Metal pipes for oil wells

Abstract

Provided is a metal pipe for an oil well, the metal pipe having excellent seizure resistance, even when a plating layer is formed only on or above the contact surface of one among a pin and a box. A metal pipe for an oil well (1) according to the present disclosure comprises: a pin (40) including a pin contact surface (400) having a male thread portion (41); and a box (50) including a box contact surface (500) having a female thread portion (51). The metal pipe for an oil well (1) according to the present disclosure further has: a zirconium oxide coating film (100) formed on one among the pin contact surface (400) and the box contact surface (500); a first resin coating film (310) formed on or above the zirconium oxide coating film (100); a plating layer (200) formed on or above the other among the pin contact surface (400) and the box contact surface (500); and a second resin coating film (320) formed on or above the plating layer (200).

Description

[Technical Field]

[0001] The present disclosure relates to metal tubing, and more particularly to metal tubing for oil wells. [Background technology]

[0002] Metallic oil well pipes are used in oil wells and gas wells (hereinafter, oil wells and gas wells will be collectively referred to simply as "oil wells"). Metallic oil well pipes have threaded joints. Specifically, at oil well drilling sites, multiple metallic oil well pipes are connected according to the depth of the oil well to form a connected oil well pipe assembly, typically casing or tubing. A connected oil well pipe assembly is formed by screwing metallic oil well pipes together. Inspection of the connected oil well pipe assembly may also be carried out. When inspection is carried out, the connected oil well pipe assembly is pulled up and unscrewed. Then, the metallic oil well pipe is removed from the connected oil well pipe assembly by unscrewing, and inspected. After inspection, the metallic oil well pipes are screwed together again, and the metallic oil well pipe is reused as part of the connected oil well pipe assembly.

[0003] The metal oil well pipe includes a pin and a box. The pin has a pin contact surface including a male thread portion on the outer peripheral surface of the end of the metal oil well pipe. The box has a box contact surface including a female thread portion on the inner peripheral surface of the end of the metal oil well pipe. In this specification, the male thread portion and the female thread portion are collectively referred to as "thread portion." Note that the pin contact surface may further include a pin-unthreaded metal contact portion including a pin seal surface and a pin shoulder surface. Similarly, the box contact surface may further include a box-unthreaded metal contact portion including a box seal surface and a box shoulder surface.

[0004] The pin contact surface and the box contact surface of an oil well metal pipe are repeatedly subjected to strong friction when the pipe is screwed in and out. Therefore, the pin contact surface and the box contact surface are prone to galling (irreparable seizure) when the pipe is screwed in and out repeatedly. Therefore, oil well metal pipe is required to have sufficient durability against friction, i.e., excellent seizure resistance.

[0005] Conventionally, compound grease containing heavy metal powder, called dope, has been used to improve the seizure resistance of oil well metal pipes. The application of compound grease to the pin contact surface and / or box contact surface can improve the seizure resistance of oil well metal pipes. However, the heavy metal powders, such as Pb, Zn, and Cu, contained in the compound grease may have an adverse effect on the environment. Therefore, there is a need to develop oil well metal pipes that have excellent seizure resistance without the use of compound grease.

[0006] Techniques for improving the galling resistance of metal pipes for oil wells have been proposed, for example, in International Publication No. 2006 / 104251 (Patent Document 1), International Publication No. 2008 / 108263 (Patent Document 2), and International Publication No. 2016 / 170031 (Patent Document 3).

[0007] The oil well metal pipe disclosed in Patent Document 1 has a threaded joint and has a viscous liquid or semi-solid lubricating coating and a dry solid coating formed thereon on the contact surface of at least one of the pin and box. Patent Document 1 discloses that this oil well metal pipe can suppress the occurrence of rust and improve seizure resistance and airtightness without using compound grease.

[0008] The oil well metal pipe disclosed in Patent Document 2 has a threaded joint, and has a Cu alloy plating layer selected from the group consisting of Cu-Zn alloy and Cu-Zn-M1 alloy (M1 is one or more elements selected from the group consisting of Sn, Bi, and In) on the contact surface of at least one of the pin and box. Patent Document 2 discloses that this oil well metal pipe can prevent the occurrence of crevice corrosion and improve airtightness and seizure resistance without using compound grease.

[0009] The oil well metal pipe disclosed in Patent Document 3 has a threaded joint and a Zn-Ni alloy plating layer on the contact surface of at least one of the pin and the box. Patent Document 3 discloses that this oil well metal pipe can improve corrosion resistance and seizure resistance without using compound grease. [Prior art documents] [Patent documents]

[0010] [Patent Document 1] International Publication No. 2006 / 104251 [Patent Document 2] International Publication No. 2008 / 108263 [Patent Document 3] International Publication No. 2016 / 170031 Summary of the Invention [Problem to be solved by the invention]

[0011] According to the technology disclosed in Patent Document 1, the seizure resistance of a metal oil well pipe can be improved by forming a lubricating coating on or above the contact surface of at least one of the pin and the box. According to the technologies disclosed in Patent Documents 2 and 3, the seizure resistance of a metal oil well pipe can be improved by forming a plating layer on the contact surface of at least one of the pin and the box.

[0012] In oil well pipes, from the viewpoint of productivity and manufacturing costs, a coating layer may be formed only on or above the contact surface of one of the pin and box. For example, in a T&C (Threaded and Coupled) type oil well pipe, which is one form of oil well pipe described below, a pin is formed on a long steel pipe and a box is formed on a short steel pipe (coupling). Here, the coupling does not require special equipment or the like compared to the long steel pipe, and a coating layer can be easily formed on the surface. Therefore, there are cases where a coating layer is formed only on or above the contact surface of the box, and no coating layer is formed on or above the contact surface of the pin.

[0013] Thus, in consideration of industrial productivity, there has been a demand for a metal oil well pipe that has excellent galling resistance even when a coating layer is formed only on or above the contact surface of one of the pin and the box. However, Patent Documents 2 and 3 do not consider at all the relationship between the structure of the contact surface on which the coating layer is not formed and the galling resistance of the metal oil well pipe when a coating layer is formed only on or above the contact surface of one of the pin and the box.

[0014] An object of the present disclosure is to provide a metal oil well pipe having excellent galling resistance even when a plating layer is formed only on or above the contact surface of one of the pin and the box. [Means for solving the problem]

[0015] The metal pipe for oil well use according to the present disclosure comprises: a tube body including a first end and a second end; The tube body is a pin formed on the first end; a box formed at the second end; The pin is a pin contact surface including an external thread; The box a box contact surface including an internal thread; The metal oil well pipe further comprises: a zirconium oxide coating formed on one of the pin contact surface and the box contact surface; a first resin coating formed on or above the zirconium oxide coating; a plating layer formed on or above the other of the pin contact surface and the box contact surface; and a second resin coating formed on or above the plating layer. [Effects of the Invention]

[0016] The metal oil well pipe according to the present disclosure has excellent galling resistance even when a plating layer is formed only on or above the contact surface of one of the pin and the box. [Brief explanation of the drawings]

[0017] [Figure 1] FIG. 1 is a diagram showing the relationship between the number of times a screw is tightened (times) and shouldering torque (ft.lbs), which is an index of seizure resistance, in Examples described later. [Figure 2] FIG. 2 is a side view of the metal oil well pipe according to this embodiment. [Figure 3] 3 is a partial cross-sectional view showing a cross section (longitudinal cross section) parallel to the pipe axis direction of the coupling of the metallic pipe for oil well use shown in FIG. [Figure 4] FIG. 4 is a cross-sectional view of a portion of the metallic oil well pipe shown in FIG. 3 near a pin, taken along a line parallel to the axial direction of the metallic oil well pipe. [Figure 5] FIG. 5 is a cross-sectional view of a portion of the metallic oil well pipe shown in FIG. 3 near the box, taken along a line parallel to the axial direction of the metallic oil well pipe. [Figure 6] FIG. 6 is a partial cross-sectional view including a longitudinal section of a metallic pipe for oil well use according to this embodiment, which has another configuration different from that shown in FIG. [Figure 7] FIG. 7 is a partial cross-sectional view including a longitudinal section of the integral type metallic pipe for oil well according to this embodiment. [Figure 8] FIG. 8 is a cross-sectional view of the vicinity of the pin contact surface of the metallic pipe for oil well according to this embodiment. [Figure 9] FIG. 9 is a cross-sectional view of the vicinity of the contact surface of the box corresponding to FIG. [Figure 10] FIG. 10 is a cross-sectional view of the vicinity of another pin contact surface having a different configuration from that of FIG. [Figure 11] FIG. 11 is a cross-sectional view of the vicinity of the contact surface of the box corresponding to FIG. DETAILED DESCRIPTION OF THE INVENTION

[0018] The present embodiment will be described in detail below with reference to the drawings. In the drawings, the same or corresponding parts are designated by the same reference numerals and description thereof will not be repeated.

[0019] The present inventors have conducted detailed studies on means for improving the galling resistance of a metal oil well pipe in which a plating layer is formed only on or above the contact surface of one of the pin and the box, and have obtained the following findings.

[0020] First, the inventors investigated forming a resin coating on the upper surface of both the pin and the box of a metal oil well pipe in which a plating layer is formed only on or above the contact surface of one of the pin and the box. If a resin coating is formed, the resin coating penetrates between the contact surfaces when the metal oil well pipes are screwed together. As a result, it is possible to suppress the occurrence of seizure on the contact surfaces. If a resin coating is formed on the upper surface of both the pin and the box, it is possible to further improve the corrosion resistance of the contact surfaces of the pin and the box to a certain extent.

[0021] In the oil well metal pipe according to this embodiment, a plating layer is formed only on or above the contact surface of one of the pin and the box. That is, the oil well metal pipe according to this embodiment includes a contact surface on or above which a plating layer is not formed. In the past, when a resin coating was formed above a contact surface on which a plating layer was not formed, a chemical conversion coating was sometimes formed below the resin coating (between the resin coating and the contact surface). The chemical conversion coating improves the corrosion resistance of the contact surface. Furthermore, the zinc phosphate coating among the chemical conversion coatings improves the adhesion of the resin coating.

[0022] Specifically, zinc phosphate coatings tend to have coarse crystal grains, which increases their surface roughness. Therefore, if a resin coating is formed on the zinc phosphate coating, the adhesion of the resin coating is enhanced due to the so-called anchor effect. As described above, when oil well pipes are screwed together, high surface pressure is applied to the contact surfaces. Therefore, repeated screwing and unscrewing may cause the resin coating to peel off. However, by improving the adhesion of the resin coating, it may be possible to suppress peeling of the resin coating even when screwing and unscrewing are repeated. As a result, it is expected that the seizure resistance of oil well pipes will be enhanced. Therefore, in order to improve the corrosion resistance of the contact surfaces and the adhesion of the resin coating, zinc phosphate coatings have been used as chemical conversion coatings for oil well pipes.

[0023] However, as a result of detailed studies by the present inventors, it has become clear that forming a zirconium oxide coating as a chemical conversion coating on the contact surface on which no plating layer is formed can sometimes improve the galling resistance of a metal oil well pipe compared to forming a zinc phosphate coating. This point will be explained in detail with reference to the drawings.

[0024] FIG. 1 shows the relationship between the number of times the screw was tightened (times) and the shouldering torque (ft.lbs), which is an index of seizure resistance, in the examples described later. FIG. 1 was obtained by repeatedly tightening and loosening a metal oil well pipe having a pin contact surface formed with a chemical conversion coating and a resin coating, and a box contact surface formed with a plating layer and a resin coating, in the examples described later. The circles (○) in FIG. 1 indicate the results of Test No. 1, in which a zirconium oxide coating was formed as the chemical conversion coating. The squares (□) in FIG. 1 indicate the results of Test No. 2, in which a zinc phosphate coating was formed as the chemical conversion coating. In addition, metal oil well pipes with the same configuration, except for the chemical conversion coating, were used in Test Nos. 1 and 2.

[0025] The horizontal axis of Fig. 1 shows the number of times the metal oil well pipe was tightened and unscrewed. The vertical axis of Fig. 1 shows the shouldering torque (ft.lbs) when the metal oil well pipe was tightened. The shouldering torque means the torque when the pin shoulder surface on the pin contact surface comes into contact with the box shoulder surface on the box contact surface when the metal oil well pipe used in the examples described later is tightened. In other words, the lower the shouldering torque maintained after repeated tightening and unscrewing, the better the galling resistance can be determined to be.

[0026] Referring to FIG. 1, during the second tightening, Test No. 1, which had a zirconium oxide coating formed on the contact surface, exhibited a higher shouldering torque than Test No. 2, which had a zinc phosphate coating formed on the contact surface. Furthermore, referring to FIG. 1, after the fourth tightening, Test No. 1 exhibited a lower shouldering torque than Test No. 2. In other words, referring to FIG. 1, after one tightening and loosening cycle, Test No. 1 exhibited a higher shouldering torque than Test No. 2. However, even after repeated tightening and loosening cycles, Test No. 1 maintained a shouldering torque within a certain range. On the other hand, Test No. 2 exhibited an increased shouldering torque with each tightening and loosening cycle. As a result, it was confirmed that Test No. 1 exhibited a lower shouldering torque than Test No. 2 when the number of tightening and loosening cycles increased to four or more. Thus, it has been revealed that when the metal pipe for oil well use is repeatedly tightened and loosened, the formation of a zirconium oxide coating on the contact surface improves the galling resistance of the metal pipe for oil well use compared to the formation of a zinc phosphate coating on the contact surface. The details of the reason for this are not clear. However, the inventors speculate as follows.

[0027] As mentioned above, zinc phosphate coatings tend to have coarse crystal grains and high surface roughness. On the other hand, zirconium oxide coatings tend to form dense, uniform, thin coatings. In other words, in terms of the adhesion of the resin coating formed on the chemical conversion coating, a resin coating on a zinc phosphate coating is thought to have higher adhesion than a resin coating on a zirconium oxide coating. In other words, a resin coating on a zirconium oxide coating is more likely to peel off than a resin coating on a zinc phosphate coating. As a result, during the second screw tightening, test number 2, which had a zinc phosphate coating with a larger amount of remaining resin coating, may have exhibited a lower shouldering torque.

[0028] Further repeated tightening and loosening of the screw may result in further peeling of the resin coating on the zirconium oxide coating. On the other hand, the resin coating on the zinc phosphate coating is more likely to remain, which may actually damage the resin coating on the plating layer during tightening and loosening. As a result, it is speculated that the total amount of resin coating on the plating layer and the resin coating on the zinc phosphate coating may be lower than when a zirconium oxide coating is formed. In short, the inventors speculate that the resin coating on the zirconium oxide coating is less likely to be damaged by repeated tightening and loosening due to its ease of peeling. As a result, the inventors speculate that Test No. 1, in which the resin coating on the plating layer is more likely to remain even after repeated tightening and loosening, was able to maintain a low shouldering torque.

[0029] It is possible that the galling resistance of a metal oil well pipe may be improved by forming a zirconium oxide coating on the contact surfaces where no plating layer is formed even after repeated screwing and unscrewing through a mechanism other than the above. However, it has been proven by the examples described below that the galling resistance of a metal oil well pipe may be improved by forming a zirconium oxide coating on one of the contact surfaces of the pin and the box, forming a resin coating on or above that zirconium oxide coating, forming a plating layer on or above the other contact surface of the pin and the box, and forming a resin coating on or above that plating layer.

[0030] The metallic oil well pipe according to the present embodiment, which has been completed based on the above findings, has the following features.

[0031] [1] A metal pipe for oil wells, a tube body including a first end and a second end; The tube body is a pin formed on the first end; a box formed at the second end; The pin is a pin contact surface including an external thread; The box a box contact surface including an internal thread; The metal oil well pipe further comprises: a zirconium oxide coating formed on one of the pin contact surface and the box contact surface; a first resin coating formed on or above the zirconium oxide coating; a plating layer formed on or above the other of the pin contact surface and the box contact surface; A second resin coating formed on or above the plating layer. Metal pipes for oil wells.

[0032] [2] The metal pipe for oil well use according to [1], the zirconium oxide coating is formed on the pin contact surface; The plating layer is formed on or above the box contact surface. Metal pipes for oil wells.

[0033] [3] The metal pipe for oil well use according to [1] or [2], The plating layer is a Zn-Ni alloy plating layer. Metal pipes for oil wells.

[0034] The metallic oil well pipe according to this embodiment will be described in detail below.

[0035] [Configuration of metal pipe for oil wells] First, the configuration of the oil well metallic pipe of this embodiment will be described. The oil well metallic pipe has a well-known configuration. There are two types of oil well metallic pipe: T&C type oil well metallic pipe and integral type oil well metallic pipe. Each type of oil well metallic pipe will be described in detail below.

[0036] [When oil well metal pipe 1 is T&C type] Fig. 2 is a side view of the metal oil well pipe 1 according to this embodiment. Fig. 2 is a side view of a so-called T&C (Threaded and Coupled) type metal oil well pipe 1. Referring to Fig. 2, the metal oil well pipe 1 includes a pipe body 10.

[0037] The pipe body 10 extends in the pipe axis direction. A cross section of the pipe body 10 perpendicular to the pipe axis direction is circular. The pipe body 10 includes a first end portion 10A and a second end portion 10B. The first end portion 10A is the end portion opposite the second end portion 10B. In the T&C type metal pipe for oil well use 1 shown in FIG. 2, the pipe body 10 includes a pin pipe body 11 and a coupling 12. The coupling 12 is attached to one end of the pin pipe body 11. More specifically, the coupling 12 is fastened to one end of the pin pipe body 11 by a screw.

[0038] Fig. 3 is a partial cross-sectional view showing a cross section (longitudinal cross section) parallel to the pipe axis direction of the coupling 12 of the metal oil well pipe 1 shown in Fig. 2. With reference to Figs. 2 and 3, the pipe body 10 includes a pin 40 and a box 50. The pin 40 is formed at a first end 10A of the pipe body 10. At the time of fastening, the pin 40 is inserted into the box 50 of another metal oil well pipe 1 (not shown) and fastened to the box 50 of the other metal oil well pipe 1 by a screw.

[0039] The box 50 is formed at the second end 10B of the pipe body 10. At the time of fastening, the pin 40 of another metal pipe for oil well use 1 is inserted into the box 50, and the box 50 is fastened to the pin 40 of the other metal pipe for oil well use 1 by a screw.

[0040] [About the configuration of pin 40] Fig. 4 is a cross-sectional view parallel to the pipe axis direction of the metal oil well pipe 1 of a portion near a pin 40 of the metal oil well pipe 1 shown in Fig. 3. The dashed line portion in Fig. 4 shows the configuration of a box 50 of another metal oil well pipe 1 when fastening to another metal oil well pipe 1. Referring to Fig. 4, the pin 40 has a pin contact surface 400 on the outer circumferential surface of the first end 10A of the pipe body 10. When fastening to another metal oil well pipe 1, the pin contact surface 400 is screwed into the box 50 of the other metal oil well pipe 1 and comes into contact with a box contact surface 500 (described later) of the box 50.

[0041] The pin contact surface 400 includes at least a male thread portion 41 formed on the outer circumferential surface of the first end portion 10A. The pin contact surface 400 may further include a pin seal surface 42 and a pin shoulder surface 43. In FIG. 4, the pin shoulder surface 43 is located on the tip surface of the first end portion 10A, and the pin seal surface 42 is located on the outer circumferential surface of the first end portion 10A closer to the tip of the first end portion 10A than the male thread portion 41. In other words, the pin seal surface 42 is located between the male thread portion 41 and the pin shoulder surface 43. The pin seal surface 42 is tapered. Specifically, the outer diameter of the pin seal surface 42 gradually decreases from the male thread portion 41 to the pin shoulder surface 43 in the longitudinal direction (pipe axis direction) of the first end portion 10A.

[0042] When fastening another oil well metal pipe 1, the pin seal surface 42 comes into contact with a box seal surface 52 (described later) of the box 50 of the other oil well metal pipe 1. More specifically, when fastening, the pin 40 is inserted into the box 50 of the other oil well metal pipe 1, so that the pin seal surface 42 comes into contact with the box seal surface 52. Then, when the pin 40 is further screwed into the box 50 of the other oil well metal pipe 1, the pin seal surface 42 comes into close contact with the box seal surface 52. As a result, when fastening, the pin seal surface 42 comes into close contact with the box seal surface 52, forming a seal based on metal-metal contact. Therefore, the airtightness of the oil well metal pipes 1 fastened to each other can be improved.

[0043] In Fig. 4, the pin shoulder surface 43 is disposed on the tip surface of the first end portion 10A. That is, in the pin 40 shown in Fig. 4, the male thread portion 41, the pin seal surface 42, and the pin shoulder surface 43 are disposed in this order from the center of the pipe body 10 toward the first end portion 10A. When fastening with another oil well metal pipe 1, the pin shoulder surface 43 faces and contacts a box shoulder surface 53 (described later) of a box 50 of the other oil well metal pipe 1. More specifically, when fastening, the pin 40 is inserted into the box 50 of the other oil well metal pipe 1, so that the pin shoulder surface 43 contacts the box shoulder surface 53. This allows a high torque to be obtained when fastening. Furthermore, the positional relationship between the pin 40 and the box 50 in the fastened state can be stabilized.

[0044] The pin contact surface 400 of the pin 40 includes at least the male thread portion 41. In other words, the pin contact surface 400 may include the male thread portion 41, but not the pin seal surface 42 or the pin shoulder surface 43. The pin contact surface 400 may include the male thread portion 41 and the pin shoulder surface 43, but not the pin seal surface 42. The pin contact surface 400 may include the male thread portion 41 and the pin seal surface 42, but not the pin shoulder surface 43.

[0045] [About the composition of Box 50] Fig. 5 is a cross-sectional view parallel to the pipe axis direction of the metal oil well pipe 1 of a portion near the box 50 of the metal oil well pipe 1 shown in Fig. 3. The dashed line portion in Fig. 5 shows the configuration of the pin 40 of another metal oil well pipe 1 when fastening to another metal oil well pipe 1. Referring to Fig. 5, the box 50 has a box contact surface 500 on the inner circumferential surface of the second end 10B of the pipe body 10. When fastening to another metal oil well pipe 1, the pin 40 of the other metal oil well pipe 1 is screwed into the box 50 and the box contact surface 500 comes into contact with the pin contact surface 400 of the pin 40.

[0046] The box contact surface 500 includes at least a female thread portion 51 formed on the inner circumferential surface of the second end portion 10B. During fastening, the female thread portion 51 meshes with the male thread portion 41 of the pin 40 of another metal oil well pipe 1.

[0047] The box contact surface 500 may further include a box seal surface 52 and a box shoulder surface 53. In FIG. 5, the box seal surface 52 is located on the inner circumferential surface of the second end portion 10B, closer to the pipe body 10 than the female thread portion 51. In other words, the box seal surface 52 is located between the female thread portion 51 and the box shoulder surface 53. The box seal surface 52 is tapered. Specifically, the inner diameter of the box seal surface 52 gradually decreases from the female thread portion 51 toward the box shoulder surface 53 in the longitudinal direction (pipe axial direction) of the second end portion 10B.

[0048] When fastening another metal oil well pipe 1, the box seal surface 52 comes into contact with the pin seal surface 42 of the pin 40 of the other metal oil well pipe 1. More specifically, when fastening, the pin 40 of the other metal oil well pipe 1 is screwed into the box 50, so that the box seal surface 52 comes into contact with the pin seal surface 42, and when further screwed, the box seal surface 52 comes into close contact with the pin seal surface 42. As a result, when fastening, the box seal surface 52 comes into close contact with the pin seal surface 42, forming a seal based on metal-metal contact. Therefore, the airtightness of the metal oil well pipes 1 fastened together can be improved.

[0049] The box shoulder surface 53 is located closer to the pipe body 10 than the box seal surface 52. That is, in the box 50, the box shoulder surface 53, the box seal surface 52, and the female thread portion 51 are located in this order from the center of the pipe body 10 toward the tip of the second end 10B. When fastening another oil well metal pipe 1, the box shoulder surface 53 faces and contacts the pin shoulder surface 43 of the pin 40 of the other oil well metal pipe 1. More specifically, when fastening, the pin 40 of the other oil well metal pipe 1 is inserted into the box 50, so that the box shoulder surface 53 contacts the pin shoulder surface 43. This allows a high torque to be obtained when fastening. Furthermore, the positional relationship between the pin 40 and the box 50 in the fastened state can be stabilized.

[0050] The box contact surface 500 includes at least an internal thread portion 51. During fastening, the internal thread portion 51 of the box contact surface 500 of the box 50 corresponds to and contacts the external thread portion 41 of the pin contact surface 400 of the pin 40. The box seal surface 52 corresponds to and contacts the pin seal surface 42. The box shoulder surface 53 corresponds to and contacts the pin shoulder surface 43.

[0051] When the pin contact surface 400 includes the male thread portion 41 but does not include the pin seal surface 42 or the pin shoulder surface 43, the box contact surface 500 includes the female thread portion 51 but does not include the box seal surface 52 or the box shoulder surface 53. When the pin contact surface 400 includes the male thread portion 41 and the pin shoulder surface 43 but does not include the pin seal surface 42, the box contact surface 500 includes the female thread portion 51 and the box shoulder surface 53 but does not include the box seal surface 52. When the pin contact surface 400 includes the male thread portion 41 and the pin seal surface 42 but does not include the pin shoulder surface 43, the box contact surface 500 includes the female thread portion 51 and the box seal surface 52 but does not include the box shoulder surface 53.

[0052] The pin contact surface 400 may include multiple male thread portions 41, multiple pin seal surfaces 42, or multiple pin shoulder surfaces 43. For example, on the pin contact surface 400 of the pin 40, the pin shoulder surface 43, the pin seal surface 42, the male thread portion 41, the pin seal surface 42, the pin shoulder surface 43, the pin seal surface 42, and the male thread portion 41 may be arranged in this order from the tip of the first end 10A toward the center of the pipe body 10. In this case, on the box contact surface 500 of the box 50, the female thread portion 51, the box seal surface 52, the box shoulder surface 53, the box seal surface 52, the female thread portion 51, the box seal surface 52, and the box shoulder surface 53 are arranged in this order from the tip of the second end 10B toward the center of the pipe body 10.

[0053] 4 and 5 show a so-called premium joint in which the pin 40 includes a male thread portion 41, a pin seal surface 42, and a pin shoulder surface 43, and the box 50 includes a female thread portion 51, a box seal surface 52, and a box shoulder surface 53. However, as described above, the pin 40 may include the male thread portion 41 and not include the pin seal surface 42 or the pin shoulder surface 43. In this case, the box 50 includes the female thread portion 51, but not the box seal surface 52 or the box shoulder surface 53. FIG. 6 is a partial cross-sectional view including a longitudinal section of a metal oil well pipe of this embodiment, which has another configuration different from that shown in FIG.

[0054] [When the oil well metal pipe 1 is an integral type] 2, 3 and 6 is a so-called T&C type metal oil well pipe 1 in which a pipe body 10 includes a pin pipe body 11 and a coupling 12. However, the metal oil well pipe 1 of this embodiment may be an integral type instead of a T&C type.

[0055] FIG. 7 is a partial cross-sectional view including a longitudinal section of an integral type metal oil well pipe 1 according to this embodiment. Referring to FIG. 7, the integral type metal oil well pipe 1 includes a pipe body 10. The pipe body 10 includes a first end portion 10A and a second end portion 10B. The first end portion 10A is located on the opposite side to the second end portion 10B. As described above, in the T&C type metal oil well pipe 1, the pipe body 10 includes a pin pipe body 11 and a coupling 12. That is, in the T&C type metal oil well pipe 1, the pipe body 10 is formed by fastening two separate members (the pin pipe body 11 and the coupling 12). In contrast, in the integral type metal oil well pipe 1, the pipe body 10 is integrally formed.

[0056] The pin 40 is formed at a first end 10A of the pipe body 10. When fastening, the pin 40 is inserted into and screwed into a box 50 of another integral type metallic pipe for oil well use 1, and is fastened to the box 50 of another integral type metallic pipe for oil well use 1. The box 50 is formed at a second end 10B of the pipe body 10. When fastening, the pin 40 of another integral type metallic pipe for oil well use 1 is inserted into and screwed into the box 50, and is fastened to the pin 40 of another integral type metallic pipe for oil well use 1.

[0057] The configuration of the pin 40 of the integral type metal oil well pipe 1 is the same as the configuration of the pin 40 of the T&C type metal oil well pipe 1 shown in Fig. 4. Similarly, the configuration of the box 50 of the integral type metal oil well pipe 1 is the same as the configuration of the box 50 of the T&C type metal oil well pipe 1 shown in Fig. 5. In Figs. 4 and 5, in the pin 40, the pin shoulder surface 43, the pin seal surface 42, and the male thread portion 41 are arranged in this order from the tip of the first end 10A toward the center of the pipe body 10. Therefore, in the box 50, the female thread portion 51, the box seal surface 52, and the box shoulder surface 53 are arranged in this order from the tip of the second end 10B toward the center of the pipe body 10. However, like the pin contact surface 400 of the pin 40 of the T&C type metal oil well pipe 1, the pin contact surface 400 of the pin 40 of the integral type metal oil well pipe 1 only needs to include at least the male thread portion 41. Furthermore, like the box contact surface 500 of the box 50 of the T&C type metal pipe for oil well use 1, the box contact surface 500 of the box 50 of the integral type metal pipe for oil well use 1 may include at least the female thread portion 51.

[0058] In short, the metal oil well pipe 1 of this embodiment may be of the T&C type or the integral type.

[0059] [Zirconium oxide coating] The metal oil well pipe 1 according to this embodiment has a zirconium oxide coating 100 on either the pin contact surface 400 or the box contact surface 500. Fig. 8 is a cross-sectional view of the vicinity of the pin contact surface 400 of the metal oil well pipe 1 according to this embodiment. Fig. 9 is a cross-sectional view of the vicinity of the box contact surface 500 corresponding to Fig. 8. Fig. 10 is a cross-sectional view of the vicinity of another pin contact surface 400 having a different configuration from that shown in Fig. 8. Fig. 11 is a cross-sectional view of the vicinity of the box contact surface 500 corresponding to Fig. 10.

[0060] With reference to Fig. 8, the zirconium oxide coating 100 may be formed on the pin contact surface 400. In this case, with reference to Fig. 9, a plating layer 200 is formed on or above the corresponding box contact surface 500. Also, with reference to Fig. 11, the zirconium oxide coating 100 may be formed on the box contact surface 500. In this case, with reference to Fig. 10, a plating layer 200 is formed on or above the corresponding pin contact surface 400. That is, the zirconium oxide coating 100 may be formed on either the pin contact surface 400 or the box contact surface 500. In short, the metal oil well pipe 1 according to this embodiment has the zirconium oxide coating 100 formed on either the pin contact surface 400 or the box contact surface 500.

[0061] The zirconium oxide coating 100 primarily contains amorphous zirconium oxide (ZrO2) and / or amorphous zirconium hydroxide (Zr(OH)4). That is, in the zirconium oxide coating 100 according to this embodiment, the total content of amorphous zirconium oxide (ZrO2) hydrate and amorphous zirconium hydroxide (Zr(OH)4) is, for example, 80 mass% or more. The zirconium oxide coating 100 may further contain an organic compound. The zirconium oxide coating 100 is a dense, thin, and uniform coating. Therefore, a resin coating formed on or above the zirconium oxide coating 100 has low adhesion and is easily peeled off. Therefore, the resin coating formed on or above the plating layer 200 is likely to remain even after repeated screwing and unscrewing, which is thought to result in improved seizure resistance of the metal oil well pipe 1. The resin coating will be described later.

[0062] As described above, the zirconium oxide coating 100 is a thin coating. Therefore, it is difficult to measure the thickness of the zirconium oxide coating 100. However, the zirconium oxide coating 100 can be confirmed by the following method. First, a calibration curve is created for the zirconium oxide coating, measuring the Zr content by inductively coupled plasma atomic emission spectroscopy (ICP-AES) and the Zr signal amount detected by X-ray fluorescence analysis. Specifically, the Zr signal amount is measured by X-ray fluorescence analysis for multiple steel sheets on which zirconium oxide coatings of different thicknesses are formed. The multiple steel sheets on which zirconium oxide coatings of different thicknesses are formed are further immersed in a hydrofluoric acid solution or the like to dissolve the zirconium oxide coating. Elemental analysis is then performed by ICP-AES on the hydrofluoric acid solution in which the zirconium oxide coating has been dissolved. A calibration curve is created using the Zr content obtained by elemental analysis and the Zr signal amount obtained by X-ray fluorescence analysis. X-ray fluorescence analysis is performed on the pin contact surface 400 or the box contact surface 500 according to this embodiment to determine the amount of Zr signal. The Zr content in the zirconium oxide coating is quantified from the determined amount of Zr signal using a calibration curve, thereby confirming the presence of the zirconium oxide coating.

[0063] [Plating layer] The oil well metal pipe 1 according to this embodiment has a zirconium oxide coating 100 on one of the pin contact surface 400 and the box contact surface 500, and a plating layer 200 on or above the other of the pin contact surface 400 and the box contact surface 500. As described above, with reference to Figures 8 and 9, when the zirconium oxide coating 100 is formed on the pin contact surface 400, the plating layer 200 is formed on or above the box contact surface 500. Similarly, with reference to Figures 10 and 11, when the zirconium oxide coating 100 is formed on the box contact surface 500, the plating layer 200 is formed on or above the pin contact surface 400.

[0064] Here, the plating layer 200 being formed on or above the pin contact surface 400 or the box contact surface 500 means that the plating layer 200 may be formed directly on the pin contact surface 400, the plating layer 200 may be formed directly on the box contact surface 500, another layer may be formed on the pin contact surface 400 and the plating layer 200 may be formed thereon, or another layer may be formed on the box contact surface 500 and the plating layer 200 may be formed thereon. Specifically, with reference to FIG. 9 , another layer 350 may be formed on the box contact surface 500 and the plating layer 200 may be formed thereon. Also, with reference to FIG. 10 , the plating layer 200 may be formed directly on the pin contact surface 400. The other layer 350 will be described later.

[0065] In the present embodiment, the plating layer 200 is not particularly limited. The plating layer 200 can be appropriately selected from known plating layers. The plating layer 200 may be, for example, a Cu plating layer, a Cr plating layer, a Zn plating layer, a Ni plating layer, a Cu-Sn alloy plating layer, a Zn-Co alloy plating layer, a Zn-Ni alloy plating layer, a Ni-P alloy plating layer, or a Cu-Sn-Zn alloy plating layer. Preferably, the plating layer 200 is a Zn-Ni alloy plating layer. If the plating layer 200 is a Zn-Ni alloy plating layer, its excellent wear resistance further enhances the seizure resistance of the metal oil well pipe 1 according to the present embodiment.

[0066] Furthermore, in this embodiment, the plating layer 200 may be a multi-layer plating layer including a plurality of plating layers. Furthermore, in this embodiment, the thickness of the plating layer 200 is not particularly limited. The thickness of the plating layer 200 is, for example, 1 to 50 μm.

[0067] [First resin coating] The oil well metal pipe 1 according to this embodiment has a zirconium oxide coating 100 on either the pin contact surface 400 or the box contact surface 500, and a first resin coating 310 on or above the zirconium oxide coating 100. Here, "having the first resin coating 310 on or above the zirconium oxide coating 100" means that the first resin coating 310 may be formed directly on the zirconium oxide coating 100, or that another layer may be formed on the zirconium oxide coating 100 and the first resin coating 310 may be formed on top of that. Specifically, with reference to FIG. 8, the first resin coating 310 may be formed directly on the zirconium oxide coating 100. Alternatively, with reference to FIG. 11, another layer 350 may be formed on the zirconium oxide coating 100 and the first resin coating 310 may be formed on top of that.

[0068] In this embodiment, the first resin coating 310 is not particularly limited. The first resin coating 310 can be appropriately selected from well-known resin coatings. The base material of the first resin coating 310 is resin. The type of resin is not particularly limited, and well-known resins can be used. The resin may be, for example, a thermosetting resin or an ultraviolet-curing resin. Specifically, the resin may be, for example, an acrylic resin, a silicone resin, an acrylic silicone resin, a urethane resin, an epoxy resin, a fluororesin, a phenolic resin, a polyimide resin, a polyamide-imide resin, a polyamide resin, or a polyether ether ketone resin. Preferably, the first resin coating 310 is one or more resins selected from the group consisting of an acrylic resin, a urethane resin, and an epoxy resin. In this case, the resin hardens upon thermal curing, further improving the seizure resistance of the metal oil well pipe 1 according to this embodiment. More preferably, the first resin coating 310 is an epoxy resin.

[0069] The first resin coating 310 according to this embodiment may further contain a lubricating material. The lubricating material is not particularly limited as long as it enhances the lubricity of the first resin coating 310. The lubricating material may be, for example, graphite, zinc oxide, boron nitride, talc, molybdenum disulfide, tungsten disulfide, graphite fluoride, tin sulfide, bismuth sulfide, organic molybdenum, thiosulfate, polytetrafluoroethylene (PTFE), melamine cyanurate (MCA), or perfluoropolyether (PFPE). A combination of the above-described lubricating materials may also be contained.

[0070] The first resin coating 310 according to this embodiment may contain other materials. For example, it may contain a pigment, an anti-rust additive, or an antiseptic. That is, in this embodiment, the first resin coating 310 is not particularly limited as long as it has a well-known configuration. Furthermore, in this embodiment, the thickness of the first resin coating 310 is not particularly limited. The thickness of the first resin coating 310 is, for example, 1 to 100 μm.

[0071] [Second resin coating] The oil well metal pipe 1 according to this embodiment includes a zirconium oxide coating 100 on one of the pin contact surface 400 and the box contact surface 500, a plating layer 200 on or above the other of the pin contact surface 400 and the box contact surface 500, and a second resin coating 320 on or above the plating layer 200. Here, "including the second resin coating 320 on or above the plating layer 200" means that the second resin coating 320 may be formed directly on the plating layer 200, or another layer may be formed on the plating layer 200 and the second resin coating 320 may be formed thereon. Specifically, with reference to FIG. 9 , the second resin coating 320 may be formed directly on the plating layer 200. Alternatively, with reference to FIG. 10 , another layer 350 may be formed on the plating layer 200 and the second resin coating 320 may be formed thereon.

[0072] In this embodiment, the second resin coating 320 is not particularly limited. The second resin coating 320 can be appropriately selected from well-known resin coatings. The base material of the second resin coating 320 is a resin. The type of resin is not particularly limited, and well-known resins can be used. The resin may be, for example, a phenolic resin, a urethane resin, an epoxy resin, a furan resin, a polyimide resin, a polyamideimide resin, a polyamide resin, or a polyetheretherketone resin. Preferably, the second resin coating 320 is one or more resins selected from the group consisting of a phenolic resin, a urethane resin, and an epoxy resin. In this case, the resin hardens upon thermal curing, further improving the seizure resistance of the metal oil well pipe 1 according to this embodiment. More preferably, the second resin coating 320 is an epoxy resin.

[0073] The second resin coating 320 according to this embodiment may further contain a lubricating material. The lubricating material is not particularly limited as long as it enhances the lubricity of the second resin coating 320. The lubricating material may be, for example, graphite, zinc oxide, boron nitride, talc, molybdenum disulfide, tungsten disulfide, graphite fluoride, tin sulfide, bismuth sulfide, organic molybdenum, thiosulfate, polytetrafluoroethylene (PTFE), melamine cyanurate (MCA), or perfluoropolyether (PFPE). A combination of the above-described lubricating materials may also be contained.

[0074] The second resin coating 320 according to this embodiment may contain other materials. For example, it may contain a pigment, an anti-rust additive, or an antiseptic. That is, in this embodiment, the second resin coating 320 is not particularly limited as long as it has a well-known configuration. Furthermore, in this embodiment, the thickness of the second resin coating 320 is not particularly limited. The thickness of the second resin coating 320 is, for example, 1 to 100 μm. The second resin coating 320 may have the same configuration as the first resin coating 310 or may have a different configuration. That is, the second resin coating 320 may contain the same resin, the same lubricating material, and the same antiseptic as the first resin coating 310. The second resin coating 320 may also contain a different resin, a different lubricating material, and a different pigment than the first resin coating 310.

[0075] [Other layers] The oil well metal pipe 1 according to this embodiment may have a layer 350 other than the zirconium oxide coating 100, the plating layer 200, the first resin coating 310, and the second resin coating 320 on or above the pin contact surface 400 and / or the box contact surface 500. Referring to FIG. 9 , the other layer 350 may be provided below the plating layer 200 (between the box contact surface 500 and the plating layer 200). In this case, for example, a zinc phosphate coating may be provided below the plating layer 200 as a chemical conversion coating. Referring to FIG. 10 , the other layer 350 may be provided above the plating layer 200 and below the second resin coating 320 (between the plating layer 200 and the second resin coating 320). In this case, for example, a zinc phosphate coating or a chromate coating may be provided above the plating layer 200 as a chemical conversion coating. Referring to FIG. 11, an additional layer 350 may be provided above the zirconium oxide coating 100 and below the first resin coating 310 (between the zirconium oxide coating 100 and the first resin coating 310).

[0076] [Chemical composition of the tube body] The chemical composition of the pipe body 10 of the oil well metal pipe 1 according to this embodiment is not particularly limited. That is, in this embodiment, the steel type of the pipe body 10 of the oil well metal pipe 1 is not particularly limited. The pipe body 10 may be formed of, for example, carbon steel, stainless steel, alloy, or the like. That is, the oil well metal pipe 1 may be a steel pipe made of an Fe-based alloy, or an alloy pipe typified by a Ni-based alloy pipe. Here, the steel pipe may be, for example, a low-alloy steel pipe, a martensitic stainless steel pipe, a duplex stainless steel pipe, or the like. On the other hand, among alloy steels, high-alloy steels such as Ni-based alloys and duplex stainless steels containing alloy elements such as Cr, Ni, and Mo have high corrosion resistance. Therefore, when these high-alloy steels are used as the pipe body 10, excellent corrosion resistance can be obtained in corrosive environments containing hydrogen sulfide, carbon dioxide, and the like.

[0077] [Manufacturing method] A method for manufacturing the metal oil well pipe 1 according to this embodiment will be described below.

[0078] The method for manufacturing the metal oil well pipe 1 according to this embodiment includes a preparation step, a zirconium chemical conversion treatment step, a plating step, and a resin coating formation step.

[0079] [Preparation process] In the preparation step, a metal oil well pipe 1 is prepared, which includes a pipe body 10 including a pin 40 having a pin contact surface 400 including a male thread portion 41, and a box 50 having a box contact surface 500 including a female thread portion 51. As described above, the metal oil well pipe 1 according to this embodiment has a well-known configuration. That is, in the preparation step, it is sufficient to prepare a metal oil well pipe 1 having a well-known configuration.

[0080] [Zirconium conversion treatment process] In the zirconium chemical conversion treatment step, the prepared oil well metal pipe 1 is subjected to zirconium chemical conversion treatment to form the zirconium oxide coating 100. The zirconium chemical conversion treatment can be performed by a well-known method. For example, the zirconium chemical conversion treatment may be performed by immersing the pin contact surface 400 or the box contact surface 500 in a treatment solution, or by spraying the treatment solution onto the pin contact surface 400 or the box contact surface 500. A commercially available zirconium chemical conversion treatment solution can be used. The treatment conditions in the zirconium chemical conversion treatment step can be set appropriately. For example, the zirconium chemical conversion treatment can be performed by setting the concentration of the treatment solution to 3 to 10 g / L, the temperature of the treatment solution to 20 to 45°C, and the treatment time to 30 to 240 seconds.

[0081] [Plating process] In the plating step, the pin contact surface 400 and the box contact surface 500 of the prepared metal oil well pipe 1, on which the zirconium oxide coating 100 is not formed, are plated to form the plating layer 200. The plating can be performed by a well-known method, such as electroplating.

[0082] When a Zn-Ni alloy plating layer is formed as the plating layer, the plating bath contains zinc ions and nickel ions. The plating bath has a composition of, for example, 1 to 100 g / L of Zn and 1 to 50 g / L of Ni. The electroplating conditions can be set appropriately. For example, the pH of the plating bath is set to 1 to 10, the temperature of the plating bath is set to 30 to 80°C, and the current density is set to 1 to 100 A / dm 2 The plating treatment can be carried out with the treatment time set to 0.1 to 30 minutes.

[0083] [Resin film formation process] In the resin film formation step, a first resin film 310 and a second resin film 320 are formed on the contact surface (400 or 500) on which the zirconium oxide film 100 is formed and on the contact surface (400 or 500) on which the plating layer 200 is formed. The method for forming the first resin film 310 and the second resin film 320 is not particularly limited. That is, the first resin film 310 and the second resin film 320 can be formed by a well-known method. For example, the resin film may be formed by applying a composition for the first resin film 310 to the contact surface (400 or 500) on which the zirconium oxide film 100 is formed and then drying. Similarly, the resin film may be formed by applying a composition for the second resin film 320 to the contact surface (400 or 500) on which the plating layer 200 is formed and then drying. In this case, the method for applying the composition is not particularly limited. For example, spray coating, brush coating, or dipping may be used. The drying method is not particularly limited. For example, the film may be dried by heating at 60° C. for 20 minutes, or by leaving the film in the air.

[0084] [Other processes] The manufacturing process of the oil well metal pipe 1 according to this embodiment may include other processes. For example, a surface treatment such as sandblasting may be performed. For example, a chemical conversion treatment other than zirconium chemical conversion treatment may be performed. For example, a chromate treatment may be performed. In this way, well-known manufacturing processes may be further performed.

[0085] The metal oil well pipe 1 according to this embodiment is manufactured by the above steps. However, the above-described manufacturing method is only one example of the manufacturing method of the metal oil well pipe 1 according to this embodiment, and the manufacturing method is not limited to this. The metal oil well pipe 1 according to this embodiment may be manufactured by other methods. [Example]

[0086] The effects of the metallic oil well pipe of this embodiment will be described in more detail below with reference to examples. The conditions in the following examples are one example of conditions adopted to confirm the feasibility and effects of the metallic oil well pipe of this embodiment. Therefore, the metallic oil well pipe of this embodiment is not limited to this one example of conditions.

[0087] In Example 1, VAM21 (registered trademark) manufactured by Nippon Steel Corporation was used as the oil well metal pipe. VAM21 (registered trademark) is an oil well metal pipe having an outer diameter of 244.48 mm (9.5 inches) and a wall thickness of 13.84 mm. The steel type was equivalent to P110 specified in the API 5CT standard.

[0088] [Test No. 1] In test number 1, a zirconium conversion treatment was performed on the pin contact surface to form a zirconium oxide coating. The zirconium conversion treatment used a treatment solution manufactured by Nihon Parkerizing Co., Ltd. under the trade name Palseed 1500. The concentration of the treatment solution was 50 g / L, the treatment temperature was 45°C, and the treatment time was 60 seconds.

[0089] A first resin coating was then formed on the pin contact surface of test number 1 on which the zirconium oxide coating had been formed. Specifically, a composition containing an epoxy resin was applied. The application method was spray coating. After application, the first resin coating was dried by heating at 50°C for 5 minutes.

[0090] The contact surface of the box was electroplated to form a Zn-Ni alloy plating layer. The Zn-Ni alloy plating bath used was Dainjin Alloy N-PL, a product of Daiwa Kasei Co., Ltd. The electroplating conditions were a pH of 6.5, a temperature of 25°C, and a current density of 2 A / dm 2 The plating bath contained 85% Zn and 15% Ni, and the treatment time was 18 minutes.

[0091] A second resin coating was further formed on the contact surface of the box of test number 1 on which the Zn-Ni alloy plating layer had been formed. Specifically, a composition containing an epoxy resin was applied. The application method was spray coating. After application, the coating was heated at 230°C for 10 minutes and dried.

[0092] [Test No. 2] In Test No. 2, a zinc phosphate conversion treatment was performed on the pin contact surface to form a zinc phosphate coating. For the zinc phosphate conversion treatment, a treatment solution manufactured by Nihon Parkerizing Co., Ltd., under the product name PB-181X, was used. The total acidity of the treatment solution was 45 pt, the treatment temperature was 80°C, and the treatment time was 400 seconds. The other configurations of Test No. 2 were the same as those of Test No. 1. That is, on the pin contact surface of Test No. 2, a first resin coating containing the same epoxy resin as in Test No. 1 was formed on top of the zinc phosphate coating.

[0093] [Seizure resistance evaluation test] Repeated tightening tests were conducted on test numbers 1 and 2 to evaluate seizure resistance. Using the pins and boxes of test numbers 1 and 2, the screws were repeatedly tightened and loosened at room temperature (20°C). Specifically, the tightening speed was set to 10 rpm and the tightening torque was set to 42.8 kN m, and the torque was measured during tightening. The shoulder torque for each tightening cycle for test numbers 1 and 2 is shown in Table 1.

[0094] [Table 1]

[0095] [Evaluation results] Referring to Table 1, in Test No. 1, a zirconium oxide coating was formed on the pin contact surface. As a result, compared with an oil well pipe having a zinc phosphate coating formed on the pin contact surface, the shouldering torque was suppressed lower with an increase in the number of screw tightenings. In other words, the oil well pipe of Test No. 1 exhibited excellent galling resistance. [Example]

[0096] In Example 2, a chemical conversion coating, a resin coating, a plating layer, and a resin coating were formed on a plate-shaped test piece, and the peel strength of the resin coating was evaluated. Specifically, a cold-rolled steel sheet with a thickness of 0.8 mm and a size of 70 mm × 150 mm was used as the test piece. The steel type of the cold-rolled steel sheet used as the test piece corresponded to SPCC as specified in JIS G 3141 (2017).

[0097] [Test No. 3] The test piece of Test No. 3 was subjected to a zirconium chemical conversion treatment to form a zirconium oxide coating, similar to the pin contact surface of Test No. 1 in Example 1. Furthermore, a first resin coating was formed on the pin contact surface of Test No. 1 in Example 1. The method of the zirconium chemical conversion treatment and the method of forming the first resin coating were the same as those for Test No. 1 in Example 1.

[0098] [Test No. 4] The test piece of Test No. 4 was subjected to a zinc phosphate conversion treatment to form a zinc phosphate coating, similar to the pin contact surface of Test No. 2 in Example 1. Furthermore, a first resin coating was formed on the pin contact surface of Test No. 2 in Example 1. The method of zinc phosphate conversion treatment and the method of forming the first resin coating were the same as those for Test No. 2 in Example 1.

[0099] [Test No. 5] The test piece of Test No. 5 was subjected to electroplating treatment to form a Zn-Ni alloy plating layer, similar to the box contact surface of Test No. 1 in Example 1. Furthermore, a second resin coating was formed on the box contact surface of Test No. 1 in Example 1. The electroplating method and the method for forming the second resin coating were the same as those for Test No. 1 in Example 1.

[0100] [Pencil hardness test] The test pieces numbered 3 to 5 were subjected to a scratch hardness test (pencil method) according to JIS K 5600-5-4 (1999) to evaluate the peel strength of the resin coating for each test number. Specifically, for test pieces numbered 3 to 5, the tip of a pencil was placed on the resin coating, and then immediately pushed away at a speed of 0.5 to 1.0 mm / sec for a distance of 7 mm or more. The presence or absence of scratches was checked with the naked eye. If no scratches were observed, the hardness of the pencil lead was increased by one level and the test was continued. In this way, the hardness of the pencil lead where no scratches were observed after scratching with the pencil, the hardness of the pencil lead where scratches were first observed, and the hardness of the pencil lead where the resin coating peeled off were obtained. The results of the pencil hardness test for each test number are shown in Table 2.

[0101] [Table 2]

[0102] [Evaluation results] Referring to Table 2, it was confirmed that the resin coating formed on the zirconium oxide coating shown in Test No. 3 peeled off more easily than those shown in Test Nos. 4 and 5. On the other hand, it was confirmed that the resin coating formed on the zinc phosphate coating shown in Test No. 4 peeled off just as easily as the resin coating formed on the Zn—Ni alloy plating layer shown in Test No. 5.

[0103] The embodiments of the present disclosure have been described above. However, the above-described embodiments are merely examples for implementing the present disclosure. Therefore, the present disclosure is not limited to the above-described embodiments, and can be implemented by appropriately modifying the above-described embodiments within the scope of the present disclosure. [Explanation of symbols]

[0104] 1 Metal pipe for oil well 10 Tube body 10A 1st end 10B 2nd end 11-pin body 12 Coupling 40-pin 41 Male thread 42 Pin seal surface 43 Pin shoulder surface 50 boxes 51 Female thread 52 Box seal surface 53 Box shoulder surface 100 Zirconium oxide coating 200 plating layers 310 First resin coating 320 Second resin coating 400 pin contact surface 500 box contact surface

Claims

1. A metal pipe for oil wells, a tube body including a first end and a second end; The tube body is a pin formed on the first end; a box formed at the second end; The pin is a pin contact surface including an external thread; The box a box contact surface including an internal thread; The metal oil well pipe further comprises: a zirconium oxide coating formed on one of the pin contact surface and the box contact surface; a first resin coating formed on or above the zirconium oxide coating; a plating layer formed on or above the other of the pin contact surface and the box contact surface; A second resin coating formed on or above the plating layer. Metal pipes for oil wells.

2. The metal pipe for oil well use according to claim 1, the zirconium oxide coating is formed on the pin contact surface; The plating layer is formed on or above the box contact surface. Metal pipes for oil wells.

3. The metal pipe for oil well use according to claim 1 or 2, The plating layer is a Zn—Ni alloy plating layer. Metal pipes for oil wells.

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