Process for application of oxyhydroxide coatings on aluminum-containing materials

Abstract

A process for providing a surface of an aluminum-containing material having a chromate-free protective coating includes degreasing the surface of the aluminum-containing material to produce a degreased surface, treating the degreased surface with a high alkaline treatment immediately after degreasing to produce an alkaline treated surface having soot on the surface, and treating the alkaline treated soot surface with a hot water treatment immediately after the high alkaline treatment.

Description

[Background technology]

[0001] The present disclosure relates to a process for preparing the surface of an aluminum-containing material to replace a chromate conversion coating for the application of an organic coating.

[0002] Aluminum, aluminum alloys, and other aluminum-containing materials are frequently used to form structures that require corrosion resistance. Protection against corrosion can be achieved by application of organic protective coatings (e.g., primers, topcoat paints). Although aluminum, being an active metal, can easily undergo oxidation / corrosion reactions, the presence of a relatively thin, non-continuous, natural native oxide layer (3-6 nm) on the surface provides some level of corrosion protection. This native oxide film may not be sufficiently resistant to highly corrosive environments such as salt water, nor may it provide a sufficient base for painting. Improved films that are more corrosion resistant and suitable as a base for painting can usually be formed on the surface of aluminum-containing materials by anodization or by a chromate conversion process.

[0003] In the field of chemical conversion coatings, hexavalent chromium ions (Cr 6+)-based chromate conversion coatings are commonly used for stand-alone corrosion protection of aluminum and as an adhesion layer basecoat for bonding and painting applications. For fields of products in highly corrosive environments, aluminum can typically be painted with a hexavalent-based chromate conversion coating as a basecoat, followed by a layer of polymeric epoxy as a primer and polymeric polyurethane as a topcoat. In a three-layer system for painting applications, the chromate acts as an adhesion layer, the primer acts as a corrosion inhibitor layer that provides the bulk of the corrosion protection, and the topcoat acts as a barrier / UV protection layer. In some systems, a hexavalent-based chromate wash primer is sprayed directly onto the metal surface to form the basecoat. Coatings with hexavalent chromium ions have shown excellent performance, reliability, and have been considered the standard for decades. However, hexavalent chromium ions can have deleterious effects and are being phased out of future designs and applications.

[0004] One of the manufacturing and field problems observed with chromate coatings is the water-bound Cr in the coating. 3+ -O-Cr 6+ The proper adhesion of the primer is due to the aging and structural changes that occur in the skeleton and the resulting hydrophobicity. Alternatives (e.g., trivalent chromium ion-based coatings and zirconium-based coatings) are commercially available, but may not provide satisfactory performance. Typically, the chromate conversion coating (CCC) process involves multiple steps with complex and toxic chemical formulations. For example, the commonly used specification MIL-DTL-5541 specifies type 1 (hexavalent-based chromate) and type II (trivalent-based chromate) coatings with chemical solution tanks such as alkaline degreaser, alkaline etch, acid deoxidizer, etc., and a chromate coating tank is used to produce the final coating. Each chemical process tank is inevitably followed by a rinse water tank, resulting in an increase in the environmental area. Summary of the Invention

[0005] A process according to one disclosed non-limiting embodiment of the present disclosure includes degreasing a surface of an aluminum-containing material to produce a degreased surface; treating the degreased surface with a high alkaline treatment immediately after degreasing to produce an alkaline-treated surface having soot on the surface; and treating the alkaline-treated surface with a hot water treatment immediately after the high alkaline treatment to provide a surface of the aluminum-containing material having a chromate-free coating.

[0006] Further embodiments of any of the preceding embodiments of the present disclosure include where degreasing comprises treating the surface in an immersion tank for 5 to 10 minutes.

[0007] Further embodiments of any of the foregoing embodiments of the present disclosure include where the degreasing is carried out at a pH of 9-11 and a temperature of 110-150 F (43-66 C).

[0008] Further embodiments of any of the foregoing embodiments of the present disclosure include that the step of treating the surface with a highly alkaline treatment occurs in an immersion tank containing a highly alkaline solution for a period of between 30 seconds and 3 minutes.

[0009] Further embodiments of any of the foregoing embodiments of the present disclosure include that the step of treating the surface with a highly alkaline treatment occurs at a temperature of 135-150 F (57-66 C) and a pH greater than 12.

[0010] Further embodiments of any of the foregoing embodiments of the present disclosure include a highly alkaline solution comprising 15-60 g / l sodium hydroxide (NaOH), 5-20 g / l sodium bicarbonate (NaHCO3), 5-10 g / l sodium nitrate (NaNO3), along with sodium sulfide (Na2S), triethanolamine (CH6H6H8H2O4), and 10 g / l sodium nitrate (NaNO3). 15 NO3) and potassium gluconate (C6H 11 KO7).

[0011] Further embodiments of any of the foregoing embodiments of the present disclosure include where the soot from the highly alkaline treatment is not removed and the aluminum is subjected directly to the hydrothermal treatment, and the soot comprises oxyhydroxides of aluminum and other metals present in the aluminum-containing material.

[0012] Further embodiments of any of the foregoing embodiments of the present disclosure include where the oxyhydroxide comprises one or more of NaAl(OH)4, Al(OH)3, Mg(OH)2, Cu(OH)2, CuO, Cu2O, Cu2S, Na2Zn(OH)4, SiO2.xH2O.

[0013] Further embodiments of any of the foregoing embodiments of the present disclosure include the step of treating the surface with a hot water treatment is performed for a period of 20 to 60 minutes.

[0014] Further embodiments of any of the foregoing embodiments of the present disclosure include where the step of treating the surface with a hot water treatment includes immersion in a surface tank containing deionized water at 185-212 F (85-100 C) and a pH of 6.4 for 20-30 minutes.

[0015] Further embodiments of any of the foregoing embodiments of the present disclosure include where the step of treating the surface with a hydrothermal treatment includes exposing the surface to steam at 250-270 F (121-132 C) and 30-35 PSI for 50-60 minutes.

[0016] Further embodiments of any of the foregoing embodiments of the present disclosure include degreasing the aluminum in a dip tank for 5 to 10 minutes; treating the aluminum in a high alkali treatment dip tank for 30 seconds to 3 minutes; and treating the aluminum in a hot water treatment for 20 to 60 minutes.

[0017] Further embodiments of any of the foregoing embodiments of the present disclosure include painting or bonding the aluminum-containing material after the hydrothermal treatment.

[0018] A process according to one disclosed non-limiting embodiment of the present disclosure includes degreasing a surface of an aluminum-containing material in a dip tank for 5-10 minutes at a pH of 9-11 and a temperature of 110-150F (43-66C) to produce a degreased surface; immediately after degreasing, treating the degreased surface in a high alkali treatment dip tank for 30 seconds to 3 minutes at a temperature of 135-150F (57-66C) and a pH greater than 12 to produce an alkali treated surface having soot on the surface; and immediately after the high alkali treatment, treating the alkali treated surface with a hot water treatment for 20-60 minutes, wherein the soot from the high alkali treatment is not removed and the aluminum alkali treated surface having soot on the surface is directly subjected to the hot water treatment dip to provide a surface of an aluminum-containing material having a chromate-free coating.

[0019] Further embodiments of any of the foregoing embodiments of the present disclosure include a high alkali solution in the high alkali treatment soak tank that contains 15-60 g / l sodium hydroxide (NaOH), 5-20 g / l sodium bicarbonate (NaHCO3), 5-10 g / l sodium nitrate (NaNO3), along with sodium sulfide (Na2S), triethanolamine (CH6H2O4), and 10 g / l sodium nitrate (NaNO3). 15 NO3) and potassium gluconate (C6H 11 KO7), where the high alkaline treatment dip forms soot which is an oxyhydroxide of aluminum and other metals present in the aluminum-containing material, the oxyhydroxides including one or more of NaAl(OH)4, Al(OH)3, Mg(OH)2, Cu(OH)2, Cu2O, CuO, Cu2S, Na2Zn(OH)4, SiO2.xH2O.

[0020] Further embodiments of any of the foregoing embodiments of the present disclosure include the hot water treatment comprises deionized water at 185-212 F (85-100 C) and a pH of 6.4 for 20-30 minutes.

[0021] Further embodiments of any of the foregoing embodiments of the present disclosure include where the hydrothermal treatment includes steaming at 250-270 F (121-132 C) and 30-35 PSI for 50-60 minutes.

[0022] Further embodiments of any of the foregoing embodiments of the present disclosure include painting and / or bonding the aluminum-containing material after the hot water treatment.

[0023] A process according to one disclosed non-limiting embodiment of the present disclosure includes degreasing a surface of an aluminum-containing material in a dip tank for 5-10 minutes at a pH of 9-11 and a temperature of 110-150F (43-66C) to produce a degreased surface; immediately after degreasing, treating the degreased surface in a first high alkali treatment dip tank to produce an alkali treated surface having soot on the surface; deoxidizing the alkali treated surface having soot on the surface after the first high alkali treatment; immediately after deoxidizing, treating the deoxidized, alkali treated surface in a second high alkali treatment dip tank for 30 seconds to 3 minutes at a temperature of 135-150F (57-66C) and a pH greater than 12; and immediately after the high alkali treatment, treating the aluminum with a hot water treatment for 20-60 minutes, wherein the soot from the high alkali treatment is not removed and the aluminum is directly subjected to the hot water treatment dip to provide a surface of the aluminum-containing material having a chromate-free coating.

[0024] Further embodiments of any of the foregoing embodiments of the present disclosure include painting and / or bonding the aluminum-containing material after the hot water treatment.

[0025] The foregoing features and elements may be combined in various combinations without exclusivity unless expressly stated otherwise. These features and elements and the operation of the present invention will become more apparent in light of the following description and the accompanying drawings. It should be understood, however, that the following description and drawings are intended to be illustrative and non-limiting in nature.

[0026] Various features will become apparent to those skilled in the art from the following detailed description of the disclosed non-limiting embodiments. The drawings that accompany the detailed description can be briefly described as follows. [Brief description of the drawings]

[0027] [Figure 1] FIG. 2 is a schematic diagram of a process for application of a basecoat on aluminum according to one disclosed non-limiting embodiment. [Diagram 2] FIG. 2 is a schematic diagram of a process for application of a basecoat over aluminum in accordance with another disclosed non-limiting embodiment. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0028] FIG. 1 illustrates generally a process 20 for the application of a basecoat formed on aluminum with a non-toxic chemical process that may be used to replace hexavalent-based conversion coatings as well as other complex coating systems based on trivalent chromium and zirconium chemistries. The process 20 may be referred to herein as ALSC (Aluminum (AL) Soot (S) Coating (C)) and utilizes an alloy oxyhydroxide film formed on the aluminum surface during a high alkaline treatment step. In the disclosed embodiment, the ALSC process 20 is defined by three chemical dips in associated dip tanks (not shown). The process 20 typically includes a degreaser dip (step 22), a high alkaline treatment dip (step 24), and a hot water treatment dip (step 26). Each dip is of relatively long duration, e.g., a degreaser step (step 22) of 5-10 minutes, a high alkaline treatment dip (step 24) of 30 seconds to 3 minutes, and a hot water treatment dip (step 26) of 20-60 minutes.

[0029] Aluminum is used in the military, aerospace, automotive, and medical industries due to its high strength-to-weight ratio, tunable functional properties, and recyclability. Wrought (e.g., 6061, 5052) and cast (e.g., A356, A380) aluminum alloys are routinely utilized for several applications.

[0030] The term "aluminum" in reference to the base metal being treated includes aluminum alloys having an aluminum content varying from 85% to 99%, which aluminum alloys are usually subjected to cleaning and deoxidation treatments before chromating or other chemical or electrochemical treatments. Aluminum alloys usually contain greater amounts of other alloying metals, such as silicon, chromium, lead, iron, copper, magnesium, manganese, zinc, etc. As used herein, aluminum-containing materials include aluminum alloys containing more than 85% aluminum by weight. All references to percent compositions herein are by weight unless otherwise stated.

[0031] First, the degreaser dip (step 22) of the ALSC process 20 provides for cleaning of the aluminum in an alkaline solution to remove coolants, oils, greases, and machining contaminants from the metal surface. A water-free surface is obtained during this process step, indicating the aluminum is ready for the next processing step.

[0032] One degreaser solution may contain, for example, alkaline salts (i.e., sodium or potassium silicates and phosphates), surfactants, sequestering agents, and solvents as ingredients, and operates at a pH of 9-11 and a temperature of 110-150F (43-66C). In one embodiment, the immersion time may be 5-10 minutes. Commercially available Chemetall Aluminum Cleaner NST manufactured by BASF of New Jersey, USA; or a bath having a similar composition as above, may be utilized. A rinse (e.g., tap water or deionized (DI) water) bath may optionally follow the degreaser bath to remove residual chemicals. This extra rinse bath may be omitted by spray rinsing the cleaned metal over the degreaser bath, or may be transferred without rinsing to the next process (step 24) having similar pH and chemicals. The aluminum surface may be wiped with an isopropyl alcohol or acetone saturated cloth to remove organic contaminants prior to the degreaser step.

[0033] Next, the high alkali treatment dip (step 24) of the ALSC process 20 dilutes the cleaned aluminum with, for example, 15-60 g / l sodium hydroxide (NaOH), 5-20 g / l sodium bicarbonate (NaHCO3), 5-10 g / l sodium nitrate (NaNO3), sodium sulfide (Na2S), triethanolamine (C6H4O5), and sodium nitrate (NaNO3). 15 NO3) and potassium gluconate (C6H 11 This involves treating the metal in a highly alkaline solution containing 1,2-dichloroethane (KO7). The bath is operated at a temperature of 135-150° F. (57-66° C.) and a pH of greater than 12. In one embodiment, immersion time in the solution can be from 30 seconds to 3 minutes.

[0034] During the high alkali treatment soak (step 24), oxyhydroxides of aluminum and other metals present in the aluminum alloy matrix form on the aluminum, such as NaAl(OH)4, Al(OH)3, Mg(OH)2, Cu(OH)2, Cu2O, CuO, Cu2S, Na2Zn(OH)4, SiO2.xH2O or mixed metal oxyhydroxides. See Equations 1-5 for examples of oxyhydroxide formation reactions.

[0035] 2Al+2NaOH+6H2O→2NaAl(OH)4+3H2(1)

[0036] Mg+2(OH) - →Mg(OH)2+2e - (2)

[0037] Si+2H2O→SiO2+2H2(3)

[0038] Cu2O+H2O+2OH - →2Cu(OH)2+2e - (4)

[0039] 2Cu+2OH - →Cu2O+H2O+2e - (5)

[0040] The formation of metal oxyhydroxides was confirmed by X-ray photoelectron spectroscopy (XPS) analysis, which showed the presence of elements related to metal oxyhydroxides on highly alkaline treated surfaces (e.g., Al, Mg, O, Si, Cu, and Cr on 6061 aluminum alloy), whereas bare or coated aluminum surfaces did not show all of the elements listed above. The oxyhydroxides turn the metal surface into a gray or black shade with iridescence. The color and thickness of the film formed varies depending on the composition of the aluminum alloy (e.g., 6061, 2024, 7075), the treatment time, and the highly alkaline bath activity (i.e., etch rate). For example, on 2024 aluminum, a bright black film is observed due to the presence of copper sulfide and / or copper (II) oxide, whereas on 6061 aluminum, a bright gray film is observed due to the presence of magnesium hydroxide and hydrated silicon dioxide. The aluminum can then be rinsed with tap water or DI water to remove residual alkaline chemicals.

[0041] The highly alkaline treatment dip of the aluminum (step 24) results in violent reactions producing free hydrogen, heat, and complex oxides and hydroxides of aluminum and other metals present in the aluminum alloy matrix. Some of these reaction products, such as magnesium hydroxide, copper sulfide, copper oxide, chromium oxide, silicon oxide, are insoluble and remain on the surface of the aluminum in the form of "soot". Typically, soot is removed by using acidic chemicals in chromate and anodizing processes. In the disclosed embodiment, the soot is not removed and the aluminum is directly subjected to a hot water treatment dip (step 26) to form a soot coating.

[0042] The hot water treatment dip (step 26) of the ALSC process 20 involves converting the film formed in the highly alkaline treatment dip (step 24) into an adherent functional coating. The hot water treatment dip (step 26) may be carried out in boiling deionized water at 185-212 F (85-100 C) and a pH of 6.4 for 20-30 minutes. Alternatively, the hot water treatment dip (step 26) may be carried out in steam at 250-270 F (121-132 C) and 30-35 PSI for 50-60 minutes.

[0043] The final coating composition as measured by XPS and scanning electron microscope energy dispersive X-ray spectroscopy (SEM-EDS) on 6061 aluminum alloy consists of aluminum (63 wt%), magnesium (1.8 wt%), iron (2 wt%), copper (1.7 wt%) and oxygen (31 wt%) when treated by steam (SEM-EDS measurement), and aluminum (18 at%), magnesium (0.4 at%), carbon (16 at%) and oxygen (65 at%) when treated by boiling DI water (XPS measurement). On 2024 aluminum alloy, the AlSC coating consists of aluminum (37 wt%), copper (1 wt%), magnesium (1 wt%), manganese (3 wt%), carbon (3 wt%) and oxygen (54 wt%) when treated by steam (SEM-EDS measurement). Mechanical cross-sections / SEM and XPS show a thickness range of 0.45-4 μm for ALSC. The thickness is controlled by the treatment times and conditions of the high alkali treatment dip (step 24) and the hot water treatment dip (step 26).

[0044] 2, an alternative embodiment of the ALSC process 20A involves an additional high alkaline treatment (step 30) followed by an oxygen scavenger treatment (step 32) prior to the high alkaline treatment soak (step 24). The high alkaline treatment (step 30) can be equivalent to the high alkaline treatment soak (step 24). The additional high alkaline treatment (step 30) and oxygen scavenger treatment (step 32) are used to provide a new bulk-like composition on the surface prior to the ALSC coating formation.

[0045] After the aluminum substrate has been treated according to the ALSC process, the treated aluminum may be used alone in high pH / corrosive / oxidative environments or may be painted or adhesively bonded or otherwise finished with a curable organic protectant (step 28).

[0046] Coatings formed on aluminum by the ALSC process have the potential to replace chromate conversion coatings for painting and adhesive bonding applications. Testing has shown that the ALSC surface has high surface energy and wettability compared to Type I chromate surfaces. For example, contact angle measurements showed 17° for ALSC, 90° for TYI chromate, 80° for TYIII sealed anodized, 36° for TYIII unsealed anodized, 36° for a surface treated with hot water only, and 86° for bare 6061 Al alloy. ALSC had the lowest contact angle value among the samples measured, which indicates the hydrophilic nature of ALSC compared to the hydrophobicity of the other samples measured, especially the chromate and sealed anodized surfaces. This characteristic would be an advantage and may result in minimal or no surface preparation of the ALSC surface prior to painting and bonding, unlike chromate and anodized coatings. Primer (e.g., MIL-PRF-23377) adhesion testing to ALSC surfaces according to ASTM D3359 Methods A and B showed ratings of 5A and 5B, respectively. Also, 24-month-old, primer-coated, steam-treated ALSC surfaces passed wet tape adhesion testing according to MIL-DTL-5541 and FED-STD-141 Methods 6301.3 with minimal surface preparation. 168-hour salt spray testing according to ASTM B117 on primer-coated ALSC surfaces showed no blistering, coating lifting, or corrosion. There was some corrosion on the X-cut areas and unprotected bare metal edges, but no creep corrosion was observed. Primer adhesion after salt spray (168 hours) was better for ALSC compared to Type I chromate, which showed some delamination of the primer near the X-cut interface (>1 mm, 3A according to ASTM D3359 Method A). Based on the properties of ALSC that have been studied, it has the potential to be used as a TT-C-490 Type IV and MIL-DTL-5541 QPL / QPD coating material.

[0047] Other applications, such as adhesive bonds and coolant contact areas, may benefit from the ALSC process. ALSC coatings resist corrosive chemical attack and can be used on aluminum in high pH / oxidizing environments. Medical device companies using Sterrad and Steris systems and automotive companies using products in GMV 14665-like conditions may benefit from stand-alone ALSC. The coating passes the GMV 14665 pH 13.5 test and performs better than anodized coatings when immersed in an alkaline etch solution containing 40g / l sodium hydroxide, 5ml / l TritonX-100, 8.5g / l sodium nitrate, 2-5g / l 2024Al metal chips and 8.4g / l sodium bicarbonate. Weight loss techniques and visual inspection indicate that the anodized coatings (MIL-A-8625, TYIII hardcoat, 0.002" thick, sealed and unsealed) completely disintegrate in 15 minutes in the alkaline etch solution described above, while 66-94% integrity of the ALSC coating remains unaffected.

[0048] Although a particular order of steps has been shown, described, or claimed, it should be understood that the steps can be performed in any order, separated, or combined unless otherwise indicated, and still benefit from the present disclosure.

[0049] The foregoing description is illustrative rather than defined by the limitations therein. Although various non-limiting embodiments have been disclosed herein, those skilled in the art will recognize that various modifications and changes in light of the above teachings fall within the scope of the appended claims. It is therefore understood that within the scope of the appended claims, the present disclosure may be practiced other than as specifically described. For that reason, the appended claims should be studied to determine true scope and content.

Claims

1. 1. A process for coating the surface of an aluminium-containing material, comprising the steps of: degreasing a surface of an aluminum-containing material to produce a degreased surface; treating the degreased surface with a high alkali treatment immediately after the degreasing to produce an alkali treated surface having smut thereon; and treating the alkaline treated surface with a hot water treatment immediately following the highly alkaline treatment to provide the surface of the aluminum-containing material with a chromate-free coating. Including, treating said surface with a highly alkaline treatment is conducted in an immersion tank containing a highly alkaline solution at a temperature of 135-150° F. (57-66° C.) and a pH of greater than 12 for 30 seconds to 3 minutes; The highly alkaline solution contains 15-60 g / l sodium hydroxide (NaOH), 5-20 g / l sodium bicarbonate (NaHCO 3 ), 5-10 g / l sodium nitrate (NaNO 3 ) along with sodium sulfide (Na 2 S), triethanolamine (C 6 H 15 NO 3 ) and potassium gluconate (C 6 H 11 KO 7 ).

2. The process of claim 1, wherein the degreasing comprises treating the surface in an immersion tank for 5 to 10 minutes.

3. 3. The process of claim 2, wherein the degreasing is carried out at a pH of 9 to 11 and a temperature of 110 to 150 F (43 to 66 C).

4. 2. The process of claim 1, wherein the soot from the highly alkaline treatment is not removed and the aluminum-containing material is subjected directly to the hydrothermal treatment, and the soot comprises oxyhydroxides of aluminum and other metals present in the aluminum-containing material.

5. The oxyhydroxide is NaAl(OH). ４ , Al(OH) ３ , Mg(OH) ２ , Cu(OH) ２ , Na ２ 5. The process of claim 4, further comprising one or more of:

6. 2. The process of claim 1, wherein the step of treating the surface with the hot water treatment is carried out for 20 to 60 minutes.

7. 7. The process of claim 6, wherein said step of treating said surface with said hot water treatment comprises immersing said surface in a tank containing deionized water at 185-212 F (85-100 C) and a pH of 6.4 for 20-30 minutes.

8. 7. The process of claim 6, wherein said step of treating said surface with said hydrothermal treatment comprises exposing said surface to steam at 250-270 F (121-132 C) and 30-35 PSI for 50-60 minutes.

9. 10. The process of claim 1, further comprising painting or bonding the aluminum-containing material after the hydrothermal treatment.

10. 1. A process for coating the surface of an aluminium-containing material, comprising the steps of: degreasing the surface of the aluminum-containing material in an immersion tank for 5-10 minutes at a pH of 9-11 and a temperature of 110-150 F (43-66 C) to produce a degreased surface; a high-alkaline treatment of the degreased surface immediately after the degreasing in a high-alkaline treatment dip tank for 30 seconds to 3 minutes at a temperature of 135-150°F (57-66°C) and a pH of greater than 12 to produce an alkaline treated surface having soot thereon; and treating the alkali treated surface with a hot water treatment for 20 to 60 minutes immediately following the high alkaline treatment, wherein soot from the high alkaline treatment is not removed and the alkali treated surface having soot thereon is subjected directly to a hot water treatment dip to provide the surface of the aluminum-containing material with a chromate-free coating. Including, The high-alkali solution in the high-alkali treatment soak tank contains 15-60 g / l sodium hydroxide (NaOH), 5-20 g / l sodium bicarbonate (NaHCO 3 ), 5-10 g / l sodium nitrate (NaNO 3 ), as well as sodium sulfide (Na 2 S), triethanolamine (C 6 H 15 NO 3 ) and potassium gluconate (C 6 H 11 KO 7 ); The process wherein the highly alkaline treatment forms the soot which is an oxyhydroxide of aluminum and other metals present in the aluminum-containing material, the oxyhydroxides including one or more of NaAl(OH)4, Al(OH)3, Mg(OH)2, Cu(OH)2, Na2Zn(OH)4.

11. 11. The process of claim 10, wherein the hydrothermal treatment comprises deionized water at 185-212 F (85-100 C) and a pH of 6.4 for 20-30 minutes.

12. 11. The process of claim 10, wherein the hydrothermal treatment comprises steam at 250-270 F (121-132 C) and 30-35 PSI for 50-60 minutes.

13. 11. The process of claim 10, further comprising painting and / or bonding the aluminum-containing material after the hydrothermal treatment.

Images