Polarizer Film

Abstract

A multilayer optical film usable as a polarizer or mirror film and capable of being incorporated into an optical stack, the optical film comprising a plurality of more than 50 alternating polymeric first and second interference layers disposed between and integrally formed with first and second skin layers, each of the first and second interference layers having an average thickness of less than 250 nm, the first and second interference layers and the first and second skin layers being a composition comprising polyester.

Description

[Technical field]

[0001] FIELD OF THE DISCLOSURE This disclosure relates to multilayer optical films. [Background technology]

[0002] Polymer films are used in a wide variety of applications. One particular use of polymer films is as optical films that control light. Examples of optical films that control light include mirrors and reflective polarizers that reflect light in a given polarization state or wavelength range. Such reflective films are used, for example, in liquid crystal displays with backlights to increase brightness. A reflective polarizing film can be placed between the user and the backlight to recycle the polarization state that results in the image, thereby increasing brightness. A mirror film can be placed behind the backlight to reflect light back toward the user, thereby increasing brightness. Another use of polarizing films is to reduce luminosity and glare in articles such as sunglasses.

[0003] One type of polymer that is useful for making polarizer or mirror films is polyester. An example of a polyester-based polarizer is a stack of polyester layers of different compositions. One configuration of this stack includes a first set of birefringent layers and a second set of layers with an isotropic refractive index. The second set of layers alternates with the birefringent layers to form a series of interfaces that reflect light. Summary of the Invention

[0004] Disclosed herein is a multilayer optical film (MOF) that can be used as a reflective polarizer or mirror film and can be incorporated into an optical stack. In some embodiments, the optical film (100) comprises more than 50 alternating polymeric first and second interference layers (10) and (20) disposed between and integrally formed with a first skin layer (30) and a second skin layer (40), each of which has an average thickness less than about 250 nm. The first and second skin layers have a first composition and a second composition, respectively, that include polyester. The second skin layer includes at least 70% by weight of polyethylene terephthalate (PET) and has an average thickness greater than about 50 micrometers. For substantially perpendicular incident light (50) and for each wavelength within a predetermined wavelength range (60) spanning at least about 430 nm to at least about 600 nm, the optical film has an optical reflectivity of at least 40% for a first polarization state (Px). The adjacent first and second interference layers have planar indices of refraction of n1x and n2x along the first polarization state, n1y and n2y along an orthogonal second polarization state (Py), and n1z and n2z along a z-axis orthogonal to the first and second polarization states, respectively. For at least one wavelength (61) within the predetermined wavelength range, n1x is at least 0.14 greater than each of n1y and n1z, the difference between n1y and n1z is greater than about 0.07, the maximum difference between n2x, n2y, and n2z is less than about 0.01, and the difference between n1x and n2x is greater than 0.14.

[0005] Also disclosed is an optical laminate. In some embodiments, the optical laminate (200) comprises a structured film (110) including a plurality of structures (111), each structure including opposing small faces (112, 113) that meet at a top (114), the multilayer optical film described above is disposed on the top of the structures, a first adhesive layer (120) bonds the optical film to the top of the structures, and the optical laminate has a flexural modulus of greater than about 1500 MPa when measured according to the ASTM D790 standard. [Brief description of the drawings]

[0006] The present disclosure may be more fully understood from the following detailed description of various embodiments of the disclosure, taken in conjunction with the accompanying drawings. [Figure 1] FIG. 1 is a cross-sectional view of a multilayer optical film of the present disclosure. [Diagram 2] FIG. 2 is a cross-sectional view of an optical laminate article of the present disclosure.

[0007] While the present disclosure is susceptible to various modifications and alternative forms, certain features have been shown by way of example in the drawings and will be described in detail. It is to be understood, however, that the intention is not to limit the disclosure to the particular embodiments described. On the contrary, the intention is to cover all modifications, equivalents, and alternatives that do not depart from the spirit and scope of the disclosure as defined by the appended claims. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0008] Polymeric films are used in a wide variety of applications. One particular use of polymeric films is as mirrors and reflective polarizers that reflect light in a given polarization state or wavelength range. Such reflective films are used, for example, in liquid crystal displays with backlights to increase brightness. A reflective polarizing film can be placed between the user and the backlight to recycle the polarization state that results in the image, thereby increasing brightness. A mirror film can be placed behind the backlight to reflect light back toward the user, thereby increasing brightness. Another use of polarizing films is to reduce luminosity and glare in articles such as sunglasses.

[0009] One type of polymer that is useful for making polarizer or mirror films is polyester. An example of a polyester-based polarizer is a stack of polyester layers of different compositions. One configuration of this stack includes a first set of birefringent layers and a second set of layers with an isotropic refractive index. The second set of layers alternates with the birefringent layers to form a series of interfaces that reflect light.

[0010] In particular, because the individual layers of the multilayer reflective polarizer film are very thin (typically 55-130 nanometers) and in some cases the number of layers is relatively small, it is often desirable for the multilayer reflective polarizer film to include a relatively thick, rigid outer layer to help increase the stiffness and ease of handling of the film. Typically, a relatively thick, rigid outer layer is laminated to the multilayer reflective polarizer film. Lamination of the outer layer to the multilayer reflective polarizer film has several disadvantages. Lamination is an extra step in the formation of the film article, which can add cost and manufacturing time to the preparation of the film article. Also, lamination can add defects to the film article. In many cases, an adhesive is required to adhere the outer layer to the multilayer reflective polarizer film, which also adds cost to the prepared article, and the presence of the adhesive layer can adversely affect the optical properties of the formed article. In addition, the outer layer is often prepared from a polymeric material, such as polycarbonate or polyester, which tends to add cost to the film article. As mentioned above, the outer layer is relatively thick to provide the desired stiffness to the formed article, and therefore the outer layer constitutes a significant portion of the mass of the formed article.

[0011] For optical films such as mirrors and reflective polarizer films, it is desirable to utilize relatively inexpensive polyester materials. However, polyester materials present problems in achieving the desired optical effects and preparing optical films by coextrusion. Polyethylene terephthalate (PET) is not co-stretchable with typical reflective polarizers (RPs). In typical RPs, the high index optics (HIO) materials are polyethylene naphthalate (PEN) or copolyethylene naphthalate (CoPEN) with a high mole fraction (>75 mol%) of dibasic acid, which is naphthalene dicarboxylate (NDC). When co-stretching PET with RPs, the required temperature is so high (about 137-160°C according to U.S. Pat. No. 5,882,774) that the PET crystallizes before it is stretched. This type of crystallization is often referred to as thermally induced crystallization rather than strain-induced crystallization. This thermally induced crystallized PET is undesirable for several reasons. Thermally induced crystallized PET is hazy due to the presence of large crystallites, tends to break before full stretching when stretched in a tenter, and does not have the excellent mechanical properties (high modulus and crystallinity) of strain hardened PET. Typical temperatures for 1D orientation of reflective polarizers are 137-160°C (based on the example of US Pat. No. 5,882,774 where the HIO is PEN). Multilayer reflective polarizers typically use HIOs made of PEN or CoPEN with 90 mol% or more NDC. This HIO breaks or becomes hazy at low temperatures. Typical 1D orientation temperature for PET is 95°C (see US Pat. No. 9,664,834). Thus, it is clear that there is no overlap between the orientation temperatures used for HIOs that exhibit the high birefringence required for RP and those used for PETs that have good mechanical properties for a stiff film at low cost. Thus, the use of PET in the films of the present disclosure is unexpected.

[0012] In this disclosure, optical films are described that include multilayer reflective polarizer films that include skin layers prepared from PET (polyethylene terephthalate) polyester material and coextruded with optically active microlayers so that extra outer layer lamination is not required. The multilayer reflective polarizer film may be a mirror-like film that reflects essentially all light, or it may be a reflective polarizer film that reflects light of one polarity and transmits light of the orthogonal polarity. The polyester material in the skin layer allows the optical film to be prepared by coextrusion, thus avoiding the additional cost and time of the lamination process. In addition, the relatively low cost PET material reduces the cost of the formed article compared to articles formed with more expensive skin layers. Furthermore, the PET skin layer has stretching properties that are compatible with the optically active layers of the multilayer portion of the film, so that the coextruded article can be stretched to form a film article with desired optical and physical properties.

[0013] For the following defined terms, these definitions shall be applied, unless a different definition is given in the claims or elsewhere in this specification.

[0014] The term "polymer" is understood to include polymers, copolymers (e.g., polymers formed using two or more different monomers), oligomers, and combinations thereof, as well as polymers, oligomers, or copolymers that may be formed in a miscible blend by reaction, such as, for example, coextrusion or transesterification. Both block and random copolymers are included unless otherwise indicated.

[0015] Unless otherwise indicated, all numerical values ​​expressing quantities or properties of ingredients, such as molecular weights and reaction conditions, used above in the specification and claims are to be understood as being modified in all instances by the word "about." Accordingly, unless indicated to the contrary, the numerical parameters set forth in the above specification and appended claims are approximations that may vary depending upon the desired properties sought to be obtained by those of ordinary skill in the art utilizing the teachings of the present disclosure.

[0016] Mole percent, or mol%, and the like, are synonyms that refer to the concentration of a substance as the number of moles of that substance divided by the number of moles of the composition multiplied by 100. Similarly, weight % refers to the weight of a substance in a composition divided by the total weight of the composition multiplied by 100.

[0017] The recitation of numerical ranges by endpoints includes all numbers subsumed within that range (eg, 1 to 5 includes 1, 1.5, 2, 2.75, 3, 3.80, 4, and 5) and any range within that range.

[0018] As used in this specification and the appended claims, the singular forms "a," "an," and "the" include plural referents unless the content clearly dictates otherwise. Thus, for example, reference to a composition containing a "polymer" includes a mixture of two or more polymers. As used in this specification and the appended claims, the term "or" is generally used in its sense including "and / or" unless the content clearly dictates otherwise.

[0019] In the present specification, a multilayer optical film is disclosed. In some embodiments, the multilayer optical film comprises an optically active portion comprising a plurality of alternating polymeric first and second interference layers, the number of layers being greater than 50, and the optically active portion being disposed between and integrally formed with the first and second skin layers. The optical film may also comprise additional layers, as described in detail below.

[0020] The multilayer polymer film of the present disclosure may be used, for example, as an optical reflective polarizer or mirror. The film includes an optical layer with alternating layers of a first interference layer and a second interference layer, and a non-optical layer such as a skin layer. The non-optical layer typically provides protection and stiffness to the film article. The first interference layer is generally a uniaxially or biaxially oriented birefringent polymer layer. The second interference layer may also be a birefringent and uniaxially or biaxially oriented polymer layer. More typically, however, the second interference layer has an isotropic refractive index that is different from at least one of the refractive indices of the first interference layer after orientation. Methods of making and using multilayer polymer films, as well as design considerations, are described, for example, in U.S. Pat. No. 5,882,774 and U.S. Patent Application Publication No. 2001 / 0011779(A1).

[0021] 1 is a cross-sectional view of one embodiment of a multilayer optical film of the present disclosure. The optical film 100 includes a plurality of alternating polymeric first and second interference layers 10 and 20, the number of layers being greater than 50. In some embodiments, the number of layers is greater than 100. The alternating polymeric first and second interference layers 10 and 20 are disposed between and integrally formed with a first skin layer 30 and a second skin layer 40.

[0022] For substantially normally incident light 50, and for each wavelength within a predetermined wavelength range 60 spanning at least about 430 nanometers (nm) to about 600 nm, the optical film has an optical reflectance of at least 40% for the first polarization state (Px). In some embodiments, the predetermined wavelength range spans at least about 400 nm to about 650 nm, at least about 430 nm to about 650 nm, or at least about 400 nm to about 600 nm. In some embodiments, the optical film has an optical reflectance of at least 50%, at least 60%, or even at least 70% for the first polarization state (Px).

[0023] Each of the first and second interference layers has an average thickness less than about 250 nm. The adjacent first and second interference layers have planar indices of n1x and n2x along a first polarization state, n1y and n2y along an orthogonal second polarization state (Py), and n1z and n2z along a z-axis orthogonal to the first polarization state and the second polarization state, respectively. For at least one wavelength 61 within a predetermined wavelength range 60 spanning at least about 430 nm to at least about 600 nm, n1x is at least 0.14 greater than each of n1y and n1z. The difference between n1y and n1z is greater than about 0.07. The maximum difference between n2x, n2y, and n2z is less than about 0.01, and the difference between n1x and n2x is greater than about 0.14.

[0024] The first skin layer 30 has a first composition comprising a polyester, and the first interference layer 10 has a second composition comprising a polyester. In some embodiments, the first composition and the second composition are substantially the same composition. A wide variety of polyesters are suitable for the first and second compositions. The polyesters include carboxylate and glycol subunits and are produced by the reaction of carboxylic acid monomer molecules with glycol monomer molecules. Each carboxylic acid monomer molecule has two or more carboxylic acid or ester functional groups, and each glycol monomer molecule has two or more hydroxy functional groups. The carboxylic acid monomer molecules may all be the same or may be two or more different types of molecules. The same is true for the glycol monomer molecules.

[0025] Suitable carboxylic acid monomer molecules for use in forming the carboxylic acid subunits of the polyester layers include, for example, 2,6-naphthalenedicarboxylic acid and its isomers, terephthalic acid, isophthalic acid, phthalic acid, azelaic acid, adipic acid, sebacic acid, norbornene dicarboxylic acid, bicyclooctane dicarboxylic acid, 1,6-cyclohexane dicarboxylic acid and its isomers, t-butylisophthalic acid, trimellitic acid, sulfonated sodium isophthalate, 4,4'-biphenyl dicarboxylic acid and its isomers, and the lower alkyl esters, e.g., methyl or ethyl esters, of these acids. The term "lower alkyl" in this context refers to C1-C 10 The term "polyester" also includes polycarbonates derived from the reaction of glycol monomer molecules with esters of carbonic acid, and blends of polycarbonates with copolyesters made from the above comonomers.

[0026] Suitable glycol monomer molecules used to form the glycol subunits of the polyester layers include ethylene glycol, propylene glycol, 1,4-butanediol and its isomers, 1,6-hexanediol, neopentyl glycol, polyethylene glycol, diethylene glycol, tricyclodecanediol, 1,4-cyclohexanedimethanol and its isomers, 2-butyl-2-ethyl-1,3-propanediol, 2,2,4-trimethyl-1,3-pentanediol, norbornene diol, bicyclooctanediol, trimethylolpropane, pentaerythritol, 1,4-benzenedimethanol and its isomers, bisphenol A, 1,8-dihydroxybiphenyl and its isomers, and 1,3-bis(2-hydroxyethoxy)benzene.

[0027] 1,4-cyclohexanedimethanol (CHDM) has also been found to be useful in some exemplary embodiments of the present disclosure due to its inverse effect on the polymer properties of glass transition temperature and refractive index. By increasing the mole fraction of CHDM, the glass transition temperature of the copolymer can be increased while simultaneously decreasing its refractive index. Specifically, it has been found that copolyesters containing both tbia and CHDM have relatively high glass transition temperatures relative to their respective refractive indices.

[0028] Suitable polyester materials for use in the first and second compositions, i.e., first interference layer 10 and first skin layer 30, include PET, PEN, coPEN, and copolymers comprising about 1-20 mol % cyclohexanedimethanol and about 80-99 mol % ethylene glycol. These materials are understood by those skilled in the art, where PET is polyethylene terephthalate, PEN is polyethylene naphthalate, and coPEN is co(polyethylene naphthalate). In some embodiments, these coPEN copolymers contain 10-50 mol % naphthalate dicarboxylate or 30-90 mol % carboxylate subunits derived from t-butyl-isophthalic acid (TBIA) or esters thereof, with terephthalate optionally being present up to 100 mol %, or 0-100 mol %.

[0029] In some embodiments where the first and second compositions are the same, the first and second compositions comprise at least 70% by weight PET, at least 80% by weight PET, or even at least 90% by weight PET. In other embodiments, the first and second compositions comprise at least 20% by weight co(polyethylene naphthalate) (coPEN) and at least 40% by weight PET. In other embodiments, the first and second compositions comprise at least 20% by weight polyethylene naphthalate (PEN) and at least 40% by weight PET. In some embodiments, the first and second compositions comprise a copolymer comprising about 20-60 mol % cyclohexanedimethanol and about 40-80 mol % ethylene glycol.

[0030] In other embodiments, the first and second compositions are different compositions, but each composition comprises a polyester. In some of the embodiments in which the first and second compositions are different, the composition of the first skin layer and the composition of the second interference layer are substantially the same. The second interference layer and its composition are described in more detail below.

[0031] The first skin layer can have a wide variety of thicknesses and compositions. In some embodiments, the first skin layer has an average thickness of about 0.5 to 20 micrometers. In other embodiments, the first skin layer has an average thickness of greater than about 2 micrometers.

[0032] The second interference layer can also have a wide range of compositions and thicknesses. The composition of the second interference is different from the composition of the first interference to provide the desired optical effect. In some embodiments, the material of the second interference layer is predominantly polyester or copolyester, and in other embodiments, the material of the second interference layer is predominantly one or more (meth)acrylates. Examples of suitable polyester and copolyester materials are described above. In addition to the above materials, in some embodiments, the copolyester is also suitable as a copolyester ether, such as NEOSTAR ELASTOMER FN007, available from EASTMAN Chemical Company. The term "(meth)acrylate" refers to both acrylate and methacrylate materials. Acrylates and methacrylates are generally esters of acrylic or methacrylic acid prepared by the reaction of an acid with an alcohol. Particularly suitable (meth)acrylate materials are polymers (PMMA) and copolymers (coPMMA) of MMA (methyl methacrylate). One example of a suitable coPMMA material is a copolymer of 75% by weight MMA and 25% by weight ethyl acrylate, such as PERSPEX CP63, available from Ineos Acrylics, Inc.

[0033] In some embodiments, the material of the second interference layer is mostly polyester. Particularly suitable materials are copolyesters, such as PET and copolyester ether. In some embodiments, the second interference layer comprises at least 80% by weight of PET, at least 90% by weight of PET, or even at least 95% by weight of PET. In other embodiments, the second interference layer comprises at least 80% by weight of copolyester, at least 90% by weight of copolyester, or at least 95% by weight of copolyester.

[0034] In other embodiments, the second interference layer comprises at least 50% by weight of at least one (meth)acrylate. In other embodiments, the second interference layer comprises at least 60% by weight of at least one (meth)acrylate, at least 70% by weight of at least one (meth)acrylate, at least 80% by weight of at least one (meth)acrylate, at least 90% by weight of at least one (meth)acrylate, or at least 95% by weight of at least one (meth)acrylate. In some embodiments, the (meth)acrylate comprises coPMMA. In these embodiments, the second interference layer comprises at least 50% by weight of coPMMA. In other embodiments, the second interference layer comprises at least 60% by weight of coPMMA, at least 70% by weight of coPMMA, at least 80% by weight of coPMMA, at least 90% by weight of coPMMA, or at least 95% by weight of coPMMA.

[0035] As with the other layers, the second skin layer 40 can comprise a wide range of materials and thicknesses. The second skin layer 40 comprises at least 70% by weight polyethylene terephthalate (PET) and has an average thickness greater than about 50 micrometers. In some embodiments, the average thickness of the second skin layer is greater than about 100 micrometers, or even greater than 150 micrometers. In some embodiments, the average thickness of the second skin layer is less than about 400 micrometers, or less than about 350 micrometers. In some embodiments, the second skin layer comprises at least 80% by weight PET, at least 85% by weight PET, or about 90% by weight PET. In some embodiments, the second skin layer further comprises at least about 5% by weight PETg. The PETg (polyethylene terephthalate glycol) is a glycol modified PET, such as EASTAR COPOLYESTER GN007, available from Eastman Chemical Company.

[0036] The multilayer film article of the present disclosure may also include a variety of optional layers, as shown in FIG. 1. In some embodiments, the multilayer article further includes a first protective layer 70 disposed between the plurality of alternating polymeric first and second interference layers and the second skin layer 40. The first protective layer may have a wide range of material compositions. In some embodiments, the first protective layer and the first interference layer have substantially the same composition. The first protective layer may have a wide range of thicknesses. In some embodiments, the first protective layer has an average thickness of about 0.5 micrometers to about 20 micrometers.

[0037] In some embodiments, the multilayer article further comprises a light diffusing layer 80 disposed on the first skin layer 30 opposite the first and second interference layers of the plurality of alternating polymers. The light diffusing layer can have a wide variety of thicknesses. In some embodiments, the average thickness is from about 0.5 to about 12 micrometers. In some embodiments, the light diffusing layer comprises a plurality of particles 81 dispersed within a material 82. In some embodiments, the particles have a volume percentage of from about 40% to about 65% of the total volume of the light diffusing layer. In some embodiments, the material comprises a polyester (such as PET or polylactic acid) and a (meth)acrylate.

[0038] A wide range of particles are suitable. In some embodiments, the particles comprise (meth)acrylate. In some embodiments, the particles comprise polystyrene. In yet other embodiments, the particles comprise an inorganic material such as glass. In some embodiments, the particles have an average size of about 1 micrometer to about 20 micrometers. In some embodiments, at least some of the particles protrude from an upper surface of the light diffusing layer.

[0039] As mentioned above, the first and second skin layers are present in the multilayer optical film article 100 to provide the article with ease of handling and rigidity. Because the skin layers are relatively thick, they are desirably prepared from relatively inexpensive materials and are desirably co-processable with the first and second interference layers. In some particular embodiments, the multilayer optical film 100 comprises a plurality of up to 50 alternating first and second polymer layers 10, 20 disposed between and integrally formed with the first and second skin layers 30, 40. In these embodiments, the first skin layer and the first and second polymer layers have first and second compositions, respectively, that include polyester, the second skin layer includes at least 70% by weight polyethylene terephthalate (PET), and the first and second skin layers, combined, include at least 70% by volume polyester. For substantially normally incident light 50, and for each wavelength within a predetermined wavelength range 60 spanning at least about 400 nm to about 600 nm, the multilayer optical film has an optical reflectivity for a first polarization state (Px) of at least 50%. In some embodiments, the first skin layer and the second skin layer, in combination, comprise at least 80% by volume polyester.

[0040] In some embodiments, the multilayer optical film article 100 is integrally formed and has an average thickness greater than about 200 micrometers, or greater than about 250 micrometers.

[0041] A variety of methods can be used to describe the relative stiffness of the multilayer optical articles of the present disclosure. In some embodiments, the multilayer optical articles have a flexural modulus of greater than about 1500 MPa as measured according to the ASTM D790 test method.

[0042] In some particular embodiments, the multilayer optical film 100 comprises a plurality of more than 50 alternating polymer first and second polymer layers 10 and 20 disposed between and integrally formed with a first skin layer 30 and a second skin layer 40, the first skin layer and the first and second polymer layers having a first and second composition, respectively, comprising polyester. The second skin layer comprises at least 70% by weight polyethylene terephthalate (PET). For substantially normally incident light 50 and for each wavelength in a predetermined range of wavelengths 60 spanning at least about 400 nm to at least about 600 nm, the optical film has an optical reflectance of at least 50% for a first polarization state (Px), and the optical film has a flexural modulus of greater than about 1500 MPa as measured according to the ASTM D790 standard test method.

[0043] In some embodiments, the multilayer optical film 100 has mirror-like properties and has an optical reflectance for the second polarization state (Py) of at least 50%. In some embodiments, the optical reflectance is at least 60% or even 70% for the second polarization state (Py).

[0044] In some particular embodiments of the multilayer optical film, the film 100 comprises a plurality of up to 100 alternating polymeric first and second interference layers 10 and 20 disposed between and integrally formed with a first skin layer 30 and a second skin layer 40, each of which has an average thickness less than about 250 nm, and the first and second skin layers have a first and second composition, respectively, comprising polyester. The second skin layer comprises at least 70% by weight polyethylene terephthalate (PET) and has an average thickness greater than about 100 micrometers. For substantially perpendicular incident light 50, and for each wavelength within a predetermined wavelength range 60 spanning at least about 400 nm to at least about 600 nm, the optical film has an optical reflectance of at least 50% for each of orthogonal first (Px) and second (Py) polarization states. The adjacent first and second interference layers have planar indices of refraction of n1x and n2x along a first polarization state, n1y and n2y along an orthogonal second polarization state, and n1z and n2z along a z-axis orthogonal to the first and second polarization states, respectively. For at least one wavelength (61) within a predetermined wavelength range 60, n1x is greater than each of n1y and n1z by at least 0.14, the difference between n1y and n1z is greater than about 0.07, the maximum difference between n2x, n2y, and n2z is less than about 0.01, and the difference between n1x and n2x is greater than 0.14.

[0045] In some embodiments, the multilayer optical film 100 is a reflective polarizer that has a light transmission for the second polarization state (Py) of at least 60%. In some embodiments, the light transmission is at least 70% or even 80% for the second polarization state (Py).

[0046] The multilayer optical film of the present disclosure can be prepared in a variety of different ways. As mentioned above, an advantage of the present disclosure is the simple and straightforward techniques that can be used to create the article. One particularly suitable technique for forming the article is coextrusion. The technique of coextrusion is well understood by those skilled in the art. In some embodiments, the first and second interference layers of the multiple alternating polymers and the first and second skin layers are coextruded. In some embodiments, the first and second interference layers of the multiple alternating polymers and the first and second skin layers are further costretched at a temperature of about 190-220°F.

[0047] In this method, a multilayer optical film is formed by co-extruding a plurality of alternating polymeric first and second interference layers and first and second skin layers, and in some embodiments, the optical film is formed by further co-stretching the plurality of alternating polymeric first and second interference layers and first and second skin layers at a temperature of about 190-220°F.

[0048] In some embodiments, the multilayer optical film may include additional optional layers as described above. In some embodiments, the multilayer optical film further includes a light diffusing layer. In some embodiments, the light diffusing layer is coextruded with the multiple alternating polymeric first and second interference layers and the first and second skin layers. In other embodiments, the light diffusing layer is coated on the multiple alternating polymeric first and second interference layers.

[0049] Also disclosed herein is an optical stack article, including a multilayer optical film article such as that described in FIG. 1 above. One embodiment of an optical stack article is shown in FIG. 2. In FIG. 2, the optical stack 200 comprises a structured film 110 including a plurality of structures 111, each structure including opposing facets 112, 113 that meet at a top 114, with the multilayer optical film article 100 disposed on top of the structure. A first adhesive layer 120 bonds the optical film 100 to the top 114 of the structures 111. The optical stack has a flexural modulus of greater than about 1500 MPa as measured according to the ASTM D790 test method. In some embodiments, the plurality of structures 111 are embedded within the first adhesive layer 120, as shown in FIG. 2. In some embodiments, the structured film 110 further includes a first substrate 115, with the plurality of structures 111 disposed on a major surface 116 of the first substrate 115.

[0050] The optical stack article can include a variety of additional layers and features in addition to the structured film 110 and the multilayer film article 100. In some embodiments, the optical stack further includes a second substrate 130 disposed between the optical film and the first adhesive layer, and a second adhesive layer 140 bonding the second substrate to the multilayer optical film article 100. A wide variety of optically clear adhesives are suitable for use as the adhesive layers 120 and 140. Additionally, these adhesive layers can be the same or different.

[0051] The present disclosure includes the following embodiments.

[0052] A first embodiment is an optical film (100) comprising a plurality of greater than 50 alternating polymeric first and second interference layers (10) and (20) disposed between and integrally formed with a first skin layer (30) and a second skin layer (40), each of the first and second interference layers having an average thickness less than about 250 nm, the first and second skin layers having first and second compositions, respectively, comprising polyester, the second skin layer comprising at least 70% by weight polyethylene terephthalate (PET), an average thickness greater than about 50 micrometers, and a wavelength resolution of at least about 430 nm to at least about 600 nm for substantially normally incident light (50). and wherein for each wavelength within a predetermined wavelength range (60) spanning from 1 to 3, the optical film has an optical reflectivity of at least 40% for a first polarization state (Px), and adjacent first and second interference layers have planar indices of refraction of n1x and n2x along the first polarization state, n1y and n2y along an orthogonal second polarization state, and n1z and n2z along a z-axis orthogonal to the first and second polarization states, respectively, and wherein for at least one wavelength (61) within the predetermined wavelength range, n1x is at least 0.14 greater than each of n1y and n1z, the difference between n1y and n1z being greater than about 0.07, the maximum difference between n2x, n2y, and n2z being less than about 0.01, and the difference between n1x and n2x being greater than 0.14.

[0053] Embodiment 2 is the optical film of embodiment 1, wherein the average thickness of the second skin layer is less than about 400 micrometers.

[0054] Embodiment 3 is the optical film of embodiment 1 or 2, wherein the average thickness of the second skin layer is less than about 350 micrometers.

[0055] Embodiment 4 is the optical film of any of Embodiments 1-3, wherein the second skin layer comprises at least 80% by weight polyethylene terephthalate (PET).

[0056] Embodiment 5 is the optical film of any of Embodiments 1-4, wherein the first composition and the second composition are substantially the same composition comprising a polyester.

[0057] Embodiment 6 is the optical film of any one of Embodiments 1 to 4, wherein the first composition and the second composition are different compositions each containing a polyester.

[0058] Embodiment 7 is the optical film of any of Embodiments 1-6 having a light reflectance of at least 60% for the first polarization state.

[0059] Embodiment 8 is the optical film of any of Embodiments 1-7 having a light reflectance of at least 70% for the first polarization state.

[0060] Embodiment 9 is the optical film of any of Embodiments 1-8, wherein the plurality of alternating polymer first and second interference layers amounts to more than 100.

[0061] Embodiment 10 is the optical system of any of Embodiments 1-9, wherein the average thickness of the second skin layer is greater than about 100 micrometers.

[0062] An eleventh embodiment is the optical film of any one of the first to tenth embodiments, wherein the predetermined wavelength range (60) ranges from about 430 nm to about 650 nm.

[0063] A twelfth embodiment is the optical film of any one of the first to tenth embodiments, wherein the predetermined wavelength range (60) ranges from about 400 nm to about 650 nm.

[0064] Embodiment 13 is the optical film of any of Embodiments 1-12 having a light reflectance of at least 50% for the first polarization state (Px).

[0065] Embodiment 14 is the optical film of any of Embodiments 1-13, wherein the difference between n1y and n1z is greater than about 0.07.

[0066] Embodiment 15 is the optical film of any of Embodiments 1-14, wherein the first skin layer and the second interference layer have substantially the same composition.

[0067] Embodiment 16 is the optical film of any of Embodiments 1-15 having a light reflectance of at least 50% for the second polarization state.

[0068] Embodiment 17 is the optical film of any of Embodiments 1-16 having a light reflectance of at least 60% for the second polarization state.

[0069] Embodiment 18 is the optical film of any of Embodiments 1-17 having a light reflectance of at least 70% for the second polarization state.

[0070] Embodiment 19 is the optical film of any of Embodiments 1-15 having a light transmission of at least 60% for the second polarization state.

[0071] Embodiment 20 is the optical film of any of Embodiments 1-15 having a light transmission of at least 70% for the second polarization state.

[0072] Embodiment 21 is the optical film of any of Embodiments 1-15 having a light transmission of at least 80% for the second polarization state.

[0073] Embodiment 22 is the optical film of any of Embodiments 1-21, wherein the first skin layer and the interference layer comprise at least 70% by weight PET.

[0074] Embodiment 23 is the optical film of any of Embodiments 1-22, wherein the first skin layer and the interference layer comprise at least 80% by weight PET.

[0075] Embodiment 24 is the optical film of any of Embodiments 1-23, wherein the first skin layer and the interference layer comprise at least 90% by weight PET.

[0076] Embodiment 25 is the optical film of any of Embodiments 1-24, wherein the first skin layer and the interference layer comprise at least 20 weight percent co(polyethylene naphthalate) (coPEN) and at least 40 weight percent PET.

[0077] Embodiment 26 is the optical film of any of Embodiments 1-24, wherein the first skin layer and the interference layer comprise at least 20% by weight polyethylene naphthalate (PEN) and at least 40% by weight PET.

[0078] Embodiment 27 is the optical film of any of Embodiments 1-24, wherein the first skin layer and the interference layer comprise a polyester having a diol moiety of about 20-60 mol % cyclohexanedimethanol and about 40-80 mol % ethylene glycol.

[0079] Embodiment 28 is the optical film of any of Embodiments 1-27, wherein the second skin layer comprises at least 85% by weight PET.

[0080] Embodiment 29 is the optical film of any of Embodiments 1-28, wherein the second skin layer comprises about 90% by weight PET.

[0081] Embodiment 30 is the optical film of any of embodiments 1-29, wherein the second skin layer further comprises at least about 5 wt. % PETg.

[0082] Embodiment 31 is the optical film of any of Embodiments 1-30, wherein the second interference layer comprises at least 80% by weight PET.

[0083] Embodiment 32 is the optical film of any of Embodiments 1-31, wherein the second interference layer comprises at least 90% by weight PET.

[0084] Embodiment 33 is the optical film of any of Embodiments 1-32, wherein the second interference layer comprises at least 95% by weight PET.

[0085] Embodiment 34 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 50% by weight coPMMA.

[0086] Embodiment 35 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 60% by weight coPMMA.

[0087] Embodiment 36 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 70% by weight coPMMA.

[0088] Embodiment 37 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 80% by weight coPMMA.

[0089] Embodiment 38 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 90% by weight coPMMA.

[0090] Embodiment 39 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 95% by weight coPMMA.

[0091] Embodiment 40 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 50% by weight of at least one (meth)acrylate.

[0092] Embodiment 41 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 60% by weight of at least one (meth)acrylate.

[0093] Embodiment 42 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 70% by weight of at least one (meth)acrylate.

[0094] Embodiment 43 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 80% by weight of at least one (meth)acrylate.

[0095] Embodiment 44 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 90% by weight of at least one (meth)acrylate.

[0096] Embodiment 45 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 95% by weight of the at least one (meth)acrylate.

[0097] Embodiment 46 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 80 weight percent of the copolyester.

[0098] Embodiment 47 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 90% by weight of the copolyester.

[0099] Embodiment 48 is the optical film of any of Embodiments 1-27, wherein the second interference layer comprises at least 95 weight percent of the copolyester.

[0100] Embodiment 49 is the optical film of any of Embodiments 1-48, wherein the second skin layer has an average thickness greater than about 150 micrometers.

[0101] Embodiment 50 is the optical film of any of Embodiments 1-49 that is integrally formed and has an average thickness greater than about 200 micrometers.

[0102] Embodiment 51 is the optical film of any of Embodiments 1-50 which is integrally formed and has an average thickness greater than about 250 micrometers.

[0103] Embodiment 52 is the optical film of any of Embodiments 1-51, wherein the first skin layer has an average thickness greater than about 2 micrometers.

[0104] Embodiment 53 is the optical film of any of Embodiments 1-51, wherein the first skin layer has an average thickness of about 0.5 to 20 micrometers.

[0105] Embodiment 54 is the optical film of any of Embodiments 1-53, wherein the multiple alternating polymer first and second interference layers and first and second skin layers are coextruded.

[0106] Embodiment 55 is the optical film of embodiment 54, wherein the plurality of alternating polymer first and second interference layers and first and second skin layers are further co-stretched at a temperature of about 190-220°F.

[0107] Embodiment 56 is the optical film of any of embodiments 1-53 formed by coextrusion of a plurality of alternating polymer first and second interference layers, and first and second skin layers.

[0108] Embodiment 57 is the optical film of embodiment 56 formed by further co-stretching the plurality of alternating polymer first and second interference layers, and first and second skin layers at a temperature of about 190-220°F.

[0109] Embodiment 58 is the optical film of any of Embodiments 1-57, having a flexural modulus of greater than about 1500 MPa, as measured according to the ASTM D790 standard.

[0110] Embodiment 59 is the optical film of any of embodiments 1-58, further comprising a first protective layer (70) disposed between the plurality of alternating polymer first and second interference layers and the second skin layer.

[0111] Embodiment 60 is the optical film of embodiment 59, wherein the first protective layer and the first interference layer have substantially the same composition.

[0112] Embodiment 61 is the optical film of embodiment 59 or 60, wherein the first protective layer has an average thickness of about 0.5 micrometers to about 20 micrometers.

[0113] Embodiment 62 is the optical film of any of embodiments 1-61, further comprising a light diffusing layer (80) disposed on the first skin layer opposite the first and second interference layers of the multiple alternating polymers.

[0114] Embodiment 63 is the optical film of embodiment 62, wherein the light diffusing layer is coextruded with a plurality of alternating polymeric first and second interference layers and first and second skin layers.

[0115] Embodiment 64 is the optical film of embodiment 62, wherein a light diffusing layer is coated on the plurality of alternating polymeric first and second interference layers.

[0116] Embodiment 65 is the optical film of embodiment 62, wherein the light diffusing layer comprises a plurality of particles (81) dispersed within the material (82).

[0117] Embodiment 66 is the optical film of embodiment 65, wherein the particles comprise an acrylate.

[0118] Embodiment 67 is the optical film of embodiment 65, wherein the particles comprise an inorganic material.

[0119] Embodiment 68 is the optical film of embodiment 67, wherein the inorganic material comprises glass.

[0120] Embodiment 69 is the optical film of embodiment 65, wherein the particles comprise polystyrene.

[0121] Embodiment 70 is the optical film of any of Embodiments 65-69, wherein the particles have a volume percentage of about 40% to about 65% of the total volume of the light diffusing layer.

[0122] Embodiment 71 is the optical film of any of embodiments 65-70, wherein the particles have an average size of from about 1 micrometer to about 20 micrometers.

[0123] Embodiment 72 is the method of any of embodiments 65-71, wherein the material comprises polyester and acrylate.

[0124] Embodiment 73 is the optical film of any of Embodiments 62-72, wherein the light diffusing layer has an average thickness of from about 0.5 to about 12 micrometers.

[0125] Embodiment 74 is the optical film of any of Embodiments 65-72, wherein at least some of the plurality of particles protrude from the upper surface of the light diffusing layer.

[0126] Embodiment 75 is the optical film of any of embodiments 1-74, wherein the first skin layer and the second skin layer combined comprise at least 80 volume percent polyester.

[0127] Embodiment 76 is an optical laminate (200) comprising a structured film (110) including a plurality of structures (111), each structure including opposing small planes (112, 113) abutting at an apex (114), a multilayer optical film of any of embodiments 1 to 75 disposed on the apex of the structures, a first adhesive layer (120) bonding the optical film to the apex of the structures, and the optical laminate having a flexural modulus of greater than about 1500 MPa when measured according to the ASTM D790 standard.

[0128] Embodiment 77 is the optical stack of embodiment 76, wherein the apexes of at least some of the structures of the plurality of structures are embedded in the first adhesive layer.

[0129] Embodiment 78 is the optical laminate of embodiment 76 or 77, wherein the structured film further comprises a first substrate (115) and the plurality of structures are disposed on a major surface (116) of the first substrate.

[0130] Embodiment 79 is any of the optical laminates of embodiments 76 to 78, wherein the optical laminate further includes a second substrate (130) disposed between the optical film and the first adhesive layer, and a second adhesive layer (140) bonding the second substrate to the optical film.

[0131] Embodiment 80 is an optical film (100) comprising a plurality of up to 100 alternating polymeric first and second interference layers (10) and (20) disposed between and integrally formed with a first skin layer (30) and a second skin layer (40), each of the first and second interference layers having an average thickness less than about 250 nm, the first and second skin layers having first and second compositions, respectively, comprising polyester, the second skin layer comprising at least 70% by weight polyethylene terephthalate (PET), having an average thickness greater than about 100 micrometers, and having a predetermined optical transmittance (A) of at least about 400 nm to at least about 600 nm for substantially normally incident light (50). For each wavelength within the wavelength range (60), the optical film has an optical reflectivity of at least 50% for each of orthogonal first and second polarization states (Px and Py), and adjacent first and second interference layers have planar indices of refraction of n1x and n2x along the first polarization state, n1y and n2y along the second polarization state, and n1z and n2z along a z-axis orthogonal to the first and second polarization states, respectively, and for at least one wavelength (61) within the predetermined wavelength range, n1x is at least 0.14 greater than each of n1y and n1z, the difference between n1y and n1z is greater than about 0.07, the maximum difference between n2x, n2y, and n2z is less than about 0.01, and the difference between n1x and n2x is greater than 0.14.

[0132] Embodiment 81 is an optical film (100) comprising a plurality of more than 50 alternating polymeric first and second interference layers (10) and (20) disposed between and integrally formed with a first skin layer (30) and a second skin layer (40), the first skin layer and the first and second polymer layers having first and second compositions, respectively, comprising polyester, the second skin layer comprising at least 70% by weight polyethylene terephthalate (PET), the optical film having a light reflectance of at least 50% for a first polarization state (Px) for substantially perpendicular incident light (50) and for each wavelength in a predetermined wavelength range (60) spanning at least about 400 nm to at least about 600 nm, the optical film having a flexural modulus of greater than about 1500 MPa as measured according to the ASTM D790 standard.

[0133] Embodiment 82 is an optical film (100) comprising a plurality of greater than 50 alternating polymeric first and second interference layers (10) and (20) disposed between and integrally formed with a first skin layer (30) and a second skin layer (40), the first skin layer and the first and second polymer layers having first and second compositions, respectively, comprising polyester, the second skin layer comprising at least 70% by weight polyethylene terephthalate (PET), the optical film having an optical reflectance of at least 50% for a first polarization state (Px) for substantially normally incident light (50) and for each wavelength within a predetermined wavelength range (60) spanning at least about 400 nm to about 600 nm, and the first and second skin layers combined comprise 70% by volume polyester. EXAMPLES

[0134] These examples are merely for illustrative purposes and are not meant to limit the scope of the appended claims. All parts, percentages, ratios, etc. in the examples and elsewhere herein are by weight unless otherwise indicated. The following abbreviations are used: Ib = pounds, hr = hours. The terms "mol%" and "mole%" are used interchangeably to define the mole percentage of a component. Similarly, the terms "wt%" and "weight %" are used interchangeably to define the weight percentage of a component. [Table 1]

[0135] sample 1: Four extruders were used to make the multilayer optical films. ● HIO Extruder: Feeds a feedblock that produces 88 layers. 20 wt% of the extruder output is diverted to protective boundary layers on each side of the microlayer packet. The protective boundary layers are described in US Patent No. 5,882,774 and are thick layers that protect the microlayer packet from high shear rates. ● LIO extruder: Feeds the same feedblock as the HIO extruder, producing 89 layers. • Air Side Skin Extruder: Feeds the skin on the air side of the casting wheel. This extruder uses the same input material as the HIO so that the refractive index can be measured directly from the surface. • Wheel side skin extruder: Supplies the skin to the wheel side of the casting wheel.

[0136] sample In 1, the HIO, air side skin, and LIO materials are all supplied with PET. The wheel side skin is 90 wt% PET and 10 wt% PETg. PETg is added to explore compositions that may have superior mechanical properties compared to 100% PET (i.e., lower crystallinity).

[0137] The feedblock produces a single packet with 177 microlayers. An axial rod heater is used to adjust the layer profile by adjusting the casting speed to give a left band edge of about 400 nm and a right band edge of about 900 nm, as measured in transmission through the block at normal incidence (axial rods are described in U.S. Pat. No. 6,830,713).

[0138] The film was cast onto a casting wheel with the thinnest microlayer facing the casting wheel. The film was then stretched to a transverse direction (TD) stretch ratio (TDSR) of 5.5 at a temperature of 222°F (106°C). This stretch ratio was obtained by drawing two marks on an unoriented web with a marker and measuring the distance between the marks before and after stretching. The TDSR is the oriented distance divided by the unoriented distance. sample The materials and process conditions for 1 to 22 are shown in Table 1. [Table 2]

[0139] In Table 1, Mix A is a mixture of CoPEN90-10 / PET in a weight ratio of 50 / 50, Mix B is a mixture of CoPEN90-10 / PET in a weight ratio of 40 / 60, Mix C is a mixture of PEN / PET in a weight ratio of 30 / 70, and Mix D is a mixture of PET / PET in a weight ratio of 90 / 10.

[0140] The refractive index of the film was then measured using a Metricon refractometer (Pennington, NJ) to determine the optical capabilities of a particular material. The results showed that the wheel side skin had a refractive index of 1.6574 at 633 nm and the wheel side had a refractive index of 1.6500. The refractive indices are shown in Table 2. [Table 3]

Claims

1. An optical film comprising a plurality of up to 50 alternating polymeric first and second interference layers disposed between and integrally formed with a first skin layer and a second skin layer; each of the first interference layer and the second interference layer has an average thickness of less than 250 nm; the first skin layer and the first interference layer have a first composition and a second composition, respectively, comprising a polyester; the second skin layer comprises at least 70% by weight polyethylene terephthalate (PET) and has an average thickness greater than 50 micrometers; for normally incident light, and for each wavelength within a predetermined wavelength range spanning at least 430 nm to 600 nm, the optical film has a light reflectance of at least 40% for a first polarization state; The adjacent first interference layer and the adjacent second interference layer each have n1x and n2x along the first polarization state, n1y and n2y along the second orthogonal polarization state, and a planar refractive index of n1z and n2z along a z-axis orthogonal to the first and second polarization states, and for at least one wavelength within the predetermined wavelength range: n1x is greater than each of n1y and n1z by at least 0.14; the difference between n1y and n1z is greater than 0.07; the maximum difference between n2x, n2y, and n2z is less than 0.01; the difference between n1x and n2x is greater than 0.14; Optical film.

2. 10. The optical film of claim 1, wherein the first skin layer and the first interference layer comprise a polyester having a diol moiety of 20-60 mol % cyclohexanedimethanol and 40-80 mol % ethylene glycol.

3. The optical film of claim 1 , wherein the second skin layer has an average thickness greater than 150 micrometers.

4. 10. The optical film of claim 1 which is integrally formed and has an average thickness greater than 250 micrometers.

5. A method for manufacturing the optical film described in claim 1, wherein the first interference layer and the second interference layer, and the first skin layer and the second skin layer of a plurality of alternating polymers are co-extruded.

6. 6. The method of claim 5, wherein the first and second interference layers and the first and second skin layers of a plurality of alternating polymers are further co-stretched at a temperature of 190-220°F.

7. A method for producing the optical film according to claim 1, comprising the steps of: the optical film further comprises a light diffusing layer disposed on the first skin layer opposite the first and second interference layers of a plurality of alternating polymers; A method of manufacturing wherein the light diffusing layer is coextruded with the first and second interference layers and the first and second skin layers of a plurality of alternating polymers.

8. The number of first and second interference layers of the plurality of alternating polymers is more than 100; the second skin layer has an average thickness greater than 100 micrometers; for normally incident light, and for each wavelength within the predetermined wavelength range, the optical film has a light reflectance of at least 50% for each of the first polarization state and the second polarization state. The optical film according to claim 1 .

9. Having a flexural modulus of greater than 1500 MPa when measured according to the ASTM D790 standard. The optical film according to claim 1 .

10. the first skin layer and the second skin layer, in combination, comprise at least 70% by volume polyester; The optical film according to claim 1 .

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