Ceramic electronic components and circuit boards

Auxiliary electrodes on multilayer ceramic capacitors counteract solder tension to prevent tombstoning, enhancing mounting stability and reducing defects in smaller capacitors.

JP7752003B2Active Publication Date: 2025-10-09TAIYO YUDEN KK
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Patent Information

Application Number
JP2021131503
Authority / Receiving Office
JP · JP
Patent Type
Patents
Current Assignee / Owner
Filing Date
2021-08-12
Publication Date
2025-10-09
Estimated Expiration
2041-08-12

AI Technical Summary

Technical Problem

Multilayer ceramic capacitors, particularly those designed for thinner devices, are prone to tombstoning during mounting due to surface tension of the solder, leading to mounting defects.

Method used

The ceramic electronic component features auxiliary electrodes on each end face that counteract the surface tension of the solder, preventing the capacitor from standing up during mounting by providing opposing forces on the terminal electrodes.

Benefits of technology

This design effectively suppresses tombstoning, reducing mounting defects and ensuring stable electrical connections, even in smaller and lighter capacitors.

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Patent Text Reader

Abstract

To provide a ceramic electronic component in which mount detects hardly occur.SOLUTION: A ceramic electronic component includes: a ceramic element body; and first and second external electrode units. The ceramic element body includes: first and second main surfaces vertical to a first axis; first and second end surfaces vertical to a second axis orthogonal to the first axis; first and second side surfaces vertical to a third axis orthogonal to the first and second axes; and first and second ridge parts connecting respectively the first and second side surfaces to the first main surface. The first and second external electrode units are provided respectively on the first and second end surface sides of the ceramic element. The first and second external electrode units contain respectively: first and second terminal electrodes that coat the first and second end surfaces, and extend to the first main surface from the first and second end surfaces; and a pair of first and second auxiliary electrodes that is provided separated from the first and second terminal electrodes, as well as, mutually, extending in a third axis direction along the first main surface respectively from the first and second ridge parts.SELECTED DRAWING: Figure 1
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Description

[Technical Field]

[0001] The present invention relates to a ceramic electronic component and a circuit board that include a pair of terminal electrodes. [Background technology]

[0002] A multilayer ceramic capacitor includes a ceramic body including a plurality of stacked internal electrodes and a pair of external electrodes covering the ends of the ceramic body. The multilayer ceramic capacitor is mounted by soldering the pair of external electrodes to a pair of terminals on a mounting substrate. For example, a reflow method is used to mount the multilayer ceramic capacitor.

[0003] When mounting a multilayer ceramic capacitor, if the solder spreads onto one of the pair of external electrodes first, the multilayer ceramic capacitor may stand up due to the surface tension of the solder acting on that external electrode (see, for example, paragraph 0008 and FIG. 3 of Patent Document 1). This phenomenon is called tombstoning.

[0004] In contrast, the multilayer ceramic capacitor described in Patent Document 1 is configured so that the end faces of the external electrodes are less likely to bulge outward, thereby suppressing the occurrence of tombstoning during mounting. Specifically, in this multilayer ceramic capacitor, the end faces of the ceramic body are made concave, which makes it easier for the end faces of the external electrodes to be flat. [Prior art documents] [Patent documents]

[0005] [Patent Document 1] Japanese Patent Application Laid-Open No. 2000-49032 Summary of the Invention [Problem to be solved by the invention]

[0006] In recent years, multilayer ceramic capacitors have become smaller and thinner, along with their height reduction, in response to trends such as thinner smartphones and wearable devices, increased functionality, and larger battery capacities. However, it has been confirmed that lighter multilayer ceramic capacitors tend to be more susceptible to tombstoning during mounting.

[0007] As multilayer ceramic capacitors become lighter, it is expected that it will become increasingly difficult to adequately prevent the occurrence of tombstoning during mounting. Therefore, technology that can more effectively suppress the occurrence of tombstoning during mounting is required for multilayer ceramic capacitors.

[0008] In view of the above circumstances, an object of the present invention is to provide a ceramic electronic component and a circuit board that are less likely to cause mounting defects. [Means for solving the problem]

[0009] To achieve the above object, a ceramic electronic component according to one aspect of the present invention includes a ceramic body, a first external electrode unit, and a second external electrode unit. The ceramic body has first and second main surfaces perpendicular to a first axis, first and second end surfaces perpendicular to a second axis perpendicular to the first axis, first and second side surfaces perpendicular to a third axis perpendicular to the first and second axes, and first and second ridge portions connecting the first and second side surfaces to the first main surface, respectively. The first external electrode unit is provided on the first end face side of the ceramic body and includes a first terminal electrode covering the first end face and extending from the first end face to the first main surface, and a pair of first auxiliary electrodes spaced apart from the first terminal electrode and spaced apart from each other and extending from the first and second edge portions along the first main surface in the third axis direction. The second external electrode unit is provided on the second end face side of the ceramic body and includes a second terminal electrode covering the second end face and extending from the second end face to the first main surface, and a pair of second auxiliary electrodes spaced apart from the second terminal electrode and spaced apart from each other and extending from the first and second ridge portions along the first main surface in the third axis direction. When the first main surface is viewed from the front, approximately central portions of the first and second terminal electrodes in the direction of the third axis bulge toward the center of the ceramic body in the direction of the second axis. The edge of each of the pair of first auxiliary electrodes on the first end face side is closer to the first end face in the direction of the second axis than the apex of the bulge at the approximately central portion of the first terminal electrode. The edge of each of the pair of second auxiliary electrodes on the second end face side is closer to the second end face in the second axis direction than the apex of the bulge at the approximately central portion of the second terminal electrode.

[0010] When mounting this ceramic electronic component, the first external electrode unit is soldered to a first terminal of the mounting board, and the second external electrode unit is soldered to a second terminal of the mounting board. During the mounting process, the surface tension of the molten solder acts on the first external electrode unit on the first terminal, and on the second external electrode unit on the second terminal. In the first external electrode unit, a force acts on the first auxiliary electrode in the opposite direction to the force acting on the first terminal electrode to make the ceramic electronic component stand up on the first terminal, and in the second external electrode unit, a force acts on the second auxiliary electrode in the opposite direction to the force acting on the second terminal electrode to make the ceramic electronic component stand up on the second terminal. As a result, even if the molten solder spreads over one of the first and second external electrode units first during the mounting process, the ceramic electronic component is less likely to become tombstoned, meaning that the ceramic electronic component stands up.As a result, the occurrence of mounting defects can be effectively suppressed with this ceramic electronic component.

[0011] The first terminal electrode, the pair of first auxiliary electrodes, the second terminal electrode, and the pair of second auxiliary electrodes may include a sintered film of a conductor.

[0012] The pair of first auxiliary electrodes may extend in the first axis direction from the first and second edge portions along the first and second side surfaces, respectively. The pair of second auxiliary electrodes may extend in the first axis direction from the first and second edge portions along the first and second side surfaces, respectively.

[0013] The dimension of the pair of first auxiliary electrodes in the second axis direction may be 2% to 10% of the dimension of the first terminal electrode in the second axis direction. The dimension of the pair of second auxiliary electrodes in the second axis direction may be 2% to 10% of the dimension of the second terminal electrode in the second axis direction.

[0014] The distance between the first terminal electrode and the pair of first auxiliary electrodes may be 2% to 10% of the dimension of the first terminal electrode in the second axis direction. The distance between the second terminal electrode and the pair of second auxiliary electrodes may be 2% to 10% of the dimension of the second terminal electrode in the second axis direction.

[0015] A circuit board according to one embodiment of the present invention includes a ceramic electronic component and a mounting substrate. The ceramic electronic component includes a ceramic body, a first external electrode unit, and a second external electrode unit. The ceramic body has first and second main surfaces perpendicular to a first axis, first and second end surfaces perpendicular to a second axis perpendicular to the first axis, first and second side surfaces perpendicular to a third axis perpendicular to the first and second axes, and first and second ridge portions connecting the first and second side surfaces to the first main surface, respectively. The first external electrode unit is provided on the first end face side of the ceramic body and includes a first terminal electrode covering the first end face and extending from the first end face to the first main surface, and a pair of first auxiliary electrodes spaced apart from the first terminal electrode and spaced apart from each other and extending from the first and second edge portions along the first main surface in the third axis direction. The second external electrode unit is provided on the second end face side of the ceramic body and includes a second terminal electrode covering the second end face and extending from the second end face to the first main surface, and a pair of second auxiliary electrodes spaced apart from the second terminal electrode and spaced apart from each other and extending from the first and second ridge portions along the first main surface in the third axis direction. The mounting board has a substrate main body, a first terminal provided on the substrate main body and having the first terminal electrode and the first auxiliary electrode soldered thereto, and a second terminal provided on the substrate main body and having the second terminal electrode and the second auxiliary electrode soldered thereto. When the first main surface is viewed from the front, approximately central portions of the first and second terminal electrodes in the direction of the third axis bulge toward the center of the ceramic body in the direction of the second axis. The edge of each of the pair of first auxiliary electrodes on the first end face side is closer to the first end face in the direction of the second axis than the apex of the bulge at the approximately central portion of the first terminal electrode. The edge of each of the pair of second auxiliary electrodes on the second end face side is closer to the second end face in the second axis direction than the apex of the bulge at the approximately central portion of the second terminal electrode. [Effects of the Invention]

[0016] According to the present invention, it is possible to provide a ceramic electronic component and a circuit board that are less likely to cause mounting defects. [Brief explanation of the drawings]

[0017] [Figure 1] 1 is a perspective view of a multilayer ceramic capacitor according to an embodiment of the present invention; [Figure 2] 2 is a cross-sectional view of the multilayer ceramic capacitor taken along line AA' in FIG. [Figure 3] 2 is a cross-sectional view of the multilayer ceramic capacitor taken along line BB' in FIG. [Figure 4] FIG. 2 is a plan view of the multilayer ceramic capacitor. [Figure 5] 2 is a cross-sectional view of the multilayer ceramic capacitor taken along line CC' in FIG. [Figure 6] FIG. 2 is a side view of a circuit board on which the multilayer ceramic capacitor is mounted. [Figure 7] 10A to 10C are side views showing a mounting process of the comparative example of the multilayer ceramic capacitor. [Figure 8]FIG. 2 is a plan view of the multilayer ceramic capacitor. DETAILED DESCRIPTION OF THE INVENTION

[0018] Hereinafter, an embodiment of the present invention will be described with reference to the drawings. The drawings show mutually orthogonal X-axis, Y-axis, and Z-axis, which are common to all the drawings.

[0019] [Overall Configuration of Multilayer Ceramic Capacitor 10] 1 to 3 are diagrams showing a multilayer ceramic capacitor 10 according to one embodiment of the present invention. Fig. 1 is a perspective view of the multilayer ceramic capacitor 10. Fig. 2 is a cross-sectional view of the multilayer ceramic capacitor 10 taken along line A-A' in Fig. 1. Fig. 3 is a cross-sectional view of the multilayer ceramic capacitor 10 taken along line B-B' in Fig. 1.

[0020] The multilayer ceramic capacitor 10 includes a ceramic body 11, a first terminal electrode 14a, and a second terminal electrode 15a. The ceramic body 11 constitutes the main body of the multilayer ceramic capacitor 10. The terminal electrodes 14a and 15a constitute a pair of terminals for receiving electrical connection in the multilayer ceramic capacitor 10.

[0021] The ceramic body 11 is configured as a hexahedron having outer surfaces including first and second end faces E1, E2 perpendicular to the X axis, first and second side faces S1, S2 perpendicular to the Y axis, and first and second main faces M1, M2 perpendicular to the Z axis. The end faces E1, E2, side faces S1, S2, and main faces M1, M2 of the ceramic body 11 are all configured as flat surfaces.

[0022] The flat surface according to this embodiment does not have to be strictly planar as long as it is recognized as flat when viewed overall, and includes, for example, a surface having minute irregularities or a gently curved shape existing within a predetermined range. The end faces E1, E2, side faces S1, S2, and main faces M1, M2 may each have a portion perpendicular to the X-axis, Y-axis, and Z-axis, respectively.

[0023] The ceramic body 11 has first and second ridges R1 and R2 extending along the X-axis. The first ridge R1 connects the first side surface S1 and the first main surface M1, and the second ridge R2 connects the second side surface S2 and the first main surface M1. The ceramic body 11 is preferably chamfered so that the ridges R1 and R2 form rounded curved surfaces.

[0024] The first main surface M1 of the ceramic body 11 forms the lower surface in the Z-axis direction that faces the mounting substrate during mounting. The second main surface M2 of the ceramic body 11 forms the upper surface in the Z-axis direction, that is, the second main surface M2 is held by suction during mounting. Note that FIG. 1 shows the multilayer ceramic capacitor 10 from the first main surface M1 side of the ceramic body 11.

[0025] The first and second terminal electrodes 14a, 15a cover the first and second end faces E1, E2 of the ceramic body 11 and face each other in the X-axis direction across the ceramic body 11. The terminal electrodes 14a, 15a extend from the end faces E1, E2 of the ceramic body 11 to the main faces M1, M2 and side faces S1, S2, and are spaced apart in the X-axis direction on the main faces M1, M2 and side faces S1, S2.

[0026] The ceramic body 11 is made of dielectric ceramic and has a plurality of first internal electrodes 12 and second internal electrodes 13 covered with dielectric ceramic. The plurality of internal electrodes 12, 13 are each in the form of a sheet extending along the XY plane and arranged alternately along the Z-axis direction.

[0027] That is, the ceramic body 11 has a facing region where the internal electrodes 12 and 13 face each other in the Z-axis direction with the ceramic layer sandwiched between them. The first internal electrode 12 is drawn from the facing region to the first end face E1 and connected to the first terminal electrode 14a. The second internal electrode 13 is drawn from the facing region to the second end face E2 and connected to the second terminal electrode 15a.

[0028] With this configuration, when a voltage is applied between the first terminal electrode 14a and the second terminal electrode 15a in the multilayer ceramic capacitor 10, the voltage is applied to the plurality of ceramic layers in the opposing regions of the internal electrodes 12, 13. As a result, a charge corresponding to the voltage between the first terminal electrode 14a and the second terminal electrode 15a is stored in the multilayer ceramic capacitor 10.

[0029] The ceramic body 11 uses a dielectric ceramic with a high dielectric constant to increase the capacitance of each ceramic layer between the internal electrodes 12 and 13. Examples of dielectric ceramic with a high dielectric constant include materials with a perovskite structure containing barium (Ba) and titanium (Ti), such as barium titanate (BaTiO).

[0030] Dielectric ceramics include strontium titanate (SrTiO3), calcium titanate (CaTiO3), magnesium titanate (MgTiO3), calcium zirconate (CaZrO3), calcium titanate zirconate (Ca(Zr,Ti)O3), barium zirconate (BaZrO3), titanium oxide (TiO2), barium strontium titanate, barium calcium titanate, barium zirconate, barium titanate zirconate, calcium titanate zirconate, and barium calcium titanate zirconate (Ba 1-x-y Ca x Sr y Ti 1-z Zr z O3) or other compositional systems may also be used.

[0031] In the multilayer ceramic capacitor 10, the first terminal electrode 14a is configured as part of a first external electrode unit 14 provided on the first end face E1 side of the outer surface of the ceramic body 11. The second terminal electrode 15a is configured as part of a second external electrode unit 15 provided on the second end face E2 side of the outer surface of the ceramic body 11.

[0032] The first external electrode unit 14 includes a pair of first auxiliary electrodes 14b in addition to the first terminal electrode 14a. The second external electrode unit 15 includes a pair of second auxiliary electrodes 15b in addition to the second terminal electrode 15a. Unlike the terminal electrodes 14a and 15a, the auxiliary electrodes 14b and 15b are electrodes that do not function as terminals of the multilayer ceramic capacitor 10.

[0033] The external electrode units 14, 15 can be configured as sintered films of a conductor. The sintered films of a conductor that constitute the external electrode units 14, 15 can be formed by applying a conductive paste to the outer surface of the ceramic body 11 at positions corresponding to the terminal electrodes 14 a, 15 a and the auxiliary electrodes 14 b, 15 b, and then baking the applied paste.

[0034] The conductor constituting the sintered film is typically composed mainly of Ni (nickel). However, the main component of the conductor constituting the sintered film may be other than Ni, such as Cu (copper), Pd (palladium), and Ag (silver). In this embodiment, the main component refers to the component with the highest content.

[0035] The external electrode units 14, 15 may have a single-layer structure made up of a single layer or a multi-layer structure made up of multiple layers. For example, the external electrode units 14, 15 may have a conductive plating layer formed by a wet plating method on a base layer made of a sintered film of a conductor.

[0036] The plating layer constituting the external electrode units 14, 15 may have a single-layer structure made of a single plating film or a laminate structure made of multiple plating films. As an example, the plating layer may have a laminate structure in which a Cu (copper) film, a Ni (nickel) film, and a Sn (tin) film are laminated in this order on a base layer.

[0037] The multilayer ceramic capacitor 10 can effectively prevent mounting defects caused by the tombstone phenomenon due to the action of the auxiliary electrodes 14b and 15b. In particular, the multilayer ceramic capacitor 10 can more effectively prevent mounting defects even in a small and lightweight configuration in which the tombstone phenomenon is more likely to occur during mounting.

[0038] Specifically, the effect of suppressing mounting defects is more likely to be effectively achieved when the multilayer ceramic capacitor 10 has a size of 2.0±0.15 mm×1.2±0.15 mm×1.2±0.15 mm or less. In other words, the effect of suppressing mounting defects is more likely to be effectively achieved when the dimension in the X-axis direction is 2.0 mm or less and the dimensions in the Y-axis and Z-axis directions are 1.2 mm or less.

[0039] The size of the multilayer ceramic capacitor 10 can be, for example, 1.0±0.10 mm×0.5±0.10 mm×0.5±0.10 mm, 0.6±0.05 mm×0.3±0.05 mm×0.3±0.05 mm, 0.2±0.015 mm×0.1±0.015 mm×0.1±0.015 mm, etc. However, the size of the multilayer ceramic capacitor 10 is not limited to these and various sizes can be used depending on the application, etc.

[0040] [Auxiliary electrodes 14b, 15b] Fig. 4 is a plan view showing the multilayer ceramic capacitor 10 from the first main surface M1 side of the ceramic body 11. Fig. 5 is a cross-sectional view of the multilayer ceramic capacitor 10 taken along line CC' in Fig. 1. That is, Fig. 5 shows a cross section passing through one of the auxiliary electrodes 14b, 15b of the multilayer ceramic capacitor 10.

[0041] In the first external electrode unit 14, a pair of first auxiliary electrodes 14b are provided at positions adjacent to the first terminal electrode 14a on the ridges R1 and R2. Each of the pair of first auxiliary electrodes 14b is spaced apart from the first terminal electrode 14a in the X-axis direction. The pair of first auxiliary electrodes 14b also face each other with a gap in the Y-axis direction.

[0042] Each of the pair of first auxiliary electrodes 14b extends from the ridges R1 and R2 along the first main surface M1 toward the center in the Y-axis direction. Each of the pair of first auxiliary electrodes 14b also extends from the ridges R1 and R2 upward in the Z-axis direction along the side surfaces S1 and S2. As a result, each of the first auxiliary electrodes 14b has an L-shaped cross section parallel to the YZ plane.

[0043] In the second external electrode unit 15, a pair of second auxiliary electrodes 15b are provided at positions adjacent to the second terminal electrode 15a on the ridges R1 and R2. Each of the pair of second auxiliary electrodes 15b is spaced apart from the second terminal electrode 15a in the X-axis direction. The pair of second auxiliary electrodes 15b also face each other with a gap in the Y-axis direction.

[0044] Each of the pair of second auxiliary electrodes 15b extends from the ridges R1 and R2 along the first main surface M1 toward the center in the Y-axis direction. Each of the pair of second auxiliary electrodes 15b also extends from the ridges R1 and R2 upward in the Z-axis direction along the side surfaces S1 and S2. As a result, each of the second auxiliary electrodes 15b has an L-shaped cross section parallel to the YZ plane.

[0045] 6 is a side view showing a circuit board 100 on which a multilayer ceramic capacitor 10 is mounted. The circuit board 100 includes a mounting substrate 20 having a substrate main body 21, a first terminal 22, and a second terminal 23. The terminals 22 and 23 form a pair of terminals of the mounting substrate 20, and are provided on a mounting surface of the substrate main body 21 facing upward in the Z-axis direction.

[0046] In the circuit board 100, the external electrode units 14 and 15 of the multilayer ceramic capacitor 10 are soldered to the terminals 22 and 23 of the mounting board 20, respectively. As a result, in the circuit board 100, the multilayer ceramic capacitor 10 is electrically connected to and physically fixed to the mounting board 20.

[0047] A general reflow method can be used to mount the multilayer ceramic capacitor 10 on the mounting substrate 20. In the reflow method, the external electrode units 14, 15 of the multilayer ceramic capacitor 10 are placed on the terminals 22, 23 of the mounting substrate 20 on which the solder H is arranged, and the solder H is melted and then solidified in the process of passing through a reflow furnace.

[0048] As a result, the molten solder H substantially simultaneously wets and spreads onto the adjacent first terminal electrode 14a and first auxiliary electrode 14b on the first terminal 22 of the mounting substrate 20. Also, the molten solder H substantially simultaneously wets and spreads onto the adjacent second terminal electrode 15a and second auxiliary electrode 15b on the second terminal 23 of the mounting substrate 20.

[0049] In this way, in the multilayer ceramic capacitor 10, the terminal electrodes 14a, 15a and the auxiliary electrodes 14b, 15b can be collectively soldered to the terminals 22, 23. Therefore, in the multilayer ceramic capacitor 10, no additional work is required to solder the auxiliary electrodes 14b, 15b to the terminals 22, 23 of the mounting substrate 20.

[0050] In the multilayer ceramic capacitor 10, the provision of the auxiliary electrodes 14b and 15b can prevent the occurrence of tombstone formation, which occurs on one of the terminals 22 and 23 due to the surface tension of the molten solder H. The function of the auxiliary electrodes 14b and 15b in the multilayer ceramic capacitor 10 will be described below.

[0051] 7 is a side view showing a process of mounting a multilayer ceramic capacitor 10a according to a comparative example of this embodiment. The multilayer ceramic capacitor 10a according to the comparative example is different from the multilayer ceramic capacitor 10 according to this embodiment in that it has terminal electrodes 14a and 15a but does not have auxiliary electrodes 14b and 15b.

[0052] 7, a tombstone phenomenon occurs in which the tombstone rises on the second terminal 23 of the mounting board 20. This tombstone phenomenon occurs because a moment occurs in the direction indicated by the arrow in FIG. 7 due to the action of surface tension of the solder H that has spread to the second terminal electrode 15a before spreading to the first terminal electrode 14a.

[0053] 7, the tombstoning phenomenon causes the first terminal electrode 14a to rise above the first terminal 22 of the mounting substrate 20, resulting in loss of electrical continuity between the first terminal electrode 14a and the first terminal 22 of the mounting substrate 20. Therefore, the multilayer ceramic capacitor 10a shown in FIG. 7 is defective in mounting.

[0054] Furthermore, in the multilayer ceramic capacitor 10a, even when the solder H spreads onto the first terminal electrodes 14a before spreading onto the second terminal electrodes 15a, a tombstone phenomenon occurs in which the solder H rises up on the first terminals 22 of the mounting substrate 20. Thus, the multilayer ceramic capacitor 10a according to the comparative example is prone to mounting defects due to the tombstone phenomenon.

[0055] In contrast, in the multilayer ceramic capacitor 10 according to this embodiment, the surface tension of the solder H acts on the auxiliary electrodes 14b and 15b to prevent them from rising up on the terminals 22 and 23 of the mounting substrate 20. As a result, the multilayer ceramic capacitor 10 can suppress the occurrence of the tombstone phenomenon.

[0056] That is, in the first external electrode unit 14, the surface tension of the solder H acts on the first auxiliary electrode 14b in the opposite direction to the force acting on the first terminal electrode 14a to cause the multilayer ceramic capacitor 10 to stand up on the first terminal 22. This makes it difficult for the multilayer ceramic capacitor 10 to stand up on the first terminal 22.

[0057] Furthermore, in the second external electrode unit 15, the surface tension of the solder H acts on the second auxiliary electrode 15b in a direction opposite to the force acting on the second terminal electrode 15a to cause the multilayer ceramic capacitor 10 to stand up on the second terminal 23. This makes it difficult for the multilayer ceramic capacitor 10 to stand up on the second terminal 23.

[0058] Therefore, in the multilayer ceramic capacitor 10, even if the solder H spreads over one of the external electrode units 14, 15 before the tombstone phenomenon occurs, and the multilayer ceramic capacitor 10 is likely to maintain a normal posture on the mounting board 20 during the mounting process. Therefore, the occurrence of mounting defects can be suppressed in the multilayer ceramic capacitor 10.

[0059] In the multilayer ceramic capacitor 10, by providing the auxiliary electrodes 14b, 15b away from the terminal electrodes 14a, 15a, respectively, the effect of the surface tension of the solder H acting on the auxiliary electrodes 14b, 15b can be stably obtained. This makes it possible to more effectively suppress the occurrence of tombstone phenomenon in the multilayer ceramic capacitor 10.

[0060] 8, in the multilayer ceramic capacitor 10, the portions of the terminal electrodes 14a, 15a that extend onto the first main surface M1 tend to bulge inward in the X-axis direction at the center in the Y-axis direction. This is due to the fluidity of the conductive paste on the ceramic body 11 that is used to form the terminal electrodes 14a, 15a.

[0061] That is, on the outer surface of the ceramic body 11, the fluidity of the conductive paste in the X-axis direction is higher at the center in the Y-axis direction of the first main surface M1 than at the ridges R1, R2. As a result, the terminal electrodes 14a, 15a extend further at the center in the Y-axis direction of the first main surface M1 than at the ridges R1, R2, and are therefore likely to have the bulging shape described above.

[0062] In this regard, in the multilayer ceramic capacitor 10, the auxiliary electrodes 14b, 15b are provided only at four locations near the ridges R1, R2 where the terminal electrodes 14a, 15a extend only a small amount inward in the X-axis direction on the outer surface of the ceramic body 11. Therefore, in the multilayer ceramic capacitor 10, the auxiliary electrodes 14b, 15b can be positioned closer to the end faces E1, E2.

[0063] Therefore, in the multilayer ceramic capacitor 10, the distance between the auxiliary electrodes 14b, 15b in the X-axis direction can be increased by the amount that the auxiliary electrodes 14b, 15b are moved closer to the end faces E1, E2, thereby making it possible to prevent poor moisture resistance due to migration between the auxiliary electrodes 14b, 15b in the multilayer ceramic capacitor 10.

[0064] Furthermore, in the multilayer ceramic capacitor 10, the auxiliary electrodes 14b, 15b can be made smaller by providing them only at four locations near the edges R1, R2, and therefore the area on the outer surface of the ceramic body 11 where the conductive paste is applied when the external electrode units 14, 15 are formed can be reduced.

[0065] Therefore, even in a process in which multiple ceramic bodies 11 are handled simultaneously, such as firing to bake the conductive paste, it is possible to reduce the probability of contact between the conductive pastes of adjacent ceramic bodies 11. This makes it possible to prevent adhesion defects, in which the external electrode units 14, 15 of multiple multilayer ceramic capacitors 10 are stuck to each other.

[0066] In the multilayer ceramic capacitor 10, even if the auxiliary electrodes 14b, 15b are small, the auxiliary electrodes 14b, 15b can be extended from the ridges R1, R2 to the first main surface M1 and the side surfaces S1, S2, thereby making it possible to fully and accurately obtain the above-described effect of the surface tension of the solder H on the auxiliary electrodes 14b, 15b.

[0067] [Dimensions of external electrode units 14 and 15] 4 and 5 show the following dimensions of the external electrode units 14 and 15. "L0" indicates the length of each terminal electrode 14a and 15a in the X-axis direction. "W0" indicates the width of each terminal electrode 14a and 15a in the Y-axis direction. "T0" indicates the thickness of each terminal electrode 14a and 15a in the Z-axis direction on the first main surface M1.

[0068] Furthermore, "L" indicates the length in the X-axis direction of each auxiliary electrode 14b, 15b in each external electrode unit 14, 15. "W" indicates the width in the Y-axis direction of each auxiliary electrode 14b, 15b in each external electrode unit 14, 15. "T" indicates the thickness in the Z-axis direction of each auxiliary electrode 14b, 15b in each external electrode unit 14, 15 on the first main surface M1.

[0069] Furthermore, "D1" indicates the distance in the X-axis direction between the first auxiliary electrode 14b and the second auxiliary electrode 15b. "D2" indicates the distance in the X-axis direction between the terminal electrodes 14a, 15a and the auxiliary electrodes 14b, 15b in each external electrode unit 14, 15. "D3" indicates the distance in the Y-axis direction between the first auxiliary electrodes 14b and between the second auxiliary electrodes 15b.

[0070] It is assumed that the above dimensions of the multilayer ceramic capacitor 10 may not be constant over the entire range. In this case, the lengths L0 and L, widths W0 and W, and thicknesses T0 and T are defined as the maximum values ​​of each dimension. Furthermore, the distances D1, D2, and D3 are defined as the minimum values ​​of each dimension.

[0071] The distance D1 in the X-axis direction between the auxiliary electrodes 14b and 15b is preferably 160% or more of the dimension L0 in the X-axis direction of the terminal electrodes 14a and 15a, which makes it possible to more effectively prevent poor moisture resistance due to migration between the auxiliary electrodes 14b and 15b in the multilayer ceramic capacitor 10.

[0072] The distance D2 in the X-axis direction between the terminal electrode 14a, 15a and the auxiliary electrode 14b, 15b in each external electrode unit 14, 15 is preferably 2% or more of the dimension L0 in the X-axis direction of the terminal electrode 14a, 15a, which allows the auxiliary electrodes 14b, 15b to be more stably affected by the surface tension of the solder H.

[0073] Furthermore, the distance D2 in the X-axis direction between the terminal electrodes 14a, 15a and the auxiliary electrodes 14b, 15b in each external electrode unit 14, 15 is preferably 10% or less of the dimension L0 in the X-axis direction of the terminal electrodes 14a, 15a. This makes it easier to collectively solder the terminal electrodes 14a, 15a and the auxiliary electrodes 14b, 15b to the terminals 22, 23 of the mounting board 20.

[0074] The distance D3 in the Y-axis direction between the auxiliary electrodes 14b, 15b in each external electrode unit 14, 15 is preferably 40% or more of the dimension W0 in the Y-axis direction of the terminal electrodes 14a, 15a, which allows the auxiliary electrodes 14b, 15b to be positioned closer to the end faces E1, E2.

[0075] In each of the external electrode units 14, 15, the length L in the X-axis direction of each auxiliary electrode 14b, 15b is preferably 2% or more of the length L0 in the X-axis direction of the terminal electrode 14a, 15a, which allows the auxiliary electrodes 14b, 15b to be more effectively subjected to the effect of the surface tension of the solder H.

[0076] Furthermore, in each external electrode unit 14, 15, the length L in the X-axis direction of each auxiliary electrode 14b, 15b is preferably 10% or less of the length L0 in the X-axis direction of the terminal electrode 14a, 15a. This makes it easier to ensure a large distance D1 in the X-axis direction between the auxiliary electrodes 14b, 15b, and also enables the auxiliary electrodes 14b, 15b to be made smaller.

[0077] In each external electrode unit 14, 15, the width W in the Y-axis direction of each auxiliary electrode 14b, 15b is preferably 1% or more of the width W0 in the Y-axis direction of the terminal electrode 14a, 15a, which allows the auxiliary electrodes 14b, 15b to be more effectively subjected to the effect of the surface tension of the solder H.

[0078] Furthermore, in each external electrode unit 14, 15, the width W in the Y-axis direction of each auxiliary electrode 14b, 15b is preferably 100 μm or less and 10% or less of the width W0 in the Y-axis direction of the terminal electrode 14a, 15a. This allows the auxiliary electrodes 14b, 15b to be positioned closer to the end faces E1, E2, and also allows the auxiliary electrodes 14b, 15b to be made smaller.

[0079] In each of the external electrode units 14, 15, the thickness T in the Z-axis direction of the auxiliary electrodes 14b, 15b is preferably 10% to 100% of the thickness T0 in the Z-axis direction of the terminal electrodes 14a, 15a. This makes it easier to collectively solder the terminal electrodes 14a, 15a and the auxiliary electrodes 14b, 15b to the terminals 22, 23 of the mounting board 20.

[0080] [Examples and Comparative Examples] As examples of the above embodiment, samples of the multilayer ceramic capacitor 10 were fabricated in which the dimensions of the external electrode units 14, 15 were varied. Furthermore, as comparative examples of the above embodiment, samples were fabricated in which the auxiliary electrodes 14b, 15b were eliminated from the multilayer ceramic capacitor 10 according to the above embodiment.

[0081] In both the example and the comparative example, the dimension in the X-axis direction was 2.0 mm, and the dimensions in the Y-axis and Z-axis directions were 1.2 mm. In both the example and the comparative example, the length L0 of the terminal electrodes 14a, 15a in the X-axis direction was 0.52 mm, and the width W0 of the terminal electrodes 14a, 15a in the Y-axis direction was 1.2 mm.

[0082] In each example and comparative example, the rate of defective adhesion was determined, which is the rate of samples with defective adhesion, in which the external electrode units 14, 15 were stuck together, by simultaneously firing the conductive paste onto a plurality of ceramic bodies 11. In each example and comparative example, the rate of defective adhesion was determined by simultaneously firing 10,000 samples.

[0083] Furthermore, in each example and comparative example, a plurality of normally manufactured samples were mounted on the mounting board 20 by the reflow method, and the mounting defect rate, which is the ratio of samples in which the tombstone phenomenon occurred, was calculated. In each example and comparative example, 800 samples were mounted on the mounting board 20 to calculate the mounting defect rate.

[0084] Furthermore, for each example and comparative example, a moisture resistance defect rate was determined, which is the percentage of circuit boards on which samples were normally mounted that had an electrical resistance of less than 1 MΩ after being held at a temperature of 60°C, a humidity of 95%, and a rated voltage of 10 V. For each example and comparative example, the moisture resistance defect rate was determined using 800 circuit boards.

[0085] Table 1 shows the dimensions of the external electrode units 14, 15, the adhesion defect rate, the mounting defect rate, and the moisture resistance defect rate for Examples 1 to 5 and the comparative example. In the samples according to Examples 1 to 5, the length L in the X-axis direction of the auxiliary electrodes 14b, 15b was varied, that is, the ratio of length L1 to length L0 was different from one another.

[0086] No adhesion failure occurred in any of Examples 1 to 5 and the Comparative Example. Furthermore, no mounting failure occurred in any of Examples 1 to 5, whereas mounting failure occurred in the Comparative Example. Furthermore, no moisture resistance failure occurred in Examples 1 to 3 and the Comparative Example, whereas moisture resistance failure occurred in Examples 4 and 5.

[0087] The results of the mounting defect rate show that the occurrence of tombstone phenomenon was suppressed more in Examples 1 to 5, which were provided with auxiliary electrodes 14b and 15b, than in the comparative example. Also, the results of the moisture resistance defect rate show that Examples 1 to 3, in which the ratio of length L1 to length L0 was 10% or less, had higher moisture resistance than Examples 4 and 5, in which the ratio of length L1 to length L0 was more than 10%.

[0088] [Table 1]

[0089] Table 2 shows the dimensions of the external electrode units 14 and 15, the adhesion defect rate, the mounting defect rate, and the moisture resistance defect rate for Examples 2, 6, and 7. In Examples 2, 6, and 7, the width W in the Y-axis direction of the auxiliary electrodes 14b and 15b in the samples was varied, but no adhesion defect, mounting defect, or moisture resistance defect occurred in any of the samples.

[0090] [Table 2]

[0091] [Other embodiments] Although the embodiments of the present invention have been described above, it goes without saying that the present invention is not limited to the above-described embodiments and that various modifications can be made.

[0092] For example, the multilayer ceramic capacitor 10 is not limited to a configuration in which the auxiliary electrodes 14b, 15b are provided only on the first principal surface M1, but may be provided on both the principal surfaces M1, M2. This eliminates the need to consider the orientation of the multilayer ceramic capacitor 10 in the Z-axis direction when mounting the multilayer ceramic capacitor 10 on the mounting substrate 20.

[0093] In the multilayer ceramic capacitor 10, the terminal electrodes 14a, 15a only need to extend onto the first main surface M1, and if the auxiliary electrodes 14b, 15b are not provided on the second main surface M2, the terminal electrodes 14a, 15a do not need to extend onto the second main surface M2. In addition, the terminal electrodes 14a, 15a do not need to extend onto the side surfaces S1, S2.

[0094] Furthermore, the external electrode units 14, 15 may not necessarily include a sintered film of a conductive material, but may instead include, for example, a sputtered film formed by sputtering a metal material as a base film. In this case, the multilayer ceramic capacitor 10 can also achieve the effect of suppressing the occurrence of tombstones due to the auxiliary electrodes 14b, 15b.

[0095] In addition, the present invention is applicable not only to multilayer ceramic capacitors but also to ceramic electronic components in general that have a pair of terminal electrodes, such as chip varistors, chip thermistors, and multilayer inductors, in addition to multilayer ceramic capacitors. [Explanation of symbols]

[0096] 10...Multilayer ceramic capacitor 11...Ceramic body 12,13…Internal electrode 14, 15...External electrode unit 14a,15a...Terminal electrode 14b,15b…Auxiliary electrode E1,E2…end face S1,S2…side M1,M2…main surface R1,R2…Ridge

Claims

1. a ceramic body having first and second main surfaces perpendicular to a first axis, first and second end surfaces perpendicular to a second axis orthogonal to the first axis, first and second side surfaces perpendicular to a third axis orthogonal to the first and second axes, and first and second ridge portions connecting the first and second side surfaces to the first main surfaces, respectively; a first external electrode unit provided on the first end surface side of the ceramic body; a second external electrode unit provided on the second end surface side of the ceramic body; Equipped with The first external electrode unit includes: a first terminal electrode covering the first end surface and extending from the first end surface to the first main surface; and a pair of first auxiliary electrodes spaced apart from the first terminal electrode and spaced apart from each other, the first auxiliary electrodes extending in the third axis direction from the first and second edge portions along the first main surface. the second external electrode unit includes: a second terminal electrode covering the second end surface and extending from the second end surface to the first main surface; and a pair of second auxiliary electrodes spaced apart from the second terminal electrode and spaced apart from each other, the second auxiliary electrodes extending from the first and second edge portions along the first main surface in the third axis direction, when the first main surface is viewed from the front, approximately central portions of the first and second terminal electrodes in the direction of the third axis bulge toward a center of the ceramic body in the direction of the second axis, an edge of each of the pair of first auxiliary electrodes on the first end surface side is closer to the first end surface in the direction of the second axis than an apex of the bulge at the approximately central portion of the first terminal electrode; an edge of each of the pair of second auxiliary electrodes on the second end surface side is closer to the second end surface in the second axis direction than an apex of the bulge at the approximately central portion of the second terminal electrode; Ceramic electronic components.

2. 2. The ceramic electronic component according to claim 1, The first terminal electrode, the pair of first auxiliary electrodes, the second terminal electrode, and the pair of second auxiliary electrodes each include a sintered film of a conductor. Ceramic electronic components.

3. 3. The ceramic electronic component according to claim 1, the pair of first auxiliary electrodes extend in the first axis direction from the first and second edge portions along the first and second side surfaces, respectively; The pair of second auxiliary electrodes extend in the first axial direction from the first and second edge portions along the first and second side surfaces, respectively. Ceramic electronic components.

4. 4. The ceramic electronic component according to claim 1, a dimension of the pair of first auxiliary electrodes in the second axis direction is 2% to 10% of a dimension of the first terminal electrode in the second axis direction, The dimension of the pair of second auxiliary electrodes in the second axis direction is 2% to 10% of the dimension of the second terminal electrode in the second axis direction. Ceramic electronic components.

5. 4. The ceramic electronic component according to claim 1, a distance between the first terminal electrode and the pair of first auxiliary electrodes is 2% or more and 10% or less of a dimension of the first terminal electrode in the second axis direction, The distance between the second terminal electrode and the pair of second auxiliary electrodes is 2% to 10% of the dimension of the second terminal electrode in the second axis direction. Ceramic electronic components.

6. a ceramic body having first and second main surfaces perpendicular to a first axis, first and second end surfaces perpendicular to a second axis orthogonal to the first axis, first and second side surfaces perpendicular to a third axis orthogonal to the first and second axes, and first and second ridge portions connecting the first and second side surfaces to the first main surfaces, respectively; a first external electrode unit provided on the first end surface side of the ceramic body; a second external electrode unit provided on the second end surface side of the ceramic body; Equipped with The first external electrode unit includes: a first terminal electrode covering the first end surface and extending from the first end surface to the first main surface; and a pair of first auxiliary electrodes spaced apart from the first terminal electrode and spaced apart from each other, the first auxiliary electrodes extending in the third axis direction from the first and second edge portions along the first main surface. The second external electrode unit includes: a second terminal electrode covering the second end surface and extending from the second end surface to the first main surface; and a pair of second auxiliary electrodes spaced apart from the second terminal electrode and spaced apart from each other, the second auxiliary electrodes extending in the third axis direction from the first and second edge portions along the first main surface. Ceramic electronic components, a mounting substrate including: a substrate body; a first terminal provided on the substrate body and having the first terminal electrode and the first auxiliary electrode soldered thereto; and a second terminal provided on the substrate body and having the second terminal electrode and the second auxiliary electrode soldered thereto; Equipped with when the first main surface is viewed from the front, approximately central portions of the first and second terminal electrodes in the direction of the third axis bulge toward a center of the ceramic body in the direction of the second axis, an edge of each of the pair of first auxiliary electrodes on the first end surface side is closer to the first end surface in the direction of the second axis than an apex of the bulge at the approximately central portion of the first terminal electrode; an edge of each of the pair of second auxiliary electrodes on the second end surface side is closer to the second end surface in the second axis direction than an apex of the bulge at the approximately central portion of the second terminal electrode; Circuit board.

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