Nonaqueous composition and hair treatment method
Incorporating volatile acyclic silicones and silicone surfactants with vegetable oils in non-aqueous compositions addresses turbidity issues, ensuring transparency and quality.
Patent Information
- Application Number
- JP2024064469
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2024-04-12
- Publication Date
- 2025-10-24
AI Technical Summary
Non-aqueous compositions containing volatile cyclic silicones and hydrocarbons can develop turbidity when exposed to light, causing concerns about product quality.
Incorporating volatile acyclic silicones, vegetable oils, and silicone surfactants into the composition, with specific amounts and types, to inhibit turbidity development.
The composition effectively suppresses turbidity, enhancing transparency and consumer confidence in product quality.
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Abstract
Description
[Technical Field]
[0001] The present invention relates to a non-aqueous composition suitable for use as a cosmetic, such as for hair applications, and a hair treatment method using the composition. [Background technology]
[0002] Treatment with a non-aqueous composition suitable as a leave-in treatment can impart a different feel to hair than aqueous treatments. Volatile cyclic silicones such as decamethylcyclopentasiloxane are known as commonly used ingredients in non-aqueous compositions, but due to the increasing global demand for cosmetics, there are concerns about their supply. Under these circumstances, there is a need to reduce the amount of volatile cyclic silicones used.
[0003] Volatile acyclic silicones and volatile hydrocarbons are considered to be candidates for alternative ingredients to volatile cyclic silicones. As an example of a non-aqueous composition containing these candidate alternative ingredients, Patent Document 1 discloses an oily hair cosmetic containing a volatile hydrocarbon oil, a vegetable oil, and dimethiconol with a viscosity of 10,000 mPa·s or more and 5,000,000 mPa·s or less at 25°C (see claim 1 of Patent Document 1). [Prior art documents] [Patent documents]
[0004] [Patent Document 1] Japanese Patent Application Laid-Open No. 2008-273902 Summary of the Invention [Problem to be solved by the invention]
[0005] However, when a non-aqueous composition is exposed to light, the composition may develop or develop turbidity. The development or development of turbidity during product manufacturing or on the market may cause manufacturers and consumers to feel uneasy about the quality of the product, and therefore, it is desirable to propose a technology for suppressing the development or development of turbidity.
[0006] In view of the above circumstances, an object of the present invention is to provide a non-aqueous composition that is excellent in inhibiting the occurrence or progression of cloudiness, and a hair treatment method using the composition. [Means for solving the problem]
[0007] As a result of intensive research, the present inventors have discovered that turbidity in non-aqueous compositions containing volatile acyclic silicones and / or volatile hydrocarbons occurs or progresses when vegetable oils are also blended in. The present inventors have then discovered that blending a silicone surfactant together with vegetable oils can inhibit the occurrence or progression of turbidity caused by vegetable oils, leading to the completion of the present invention.
[0008] That is, the present invention includes the non-aqueous compositions and hair treatment methods according to the following items [1] to [8]. [1] A non-aqueous composition comprising the following components (A), (B), and (C): (A) Volatile acyclic silicone and / or volatile hydrocarbon (B) Vegetable oil (C) Silicone surfactants
[0009] [2] The non-aqueous composition according to [1], wherein the amount of volatile cyclic silicone blended is less than 5% by mass or is zero. The composition of invention [2] reduces the amount of volatile cyclic silicone blended, which is subject to supply concerns.
[0010] [3] The non-aqueous composition according to [1] or [2], further comprising the following component (D): (D) Highly polymerized methylpolysiloxane and / or highly polymerized dimethiconol According to the invention [3], the incorporation of component (D) tends to cause or progress cloudiness, but component (C) inhibits the occurrence or progress of cloudiness.
[0011] [4] The non-aqueous composition according to any one of [1] to [3], which is used for hair treatment. According to the invention [4], the non-aqueous composition imparts to hair the feel of a non-aqueous hair composition.
[0012] [5] The non-aqueous composition according to any one of [1] to [4], wherein component (C) is a silicone surfactant having an organopolysiloxane in the main chain and a polyethylene glycol group or a polyglycerin group in the side chain. —(OCH2CH2)n-OH (1) [In the above general formula (1), n represents an average number of moles added of 2 or more.] —(OCH2-CHOH-CH2)m-OH (2) [In the above general formula (2), m represents an average number of moles added of 2 or more.]
[0013] [6] The non-aqueous composition according to any one of [1] to [5], wherein the blending amount of the component (A) is 30 mass% or more. The composition of the invention [6] reduces the blending amount of the volatile cyclic silicone, which is subject to supply concerns.
[0014] [7] The non-aqueous composition according to [6], wherein a volatile acyclic silicone is blended as the component (A), and the blending amount of the volatile acyclic silicone is 10 mass % or more.
[0015] [8] The non-aqueous composition according to [6] or [7], wherein a volatile hydrocarbon is blended as the component (A), and the blending amount of the volatile hydrocarbon is 10 mass% or more.
[0016] [9] The non-aqueous composition according to any one of [1] to [8], wherein the amount of component (B) blended is 3 mass% or less. According to the invention [9], the amount of component (B) blended, which causes the occurrence or progression of turbidity, is reduced, and therefore the occurrence or progression of the turbidity is also suppressed.
[0017]
[10] A hair treatment method using the non-aqueous composition according to any one of [1] to [9]. [Effects of the Invention]
[0018] The non-aqueous composition of the present invention contains a silicone surfactant, which makes it excellent at inhibiting the occurrence or progression of turbidity that accompanies the incorporation of vegetable oils.
[0019] According to the hair treatment method of the present invention, a non-aqueous composition that is excellent in inhibiting the occurrence or progression of cloudiness is used, thereby alleviating consumer concerns about quality. DETAILED DESCRIPTION OF THE INVENTION
[0020] The present invention will be described below based on the embodiments of the present invention. The non-aqueous composition according to this embodiment contains the following components (A), (B), and (C): The non-aqueous composition according to this embodiment may also contain, as optional components, components that are contained in known non-aqueous hair compositions. (A) Volatile acyclic silicone and / or volatile hydrocarbon (B) Vegetable oil (C) Silicone surfactants
[0021] The composition of this embodiment is non-aqueous, and "non-aqueous" means that the external phase of the composition does not have an oil phase or an aqueous phase. Furthermore, since adding water tends to cause separation of the aqueous phase and the oil phase and cloudiness of the composition, it is preferable not to add water. If water is added, the amount of water added is preferably less than 3.0% by mass, preferably less than 1.0% by mass, more preferably less than 0.5% by mass, even more preferably less than 0.1% by mass, and even more preferably less than 0.05% by mass.
[0022] (Component (A) Volatile Acyclic Silicone and / or Volatile Hydrocarbon) The non-aqueous composition of this embodiment contains component (A), which is a volatile acyclic silicone, a volatile hydrocarbon, or a volatile acyclic silicone and a volatile hydrocarbon. As long as the non-aqueous composition of this embodiment contains either a volatile acyclic silicone or a volatile hydrocarbon, it may not contain a volatile acyclic silicone or a volatile hydrocarbon. Component (A) is suitable as a replacement for volatile cyclic silicones such as decamethylcyclopentasiloxane.
[0023] The amount of component (A) in the non-aqueous composition of this embodiment is preferably 30% by mass or more, more preferably 55% by mass or more, more preferably 70% by mass or more, even more preferably 80% by mass or more, and even more preferably 90% by mass or more in order to reduce the amount of volatile cyclic silicone. Furthermore, the amount of component (A) is preferably 98% by mass or less, more preferably 95% by mass or less, and more preferably 93% by mass or less in order to increase the amounts of other components.
[0024] The volatile acyclic silicone, component (A), does not have a cyclic skeleton in its molecular structure, unlike volatile cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane. The kinematic viscosity of the volatile acyclic silicone at 25°C is 3.0 mm. 2 / s or less, and to make it easier to dry hair etc. during use, 2.5mm 2 / s or less is good, 2.0mm 2 / s or less (the lower limit of the kinematic viscosity is set to, for example, 1.0 mm 2 / s or more is preferable.)
[0025] When blending the volatile acyclic silicone as component (A), it is advisable to blend one or more types selected from known volatile acyclic silicones, such as linear dimethylpolysiloxanes such as trisiloxane, branched silicones such as methyltrimethicone, and silicones having alkyl groups on the side chains such as ethylmethicone.
[0026] When the volatile acyclic silicone (component (A)) is blended in the non-aqueous composition of this embodiment, the blending amount of the volatile acyclic silicone in the composition is preferably 10% by mass or more, more preferably 30% by mass or more, more preferably 50% by mass or more, even more preferably 70% by mass or more, and even more preferably 90% by mass or more in order to reduce the blending amount of the volatile cyclic silicone. Furthermore, in order to reduce the cost of the non-aqueous composition, the blending amount of the volatile acyclic silicone is preferably 90% by mass or less, more preferably 80% by mass or less, more preferably 60% by mass or less, even more preferably 50% by mass or less, and even more preferably 40% by mass or less.
[0027] When a volatile hydrocarbon (component (A)) is blended, it is preferable to blend one or more types selected from known volatile hydrocarbons. Examples of such volatile hydrocarbons include isododecane, light liquid isoparaffin, and undecane / tridecane. The boiling point of the volatile hydrocarbon at normal pressure is preferably 260°C or less or 265°C or less. Furthermore, the volatile hydrocarbon should have a kinematic viscosity of 5.0mm at 37.8°C to facilitate drying of hair and the like during use. 2 / s or less is good, 4.0mm 2 / s or less is preferred.
[0028] When a volatile hydrocarbon (component (A)) is blended, the blending amount of the volatile hydrocarbon in the composition is preferably 10% by mass or more, more preferably 30% by mass or more, more preferably 50% by mass or more, even more preferably 70% by mass or more, and even more preferably 90% by mass or more in order to reduce the blending amount of the volatile cyclic silicone. Also, from the viewpoint of increasing the blending amounts of other components, the blending amount of the volatile hydrocarbon is preferably 90% by mass or less, more preferably 70% by mass or less, more preferably 50% by mass or less, and even more preferably 30% by mass or less.
[0029] (Component (B) vegetable oil) The non-aqueous composition of this embodiment contains a vegetable oil, which is an oil and fat mainly composed of a triester of fatty acid and glycerin, as component (B). Both liquid vegetable oils that are fluid at 25°C and solid vegetable oils that are not fluid at 25°C ("solid" refers to those that are not fluid, and semi-solids are also included in the solid category as long as they are not fluid) fall under component (B) in this embodiment.
[0030] The non-aqueous composition of this embodiment contains a liquid vegetable oil, a solid vegetable oil, or a liquid and solid vegetable oils as component (B). The vegetable oil as component (B) is selected from known vegetable oils, such as almond oil, avocado oil, olive oil, kukui nut oil, rice bran oil, corn oil, safflower oil, shea butter, shea butter, evening primrose oil, passionflower seed oil, camellia oil, persic oil, baobab seed oil, babassu oil, palm kernel oil, peanut oil, sunflower oil, grape seed oil, hazelnut oil, macadamia nut oil, meadowfoam oil, and rosehip oil.
[0031] The non-aqueous composition of this embodiment contains one or more vegetable oils as component (B). From the viewpoint of imparting a pleasant feel to hair, the amount of component (B) in the non-aqueous composition of this embodiment is preferably 0.001% by mass or more, more preferably 0.005% by mass or more, more preferably 0.03% by mass or more, even more preferably 0.1% by mass or more, and even more preferably 0.3% by mass or more. From the viewpoint of suppressing the occurrence or progression of cloudiness, the amount of component (B) is preferably 3% by mass or less, more preferably 2% by mass or less, more preferably 1.5% by mass or less, even more preferably 1.0% by mass or less, and even more preferably 0.5% by mass or less.
[0032] (Component (C) Silicone-based surfactant) The silicone surfactant blended as component (C) in the non-aqueous composition of this embodiment suppresses the occurrence or progression of clouding due to light exposure. Silicone surfactants as component (C) that have the dispersibility or solubility of component (A) are suitable from the viewpoints of suppressing clouding, suppressing the progression of clouding, and improving transparency of the non-aqueous composition of this embodiment. When a volatile acyclic silicone is blended in the non-aqueous composition of this embodiment, the silicone surfactant should have a kinematic viscosity at 25°C of 1.5 mm or less. 2 It is preferable to select as component (C) a silicone surfactant that dissolves in methylpolysiloxane, which is / s, and when a volatile hydrocarbon is blended into the nonaqueous composition of this embodiment, it is preferable to select as component (C) a silicone surfactant that dissolves in isododecane.
[0033] The silicone surfactant of component (C) is preferably a non-crosslinked structure, rather than a crosslinked structure such as a (dimethicone / (PEG-10 / 15)) crosspolymer. The silicone surfactant of component (C) preferably has an organopolysiloxane in the main chain and a polyethylene glycol group represented by the following general formula (1) or a polyglycerin group represented by the following general formula (2) in the side chain. —(OCH2CH2)n-OH (1) [In the above general formula (1), n represents an average number of moles added of 2 or more.] —(OCH2-CHOH-CH2)m-OH (2) [In the above general formula (2), m represents an average number of moles added of 2 or more.]
[0034] The non-aqueous composition of this embodiment contains a known silicone surfactant as component (C). Examples of the silicone surfactant as component (C) include linear polyether-modified silicone surfactants such as PEG-3 dimethicone, PEG-7 dimethicone, PEG-8 dimethicone, PEG-9 dimethicone, PEG-10 dimethicone, and PEG-12 dimethicone ("linear" in the silicone surfactant context means that the main chain contains organopolysiloxane and the side chain does not contain organopolysiloxane); branched polyether-modified silicone surfactants such as PEG-9 polydimethylsiloxyethyl dimethicone (silicone surfactants); In surfactants, "branched" means that the main chain contains organopolysiloxane and the side chain contains organopolysiloxane; branched polyglycerin-modified silicone surfactants such as polyglyceryl-3 polydimethylsiloxyethyl dimethicone; branched polyether-alkyl co-modified silicone surfactants such as lauryl PEG-9 polydimethylsiloxyethyl dimethicone; and branched polyglycerin-alkyl co-modified silicone surfactants such as lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone.
[0035] The non-aqueous composition of this embodiment contains one or more silicone surfactants as component (C). From the viewpoint of suppressing the occurrence or progression of cloudiness, the amount of component (C) in the non-aqueous composition of this embodiment is preferably 0.001% by mass or more, more preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and even more preferably 0.5% by mass or more. Furthermore, from the viewpoint of suppressing the progression of cloudiness when exposed to light, the amount of component (C) is preferably 10% by mass or less, more preferably 5% by mass or less, and more preferably 1% by mass or less.
[0036] (optional ingredient) The non-aqueous composition of this embodiment can contain optional components that are included in known non-aqueous compositions. Among the optional components, highly polymerized methylpolysiloxane and / or highly polymerized dimethiconol (component (D)) are suitable for improving hair smoothness, etc. While the incorporation of component (D) tends to cause clouding or the progression of clouding, component (C) inhibits the occurrence or progression of clouding.
[0037] When the non-aqueous composition of this embodiment contains component (D), it is preferable to use one or more selected from highly polymerized methylpolysiloxanes and highly polymerized dimethiconols. As long as either highly polymerized methylpolysiloxanes or highly polymerized dimethiconols are contained, the highly polymerized methylpolysiloxanes or highly polymerized dimethiconols may be absent. The amount of component (D) contained in the non-aqueous composition of this embodiment is preferably 1% by mass or more and less than 15% by mass, and more preferably 2% by mass or more and less than 10% by mass. A content of component (D) of 1% by mass or more and less than 15% by mass is favorable for improving the ease of combing hair when drying, as well as the softness, smoothness, and moisturized feel of hair after drying.
[0038] The highly polymerized methylpolysiloxane of component (D) is a linear polymer having a siloxane bond as the backbone and an average degree of polymerization of 650 or more, and is preferably one or more types selected from known highly polymerized methylpolysiloxanes. The amount of the highly polymerized methylpolysiloxane in the non-aqueous composition according to this embodiment is preferably 1% by mass or more but less than 15% by mass, 2% by mass or more but less than 10% by mass, or 3% by mass or more but less than 5% by mass. A content of component (D) of 1% by mass or more but less than 15% by mass is favorable for improving the ease of running fingers through hair when drying, as well as the softness, smoothness, and moisturized feel of hair after drying.
[0039] The highly polymerized dimethiconol of component (D) is a linear polymer having a siloxane bond as the backbone and an average degree of polymerization of 650 or more, and has hydroxyl groups at the terminals of the polymer. One or more types selected from known highly polymerized dimethiconols may be blended as component (D). The amount of the highly polymerized dimethiconol blended in the non-aqueous composition according to this embodiment may be 1% by mass or more but less than 15% by mass, 2% by mass or more but less than 10% by mass, or 3% by mass or more but less than 5% by mass. A blending amount of component (D) of 1% by mass or more but less than 15% by mass is favorable for improving the ease of combing hair when drying, as well as the softness, smoothness, and moisturized feel of hair after drying.
[0040] The non-aqueous composition of this embodiment can contain volatile cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane as optional components, but due to supply concerns about volatile cyclic silicones, it is preferable to avoid their incorporation and either not incorporate them or limit the amount incorporated. The amount of volatile cyclic silicone incorporated in the non-aqueous composition of this embodiment is preferably less than 5% by mass, preferably less than 3% by mass, more preferably less than 1% by mass, even more preferably less than 0.1% by mass, and even more preferably less than 0.05% by mass.
[0041] Furthermore, in order to prevent separation of the aqueous phase and the oil phase, it is preferable to avoid incorporating highly hygroscopic components such as ethanol into the non-aqueous composition of this embodiment, or to limit the amount of ethanol incorporated. The amount of ethanol incorporated in the non-aqueous composition of this embodiment is preferably less than 3% by mass, preferably less than 1% by mass, more preferably less than 0.5% by mass, even more preferably less than 0.1% by mass, and even more preferably less than 0.01% by mass.
[0042] Examples of optional components that can be blended into the non-aqueous composition of the present embodiment include nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, higher alcohols, hydrocarbons (other than those corresponding to component (A)), waxes, ester oils, silicones (other than those corresponding to components (A) and (D)), polymeric compounds, ultraviolet absorbers, preservatives, chelating agents, fragrances, and colorants.
[0043] (Dosage form) The dosage form of the non-aqueous composition of this embodiment when used is not particularly limited, and examples thereof include liquid, cream, and mist forms.
[0044] (viscosity) When the viscosity of the non-aqueous composition of this embodiment is measured using a Brookfield viscometer (temperature: 25°C, rotor: set appropriately according to viscosity, rotor rotation speed: set appropriately according to viscosity), the value measured 60 seconds after the start of viscosity measurement is preferably 1000 mPa·s to 20,000 mPa·s, more preferably 3000 mPa·s to 15,000 mPa·s, more preferably 4000 mPa·s to 12,000 mPa·s, and even more preferably 5000 mPa·s to 10,000 mPa·s. A viscosity of 1000 mPa·s or higher can prevent dripping when applied to the hand, and a viscosity of 20,000 mPa·s or lower can easily be spread on the hair surface. When used by spraying, the viscosity is preferably less than 10,000 mPa·s to facilitate spraying.
[0045] (Application) The non-aqueous composition of this embodiment is preferably used as a hair treatment composition. The hair treatment method in this use is, for example, use as a leave-in treatment. When used in this manner, the target is hair that has been chemically treated (by oxidation hair dyeing, bleaching, straightening, or the like) or hair that has not been chemically treated. For example, the non-aqueous composition of this embodiment is sprayed or applied by hand to dry hair or to wet hair that has been towel-dried after washing, and then dried with warm air as needed.
[0046] When the non-aqueous composition of the present embodiment is used as a product, the product may include, for example, the non-aqueous composition of the present embodiment and a container for containing the composition. Even if the container is translucent or transparent and light-transmitting, the occurrence or progression of cloudiness can be prevented by the product user. [Example]
[0047] The present invention will be described in detail below based on examples, but the present invention should not be construed as being limited by the descriptions in these examples.
[0048] Non-aqueous compositions of Examples, Comparative Examples, and Reference Examples that can be used as leave-in hair treatments were prepared, and the suppression of cloudiness of these compositions was evaluated. The details are as follows.
[0049] (Non-aqueous composition) As compositions for the Examples, Comparative Examples, and Reference Examples, non-aqueous compositions were prepared with the ingredients and amounts listed in Tables 1 to 4 below. The ingredients used in these preparations were decamethyltetrasiloxane (kinematic viscosity at 25°C: 1.5 mm 2 / s), light liquid isoparaffin (kinematic viscosity at 37.8°C: 2.6 mm 2 / s), isododecane, mixed raw material 1 (Dow-Toray "DOWSIL PMX-1507 Fluid", kinematic viscosity at 25°C 2 mm 2 / s), Mixed Stock 2 (Momentive Performance Materials' "XF49-B2317", a mixture of light liquid isoparaffin and highly polymerized methylpolysiloxane), Mixed Stock 3 (Momentive Performance Materials' "Silsoft B3020", a mixture of isododecane and highly polymerized methylpolysiloxane), Evening Primrose Oil (TEXTRON Tecnica's "EVENING PRIMROSE OIL REFINED"), Baobab Seed Oil (Cremer Oleo's "CremerVERO Baobab Oil") Organic), PEG-9 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd. "KF-6028P"), polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd. "KF-6104"), PEG-10 dimethicone (Shin-Etsu Chemical Co., Ltd. "KF-6017P"), POE lauryl ether (2E.O.), POE·POP cetyl ether (1E.O.) (4P.O.). Note that "POE" above stands for "polyoxyethylene" and "POP" stands for "polyoxypropylene," and the number immediately before "EO" stands for the average number of moles of ethylene oxide added, and the number immediately before "PO" stands for the average number of moles of propylene oxide added.
[0050] (Evaluation of inhibition of progression of cloudiness) Each non-aqueous composition was poured into a transparent vial (height 12 cm, diameter approximately 4 cm), and the container was sealed. Thereafter, the container was irradiated with light (using a xenon weather meter "XT750L" manufactured by Suga Test Instruments Co., Ltd., at an ultraviolet intensity of 9.4 W / m 2 The test was carried out under conditions of 24 hours and a temperature of 25°C.) The light irradiation time was 24 hours for Examples 1 and 2, Comparative Examples 1a and 1b, and Comparative Examples 2a and 2b, 18 hours for Examples 3a to 3c and Comparative Examples 3a and 3b, and 34 hours for Comparative Examples 4a and 4b and Reference Examples 1 to 3.
[0051] The container was photographed before and after the above-mentioned light irradiation, and the inhibition of the progress of clouding of the non-aqueous composition due to light irradiation was evaluated as follows. ◎: No cloudiness has developed ○: The degree of cloudiness is less than the standard △: Standard (clouding progresses due to light exposure) or the degree of clouding is equivalent to the standard ×: The degree of cloudiness is greater than the standard
[0052] The components, blend amounts, and evaluation results of the clouding suppression of the compositions of Example 1 and Comparative Examples 1a and 1b are shown in Table 1. Table 1 confirms that (1) Comparative Example 1b, which contained component (D), resulted in more clouding than Comparative Example 1a, which did not contain component (D), and (2) Example 1, which contained component (D) like Comparative Example 1b, was better at suppressing the clouding suppression than Comparative Example 1a due to the inclusion of component (C).
[0053] [Table 1]
[0054] The components, blend amounts, and evaluation results of the clouding suppression of the compositions of Examples 2a-2b and Comparative Examples 2a-2b are shown in Table 2. Table 2 confirms that (1) Comparative Example 2b, which contained component (D), resulted in more clouding than Comparative Example 2a, which did not contain component (D), and (2) on the other hand, Examples 2a-2b, which contained component (D) like Comparative Example 2b, were better at suppressing the clouding suppression than Comparative Example 2a due to the inclusion of component (C).
[0055] [Table 2]
[0056] The components, blend amounts, and evaluation results of the clouding suppression of the compositions of Examples 3a to 3c and Comparative Examples 3a to 3c are shown in Table 3. Table 3 confirms that (1) Comparative Examples 3b to 3c, which are compositions in which a specific nonionic surfactant was added to Comparative Example 3a, were equivalent to Comparative Example 3a in that no clouding suppression was observed, and (2) on the other hand, Examples 3a to 3c, which contained component (C), were better at suppressing clouding than Comparative Example 3a due to the inclusion of component (C).
[0057] [Table 3]
[0058] Table 4 below shows the components, blend amounts, and evaluation results for the inhibition of clouding progression of the compositions of Examples 4a to 2b and Reference Examples 1 to 3. Table 4 confirms that (1) Comparative Examples 4a to 4b, which contained component (B), resulted in more clouding than Reference Example 1, which did not contain component (B), and (2) Reference Examples 2 and 3, which contained an oily component other than component (B), such as isostearyl isostearate, achieved evaluation results equivalent to those of Reference Example 1.
[0059] [Table 4]
Claims
1. A non-aqueous composition comprising the following components (A), (B), and (C): (A) Volatile acyclic silicone and / or volatile hydrocarbon (B) Vegetable oil (C) Silicone surfactant
2. The non-aqueous composition according to claim 1, wherein the amount of the volatile cyclic silicone blended is less than 5% by mass or the volatile cyclic silicone is not blended at all.
3. The non-aqueous composition according to claim 1 or 2, further comprising the following component (D): (D) Highly polymerized methylpolysiloxane and / or highly polymerized dimethiconol
4. The non-aqueous composition according to claim 1 or 2, which is used for treating hair.
5. 3. The non-aqueous composition according to claim 1, wherein component (C) is a silicone surfactant having an organopolysiloxane main chain and a polyethylene glycol group represented by the following general formula (1) or a polyglycerin group represented by the following general formula (2) in a side chain: ―(OCH 2 CH 2 )n-OH (1) In the above general formula (1), n represents an average number of moles added of 2 or more. ―(OCH 2 -CHOH-H 2 )m-OH (2) [In the above general formula (2), m represents that the average number of moles added is 2 or more.]
6. The non-aqueous composition according to claim 1 or 2, wherein the blending amount of the component (A) is 30% by mass or more.
7. 7. The non-aqueous composition according to claim 6, wherein a volatile acyclic silicone is blended as the component (A), and the blending amount of the volatile acyclic silicone is 10 mass% or more.
8. The non-aqueous composition according to claim 6, wherein a volatile hydrocarbon is blended as the component (A), and the blending amount of the volatile hydrocarbon is 10 mass % or more.
9. The non-aqueous composition according to claim 1 or 2, wherein the blending amount of the component (B) is 3 mass % or less.
10. A hair treatment method using the non-aqueous composition according to claim 1 or 2.
Citation Information
Patent Citations
Oily hair cosmetic
JP2008273902A