Secondary battery and manufacturing method thereof

Abstract

To efficiently accommodate a laminated electrode body, in which a positive electrode plate and a negative electrode plate are laminated, into a case while preventing the electrode body from being damaged.SOLUTION: A secondary battery includes a laminated electrode body in which a plurality of positive electrode plates and a plurality of negative electrode plates each are laminated via a separator, and a case accommodating the electrode body. Each of the positive electrode plates and each of the negative electrode plates have a main surface stacked in a lamination direction of the positive electrode plates and the negative electrode plates, and an end surface intersecting the main surface, respectively. The separator includes a first area disposed on an outermost periphery of the electrode body on the end surface. The secondary battery further includes a sheet member that is disposed between the first area of the separator and the end surfaces of the positive electrode plates and the negative electrode plates and that comprises a separate member from the separator.SELECTED DRAWING: Figure 6

Description

[Technical field]

[0001] The present technology relates to a secondary battery and a manufacturing method thereof. [Background technology]

[0002] Japanese Patent No. 4537353 (Patent Document 1) shows a rectangular secondary battery in which an electrode group (25) is housed in a case (14) having openings (14a, 14b) at both ends, and electrode terminals (21, 23) are attached to cap plates (33, 33') that seal the openings (14a, 14b).

[0003] In addition, JP 2021-048141 A (Patent Document 2) and JP 2016-103425 A (Patent Document 3) disclose that the separator interposed between the positive and negative electrode plates is folded zigzag and arranged so as to surround the outer periphery of the stack of positive and negative electrode plates. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Patent No. 4537353 [Patent Document 2] Patent Publication No. 2021-048141 [Patent Document 3] JP 2016-103425 A Summary of the Invention [Problem to be solved by the invention]

[0005] There is a demand for efficiently housing a laminated electrode assembly, in which positive and negative electrode plates are stacked, in a case while suppressing damage to the electrode assembly.

[0006] An object of the present technology is to provide a secondary battery that can meet such demands and a manufacturing method thereof. [Means for solving the problem]

[0007] The present technology provides the following secondary battery and method for manufacturing the same.

[0008] [1] A secondary battery comprising: a laminated electrode assembly in which a plurality of positive plates and a plurality of negative plates are stacked with separators interposed between them; and a case for housing the electrode assembly, wherein the plurality of positive plates and the plurality of negative plates each have a main surface where the plurality of positive plates and the plurality of negative plates are stacked in a stacking direction of the plurality of positive plates and the plurality of negative plates, and an end surface intersecting the main surface, wherein the separator includes a first region that is arranged on the end surface around the outermost periphery of the electrode assembly, and further comprising a sheet member that is arranged between the first region of the separator and the end surfaces of the plurality of positive plates and the plurality of negative plates and is made of a material separate from the separator.

[0009] [2] The secondary battery according to [1], wherein the separator includes a second region that is zigzag folded along the plurality of positive electrode plates and the plurality of negative electrode plates.

[0010] [3] The secondary battery according to [1] or [2], wherein the end faces include a first end face and a second end face opposing each other, and the sheet member is disposed on only one side of the first end face and the second end face.

[0011] [4] The secondary battery according to any one of [1] to [3], wherein the first region of the separator directly faces the inner circumferential surface of the case via only the gas, only the electrolyte, or only the gas and the electrolyte.

[0012] [5] The secondary battery according to any one of [1] to [4], further comprising a positive electrode terminal and a negative electrode terminal electrically connected to the plurality of positive electrode plates and the plurality of negative electrode plates, respectively, wherein the case includes a case body having a first opening and a second opening opposing the first opening, a first sealing plate provided with a positive electrode terminal and sealing the first opening, and a second sealing plate provided with a negative electrode terminal and sealing the second opening.

[0013] [6] A method for manufacturing a secondary battery, comprising: preparing a case body having a first opening and a second opening opposing the first opening; preparing a stacked electrode body in which a plurality of positive electrode plates and a plurality of negative electrode plates are stacked with a separator interposed therebetween; accommodating the electrode body in the case body; and after accommodating the electrode body in the case body, sealing the first opening and the second opening with a first sealing plate and a second sealing plate, respectively, wherein the plurality of positive electrode plates and the plurality of negative electrode plates each have a main surface where they are overlapped in a stacking direction of the plurality of positive electrode plates and the plurality of negative electrode plates and an end surface intersecting the main surface, the step of preparing the electrode body includes arranging a first region of the separator on the end surface around an outermost periphery of the electrode body, and further comprising a step of arranging a sheet member made of a material separate from the separator between the first region of the separator and the end surfaces of the plurality of positive electrode plates and the plurality of negative electrode plates, and the step of accommodating the electrode body in the case body includes inserting the electrode body together with the sheet member into the case body with the sheet member positioned vertically below the electrode body. Effect of the Invention

[0014] According to the present technology, by disposing a sheet member made of a material separate from the separator between the first region of the separator arranged on the outermost periphery of the electrode body and the end faces of the positive and negative electrode plates, the electrode body can be efficiently housed in a case while suppressing damage to a laminated electrode body in which positive and negative electrode plates are stacked. [Brief description of the drawings]

[0015] [Figure 1] FIG. [Diagram 2] 2 is a diagram showing the secondary battery shown in FIG. 1 as viewed from the direction of arrow II. [Diagram 3] 3 is a diagram showing the secondary battery shown in FIG. 1 as viewed from the direction of arrow III. [Figure 4] 4 is a diagram showing the secondary battery shown in FIG. 1 as viewed from the direction of arrow IV. [Diagram 5] FIG. 2 is a diagram showing an electrode assembly taken out from the electrode assembly shown in FIG. [Figure 6] FIG. 6 is a cross-sectional view of the electrode body shown in FIG. [Figure 7] FIG. 2 is a front view showing a negative electrode original plate before the negative electrode plate is formed. [Figure 8] 8 is a cross-sectional view taken along the line VIII-VIII of the negative electrode original plate shown in FIG. 7. [Figure 9] FIG. 2 is a front view showing a negative electrode plate formed from the negative electrode original plate. [Figure 10] FIG. 2 is a front view showing a positive electrode original plate before the positive electrode plate is formed. [Figure 11] 11 is a cross-sectional view taken along the line XI-XI of the positive electrode plate shown in FIG. [Figure 12] FIG. 2 is a front view showing a positive electrode plate formed from a positive electrode original plate. [Figure 13] FIG. 4 is a cross-sectional view of a connection structure between a negative electrode tab group and a negative electrode current collector. [Figure 14] FIG. 4 is a cross-sectional view of a connection structure between a positive electrode tab group and a positive electrode current collector. [Figure 15] FIG. 2 is a top view (part 1) of a sheet member according to an example. [Figure 16] FIG. 2 is a top view (part 2) of a sheet member according to an example. [Figure 17] 17 is a cross-sectional view taken along the line AA of the sheet member shown in FIGS. 15 and 16. FIG. [Figure 18] 18 is a diagram showing a modification of the cross section taken along the line AA shown in FIG. 17. [Figure 19] FIG. 11 is a top view (part 3) of a sheet member according to an example. [Figure 20] 20 is a cross-sectional view of the sheet member shown in FIG. 19 taken along line BB. [Figure 21] FIG. 1 is a diagram (part 1) showing a state in which the electrode body is held by a holding member. [Figure 22] FIG. 2 is a second diagram showing a state in which the electrode body is held by a holding member. [Diagram 23] FIG. 11 is a diagram (part 1) showing the process of inserting an electrode body held by a holding member into a case. [Figure 24] FIG. 2 is a diagram (part 2) showing the process of inserting the electrode body held by the holding member into the case. [Diagram 25] FIG. 2 is a flow chart showing each step of a method for producing a secondary battery. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0016] Hereinafter, embodiments of the present technology will be described. Note that the same or corresponding parts are denoted by the same reference characters, and description thereof will not be repeated.

[0017] In the embodiments described below, when referring to the number, amount, etc., the scope of the present technology is not necessarily limited to the number, amount, etc., unless otherwise specified. In addition, in the following embodiments, each component is not necessarily essential to the present technology, unless otherwise specified. In addition, the present technology is not necessarily limited to those that achieve all of the effects and advantages mentioned in the present embodiment.

[0018] In this specification, the words "comprise", "include" and "have" are open-ended, i.e., when a certain configuration is included, other configurations may or may not be included.

[0019] Furthermore, when geometric terms and terms expressing positional and directional relationships, such as "parallel," "orthogonal," "45° diagonal," "coaxial," and "along" are used in this specification, these terms allow for manufacturing errors and slight variations. When terms expressing relative positional relationships, such as "upper side" and "lower side," are used in this specification, these terms are used to indicate relative positional relationships in one state, and the relative positional relationships can be inverted or rotated to any angle depending on the installation direction of each mechanism (for example, by turning the entire mechanism upside down).

[0020] In this specification, the term "battery" is not limited to lithium ion batteries, but may include other batteries such as nickel-metal hydride batteries and sodium ion batteries. In this specification, the term "electrode" may collectively refer to positive and negative electrodes. In addition, the term "electrode plate" may collectively refer to positive and negative plates.

[0021] (Overall battery configuration) Fig. 1 is a front view of a secondary battery 1 according to the present embodiment. Fig. 2 to Fig. 4 are views showing the secondary battery 1 shown in Fig. 1 as viewed in the directions of arrows II, III and IV, respectively.

[0022] The secondary battery 1 can be mounted in an electric vehicle (BEV: Battery Electric Vehicle), a plug-in hybrid electric vehicle (PHEV: Plug-in Hybrid Electric Vehicle), a hybrid electric vehicle (HEV: Hybrid Electric Vehicle), etc. However, the use of the secondary battery 1 is not limited to being mounted on a vehicle.

[0023] 1 to 4, the secondary battery 1 includes an exterior body 100 and an electrode assembly 200. The exterior body 100 includes a case body 110, a sealing plate 121 (first sealing plate), and a sealing plate 122 (second sealing plate).

[0024] In this specification, the X-axis direction (first direction) shown in Figures 1 to 4 may be referred to as the "width direction" of the secondary battery 1 or the case body 110, the Y-axis direction (second direction) may be referred to as the "thickness direction" of the secondary battery 1 or the case body 110, and the Z-axis direction (third direction) may be referred to as the "height direction" of the secondary battery 1 or the case body 110.

[0025] When configuring an assembled battery including the secondary batteries 1, multiple secondary batteries 1 are stacked in their thickness direction. The stacked secondary batteries 1 may be constrained in the stacking direction (Y-axis direction) by a restraining member to form a battery module, or the assembled battery may be directly supported on the side surface of a battery pack case without using a restraining member.

[0026] The case body 110 is made of a cylindrical, preferably rectangular, member. This results in a rectangular secondary battery 1. The case body 110 is made of metal. Specifically, the case body 110 is made of aluminum, an aluminum alloy, iron, an iron alloy, or the like.

[0027] As shown in Figures 1 and 2, sealing plates 121, 122 are provided at both ends of the case body. The case body 110 can be formed into a square tube shape, for example, by abutting the ends of bent plate-like members (joint 110A shown in Figure 2) and joining them together (for example, by laser welding). The corners of the "square tube" may have a rounded shape.

[0028] In this embodiment, the case body 110 is formed to be longer in the width direction (X-axis direction) of the secondary battery 1 than in the thickness direction (Y-axis direction) and height direction (Z-axis direction) of the secondary battery 1. The dimension (width) of the case body 110 in the X-axis direction is preferably about 30 cm or more. This allows a relatively large (high capacity) secondary battery 1 to be configured. The dimension (height) of the case body 110 in the Z-axis direction is preferably about 20 cm or less, more preferably about 15 cm or less, and even more preferably about 10 cm or less. This allows a relatively low height (low height) secondary battery 1 to be configured, improving the mountability in a vehicle, for example.

[0029] 3, an opening 111 (first opening) is provided at one end of the case body 110. The opening 111 is sealed by a sealing plate 121. A negative electrode terminal 131 (first electrode terminal), a liquid injection hole 141, and a gas exhaust valve 151 are provided on the sealing plate 121. The positions of the negative electrode terminal 131, the liquid injection hole 141, and the gas exhaust valve 151 can be changed as appropriate. The opening 111 and the sealing plate 121 have a substantially rectangular shape with the Y-axis direction as the short side direction and the Z-axis direction as the long side direction.

[0030] 4, an opening 112 (second opening) is provided at one end of the case body 110. The opening 112 is sealed by a sealing plate 122. A positive electrode terminal 132 (second electrode terminal), a liquid injection hole 142, and a gas exhaust valve 152 are provided on the sealing plate 122. The positions of the positive electrode terminal 132, the liquid injection hole 142, and the gas exhaust valve 152 can be changed as appropriate. The opening 112 and the sealing plate 122 have a substantially rectangular shape with the Y-axis direction as the short side direction and the Z-axis direction as the long side direction.

[0031] The sealing plates 121 and 122 are made of metal. Specifically, the sealing plates 121 and 122 are made of aluminum, an aluminum alloy, iron, an iron alloy, or the like.

[0032] The negative electrode terminal 131 is electrically connected to the negative electrode of the electrode assembly 200. The positive electrode terminal 132 is electrically connected to the positive electrode of the electrode assembly 200.

[0033] The negative electrode terminal 131 is made of a conductive material (more specifically, a metal), and may be made of, for example, copper or a copper alloy. The outer surface of the negative electrode terminal 131 may be provided with a portion or layer made of aluminum or an aluminum alloy.

[0034] The positive electrode terminal 132 is made of a conductive material (more specifically, a metal), and may be made of, for example, aluminum or an aluminum alloy.

[0035] The liquid inlet holes 141 and 142 are sealed with a sealing member (not shown) which may be, for example, a blind rivet or other metal member.

[0036] Gas exhaust valves 151 and 152 break when the pressure inside exterior body 100 reaches or exceeds a predetermined value, and exhaust gas inside exterior body 100 to the outside.

[0037] (Configuration of electrode body 200) Fig. 5 is a diagram showing the electrode assembly 200 housed in the exterior housing 100. Fig. 6 is a cross-sectional view of the electrode assembly 200. The electrode assembly 200 is housed in the exterior housing 100 so that its longitudinal direction is parallel to the X-axis direction.

[0038] The electrode body 200 includes a negative electrode tab group 210A (first electrode tab group) provided at an end (first end) on the sealing plate 121 side, and a positive electrode tab group 220A (second electrode tab group) provided at an end (second end) on the sealing plate 122 side. The negative electrode tab group 210A and the positive electrode tab group 220A are connected to the negative electrode plate 210 and the positive electrode plate 220, respectively, of the electrode body 200. The negative electrode tab group 210A and the positive electrode tab group 220A are formed so as to protrude from a main body portion of the electrode body 200 (a portion where a positive electrode plate and a negative electrode plate are stacked with a separator interposed therebetween) toward the sealing plates 121, 122, respectively.

[0039] The electrode body 200 is housed together with an electrolytic solution (electrolyte) not shown. As the electrolytic solution (non-aqueous electrolytic solution), for example, LiPF6 dissolved at a concentration of 1.2 mol / L in a non-aqueous solvent in which ethylene carbonate (EC), ethyl methyl carbonate (EMC), and diethyl carbonate (DEC) are mixed in a volume ratio (25°C) of 30:30:40 can be used. Note that a solid electrolyte may be used instead of the electrolytic solution.

[0040] As shown in Figures 5 and 6, the electrode body 200 includes a negative electrode plate 210, a positive electrode plate 220, and a separator 230. The negative electrode plate 210 and the positive electrode plate 220 each have a main surface (a surface extending in the vertical direction in Figure 6) and an end surface (a surface extending in the horizontal direction in Figure 6). The main surface and the end surface intersect each other so as to be approximately perpendicular to each other. The main surfaces of the negative electrode plate 210 and the positive electrode plate 220 are stacked in the stacking direction (Y-axis direction).

[0041] The number of stacked negative electrode plates 210 and positive electrode plates 220 is not limited to that shown in Fig. 6. In one example, 30 or more negative electrode plates 210 and 30 or more positive electrode plates 220 are stacked.

[0042] The negative electrode plate 210 and the positive electrode plate 220 are laminated via a separator 230. The separator 230 has a first region 231, a second region 232, and a third region 233. The first region 231 is a region arranged on the outermost periphery of the electrode body 200 on one end face (first end face) of the negative electrode plate 210 and the positive electrode plate 220 (lower side in FIG. 6). The second region 232 is a region folded in a zigzag pattern along the multiple positive electrode plates 220 and the multiple negative electrode plates 210. The third region 233 is a region arranged on the outermost periphery of the electrode body 200 on the other end face (second end face) of the negative electrode plate 210 and the positive electrode plate 220 (upper side in FIG. 6).

[0043] In the cross-sectional view of Figure 6, the first region 231, the second region 232, and the third region 233 of the separator 230 are composed of a continuous strip-shaped insulating sheet, but the scope of the present technology is not limited to this, and for example, the first region 231 and the third region 233 (peripheral portions) and the second region 232 (laminated portion) may be composed of separate insulating sheets.

[0044] More specifically, for example, the second region 232 of the separator 230 may be formed from a rectangular or bag-shaped insulating sheet, and a strip-shaped insulating sheet may be used to cover (wrap around) the outer periphery of the electrode body 200, thereby forming the first region 231 and the third region 233 of the separator 230. To secure the edge of the separator 230 wrapped around the outer periphery of the electrode body 200, a tape may be used, or adhesive may be used to adhere the separators 230 to each other, or the separators 230 may be welded together.

[0045] In addition, the insulating sheet may be overlapped in the first region 231 and the third region 233, that is, the portion extending from the zigzag second region 232 may be wound around the outer periphery of the negative electrode plate 210 and the positive electrode plate 220 multiple times.

[0046] In one example, the separator 230 faces the inner circumferential surface of the case body 110 without any other member therebetween. In this case, the separator 230 directly faces the inner circumferential surface of the case body 110 via only the gas, only the electrolyte, or only the gas and the electrolyte. However, the scope of the present technology is not limited thereto, and other members such as an insulating electrode body holder may be provided between the separator 230 and the case body 110.

[0047] 5 and 6, a sheet member 500 is disposed between the first region 231 of the separator 230 and the end faces of the plurality of negative electrode plates 210 and positive electrode plates 220. The sheet member 500 is formed of a member separate from the separator 230. The sheet member 500 is formed of an insulating material. In one example, the sheet member 500 is formed of a resin such as polypropylene (PP).

[0048] 5 and 6, the sheet member 500 is disposed only on the first region 231 side (first end face side) of the first region 231 side and the third region 233 side of the separator 230. However, the scope of the present technology is not limited thereto, and the separator 230 may be disposed on both the first region 231 and the third region 233.

[0049] The length (L2) of the sheet member 500 in the Y-axis direction is preferably about 0.7 times or more the length of the negative electrode active material layer 212 in the Y-axis direction, which will be described later, and is more preferably greater than the length of the negative electrode active material layer 212 in the Y-axis direction. More preferably, the length (L2) of the sheet member 500 in the Y-axis direction is greater than the length (L1) of the long side of the electrode body 200, i.e., the width of the strip-shaped separator 230, as shown in FIG.

[0050] 6, the width (W2) of the sheet member 500 in the X-axis direction is preferably smaller than the thickness (W1) of the electrode body 200 including the outermost separator 230. The width (W2) of the sheet member 500 is preferably about 0.5 times or more, and more preferably about 0.7 times or more, the thickness (W1) of the electrode body 200.

[0051] The thickness of the sheet member 500 is preferably greater than the thickness of the separator 230. In one example, the thickness of the sheet member 500 is preferably about 100 μm (0.1 mm) or more, or about 200 μm (0.2 mm) or more. The thickness of the sheet member 500 is, for example, about 500 μm (0.5 mm) or less. In one example, the sheet member 500 is made of a non-porous material or a material with a porosity of about less than 10%. In one example, the sheet member 500 has a groove formed therein, or has a plurality of openings (for example, 5 or more) having a diameter of about 5 mm or more formed therein. In one example, the sheet member 500 is disposed in a direction substantially perpendicular to the negative electrode plate 210 and the positive electrode plate 220. However, the scope of the present technology is not limited thereto.

[0052] (Electrode plate configuration) FIG. 7 is a front view showing the negative electrode original plate 210S before the negative electrode plate 210 (first electrode) is formed, FIG. 8 is a cross-sectional view taken along line VIII-VIII of the negative electrode original plate 210S shown in FIG. 7, and FIG. 9 is a front view showing the negative electrode plate 210 formed from the negative electrode original plate 210S.

[0053] The negative electrode plate 210 is manufactured by processing a negative electrode original plate 210S. As shown in Figures 7 and 8, the negative electrode original plate 210S includes a negative electrode core 211 and a negative electrode active material layer 212. The negative electrode core 211 is a copper foil or a copper alloy foil.

[0054] A negative electrode active material layer 212 is formed on both sides of the negative electrode core 211 except for one end portion. The negative electrode active material layer 212 is formed by applying a negative electrode active material layer slurry with a die coater.

[0055] The negative electrode active material layer slurry is prepared by kneading graphite as the negative electrode active material, styrene butadiene rubber (SBR) and carboxymethyl cellulose (CMC) as binders, and water as a dispersion medium so that the mass ratio of graphite:SBR:CMC is approximately 98:1:1.

[0056] The negative electrode core 211 coated with the negative electrode active material layer slurry is dried to remove water contained in the negative electrode active material layer slurry, thereby forming the negative electrode active material layer 212. Furthermore, the negative electrode active material layer 212 is compressed to form a negative electrode original plate 210S including the negative electrode core 211 and the negative electrode active material layer 212. The negative electrode original plate 210S is cut into a predetermined shape to form the negative electrode plate 210. The negative electrode original plate 210S can be cut by laser processing using energy beam irradiation, die processing, cutter processing, or the like.

[0057] As shown in Fig. 9, a plurality of negative electrode tabs 210B made of negative electrode cores 211 are provided at one end in the width direction of a negative electrode plate 210 formed from a negative electrode original plate 210S. When the negative electrode plates 210 are stacked, the plurality of negative electrode tabs 210B are stacked to form a negative electrode tab group 210A. The shape of the negative electrode tabs 210B is not limited to the one exemplified in Fig. 9.

[0058] FIG. 10 is a front view showing the positive electrode original plate 220S before the positive electrode plate 220 (second electrode) is formed, FIG. 11 is a cross-sectional view taken along line XX of the positive electrode original plate 220S shown in FIG. 10, and FIG. 12 is a front view showing the positive electrode plate 220 formed from the positive electrode original plate 220S.

[0059] The positive electrode plate 220 is manufactured by processing a positive electrode original plate 220S. As shown in Figures 10 and 11, the positive electrode original plate 220S includes a positive electrode core 221, a positive electrode active material layer 222, and a positive electrode protective layer 223. The positive electrode core 221 is an aluminum foil or an aluminum alloy foil.

[0060] A positive electrode active material layer 222 is formed on both sides of the positive electrode core 221 except for one end portion. The positive electrode active material layer 222 is formed on the positive electrode core 221 by applying a positive electrode active material layer slurry with a die coater.

[0061] The positive electrode active material layer slurry is prepared by kneading lithium nickel cobalt manganese composite oxide as the positive electrode active material, polyvinylidene fluoride (PVdF) as a binder, a carbon material as a conductive material, and N-methyl-2-pyrrolidone (NMP) as a dispersion medium, so that the mass ratio of lithium nickel cobalt manganese composite oxide:PVdF:carbon material is approximately 97.5:1:1.5.

[0062] The positive electrode protective layer 223 is in contact with the positive electrode core 221 and is formed at one end in the width direction of the positive electrode active material layer 222. The positive electrode protective layer 223 is formed on the positive electrode core 221 by applying a positive electrode protective layer slurry with a die coater. The positive electrode protective layer 223 has a larger electric resistance than the positive electrode active material layer 222.

[0063] The positive electrode protective layer slurry is prepared by kneading alumina powder, a carbon material as a conductive material, PVdF as a binder, and NMP as a dispersion medium so that the mass ratio of alumina powder:carbon material:PVdF is approximately 83:3:14.

[0064] The positive electrode core 221 coated with the positive electrode active material layer slurry and the positive electrode protective layer slurry is dried, and the NMP contained in the positive electrode active material layer slurry and the positive electrode protective layer slurry is removed to form the positive electrode active material layer 222 and the positive electrode protective layer 223. Furthermore, the positive electrode active material layer 222 is compressed to form a positive electrode original plate 220S including the positive electrode core 221, the positive electrode active material layer 222, and the positive electrode protective layer 223. The positive electrode original plate 220S is cut into a predetermined shape to form the positive electrode plate 220. The positive electrode original plate 220S can be cut by laser processing using energy beam irradiation, die processing, cutter processing, or the like.

[0065] 12, a plurality of positive electrode tabs 220B made of positive electrode cores 221 are provided at one end in the width direction of a positive electrode plate 220 formed from a positive electrode original plate 220S. When the positive electrode plates 220 are stacked, the plurality of positive electrode tabs 220B are stacked to form a positive electrode tab group 220A. The shape of the positive electrode tabs 220B is not limited to the one exemplified in FIG.

[0066] A positive electrode protection layer 223 is provided at the base of each of the positive electrode tabs 220B. The positive electrode protection layer 223 does not necessarily have to be provided at the base of the positive electrode tab 220B.

[0067] In a typical example, the thickness of the negative electrode tab 210B (one piece) is smaller than the thickness of the positive electrode tab 220B (one piece). In this case, the thickness of the negative electrode tab group 210A is smaller than the thickness of the positive electrode tab group 220A.

[0068] (Connection structure between electrode body 200 and current collector) 13 is a cross-sectional view of a connection structure between the negative electrode tab group 210A and the negative electrode current collector 310. As shown in FIG. 13, the negative electrode tab group 210A is joined to the negative electrode current collector 310 at a joint 310A. The joint 310A can be formed by, for example, ultrasonic bonding, resistance welding, laser welding, crimping, or the like. The joint 310A constitutes a conductive path between the negative electrode tab group 210A and the negative electrode terminal 131.

[0069] The negative electrode current collector 310 is connected to the negative electrode terminal 131 between the electrode body 200 and the sealing plate 121. The negative electrode current collector 310 includes a first conductive member 311 and a second conductive member 312. The first conductive member 311 and the second conductive member 312 are joined at a joint 313.

[0070] The negative electrode tab group 210A is joined to a first conductive member 311 of the negative electrode current collector 310 at a joint 310A. The first conductive member 311 is connected to a second conductive member 312 at a joint 313. The joint 313 can be formed by, for example, ultrasonic bonding, resistance welding, laser welding, crimping, or the like.

[0071] The first conductive member 311 and the second conductive member 312 are attached to the inner surface side of the sealing plate 121 via an insulating member 410 made of resin.

[0072] The negative electrode terminal 131 is attached to the sealing plate 121 via a resin insulating member 410A. The negative electrode terminal 131 is provided so as to be exposed to the outside of the sealing plate 121 and reach the second conductive member 312 of the negative electrode current collector 310 provided on the inner side of the sealing plate 121. The negative electrode terminal 131 and the second conductive member 312 can be connected to each other by, for example, ultrasonic bonding, resistance welding, laser welding, crimping, or the like. In this embodiment, a through hole is provided in the second conductive member 312, the negative electrode terminal 131 is inserted into the through hole, the negative electrode terminal 131 is crimped on the second conductive member 312, and then the crimped portion and the second conductive member 312 are welded at a joint portion 131A to connect the negative electrode terminal 131 and the second conductive member 312.

[0073] As a procedure for assembling each part, first, the negative electrode terminal 131 and the second conductive member 312 are attached to the sealing plate 121 together with the insulating members 410 and 410A. Next, the first conductive member 311 connected to the electrode body 200 is attached to the second conductive member 312. At this time, the first conductive member 311 is placed on the insulating member 410 so that a portion of the first conductive member 311 overlaps with the second conductive member 312. Next, the first conductive member 311 and the second conductive member 312 are welded and connected at the joint 313. Note that the insulating members 410 and 410A may be composed of a single member.

[0074] However, the negative electrode terminal 131 may be electrically connected to the sealing plate 121. Also, the sealing plate 121 may serve as the negative electrode terminal 131.

[0075] Although FIG. 13 illustrates the negative electrode current collector 310 made up of two components (the first conductive member 311 and the second conductive member 312), the negative electrode current collector 310 may be made up of a single component.

[0076] 14 is a cross-sectional view of a connection structure between the positive electrode tab group 220A and the positive electrode current collector 320. As shown in FIG. 14, the positive electrode current collector 320 is provided on the inner surface side of the sealing plate 122, and is connected to the electrode body 200 and the positive electrode terminal 132. The positive electrode current collector 320 includes a first conductive member 321 (first part) and a second conductive member 322 (second part). The first conductive member 321 and the second conductive member 322 are joined at a joint 323. The first conductive member 321 and the second conductive member 322 are attached to the inner surface side of the sealing plate 122 via a resin insulating member 420.

[0077] The first conductive member 321 has a step portion 321A. The step portion 321A extends in the long side direction (Z-axis direction) of the rectangular sealing plate 122. As shown in Fig. 14, in a region (first region) on one side (left side in Fig. 14) of the step portion 321A, the first conductive member 321 is provided along the sealing plate 122 and is joined to the positive electrode tab group 220A (joint portion 320A). In a region (second region) on the other side (right side in Fig. 14) of the step portion 321A, the first conductive member 321 is provided to overlap with the second conductive member 322.

[0078] The positive electrode tab group 220A is joined to a first conductive member 321 of the positive electrode current collector 320 at a joint 320A. The first conductive member 321 is connected to a second conductive member 322 at a joint 323. The joint 323 can be formed by, for example, ultrasonic bonding, resistance welding, laser welding, crimping, or the like.

[0079] The positive electrode terminal 132 is attached to the sealing plate 122 via a resin insulating member 420A. The positive electrode terminal 132 is provided so as to be exposed to the outside of the sealing plate 122 and reach the second conductive member 322 of the positive electrode current collector 320 provided on the inner side of the sealing plate 122. The positive electrode terminal 132 and the second conductive member 322 can be connected by, for example, ultrasonic bonding, resistance welding, laser welding, crimping, or the like. In this embodiment, a through hole is provided in the second conductive member 322, the positive electrode terminal 132 is inserted into the through hole, the positive electrode terminal 132 is crimped on the second conductive member 322, and then the crimped portion and the second conductive member 322 are welded at a joint 132A to connect the positive electrode terminal 132 and the second conductive member 322.

[0080] As a procedure for assembling each part, first, the positive electrode terminal 132 and the second conductive member 322 are attached to the sealing plate 122 together with the insulating members 420 and 420A. Next, the first conductive member 321 connected to the electrode body 200 is attached to the second conductive member 322. At this time, the first conductive member 321 is placed on the insulating member 420 so that a portion of the first conductive member 321 overlaps with the second conductive member 322. Next, the first conductive member 321 and the second conductive member 322 are welded and connected at the joint 323. Note that the insulating members 420 and 420A may be composed of a single member.

[0081] However, the positive electrode terminal 132 may be electrically connected to the sealing plate 122. Also, the sealing plate 122 may serve as the positive electrode terminal 132.

[0082] Although FIG. 14 illustrates positive electrode current collector 320 made up of two parts (first conductive member 321 and second conductive member 322), positive electrode current collector 320 may be made up of a single part.

[0083] In the present technology, the connection structure between the electrode assembly 200 and the current collector is not limited to the structures shown in Fig. 13 and Fig. 14. For example, the positive electrode tab group 220A may be electrically connected to the sealing plate 122 directly or via the positive electrode current collector 320. In this case, the sealing plate 122 may also serve as the positive electrode terminal 132.

[0084] (Configuration of sheet member 500) Fig. 15 and Fig. 16 are top views of a sheet member 500 according to an example. Fig. 17 is a cross-sectional view taken along line AA of the sheet member 500 shown in Fig. 15 and Fig. 16, and Fig. 18 is a view showing a modified example of the cross-section taken along line AA shown in Fig. 17.

[0085] 15 to 18, the sheet member 500 may have an uneven surface including protrusions 510 and grooves 520. The protrusions 510 and the grooves 520 extend over the entire sheet member 500 along the insertion direction (X-axis direction) of the electrode body 200. By forming the protrusions 510 and the grooves 520, the frictional resistance between the electrode body 200 with the sheet member 500 interposed therebetween and the inner surface of the case body 110 is reduced, allowing the electrode body 200 to be inserted more smoothly.

[0086] The convex portion 510 and the groove portion 520 may be formed on both the upper and lower surfaces as shown in FIG. 17, or may be formed only on the lower surface side (case body 110 side) as shown in FIG.

[0087] The depth of groove 520 is preferably, for example, about 100 μm (0.1 mm) or more, and more preferably about 200 μm (0.2 mm) or more.

[0088] 16, a through hole 500A is provided in the sheet member 500. By forming the through hole 500A in the sheet member 500, the flow of the electrolyte solution is promoted after the electrode body 200 is housed in the exterior body 100, and as a result, the permeation of the electrolyte solution into the electrode body 200 can be promoted.

[0089] FIG. 19 is a top view of a sheet member 500 according to an example, and FIG. 20 is a cross-sectional view taken along line BB of the sheet member 500 shown in FIG.

[0090] 19 and 20, a through hole 530 is formed extending in the X-axis direction over almost the entire X-axis direction. Like the uneven shape described above, the through hole 530 reduces the frictional resistance between the electrode body 200 and the inner surface of the case body 110 when the electrode body 200 is inserted, and promotes the flow of the electrolyte after the electrode body 200 is inserted, thereby facilitating the permeation of the electrolyte into the electrode body 200.

[0091] (Insertion of the electrode body 200 into the case body 110) 21 and 22 are diagrams showing a state in which the electrode body 200 is held by a holding member 600. As shown in Fig. 21 and Fig. 22, the electrode body 200 is sandwiched by the holding members 600 from both sides in its thickness direction (Y-axis direction). In Fig. 21, the negative electrode tab group 210A and the positive electrode tab group 220A are in a state in which the negative electrode plates 210 and the positive electrode plates 220 remain stacked.

[0092] From the state shown in FIG. 21, the negative electrode tab group 210A and the positive electrode tab group 220A are collected into a foil while the electrode body 200 is held by the holding member 600, as shown in FIG.

[0093] 23 and 24 are diagrams showing the process of inserting the electrode body 200 held by the holding member 600 into the case body 110. FIG.

[0094] As shown in FIGS. 23 and 24, after the negative electrode tab group 210A and the positive electrode tab group 220A are collected into a foil, the electrode body 200 is inserted into the case body 110 together with the holding member 600 while still being held by the holding member 600.

[0095] As shown in FIG. 23, the electrode body 200 may be inserted with the longitudinal direction (X-axis direction) of the case body 110 kept horizontal, or as shown in FIG. 24, the electrode body 200 may be inserted with the longitudinal direction (X-axis direction) of the case body 110 tilted obliquely relative to the horizontal direction (tilted by an angle θ (0°<θ<90°) so that the insertion opening is facing upward).

[0096] In this way, by continuing to hold the electrode body 200 by the holding member 600 from the time when the negative electrode tab group 210A and the positive electrode tab group 220A are collected to the time when they are inserted into the case body 110, it is possible to suppress stacking misalignment of the negative electrode plates 210 and the positive electrode plates 220 due to processing and transportation up to insertion into the case body 110.

[0097] 23 and 24, the step of housing the electrode body 200 in the case body 110 is performed by inserting the electrode body 200 together with the holding member 600 into the case body 110 with the sheet member 500 disposed vertically below the electrode body 200. After the electrode body 200 is inserted into the case body 110, the holding (chuck) of the electrode body 200 by the holding member 600 is released, and only the holding member 600 is pulled out from the case body 110 while leaving the electrode body 200 in the case body 110.

[0098] By doing so, it is possible to suppress stacking misalignment of the negative electrode plate 210 and the positive electrode plate 220 during the process of inserting the electrode body 200 into the case body 110, and it is also possible to reduce the load acting on the ends of the electrode body 200 and suppress damage to the electrode body 200.

[0099] (Manufacturing process of secondary battery 1) Fig. 25 is a flow diagram showing each step of the manufacturing method of the secondary battery 1. As shown in Fig. 25, in S10, the case body 110 is prepared. Next, in S20, the electrode body 200 is produced, in S30, the sheet member 500 is arranged, and in S40, the electrode body 200 is inserted into the case body 110.

[0100] At this time, first, a plurality of negative electrode plates 210 and positive electrode plates 220 are stacked with separators 230 interposed therebetween (S21), and then, a sheet member 500 is placed between the electrode body 200 and the first region 231 of the separator 230 (S30). Next, the electrode body 200 is held by the holding member 600 (S41). With the electrode body 200 held, the negative electrode tab group 210A and the positive electrode tab group 220A are each collected (S22), and then, the electrode body 200 together with the holding member 600 is inserted into the case body 110 (S42). After the electrode body 200 and the holding member 600 are inserted into the case body 110, only the holding member 600 is pulled out from the case body 110 while the electrode body 200 is left inside the case body 110 (S43).

[0101] After the insertion of the electrode body 200 into the case body 110 (S40) is completed, the negative electrode tab group 210A and the positive electrode tab group 220A are electrically connected to the negative electrode terminal 131 and the positive electrode terminal 132, respectively. This electrical connection step may be performed before the electrode body 200 is inserted into the case body 110. Furthermore, the openings 111 and 112 are sealed with the sealing plates 121 and 122, respectively (S50). The sealing step with the sealing plates 121 and 122 is performed by, for example, laser welding.

[0102] The step (S51) of sealing the opening 111 with the negative electrode side sealing plate 121 may be performed after the step (S52) of sealing the opening 112 with the positive electrode side sealing plate 122, or at least some of the steps (S51, S52) of sealing with the sealing plates 121, 122 may be performed simultaneously. Furthermore, one of the steps (S51, S52) of sealing with the sealing plates 121, 122 may be performed before the electrode body 200 is inserted into the case body 110 (S40).

[0103] After the sealing step (S50) using sealing plates 121, 122 is completed, electrolyte is poured into exterior body 100 through filling holes 141, 142, and then filling holes 141, 142 are sealed. After filling holes 141, 142 are sealed, secondary battery 1 is completed through a predetermined inspection step.

[0104] (Action and effect) According to the secondary battery 1 of this embodiment, the electrode body 200 is inserted into the case body 110 having openings 111, 112 facing each other, and a negative terminal 131 and a positive terminal 132 are respectively provided on sealing plates 121, 122 that seal the openings 111, 112, respectively, thereby reducing the height of the secondary battery 1 and improving the mountability of the secondary battery 1 in a vehicle.

[0105] Furthermore, by disposing a sheet member 500 made of a separate material from the separator 230 between the first region 231 of the separator 230 arranged on the outermost periphery of the electrode body 200 and the end faces of the negative electrode plate 210 and the positive electrode plate 220, and having the sheet member 500 function as a guide when the electrode body 200 is inserted into the case body 110, it is possible to suppress shifting of the stacking of the negative electrode plate 210 and the positive electrode plate 220 in the stacked electrode body 200 and to reduce the load acting on the ends of the electrode body 200.

[0106] Furthermore, by using a strip-shaped separator 230 in which the first region 231 and the third region 233 provided on the outermost periphery of the electrode body 200 are continuous with the second region 232 folded zigzag along the multiple negative electrode plates 210 and positive electrode plates 220, the stacking misalignment of the negative electrode plates 210 and positive electrode plates 220 can be more effectively suppressed.

[0107] Furthermore, by providing the sheet member 500 only on the first region 231 side of the separator 230 between the first region 231 and the third region 233, it is possible to suppress stacking misalignment of the negative electrode plate 210 and the positive electrode plate 220 while suppressing a decrease in the volumetric energy density of the secondary battery 1.

[0108] Furthermore, by directly opposing the electrode body 200 to the inner surface of the case body 110 without using other components such as an insulator holder, it is possible to suppress stacking misalignment of the negative electrode plate 210 and the positive electrode plate 220 while suppressing a decrease in the volumetric energy density of the secondary battery 1.

[0109] Furthermore, by continuing to hold the electrode body 200 by the holding member 600 from the time when the negative electrode tab group 210A and the positive electrode tab group 220A are collected to the time when they are inserted into the case body 110, stacking misalignment of the negative electrode plates 210 and the positive electrode plates 220 can be more effectively suppressed.

[0110] As a result of the above, according to the secondary battery 1 and the manufacturing method thereof according to the present embodiment, the electrode body 200 can be efficiently housed in the case body 110 while preventing damage to the electrode body 200.

[0111] Although the embodiment of the present technology has been described above, the embodiment disclosed herein should be considered as illustrative and not restrictive in all respects. The scope of the present technology is defined by the claims, and it is intended to include all modifications within the scope and meaning equivalent to the claims. [Explanation of symbols]

[0112] 1 secondary battery, 100 exterior body, 110 case body, 110A joint, 111, 112 opening, 121, 122 sealing plate, 131 negative electrode terminal, 131A joint, 132 positive electrode terminal, 132A joint, 141, 142 liquid injection hole, 151, 152 gas exhaust valve, 200 electrode body, 210 negative electrode plate, 210A negative electrode tab group, 210B negative electrode tab, 210S negative electrode base plate, 211 negative electrode core, 212 negative electrode active material layer, 220 positive electrode plate, 220A positive electrode tab group, 220B positive electrode tab, 220S positive electrode base plate, 221 positive electrode core, 222 positive electrode active material layer, 223 positive electrode protective layer, 230 separator, 231 First region, 232, second region, 233, third region, 310, negative electrode collector, 310A, joint portion, 311, 321, first conductive member, 312, 322, second conductive member, 313, 323, joint portion, 320, positive electrode collector, 320A, joint portion, 321A, step portion, 410, 410A, 420, 420A, insulating member, 500, sheet member, 500A, through hole, 510, convex portion, 520, groove portion, 530, through hole, 600, holding member.

Claims

1. A laminated electrode assembly in which a plurality of positive electrode plates and a plurality of negative electrode plates are laminated with separators interposed therebetween; A case for accommodating the electrode body, The plurality of positive electrode plates and the plurality of negative electrode plates each have a main surface that is stacked in a stacking direction of the plurality of positive electrode plates and the plurality of negative electrode plates, and an end surface that intersects with the main surface, the separator includes a first region disposed on the end surface at the outermost periphery of the electrode assembly, a sheet member disposed between the first region of the separator and the end faces of the plurality of positive electrode plates and the plurality of negative electrode plates, the sheet member being made of a separate material from the separator.

2. The secondary battery according to claim 1 , wherein the separator includes a second region zigzag along the plurality of positive electrode plates and the plurality of negative electrode plates.

3. The end faces include a first end face and a second end face opposed to each other, The secondary battery according to claim 1 , wherein the sheet member is disposed on only one side of the first end surface and the second end surface.

4. 3. The secondary battery according to claim 1, wherein the first region of the separator directly faces an inner circumferential surface of the case via only a gas, only an electrolyte, or only both a gas and an electrolyte.

5. a positive electrode terminal and a negative electrode terminal electrically connected to the plurality of positive electrode plates and the plurality of negative electrode plates, respectively; The case is a case body having a first opening and a second opening opposite the first opening; a first sealing plate provided with the positive electrode terminal and configured to seal the first opening; 3 . The secondary battery according to claim 1 , further comprising: a second sealing plate provided with the negative electrode terminal and sealing the second opening.

6. preparing a case body having a first opening and a second opening opposite the first opening; A step of preparing a laminated electrode assembly in which a plurality of positive electrode plates and a plurality of negative electrode plates are laminated with separators interposed therebetween; A step of housing the electrode body in the case body; and after accommodating the electrode body in the case body, sealing the first opening and the second opening with a first sealing plate and a second sealing plate, respectively. The plurality of positive electrode plates and the plurality of negative electrode plates each have a main surface that is stacked in a stacking direction of the plurality of positive electrode plates and the plurality of negative electrode plates, and an end surface that intersects with the main surface, The step of preparing the electrode assembly includes disposing the first region of the separator on the end surface at an outermost periphery of the electrode assembly, A method for manufacturing a secondary battery, further comprising a step of placing a sheet member made of a separate material from the separator between the first region of the separator and the end faces of the plurality of positive electrode plates and the plurality of negative electrode plates, and a step of accommodating the electrode body in the case body includes inserting the electrode body together with the sheet member into the case body with the sheet member positioned vertically below the electrode body.

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