Active material separation device
The active material separation device addresses the energy inefficiencies and material damage of conventional methods by using a movable base and container design to optimize the separation process, achieving cost-effective and efficient recovery of active materials.
Patent Information
- Application Number
- JP2022059047
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Filing Date
- 2022-03-31
- Publication Date
- 2026-01-09
- Estimated Expiration
- 2042-03-31
AI Technical Summary
Conventional methods for separating active materials from electrodes in batteries are energy-intensive and cause significant damage to the materials, leading to high processing costs and reduced recovery efficiency.
An active material separation device with a movable base member, a nozzle for spraying a liquid onto the battery components, and a container design that divides the interior into multiple spaces to manage liquid flow and collision energy, minimizing damage and optimizing recovery efficiency.
The device reduces processing costs and minimizes active material damage while enhancing recovery efficiency by adjusting collision energy and managing liquid discharge, thereby improving the overall separation process.
Smart Images

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Abstract
Description
[Technical Field]
[0001] The present invention relates to an active material separation device. [Background technology]
[0002] In light of climate-related disasters, there is growing interest in electric vehicles as a way to reduce CO2 emissions, and the demand for batteries installed in electric vehicles is also increasing. In this context, research into the recycling of battery materials is progressing. For example, research is being conducted focusing on the highly efficient recovery of metals used in the active materials of the electrodes and the cost reduction of the recovery process.
[0003] For example, Patent Document 1 discloses a method for treating battery components, which includes a positive electrode active material recovery step in which the battery components are brought into contact with treated water containing water to recover the positive electrode active material, which is an insoluble component. [Prior art documents] [Patent documents]
[0004] [Patent Document 1] International Publication No. 2010 / 106618 Summary of the Invention [Problem to be solved by the invention]
[0005] When separating the active material from the electrode, it is desirable to minimize damage to the active material.
[0006] Furthermore, in the recycling of batteries whose capacity has decreased due to material degradation, the active material is separated from the electrodes and then restored. In conventional recycling methods, the active material is sometimes roasted at temperatures of, for example, 500°C or higher to separate the active material from the electrodes. However, such methods are known to consume a large amount of energy. Therefore, there is a need to improve the energy efficiency of recycling. Improved energy efficiency can reduce recycling costs.
[0007] The present invention has been made in view of the above problems, and an object of the present invention is to provide an active material separation device that can reduce processing costs and separate active materials while suppressing damage. [Means for solving the problem]
[0008] The gist of the present invention is as follows. [1] An active material separation device according to one embodiment of the present invention is an active material separation device that separates an active material from a battery component containing the active material, and includes a container, a base member disposed inside the container and supporting the battery component, and a nozzle disposed above the container and spraying a liquid onto the battery component, wherein the base member is movable at least in a horizontal direction. [2] The active material separation device described in [1] above may include a waste liquid section disposed below the container and having an on-off valve. [3] In the active material separation device according to the above [1] or [2], the base member may be movable in the vertical direction. [4] In the active material separation device described in [2] above, the waste liquid section is arranged below the base member, and the inner surface of the container is provided with a contact section having a shape corresponding to the shape of the lower surface edge of the base member, the base member is movable in the vertical direction, and the lower surface edge of the base member comes into contact with the contact section, thereby dividing the interior of the container into a first space above the contact section and a second space below the contact section. [5] The active material separation device described in the above item [4] may include a second waste liquid section different from the first waste liquid section. [6] The active material separator according to any one of the above [1] to [5] may include an annular inner lid portion inside the container. [7] The active material separation device according to any one of the above [1] to [6] may include a collection filter disposed inside the container. [Effects of the Invention]
[0009] According to the above aspect of the present invention, it is possible to reduce processing costs and separate the active material while suppressing damage.
[0010] Furthermore, according to the active material separation device described in [2] above, scattering of the active material can be suppressed, and the recovery efficiency of the active material can be increased.
[0011] Furthermore, according to the active material separation device described in [3] above, the collision energy of the ejection body with the battery component can be adjusted by adjusting the distance between the battery component and the nozzle, and the nozzle can be made with a simple configuration, thereby reducing the cost of the device.
[0012] Furthermore, according to the active material separation device described in [4] above, since the interior of the container is divided into the first space and the second space, even if the active material is stirred up when the liquid is discharged, the active material is prevented from stirring up into the first space and is prevented from being discharged from the second waste liquid section, thereby suppressing a decrease in the recovery rate of the active material.
[0013] Furthermore, according to the active material separation device described in [5] above, the liquid can be discharged from the second waste liquid section together with the first waste liquid section, and the liquid discharge speed can be increased.
[0014] Furthermore, according to the active material separation device described in [6] above, the inner lid suppresses fluctuations in the liquid level, preventing the separated active material from scattering and adhering to the lid or the inner surface of the container, thereby improving the recovery efficiency of the active material.
[0015] Furthermore, the active material separation device described in [7] above can increase the recovery rate of the active material. [Brief explanation of the drawings]
[0016] [Figure 1] 1 is a diagram showing a schematic configuration of an active material separation device according to one embodiment of the present invention. [Figure 2] FIG. 2 is a view taken along the arrow II in FIG. [Figure 3] 2 is a view taken along the arrow II in FIG. 1, showing a modified example of the active material separation device according to the embodiment. DETAILED DESCRIPTION OF THE INVENTION
[0017] An active material separation device according to one embodiment of the present invention will be described with reference to Figures 1 and 2. Figure 1 is a diagram showing a schematic configuration of the active material separation device according to this embodiment. Figure 2 is a view taken along the arrow II in Figure 1. In this specification and drawings, components having substantially the same functional configuration are designated by the same reference numerals, and redundant description will be omitted.
[0018] The active material separation device 1 according to this embodiment is a device that separates active material from a battery component 70. The active material separation device 1 includes a container 10, a nozzle 20 disposed above the container 10, a base member (table) 30 disposed inside the container 10, a collection filter 40 disposed inside the container 10, a displacement meter 50, and an inner lid portion 60.
[0019] The container 10 has a body 110 whose internal space has approximately the same diameter in the vertical direction, a first reduced-diameter section 120 connected to the body 110 and tapering downward as shown in FIG. 1 , a collection section 130 connected to the first reduced-diameter section 120, a second reduced-diameter section 140 connected to the collection section 130 and tapering downward, and a lid 150 disposed above the body 110 and covering the interior of the container 10. The horizontal cross-sectional areas of the first reduced-diameter section 120 and the second reduced-diameter section 140 decrease downward. The first reduced-diameter section 120 has, on its inner surface, a contact section 121 whose shape corresponds to the shape of the lower edge 34 of the table 30. The collection section 130 is provided with a collection filter 40 whose shape corresponds to that of the collection section 130.
[0020] As shown in FIG. 1, the container 10 also includes an exhaust port 160, a first waste liquid section 170, and a second waste liquid section 180.
[0021] The exhaust port 160 exhausts gas generated when the battery component 70 comes into contact with the jet 21 sprayed from the nozzle 20 or the liquid 22 constituting the jet 21 to the outside of the container 10. The exhaust port 160 is provided in the body 110, and the gas can be easily discharged to the outside of the container 10.
[0022] The first waste liquid section 170 is a tubular member connected to the lower end of the second reduced diameter section 140 of the container 10. The liquid 22 in the container 10 flows downward together with the active material separated from the battery components 70. The active material is collected by the collection filter 40, and the liquid 22 passes through the collection filter 40 and is discharged to the outside of the container 10 via the first waste liquid section 170.
[0023] The first waste liquid section 170 is provided with a first on-off valve 171. When the ejection body 21 is ejected with the first on-off valve 171 closed, the liquid 22 is stored inside the container 10. By ejecting the ejection body 21 from the nozzle 20 toward the battery component 70 in a state in which the liquid level S of the stored liquid 22 is higher than the surface of the battery component 70, the collision energy that the battery component 70 receives from the ejection body 21 is reduced, and damage to the active material is further suppressed.
[0024] The second waste liquid section 180 is a tubular member connected to the interior of the container 10 from the side of the body 110 of the container 10. The liquid 22 stored inside the container 10 is discharged to the outside of the container 10 through the second waste liquid section 180. Therefore, by discharging the liquid 22 from the second waste liquid section 180 together with the first waste liquid section 170, the discharge rate of the liquid 22 can be increased. Furthermore, the second waste liquid section 180 is connected to the inner surface 111 of the body 110 and is provided at a higher position than the first reduced diameter section 120. Therefore, the liquid 22 discharged from the second waste liquid section 180 contains only a small amount of active material. Therefore, the discharge of the liquid 22 from the container 10 proceeds without a decrease in the recovery rate of the active material. Furthermore, the second waste liquid section 180 is provided with a second on-off valve 181. When the second on-off valve 181 is closed, a larger volume of the liquid 22 can be stored inside the container 10.
[0025] The lid 150 of the container 10 is provided with a nozzle 20 for spraying a spray body 21. The nozzle 20 sprays the spray body 21 toward the cell components 70.
[0026] The injection body 21 is a liquid that reacts with the solid electrolyte material contained in the battery component 70. Examples of the injection body 21 include protic polar solvents, and more specifically, examples of the injection body 21 include water, ethanol, methanol, acetone, etc. A mixture of these may also be used as the injection body 21.
[0027] The liquid 22 is the liquid that constitutes the ejection body 21, or the liquid that is stored inside the container 10, the first waste liquid section 170, and the second waste liquid section 180 after the ejection body 21 collides with the battery component 70. The liquid 22 after colliding with the battery component 70 contains the components of the ejection body 21 as well as the dissolved components of the battery component 70.
[0028] When the battery component 70 is exposed above the liquid level S of the liquid 22, the ejection body 21 directly collides with the battery component 70. On the other hand, when the upper surface of the battery component 70 is located below the liquid level S, in other words, when the battery component 70 is immersed in the liquid 22, the ejection body 21 collides with the battery component 70 while its collision energy is reduced by the liquid 22. This makes it possible to suppress scattering of the active material. As a result, it is possible to increase the recovery efficiency of the active material.
[0029] The table 30 supports the battery components 70. The table 30 moves at least in the horizontal direction. For example, as shown in FIGS. 1 and 2, the table 30 has a plurality of first shafts 31 extending in one direction on a horizontal plane, and a plurality of second shafts 32 perpendicular to the plurality of first shafts 31 on the horizontal plane. As the first shafts 31 and the second shafts 32 move in their respective axial directions, the table 30 moves in those axial directions. Therefore, the table 30 is movable in the horizontal direction.
[0030] As shown in FIG. 1, the table 30 also has a plurality of third shafts 33 extending in the vertical direction. The third shafts 33 allow the table 30 to move in the vertical direction. By moving the battery member 70 in the vertical direction using the third shafts 33, the distance between the battery member 70 and the nozzle 20 can be adjusted, and the collision energy of the ejection body 21 with the battery member 70 can be adjusted. As a result, the nozzle 20 can be configured simply. This allows for reduced device costs.
[0031] Furthermore, each of the third shafts 33 can operate independently, and when only one of the third shafts 33 is raised or lowered, the side of the table 30 corresponding to that third shaft 33 rises or falls. As a result, the table 30 tilts relative to the horizontal. If the table 30 is not tilted, active material is likely to remain on the surface of the table 30 even after the active material separation process is completed. If active material remains on the surface of the table 30, it becomes difficult to stably place the battery component 70, which is the next target for processing, on the table 30. Therefore, a process of rinsing the active material with water or the like is performed to remove the active material remaining on the table 30. However, tilting the table 30 makes it easier to remove the active material remaining on the table 30.
[0032] 1, the lower surface edge 34 of the table 30 has a shape corresponding to the shape of the contact portion 121 of the first reduced diameter portion 120. When the table 30 is moved vertically by the third shaft 33 and the lower surface edge 34 of the table 30 comes into contact with the contact portion 121 of the first reduced diameter portion 120, the interior of the container 10 is divided into a first space above the contact portion 121 and a second space below the contact portion.
[0033] When the liquid 22 stored inside the container 10 is discharged from the first waste liquid section 170 and the second waste liquid section 180, the active material that has settled on the collection filter 40 and the first reduced diameter section 120 may rise up in the liquid 22. In this case, the raised active material may be discharged to the outside from the second waste liquid section 180 along with the liquid 22. However, when the liquid 22 is stored inside the container 10 and the active material is settled near the collection filter 40 in the first reduced diameter section 120 and on the collection filter 40, the lower surface edge 34 of the table 30 is brought into contact with the contact portion 121 of the first reduced diameter section 120 to divide the interior of the container 10 into a first space and a second space. Even if the active material rises up when the liquid 22 is discharged, the active material is prevented from rising up to the first space and from being discharged from the second waste liquid section 180. As a result, a decrease in the recovery rate of the active material can be suppressed.
[0034] The displacement meter 50 is a device that measures the height of the liquid surface S of the liquid 22 in the container 10, and is provided on the lid 150. The displacement meter 50 is, for example, a laser displacement meter that measures the height of the liquid surface S by irradiating a laser downward.
[0035] The inner lid portion 60 is an annular member made of a material with a lower density than the liquid 22, and can float on the liquid surface S. The outer shape of the inner lid portion 60 corresponds to the inner surface 111 of the body portion 110 in a plan view, and the outer diameter of the inner lid portion 60 approximately matches the inner diameter of the body portion 110 in the horizontal plane of the container 10. When the active material separation process is performed with the inner lid portion 60 floating on the liquid surface S, the inner lid portion 60 suppresses fluctuations in the liquid surface S, thereby preventing the separated active material from scattering together with the liquid 22 and adhering to the lid 150 or the inner surface 111 of the container 10. This makes it easier to recover the active material adhering to the lid 150 or the inner surface 111, thereby improving the recovery efficiency of the active material. Furthermore, if the battery component 70 contains, for example, a sulfide-based solid electrolyte and water is used for the ejection body 21, hydrogen sulfide will be generated by reaction with the ejection body 21 during the separation process, but since the inner lid portion 60 is located at the liquid surface S, the generated hydrogen sulfide will be more likely to dissolve in the liquid 22. As a result, hydrogen sulfide dissolved in the liquid 22 is easier to handle than hydrogen sulfide in a gaseous state, and therefore the hydrogen sulfide can be easily recovered.
[0036] Furthermore, the inner diameter of the inner lid portion 60 is longer than the maximum horizontal length of the battery component 70. Because the inner diameter of the inner lid portion 60 is longer than the maximum horizontal length of the battery component 70, the battery component 70 can be easily attached to and detached from the table 30.
[0037] The battery component 70 is the target of processing by the active material separation device according to this embodiment. The battery component 70 contains, for example, a positive electrode active material containing Li and a solid electrolyte material. The battery component 70 may also contain at least one of a conductive material and a negative electrode active material.
[0038] The positive electrode active material is not particularly limited, but may contain, for example, Li. The positive electrode active material is usually insoluble in the injection body 21 and the liquid 22. Examples of the positive electrode active material include layered positive electrode active materials, spinel type positive electrode active materials, and olivine type positive electrode active materials. Examples of the layered positive electrode active material include LiCoO2, LiNiO2, and LiCo 1 / 3 Ni 1 / 3 Mn 1 / 3 Examples of spinel-type positive electrode active materials include LiMn2O4, LiCoMnO4, Li2NiMn3O8, LiNi 0.5 Mn 1.5 Examples of olivine-type positive electrode active materials include LiCoPO4, LiMnPO4, and LiFePO4.
[0039] The solid electrolyte material contains a component that dissolves in the ejection body 21 and the liquid 22. The solid electrolyte material contains, for example, Li and S. It is preferable that the solid electrolyte material does not contain a component that is insoluble in the ejection body 21 and the liquid 22. If the solid electrolyte material contains only components that dissolve in the ejection body 21 and the liquid 22, separation processing of the insoluble component and the positive electrode active material is unnecessary, and recovery of the positive electrode active material becomes easy. Examples of solid electrolyte materials containing Li and S include those containing Li, S, and a third component. Examples of the third component include at least one selected from the group consisting of P, Ge, B, Si, I, Al, Ga, and As. The sulfide solid electrolyte material may be a compound containing LiS and a sulfide other than LiS.
[0040] Examples of negative electrode active materials include metal active materials and carbon active materials. Examples of metal active materials include In, Al, Si, and Sn. Examples of carbon active materials include mesocarbon microbeads, highly oriented graphite, hard carbon, and soft carbon.
[0041] Examples of the conductive material include acetylene black and carbon fiber.
[0042] The battery member 70 may also have a current collector foil 71. The current collector foil 71 is, for example, an aluminum foil provided on the positive electrode of the battery member 70, or a copper foil provided on the negative electrode of the battery member 70.
[0043] So far, the active material separation device 1 according to this embodiment has been described. Next, an example of a method for separating an active material from a battery component 70 using the active material separation device 1 according to this embodiment will be described.
[0044] First, with the first on-off valve 171 and the second on-off valve 181 closed, the battery component 70 is placed on the upper surface of the table 30. At this time, the table 30 is spaced apart from the first reduced diameter portion 120 of the container 10. In detail, the contact portion 121 of the first reduced diameter portion 120 and the lower surface edge portion 34 of the table 30 are spaced apart.
[0045] Next, the ejection body 21 is sprayed from the nozzle 20 toward the battery component 70. The solid electrolyte material of the battery component 70 dissolves in the ejection body 21, and the collision of the ejection body 21 with the battery component 70 separates the active material from the battery component 70. The table 30 is moved horizontally by the first shaft 31 and the second shaft 32, and the collision position of the ejection body 21 on the battery component 70 is changed. While the ejection body 21 is being sprayed, the liquid 22 accumulates inside the container 10, and the position of the liquid level S rises. Meanwhile, the active material separated from the battery component 70 settles on the collection filter 40. During this time, the position of the liquid level S is measured by the displacement meter 50.
[0046] After the separation of the active material from the battery components 70 on the table 30 is completed, the ejection of the ejection body 21 from the nozzle 20 is stopped and the table is left to stand, which allows the precipitation of the active material to proceed.
[0047] After the container 10 is left standing, the table 30 is lowered to bring the contact portion 121 of the first reduced diameter portion 120 into contact with the lower edge portion 34 of the table 30. This divides the interior of the container 10 into a first space below the contact portion 121 and a second space above the contact portion 121.
[0048] Thereafter, the first on-off valve 171 and the second on-off valve 181 are opened, and the liquid 22 stored in the container 10 is discharged to the outside of the container 10. At this time, the first waste liquid section 170 discharges the liquid 22 stored in the first space, and the second waste liquid section 180 discharges the liquid 22 stored in the second space. As a result, the active material is collected by the collection filter 40.
[0049] If necessary, the table 30 is moved upward to release the contact between the contact portion 121 and the lower edge portion 34 of the table 30, and then only one of the third shafts 33, 33, is operated to tilt the table 30. After the table 30 has tilted, the ejection body 21 is sprayed from the nozzle 20 toward the table 30. This removes the active material remaining on the table 30 from the table 30, and the removed active material is collected in the collection filter 40.
[0050] After the process of separating the active material from one battery component 70 is completed, the table 30 is moved to its initial position, a new battery component 70 to be processed is placed on the table 30, and the above operation is repeated. So far, an example of the method for separating the active material from the battery component 70 using the active material separation device 1 according to this embodiment has been described.
[0051] As described above, the active material separation apparatus 1 includes a container 10, a base member (table) 30 disposed inside the container 10 and supporting the battery components 70, and a nozzle 20 disposed above the container 10 and spraying a spray body 21 toward the battery components 70. The base member 30 is movable at least horizontally. The spray body 21 dissolves the solid electrolyte material of the battery components 70, and the active material is separated from the battery components 70 by the collision of the spray body 21 with the battery components 70. While mechanical processing such as grinding can significantly damage the active material when separating the active material, this embodiment can minimize damage to the active material. Furthermore, this embodiment does not require high-temperature roasting, resulting in high energy efficiency in the separation process. Furthermore, because the table 30 is movable horizontally, a fixed nozzle 20 can be used, reducing equipment costs. Therefore, this embodiment enables active material separation while reducing processing costs and minimizing damage.
[0052] Furthermore, since the first waste liquid section 170 has the first on-off valve 171, the liquid 22 is stored in the container 10, and the battery components 70 can be immersed in the liquid 22. Since the active material is separated while the battery components 70 are immersed in the liquid 22, scattering of the active material can be suppressed. As a result, the recovery efficiency of the active material can be improved.
[0053] Furthermore, because the table 30 is movable in the vertical direction, the collision energy of the ejection body 21 with the battery member 70 can be adjusted by adjusting the distance between the battery member 70 and the nozzle 20. Therefore, it is not necessary to adjust the flow rate of the ejection body using the nozzle 20. As a result, the nozzle 20 can be configured simply, and the cost of the device can be reduced.
[0054] Furthermore, table 30 is movable in the vertical direction, first waste liquid section 170 is disposed below table 30, and container 10 has an inner surface provided with contact section 121 having a shape corresponding to the shape of bottom edge 34 of table 30. Contact between bottom edge 34 of table 30 and contact section 121 divides the interior of container 10 into a first space above contact section 121 and a second space below the contact section. By dividing the interior of container 10 into the first and second spaces, even if the active material rises in liquid 22 during discharge, the active material is prevented from rising up into the first space, and discharge of the active material from second waste liquid section 180 can be prevented. As a result, a decrease in the recovery rate of the active material can be suppressed.
[0055] Furthermore, since the container 10 has a second waste liquid section 180 that is different from the first waste liquid section 170, the liquid 22 in the container 10 can be discharged from the second waste liquid section 180 together with the first waste liquid section 170, thereby increasing the discharge speed of the liquid 22.
[0056] Furthermore, the annular inner lid portion 60 disposed inside the container 10 suppresses fluctuations in the liquid level S, thereby preventing the separated active material from scattering and adhering to the lid 150 or the inner surface 111 of the container 10. This improves the recovery efficiency of the active material.
[0057] Furthermore, since the collection filter 40 is disposed inside the container 10 and the distance from the position where the battery components 70 are disposed to the collection filter 40 is short, the recovery loss of the active material is reduced, and the recovery rate of the active material can be improved.
[0058] Although one embodiment of the present invention has been described above, the present invention is not limited to this. The above is merely an example, and anything that has substantially the same configuration as the technical idea described in the claims of the present invention and exhibits similar effects is included within the technical scope of the present invention.
[0059] For example, in the above-described embodiment, the shape of the inner surface 111 in the horizontal cross section of the body 110 is circular, but the shape of the inner surface 111 in the horizontal cross section does not have to be circular. For example, as shown in FIG. 3, the shape of the inner surface 111A in the horizontal cross section of the body 110A may be square. In this case, the shape of the horizontal cross section of the first reduced diameter portion is also square. Furthermore, the shape of the horizontal cross section of the table 30A is also rectangular. Then, the lower end of the table 30A comes into contact with the contact portion of the first reduced diameter portion, dividing the interior of the container 10A into a first space and a second space.
[0060] Furthermore, for example, although the exhaust port 160 is provided in the body portion 110 in the above-described embodiment, it may be provided in the lid 150.
[0061] Furthermore, for example, a collection filter (not shown) may be provided in the second waste liquid section 180. Even if the active material flows out into the second waste liquid section 180, the collection filter provided in the second waste liquid section 180 collects the active material, thereby preventing a decrease in the recovery rate of the active material.
[0062] Furthermore, the number of second waste liquid sections is not limited to one, and a plurality of second waste liquid sections may be provided.
[0063] Furthermore, the number of nozzles is not limited to one, and multiple nozzles may be provided. Multiple nozzles allow multiple injection bodies to be injected, thereby increasing the active material separation speed. When multiple nozzles are provided, their arrangement may be determined according to the size and shape of the battery components.
[0064] The battery component may be supported on the upper surface of a support member (not shown) that is smaller than the table, and the support member may be provided on the table. The support member makes it easy to place the battery component on the table.
[0065] Furthermore, the number of displacement meters is not limited to one, and multiple displacement meters may be provided. When multiple displacement meters are provided, they are preferably provided at equal intervals along the inner surface of the container. By providing multiple displacement meters along the inner surface of the container, the influence of fluctuations in the liquid level caused by the ejection body ejected from the nozzle can be reduced. Furthermore, by providing multiple displacement meters at equal intervals, the position of the liquid level can be measured with higher accuracy.
[0066] Furthermore, in the above-described embodiment, the outer shape of the inner lid portion 60 corresponds to the shape of the inner surface 111, and the outer shape of the inner lid portion 60 is approximately the same as the diameter in the horizontal plane of the body portion 110. However, the outer shape of the inner lid portion does not have to correspond to the shape of the inner surface. For example, as shown in Fig. 3, the shape of the inner surface 111A of the body portion 110A is rectangular in plan view, but the outer shape of the inner lid portion 60A is circular. In this way, the outer shape of the inner lid portion may differ from the shape of the inner surface of the body portion.
[0067] Furthermore, when an inner lid portion 60 is provided, the displacement meter 50 is preferably provided above the inner lid portion 60. By providing the displacement meter 50 above the inner lid portion 60 and irradiating the upper surface of the inner lid portion 60 with a laser, the position of the liquid level S can be measured more stably.
[0068] The battery components are not limited to those containing the above-mentioned materials, and the present invention can be applied to battery components containing various components that dissolve in the jet.
[0069] Furthermore, at least the first on-off valve 171, the second waste liquid section 180, the third shaft 33, the collection filter 40, and the inner lid section 60 are optional components and may not necessarily be included in the active material separation device according to the present invention. If the collection filter 40 is not provided, a collection filter may be provided outside the container 10, and the active material may be recovered by the collection filter.
[0070] The above-described configurations may be omitted or combined as appropriate within the scope of the effects of the present invention. Furthermore, the above-described method for separating the active material from the battery component 70 is merely an example, and the order of the steps may be rearranged or omitted as appropriate within the scope of feasibility. [Explanation of symbols]
[0071] 1 Separation device 10, 10A container 110, 110A body 111, 111A inner surface 120 First reduced diameter section 121 Contact part 130 Collection unit 140 Second reduced diameter section 150 Lid 160 exhaust port 170 First Wastewater Section 171 First shut-off valve 180 Second waste liquid section 181 Second shut-off valve 20 nozzles 21 Projectile 22 liquid Table 30, 30A 31 First Shaft 32 Second Shaft 33 Third Shaft 34 Bottom edge 40 Collection filter 50 Displacement meter 60, 60A inner lid 70 Battery components 71 Current collecting foil
Claims
1. An active material separation device for separating an active material from a battery component containing the active material, A container and a base member disposed inside the container and supporting the battery member; a nozzle disposed above the container and configured to inject a liquid onto the battery components; a waste liquid section disposed below the container and having an on-off valve; the base member is movable at least horizontally; the waste liquid portion is disposed below the base member, the inner surface of the container is provided with a contact portion having a shape corresponding to the shape of the lower surface edge of the base member; The base member is movable in a vertical direction, When the lower surface edge of the base member comes into contact with the contact portion, the interior of the container is divided into a first space above the contact portion and a second space below the contact portion. Active material separation device.
2. The base member is movable in the vertical direction. The active material separation device according to claim 1 .
3. a second waste liquid section different from the first waste liquid section; The active material separation device according to claim 1 or 2.
4. A ring-shaped inner lid portion is provided inside the container. The active material separation device according to any one of claims 1 to 3.
5. a collection filter disposed inside the container; The active material separation device according to any one of claims 1 to 4.
Citation Information
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