Multi-agent cosmetic composition and multi-agent hair dyeing or bleaching composition

Abstract

To provide a multi-agent type cosmetic composition having both physical properties of exhibiting good adhesiveness to prevent dripping when mixed in use or when applied to keratin tissues such as skin and hair, and physical properties of exhibiting spreadability after application.SOLUTION: A multi-agent type cosmetic composition comprising a plurality of constituent agents including the following components (A) an ionic surfactant, component (B) a cationic polymer, component (C) a higher alcohol, and component (D) a nonionic surfactant, wherein the composition comprises agents I and II having different viscosities at least at 30°C, and the viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and a ratio (shear viscosity a / shear viscosity b) of a shear viscosity a at a shear rate of 0.00037 s-1 to a shear viscosity b at a shear rate of 139S-1, which is measured by a rheometer at 25 °C. when the shear rate is changed from 0.0001 s-1 to 10000s-1, is 5000 or more.

Description

[Technical Field]

[0001] The present invention relates to a multi-component cosmetic composition and a multi-component hair dyeing or bleaching composition. [Background technology]

[0002] A wide variety of cosmetic products are known in terms of formulation and composition to provide various functions and effects in response to the diverse needs of users, and some cosmetic products are composed of multiple ingredients that are mixed together before use. For example, Patent Document 1 discloses a multi-component cosmetic that includes an oil-based cosmetic and an oil-in-water emulsion cosmetic, each containing specific ingredients, and is mixed at the time of use and applied to keratinous tissue, and aims to improve the fragrance that is given off after such mixing. Furthermore, Patent Document 2 discloses a cosmetic product for bleaching or dyeing hair, which comprises a first agent of a specific viscosity containing an alkaline agent and a second agent of a specific viscosity containing hydrogen peroxide, and in which the mixture of the first agent and the second agent contains specific components in a specific mass ratio, and which attempts to improve adhesion to the hair in the initial stage of application and make it easier to spread after a certain period of time has passed. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Publication No. 2020-200285 [Patent Document 2] Japanese Patent Application Laid-Open No. 2016-113462 Summary of the Invention [Problem to be solved by the invention]

[0004] When applying such multi-component cosmetics to the skin, hair, etc., it is highly desirable that the cosmetics exhibit excellent adhesion so that they do not drip unnecessarily from the hands, applicators, the target, etc. when mixing them at the time of use or when applying them to the target, and that once applied, they spread well and can be applied smoothly to the target. However, since increasing adhesion to prevent unwanted dripping and realizing ease of spreadability depend on mutually contradictory physical properties, it is extremely difficult to fully achieve both of these in a multi-component cosmetic, even if simple viscosity control, etc. is implemented. For this reason, detailed investigations have yet to be fully conducted on any of the technologies described in the above patent documents, and this goal has yet to be achieved.

[0005] That is, the present invention relates to a multi-component cosmetic composition that combines physical properties that exhibit good adhesion to prevent dripping when mixed during use or when applied to keratinous tissues such as skin or hair, and physical properties that exhibit ease of spreadability after application.The present invention also relates to a multi-component hair dyeing or bleaching composition that, when applied to hair, exhibits excellent application properties that exhibit a good balance of adhesion, spreadability, and penetration in hair, while suppressing the noticeable unevenness of hair color and exhibiting excellent effect of hair color compatibility. [Means for solving the problem]

[0006] Therefore, the present inventors conducted extensive research and found that by creating a multi-component cosmetic composition that contains an ionic surfactant, a cationic polymer, a higher alcohol, and a nonionic surfactant, and that comprises multiple components including at least two components with different viscosities, and that is mixed together at the time of use, when applied to keratinous tissues such as skin and hair, the composition has excellent adhesion, preventing dripping, while being very easy to spread, and also providing a smooth feel to the touch, which led to the completion of the present invention. Furthermore, when hair is the target of application, the inventors have discovered that a multi-component hair dyeing or bleaching composition is a composition in which all components are mixed together at the time of use, and the composition comprises two components: an agent containing an ionic surfactant and a cationic polymer, and an agent containing a higher alcohol and a nonionic surfactant containing two specific surfactants in a specific mass ratio, and the mixture obtained by mixing all the components contains a specific amount of nonionic surfactant. This composition has excellent applicability, exhibiting a good balance of adhesion, spreadability, and penetration, while suppressing the noticeable unevenness of hair color, allowing for hair dyeing or bleaching with excellent compatibility with the hair color, and has led to the completion of the present invention.

[0007] Therefore, the present invention provides the following components (A) to (D): (A) Ionic surfactant (B) Cationic polymer (C) Higher alcohol (D) Nonionic surfactant A multi-component cosmetic composition comprising a plurality of components, including a component I and a component II, each of which has a different viscosity at 30°C, and in which all of the components are mixed together at the time of use, The viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and In a mixture obtained by mixing all the constituent ingredients, the shear rate measured by a rheometer at 25°C was 0.001 S -1 ~1000S -1 When the shear rate was changed to 0.0037S -1 Shear viscosity a and shear rate at 139S -1The present invention provides a multi-component cosmetic composition in which the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5,000 or more.

[0008] The present invention also provides a cosmetic kit comprising a multi-component cosmetic composition and a treatment composition that is separate and independent and contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), A multi-component cosmetic composition comprising the following components (A) to (D): (A) Ionic surfactant (B) Cationic polymer (C) Higher alcohol (D) Nonionic surfactant A multi-component cosmetic composition comprising a plurality of components, including a component I and a component II, each of which has a different viscosity at 30°C, and in which all of the components are mixed together at the time of use, The viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and In a mixture obtained by mixing all the constituent ingredients, the shear rate measured by a rheometer at 25°C was 0.001 S -1 ~1000S -1 When the shear rate was changed to 0.0037S -1 Shear viscosity a and shear rate at 139S -1 The present invention provides a cosmetic kit in which the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5000 or more.

[0009] Furthermore, the present invention provides a multi-component hair dyeing or bleaching composition comprising a plurality of components including component I' and component II', which are mixed together at the time of use, comprising: The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) A nonionic surfactant containing a polyoxyethylene-added nonionic surfactant (D-1) having an average number of moles of ethylene oxide added of 100 or less, and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of moles of ethylene oxide added of more than 100. The present invention provides a multi-component hair dyeing or bleaching composition comprising: a component (D-1) content and a component (D-2) content (D-1 / D-2) mass ratio of 2 or less; and a component (D) content of 1.63 mass% or more in a mixture obtained by mixing all of the constituent components. [Effects of the Invention]

[0010] The multi-component cosmetic composition of the present invention exhibits good adhesion that effectively prevents unwanted dripping when the agents are mixed during use or when applied to keratinous tissue, and also exhibits excellent spreadability that makes it easy to spread and coat after application to keratinous tissue. This also promotes the penetration of the multi-component cosmetic composition of the present invention into keratinous tissue, allowing it to fully exert its desired effects on keratinous tissue. Furthermore, if a cosmetic kit is prepared that includes the above-mentioned multi-component cosmetic composition and a separate, independent treatment composition, the desired effects on keratinous tissue can be more effectively and practically exerted. Furthermore, when the multi-component hair dyeing or bleaching composition of the present invention is applied to hair, it exhibits excellent penetration and spreadability in hair, while effectively suppressing the conspicuousness of uneven hair color due to dyeing or bleaching, and exhibits excellent hair color compatibility from the roots to the ends, and from the surface to the inside of the hair strand, making it possible to dye or bleach hair to give a uniform hair color. DETAILED DESCRIPTION OF THE INVENTION

[0011] The present invention will be described in detail below. In the present invention, "adhesion" means the property of the composition to adhere firmly and tightly to the hand or applicator used, or the keratinous tissue to which it is applied, when the composition is applied, such as when the agent is applied to the keratinous tissue, thereby preventing unwanted dripping. Furthermore, "extendability" refers to the property of the composition to spread evenly over the surface of the application without being unevenly distributed in one part of the application area, and to the property of providing good spreadability and a smooth feel along the application direction. Furthermore, "penetration" means the property of the composition to reach from the surface to the inside of the hair bundle and to be evenly applied, particularly when the keratinous tissue is a hair bundle containing hair. Furthermore, "applicability" refers to the property of exhibiting three physical properties in a balanced manner: adhesion to keratinous tissues, spreadability, and penetration. Furthermore, "hair color compatibility" means that the composition does not become concentrated in certain areas such as the roots of the hair or the surface of the hair bundle, but spreads well and easily reaches every corner of the entire application area, including the ends of the hair and the inside of the hair bundle, thereby effectively suppressing the appearance of uneven hair color and expressing a hair color that is compatible and uniform throughout the entire application area, from the roots to the ends of the hair, and from the surface to the inside of the hair bundle. Also, "the roots of the hair" means the part where the hair grows out from the scalp, that is, the part close to the skin. Furthermore, "the difference in hair color is noticeable" means that the roots of hair dyed with hair dye have grown out, and the border between the dyed part and the hair color is noticeable, in other words, it is in a state of "pudding-like." The term "average number of moles added" refers to the average number of ethylene oxide units bonded to the activator molecule, and is a value determined by reverse phase liquid chromatography or size exclusion chromatography.

[0012] The multi-component cosmetic composition of the present invention is a multi-component composition comprising multiple components, including two components, component I and component II, which have different viscosities at at least 30°C, and is a composition in which, at the time of use, all of the components, including these two components, are mixed together in advance, and the mixture is applied to keratinous tissue. The keratinous tissue to which the multi-component cosmetic composition of the present invention is applied refers to the keratin-containing layer that protects the outermost layer on the body surface of mammals such as humans, and specifically includes skin, hair, body hair other than hair, toenails, fingernails, etc. Among keratinous tissues, from the viewpoint of fully enjoying the effects of the present invention, it is preferable to use the skin or hair, and it is more preferable to use the hair.

[0013] The multi-component cosmetic composition of the present invention contains at least two components, component I and component II, and may contain other components in addition to these two components. Thus, it may be a two-component cosmetic composition containing components I and II as components, or it may be a three-component cosmetic composition, four-component cosmetic composition, or five-component cosmetic composition that contains one or more components in addition to components I and II, or a cosmetic composition that contains five or more components.

[0014] The components I and II contained in the multi-component cosmetic composition of the present invention have different viscosities at 30°C, and the viscosity ratio of the viscosity of component II at 30°C to the viscosity of component I at 30°C (component II / component I) is 3 or greater. The multi-component cosmetic composition of the present invention comprises two components having this viscosity relationship, and also contains specific components (A) to (D) as described below, and is able to exhibit unique viscosity characteristics in the mixture obtained when all of the components are mixed. The reason why the composition of the present invention exhibits such effects is not clear, but is presumed to be as follows. The agents I and II of the multi-component cosmetic composition of the present invention have different viscosities at 30°C, and the viscosity ratio of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) is 3 or more, which increases the permeability of the mixture of agents I and II into keratinous tissues. Furthermore, a coacervate complex is formed during mixing of the mixture, and this complex causes the mixture obtained by mixing all of the constituent agents to penetrate the keratinous tissue at a shear rate of 0.0037 S. -1 Shear viscosity a and shear rate at 139S -1Since the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5000 or more, it is presumed that the adhesion of the mixture is high and that when the mixture is subjected to shear, the viscosity decreases and extensibility increases. Furthermore, it is presumed that the mixture exhibits a good balance of the three physical properties of penetration into keratinous tissues, adhesion, and extensibility, which improves the ease of application to keratinous tissues, and when used as a hair coloring or hair bleaching composition, the composition can instantly penetrate deep into hair strands, easily achieving hair coloring or bleaching that exhibits excellent compatibility with the hair color.

[0015] The viscosity ratio of the viscosity of Agent II at 30°C to the viscosity of Agent I at 30°C (Agent II / Agent I) (the value obtained by dividing the viscosity of Agent II at 30°C by the viscosity of Agent I at 30°C) is, from the viewpoint of exhibiting good penetration into keratinous tissues, 3 or more, preferably 100 or more, more preferably 800 or more, even more preferably 1200 or more, still more preferably 1500 or more, and preferably 6000 or less, more preferably 5000 or less, even more preferably 4000 or less, and still more preferably 3000 or less. The viscosity ratio of the viscosity of Agent II at 30°C to the viscosity of Agent I at 30°C (Agent II / Agent I) is 3 or more, preferably 100 to 6000, more preferably 800 to 5000, even more preferably 1200 to 4000, and still more preferably 1500 to 3000.

[0016] The viscosity of agent I at 30°C should be lower than that of agent II so long as the above viscosity ratio is maintained, but is preferably 5000 mPa·s or less, more preferably 3000 mPa·s or less, and even more preferably 1 mPa·s or more.

[0017] The viscosity of component II at 30°C should be higher than that of component I so long as the above viscosity ratio is maintained, but is preferably 1000 mPa·s or more, more preferably 3000 mPa·s or more, even more preferably 5000 mPa·s or more, and preferably 50000 mPa·s or less, more preferably 40000 mPa·s or less, and even more preferably 30000 mPa·s or less.

[0018] The viscosity at 30°C refers to a value measured using a Brookfield viscometer, specifically, by the method described in the examples.

[0019] When using the multi-component cosmetic composition of the present invention, all of the components, including the two components I and II, are mixed in advance, and the resulting mixture is applied to keratinous tissue. The mixture obtained by mixing all of the components is subjected to a shear rate of 0.001 s measured with a rheometer at 25°C. -1 ~1000S -1 When the shear rate was changed to 0.0037S -1 Shear viscosity a and shear rate at 139S -1 The ratio of shear viscosity a to shear viscosity b at shear rate (shear viscosity a / shear viscosity b) is not less than 5000. Here, the rheometer is a rotational rheometer, and for example, an MCR301 manufactured by Anton Paar can be used to examine the shear rate dependency of the shear viscosity of the multi-component cosmetic composition of the present invention as a mixture obtained by mixing all of the constituent ingredients. The shear rate is 0.0037S. -1 Shear viscosity a and shear rate at 139S -1 Specifically, the ratio of shear viscosity a to shear viscosity b at a shear rate of 0.0037 S (shear viscosity a / shear viscosity b) is measured by the method described in the Examples. -1 The shear viscosity a and shear rate at 139 s -1 It means the value calculated by dividing the shear viscosity b at the time of the shear viscosity b by the shear viscosity b at the time of the shear viscosity b.

[0020] For example, the shear rate is 0.0037 S, which is the low speed range. -1Shear viscosity a at a shear rate of 139 S -1 A composition with a small ratio of shear viscosity a to shear viscosity b at a shear rate of 0.0037 (shear viscosity a / shear viscosity b) either has good adhesion but is difficult to spread, or has no adhesion but is easy to spread. On the other hand, when this ratio is very large, the composition has physical properties that provide excellent adhesion and good ease of spreading. Therefore, the multi-component cosmetic composition of the present invention has a shear rate of 0.0037 when the mixture obtained by mixing all of the constituent ingredients is -1 Shear viscosity a and shear rate at 139S -1 It is believed that the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5000 or more, and this is due in part to the coacervate complex formed, which results in both good adhesion and excellent extensibility during use.

[0021] In the mixture, the shear rate is 0.0037 -1 Shear viscosity a and shear rate at 139S -1 From the viewpoint of exhibiting both good adhesion and excellent extensibility, the ratio of shear viscosity a to shear viscosity b at a shear rate of 0.0037 (shear viscosity a / shear viscosity b) is 5000 or more, preferably 6000 or more, more preferably 7000 or more, and preferably 20000 or less, more preferably 18000 or less, and even more preferably 10200 or less. -1 Shear viscosity a and shear rate at 139S -1 The ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5,000 or more, preferably 5,000 to 20,000, more preferably 6,000 to 18,000, and even more preferably 7,000 to 10,200.

[0022] The multi-component cosmetic composition of the present invention contains an ionic surfactant as component (A), a cationic polymer as component (B), a higher alcohol as component (C), and a nonionic surfactant as component (D). Unless otherwise specified, the content of each component contained in the multi-component cosmetic composition of the present invention is expressed as a value relative to the total amount of the multi-component cosmetic composition of the present invention, i.e., the total amount of the mixture obtained by mixing all of the constituent components, which is 100% by mass.

[0023] The multi-component cosmetic composition of the present invention contains an ionic surfactant as component (A). Specifically, component (A) preferably contains one or two surfactants selected from an anionic surfactant (A-1) and a cationic surfactant (A-2).

[0024] The anionic surfactant of component (A-1) preferably contains an anionic surfactant having a sulfate group. Specifically, it is preferred to contain one or more selected from alkyl sulfates, alkenyl sulfates, polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, and polyoxyalkylene alkyl phenyl ether sulfates. The number of carbon atoms in the alkyl or alkenyl group contained in component (A-1) is preferably 6 to 18, more preferably 12 to 18. More specifically, it is preferred to contain a lauryl or lauroyl group, or a stearyl or stearoyl group as the preferred alkyl or alkenyl group. In particular, it is preferable that component (A-1) contains a polyoxyalkylene alkyl ether sulfate, and the average number of moles of ethylene oxide added in such a polyoxyalkylene alkyl ether sulfate is preferably 1 to 4, and more preferably 1 to 2.

[0025] However, in order to avoid imparting unique viscosity characteristics to the mixture, it is preferable to limit the content of anionic surfactants having a carboxyl group in the multi-component cosmetic composition of the present invention. Specifically, the content of anionic surfactants having a carboxyl group in the multi-component cosmetic composition of the present invention is preferably 0.45% by mass or less, more preferably 0.35% by mass or less, and even more preferably 0.10% by mass or less. Alternatively, it is preferable that the multi-component cosmetic composition of the present invention is substantially free of anionic surfactants having a carboxyl group. Examples of such anionic surfactants having a carboxyl group include N-acylamino acid salts, N-acyl-N-alkylamino acid salts, amide-type N-acylamino acid salts, ether carboxylate salts, fatty acid salts, alkyl succinate salts, and alkenyl succinate salts. In particular, the anionic surfactant having a carboxyl group whose inclusion is restricted in the multi-component cosmetic composition of the present invention preferably contains one or more N-acylamino acids selected from N-lauroyl glutamic acid, N-myristoyl glutamic acid, and N-cocoyl glutamic acid, from the viewpoint of not inhibiting the unique viscosity characteristics of the mixture, and more preferably contains N-cocoyl glutamic acid or its sodium salt.

[0026] The cationic surfactant of component (A-2) preferably contains a cationic surfactant having a quaternary ammonium group represented by the following formula (1).

[0027] [ka]

[0028] (In formula (1), R 1 , R 2 , R 3 and R 4 each independently represents a hydrocarbon group which may have a substituent, and R 1 , R 2 , R 3 and R 4One or two of X1 have 8 to 36 carbon atoms, and the remainder have 1 to 7 carbon atoms. - indicates an anion.)

[0029] The hydrocarbon group preferably contains a linear or branched alkyl group, a linear or branched alkenyl group, an aryl group, or an aralkyl group, and the substituent preferably contains a hydroxy group, an alkoxy group, an aryloxy group, an epoxy group, an amino group, a mono- or di-alkylamino group, a trialkylammonium group, a fatty acid amide group, or a fatty acid ester group.

[0030] R 1 , R 2 , R 3 and R 4 One or two (preferably one) of R is a linear or branched alkyl group, and the number of carbon atoms therein is preferably 8 to 30, more preferably 10 to 24, and even more preferably 12 to 18. 1 , R 2 , R 3 and R 4 The remainder of the above is an alkyl group, preferably having 1 to 3 carbon atoms, more preferably 1 or 2, and even more preferably 1 carbon atom.

[0031] X - Examples of the cation include chloride ion, bromide ion, iodide ion, methyl sulfate ion, ethyl sulfate ion, acetate ion, phosphate ion, sulfate ion, lactate ion, and saccharin ion. Among these, chloride ion or bromide ion is preferred from the viewpoint of availability.

[0032] Specific examples of such component (A-2) include cetyltrimethylammonium chloride (cetrimonium chloride), stearyltrimethylammonium chloride (steartrimonium chloride), isostearyltrimethylammonium chloride (isostearyltrimonium chloride), lauryltrimethylammonium chloride (lauryltrimonium chloride), behenyltrimethylammonium chloride (behentrimonium chloride), cocoyltrimethylammonium chloride (cocotrimonium chloride), cetyltrimethylammonium bromide (cetrimonium chloride), It is preferable that the surfactant contains one or more selected from the group consisting of stearyltrimethylammonium bromide (steartrimonium bromide), lauryltrimethylammonium bromide (lauryltrimonium bromide), isostearyl lauryl dimethylammonium chloride (isostearyl lauryl dimonium chloride), dicetyl dimethyl ammonium chloride (dicetyldimonium chloride), distearyl dimethyl ammonium chloride (distearyldimonium chloride), and dicocoyl dimethyl ammonium chloride (dicoccodimonium chloride).

[0033] Among these, component (A-2) preferably contains one or more selected from monoalkyltrimethylammonium chloride and monoalkyltrimethylammonium bromide, and more preferably contains one or more selected from stearyltrimethylammonium chloride (steartrimonium chloride), cetyltrimethylammonium chloride (cetrimonium chloride), and lauryltrimethylammonium chloride (lauryltrimonium chloride).

[0034] From the viewpoint of achieving good adhesion and excellent extensibility, it is preferable that the mixture contains both an anionic surfactant (A-1) and a cationic surfactant (A-2) as component (A).

[0035] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (A) in the multi-component cosmetic composition of the present invention is preferably 0.48% by mass or more, more preferably 0.60% by mass or more, even more preferably 0.96% by mass or more, and preferably 1.99% by mass or less, more preferably 1.8% by mass or less, and even more preferably 1.44% by mass or less. The content of component (A) in the multi-component cosmetic composition of the present invention is preferably 0.48 to 1.99% by mass, more preferably 0.60 to 1.8% by mass, and even more preferably 0.96 to 1.44% by mass.

[0036] The multi-component cosmetic composition of the present invention contains a cationic polymer as component (B). The term "cationic polymer" refers to a polymer having a substituent that becomes a cation when dissolved in water.

[0037] Specifically, such component (B) preferably contains one or more selected from the group consisting of a polymer containing a diallyl quaternary ammonium salt as a constituent unit, a cationized polygalactomannan, a cationized hydroxyalkyl cellulose, a copolymer containing methacrylamide propyl trimethyl ammonium chloride, and a crosslinked cationic polymer.

[0038] The polymer containing a diallyl quaternary ammonium salt as a constituent unit preferably contains a polymer represented by the following formula (2) or (3).

[0039] [ka]

[0040] (In formula (2) or (3), R 5 and R 6may be the same or different and represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an aryl group (e.g., a phenyl group), a hydroxyalkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxyalkyl group, or a carboalkoxyalkyl group; R 7 and R 8 may be the same or different and represent a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, or a phenyl group; X2 - represents an anion (chloride ion, bromide ion, iodide ion, sulfate anion, sulfonate anion, methyl sulfate anion, phosphate anion, nitrate anion, etc.).

[0041] From the viewpoint of effectively achieving both good adhesion and excellent extensibility, the polymer containing a diallyl quaternary ammonium salt as a structural unit preferably contains structural units represented by formula (2) or (3) in an amount of 85 to 100 mol %, more preferably 90 to 100 mol %, and even more preferably 95 to 100 mol % per molecule. The mass-average molecular weight is preferably 10,000 or more, more preferably 50,000 or more, and even more preferably 100,000 or more, and preferably 3,000,000 or less, more preferably 1,000,000 or less, and even more preferably 200,000 or less.

[0042] The mass average molecular weight means a value measured by gel permeation chromatography (GPC) under the following conditions. Mobile phase: 50 mM LiBr, 1% by mass CH3COOH / ethanol:water = 3:7 Column: TSK gel α-M (two columns in series) Standard substance: polyethylene glycol

[0043] More specifically, the cationized polygalactomannan of component (B) preferably contains one or more species selected from cationized guar gum, cationized tara gum, cationized locust bean gum, and the like. More specifically, the cationized hydroxyalkyl cellulose of component (B) preferably contains one or two types selected from cationized hydroxyethyl cellulose, cationized hydroxypropyl cellulose, and the like. The copolymer containing methacrylamidepropyltrimethylammonium chloride of component (B) preferably contains one or more selected from acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymers and acrylic acid / acrylamide / methacrylamidopropyltrimethylammonium chloride copolymers. More specifically, the crosslinked cationic polymer of component (B) preferably contains an N,N-dimethylaminoethyl methacrylate diethyl sulfate / N,N-dimethylacrylamide / polyethylene glycol dimethacrylate copolymer or the like.

[0044] Among such component (B), component (B) preferably contains a polymer containing a diallyl quaternary ammonium salt as a constituent unit, and more preferably contains one or more selected from a homopolymer of a diallyl quaternary ammonium salt and a copolymer of a diallyl quaternary ammonium salt and acrylic acid. More specifically, component (B) preferably contains one or more selected from polydiallyldimethylammonium chloride, diallyldimethylammonium chloride / acrylic acid copolymer, diallyldimethylammonium chloride / acrylamide copolymer, and diallyldimethylammonium chloride / acrylic acid / acrylamide copolymer.

[0045] From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the charge density of component (B) is preferably 4.0 meq / g or more, more preferably 4.3 meq / g or more, even more preferably 4.6 meq / g or more, still more preferably 4.9 meq / g or more, even more preferably 5.2 meq / g or more, even more preferably 5.5 meq / g or more, and preferably 8.0 meq / g or less, more preferably 7.0 meq / g or less, and even more preferably 6.5 meq / g or less. The term "charge density" means the number of moles of cationic groups per gram of polymer x 1000 (meq / g).

[0046] Of these components (B), it is preferable that component (B) contains a polymer containing a diallyl quaternary ammonium salt as a structural unit, and more specifically, it is preferable that component (B) contains one or more selected from Merquat 100 (manufactured by Lubrizol Advanced Materials, a homopolymer of diallyl quaternary ammonium), Merquat 280NP Polymer, and Merquat 295 Polymer (all manufactured by Lubrizol Advanced Materials, a copolymer of diallyl quaternary ammonium salt and acrylic acid).

[0047] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (B) in the multi-component cosmetic composition of the present invention is preferably 0.03% by mass or more, more preferably 0.18% by mass or more, even more preferably 0.29% by mass or more, and preferably 0.59% by mass or less, more preferably 0.55% by mass or less, and even more preferably 0.44% by mass or less. The content of component (B) in the multi-component cosmetic composition of the present invention is preferably 0.03 to 0.59% by mass, more preferably 0.18 to 0.55% by mass, and even more preferably 0.29 to 0.44% by mass.

[0048] The multi-component cosmetic composition of the present invention contains a higher alcohol as component (C), which can be exemplified by the following formula (4):

[0049] R 9 -OH (4) (In formula (4), R 9 represents a straight or branched chain hydrocarbon group having 6 to 36 carbon atoms.

[0050] R 9 From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the number of carbon atoms in R is preferably 10 to 24, more preferably 12 to 22, and even more preferably 14 to 22. 9 is preferably a straight-chain or branched-chain alkyl or alkenyl group, more preferably a straight-chain alkyl group.

[0051] More specifically, such component (C) may be one or more selected from myristyl alcohol, cetanol, stearyl alcohol, arachyl alcohol, behenyl alcohol, oleyl alcohol, etc. Among these, it is preferable to contain one or more selected from cetanol, stearyl alcohol, and behenyl alcohol, and it is more preferable to contain two or more of these.

[0052] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (C) in the multi-component cosmetic composition of the present invention is preferably 1.52% by mass or more, more preferably 1.9% by mass or more, even more preferably 3.03% by mass or more, and preferably 6.08% by mass or less, more preferably 5.7% by mass or less, and even more preferably 4.54% by mass or less. The content of component (C) in the multi-component cosmetic composition of the present invention is preferably 1.52 to 6.08% by mass, more preferably 1.9 to 5.7% by mass, and even more preferably 3.03 to 4.54% by mass.

[0053] In the multi-component cosmetic composition of the present invention, the mass ratio of the content of component (C) to the content of component (A) ((C) / (A)) is preferably 2 or more, more preferably 2.5 or more, even more preferably 2.77 or more, still more preferably 3.1 or more, and preferably 5 or less, more preferably 3.75 or less, and even more preferably 3.50 or less, from the viewpoint of effectively achieving good adhesion and excellent spreadability. In the multi-component cosmetic composition of the present invention, the mass ratio of the content of component (C) to the content of component (A) ((C) / (A)) is preferably 2 or more, more preferably 2.5 to 5, even more preferably 2.77 to 3.75, and even more preferably 3.1 to 3.50.

[0054] The multi-component cosmetic composition of the present invention contains a nonionic surfactant as component (D). Specifically, component (D) preferably contains one or more surfactants selected from polyoxyalkylene alkyl ethers, alkyl alkanolamides, polyoxyalkylene alkylamines, alkyl polyglucosides, alkyl glyceryl ethers, and the like. The polyoxyalkylene alkyl ether preferably contains one represented by the following formula (5). R 10 -O-(A a O) r -H (5) (In formula (5), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r represents an average number of 1 to 300.

[0055] R 10 The number of carbon atoms in the alkyl group is preferably 10 to 22, more preferably 12 to 20, and even more preferably 12 to 18, from the viewpoint of effectively promoting the formation of a coacervate complex in the mixture. A is preferably an ethylene group or a propylene group, more preferably an ethylene group. r is the so-called average number of moles added, and is preferably 1 to 300, more preferably 2 to 250, even more preferably 30 to 200, and even more preferably 90 to 180.

[0056] Among such polyoxyalkylene alkyl ethers, it is preferable to contain those represented by the following formula (5a) or (5b).

[0057] [ka]

[0058] (In formula (5a), the sum of m and n is 9 to 11, and p is a number from 3 to 15.) In addition, p in the formula (5a) means the so-called average number of moles added.

[0059] R 11 -O-(A b O)qH (5b) (In formula (5b), R 11 represents a linear saturated hydrocarbon group having 16 carbon atoms, and A b represents an alkylene group having 2 carbon atoms, and q represents an average value of 20 to 200. In addition, q in the formula (5b) means the so-called average number of moles added.

[0060] Examples of the alkyl alkanolamide of component (D) include those represented by the following formula (6).

[0061] [ka]

[0062] (In formula (6), R 12 represents a linear or branched, saturated or unsaturated hydrocarbon group having 5 to 23 carbon atoms, and R 13 and R 14 each independently represents a hydrogen atom or an alkanol group having 1 to 4 carbon atoms, provided that R 13 and R 14Except when is also a hydrogen atom.)

[0063] R 12 The number of carbon atoms in the alkyl group is preferably 8 to 22, more preferably 10 to 20, and even more preferably 12 to 18, from the viewpoint of effectively promoting the formation of a coacervate complex in the mixture.

[0064] More specifically, such alkylalkanolamides include one or more selected from coconut oil fatty acid monoethanolamide, coconut oil fatty acid diethanolamide, lauric acid isopropanolamide, and oleic acid diethanolamide.

[0065] An example of the polyoxyalkylene alkylamine of component (D) is one represented by the following formula (7).

[0066] [ka]

[0067] (In formula (7), R 15 represents a linear or branched, saturated or unsaturated hydrocarbon group having 5 to 23 carbon atoms; A c and A d each independently represents an ethylene group or a propylene group, s and t each represent an average value, and the sum of s and t is 5 to 50.

[0068] R 15 From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the number of carbon atoms in A is preferably 8 to 22, more preferably 10 to 20, and even more preferably 12 to 18. c and A d is preferably an ethylene group. The sum of s and t is preferably 8 to 30, and more preferably 10 to 20.

[0069] More specifically, such polyoxyalkylene alkylamines include one or more selected from polyoxyethylene laurylamine, polyoxyethylene cetylamine, polyoxyethylene cocamine, and the like.

[0070] Examples of the alkyl polyglucoside of component (D) include those having an alkyl group with 6 to 22 carbon atoms and a condensation degree of the glucoside unit of 1 to 7. Specific examples include one or more selected from octyl polyglucoside, 2-ethylhexyl polyglucoside, decyl polyglucoside, lauryl polyglucoside, myristyl polyglucoside, palmityl polyglucoside, isostearyl polyglucoside, stearyl lauryl polyglucoside, oleyl polyglucoside, and behenyl polyglucoside. Of these, the alkyl polyglucoside of component (D) preferably contains those having an alkyl group with 8 to 18 carbon atoms and a condensation degree of the glucoside unit of 1 to 7.

[0071] More specifically, such alkyl glyceryl ethers include one or more selected from isostearyl glyceryl ether, isostearyl pentaerythryl glyceryl ether, and the like.

[0072] Among these components (D), from the viewpoint of effectively achieving both good adhesion and excellent extensibility, it is preferable that component (D) contains a polyoxyalkylene alkyl ether, and it is more preferable that the polyoxyalkylene alkyl ether contains at least a polyoxyalkylene alkyl ether represented by the above formula (5a) or (5b).

[0073] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (D) in the multi-component cosmetic composition of the present invention is preferably 1.63% by mass or more, more preferably 2.04% by mass or more, even more preferably 3.26% by mass or more, and preferably 6.51% by mass or less, more preferably 6.11% by mass or less, and even more preferably 4.95% by mass or less. The content of component (D) in the multi-component cosmetic composition of the present invention is preferably 1.63 to 6.51% by mass, more preferably 2.04 to 6.11% by mass, and even more preferably 3.26 to 4.95% by mass.

[0074] From the viewpoint of further enhancing the good adhesion and excellent spreadability exhibited during use, the multi-component cosmetic composition of the present invention preferably further contains component (E), which is a chloride of one or two selected from alkali metal salts of organic acids having 6 or less carbon atoms, alkaline earth metal salts of organic acids having 6 or less carbon atoms, inorganic alkali metal salts, and inorganic alkaline earth metal salts. Examples of organic acids constituting the alkali metal salts of organic acids having 6 or less carbon atoms and the alkaline earth metal salts of organic acids having 6 or less carbon atoms include acetic acid, carbonic acid, carboxylic acid, sulfuric acid, etc. Furthermore, examples of the alkali metals in these alkali metal salts include sodium and potassium, and examples of the alkaline earth metals in these alkaline earth metal salts include calcium and magnesium. Specifically, the alkali metal salt of an organic acid having 6 or less carbon atoms and the alkaline earth metal salt of an organic acid having 6 or less carbon atoms preferably contain one or more selected from potassium acetate, calcium acetate, potassium sulfate, and calcium sulfate.

[0075] Examples of the alkali metal in the inorganic alkali metal salt include sodium and potassium, and examples of the alkaline earth metal in the inorganic alkaline earth metal salt include calcium and magnesium. Specifically, the inorganic alkali metal salt and inorganic alkaline earth metal salt preferably contain one or more salts selected from potassium chloride, sodium chloride, calcium chloride, magnesium chloride, and the like.

[0076] Among these components (E), it is more preferable to contain one or more selected from sodium chloride, magnesium chloride, and potassium chloride as component (E), from the viewpoint of effectively enhancing good adhesion and excellent extensibility.

[0077] The content of component (E) in the multi-component cosmetic composition of the present invention is preferably 0.01% by mass or more, more preferably 0.3% by mass or more, even more preferably 0.7% by mass or more, and preferably 1.3% by mass or less, more preferably 1.2% by mass or less, and even more preferably 1.0% by mass or less. The content of component (E) in the multi-component cosmetic composition of the present invention is preferably 0.01 to 1.3% by mass, more preferably 0.3 to 1.2% by mass, and even more preferably 0.7 to 1.0% by mass.

[0078] The multi-component cosmetic composition of the present invention preferably contains water, from the viewpoint of ensuring the solubility or dispersibility of each component in the mixture and effectively achieving both good adhesion and excellent spreadability. The water content in the multi-component cosmetic composition of the present invention is preferably 50% by mass or more, more preferably 60% by mass or more, even more preferably 70% by mass or more, and preferably 98% by mass or less, more preferably 95% by mass or less, and even more preferably 90% by mass or less. The water content in the multi-component cosmetic composition of the present invention is preferably 50 to 98% by mass, more preferably 60 to 95% by mass, and even more preferably 70 to 90% by mass.

[0079] The multi-component cosmetic composition of the present invention preferably contains a dye when it is intended for use on hair, i.e., when it is used as a hair cosmetic composition, preferably a composition for hair coloring or hair bleaching. This allows the composition to instantly penetrate deep into the hair strands due to the good adhesion and excellent spreadability that it exhibits during use, making it easy to achieve hair coloring or bleaching that is excellent in compatibility with the hair color. Such dyes include oxidation dye intermediates or direct dyes.

[0080] Examples of oxidation dye intermediates include precursors such as paraphenylenediamine, toluene-2,5-diamine, orthochloroparaphenylenediamine, N-phenylparaphenylenediamine, N,N-bis(hydroxyethyl)paraphenylenediamine, 3-methyl-4-aminophenol, 2-hydroxyethylparaphenylenediamine, paraaminophenol, paramethylaminophenol, 4-amino-metacresol, orthoaminophenol, 1-hydroxyethyl-4,5-diaminopyrazole, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-pyrimidinol, 2-methoxymethyl-paraphenylenediamine, and salts thereof; Examples of couplers include one or more selected from couplers such as resorcinol, 2-methylresorcinol, 1-naphthol, 1,5-dihydroxynaphthalene, 5-amino-o-cresol, meta-phenylenediamine, meta-aminophenol, 2,4-diaminophenoxyethanol, 2,6-diaminopyridine, 2-methyl-5-hydroxyethylaminophenol, 2-amino-3-hydroxypyridine, 4-chlororesorcinol, and salts thereof.

[0081] The content of the oxidative dye intermediate in the multi-component cosmetic composition of the present invention is preferably 0.003% by mass or more, more preferably 0.03% by mass or more, and preferably 1.67% by mass or less, more preferably 1.33% by mass or less. The content of the oxidative dye intermediate in the multi-component cosmetic composition of the present invention is preferably 0.003 to 1.67% by mass, more preferably 0.03 to 1.33% by mass.

[0082] Examples of direct dyes include acid dyes such as Blue No. 1, Purple No. 401, Black No. 401, Orange No. 205, Red No. 227, Red No. 106, Yellow No. 203, and Acid Orange 3; Nitro dyes such as 2-nitro-p-phenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-p-hydroxyethylaminophenol, 4-nitro-o-phenylenediamine, 4-amino-3-nitrophenol, 4-hydroxypropylamino-3-nitrophenol, HC Blue 2, HC Orange 1, HC Red 1, HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Red 3, and N,N-bis(2-hydroxyethyl)-2-nitro-p-phenylenediamine; Disperse dyes such as Disperse Purple 1, Disperse Blue 1, Disperse Black 9; Basic dyes such as Basic Blue 99, Basic Brown 16, Basic Brown 17, Basic Red 76, Basic Yellow 76, Basic Orange 31, Basic Red 51, etc.; Examples of other dyes include one or more selected from the group consisting of picramic acid, basic purple 2, basic yellow 57, basic brown 16, yellow No. 403, basic purple 2, basic yellow 87, HC blue 18, HC yellow 16, HC red 16, basic blue 124, yellow No. 4, HC blue 15, and tetrabromophenol blue.

[0083] The content of the direct dye in the multi-component cosmetic composition of the present invention is preferably 0.0003% by mass or more, more preferably 0.003% by mass or more, and preferably 1.67% by mass or less, more preferably 1.33% by mass or less. The content of the direct dye in the multi-component cosmetic composition of the present invention is preferably 0.003 to 1.67% by mass, more preferably 0.03 to 1.33% by mass.

[0084] The multi-component cosmetic composition of the present invention, particularly when it is intended for use on hair, i.e., when it is used as a hair cosmetic composition, preferably a composition for hair coloring or hair bleaching, preferably contains a dye, an alkaline agent, and hydrogen peroxide. It is also desirable that the alkaline agent and hydrogen peroxide are contained in different constituents of the multi-component cosmetic composition of the present invention. Furthermore, granulated substances such as persulfates may be contained.

[0085] Examples of such alkaline agents include one or more selected from ammonia and its salts, such as strong aqueous ammonia and ammonium chloride; alkanolamines and their salts, such as monoethanolamine, isopropanolamine, 2-amino-2-methylpropanol, and 2-aminobutanol; alkanediamines and their salts, such as 1,3-propanediamine; and carbonates, such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, and potassium hydrogencarbonate.

[0086] From the viewpoint of achieving a sufficient hair dyeing or bleaching effect and preventing excessive damage or irritation to the subject of application, the content of the alkaline agent in the multi-component cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, even more preferably 0.2% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less, even more preferably 10% by mass or less, and still more preferably 5% by mass or less. The content of the alkaline agent in the multi-component cosmetic composition of the present invention is preferably 0.05 to 20% by mass, more preferably 0.1 to 15% by mass, even more preferably 0.2 to 10% by mass, and even more preferably 0.2 to 5% by mass.

[0087] Hydrogen peroxide is contained in a component of the multi-component cosmetic composition of the present invention that is different from the component containing the alkaline agent. The content of hydrogen peroxide in the multi-component cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1% by mass or more, even more preferably 2% by mass or more, and preferably 6% by mass or less, more preferably 5% by mass or less.

[0088] The multi-component cosmetic composition of the present invention may contain an oily component as a component other than the above-mentioned components. Specific examples of such oily components include non-volatile silicones such as dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, and aminopolyether-modified silicone; low-boiling chain silicones such as hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and hexadecamethylheptasiloxane; cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane; Hydrocarbon oils such as liquid paraffin, liquid isoparaffin, light liquid isoparaffin, polybutene, hydrogenated polydecene, petrolatum, squalane, and isododecane; Ester oils such as diglyceryl isostearate, triglyceryl isostearate, triglyceryl 2-ethylhexanoate (trioctanoin), caprylic / capric triglycerin, isopropyl myristate, isopropyl palmitate, cetyl 2-ethylhexanoate, diisostearyl maleate, 2-heptylundecyl palmitate, isotridecyl isononanoate, and octyldodecyl myristate; Waxes such as beeswax, spermaceti, lanolin, carnauba wax, candelilla wax, hydrogenated jojoba oil, and montan wax; Examples include one or more selected from aliphatic alcohols having 1 to 5 carbon atoms, such as methanol, ethanol, propanol, isopropyl alcohol, and butanol.

[0089] The content of the oily component in the multi-component cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, even more preferably 1% by mass or more, and preferably 15% by mass or less, more preferably 10% by mass or less, and even more preferably 3% by mass or less. The content of the oily component in the multi-component cosmetic composition of the present invention is preferably 0.1 to 15% by mass, more preferably 0.3 to 10% by mass, and even more preferably 1 to 3% by mass.

[0090] In addition to the above-mentioned components, the multi-component cosmetic composition of the present invention may contain other components commonly used as cosmetic raw materials, such as fragrances, moisturizers, preservatives, chelating agents, pH adjusters, stabilizers, antioxidants, disinfectants, protein derivatives, hydrolyzed proteins, amino acids, plant extracts, herbal extracts, vitamins, and ultraviolet absorbers.

[0091] However, from the viewpoint of not inhibiting the development of good adhesion and excellent spreadability during use, the multi-component cosmetic composition of the present invention preferably does not contain salicylic acid or acetaminophen, and more preferably does not contain either of these.

[0092] The forms of the constituent ingredients contained in the multi-component cosmetic composition of the present invention, including Agent I and Agent II, can be appropriately selected from liquid, gel, paste, cream, foam, mist, etc. Among these, from the viewpoint of imparting the above-mentioned viscosity ratio (Agent II / Agent I) and from the viewpoint of imparting the above-mentioned ratio of shear viscosity a to shear viscosity b (shear viscosity a / shear viscosity b) in the mixture obtained by mixing all the constituent ingredients, it is preferable that Agent I be in the form of a liquid and Agent II be in the form of a cream. Furthermore, it is preferable that the form of the mixture obtained by mixing all the constituent ingredients contained in the multi-component cosmetic composition of the present invention be in the form of a gel.

[0093] Furthermore, from the viewpoint of promoting the formation of a coacervate complex in the mixture obtained by mixing all of the constituent ingredients, imparting the above-mentioned ratio of shear viscosity a to shear viscosity b (shear viscosity a / shear viscosity b), and effectively exhibiting good adhesion and excellent extensibility, it is preferable that at least component I contains component (A-1) and component (B), and that at least component II contains component (A-2), component (C), and component (D).

[0094] Furthermore, when the multi-component cosmetic composition of the present invention is to be applied to hair, i.e., when it is used as a hair cosmetic composition, preferably a composition for hair coloring or hair bleaching, it is preferable to include the dye in the above-mentioned Agent I, from the viewpoint of allowing the composition to instantly penetrate deep into the hair strands due to the good adhesion and excellent spreadability that are exhibited during use, and easily achieving hair coloring or bleaching that is excellent in compatibility with the hair color.

[0095] When obtaining a mixture of all the components contained in the multi-component cosmetic composition of the present invention, the order of mixing these components is not particularly limited, and they may be mixed all at once or may be mixed sequentially as appropriate. In particular, when agent I is in the form of a liquid and agent II is in the form of a cream, it is preferable to add agent I to at least agent II and mix them, from the viewpoint of achieving uniform mixing and more effectively achieving good adhesion and excellent spreadability.

[0096] The present invention relates to a multi-component hair dyeing or bleaching composition for use on hair, more specifically, the composition comprises a plurality of components including components I' and II', and all of the components are mixed together at the time of use, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) A nonionic surfactant containing a polyoxyethylene-added nonionic surfactant (D-1) having an average number of moles of ethylene oxide added of 100 or less, and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of moles of ethylene oxide added of more than 100. The multi-component hair dyeing or bleaching composition contains the above components, wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (D) in the mixture obtained by mixing all of the constituent components is 1.63 mass% or more.

[0097] That is, in the case of the multi-component hair dyeing or bleaching composition of the present invention, which is intended for application to hair, it does not necessarily comprise, as constituents, two components which have different viscosities at 30°C and a specific viscosity ratio (component II / component I) as in the above-mentioned multi-component cosmetic composition, but rather comprises, as constituents, an agent I' containing components (A) and (B), and an agent II' containing components (D-1) and (D-2) as components (C) and (D), wherein the contents of components (D-1) and (D-2) are in a specific mass ratio (D-1 / D-2), and the content of component (D) in the mixture obtained by mixing all of the constituents is 1.63 mass% or more. As a result, if component (D-1) is contained but component (D-2) is not contained, there is a risk that adhesion to hair will decrease, and if component (D-2) is contained but component (D-1) is not contained, there is a risk that problems will arise in manufacturability. However, the multi-component hair dyeing or bleaching composition of the present invention makes it possible to achieve hair dyeing or bleaching that exhibits excellent penetration and spreadability in hair, while also exhibiting excellent effects in terms of hair color compatibility.

[0098] In the agent I' of the multi-component hair dyeing or bleaching composition of the present invention, the components (A) and (B) contained therein are the same as the components (A) and (B) contained in the multi-component cosmetic composition. However, when contained in agent I', component (A) is preferably component (A-1), and it is also preferable that component (A-2) is not contained. The content of component (A) in the total amount of agent I' is preferably 1.2 mass% or more, more preferably 1.5 mass% or more, even more preferably 2 mass% or more, and preferably 5 mass% or less, more preferably 4 mass% or less, and even more preferably 3.5 mass% or less. The content of component (A) in the total amount of agent I' is preferably 1.2 to 5 mass%, more preferably 1.5 to 4 mass%, and even more preferably 2 to 3.5 mass%. The content of component (A-1) in the total amount of agent I' is preferably 1.2% by mass or more, more preferably 1.5% by mass or more, even more preferably 2% by mass or more, and preferably 5% by mass or less, more preferably 4% by mass or less, and even more preferably 3.5% by mass or less. The content of component (A-1) in the total amount of agent I' is preferably 1.2 to 5% by mass, more preferably 1.5 to 4% by mass, and even more preferably 2 to 3.5% by mass. The content of component (B) in the total amount of agent I' is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, even more preferably 0.8% by mass or more, and preferably 3% by mass or less, more preferably 2% by mass or less, and even more preferably 1.5% by mass or less. The content of component (B) in the total amount of agent I' is preferably 0.1 to 3% by mass, more preferably 0.5 to 2% by mass, and even more preferably 0.8 to 1.5% by mass. The contents of component (A) and component (B) in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the contents of component (A) and component (B) when the total amount of the mixture obtained by mixing all the constituent components including agent I' and agent II' is 100% by mass, are the same as the contents of component (A) and component (B) in the total amount of the above-mentioned multi-component cosmetic composition, respectively.

[0099] In order to fully exert the highly useful hair dyeing or bleaching effect, it is preferable that Agent I' contained in the multi-component hair dyeing or bleaching composition of the present invention contains the same dye as in the multi-component cosmetic composition, and it is also preferable that Agent I' contain the same alkaline agent as in the multi-component cosmetic composition. The content of the dye in the total amount of Agent I' is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and preferably 5% by mass or less, more preferably 4.6% by mass or less. The content of the dye in the total amount of Agent I' is preferably 0.01 to 5% by mass, more preferably 0.1 to 3.5% by mass. The content of the alkaline agent in the total amount of Agent I' is preferably 0.15% by mass or more, more preferably 0.3% by mass or more, even more preferably 0.6% by mass or more, and preferably 45% by mass or less, more preferably 30% by mass or less, and even more preferably 20% by mass or less. The content of the alkaline agent in the total amount of Agent I' is preferably 0.15 to 45% by mass, more preferably 0.3 to 30% by mass, and more preferably 0.6 to 15% by mass. The dye content and alkaline agent content in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the dye content and alkaline agent content based on 100% by mass of the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II', are the same as the dye content and alkaline agent content in the total amount of the above-mentioned multi-component cosmetic composition, respectively.

[0100] In addition, in addition to components (A) and (B), the dye, and the alkaline agent, Agent I' contained in the multi-component hair dyeing or bleaching composition of the present invention may contain, as in the multi-component cosmetic composition described above, components (C), (D), (E), water, and other components commonly used as cosmetic raw materials, as appropriate, to the extent that the effects of the present invention are not impaired. However, with regard to the inclusion of component (C) in particular, from the viewpoint of effectively improving the compatibility of the hair color while exhibiting excellent penetration and spreadability in the hair, it is preferable that only Agent II' described below contains component (C), and that Agent I' does not contain component (C). When the I' agent contains a polyoxyalkylene alkyl ether represented by the above formula (5a) as component (D), its content is preferably 3 mass% or more, more preferably 5 mass% or more, and preferably 20 mass% or less, more preferably 15 mass% or less, of the total amount of the I' agent.

[0101] The component (C) contained in the component II' of the multi-component hair dyeing or bleaching composition of the present invention is the same as the component (C) contained in the multi-component cosmetic composition. Among these, component (C) is preferably one or more selected from cetyl alcohol, stearyl alcohol, and behenyl alcohol, more preferably two or more of these, and even more preferably three of these, cetyl alcohol, stearyl alcohol, and behenyl alcohol. The content of component (C) in the total amount of agent II' is preferably 3 mass% or more, more preferably 4 mass% or more, even more preferably 5 mass% or more, and preferably 12 mass% or less, more preferably 8 mass% or less, even more preferably 6.5 mass% or less. The content of component (C) in the total amount of agent II' is preferably 3 to 12 mass%, more preferably 4 to 8 mass%, even more preferably 5 to 6.5 mass%. In particular, the content of cetyl alcohol in the total amount of Agent II' is preferably 0.5% by mass or more, more preferably 1% by mass or more, even more preferably 1.7% by mass or more, and preferably 4% by mass or less, more preferably 3% by mass or less, and even more preferably 2% by mass or less.The content of cetyl alcohol in the total amount of Agent II' is preferably 0.5 to 4% by mass, more preferably 1 to 3% by mass, and even more preferably 1.7 to 2% by mass. The content of component (C) in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the content of component (C) when the total amount of the mixture obtained by mixing all the constituent components including agent I' and agent II' is 100% by mass, is the same as the content of component (C) in the total amount of the above-mentioned multi-component cosmetic composition.

[0102] In Agent II' of the multi-component hair dye or bleaching composition of the present invention, component (D) is the same as component (D) contained in the above-mentioned multi-component cosmetic composition, but further contains a polyoxyethylene-added nonionic surfactant (D-1) having an average number of added moles of ethylene oxide of 100 or less, and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of added moles of ethylene oxide of more than 100, and the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less. Thus, by containing these specific components (D-1) and (D-2), which are nonionic surfactants, in the specific mass ratio (D-1 / D-2) in Agent II' of the multi-component hair dye or bleaching composition of the present invention, it is possible to sufficiently improve the compatibility of the hair color.

[0103] That is, these components (D-1) and (D-2) both correspond to the polyoxyalkylene alkyl ether represented by the above formula (5b), where q in formula (5b) representing these components (D-1) and (D-2), i.e., the average number of moles added, is as follows: For component (D-1), q' in the above formula (5b) is, on average, 100 or less, preferably 80 or less, more preferably 50 or less, and usually 20 or more. q' in the above formula (5b) is, on average, preferably 20 to 100, more preferably 20 to 80, and even more preferably 20 to 50. For component (D-2), q'' in the above formula (5b) is, on average, more than 100, preferably 120 or more, more preferably 140 or more, and usually 200 or less. q'' in the above formula (5b) is, on average, preferably more than 100 and 200 or less, more preferably 120 to 200, and even more preferably 140 to 200.

[0104] In the multi-component hair dye or bleaching composition of the present invention, the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) in Agent II' is 2 or less, preferably 0.1 or more, more preferably 0.2 or more, and even more preferably 0.4 or more, from the viewpoint of improving hair color compatibility while exhibiting excellent penetration and spreadability in hair. The mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) in Agent II' is preferably 0.1 to 2, more preferably 0.2 to 2, and even more preferably 0.4 to 2.

[0105] The content of component (D-1) in the total amount of agent II' is preferably 0.2 mass% or more, more preferably 0.4 mass% or more, even more preferably 0.6 mass% or more, and preferably 3 mass% or less, more preferably 2 mass% or less, and even more preferably 1 mass% or less. The content of component (D-1) in the total amount of agent II' is preferably 0.2 to 3 mass%, more preferably 0.4 to 2 mass%, and even more preferably 0.6 to 1 mass%. The content of component (D-2) in the total amount of agent II' is preferably 0.5% by mass or more, more preferably 0.7% by mass or more, even more preferably 0.9% by mass or more, and preferably 4% by mass or less, more preferably 3% by mass or less, and even more preferably 2% by mass or less. The content of component (D-2) in the total amount of agent II' is preferably 0.5 to 4% by mass, more preferably 0.7 to 3% by mass, and even more preferably 0.9 to 2% by mass. The agent II' may contain a nonionic surfactant other than the component (D-1) and the component (D-2) as the component (D). The total content of component (D), including components (D-1) and (D-2), in the total amount of the multi-component hair dyeing or bleaching composition of the present invention, i.e., the total content of component (D) relative to the total amount of the mixture obtained by mixing all the components, including Agents I' and II', is 100% by mass, i.e., the content of component (D) in the total amount of the mixture obtained by mixing all the components, is 1.63% by mass or more, preferably 2% by mass or more, more preferably 3% by mass or more, and preferably 6.5% by mass or less, more preferably 5.5% by mass or less, and even more preferably 4.5% by mass or less, from the viewpoint of sufficiently enhancing hair color compatibility. In the multi-component hair dyeing or bleaching composition of the present invention, the content of component (D) in the total amount of the mixture obtained by mixing all the components is preferably 1.63 to 6.5% by mass, more preferably 2 to 5.5% by mass, and even more preferably 3 to 4.5% by mass.

[0106] In order to fully exert the highly useful hair dyeing or bleaching effect, it is preferable that Agent II' in the multi-component hair dyeing or bleaching composition of the present invention contains hydrogen peroxide, similar to that in the multi-component cosmetic composition described above. The content of hydrogen peroxide in agent II' is preferably 0.75% by mass or more, more preferably 1.5% by mass or more, and preferably 9% by mass or less, more preferably 7.5% by mass or less, and even more preferably 6% by mass or less. The content of hydrogen peroxide in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the content of hydrogen peroxide when the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II' is 100% by mass, is the same as the content of hydrogen peroxide in the total amount of the above-mentioned multi-component cosmetic composition.

[0107] In addition, in addition to components (C) and (D) and hydrogen peroxide, Agent II' contained in the multi-component hair dyeing or bleaching composition of the present invention may contain, as in the multi-component cosmetic composition described above, components (A), (B), (E), water, and other components commonly used as cosmetic raw materials, as appropriate, to the extent that the effects of the present invention are not impaired. However, with regard to the inclusion of component (B) in particular, from the viewpoint of effectively improving hair color compatibility while exhibiting excellent penetration and spreadability in hair, it is preferable that only Agent I' contains component (B) and that Agent II' does not contain component (B). When component (A) is contained in agent II', component (A-2) is preferred, and component (A-1) is preferably not contained. In this case, the content of component (A-2) in agent II' is preferably 0.1 mass% or more, more preferably 0.3 mass% or more, and preferably 1 mass% or less, more preferably 0.7 mass% or less.

[0108] From the viewpoint of sufficiently enhancing hair color compatibility, the mass ratio ((C) / (A)) of the content of component (C) to the content of component (A) in the multi-component hair dyeing or bleaching composition of the present invention is preferably 2 or more, more preferably 2.5 or more, even more preferably 2.6 or more, and preferably 5 or less, more preferably 4 or less, and even more preferably 3.2 or less. In the multi-component hair dyeing or bleaching composition of the present invention, the mass ratio ((C) / (A)) of the content of component (C) to the content of component (A) is preferably 2 to 5, more preferably 2.5 to 4, and even more preferably 2.6 to 3.2. Furthermore, in order not to inhibit the development of excellent penetration and spreadability in hair, the multi-component hair dyeing or bleaching composition of the present invention, like the above-mentioned multi-component cosmetic composition, preferably does not contain salicylic acid or acetaminophen, and more preferably does not contain either of these.

[0109] The content of component (E) in the multi-component hair dye or bleaching composition of the present invention is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, even more preferably 0.3% by mass or more, and preferably 1.3% by mass or less, more preferably 1.2% by mass or less, and even more preferably 1.0% by mass or less. The content of component (E) in the multi-component hair dye or bleaching composition of the present invention is preferably 0.01 to 1.3% by mass, more preferably 0.1 to 1.2% by mass, and even more preferably 0.3 to 1.0% by mass.

[0110] Such a multi-component hair dyeing or bleaching composition of the present invention does not necessarily have to comprise two components that have different viscosities at 30°C and a specific viscosity ratio (component II / component I) as constituents, as in the above-mentioned multi-component cosmetic composition, and can exhibit excellent penetration and spreadability in hair while effectively suppressing the prominence of hair color differences and thereby exhibiting excellent hair color compatibility. However, the components I' and II' contained in the multi-component hair dyeing or bleaching composition of the present invention may also be two components that have the same viscosity ratio as the above-mentioned two components. In other words, in this case, the agent I contained in the multi-component cosmetic composition corresponds to the agent I' contained in the multi-component hair dyeing or bleaching composition, and the agent II contained in the multi-component cosmetic composition corresponds to the agent II' contained in the multi-component hair dyeing or bleaching composition, and the viscosity ratio of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) corresponds to the viscosity ratio of the viscosity of agent II' at 30°C to the viscosity of agent I' at 30°C (agent II' / agent I'). Similarly, the viscosity of agent I of the above multi-component cosmetic composition at 30°C corresponds to the viscosity of agent I' of the multi-component hair dye or bleaching composition at 30°C, and the viscosity of agent II of the above multi-component cosmetic composition at 30°C corresponds to the viscosity of agent II' of the multi-component hair dye or bleaching composition at 30°C. When Agent I' and Agent II' in the multi-component hair dye or bleaching composition of the present invention are two components having the same viscosity ratio as the two components described above, the viscosity ratio of Agent II' to Agent I' at 30°C (Agent II' / Agent I') (the value obtained by dividing the viscosity value of Agent II' at 30°C by the viscosity value of Agent I' at 30°C) is 3 or more, preferably 100 or more, more preferably 500 or more, even more preferably 1000 or more, and preferably 6000 or less, more preferably 2000 or less, and even more preferably 1500 or less, from the viewpoint of exhibiting excellent penetration and spreadability in hair while exhibiting excellent hair color compatibility. The viscosity ratio of Agent II' to Agent I' at 30°C (Agent II' / Agent I') is 3 or more, preferably 100 to 6000, more preferably 500 to 2000, and even more preferably 1000 to 1500.

[0111] In the components including Agent I' and Agent II' contained in the multi-component hair dye or bleaching composition of the present invention, the form of each component can be appropriately selected from the same form as the form of the component contained in the above-mentioned multi-component cosmetic composition. In particular, with regard to the forms of Agent I' and Agent II', from the viewpoint of exhibiting excellent penetration and spreadability in hair while also exhibiting excellent hair color compatibility, it is preferable that Agent I' be in the form of a liquid and Agent II' be in the form of a cream, and when obtaining a mixture of all the components, it is preferable to add Agent I' to at least Agent II' and mix them.

[0112] Thus, the multi-component hair dyeing or bleaching composition of the present invention exhibits excellent penetration and spreadability in the hair to which it is applied, while effectively suppressing the noticeable unevenness of hair color due to dyeing or bleaching, and exhibits excellent hair color compatibility from the roots to the ends and from the surface to the inside of the hair bundle, making it possible to dye or bleach hair with a uniform hair color. Therefore, this multi-component hair dyeing or bleaching composition is also highly useful as a hair dyeing method that includes applying the multi-component hair dyeing or bleaching composition to the roots of the hair and then spreading it to the ends. For example, specifically, if the roots to which the multi-component hair dyeing or bleaching composition is applied are roots where the difference in hair color is noticeable, the excellent hair compatibility can be fully realized.

[0113] The multi-component cosmetic composition of the present invention can be made into a cosmetic kit that separately and independently contains other agent compositions to be further applied to keratinous tissue after application of the multi-component cosmetic composition to keratinous tissue. That is, such a cosmetic kit of the present invention contains the above-mentioned multi-component cosmetic composition as well as other agent compositions to be applied separately and independently from the multi-component cosmetic composition. In this way, after the multi-component cosmetic composition of the present invention has been applied to keratinous tissue to fully exert its effects, further desired effects can be exerted by applying the other agent compositions to keratinous tissue. As with the above-described multi-component cosmetic composition, the multi-component hair dyeing or bleaching composition of the present invention can also be made into a cosmetic kit that further comprises, separately and independently, other agent compositions for application to keratinous tissue. Therefore, hereinafter, in relation to a cosmetic kit that comprises the multi-component hair dyeing or bleaching composition of the present invention and other agent compositions, the term "multi-component cosmetic composition of the present invention" will be read as "multi-component hair dyeing or bleaching composition of the present invention."

[0114] Examples of other compositions included in such a cosmetic kit include a moisturizer composition, a beauty serum composition, a coating composition, a sunscreen composition, a rinse composition, a conditioner composition, and a treatment composition. In particular, when the multi-component cosmetic composition of the present invention is a hair cosmetic composition intended for application to hair, preferably a hair bleaching or hair dyeing composition, a treatment composition is preferably included as the other composition included in the kit. Thus, by further applying such a treatment composition to hair after applying the multi-component cosmetic composition of the present invention as a hair cosmetic composition, it is possible to effectively suppress hair damage that tends to occur due to repeated application treatments, effectively increase the color density of the hair (also referred to as "deepening"), and also impart a good feel.

[0115] The treatment composition may be in an embodiment containing one constituent agent, specifically, for example, a rinse-off treatment agent, or a leave-in treatment agent. The treatment composition may also be in an embodiment containing multiple constituent agents, specifically, for example, a rinse-off treatment agent and a leave-in treatment agent, for a total of two constituent agents.

[0116] The treatment composition included in the cosmetic kit of the present invention preferably contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2).

[0117] The amino-modified silicone (x1-1) of component (X1) that may be contained in the treatment composition is a silicone that has an amino group but does not have a polyether structure, and specific examples include one or more selected from amodimethicone, aminopropyl dimethicone, bis(aminopropyl) dimethicone, and bis(cetearyl) amodimethicone. Of these, amodimethicone is preferred from the viewpoint of effectively suppressing hair damage while effectively increasing hair color intensity. As commercially available products of such component (x1-1), for example, DOWSIL CF 1046 (manufactured by Dow-Toray Industries, Inc.) and Silicone SF 8457 C (manufactured by Dow-Toray Industries, Inc.) can be used.

[0118] The aminopolyether-modified silicone (x1-2) of component (X1) that may be contained in the treatment composition is a silicone having an amino group and a polyether structure, and the polyether structure of component (x1-2) is preferably a polyoxyalkylene group. Of these, from the viewpoint of effectively suppressing hair damage while effectively increasing hair color depth, specifically, for example, an aminopolyether-modified silicone represented by the following formula (8) is preferred.

[0119] [ka]

[0120] (In formula (8), d represents a number of 2 or more, and preferably a number of 2 or more and 1000 or less. e represents a number of 1 or more, and preferably a number of 1 or more and 50 or less. f represents a number of 2 or more and 100 or less, and preferably a number of 4 or more and 50 or less. g represents a number of 1 or more, and preferably a number of 1 or more and 100 or less.) Examples of commercially available products of component (x1-2) that can be used include DOWSIL SS-3588 FLUID (bisisobutyl PEG-15 / amodimethicone copolymer), DOWSIL SILSTYLE 104 (bisisobutyl PEG-14 / amodimethicone copolymer, manufactured by Dow-Toray Industries, Inc.), and DOWSIL SILSTYLE 201 (bisisobutyl PEG-14 / amodimethicone copolymer, manufactured by Dow-Toray Industries, Inc.).

[0121] From the viewpoint of effectively suppressing hair damage while effectively increasing hair color depth, the content of component (X1) is preferably 0.1% by mass or more, more preferably 0.4% by mass or more, and preferably 10% by mass or less, and more preferably 7% by mass or less, based on the total amount of the treatment composition. The content of component (X1) is preferably 0.1 to 10% by mass, more preferably 0.4 to 7% by mass, based on the total amount of the treatment composition. In particular, when the treatment composition contains only one component, a rinse-off treatment agent, the content of component (X1) may be 0.8% by mass or more and 5% by mass or less, based on the total amount of the treatment composition.

[0122] The dimethicone of component (X2) that may be contained in the treatment composition is a so-called dimethylpolysiloxane that has a silicone skeleton. Examples of commercially available products of such component (X2) include silicone X-52-2162 (manufactured by Shin-Etsu Chemical Co., Ltd.), silicone KHS-3 (manufactured by Shin-Etsu Chemical Co., Ltd.), silicone KHS-9 (manufactured by Shin-Etsu Chemical Co., Ltd.), TSE200A (manufactured by Momentive Performance Materials), SH200-1,000,000cs (manufactured by Dow Corning Toray Co., Ltd.), and TSF451-100MA (manufactured by Momentive Performance Materials).

[0123] From the viewpoint of effectively suppressing hair damage while effectively increasing hair color depth, the content of component (X2) is preferably 0.1% by mass or more, more preferably 1% by mass or more, and preferably 15% by mass or less, and more preferably 12% by mass or less, based on the total amount of the treatment composition. The content of component (X2) is preferably 0.1 to 15% by mass, more preferably 1 to 12% by mass, based on the total amount of the treatment composition. In particular, when the treatment composition contains only one component, a rinse-off treatment agent, the content of component (X1) may be 2% by mass or more, and 6% by mass or less, based on the total amount of the treatment composition.

[0124] The treatment composition provided in the cosmetic kit of the present invention may contain only component (X1) of the above-mentioned component (X1) and component (X2), or may contain only component (X2). However, it is preferable that the treatment composition contain both component (X1) and component (X2). When both component (X1) and component (X2) are contained, the total content of these components (X1) and (X2) is preferably 1% by mass or more, more preferably 2% by mass or more, even more preferably 3% by mass or more, still more preferably 5% by mass or more, preferably 15% by mass or less, more preferably 12% by mass or less, even more preferably 10% by mass or less, and still more preferably 8% by mass or less, based on the total amount of the treatment composition. The total content of components (X1) and (X2) is preferably 1 to 15% by mass, more preferably 1 to 12% by mass, even more preferably 1 to 10% by mass, still more preferably 2 to 10% by mass, even more preferably 3 to 10% by mass, and still more preferably 5 to 8% by mass, based on the total amount of the treatment composition.

[0125] Furthermore, when the treatment composition contains both component (X1) and component (X2), from the viewpoint of effectively suppressing hair damage while effectively increasing hair color intensity, it is preferable that the treatment composition comprises a total of two components: a rinse-off treatment and a leave-in treatment; it is more preferable that the rinse-off treatment contains component (X1) and component (X2), and that the leave-in treatment contains component (X2) without containing component (X1); and it is even more preferable that the component (X1) contained in the rinse-off treatment is component (x1-1).

[0126] More specifically, when the treatment composition provided in the cosmetic kit of the present invention comprises, as constituents, a rinse-off treatment containing component (X1) and component (X2), and a leave-in treatment containing component (X2) but not component (X1), the content of component (X1) in the rinse-off treatment is, relative to 100% by mass of the rinse-off treatment, preferably 0.5% by mass or more, more preferably 0.8% by mass or more, even more preferably 1.0% by mass or more, and preferably 1.8% by mass or less, more preferably 1.5% by mass or less, and even more preferably 1.2% by mass or less. Furthermore, the content of component (X2) in the rinse-off treatment is, based on 100% by mass of the rinse-off treatment, preferably 2% by mass or more, more preferably 3% by mass or more, even more preferably 4% by mass or more, preferably 8% by mass or less, more preferably 7% by mass or less, even more preferably 6% by mass or less, and even more preferably 5% by mass or less. On the other hand, when the treatment composition provided in the cosmetic kit of the present invention is in the above-described embodiment, the content of component (X2) in the leave-in treatment is preferably 0.5% by mass or more, more preferably 1% by mass or more, even more preferably 1.5% by mass or more, and preferably 30% by mass or less, more preferably 25% by mass or less, and even more preferably 20% by mass or less, based on 100% by mass of the leave-in treatment.

[0127] Furthermore, the treatment composition provided in the cosmetic kit of the present invention may contain, in addition to the above-mentioned (X1) and (X2), other components appropriately selected from components (A) to (D) and other components that may be contained in the above-mentioned multi-component cosmetic composition.

[0128] The form of the constituents of the treatment composition included in the cosmetic kit of the present invention can be appropriately selected from liquid (oil), emulsion (milk), gel, paste, cream, foam, mist, etc. In particular, when the treatment composition includes a rinse-off treatment containing component (X1) and component (X2) and a leave-in treatment containing component (X2) but not component (X1), the rinse-off treatment is preferably in cream form, and the leave-in treatment is preferably in liquid (oil) or emulsion (milk) form, more preferably emulsion (milk). When the leave-in treatment agent is in the form of a milky lotion, it is preferable to adjust the pH of the leave-in treatment agent to a specific range. Specifically, when the leave-in treatment agent is in the form of a milky lotion, the pH of the leave-in treatment agent at 25°C is preferably 3 or higher, more preferably 3.5 or higher, and preferably 5 or lower, more preferably 4 or lower.

[0129] In the cosmetic kit of the present invention, a multi-component cosmetic composition is first applied to keratinous tissues, and then a treatment composition is applied to keratinous tissues. For example, in an embodiment in which the treatment composition comprises, as constituents, a rinse-off treatment agent containing component (X1) and component (X2) and a leave-in treatment agent containing component (X2) but not component (X1), the rinse-off treatment agent is applied to the keratinous tissues to which the multi-component cosmetic composition has been applied, and after rinsing, the leave-in treatment agent is applied to the keratinous tissues, and the keratinous tissues are then dried without rinsing. This can more effectively prevent hair damage and more effectively increase the color intensity of the hair.

[0130] In relation to the above-described embodiments, the present invention further discloses the following multi-component cosmetic composition, multi-component hair dyeing or bleaching composition, and cosmetic kit and method of use thereof. [1] The following components (A) to (D): (A) Ionic surfactant (B) Cationic polymer (C) Higher alcohol (D) Nonionic surfactant A multi-component cosmetic composition comprising a plurality of components, including a component I and a component II, each of which has a different viscosity at 30°C, and in which all of the components are mixed together at the time of use, The viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and In a mixture obtained by mixing all the constituent ingredients, the shear rate measured by a rheometer at 25°C was 0.001 S -1 ~1000S -1 When the shear rate was changed to 0.0037S -1 Shear viscosity a and shear rate at 139S -1 a ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) of 5000 or more. [2] The multi-component cosmetic composition of [1] above, wherein the viscosity ratio of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) is preferably 100 or more, more preferably 800 or more, even more preferably 1200 or more, still more preferably 1500 or more, and preferably 6000 or less, more preferably 5000 or less, even more preferably 4000 or less, and still more preferably 3000 or less. [3] Shear rate of 0.0037 in the mixture obtained by mixing all components -1 Shear viscosity a and shear rate at 139S -1 The multi-component cosmetic composition of [1] or [2] above, wherein the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is preferably 6,000 or more, more preferably 7,000 or more, and preferably 20,000 or less, more preferably 18,000 or less, and even more preferably 10,200 or less.

[0131] [4] The multi-component cosmetic composition of any one of [1] to [3] above, wherein component (A) comprises an anionic surfactant (A-1), and said component (A-1) is preferably an anionic surfactant having a sulfate group, and more preferably the content of an anionic surfactant having a carboxyl group in the multi-component cosmetic composition of the present invention is preferably 0.45% by mass or less, more preferably 0.35% by mass or less, and even more preferably 0.10% by mass or less, or wherein the multi-component cosmetic composition of the present invention is substantially free of an anionic surfactant having a carboxyl group. [5] The multi-component cosmetic composition according to any one of [1] to [4] above, wherein component (A) contains a cationic surfactant of component (A-2), and such component (A-2) is preferably monoalkyltrimethylammonium chloride or monoalkyltrimethylammonium bromide, more preferably stearyltrimethylammonium chloride (steartrimonium chloride), cetyltrimethylammonium chloride (cetrimonium chloride), or lauryltrimethylammonium chloride (lauryltrimonium chloride). [6] The multi-component cosmetic composition according to any one of [1] to [5] above, wherein component (B) is preferably a polymer containing a diallyl quaternary ammonium salt as a structural unit, more preferably a homopolymer of a diallyl quaternary ammonium salt, or a copolymer of a diallyl quaternary ammonium salt and acrylic acid. [7] The multi-component cosmetic composition according to any one of [1] to [6] above, wherein component (C) is one or more alcohols selected from myristyl alcohol, cetyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, oleyl alcohol, and the like, preferably one or more alcohols selected from cetyl alcohol, stearyl alcohol, and behenyl alcohol, and it is more preferable to use two or more of these. [8] The multi-component cosmetic composition of any one of [1] to [7] above, wherein the mass ratio of the content of component (C) to the content of component (A) ((C) / (A)) is preferably 2 or more, more preferably 2.5 or more, even more preferably 2.77 or more, still more preferably 3.1 or more, and is preferably 5 or less, more preferably 3.75 or less, and even more preferably 3.50 or less. [9] The multi-component cosmetic composition according to any one of the above [1] to [8], wherein component (D) is a polyoxyalkylene alkyl ether represented by the following formula (5): R 10 -O-(A a O) r -H (5) (In formula (5), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r represents an average number of 1 to 250.

[10] The multi-component cosmetic composition of any one of the above [1] to [9], wherein the content of component (A) in the multi-component cosmetic composition of the present invention is preferably from 0.48% by mass to 1.99% by mass, the content of component (B) is preferably from 0.03% by mass to 0.59% by mass, and the content of component (C) is preferably from 1.52% by mass to 6.08% by mass.

[11] The multi-component cosmetic composition according to any one of the above [1] to

[10] , further comprising a component (E) which is a chloride of one or two selected from alkali metal salts of organic acids having 6 or less carbon atoms, alkaline earth metal salts of organic acids having 6 or less carbon atoms, inorganic alkali metal salts, and inorganic alkaline earth metal salts.

[12] The multi-component cosmetic composition according to any one of [1] to

[11] above, which preferably does not contain salicylic acid or acetaminophen, and more preferably does not contain either of them.

[0132]

[13] The following components (A) to (D): (A) Ionic surfactant (B) Cationic polymer (C) Higher alcohol (D) Nonionic surfactant 1. A method for using a multi-component cosmetic composition comprising a plurality of components, including a component I and a component II, each of which has a different viscosity at at least 30°C, the method comprising mixing all of the components in advance and then applying the resulting mixture to keratinous tissue, the method comprising: The viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, The mixture obtained by mixing all the constituents was measured with a rheometer at 25°C and the shear rate was 0.001 S -1 ~1000S -1 When the shear rate was changed to 0.0037S -1 Shear viscosity a and shear rate at 139S -1 a / shear viscosity b) of 5,000 or more.

[0133]

[14] A cosmetic kit comprising a multi-component cosmetic composition and a treatment composition that is separate and independent and contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), A multi-component cosmetic composition comprising the following components (A) to (D): (A) Ionic surfactant (B) Cationic polymer (C) Higher alcohol (D) Nonionic surfactant A multi-component cosmetic composition comprising a plurality of components, including a component I and a component II, each of which has a different viscosity at 30°C, and in which all of the components are mixed together at the time of use, The viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and In a mixture obtained by mixing all the constituent ingredients, the shear rate measured by a rheometer at 25°C was 0.001 S -1 ~1000S -1 When the shear rate was changed to 0.0037S -1 Shear viscosity a and shear rate at 139S -1 The ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5000 or more.

[15] A method for using the cosmetic kit according to

[14] above, comprising applying the multi-component cosmetic composition to keratinous tissue, and then applying a treatment composition to keratinous tissue.

[0134]

[16] A multi-component hair dyeing or bleaching composition comprising a plurality of components, including components I' and II', which are mixed together at the time of use, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) A multi-component hair dyeing or bleaching composition containing nonionic surfactants including a polyoxyethylene-added nonionic surfactant (D-1) having an average number of added moles of ethylene oxide of 100 or less and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of added moles of ethylene oxide of more than 100, wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (D) in the mixture obtained by mixing all the constituent components is 1.63 mass% or more.

[17] The multi-component hair dyeing or bleaching composition according to

[16] above, wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) in agent II' is preferably 0.1 to 2, more preferably 0.2 to 2, and even more preferably 0.4 to 2.

[18] The multi-component hair dyeing or bleaching composition according to

[16] or

[17] above, wherein the average number of moles of component (D-1) added is preferably 20 to 100, more preferably 20 to 80, and even more preferably 20 to 50.

[19] The multi-component hair dyeing or bleaching composition according to any one of

[16] to

[18] above, wherein the average number of moles of component (D-2) added is preferably more than 100 and not more than 200, more preferably 120 to 200, and even more preferably 140 to 200.

[20] The multi-component hair dyeing or bleaching composition according to any one of the above

[16] to

[19] , wherein the content of component (D) in the mixture obtained by mixing all of the constituent components is preferably 1.63 to 6.5 mass%, more preferably 2 to 5.5 mass%, and even more preferably 3 to 4.5 mass%.

[21] The multi-component hair dyeing or bleaching composition according to any one of the above

[16] to

[20] , wherein the content of component (D-1) in the total amount of agent II' is preferably 0.2 to 3 mass%, more preferably 0.4 to 2 mass%, and even more preferably 0.6 to 1 mass%.

[22] The multi-component hair dyeing or bleaching composition according to any one of

[16] to

[21] above, wherein the content of component (D-2) in the total amount of agent II' is preferably 0.5 to 4 mass%, more preferably 0.7 to 3 mass%, and even more preferably 0.9 to 2 mass%.

[23] A multi-component hair dyeing or bleaching composition comprising a plurality of components including an agent I' and an agent II', in which all the components are mixed together at the time of use, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) A multi-component hair dyeing or bleaching composition containing nonionic surfactants including a polyoxyethylene-added nonionic surfactant (D-1) having an average number of moles of ethylene oxide added of 20 or more and 50 or less, and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of moles of ethylene oxide added of 140 or more and 200 or less, wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 0.4 to 2, and the content of component (D) in the mixture obtained by mixing all of the constituent components is 1.63 to 5.5 mass%.

[24] A multi-component hair dyeing or bleaching composition comprising a plurality of components including an agent I' and an agent II', in which all the components are mixed together at the time of use, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) A multi-component hair dyeing or bleaching composition containing nonionic surfactants including a polyoxyethylene-added nonionic surfactant (D-1) having an average number of added moles of ethylene oxide of 100 or less and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of added moles of ethylene oxide of more than 100, wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (A) in a mixture obtained by mixing all of the constituent components is 0.96 to 1.44, the content of component (B) is 0.29 to 0.44, the content of component (C) is 3.03 to 4.54, and the content of component (D) is 1.63 mass% or more.

[25] A multi-component hair dyeing or bleaching composition comprising a plurality of components including an agent I' and an agent II', wherein the viscosity ratio of the viscosity of the agent II' at 30°C to the viscosity of the agent I' at 30°C (agent II' / agent I') is 3 or more, and all of the components are mixed together when used, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) A multi-component hair dyeing or bleaching composition containing nonionic surfactants including a polyoxyethylene-added nonionic surfactant (D-1) having an average number of added moles of ethylene oxide of 100 or less and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of added moles of ethylene oxide of more than 100, wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (D) in the mixture obtained by mixing all of the constituent components is 1.63 mass% or more.

[26] The multi-component hair dyeing or bleaching composition according to any one of the above

[16] to

[25] , wherein only the agent II' contains the component (C), and the agent I' does not contain the component (C).

[27] The multi-component hair dyeing or bleaching composition according to any one of the above

[16] to

[25] , wherein only agent I' contains component (B), and agent II' does not contain component (B).

[0135]

[28] A hair dyeing method comprising the steps of applying the multi-component hair dyeing or bleaching composition according to any one of

[16] to

[27] above to the roots of the hair and then spreading it to the ends.

[29] The hair dyeing method according to

[28] above, wherein the roots of the hair are those at which the step of hair color is prominent.

[30] The following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer and an agent I' containing The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) Nonionic surfactants containing a polyoxyethylene-added nonionic surfactant (D-1) having an average number of moles of ethylene oxide added of 100 or less, and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of moles of ethylene oxide added of more than 100. a method for using a multi-component hair dyeing or bleaching composition comprising a plurality of components, including an agent II', which comprises the above components, and in which the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (D) in the mixture obtained by mixing all of the components is 1.63 mass% or more, and which comprises mixing all of the components in advance and then applying the resulting mixture to hair.

[0136]

[31] A cosmetic kit comprising a multi-component hair dyeing or bleaching composition and a treatment composition that is separate and independent and contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), A multi-component hair dyeing or bleaching composition comprising a plurality of components including an agent I' and an agent II', wherein all of the components are mixed together at the time of use, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' contains the following components (C) and (D): (C) Higher alcohol (D) Nonionic surfactants containing a polyoxyethylene-added nonionic surfactant (D-1) having an average number of moles of ethylene oxide added of 100 or less, and a polyoxyethylene-added nonionic surfactant (D-2) having an average number of moles of ethylene oxide added of more than 100. wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (D) in a mixture obtained by mixing all of the constituent ingredients is 1.63 mass% or more.

[32] A method for using the cosmetic kit according to

[31] above, which comprises applying the multi-component hair dyeing or bleaching composition to the hair, and then applying the treatment composition to the hair.

[33] The multi-component hair dyeing or bleaching composition according to any one of

[16] to

[27] above, wherein the viscosity ratio of agent II' at 30°C to agent I' at 30°C (agent II' / agent I') is 3 or more, preferably 100 to 6,000, more preferably 500 to 2,000, and even more preferably 1,000 to 1,500.

[34] The multi-component hair dyeing or bleaching composition according to any one of

[16] to

[27] above, wherein the mixture obtained by mixing all of the constituent components of the multi-component cosmetic composition of the present invention is in the form of a gel. [Example]

[0137] The present invention will be described in detail below with reference to the following examples. Unless otherwise specified in the tables, the content of each component is expressed in mass %.

[0138] Test Example 1: Examples 1 to 8, Comparative Examples 1 to 7 Agent I and agent II were prepared according to the formulations shown in Table 1, and then agent I was added to agent II and mixed at a mass ratio of 1:2 (agent I:agent II). The resulting mixture was subjected to measurements and evaluations according to the following methods. The results are shown in Table 1.

[0139] <<Measurement of viscosity of agent I or agent II>> Using a Brookfield viscometer (TVB-10, manufactured by Toki Sangyo Co., Ltd.), the viscosity at 30°C was measured under the following measurement conditions selected appropriately depending on the form of the obtained agent I or agent II. Specifically, when the formulation was in liquid form, 90 g of each formulation was sampled and measured at a temperature of 30°C using rotor No. 1 at a rotation speed of 60 rpm for 1 minute. Note that if the measured value was below 10 mPa·s, that value was also used. On the other hand, when the formulation was in cream form, 45 g of each formulation was sampled and measured at a temperature of 30°C using a rotor TC at a rotation speed of 10 rpm for 1 minute. If the measured value was below 20,000 mPa·s, the value measured using a rotor TB at 10 rpm for 1 minute was used.

[0140] <<Measurement of Shear Viscosity of Mixtures>> The shear viscosity of the mixture obtained by mixing component I or component II was measured using an MCR301 manufactured by Anton Paar. 4 g of component II was weighed out into a 50 mL plastic cup, to which 2 g of component I was added and stirred with a plastic spatula for 30 seconds to obtain a mixture, which was then placed on the stage of the rheometer and clamped with a jig (approximately 0.7 g of the mixture was placed, and any excess mixture that spilled over was removed with a silicone spatula). Measurement began 3 minutes after mixing. Specifically, the obtained mixture was sandwiched between a plate and a jig (PP25, manufactured by Anton Paar) with a gap of 1 mm, and the shear rate was set to 0.001 s. -1 ~1000S -1 The shear rate was changed to 0.0037 S. -1 Shear viscosity a at a shear rate of 139 s -1 Next, based on the obtained values ​​of shear viscosity a and shear viscosity b, the ratio between these (shear viscosity a / shear viscosity b) was calculated.

[0141] (i) Evaluation of Adhesion After mixing the first and second components, the mixture was left to stand for 5 minutes to stabilize the viscosity, and then the adhesion was evaluated. Specifically, 0.5 g of the mixture was placed on a glass plate, which was tilted 20° and left for 1 minute. The distance (mm) that the mixture moved from the place where it was placed was measured, and this was used as an index for evaluating the adhesion according to the following criteria. The larger the obtained value, the better the adhesion and the more effectively it can be evaluated as preventing unwanted dripping.

[0142] 5: The distance moved was less than 0.5 cm 4: The distance moved was 0.5 cm or more but less than 1 cm 3: The distance moved was 1cm or more but less than 2cm 2: The distance moved was 2cm or more but less than 3cm 1: The distance moved was 3cm or more

[0143] (ii) Evaluation of extensibility (ease of spreading) A 20 cm square piece of wool muslin was used as a test piece, and 0.5 g of the mixture obtained was applied to an area within 2 cm from one end of the test piece. The applied mixture was then spread with a finger toward the other end of the test piece, and the distance (cm) from one end was measured as the spreadable distance, and the spreadability (ease of spreading) was evaluated according to the following criteria.

[0144] 5: The spread distance from one end of the test piece was 12 cm or more 4: The spread distance from one end of the test piece was 10 cm or more but less than 12 cm. 3: The spread distance from one end of the test piece was 8 cm or more but less than 10 cm. 2: The spread distance from one end of the test piece was 6 cm or more but less than 8 cm. 1: The spread distance from one end of the test piece was less than 6 cm

[0145] (iii) Evaluation of permeability into keratinous tissue A panel of experts took about 3 g of the mixture and applied it three times over a distance of about 20 cm from the top of the head of a mannequin with medium-length hair, applying a force of about 600 g. This action was repeated twice. Next, using the tip of the handle of a standard ring comb (tail comb), the inside of a hair bundle approximately 5 cm from the top of the head was sliced ​​(the operation of parting the hair bundle and opening the inside of the hair bundle), and the state of application of the mixture was visually confirmed, and its penetration into the keratinous tissue was evaluated according to the following criteria.

[0146] 4: The mixture is evenly applied to the inside of the hair strands 3: The mixture is uneven, but it is partially applied about halfway. 2: The mixture is unevenly applied, but in some places 1: No mixture applied to the inside of the hair strands

[0147] <<Overall evaluation of application properties>> The total value of the evaluation results obtained from the above "(i) Evaluation of adhesion," "(ii) Evaluation of spreadability (ease of application)," and "(iii) Evaluation of penetration into keratinous tissues" was calculated and used as an index for the overall evaluation of application properties.

[0148] <<Evaluation of texture>> A panel of experts applied 1 g of the mixture obtained to 1 g of gray hair tress (manufactured by Beaulux Co., Ltd.), and then performed a sensory evaluation of the feel (tactile sensation) of the mixture to the touch, using the degree of smoothness as an index according to the following criteria.

[0149] 4: Very smooth 3: Smooth 2: Slightly lacking in smoothness 1: Lack of smoothness

[0150] [Table 1]

[0151] *1: Emar 227-PH11 (Kao Corporation) *2: Nikkor SCS (manufactured by Nikko Chemicals) *3: Marquardt 295 polymer (manufactured by Lubrizol Advanced Materials, charge density: 6.04 meq / g) *4: Softanol 90 ((C12-14) s-Palace-9, manufactured by Nippon Shokubai Co., Ltd.) *5: Kalcol 6098 (Kao Corporation) *6: Kalcol 8098 (Kao Corporation) *7: Kalcol 220-80 (Kao Corporation) *8: Nikkor BC-40TX (Nikko Chemicals) *9: Nikkor BC-150 (Nikko Chemicals) *10: Kotamin 86W (Kao Corporation)

[0152] [Test 2: Examples 9-10] The darkening effect using the kit was evaluated by applying the mixture obtained by mixing Agents I and II of Example 1, together with Treatment Agent XA (rinse-off type) having the formulation shown in Table 2, and Treatment Agent XB-1 (leave-in type, emulsion (milky) form) or Treatment Agent XB-2 (leave-in type, liquid (oil) form) to the hair bundle for evaluation described below according to the method described below. The results are shown in Table 2.

[0153] <<Preparing hair bundles for evaluation>> A bundle of untreated black hair (BS-BA, manufactured by Bealux, length 30 cm, weight 10 g) was placed in 7 tones (lightness L * :22.5~25.1, saturation C * A bleached hair bundle was prepared as the hair bundle for evaluation.

[0154] Darkening effect The hair bundle for evaluation was combed and aligned in one direction, and then measured using a colorimeter (Konica Minolta, CR-400) in the CIE color system (L * ,a * ,b * ) and lightness (L0 * ) was measured. * Measurements were taken at six different points on the hair bundle (two points in the center of each of the three equal areas that were obtained by dividing the hair bundle lengthwise), and the average value was calculated. Next, 10 g of a mixture obtained by mixing Agents I and II of Example 1 was applied to the hair bundle for evaluation, left to stand, then rinsed with water, shampooed, and rinsed away. Next, 1 g of treatment agent XA with the formulation shown in Table 2 was applied evenly to the hair bundle, rinsed with water, and towel-dried. Next, 0.2 g of treatment agent XB-1 or treatment agent XB-2 shown in Table 2 was applied evenly to the hair bundle, and then the hair bundle was dried with cold air for 30 minutes using a hair dryer (Hitachi, Ltd., "P2-D250," set to HIGH). The dried hair bundle was combed, and the brightness (L1) of the treated hair bundle was measured in the same manner as above. * ) was measured, and the difference in brightness (ΔL* ) was calculated. ΔL * If the value is 1.0 or more, it can be evaluated that there is a deep coloring effect, if it is 2.0 or more, the effect is better, and if it is 3.0 or more, it can be evaluated that the effect is even better. ΔL * =L0 * -L1 * L0 * : Brightness of hair bundle before treatment L1 * : Brightness of hair strands after treatment

[0155] [Table 2]

[0156] [Test 3: Examples 11 to 14, Comparative Example 8] Using Agents I' and II' having the formulations shown in Table 4, the compatibility of hair color was evaluated according to the following method. The results are shown in Table 4.

[0157] 《Hair color compatibility》 An untreated gray hair tress (manufactured by Beaulux, 10 cm long, 1 g mass) was used as the hair bundle for evaluation. First, 1 g of Agent I' and 2 g of Agent II' were mixed, and 1.5 g of the resulting mixture was applied to the roots of the front side of the hair bundle, and the mixture was spread toward the ends with the index finger at a load of approximately 200 g. This process was repeated five times. Next, the treated tress was wrapped in plastic wrap and left at 30°C for 30 minutes. The tresses were then rinsed for 30 seconds and then washed for 30 seconds with a plain shampoo having the formula shown in Table 3. After repeating this rinsing and washing process twice, a plain rinse having the formula shown in Table 3 was applied for 30 seconds, followed by a 30-second rinse. After the treatment, the tress was towel-dried and then cooled using the dryer described above to dry the tress for 30 minutes. The obtained trace was measured using a colorimeter (Konica Minolta, CR-400) in the CIE color system (L * ,a * ,b * ) and measured the color.* ,a * ,b * Measurements were taken at six different points on the hair bundle (front root, front middle, front end, back root, back middle, back end), and the values ​​for each area were calculated using the following formula: * 1-6 was calculated.

[0158]

number

[0159] ΔE * 1-6 The difference between the maximum value ΔEmax and the minimum value ΔEmin was calculated and scored according to the criteria shown below. If the difference between the maximum value ΔEmax and the minimum value ΔEmin is 10 or less, it can be judged that the hair compatibility is excellent, and if the difference between the maximum value ΔEmax and the minimum value ΔEmin is 5 or less, it can be evaluated as having even better hair compatibility. 5: The difference between the maximum value ΔEmax and the minimum value ΔEmin is 5 or less 4: The difference between the maximum value ΔEmax and the minimum value ΔEmin is more than 5 and 10 or less 3: The difference between the maximum value ΔEmax and the minimum value ΔEmin is more than 10 and 15 or less 2: The difference between the maximum value ΔEmax and the minimum value ΔEmin is more than 15 and less than 20 1: The difference between the maximum value ΔEmax and the minimum value ΔEmin is more than 20 and 25 or less

[0160] [Table 3]

[0161] [Table 4]

[0162] *11: Farmin DM E-80 (Kao Corporation) *12: Kotamin 60W (Kao Corporation) *13: SILSOFT EM341N EMULSION (manufactured by Momentive Performance Materials Japan LLC) *14: DOWSIL CF 1046 (Dow Toray) *15: Kotamin 2285E-E (Kao Corporation) *16: Emanon CH-40 (Kao Corporation) *17: Kalcol 6850 (Kao Corporation) *18:DPG-RF (ADEKA) *19: Exepar TGO (Kao Corporation) *20: SILKFLO 364 (Vantage Specialty Chemicals) *21: NIKKOL Sugar Squalane (manufactured by Nippon Surfactant Industries Co., Ltd.) *22: Pearleem EX (NOF Corporation) *23: Salakos 913 (manufactured by Nisshin Oillio Group) *24: Aminone L-02 (Kao Corporation) *25: Kotamin D86P (Kao Corporation) *26: Clewatt S1 (manufactured by Nagase & Co., Ltd.) *27: Purified anhydrous sodium sulfite (manufactured by Air Water Performance Chemicals) *28: Oxyquinoline sulfate (2) (manufactured by Nippon Rika Pharmaceuticals) *29: Dayquest 2010CS (manufactured by Italmatch Japan)

Claims

1. A multi-component hair dyeing or bleaching composition comprising a plurality of components including components I' and II', wherein all of the components are mixed together at the time of use, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' comprises the following components (C) and (D): (C) higher alcohol (D) Nonionic surfactants containing polyoxyethylene-added nonionic surfactants (D-1) having an average number of moles of ethylene oxide added of 100 or less, and polyoxyethylene-added nonionic surfactants (D-2) having an average number of moles of ethylene oxide added of more than 100 wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (D) in a mixture obtained by mixing all of the constituent components is 1.63 mass% or more.

2. 2. The multi-component hair dyeing or bleaching composition according to claim 1, wherein component (A) comprises one or more surfactants selected from the group consisting of anionic surfactants and cationic surfactants.

3. 3. The multi-component hair dyeing or bleaching composition according to claim 1 or 2, further comprising a component (E) which is one or more chlorides selected from alkali metal salts of organic acids having 6 or less carbon atoms, alkaline earth metal salts of organic acids having 6 or less carbon atoms, inorganic alkali metal salts, and inorganic alkaline earth metal salts.

4. A hair dyeing method comprising the steps of applying the multi-component hair dyeing or bleaching composition according to claim 1 or 2 to the roots of the hair and then spreading it to the ends.

5. A multi-agent hair dyeing or bleaching kit comprising a plurality of components including agent I' and agent II', all of which are mixed together at the time of use, The agent I' comprises the following components (A) and (B): (A) Ionic surfactant (B) Cationic polymer Contains The agent II' comprises the following components (C) and (D): (C) higher alcohol (D) Nonionic surfactants containing polyoxyethylene-added nonionic surfactants (D-1) having an average number of moles of ethylene oxide added of 100 or less, and polyoxyethylene-added nonionic surfactants (D-2) having an average number of moles of ethylene oxide added of more than 100 wherein the mass ratio (D-1 / D-2) of the content of component (D-1) to the content of component (D-2) is 2 or less, and the content of component (D) in a mixture obtained by mixing all of the constituent components is 1.63 mass% or more.

6. The following components (A) to (D): (A) Ionic surfactant (B) Cationic polymer (C) higher alcohol (D) Nonionic surfactant and a plurality of components including an agent I and an agent II having different viscosities at 30°C, wherein all of the components are mixed together at the time of use, The viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and In a mixture obtained by mixing all the constituent ingredients, the shear rate measured by a rheometer at 25°C was 0.001 S -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 a ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) of 5,000 or more.

7. 7. The multi-component cosmetic composition according to claim 6, which does not contain salicylic acid or acetaminophen.

8. A cosmetic kit comprising a multi-component cosmetic composition and a treatment composition which is separate and independent and contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), The multi-component cosmetic composition comprises the following components (A) to (D): (A) Ionic surfactant (B) Cationic polymer (C) higher alcohol (D) Nonionic surfactant and a plurality of components including an agent I and an agent II having different viscosities at 30°C, wherein all of the components are mixed together at the time of use, The viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and In a mixture obtained by mixing all the constituent ingredients, the shear rate measured by a rheometer at 25°C was 0.001 S -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 The ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5000 or more.

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