among them, X a71 is a single bond and the formula (X 10 -1'), expression (X 10 -3')~expression(X 10 -9'), which is preferably a single bond or a group represented by the formula (X 10 -1'), expression (X 10 -4'), expression (X 10 -5'), expression (X 10 -6') and formula (X 10 -9'), a single bond, a group represented by the formula (X 10 -1'), a group represented by the formula (X 10 -5'), a group represented by the formula (X 10-6') or formula (X 10 -9') is more preferable.

[0147] L a71 The hydrocarbon group is a group formed by removing one hydrogen atom from a chain hydrocarbon group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, or a group combining two or more of these groups, to form X. a71 and X a72 Also, L a72 The hydrocarbon group is a group formed by removing one hydrogen atom from a chain hydrocarbon group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, or a group combining two or more of these groups, to form X. a72 and R.A. - Examples of such groups include groups that bond to the L a71 and L a72 Examples of the chain hydrocarbon group include a group in which one hydrogen atom has been removed from an alkyl group or an alkenyl group. The alkyl group may be linear or branched, and specific examples thereof include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a tetradecyl group, a pentanedecyl group, and a heptadecyl group. Examples of the alkenyl group include an ethenyl group, a propenyl group, an isopropenyl group, a butenyl group, an isobutenyl group, a tert-butenyl group, a pentenyl group, a hexenyl group, a heptenyl group, an octenyl group, an isooctenyl group, and a nonenyl group. The chain hydrocarbon group preferably has 1 to 20 carbon atoms, more preferably 1 to 18 carbon atoms, and even more preferably 1 to 10 carbon atoms. L a71 and L a72 Examples of the alicyclic hydrocarbon group include a group in which one hydrogen atom has been removed from a monocyclic or polycyclic cycloalkyl group. Examples of the monocyclic cycloalkyl group include a cyclobutyl group, a cycloheptyl group, a cyclohexyl group, a cyclopentyl group, and a cyclooctyl group. L a71 and La72 Examples of the polycyclic cycloalkyl group include a cycloalkyl group having a bridged structure, a cycloalkyl group in which two or more rings are condensed, or a cycloalkyl group in which two rings are bonded by a spiro bond. Examples of the cycloalkyl group having a bridged structure include a norbornyl group and an adamantyl group. Examples of the cycloalkyl group in which two or more rings are condensed include a bicyclo[4,4,0]decane group and a steroid group (steroid skeleton). Examples of the cycloalkyl group in which two rings are bonded by a spiro bond include a spirocyclic cycloalkyl group in which one cycloalkyl group selected from the group consisting of a cyclopentyl group, a cyclohexyl group, a norbornyl group, and an adamantyl group is bonded by a spiro bond to a cycloalkyl group having 5 to 8 carbon atoms. A double bond may be formed between two carbon atoms contained in the alicyclic hydrocarbon group. More specifically, examples of the alicyclic hydrocarbon group include the following formula: TIFF2025017356000122.tif28158When the alicyclic hydrocarbon group is a monocyclic cycloalkyl group, the alicyclic hydrocarbon group preferably has 3 to 18 carbon atoms, more preferably 3 to 12, and even more preferably 3 to 8. When the alicyclic hydrocarbon group is a polycyclic cycloalkyl group, the alicyclic hydrocarbon group preferably has 6 to 18 carbon atoms, and more preferably 7 to 12. L a71 and L a72 The aromatic hydrocarbon group may be a group in which one hydrogen atom has been removed from an aryl group. Examples of the aryl group include a phenyl group, a naphthyl group, an anthryl group, a biphenyl group, and a fluorenyl group. The number of carbon atoms in the aromatic hydrocarbon group is preferably 5 to 14, more preferably 6 to 14, and further preferably 6 to 10. L a71 and L a72 -CH contained in the hydrocarbon group 2 - is -O-, -CO-, -S- or -SO 2 When it is replaced with -, the number of carbon atoms before the replacement is regarded as the number of carbon atoms of the hydrocarbon group. L a71 and L a72Among the hydrocarbon groups, -CH 2 - is -O-, -CO-, -S- or -SO 2 The group substituted for - is a hydroxy group (-CH 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH 2 - is replaced by -O-CO-), thiol group (-CH 2 - is replaced by -S-), carbonyl group (-CH 2 - is replaced by -CO-), oxy group (-CH 2 - is replaced by -O-), thio group (-CH 2 - is replaced by -S-), sulfonyl group (-CH 2 -But-SO 2 - substituted), alkoxy group (-CH at any position in the alkyl group) 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), alkanediyloxy group (-CH at any position in the alkanediyl group) 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group)2 -CH 2 Examples of these substituted groups include those similar to the groups exemplified in this specification, within the range permitted by the upper limit of the number of carbon atoms. L a71 and L a72 Among the hydrocarbon groups, -CH contained in alicyclic hydrocarbon groups 2 - is -O-, -CO-, -S- or -SO 2 Examples of the group substituted with - include groups containing a cyclic ether, cyclic ketone, cyclic ester (lactone), cyclic thioether, cyclic acetal, and cyclic sulfonate ester (sultone) structure. Specific examples include alicyclic hydrocarbon groups represented by the following formula. The bonding position of the alicyclic hydrocarbon groups represented by the following formula may be any position. TIFF2025017356000123.tif46146L a71 and L a72 Among the hydrocarbon groups, -CH contained in aromatic hydrocarbon groups 2 - may be replaced by -O- or -S-, -CH 2 Examples of the group in which - is replaced by -O- or -S- include groups derived from a furan ring or a thiophene ring, respectively. L a71 and L a72 Examples of the group in which two or more of the chain hydrocarbon group, alicyclic hydrocarbon group, and aromatic hydrocarbon group are combined include a group in which the chain hydrocarbon group and the alicyclic hydrocarbon group are combined, a group in which the chain hydrocarbon group and the aromatic hydrocarbon group are combined, a group in which the alicyclic hydrocarbon group and the aromatic hydrocarbon group are combined, and a group in which the chain hydrocarbon group, the alicyclic hydrocarbon group and the aromatic hydrocarbon group are combined. The group in which the alicyclic hydrocarbon group and the aromatic hydrocarbon group are combined may be a condensed ring. L a71 and L a72 The substituents which the hydrocarbon group may have include a halogen atom, a cyano group, and a nitro group. Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. La71 and L a72 When L is a group in which an alicyclic hydrocarbon group or an aromatic hydrocarbon group is combined with a chain hydrocarbon group, the chain hydrocarbon group may be regarded as a substituent that the alicyclic hydrocarbon group or the aromatic hydrocarbon group has. a71 and L a72 The -CH chain hydrocarbon group contained in the hydrocarbon group 2 - is -O-, -CO-, -S- or -SO 2 - is replaced by L a71 and L a72 The hydrocarbon group may substantially have a substituent such as a hydroxy group, a carboxy group, an alkoxy group, an alkylcarbonyl group, an alkoxycarbonyl group, an alkylcarbonyloxy group, a thiol group, or a sulfonyl group. na7 is preferably 0 or 1. ZA in formula (a7-A) + Examples of the cation include the same as the cation in the salt represented by formula (B1) etc.

[0148] In formula (a7-A), L a71 and L a72 When the hydrocarbon group is a saturated hydrocarbon group, in the formula (a7-B) described later, b7 The divalent linking group may include the same groups as those exemplified above. Examples of the structural unit represented by formula (a7-A) include a structural unit represented by formula (a7-A1). TIFF2025017356000124.tif30138[In formula (a7-A1), R a7 , X a71 , L a71 , X a72 , na7, R.A. - and Z.A. + has the same meaning as above. z7 represents an integer of 0 to 6. Q a7 , Q b7 , R z71 and R z72each independently represents a hydrogen atom, a fluorine atom, a perfluoroalkyl group having 1 to 6 carbon atoms, or an alkyl group having 1 to 6 carbon atoms; when z7 is 2 or more, z71 and R z72 may be the same or different.] Q a7 , Q b7 , R z71 and R z72 As the perfluoroalkyl group having 1 to 6 carbon atoms or the alkyl group having 1 to 6 carbon atoms in R a7 Examples of the groups include the same groups as those exemplified in the above.

[0149] Examples of the structural unit represented by formula (a7-A) include the following structural units, R a7 Examples of the structural units include those in which the group corresponding to the methyl group in the above formula (I) is replaced with a hydrogen atom, a halogen atom (e.g., a fluorine atom) or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom (e.g., a trifluoromethyl group, etc.), and the structural units described in WO 2012 / 050015. + represents an organic cation. TIFF2025017356000125.tif244163

[0150] TIFF2025017356000126.tif131160

[0151] The structural unit having a sulfonio group and an organic anion on the side chain is preferably a structural unit represented by formula (a7-B). TIFF2025017356000127.tif27104[In formula (a7-B), R a7 represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. A b7 represents a single bond or a divalent linking group. R b71 represents a divalent aromatic hydrocarbon group having 6 to 18 carbon atoms which may have a substituent. R b72 and R b73each independently represents a hydrocarbon group having 1 to 18 carbon atoms which may have a substituent; R b72 and R b73 may be bonded to each other to form a ring together with the sulfur atom to which they are attached. A - represents an organic anion. R a7 Examples of the halogen atom and the alkyl group which may have a halogen atom in the formula (a7-A) include the same halogen atom and the alkyl group which may have a halogen atom as in the formula (a7-A). R b71 Examples of the divalent aromatic hydrocarbon group having 6 to 18 carbon atoms represented by the formula (I) include a phenylene group and a naphthylene group. R b72 and R b73 Examples of the hydrocarbon group represented by the formula (I) include an alkyl group, an alicyclic hydrocarbon group, an aromatic hydrocarbon group, and a group formed by combining these groups. Examples of the alkyl group, alicyclic hydrocarbon group, aromatic hydrocarbon group, and groups formed by combining these groups include those similar to those described above. A b7 Examples of the divalent linking group represented by the formula (I) include a divalent saturated hydrocarbon group having 1 to 18 carbon atoms. 2 - may be replaced by -O-, -S- or -CO-. Examples of the divalent saturated hydrocarbon group include divalent chain saturated hydrocarbon groups such as linear or branched alkanediyl groups, and monocyclic or polycyclic divalent alicyclic saturated hydrocarbon groups, and combinations of these are also possible. Specifically, straight-chain alkanediyl groups such as methylene group, ethylene group, propane-1,3-diyl group, propane-1,2-diyl group, butane-1,4-diyl group, pentane-1,5-diyl group, hexane-1,6-diyl group, heptane-1,7-diyl group, octane-1,8-diyl group, nonane-1,9-diyl group, decane-1,10-diyl group, undecane-1,11-diyl group, and dodecane-1,12-diyl group; divalent monocyclic alicyclic saturated hydrocarbon groups such as monocyclic cycloalkanediyl groups, such as cyclobutane-1,3-diyl group, cyclopentane-1,3-diyl group, cyclohexane-1,4-diyl group, and cyclooctane-1,5-diyl group; and divalent polycyclic alicyclic saturated hydrocarbon groups, such as polycyclic cycloalkanediyl groups, such as norbornane-1,4-diyl group, norbornane-2,5-diyl group, adamantane-1,5-diyl group, and adamantane-2,6-diyl group. -CH contained in saturated hydrocarbon groups 2 Examples of the divalent groups in which - is replaced by -O-, -S- or -CO- include the following divalent groups. However, -CH contained in a saturated hydrocarbon group is not included. 2 The number of carbon atoms before - is replaced by -O-, -S-, or -CO- is 17 or less. In the following formula, * and ** represent binding sites, * represents R b71 represents the binding site with TIFF2025017356000128.tif123162[where X 3 represents a divalent saturated hydrocarbon group having 1 to 16 carbon atoms. X 4 represents a divalent saturated hydrocarbon group having 1 to 15 carbon atoms. X 5 represents a divalent saturated hydrocarbon group having 1 to 13 carbon atoms. X 6 represents a divalent saturated hydrocarbon group having 1 to 14 carbon atoms. X 7 represents a trivalent saturated hydrocarbon group having 1 to 14 carbon atoms. X8 represents a divalent saturated hydrocarbon group having 1 to 13 carbon atoms.

[0152] The structural unit containing a cation in formula (a7-B) includes the structural units represented by the following formula: a7 Examples of such structural units include those in which a group corresponding to the methyl group in the above formula (I) is replaced with a hydrogen atom, a halogen atom (e.g., a fluorine atom), or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom (e.g., a trifluoromethyl group, etc.). JPEG2025017356000129.jpg72164

[0153] A - Examples of the organic anion represented by the formula (I) include a sulfonate anion, a sulfonylimide anion, a sulfonylmethide anion, and a carboxylate anion. - The organic anion represented by the formula (I) is preferably a sulfonate anion, and the sulfonate anion is more preferably the same as the anion exemplified for the acid generator (B). Examples of the sulfonylimide anion, sulfonylmethide anion, and carboxylate anion include the same anions exemplified for the acid generator (B).

[0154] Examples of the structural unit represented by formula (a7-B) include structural units represented below. TIFF2025017356000130.tif95157 When the resin (A) or the like contains the structural unit (a7), the structural unit (a7) may be contained alone or in combination of two or more kinds. The total content of the structural unit (a7) is preferably 1 to 30 mol%, more preferably 1 to 25 mol%, even more preferably 2 to 20 mol%, still more preferably 3 to 15 mol%, and even more preferably 3 to 10 mol%, based on the total structural units of the resin (A) or the like.

[0155] The resin (A) etc. is preferably a resin containing the structural unit (a1). In particular, the resin (Ap) is more preferably a resin consisting of the structural unit (IP), the structural unit (a1) and the structural unit (s), that is, a copolymer of the carboxylate (I), the monomer (a1) and the monomer (s). The resin (A) not containing the structural unit (IP) is preferably a resin consisting of the structural unit (a1) and the structural unit (s), that is, a copolymer of the monomer (a1) and the monomer (s). The structural unit (a1) is preferably at least one selected from the group consisting of the structural unit (a1-0), the structural unit (a1-1), the structural unit (a1-2) (preferably the structural unit having a cyclohexyl group or a cyclopentyl group), the structural unit represented by formula (a1-4), the structural unit represented by formula (a1-5), and the structural unit represented by formula (a1-6), more preferably at least two, and even more preferably at least two selected from the group consisting of the structural unit (a1-1) and the structural unit (a1-2). The structural unit (s) is preferably at least one selected from the group consisting of the structural unit (a2) and the structural unit (a3). The structural unit (a2) is preferably the structural unit (a2-C) or the structural unit (a2-A). The structural unit (a3) ​​is preferably at least one selected from the group consisting of the structural unit represented by the formula (a3-1), the structural unit represented by the formula (a3-2), and the structural unit represented by the formula (a3-4).

[0156] Each structural unit constituting the resin (A) may be used alone or in combination of two or more, and can be produced by a known polymerization method (for example, radical polymerization method) using a monomer that leads to these structural units. The content of each structural unit contained in the resin (A) can be adjusted by the amount of monomer used for polymerization. The weight average molecular weight of the resin (Ap) and the resin (A) is preferably 2,000 or more (more preferably 2,500 or more, even more preferably 3,000 or more) and 50,000 or less (more preferably 30,000 or less, even more preferably 15,000 or less), but may contain an oligomer having a weight average molecular weight smaller than this. In this specification, the weight average molecular weight is a value determined by gel permeation chromatography under the conditions described in the Examples. The structural unit (IP) may constitute a dimer, a trimer, or a compound or oligomer having a weight average molecular weight of less than 2,000.

[0157] [Resist Composition] The resist composition of the present invention contains the carboxylic acid generator of the present invention. The carboxylic acid generator here contains a carboxylate (I) and / or a structural unit (IP), and may contain any known carboxylic acid generator. The structural unit (IP) may be in the form of a compound or a resin. In other words, the resist composition of the present invention may contain a resin (Ap) and a carboxylate (I) as a carboxylic acid generator. The resist composition of the present invention may contain, in addition to the carboxylic acid generator of the present invention, an acid generator other than the carboxylic acid generator (hereinafter sometimes referred to as "acid generator (B)"). The resist composition of the present invention may also contain a resin. The resin may be a resin (A) containing a structural unit (a1) having an acid labile group, or may not contain a structural unit (a1). However, it is preferable that the resist composition contains a resin (A) containing a structural unit (a1) having an acid labile group. That is, at least (a) a resin (A) containing a carboxylate (I) and a structural unit (a1) having an acid labile group, (b) a resin (Ap) containing a structural unit (IP) and a structural unit (a1) having an acid labile group; (c) It is more preferable that the resin (Ap) contains the structural unit (IP) and the resin (A) contains a structural unit (a1) having an acid labile group. Among them, a resist composition containing the above (b) structural unit (IP) and a resin (Ap) containing a structural unit (a1) having an acid labile group is preferable. Two or more kinds of resins (A) and / or resins (Ap) may be contained. The resist composition of the present invention preferably further contains an acid generator (hereinafter sometimes referred to as "acid generator (B)" or "compound (B)"), a quencher (hereinafter sometimes referred to as "quencher (C)") and / or a solvent (hereinafter sometimes referred to as "solvent (E)") that are known in the resist field. The resist composition of the present invention may further contain a resin other than the above-mentioned resin (A) etc.

[0158] [Carboxylic Acid Generator] The content of the carboxylate (I) of the present invention is preferably about 0.001 to 15 mass%, more preferably about 0.001 to 10 mass%, even more preferably about 0.001 to 8 mass%, and even more preferably about 0.005 to 7 mass%, based on the solid content of the resist composition. The content of the resin (Ap) of the present invention is preferably from 80 to 99% by mass, and more preferably from 90 to 99% by mass, based on the solid content of the resist composition.

[0159] <Acid Generator (B)> The acid generator (B) may be either a nonionic compound or an ionic compound. Examples of nonionic compounds include sulfonate esters (e.g., 2-nitrobenzyl ester, aromatic sulfonate, oxime sulfonate, N-sulfonyloxyimide, sulfonyloxyketone, diazonaphthoquinone 4-sulfonate), sulfones (e.g., disulfone, ketosulfone, sulfonyldiazomethane), and the like. Examples of ionic compounds include onium salts containing onium cations (e.g., diazonium salts, phosphonium salts, sulfonium salts, iodonium salts). Examples of anions of onium salts include sulfonate anion, sulfonylimide anion, sulfonylmethide anion, and carboxylate anion. The acid generator (B) may be a part of a structural unit constituting the resin contained in the resist composition, like the structural unit (a7) described above.

[0160] As the acid generator (B), compounds that generate acid by radiation, such as those described in JP-A-63-26653, JP-A-55-164824, JP-A-62-69263, JP-A-63-146038, JP-A-63-163452, JP-A-62-153853, JP-A-63-146029, U.S. Pat. No. 3,779,778, U.S. Pat. No. 3,849,137, German Patent No. 3914407, and European Patent No. 126,712, can be used. Compounds produced by known methods can also be used. The acid generator (B) can be used alone or in combination of two or more. The acid generator (B) may be an acid generator having an acid labile group. For example, the compound or resin serving as the acid generator may contain a partial structure that becomes an acid labile group.

[0161] A preferred embodiment of the acid generator (B) is a salt represented by formula (B1) (hereinafter may be referred to as "salt (B1)" or "acid generator (B1)") or a salt represented by formula (B2) (hereinafter may be referred to as "salt (B2)" or "acid generator (B2)"). TIFF2025017356000131.tif1392 [In formula (B1), all symbols have the same meanings as defined above.] L b1 The (nb1+1)-valent hydrocarbon group is a monovalent chain hydrocarbon group, a monovalent alicyclic hydrocarbon group, a monovalent aromatic hydrocarbon group, or a monovalent group that is a combination of two or more of these groups, from which nb1 hydrogen atoms have been removed to form one or more L b2 Examples of such groups include groups that bond to the The hydrocarbon group preferably has 1-48 carbon atoms, more preferably 1-42 carbon atoms, even more preferably 1-36 carbon atoms, even more preferably 1-30 carbon atoms, and even more preferably 1-24 carbon atoms. Examples of the chain hydrocarbon group include a group in which nb1 hydrogen atoms have been removed from an alkyl group or an alkenyl group. The alkyl group may be linear or branched, and specific examples thereof include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, an isobutyl group, a tert-butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a tetradecyl group, a pentanedecyl group, and a heptadecyl group. Examples of the alkenyl group include an ethenyl group, a propenyl group, an isopropenyl group, a butenyl group, an isobutenyl group, a tert-butenyl group, a pentenyl group, a hexenyl group, a heptenyl group, an octenyl group, an isooctenyl group, and a nonenyl group. The number of carbon atoms in the chain hydrocarbon group is preferably 1 to 36, more preferably 1 to 24, even more preferably 1 to 20, still more preferably 1 to 18, even more preferably 1 to 12, and even more preferably 1 to 10. Examples of the alicyclic hydrocarbon group include a group in which nb1 hydrogen atoms have been removed from a monocyclic or polycyclic cycloalkyl group. Examples of the monocyclic cycloalkyl group include a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, and a cyclooctyl group. Examples of polycyclic cycloalkyl groups include cycloalkyl groups having a bridged structure, cycloalkyl groups in which two or more rings are condensed, and cycloalkyl groups in which two rings are bonded by a spiro bond. Examples of cycloalkyl groups having a bridged structure include a norbornyl group and an adamantyl group. Examples of cycloalkyl groups in which two or more rings are condensed include a bicyclo[4,4,0]decane group and a steroid group (steroid skeleton). Examples of cycloalkyl groups in which two rings are bonded by a spiro bond include spirocyclic cycloalkyl groups in which one cycloalkyl group selected from the group consisting of a cyclopentyl group, a cyclohexyl group, a norbornyl group, and an adamantyl group is bonded by a spiro bond to a cycloalkyl group having 5 to 8 carbon atoms. A double bond may be formed between two carbon atoms contained in the alicyclic hydrocarbon group. More specifically, alicyclic hydrocarbon groups represented by the following formulas are included. TIFF2025017356000132.tif26168When the alicyclic hydrocarbon group is a monocyclic cycloalkyl group, the number of carbon atoms in the alicyclic hydrocarbon group is preferably 3 to 24, more preferably 3 to 20, even more preferably 3 to 18, even more preferably 3 to 12, even more preferably 3 to 10, and even more preferably 3 to 8.When the alicyclic hydrocarbon group is a polycyclic cycloalkyl group, the number of carbon atoms in the alicyclic hydrocarbon group is preferably 6 to 24, more preferably 6 to 20, even more preferably 6 to 18, even more preferably 6 to 12, and even more preferably 7 to 12. The aromatic hydrocarbon group may be an aryl group having nb1 hydrogen atoms removed therefrom, such as a phenyl group, a naphthyl group, an anthryl group, a biphenyl group, or a fluorenyl group. More specifically, aromatic hydrocarbon groups represented by the following formulas are included. TIFF2025017356000133.tif1285The number of carbon atoms in the aromatic hydrocarbon group is preferably 4 to 24, more preferably 4 to 20, even more preferably 4 to 18, even more preferably 5 to 14, even more preferably 5 to 10, and even more preferably 6 to 10. L b1 -CH contained in the hydrocarbon group 2 - is -O-, -CO-, -S- or -SO 2 When it is replaced with -, the number of carbon atoms before the replacement is regarded as the number of carbon atoms of the hydrocarbon group. L b1 Among the hydrocarbon groups, -CH 2 - is -O-, -CO-, -S- or -SO 2 The group substituted for - is a hydroxy group (-CH 2 - is replaced by -O-), carboxy group (-CH contained in ethyl group) 2 -CH2 - is replaced by -O-CO-), carbonyl group (-CH 2 - is replaced by -CO-), oxy group (-CH 2 - is replaced by -O-), alkoxy group (-CH 2 - is replaced by -O-), alkoxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkylcarbonyl group (-CH 2 - is replaced by -CO-), alkylcarbonyloxy group (-CH 2 -CH 2 - is replaced by -CO-O-), alkanediyloxy group (-CH at any position in the alkanediyl group) 2 - is replaced by -O-), alkanediyloxycarbonyl group (-CH 2 -CH 2 - is replaced by -O-CO-), alkanediylcarbonyl group (-CH at any position in the alkanediyl group) 2 - is replaced by -CO-), alkanediylcarbonyloxy group (-CH at any position in the alkanediyl group) 2 -CH 2 Examples of these substituted groups include those similar to the groups exemplified in this specification, within the range permitted by the upper limit of the number of carbon atoms. L b1 Among the hydrocarbon groups, -CH contained in alicyclic hydrocarbon groups 2 - is -O-, -CO-, -S- or -SO 2Examples of the group substituted with - include groups containing structures such as cyclic ether, cyclic ketone, cyclic ester (lactone), cyclic thioether, cyclic acetal, and cyclic sulfonate ester (sultone). Specific examples include alicyclic hydrocarbon groups represented by the following formula. The bonding position of the alicyclic hydrocarbon groups represented by the following formula may be any position. TIFF2025017356000134.tif48165L b1 Among the hydrocarbon groups, -CH contained in aromatic hydrocarbon groups 2 - may be replaced by -O- or -S-, -CH 2 Examples of the group in which - is replaced by -O- or -S- include groups derived from a furan ring or a thiophene ring, etc. Specific examples include aromatic hydrocarbon groups represented by the following formulas. TIFF2025017356000135.tif1325 Examples of the group that combines two or more groups selected from the group consisting of a chain hydrocarbon group, an alicyclic hydrocarbon group, and an aromatic hydrocarbon group include a group that combines the above chain hydrocarbon group with the above alicyclic hydrocarbon group, a group that combines the above chain hydrocarbon group with the above aromatic hydrocarbon group, a group that combines the above alicyclic hydrocarbon group with the above aromatic hydrocarbon group, and a group that combines the above chain hydrocarbon group with the above alicyclic hydrocarbon group with the above aromatic hydrocarbon group. The group that combines an alicyclic hydrocarbon group with an aromatic hydrocarbon group may be a condensed ring. L b2 The divalent hydrocarbon group includes a divalent chain hydrocarbon group, a divalent alicyclic hydrocarbon group, a divalent aromatic hydrocarbon group, and a group combining two or more of these groups. b1 Examples of such groups include groups that bond to the L b2 The divalent chain hydrocarbon group, the divalent alicyclic hydrocarbon group, the divalent aromatic hydrocarbon group, and the divalent group consisting of two or more of these groups are each, within the range permitted by the upper limit of the number of carbon atoms, L b1 Examples of the monovalent hydrocarbon group include a monovalent chain hydrocarbon group, a monovalent alicyclic hydrocarbon group, a monovalent aromatic hydrocarbon group, and a monovalent group obtained by combining two or more of these groups from which one hydrogen atom has been removed. L b1 and L b2 Examples of the substituent that the hydrocarbon group may have include a halogen atom, a cyano group, a nitro group, and the like. Examples of the halogen atom include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. L b1 and L b2 In the case where L is a group in which an alicyclic hydrocarbon group or an aromatic hydrocarbon group is combined with a chain hydrocarbon group, the chain hydrocarbon group may be regarded as a substituent that the alicyclic hydrocarbon group or the aromatic hydrocarbon group has. b1 and L b2 The -CH chain hydrocarbon group contained in the hydrocarbon group 2 - is -O-, -CO-, -S- or -SO 2 - is replaced by L b1 and L b2 The hydrocarbon group may substantially have a substituent such as a hydroxy group, a carboxy group, a carbonyl group, an oxycarbonyl group, a carbonyloxy group, an alkoxy group, an alkylcarbonyl group, an alkoxycarbonyl group, an alkylcarbonyloxy group, a thiol group, or a sulfonyl group. L b1 and L b2 The number of substituents that may be possessed by the group is not particularly limited, and the group may have a plurality of substituents. Y b1 Examples of the cyclic hydrocarbon group include an alicyclic hydrocarbon group, an aromatic hydrocarbon group, and a group in which an alicyclic hydrocarbon group and an aromatic hydrocarbon group are combined. Y b1 The alicyclic hydrocarbon group and the aromatic hydrocarbon group are represented by L b1 Examples of the alicyclic hydrocarbon groups and aromatic hydrocarbon groups are the same as those exemplified in 1. When the alicyclic hydrocarbon groups and aromatic hydrocarbon groups do not have a substituent, they may be monovalent alicyclic hydrocarbon groups and aromatic hydrocarbon groups. Y b1 Examples of the substituent that the methyl group may have include a halogen atom, a cyano group, a hydroxy group, and a nitro group. Y b1The substituent that the cyclic hydrocarbon group may have is, for example, a halogen atom, a cyano group, a nitro group, or a hydrocarbon group having 1 to 18 carbon atoms (including the -CH 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced with .) etc. Y b1 The number of carbon atoms in the hydrocarbon group that may be contained in the cyclic hydrocarbon group is b1 The carbon number of the cyclic hydrocarbon group is not included in the carbon number of the cyclic hydrocarbon group. The halogen atoms are L b1 and L b2 Examples of the halogen atoms include the same halogen atoms as those exemplified as the substituent of the above. Y b1 Examples of the hydrocarbon group having 1 to 18 carbon atoms that may be substituted on the cyclic hydrocarbon group include chain hydrocarbon groups, alicyclic hydrocarbon groups, aromatic hydrocarbon groups, and groups combining these groups. Examples of the chain hydrocarbon group, alicyclic hydrocarbon group, aromatic hydrocarbon group, and groups combining two or more of these groups include, within the range permitted by the upper limit of the carbon number, b1 Examples of the alkyl group include the chain hydrocarbon group, the alicyclic hydrocarbon group, the aromatic hydrocarbon group, and the group obtained by combining two or more of these groups. b1 The cyclic hydrocarbon group may have a substituent selected from the group consisting of -CH 2 - is -O-, -S-, -CO- or -SO 2 Examples of groups substituted with - include, within the upper limit of the carbon number, L b1 -CH contained in the hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 The same groups as those exemplified as the groups substituted with - can be mentioned. b1 The hydrocarbon group having 1 to 18 carbon atoms which the cyclic hydrocarbon group may have as a substituent may constitute a protecting group or leaving group (acid labile group or base labile group) generally used in the art.

[0162] The anion in the salt represented by formula (B1) is preferably an anion represented by the following formula (B1-A1) (hereinafter, may be referred to as "anion (B1-A1)") or an anion represented by formula (B1-A2) (hereinafter, may be referred to as "anion (B1-A2)"). TIFF2025017356000136.tif30124[In formula (B1-A1), L b2 and Y b1 has the same meaning as in formula (B1). Q b1 , Q b2 , Q b3 and Q b4 each independently represents a hydrogen atom, a fluorine atom, a perfluoroalkyl group having 1 to 6 carbon atoms, or an alkyl group having 1 to 6 carbon atoms. z1 represents an integer of 0 to 6. When z1 is 2 or more, the groups in the multiple parentheses may be the same or different. X 1 represents -O-CO-, -CO-O-, -O-CO-O- or -O-. L b3 represents a single bond or a (nb2+1)-valent hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and -CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced with -. nb2 represents an integer of 1 to 3. When nb2 is 2 or more, the groups in the parentheses may be the same or different.] Q b1 , Q b2 , Q b3 and Q b4 Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, and a hexyl group. Q b1 , Q b2 , Q b3 and Q b4Examples of the perfluoroalkyl group include a trifluoromethyl group, a perfluoroethyl group, a perfluoropropyl group, a perfluoroisopropyl group, a perfluorobutyl group, a perfluorosec-butyl group, a perfluorotert-butyl group, a perfluoropentyl group, and a perfluorohexyl group. Q b1 and Q b2 Q b1 and Q b2 At least one of the groups preferably contains a fluorine atom or a perfluoroalkyl group, more preferably a fluorine atom or a perfluoroalkyl group, even more preferably a fluorine atom or a trifluoromethyl group, and even more preferably both are fluorine atoms. Q b3 and Q b4 are each preferably independently a hydrogen atom, a fluorine atom, or a perfluoroalkyl group having 1 to 3 carbon atoms, and Q b3 is preferably a hydrogen atom, a fluorine atom, or a perfluoroalkyl group having 1 to 3 carbon atoms, and Q b4 is preferably a hydrogen atom or a fluorine atom. z1 is preferably an integer of 0 to 3, and more preferably 0, 1 or 2. X 1 is preferably -O-CO- or -CO-O-.

[0163] L b3 The hydrocarbon group in the formula (B1) is, within the range permitted by the upper limit of the number of carbon atoms, b1 The same hydrocarbon groups as those exemplified above are included. In formula (B1-A1), L b3 is a single bond, a chain hydrocarbon group having 1 to 12 carbon atoms which may have a substituent (-CH contained in the chain hydrocarbon group). 2 - may be replaced by -O- or -CO-), an alicyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent (the -CH 2 - is -O-, -S-, -CO- or -SO 2-), an aromatic hydrocarbon group having 6 to 10 carbon atoms which may have a substituent (the -CH 2 - may be replaced by -O- or -S-.) or a group combining two or more of these groups is preferable, and a single bond, a chain hydrocarbon group having 1 to 6 carbon atoms, or a group represented by the following formula (Lb3-1) is more preferable. When the chain hydrocarbon group is replaced by -O- or -CO-, the -CH 2 The number of - replaced by -O- or -CO- is preferably 1 to 4, and one -CH 2 -CH 2 - is replaced by -O-CO- or -CO-O-, or one -CH 2 -CH 2 -CH 2 It is preferred that - is replaced by -O-CO-O-. TIFF2025017356000137.tif1481[In formula (Lb3-1), nb2 has the same meaning as in formula (B1-A1). L b31 represents a single bond or a chain hydrocarbon group having 1 to 12 carbon atoms, and the —CH 2 - may be replaced by -O- or -CO-, and the chain hydrocarbon group may have a substituent. W b3 represents an alicyclic hydrocarbon group having 3 to 18 carbon atoms or an aromatic hydrocarbon group having 6 to 10 carbon atoms, and -CH contained in the alicyclic hydrocarbon group 2 - is -O-, -S-, -CO- or -SO 2 - may be replaced by -CH contained in the aromatic hydrocarbon group. 2 - may be replaced by -O- or -S-, and the alicyclic hydrocarbon group and the aromatic hydrocarbon group may have a substituent. * and ** represent binding sites, * represents X 1 represents the binding site for In formula (Lb3-1), L b31 The chain hydrocarbon group of L is as long as the upper limit of the carbon number allows. b1Examples of the chain hydrocarbon groups include the same groups as those exemplified above. In formula (Lb3-1), W b3 The alicyclic and aromatic hydrocarbon groups of L are as long as the upper limit of the carbon number permits. b1 Examples of the alicyclic hydrocarbon groups and aromatic hydrocarbon groups are the same as those exemplified by 1. In formula (Lb3-1), L b31 The substituents which the chain hydrocarbon group may have and W b1 The substituents that the alicyclic hydrocarbon group and aromatic hydrocarbon group may have are b1 The substituents which the hydrocarbon group may have include the same groups as those exemplified above. L b31 is a single bond or an alkanediyl group having 1 to 6 carbon atoms (the —CH 2 - may be replaced by -O- or -CO-. Among them, W b3 The alicyclic hydrocarbon group and aromatic hydrocarbon group of are preferably the alicyclic hydrocarbon group and aromatic hydrocarbon group represented below. In the alicyclic hydrocarbon group and aromatic hydrocarbon group represented below, * and ** represent a bonding site, * represents X 1 Or L b31 represents a bonding site with L, and ** represents a hydrogen atom, a substituent, or L b2 At least one ** represents a binding site for L b2 In the alicyclic hydrocarbon group shown below, -CH 2 - is -O-, -S-, -CO- or -SO 2 The -CH contained in the alicyclic hydrocarbon group may be replaced with -. 2 - is -O-, -S-, -CO- or -SO 2 When it is replaced by -, it is preferable that an ether ring, an ester ring (lactone), a carbonate ring, a sulfonate ring (sultone) or an acetal ring is formed. In the formula (B1-A1) of TIFF2025017356000138.tif37165, L b2is a single bond or a chain hydrocarbon group having 1 to 12 carbon atoms (-CH contained in the chain hydrocarbon group). 2 - may be replaced by -O- or -CO-.) is preferred, and a single bond, -O-, -O-CO-, -CO-O-, -O-CO-O- or *-L b21 -X 2 -L b22 -**(L b21 and L b22 One of X represents a chain hydrocarbon group having 1 to 6 carbon atoms, and the other represents a single bond or a chain hydrocarbon group having 1 to 6 carbon atoms. 2 represents -O-, -CO-O-, -O-CO-, or -O-CO-O-. * and ** represent binding sites, and ** represents Y b1 where L b21 , X 2 and L b22 The total number of carbon atoms is 12 or less. In formula (B1-A1), Y b1 is a cyclic hydrocarbon group having 3 to 20 carbon atoms which may have a substituent (-CH contained in the cyclic hydrocarbon group). 2 - is -O-, -CO-, -S- or -SO 2 -), and an alicyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent (the -CH 2 - is -O-, -CO-, -S- or -SO 2 -) or an aromatic hydr...

Claims

1. A carboxylic acid generator comprising a carboxylate represented by formula (I) or a structural unit derived from a carboxylate represented by formula (I). [In formula (I), X represents a sulfur atom or an iodine atom. m10 represents 0 or 1, and when X is a sulfur atom, m10 is 1, and when X is an iodine atom, m10 is 0. R １Ａ , R １Ｂ , R １Ｃ and R １Ｄ each independently represents a group represented by formula (4a). R ４ represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, and the —CH 2 - is -O-, -S-, -CO-, -SO- or -SO ２ It may be replaced by -. R ７ , R ８ and R ９ each independently represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, 2 - is -O-, -S-, -CO-, -SO- or -SO ２ When X is a sulfur atom, R ７ and R ８ Or R ８ and R ９ is bonded to S ＋ The R forming the ring may form a ring containing ７ and R ８ Or R ８ and R ９ , S ＋ The —CH 2 - is -O-, -S-, -CO-, -SO- or -SO ２ It may be replaced by -. m1A, m1C, and m1D each independently represent an integer of 0 to 5. When m1A, m1C, and m1D each represent 2 or more, a plurality of R １Ａ , R １Ｃ and R １Ｄ may be the same or different from each other. m1B represents an integer of 0 to 4, and when m1B is 2 or more, a plurality of R １Ｂ may be the same or different from each other. However, at least one of m1A, m1B, m1C, and m1D is an integer of 1 or more. m4 represents an integer of 0 to 5, and when m4 is 2 or more, a plurality of R ４ may be the same or different, and satisfy 0≦m1A+m4≦5. m7 represents an integer of 0 to 4, and when m7 is 2 or more, a plurality of R ７ may be the same or different, and satisfy 0≦m1B+m7≦4. m8 represents an integer of 0 to 5, and when m8 is 2 or more, a plurality of R ８ may be the same or different, and satisfy 0≦m1C+m8≦5. m9 represents an integer of 0 to 5, and when m9 is 2 or more, a plurality of R ９ may be the same or different, and satisfy 0≦m1D+m9≦5. X ０ represents a hydrocarbon group having 2 to 72 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -CO- or -SO ２ - may be replaced. [In formula (4a), R １０ represents a hydrogen atom or a methyl group. X １０ represents *-O-**, *-CO-O-**, *-O-CO-O-** or *-Ax-Ph-Ay-**. Ph represents a phenylene group which may have a substituent. Ax and Ay each independently represent one or more bond types selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate bond. * is R １０ represents the bonding site with the carbon atom to which it is bonded, and ** represents L １０ represents the binding site with L １０ represents a single bond or a hydrocarbon group having 1 to 36 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -SO ２ It may be replaced by --or --CO--. *10 represents the bonding site with the benzene ring.

2. The composition contains a resin containing a structural unit derived from a carboxylate represented by formula (I), 2. The carboxylic acid generator according to claim 1, wherein the structural unit derived from the carboxylate represented by formula (I) is a structural unit represented by formula (IP). [In the formula (IP), X, R ４ , R ７ , R ８ , R ９ , m1A, m1B, m1C, m1D, m4, m7, m8, m9, m10, X ０ has the same meaning as in formula (I). R １ａ , R １ｂ , R １ｃ and R １ｄ each independently represents a group represented by formula (4a) or formula (4a-1); R １ａ , R １ｂ , R １ｃ and R １ｄ At least one of represents a group represented by formula (4a-1). [In formula (4a-1), all symbols have the same meaning as in formula (4a)]

3. X １０ is a single bond or a group represented by the formula (X １０ -1) ~Formula (X １０ 2. The carboxylic acid generator according to claim 1, wherein the carboxylic acid generator is a group represented by any one of the following formulas: [Formula (X １０ -1) ~ Type (X １０ -10) *, ** are binding sites, * is R １０ represents the bonding site with the carbon atom to which it is bonded. Rx represents a halogen atom, a hydroxy group, a fluorinated alkyl group having 1 to 6 carbon atoms, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms. mx represents an integer of 0 to 4. X ２０ is -O- or -NR ３ Represents -. R ３ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.

4. X ０ but, an alicyclic hydrocarbon group having 3 to 36 carbon atoms, an aromatic hydrocarbon group having 6 to 36 carbon atoms, or a group comprising a combination of a chain hydrocarbon group having 1 to 18 carbon atoms and an alicyclic hydrocarbon group having 3 to 36 carbon atoms or an aromatic hydrocarbon group having 6 to 36 carbon atoms, The alicyclic hydrocarbon group, the chain hydrocarbon group and the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms or a hydroxy group. ２ - is -O-, -S-, -CO- or -SO ２ The carboxylic acid generator according to claim 1, wherein - may be replaced by .

5. X ０ The carboxylic acid generator according to claim 1 , wherein is a group represented by formula (aa): [In formula (aa), X ａ and X ｂ each independently represents --O-- or --S--. X １ａ represents a hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and the —CH ２ - is -O-, -S-, -CO- or -SO ２ It may be replaced with -. X ２ａ represents a hydrocarbon group having 1 to 48 carbon atoms which may have a substituent, and the —CH 2 - is -O-, -S-, -CO- or -SO ２ It may be replaced with -. * indicates -COO － represents the bonding site with the carbon atom of

6. X ０ 2. The carboxylic acid generator according to claim 1, wherein is a phenyl group which may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms or a hydroxy group.

7. 7. A resist composition comprising the carboxylic acid generator according to claim 1 and an acid generator other than said carboxylic acid generator.

8. A carboxylate represented by formula (I) 8. The resist composition according to claim 7, further comprising a resin containing a structural unit having an acid labile group.

9. The composition contains a resin containing a structural unit derived from a carboxylate represented by formula (I), 8. The resist composition according to claim 7, wherein the resin containing a structural unit derived from a carboxylate represented by formula (I) further contains a structural unit having an acid labile group.

10. Further comprising a resin including a structural unit having an acid labile group, The resist composition according to claim 7, wherein the structural unit having an acid labile group includes at least one selected from the group consisting of a structural unit represented by formula (a1-0), a structural unit represented by formula (a1-1), a structural unit represented by formula (a1-2), a structural unit represented by formula (a1-4), a structural unit represented by formula (a1-5), and a structural unit represented by formula (a1-6). [In formula (a1-0), formula (a1-1) and formula (a1-2), L a01 , L a1 and L a2 are each independently -O- or *-O-(CH 2 ) k1 represents --CO--O--, k1 represents an integer of 1 to 7, and * represents the bonding site with --CO--. R a01 , R ａ４ and R ａ５ each independently represents a hydrogen atom, a halogen atom, or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R a02 , R a03 and R a04 each independently represents an alkyl group having 1 to 8 carbon atoms, an alicyclic hydrocarbon group having 3 to 18 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or a combination thereof, and the alkyl group, alicyclic hydrocarbon group and aromatic hydrocarbon group may contain a halogen atom. R a6 and R a7 each independently represents an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 8 carbon atoms, an alicyclic hydrocarbon group having 3 to 18 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or a group formed by combining these, and the alkyl group, alkenyl group, alicyclic hydrocarbon group and aromatic hydrocarbon group may have a halogen atom. m1 represents an integer of 0 to 14. n1 represents an integer of 0 to 10. n1' represents an integer of 0 to 3. [In formula (a1-4), R ａ１ represents a hydrogen atom, a halogen atom, or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R ａ１７ represents a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 6 carbon atoms, an alkoxyalkyl group having 2 to 12 carbon atoms, an alkoxyalkoxy group having 2 to 12 carbon atoms, an alkylcarbonyl group having 2 to 4 carbon atoms, an alkylcarbonyloxy group having 2 to 4 carbon atoms, an acryloyloxy group, or a methacryloyloxy group. A ａ１１ represents a single bond or an alkanediyl group having 1 to 12 carbon atoms, and the —CH ２ - is -O-, -CO- or -NR ａ１８ May be replaced with -. R ａ１８ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. X ａ１ represents a single bond or --CO--. R a34 and R a35 each independently represents a hydrogen atom or a hydrocarbon group having 1 to 12 carbon atoms; R a36 represents a hydrocarbon group having 1 to 20 carbon atoms, or R a35 and R a36 are bonded to each other to form a divalent hydrocarbon group having 2 to 20 carbon atoms together with the -C-O- to which they are bonded, and the hydrocarbon group and the -CH 2 - may be replaced by -O- or -S-. na1 represents an integer of 1 to 5, and when na1 is 2 or more, the groups in the parentheses may be the same or different. na11 represents an integer of 0 to 4, and when na11 is 2 or more, a plurality of R ａ１７ may be the same or different from each other. mc represents an integer of 0 to 2. [In formula (a1-5), R a8 represents an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, a hydrogen atom or a halogen atom. Z a1 is a single bond or *-(CH 2 ) h3 -CO-L 54 -, h3 represents an integer of 1 to 4, * represents L 51 represents the binding site with L 51 , L 52 , L 53 and L 54 each independently represents --O-- or --S--. s1 represents an integer of 1 to 3. s1′ represents an integer of 0 to 3.] [In formula (a1-6), R a61 represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R a6２ , R a63 and R a6４ each independently represents an alkyl group having 1 to 6 carbon atoms or a cyclic hydrocarbon group having 3 to 18 carbon atoms which may have a substituent, or R a6２ and R a63 are bonded to each other to form, together with the carbon atoms to which they are attached, a ring having 3 to 20 carbon atoms. X a61 is a single bond, -CO-O-* or -CO-NR 5 - represents *, * represents a bonding site with Ar, R 5 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms. X a62 is a single bond, *-O-L a61 - or *-CO-OL a62 -, * represents a bonding site with Ar, L a61 and L a62 each independently represents an alkanediyl group having 1 to 4 carbon atoms. Ar represents an aromatic hydrocarbon group having 6 to 20 carbon atoms which may have a substituent.]

11. The resist composition according to claim 7, which contains a resin containing a structural unit represented by formula (a2-A). [In formula (a2-A), R a２ represents a hydrogen atom, a halogen atom or an alkyl group having 1 to 6 carbon atoms which may have a halogen atom. R a27 represents a halogen atom, a hydroxy group, a carboxy group, an alkyl group having 1 to 6 carbon atoms which may have a halogen atom, an alkoxy group having 1 to 6 carbon atoms, an alkoxyalkyl group having 2 to 12 carbon atoms, an alkoxyalkoxy group having 2 to 12 carbon atoms, an alkylcarbonyl group having 2 to 4 carbon atoms, an alkylcarbonyloxy group having 2 to 4 carbon atoms, an acryloyloxy group, or a methacryloyloxy group. A ａ２１ represents a single bond or an alkanediyl group having 1 to 12 carbon atoms, and the —CH ２ - is -O-, -CO- or -NR ａ２８ It may be replaced with -. R ａ２８ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms. X ａ２ represents a single bond or --CO--. nA2 represents an integer of 1 to 5. When nA2 is 2 or more, the groups in the parentheses may be the same or different. na21 represents an integer of 0 to 4. When na21 is 2 or more, a plurality of R a27 may be the same or different from each other. mc represents an integer of 0 to 2.

12. 8. The resist composition according to claim 7, wherein the acid generator comprises a salt represented by formula (B1) or a salt represented by formula (B2). [In formula (B1), L b1 represents a single bond or a (nb1+1)-valent hydrocarbon group which may have a substituent, and —CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced with -. L b2 represents a single bond or a divalent hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and the —CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced by -. Y b1 represents a methyl group which may have a substituent or a cyclic hydrocarbon group having 3 to 24 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -SO 2 It may be replaced by --or --CO--. nb1 represents an integer of 1 to 6. When nb1 is 2 or more, the groups in the parentheses may be the same or different. Z1 ＋ represents an organic cation. [In formula (B2), A １ represents a nitrogen atom or a carbon atom. L ｂ２ represents a single bond or a divalent hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and the —CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced by -. Y ｂ１’ represents a methyl group which may have a substituent or a cyclic hydrocarbon group having 3 to 24 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -CO- or -SO 2 It may be replaced by -. nb5 represents an integer of 2 or 3. When nb5 is 2, A １ is a nitrogen atom, and when nb5 is 3, A １ A is a carbon atom. The groups in the parentheses may be the same or different from each other, and the two groups in the parentheses are bonded to form A １ may form a ring comprising: Z2 ＋ represents an organic cation.

13. (1) A step of applying the resist composition according to claim 7 onto a substrate; (2) A step of drying the applied resist composition to form a composition layer; (3) exposing the composition layer to light; (4) heating the composition layer after exposure; and (5) developing the composition layer after heating; A method for producing a resist pattern comprising the steps of:

14. A carboxylate represented by formula (I): [In formula (I), X represents a sulfur atom or an iodine atom. m10 represents 0 or 1, and when X is a sulfur atom, m10 is 1, and when X is an iodine atom, m10 is 0. R １Ａ , R １Ｂ , R １Ｃ and R １Ｄ each independently represents a group represented by formula (4a). R ４ represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, and the —CH 2 - is -O-, -S-, -CO-, -SO- or -SO ２ It may be replaced by -. R ７ , R ８ and R ９ each independently represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, 2 - is -O-, -S-, -CO-, -SO- or -SO ２ When X is a sulfur atom, R ７ and R ８ Or R ８ and R ９ is bonded to S ＋ The R forming the ring may form a ring containing ７ and R ８ Or R ８ and R ９ , S ＋ The —CH 2 - is -O-, -S-, -CO-, -SO- or -SO ２ It may be replaced by -. m1A, m1C, and m1D each independently represent an integer of 0 to 5. When m1A, m1C, and m1D each represent 2 or more, a plurality of R １Ａ , R １Ｃ and R １Ｄ may be the same or different from each other. m1B represents an integer of 0 to 4, and when m1B is 2 or more, a plurality of R １Ｂ may be the same or different from each other. However, at least one of m1A, m1B, m1C, and m1D is an integer of 1 or more. m4 represents an integer of 0 to 5, and when m4 is 2 or more, a plurality of R ４ may be the same or different, and satisfy 0≦m1A+m4≦5. m7 represents an integer of 0 to 4, and when m7 is 2 or more, a plurality of R ７ may be the same or different, and satisfy 0≦m1B+m7≦4. m8 represents an integer of 0 to 5, and when m8 is 2 or more, a plurality of R ８ may be the same or different, and satisfy 0≦m1C+m8≦5. m9 represents an integer of 0 to 5, and when m9 is 2 or more, a plurality of R ９ may be the same or different, and satisfy 0≦m1D+m9≦5. X ０ represents a hydrocarbon group having 2 to 72 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -CO- or -SO ２ - may be replaced. [In formula (4a), R １０ represents a hydrogen atom or a methyl group. X １０ represents *-O-**, *-CO-O-**, *-O-CO-O-** or *-Ax-Ph-Ay-**. Ph represents a phenylene group which may have a substituent. Ax and Ay each independently represent one or more bond types selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate bond. * is R １０ represents the bonding site with the carbon atom to which it is bonded, and ** represents L １０ represents the binding site with L １０ represents a single bond or a hydrocarbon group having 1 to 36 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -SO ２ It may be replaced by --or --CO--. *10 represents the bonding site with the benzene ring.

15. X １０ is a single bond or a group represented by the formula (X １０ -1) ~Formula (X １０ The carboxylate according to claim 14, wherein the carboxylate is a group represented by any one of the following formulas: [Formula (X １０ -1) ~ Type (X １０ -10) *, ** are binding sites, * is R １０ represents the bonding site with the carbon atom to which it is bonded. Rx represents a halogen atom, a hydroxy group, a fluorinated alkyl group having 1 to 6 carbon atoms, an alkyl group having 1 to 18 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms. mx represents an integer of 0 to 4. X ２０ is -O- or -NR ３ Represents -. R ３ represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms.

16. X ０ but, an alicyclic hydrocarbon group having 3 to 36 carbon atoms, an aromatic hydrocarbon group having 6 to 36 carbon atoms, or a group comprising a combination of a chain hydrocarbon group having 1 to 18 carbon atoms and an alicyclic hydrocarbon group having 3 to 36 carbon atoms or an aromatic hydrocarbon group having 6 to 36 carbon atoms, The alicyclic hydrocarbon group, the chain hydrocarbon group and the aromatic hydrocarbon group may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms or a hydroxy group. ２ - is -O-, -S-, -CO- or -SO ２ The carboxylate according to claim 14 or 15, which may be replaced by -.

17. X ０ The carboxylate according to claim 14 or 15, wherein is a group represented by formula (aa): [In formula (aa), X ａ and X ｂ each independently represents --O-- or --S--. X １ａ represents a hydrocarbon group having 1 to 24 carbon atoms which may have a substituent, and the —CH ２ - is -O-, -S-, -CO- or -SO ２ It may be replaced with -. X ２ａ represents a hydrocarbon group having 1 to 48 carbon atoms which may have a substituent, and the —CH 2 - is -O-, -S-, -CO- or -SO ２ It may be replaced with -. * indicates -COO － represents the bonding site with the carbon atom of

18. X ０ The carboxylate according to claim 14 or 15, wherein is a phenyl group which may have a fluorine atom, an iodine atom, a fluorinated alkyl group having 1 to 4 carbon atoms, or a hydroxy group.

19. A resin comprising a structural unit represented by formula (IP): [In the formula (IP), X represents a sulfur atom or an iodine atom. m10 represents 0 or 1, and when X is a sulfur atom, m10 is 1, and when X is an iodine atom, m10 is 0. R １ａ , R １ｂ , R １ｃ and R １ｄ each independently represents a group represented by formula (4a) or formula (4a-1); R １ａ , R １ｂ , R １ｃ and R １ｄ At least one of the groups represented by formula (4a-1) is a group represented by formula (4a-1). R ４ represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, and the —CH 2 - is -O-, -S-, -CO-, -SO- or -SO ２ It may be replaced by -. R ７ , R ８ and R ９ each independently represents a halogen atom or a hydrocarbon group having 1 to 36 carbon atoms, the hydrocarbon group optionally having a substituent, 2 - is -O-, -S-, -CO-, -SO- or -SO ２ When X is a sulfur atom, R ７ and R ８ Or R ８ and R ９ is bonded to S ＋ The R forming the ring may form a ring containing ７ and R ８ Or R ８ and R ９ , S ＋ The —CH 2 - is -O-, -S-, -CO-, -SO- or -SO ２ It may be replaced by -. m1A, m1C, and m1D each independently represent an integer of 0 to 5. When m1A, m1C, and m1D each represent 2 or more, a plurality of R １Ａ , R １Ｃ and R １Ｄ may be the same or different from each other. m1B represents an integer of 0 to 4, and when m1B is 2 or more, a plurality of R １Ｂ may be the same or different from each other. However, at least one of m1A, m1B, m1C, and m1D is an integer of 1 or more. m4 represents an integer of 0 to 5, and when m4 is 2 or more, a plurality of R ４ may be the same or different, and satisfy 0≦m1A+m4≦5. m7 represents an integer of 0 to 4, and when m7 is 2 or more, a plurality of R ７ may be the same or different, and satisfy 0≦m1B+m7≦4. m8 represents an integer of 0 to 5, and when m8 is 2 or more, a plurality of R ８ may be the same or different, and satisfy 0≦m1C+m8≦5. m9 represents an integer of 0 to 5, and when m9 is 2 or more, a plurality of R ９ may be the same or different, and satisfy 0≦m1D+m9≦5. X ０ represents a hydrocarbon group having 2 to 72 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -CO- or -SO ２ - may be replaced. [In formula (4a) and formula (4a-1), R １０ represents a hydrogen atom or a methyl group. X １０ represents *-O-**, *-CO-O-**, *-O-CO-O-** or *-Ax-Ph-Ay-**. Ph represents a phenylene group which may have a substituent. Ax and Ay each independently represent one or more bond types selected from the group consisting of a single bond, an ether bond, a thioether bond, an ester bond, an amide bond, and a carbonate bond. * is R １０ represents the bonding site with the carbon atom to which it is bonded, and ** represents L １０ represents the binding site with L １０ represents a single bond or a hydrocarbon group having 1 to 36 carbon atoms which may have a substituent, and —CH 2 - is -O-, -S-, -SO ２ It may be replaced by --or --CO--. *10 represents the bonding site with the benzene ring.

Images