Solid cosmetics

Abstract

Provided is a composition solidified by means of a solidifying agent that is dissolved in a single-phase liquid composition that has been obtained by phase-dissolving a moisturizing agent having an expected moisture retention effect in an oil phase having an occlusion effect.　The solid composition includes: an oily liquid medium which is separated when mixed with water in a ratio of 1:1; an aqueous liquid medium which is an organic liquid medium other than water and which forms a homogeneous phase when mixed with water in a ratio of 1:1, and forms a homogeneous phase when mixed with the oily liquid medium; and an aqueous solidifying agent which is soluble in the aqueous liquid medium, and gelates and / or solidifies the aqueous liquid medium, and / or an oily solidifying agent which is soluble in the oily liquid medium, and gelates and / or solidifies the oily liquid medium, wherein the oily liquid medium and the aqueous liquid medium are gelated and / or solidified by the aqueous solidifying agent and / or oily solidifying agent, and the total amount of the aqueous liquid medium, the oily liquid medium, the aqueous solidifying agent, and the oily solidifying agent is at least 90 mass% with respect to the amount of the composition excluding powder.

Description

Related Applications

[0001] This application claims priority from Japanese Patent Application No. 2020-212031, filed on December 22, 2020, which is incorporated herein by reference. [Technical Field]

[0002] The present invention relates to a solid cosmetic product, and more particularly to a cosmetic product solidified by a solidifying agent. [Background technology]

[0003] Conventionally, when preparing solid cosmetics such as lipstick, it is common to use wax, solid oil such as hydrogenated oil, or oily gelling agents such as 12-hydroxyisostearic acid (Patent Documents 1 to 3). [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Patent No. 6465700 [Patent Document 2] Patent No. 6468891 [Patent Document 3] Patent No. 6465701 Summary of the Invention [Problem to be solved by the invention]

[0005] However, solid cosmetics solidified using the solid oils and fats or oil-based gelling agents cannot be solidified with a moisturizing agent dissolved therein, as is the case with so-called solid lipsticks. On the other hand, although it is easy to blend a moisturizing agent into a water-soluble solid, it is not possible to dissolve and solidify an oil component having an occlusion effect. The present invention has been made in view of the above-mentioned prior art, and the problem to be solved by the present invention is to provide a cosmetic product which is prepared by dissolving a moisturizing agent expected to have a moisturizing effect in an oil phase having an occlusion effect to form a one-phase liquid composition, and then solidifying the one-phase liquid composition using a solidifying agent which dissolves in the one-phase liquid composition. [Means for solving the problem]

[0006] That is, the present invention includes the following. (1) an oily liquid medium that separates when mixed with water in a 1:1 ratio; an aqueous liquid medium which is an organic liquid medium other than water and which forms a homogeneous phase when mixed with water in a 1:1 ratio, and which forms a homogeneous phase when mixed with the oily liquid medium; an aqueous solidifying agent that is soluble in the aqueous liquid medium and that gels and / or solidifies the aqueous liquid medium, and / or an oily solidifying agent that is soluble in the oily liquid medium and that gels and / or solidifies the oily liquid medium; Including, the oily liquid medium and the aqueous liquid medium are gelled and / or solidified by an aqueous solidifying agent and / or an oily solidifying agent, The solid composition is characterized in that the total amount of the aqueous liquid medium, oily liquid medium, aqueous solidifying agent, and oily solidifying agent is 90% by mass or more of the amount of the composition excluding powder. (2) A solid composition characterized by containing an oil-absorbing powder containing an oil component other than the oily liquid medium. (3) A solid composition characterized by having a hardness of 10 to 500 when a probe having a diameter of 5.6 mm is inserted into the solid composition at a rate of 20 mm / min using a rheometer. (4) The oily liquid medium contains, as a phenyl-containing substance, a cinnamic acid derivative selected from ethylhexyl methoxycinnamate, isopropyl methoxycinnamate, and isoamyl methoxycinnamate; a PABA derivative selected from para-aminobenzoic acid, ethyl PABA, ethyl-dihydroxypropyl PABA, ethylhexyl-dimethyl PABA, and glyceryl PABA; a salicylic acid derivative selected from homosalate, ethylhexyl salicylate, dipropylene glycol salicylate, and TEA salicylate; a benzo benzophenone derivatives selected from benzophenone-1, benzophenone-2, benzophenone-3 or oxybenzone, benzophenone-4, benzophenone-5, benzophenone-6, benzophenone-8, benzophenone-9, and benzophenone-12; benzylidene camphor selected from 3-benzylidene camphor, 4-methylbenzylidene camphor, benzylidene camphorsulfonic acid, benzalkonium camphor methosulfate, terephthalidene discamphorsulfonic acid, and polyacrylamidomethyl benzylidene camphor triazine derivatives selected from anisotriazine, ethylhexyl triazone, diethylhexylbutamidotriazone, 2,4,6-tris(diisobutyl-4'-aminobenzalmalonate)-s-triazine, 2,4-bis-[{4-(2-ethylhexyloxy)-2-hydroxy}-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine, and 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]1,3,5-triazine; phenyl dibenzimidazole tetrasulfonic acid di phenylbenzimidazole derivatives selected from sodium; phenylbenzotriazole derivatives selected from drometrizole trisiloxane and methylenebis(benzotriazolyltetramethylbutylphenol); anthranil derivatives selected from menthyl anthranilate; imidazoline derivatives selected from ethylhexyl dimethoxybenzylidene dioxoimidazoline propionate; benzalmalonate derivatives selected from polyorganosiloxanes having benzalmalonate functional groups;one or more selected from the group consisting of 4,4-diarylbutadiene derivatives selected from 1,1-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene, diethylaminohydroxybenzoylhexylbenzoate, bisethylhexyloxyphenol methoxyphenyl triazine, and homosalate, and diols and triols that are not miscible with water in a 1:1 ratio; the aqueous liquid medium is one or more selected from the group consisting of dipropylene glycol, polyethylene glycol that is liquid at room temperature, PEG / PPG-14 / 7 dimethyl ether, PEG / PPG-9 / 2 dimethyl ether, PEG / PPG-36 / 41 dimethyl ether, PEG / PPG-55 / 28 dimethyl ether, PEG / PPG-17 / 4 dimethyl ether, 1,2-hexanediol, isopropylene glycol, propylene glycol, and 1,3-butylene glycol; the aqueous solidifying agent is one or more selected from the group consisting of bis(polyethylene glycol methyl ether dimethyl silane), polyethylene glycol-decyltetradeceth-20-hexamethylene diisocyanate copolymer, polyethylene glycol that is solid at 25°C, and polyurethane-59; The solid composition is characterized in that the oil-based solidifying agent is one or more selected from the group consisting of dibutyl lauroyl glutamide, dibutyl ethyl hexanoyl glutamide, polyamide-3, polyamide-8, and 12-hydroxystearic acid. [Effects of the Invention]

[0007] The present invention makes it possible to obtain a wide variety of physical properties by solidifying a homogeneous one-phase liquid composition using an oil-soluble medium and an aqueous medium with an oil-based and / or aqueous solidifying agent. DETAILED DESCRIPTION OF THE INVENTION

[0008] Preferred embodiments of the present invention will now be described. The present invention solidifies an oily composition using an oily liquid medium, an aqueous liquid medium that is compatible with the oily liquid medium, and various solidifying agents.

[0009] [Oil-based liquid medium] In the present invention, the oily liquid medium means an oily substance that separates when mixed with water in a mass ratio of 1:1. Specifically, cinnamic acid derivatives such as ethylhexyl salicylate, ethylhexyl methoxycinnamate, isopropyl methoxycinnamate, and isoamyl methoxycinnamate; PABA derivatives such as para-aminobenzoic acid (hereinafter abbreviated as "PABA"), ethyl PABA, ethyl-dihydroxypropyl PABA, ethylhexyl-dimethyl PABA, and glyceryl PABA; salicylic acid derivatives such as homosalate, ethylhexyl salicylate, dipropylene glycol salicylate, and TEA salicylate. Conductors; benzophenone derivatives such as benzophenone-1, benzophenone-2, benzophenone-3 or oxybenzone, benzophenone-4, benzophenone-5, benzophenone-6, benzophenone-8, benzophenone-9, and benzophenone-12; benzyl compounds such as 3-benzylidene camphor, 4-methylbenzylidene camphor, benzylidene camphorsulfonic acid, benzalkonium camphor methosulfate, terephthalidene discamphorsulfonic acid, and polyacrylamidomethyl benzylidene camphor Lidencamphor derivatives; triazine derivatives such as anisotriazine, ethylhexyl triazone, diethylhexylbutamido triazone, 2,4,6-tris(diisobutyl-4'-aminobenzalmalonate)-s-triazine, 2,4-bis-[{4-(2-ethylhexyloxy)-2-hydroxy}-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine, and 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]1,3,5-triazine; phenyldibenzoyl Phenylbenzimidazole derivatives such as disodium midazole tetrasulfonate; phenylbenzotriazole derivatives such as drometrizole trisiloxane and methylenebis(benzotriazolyltetramethylbutylphenol); anthranil derivatives such as menthyl anthranilate; imidazoline derivatives such as ethylhexyl dimethoxybenzylidene dioxoimidazoline propionate; benzalmalonate derivatives such as polyorganosiloxanes having benzalmalonate functional groups;Examples include 4,4-diarylbutadiene derivatives such as 1,1-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene, diethylaminohydroxybenzoylhexylbenzoate, bisethylhexyloxyphenol methoxyphenyl triazine, and homosalate. Particularly preferred oily liquid media include ethylhexyl salicylate and ethylhexyl methoxycinnamate. The preferred amount of oily liquid medium, in relation to the aqueous liquid medium described below, is such that the mass ratio of oily liquid medium / (aqueous liquid medium+oily liquid medium) is in the range of 0.1 to 0.9, more preferably 0.3 to 0.7. In the present invention, the "oil-based liquid medium" may be an oil component that is solid at room temperature (20°C) by itself, as long as it dissolves in other coexisting oil-based liquid media and is liquid as a whole.

[0010] [Aqueous liquid medium] In the present invention, an aqueous liquid medium refers to an organic liquid medium other than water, which forms a homogeneous phase when mixed with water in a 1:1 ratio, and also forms a homogeneous phase when mixed with the oily liquid medium. Specific examples include dipropylene glycol, polyethylene glycol (for example, PEG-8) that is liquid at room temperature, alkylene oxide derivatives, 1,2-hexanediol, isopropylene glycol, propylene glycol, and 1,3-butylene glycol. More preferred are dipropylene glycol, polyethylene glycol (for example, PEG-8) which is liquid at room temperature, alkylene oxide derivatives, and 1,2-hexanediol. Some examples may include 1,3-propanediol, diglycerin, dynamite glycerin. Particularly preferred are dipropylene glycol and polyethylene glycol which is liquid at room temperature.

[0011] [Water-based solidifying agent] In the present invention, the aqueous solidifying agent that is particularly preferably used is soluble in the aqueous liquid medium and has a solidifying function. Specific examples include bis(polyethylene glycol methyl ether dimethyl silane), polyethylene glycols that are solid at 25°C (e.g., polyethylene glycol-400), and polyethylene glycol-decyltetradeceth-20-hexamethylene diisocyanate copolymers.

[0012] [Oil-based solidifying agent] Although not an essential component, a small amount of an oil-based solidifying agent can be added to the present invention. Examples of oily solidifying agents that can be suitably used in the present invention include 12-hydroxystearic acid and dibutyl lauroyl glutamide.

[0013] [Amount of each ingredient] In the present invention, the total amount of the aqueous liquid medium, oily liquid medium, and aqueous solidifying agent is preferably 90% by mass or more of the composition excluding powder. If the essential components are less than 90% by mass of the composition excluding the powder, the solidification property may be reduced. Here, the powder also includes porous powders carrying oily components and aqueous components. Since these powders do not affect the affinity of the aqueous liquid medium and oily liquid medium, they can be considered as being excluded from the system, including the carried oily and aqueous components. In the present invention, the mass ratio of oily liquid medium to (aqueous liquid medium + oily liquid medium) is preferably 0.1 to 0.9, more preferably 0.3 to 0.7. If the mass ratio of the oily liquid medium is less than 0.3, the properties of the oily composition are difficult to exhibit. If it exceeds 0.7, the proportion of the aqueous liquid medium decreases relatively, and solidification tends to deteriorate.

[0014] [Other ingredients] Cosmetics using the cosmetic raw material according to the present invention can be produced by a conventional method according to the desired dosage form by appropriately blending other ingredients, such as inorganic powders, organic powders, esters, anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, moisturizers, water-soluble polymers, thickeners, film-forming agents, ultraviolet absorbers, sequestering agents, lower alcohols, polyhydric alcohols, sugars, amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, fragrances, water, etc., as needed, within the range that does not impair the effects of the present invention.

[0015] Examples of inorganic powders include talc, boron nitride, sericite, natural mica, calcined mica, synthetic mica, synthetic sericite, alumina, mica, kaolin, bentonite, smectite, calcium carbonate, magnesium carbonate, calcium phosphate, anhydrous silicic acid, magnesium oxide, tin oxide, iron oxide, yttrium oxide, chromium oxide, zinc oxide, cerium oxide, aluminum oxide, magnesium oxide, chromium hydroxide, Prussian blue, ultramarine, calcium phosphate, aluminum hydroxide, barium sulfate, magnesium sulfate, silicic acid, magnesium aluminum silicate, calcium silicate, barium silicate, magnesium silicate, aluminum silicate, strontium silicate, silicon carbide, magnesium fluoride, metal tungstate, magnesium aluminate, magnesium aluminometasilicate, aluminum chlorohydrate, clay, zeolite, hydroxyapatite, ceramic powder, spinel, mullite, cordierite, aluminum nitride, titanium nitride, silicon nitride, Lanthanum, samarium, tantalum, terbium, europium, neodymium, Mn-Zn ferrite, Ni-Zn ferrite, silicone carbide, cobalt titanate, barium titanate, iron titanate, lithium cobalt titanate, cobalt aluminate, antimony-containing tin oxide, tin-containing indium oxide, magnetite, aluminum powder, gold powder, silver powder, platinum powder, copper powder, precious metal colloid, iron powder, zinc powder, cobalt blue, cobalt violet, cobalt green, low-grade oxide Titanium, fine particle titanium oxide, butterfly-shaped barium sulfate, petal-shaped zinc oxide, tetrapod-shaped zinc oxide, fine particle zinc oxide, pearl pigments include titanium oxide-coated mica, titanium oxide-coated mica, titanium oxide-coated synthetic mica, titanium oxide-coated silica, titanium oxide-coated synthetic mica, titanium oxide-coated talc, zinc oxide-coated silica, titanium oxide-coated colored mica, red iron oxide-coated mica titanium, red iron oxide / black iron oxide-coated mica titanium, carmine-coated mica titanium, and konjou-coated mica titanium.

[0016] Examples of suitable organic powders include: organic powders (e.g., silicone elastomer powder, silicone powder, silicone resin-coated silicone elastomer powder, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder (e.g., methyl methacrylate crosspolymer), polystyrene powder, styrene-acrylic acid copolymer resin powder, benzoguanamine resin powder, polytetrafluoroethylene powder, and cellulose powder); and organic pigments such as zirconium, barium, or aluminum lakes (e.g., organic pigments such as Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, and Blue No. 404).

[0017] Examples of anionic surfactants include fatty acid soaps (e.g., sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (e.g., sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (e.g., POE-lauryl triethanolamine sulfate, sodium POE-lauryl sulfate, etc.); N-acyl sarcosinates (e.g., sodium lauroyl sarcosinate, etc.); higher fatty acid amide sulfonates (e.g., sodium N-myristoyl-N-methyl taurate, sodium coconut oil fatty acid methyl tauride, sodium lauryl methyl tauride, etc.); phosphate salts (sodium POE-oleyl ether phosphate, sodium POE-stearyl ether phosphate, etc.); sulfosuccinates (e.g., sodium di-2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol ... sodium succinate, etc.); alkylbenzenesulfonates (e.g., sodium linear dodecylbenzenesulfonate, triethanolamine linear dodecylbenzenesulfonate, linear dodecylbenzenesulfonic acid, etc.); higher fatty acid ester sulfate salts (e.g., sodium hydrogenated coconut oil fatty acid glycerin sulfate, etc.); N-acylglutamates (e.g., monosodium N-lauroylglutamate, disodium N-stearoylglutamate, monosodium N-myristoyl-L-glutamate, etc.); sulfated oils (e.g., turmeric oil, etc.); POE-alkyl ether carboxylic acids; POE-alkyl allyl ether carboxylate salts; α-olefin sulfonates; higher fatty acid ester sulfonates; secondary alcohol sulfate salts; higher fatty acid alkylolamide sulfate salts; sodium lauroylmonoethanolamide succinate; ditriethanolamine N-palmitoyl aspartate; sodium caseinate, etc.

[0018] Examples of cationic surfactants include alkyltrimethylammonium salts (e.g., stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (e.g., cetylpyridinium chloride, etc.); distearyldimethylammonium chloride dialkyldimethylammonium salts; poly(N,N'-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salts; alkyldimethylbenzylammonium salts; alkylisoquinolinium salts; dialkylmorphonium salts; POE-alkylamines; alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride, etc.

[0019] Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (e.g., 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc.); betaine-based surfactants (e.g., 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkyl betaine, amido betaine, sulfobetaine, etc.).

[0020] Examples of lipophilic nonionic surfactants include sorbitan fatty acid esters (e.g., sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate, etc.); glycerin polyglycerin fatty acids (e.g., glycerin monocottonseed oil fatty acid, glycerin monoerucate, glycerin sesquioleate, glycerin monostearate, glycerin α,α'-oleic acid pyroglutamate, glycerin monostearate malate, etc.); propylene glycol fatty acid esters (e.g., propylene glycol monostearate, etc.); hydrogenated castor oil derivatives; and glycerin alkyl ethers.

[0021] Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (e.g., POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE-sorbitol fatty acid esters (e.g., POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol monostearate, etc.); POE-glycerin fatty acid esters (e.g., POE-glycerin monostearate, POE-monooleates such as POE-glycerin monoisostearate and POE-glycerin triisostearate; POE-fatty acid esters (e.g., POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (e.g., POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic (registered trademark) types (e.g., Pluronic POE·POP-alkyl ethers (e.g., POE·POP-cetyl ether, POE·POP-2-decyltetradecyl ether, POE·POP-monobutyl ether, POE·POP-hydrogenated lanolin, POE·POP-glycerin ether, etc.); tetraPOE·tetraPOP-ethylenediamine condensates (e.g., Tetronic, etc.); POE-hydrogenated castor oil derivatives (e.g., POE-castor oil, POE-hydrogenated castor oil, POE-hydrogenated castor oil monoisostearate, POE-hydrogenated castor oil triisostearate, etc.); POE-hydrogenated castor oil monopyroglutamic acid monoisostearate diester, POE-hydrogenated castor oil maleic acid, etc.); POE-beeswax and lanolin derivatives (e.g., POE-sorbitol beeswax, etc.); alkanolamides (e.g., coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid esters; POE-alkylamines; POE-fatty acid amides; sucrose fatty acid esters; alkylethoxydimethylamine oxide; trioleyl phosphate, etc.

[0022] Examples of moisturizing agents include xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, alkylene oxide derivatives, short-chain soluble collagen, diglycerin (EO)PO adducts, Rosa robur extract, yarrow extract, and melilot extract. These moisturizing agents are soluble in the aqueous liquid medium characteristic of the present invention, and therefore may affect the affinity between the oily liquid medium and the aqueous liquid medium. Therefore, they must be added while taking into consideration their affinity with the oily liquid medium.

[0023] Examples of natural water-soluble polymers include plant-derived polymers (e.g., gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (marmella), algae colloid (cassowia extract), starch (rice, corn, potato, wheat), glycyrrhizic acid); microbial-derived polymers (e.g., xanthan gum, dextran, succinoglucan, pullulan, etc.); and animal-derived polymers (e.g., collagen, casein, albumin, gelatin, etc.).

[0024] Examples of semi-synthetic water-soluble polymers include starch-based polymers (e.g., carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose-based polymers (methyl cellulose, ethyl cellulose, methylhydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, etc.); and alginic acid-based polymers (e.g., sodium alginate, propylene glycol alginate, etc.).

[0025] Examples of synthetic water-soluble polymers include vinyl polymers (e.g., polyvinyl alcohol, polyvinyl methyl ether, polyvinylpyrrolidone, carboxyvinyl polymer, etc.); polyoxyethylene polymers (e.g., polyoxyethylene-polyoxypropylene copolymers of polyethylene glycol 20,000, 40,000, 60,0000, etc.); acrylic polymers (e.g., sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers, etc.

[0026] Examples of thickeners include gum arabic, carrageenan, karaya gum, tragacanth gum, carob gum, quince seed, casein, dextrin, gelatin, sodium pectinate, sodium allaginate, methylcellulose, ethylcellulose, CMC, hydroxyethyl cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, dialkyldimethylammonium cellulose sulfate, xanthan gum, magnesium aluminum silicate, bentonite, hectorite, magnesium aluminum silicate (Bee Gum), laponite, and anhydrous silicic acid.

[0027] Examples of sequestering agents include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, edetate disodium, edetate trisodium, edetate tetrasodium, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, and ethylenediaminehydroxyethyltriacetate trisodium salt.

[0028] Examples of monosaccharides include trioses (e.g., D-glyceryl aldehyde, dihydroxyacetone, etc.); tetraoses (e.g., D-erythrose, D-erythrulose, D-threose, erythritol, etc.); pentoses (e.g., L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc.); hexoses (e.g., D-glucose, D-talose, D-busicose, D-galactose, D-fructose, L-galactose, L- -mannose, D-tagatose, etc.); heptoses (e.g., aldoheptose, heprose, etc.); octooses (e.g., octulose, etc.); deoxysugars (e.g., 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc.); aminosugars (e.g., D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); uronic acids (e.g., D-glucuronic acid, D-mannuronic acid, L-guluronic acid, D-galacturonic acid, L-iduronic acid, etc.), etc.

[0029] Examples of oligosaccharides include sucrose, gunthianose, umbelliferose, lactose, planteose, isolichinoses, α,α-trehalose, raffinose, lychinoses, umbilicin, stachyose, verbascoses, and the like.

[0030] Examples of polysaccharides include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, keratosulfate, locust bean gum, succinoglucan, and caronic acid.

[0031] Examples of amino acids include neutral amino acids (e.g., threonine, cysteine, etc.), basic amino acids (e.g., hydroxylysine, etc.), etc. Examples of amino acid derivatives include sodium acyl sarcosine (sodium lauroyl sarcosine), acyl glutamate, sodium acyl β-alanine, glutathione, pyrrolidone carboxylic acid, etc.

[0032] Examples of organic amines include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Examples of polymer emulsions include acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion, and natural rubber latex.

[0033] Examples of pH adjusters include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate. Examples of vitamins include vitamins A, B1, B2, B6, C, E and their derivatives, pantothenic acid and its derivatives, biotin, etc. Examples of antioxidants include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, and gallic acid esters.

[0034] Examples of antioxidant aids include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, cephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

[0035] Other ingredients that can be added include, for example, preservatives (ethylparaben, butylparaben, chlorphenesin, phenoxyethanol, etc.); anti-inflammatory agents (for example, glycyrrhizinic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents (for example, placenta extract, saxifrage extract, arbutin, etc.); various extracts (for example, Phellodendron bark, Coptis chinensis, Lithospermum root, Peony, Swertia japonica, Birch, Sage, Loquat, Carrot, Aloe, Mallow, Iris, Grape, Job's tears, Loofah, Lily, Saffron, Cnidium rhizome, Angelica acutiloba, Hypericum perforatum, Ononis, Garlic, Chili pepper, Citrus fruit, Tomato, float, seaweed, etc.), activators (e.g., royal jelly, photosensitizers, cholesterol derivatives, etc.); blood circulation promoters (e.g., nonylic acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharides tincture, ichthammol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, etc.); antiseborrheic agents (e.g., sulfur, thianthol, etc.); anti-inflammatory agents (e.g., tranexamic acid, thiotaurine, hypotaurine, etc.), etc.

[0036] Furthermore, sequestering agents such as disodium edetate, trisodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, and malic acid, caffeine, tannin, verapamil, tranexamic acid and derivatives thereof, various herbal extracts such as licorice, Chinese quince, and Chinese anemone, drugs such as tocopherol acetate, glycyrrhesic acid, glycyrrhizic acid and derivatives thereof or salts thereof, whitening agents such as vitamin C, magnesium ascorbyl phosphate, ascorbic acid glucoside, arbutin, and kojic acid, amino acids such as arginine and lysine and derivatives thereof, and sugars such as fructose, mannose, erythritol, trehalose, and xylitol may also be appropriately blended.

[0037] Preferred embodiments of the solid oily composition of the present invention will be described below. First, the inventors investigated aqueous liquid media that are compatible with oily liquid media in order to solidify the oily liquid media with an aqueous solidifying agent. The results are shown in Table 1. The evaluation of the solidification property was carried out visually, and the hardness was measured using a rheometer by reading the range when a probe with a diameter of 5.6 mm was inserted 2 mm at a speed of 20 mm / min. The hardness of the solid oily composition of the present invention is preferably 10-500, and more preferably 20-250.

[0038] [Table 1]

[0039] As shown in Table 1, first, ethylhexyl methoxycinnamate, a relatively highly polar oil, was used as the oil-based liquid medium, and an aqueous liquid medium compatible with ethylhexyl methoxycinnamate in a mass ratio of 1:1 was selected. As a result, dipropylene glycol (Test Example 1-1) and polyethylene glycol 400 (Test Example 1-2) were miscible with the ethylhexyl methoxycinnamate in a mass ratio of 1:1, but glycerin, propanediol, and diglycerol (Test Examples 1-3 to 1-5) were not miscible and separated. Furthermore, when polyethylene glycol-400 was added as an aqueous solidifying agent to attempt solidification, gelation of the entire system was observed in Test Examples 1-1 and 1-2.

[0040] Next, the inventors investigated oily liquid media, and the results are shown in Table 2.

[0041] [Table 2]

[0042] As shown in Table 2, ethylhexyl salicylate formed a homogeneous phase when combined with dipropylene glycol (Test Example 2-1), but did not show good compatibility with PEG-8 (Test Example 2-2). Furthermore, silicone oil, isopropyl myristate, and phenyl silicone, which have low polarity, did not show good compatibility with either DPG or PEG-8 (Test Examples 2-3 to 2-5).

[0043] Next, the inventors investigated solidifying agents, and the results are shown in Table 3.

[0044] [Table 3]

[0045] As shown in Table 3, a mixed medium of ethylhexyl methoxycinnamate and ethylhexyl salicylate was used as the oil medium, and a mixed medium of DPG and PEG-8 was used as the aqueous medium, and both showed good compatibility. The aqueous solidifying agents PEG-400, bisPEG-18 methyl ether dimethyl silane, and PEG-240·decyltetradeceth-20·hexamethylene diisocyanate copolymer had gelling ability in aqueous / oil-based mixed systems, but the oil-based solidifying agent 12-hydroxystearic acid alone showed only very weak solidifying ability.

[0046] Furthermore, the inventors investigated the polarity of the solidifying agent and its solidifying ability. The results are shown in Table 4.

[0047] [Table 4]

[0048] As is clear from Table 4, the aqueous solidifying agent PEG-400 and the oil-based solidifying agents 12-hydroxystearic acid and dibutyl lauroyl glutamide had the gelling ability for aqueous / oil-based mixed systems, but the aqueous solidifying agent Adekanol only had a weak solidifying ability, and the highly polar aqueous solidifying agent gellan gum (a sugar derivative) and the less polar oil-based solidifying agents dextrin palmitate and microcrystalline wax had no solidifying ability.

[0049] Furthermore, the inventors used ethylhexyl methoxycinnamate, a relatively highly polar oil, as an oil-based liquid medium to select aqueous liquid media that are compatible with ethylhexyl methoxycinnamate at a mass ratio of 1:1. The results are shown in Table 5.

[0050] [Table 5]

[0051] As is clear from Table 5, dipropylene glycol (DPG), polyethylene glycols (PG; PEG-6, PEG-8) which are liquid at room temperature, 1,2-hexanediol (1,2-HD), and alkylene oxide derivatives (PEG / PPG-14 / 7 dimethyl ether, PEG / PPG-9 / 2 dimethyl ether, PEG / PPG-36 / 41 dimethyl ether, PEG / PPG-55 / 28 dimethyl ether, PEG / PPG-17 / 4 dimethyl ether) are superior aqueous liquid media to oil-based liquid media (ethylhexyl methoxycinnamate; MCX).

[0052] Furthermore, the present inventors have selected aqueous liquid media that are compatible with ethylhexyl methoxycinnamate at various mass ratios. The results of this investigation are shown in Table 6.

[0053] [Table 6]

[0054] As is clear from Table 6, the good solvents that showed high compatibility in Table 5 were compatible with the oil-based liquid medium at any mass ratio. In contrast, the highly hydrophilic solvents isopropylene glycol (IPG), propylene glycol (PG), and 1,3-butylene glycol became compatible by changing the ratio, but the extremely hydrophilic solvents 1,3-propanediol (1,3-PD), diglycerin (DG), and dynamite glycerin (DDG) were not compatible even when the ratio was changed.

[0055] The present inventors also investigated the behavior of aqueous liquid media that are unlikely or unable to function alone as solvents for oily liquid media, specifically 1,3-butylene glycol (1,3-BG), diglycerin (DG), 1,3-propanediol (1,3-PD), propylene glycol (PG), isopropylene glycol (IPG), and dynamite glycerin (DDG), in the presence of dipropylene glycol, a good solvent. The results are shown in Table 7.

[0056] [Table 7]

[0057] Table 7 above shows that even for aqueous liquid media with low affinity to oily liquid media, the compatibility with the oily liquid medium is improved by coexistence with an aqueous liquid medium with high affinity (dipropylene glycol), and it can also be seen that 1,3-propanediol (1,3-PD), diglycerin (PG), and dynamite glycerin (DDG) are also compatible depending on the proportions at which they coexist as aqueous liquid solvents.

[0058] The present inventors further investigated the ethylhexyl methoxycinnamate:DPG ratio of 1:2, which showed improved compatibility in Table 6. The results are shown in Table 8.

[0059] [Table 8]

[0060] From Table 8, it was found that compatibility with the aqueous medium was improved by including an oil-based liquid medium:aqueous liquid medium with high affinity=1:2. In Table 6, 1,3-propanediol, diglycerin, and dynamite glycerin, which were not compatible at any concentration, were compatible when mixed with ethylhexyl methoxycinnamate:DPG at a ratio of 1:2, depending on the concentration.

[0061] The present inventors have investigated the state of a solid composition when an oil-absorbing powder is contained therein. The results are shown in Table 9. The smoothness and stability were evaluated as follows. [Method of evaluating smoothness] A panel of 10 experts applied the solid compositions to their skin and evaluated them based on the number of people who felt a smooth sensation. ◎: More than 8 out of 10 people felt smoothness 〇: 7 out of 10 people felt smoothness 〇△: 6 out of 10 people felt smoothness △: 4-5 out of 10 people felt smoothness ×: Fewer than 3 out of 10 people felt smoothness [Stability evaluation method] The test was visually inspected at 25°C and 50% humidity to see if any separation or lumps had occurred. 〇: No separation or lumps have occurred ×: Separation or lumps have occurred

[0062] [Table 9]

[0063] As can be seen from Table 9, when oil-absorbing powder is added, smoothness tends to improve, but it is preferable that the total amount of liquid is slightly higher (55% by mass or more).

[0064] Examples of formulations of cosmetics according to the present invention are given below. Formulation example 1: Skin care solid Ingredients Amount (mass%) Ethylhexyl methoxycinnamate 15% Ethylhexyl salicylate 10% Dipropylene glycol 21% PEG-6 26% BisPEG-18 methyl ether dimethyl silane 20% PEG-400 8%

[0065] Formulation example 2: Lipstick Ingredients Amount (mass%) Ethylhexyl methoxycinnamate 15% Ethylhexyl salicylate 10% Dipropylene glycol 21% PEG-6 23% BisPEG-18 methyl ether dimethyl silane 20% PEG-400 8% Red 202 3%

[0066] Formulation example 3: Foundation Ingredients Amount (mass%) Mica residue Silica-coated mica 5% Boron nitride 3.5% Hydrophobic treated pigment grade titanium dioxide 7% Hydrophobic red iron oxide 0.1% Hydrophobic treated yellow iron oxide 0.9% Hydrophobic treated black iron oxide 0.07% Silica 15% (Dimethicone / vinyl dimethicone) crosspolymer 5% Clophenesin 0.15% Dimethicone (10CS) 18.5% Bis-butyldimethicone polyglyceryl-3 0.5% Ethylhexyl methoxycinnamate 7.5% Ethylhexyl salicylate 5% Dipropylene glycol 8% PEG-6 13% PEG-400 2.5%

[0067] Prescription example 4: Eye shadow Ingredients Amount (mass%) Mica residue Silica-coated mica 9% Talc 5% Boron nitride 3.5% Pearlizing agent (mica / iron oxide) 12% Silica 14% (Dimethicone / vinyl dimethicone) crosspolymer 6% Chlorphenesin 0.15% Dimethicone (100CS) 18.5% Bis-butyldimethicone polyglyceryl-3 0.5% Ethylhexyl methoxycinnamate 5% Ethylhexyl salicylate 5% Dipropylene glycol 7% PEG-300 10% PEG-400 1.5%

[0068] Prescription example 5: Cleaning agent Ingredients Amount (mass%) Ethylhexyl methoxycinnamate 15% Ethylhexyl salicylate 10% Dipropylene glycol 19% PEG-6 26% BisPEG-18 methyl ether dimethyl silane 20% PEG-400 8% Lauryl Betaine 2%

[0069] Prescription example 6: Cleaning agent Ingredients Amount (mass%) Ethylhexyl methoxycinnamate 15% Ethylhexyl salicylate 10% Dipropylene glycol 18% PEG-6 26% BisPEG-18 methyl ether dimethyl silane 20% PEG-400 8% Triglyceryl-6 Dicaprate 3%

Claims

1. an oily liquid medium that separates when mixed with water in a 1:1 ratio; an aqueous liquid medium which is an organic liquid medium other than water and which forms a homogeneous phase when mixed with water in a 1:1 ratio, and which forms a homogeneous phase when mixed with the oily liquid medium; an aqueous solidifying agent that is soluble in the aqueous liquid medium and that gels and / or solidifies the aqueous liquid medium; Including, the oily liquid medium and the aqueous liquid medium are gelled and / or solidified by an aqueous solidifying agent; A solid composition, characterized in that the total amount of the aqueous liquid medium, the oily liquid medium, and the aqueous solidifying agent is 90% by mass or more of the amount of the composition excluding powder.

2. 2. The solid composition according to claim 1, further comprising an oil-absorbing powder containing an oil component other than the oily liquid medium.

3. 3. The solid composition according to claim 1, wherein the hardness of the solid composition is 10 to 500 when a probe having a diameter of 5.6 mm is inserted at a rate of 20 mm / min using a rheometer.

4. The composition according to any one of claims 1 to 3, The oily liquid medium may contain, as a phenyl-containing substance, a cinnamic acid derivative selected from ethylhexyl methoxycinnamate, isopropyl methoxycinnamate, and isoamyl methoxycinnamate; a PABA derivative selected from para-aminobenzoic acid, ethyl PABA, ethyl-dihydroxypropyl PABA, ethylhexyl-dimethyl PABA, and glyceryl PABA; a salicylic acid derivative selected from homosalate, ethylhexyl salicylate, dipropylene glycol salicylate, and TEA salicylate; a benzophenone benzophenone derivatives selected from benzophenone-1, benzophenone-2, benzophenone-3, oxybenzone, benzophenone-4, benzophenone-5, benzophenone-6, benzophenone-8, benzophenone-9, and benzophenone-12; benzylidene camphor derivatives selected from 3-benzylidene camphor, 4-methylbenzylidene camphor, benzylidene camphorsulfonic acid, benzalkonium camphor methosulfate, terephthalidene discamphorsulfonic acid, and polyacrylamidomethylbenzylidene camphor Conductors; triazine derivatives selected from anisotriazine, ethylhexyl triazone, diethylhexylbutamido triazone, 2,4,6-tris(diisobutyl-4'-aminobenzalmalonate)-s-triazine, 2,4-bis-[{4-(2-ethylhexyloxy)-2-hydroxy}-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine, and 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]1,3,5-triazine; phenyl dibenzimidazole tetrasulfonic acid dinamate phenylbenzimidazole derivatives selected from thorium; phenylbenzotriazole derivatives selected from drometrizole trisiloxane and methylenebis(benzotriazolyltetramethylbutylphenol); anthranil derivatives selected from menthyl anthranilate; imidazoline derivatives selected from ethylhexyl dimethoxybenzylidene dioxoimidazoline propionate; benzalmalonate derivatives selected from polyorganosiloxanes having benzalmalonate functional groups;one or more selected from the group consisting of 4,4-diarylbutadiene derivatives selected from 1,1-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene, diethylaminohydroxybenzoylhexylbenzoate, bisethylhexyloxyphenol methoxyphenyl triazine, and homosalate, and diols and triols that are not miscible with water at a 1:1 ratio; the aqueous liquid medium is one or more selected from the group consisting of dipropylene glycol, polyethylene glycol that is liquid at room temperature, PEG / PPG-14 / 7 dimethyl ether, PEG / PPG-9 / 2 dimethyl ether, PEG / PPG-36 / 41 dimethyl ether, PEG / PPG-55 / 28 dimethyl ether, PEG / PPG-17 / 4 dimethyl ether, 1,2-hexanediol, isopropylene glycol, propylene glycol, and 1,3-butylene glycol; The aqueous solidifying agent is one or more selected from the group consisting of bis(polyethylene glycol methyl ether dimethyl silane), polyethylene glycol-decyltetradeceth-20-hexamethylene diisocyanate copolymer, polyethylene glycol that is solid at 25°C, and polyurethane-59.

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