Combination of active ingredients having insecticidal, fungicidal and acaricidal properties
Patent Information
- Application Number
- JP2023132665
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Priority Date
- 2018-04-13
- Filing Date
- 2023-08-16
- Publication Date
- 2025-02-26
- Estimated Expiration
- 2039-04-12
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Figure 0007636484000001 
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Abstract
Description
[Technical field]
[0001] The present invention relates on the one hand to known compounds of formula (I) and on the other hand to further known nematicidal active ingredients and (b) controlling pests such as insects, nematodes and / or undesirable mites (animal pes The present invention relates to novel active ingredient combinations which have very good suitability for controlling .ts. [Background technology]
[0002] The compounds of formula (I) are disclosed in WO 200, where their use for controlling pests is described. However, the activity and / or activity spectrum of this compound is unknown. The suitability for bacteria and / or plants, especially crop plants, is not always adequate.
[0003] Mixtures of compounds of formula (I) with other insecticides and / or acaricides are also described, for example in WO200 It is known from US Pat. No. 5,995,131. [Prior art documents] [Patent documents]
[0004] [Patent Document 1] WO2006 / 089633 [Patent Document 2] WO2009 / 039951 Summary of the Invention [Means for solving the problem]
[0005] This time, at least one compound of formula (I): [ka]
[0006] [During the ceremony, W and Y are independently hydrogen, C1-C4-alkyl, chlorine, bromine, iodine or fluorine. and X is C1-C4-alkyl, C1-C4-alkoxy, chlorine, bromine or iodine , D is hydrogen or methyl; A, B and the carbon atom to which they are attached are C3-C6-cycloalkyl, where One ring member may be replaced by nitrogen and the ring is C1-C4-alkoxy. or A, B and the carbon atom to which they are attached are C1-C4-alkyl- or C1-C4 -Alkoxy-C1-C2-alkyl-substituted with optionally substituted alkylenedioxy groups The C3-C6-cycloalkyl (the alkylenedioxy group is together with the carbon atom forming a 5- or 6-membered ketal, G is hydrogen (a) or the group: [ka]
[0007] [During the ceremony, E is a metal ion or an ammonium ion; M is oxygen or sulfur; R 1 is linear or branched C1-C6-alkyl, R 2 is a straight-chain or branched C1-C6-alkyl. It is one of the Compound and (B-1): [ka] (known from WO2014 / 053450); (B-2) Thioxazafen: [ka] (known from WO2006 / 114400); (B-3) Fluensulfone: [ka] (known from WO2001 / 002378); (B-4) Fluazaindolizin: [ka] (Publicly known from WO2010 / 129500) (B-5) Fluopyram: [ka] (Publicly known from WO2004 / 016088) At least one further compound selected from The combination of active ingredients comprising It was found that.
[0008] A compound of formula (I) in which the groups are as defined below: W is preferably methyl; X is preferably chlorine or methyl, in particular methyl; Y is preferably chlorine, bromine or methyl; D is preferably hydrogen, A, B and the carbon atom to which they are attached are preferably substituted with an alkylenedioxy group. A saturated C6-cycloalkyl (the alkylenedioxy group is a C6-cycloalkyl group attached to the carbon atom to which it is attached) (which together with the atom form a 5- or 6-membered ketal) G is preferably hydrogen (A) or the group: [ka]
[0009] [During the ceremony, M is oxygen; E is one metal ion equivalent or an ammonium ion, especially sodium or potassium and R 1 is preferably linear or branched C1-C4-alkyl, R 2 is preferably linear or branched C1-C4-alkyl. It is one of the Preferred is a combination of active ingredients comprising:
[0010] Particularly preferred are compounds of formula (I) where G=hydrogen.
[0011] Very particular preference is given to combinations of active ingredients which comprise compounds of formula (I) in which the radicals are defined below. New: [ka] [Table 1]
[0012] Particularly preferred is the compound of formula (I-2): [ka]
[0013] Compound and At least one selected from (B-1), (B-2), (B-3), (B-4), and (B-5) Another compound It is a combination of active ingredients including:
[0014] Particularly preferred are compounds of formula (I-2) and At least one further compound selected from (B-1), (B-2) It is a combination of active ingredients including:
[0015] Emphasis is placed on the combination of active ingredients comprising the compound of formula (I-2) and the compound (B-1) .
[0016] Emphasis is placed on the combination of active ingredients comprising the compound of formula (I-2) and the compound (B-2) .
[0017] Emphasis is placed on the combination of active ingredients comprising the compound of formula (I-2) and the compound (B-3): .
[0018] Emphasis is placed on the combination of active ingredients comprising the compound of formula (I-2) and the compound (B-4): .
[0019] Emphasis is placed on the combination of active ingredients comprising the compound of formula (I-2) and the compound (B-5). .
[0020] Surprisingly, the insecticidal, nematicidal and / or daemonicidal activity of the active ingredient combinations according to the invention is The activity of the two active ingredients is significantly greater than the sum of the activities of the individual active ingredients. It's not just about adding effects.
[0021] The active ingredient combination of the present invention comprises a compound of formula (I) and a mixing partner (B-1), ( B-2), (B-3), (B-4), and (B-5), preferably in synergistically effective amounts. .
[0022] When the active ingredients are present in the active ingredient combination according to the invention in certain weight ratios, The synergistic effect is particularly pronounced. However, the weight ratio of the compounds in the active ingredient combination can vary within a relatively wide range. In general, the combinations of the present invention are I) and the mixed partners (B-1), (B-2), (B-3), (B-4), ( B-5) are preferably, particularly preferably and very particularly preferably selected from those specified in the table below. Mixture ratio: *The mixing ratio is based on weight ratio. This ratio is determined by the compound of formula (I): mixing partner (B-1) or a compound of formula (I): mixed partner (B-2), or a compound of formula (I): mixed partner ( B-3) or a compound of formula (I): This should be understood to mean the compound of the mixed partner (B-5). [Table 2]
[0023] Furthermore, the active ingredient combination may also have fungicidal, acaricidal, nematicidal and / or nematocidal activity. or may contain ingredients with added insecticidal activity.
[0024] In the context of the present invention, the term "active ingredient combination" refers to, for example, a single ready-to-use in the form of a mix, in a combination spray mixture consisting of separate formulations of the individual active ingredients , e.g. in a tank mix, or by continuous application of the individual active ingredients, e.g. for a suitable short period, e.g. In combination with the individual active ingredients, for example when applied consecutively within a few hours or days, Compounds with mixed partners (B-1), (B-2), (B-3), (B-4), (B-5 In a preferred embodiment, the active ingredient of formula (I) and the mixture The order of application of partners (B-1), (B-2), (B-3), (B-4), and (B-5) is , are not critical to the practice of the invention.
[0025] Methods and Uses The present invention further relates to a method for controlling pests, in which the method comprises the step of The active ingredient combination is applied to the pests and / or their habitat. In particular, in agriculture and forestry, and in the protection of materials, This is preferably achieved by a method for surgical or therapeutic treatment of the human or animal body. and excludes diagnostic methods performed on the human or animal body.
[0026] The present invention further relates to the activity of the compounds of the present invention as pesticides, in particular as crop protection agents. It also relates to the use of combinations of ingredients.
[0027] In the context of this application, the term "pesticides" is always used interchangeably with the term " The term "crop protection composition" also includes the term "crop protection composition".
[0028] The active ingredient combinations according to the invention are well tolerated by plants and have a desirable anti-warm-blooding effect on animals. If they exhibit toxicity and good environmental compatibility, they can withstand biotic and abiotic stressors. It is suitable for protecting plants and plant organs from loess factors and for increasing yields. It is suitable for improving the quality of crops and is also useful in agriculture, horticulture and forestry. Pests encountered in woodlands, gardens and leisure facilities, especially insects, arachnids and worms , in particular for controlling nematodes and mollusks.
[0029] The active ingredient combinations according to the invention can preferably be used as pesticides. They are effective against normally sensitive and resistant species and, moreover, all The pests are: The following can be mentioned: Pests of the Arthropoda phylum, in particular the Arachnida class, e.g. Acarus species Acarus spp., e.g. Acarus siro, Acarus Aceria kuko, Aceria sheldonii ldoni, Aculops spp., Aculus spp. us spp.), e.g. Aculus fockeui , Aculus schlechtendali, Ann Amblyomma spp., Amphitetranyx bienensi Amphitetranychus viennensis, Argus species gas spp., Boophilus spp., Brevipal Brevipalpus spp., e.g., Brevipalpus hoensis (Brevipalpus phoenicis), Bryobia graminoum (Bryo Bryobia graminum, Bryobia praetiosa iosa, Centruroides spp., Coriopsis Chorioptes spp., Dermanisus gallinae yssus gallinae), Dermatophagoides pteronyssinus (Derma tophagoides pteronyssinus, Dermatophagoides phagoides Dermatophagoides farinae, Dermatophagoides species ( Dermacentor spp., Eotetranych spp. us spp.), e.g., Eotetranychu s hicoriae), Epitrimerus pyri , Eutetranychus spp., e.g., Eutet Eutetranychus banksi, Eriophyes genus Eriophyes spp., e.g. Eriophyes pili es pyri), Glycyphagus domesticus (Glycyphagus dome sticus, Halotydeus destru ctor), Hemitarsonemus spp., e.g. For example, Hemitarsonemus latus (= Poly Polyphagotarsonemus latus ), Hyalomma spp., Ixodes spp. spp.), Latrodectus spp., Loxoskelet Loxosceles spp., Neutrombicula autumnalis utrombicula autumnalis, Nuphersa species spp.), Oligonychus spp., e.g. Oligonychus coffeae, Oligonychus coffeae Niferarum (Oligonychus coniferarum), Oligonychus i Oligonychus ilicis, Oligonychus indicus gonychus indicus, Oligonyx mangiferus chus mangiferus), Oligonychus platensis (Oligonychus mangiferus) us pratensis), Oligonychus punicae nicae), Oligonychus yothersi ), Ornithodorus spp., Ornithonisus spp. (Ornithonyssus spp.), Panonychus spp. spp.), e.g. Panonychus citri (=Me Metatetranychus citri, Panonic Panonychus ulmi (=Met atetranychus ulmi), Phyllocopterta oleivora ocoptruta oleivora), Platytetranyx multidigitalis (Pl atytetranychus multidigituli), Polyphagotarsonemu Polyphagotarsonemus latus, Psoroptis genus species (Psoroptes spp.), Rhipicephalus spp. spp.), Rhizoglyphus spp., Sarcoptes Sarcoptes spp., Scorpio maurus maurus, Steneotarsonemus sp. p.), Steneotarsonemus spi nki), Tarsonemus spp., e.g. Tarsonemus Tarsonemus confusus, Tarsonemus parizus (Tarsonemus pallidus), Tetranych us spp.), e.g. Tetranychus canadensis (Tetranychus c anadensis), Tetranychus cinnabarinus nnabarinus, Tetranychus tulkestani rkestani), Tetranychus urticae ae), Trombicula alfredduge si), Vaejovis spp., Basatethus lycopersici Vasates lycopersici); From the class Chilopoda, for example, the genus Geophilus spp.), Scutigera spp.; From the order Collembola or class of Collembola, for example, Onychiurus armatus; Sminturus viridis (Sminthurus viridis); From the class Diplopoda, for example, Blaniurus guttulatus ulus guttulatus); From the class Insecta, e.g., from the order Blattodea, e.g. , Blatta orientalis, Blatta a Blattella asahinai, Blattella germanica ttella germanica, Leucophaea maderae (Leucophae a maderae, Loboptera decipiens ens), Neostylopyga rhombifolia folia, Panchlora spp., Parcobratta spp. (Parcoblatta spp.), Periplaneta spp. spp.), e.g., Periplaneta americana (Periplaneta americana) cana), Periplaneta australasiae (Periplaneta australasiae) alasiae, Pycnoscelus surinamensis namensis), Supella longipalpa ; Coleoptera, e.g. Acalinma vitatum ymma vittatum, Acanthocerides obtectus elides obtectus), Adoretus spp. Aethina tumida, Agelastica arnii astica alni), Agrilus spp., e.g. Agrilus planipennis, Agrilus planipennis Coccolith (Agrilus coxalis), Agrilus bilineatus (Agri agrilus bilineatus, agrilus anxi us), Agriotes spp., e.g., Agriotes ri Agriotes linneatus, Agriotes manx riotes mancus), Alphitobius siaperinus (Alphitobi us diaperinus), Amphimaron solstitialis (Amphimal lon solstitialis), Anobium p punctatum unctatum, Anoplophora spp., e.g. , Anoplophora glabripennis s), Anthonomus spp., e.g., Anthonomus Anthonomus grandis, Anthronys species enus spp., Apion spp., Apogonia spp. ogonia spp., Atomaria spp., e.g. Atomaria linearis, Atagenus species tagenus spp.), Baris caerules cens), Bruchidius obtectus , Bruchus spp., e.g., Bruchus pisorum hus pisorum, Bruchus rufimanus us), Cassida spp., Ceratomycota trifulcata otoma trifurcata, Ceutorhynchus species us spp.), e.g. Ceutorrhynchus assimilis s assimilis), Ceutorhynchus quadridens (Ceutorrhync hus quadridens), Ceutorhynchus rapae us rapae), Chaetocnema spp., e.g. , Chaetocnema confinis, Chaetocnema Chaetocnema denticulata, Chaetocnema Chaetocnema ectypa, Cleonus menzicus Cleonus mendicus), Conoderus spp. ), Cosmopolites spp., e.g. Cosmopolites sordidus, Costerithra Costelytra zealandica, Ctenicella species nicera spp., Curculio spp., e.g. Curculio caryae, Curculio caryatripe Curculio caryatrypes, Curculio obtusus ulio obtusus), Curculio sayi, Cryptolestes ferrugineus ), Cryptolestes pusillus, Cryptorhynchus lapathi, Crypto Lynx mangiferae (Cryptorhynchus mangiferae), Cylindrocopturus spp., Cylindrocopterus Cylindrocopturus adspersu s), Cylindrocopturus furnisi issi), Dendroctonus spp., e.g. Dendroctonus ponderosae , Dermestes spp., Diabrotica spp. otica spp., e.g. Diabrotica balteata balteata), Diabrotica barberi ), Diabrotica undecimpunctata howardii (Diabrotica undecimpunctata howardii cimpunctata howardi), Diabrotica undecimpunctata Diabrotica undecimpunctata und ecimpunctata), Diabrotica virgifera virgifera (Diabr otica virgifera virgifera), diabrotica virgifera Zeae (Diabrotica virgifera zeae), Diabrotica spp. (Dichocrocis spp.), Dichocrocis armigera (Dicladis pa armigera), Diloboderus spp., Epicaerus spp., Epilachna spp. na spp., e.g., Epilachna borealis lis), Epilachna varivestis, Epitrix spp., e.g., Epitrix cucumeris ( Epitrix cucumeris, Epitrix fuscula (Epitrix f uscula), Epitrix hirtipennis Epitrix subcrinita, Epitrix subcrinita Epitrix tuberis, Faustinus species stinus spp.), Gibbium psylloi des), Gnathocerus cornutus, Hellula undalis, Heteronyx alatre eteronychus arator), Heteronyx s. pp.), Hylamorpha elegans, Hiro Hylotrupes bajulus, Hypera postica ( Hypera postica, Hypomeces squamosus quamosus), Hypothenemus spp., e.g. For example, Hypothenemus hampei, Hypothenemus Hypothenemus obscurus, Hypothenemus purpurea Hypothenemus pubescens, Lachnosterna consa Nguinea (Lachnosterna consanguinea), Rashidelma Lasioderma serricorne, Laticus oryzae Latheticus oryzae, Lathridius spp. pp.), Lema spp., Leptinotarsa decemlineata (Lep tinotarsa decemlineata, Leucoptera spp. era spp., e.g. Leucoptera cophaera ffeella), Limonius ectypus, Lissorhoptrus oryzophilus us), Listronotus spp. (= Hyperodes spp.) (Hyperodes spp.), Lixus spp., Ruperodes Luperodes spp., Luperomorpha xanthodera omorpha xanthodera), Lyctus spp. Megacyllene spp., e.g., Megacyllene robii Megacyllene robiniae, Megascelli species elis spp., Melanotus spp., e.g. Melanotus longulus oregonensis egonensis, Meligethes aeneus ), Melolontha spp., e.g. Melolontha meloro Melolontha melolontha, Migdolus species us spp.), Monochamus spp., Naupactus Naupactus xanthographus, Necrobia Necrobia spp., Neogalerucel la spp.), Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus Oryzaephilus surinamensis, Oryzaephilus surinamensis Oryzaphagus oryzae, Othiorhynchus species tiorhynchus spp., e.g., Ot iorhynchus cribricollis), Othiorhynchus ligusticii (O tiorhynchus ligustici, Otio rhynchus ovatus), Otiorhynchus rugosostialus hynchus rugosostriarus, Othiorhynchus sulcatus iorhynchus sulcatus), Oulema spp. For example, Oulema melanopus, Oulema o Oulema oryzae, Oxycetonia jukunda nia jucunda, Phaedon cochleareae eariae, Phyllophaga spp., Phyllophaga Phyllophaga helleri, Phyllotoreta species lotreta spp., e.g., Phyllotreta armorasiae (Phyllot reta armoraciae, Phyllotreta pusilla pusilla), Phyllotreta ramosa, Phyllotreta striolata, Popiri Popillia japonica, Premnotrypes spp. emnotrypes spp.), Prostephanus toruncatus hanus truncatus), Psylliodes spp. .), e.g., Psylliodes affinis, Psylliodes chrysocephala , Psylliodes punctulata, Petite Ptinus spp., Rhizobius ventralis ventralis, Rhizopertha domini ca), Rhynchophorus spp., Rhynchophorus· Rhynchophorus ferrugineus, Rhynchophor Rhynchophorus palmarum, Scolytus species (Scolytus spp.), e.g., Scolytus multistriatus (Sc olytus multistriatus), Sinoxylon perforans (Sino xylon perforans, Sitophilus spp. .), e.g., Sitophilus granariu s), Sitophilus linearis, Sitophilus linearis Sitophilus oryzae, Sitophilus zeamais (Sitophilus zeamais), Sphenophorus species rus spp.), Stegobium paniceum (Stegobium paniceu m), Sternechus spp., e.g., Sternechus Sternechus paludatus, Syphilethes species mphyletes spp., Tanymecus spp., For example, Tanymecus dilaticollis , Tanymecus indicus, Tanymecus paris Tanymecus palliatus, Tenebrio molitor brio molitor, Tenebrioides mauretanicus (Tenebrioides des mauretanicus, Tribolium spp. .), e.g. Tribolium audax, Tribo Tribolium castaneum, Tribolium co Tribolium confusum, Trogoderma species erma spp., Tychius spp., Xylotrex spp. Xylotrechus spp., Zabrus spp., For example, Zabrus tenebrioides; For example, Anithorabis marichime (Ani solabis maritime), Forficula auricularia la auricularia, Labidura riparia ia); From the order Diptera, for example, Aedes spp., e.g. Aedes aegypti, Aedes albopictus (Aedes albopictus), Aedes sti cticus, Aedes vexans, Agromyza spp. (Agromyza spp.), e.g. Agromyza frontera (Agromyza frontella), Agromyza parvicornis cornis, Anastrepha spp., Anopheles Anopheles spp., e.g. Anopheles quadrimaculatus (Anopheles quadrimaculatus), Anopheles gumbiae (Anopheles gambiae), Asphondylia species a spp.), Bactrocera spp., e.g. Bactrocera cucurbitae, Bactrocera La dorsalis (Bactrocera dorsalis), Bactrocera oleae (Bactrocera oleae), Bibio hort ulanus), Calliphora erythrocephala cephala), Calliphora vicina, Serratia Ceratitis capitata, Chironomus species onomus spp., Chrysomya spp., Chrysomya Chrysops spp., Chrysozona pluvialis ona pluvialis, Cochliomya spp. , Contarinia spp., e.g., Contarinia jo Contarinia johnsoni, Contarinia nasturtii ontarinia nasturtii, Contari nia pyrivora), Contarinia scruzi ulzi), Contarinia sorghicola ), Contarinia tritici, Cordylobia Cordylobia anthropophaga, Klicot Cricotopus sylvestris, Cricotopus species (Culex spp.), e.g., Culex pipiens Culex quinquefasciatus us), Culicoides spp., Culicateta spp. iseta spp., Cuterebra spp., Dacus spp. Dacus oleae, Dasineura spp. ), e.g., Dasineura brassicae, Delia spp., e.g. Delia antqua iqua), Delia coarctata, Delia flora Delia florilega, Delia plattura ura), Delia radicum, Dermatobia hominis (Dermatobia hominis), Drosophila species spp.), e.g. Drosophila melanogaster (Drosphila mela nogaster, Drosophila suzukii ), Echinocnemus spp., Eureia hercules Ray (Euleia heraclei), Fannia spp. , Gasterophilus spp., Glossina spp. Glossina spp., Haematopota spp. ), Hydrellia spp., Hydrellia griseola drellia griseola, Hylemya spp., Hippobosca spp., Hypoderma spp. ma spp.), Liriomyza spp., e.g. Liriomyza brassicae, Liriomyza phidoides Liriomyza huidobrensis, Liriomyza sativae ( Liriomyza sativae), Lucilia spp., For example, Lucilia cuprina, Lutzomyia spp. Lutzomyia spp., Mansonia spp., Musca spp., e.g. Musca domestica estica), Musca domestica vi cina), Oestrus spp., Oscinella fritillaria cinella frit, Paratanytarsus species spp.), Paralauterborniella subsincta (Paralauterborni Pegomya or ella subcincta, Pegomya or Pegomia species Pegomyia spp., e.g. Pegomyia bet ae), Pegomya hyoscyami, Pegomya r Pegomya rubivora, Phlebotom species us spp., Phorbia spp., Pho rmia spp., Piophila casei, Platycodon spp. Platyparea poeciloptera, project Prodiplosis spp., Psila rosae osae), Rhagoletis spp., e.g. Rhagoletis cingulata, Rhagoletis completa (Rhagoletis completa), Rhagoletis fausta (Rhagol etis fausta), Rhagoletis inferens ndifferens, Rhagoletis menda x), Rhagoletis pomonella, Sarcov Sarcophaga spp., Simulium spp. pp.), e.g., Simulium meridiona le), Stomoxys spp., Tabanus spp. spp.), Tetanops spp., Tipra spp. pula spp., e.g. Tipula paludosa , Tipula simplex, Toxotrypana curvica Uda (Toxotrypana curvicauda); Hemiptera, e.g., Assisia acacia ebayeianae (Acizzia acaciaebaileyanae), Acizzia dodonaeae ( Acizzia dodonaeae, Acizzia uncatatoides (Acizzia uncatoides, Acrida turrita, Acyl Acyrthosiphon spp., e.g. Acyrthosiphon pi Acyrthosiphon pisum, Acrogonia species ia spp.), Aeneolamia spp., Agonose Agnoscena spp., Aleurocanthus spp. nthus spp., Aleyrodes prole tella), Aleurolobus barodensis nsis), Aleurothrix flocc osus), Allocaridara malayensis nsis), Amrasca spp., e.g. Amrasca vigneronii Amrasca bigutulla, Amrasca devastans ca devastans, Anuraphis cardzii ui), Aonidiella spp., e.g. iella aurantii), (Aonidiella citrina), Aonidiella citrina Aonidiella inornata, Aphanostigma Aphanostigma piri, Aphis spp. For example, Aphis citricola, Aphis clavata Cibola (Aphis craccivora), Aphis fabae (Aphis fa bae), Aphis forbesi, Aphis glycines (Aphis glycines), Aphis gossypii i), Aphis hederae, Aphis illinoisense Aphis illinoisensis, Aphis midretoni middletoni), Aphis nasturtii , Aphis nerii, Aphis pomi i), Aphis spiraecola, Aphis bib Luniphila (Aphis viburniphila), Arborizia apicalis (A rboridia apicalis, Arytainilla species spp.), Aspidiella spp., Aspidiola spp. Species (Aspidiotus spp.), e.g. Aspidiotus nerii (Aspid iotus nerii), Atanus spp., Auracortum Aulacorthum solani, Bemisia tabaci a tabaci, Blastopsylla occidentalis occidentalis), Boreioglicaspis melaleucae (Boreioglicaspis melaleucae) ycaspis melaleucae, Brachycauzus heliclysi caudus helichrysi, Brachycolus spp.), Brevicoryne brassicae ), Cacopsylla spp., e.g., Cacopsylla pyriko Cacopsylla pyricola, Calligipona marginata gypona marginata), Capulinia spp. ), Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae (Cercopidae), Ceroplastes spp. , Chaetosiphon fragaefolii ), Chionaspis tegalensis, Chlorita onukii, Chondraclys rosea ondracris rosea, Chromaphis juglandicola his juglandicola, Chrysomphalus aonismus phalus aonidum, Chrysomphalus ficus lus ficus), Cicadulina mbila, Coccomytilus halli, Coccomytilus spp. ccus spp., e.g. Coccus hesper idum), Cox's longulus, Cox's Coccus pseudomagnoliarum, Cock Coccus viridis, Cryptomyzus ribis omyzus ribis, Cryptoneossa spp. .), Ctenarytaina spp., Dalbrus spp. Dalbulus spp., Dialeurodes kitendeni chittendeni, Dialeurodes citri tri), Diaphorina citri, Diaspis spp. (Diaspis spp.), Diuraphis spp., Doralis spp., Drosicha spp. .), Dysaphis spp., e.g. Dysaphis apiho Dysaphis apiifolia, Dysaphis plantaginea aphis plantaginea, Dysaphis t ulipae, Dysmicoccus spp., Empoa Empoasca spp., e.g. Empoasca abulputa oasca abrupta, Empoasca fabae e), Empoasca maligna, Empoasca Empoasca solana, Empoasca stebensis ca stevensi), Eriosoma spp., e.g. Eriosoma americanum, Eriosoma Eriosoma lanigerum, Eriosoma pyricola osoma pyricola, Erythroneura spp. pp.), Eucalyptolyma spp., Euphyon Euphyllura spp., Euscelis bilobatus is bilobatus, Ferrisia spp., Fiorella Fiorinia spp., Furcas oceanica pis oceanica, Geococcus cofeae feae), Glycaspis spp., Heteropsilla cuba Heteropsylla cubana, Heteropsylla spinulosa ropsylla spinulosa, Homalod isca coagulata, Hyalopterus alundinis (Hyalopter us arundinis), Hyalopterus pruni uni), Icerya spp., e.g., Icerya purcasi cerya purchasi), Idiocerus spp. , Idioscopus spp., Laodelphacis striatus Laodelphax striatellus, Lecanium species anium spp., e.g., Lecanium corni )(=Parthenolecanium corni) ), Lepidosaphes spp., e.g. Lepidosaphes ulmi, Lipaphis elisimi aphis erysimi, Loholeuca japonica spis japonica), Lycorma delica tula), Macrosiphum spp., e.g. Macrosiphum euphorbiae, Macrosiphum euphorbiae Macrosiphum lilii, Macrosiphum rosae rosiphum rosae, Macrosteles fasciifrons les facifrons, Mahanarva spp., Me Melanaphis sacchari, Metcalfiella Metcalfiella spp., Metcalfa pruinosa lfa pruinosa, Metopolophium gyrosum m dirhodum), Monellia costalis ), Monelliopsis pecanis, Mizusu Myzus spp., e.g. Myzus ascalonyx alonicus), Myzus cerasi, Myzus ligusto Myzus ligustri, Myzus ornatus s), Myzus persicae, Myzus nicotianae Myzus nicotianae, Nasonovia libisnigri ribisnigri), Neomaskellia spp. ), Nephotettix spp., e.g. Nephotettix cincticeps, Nephotettix Nephotettix nigropictus, Nephotettix nigropictus Nettigoniclla spectra, Nilaparvata rhubarb Nilaparvata lugens, Oncometopia species opia spp., Orthezia praelon ga), Oxya chinensis, Pachypsilla spp. achypsylla spp., Parabemisia myricae myricae, Paratrioza spp., e.g. Paratrioza cockerelli, Parlato Parlatoria spp., Pemphigus spp. spp., e.g., Pemphigus bursa rius), Pemphigus populivenae e), Peregrinus maidis, Perkinsia Perkinsiella spp., Phenacox spp. ccus spp., e.g., Phenacoccus madeirensis (Phenacocc u s madeirensis), Proeomyzus passerinii (Phloeomyzu s passerinii), Phorodon humuli, Phylloxera spp., e.g. Phylloxera devus Phylloxera devastatrix, Phylloxera nota Billis (Phylloxera notabilis), Pinnaspis aspidistra Pinnaspis aspidistrae, Planococcus species coccus spp., e.g. Planococcus citri citri), Prosopidopsylla flava va), Protopulvinaria pyriformis iformis, Pseudaulacaspi s pentagona, Pseudococcus spp. .), e.g., Pseudococcus calceolariae (Pseudococcus ca lceolariae, Pseudococcus comstocki), Pseudococcus longispinus (Pseudococcus s longispinus, Pseudococc maritimus us maritimus, Pseudococcus viburni viburni), Psyllopsis spp., Psyllopsis spp. Species (Psylla spp.), e.g. Psylla buxi, Psylla mali, Psylla pyri, Pteromalus spp., Pulvinaria spp. naria spp., Pyrilla spp., Quadraspidio Quadraspidiotus spp., e.g. Quadraspidiotus Quadraspidiotus juglansregi ae), Quadraspidiotu ostraeaeformis s ostreaeformis), Quadraspiziotus perniciosus (Quad raspidiotus perniciosus, Quesada gigas gigas), Rastrococcus spp., Rhopalosiphum spp., e.g., Rhopalosiphum ma Rhopalosiphum maidis, Rhopalosiphum oxyacantha Rhopalosiphum oxyacanthae, Rhopalosiphum··paji( Rhopalosiphum padi, Rhopalosiphum rufiabdominale (Rho palosiphum rufiabdominale), Saissetia sp. etia spp., e.g. Saissetia cofeae feae), Saissetia miranda, Saissetia Saissetia neglecta, Saissetia oleae (S aissetia oleae), Scaphoideus titanus titanus, Schizaphis graminum um), Selenaspidus articulatus atus), Sipha flava, Sitobion avenae tobion avenae), Sogata spp., Sogatela f. Sogatella furcifera, Sogatella species odes spp.), Stictocephala festinae festina, Siphoninus phillyrae eae), Tenalapha malayens is), Tetragonocephala spp., Tinocallis caryaefoliae, T Tomaspis spp., Toxoptera spp. spp., e.g. Toxoptera aurantii tii), Toxoptera citricidus , Trialeurodes vaporariorum rum), Trioza spp., e.g. Trioza geospiri ( Trioza diospyri), Typhlocyba spp. ), Unaspis spp., Viteus vitis horii s vitifolii), Zygina spp.; For example, Aelia spp. pp.), Anasa tristis, Anthethiopsis spp. species (Antestiopsis spp.), Boisea spp. , Blissus spp., Calocoris spp. spp.), Campylomma livida, Caveleri Cavelerius spp., Cimex spp. For example, Cimex adjunctus, Cimex Cimex hemipterus, Cimex rectularius imex lectularius, Cimex pilos ellus, Collaria spp., Creonthiades jillus Creontiades dilutus, Dasynu piperis s piperis), Dichelops furcatus s), Diconocoris hewetti, Dist. Dysdercus spp., Euschistus spp. us spp.), e.g., Euschistus herous s), Euschistus servus, Euschistus Euschistus tristigmus, Euschistus Euschistus variolarius, Eurydema genus Eurydema spp., Eurygaster sp. p.), Halyomorpha halys, Heliopal Heliopeltis spp., Horcius nobilis as nobilellus), Leptocorisa spp. ), Leptocorisa varicornis, Leptoglossus occidentalis is), Leptoglossus phyllopus ), Lygocoris spp., e.g., Lygocoris publignus Lygocoris pabulinus, Lygus spp. For example, Lygus elisus, Lygus hesperus gus hesperus, Lygus lineolari s), Macropes excavatus, Megaco Megacopta cribraria, Miridae dae), Monalonion atratum, Neza Nezara spp., e.g., Nezara virizura idula, Nysius spp., Oebalus spp. us spp.), Pentomidae, Piesma quadrata (P iesma quadrata), Piezodorus spp. ), e.g., Piezodorus guildinii ), Psallus spp., Pseu dacysta persea, Rhodnius spp., Sahlbergella singularis, S Scaptocoris castanea, Scotchinoho Scotinophora spp., Stepha nitis nashi), Tibraca spp., Triatoma spp. Species (Triatoma spp.); From the order Hymenoptera, for example, Acromyrmekis species rmex spp.), Athalia spp., e.g. Athalia rosae, Atta spp., Campo Camponotus spp., Dolichovespra spp. vespula spp., Diprion spp., e.g. Diprion similis, Hopplocampa species locampa spp., e.g., Hoplocampa cookei), Hoplocampa testud inea), Lasius spp., Linepithema (Iridiomyrmex Linepithema (Iridiomyrmex) humile , Monomorium pharaonis, Parato Paratrechina spp., Paravespra spp. spula spp.), Plagiolepis spp., Sirex spp., e.g. Sirex noctilia noctilio, Solenopsis invicta a), Tapinoma spp., Technomyrmecides albipes ( Technomyrmex albipes, Urocerus spp. pp.), Vespa spp., e.g. Vespa clavulo a crabro), Wasmannia auropunctata punctata), Xeris spp.; Isopoda, e.g. Armadillidium vulgare dillidium vulgare, Oniscus asellus ellus), Porcellio scaber; From the order Isoptera, for example, Coptotermes species mes spp., e.g., Coptotermes formosanus formosanus, Cornitermes cumulans umulans, Cryptotermes spp., Incisitermes spp., Ka lotermes spp., Microtermes ovesi besi), Nasutitermis spp., Odontothe Odontotermes spp., Porotetermes spp. rmes spp., Reticulitermes spp. .), for example, Reticulitermes flavipes vipes, Reticulitermes hes perus); From the order Lepidoptera, for example, Achro ia grisella), Acronicta major ), Adoxophyes spp., e.g. Adoxophyes orana, Aed ia leucomelas), Agrotis spp., e.g. , Agrotis segetum, Agrotis epsilon (Agrotis ipsilon), Alabama spp., e.g. For example, Alabama argillacea, Amieloi Amyelois transitella, Anarsia spp. narsia spp., Anticarsia spp., For example, Anticarsia gemmatalis ), Argyroploce spp., Autographa spp. Autographa spp.), Barathra brassicae (Barathra bra ssicae), Blastodacna atra, Bol Borbo cinnara, Bu latrix tulberiiera cculatrix thurberiella, Bupa piniarius lus piniarius, Busseola spp., Cacoecia spp., Caloptilia teivora lia theivora), Capua reticulana ), Carpocapsa pomonella, Carposi Carposina niponensis, Carposina niponensis Cheimatobia brumata, Chilo spp. For example, Chilo plejadellus, Chilo sp. Chilo suppressalis, Coleucis pariana reutis pariana), Choristoneura sp. spp.), Chrysodeixis chalcites es), Clysia ambiguella, Cunafarro Cnaphalocerus spp., Cnaphalocerus medinarii Cnaphalocrocis medinalis, Cnephasia species phasia spp., Conopomorpha spp. ), Conotrachelus spp., Copitarsia spp. (Copitarsia spp.), Cydia spp., e.g. Cydia nigricana, Cydia pomonella a pomonella, Dalaca noctuides ), Diaphania spp., Diapalopsis spp. ropsis spp.), Diatraea saccharalis haralis), Dioryctria spp., Dioryctria Dioryctria zimmermani, Aeriaceae Earias spp., Ecdytropha aurantium (Ecdytolop ha aurantium, Elasmopalpus lignocellus us lignosellus), Eldana saccha rina), Ephestia spp., e.g. Ephestia elutella, Ephestia queniella phestia kuehniella), Epinotia spp. .), Epiphyas postvittana, Erannis spp., Erscoviella musculana hoviella musculana), Etiella spp. , Eudocima spp., Eulia spp. .), Eupoecilia ambiguella , Euproctis spp., e.g., Euproctis cruzi Euproctis chrysorrhoea, Euproctis species xoa spp., Feltia spp., Galleria mellonella (Galleria mellonella), Gracilaria species ia spp., Grapholitha spp., e.g. Grapholita molesta, Grapholita purnibo Grapholita prunivora, Hedylepta species a spp.), Helicoverpa spp., e.g. Helicoverpa armigera, Helicoverpa Helicoverpa zea, Heliothis spp. pp.), e.g., Heliothis virescens ), Hofmannophila pseudospreterella ospretella, Homoeosoma spp., Homo Homona spp., Hyponomeuta padera padella, Kakivoria flavofacciata asciata), Lampides spp., Rafigma spp. Laphygma spp., Laspeyresia molesta molesta, Leucinodes orbonalis lis), Leucoptera spp., e.g. Leucoptera coffeella, Litocoretis species (L ithocolletis spp.), e.g., Lithocolletis brancaldera (Li thocolletis blancardella), Lithophane antenata (L ithophane antennata), Lobesia spp. ), e.g., Lobesia botrana, Loxaglotis Loxagrotis albicosta, Lymantria spp. ymantria spp., e.g. Lymantria dispar dispar), Lyonetia spp., e.g. Lyonetia clerkella, Malacosoma neustria (Malacosoma neustria), Maruca testularis (Maruca testulalis, Mamestra brassicae ae), Melanitis leda, Mocis spp. spp.), Monopis obviella, Michimna Mythimna separata, Nemapogon croacerus mapogon cloacellus), Nymphula spp. ), Oiketicus spp., Omphisa spp. sa spp.), Operophtera spp., Orya spp. Oria spp., Orthaga spp., Ostrinia Ostrinia spp., e.g. Ostrinia nubilalis nia nubilalis, Panolis flammea a), Parnara spp., Pectinophora spp. phora spp., e.g. Pectinophora gossipiera gossypiella, Perileucopter species a spp.), Phthorimaea spp., e.g. Phthorimaea operculella, Filipina Phyllocnistis citrella, Phyllocnistis Phyllonorycter spp., e.g., Phyllonorycter Blancardella (Phyllonorycter blancardella), Phyllonorycter crataegella ), Pieris spp., e.g., Pieris rapae s rapae), Platynota stultana , Plodia interpunctella, Plusia spp., Plutella xylostella xylostella (=Plutella macul ipennis), Podesia spp., e.g. Podesia Podesia syringae, Prays spp. .), Prodenia spp., Protoparce spp. parce spp., Pseudaletia spp., For example, Pseudaletia unipuncta ), Pseudoplusia includens s), Pyrausta nubilalis, Lakkiprushi Rachiplusia nu, Schoenobius species spp.), e.g., Schoenobius bipunctiferus bipunctifer), Scirpophaga spp. For example, Scirpophaga innotata, Scotia segetum, Sesamia species spp., e.g., Sesamia inferens ), Sparganothis spp., Spodoptera spp. Spodoptera spp., e.g. Spodoptera ellagiana (Spodoptera tera eradiana), Spodoptera exigua (Spodoptera xigua), Spodoptera frugiperda da), Spodoptera praefica, Stathmopoda spp., Stenoma spp. spp.), Stomopteryx subsexibera civella, Synanthedon spp., Thessia Tecia solanivora, Thaumetopoeia species topoea spp.), Thermesia gemmatalis (Thermesia gemmatalis) atalis), Tinea cloacella, Tinea pet Tinea pellionella, Tineola biselliera ola bisselliella), Tortrix spp. , Trichophaga tapetzella, Trichophaga Trichoplusia spp., e.g., Trichoplusia ni ( Trichoplusia ni), Tryporyza inselturus incertulas), Tuta absoluta, Viraco Virachola spp.; Orthoptera or Saltatoria, for example Acheta Acheta domesticus, Dichlopulus species roplus spp., Gryllotalpa spp., For example, Gryllotalpa gryllotalpa a), Hieroglyphus spp., L ocusta spp., e.g. Locusta migratoria ratoria, Melanoplus spp., e.g. Melanoplus devastator, Paratra Paratlanticus ussuriensis, Schistocerca gregaria; From the order Phthiraptera, for example, Damalinia species ia spp.), Haematopinus spp., Rhino Linognathus spp., Pedicul us spp.), Phylloxera vasta trix), Phthirus pubis, Trichodectes spp. (Trichodectes spp.); From the order Psocoptera, for example, Lepinothus species tus spp.), Liposcelis spp.; From the order Siphonaptera, for example, Ceratophyllus species phyllus spp., Ctenocephalides spp. spp.), e.g., Ctenocephalides canis s canis, Ctenocephalides felis felis, Pulex irritans, Tunga pene Tunga penetrans, Xenops ylla cheopis); Thysanoptera, e.g. Anaphotryps obscurus Anaphothrips obscurus, Variothrips biformis (B aliothrips biformis, Caetanahotryps leuweni (Ch aetanaphothrips leeuweni), Drepanothrips leeuweni ( Drepanothrips reuteri, Enneothrips flavens neothrips flavens, Frankliniella species lla spp., e.g., Frankliniella fusca fusca), Frankliniella occidentalis (Frankliniella occidentalis), Frankliniella sculltsei (Franklinie Frankliniella schultzei, Frankliniella tritisi la tritici, Frankliniella bassinii vaccinii), Frankliniella williamsii (Frankliniella williamsi), Haplothrips spp., He Heliothrips spp., Heliothrips femora Squirrel (Hercinothrips femoralis), Kakothrips species othrips spp.), Rhipiphorothrips cruentatus othrips cruentatus, Scirtothri ps spp.), Taeniothrips cardamom damomi), Thrips spp., e.g., Thrips palmi (Thrips palmi), Thrips tabaci; Zygentoma (=Thysanura), e.g., Ctenolepisma Genus species (Ctenolepisma spp.), Lepisma saccharina (Lepisma saccharina, Lepismodes inquilinus nquilinus, Thermobia domestica ca); From the class Symphyla, for example, Scutigere species lla spp., e.g., Scutigerella immaculata immaculata); Pests of the phylum Mollusca, e.g. Bivalvia For example, Dreissena spp.; and also For example, Arion spp. .), e.g., Arion ater rufus, Bio Biomphalaria spp., Bulinus spp. us spp.), Deroceras spp., e.g. Deroceras laeve, Galba spp. ), Lymnaea spp., Oncomelania spp. lania spp., Pomacea spp., Succinea spp. (Succinea spp.); Plant pests of the phylum Nematoda (i.e., plant parasitic nematodes), in particular aggrecanidae Aglenchus spp., e.g. Aglenchus agricola (A glenchus agricola), Anguina spp. For example, Anguina tritici, Aferenkoi Aphelenchoides spp., e.g., Aphelenchoides Aphelenchoides arachidis, Aphelenchoides Aphelenchoides fragariae, Veronolliidae Mus spp. (Belonolaimus spp.), e.g. Belonolaimus gracilis Belonolaimus gracilis, Belonolaimus longicausatus Belonolaimus longicaudatus, Belonolaimus norvegicus Toni (Belonolaimus nortoni), Bursaphelenchus species (Bursaphelenchus species) saphelenchus spp.), e.g., Bursaphelenchus coccophyllus ( Bursaphelenchus cocophilus, Bursaphelenchus elegans Mus (Bursaphelenchus eremus), Bursaphelenchus sukiro Bursaphelenchus xylophilus, Cacopaurus genus Cacopaurus spp., e.g. Cacopaurus pestis aurus pestis), Criconemella spp. ), for example, Criconemella curvata, Criconemella onoensis, Crico Nemella ornata (Criconemella ornata), Criconemella lucius Criconemella rusium, Criconemella xenoplakis iconemella xenoplax (= Mesocriconema xenoplax (Me socriconema xenoplax), Cricon emoides spp., e.g. Cricon emoides ferniae emoides ferniae, Criconemoides onoense oides onoense, Criconemoides ornatum des ornatum), Ditylenchus spp. For example, Ditylenchus dipsaci, Dolicho Dolichodorus spp., Globodera spp. ra spp., e.g. Globodera pallida ), Globodera rostochiensis ), Helicotylenchus spp., e.g. Helicotylenchus dihystera , Hemicriconemoides spp., Hemi Hemicycliophora spp., Heterodera spp. eterodera spp., e.g. Heterodera avenae avenae), Heterodera glycine s), Heterodera schachtii, Hills Hirschmaniella spp., Hoplolimus spp. oplolaimus spp., Longidorus spp. .), e.g., Longidorus africanu s), Meloidogyne spp., e.g. Meloidogyne Meloidogyne chitwoodi, Meloidogyne phala Rachis (Meloidogyne fallax), Meloidogyne hapura (Meloi dogyne hapla, Meloidogyne incognita incognita, Meloinema spp., Nacob Nacobbus spp., Neotylenchus spp. spp.), Paralongidorus spp., Paraphelenchus spp., Paratrichodorus spp. Species (Paratrichodorus spp.), e.g. Paratrichodorus minor (Paratrichodorus minor), Paratylenchus species (Paraty lenchus spp., Pratylenchus spp. .), e.g., Pratylenchus penetrance (Pratylenchus penetrance) rans), Pseudohalenchus spp., Psilenchus spp., Punct odera spp., Quinisulcius spp. ), Radopholus spp., e.g., Radopholus citro Radopholus citrophilus, Radopholus similis ( Radopholus similis), Rotylenchu spp. lus spp., Rotylenchus spp., Scutellaria Scutellonema spp., Subanguina spp. uina spp., Trichodorus spp., e.g. For example, Trichodorus obtusus, Trichodorus Trichodorus primitivus, Chilencorhynchus Tylenchorhynchus spp., e.g. Tylenchorhynchus Tylenchorhynchus annulatus, Chilenk Tylenchulus spp., e.g., Tylenchulus semipenaetra lance (Tylenchulus semipenetrans), Xiphinema spp. (X iphinema spp., e.g., Xiphinema index (Xiphinema a index).
[0030] Nematodes In the context of the present invention, the term "nematodes" includes all species of the phylum Nematoda, where in particular They act as parasites on plants or fungi or live inside or on these organisms. Species that cause damage on the surface (e.g., Aphelenchida ), Meloidogyne, Tylenchida ), or act as or are parasites to humans and animals. species that cause damage inside or on the surface of these organisms (e.g., Trichinellidae) chinellida, Tylenchida, Rh abdititina and Spirurida. It also includes other parasitic helminths.
[0031] Nematicides in crop protection, as described herein, are compounds that control nematodes. It is possible.
[0032] The expression "controlling nematodes" refers to the is meant to kill nematodes or to hinder or retard the development or growth of nematodes. or the penetration of nematodes into or out of plant tissue. It means to prevent or retard the absorption of juice.
[0033] The efficacy of the compound is determined by the amount of the active ingredient of the present invention that is applied to the plant or part of the plant. or treated soil and untreated plants or plant parts or untreated In soil (100%), the mortality rate of nematodes, the formation of galls, the formation of cysts, and the unit volume of soil Nematode density per root, nematode density per root, nematode eggs per unit volume of soil The number of nematodes and the motility of the nematodes are compared to confirm the presence or absence of the nematodes. 25-50% lower than untreated plants, plant parts or untreated soil A reduction of 51-79% is achieved, more preferably a reduction of 51-79% is achieved, and most preferably It is possible to completely kill insects or completely prevent (reduce by 80% to 100%) the development and growth of nematodes. The "control of nematodes" described herein refers to the suppression of nematode proliferation (cysts and Furthermore, the present invention also means to control the development of insect pests (e.g., larvae and / or eggs). It can also be used to maintain the health of plants or animals, and It may also be used therapeutically, prophylactically or systemically to control insects.
[0034] Those skilled in the art will appreciate that nematode mortality, gall formation, cyst formation, nematode count per unit volume of soil, Nematode density, nematode density per root, number of nematode eggs per unit volume of soil, nematode Know how to check for motility.
[0035] By using the active ingredient combination of the present invention, it is possible to maintain plants in a healthy state. The use of the active ingredient combination of the present invention is also effective in preventing damage caused by nematodes. This also includes reducing the amount of fertilizer and increasing the yield.
[0036] In the context of the present invention, the term "nematodes" includes all nematodes that cause damage to plants. The plant nematodes include plant parasitic nematodes and soil-borne nematodes. Plant parasitic nematodes include: ectoparasites , for example, Xiphinema spp., Longidorus spp. ongidorus spp. and Trichodorus sp. p.);hemiparasites, e.g., Tylenchulus spp.; Migratory endoparasites, e.g., Platycodon Pratylenchus spp., Radoph olus spp. and Scutellonema spp.; Non-migratory parasites, e.g., Heterodera Heterodera spp., Globodera spp. pp.) and Meloidogyne spp.; and, further Stem and leaf endoparasites, e.g., Ditylenchus spp. , Aphelenchoides spp. and Hirschma Hirschmaniella spp., particularly harmful root-parasitic soil nematodes The genus Heterodera or Globodera is, for example, odera and / or Meloidogyne Harmful species of these genera are, for example: : Meloidogyne incognita, Hete Rodella glycines (Heterodera glycines) (Soybean cyst centrifugal forceps) Globodera pallida and Globodera Globodera rostochiensis (potato These species are effectively controlled with the compounds described herein. However, the use of the compounds described herein is by no means intended to The term is not limited to these genera or species, and extends to other nematodes as well.
[0037] Plant nematodes include, for example: Agrencus aureus Aglicola (Aglenchus agricola), Anguina tritici (Angu ina tritici, Aphelenchoides arachis des arachidis), Aphelenchoides fragaria (Aphelench oides fragaria), and stem and leaf endoparasites, Aphelenchoides spp. species (Aphelenchoides spp.), Belonoraimus gracilis (Bel onolaimus gracilis), Belonoraimus longicaudatus (Bel onolaimus longicaudatus, Belonoraimus nortonii (Be lonolaimus nortoni, Bursaphelenchus coccophyllus saphelenchus cocophilus), Bursaphelenchus eremus ( Bursaphelenchus eremus, Bursaphelenchus xylophilus Bursaphelenchus xylophilus and Bursaphelenchus Bursaphelenchus spp., Cacopaulus pestis (C acopaurus pestis), Criconemella curvata la curvata), Criconemella onoensis noensis, Criconemella ornata ), Criconemella rusium, Criconemella Criconemella xenoplax (= Mesocricone Mesocriconema xenoplax, and Criconemella spp., Criconemoides ferniae, Criconemoides onoense, Criconemoides onoense Criconemoides ornatum and Criconemoides spp., Dithyleneguin Desto Ditylenchus destructor, Ditylenchus gypsophila (Ditylenchus dipsaci), Ditylenchus myceliofagus (Di tylenchus myceliophagus), and stem and leaf endoparasites, Ditylenchus spp., Dolichodorus heterocephala Dolichodorus heterocephalus, Globodera pallida (Globodera pallida) (= Heterodera pallida) a pallida), Globodera rostochiensis tochiensis) (Potato cyst nematode), Globodera solanacearum (Globodera solanacearum), Globodera tabacum (Glob odera tabacum, Globodera virginia ginia, as well as the non-motile cyst-forming parasite, Globodera spp. ra spp.), Helicotylenchus zygonyx digonicus, Helicotylenchu dihystera s dihystera), Helicotylencus erythrina (Helicotylencus hus erythrine), Helicothyrencus multicinctus (Helicot ylenchus multicinctus, Helicochilenchus nannus icotylenchus nannus), Helicotylenchus pseudorobustus ( Helicotylenchus pseudorobustus) and Helicotylenchus Helicotylenchus spp., Hemicriconemoides emicriconemoides, Hemicyc liophora arenaria), Hemicycliophora nudata iophora nudata, Hemicycliophora parbana phora parvana, Heterodera avenae nae), Heterodera cruciferae ), Heterodera glycines (soybean system Nematode, Heterodera oryzae, Heterodera Rodella schakhachii (Heterodera schachtii), Heterodera ze Heterodera zeae, and the non-migratory cyst-forming nematode, Heterodera Heterodera spp., Hirschmaniella gracilis schmaniella gracilis, Hirschmaniella oryzae chmaniella oryzae, Hirschmaniella spinicaudata chmaniella spinicaudata), and stem and leaf endoparasites, Hirschmaniella spp., Hoplolimus a Hoplolaimus aegyptii, Hoplolaimus calliphor Nix (Hoplolaimus californicus), Hoplolaimus col Mubus (Hoplolaimus columbus), Hoplolaimus galeatus ( Hoplolaimus galeatus, Hoplolaimus indicus olaimus indicus, Hoplola magnistilus imus magnistylus, Hoplolimus paralobustus aimus pararobustus, Longidorus africanus orus africanus, Longidorus breviannellus (Longido rus breviannulatus, Longidorus elongatus orus elongatus, Longidorus laevicapitatus us laevicapitatus, Longidorus vineacola us vineacola, and the ectoparasite, Longidorus spp. us spp.), Meloidogyne acronea a), Meloidogyne africana, melo Meloidogyne arenaria, Meloidogyne Meloidogyne arenaria thamesi, Meloidogyne artiella, Meloidogyne Meloidogyne chitwoodi, Meloidogyne co Meloidogyne coffeicola, Meloidogyne aethiopica Meloidogyne ethiopica, Meloidogyne exigua (M eloidogyne exigua, Meloidogyne falakis yne fallax), Meloidogyne graminicola aminicola, Meloidogyne graminis inis), Meloidogyne hapla, Meloid Meloidogyne incognita, Meloidogyne Meloidogyne incognita acrita ), Meloidogyne javanica, Meloy Meloidogyne kikuyensis, Meloidogyne Meloidogyne minor, Mel oidogyne naasi), Meloidogyne paranaensis (Meloidogy ne paranaensis), Meloidogyne tameshi hamesi, and the non-migratory parasite Meloidogyne spp. spp.), Meloinema spp., Nacobus averlans Nacobbus aberrans, Neotyle nchus vigissi, Paraphelenchus pseudopalietinus helenchus pseudoparietinus), Paratrichodorus aliu Paratrichodorus allius, Paratrichodorus robustus Paratrichodorus lobatus, Paratrichodorus minor (Pa ratrichodorus minor), Paratrichodorus nanus (Paratr ichodorus nanus, Paratrichodorus porosus odorus porosus, Paratrichodorus teres orus teres, and Paratrichodoru species s spp.), Paratylenchus hamat us), Paratylenchus minutus, Paratylenchus projectus , and Paratylenchus spp., Pratylenchus agilis, Pratylenchus arenii Pratylenchus alleni, Pratylenchus anguinus (Praty lenchus andinus, Pratylenchus brachyurus chus brachyurus, Pratylenchus cerealis hus cerealis, Pratylenchus cofeae coffeae, Pratylenchus cre natus), Pratylenchus delatt rei), Pratylenchus giibb icaudatus), Pratylenchus godeii odeyi, Pratylenchus hamatus ), Pratylenchus hexincisu s), Pratylenchus loosi, Pratylenchus Pratylenchus neglectus, Pratylenchus neglectus Pratylenchus penetrans, Pratylenchus ·Pratylenchus pratensis, Pratylenchus · Pratylenchus scribneri, Pratylenchus te Lesser stag beetle (Pratylenchus teres), Pratylenchus tornei (Prat ylenchus thornei), Pratylenchus vulnus hus vulnus, Pratylenchus zea e) and the migratory endoparasite, Pratylenchus sp. p.), Pseudohalenchus minutus us), Psilenchus magnidens, Psilenchus tumidus, Punct de la Ca Punctodera chalcoensis, Cynis lucius a Quinisulcius acutus, Radhorus citrophilus (R adopholus citrophilus, Radopholus similis olus similis), a migratory endoparasite, Radopholu spp. spp.), Rotylenchulus borealis alis), Rotylenchulus parvus , Rotylenchulus reniformis ), and Rotylenchulus spp., Rotylench Rotylenchus laurentinus, Rotylenc Rotylenchus macrodoratus, Rotylenchus Rotylenchus robustus, Rotylenchus sea urchin Rotylenchus uniformis and Rotylenchus spp. Rotylenchus spp.), Scutello nema brachyurum, Scutellonema brachyurum a bradys, Scutellonema clathricaudatum, and the migratory endoparasite, Scutellonema spp. utellonema spp.), Subanguina radiciola radiciola), Tetylenchus nicotianae cotianae), Trichodorus cylindrix indricus), Trichodorus minor, Trichodorus primitivus, bird Trichodorus proximus, Trichodorus · Similis (Trichodorus similis), Trichodorus sparsus (T richodorus sparsus, and the ectoparasite Trichodorus spp. ichodorus spp.), Tylenchorhynchus agri nchus agri), Tylenchorhynchus brassicae hus brassicae, Tylenchorhynchus clarus nchus clarus, Tylenchorhynchus klytnii nchus claytoni, Tylenchorhynchus digitalis hynchus digitatus), Tylenchorhynchus everiensis nchorhynchus ebriensis), Chilenchorhynchus maximus (T ylenchorhynchus maximus), Ty lenchorhynchus nudus), Tylorhynchus vulgaris (Tylorhynchus vulgaris) enchorhynchus vulgaris and Tyrenchorhynchus species lenchorhynchus spp.), Tyl enchulus semipenetrans), and the hemiparasite, Chilenculus spp. (Tylenchulus app.), Xiphinema americanum (Xiphine ma americanum), Xiphinema brevicore (Xiphinema brevicore) evicolle), Xiphinema dimorphicaudatum (Xiphinema di morphicaudatum), Xiphinema indexum (Xiphinema i ndex), and ectoparasites, Xiphinema spp.
[0038] Nematodes that can be controlled by using the active ingredient combination of the present invention include Examples of nematodes include: Meloidogyne nematodes, e.g. Meloidogyne incognita, Java Root-knot Nematode Meloidogyne javanica, Meloi dogyne hapla, and Meloidogy ne arenaria); nematodes of the genus Dithyrenchus, e.g., Dithyrenchus nematode (D itylenchus destructor) and Dity lenchus dipsaci); nematodes of the genus Pratylenchus, e.g., Pratylenchus penetrans, Chrysanthemum Lesion Nematode (Pratylenchus fallax), Southern root-lesion nematode (Praty lenchus coffeae, Pratylenchu s loosi, and Pratylenchus vu lnus; nematodes of the genus Globodera, e.g., potato cyst nematode (yellow potato cyst nematode)(Globodera rostoch) iensis) and the white potato cyst nematode st nematode)(Globodera pallida); Heterodera spp. Insects, such as the soybean cyst nematode (Heterodera glycines), and and beet cyst eelworm (Hetero dera schachtii); nematodes of the genus Aphelenchoides, e.g. Nematode (Aphelenchoides besseyi), Peel nematode (c hrysanthemum nematode)(Aphelenchoides ri tzemabosi) and strawberry nematode (Aphelenchoides fr agariae; nematodes of the genus Aferenc, e.g., Fungus nematode givorous nematode)(Aphelenchus avenae); Nematodes of the genus Dohorus, e.g., Burrowing nematodes e) (Radopholus similis); nematodes of the genus Chilenculus, e.g., Mica Tylenchulus semipenetrans; Nematodes of the genus Rotylenchulus, e.g. Rotylenchulus ren iformis; nematodes that live in trees, e.g., Bursaphelenchus xylophilus Helenchus xylophilus and red ring nematode ng nematode)(Bursaphelenchus cocophilus) ;etc.
[0039] Plants which can be protected by using the active ingredient combinations according to the invention include For example, the following may be mentioned: cereals (e.g. rice, barley, wheat, etc.) barley, rye, oats, corn, etc.), legumes (soybeans, adzuki beans, broad beans, peas, peanuts, etc.), fruits (apples, citrus, pears, grapes, peaches) , plum, cherry, walnut, almond, banana, strawberry, etc.), vegetable seeds (cabbage, tomato, etc.) tomato, spinach, broccoli, lettuce, onion, leek, pepper, etc.), root vegetables ( Carrots, potatoes, sweet potatoes, radishes, lotus roots, turnips, etc.), industrial raw materials Plants (cotton, hemp, paper mulberry, mitsumata, rapeseed, beets, hops, sugarcane, tea bean, olive, rubber, palm, coffee, tobacco, tea, etc.), Cucurbitaceae plants (pumpkin, etc.) , cucumber, watermelon, melon, etc.), pasture grasses (orchard grass, sorghum, timothy, clover -, alfalfa, etc.), turfgrass (mascarene grass ), bentgrass, etc.), aromatic plants, etc. (lavender, rosemary, thyme, parsley, pepper, ginger, etc.) and flowers (chrysanthemums, roses, orchids, etc.).
[0040] The active ingredient combinations according to the invention are useful for controlling nematodes in coffee, in particular: Particularly suitable for: Pratylenchus brachyurus (Pratylenchus b rachyurus, Pratylenchus cophaeae ffeae), Meloidogyne exigua, Meloidogyne incognita, Meloy Meloidogyne coffeicola, Helicotyle Helicotylenchus spp. and also Meloidogyne Meloidogyne paranaensis, Lochilenk Rotylenchus spp., Xiphinema spp. spp.), Tylenchorhynchus spp. , and Scutellonema spp.
[0041] The active ingredient combinations according to the invention are useful for controlling potato nematodes, in particular: Particularly suitable for: Pratylenchus brachyurus brachyurus, Pratylenchus pratensis pratensis), Pratylenchus scribneri cribneri, Pratylenchus penetrans netrans), Pratylenchus coffeae eae), Ditylenchus dipsaci, and , and Pratylenchus alleni, Platylenchus Pratylenchus andinus, Pratylenchus andinus Pratylenchus cerealis, Pratylenchus cerealis Pratylenchus crenatus, Pratylenchus hexine Pratylenchus hexincisus, Pratylenchus roosi (Pratylenchus loosi), Pratylenchus neglectus (Prat ylenchus neglectus), Pratylenchus teres th teres, Pratylenchus tornai ornei), Pratylenchus vulnus , Belonolaimus longicaudatus atus), Trichodorus cylindr icus, Trichodorus primitibus us), Trichodorus proximus, Trichodorus similis, Trichodorus Trichodorus sparsus, Paratrichodorus minor ( Paratrichodorus minor, Paratrichodorus arius atrichodorus allius, Paratrichodorus nanus ichodorus nanus, Paratricho dorus teres, Meloidogyne arenaria enaria), Meloidogyne fallax , Meloidogyne hapla, Meloidogyne tame Meloidogyne thamesi, Meloidogyne incognita oidogyne incognita, Meloidogyne kitowoji ogyne chitwoodi, Meloidogyne javanica e javanica), Nacobbus aberran s), Globodera rostochiensi s), Globodera pallida, Ditylenex de Struktor (Ditylenchus destructor), Radhorus similis Radopholus similis, Rott ylenchulus reniformis, Neotylenchus bigisi lenchus vigissi), Paraferenchus pseudoparietinus (Par aphelenchus pseudoparietinus), Aphelenchoides Aphelenchoides fragariae and Meloine Meloinema spp.
[0042] The active ingredient combinations according to the invention are useful for controlling nematodes in tomatoes, in particular: Particularly suitable for: Meloidogyne arena ria), Meloidogyne hapla, Meloidogyne Meloidogyne javanica, Meloidogyne parakeet Meloidogyne incognita, Pratylenchus penetran Pratylenchus penetrans, and also Pratylenchus Brachyurus (Pratylenchus brachyurus) · Pratylenchus coffeae, Pratylenchus scribati Buneri (Pratylenchus scribneri), Pratylenchus vulnus (Pratylenchus vulnus), Paratrichodorus minor (Parat richodorus minor, Meloidogyne exigua ne exigua, Nacobbus aberrans ), Globodera solanacearum, Dolichodorus heterocephalus lus, and Rotylenchulus reniformis iformis).
[0043] The active ingredient combinations according to the invention are useful for controlling nematodes of Cucurbitaceae plants, in particular: Particularly suitable for: Meloidogyne arenaria naria), Meloidogyne hapla, Meloy Meloidogyne javanica, Meloidogyne javanica Meloidogyne incognita, Lochilencrus renijo Rotylenchulus reniformis and Pratylenchus Torney (Pratylenchus thornei).
[0044] The active ingredient combinations according to the invention are useful for controlling nematodes in cotton, in particular: Particularly suitable for: Belonolaimus longicaudatus (Belonolaimus l ongicaudatus, Meloidogyne incognita incognita, Hoplolaimus columbus umbus), Hoplolaimus galeatus s) and Rotylenchulus reniformis ormis).
[0045] The active ingredient combinations according to the invention control nematodes in corn, in particular Particularly suitable for: Belonolaimus longicaudatus us longicaudatus, Paratrichodorus minor odorus minor), and also Pratylenchus brachyurus (Prat ylenchus brachyurus, Pratylenchus delatoryi lenchus delattrei, Pratylenchus hexincisus lenchus hexincisus, Pratylenchus penetrans lenchus penetrans, Pratylenchus zeae hus zeae), (Belonolaimus gracilis acilis), Belonolaimus norto ni), Longidorus breviannulatus ulatus), Meloidogyne arenari a), Meloidogyne arenaria thamesi), Meloidogyne grami nis), Meloidogyne incognita ), Meloidogyne incognita acrita (Meloidogyne incognita acrita), Meloidogyne javanica nica), Meloidogyne naasi, Heterode Heterodera avenae, Heterodera oryzae erodera oryzae, Heterodera zea e), Punctodera chalcoensis ), Ditylenchus dipsaci, Hoplorai Mus aegyptii (Hoplolaimus aegyptii), Hoplolaimus Hoplolaimus magnistylus, Hoplolaimus -Hoplolaimus galeatus, Hoplolaimus inji Hoplolaimus indicus, Helicochilenchus zygonycus (H elicotylenchus digonicus), Helicotylenchus dihystera (Helicotylenchus dihystera), Helicotylenchus pseudo Helicotylenchus pseudorobustus, Xiphinema americanum, Dolichodol Dolichodorus heterocephalus, Criconemella ornata, Criconemella ornata Criconemella onoensis, Radhorus similis (Radopholus similis), Rotyleculus borealis (Rotyl enchulus borealis, Rotylenculus parvus hulus parvus, Tylenchorhynchus agri hus agri), Tylenchorhynchus clarus clarus), Tylenchorhynchus klytnii claytoni), Tylenchorhynchus maximus us maximus, Tylenchorhynchus nuzus s nudus), Tylenchorhynchus vulgaris vulgaris, Quinisulcius acu tus), Paratylenchus minutus , Hemicycliophora parvana, Aglenchus agricola, Anguina to Anguina tritici, Aphelenchoides arachis elenchoides arachidis), Scutelloma brachyurum (Scu tellonema brachyurum and Su banguina radiciola).
[0046] The active ingredient combinations according to the invention are useful for controlling nematodes in soybeans, in particular: Particularly suitable for: Pratylenchus brachyurus achyurus, Pratylenchus pr atensis, Pratylenchus penetrans etrans), Pratylenchus scribneri bneri), Belonolaimus longicaudatus (Belonolaimus lon gicaudatus, Heterodera glycines nes), Hoplolaimus columbus , and furthermore, Pratylenchus coffeae ae), Pratylenchus hexincisus sus, Pratylenchus neglect us), Pratylenchus crenatus , Pratylenchus alleni, Pratylenchus Pratylenchus agilis, Pratylenchus zeae ( Pratylenchus zeae, Pratylenchus brunnus chus vulnus), (Belonolaimus gracilis gracilis), Meloidogyne arenaria naria, Meloidogyne incognita ta), Meloidogyne javanica, Meloidogyne hapla, Hoplolymus corum Hoplolaimus columbus, Hoplolaimus galeatus (H oplolaimus galeatus) and Lotylenculus reniformis (R otylenchulus reniformis).
[0047] The active ingredient combinations according to the invention are useful for controlling nematodes in tobacco, in particular: Particularly suitable for: Meloidogyne incognita gnita), Meloidogyne javanica ), and furthermore, Pratylenchus brachyurus chyurus, Pratylenchus pratensis tensis, Pratylenchus hex tensis incisus, Pratylenchus penetrans etrans), Pratylenchus neglectus ectus), Pratylenchus crenat us), Pratylenchus thornei, Pratylenchus vulnus, Pratylenchus ·Pratylenchus zeae, Longidorus elongatus gidorus elongatu, Paratrichodorus lobatus hodorus lobatus, Trichodorus sp. p.), Meloidogyne arenaria, Meloidogyne Meloidogyne hapla, Globodera tabacum Globodera tabacum, Globodera solanacearum ra solanacearum, Globodera virginiae virginiae, Ditylenchus dipsa ci), Rotylenchus spp., Helicotylenchus spp. species (Helicotylenchus spp.), Xiphiinema americanum (Xi phinema americanum, Criconemella species a spp.), Rotylenchulus reniformis (Rotylenchulus ren iformis, Tylenchorhynchus klytnii claytoni), Paratylenchus spp. , and Tetylenchus nicotianae ).
[0048] The active ingredient combinations according to the invention are useful for controlling citrus nematodes, in particular: Particularly suitable for: Pratylenchus cofeae feae, and also Pratylenchus brachyurus. brachyurus, Pratylenchus vulnus ulnus), Belonolaimus longicaudatus (Belonolaimus lon gicaudatus, Paratrichodorus minor minor), Paratrichodorus po rosus), Trichodorus, Meloidogyne incognita (Meloidogyne incognita), Meloidogyne incognita acrocephalus Rita (Meloidogyne incognita acrita), Meloidogyne Meloidogyne javanica, Lotylenchus macrodora Rotylenchus macrodoratus, Xyphenema americana Xiphinema americanum, Xiphinema brevicore (Xi phinema brevicolle), Xiphinema index (Xiphine ma index), Criconemella spp., Hemi Hemicriconemoides, Radhorus similis (R adopholus similis, and Radophorus citrophilus pholus citrophilus, Hemicychophora arenaria ycliophora arenaria), Hemicy cliophora nudata) and Tyl enchulus semipenetrans).
[0049] The active ingredient combinations according to the invention are useful for controlling nematodes on bananas, in particular: Particularly suitable for: Pratylenchus cofeae feae), Radopholus similis, and In addition, Pratylenchus giibbi caudatus, Pratylenchus loosi ), Meloidogyne spp., Helicotylenchus mull Helicotylenchus multicinctus, Helico Helicotylenchus dihystera, and and Rotylenchulus spp.
[0050] The active ingredient combinations according to the invention control pineapple nematodes, in particular Particularly suitable for: Pratylenchus zeae ae), Pratylenchus pratensis s), Pratylenchus brachyuru s), Pratylenchus goodeyi, Me Meloidogyne spp., Rottlencrus reniformis (Rotylenchulus reniformis), and also longidorus Elongatus (Longidorus elongatus), Longidorus laevis Capitatus (Longidorus laevicapitatus), Trichodorus Trichodorus primitivus, Trichodorus minnow Trichodorus minor, Heterodera species spp.), Ditylenchus myceliofagus ophagus), Hoplolaimus californicus (Hoplolaimus californicus) ifornicus, Hoplolaimus paralobustus ararobustus), Hoplolaimus indicus ndicus, Helicotylenchus dihystera ihystera, Helicotylenchus nannus nannus), Helicotylenchu multicinctus s multicinctus), Helicotyl enchus erythrine), Xiph inema dimorphicaudatum, Radophorus similis (Radop holus similis, Tylenchorh ynchus digitatus, Tylencorhynchus everiensis chorhynchus ebriensis, Paratylenchus minutus (Para tylenchus minutus, Scutellonema cratrichadatum (Scut ellonema clathricaudatum), Scutellonema brazis (Sc utellonema bradys, Psilenchu s tumidus, Psilenchus magnidens idens, Pseudohalenchus minutus nutus), Criconemoides ferniae niae), Criconemoides onoense se) and Criconemoides ornatum tum).
[0051] The active ingredient combinations according to the invention are useful for controlling vine nematodes, in particular: Particularly suitable for: Pratylenchus vulnus lnus), Meloidogyne arenaria , Meloidogyne incognita, Melo Meloidogyne javanica, Xyphinema Xiphinema americanum, Xiphinema index Xiphinema index, and furthermore, Pratylenchus pratensis (Pratylenchus pratensis), Pratylenchus scribneri ( Pratylenchus scribneri), Pratylenchus neglectus (P ratylenchus neglectus), Pratylenchus brachyurus (Pr atylenchus brachyurus, Pratylenchus tornei (Prat ylenchus thornei) and Tyl enchulus semipenetrans).
[0052] The active ingredient combinations according to the invention are useful for controlling nematodes of tree crops - pome fruit, in particular Particularly suitable for: Pratylench Penetrans us penetrans, and Pratylenchus vulnus us vulnus, Longidorus elongatus gatus), Meloidogyne incognita ta), and Meloidogyne hapla.
[0053] The active ingredient combinations according to the invention are useful for controlling nematodes of tree crops - stone fruit, in particular Particularly suitable for: Pratylench Penetrans us penetrans), Pratylenchus vulnus vulnus, Meloidogyne arenari a), Meloidogyne hapla, Meloidogyne Meloidogyne javanica, Meloidogyne incognita Meloidogyne incognita, Cryconema xenoplakis Criconemella xenoplax), and also Pratylenchus brachyurus Pratylenchus brachyurus, Pratylenchus cophea Pratylenchus coffeae, Pratylenchus scribneri (P ratylenchus scribneri, Pratylenchus zeae (Praty lenchus zeae), Belonolai longicaudatus mus longicaudatus), Helicochilenchus dihystera (Helico tylenchus dihystera), Xiphi nema americanum, Criconemella curvata a curvata, Tylenchorhynchus klytnii us claytoni, Paratylenchus hamatus, Paratylenchus projectus rojectus, Scutellonema brachyurum chyurum, and Hoplolaimus galeatus leatus).
[0054] The active ingredient combinations according to the invention are effective against nematodes in tree crops, sugarcane and rice, in particular It is particularly suitable for controlling: Trichodorus spp. spp.), Criconemella spp., and Pratylenchus spp., Paratrichodorus spp. (Paratrichodorus spp.), Meloidogynae spp. yne spp., Helicotylenchus spp. .), Tylenchorhynchus spp., Aphe Aphelenchoides spp., Heterodera spp. rodera spp., Xiphinema spp., and , Cacopaurus pestis.
[0055] The active ingredient combinations of the present invention, optionally at a particular concentration or application rate, They may also be used as herbicides, safeners, growth regulators or agents that improve plant properties. or by using a microbicide or gametocide. As a bactericide, for example, a fungicide, an antifungal agent, ic), bactericides or viricides (which also include agents acting against viroids) ), or to treat MLOs (mycoplasma-like organisms) and RLOs (rickettsial They can also be used as agents against inflammatory bowel disease (e.g., rheumatoid arthritis ... and rheumatoid arthritis). It can also be used as an intermediate or precursor for the synthesis.
[0056] formulation The present invention further relates to a sterilizing agent comprising at least one of the active ingredient combinations of the present invention. Formulations as pesticides and application forms prepared from the formulations (e.g., irrigation solutions, dripping solutions, etc.) Optionally, the application form also comprises a further pesticide and / or a spray solution. adjuvants to improve the action, such as penetrating agents, for example vegetable oils (e.g. rapeseed oil) oil, sunflower oil), mineral oil (e.g. paraffin oil), vegetable fatty acid alkyl esters (e.g. For example, rapeseed oil methyl ester or soybean oil methyl ester), or alkanol alkanol siloxanes and / or spreading agents, e.g. alkylsiloxanes and / or salts, e.g. For example, organic or inorganic ammonium or phosphonium salts (e.g., ammonium sulfate or diammonium hydrogen phosphate) and / or retention promoters motor) (e.g., dioctyl sulfosuccinate or hydroxypropyl guar polymers -), and / or wetting agents (e.g., glycerol), and / or fertilizers (e.g., an ammonium-containing fertilizer, potassium-containing fertilizer or phosphorus-containing fertilizer.
[0057] Conventional formulations are, for example: aqueous solutions (SL), emulsifiable concentrates (EC), Oil-in-water emulsion (EW), suspension formulation (SC, SE, FS, OD), water dispersible granule ( WG), granules (GR), and capsule concentrates (capsule concentrate es) (CS); these and other possible formulations are described, for example, in Crop Life International and in Pe sticide Specifications, Manual on develo pment and use of FAO and WHO specificity ons for pesticides, FAO Plant Production and Protection Papers -173 (Produced by: the FAO / WHO Joint Meeting on Pesticide Specifica tions, 2004, ISBN:9251048576). The preparation may be one or more In addition to the active ingredient combination of the present invention, optionally further active pesticide ingredients are contained. .
[0058] Preferred are auxiliaries such as extenders, solvents, spontaneous promoters, etc. promoter), carrier, emulsifier, dispersant, frost protection agent ction agents), biocides, thickeners and / or other adjuvants (e.g., ajuva In this context, adjuvants are preparations or forms of use that contain , a component that enhances the biological effect of the preparation, the component itself having a biological effect Examples of adjuvants include those that aid in retention, spreading, and hydration of the leaf surface. An adhesion promoting agent or a penetration promoting agent.
[0059] These preparations can be prepared in a known manner, for example by incorporating the active ingredient combination according to the invention in an adjuvant, e.g. , a bulking agent, a solvent and / or a solid carrier, and / or other auxiliary substances, such as surfactants Such preparations are prepared by mixing with the appropriate equipment or is prepared before or during application.
[0060] The auxiliary used may be a formulation of the active ingredient combination of the present invention or a preparation prepared from such a formulation. Form of use (e.g. ready-to-use pesticides, e.g. The product (e.g. spray or seed dressing product) has special properties, e.g. specific physical or technical properties. and / or may be a substance suitable for imparting biological properties, etc.
[0061] Suitable extenders include, for example, water and polar and non-polar organic chemical liquids, such as Selected from the following classes: aromatic and non-aromatic hydrocarbons (e.g., paraffin, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols, which may, where appropriate, be substituted and etherified. and / or esterified), ketones (e.g., acetonitrile, cyclohexanone), esters (which include fats and oils) and (poly ) ethers, simple and substituted amines, amides, lactams (e.g. For example, N-alkylpyrrolidones), and lactones, sulfones and sulfoxides ( For example, dimethylsulfoxide), carbonates and nitriles.
[0062] When the extender used is water, for example an organic solvent may be used as a co-solvent. Useful liquid solvents are essentially the following: aromatic compounds, e.g., xylene, toluene ... benzene or alkylnaphthalenes, chlorinated aromatic compounds or chlorinated aliphatic hydrocarbons, e.g. For example, chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, for example cyclohexane or paraffins, e.g. petroleum fractions, mineral oils and vegetable oils, alcohols, For example, butanols or glycols and their ethers and esters, ketones, e.g. , acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strong Solvents such as dimethylformamide or dimethylsulfoxide, carbonates, e.g. For example, propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate. ethyl carbonate, or nitriles, such as acetonitrile or propanenitrile.
[0063] In principle, it is possible to use all suitable solvents. Examples of suitable solvents are aromatic aromatic hydrocarbons, for example, xylene, toluene or alkylnaphthalenes, chlorinated aromatic hydrocarbons Hydrogen or chlorinated aliphatic hydrocarbons, such as chlorobenzene, chloroethylene or methylene chloride olefins, aliphatic hydrocarbons such as cyclohexane, paraffins, petroleum fractions, mineral oils and vegetable oils. Oils, alcohols, such as methanol, ethanol, isopropanol, butanol or glycols and their ethers and esters, ketones, e.g., acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, e.g. Methyl sulfoxide, carbonates such as propylene carbonate, butylene carbonate carbonate, diethyl carbonate or dibutyl carbonate, nitriles such as acetone, trinitrile or propanenitrile, and further water.
[0064] In principle, all suitable carriers can be used. Examples of suitable ammonium salts include ammonium salts and natural, ground ammonium salts. Minerals such as kaolin, alumina, talc, chalk, quartz, attapulgite, molybdenum, etc. Ammonium nitrite or diatomaceous earth, and synthetic, ground minerals, e.g., micronized silica, aluminium Aluminum oxide and natural or synthetic silicates, resins, waxes, and / or , solid fertilizers. Mixtures of such carriers can be used as well. Useful for granules Suitable carriers include, for example, crushed and fractionated natural rocks. Stones, such as calcite, marble, pumice, sepiolite, dolomite, and inorganic and organic powders Synthetic granules, as well as organic materials (e.g. sawdust, paper, coconut shells, straw, etc.) Granules made from sorghum cobs and tobacco stems, etc.
[0065] It is also possible to use liquefied gas extenders or solvents. Particularly suitable are standard A bulking agent or carrier that is a gas at room temperature and atmospheric pressure, such as an aerosol propellant, e.g. halogenated hydrocarbons, and further, butane, propane, nitrogen and carbon dioxide. .
[0066] Emulsifiers and / or foam formers, dispersants or Examples of wetting agents or mixtures of these surface-active substances are: polyacrylonitrile, polyisobutene ... salts of lignosulfonic acid, salts of lignosulfonic acid, phenolsulfonic acid or naphthalenesulfonic acid Salts of acids, polycondensates of ethylene oxide and fatty alcohols or polycondensates of ethylene oxide and fatty Polycondensation products of acids or polycondensation products of ethylene oxide and fatty amines, of substituted phenols (preferably alkylphenols or arylphenols) Polycondensates, salts of sulfosuccinic acid esters, taurine derivatives (preferably alkyl taurine isethionate derivatives of polyethoxylated alcohols or phenols or phosphate esters esters, fatty acid esters of polyols, and sulfate anions, sulfonate anions, and Derivatives of the compounds containing phosphate anions, such as alkylaryl polyglycols. ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates The present invention is based on the above-mentioned cellulose, protein hydrolysate, lignosulfite waste liquid, and methylcellulose. One of the active ingredient combinations and / or one of the inert carriers is water-insoluble If the composition is of a natural origin and application is carried out with water, the presence of a surfactant is advantageous.
[0067] Further auxiliaries which may be present in the formulation and in the use forms derived therefrom are Coloring agents, such as inorganic pigments, for example, iron oxide, titanium oxide, and Prussian blue sian Blue), and organic dyes such as alizarin dyes, azo dyes and metal dyes. Phthalocyanine dyes, and nutrients and micronutrients, such as iron salts, manganese salts, boron salts, etc. These include copper salts, copper salts, cobalt salts, molybdenum salts and zinc salts.
[0068] Further ingredients which may be present include stabilizers (e.g. low temperature stabilizers), preservatives, antioxidants, It is a light stabilizer or another agent that improves chemical and / or physical stability. Additionally, a foam generating or defoaming agent may also be present.
[0069] Furthermore, the formulation and the use forms derived therefrom contain, as additional adjuvants, , adhesives such as carboxymethylcellulose, and powders or granules or latex Natural and synthetic polymers in the form of gum arabic, polyvinyl alcohol, and polyvinyl acetate, or natural phospholipids, such as cephalin and lecithin, and Further adjuvants include mineral oils and vegetable oils. It is possible.
[0070] Where appropriate, further auxiliary substances may be present in the preparation and in the use forms derived therefrom. Examples of such additives are fragrances, protective colloids, binders, etc. , adhesives, thickeners, thixotropic agents, penetrating agents, retention promoters, stabilizing agents, sequestering agents, complexing agents In general, the active ingredient combinations of the present invention are used for formulation purposes. It may be combined with any commonly used solid or liquid additive.
[0071] Useful retention enhancers include any material that reduces dynamic surface tension (e.g., sulfosuccinic acid, dioctyl acetate) or any substance that increases viscoelasticity (e.g., hydroxypropyl guar Polymers) are included.
[0072] Penetrants useful in the context of the present invention are compounds that are capable of enhancing the penetration of active pesticide ingredients into plants. In this context, penetrants are all substances that are typically used in The chemicals are absorbed into the plant cuticle from the application solution (aqueous) and / or from the coating produced by spraying. by its ability to penetrate the skin and thereby enhance the mobility of the active ingredient within the cuticle. To confirm this property, the literature (Baur et al., 199 7, Pesticide Science 51, 131-152) Examples of such methods include the use of alcohol alkoxylates, e.g. Coconut fatty ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters, such as sodium Seed oil methyl ester or soybean oil methyl ester, fatty amine alkoxylates, For example, tallow amine ethoxylates (15), or ammonium salts and / or phosphatides. ammonium salts, such as ammonium sulfate or diammonium hydrogen phosphate; It is possible.
[0073] The preparation preferably contains 0.00000001% by weight to 9% by weight based on the weight of the preparation. 8% by weight of the active ingredient combination of the present invention, more preferably 0.01% by weight % to 95% by weight of the active ingredient combination of the present invention, and most preferably 0.5% to 95% by weight of the active ingredient combination of the present invention. The active ingredient combination of the present invention is contained in an amount of 50% to 90% by weight.
[0074] The active ingredient combinations according to the invention in the use forms prepared from said formulations (especially pesticides) The content of the active ingredient composition of the present invention in the use form can vary within a wide range. The concentration of the combination is based on the weight of the formulation used, generally in increments of 0.00000001 by weight. % to 95% by weight of the active ingredient combination of the present invention, preferably 0.00001% to 1 The active ingredient combination according to the invention is in the form of an active ingredient in an amount of 100% by weight. This is done by law.
[0075] mixture The active ingredient combinations according to the invention can be used, for example, to extend the spectrum of action, To increase the time to action, to increase the speed of action, to prevent repellency, or to improve resistance One or more suitable fungicides, bactericides, acaricides, molluscicides, or other insecticides to prevent the development of resistance. Pesticides, nematicides, insecticides, microbiological agents ), beneficial organisms, herbicides, fertilizers, bird repellents, phytotonic agents, sterilants , safeners, semiochemicals and / or plant growth regulators. Moreover, this type of active ingredient combination can improve plant growth. and / or tolerance to abiotic factors (e.g. high or low temperatures), drought tolerance It is possible to improve the resistance to high salt content in water or soil. Furthermore, it is possible to improve flowering and fruiting performance, and improve germination and root development. It is also possible to optimize the development of the plant and facilitate harvesting, thus improving yields. It can also increase the temperature of the crop, affect the maturation of the crop, and It is also possible to improve the quality and / or nutritional value and shelf life of harvested produce. It is possible to increase the length of time required for harvesting and / or improve the processability of the harvested product. is also possible.
[0076] Furthermore, the active ingredient combination of the present invention may be administered in the presence of another active ingredient or semiochemical (e.g. attractants, and / or bird repellents, and / or plant activators, and / or growth regulators, The active ingredient of the present invention can also be present in a mixture with a fertilizer or a compost. The combination is intended to improve plant characteristics (e.g., growth, yield, and crop quality). It is also possible to use it for
[0077] In a particular embodiment according to the invention, the active ingredient combination of the invention is present in the formulation or In the use forms prepared from such formulations, further compounds (preferably as described below) may be added. It is present in a mixed state with the compounds listed above.
[0078] When one of the compounds described below can exist in various tautomeric forms , and in each case, even if not explicitly mentioned, these forms are equally included. All the mentioned mixed partners are, in some cases, If it is possible to do so based on the group, it is also possible to form bonds with a suitable base or acid. do.
[0079] Insecticides / Acaricides / Nematocides
[0150] The active ingredients identified herein by "generic name" are For example, see “The Pesticide Manual”, 16t h ed.,British Crop Protection Council 20 12 or can be found on the Internet (e.g. "http: / / www.alanwood.net / pesticides"). classification The IRAC Mode of Action Cl applicable at the time of filing of this patent application Based on the assification scheme.
[0080] (1) Acetylcholinesterase (AChE) inhibitors, preferably Alanycarb, aldicarb, bendiocarb, benfuracarb, butocarboxim, Butoxycarboxim, carbaryl, carbofuran, carbosulfan, etiophen Lub, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb , methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb , thiofanox, triazamate, trimethacarb, XMC, and xylylcarb or a carbamate selected from Acephate, Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Cadusafos , Chlorethoxyphos, Chlorfenvinphos, Chlormephos, Chlorpyrifos-methyl , Coumaphos, Cyanophos, Demeton-S-methyl, Diazinon, Dichlorvos / DDV P, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethiopidine fenthion, ethoprophos, famfur, fenamiphos, fenitrothion, fenthion, Sthiazate, heptenophos, imidazolium phos, isofenphos, O-(methoxyaminothio Ophosphoryl) isopropyl salicylate, isoxathion, malathion, mecarbam, Tamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxalate Cidimethon-methyl, parathion, parathion-methyl, phenthoate, phorate, phorate Salon, Phosmet, Phosphamidon, Phoxim, Pirimiphos-methyl, Profenofos , Propetamphos, Prothiofos, Pyraclofos, Pyridafenthion, Quinalphos, Ruhotep, Tebupirimphos, Temephos, Terbufos, Tetrachlorvinphos, Thiometh an organophosphate ester selected from the group consisting of thion, triazophos, trichlorfon, and vamidothion; Teru type.
[0081] (2) GABA-regulated chloride channel blockers, preferably A cyclodiene-organochlorine selected from chlordane and endosulfan; or , Phenylpyrazoles selected from ethiprole and fipronil (fipronil) (ru type).
[0082] (3) a sodium channel modulator, preferably Acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin Bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, Bioresmethrin, Cycloprothrin, Cyfluthrin, Beta-Cyfluthrin, Cyhalothrin Phosphorus, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin Lumethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [ (EZ)-(1R) isomer], esfenvalerate, etofenprox, fenp Lopatryn, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate , Halfenprox, Imiprothrin, Kadethrin, Momfluorothrin, Perme thorin, fenothrin [(1R)-trans isomer], prallethrin, pyrethrins (except Pyrethrum, Resmethrin, Silafluofen, Tefluthrin, Tet Lametrin, tetramethrin [(1R) isomer], tralomethrin, and transflumethrin A pyrethroid selected from the group consisting of thorin; or DDT; or methoxychlor.
[0083] (4) Nicotinic acetylcholine receptor (nAChR) agonists, preferably Acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, A neonicotinoid selected from thiacloprid and thiamethoxam; or Nicotine; or Sulfoxamines selected from sulfoxaflor, or flupyradifurone Butenolides are used.
[0084] (5) Nicotinic acetylcholine receptor (nAChR) allosteric agonists, Preferably, A spinosyn selected from spinetoram and spinosad.
[0085] (6) GluCl-gated chloride channel allosteric agonists, Preferably, Selected from abamectin, emamectin benzoate, lepimectin, and milbemectin. The avermectins / milbemycins are the preferred class.
[0086] (7) Juvenile hormone mimetics, preferably Juvenile hormone analogs selected from hydroprene, kinoprene, and methoprene; Or, Fenoxycarb; or pyriproxyfen.
[0087] (8) Other non-specific (multi-site) inhibitors, preferably an alkyl halide selected from methyl bromide and another alkyl halide; or teeth, Chloropicrin; or sulfuryl fluoride; or borax; or tartar emetic; diazometh a methyl isocyanate generator selected from methyl and methyl;
[0088] (9) Chordal organ TRPV channel selected from pymetrozine and pyrifluquinazon Agonist.
[0089] (10) Clofentezine, hexythiazox, diflovidazin and etoxazole A mite growth inhibitor selected from the group consisting of
[0090] (11) Bacillus thuringiensis subsp. israelensis thuringiensis subspecies israelensis), Bacillus sphaericus, Bacillus thurii Bacillus thuringiensis s. ubspecies aizawai), Bacillus thuringiensis subspecies crusta Bacillus thuringiensis subspecies kurs taki), Bacillus thuringiensis subsp. tenebrionis (Bacillus thuringiensis subspecies tenebrionis) Microbial disruptors of the insect midgut membrane and Cry1Ab, Cry1Ac, and Cr y1Fa, Cry1A.105, Cry2Ab, VIP3A, mCry3A, Cry3A b, Cry3Bb and Cry34Ab1 / 35Ab1 Stuffy.
[0091] (12) Inhibitors of mitochondrial ATP synthase, preferably an ATP disruptor selected from diafenthiuron; or Organotin compounds selected from azocyclotin, cyhexatin, and fenbutatin oxide or Propargite; or tetradifon.
[0092] (13) A protozoan selected from chlorfenapyr, DNOC, and sulfluramide. Uncouplers of oxidative phosphorylation by disrupting the ATP gradient.
[0093] (14) Bensultap, cartap hydrochloride, thiocyclam, and thiosultap - A nicotinic acetylcholine receptor channel blocker selected from sodium.
[0094] (15) Bistrifluron, chlorfluazuron, diflubenzuron, flucycloc Sulon, Flufenoxuron, Hexaflumuron, Lufenuron, Novaluron, Noviful An inhibitor of chitin biosynthesis selected from muron, teflubenzuron, and triflumuron. (Type 0).
[0095] (16) A chitin biosynthesis inhibitor (type 1) selected from buprofezin.
[0096] (17) Molting inhibitors selected from cyromazine (especially for Diptera).
[0097] (18) Chromafenozide, halofenozide, methoxyfenozide, and tebufen An ecdysone receptor agonist selected from nozide.
[0098] (19) An octopamine receptor agonist selected from amitraz.
[0099] (20) Mitochondrial compounds selected from hydramethylnon, acequinocyl and fluacrypyrim. Andria complex III electron transport inhibitor.
[0100] (21) Mitochondrial complex I electron transport inhibitors, preferably Fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyra , and tolfenpyrad; or METI acaricides selected from rotenone (Derris).
[0101] (22) A voltage-dependent sodium salt selected from indoxacarb and metaflumizone Channel blockers.
[0102] (23) Acetyl-CoA carboxylase inhibitors, preferably A tetracycline selected from spirodiclofen, spiromesifen, and spirotetracycline. Ronic acid derivatives and tetramic acid derivatives.
[0103] (24) Mitochondrial complex IV electron transport inhibitors, preferably Selected from aluminum phosphide, calcium phosphide, phosphine, and zinc phosphide. or A cyanide selected from calcium cyanide, potassium cyanide and sodium cyanide. monster.
[0104] (25) Mitochondrial complex II electron transport inhibitors, preferably A beta-ketonitrile derivative selected from cyenopyrafen and cyflumetofen. body; or Carboxanilides selected from piflubumid.
[0105] (28) Ryanodine receptor agonists, preferably Selected from chlorantraniliprole, cyantraniliprole, and flubendiamide. Diamides are the preferred choice.
[0106] (29) Chordal organ agonists selected from flonicamid (with undefined target structure) .
[0107] (30) Further active ingredients, such as afidopiropen, afoxolaner, aza Ziractin, Benclothiaz, Benzoximate, Bifenazate, Broflanilide (b roflanilide), bromopropylate, chinomethionate, chloropraletri Chloroprallethrin, cryolite, cyclaniline Prole, cycloxaprid, cyhalodiamide odiamide), dichloromezotiaz, dicopho ε-metofluthrin, ε-momfluthrin Trin (epsilon momfluthrin), flometoquin, fluazanedri Fluazindolizine, Fluensulfone, Flufenerim, Flu phenoxystrobin, flufiprole, fluhexafon, Fluopyram, fluralaner, fluxamethamide, fufenozide ), guadipyr, heptafluthrin, imidaclothiz, iprodione κ-bifenthrin, κ-tefluthrin, lotilaner, mepe Rufluthrin, Paichongding, Pyridalyl, Pyrif Luquinazone, pyriminostrobin, spirobudiclofen en), tetramethylfulthrin, tetraniliprole ), tetrachlorantraniliprole le), thioxazaphen, thiofluoximate, Triflumezopyrim and iodomethane; and Bacillus firmus (Bacil A preparation based on Lus firmus (I-1582, BioNeem, Voti vo) and the following compound: 1-{2-fluoro-4-methyl-5-[(2,2,2- trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H- 1,2,4-Triazol-5-amine (known from WO2006 / 043635) (CA S 885026-50-6), {1'-[(2E)-3-(4-chlorophenyl)propane Per-2-en-1-yl]-5-fluorospiro[indole-3,4'-piperidine] -1(2H)-yl}(2-chloropyridin-4-yl)methanone (WO2003 / 10 6457) (CAS 637360-23-7), 2-chloro-N-[2-{1 -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidine- 4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (WO2006 / 003494) (CAS 872999-66-1), 3-(4-chloro-2 ,6-Dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4 .5] Dec-3-en-2-one (known from WO2010052161) (CAS 12 25292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy C-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl ethyl carboxylate Carboxylate (known from EP2647626) (CAS-1440516-42-6), 4 -(But-2-yn-1-yloxy)-6-(3,5-dimethylpiperidin-1-yl) )-5-fluoropyrimidine (known from WO2004 / 099160) (CAS 792 914-58-0), PF1364 (known from JP2010 / 018586) (CAS Reg. No. 1204776-60-2), N-[(2E)-1-[(6-chloropyridine) 2,2,2-Trifluorophenyl)pyridin-2(1H)-ylidene Isoacetamide (known from WO2012 / 029672) (CAS 1363400-4 1-2), (3E)-3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridyl Lithidene]-1,1,1-trifluoropropan-2-one (WO2013 / 144213 (CAS 1461743-15-6), N-[3-(benzylcarbamoyl )-4-Chlorophenyl]-1-methyl-3-(pentafluoroethyl)-4-(trifluorophenyl) (fluoromethyl)-1H-pyrazole-5-carboxamide (WO2010 / 051926 (CAS 1226889-14-0), 5-bromo-4-chloro-N-[4 -Chloro-2-methyl-6-(methylcarbamoyl)phenyl]-2-(3-chloro-2 -pyridyl)pyrazole-3-carboxamide (known from CN103232431) (C AS 1449220-44-3), 4-[5-(3,5-dichlorophenyl)-4,5 -Dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N- (cis-1-oxido-3-thietanyl)benzamide, 4-[5-(3,5-dichloro phenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl] -2-Methyl-N-(trans-1-oxido-3-thietanyl)benzamide and 4- [(5S)-5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoro 2-methyl-N-(cis-1-oxido-3-thiazolyl)-3-isoxazolyl ethanyl)benzamide (known from WO2013 / 050317A1) (CAS 133 2628-83-7), N-[3-chloro-1-(3-pyridinyl)-1H-pyrazole -4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl ]propanamide, (+)-N-[3-chloro-1-(3-pyridinyl)-1H-pyrazo -4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfide N-[3-chloro-1-(3-pyridinyl)-1H-propanamide and (-)-N-[3-chloro-1-(3-pyridinyl)-1H- Pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfonyl rufinyl]propanamide (WO2013 / 162715A2, WO2013 / 162 716A2, known from US2014 / 0213448A1) (CAS 1477923- 37-7), 5-[[(2E)-3-chloro-2-propen-1-yl]amino]-1- [2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl) 1H-pyrazole-3-carbonitrile (CN10133793 7A) (CAS 1105672-77-2), 3-bromo-N-[4-chloro -2-Methyl-6-[(methylamino)thioxomethyl]phenyl]-1-(3-chloro -2-pyridinyl)-1H-pyrazole-5-carboxamide, (Liudaibenj iaxuanan, known from CN103109816A) (CAS 1232543-8 5-9);N-[4-chloro-2-[[(1,1-dimethylethyl)amino]carbonyl ]-6-Methylphenyl]-1-(3-chloro-2-pyridinyl)-3-(fluorometh oxy)-1H-pyrazole-5-carboxamide (from WO2012 / 034403A1 Known) (CAS 1268277-22-0), N-[2-(5-amino-1,3,4- Thiadiazol-2-yl)-4-chloro-6-methylphenyl]-3-bromo-1-( 3-Chloro-2-pyridinyl)-1H-pyrazole-5-carboxamide (WO2011 / 085575A1) (CAS 1233882-22-8), 4-[3-[2 ,6-Dichloro-4-[(3,3-dichloro-2-propen-1-yl)oxy]pheno [Oxy]propoxy]-2-methoxy-6-(trifluoromethyl)pyrimidine (CN10 1337940A) (known from CAS 1108184-52-6); (2E)- and 2 (Z)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl] [4-(difluoromethoxy)phenyl]hydrazinecarboxamide amide (known from CN101715774A) (CAS 1232543-85-9); Chloropropanecarboxylic acid 3-(2,2-dichloroethenyl)-2,2-dimethyl-4-( 1H-benzimidazol-2-yl)phenyl ester (CN103524422A) (4aS)-7-chloro-2,5-diphenyl ether (known from Hydro-2-[[(methoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl [1,2-e][1,3,4]oxadiazine-4a (3H)-Carboxylic acid methyl ester (known from CN102391261A) (CAS 1370358-69-2);6-deoxy-3-O-ethyl-2,4-di-O-methyl -1-[N-[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl Nyl-1H-1,2,4-triazol-3-ylphenylcarbamate-α- L-Mannopyranose (known from US2014 / 0275503A1) (CAS 118 1213-14-8; 8-(2-cyclopropylmethoxy-4-trifluoromethyl Phenoxy)-3-(6-trifluoromethylpyridazin-3-yl)-3-azabicyclo [3.2.1]Octane (CAS 1253850-56-4), (8-anti)-8- (2-Cyclopropylmethoxy-4-trifluoromethylphenoxy)-3-(6-trifluoromethylphenoxy) Fluoromethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octane (C AS 933798-27-7), (8-syn)-8-(2-cyclopropylmethoxy- 4-Trifluoromethylphenoxy)-3-(6-trifluoromethylpyridazine-3- yl)-3-azabicyclo[3.2.1]octane (WO2007040280A1, W Known from O2007040282A1) (CAS 934001-66-8), N-[3 -Chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3- [(3,3,3-trifluoropropyl)thio]propanamide (WO2015 / 058 021A1, known from WO2015 / 058028A1) (CAS 1477919-2 7-9), and N-[4-(aminothioxomethyl)-2-methyl-6-[(methylamino) 3-bromo-1-(3-chloro-2-pyridinyl)- 1H-Pyrazole-5-carboxamide (known from CN103265527A) (CAS 1452877-50-7), 5-(1,3-dioxan-2-yl)-4-[[4- (Trifluoromethyl)phenyl]methoxy]pyrimidine (WO2013 / 115391 A1) (CAS 1449021-97-9), 3-(4-chloro-2,6-di Methylphenyl)-4-hydroxy-8-methoxy-1-methyl-1,8-diazaspiro [4.5] Deca-3-en-2-one (WO2010 / 066780A1, WO2011 / 151146A1) (CAS 1229023-34-0), 3-(4-chloro (2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[ 4.5]Decane-2,4-dione (known from WO2014 / 187846A1) (CAS 1638765-58-8), Ethyl 3-(4-chloro-2,6-dimethylphenyl) -8-Methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]deca-3- En-4-yl carboxylate (WO2010 / 066780A1, WO201115 1146A1) (CAS 1229023-00-0), N-[1-[(6- 1H-pyridinylidene-2,2,2-trifluoromethyl-3-pyridinyl Luoroacetamide (known from DE3639877A1, WO2012029672A1) (CAS 1363400-41-2), [N(E)]-N-[1-[(6-chloro-3 -pyridinyl)methyl]-2(1H)-pyridinylidene]-2,2,2-trifluoro Cetamide (known from WO2016005276A1) (CAS 1689566-03- 7), [N(Z)]-N-[1-[(6-chloro-3-pyridinyl)methyl]-2(1H ) -pyridinylidene]-2,2,2-trifluoroacetamide (CAS 1702305- 40-5), 3-endo-3-[2-propoxy-4-(trifluoromethyl)pheno 5-(trifluoromethyl)-2-pyridinyloxy]-9-azabi Cyclo[3.3.1]nonane (WO2011 / 105506A1, WO2016 / 133 011A1) (CAS 1332838-17-1).
[0108] Fungicides The active ingredients identified herein by generic name are known and For example, see the Pesticide Manual (16th Ed., British Crop Protection Council (Crop Protection Council) or You can search for it on the internet (for example, "http: / / www.alanwo od.net / pesticides).
[0109] All mixing partners described in classes (1) to (15) have functional groups If possible, salts can be formed with suitable bases or acids. All fungicide mixing partners of classes (1) to (15) listed are compatible where applicable. Mutant forms may be included.
[0110] (1) Inhibitors of ergosterol biosynthesis, e.g., (1.001) cyproconazole , (1.002) difenoconazole, (1.003) epoxiconazole, (1.00 4) Fenhexamid, (1.005) Fenpropidin, (1.006) Fenpropy Morph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1. 009) Flutriafol, (1.010) Imazalil, (1.011) Imazalil sulfate , (1.012) Ipconazole, (1.013) Metconazole, (1.014) Miconazole lobutanil, (1.015) paclobutrazol, (1.016) prochloraz, (1. 017) Propiconazole, (1.018) Prothioconazole, (1.019) Pyridine Xazol, (1.020) Spiroxamine, (1.021) Tebuconazole, (1.0 22) Tetraconazole, (1.023) Triadimenol, (1.024) Tridemole F, (1.025) Triticonazole, (1.026) (1R,2S,5S)-5-(4 -chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-trimethyl (1.027) (1S,2R,5R) cyclopentanol )-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1 ,2,4-triazol-1-ylmethyl)cyclopentanol, (1.028)(2R )-2-(1-chlorocyclopropyl)-4-[(1R)-2,2-dichlorocyclopropyl pyryl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol (1. 029) (2R)-2-(1-chlorocyclopropyl)-4-[(1S)-2,2-dichloro
[0046] -1-(1H-1,2,4-triazol-1-yl)butane-2 -ol, (1.030)(2R)-2-[4-(4-chlorophenoxy)-2-(trimethylol, Fluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propionate Pan-2-ol, (1.031)(2S)-2-(1-chlorocyclopropyl)-4- [(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazolidinediamine) (1.032)(2S)-2-(1-chlorocyclobutan-1-yl)butan-2-ol, propyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2 ,4-triazol-1-yl)butan-2-ol, (1.033)(2S)-2-[ 4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H- 1,2,4-triazol-1-yl)propan-2-ol, (1.034)(R)- [3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)- 1,2-Oxazol-4-yl](pyridin-3-yl)methanol, (1.035) (S)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl] nyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1. 036) [3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl nyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1. 037) 1-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy)fluor phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4 -Triazole, (1.038) 1-({(2S,4S)-2-[2-chloro-4-(4 -Chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl (1.039)1-{[3-(2-chlorophenyl)-1H-1,2,4-triazole, nyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H- 1,2,4-Triazol-5-yl thiocyanate, (1.040)1-{[rel( 2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxy Silane-2-yl]methyl}-1H-1,2,4-triazol-5-ylthiocyanate (1.041) 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2- (2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4- Triazol-5-yl thiocyanate, (1.042) 2-[(2R,4R,5R)- 1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptane -4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1 .043) 2-[(2R,4R,5S)-1-(2,4-dichlorophenyl)-5-hydro hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1, 2,4-Triazole-3-thione, (1.044)2-[(2R,4S,5R)-1- (2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptane-4 -yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.0 45) 2-[(2R,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy 3H-1,2-dihydro-2,6,6-trimethylheptan-4-yl 4-Triazole-3-thione, (1.046)2-[(2S,4R,5R)-1-(2 ,4-Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptane-4-yl 1,2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.047 )2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy- 2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4- Triazole-3-thione, (1.048)2-[(2S,4S,5R)-1-(2,4 -dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049)2 -[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2, 6,6-Trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-trimethylheptan-4-yl Azole-3-thione, (1.050) 2-[1-(2,4-dichlorophenyl)-5- Hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H- 1,2,4-Triazole-3-thione, (1.051) 2-[2-chloro-4-(2, 4-Dichlorophenoxy)phenyl]-1-(1H-1,2,4-triazole-1-yl (1.052) 2-[2-chloro-4-(4-chlorophenoxy)propan-2-ol, 1-(1H-1,2,4-triazol-1-yl)butan-2-yl 1.053) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl )phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol , (1.054) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)fluor phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol, (1.055) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenoxy] nyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, ( 1.056) 2-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl )Oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazol 2-{[rel(2R,3R)-3-(2-chlorophenyl)-3-thione, (1.057) nyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4 -Dihydro-3H-1,2,4-triazole-3-thione, (1.058)2-{[r el(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl )Oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazol Ru-3-thione, (1.059) 5-(4-chlorobenzyl)-2-(chloromethyl)- 2-Methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentano , (1.060) 5-(arylsulfanyl)-1-{[3-(2-chlorophenyl )-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1, 2,4-Triazole, (1.061) 5-(arylsulfanyl)-1-{[rel( 2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxy Silane-2-yl]methyl}-1H-1,2,4-triazole, (1.062) 5-( arylsulfanyl)-1-{[rel(2R,3S)-3-(2-chlorophenyl)- 2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2, 4-Triazole, (1.063) N'-(2,5-dimethyl-4-{[3-(1,1, 2,2-Tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl- N-Methylimidoformamide, (1.064) N'-(2,5-dimethyl-4-{[3 -(2,2,2-trifluoroethoxy)phenyl]sulfanyl}phenyl)-N- N'-(2,5-dimethyl-4- {[3-(2,2,3,3-tetrafluoropropoxy)phenyl]sulfanyl}phenyl N'-(2,5-nyl)-N-ethyl-N-methylimidoformamide, (1.066)N'-(2,5- Dimethyl-4-{[3-(pentafluoroethoxy)phenyl]sulfanyl}phenyl )-N-ethyl-N-methylimidoformamide, (1.067)N'-(2,5-dimethyl Thiol-4-{3-[(1,1,2,2-tetrafluoroethyl)sulfanyl]phenoxy (1.068)N'-(phenyl)-N-ethyl-N-methylimidoformamide 2,5-Dimethyl-4-{3-[(2,2,2-trifluoroethyl)sulfanyl]fluor (1.069)N-ethyl-N-methylimidoformamide '-(2,5-dimethyl-4-{3-[(2,2,3,3-tetrafluoropropyl)s (phenyl)-N-ethyl-N-methylimidoformamide, 1.070)N'-(2,5-dimethyl-4-{3-[(pentafluoroethyl)sulfonyl) (phenyl)phenoxy}phenyl)-N-ethyl-N-methylimidoformamide, (1. 071) N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methyl Imidoformamide, (1.072)N'-(4-{[3-(difluoromethoxy) phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N-methylimide Formamide, (1.073) N'-(4-{3-[(difluoromethyl)sulfanyl ]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoforma mido, (1.074) N'-[5-bromo-6-(2,3-dihydro-1H-indene- 2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylimidophos amide, (1.075)N'-{4-[(4,5-dichloro-1,3-thiazole- 2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylimidoform amide, (1.076)N'-{5-bromo-6-[(1R)-1-(3,5-difluoro (O-phenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyl Imidoformamide, (1.077)N'-{5-bromo-6-[(1S)-1-(3, 5-Difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl- N-Methylimidoformamide, (1.078)N'-{5-bromo-6-[(cis-4 -isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl N'-{5-bromo-6-[(tetrahydrofuran) 4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}- N-Ethyl-N-methylimidoformamide, (1.080)N'-{5-bromo-6- [ 1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N -Ethyl-N-methylimidoformamide, (1.081) Mefentrifluconazole (mefentrifluconazole), (1.082) ipfentrifluconazole Ifentrifluconazole.
[0111] (2) Inhibitors of the respiratory chain in complex I or complex II, e.g., (2.001) beta Nzobindiflupyr, (2.002) bixafen, (2.003) boscalid, (2. 004) Carboxin, (2.005) Fluopyram, (2.006) Flutolanil, ( 2.007) Fluxapyroxad, (2.008) Furametpyr, (2.009) Isoflurane etamide, (2.010) isopyrazam (anti-epimeric enantiomer 1R,4 S,9S), (2.011) isopyrazam (anti-epimeric enantiomer 1S, 4R,9R), (2.012) isopyrazam (anti-epimer racemic compound 1RS ,4SR,9SR), (2.013) isopyrazam (syn-epimer racemic compound (1 RS, 4SR, 9RS) and the anti-epimer racemic compound (1RS, 4SR, 9SR) (2.014) Isopyrazam (mixture of syn-epimer enantiomers 1R,4 S,9R), (2.015) isopyrazam (syn-epimeric enantiomer 1S,4 R,9S), (2.016) isopyrazam (syn-epimer racemic compound 1RS,4 SR,9RS), (2.017) Penflufen, (2.018) Penthiopyrad, (2 .019) pydiflumetofen, (2.020) pyridoxine Diflumid, (2.021) Sedaxane, (2.022) 1,3-Dimethyl-N-(1, 1,3-Trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazo 1,3-Dimethyl-N-[(3R)-1,1, 3-Trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole 4-Carboxamide, (2.024) 1,3-Dimethyl-N-[(3S)-1,1,3- Trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4- Carboxamide, (2.025) 1-Methyl-3-(trifluoromethyl)-N-[2' -(Trifluoromethyl)biphenyl-2-yl]-1H-pyrazole-4-carboxamide Mido, (2.026) 2-fluoro-6-(trifluoromethyl)-N-(1,1,3- Trimethyl-2,3-dihydro-1H-inden-4-yl)benzamide, (2.02 7) 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3- Dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2 .028) 3-(difluoromethyl)-1-methyl-N-[(3R)-1,1,3-trifluoromethyl] Methyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide Voxamide, (2.029) 3-(difluoromethyl)-1-methyl-N-[(3S)- 1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyra 3-(difluoromethyl)-N-(7-fluorophenyl)-4-carboxamide, (2.030) Fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1 -Methyl-1H-pyrazole-4-carboxamide, (2.031) 3-(difluoromethyl (3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro- 1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, ( 2.032) 3-(Difluoromethyl)-N-[(3S)-7-fluoro-1,1,3- Trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyra 2,033-5,8-difluoro-N-[2-(2-fluorophenyl) Fluoro-4-{[4-(trifluoromethyl)pyridin-2-yl]oxy}phenyl) Ethyl]quinazolin-4-amine, (2.034) N-(2-cyclopentyl-5-fluoro (Orobenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1- Methyl-1H-pyrazole-4-carboxamide, (2.035)N-(2-tert- Butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5- Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.036)N-( 2-tert-Butylbenzyl)-N-cyclopropyl-3-(difluoromethyl)-5 -Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.037)N- (5-Chloro-2-ethylbenzyl)-N-cyclopropyl-3-(difluoromethyl) -5-Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) N-(5-chloro-2-isopropylbenzyl)-N-cyclopropyl-3-(difluoro (2-fluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide .039)N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrachloromethylene Hydro-1,4-methanonaphthalene-5-yl]-3-(difluoromethyl)-1-methyl 1H-pyrazole-4-carboxamide, (2.040)N-[(1S,4R)-9 -(Dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalene- 5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxylate amide, (2.041) N-[1-(2,4-dichlorophenyl)-1-methoxypropane 3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxylate Voxamide, (2.042) N-[2-chloro-6-(trifluoromethyl)benzyl] -N-Cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H- Pyrazole-4-carboxamide, (2.043)N-[3-chloro-2-fluoro-6 -(trifluoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl) -5-Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N-[5-chloro-2-(trifluoromethyl)benzyl]-N-cyclopropyl-3- (Difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide mido, (2.045) N-cyclopropyl-3-(difluoromethyl)-5-fluoro- 1-Methyl-N-[5-methyl-2-(trifluoromethyl)benzyl]-1H-pyrazo N-Cyclopropyl-3-(difluoromethyl) N-(2-fluoro-6-isopropylbenzyl)-5-fluoro-1-methyl- 1H-Pyrazole-4-carboxamide, (2.047) N-Cyclopropyl-3-(di Fluoromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1 -Methyl-1H-pyrazole-4-carboxamide, (2.048) N-cyclopropyl -3-(Difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1- Methyl-1H-pyrazole-4-carbothioamide, (2.049) N-cyclopropyl -3-(Difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1- Methyl-1H-pyrazole-4-carboxamide, (2.050) N-cyclopropyl- 3-(Difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzene (2.051)N-cyclohexyl)-1-methyl-1H-pyrazole-4-carboxamide 3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)propyl )-5-Fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.052 )N-Cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl (2. 053) N-Cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methyl) (benzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, 2.054) N-Cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl) -3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide Voxamide, (2.055) N-cyclopropyl-N-(2-cyclopropyl-5-methyl (1-Benzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazo N-cyclopropyl-N-(2-cyclopropyl) (1-Benzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazo Le-4-carboxamide.
[0112] (3) Inhibitors of the respiratory chain at complex III, for example (3.001) Ametoctra Jin, (3.002) Amisulfurbrom, (3.003) Azoxystrobin, (3.00 4) Coumethoxystrobin, (3.005) Moxystrobin, (3.006) Cyazofamid, (3.007) Dimoxystrobin , (3.008) Enoxastrobin, (3.009) Famoxadone, (3.010) Fenamidon, (3.011) Flufenoxystrobin obin), (3.012) fluoxastrobin, (3.013) kresoxime-methy le, (3.014) metominostrobin, (3.015) orysastrobin, (3.01 6) Picoxystrobin, (3.017) Pyraclostrobin, (3.018) Pyramet Strobin, (3.019) pyraoxystrobin, (3.020) trifloxystrobin Bin, (3.021)(2E)-2-{2-[({[(1E)-1-(3-{[(E)- 1-Fluoro-2-phenylvinyl]oxy}phenyl)ethylidene]amino}oxy) methyl]phenyl}-2-(methoxyimino)-N-methylacetamide, (3.022 )(2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl ]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3 .023)(2R)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl} -2-Methoxy-N-methylacetamide, (3.024)(2S)-2-{2-[(2 ,5-Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide (3.025) (3S,6S,7R,8R)-8-benzyl-3-[({3-[(isopropyl Sobutyryloxy)methoxy]-4-methoxypyridin-2-yl}carbonyl)amino ]-6-Methyl-4,9-dioxo-1,5-dioxonan-7-yl 2-methylpropionate Panoate, (3.026) 2-{2-[(2,5-dimethylphenoxy)methyl]phenanthate N-(3-ethyl-3-methyl-2-methoxy-N-methylacetamide, (3.027) N-(3-ethyl-3-methyl-2-methoxy-N-methylacetamide ,5,5-trimethylcyclohexyl)-3-formamido-2-hydroxybenzamide (3.028)(2E,3Z)-5-{[1-(4-chloro-2-fluorophenyl )-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethyl Lupent-3-enamide, (3.029) {5-[3-(2,4-dimethylphenyl) -1H-pyrazol-1-yl]-2-methylbenzyl}carbamate methyl.
[0113] (4) Mitosis and cell division inhibitors, for example, (4.001) Carbendazim, ( 4.002) Diethofencarb, (4.003) Ethaboxam, (4.004) Fluo Picolide, (4.005) Pencycuron, (4.006) Thiabendazole, (4.00 7) Thiophanate-methyl, (4.008) Zoxamide, (4.009) 3-chloro- 4-(2,6-difluorophenyl)-6-methyl-5-phenylpyridazine, (4.0 10) 3-Chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl) -6-Methylpyridazine, (4.011) 3-chloro-5-(6-chloropyridine-3- yl)-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.0 12) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl) )-1,3-Dimethyl-1H-pyrazol-5-amine, (4.013) 4-(2-bromo 2-bromo-6-fluorophenyl)-N-(2-bromo-4-fluorophenyl)-1,3-di Methyl-1H-pyrazol-5-amine, (4.014) 4-(2-bromo-4-fluoro (2-bromophenyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazole-5 -Amine, (4.015) 4-(2-bromo-4-fluorophenyl)-N-(2-chloro (4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, .016) 4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)- 1,3-Dimethyl-1H-pyrazol-5-amine, (4.017) 4-(2-bromo- 4-Fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pi 4-(2-chloro-4-fluorophenyl)-N -(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine , (4.019) 4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6- Fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.020 ) 4-(2-chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3- Dimethyl-1H-pyrazol-5-amine, (4.021) 4-(2-chloro-4-fluoro (2-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazole -5-Amine, (4.022) 4-(4-chlorophenyl)-5-(2,6-difluoro phenyl)-3,6-dimethylpyridazine, (4.023)N-(2-bromo-6-fluoro (2-chloro-4-fluorophenyl)-1,3-dimethyl-1H -Pyrazol-5-amine, (4.024) N-(2-bromophenyl)-4-(2-chlorophenyl) (4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, 4.025) N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4 -fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine.
[0114] (5) Compounds with multi-site activity, e.g., (5.001) Bordeaux mixture, (5.0 02) Captafol, (5.003) Captan, (5.004) Chlorothalonil (ch lorthalonil), (5.005) copper hydroxide, (5.006) copper naphthenate, ( 5.007) Copper oxide, (5.008) Basic copper chloride, (5.009) Copper(2+) sulfate, ( 5.010) Dithianon, (5.011) Dodine, (5.012) Folpet, (5.0 13) Mancozeb, (5.014) Maneb, (5.015) Metiram, (5.016) Methiram Thiram zinc (zinc metiram), (5.017) oxine copper (copper oxine), (5.018) propineb, (5.019) sulfur and sulfur agents, e.g. Calcium sulfide, (5.020) thiuram, (5.021) zineb, (5.022) zira (5.023) 6-Ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo[ 3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carboxylate Carbonitrile.
[0115] (6) Compounds capable of inducing host defenses, e.g. (6.001) acibenzolar-S -Methyl, (6.002) Isotianil, (6.003) Probenazole, (6.004 )Tiadinil.
[0116] (7) Inhibitors of amino acid and / or protein biosynthesis, e.g. (7.001) cyclohexyl Prodinil, (7.002) Kasugamycin, (7.003) Kasugamycin hydrochloride hydrate (7.004) oxytetracycline, (7.005) pyrimethanil, (7.00 6) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinol (1-phenyl)quinoline.
[0117] (8) ATP production inhibitors, for example, (8.001) silthiofam.
[0118] (9) Cell wall synthesis inhibitors, for example, (9.001) benthiavalicarb, (9.00 2) Dimethomorph, (9.003) Flumorph, (9.004) Iprovalicarb, (9 .005) Mandipropamid, (9.006) Pyrimorph, (9 .007) Valifenalate, (9.008) (2E)-3-(4-tert-butyl ether (phenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)propionate Per-2-en-1-one, (9.009)(2Z)-3-(4-tert-butylphenyl (2-chloropyridin-4-yl)-1-(morpholin-4-yl)propanol 2-en-1-on.
[0119] (10) Inhibitors of lipid and membrane synthesis, for example, (10.001) propamocarb, ( 10.002) Propamocarb hydrochloride, (10.003) Tolclofos-methyl.
[0120] (11) Melanin biosynthesis inhibitors, for example, (11.001) tricyclazole, (1 1.002) 2,2,2-trifluoroethyl {3-methyl-1-[(4-methylbenzoyl) yl)amino]butan-2-yl}carbamate.
[0121] (12) Nucleic acid synthesis inhibitors, for example, (12.001) benalaxyl, (12.002 ) Benalaxyl-M (chiralaxyl), (12.003) Metalaxyl, (12.004 ) Metalaxyl-M (mefenoxam).
[0122] (13) Signal transduction inhibitors, for example (13.001) fludioxonil, (13 .002) Iprodione, (13.003) Procymidone, (13.004) Proquinazid , (13.005) quinoxyfen, (13.006) vinclozolin.
[0123] (14) Compounds capable of acting as decouplers, e.g. (14.001) fluazide Nam, (14.002) Meptylzinocap.
[0124] (15) Further compounds, such as (15.001) abscisic acid, (15.002 ) Benthazole, (15.003) Bethoxadin, (15.004) Capsimycin ( capsimycin), (15.005) carvone, (15.006) chinomethionine , (15.007) khuraneb, (15.008) cyflufenamid, (15.009 ) Cymoxanil, (15.010) Cyprosulfamide, (15.011) Flutianil , (15.012) fosetyl-aluminium, (15.013) fosetyl-calcium, (15.014) Fosetyl sodium, (15.015) Methyl isothiocyanate, ( 15.016) Metrafenone, (15.017) Mildiomycin, (15.018) ) Natamycin, (15.019) Nickel dimethyldithiocarbamate, (15.02 0) Nitrothal-isopropyl, (15.021) Oxamocarb ), (15.022) oxathiapiproline, (15.023) oxyfenthiine (o xyfenthiin), (15.024) Pentachlorophenol and salts, (15.0 25) Phosphonic acids and their salts (15.026) Propamocarb-fosetylate (pro pamocarb-fosetylate), (15.027) pyriophenone (Craza phenone (chlazafenone), (15.028) tebufloquine, (15.0 29) Tecloftalam, (15.030) Tornifanide, (15.031) 1-(4- {4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2- oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)- 2-[5-Methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethano 1-(4-{4-[(5S)-5-(2,6-difluorophenyl )-4,5-Dihydro-1,2-oxazol-3-yl]-1,3-thiazole-2- yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H -pyrazol-1-yl]ethanone, (15.033) 2-(6-benzylpyridine-2 -yl)quinazoline, (15.034) 2,6-dimethyl-1H,5H-[1,4]dithi Ino[2,3-c:5,6-c']dipyrrole-1,3,5,7(2H,6H)-tetrahydrofuran 2-[3,5-bis(difluoromethyl)-1H-pyrazole-1 -yl]-1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl 4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazole-2 -yl)piperidin-1-yl]ethanone, (15.036) 2-[3,5-bis(difluorophenyl) 4-(4-{5-[2-chloro-4-methylphenyl]-1H-pyrazol-1-yl)- -6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2- oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]e Tanone, (15.037) 2-[3,5-bis(difluoromethyl)-1H-pyrazole -1-yl]-1-[4-(4-{5-[2-fluoro-6-(prop-2-yn-1- 4,5-dihydro-1,2-oxazol-3-yloxy)phenyl]-1, 3-Thiazol-2-yl)piperidin-1-yl]ethanone, (15.038) 2-[ 6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazo Phosphorus, (15.039) 2-{(5R)-3-[2-(1-{[3,5-bis(difluoro) 1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3 -thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3 -Chlorophenyl methanesulfonate, (15.040)2-{(5S)-3-[2- (1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl }piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1, 2-Oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.0 41) 2-{2-[(7,8-difluoro-2-methylquinolin-3-yl)oxy]- 6-Fluorophenyl}propan-2-ol, (15.042) 2-{2-fluoro- 6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propane- 2-ol, (15.043) 2-{3-[2-(1-{[3,5-bis(difluoromethyl) acetyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thi Azole-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlor 2-{3-[2-(1-{[3, 5-Bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidine- 4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol {5-yl}phenyl methanesulfonate, (15.045) 2-phenylphenol and its salts, (15.046) 3-(4,4,5-trifluoro-3,3-dimethyl- 3,4-Dihydroisoquinolin-1-yl)quinoline, (15.047) 3-(4,4- Difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.048) 4-Amino-5-fluoropyrimidin-2-ol (tautomeric form: 4 -amino-5-fluoropyrimidin-2(1H)-one), (15.049) 4-oxo -4-[(2-phenylethyl)amino]butyric acid, (15.050) 5-amino-1,3, 4-Thiadiazole-2-thiol, (15.051) 5-chloro-N'-phenyl-N '-(Prop-2-yn-1-yl)thiophene 2-sulfonohydrazide, (15.0 52) 5-Fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine , (15.053) 5-fluoro-2-[(4-methylbenzyl)oxy]pyrimidine- 4-Amine, (15.054) 9-Fluoro-2,2-dimethyl-5-(quinoline-3- (15.055) buta-3-yl)-2,3-dihydro-1,4-benzoxazepine, Yn-1-yl{6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl) (phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.056) (2Z)-3-amino-2-cyano-3-phenylacrylate ethyl ester (15.057) Phenazine-1-carboxylic acid, (15.058) 3,4,5-trihydro Propyloxybenzoate, (15.059) Quinolin-8-ol, (15.060) Quinolin-8-ol Norlin-8-ol sulfate (2:1), (15.061){6-[({[(1-methyl 1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl ]pyridin-2-yl}carbamate tert-butyl, (15.062) 5-fluoro -4-Imino-3-methyl-1-[(4-methylphenyl)sulfonyl]-3,4-dihydro Dropyrimidin-2(1H)-one.
[0125] Biological pesticides as mixture components The active ingredient combination of the present invention may be combined with a biological pesticide.
[0126] Biological pesticides include, in particular, bacteria, fungi, yeasts, plant extracts and e.g. These include products formed by microorganisms (e.g., proteins and secondary metabolites).
[0127] Biological pesticides include bacteria, e.g., spore-forming bacteria, root-colonizing These include bacteria that produce fungi and bacteria that act as biological insecticides, fungicides or nematicides.
[0128] The above-mentioned bacteria are used or can be used as biological pesticides. An example is the following: Bacillus amyloliquefaciens iens strain FZB42 (DSM 231179) or Bacillus cereus (Bac illus cereus, in particular B. cereus strain CN CM I-1562, or Bacillus firmus strain I-1582 (accession number CNCM I-1582), or Bacillus pumilus (B acillus pumilus), in particular the strain GB34 (accession number ATCC 7008 14) and strain QST2808 (accession no. NRRL B-30087), or Bacillus Bacillus subtilis, in particular the strain GB03 (accession no. ATCC SD-1397, or Bacillus subtilis tilis strain QST713 (accession number NRRL B-21661), or Bacillus Bacillus subtilis strain OST 30002 (accession number NRRL B-50421), Bacillus thuringiensis uringiensis), especially Bacillus thuringiensis subsp. israelensis B. thuringiensis subspecies israelensi s) (antigen type H-14) strain AM65-52 (accession number ATCC 1276), or Bacillus thuringiensis subspecies Aizawai (B. thuringiensis subsp. aizawai), in particular, strain ABTS-1857 (SD-1372), It is B. thuringiensis subsp. kurstaki. s subsp. kurstaki) strain HD-1, or Bacillus thuringiensis Subspecies tenebrionis (B. thuringiensis subsp. tene brionis strain NB 176 (SD-5428), Pasteuria penetrans (P asteuria penetrans, Pasteuria spp. pp.) (Rotylenchulus reniformis) rmis)-PR3 (Accession No. ATCC SD-5834), Streptomyces Streptomyces microflavus strain AQ612 1 (=QRD 31.013, NRRL B-50550), Streptomyces galli Streptomyces galbus strain AQ 6047 (accession number NRR L 30232).
[0129] Fungi and yeasts that are or can be used as biological pesticides Examples of classes are: Beauveria bassiana, specifically strain ATCC 74040, Coniothyrium minita ns), in particular strain CON / M / 91-8 (accession no. DSM-9660), Lecanisiliu Lecanicillium spp., in particular strain HRO LEC 12, Lecanicillium spp. Lecanicillium lecanii (formerly known as Known as Verticillium lecanii In particular, strain KV01, Metarhizium anisopliae anisopliae, in particular strain F52 (DSM3884 / ATCC 90448) , Metschnikowia fructico la), in particular strain NRRL Y-30752, Paecilomyces fumosoroseus (Pae cilomyces fumosoroseus (New: Isaria fumosoroseus (I saria fumosorosea), in particular the strain IFPC 200613 or the strain Ap opka 97 (accession number ATCC 20874), Paecilomyces lilacinus (P aecilomyces lilacinus), especially Paecilomyces lilacinus ( P. lilacinus) strain 251 (AGAL 89 / 030550), Talaromyces Talaromyces flavus, especially strain V117b, Trichoderma Trichoderma atroviride, specifically, strain SC 1 (Accession No. CBS 122089), Trichoderma harzianum (Trichod erma harzianum), especially Trichoderma harzianum rifai (T. harzianum rifai)T39 (accession number CNCM I-952).
[0130] Viruses that are or could be used as biological pesticides An example is the following: Adoxophyes orana granulosis virus (GV) , Cydia pomonella granulosis virus (GV), Nicotiana tabacum Helicoverpa armigera nuclear polyhedrosis virus (NPV), Spodoptera exigua mNPV, Fall armyworm (Spodoptera frugiperda) mNPV, Egyptian armyworm (Afri can cotton leafworm)(Spodoptera littoral is) NPV.
[0131] It is added as an "inoculum" to a plant or plant part or plant organ and its characteristics are Bacteria and fungi that promote plant growth and plant health through certain properties are also included. Examples include: Agrobacterium spp., Azorhizobium Azorhizobium caulinodans, Azospirill Azospirillum spp., Azotobacter spp. cter spp., Bradyrhizobium spp. .), Burkholderia spp., especially Burkholderia Burkholderia cepacia (formerly known as Pseudomonas cepacia) Monas cepacia (formerly known as Pseudomonas cepacia), Gigaspora spp. or Gigaspora monosporum gaspora monosporum, Glomus spp., Laccaria spp., Lactobacillus buchneri obacillus buchneri, Paraglomus species spp.), Pisolithus tinctorus , Pseudomonas spp., Rhizobium spp. zobium spp., especially Rhizobium trifoli ifolii, Rhizopogon spp., Scleroderma Scleroderma spp., Suillus spp. ), Streptomyces spp.
[0132] Plant extracts that are or can be used as biological pesticides and products formed by microorganisms, which include proteins and secondary metabolites. ) is the following: Garlic (Allium sativum), Wormwood (Artemisia abs inthium, azadirachtin, Biokeeper WP, Cassia nigricans, Celastrus Celastrus angulatus, American antler plant henopodium anthelminticum), chitin, Armour-Ze n, Dryopteris filix-mas, Horsetail (Equi setum arvense), Fortune Aza, Fungastop, Hea ds Up (Quinopodium quinoa saponin extract), insect repellent Chrysanthemum (pyrethrum / pyrethrins), Surinam bittersweet (Quassia amara), Quercus, Quillaja, Rega lia, ("Requiem TM Insecticide), rotenone, riania / Ryanodine, Symphytum officinale, Artemisia (Tanacetum vulgare), Thymol, Triact 70, TriCo n, Tropaeulum majus, Urticaria dioica a dioica), Veratrin, European mistletoe (Viscum album ), Brassicaceae extracts, in particular rapeseed flour or mustard flour End.
[0133] Safeners as blend components The active ingredient combination of the present invention may also contain safeners, e.g. benoxacor, cloquinthacea, -mexyl, cyometrinil, cyprosulfamide, dichlormid, fenclo Flurazole (-ethyl), Fenclorim, Flurazole, Fluxofenim, Furilazol ru, isoxadifen (-ethyl), mefenpyr (-diethyl), naphthalic anhydride, Oxabetrinil, 2-Methoxy-N-({4-[(methylcarbamoyl)amino]phenyl 4-(dichloro)benzamide (CAS 129531-12-0), Acetyl)-1-oxa-4-azaspiro[4.5]decane (CAS 71526-07 -3), 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (CAS 52836-31-4) and the like.
[0134] Plants and plant parts According to the invention, all plants and plant parts can be treated, where the plants are desirable and undesirable wild or crop plants (including naturally occurring crop plants); All plants and plant populations such as cereals (wheat, rice, triticale, Barley, rye, oats), corn, soybeans, potatoes, sugar beets, sugar Squid, tomato, pepper, cucumber, melon, carrot, watermelon, onion, lettuce, Spinach, leeks, beans, Brassica oleracea) (e.g., cabbage) and other vegetable species, cotton, tobacco, rapeseed, etc. and further, fruit plants (wherein the fruits are apples, pears, citrus fruits and grapes). Crop plants are understood to mean those obtained by conventional breeding and optimization methods. The plant may be a plant capable of producing the desired product or may be obtained by biotechnological and genetic engineering methods. The plant may be a plant that can be cultivated or a plant that can be obtained by a combination of the above methods. Such crop plants also include transgenic plants, It also includes plant varieties which may or may not be protected by plant breeders' rights. Plants include all stages of development, such as seeds, seedlings, and young plants (immature plants). The term "plant parts" should be understood to mean the shoots, shoots, shoot root ... It is understood to mean all above-ground and below-ground parts and organs of a plant, such as leaves, flowers and roots. It should be understood that examples which may be mentioned are leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds. , and further including roots, tubers and rhizomes. Parts and vegetative propagation organs erial and generative propagation terial, e.g., cuttings, tubers, rhizomes, slips and The parts of a plant also include the stems, stems, and seeds.
[0135] The treatment according to the invention of plants and plant parts with the active ingredient combinations according to the invention can be carried out in a conventional manner. By practical treatment methods, such as immersion, spraying, vaporization, fogging, scattering, etc. The compounds may be administered directly to plants or plant parts by application, coating, injection, etc., or by injecting the compounds into the surrounding environment of the plants and plant parts. This is done by affecting the enclosure, habitat or storage space of the plant, and also by affecting the reproductive organs. In the case of agation material, especially in the case of seeds, one or more This can also be achieved by applying
[0136] As already mentioned above, all plants and their parts can be treated according to the invention. In a preferred embodiment, wild plant species and plant cultivars, or hybrids or progeny, Plant species and plant cultivars obtained by conventional biological breeding methods such as rotoplast fusion; In yet another preferred embodiment, the conventional method is used where appropriate. Transgenic plants obtained by genetic engineering methods in combination with conventional methods and Processing of plant varieties (genetically modified organisms) and their parts. The term "parts" " or "parts of plants" or "plants" t parts) have already been explained above. According to the invention, it is particularly preferred , plants of commercially available conventional plant varieties or conventional plant varieties in use, respectively Plant varieties are developed by conventional breeding or by mutagenesis or by recombinant DNA techniques. This is understood to mean the plants having the obtained new properties ("traits"). The plant may be a variety, cultivar, biotype or genotype.
[0137] Transgenic plants Receiving genetic material through genetic modification that confers particularly advantageous or beneficial characteristics ("traits") to a plant All plants collected are preferred transgenic plants to be treated according to the invention or Examples of such traits include plant varieties (obtained by genetic engineering). Improved growth, improved tolerance to high or low temperatures, drought or the presence of Improved tolerance to salinity levels in plants, increased flowering ability, and improved ease of harvesting. , accelerated maturation, increased yield, improved quality of the harvested product and / or improved improved nutritional value, improved storability and / or improved processability of the harvested products. Yet another particularly important example of such a property is the ability to inhibit pests and harmful microorganisms (e.g. insects). Plant enhancement against insects (e.g., spiders, arachnids, nematodes, mites, slugs and snails) resistance to toxins produced in plants, especially Bacillus thuringiensis Genetic material derived from Bacillus thuringiensis, e.g. Genes CryIA(a), CryIA(b), CryIA(c), CryIIA, Cry IIIA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CryIF and combinations thereof] toxins formed in the plant body, causing insect pests and harmful microorganisms (e.g. insects, arachnids, nematodes, mites, slugs and snails) Improved resistance of plants to plant pathogenic fungi, bacteria and / or viruses. Improved plant resistance to pathogens, e.g. systemic acquired resistance (SAR), systemin (sys temin), phytoalexins, inducers, and resistance genes and their expressed Anti-plant control by proteins and toxins against plant pathogenic fungi, bacteria and / or viruses Improved resistance of the herbicidal agent and, furthermore, the use of certain herbicidal active ingredients (e.g., imidazolinones, Improved plant tolerance to sulfonylureas, glyphosate or phosphinothricin (e.g., the "PAT" gene). A gene that confers a desired characteristic ("trait") of interest. can also be present in combination with one another in the transgenic plant. Examples of such transgenic plants include important crop plants, such as cereals (wheat, wheat, triticale, barley, rye, oats), corn, soybeans, potatoes , sugar beets, sugarcane, tomatoes, peas and other kinds of vegetables, cotton, tobacco, rapeseed Seeds, and also fruit plants, where the fruits include apples, pears, citrus fruits and blueberries. Examples of the crops that are used include corn, soybeans, wheat, rice, and potatoes. Of particular importance are wheat, cotton, sugarcane, tobacco and rapeseed. ) is a list of the effects of plants on insects, arachnids, nematodes, and slugs and snails. Improved resistance.
[0138] Crop protection - types of treatment The treatment of plants and plant parts with the active ingredient combinations according to the invention can be carried out in a manner similar to conventional treatment methods. Thus, for example, immersion, spraying, atomization, irrigation, vaporization, dusting, fume, scattering, foaming, painting , spreading-on, injection, drenching, point The compounds may be applied directly to the plants, such as by drip irrigation, or may be applied to the surroundings, surrounding areas, or surrounding the plants and plant parts. This is done by influencing the breathing environment or storage space, and also by the propagation organs. In the case of fertilization materials, especially in the case of seeds, furthermore, dry seed treatment, wet Also by seed treatment, slurry treatment, covering, or coating with one or more films. Furthermore, the active ingredient combination of the present invention can be applied by ultra-low vol spraying. It is also possible to use the composition by the ume method, or the use form or the present invention It is also possible to inject the active ingredient combination itself into the soil.
[0139] A preferred direct treatment of plants is foliar application, for example with the active ingredient combinations of the invention. In this case, the frequency and amount of application should be determined based on the occurrence of the pest. It should be adapted according to the level.
[0140] The good insecticidal and / or acaricidal and / or nematicidal action of the active ingredient combinations according to the invention is due to It can be seen from the examples below that the individual active ingredients show weaknesses in their effectiveness. However, the combination exhibits effects that go beyond the simple sum of the effects.
[0141] When the effect of the active ingredient combination exceeds the sum of the effects of the active ingredients when applied individually Whenever possible, synergistic effects exist between insecticides, nematicides and acaricides.
[0142] Formula for the killing power of a combination of two active ingredients The expected activity of a given combination of two active ingredients is given by S.R. Colby ( "Calculating Synergistic and Antagonist" c Responses of Herbicide Combinations”, W. According to EEDS 15, 20-22, 1967, it can be calculated as follows: : X is the percentage of untreated soil with active ingredient A applied at a rate of mg / ha or at a concentration of m ppm. is the kill rate expressed as a % of the control, Y is the percentage of untreated plants when active ingredient B is applied at a rate of ng / ha or at a concentration of n ppm. is the kill rate expressed as a % of the control, and E is the concentration of active ingredients A and B at rates of m and ng / ha or at concentrations of m and n ppm. is the kill rate expressed as % of the untreated control when That is
number
[0143] If the actual kill rate is greater than the calculated kill rate (E), then the effect of the combination is superadditive. , i.e. there is a synergistic effect. EXAMPLES
[0144] Example A Meloidogyne incognita test Solvent: 125.0 parts by weight acetone To prepare a suitable preparation of the active ingredient, 1 part by weight of the active ingredient is mixed with the above amount of solvent. The resulting concentrate is then diluted with water to the desired concentration.
[0145] In a container, add sand, active ingredient solution, and sweet potato root-knot nematode (Meloidogyne incognita egg / larvae suspension and lettuce seeds. The lettuce seeds germinate. The plant grows. Galls form on the roots.
[0146] After a desired period of time, the nematicidal efficacy (%) is determined by the formation of galls. 0% means that no galls were observed; 0% means that the number of galls on the treated plants was The values obtained correspond to the number of galls in the control without galls. Be encouraged.
[0147] In this test, the following active ingredient combinations according to the present application were found to be more effective than those applied individually: The components showed synergistically enhanced efficacy compared to: [Table 3]
[0148] Example B Meloidogyne incognita test Solvent: 125.0 parts by weight acetone To prepare a suitable preparation of the active ingredient, 1 part by weight of the active ingredient is mixed with the above amount of solvent. The resulting concentrate is then diluted with water to the desired concentration.
[0149] In a container, add sand, active ingredient solution, and sweet potato root-knot nematode (Meloidogyne incognita egg / larvae suspension and lettuce seeds. The lettuce seeds germinate. The plant grows. Galls form on the roots.
[0150] After a desired period of time, the nematicidal efficacy (%) is determined by the formation of galls. 0% means that no galls were observed; 0% means that the number of galls on the treated plants was The values obtained correspond to the number of galls in the control without galls. Be encouraged.
[0151] In this test, the following active ingredient combinations according to the present application were found to be more effective than those applied individually: The components showed synergistically enhanced efficacy compared to: [Table 4]
Claims
1. [In the formula, W and Y are independently hydrogen, C 1 -C 4 alkyl, chlorine, bromine, iodine or fluorine, X is C 1 -C 4 -Alkyl, C 1 -C 4 -alkoxy, chlorine, bromine or iodine, D is hydrogen or methyl; A, B and the carbon atom to which they are attached are C 3 -C 6 -cycloalkyl, where one ring member may be replaced by nitrogen and the ring is 1 -C 4 -alkoxy), or A, B and the carbon atom to which they are attached are C 1 -C 4 -Alkyl- or C 1 -C 4 -Alkoxy-C 1 -C 2 -C substituted with an alkyl-optionally substituted alkylenedioxy group 3 -C 6 -cycloalkyl (the alkylenedioxy group together with the carbon atom to which it is attached forms a 5- or 6-membered ketal); G is hydrogen (a) or the group: [During the ceremony, E is a metal ion or an ammonium ion; M is oxygen or sulfur; R 1 is a straight or branched C 1 -C 6 - alkyl, R 2 is a straight or branched C 1 -C 6 -alkyl] It is one of the Compound and (B-2) Thioxazaphene: Compound A combination of active ingredients comprising:
2. The compound of formula (I) has the following definition: W is methyl; X is chlorine or methyl; Y is chlorine, bromine or methyl; D is hydrogen; A, B and the carbon atom to which they are attached are saturated C alkylene dioxy groups substituted with alkylenedioxy groups. 6 -cycloalkyl (the alkylenedioxy group together with the carbon atom to which it is attached forms a 5- or 6-membered ketal); G is hydrogen (a) or the group: [During the ceremony, M is oxygen; E is one metal ion equivalent or an ammonium ion; R 1 is a linear or branched C 1 -C 4 - alkyl, R 2 is a linear or branched C 1 -C 4 -alkyl] It is one of 2. The active ingredient combination according to claim 1, having the formula:
3. The compound of formula (I) may be the compound:
2. The active ingredient combination according to claim 1, selected from:
4. A compound of the following formula (I-2) (I-2) and compound (B-2).
5. 5. Use of an active ingredient combination according to any one of claims 1, 2, 3 and 4 for controlling pests.
6. 5. Use of an active ingredient combination according to any one of claims 1, 2, 3 and 4 for controlling nematodes.
7. Use of an active ingredient combination according to any one of claims 1, 2, 3 and 4 in transgenic plants.
8. A method for controlling pests, comprising applying an active ingredient combination according to any one of claims 1, 2, 3 and 4 to pests and / or their habitats, Methods that exclude surgical or therapeutic treatment methods of the human body and diagnostic methods performed on the human body.
9. 5. A process for the preparation of an insecticidal, nematicidal and / or acaricidal composition, which comprises mixing an active ingredient combination according to any one of claims 1, 2, 3 and 4 with a extender and / or a surfactant.
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