Cosmetic composition and hair cosmetic composition
Patent Information
- Application Number
- JP2023136176
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2023-08-24
- Publication Date
- 2025-03-07
AI Technical Summary
【0018】 本発明の上記手段により、紫外線によるダメージを軽減させ、かつべたつきを抑えた化粧料組成物を提供することができる。
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Figure 2025030676000001_ABST
Abstract
Description
[Technical field]
[0001] The present invention relates to a cosmetic composition and a cosmetic composition for hair. [Background technology]
[0002] Skin and hair are easily damaged by ultraviolet rays, heat (hair dryers, etc.), friction (brushing), etc. Hair damage can be felt particularly in changes to the feel of the hair, such as thinning, loss of elasticity and strength, and difficulty in running your fingers through it. Hair damage can also be felt in changes to the appearance, such as loss of shine and slackness.
[0003] Normally, hair is protected by the cuticle. Dyed hair is protected by the cuticle with the pigment fixed inside the hair. When dyed hair is damaged by ultraviolet rays or the like, the long-chain fatty acids on the surface of the cuticle are released and the hair is damaged. Then, the pigment is removed from the damaged cuticle, and the hair becomes prone to fading. Therefore, by preventing damage to dyed hair and making it difficult for the pigment to be removed from the cuticle, the color retention of dyed hair can be improved.
[0004] Patent Document 1 discloses a technique for a hair composition containing a color fading suppressing component. However, this technique is intended to suppress color fading (discoloration) of dyed hair caused by heat, but is not intended to suppress color fading caused by ultraviolet rays.
[0005] Patent Document 2 discloses a technology relating to a cosmetic composition for improving hair strength. However, this technology does not suppress color fading of dyed hair due to ultraviolet rays. [Prior art documents] [Patent documents]
[0006] [Patent Document 1] Patent No. 7281931 [Patent Document 2] Special Publication No. 2015-513560 Summary of the Invention [Problem to be solved by the invention]
[0007] The present invention has been made in consideration of the above problems and circumstances, and an object of the present invention is to provide a cosmetic composition and a hair cosmetic composition that reduce damage caused by ultraviolet rays and are less sticky. [Means for solving the problem]
[0008] In order to solve the above problems, the present inventors investigated the causes of the above problems and discovered that a cosmetic composition containing a fermentation product of a plant extract with lactic acid bacteria can reduce damage caused by ultraviolet rays and suppress stickiness, thereby arriving at the present invention. That is, the above-mentioned problems of the present invention are solved by the following means.
[0009] 1. Contains almond extract fermented by lactic acid bacteria A cosmetic composition comprising:
[0010] 2. It is oily 2. The cosmetic composition according to claim 1,
[0011] 3. Also contains shea butter 3. The cosmetic composition according to claim 1 or 2,
[0012] 4. The content of the fermented product is within the range of 0.008 to 0.170% by mass relative to the total mass of the cosmetic composition. 3. The cosmetic composition according to claim 1 or 2,
[0013] 5. The lactic acid bacteria is a bacillus. 3. The cosmetic composition according to claim 1 or 2,
[0014] 6. The lactic acid bacterium is a member of the genus Lactobacillus. 6. The cosmetic composition according to claim 5,
[0015] 7. A cosmetic composition comprising the cosmetic composition according to claim 1 or 2. A hair cosmetic composition comprising:
[0016] 8. For use on dyed hair 8. The hair cosmetic composition according to claim 7,
[0017] 9. Use as a styling product or leave-in treatment 8. The hair cosmetic composition according to claim 7, Effect of the Invention
[0018] According to the above-mentioned means of the present invention, it is possible to provide a cosmetic composition which reduces damage caused by ultraviolet rays and is less sticky.
[0019] Although the mechanism by which the effects of the present invention are manifested or the mechanism by which the effects of the present invention are acted upon has not been clearly understood, it is speculated as follows.
[0020] It is known that the intake of almonds strengthens the skin's ability to protect itself from UVB (ultraviolet B rays). However, according to the inventors, although the relationship with ultraviolet rays is unclear, the inventors found that the function of reducing damage caused by ultraviolet rays is dramatically improved by further fermenting the components extracted from almonds with lactic acid bacteria. In particular, it was found that the color retention of dyed hair is improved (fading can be suppressed).
[0021] Additionally, ingredients extracted from almonds contain many antioxidants, such as vitamin E. Antioxidant action refers to the ability to inhibit oxidation caused by active oxygen, and one of the causes of active oxygen is ultraviolet light. Although it is not clear, it is believed that ingredients with antioxidant action likely contribute to reducing damage caused by ultraviolet light.
[0022] The cosmetic composition of the present embodiment contains the fermented product and thus has the function of absorbing ultraviolet rays. Therefore, it is considered that by applying the cosmetic composition to skin, hair, etc., damage to skin, hair, etc. caused by ultraviolet rays can be reduced.
[0023] Compared to ultraviolet absorbers that have conventionally been used in cosmetic compositions, the fermented product is less sticky, and it is believed that stickiness can also be suppressed in cosmetic compositions containing the fermented product.
[0024] Fermented products also contain a lot of lactic acid, which is a natural moisturizing factor (NMF), and so applying them to skin or hair is thought to help maintain moisture and give the skin or hair a smooth feel. [Brief description of the drawings]
[0025] [Figure 1] SEM images of hair a in Example 1 and Comparative Example 4 DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0026] The cosmetic composition of the present embodiment is characterized by containing a fermentation product of an almond extract with lactic acid bacteria. This feature is a technical feature common to or corresponding to the following embodiments.
[0027] In this embodiment, from the viewpoint of imparting a smooth feel to the skin and hair, an oily composition is preferable.
[0028] In this embodiment, it is preferable to further contain shea butter from the viewpoint of improving color retention for dyed hair.
[0029] In this embodiment, from the viewpoint of being able to adequately impart the ultraviolet absorbing function to the cosmetic composition and obtaining sufficient storage stability, it is preferable that the content of the fermented product is within the range of 0.008 to 0.170 mass % relative to the total mass of the cosmetic composition.
[0030] In this embodiment, from the viewpoint of obtaining the effects of the present invention significantly, the lactic acid bacteria are preferably bacilli, and more preferably the lactic acid bacteria belong to the genus Lactobacillus.
[0031] The hair cosmetic composition of the present embodiment is characterized by containing the above-mentioned cosmetic composition.
[0032] The hair cosmetic composition of the present embodiment is preferably used on dyed hair, from the viewpoint of also obtaining the effect of improving color retention.
[0033] The hair cosmetic composition of the present embodiment is preferably used as a styling agent or a leave-in treatment, from the viewpoint of obtaining the effects of the present invention prominently.
[0034] The present invention, its components, and modes and aspects for carrying out the present invention will be described in detail below. In this application, the symbol "to" is used to mean that the numerical values before and after the symbol "to" are included as the lower limit and upper limit.
[0035] 1. Overview of cosmetic compositions The cosmetic composition of the present embodiment is characterized by containing a fermentation product of an almond extract with lactic acid bacteria. In this specification, the term "cosmetic" refers to cosmetics and quasi-drugs, and the cosmetic is used by applying it to the skin or hair.
[0036] Natural ingredients such as plants contain many components. Therefore, it is known that natural ingredients such as plants exert useful functions on the human body that cannot be obtained from chemically synthesized ingredients. In recent years, natural ingredients such as plants are blended as active ingredients in many cosmetics.
[0037] Sugar is broken down into lactic acid, organic acids, etc. by the enzymes contained in lactic acid bacteria. This series of processes is called "fermentation." The components obtained by fermentation with lactic acid bacteria are significantly different from the original components. Therefore, the components after fermentation may have functions that the components before fermentation did not have, and in recent years, fermented products of components extracted from plants have been attracting attention.
[0038] The inventors have found that by further fermenting the components extracted from almonds with lactic acid bacteria, the function of reducing damage caused by ultraviolet rays is dramatically improved. In particular, it has been found that the color retention of dyed hair is improved (fading can be suppressed).
[0039] 2. Components of the cosmetic composition The cosmetic composition of the present embodiment may contain, in addition to the fermentation product of an almond extract with lactic acid bacteria, known ingredients contained in cosmetic compositions, such as vegetable oils and fats, as necessary.
[0040] (1) Almond extract fermented with lactic acid bacteria In this specification, "fermentation product of almond extract with lactic acid bacteria" refers to a product obtained by fermenting almond extract with lactic acid bacteria, and is also simply referred to as "fermentation product."
[0041] In reality, plant extracts contain many components, some of which are decomposed and fermented by enzymes derived from lactic acid bacteria. Therefore, the "fermented product" contains components contained in the almond extract that are not involved in the fermentation reaction, lactic acid bacteria, and components newly produced by fermentation. The "components newly produced by fermentation" include not only the components produced by decomposition with enzymes derived from lactic acid bacteria, but also components produced by the reaction of these and other components.
[0042] (1.1) Almond extract The scientific name for almonds is "Prunus dulcis" or "Prunus amygdalus." The almond extract is not particularly limited as long as it is extracted from almonds. The extract includes not only those extracted with a solvent, but also raw materials and dried products. The part to be extracted may be any of leaves, flowers, seeds, buds, etc., but among them, seeds are preferable. These may be used as they are, or may be processed by crushing or the like.
[0043] The form of the extract is not particularly limited, and examples thereof include the extract itself, a diluted solution of the extract, a concentrated solution of the extract, a dried product thereof, a roughly purified product thereof, and a purified product thereof.
[0044] When extracting with a solvent, the extraction method and the extraction solvent are not particularly limited. Examples of the extraction method include immersion in the extraction solvent and extraction with supercritical carbon dioxide. Examples of the extraction solvent include water, ethanol, aqueous ethanol, methanol, aqueous methanol, propanol, isopropanol, 1,3-butylene glycol, propylene glycol, dipropylene glycol, glycerin, benzene, toluene, xylene, ethyl ether, methyl ethyl ketone, methyl isobutyl ketone, dichloromethane, dichloroethane, chloroform, ethyl acetate, propyl acetate, butyl acetate, and acetone. These may be used alone or in combination of two or more. The temperature of the extraction solvent is not particularly limited, and is preferably room temperature or higher and the boiling point of the extraction solvent or lower.
[0045] The cosmetic composition of the present invention is preferably oil-based, and the almond extract is preferably oil-soluble, so the extraction solvent is preferably a highly hydrophobic solvent.
[0046] The obtained extract may be subjected to centrifugation, filtration or the like to remove insoluble matter, and then may be diluted, concentrated, dried, purified, or the like by a known method.
[0047] (1.2) Lactic acid bacteria The lactic acid bacteria is not particularly limited, and examples thereof include bacteria belonging to the genera Lactobacillus, Pediococcus, Bifidobacterium, Lactococcus, Leuconostoc, and Enterococcus. Among them, the bacillus species of the Lactobacillus genus are preferred.
[0048] Examples of species of lactic acid bacteria include the genus Lactobacillus, such as Lactobacillus plantarum, Lactobacillus salivalius, Lactobacillus amylovorus, Lactobacillus casei, Lactobacillus kitasatonisi, Lactobacillus reuteri, Lactobacillus jhonsonii, Lactobacillus acidophilus, Lactobacillus brevis, Lactobacillus coryniformis, and Lactobacillus culbatus. curvatus, Lactobacillus delbrueckii, Lactobacillus farciminus, Lactobacillus rhamnosus; Pediococcus damnosus, Pediococcus halophilus, Pediococcus parvulus, Pediococcus pentosaceus; Bifidobacterium adolescentis, Bifidobacterium bifidus; bifidus); Lactococcus genus, including Lactococcus cremoris and Lactococcus lactis;Examples of the genus Leuconostoc include Leuconostoc oenos, Leuconostoc lactis, and Leuconostoc mesenteroides; examples of the genus Enterococcus include Enterococcus faecalis. Among these, Lactobacillus plantarum is preferred from the viewpoints of efficient proliferation and strong activity of the fermented product obtained.
[0049] The form of the lactic acid bacteria is not particularly limited, and may be, for example, a lactic acid bacteria powder. Specific examples include freeze-dried cells, cells treated with an enzyme and freeze-dried, etc. In addition to powder, the lactic acid bacteria may be in the form of a culture solution. Specific examples include a culture solution containing the cells, a culture supernatant, etc. In addition, the cells may be centrifuged, treated with an enzyme, etc., as necessary. Examples of the enzyme in the enzyme treatment include protease, lipase, etc.
[0050] (1.3) Fermented products The plant extract is fermented by lactic acid bacteria to obtain a fermented product. The fermentation conditions such as fermentation time and fermentation temperature are not particularly limited and can be adjusted as necessary. The fermentation method is also not particularly limited and can be, for example, static fermentation, stirring fermentation, shaking fermentation, and aeration fermentation.
[0051] The cosmetic composition of the present embodiment may contain the entire fermented product obtained by fermenting a plant extract with lactic acid bacteria, or may contain only a portion of the fermented product. However, when the cosmetic composition contains only a portion of the fermented product, it must contain the components newly produced by fermentation.
[0052] The form of the fermented product is not particularly limited and can be appropriately selected as needed. Examples of the form of the fermented product include a filtrate obtained by filtering the fermented product through a filter, a powder material obtained by freeze-drying the filtrate, and the like.
[0053] Examples of fermented almond extract include the Japan Cosmetic Industry Association's Ingredient Display Name: "Lactobacillus / Almond Seed Extract Ferment Filtrate" and the INCI Name: "Lactobacillus Prunus Amygdalus Dulcis (Sweet Almond) Seed Extract Ferment Filtrate." The "INCI name" is the international display name of cosmetic ingredients published by the Professional Cosmetic Product Council (PCPC) based on the International Nomenclature of Cosmetic Ingredients.
[0054] The content of the fermented product is preferably within the range of 0.008 to 0.170% by mass relative to the total mass of the cosmetic composition. By being within the above range, the cosmetic composition can be sufficiently endowed with the function of absorbing ultraviolet rays. In addition, the fermented product can be uniformly mixed with other components, and sufficient storage stability can be obtained.
[0055] (2) Vegetable oils and fats The cosmetic composition of the present embodiment may further contain vegetable oil. Vegetable oil has high affinity with skin and hair and gives the skin and hair a smooth feel.
[0056] The vegetable oil is not particularly limited, and examples thereof include coconut oil, palm kernel oil, cacao butter, palm oil, shea butter, mango seed oil, macadamia seed oil, jojoba oil, hazelnut seed oil, castor oil, camellia seed oil, meadowfoam oil, tea seed oil, olive fruit oil (olive oil), sasanqua oil, tea seed oil, peanut oil, avocado oil, rice bran oil, apricot kernel oil, almond oil, cottonseed oil, sesame oil, rapeseed oil, rice germ oil, wheat germ oil, corn oil, etc. Among them, the vegetable oil is preferably shea butter, macadamia seed oil, or camellia seed oil. These may be contained alone or in combination of two or more.
[0057] In particular, shea butter is known to have a peak in the ultraviolet region of 280 to 400 nm in the ultraviolet-visible absorption spectrum. It is believed that the inclusion of shea butter can further reduce damage caused by ultraviolet rays.
[0058] The vegetable oil may be in the form of a vegetable oil derivative. Examples of the vegetable oil derivative include sterol esters, and the sterol esters are preferably phytosterol esters. Phytosterol esters are esters of vegetable oil or fatty acids derived from vegetable oil and phytosterol.
[0059] Examples of sterol esters include phytosteryl macadamiate, phytosteryl sunflower seed oil fatty acid, and phytosteryl rice bran oil fatty acid. Phytosteryl macadamiate is an ester of a mixture of higher fatty acids obtained from macadamia seed oil and phytosterol. Phytosteryl sunflower seed oil fatty acid is an ester of fatty acids obtained from sunflower seed oil and phytosterol. Phytosteryl rice bran oil fatty acid is an ester of fatty acids obtained from rice bran oil and phytosterol.
[0060] Among them, the sterol esters are preferably macadamiate phytosteryl or rice bran oil fatty acid phytosteryl, and more preferably macadamiate phytosteryl.
[0061] The content of the vegetable oil is preferably within the range of 0.01 to 90% by mass, more preferably 0.05 to 90% by mass, and more preferably 0.1 to 90% by mass, based on the total mass of the cosmetic composition. By being within the above range, a smooth feel can be imparted to the skin and hair, and stickiness can be suppressed.
[0062] (3) Other ingredients The cosmetic composition of the present embodiment may further contain components that are typically contained in cosmetics, if necessary. The other components are not particularly limited, and examples thereof include oils, solid or semi-solid oils, surfactants, polymeric compounds, moisturizers, whitening agents, texture improvers, drugs, amino acids or derivatives thereof, antioxidants, sequestering agents, pH adjusters, preservatives, pigments, colorants, and fragrances.
[0063] The oil is not particularly limited as long as it is liquid at 25°C and is generally used in cosmetics. The oil may be volatile or non-volatile. The origin of the oil is not limited, and it may be an animal oil, a vegetable oil, or a synthetic oil. Examples of the oil include hydrocarbon oils, oils and fats, ester oils, triglycerides, amino acid-based oils, higher fatty acids, silicone oils, fluorine-based oils, and lanolin derivatives.
[0064] Specifically, for example, hydrocarbon oils ((C13-15) alkanes, (C15-19) alkanes, (C18-21) alkanes, (C21-28) alkanes, liquid paraffin, heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomers, squalane, polyisobutylene, polybutene, hydrogenated polyisobutene, isohexadecane, etc.), fats and oils (olive oil, castor oil, macadamia nut oil, etc.), ester oils (jojoba oil, diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, monoisostearyl adipate, glyceryl stearate ... Alkyl glycol acrylate, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, neopentyl glycol di-2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl 2-ethylhexanoate, oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexanoate Cetyl, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, dipentaerythritol fatty acid esters, isononyl isononanoate, isotridecyl isononanoate, isopropyl myristate, isopropyl palmitate, 2-octyldodecyl myristate, 2-hexyldecyl myristate, myristyl myristate , hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, 2-ethylhexyl methoxycinnamate, diisostearyl malate, etc.), triglycerides (glyceryl triisooctanoate, glyceryl triisostearate, diglyceryl diisostearate, diglyceryl triisostearate, diglyceryl tetraisostearate, decaglyceryl decaisostearate, glyceryl triisopalmitate, glyceryl trimyristate, diglyceryl myristate isostearate, tritridecyl trimellitate,tri(caprylic acid / capric acid)glyceryl, etc.), amino acid-based oils (N-lauroyl-L-glutamic acid-2-octyldodecyl ester, N-lauroyl-L-glutamic acid di(phytostearyl·2-octyldodecyl) ester, etc.), higher fatty acids (isostearic acid, oleic acid, lauric acid, myristic acid, palmitic acid, stearic acid, etc.), cyclic silicone oils (cyclotetrasiloxane, cyclopentasiloxane, cyclohexasiloxane, etc.), linear silicone oils (dimethylpolysiloxane, dimethiconol, methylphenylpolysiloxane, alkoxy-modified organopolysiloxane, fluorine-modified silicone, etc.), fluorine-based oils (perfluoropolyether, etc.), lanolin derivatives (lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin alcohol, etc.).
[0065] Examples of solid or semi-solid oils include fats and oils, such as Theobroma grandiflorum seed fat, mango seed fat, cacao butter, palm oil, palm kernel oil, coconut oil, shea butter, Shorea sthenoptera fat, African mango kernel fat, avocado fat, Sala soja seed fat, Astrocaryum murumuru fat, Astrocaryum murumuru seed fat, Astrocaryum tucuma seed fat, Garcinia indica seed fat, Tritilia emetica seed fat, Bassia latifolia seed fat, Garcinia indica seed fat, hydrogenated cacao butter, (macadamia seed oil / hydrogenated macadamia seed oil) esters, and milk fat.
[0066] Examples of nonionic surfactants include polyglycerin fatty acid esters (polyglyceryl-2 dipolyhydroxystearate, polyglyceryl-6 polyricinoleate, polyglyceryl-6 laurate, polyglyceryl-2 isostearate, etc.), sorbitan fatty acid esters (sorbitan monolaurate, sorbitan monopalmitate, etc.), glycerin fatty acid esters, and alkylene oxide adducts thereof.
[0067] Other examples of nonionic surfactants include polyoxyalkylene alkyl ethers, polyoxyalkylene fatty acid esters, polyoxyalkylene alkylphenols, polyoxyethylene sorbitol fatty acid esters, polyoxyethylene alkylphenyl formaldehyde condensates, polyoxyethylene sterol and derivatives thereof, polyoxyethylene lanolin and derivatives thereof, polyoxyethylene beeswax derivatives, sucrose fatty acid esters, polyoxyethylene hydrogenated castor oil, and polyoxyethylene castor oil.
[0068] Examples of anionic surfactants include higher fatty acid soaps, alkyl sulfates, alkyl phosphates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl phenyl ether sulfates, alkyl ether phosphates, alkyl ether carboxylates, acyl methyl taurines, N-acyl-N-methyl-β-alanines, N-acyl glycines, N-acyl glutamates, polyoxyethylene alkyl carboxylates, alkyl phenyl ether sulfons, alkyl sulfosuccinic acids and their salts, N-acyl sarcosines and their salts, polyoxyethylene coconut oil fatty acid monoethanolamide sulfates, lauroyl oat amino acids and their salts, and cocoyl apple amino acids and their salts.
[0069] Examples of the cationic surfactant include alkylamine salts (monoalkylamine salts, dialkylamine salts, trialkylamine salts, etc.), fatty acid amide alkylamines (stearamidoethyl diethylamine, stearamidopropyl dimethylamine, etc.), alkyl quaternary ammonium salts (monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, trialkyl quaternary ammonium salts, benzalkonium quaternary ammonium salts, etc.), cyclic quaternary ammonium salts (alkylpyridinium salts, etc.), benzethonium chloride, and the like.
[0070] Examples of amphoteric surfactants include alkyl dimethyl amino acetate betaines, alkyl amido amino acetate betaines, fatty acid amido propyl dimethyl amino acetate betaines, 2-alkyl-N-carboxy-N-hydroxyimidazolinium betaines, alkyl glycine salts, carboxymethyl glycine salts, N-acylaminoethyl-N-2-hydroxyethyl glycine salts, alkyl amino propionates, alkyl imino dipropionates, and alkyl hydroxy sulfobetaines.
[0071] Silicone surfactants include polyether modified silicones (PEG-11 methyl ether dimethicone, PEG / PPG-20 / 22 butyl ether dimethicone, PEG-9 dimethicone, PEG-3 dimethicone, PEG-9 methyl ether dimethicone, PEG-10 dimethicone, PEG-32 methyl ether dimethicone, cetyl PEG / PPG-10 / 1 dimethicone, PEG-9 polydimethylsiloxyethyl dimethicone, lauryl PEG-9 polydimethylsiloxyethyl dimethicone, methyl polysiloxane, methyl ether dimethicone ... Examples include san-cetyl methylpolysiloxane-poly(oxyethylene-oxypropylene) methylpolysiloxane copolymer, poly(oxyethylene-oxypropylene) methylpolysiloxane copolymer, (dimethicone / (PEG-10 / 15)) crosspolymer, etc.), polyglycerin modified silicone (polyglyceryl-3 polydimethylsiloxyethyl dimethicone, lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, etc.), dimethylsiloxane-methylcetyl siloxane copolymer, etc.
[0072] Examples of polymer compounds include acrylic acid-based thickeners, cellulose-based thickeners (methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, carboxyethylcellulose, stearoxyhydroxypropylmethylcellulose, nitrocellulose, sodium cellulose sulfate, etc.), naturally derived thickeners (xanthan gum, hydroxypropylxanthan gum, gum arabic, tragacanth gum, carbro gum, guar gum, dextran, etc.), polyvinyl alcohol, polymeric dimethylpolysiloxane, pectin, agar, quince seed, starch, algae colloid, succinoglucan, collagen, gelatin, casein, albumin, carboxymethylstarch, sodium alginate, polyvinyl methyl ether, sodium polyacrylate, polyethylene acrylate, etc.
[0073] Examples of acrylic acid-based thickeners include polyacrylamide, (hydroxyethyl acrylate / sodium acryloyldimethyl taurate) copolymer, (sodium acrylate / sodium acryloyldimethyl taurate) copolymer, (acrylamide / ammonium acrylate) copolymer, (sodium acrylate / acryloyldimethyl taurate / dimethylacrylamide) crosspolymer, polyacrylate-13, polyacrylate crosspolymer-6, (ammonium acryloyldimethyl taurate / vinyl pyrrolidone) copolymer, (acryloyldimethyl taurate / sodium acryloyldimethyl taurate) copolymer, (acryloyldimethyl taurate / ammonium acrylate) copolymer, (acryloyldimethyl taurate / ammonium acrylate) crosspolymer ... Examples of suitable copolymers include ammonium acryloyldimethyltaurate / beheneth-25 methacrylate crosspolymer, ammonium acryloyldimethyltaurate / steareth-25 methacrylate crosspolymer, acrylates / C10-30 alkyl acrylate crosspolymer, acrylates / steareth-20 methacrylate copolymer, acrylates / beheneth-25 methacrylate copolymer, acrylates / steareth-20 itaconate copolymer, steareth-10 allyl ether / acrylates copolymer, and carboxyvinyl polymer.
[0074] Examples of moisturizing agents include diglycerin, ethoxydiglycol, maltitol, sorbitol, sodium lactate, polyethylene glycol, sodium pyrrolidone carboxylate, and sodium hyaluronate.
[0075] Examples of whitening agents include hydroquinone, α-arbutin, β-arbutin, kojic acid, kojic acid dipalmitate, nicotinamide, astaxanthin, histidine dithiooctanamide (Na / zinc), placenta extract, rosemary extract, rucinol, magnolignan, ellagic acid, chamomile extract, licorice extract, rucinol, rosemary extract, arbutin, tranexamic acid, tranexamic acid cetyl hydrochloride, linoleic acid, 4-methoxysalicylic acid potassium salt, ascorbic acid and derivatives thereof (ascorbic acid glucoside, ascorbyl phosphate magnesium, glyceryl ascorbate, etc.).
[0076] Examples of texture improvers include PPG-9 diglyceryl, PEG-11 methyl ether dimethicone, bisethoxydiglycol cyclohexane-1,4-dicarboxylate, amylopectin (amylose), acylated amino acids, polymethylmethacrylate, boron nitride, silica, alumina, aluminum hydroxide, metal soap, silicone powder, polymethylmethacrylate, and dimethylsilylated silica.
[0077] Examples of the drug include skin roughness prevention agents and anti-inflammatory agents. Examples of the skin roughness prevention agents and anti-inflammatory agents include dipotassium glycyrrhizinate, stearyl glycyrrhetinate, methyl salicylate, pyridoxine hydrochloride, allantoin, sea salt, mulberry bark extract, aloe extract, gardenia extract, chamomile extract, licorice extract, soapberry extract, apricot kernel extract, scutellaria extract, sweet tea extract, loquat extract, ginkgo extract, hypericum extract, yarrow extract, safflower extract, spruce extract, salvia extract, white birch extract, tangerine peel extract, and peach kernel extract. , Gaiyou extract, Althea extract, Arnica extract, Carrot extract, Peony extract, Cnidium extract, Gentian extract, Cordyceps sinensis extract, Phellodendron bark extract, Inchinko extract, Geranium herb extract, Peach leaf extract, Kumazasa extract, Coix seed extract, Horse chestnut extract, Hawthorn extract, Coptis japonica extract, Ganoderma lucidum extract, Calendula officinalis extract, Peppermint extract, Comfrey extract, Butcher's broom extract, Malva sylvestris extract, Centaurea cyanus extract, and Togenashi extract. Other examples of drugs include hair growth drugs, acne drugs, dandruff and itching drugs, and drugs for preventing underarm odor.
[0078] Examples of amino acids include glycine, alanine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, asparagine, aspartic acid, glutamine, glutamic acid, cystine, cysteine, methionine, tryptophan, proline, histidine, etc. Examples of amino acid derivatives include salts of these amino acids, acylated, alkylated, glycerylated and esterified derivatives of these amino acids, etc.
[0079] Examples of antioxidants include sodium pyrosulfite, vitamin E and its derivatives, tannin, and BHT (butylhydroxytoluene).
[0080] Examples of sequestering agents include sodium edetic acid, phosphoric acid, citric acid, phytic acid, etidronic acid, sodium glutamic acid diacetate, and sodium pentetic acid.
[0081] Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, malic acid, gluconic acid, sodium hydroxide, potassium hydroxide, potassium carbonate, sodium hydrogen carbonate, and ammonium hydrogen carbonate.
[0082] Examples of preservatives include 1,2-alkanediols (1,2-pentanediol, 1,2-hexanediol, etc.), paraoxybenzoic acid alkyl esters (methylparaben, propylparaben, etc.), benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, ethylhexylglycerin, and levulinic acid.
[0083] These components may be contained alone or in combination of two or more.
[0084] 3. Uses of the cosmetic composition The cosmetic composition of the present embodiment is used in hair cosmetics, basic cosmetics (lotion, milky lotion, beauty essence, cream, sunscreen cream, etc.), makeup cosmetics (makeup base, foundation, eye color, blusher, lipstick, lip balm, etc.), body cosmetics (body cream, etc.), etc. By using the cosmetic composition of the present embodiment, damage caused by ultraviolet rays can be reduced and stickiness can be suppressed. Among these, from the viewpoint of obtaining remarkable effects, it is preferably used in hair cosmetics.
[0085] The formulation of the cosmetic composition of the present embodiment is not particularly limited. Examples of the formulation include oil-based cosmetics, emulsion-type cosmetics, solid cosmetics, liquid cosmetics, paste-type cosmetics, stick-type cosmetics, volatile oil-type cosmetics, powder-type cosmetics, jelly-type cosmetics, gel-type cosmetics, paste-type cosmetics, emulsion polymer-type cosmetics, sheet-type cosmetics, mist-type cosmetics, and spray-type cosmetics. More specifically, emulsion types include oil-in-water (O / W) type, water-in-oil (W / O) type, W / O / W type, and O / W / O type. Of these, the formulation is preferably an oil-based cosmetic.
[0086] (1) Hair cosmetic composition The cosmetic composition of the present embodiment is preferably for use on hair. In particular, by using the cosmetic composition on dyed hair, damage caused by ultraviolet rays can be reduced, color retention can be improved, and stickiness can be suppressed.
[0087] The hair cosmetic composition of the present embodiment may be used in a manner in which it is applied to hair and then rinsed off, but is preferably used in a manner in which it is applied to hair and then not rinsed off. Examples of hair cosmetic compositions used in a manner in which they are not rinsed off include styling agents and leave-in treatments.
[0088] Examples of hair cosmetic compositions that are used in a rinse-off manner include rinse-off treatments.
[0089] An example of the configuration of the hair cosmetic composition of this embodiment is shown below.
[0090] (Hair oil) Fermented almonds 0.1 parts by weight Shea butter 0.1 part by mass Dimethicone 20.0 parts by weight Dimethiconol 5.0 parts by mass Coconut oil 5.0 parts by weight Caprylic / capric triglyceride 69.8 parts by weight
[0091] (Hair wax) Fermented almonds 0.1 parts by weight Shea butter 0.1 part by mass Microcrystalline wax 10.0 parts by weight Squalane 10.0 parts by weight Olive oil 10.0 parts by weight Caprylic / capric triglyceride 69.8 parts by weight Microcrystalline wax is a mixture of hydrocarbons, the main component of which is isoparaffin.
[0092] 4. Manufacturing method of cosmetic composition The cosmetic composition of the present embodiment can be produced by uniformly mixing the above-mentioned components in predetermined amounts using a known method. EXAMPLES
[0093] The present invention will be described in detail below with reference to examples, but the present invention is not limited thereto. In the examples, the terms "parts" and "%" are used, but they represent "parts by mass" or "% by mass" unless otherwise specified. In the following examples, operations were carried out at room temperature (25° C.) unless otherwise specified.
[0094] 1. Preparation of Cosmetic Composition (1) Preparation of Cosmetic Composition 1 The following components were stirred at room temperature for 5 minutes to obtain cosmetic composition 1. Fermented almonds 0.17 parts by weight Caprylic / capric triglyceride 99.83 parts by weight The almond fermented product used was the Japan Cosmetic Industry Association ingredient name: "Lactobacillus / Almond Seed Extract Ferment Filtrate" and the INCI name: "Lactobacillus Prunus Amygdalus Dulcis (Sweet Almond) Seed Extract Ferment Filtrate."
[0095] (2) Preparation of Cosmetic Compositions 2 to 9 Cosmetic compositions 2 to 9 were obtained in the same manner as in preparation of cosmetic composition 1, except that the types and contents of the components were changed as shown in Tables I and II. Note that the "remaining amount" in Tables I and II refers to the remaining amount when the total amount is 100% by mass.
[0096] 2. Hair test Hair test bundles "Models: BM-WA and BS-C" (100% gray hair, manufactured by Beaulax) were dyed with a commercially available hair dye "Freshlight Milky Hair Color Champagne Pink" (manufactured by Henkel Japan). The dyed hair test bundles were then washed with a commercially available shampoo and rinsed with running water. The amount of shampoo was the same for each test. The dyed hair test bundles were then dried with a hair dryer to obtain dyed hair test bundle a (hair a).
[0097] 3. Evaluation Each cosmetic composition was subjected to the following evaluations.
[0098] (1) Stickiness evaluation (sensory evaluation) Each cosmetic composition was applied evenly to hair a and allowed to dry naturally. After that, hair a was touched and the stickiness was evaluated by two panelists on a 5-point scale. 5: Does not feel sticky at all. 4: Almost no stickiness. 3: Doesn't feel too sticky. 2: Neither. 1: Feels sticky.
[0099] The total score of the two panelists' five-point evaluation was used as the evaluation score, and the evaluation was performed according to the following criteria, where C or higher (A to C) was considered to be satisfactory for practical use. A: The evaluation score is 8 points or more (average score is 4 or more). B: The evaluation score is 6 or 7 points (average value 3 or 3.5). C: Evaluation score is 4 or 5 points (average value 2 or 2.5). D: The evaluation score is 3 points or less (average score is 1.5 or less).
[0100] Using the same evaluation method, each cosmetic composition was applied evenly to the skin and allowed to dry naturally. After that, the skin was touched and the sticky feeling was evaluated by two panelists on a 5-point scale. The evaluation results for the skin were the same as those for hair A.
[0101] (2) Hair cuticle evaluation Each cosmetic composition was applied evenly to hair a and allowed to dry naturally. Thereafter, the condition of the hair surface was photographed and observed using a scanning electron microscope (SEM) "TM4000Plus" (manufactured by Hitachi High-Tech Fielding Corporation). The condition of the hair surface was evaluated according to the following criteria. Note that a grade of C or higher (A to C) was deemed to be satisfactory for practical use. A: There is absolutely no peeling of the cuticle. B: There is almost no peeling of the cuticle. C: Cuticle peeling is only partially visible. D: Peeling of the cuticle is observed.
[0102] 1 shows SEM images of hair a in Example 1 and Comparative Example 4. No peeling of the cuticle was observed in hair a (Example 1) to which cosmetic composition 1 was applied, whereas it was found that the cuticle was peeled off overall in hair a (Comparative Example 4) to which cosmetic composition 9 was applied.
[0103] (3) Smoothness evaluation Each cosmetic composition was applied evenly to hair a and allowed to dry naturally. After that, a multipurpose hair tester "fibra.one" (manufactured by DiaStron) was used to slide a loaded contact on the surface of the hair bundle to measure the friction coefficient of the hair surface. The smaller the friction coefficient value, the smoother the hair is.
[0104] (4) Color retention evaluation (sensory evaluation) Each cosmetic composition was applied evenly to hair a. Then, the hair was irradiated with ultraviolet light for 24 hours using a UVA / UVB lamp. The irradiation conditions were: UVB: intensity 610 μW / cm 2 24 hours, UVA: 513μW / cm 2The hair a was washed with a commercially available shampoo, rinsed with running water, and then air-dried. The color fading inhibition effect (color retention) was visually evaluated according to the following criteria. A grade of C or higher (A to C) was deemed to be satisfactory for practical use. A: The color retention is extremely good. B: The color lasts very well. C: Color retention is good. D: The color doesn't last long.
[0105] (5) Color retention evaluation (color difference meter evaluation) First, for the hair test bundles before dyeing, "Model No.: BM-WA and BS-C" (100% gray hair, manufactured by Beaulax), * a * b * L in color space * , a * and b * was measured using a spectrophotometer "CM-700d" (manufactured by Konica Minolta Japan). Next, each cosmetic composition was applied uniformly to hair a. Then, ultraviolet light was irradiated for 24 hours using a UVA / UVB lamp. The irradiation conditions were as follows: UVB: intensity 610 μW / cm 2 24 hours, UVA: 513μW / cm 2 Hair a was washed with a commercially available shampoo, rinsed with running water, and then air-dried. After exposure to ultraviolet light, hair a was * a * b * L in color space * , a * and b * was measured using a spectrophotometer "CM-700d" (manufactured by Konica Minolta Japan, Inc.).
[0106] The difference between the values of hair a before dyeing and hair a after dyeing and UV irradiation is ΔL * , Δa * and Δb * Then, the color difference ΔE is calculated using the following formula: * ab was calculated. Color difference ΔE * The higher the ab value, the better the color retention. (Formula)ΔE *ab = {(ΔL * ) 2 +(Δa * ) 2 +(Δb * ) 2} 1 / 2
[0107] Tables I and II show the composition and evaluation results of each cosmetic composition. In the composition of Tables I and II, "-" indicates that the corresponding component is not contained. In addition, in the hair cuticle evaluation in Tables I and II, only Examples 1 to 5 and Comparative Examples 2 and 4 were observed. Comparative Examples 1 and 3 were not observed.
[0108] [Table 1]
[0109] [Table 2]
[0110] From the examples and comparative examples, it can be seen that by using the cosmetic composition of the present embodiment, peeling of the hair cuticle is reduced, and the hair feels smoother. It can also be seen that the color retention of dyed hair is improved. Furthermore, it can be seen that stickiness is suppressed.
[0111] A comparison between Example 1 and Comparative Example 2 shows that the fermented almond product contains components that reduce damage caused by ultraviolet rays and suppress stickiness, while non-fermented almond oil does not contain components with these functions.
[0112] Comparison of Example 1, Comparative Example 1, and Comparative Example 3 shows that the fermented almond product suppresses stickiness. On the other hand, shea butter and VP / eicosene copolymer, which are conventionally used in cosmetics, are found to cause relatively stickiness.
[0113] A comparison between Example 1 and Comparative Example 4 reveals that the fermented almond product contains ingredients that reduce damage caused by ultraviolet rays and suppress stickiness. On the other hand, ethylhexyl methoxycinnamate, a UV absorber that has been conventionally used in cosmetics, has the function of improving color retention, but is also known to cause stickiness.
[0114] Furthermore, a comparison between Example 1 and Example 3 shows that the cosmetic composition of the present embodiment further contains shea butter, thereby improving color retention.
Claims
1. Contains almond extract fermented by lactic acid bacteria A cosmetic composition comprising:
2. Oily The cosmetic composition according to claim 1 .
3. Further contains shea butter The cosmetic composition according to claim 1 or 2.
4. The content of the fermented product is within a range of 0.008 to 0.170% by mass based on the total mass of the cosmetic composition. The cosmetic composition according to claim 1 or 2.
5. The lactic acid bacteria is a bacillus The cosmetic composition according to claim 1 or 2.
6. The lactic acid bacteria is of the genus Lactobacillus. The cosmetic composition according to claim 5 .
7. A cosmetic composition comprising the cosmetic composition according to claim 1 or 2. A hair cosmetic composition comprising:
8. For use on dyed hair The hair cosmetic composition according to claim 7 .
9. Use as a styling product or leave-in treatment The hair cosmetic composition according to claim 7 .
Citation Information
Patent Citations
Cosmetic use of Balanites seed extract to improve hair strength.
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Hair composition and hair treatment method
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