Cleansing agent
A cleansing agent with polyglyceryl monoalkyl ether, fatty acid or its salt, and polyhydric alcohol addresses stability and usability issues, achieving stable and user-friendly performance.
Patent Information
- Application Number
- JP2021056087
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Filing Date
- 2021-03-29
- Publication Date
- 2025-12-09
- Estimated Expiration
- 2041-03-29
AI Technical Summary
Existing cleansing agents suffer from stability issues, particularly at low temperatures, and do not provide an excellent user experience in terms of foam quality and non-stickiness after washing.
A cleansing agent comprising polyglyceryl monoalkyl ether, a fatty acid or its salt, and a polyhydric alcohol, with specific ratios and components, ensuring stability and excellent usability.
The cleansing agent maintains stability at low temperatures and provides excellent foam quality and non-stickiness after washing.
Smart Images

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Abstract
Description
[Technical Field]
[0001] The present invention relates to a cleansing agent comprising a polyglyceryl monoalkyl ether, a fatty acid or its salt, and a polyhydric alcohol. [Background technology]
[0002] It is preferable that concentrates of cleansing agents such as aerosols and pump foamers have extremely low viscosity and remain in a transparent liquid state. Fatty acids are often blended into foaming cleansers, but fatty acids generally tend to precipitate as white particles at low temperatures, which can make the cleansing agent less stable.
[0003] In addition to the cleaning power that is the primary function of cleansing products, the feel of use, such as the quality of the foam produced during washing and the lack of stickiness after washing, are important points that consumers find appealing.
[0004] Patent Document 1 describes an aerosol detergent composition that has good foam quality, excellent foam persistence, and excellent cleaning properties, by blending a nonionic surfactant, an anionic surfactant, and an amphoteric surfactant in the concentrate and using a propellant that is insoluble in water as the propellant. However, it does not disclose any detergent that has excellent stability.
[0005] Patent Document 2 also describes a skin cleanser that contains a fatty acid salt, a specific polymer, a specific polyglyceryl monoalkyl ether, an acylmethyl taurine salt, and the like, and that has excellent foaming speed and creaminess, and that leaves the skin feeling moisturized and not tight after cleansing, and that does not change the moisture content of the skin. However, it does not disclose anything about a cleanser that is excellent in stability.
[0006] Under these circumstances, there is a demand for cleansing agents that have good stability and an excellent feel when used. [Prior art documents] [Patent documents]
[0007] [Patent Document 1] Japanese Patent Application Laid-Open No. 2000-095671 [Patent Document 2] Japanese Patent Application Laid-Open No. 2009-242274 Summary of the Invention
[0008] The present inventors have surprisingly found that by using a cleanser comprising a polyglyceryl monoalkyl ether, a specific amount of a fatty acid or its salt, and a polyhydric alcohol, a cleanser having good stability, particularly good low-temperature stability, and excellent usability can be obtained. The present invention is based on these findings.
[0009] Therefore, the present invention discloses a cleanser comprising (A) a polyglyceryl monoalkyl ether, (B) a fatty acid or a salt thereof, and (C) a polyhydric alcohol, wherein the (B) fatty acid or a salt thereof accounts for 2 to 15 mass % of the total amount of the cleanser.
[0010] According to the present invention, the following inventions are provided. (1) (A) polyglyceryl monoalkyl ether, (B) a fatty acid or a salt thereof, and (C) Polyhydric alcohol and the (B) fatty acid or its salt is present in an amount of 2 to 15 mass % based on the total amount of the cleanser. (2) The cleansing agent according to (1), wherein the (A) polyglyceryl monoalkyl ether is a compound represented by the following formula (I): [ka] (wherein n represents an integer of 6 to 22, and m represents an integer of 3 or more). (3) The cleansing agent according to (1) or (2), wherein the (A) polyglyceryl monoalkyl ether is polyglyceryl-4 lauryl ether. (4) The cleanser according to any one of (1) to (3), wherein the blending amount of the (A) polyglyceryl monoalkyl ether is 0.01 to 10% by mass relative to the total amount of the cleanser. (5) The cleanser according to any one of (1) to (4), wherein the blending amount of the (C) polyhydric alcohol is 20 to 60 mass % based on the total amount of the cleanser. (6) The cleanser according to any one of (1) to (5), wherein the (C) polyhydric alcohol contains dipropylene glycol and / or isopentyldiol. (7) The cleanser according to (6), wherein the amount of dipropylene glycol and / or isopentyl diol contained in the polyhydric alcohol (C) is 9% by mass or more relative to the total amount of the cleanser. (8) A cleansing agent according to any one of (1) to (7), further comprising (D) highly polymerized polyethylene glycol. (9) The cleansing agent according to (8), wherein the mass average molecular weight of the (D) highly polymerized polyethylene glycol is 15,000 to 25,000. (10) The cleanser according to any one of (1) to (9), which is a transparent liquid cleanser. (11) The cleanser according to any one of (1) to (10), which is a cleanser for pump foamers or an aerosol cleanser.
[0011] The use of the detergent of the present invention is advantageous in that it is possible to obtain a detergent that has good stability, particularly good low-temperature stability, and is excellent in usability.
[0012] The present invention provides (A) polyglyceryl monoalkyl ether, (B) a fatty acid or a salt thereof, and (C) Polyhydric alcohol and the (B) fatty acid or its salt accounts for 2 to 15 mass % of the total amount of the cleanser.
[0013] The cleansing agent of the present invention contains a polyglyceryl alkyl ether. The polyglyceryl alkyl ether contained in the cleansing agent of the present invention is formed by an ether bond between polyglycerin and one alkyl. The alkyl is preferably an alkyl having 6 to 22 carbon atoms, more preferably an alkyl having 8 to 18 carbon atoms, and even more preferably an alkyl having 8 to 16 carbon atoms. The alkyl may be linear, branched, or cyclic. The alkyl may be partially substituted or unsubstituted. When the alkyl is partially substituted, examples of the substituent include a hydroxy group and an amino group.
[0014] In polyglyceryl alkyl ethers, examples of the alkyl ether-bonded to polyglycerin include linear alkyl groups such as hexyl, heptyl, octyl (also called capryl), nonyl, decyl, undecyl, dodecyl (also called lauryl), tridecyl, tetradecyl (also called myristyl), pentadecyl, hexadecyl (also called palmityl), heptadecyl, octadecyl (also called stearyl), nonadecyl, icosyl, heneicosyl, and docosyl; branched alkyl groups such as 2-ethylhexyl, 2-methylheptyl, 2-methylnonyl, 2-octyldecyl, 3,5,5-trimethylhexyl, and isostearyl; and cyclic alkyl groups such as cyclohexyl.
[0015] According to a preferred embodiment of the cleanser of the present invention, the polyglyceryl alkyl ether contained in the cleanser of the present invention is a compound represented by the following formula (I): [ka] (wherein n represents an integer of 6 to 22, and m represents an integer of 3 or more). By incorporating such a polyglyceryl alkyl ether into a cleanser, the stability of the cleanser can be maintained even at low temperatures, and this is advantageous in that it allows the cleanser to be more easily used.
[0016] The degree of polymerization (m) of the glycerin unit of the polyglycerin in (I) above is not particularly limited, but is preferably 3 or more, more preferably 3 to 25, even more preferably 3 to 20, still more preferably 4 to 20, and particularly preferably 4 to 10.
[0017] Examples of polyglyceryl alkyl ethers include polyglyceryl-4 lauryl ether and polyglyceryl-10 lauryl ether, with polyglyceryl-4 lauryl ether being preferred. Polyglyceryl-4 lauryl ether and polyglyceryl-10 lauryl ether are available as commercially available products. Examples of such commercially available products include "Sunether L-4" (manufactured by Taiyo Kagaku Co., Ltd.) for polyglyceryl-4 lauryl ether and "Sunether L-10" for polyglyceryl-10 lauryl ether. Polyglyceryl-4 lauryl ether is a polyglyceryl alkyl ether in which, in the above formula (I), the alkyl is a lauryl group (n=12) and m is 4.
[0018] The amount of polyglyceryl alkyl ether contained in the cleanser of the present invention is not particularly limited, but is preferably 0.01 to 10% by mass relative to the total amount of the cleanser, more preferably 0.5 to 8% by mass relative to the total amount of the cleanser, and even more preferably 1 to 3% by mass relative to the total amount of the cleanser.
[0019] The detergent of the present invention contains a fatty acid or a salt thereof. The fatty acid or a salt thereof contained in the detergent of the present invention is not particularly limited as long as it is a neutralized product of a fatty acid commonly used as a detergent material, or a saponified product of a fatty acid ester or oil. The detergent of the present invention may also contain a fatty acid soap, which is a fatty acid salt obtained by neutralizing a fatty acid with an alkali.
[0020] The fatty acid is preferably a fatty acid having 8 to 22 carbon atoms, and may be linear, branched, saturated, or unsaturated. For example, one or a combination of two or more of lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, palmitoleic acid, oleic acid, isomyristic acid, isopalmitic acid, and isostearic acid may be used.
[0021] Examples of alkalis that can form fatty acid salts include inorganic alkalis such as potassium hydroxide and sodium hydroxide, organic alkalis such as triethanolamine, and basic amino acids such as lysine and arginine. Of these alkalis, potassium hydroxide is preferably used.
[0022] As the salt of a fatty acid that can be used in the cleanser of the present invention, potassium laurate, potassium myristate, potassium palmitate, and potassium stearate are preferably used, and potassium laurate, potassium myristate, and potassium palmitate are more preferably used.
[0023] Salts of fatty acids are produced, for example, by neutralizing fatty acids with an alkali, but generally, the product is not completely neutralized and may also contain unreacted (higher) fatty acids.
[0024] The amount of fatty acid or its salt contained in the cleanser of the present invention is 2 to 15% by mass, preferably 3 to 10% by mass, and more preferably 4 to 7% by mass, based on the total amount of the cleanser.
[0025] The cleansing agent of the present invention contains a polyhydric alcohol. Specific examples of the polyhydric alcohol contained in the cleansing agent of the present invention include dihydric alcohols (e.g., ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, isopentyldiol, hexylene glycol, octylene glycol, etc.); trihydric alcohols (e.g., glycerin, trimethylolpropane, etc.); tetrahydric alcohols (e.g., pentaerythritol such as 1,2,6-hexanetriol, etc.); pentahydric alcohols (e.g., xylitol, etc.); hexahydric alcohols (e.g., sorbitol, mannitol, etc.); and polyhydric alcohol polymers (e.g., diethylene glycol, dipropylene glycol, etc.). ethylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); dihydric alcohol alkyl ethers (e.g., ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono-2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc.);Dihydric alcohol alkyl ethers (e.g., diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc.); dihydric alcohol ether esters (e.g., ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol Cole diadipate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc.; glycerin monoalkyl ethers (e.g., xyl alcohol, selachyl alcohol, batyl alcohol, etc.); sugar alcohols (e.g., sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch hydrolysis sugars, maltose, xylitose, starch hydrolysis sugar reducing alcohols, etc.); glysolids; tetrahydrofurfuryl alcohol; POE-tetrahydrofurfuryl alcohol; POP-butyl ether; POP·POE-butyl ether; tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphate;Examples of suitable cleansing agents include POP·POE-pentaneerythritol ether and polyglycerin. Among these, the cleansing agent of the present invention preferably contains glycerin, 1,3-butylene glycol, sorbitol, dipropylene glycol, and / or isopentyl diol, and more preferably dipropylene glycol and / or isopentyl diol.
[0026] The amount of polyhydric alcohol contained in the cleanser of the present invention is not particularly limited, but is preferably 10 to 70% by mass, more preferably 20 to 60% by mass, based on the total amount of the cleanser.
[0027] The amount of dipropylene glycol and / or isopentyldiol contained in the polyhydric alcohol in the cleanser of the present invention is not particularly limited, but is preferably 9% by mass or more, and more preferably 10 to 50% by mass, of the total amount of the cleanser.
[0028] The cleansing agent of the present invention may further contain a polyoxyalkylene (poly)glyceryl ether. Examples of the polyoxyalkylene (poly)glyceryl ether include polyoxypropylene glyceryl ether and polyoxypropylene diglyceryl ether.
[0029] The polyoxyalkylene (poly)glyceryl ether that may be contained in the cleansing agent of the present invention is not particularly limited, but polyoxypropylene diglyceryl ether (PPG-9 diglyceryl) is preferred.
[0030] The amount of polyoxyalkylene (poly)glyceryl ether that may be contained in the cleanser of the present invention is not particularly limited, but is preferably 0.01 to 10% by mass, and more preferably 1 to 3% by mass, of the total amount of the cleanser.
[0031] According to a preferred embodiment of the cleansing agent of the present invention, the cleanser may further contain highly polymerized polyethylene glycol. The mass average molecular weight of the highly polymerized polyethylene glycol is not particularly limited, but is preferably 15,000 to 25,000.
[0032] The amount of highly polymerized polyethylene glycol that may be contained in the cleanser of the present invention is not particularly limited, but is preferably 0.01 to 10% by mass, and more preferably 1 to 5% by mass, of the total amount of the cleanser.
[0033] The cleanser of the present invention may further contain a surfactant.
[0034] Examples of surfactants that may be contained in the cleansing agent of the present invention include nonionic surfactants, cationic surfactants, anionic surfactants, and amphoteric surfactants.
[0035] Specific examples of nonionic surfactants include lipophilic nonionic surfactants and hydrophilic nonionic surfactants, such as sorbitan fatty acid esters (e.g., sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate, etc.), glycerin polyglycerin fatty acids ( For example, mono-cottonseed oil fatty acid glycerin, monoerucate glycerin, sesquioleate glycerin, monostearate glycerin, α,α'-oleic acid pyroglutamic acid glycerin, monostearate glycerin malate, etc.), propylene glycol fatty acid esters (for example, propylene glycol monostearate, etc.), hydrogenated castor oil derivatives, glycerin alkyl ether, POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate ... E-sorbitan tetraoleate, etc.), POE sorbitol fatty acid esters (for example, POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol monostearate, etc.), POE-glycerin fatty acid esters (for example, POE-monooleates such as POE-glycerin monostearate, POE-glycerin monoisostearate, POE-glycerin triisostearate, etc.), POE-fatty acid esters (for example, POE-distearate, POE-monodioleate, , ethylene glycol distearate, etc.), POE-alkyl ethers (e.g., POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.), Pluronic types (e.g., Pluronic, etc.), POE·POP-alkyl ethers (e.g., POE·POP-cetyl ether, POE·POP-2-decyltetradecyl ether, POE·POP-monobutyl ether, POE·POP-hydrogenated lanolin,POE·POP-glycerin ether, etc.), tetraPOE·tetraPOP-ethylenediamine condensates (e.g., Tetronic, etc.), POE-castor oil hydrogenated castor oil derivatives (e.g., POE-castor oil, POE-hydrogenated castor oil, POE-hydrogenated castor oil monoisostearate, POE-hydrogenated castor oil triisostearate, POE-hydrogenated castor oil monopyroglutamic acid monoisostearate diester, POE-hydrogenated castor oil maleic acid, etc.), POE-beeswax·lanolin derivatives (e.g., POE-sorbitol beeswax, etc.), alkanolamides (e.g., coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.), POE-propylene glycol fatty acid esters, POE-alkylamines, POE-fatty acid amides, sucrose fatty acid esters, alkylethoxydimethylamine oxide-trioleyl phosphate, etc.
[0036] Specific examples of the cationic surfactant include stearyl trimethylammonium chloride, cetyl trimethylammonium chloride, behenyl trimethylammonium chloride, distearyl dimethylammonium chloride, dioleyl dimethylammonium chloride, didecyl dimethylammonium chloride, lauric acid amide butylguanidine acetate, myristate amide butylguanidine acetate, palmitic acid amide butylguanidine acetate, distearyl dimethylammonium sulfate, stearyl ethyl dihydroxyethylammonium ethyl sulfate, N-coconut oil fatty acid L-arginine ethyl DL-pyrrolidone carboxylate, stearic acid dimethylaminoethylamide, stearic acid dimethylaminopropylamide, stearic acid diethylaminoethylamide, stearic acid diethylaminopropylamide, stearic acid dipropylaminoethylamide, stearic acid dipropylaminopropylamide, palmitic acid dimethylaminoethylamide, palmitic acid dimethylaminopropylamide, myristate dimethylaminoethylamide, myristate dimethylaminopropylamide, behenic acid dimethylaminoethylamide, behenic acid dimethylaminopropylamide, and the like.
[0037] Specific examples of the anionic surfactant include N-acylamino acid salts, N-acylmethyl taurine salts, alkyl ether phosphate salts, alkyl sulfate ester salts, and polyoxyethylene alkyl ether sulfate salts, and examples thereof include N-acyl glutamates such as potassium cocoyl glutamate, N-acyl-N-methyl-β-alanine salts, N-acyl sarcosinate salts, sodium N-cocoyl taurate, sodium N-cocoyl-N-methyl taurate, sodium N-lauroyl-N-methyl taurate, and N-coconut oil fatty acid-N-methyl Examples include sodium taurate, N-coconut oil fatty acid-N-methyl taurate triethanolamine, N-palm oil fatty acid-N-ethyl taurate triethanolamine, magnesium N-cocoyl taurate, magnesium N-cocoyl-N-methyl taurate, magnesium N-lauroyl-N-taurate, magnesium N-lauroyl-N-methyl taurate, magnesium N-coconut oil fatty acid-N-methyl taurate, and the like. Among these, sodium lauryl glycol acetate and / or sodium N-cocoyl-N-methyl taurate are preferred.
[0038] Specific examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (e.g., 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc.); betaine-based surfactants (e.g., 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkyl betaine, amido betaine, sulfobetaine, cocamidopropyl betaine, lauryl betaine, etc.); and the like.
[0039] Chelating agents that may be contained in the cleansing agent of the present invention include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate (disodium ethylenediaminetetraacetate (EDTA-2Na)), trisodium edetate, tetrasodium edetate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyltriacetate, and the like, with disodium edetate, trisodium edetate, and pentasodium pentetate being preferred among these.
[0040] A preferred embodiment of the cleanser of the present invention is a transparent liquid cleanser. Here, "transparent" refers to a transparency range of 98 to 100, where the transparency of purified water is 100 and the transparency of no light transmission is 0.
[0041] In a preferred embodiment, the cleanser of the present invention may be a pump-former cleanser or an aerosol cleanser. In the present invention, pump-former refers to a type of pump that extrudes the contents by pushing with a pump, or a type of squeeze-former that extrudes the contents by manually compressing the container. Pump-former cleansers can be used, for example, as facial cleansers, shampoos, body soaps, and hand soaps. Furthermore, in the present invention, an aerosol cleanser refers to a cleanser in which cleansing ingredients are dissolved in a solvent and then filled into a pressure-resistant container with a propellant such as liquefied petroleum gas (LPG), butane, or isopentane. [Example]
[0042] The present invention will be described in detail based on the following examples, but the present invention is not limited to these examples. Unless otherwise specified, the blending amounts are expressed in mass %.
[0043] Cleansers (Examples 1 to 7 and Comparative Examples 1 to 23) having the compositions shown in Tables 1 to 4 below were prepared by standard methods and evaluated for (1) appearance (2 weeks at room temperature, 1 day at 0°C, 1 week at 0°C, 2 weeks at 0°C), (2) foam quality, and (3) non-stickiness after rinsing. Each evaluation was based on the following criteria.
[0044] (1) Appearance (low temperature stability) The samples shown in Tables 1 to 4 below were stored at room temperature for 2 weeks, at 0°C for 1 day, at 0°C for 1 week, and at 0°C for 2 weeks, and then their appearance was observed and their transparency was evaluated. The appearance was evaluated by a panel of five experts according to the following evaluation criteria. <Evaluation criteria> A: It was transparent B: Slight turbidity was observed C: Cloudy
[0045] (2) Foam quality The samples shown in Tables 1 to 4 below were sprayed as foam and used in practice. A panel of five experts evaluated the foam quality (foam persistence and foam elasticity) according to the following criteria. <Evaluation criteria> A:Excellent B: Excellent C: Inferior
[0046] (3) No stickiness after washing The samples shown in Tables 1 to 4 below were evaluated by a panel of five experts for non-stickiness after washing when the cleanser was actually used, according to the following evaluation criteria. <Evaluation criteria> A: No stickiness at all B: Almost no stickiness C: Sticky
[0047] [Table 1]
[0048] [Table 2]
[0049] [Table 3]
[0050] [Table 4]
[0051] The results in Table 1 show that the cleansers of the present invention (Examples 1 to 7) have good low-temperature stability and excellent usability (foam quality and non-sticky feeling after washing). On the other hand, the results in Tables 1 to 4 show that the cleansers not included in the scope of the cleansers of the present invention (Comparative Examples 1 to 23) were all inferior to the cleansers of the present invention in terms of low-temperature stability and / or usability.
Claims
1. (A) polyglyceryl monoalkyl ether, (B) a fatty acid or a salt thereof; (C) a polyhydric alcohol, and (D) Highly polymerized polyethylene glycol A cleanser comprising: and (B) the fatty acid or its salt is present in an amount of 2 to 15% by mass based on the total amount of the cleanser; The (C) polyhydric alcohol contains dipropylene glycol and / or isopentyl diol, the mass average molecular weight of the (D) highly polymerized polyethylene glycol is 15,000 to 25,000; The detergent is a pump foamer detergent or an aerosol detergent.
2. 2. The cleansing agent according to claim 1, wherein the polyglyceryl monoalkyl ether (A) is a compound represented by the following formula (I): 【Chemistry 1】 (wherein n represents an integer of 6 to 22, and m represents an integer of 3 or more).
3. 3. The cleansing agent according to claim 1, wherein the polyglyceryl monoalkyl ether (A) is polyglyceryl-4 lauryl ether.
4. 4. The cleanser according to claim 1, wherein the blending amount of the polyglyceryl monoalkyl ether (A) is 0.01 to 10% by mass based on the total amount of the cleanser.
5. The cleanser according to any one of claims 1 to 4, wherein the blending amount of the (C) polyhydric alcohol is 20 to 60 mass% based on the total amount of the cleanser.
6. The cleanser according to any one of claims 1 to 5, wherein the blending amount of dipropylene glycol and / or isopentyl diol contained in the polyhydric alcohol (C) is 9 mass% or more based on the total amount of the cleanser.
7. 7. The cleanser according to claim 1, wherein the blending amount of the (D) highly polymerized polyethylene glycol is 0.01 to 10% by mass based on the total amount of the cleanser.
8. The cleanser according to any one of claims 1 to 7, which is a transparent liquid cleanser.
Citation Information
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