Heavy metal adsorbent

Abstract

To provide a material that can adsorb lead from water with a pH of 8 or more.SOLUTION: A porous body of a titanium-containing compound with a bulk density of 0.4 g / cm3 or less is used as an adsorbent.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a heavy metal adsorbent. [Background technology]

[0002] The lead concentration in tap water is one of the water quality standards in Japan due to concerns about the health effects of lead. The lead contained in tap water is believed to come from the lead pipes that were used as water pipes until the early 1900s. Zeolite (an aluminosilicate inorganic ion exchanger) that can adsorb heavy metals such as lead contained in water is used as an adsorbent for water purifiers (Patent Document 1). Amorphous titanosilicate is also used as an adsorbent for water purifiers (Patent Document 2). It is known that the form of lead present in water changes depending on the pH of the water (Non-Patent Document 1). When the pH of water is less than 8, lead tends to dissolve in water and exist as lead ions. When the pH of water is 8 or higher, some of the lead ions change into hydroxide colloids (colloidal lead hydroxide), and lead ions and colloidal lead hydroxide coexist. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Japanese Patent Application Publication No. 9-99284 [Patent Document 2] Patent No. 3199733 specification [Non-patent literature]

[0004] [Non-Patent Document 1] NSF / ANSI 53-2018 Drinking water treatment units Summary of the Invention [Problem to be solved by the invention]

[0005] The inventors discovered that zeolite and amorphous titanosilicate can adsorb lead in water with a pH of less than 8, but cannot adequately adsorb lead in water with a pH of 8 or higher. Therefore, the inventors set out to provide a means for adsorbing lead even from water with a pH of 8 or higher. [Means for solving the problem]

[0006] As a result of intensive research into the above-mentioned problems, the present inventors have found that a porous titanium-containing compound having a bulk density within a specific range can adsorb lead in water with a pH of 8 or higher. The present invention is based on this finding.

[0007] That is, the present invention relates to the following [1] to

[11] . [1] A porous body of a titanium-containing compound, The porous body has a g / cm 3 Has a bulk density of A heavy metal adsorbent characterized by: [2] In a porous body, the volume of pores having a pore diameter of 2 to 10 nm is 0.02 cm 3 / g or more. [3] Porous material is 50m 2 The adsorbent according to [1] or [2] above, having a BET specific surface area of ​​1 / g or more. [4] The adsorbent according to any one of the above [1] to [3], wherein the titanium content of the porous body is 5% by mass or more. [5] The adsorbent according to any one of the above [1] to [4], wherein the porous body is a reaction product of an alkaline earth metal silicate and a water-soluble titanium salt. [6] The adsorbent according to any one of [1] to [5] above, which is a lead adsorbent. [7] The adsorbent according to any one of [1] to [6] above, further comprising an additional heavy metal adsorbent substance. [8] The additional heavy metal adsorbent is zeolite or amorphous titanosilicate (however, 0.4 g / cm 3 The adsorbent according to [7] above, which is an amorphous titanosilicate porous body having the following bulk density: [9] The adsorbent according to any one of [1] to [8] above, which is an adsorbent for water having a pH of 8 or more.

[10] The adsorbent according to any one of [1] to [9] above, which is an adsorbent for a water purifier.

[11] A water purifier comprising the adsorbent according to any one of [1] to

[10] . [Effects of the Invention]

[0008] As will be shown in the examples below, the present invention can adsorb lead in water with a pH of 8 or higher. Therefore, the present invention can provide a heavy metal adsorbent with commercial value not found in conventional products, and a water purifier using the same. DETAILED DESCRIPTION OF THE INVENTION

[0009] The heavy metal adsorbent (hereinafter also referred to as "adsorbent") of the present invention contains a porous body of a titanium-containing compound as an essential component.

[0010] [Porous body of titanium-containing compound (hereinafter also referred to as "porous body")] The porous material is used to adsorb heavy metals. The porous body is composed of a titanium-containing compound, and the titanium content relative to the total mass of the titanium-containing compound is, for example, 3 to 60 mass %, preferably 5 to 50 mass %, and more preferably 8 to 30 mass %. The titanium-containing compound may contain elements other than titanium, such as at least one element selected from the group consisting of silicon, aluminum, calcium, magnesium, sodium, and sulfur. The silicon content relative to the total mass of the titanium-containing compound is, for example, 0 to 60 mass %, preferably 5 to 50 mass %, and more preferably 10 to 40 mass %. The content of aluminum relative to the total mass of the titanium-containing compound is, for example, 0 to 60 mass %, preferably 5 to 50 mass %, and more preferably 10 to 40 mass %. The calcium content relative to the total mass of the titanium-containing compound is, for example, 0 to 60 mass %, preferably 3 to 50 mass %, and more preferably 5 to 40 mass %. The content of magnesium relative to the total mass of the titanium-containing compound is, for example, 0 to 60 mass %, preferably 0 to 50 mass %, and more preferably 0 to 40 mass %. The content of sodium relative to the total mass of the titanium-containing compound is, for example, 0 to 30 mass %, preferably 3 to 20 mass %, and more preferably 5 to 15 mass %. The content of sulfur relative to the total mass of the titanium-containing compound is, for example, 0 to 20 mass %, preferably 0 to 15 mass %, and more preferably 0 to 10 mass %.

[0011] The bulk density of the porous material is 0.4 g / cm 3 or less, preferably 0.3 g / cm 3 or less, more preferably 0.25 g / cm 3 The following is the result. The bulk density can be measured according to the method described in JIS K 5101-12-1, Part 12: Apparent density or apparent specific volume - Section 1: Static method.

[0012] The volume of pores having a pore diameter of 2 to 10 nm in the porous body (hereinafter also referred to as "pore volume") is preferably 0.02 cm 3 / g or more, more preferably 0.03 cm 3 / g or more, particularly preferably 0.05 cm 3 / g or more. The pore volume is 0.02 cm 3 / g or more, the heavy metal adsorption capacity can be further improved. The pore volume can be measured according to the method described below. Measurements are performed using a fully automated gas adsorption analyzer (Quantachrome Instruments: AutosorbiQ). Specifically, measurements are performed using the argon adsorption method, and the pore volume for the corresponding pore diameter is calculated using the DFT method from the adsorption data. Additionally, the sample is pretreated by vacuum degassing at 200°C for 6 hours.

[0013] The BET specific surface area of ​​the porous body is preferably 50 m 2 / g or more, more preferably 100m 2 / g or more. BET specific surface area is 50m 2 / g or more, the heavy metal adsorption capacity can be further improved. The BET specific surface area can be measured according to the method described below. Measurements are performed using a fully automated gas adsorption analyzer (Quantachrome Instruments: AutosorbiQ). Specifically, measurements are performed using the argon adsorption method, and the specific surface area is determined by BET multipoint analysis. The sample is also pretreated by vacuum degassing at 200°C for 6 hours.

[0014] The median diameter of the porous body is preferably 10 μm or more, more preferably 10 to 1000 μm, and particularly preferably 10 to 50 μm. When the median diameter is 10 μm or more, when the adsorbent is used in a water purifier, outflow of the adsorbent from the water purifier filter and clogging of the water purifier filter by the adsorbent can be reduced. The median diameter can be measured according to a laser diffraction / scattering particle size distribution measurement method.

[0015] The porous body can be prepared by utilizing the following reaction (A) or (B). (A) Reaction of alkaline earth metal hydroxide, oxide, or silicate with water-soluble titanium salt (B) Reaction of titanium oxide, titanium hydroxide, or metatitanic acid with alkali

[0016] [Reaction (A)] Examples of the hydroxide, oxide or silicate of alkaline earth metals include magnesium silicate, calcium silicate, calcium hydroxide, calcium oxide, magnesium hydroxide, magnesium oxide, and the like. Among the hydroxides, oxides, and silicates of alkaline earth metals, silicates are preferred from the viewpoint of ease of preparation of a porous body having the above-mentioned bulk density, pore volume, and BET value, with magnesium silicate and calcium silicate being more preferred, and calcium silicate being particularly preferred. Examples of water-soluble titanium salts include titanyl sulfate, titanium sulfate, and titanium chloride. An example of a method utilizing reaction (A) is as follows. An aqueous titanyl sulfate solution (e.g., a concentration of 5 to 40% by mass) is added dropwise to an aqueous suspension of calcium silicate (e.g., a concentration of 1 to 50% by mass) at room temperature over a predetermined time (e.g., 1 to 300 minutes), followed by stirring at room temperature for a predetermined time (e.g., 1 to 72 hours). The resulting precipitate is filtered, washed, and dried (e.g., at 50 to 300°C for 1 to 72 hours), and the resulting solid is pulverized to obtain the titanium-containing compound. In the above preparation method, the bulk density, pore volume, BET specific surface area, and titanium content of the porous body can be controlled by changing the type of raw material (hydroxide, oxide, or silicate of alkaline earth metal), the amount and dropping rate of the water-soluble titanium salt, and the drying temperature.

[0017] [Reaction (B)] Examples of the alkali include sodium hydroxide, potassium hydroxide, aqueous ammonia, and sodium silicate, with sodium hydroxide and potassium hydroxide being preferred, and sodium hydroxide being more preferred. An example of a method using reaction (B) is as follows. Titanium oxide (TiO2) is added to a sodium hydroxide solution (for example, at a concentration of 1 to 10 M), and the mixture is then heated with stirring (for example, at 50 to 200°C for 1 to 72 hours). The resulting precipitate is filtered, washed, and dried (for example, at 50 to 300°C for 1 to 72 hours), and the resulting solid is pulverized to obtain a titanium-containing compound. In the above preparation method, the bulk density, pore volume, BET specific surface area, and titanium content of the porous body can be controlled by changing the particle size of the titanium raw material (titanium oxide, etc.), the alkali concentration, the heating temperature, and the reaction time.

[0018] The porous body may be of a single type or a combination of two or more types.

[0019] The content of the porous body is preferably 5 to 70 mass %, more preferably 10 to 60 mass %, and particularly preferably 20 to 50 mass %, based on the total mass of the adsorbent. In embodiments containing optional components (such as additional heavy metal adsorption substances) described below, the mass of the optional components is included in the "total mass of the adsorbent."

[0020] Although the present invention is not limited to a particular theory, the reason why lead can be adsorbed from water having a pH of 8 or higher according to the present invention is believed to be as follows. When the pH of water is less than 8, lead tends to dissolve in water and exist as lead ions, but when the pH of water is 8 or higher, some of the lead ions change into hydroxide colloids (colloidal lead hydroxide), and lead ions and colloidal lead hydroxide coexist (Non-Patent Document 1). Although zeolite and amorphous titanosilicate can adsorb lead from water with a pH of less than 8, they cannot adequately adsorb lead from water with a pH of 8 or higher (see the reference example below). Therefore, it is thought that what is adsorbed by zeolite and amorphous titanosilicate is lead ions. On the other hand, the porous body according to the present invention can sufficiently adsorb lead from water with a pH of 8 or higher (see Examples below). Therefore, it is believed that the porous body according to the present invention removes lead from water with a pH of 8 or higher by adsorbing colloidal lead hydroxide.

[0021] [Optional ingredients] The adsorbent may contain the following optional components within the range that does not impair the effects of the present invention.

[0022] [Additional heavy metal adsorbent] By further blending an "additional heavy metal adsorbent material" other than the aforementioned "porous titanium-containing compound," the heavy metal removal capacity of the adsorbent can be increased. The additional heavy metal adsorbent may be used alone or in combination of two or more kinds. As the additional heavy metal adsorbent, any known substance having heavy metal adsorption ability can be used without particular limitation, but zeolite and amorphous titanosilicate are preferred. Zeolite and amorphous titanosilicate adsorb lead ions in water, so by combining them with a "porous titanium-containing compound" that is thought to adsorb colloidal lead hydroxide in water, the lead removal ability of the adsorbent can be further enhanced. The blending ratio of the above combinations can be adjusted based on the pH of the water. For example, the lead removal capacity of the adsorbent as a whole can be further improved by increasing the blending amount of zeolite or amorphous titanosilicate for water with a pH of less than 8, where the abundance ratio of lead ions is high, and increasing the blending amount of the "porous titanium-containing compound" for water with a pH of 8 or higher, where the abundance ratio of colloidal lead hydroxide is high.

[0023] [Zeolite (aluminosilicate)] In the present invention, any zeolite that adsorbs heavy metals can be used without particular limitation. The zeolite may be either synthetic or natural, but synthetic zeolite is preferred. Examples of synthetic zeolites include A-type zeolite, X-type zeolite, Y-type zeolite, P-type zeolite, T-type zeolite, L-type zeolite, and β-type zeolite, among which A-type, X-type, Y-type, and P-type zeolite are preferred. Examples of natural zeolites include sodalite, mordenite, analcime, clinoptilolite, chabazite, and erionite.

[0024] The median diameter of the zeolite is preferably 10 μm or more, more preferably 10 to 1000 μm, and particularly preferably 20 to 50 μm. When the median diameter is 10 μm or more, when the adsorbent is used in a water purifier, the outflow of the adsorbent from the water purifier filter and the clogging of the water purifier filter by the adsorbent can be reduced. The median diameter can be measured according to a laser diffraction / scattering particle size distribution measurement method.

[0025] The content of zeolite can be appropriately set depending on the pH of the water, but is preferably 30 to 95 mass %, more preferably 40 to 90 mass %, and particularly preferably 50 to 80 mass %, based on the total mass of the adsorbent.

[0026] Zeolite is a known substance and is readily available on the market or can be prepared. Commercially available products include "Zeomic" manufactured by Sinanen Zeomic Co., Ltd. The zeolite may be used alone or in combination of two or more types.

[0027] [Amorphous titanosilicate] In the present invention, amorphous titanosilicate that adsorbs heavy metals can be used without any particular limitation. However, the amount of the amorphous titanosilicate that adsorbs heavy metals is 0.4 g / cm. 3 This does not include porous bodies of amorphous titanosilicate having the following bulk specific gravity: In other words, porous bodies of amorphous titanosilicate do not fall under the category of "porous bodies of titanium-containing compounds" which are essential components of the present invention.

[0028] The median diameter of the amorphous titanosilicate is preferably 10 μm or more, more preferably 10 to 1000 μm, and particularly preferably 20 to 50 μm. When the median diameter is 10 μm or more, when the adsorbent is used in a water purifier, the outflow of the adsorbent from the water purifier filter and the clogging of the water purifier filter by the adsorbent can be reduced. The median diameter can be measured according to a laser diffraction / scattering particle size distribution measurement method.

[0029] The content of the amorphous titanosilicate can be appropriately set depending on the pH of the water, but is preferably 30 to 95 mass %, more preferably 40 to 90 mass %, and particularly preferably 50 to 80 mass %, based on the total mass of the adsorbent.

[0030] Amorphous titanosilicates are known materials and are readily available commercially or can be prepared. Commercially available products include "ATS" manufactured by BASF. The amorphous titanosilicate may be used alone or in combination of two or more kinds.

[0031] [Activated carbon] The adsorbent of the present invention is preferably used in combination with activated carbon. Activated carbon is added to remove harmful organic compounds (such as trihalomethanes and formaldehyde) contained in water, as well as chlorine and mold odors. The activated carbon may be in the form of powder, particles, or fibers. Activated carbon is a known material and is readily available commercially or can be prepared. A single type of activated carbon may be used, or multiple types may be used in combination. The content of activated carbon is not particularly limited as long as it is an amount that can achieve the purpose of blending, but is preferably 100 to 2000 mass %, more preferably 500 to 1500 mass %, based on the total mass of the adsorbent of the present invention.

[0032] [Method of producing adsorbent] The adsorbent can be produced, for example, by putting a predetermined amount of porous titanium-containing compound and an additional heavy metal adsorbent (such as zeolite or amorphous titanosilicate) into a mixer in powder form (for example, powder with a particle size of 100 μm or less) and mixing until uniform (for example, for several minutes to several hours). The mixer is not particularly limited, but for industrial use, a rocking mixer, ribbon mixer, Henschel mixer, or the like can be used. In addition to the above-described production method, the adsorbent can also be produced by adding a porous titanium-containing compound and an additional heavy metal adsorbent (such as zeolite or amorphous titanosilicate) to water, stirring the mixture with a propeller stirrer or the like to prepare a slurry in which both components are uniformly dispersed, and then subjecting the slurry to solid-liquid separation and drying. An activated carbon filter (carbon block, etc.) for a water purifier, which is a combination of an adsorbent and activated carbon, can be produced, for example, by adding a predetermined amount of binder (polyethylene powder, fibrillated fiber, etc.) to activated carbon and a porous body, or activated carbon, a porous body, and an additional heavy metal adsorbent, mixing them, and then subjecting them to a molding process.

[0033] [Heavy metals to be adsorbed] The type of heavy metal to be adsorbed is not particularly limited. Examples of heavy metals include lead and mercury. The present invention is particularly suitable for removing lead.

[0034] [Uses of adsorbents] The adsorbent can be used to remove heavy metals from water (particularly tap water), and is particularly suitable as an adsorbent for a water purifier that removes lead from tap water. The present invention is suitable for removing heavy metals from water with a pH of 8 or higher, where conventional heavy metal adsorbents (zeolite and amorphous titanosilicate) have not been able to sufficiently remove heavy metals. [Example]

[0035] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.

[0036] [Porous body of titanium-containing compound] The following porous titanium-containing compounds A to H were used.

[0037] [Porous body of titanium-containing compound A] 30 g of magnesium silicate was suspended in 200 ml of water to prepare an aqueous suspension with a magnesium silicate concentration of approximately 13.0 mass %. 24 g of titanyl sulfate was dissolved in 200 ml of water to prepare an aqueous solution with a titanyl sulfate concentration of approximately 10.7 mass %. An aqueous solution of titanyl sulfate was added dropwise to an aqueous suspension of magnesium silicate at room temperature over 1 hour, followed by stirring at room temperature for 18 hours. The resulting precipitate was filtered, washed with water, and dried at 100°C for 24 hours. The resulting solid was crushed in a small crusher to obtain a porous titanium-containing compound A.

[0038] [Porous body of titanium-containing compound B] 30 g of calcium silicate was suspended in 300 ml of water to prepare a water suspension with a calcium silicate concentration of approximately 9.1 mass %. 12 g of titanyl sulfate was dissolved in 200 ml of water to prepare an aqueous solution with a titanyl sulfate concentration of about 5.7 mass %. An aqueous solution of titanyl sulfate was added dropwise to a water suspension of calcium silicate at room temperature over 30 minutes, and then the mixture was stirred at room temperature for 18 hours. The resulting precipitate was filtered, washed with water, and dried at 100°C for 24 hours. The resulting solid was crushed in a small crusher to obtain a porous titanium-containing compound B.

[0039] [Porous body of titanium-containing compound C] A porous body of titanium-containing compound C was obtained in the same manner as titanium-containing compound B, except that the amount of titanyl sulfate used was changed to 24 g.

[0040] [Porous body of titanium-containing compound D] A porous body of titanium-containing compound D was obtained in the same manner as titanium-containing compound B, except that the amount of titanyl sulfate used was changed to 36 g.

[0041] [Porous body of titanium-containing compound E] 5 g of titanium oxide was added to 100 ml of sodium hydroxide solution (concentration: 7 M), and then the mixture was heated at 100°C for 24 hours while stirring. The resulting precipitate was then filtered, washed with water, and dried at 100°C for 24 hours. The resulting solid was pulverized in a small pulverizer to obtain a porous titanium compound E.

[0042] [Porous body of titanium-containing compound F] A porous body of titanium-containing compound F was obtained according to the same production method as for titanium-containing compound B, except that calcium silicate was changed to aluminum silicate.

[0043] [Porous body of titanium-containing compound G] A porous body of titanium-containing compound G was obtained in the same manner as titanium-containing compound C, except that calcium silicate was changed to wollastonite (natural calcium silicate).

[0044] [Porous body of titanium-containing compound H] A porous body of titanium-containing compound H was obtained in the same manner as titanium-containing compound A, except that the amount of titanyl sulfate used was changed to 36 g.

[0045] [Porous body of non-titanium-containing compound] A commercially available porous magnesium silicate (manufactured by Tomita Pharmaceuticals, trade name: AD600) was used.

[0046] According to the above-mentioned measurement methods, the "bulk specific gravity," "volume of pores having a pore diameter of 2 to 10 nm," and "BET specific surface area" of each porous body were measured. The results are shown in Table 1. The elemental composition of the compounds constituting each porous body was measured by order analysis using a fluorescent X-ray analyzer (Rigaku Corporation: ZSX Primus II). The measurement samples were prepared by placing each compound in a 35 mm diameter PVC ring, clamping it in a die, and then pelletizing it under a pressure of 10 MPa in a press. The results are shown in Table 2. The values ​​for each element shown in Table 2 are the content (mass%) relative to the total mass of the compound.

[0047] [Additional heavy metal adsorbent]

[0048] [Zeolite] Commercially available X-type zeolite (Sinanen Zeomic Co., Ltd., product name: Zeomic) was used. Zeolite does not contain titanium and has a bulk density of 0.651 g / cm 3 It was.

[0049] [Amorphous titanosilicate] A commercially available amorphous titanosilicate (manufactured by BASF, trade name: ATS) was used. The amorphous titanosilicate had a titanium content of 32.2 mass%, a silicon content of 15.4 mass%, and a sodium content of 6.1 mass%. The bulk density of the amorphous titanosilicate was 0.876 g / cm. 3 The volume of pores with a diameter of 2 to 10 nm is 0.090 cm 3 / g, "BET specific surface area" is 192m 2 / g.

[0050] [Lead adsorption test] [Preparation of test water] A predetermined amount of lead nitrate was dissolved in distilled water to prepare a lead solution with a lead concentration of 300 ppm. 8 ml of lead solution was added to 7,992 ml of simulated tap water (leachate specified in JIS S3200-7: pH 7.0 ± 0.1, hardness 45 ± 5 mg / L, alkalinity 35 ± 5 mg / L, residual chlorine 0.3 ± 0.1 mg / L), and the pH was adjusted to 8.9 with 1 N sodium hydroxide to obtain test water with a lead concentration of 300 ppb.

[0051] [Adsorption test] To 8000 ml of test water, the porous titanium-containing compound and / or additional heavy metal adsorbent was added in the amounts shown in Table 1, and the mixture was stirred (100 rpm) for 24 hours. Solid-liquid separation was then performed using a 0.8 μm membrane filter, and the residual lead concentration (ppb) in the filtrate was measured using a graphite furnace atomic spectrometry (Hitachi High-Tech Science Corporation: ZA3000). The results are shown in Table 1. The membrane filter used for solid-liquid separation (separation of the adsorbent and the test water) does not separate lead from the test water (see the reference example below). In test water with a pH of 8.9, the adsorbent of the present invention (Example 7) showed superior lead adsorption capacity compared to conventional adsorbents (Comparative Examples 1 to 3). Furthermore, the lead adsorption capacity was improved by combining the adsorbent of the present invention with an additional heavy metal adsorbent (Examples 6 and 7).

[0052] [Mercury adsorption test] [Preparation of test water] A predetermined amount of mercury chloride was dissolved in distilled water to prepare a mercury solution with a mercury concentration of 25 ppm. One milliliter of mercury solution was added to 499 milliliters of tap water to obtain test water with a mercury concentration of 50 ppb. The pH of the test water was 6.8. Note that in water with a pH of 4 or higher, most of the mercury exists as colloidal mercury hydroxide (Adsorption Processing for the Removal of Toxic Hg(II) from Liquid Effluents: Metals 2020, 10(3), 412;).

[0053] The titanium-containing porous compound and / or additional heavy metal adsorbent was added to 500 ml of test water in the amounts shown in Table 3, and the mixture was stirred (100 rpm) for 24 hours. After that, solid-liquid separation was performed using a 0.8 μm membrane filter, and the residual mercury concentration (ppb) in the filtrate was measured using reduction vapor atomic absorption spectrometry (Nippon Instruments Co., Ltd.: Mercury RA-3). The results are shown in Table 3. Compared with the conventional adsorbent (Comparative Example 9), the adsorbents of the present invention (Examples 8 to 9) also exhibited excellent adsorption capacity for mercury.

[0054] [Reference example: Lead adsorption capacity of additional heavy metal adsorbents] [Preparation of test water] A predetermined amount of lead nitrate was dissolved in distilled water to prepare a lead solution with a lead concentration of 300 ppm. Eight ml of lead solution was added to 7,992 ml of simulated tap water (leachate specified in JIS S3200-7: pH 7.0 ± 0.1, hardness 45 ± 5 mg / L, alkalinity 35 ± 5 mg / L, residual chlorine 0.3 ± 0.1 mg / L), and the pH was adjusted to 6.7 or 8.9 with 1 N hydrochloric acid or 1 N sodium hydroxide to obtain test water with a lead concentration of 300 ppb.

[0055] [Adsorption test] Additional heavy metal adsorbent was added to 8000 ml of test water in the amounts shown in Table 4, and the mixture was stirred (100 rpm) for 24 hours. Solid-liquid separation was then performed using a 0.8 μm membrane filter, and the residual lead concentration (ppb) in the filtrate was measured using a graphite furnace atomic spectrometry (Hitachi High-Tech Science Corporation: ZA3000). The results are shown in Table 4. Both heavy metal adsorbents adsorbed almost all of the lead from the test solution at pH 6.7, but lead remained in the test solution at pH 8.9. Here, lead tends to exist as lead ions in water with a pH of 6.7, and lead ions and colloidal lead hydroxide coexist in water with a pH of 8.9 (Non-Patent Document 1). Therefore, it is believed that the lead remaining unadsorbed from the pH 8.9 test solution is colloidal lead hydroxide, and that the additional heavy metal adsorbent is a substance that adsorbs lead ions in the water. Furthermore, in a control test in which no additional heavy metal adsorbent was added, the lead concentration in the test water after filtration through a 0.8 μm membrane filter showed almost no change from the level before the test (300 ppb). This suggests that the membrane filter used for solid-liquid separation does not separate lead (lead ions and colloidal lead hydroxide) from the test water. [Industrial Applicability]

[0056] The present invention can be used in technical fields where removal of heavy metals is required, particularly in the field of water purifiers.

[0057] [Table 1]

[0058] [Table 2]

[0059] [Table 3]

[0060] [Table 4]

Claims

1. A porous body of a titanium-containing compound is included, The porous body has a g / cm 3 It has the following bulk density: In the porous body, the volume of pores having a pore diameter of 2 to 10 nm is 0.05 cm 3 / g or more. A heavy metal adsorbent characterized by:

2. Porous body 50m 2 The adsorbent according to claim 1, having a BET specific surface area of ​​1 / g or more.

3. 3. The adsorbent according to claim 1, wherein the titanium content of the porous body is 5% by mass or more.

4. The adsorbent according to any one of claims 1 to 3, which is a lead adsorbent.

5. The adsorbent of any one of claims 1 to 4, further comprising an additional heavy metal adsorbent material.

6. The additional heavy metal adsorbent material is zeolite or amorphous titanosilicate (but 0.4 g / cm 3 6. The adsorbent according to claim 5, which is an amorphous titanosilicate porous body having a bulk density of 1000 MPa or less (excluding porous bodies of amorphous titanosilicate having a bulk density of 1000 MPa or less).

7. The adsorbent according to any one of claims 1 to 6, which is an adsorbent for water having a pH of 8 or more.

8. The adsorbent according to any one of claims 1 to 7, which is an adsorbent for a water purifier.

9. A water purifier comprising the adsorbent according to any one of claims 1 to 8.

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