Semiconductor processing chamber for deposition and etching

The semiconductor processing system addresses void formation in high aspect ratio features by using a substrate support assembly with separate plasma power sources and a trigger sequence for controlled deposition, improving cooling and plasma management to enhance device quality and throughput.

JP7618784B2Active Publication Date: 2025-01-21APPLIED MATERIALS INC
View PDF 13 Cites 0 Cited by

Patent Information

Application Number
JP2023515296
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Priority Date
2020-09-08
Filing Date
2021-08-27
Publication Date
2025-01-21
Estimated Expiration
2041-08-27

AI Technical Summary

Technical Problem

Conventional semiconductor processing techniques face challenges in filling high aspect ratio features with flowable films, leading to void formation and performance issues due to unreliable plasma deposition and temperature control, often requiring separate chambers for deposition and processing, which increases processing time and reduces throughput.

Method used

A semiconductor processing system with a substrate support assembly that includes a conductive puck, insulating edge ring, and separate high-frequency and low-frequency plasma power sources, along with a trigger sequence for low-power, repeatable plasma generation, enabling controlled deposition and plasma management within a single chamber.

Benefits of technology

This system provides improved cooling and plasma management, ensuring repeatable plasma generation and stable temperatures, reducing void formation and enhancing the quality of semiconductor devices by allowing deposition and processing in a single chamber.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure 0007618784000001
    Figure 0007618784000001
  • Figure 0007618784000002
    Figure 0007618784000002
  • Figure 0007618784000003
    Figure 0007618784000003
Patent Text Reader

Abstract

An exemplary semiconductor substrate support may include a pedestal shaft. The semiconductor substrate support may include a platen. The platen may define a fluid channel across a first surface of the platen. The semiconductor substrate support may include a platen insulator positioned between the platen and the pedestal shaft. The semiconductor substrate support may include a conductive puck connected to the first surface of the platen and configured to contact a substrate supported on the semiconductor substrate support. The semiconductor substrate support may include a conductive shield extending along a backside of the platen insulator and connected between a portion of the platen insulator and the pedestal shaft.
Need to check novelty before this filing date? Find Prior Art

Description

[Technical field]

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS

[0001] This application claims the benefit of and priority to U.S. patent application Ser. No. 17 / 014,195, entitled "SEMICONDUCTOR PROCESSING CHAMBERS FOR DEPOSITION AND ETCH," filed Sep. 8, 2020, the entire contents of which are incorporated herein by reference.

[0002]

[0002] The present technology is related to the following applications, all filed simultaneously on September 8, 2020, entitled "SINGLE CHAMBER FLOWABLE FILM FORMATION AND TREATMENTS," Attorney Docket No. 44018206US01 (1190509), and "SEMICONDUCTOR PROCESSING CHAMBERS FOR DEPOSITION AND ETCH," Attorney Docket No. 44018254US01 (1192137), each of which is incorporated by reference in its entirety for all purposes.

[0003]

[0003] The present technology relates to semiconductor processing, and more particularly, to systems and methods for depositing and processing materials, including flowable films. [Background technology]

[0004]

[0004] Integrated circuits are made possible by processes that produce intricately patterned layers of material on a substrate surface. Creating patterned materials on a substrate requires controlled methods of forming and removing exposed materials. As devices become smaller, material formation can impact subsequent operations. For example, in gap-fill operations, material can be formed or deposited to fill trenches or other features formed on a semiconductor substrate. These fill operations can be challenging because the features can be characterized by high aspect ratios and reduced critical dimensions. For example, deposition can occur on top of and along the sidewalls of the features, so continued deposition can pinch off the feature, including between the sidewalls within the feature, creating voids within the feature. This can impact device performance and subsequent processing operations.

[0005]

[0005] Thus, there is a need for improved systems and methods that can be used to manufacture high quality devices and structures. These and other needs are addressed by the present technique. Summary of the Invention

[0006] An exemplary semiconductor substrate support may include a pedestal shaft. The semiconductor substrate support may include a platen. The platen may define a fluid channel across a first surface of the platen. The semiconductor substrate support may include a platen insulator positioned between the platen and the pedestal shaft. The semiconductor substrate support may include a conductive puck connected to the first surface of the platen and configured to contact a substrate supported on the semiconductor substrate support. The semiconductor substrate support may include a conductive shield extending along a backside of the platen insulator and connected between a portion of the platen insulator and the pedestal shaft.

[0007] In some embodiments, the support may include an insulating edge ring that rests on a recessed ledge of the conductive puck. The insulating edge ring may extend radially outward along an exterior edge of the platen insulator. The insulating edge ring may contact the conductive shield. The conductive puck may include a coating along a surface configured to contact the substrate. The coating may extend along the recessed ledge on which the insulating edge ring rests. The coating may include a similar insulating material of which the insulating edge ring is constructed. The support may include a lift pin assembly that extends through the platen, the platen insulator, the conductive puck, and the conductive shield. The lift pin assembly may include a lift pin, a liner, a holder, and a counterweight. The holder may define a recess in which a portion of the platen insulator is disposed. The support may include an RF rod that extends through the pedestal shaft. The RF rod may be electrically connected to the platen. The support may include a rod insulator that extends around the RF rod along a length of the RF rod. The pedestal shaft may be mounted on the hub and the rod insulator may extend into the hub. The rod insulator may extend into a portion of the platen insulator. The pedestal shaft and the platen insulator may define a purge path in the platen insulator that extends to the rod insulator. The purge path may continue along the interior and exterior of the rod insulator.

[0008]

[0008] Some embodiments of the present technology may include a semiconductor processing system. The system may include a chamber body. The system may include a substrate support configured to support a semiconductor substrate. The substrate support may include a pedestal shaft. The substrate support may include a platen defining a fluid channel across a first surface of the platen. The substrate support may include a platen insulator positioned between the platen and the pedestal shaft. The substrate support may include a conductive puck connected to the first surface of the platen and configured to contact a substrate supported on the semiconductor substrate. The substrate support may include a conductive shield extending along a backside of the platen insulator and connected between a portion of the platen insulator and the pedestal shaft. The system may include a faceplate. The chamber body, the substrate support, and the faceplate may define a processing region. The system may include a high frequency plasma source connected to the faceplate. The system may include a low frequency plasma source connected to the substrate support.

[0009] In some embodiments, the substrate support may include an electrostatic chuck. The semiconductor processing system may include a DC power source connected to the substrate support. The low frequency plasma source may be configured to operate at about 2 MHz or less. The high frequency plasma source may be configured to operate at about 13.56 MHz or greater, with a pulse frequency of about 20 kHz or less, with a duty cycle of about 20% or less. The high frequency plasma source may be configured to generate plasma at an effective power of about 5 W or less. The system may include an insulating edge ring mounted on a concave ledge of the conductive puck. The insulating edge ring may extend radially outwardly along an exterior edge of the platen insulator. The insulating edge ring may contact a conductive shield. The conductive puck may include a coating along a surface configured to contact the substrate. The coating may extend along the concave ledge on which the insulating edge ring is mounted. The system may include a first LC filter connected to the substrate support and configured to virtually ground the high frequency plasma source through the substrate support. The system can include a second LC filter connected to the faceplate and configured to substantially ground the low frequency plasma source to the chamber body.

[0010]

[0010] Such techniques may provide numerous advantages over conventional systems and techniques. For example, improved cooling and plasma management may be provided by utilizing a substrate support in accordance with the present techniques. Additionally, repeatable plasma generation may be achieved during the deposition process by performing deposition in accordance with embodiments of the present techniques. These and other embodiments, together with their many advantages and features, are described in more detail in the following description and accompanying drawings.

[0011] A further understanding of the nature and advantages of the disclosed techniques may be realized by reference to the remaining portions of the specification and the drawings. [Brief description of the drawings]

[0012] [Figure 1]1 shows a schematic cross-sectional view of an exemplary processing chamber in accordance with some embodiments of the present technique. [Diagram 2]

[0013] 1 shows a schematic partial cross-sectional view of a chamber in accordance with some embodiments of the present technique; [Diagram 3]

[0014] 1 shows a schematic partial cross-sectional view of a substrate support assembly, in accordance with some embodiments of the present technique; [Figure 4]

[0015] 1 shows a schematic partial cross-sectional view of a substrate support assembly, in accordance with some embodiments of the present technique; [Diagram 5]

[0016] 1 shows a schematic partial cross-sectional view of a substrate support assembly, in accordance with some embodiments of the present technique; [Figure 6]

[0017] 1A-C show schematic partial cross-sectional views of substrate support assembly components, according to some embodiments of the present technique. [Figure 7]

[0018] 1 illustrates exemplary steps in a processing method according to some embodiments of the present technique. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0013]

[0019] Some figures are included as schematic diagrams. It should be understood that the figures are for illustrative purposes and should not be considered to scale unless expressly stated to be to scale. Furthermore, as schematic diagrams, the figures are provided to aid in understanding and may not include all aspects or information compared to realistic depictions and may include material that is emphasized for illustrative purposes.

[0014]

[0020] In the accompanying drawings, similar components and / or features may have the same reference numbers. Furthermore, various components of the same type may be distinguished according to the reference numbers, with a letter distinguishing between the similar components. If only a first reference number is used in this specification, the description is applicable to any one of the similar components having the same first reference number, regardless of the letter.

[0015]

[0021] Amorphous silicon may be used in semiconductor device fabrication for many structures and processes, including as a sacrificial material, e.g., as a dummy gate material, or as a trench fill material. In gap-filling steps, some processes utilize a flowable film formed under process conditions to limit the conformality of the deposition, allowing the deposited material to better fill features on the substrate. Flowable silicon materials may be characterized by a relatively high amount of hydrogen and may be less dense than other formed films. As a result, subsequent processing steps may be performed to harden the resulting film. Conventional techniques may utilize a UV curing process to remove hydrogen and treat the film. However, UV curing may cause significant film shrinkage, which may create voids in the structure as well as stress the features. In addition, the processing is performed in a separate chamber from the deposition chamber, which increases processing time and reduces throughput.

[0016]

[0022] As feature sizes continue to shrink, flowable films can be a challenge for narrow features that may be further characterized by higher aspect ratios. For example, deposition on the sidewalls of the feature may more easily result in pinching of the feature, and smaller feature sizes may further restrict further flow into the feature, resulting in voids. Some conventional flowable film formation may be performed by generating radicals in a remote capacitively coupled plasma region or a remote plasma source unit connected to the chamber. However, for cyclical formation of high aspect ratio features, this process may provide unreliable deposition. For example, as radicals pass through chamber parts such as the faceplate, recombination may cause problems with consistent delivery of radical effluent. In addition, remote plasma sources may not be able to limit the amount of deposition in small pitch features. This may result in excessive deposition in the feature, limiting or preventing complete penetration of processing effluent. This may cause damage during subsequent processing and may result in scrapping of the substrate.

[0017]

[0023] The present technology overcomes these limitations by separating high and low frequency power sources and utilizing triggering sequences that can perform short periods of repeatable plasma generation at low power. This can limit deposition during trench filling to tightly controlled amounts as well as ensure complete processing during subsequent processing steps. In addition, the present technology can incorporate a substrate support assembly that can better control temperature drift during processing steps to better ensure stable and repeatable temperatures at each deposition cycle. After describing the general aspects of the chamber according to some embodiments of the present technology in which the plasma processing steps described below may be performed, specific chamber configurations and methods may be described. It is understood that the present technology is not intended to be limited to the specific films, chambers, or processes described, as the techniques described may be used to improve numerous film formation processes for any number of materials and may be applicable to a variety of processing chambers and processes.

[0018]

[0024] FIG. 1 illustrates a cross-sectional view of an exemplary processing chamber 100 according to some embodiments of the present technique. The diagram may provide an overview of a system incorporating one or more aspects of the present technique and / or that may perform one or more deposition or other processing steps according to embodiments of the present technique. Additional details of the chamber 100 or the method performed may be further described below. Although the chamber 100 may be utilized to form a film layer according to some embodiments of the present technique, it should be understood that the method may similarly be performed in any chamber in which film formation may occur. The processing chamber 100 may include a chamber body 102, a substrate support 104 disposed within the chamber body 102, and a lid assembly 106 connected to the chamber body 102 and confining the substrate support 104 within a processing space 120. A substrate 103 may be provided to the processing space 120 through an opening 126, which may be conventionally sealed for processing using a slit valve or door. The substrate 103 may be located on a surface 105 of the substrate support during processing. The substrate support 104 may be rotatable, as indicated by arrow 145, along an axis 147 about which the shaft 144 of the substrate support 104 may lie. Alternatively, the substrate support 104 may be elevated for rotation as needed during the deposition process.

[0019]

[0025] A plasma profile modulator 111 may be disposed in the process chamber 100 to control plasma distribution across the substrate 103 disposed on the substrate support 104. The plasma profile modulator 111 includes a first electrode 108 that may be disposed adjacent to the chamber body 102 and may separate the chamber body 102 from other components of the lid assembly 106. The first electrode 108 may be part of the lid assembly 106 or may be a separate sidewall electrode. The first electrode 108 may be an annular or ring-shaped member and may be a ring electrode. The first electrode 108 may be a continuous loop along the periphery of the process chamber 100 surrounding the process space 120 or may be discontinuous at selected locations as desired. The first electrode 108 may also be a perforated electrode, such as a perforated ring or mesh electrode, or may be a plate electrode, such as a secondary gas distributor, for example.

[0020]

[0026] The one or more isolators 110a, 110b may be a dielectric material such as ceramic or a metal oxide, e.g., aluminum oxide and / or aluminum nitride, and may contact the first electrode 108 and electrically and thermally isolate the first electrode 108 from the gas distributor 112 and the chamber body 102. The gas distributor 112 may define an aperture 118 for distributing the process precursors into the processing space 120. The gas distributor 112 may be connected to a first power source 142, such as an RF generator, an RF power source, a DC power source, a pulsed DC power source, a pulsed RF power source, or any other power source that may be connected to a processing chamber. In some embodiments, the first power source 142 may be an RF power source.

[0021]

[0027] The gas distributor 112 may be a conductive gas distributor or a non-conductive gas distributor. The gas distributor 112 may also be formed from conductive and non-conductive components. For example, the body of the gas distributor 112 may be conductive, but the face plate of the gas distributor 112 may be non-conductive. The gas distributor 112 may be powered, such as by a first power source 142 as shown in FIG. 1, or the gas distributor 112 may be connected to ground in some embodiments.

[0022]

[0028] The first electrode 108 may be connected to a first tuned circuit 128 that may control a ground path of the process chamber 100. The first tuned circuit 128 may include a first electronic sensor 130 and a first electronic controller 134. The first electronic controller 134 may be or may include a variable capacitor or other circuit element. The first tuned circuit 128 may be or may include one or more inductors 132. The first tuned circuit 128 may be any circuit that allows for a variable or controllable impedance under plasma conditions present in the process space 120 during processing. In some illustrated embodiments, the first tuned circuit 128 may include a first circuit leg and a second circuit leg connected in parallel between ground and the first electronic sensor 130. The first circuit leg may include a first inductor 132A. The second circuit leg may include a second inductor 132B connected in series with the first electronic controller 134. The second inductor 132B can be disposed between the first electronic controller 134 and a node coupling both the first and second circuit legs to the first electronic sensor 130. The first electronic sensor 130 can be a voltage sensor or a current sensor and can be connected to the first electronic controller 134 to allow some closed-loop control of the plasma conditions inside the process space 120.

[0023]

[0029] The second electrode 122 may be connected to the substrate support 104. The second electrode 122 may be incorporated into the substrate support 104 or may be connected to a surface of the substrate support 104. The second electrode 122 may be a plate, a perforated plate, a mesh, a wire screen, or any other distributed configuration of conductive elements. The second electrode 122 may be a tuning electrode and may be connected to a second tuning circuit 136, for example, by a conduit 146 (e.g., a cable having a selected resistance, such as 50 ohms) disposed in a shaft 144 of the substrate support 104. The second tuning circuit 136 may have a second electronic sensor 138, a second electronic controller 140, which may be a second variable capacitor. The second electronic sensor 138 may be a voltage sensor or a current sensor and may be connected to the second electronic controller 140 to provide further control over the plasma conditions in the process space 120.

[0024]

[0030] A third electrode 124, which may be a bias electrode and / or an electrostatic chuck electrode, may be connected to the substrate support 104. The third electrode is connected to a second power source 150 through a filter 148, which may be an impedance matching circuit. The second power source 150 may be DC power, pulsed DC power, RF bias power, a pulsed RF source or bias power, or a combination of these or other sources. In some embodiments, the second power source 150 may be RF bias power.

[0025]

[0031] The lid assembly 106 and substrate support 104 of FIG. 1 may be used with any processing chamber for plasma or thermal processing. In operation, the processing chamber 100 may perform real-time control of plasma conditions within the processing space 120. The substrate 103 may be placed on the substrate support 104, and process gases may flow through the lid assembly 106 using the inlet 114 according to any desired flow scheme. The gases may be exhausted from the processing chamber 100 through the outlet 152. Power may be connected to the gas distributor 112 to establish a plasma within the processing space 120. In some embodiments, the substrate may be subjected to an electrical bias using the third electrode 124.

[0026]

[0032] Upon exciting a plasma in the process space 120, a potential difference may be established between the plasma and the first electrode 108. A potential difference may also be established between the plasma and the second electrode 122. The electronic controllers 134 and 140 may then be used to adjust the flow characteristics of the ground paths represented by the two tuned circuits 128 and 136. Set points may be provided to the first tuned circuit 128 and the second tuned circuit 136 to provide independent control of the deposition rate and center-to-edge plasma density uniformity. In an embodiment in which both electronic controllers may be variable capacitors, the electronic sensors may independently adjust the variable capacitors to maximize the deposition rate and minimize the thickness non-uniformity.

[0027]

[0033] Each of the tuning circuits 128 and 136 may have a variable impedance that may be adjusted using the respective electronic controllers 134 and 140. If the electronic controllers 134, 140 are variable capacitors, the capacitance range of each of the variable capacitors and the inductance of the first inductor 132A and the second inductor 132B may be selected to provide an impedance range. This range may depend on the frequency and voltage characteristics of the plasma and may have a minimum value for the capacitance range of each variable capacitor. Thus, when the capacitance of the first electronic controller 134 is at a minimum or maximum, the impedance of the first tuning circuit 128 may be high. This results in a plasma shape that has a minimum aerial or lateral coverage above the substrate support. When the capacitance of the first electronic controller 134 reaches a value that minimizes the impedance of the first tuning circuit 128, the aerial coverage of the plasma may grow to a maximum, thus effectively covering the entire working area of ​​the substrate support 104. If the capacitance of the first electronic controller 134 deviates from the minimum impedance setting, the plasma shape may shrink from the chamber walls, reducing the aerial coverage of the substrate support. The second electronic controller 140 may have a similar effect, so that as the capacitance of the second electronic controller 140 changes, the aerial coverage of the plasma above the substrate support increases or decreases.

[0028]

[0034] Electronic sensors 130 and 138 may be used to tune the respective circuits 128, 136 in a closed loop. Depending on the type of sensor used, a set point for current or voltage may be attached to each sensor. The sensors may be provided with control software that determines adjustments to the respective electronic controllers 134, 140 to minimize deviations from the set point. As a result, the shape of the plasma may be selected and dynamically controlled during processing. Although the above description is based on the electronic controllers 134, 140 being variable capacitors, it should be understood that any electronic components having adjustable characteristics may be used to provide the tuning circuits 128 and 136 with adjustable impedance.

[0029]

[0035] 2 illustrates a schematic partial cross-sectional view of a processing chamber 200 in accordance with some embodiments of the present technique. The chamber 200 may include any of the features, components, or characteristics of the processing chamber 100 described above, and may exhibit additional features of the chamber, including certain power sources in communication with the chamber. For example, the chamber 200 may include a chamber body 205. The chamber may include a substrate support 210, which may be configured to support a substrate during semiconductor processing. The chamber may include a faceplate 215, which, together with a pedestal and the chamber body, may define a processing region above a substrate during processing.

[0030]

[0036] Some conventional processing systems may generate a plasma within the processing region by applying power to the faceplate while grounding the pedestal, or by applying source power to the pedestal and grounding the faceplate. In some systems, an additional bias power may be connected to the pedestal to enhance directionality of the plasma effluents. It should be understood that a separate DC power supply for electrostatic chucking may be connected to the pedestal and operated to further bias the plasma generated within the processing chamber in addition to chucking the substrate, as described above with respect to the processing chamber 100. The present technique may differ from conventional configurations by connecting two separate plasma power sources to the showerhead and pedestal as shown. For example, a first plasma power source 220 may be connected to the showerhead and a second plasma power source 230 may be connected to the pedestal. In some embodiments, the first plasma power source 220 may be a high frequency plasma power source and the second plasma power source 230 may be a low frequency plasma power source. In some embodiments, the low frequency plasma power supply 230 is separate from the DC power supply, which may be used to electrostatically couple the substrate to the pedestal.

[0031]

[0037] The low frequency plasma power source operates at a first frequency that is about 2 MHz or less, and may operate at about 1.5 MHz or less, about 1.0 MHz or less, about 800 kHz or less, about 600 kHz or less, about 500 kHz or less, about 400 kHz or less, about 350 kHz or less, about 300 kHz or less, about 250 kHz or less, about 200 kHz or less, or less. The high frequency plasma power source operates at a second frequency that is about 2 MHz or more, and may be about 10 MHz or more, about 13 MHz or more (such as about 13.56 MHz), about 15 MHz or more, about 20 MHz or more, about 40 MHz or more, or more.

[0032]

[0038] Additional aspects of the plasma source may be used to further tailor the plasma generated within the processing region. For example, chambers according to embodiments of the present technology may be used to fill high aspect ratio features, where a discreet amount of deposition may be produced to limit void formation within the features being filled. Conventional chambers may be limited in reducing plasma power based on an inability to generate repeatable low power plasma for a limited period of time. The present technology may be used to produce material layers characterized by thicknesses of about 10 nm or less per cycle. To achieve this limited deposition, either the deposition period may be limited or the power used during deposition may be reduced. Conventional systems may not be able to reduce plasma power to about 100 W or less, which increases the amount of deposited material, and shortening the formation period to accommodate this higher power may limit the ability to generate reproducible plasma during multiple cycles of deposition.

[0033]

[0039] The present technology overcomes these problems by generating a low power deposition plasma, which is characterized by an effective plasma power of about 20 W or less, and may be characterized by an effective plasma power of about 15 W or less, about 10 W or less, about 8 W or less, about 6 W or less, about 5 W or less, about 4 W or less, about 3 W or less, or less. To generate this low power plasma during the deposition process, the system may operate a high frequency plasma power at a pulse frequency of about 200 kHz or less, and operate the plasma power at a pulse frequency of about 150 kHz or less, about 100 kHz or less, about 80 kHz or less, about 70 kHz or less, about 60 kHz or less, about 50 kHz or less, about 40 kHz or less, about 30 kHz or less, about 20 kHz or less, about 10 kHz or less, or less. Additionally, at any of the listed pulse frequencies, the radio frequency plasma power source can be operated at a reduced duty cycle of about 50% or less, about 45% or less, about 40% or less, about 35% or less, about 30% or less, about 25% or less, about 20% or less, about 15% or less, about 10% or less, about 5% or less, or less.

[0034]

[0040] In some embodiments, the pulse frequency and duty cycle may be reduced to address plasma generation in a consistent manner. A low power plasma, once generated, may generate a slow deposition rate to limit deposition per cycle, but ignition may be problematic. Thus, in some embodiments, the plasma power may be operated in a trigger sequence to facilitate plasma generation during deposition. For example, as described above, in some embodiments, the deposition process may be performed without a low frequency plasma power source. However, in some embodiments, the low frequency plasma power source may be operated during the deposition process to facilitate ignition. In addition, the low frequency plasma power source may not be operated, and a power spike may be applied with the high frequency plasma power source to facilitate ignition. The power spike may be applied directly by the power management or through level-by-level operation of the high frequency plasma power source.

[0035]

[0041] The low frequency plasma power source may also operate to control the plasma formation and ion directionality during processing. By supplying low frequency plasma power through the pedestal, the plasma sheath formed by this powered electrode may benefit the directionality of ions to the features being densified. Although the low frequency plasma power source may operate at any of the power levels or pulse frequencies described above, in some embodiments, the second power source 230 may operate at a plasma power greater than the first power source 220 during processing steps. For example, the plasma power supplied by the second power source during processing may be about 50 W or more, about 100 W or more, about 200 W or more, about 300 W or more, about 400 W, about 500 W or more, about 600 W or more, about 700 W or more, about 800 W or more, or more. By increasing the plasma power of the low frequency power source during processing plasma formation, a greater amount of plasma effluent may be generated. By applying more low frequency power from the pedestal, the directionality of the supply perpendicular to the plane across the substrate may be increased.

[0036]

[0042] Additional adjustments can be made to further increase etching of the deposited material along the sidewalls of the feature by adjusting one or more characteristics of the supplied plasma power or bias power. For example, in some embodiments, both the plasma power source and the bias power source can be operated in a continuous wave mode. In addition, one or both of the power sources can be operated in a pulsed mode. In some embodiments, during processing, the high frequency source power can be operated in a continuous wave mode or a pulsed mode, while the low frequency power can be operated in a pulsed mode. The pulse frequency of the low frequency plasma power source can be about 1,000 Hz or less, and can be about 900 Hz or less, about 800 Hz or less, about 700 Hz or less, about 600 Hz or less, about 500 Hz or less, about 400 Hz or less, about 300 Hz or less, about 200 Hz or less, about 100 Hz or less, or less. The duty cycle of the second power source is about 50% or less, and the low frequency plasma power may be operated at a duty cycle of about 45% or less, about 40% or less, about 35% or less, about 30% or less, about 25% or less, about 20% or less, about 15% or less, about 10% or less, about 5%, or less. By operating the low frequency power at a reduced duty cycle, such as an on-time duty of about 50% or less, the longer time per cycle may result in a more isotropic etch in the feature based on the operation of the high frequency power source, which may allow for better removal of material from the sidewalls during the densification operation.

[0037]

[0043] The first plasma power source 220 may be connected to ground substantially through the pedestal. For example, as shown, a first LC filter 225 may be connected to the pedestal to substantially ground the high frequency plasma source through the pedestal. Similarly, the second plasma power source 230 may be connected to ground through the chamber. For example, a second LC filter may be connected to the faceplate, which may substantially ground the low frequency plasma source, such as the chamber body or an external ground. By separating the high frequency and low frequency power sources, improved plasma generation and operation may be provided.

[0038]

[0044] 3 shows a schematic partial cross-sectional view of a substrate support assembly 300 according to some embodiments of the present technique. As mentioned above, the present technique can be used in some embodiments to perform low temperature deposition and curing inside a single chamber. A semiconductor support assembly configured for low temperature operation with low plasma power can face many challenges. For example, when an electrostatic chuck is used, the substrate support surface or puck can be a dielectric material that includes an electrode. The electrode, which can include multiple electrodes, can be one or both of a chuck electrode to which a DC power source can be connected, and a plasma generating electrode to which an RF power source can be connected.

[0039]

[0045] The substrate support assembly according to some embodiments of the present technique may include a low frequency power source connected to the substrate support assembly as described above. The substrate support assembly may also be configured to maintain the substrate at a temperature for both deposition and processing steps. The substrate support assembly according to some embodiments of the present technique may overcome temperature gradients caused by dielectric materials by maintaining a conductive puck in contact with the substrate or by forming a thin coating of dielectric material over the surface of the conductive puck. Based on the low level plasma process performed according to some embodiments of the present technique, substrate movement may be of limited concern and therefore electrostatic chucks may not be required. As a result, in some embodiments, the puck is conductive, which may improve heat transfer and cooling of the substrate. Plasma performance may also affect the substrate temperature. For example, the present technique may include cyclic formation and processing of a flowable film. Conventional techniques move the substrate between two chambers that perform deposition and processing separately, which may facilitate ensuring that the substrate is maintained at a set point temperature during each deposition step. Because temperature may affect deposition rate and film flow characteristics, maintaining a constant substrate temperature with each deposition cycle may improve film formation through the feature.

[0040]

[0046] Since the technique may generate the processing plasma in the same processing chamber where the deposition takes place, cooling the substrate back down to the deposition set point may be problematic due to plasma exposure during processing. While the deposition plasma may be generated at low plasma power, processing may be performed at higher plasma power from the source plasma, which may be 10 times or more the plasma power, increasing the heat load on the substrate. This may result in the substrate temperature during the processing step being much higher than that experienced during deposition. By being able to maintain a cooler conductive surface in contact with the wafer, or by applying a thin coating in between, the technique may be able to improve cooling by increasing heat transfer to the backside of the substrate.

[0041]

[0047] The substrate support assembly 300 may be similar to the substrate support 104 or substrate support 210 and may include any of the features, components, or characteristics of those supports described above, including any associated components or power sources. The substrate support assembly 300 may include a pedestal shaft 305, which may be of a conductive material. The platen 310 may define one or more fluid channels 309 in a surface of the platen. The fluid channels 309 may connect to a fluid source through inlet and outlet channels through the shaft. They may include one or more channels, such as a spiral or other circuitous pattern. The fluid source may include a cooled or heated fluid in embodiments that include a chiller to further reduce the fluid temperature. The substrate support may be configured to maintain a temperature of about 100° C. or less, and in some embodiments may be configured to maintain a temperature of about 80° C. or less, about 60° C. or less, about 40° C. or less, about 20° C. or less, about 0° C. or less, about −5° C. or less, about −10° C. or less, about −15° C. or less, about −20° C. or less, about −25° C. or less, or lower.

[0042]

[0048] A platen insulator 315 may be disposed between the platen 310 and the pedestal shaft 305 and may extend completely around the platen 310. In some embodiments, the platen 310 may be completely recessed within the volume defined by the insulator 315. The pedestal shaft 305 and the platen 310 may each be made of a conductive material, such as a metal, such as aluminum, or any other material that may be thermally and / or electrically conductive. The puck 320 is connected to the platen 310 and may be made of aluminum or some other conductive material in some embodiments. The substrate may be in direct contact with the puck in some embodiments, and in some embodiments, a coating may be formed between the puck and the substrate. A conductive shield 325 may extend along a surface of the platen insulator 315 opposite a surface on which the platen 310 may rest. For example, the conductive shield 325 may be connected between a portion of the platen insulator 315 and the pedestal shaft 305.

[0043]

[0049] The substrate support assembly 300 may include one or more lift pin assemblies 335 that extend through the conductive shield, platen insulator, platen, and conductive puck. In some embodiments, an insulating edge ring 330 may rest on a concave ledge defined on the puck and extending around the outer edge of the puck. As shown, the edge ring 330 extends radially outward along the outer edge of the platen insulator 315 and, in some embodiments, may extend over and contact the outer edge of the conductive shield 325. Thus, in some embodiments, the conductive platen and puck may be completely insulated from the conductive shield and pedestal shaft to limit or prevent shorting between components. The conductive shield that interfaces with the pedestal shaft, which may all be of conductive material, provides a more symmetrical ground path to the high frequency plasma power supply, which may improve plasma uniformity in some embodiments. An RF rod 340 may extend through the platen and be connected to the RF match of the low frequency power supply as described above. The pedestal shaft 305 rests on a hub 345 through which the RF rod 340 may extend. The RF rod 340 may have a rod insulator 350 extending around the RF rod and extend with the RF rod through each of the hub 345, the pedestal shaft 305, the platen insulator 315, and the platen 310. By extending the rod insulator 350 into the hub along the length of the RF rod, an RF leakage path to the pedestal shaft may be prevented at the hub.

[0044]

[0050] At the opposite end of the RF rod 340, the RF rod may be connected to a conductive platen 310, which may act as a plasma electrode. As described further below, in embodiments where a dielectric coating extends along the puck 320, the conductive platen may also act as a chucking electrode. Since the platen itself may act as an electrode, in some embodiments, the RF rod 340 may be recessed in a connection socket formed in the platen. The connection may be made with any connector type, including a Multilam or other multiple contact connector on the RF rod. As shown, the rod insulator 350 may extend at least partially inside the platen insulator 315. The platen and rod insulators may act to completely surround the RF rod 340 through components of the substrate support assembly that extend into the processing chamber, further shortening or limiting leakage paths that may otherwise lead to stray arcing. These components are described further below.

[0045]

[0051] FIG. 4 shows a schematic partial cross-sectional view of a substrate support assembly 300 according to some embodiments of the present technique, and may show additional features of the assembly. As mentioned above, in some embodiments, the puck 320 may be in direct contact with the substrate to be processed. In addition, in some embodiments, a dielectric coating may be formed over the surface of the puck. By forming a dielectric layer between the puck and the substrate to be processed, the puck may operate as an electrostatic chuck. The coating may also accommodate features of the substrate support assembly. For example, a recessed ledge 403 may be formed on the outer edge of the puck 320, on which an edge ring may rest. In addition, counterbore openings 405 for lift pin assemblies may be formed through the platen 310 and the puck 320. A coating 410 may be formed across the substrate support surface of the puck 320, conformally formed to extend across the recessed ledge to the outer edge of the puck. The coating 410 may also extend along the sidewalls 412 of the apertures 405, such as long as the smaller inner diameter portion of the counterbore aperture, which in some embodiments may help prevent ignition of gases at the lift pin holes.

[0046]

[0052] Electrostatic chucks often have a dielectric puck, which creates a temperature delta across the puck and can cause RF leakage through the puck. In low power plasma processing according to some embodiments of the present technique, the dielectric puck can further address the generation of plasma due to losses through the puck. To limit the impact of losses, the present technique instead forms a dielectric coating, which in some embodiments is kept to a thickness of about 1 mm or less, and may be kept to a thickness of about 800 μm or less, a thickness of about 600 μm or less, a thickness of about 500 μm or less, a thickness of about 400 μm or less, a thickness of about 300 μm or less, a thickness of about 200 μm or less, or less. However, to ensure complete coverage of the puck surface to limit or prevent short circuits, the thickness may be kept to about 100 μm or more, or about 200 μm or more. The coating 410 can be made of any material, and in some embodiments can be formed of the same material as the edge ring 330, or can be a ceramic or other dielectric material, such as aluminum oxide, or any other oxide, nitride, carbide, etc., or combination material that can limit shorting from the substrate support assembly.

[0047]

[0053] In some embodiments, recessed channels may be formed along the surface of the puck 320 to allow a flow of fluid, such as a gas stream of helium, argon, or some other gas, to flow up through the pedestal shaft and across the surface of the puck. The gas may facilitate cooling of the substrate from the backside of the substrate, as the fluid may be cooled during delivery through the substrate support assembly. Thus, by adjusting the flow of fluid through the puck, improved cooling may be provided over conductive cooling from the support assembly alone. For example, by increasing the flow of fluid during and / or after a processing step, the temperature of the substrate may be more easily brought back to the deposition set point temperature. By providing multiple recessed channels that provide separate fluid flow paths, different regions may cool at different rates, addressing non-uniform temperature distribution across the substrate. As a result, heat load issues that arise during processing steps may be addressed with the substrate support assembly according to the present technique, and uniformity of the deposition process may be improved by ensuring a consistent substrate temperature at each deposition cycle.

[0048]

[0054] 5 shows a schematic partial cross-sectional view of a substrate support assembly 300 according to some embodiments of the present technique, which may show additional aspects of the lift pin assembly 335 described above, as well as additional features of the support assembly. As shown, the substrate support assembly 300 may include a conductive shield 325 that extends along the backside of the platen component. A platen insulator 315 may rest on top of the conductive shield. A conductive platen 310 is positioned on the insulator and may define a number of fluid channels as previously described for cooling the substrate support assembly and the substrate. The substrate support assembly 300 may include a puck 320 and an edge ring 330, as previously described.

[0049]

[0055] The lift pin assembly 335 may extend through the conductive shield 325, the platen insulator 315, the platen 310, and the puck 320 as shown. The lift pin assembly may be configured to limit plasma generation inside the lift pin holes and to limit entrapment of helium that may flow through the puck and into the aperture. As shown and described above, a counterbore aperture is formed through the puck with a smaller diameter aperture portion extending to the puck surface. The lift pin 520 may be characterized by an upper plug that may be located just below the access from the aperture through the puck. For example, the lift pin 520 may be recessed from the substrate support surface of the puck by about 2 mm or less, and may be recessed from the surface of the puck by about 1 mm or less, about 800 μm or less, about 700 μm or less, about 600 μm or less, about 500 μm or less, about 400 μm or less, about 300 μm or less, about 200 μm or less, or less.

[0050]

[0056] The liner 525 may fit within an aperture through the puck and rest against an inner edge of the puck 320. The liner 525 defines an interior path through which the lift pins may extend and may define a tapered entrance through which the lift pins may rest concavely on the liner as shown. The liner is held by a holder 530, which may fit within the conductive shield 325, the platen insulator 315, and the platen 310. Each of the liner and holder may be formed of dielectric or insulating components in some embodiments. A counterweight 535 may be connected to the end of the lift pin 520 opposite the substrate contacting end to maintain the lift pin in a concave position during substrate processing. The lift pin assembly is passive during operation and may be actuated by a vertically concave substrate support assembly. The counterweight can be contacted from below when the substrate support is retracted from the operating position, causing the lift pins to extend up through the assembly to lift the substrate from the support. Some embodiments of the present technology can include any number of lift pin assemblies.

[0051]

[0057] For conductive components that may act as an electrostatic chuck, the path through the lift pin assembly apertures may provide access for arcing between the components. Thus, in some embodiments, the holder may be shaped and connected to the assembly components to increase the line distance, such as by forming a tortuous path that may lower the potential and limit arcing from the conductive components. For example, a portion of the holder 530 may extend into the platen 310. Additionally, the holder 530 may define a recess, such as an annular notch as shown, within which a portion of the platen insulator may be positioned.

[0052]

[0058] 6A shows a schematic partial cross-sectional view of a substrate support assembly 300 according to some embodiments of the present technique, and may show additional features of a purge path extending through the assembly. The processing region of the chamber may be maintained at vacuum pressure, while the internal components within the pedestal shaft may be maintained near atmospheric pressure. During low temperature operation, condensation may occur within these regions, which may lead to arcing at the RF rods or other corrosion within the substrate support assembly. Therefore, in some embodiments, additional purge paths may be formed that extend around the RF rods and associated components to ensure that condensation within the system is limited or prevented.

[0053]

[0059] As shown, the purge path 605 may extend through the pedestal shaft and the platen insulator 315. The purge path 605 may then extend laterally into the central region where the RF rod extends through the shaft. In some embodiments, a gap may be formed between the RF rod insulator 350 and other components inside the platen 310. As shown, when the purge flow, which may be nitrogen or any other material, strikes the platen 310, the flow may be directed under and around the platen, as well as around the periphery of the rod insulator and in and out around the rod insulator 350. The purge path may extend down along the exterior of the rod insulator and down along the interior of the rod insulator, such as between the rod insulator and the RF rod. This ensures that air is purged from the substrate support assembly to protect against condensation.

[0054]

[0060] FIG. 6B shows a schematic partial cross-sectional view of a rod insulator 350 according to some embodiments of the present technology. As shown, the rod insulator 350 may define a ledge 610 along its inner surface, shrinking its inner diameter from the end that may extend around the platen 310 as described above. The diameter may then be reduced as the rod insulator extends along the length of the RF rod through the pedestal. Additionally, the rod insulator 350 may define one or more recesses 615 at the end of the rod insulator where it may abut the platen 310. The recesses 615 may ensure that purge gas extends from the outside to the inside of the rod insulator to purge along the RF rod. Access may be made to recessed areas inside the platen insulator so that RF leakage may be controlled or prevented. This is further illustrated in FIG. 6C, where a purge path 605 is shown extending into the platen insulator 315 up the pedestal shaft 305. When the additional recesses 620 are formed and placed on the insulator, they can form side channels between the platen insulator and the platen, which can then provide fluid access into the central channel for purging around the RF rod.

[0055]

[0061] The processing chamber 100 and / or the processing chamber 200 may be utilized in some embodiments of the present technology for processing methods that may include forming, etching, or curing materials for semiconductor structures. The chambers may include any of the substrate support assembly components or features described above. It should be understood that the described chambers should not be considered limiting and any chamber that may be configured to perform the operations as described may be used as well. FIG. 7 illustrates exemplary steps in a processing method 700 according to some embodiments of the present technology. The method may be performed in a variety of processing chambers, including the processing chamber 100 or the processing chamber 200 described above, and in one or more mainframes or tools. The method 700 may include several optional steps. These steps may or may not be specifically associated with some embodiments of the method according to the present technology. For example, many of the steps are described to provide a broader scope of structure formation, but are not critical to the present technology or may be performed by alternative methodologies that will be readily understood.

[0056]

[0062] Method 700 may include additional steps prior to the initiation of the recited steps. For example, the additional processing steps may include forming structures on the semiconductor substrate, which may include both the formation and removal of materials. For example, transistor structures, memory structures, or any other structures may be formed. The prior processing steps may be performed in the chamber in which method 700 may be performed, or processing may be performed in one or more other processing chambers prior to providing a substrate to one or more semiconductor processing chambers in which method 700 may be performed. Nevertheless, method 700 may optionally include providing a semiconductor substrate to a processing region of a semiconductor processing chamber, such as processing chamber 200 described above, or to another chamber that may include components as described above. The substrate is deposited on a substrate support, which may be a pedestal, such as substrate support 210, which may be or include substrate support assembly 300, and which may be present in a processing region of a chamber, such as processing space 120 described above.

[0057]

[0063] The substrate being processed may be or include any number of materials used in semiconductor processing. The substrate material may be or include silicon, germanium, a dielectric material including silicon oxide or silicon nitride, a metallic material, or any number of combinations of these materials, and may be a substrate or a material formed on a substrate. The features may be characterized by any shape or configuration according to the present technology. In some embodiments, the features may be or include trench structures or openings formed within the substrate. The features may be characterized by any shape or size, but in some embodiments, the features may be characterized by a higher aspect ratio, or the ratio of the depth of the feature to the width across the feature. For example, in some embodiments, the features may be characterized by an aspect ratio of about 5:1 or greater, and may be characterized by an aspect ratio of about 10:1 or greater, about 15:1 or greater, about 20:1 or greater, about 25:1 or greater, about 30:1 or greater, about 40:1 or greater, about 50:1 or greater, or greater. Additionally, the feature may be characterized by a narrow width or diameter across the feature, including between two sidewalls, such as a dimension of about 20 nm or less, and may be characterized by a width across the feature of about 15 nm or less, about 12 nm or less, about 10 nm or less, about 9 nm or less, about 8 nm or less, about 7 nm or less, about 6 nm or less, less than about 5 nm or less, or less.

[0058]

[0064] In some embodiments, method 700 may include optional processing steps, such as pre-treatment, that may be performed to prepare the surface of the substrate for deposition. Once prepared, method 700 may include supplying one or more precursors to a processing region of a semiconductor processing chamber housing the structure. The precursors may include one or more silicon-containing precursors, as well as one or more diluents or carrier gases, such as inert gases or other gases, that are supplied with the silicon-containing precursors. Although the method is described in the context of producing flowable silicon films, it should be understood that the described method and / or chamber may be used to produce any number of materials in accordance with embodiments of the present technology. At step 705, a plasma may be formed from the deposition precursors, including the silicon-containing precursors. The plasma may be formed in the processing region, which may allow a deposited material to be deposited on the substrate. For example, in some embodiments, a capacitively coupled plasma may be formed in the processing region by applying plasma power to a face plate as described above. For example, the radio frequency power source described above may be operated at a reduced effective plasma power to deposit material within features on the substrate.

[0059]

[0065] At step 710, a silicon-containing material may be deposited on the substrate from the plasma effluent of the silicon-containing precursor. The material, in some embodiments, is a flowable silicon-containing material and may be or include amorphous silicon. The deposited material may at least partially flow into a feature on the substrate to provide bottom-up gap filling. As shown, the deposited material may flow to the bottom of the feature, although an amount of material may remain on the sidewalls of the substrate. Although the amount deposited may be relatively small, the material remaining on the sidewalls may limit subsequent flow.

[0060]

[0066] The power applied during deposition may be a low power plasma to limit dissociation and maintain hydrogen incorporation into the deposited material. This incorporation of hydrogen may contribute to the flowability of the deposited material. Thus, in some embodiments, the plasma power source may provide a plasma power of about 100 W or less to the faceplate, and may provide a power of about 90 W or less, about 80 W or less, about 70 W or less, about 60 W or less, about 50 W or less, or less. This power may be further attenuated by operating the high frequency power source at a pulse frequency and duty cycle as previously described to produce an effective power of about 10 W or less, or about 5 W or less, as described above.

[0061]

[0067] Following the deposition amount, in some embodiments of the present technology, a treatment or curing process configured to densify the formed material may be formed, advantageously cleaning or etching back the material on the sidewalls of the feature. This process may be performed in the same chamber as the deposition and may be performed in a cyclic process to fill the feature. In some embodiments, the flow of the silicon-containing precursor may be stopped and the processing region may be purged. Following the purge, a processing precursor may be flowed into the processing region of the processing chamber. The processing precursor may be or may include hydrogen, helium, argon, or another inert material that may not chemically react with the film. In step 715, a processing plasma may be formed, which may also be a capacitively coupled plasma formed inside the processing region. The deposition plasma may be formed by applying a high frequency plasma power to a faceplate or showerhead, but in some embodiments may not include a separate power source engaged. The processing may utilize both a high frequency power source and a low frequency power source connected to the substrate support as described above. During processing, the high frequency power source may operate at a first power level and the low frequency power source may operate at a second power level. In embodiments of the present technology, the two power levels may be similar or different.

[0062]

[0068] The high frequency power source may be operated at a pulsed low effective power during deposition plasma, but in a continuous wave configuration during processing. This may be done at any of the plasma powers previously described. The low frequency power source may be operated in a pulsed mode during processing. This may be done at any of the pulse frequencies and / or duty cycles previously described.

[0063]

[0069] During the deposition steps, the low frequency power supply may not be operated. As described above, to allow repeatable plasma generation at low power, a trigger sequence may be utilized to ensure plasma generation during each deposition step. The trigger sequence may include a first period and a second period, which together form a deposition period. In some embodiments, to limit deposition, the deposition period may be about 30 seconds or less, about 20 seconds or less, about 15 seconds or less, about 10 seconds or less, about 8 seconds or less, about 6 seconds or less, about 5 seconds or less, about 4 seconds or less, or less. The first period may be shorter than the second period, and the first period may be used to ensure plasma generation while limiting the impact on the deposition process. Thus, in some embodiments, the first period of time is about 2 seconds or less, and can be about 1 second or less, about 0.5 seconds or less, about 0.4 seconds or less, about 0.3 seconds or less, about 0.2 seconds or less, about 0.1 seconds or less, about 0.09 seconds or less, about 0.08 seconds or less, about 0.07 seconds or less, about 0.06 seconds or less, about 0.05 seconds or less, or less.

[0064]

[0070] In some embodiments, a first power is applied by the high frequency power source during a first period, which can be higher than a second power applied by the high frequency power source during a second period. For example, during the first period, the first power can be about 50 W or more, about 80 W or more, about 100 W or more, about 120 W or more, about 140 W, about 160 W or more, about 180 W or more, about 200 W or more, or more. The high frequency power source can then apply power during a second period at any of the above-mentioned effective powers for the remainder of the deposition time. In addition, the high frequency power source can operate consistently during the deposition time, but during the first period, a low frequency power source can be applied at any of the power levels above to ensure ignition. In another example, the high frequency power source can operate in a multi-level pulse configuration during the first period before switching to the desired effective power during the second period. A multi-level pulse may include several pulses, each of which may be less than 0.1 seconds, and may occur during a first period of time, such as, for example, about 50 microseconds or less, about 40 microseconds or less, about 30 microseconds or less, about 20 microseconds or less, or less. The pulse may include a first pulse that is higher in a first fraction of the pulse, followed by a second pulse that is lower in a second fraction of the pulse. The two portions of the pulse may occur at any of the power levels discussed above.

[0065]

[0071] During processing, the substrate support assembly may be used to maintain the temperature of the substrate at step 720, and temperature control may continue prior to a subsequent deposition step. For example, in addition to conductive cooling through the substrate support assembly, in some embodiments, a backside gas may be supplied and adjusted to further control the substrate temperature during high power processing operations. Simultaneously, or in addition, the more directionally supplied plasma effluents may penetrate the remaining film formed at the bottom of the feature, reducing hydrogen uptake to densify the film at step 725. Following processing, the backside gas may continue to flow to reduce the temperature to the deposition set point prior to the subsequent deposition cycle.

[0066]

[0072] Although the deposits can be formed to a few nanometers or more, by performing the etching process as described above, the thickness of the densified material can be controlled to a thickness of about 100 Å or less, and can be about 90 Å or less, about 80 Å or less, about 70 Å or less, about 60 Å or less, about 50 Å or less, about 40 Å or less, about 30 Å or less, about 20 Å or less, about 10 Å or less, or less. By controlling the thickness of the deposited material, conversion through the entire thickness can be more easily performed and can solve penetration issues common to conventional processes. This process can then be repeated in any number of complete cycles to continue to generate densified material down to the feature.

[0067]

[0073] With regard to the deposition precursors used during any of the formation steps, any number of precursors may be used in the present technology. Silicon-containing precursors that may be used may include, but are not limited to, silane (SiH4), disilane (Si2H6), or other organosilanes, including cyclohexasilane, silicon tetrafluoride (SiF4), silicon tetrachloride (SiCl4), dichlorosilane (SiH2Cl2), tetraethyl orthosilicate (TEOS), and any other silicon-containing precursors that may be used to form silicon-containing films. Silicon-containing materials may be nitrogen-free, oxygen-free, and / or carbon-free in some embodiments. One or more additional precursors may be included in any of the steps, such as inert precursors that may include Ar, diatomic hydrogen, He, or other materials such as nitrogen, ammonia, or other precursors.

[0068]

[0074] Temperature and pressure can also affect the operation of the technique. For example, in some embodiments, the process is performed at a temperature of about 20° C. or less to facilitate film flow, and may be performed at a temperature of about 10° C. or less, about 0° C. or less, about −10° C. or less, about −20° C. or less, about −30° C. or less, or less. The temperature may be maintained in any of these ranges throughout the method, including during processing and densification. The pressure inside the chamber is kept relatively low, such as a chamber pressure of about 10 Torr or less, for any of the processes, and the pressure may be maintained at about 8 Torr or less, about 6 Torr or less, about 5 Torr or less, about 4 Torr or less, about 3 Torr or less, about 2 Torr or less, about 1 Torr or less, or less. Additionally, in some embodiments, the pressure may be maintained at different levels during deposition and processing. For example, the pressure can be maintained at about 1 Torr or more (such as about 2 Torr or more, about 3 Torr or more, or more) during deposition, and the pressure can be maintained at about 1 Torr or less (such as about 0.8 Torr or less, about 0.5 Torr or less, about 0.1 Torr or less, or less) during deposition. By performing processes according to some embodiments of the present technique, improved filling of narrow features utilizing silicon-containing or other flowable materials can be produced while ensuring adequate temperature control of the substrate within a single processing chamber.

[0069]

[0075] In the preceding description, for purposes of explanation, numerous details have been set forth in order to provide an understanding of various embodiments of the present technology. However, it will be apparent to one of ordinary skill in the art that certain embodiments may be practiced without some of these details, or with additional details.

[0070]

[0076] Although several embodiments have been disclosed, those skilled in the art will recognize that various modifications, alternative structures, and equivalents can be used without departing from the spirit of the embodiments. In addition, some well-known processes and elements have not been described to avoid unnecessarily obscuring the present technology. Therefore, the above description should not be interpreted as limiting the scope of the present technology. Furthermore, although a method or process may be described sequentially or stepwise, it should be understood that the steps may be performed simultaneously or in a different order than that listed.

[0071]

[0077] Where a range of values ​​is given, each intervening value between the upper and lower limit of that range is specifically disclosed to the smallest unit of the lower limit, unless the context clearly indicates otherwise. Any smaller ranges between any stated or unstated intervening value in a stated range, as well as any other stated or intervening value in that stated range, are also included. The upper and lower limits of such narrower ranges may be individually included or excluded from the range. Each range in which either or both limits are included in the narrower range, or neither is included in the narrower range, is also encompassed by this technology and covers any specifically excluded limit in the stated range. When a stated range includes one or both of the limits, ranges excluding either or both of those included limits are also included.

[0072]

[0078] As used in the specification and claims, the singular forms "a," "an," and "the" include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to "a precursor" includes a plurality of such precursors, reference to "the layer" includes reference to one or more layers and equivalents known to those skilled in the art, and so forth.

[0073]

[0079] Additionally, the terms "comprise(s)", "comprising", "contain(s)", "containing", "include(s)", and "including", when used in this specification and claims, are intended to specify the presence of stated features, integers, components, or steps, but do not exclude the presence or addition of one or more other features, integers, components, steps, operations, or groups.

Claims

1. A pedestal shaft; a platen defining a fluid channel across a first surface of the platen; a platen insulator positioned between the platen and the pedestal shaft; a conductive puck connected to the first surface of the platen and configured to contact a substrate supported on a semiconductor substrate support; a conductive shield extending along a backside of the platen insulator and connected between a portion of the platen insulator and the pedestal shaft; an RF rod extending through the pedestal shaft, the RF rod being electrically connected to the platen; a rod insulator extending around the RF rod along a length of the RF rod; Equipped with the pedestal shaft and the platen insulator define a vertical portion of a purge path laterally away from the rod insulator, the purge path having a lateral portion extending from the vertical portion to the rod insulator, and the purge path having a third portion extending downwardly along the rod insulator. A semiconductor substrate support.

2. an insulating edge ring resting on a recessed ledge of the conductive puck and extending radially outward along an outer edge of the platen insulator and contacting the conductive shield; The semiconductor substrate support of claim 1 further comprising:

3. 3. The semiconductor substrate support of claim 2, wherein the conductive puck includes a coating along a surface configured to contact the substrate, the coating extending along the recessed ledge upon which the insulating edge ring rests.

4. The semiconductor substrate support of claim 3 , wherein the coating comprises the same insulating material as the insulating edge ring.

5. A lift pin assembly extending through the platen, the platen insulator, the conductive puck, and the conductive shield. the lift pin assembly further comprising: A lift pin; Raina and A holder and Counterweight and The semiconductor substrate support of claim 1 , comprising:

6. The semiconductor substrate support of claim 5 , wherein the holder defines a recess in which a portion of the platen insulator is disposed.

7. The semiconductor substrate support of claim 1 , wherein the pedestal shaft is mounted on a hub and the rod insulator extends into the hub.

8. The semiconductor substrate support of claim 1 , wherein the rod insulator extends within a portion of the platen insulator.

9. The semiconductor substrate support of claim 1 , wherein the purge path runs along the interior and exterior of the rod insulator.

10. A chamber body; A substrate support configured to support a semiconductor substrate, comprising: A pedestal shaft; a platen defining a fluid channel across a first surface of the platen; a platen insulator positioned between the platen and the pedestal shaft; a conductive puck connected to the first surface of the platen and configured to contact a substrate supported on the semiconductor substrate; a conductive shield extending along a backside of the platen insulator and connected between a portion of the platen insulator and the pedestal shaft; an RF rod extending through the pedestal shaft, the RF rod being electrically connected to the platen; a rod insulator extending around the RF rod along a length of the RF rod; Equipped with the pedestal shaft and the platen insulator define a vertical portion of a purge path laterally away from the rod insulator, the purge path having a lateral portion extending from the vertical portion to the rod insulator, and the purge path having a third portion extending downwardly along the rod insulator. A substrate support; a faceplate, wherein the chamber body, the substrate support, and the faceplate define a processing region; and a radio frequency plasma source connected to the face plate; a low frequency plasma source connected to the substrate support; A semiconductor processing system comprising:

11. the substrate support comprises an electrostatic chuck, and the semiconductor processing system comprises: A DC power supply connected to the substrate support. The semiconductor processing system of claim 10 further comprising:

12. 11. The semiconductor processing system of claim 10, wherein the low frequency plasma source is configured to operate at or below 2 MHz and the high frequency plasma source is configured to operate at or above 13.56 MHz with a pulse frequency of or below 20 kHz at a duty cycle of or below 20%.

13. 13. The semiconductor processing system of claim 12, wherein the radio frequency plasma source is configured to generate a plasma with an effective power of 5 W or less.

14. an insulating edge ring resting on a recessed ledge of the conductive puck and extending radially outward along an outer edge of the platen insulator and contacting the conductive shield; The semiconductor processing system of claim 10 further comprising:

15. 15. The semiconductor processing system of claim 14, wherein the conductive puck includes a coating along a surface configured to contact the substrate, the coating extending along a recessed ledge upon which the insulating edge ring rests.

16. a first LC filter connected to the substrate support and configured to substantially ground the high frequency plasma source through the substrate support; The semiconductor processing system of claim 10 further comprising:

17. a second LC filter connected to the faceplate and configured to substantially ground the low frequency plasma source to the chamber body; 20. The semiconductor processing system of claim 16 further comprising:

Citation Information

Patent Citations

  • Plasma processing device

    JP1999233291A

  • Electrostatic chuck, plasma processing apparatus, and plasma processing method

    JP2005136350A

  • Ceramic heater

    JP2009256789A

  • Plasma reactor electrostatic chuck with coaxial RF feed and multi-zone AC heater power transmission device via coaxial feed

    JP2011520288A

  • Pedestal with multi-zone temperature control and multi-purge function

    JP2015529969A