Method for producing microporous polyolefin resin sheet and apparatus for producing microporous polyolefin resin sheet

Abstract

The present invention provides a method and a device for manufacturing a microporous polyolefin resin sheet with which it is possible to manufacture a high-quality sheet in a stable manner. This method for manufacturing a microporous polyolefin resin sheet is a method for manufacturing a sheet in which a sheet material containing a polyolefin resin and a diluent is discharged from a discharge port of a mouthpiece towards a cast device, and in a decompression chamber, the space between the sheet material and the cast device is covered, air is suctioned, and the sheet material is brought into intimate contact with the cast device. The suctioning of the air in the decompression chamber is performed from exhaust nozzles disposed on the outer side relative to the two width-direction edge sides of the sheet material so that opening parts face each other; and the relationships Y1 / H ≤ 0.13 and 0.25 ≤ Y2 / H ≤ 0.75 are satisfied, where H represents the shortest distance from the discharge port of the mouthpiece to the outer peripheral surface of the cast device, Y1 represents the shortest distance from the upper edge side of the opening parts to an edge part of the sheet material, and Y2 represents the shortest distance from the lower edge of the opening parts to an edge part of the sheet material.

Description

[Technical Field]

[0001] The present invention relates to a method and an apparatus for producing a microporous polyolefin resin sheet. [Background technology]

[0002] First, a general method for producing a microporous polyolefin resin sheet will be described. 7 1 is a schematic diagram of a general microporous polyolefin resin sheet manufacturing apparatus. 7 The manufacturing apparatus shown in Figure 1 includes a die 1 having a discharge port 5 for discharging a sheet material 3 containing a polyolefin resin and a diluent; a casting device 2 that cools and solidifies the sheet material 3 discharged from the discharge port 5 while conveying it; and a decompression chamber 4 located upstream of the discharge port 5 in the sheet conveyance direction, covering a space 13 between the sheet material 3 and the casting device 2 and drawing air to form a decompressed space. A known sheet manufacturing method involves discharging the sheet material 3 from the discharge port 5 of the die 1 toward the casting device 2, drawing air from the space 13 through openings 9 of exhaust nozzles 12 located outward from both ends of the sheet material 3 in the sheet width direction to bring the sheet material 3 into close contact with the casting device 2, and then cooling and solidifying the sheet material 3 while conveying it through the casting device 2. Generally, to prevent contact between the casting device 2 and the decompression chamber 4 while suppressing the inflow of outside air, a small gap is formed between the casting device 2 and a side wall 4a of the decompression chamber 4 that covers the surface of the space 13 perpendicular to the sheet width direction.

[0003] Incidentally, as a technology for improving the quality of sheets, there is a resin sheet manufacturing device disclosed in Patent Document 1. Patent Document 1 discloses a resin sheet manufacturing device that is provided with a shielding plate near the edge of the sheet material in order to suppress unevenness in thickness due to membrane vibration of the sheet material. 8 1 is a schematic view of the resin sheet manufacturing apparatus of Patent Document 1, observed from above in the vertical direction. 8As shown in the figure, in the manufacturing apparatus of Patent Document 1, the straightening effect of the shielding plate 6 suppresses the formation of vortices at the end of the sheet material 3, suppresses membrane vibration of the sheet material, and reduces thickness unevenness of the resin sheet. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] Japanese Patent Application Publication No. 10-180847 Summary of the Invention [Problem to be solved by the invention]

[0005] With the recent increase in resin sheet production, there is a strong demand for increasing the discharge rate of sheet material and extending the continuous film production time. However, increasing the discharge rate of sheet material and extending the continuous film production time also increases the chances that low-molecular-weight components in the sheet material, diluents, and gases derived from additives will adhere to the nozzle of the die and liquefy (hereinafter referred to as droplets). If these droplets adhere to the casting equipment or sheet material due to the airflow in the decompression chamber, they can cause defects or tearing in the sheet. However, at present, no method has been proposed to prevent droplet scattering or to suppress it.

[0006] Therefore, the present invention provides a method and apparatus for producing a microporous polyolefin resin sheet that can stably produce high-quality sheets by suppressing the scattering of droplets onto the casting device or sheet material due to airflow generated in the decompression chamber. [Means for solving the problem]

[0007] The present invention provides a method for producing a microporous polyolefin resin sheet that solves the above-mentioned problems, comprising: discharging a sheet material containing a polyolefin resin and a diluent from a discharge port of a die toward a casting device; covering the space between the sheet material and the casting device with a decompression chamber located upstream of the discharge port in the sheet conveyance direction; suctioning air from the decompression chamber to create a decompressed space; bringing the sheet material into close contact with the casting device; and cooling and solidifying the sheet material while conveying it with the casting device; wherein the air is suctioned from the decompression chamber through exhaust nozzles located outward from both widthwise ends of the sheet material so that their openings face each other; and, where H is the shortest distance from the discharge port of the die to the outer peripheral surface of the casting device, Y1 is the shortest distance from the upper end of the opening to the edge of the sheet material, and Y2 is the shortest distance from the lower end of the opening to the edge of the sheet material, the relationships Y1 / H≦0.13 and 0.25≦Y2 / H≦0.75.

[0008] In the method for producing a microporous polyolefin resin sheet of the present invention, it is preferable that the suction width L1, which is the horizontal distance from the edge of the sheet material 3 at the upper end of the opening of the exhaust nozzle to the upstream end in the sheet conveying direction when observed from the outside in the sheet width direction, is L1 / H≦0.38. In the method for producing a microporous polyolefin resin sheet of the present invention, it is preferable that a sealing gap, which is a gap between the side wall of the decompression chamber perpendicular to the sheet width direction and the casting device and is located directly below the opening of the exhaust nozzle, is physically sealed with a sealing material. In the method for producing a microporous polyolefin resin sheet of the present invention, it is preferable that the sealing material is an elastic material, and the sealing gap is closed by pressing the sealing material against the casting device. In the method for producing a microporous polyolefin resin sheet of the present invention, it is preferable to press and fix the sealing material against the decompression chamber with a pressing member.

[0009] Furthermore, the present invention provides a microporous polyolefin resin sheet manufacturing apparatus that solves the above-mentioned problems, comprising: a die having a discharge port for discharging a sheet material containing a polyolefin resin and a diluent; a casting device that cools and solidifies the sheet material discharged from the discharge port while transporting it; and a decompression chamber that is arranged upstream of the discharge port in the sheet transport direction, covers the space between the sheet material and the casting device, and draws air into the decompression space. The decompression chamber is arranged outside both ends of the sheet material in the width direction so that exhaust nozzles that draw air from the decompression chamber face each other, and is arranged so that Y1 / H≦0.13 and 0.25≦Y2 / H≦0.75, where H is the shortest distance from the discharge port of the die to the outer peripheral surface of the casting device, Y1 is the shortest distance from the upper end of the exhaust nozzle opening to the edge of the sheet material, and Y2 is the shortest distance from the lower end of the exhaust nozzle opening to the edge of the sheet material.

[0010] In addition, in the microporous polyolefin resin sheet manufacturing apparatus of the present invention, it is preferable that the die, the casting device, and the exhaust nozzle are arranged so that the suction width L1, which is the horizontal distance from the edge of the sheet material 3 at the upper end of the opening of the exhaust nozzle to the upstream end in the sheet conveying direction when observed from outside in the sheet width direction, satisfies L1 / H≦0.38. Furthermore, the microporous polyolefin resin sheet manufacturing apparatus of the present invention preferably includes a sealing material that physically seals a sealing gap, which is a gap located directly below the opening, among the gaps formed between the side wall of the vacuum chamber perpendicular to the sheet width direction and the casting device.

[0011] In the apparatus for producing a microporous polyolefin resin sheet of the present invention, it is preferable that the sealing material is an elastic material and is pressed against the casting device to close the sealing gap. The microporous polyolefin resin sheet manufacturing apparatus of the present invention preferably includes a pressing member that presses and fixes the sealing material against the decompression chamber. [Effects of the Invention]

[0012] According to the polyolefin resin sheet manufacturing method and manufacturing apparatus of the present invention, high-quality sheets can be stably manufactured by suppressing the scattering of droplets onto the casting device or sheet material due to the air flow in the decompression chamber. [Brief explanation of the drawings]

[0013] [Figure 1] 1 is a schematic view of one embodiment of a microporous polyolefin resin sheet production apparatus of the present invention, observed from downstream in the sheet conveying direction. [Figure 2] 2 is a partially enlarged cross-sectional view perpendicular to the vertical direction along line XX in FIG. 1. [Figure 3] FIG. 3 is a diagram showing a state in which Y1 / H is increased from the state in FIG. 2. [Figure 4] 1 is a schematic diagram of one embodiment of a microporous polyolefin resin sheet manufacturing apparatus of the present invention viewed from the sheet width direction. [Figure 5A] 2 is a diagram illustrating a sealing material and a pressing member disposed between a casting device and a decompression chamber of the microporous polyolefin resin sheet production apparatus of FIG. 1. FIG. [Figure 5B] 5B is a vertical cross-sectional view taken along line YY in FIG. 5A. [Figure 5C] FIG. 5B is a vertical cross-sectional view taken along line ZZ in FIG. 5A. [Figure 6] 1 is a graph showing the shortest distance from an opening to an edge of a sheet material in each example and each comparative example. [Figure 7] FIG. 1 is a schematic diagram of a general apparatus for producing a microporous polyolefin resin sheet. [Figure 8] FIG. 1 is a schematic view of the resin sheet manufacturing apparatus of Patent Document 1, observed from above in the vertical direction. DETAILED DESCRIPTION OF THE INVENTION

[0014] [Terminology] The meaning of each term in the present invention will be explained. "Sheet material" refers to the material that makes up the sheet. For example, the sheet material is made by mixing polyolefin resins such as polyethylene, polypropylene, polystyrene, and polymethylpentene with a diluent and melting them by heating. preparation A resin obtained by dissolving or blending a polyolefin resin in a solution can be used. The diluent is not particularly limited as long as it can be mixed or dissolved in the polyolefin resin. Materials that are miscible with the polyolefin in the melt-kneaded state but solid at room temperature can also be used as diluents. Examples of such solid diluents include stearyl alcohol, ceryl alcohol, and paraffin wax. To prevent unevenness during stretching and to allow for subsequent application, the diluent is preferably liquid at room temperature. Examples of liquid diluents include aliphatic, cycloaliphatic, or aromatic hydrocarbons such as nonane, decane, decalin, paraxylene, undecane, dodecane, and liquid paraffin, as well as mineral oil fractions with corresponding boiling points, and phthalate esters that are liquid at room temperature, such as dibutyl phthalate and dioctyl phthalate. Liquid paraffin is more preferred to obtain a stable gel-like sheet. The viscosity of the liquid diluent is preferably 20 to 200 cSt at 40°C. The blending ratio of the polyolefin resin and the diluent is preferably 10 to 50 mass% of the polyolefin resin and 50 to 90 mass% of the diluent, from the viewpoint of improving the moldability of the extruded product, where the total of the polyolefin resin and the diluent is 100 mass%. The uniform melt-kneading process for the sheet material is not particularly limited, but examples include a calender, various mixers, and an extruder equipped with a screw.

[0015] The term "casting device" refers to a device that conveys a sheet material discharged from a nozzle of a die downstream while cooling and solidifying it by tightly contacting the material. The form of the device is not particularly limited, but examples include a roll and a belt. The term "width direction" refers to the direction that coincides with the width direction of the sheet material when it is formed into a sheet by a die. The "sheet conveying direction" refers to the direction in which the casting device conveys the sheet. The conveying destination is the downstream side, and the opposite is the upstream side. "Decompressed space" refers to a space formed between the sheet material and the casting device, which is covered with a vacuum chamber and is kept at a negative pressure. A "decompression chamber" refers to a device that covers the space between the sheet material and the casting device and reduces the pressure to bring the sheet material into close contact with the casting device. Generally, the pressure in the decompression chamber is between -1500 Pa and -50 Pa relative to atmospheric pressure. The pressure in the decompression chamber may also be controlled depending on the film-forming conditions. The "opening" refers to a portion of the exhaust nozzle that draws air from inside the decompression chamber. The shape of the opening is not particularly limited, but examples include square, rectangular, trapezoidal, circular, and elliptical shapes. The opening may be subjected to a surface treatment such as nickel plating, chrome plating, or zinc plating. The power source for suction is not particularly limited, but examples include a blower and a vacuum pump. The "side wall" refers to the side surface of the decompression chamber that is perpendicular to the sheet width direction.

[0016] Next, the polyolefin resin sheet manufacturing apparatus and manufacturing method of the present invention will be described in detail with reference to the drawings. However, the present invention is not limited to the embodiments described here. Note that components having the same uses and functions as those in the prior art may be designated by the same reference numerals.

[0017] Referring to FIG. 1, the influence of the dimensions of the opening 9 of the exhaust nozzle 12 of the decompression chamber 4 on the airflow within the decompression chamber 4 will be described. FIG. 1 is a schematic diagram of one embodiment of the polyolefin resin sheet manufacturing apparatus of the present invention, observed from upstream in the sheet conveyance direction. In the figure, symbols Y1 and Y2 represent the shortest distances from the opening 9 to the edge of the sheet material 3, with Y1 representing the shortest distance at the upper end of the opening 9 and Y2 representing the shortest distance at the lower end of the opening 9. Symbol H represents the shortest distance from the discharge port 5 of the die 1 to the outer peripheral surface of the casting device 2. The length of H is determined by the film-forming conditions. However, if the opening 9 is small, clogging due to droplets or the like can cause unstable suction. Therefore, from the viewpoint of ensuring a sufficient height from the upper end to the lower end of the opening 9, H is preferably 10 mm or more, more preferably 30 mm or more. After extensive research, the present inventors have found that Y1 / H and Y2 / H, which are obtained by normalizing Y1 and Y2 with H, affect the airflow within the decompression chamber 4 and ultimately cause droplets to scatter within the decompression chamber 4.

[0018] The pressure and airflow near the edge of the sheet material 3 will be described with reference to Figures 2 and 3. Figure 2 is a partially enlarged cross-sectional view perpendicular to the vertical direction along line XX in Figure 1, showing the pressure near the edge of the sheet material 3 using contour lines. Figure 3 is a contour line showing the pressure near the edge of the sheet material 3 when the distance Y1 is longer than in the state of Figure 2 (when H is the same and Y1 / H is larger). Here, specific numerical values ​​of the pressure will be given to accurately convey the gist of the present invention, but these values ​​are merely examples and do not limit the scope of the present invention.

[0019] First, in the state shown in Figure 2, the pressure at each location is assumed to be atmospheric pressure near the downstream end of the sheet material 3 in the sheet conveying direction (point A), (atmospheric pressure -300) Pa near the end of the sheet material 3 on the inside of the decompression chamber 4 (point B), (atmospheric pressure -600) Pa downstream of the opening 9 (point C), and (atmospheric pressure -400) Pa near the end of the sheet material 3 on the exhaust nozzle 12 side (point D). In this case, the pressure contours are as shown in Figure 2, and according to the Navier-Stokes equation, air has the property of flowing from areas of higher pressure to areas of lower pressure, so most of the air flows to point C, where the pressure is lower than point A, like air flow 8a, i.e., to the opening 9 of the exhaust nozzle 12.

[0020] If the distance Y1 increases from the state shown in Figure 2 and Y1 / H increases, the pressure gradient from point A to point C becomes gentler, and the pressure at point D increases from the state shown in Figure 2 to (atmospheric pressure - 200) Pa. This results in a pressure distribution as shown in Figure 3, and some air flows from point A through point D to point B, where the pressure is lower, as airflow 8b, which also flows into decompression chamber 4. This airflow 8b scatters droplets 7 near outlet 5 of die 1 into the main body of decompression chamber 4, where they adhere to the casting device 2 and sheet material 3, causing defects or tearing in the sheet.

[0021] Furthermore, if the shortest distance Y2 from the lower end of the opening 9 to the end of the sheet material 3 is small, or if the shortest distance H from the discharge port 5 of the nozzle 1 to the outer surface of the casting device 2 is large and Y2 / H is too small, the airtightness inside the decompression chamber 4 becomes high, the pressure inside the decompression chamber 4 becomes lower than near the end of the sheet material 3 on the exhaust nozzle 12 side, and an air flow 8b is generated inside the decompression chamber 4, flowing from the downstream side in the sheet conveying direction, through the end of the sheet material 3, and into the decompression chamber 4, as in the case of Figure 3. On the other hand, if the shortest distance Y2 from the lower end of the opening 9 to the end of the sheet material 3 is large, or the shortest distance H from the discharge port 5 of the nozzle 1 to the outer surface of the casting device 2 is small, and Y2 / H is too large, a vortex will occur near the end of the sheet material 3, and the turbulent pressure and airflow will cause the droplets 7 to scatter.

[0022] As a result of further experiments and theoretical calculations, the inventors have found that by satisfying Y1 / H≦0.13 and 0.25≦Y2 / H≦0.75, the pressure at point B is stably higher than that at point D as shown in Figure 2, eliminating airflow within the decompression chamber 4, preventing droplets 7 from scattering into the main body of the decompression chamber 4, and suppressing adhesion of droplets 7 to the casting apparatus 2 and sheet material 3. More preferably, Y1 / H≦0.05.

[0023] In order to achieve Y1 / H≦0.13 and 0.25≦Y2 / H≦0.75, it is possible to design the decompression chamber 4 taking into consideration the amount of sheet material 3 discharged from the die 1, the shortest distance H from the discharge outlet 5 of the die 1 to the outer surface of the casting device 2, the amount of suction from the exhaust nozzle 12, etc. However, it is preferable to make the side wall 4a of the decompression chamber 4 perpendicular to the sheet width direction movable in the width direction of the sheet material 3 and adjust Y1 and Y2.

[0024] Refer to FIG. 4. FIG. 4 is a schematic diagram of one embodiment of the polyolefin resin sheet manufacturing apparatus of the present invention, observed from the sheet width direction. Although the sheet material 3 is actually obscured by the decompression chamber 4, FIG. 4 illustrates the sheet material 3 as being observable through the decompression chamber 4 for easier understanding of the present invention. The suction width L1 in the figure is the horizontal distance from the edge of the sheet material 3 at the upper end of the opening 9 of the exhaust nozzle 12 to the upstream end in the sheet conveyance direction, as observed from the outside in the sheet width direction. In the polyolefin resin sheet manufacturing method of the present invention, it is preferable that L1 / H be 0.38 or less. Even if L1 / H is greater than 0.38, the effects of the present invention can be achieved by setting Y1, Y2, and H within the above-mentioned ranges. However, by setting L1 / H to 0.38 or less, the amount of air suctioned from within the main body of the decompression chamber 4 is reduced, the pressure inside the decompression chamber 4 can be increased, and the airflow from the downstream side in the sheet conveyance direction through the edge of the sheet material 3 into the decompression chamber 4 can be suppressed. 1 and 4, the pressure in the main body of the decompression chamber 4 is not reduced by a vacuum pump or the like from the main body of the decompression chamber 4, and the space 13 within the main body of the decompression chamber 4 is made into a reduced pressure space only by the exhaust nozzle 12, but the inside of the main body of the decompression chamber 4 may also be reduced by a vacuum pump. To adjust Y1 and Y2, it is preferable to reduce the pressure in the main body of the decompression chamber 4 only by the exhaust nozzle 12, without reducing the pressure by a vacuum pump or the like.

[0025] Referring again to FIG. 1, the seal gap 14 in the figure is the gap between the side wall 4a of the vacuum chamber 4 perpendicular to the sheet width direction and the casting device 2, and is located directly below the opening 9 of the exhaust nozzle 12. As shown in FIG. 1, in the method for producing a polyolefin resin sheet of the present invention, it is preferable to close the seal gap 14 with a seal material 10. Although the effects of the present invention can be obtained without this seal material 10, providing the seal material 10 eliminates airflow that would flow through the seal gap 14 and disrupt the pressure balance near the edge of the sheet material 3, thereby suppressing the scattering of droplets 7 into the vacuum chamber. The material of the seal material 10 is not particularly limited, but examples include resin, rubber, and ceramics.

[0026] Furthermore, in the method for producing a polyolefin resin sheet of the present invention, it is preferable that the sealing material 10 is an elastic material, and that the sealing material 10 is pressed against the casting device 2 to close the sealing gap 14. By pressing the elastic sealing material 10 against the casting device 2, the sealing material 10 is deformed by the compressive load, and even small gaps between the casting device 2 and the sealing material 10 can be prevented. More preferably, the sealing material 10 is a non-conductive porous resin or rubber that does not impart conductivity to the product even if wear powder is mixed into the product. Furthermore, the hardness of the sealing material 10 is preferably Shore E10 to 35, which can impart sealing properties under low load. More preferably, it is Shore E25 to 35, which minimizes distortion due to friction with the casting device 2.

[0027] The method for fastening the sealing material 10 is not particularly limited, and examples include a method of directly fastening it to the side wall 4a with multiple bolts. However, care must be taken when fastening the sealing material 10, as friction with the casting device 2 can cause distortion or misalignment of the sealing material 10, preventing it from performing its sealing function. If the sealing material 10 is directly fastened with bolts, the fastening may be insufficient, for example, in a narrow gap between the exhaust nozzle 12 and the casting device 2, which may result in distortion or misalignment of the sealing material 10. Therefore, in the polyolefin resin sheet manufacturing method of the present invention, it is preferable to fasten the sealing material 10 by pressing it against the decompression chamber 4 with a pressing member 11. Figures 5A to 5C are diagrams illustrating the sealing material 10 and pressing member 11 arranged between the casting device 2 and the decompression chamber 4 of the microporous polyolefin resin sheet manufacturing apparatus of Figure 1. As shown in Figures 5A to 5C, the sealing material 10 is preferably fastened with bolts 15 via the pressing member 11. Even in a narrow gap between the exhaust nozzle 12 and the casting device 2 where a bolt 15 cannot be placed, as shown in FIG. 5B, the sealing material 10 is fixed over the entire surface that contacts the pressing member 11, thereby suppressing distortion and misalignment, and allowing the sealing material 10 to stably seal the sealing gap 14. The shape of the pressing member 11 is not particularly limited, and is preferably an L-shaped plate that also covers the top of the sealing material 10 as shown in FIGS. 5A and 5C, but a flat plate may also be used. Furthermore, the frictional force of the contact surface with the sealing material 10 may be increased to prevent the sealing material 10 from misaligning. For example, this may be achieved by providing protrusions, increasing the surface roughness, or applying an adhesive. [Example]

[0028] Examples of polyolefin resin sheet production using the polyolefin resin sheet production method of the present invention will be described below. [Example 1] A polyolefin resin sheet was actually produced using the polyolefin resin sheet production method, and the results of evaluating defects caused by droplet scattering will be described. Specific sheet production conditions and defect evaluation methods in this embodiment are as follows. (1) Sheet material High-density polyethylene (HDPE): Viscosity 1000 Pa·s. Here, viscosity was measured at a shear rate of 100 / s and a temperature of 200°C according to the method of JIS K7117-2. Liquid paraffin (LP): Kinematic viscosity 50 cSt (at 40°C). The blend ratio of HDPE and LP is HDPE:LP = 30:70 by mass. (2) Extrusion The sheet material was extruded at a flow rate of 250 kg / h using an extruder, passed through a gear pump and a filter, and then fed to a die. The temperature of the extruder up to the die was 220°C. (3) Base The sheet material was discharged from a discharge port with a width of 500 mm and a gap of 2 mm and formed into a sheet. The amount of LP volatilized from the discharged sheet was measured and found to be approximately 100 g / h. (4) Casting equipment The sheet was brought into close contact with a sheet forming roll rotating at a temperature of 35°C and a speed of 10 m / min, and then cooled and solidified. The die outlet was positioned directly above the center of the sheet forming roll, with the shortest distance H from the die outlet to the outer circumferential surface of the sheet forming roll being 40 mm. (5) Decompression chamber The decompression chamber was installed upstream of the die's discharge port in the conveying direction and was shaped to cover the space between the sheet material being discharged from the discharge port and the casting device. Exhaust nozzles were located on both wall surfaces of the decompression chamber, facing each other. The exhaust nozzle opening was rectangular, with the long side horizontally aligned, measuring 70 mm and the short side 32 mm. When the die was set under film-forming conditions, the distance from the die's discharge port to the upper edge of the opening was 3 mm, and the distance from the lower edge of the opening to the sheet forming roll was 5 mm. In this state, the decompression chamber was evacuated to -600 Pa from atmospheric pressure using a blower connected to the opening. The decompression chamber was equipped with a mechanism for adjusting the position of both wall surfaces. When the sheet material was being discharged from the die's discharge port, the Y1 was adjusted to 4 mm (Y1 / H = 0.1), Y2 to 20 mm (Y2 / H = 0.5), and L1 to 16 mm (L1 / H = 0.4). The decompression chamber was also positioned to provide a 1 mm seal gap. (6) Defect detection device Using the inspection device MaxEye.Impact (Hutec Corporation), the number of defects caused by droplet scattering was counted on the sheet (width 423 mm, length 100 m) collected under the above conditions. The number of defects was 5.

[0029] [Examples 2 to 6, Comparative Examples 1 to 5] Sheets were collected in the same manner as in Example 1, except that the dimensions were changed as shown in Table 1, and the number of defects was inspected.

[0030] [Example 7] Sheets were collected in the same manner as in Example 1, except that a sealing material (polytetrafluoroethylene, Shore hardness D55) was fixed to the decompression chamber with bolts to physically close the seal gap, and the number of defects was inspected.

[0031] [Example 8] The sealing material was made of elastic silicone sponge rubber (Shore hardness E30), and the sealing material was pressed against a casting device and fixed to a vacuum chamber with bolts to seal the sealing gap. Except for this, sheets were collected in the same manner as in Example 7 and the number of defects was inspected.

[0032] [Example 9] Sheets were collected in the same manner as in Example 8, except that the sealing material was pressed and fixed to the decompression chamber with a pressing member (a flat plate made of SUS304 and having a thickness of 2 mm), and the number of defects was inspected. The manufacturing conditions and the number of defects that occurred in the sheets for Examples 1 to 6 and Comparative Examples 1 to 5 are summarized in Tables 1 and 2, respectively.

[0033] [Table 1]

[0034] [Table 2]

[0035] [Evaluation results] The relationship between Y1 / H and Y2 / H in each example and comparative example will be described with reference to FIG. 6. FIG. 6 is a graph showing the positions of Y1 / H and Y2 / H for each example and comparative example, with Y1 / H on the vertical axis and Y2 / H on the horizontal axis. Here, ◯ indicates Examples 1 to 5, × indicates Comparative Examples 1 to 5, and the dotted line indicates the range satisfying the conditions "Y1 / H≦0.13" and "0.25≦Y2 / H≦0.75." As shown in FIG. 6 and Table 1, in Examples 1 to 5, which satisfied the conditions "Y1 / H≦0.13" and "0.25≦Y2 / H≦0.75," the pressure in the decompression chamber was higher than that at the edge of the sheet material, suppressing the airflow in the decompression chamber, resulting in a small number of defects (4 to 5). On the other hand, as shown in FIG. 6 and Table 2, in Comparative Examples 1 to 5 which did not satisfy the condition "Y1 / H≦0.13" or "0.25≦Y2 / H≦0.75", the number of defects was as high as 10 to 13. Furthermore, in Example 6, which satisfied the condition "L1 / H≦0.38", the small L1 further suppressed the airflow inside the decompression chamber, resulting in fewer defects than Examples 1 to 5, at three. In addition, in Example 7, in which the seal gap was blocked with a sealing material, there was no airflow flowing in through the gap and disrupting the pressure balance near the edge of the sheet material, so the number of defects was two, which was fewer than in Examples 1 to 5. In Example 8, in which the sealing material was made of an elastic material and was pressed against the casting device to seal the sealing gap, even minute gaps with the casting device could be prevented, and the number of defects was one, which was fewer than in Example 7. In Example 9, in which the sealing material was pressed and fixed to the decompression chamber with a pressing member, distortion and displacement of the sealing material were suppressed, and the number of defects was 0, which was fewer than in Example 8. [Industrial Applicability]

[0036] The present invention is not limited to a manufacturing apparatus and manufacturing method for a microporous polyolefin resin sheet, but can also be applied to a manufacturing apparatus and manufacturing method for a solution resin sheet, die coating, etc., but the scope of application is not limited to these. [Explanation of symbols]

[0037] 1 nozzle 2 Casting equipment 3 Sheet material 4. Decompression Chamber 4a side wall 5 Outlet 6 Shielding plate 7 droplets 8a, 8b Air flow 9 Openings 10 Sealing material 11 Pressing member 12 Exhaust nozzle 13 Space 14 Seal gap 15 volts

Claims

1. A sheet material containing a polyolefin resin and a diluent is discharged from a discharge port of a die toward a casting device; a decompression chamber disposed upstream of the discharge port in a sheet conveying direction, covering a space between the sheet material and the casting device; The air in the decompression chamber is sucked to form a decompression space, and the sheet material is brought into close contact with the casting device. A sheet manufacturing method comprising: cooling and solidifying the sheet material while conveying it through the casting device; The air in the decompression chamber is sucked from exhaust nozzles arranged so that openings thereof face each other outside both ends of the sheet material in the width direction, where H is the shortest distance from the discharge port of the die to the outer peripheral surface of the casting device, Y1 is the shortest distance from the upper end side of the opening to the end of the sheet material, and Y2 is the shortest distance from the lower end side of the opening to the end of the sheet material, Y1 / H≦0.13 and 0.25≦Y2 / H≦0.

75. A method for producing a microporous polyolefin resin sheet.

2. 2. The method for producing a microporous polyolefin resin sheet according to claim 1, wherein the suction width L1 is the horizontal distance from the end of the sheet material 3 at the upper end of the opening of the exhaust nozzle to the upstream end in the sheet conveying direction when observed from the outside in the sheet width direction, and L1 / H≦0.

38.

3. 3. The method for producing a microporous polyolefin resin sheet according to claim 1 or 2, wherein a sealing gap, which is a gap between a side wall of the decompression chamber perpendicular to the sheet width direction and the casting device and is located directly below the opening of the exhaust nozzle, is physically sealed with a sealing material.

4. The method for producing a microporous polyolefin resin sheet according to claim 3, wherein the sealing material is an elastic material, and the sealing gap is closed by pressing the sealing material against the casting device.

5. The method for producing a microporous polyolefin resin sheet according to claim 4, wherein the sealing material is pressed and fixed to the decompression chamber by a pressing member.

6. a die having a discharge port for discharging a sheet material containing a polyolefin resin and a diluent; a casting device that cools and solidifies the sheet material discharged from the discharge port while conveying it; a decompression chamber that is disposed upstream of the discharge port in a sheet conveying direction, covers a space between the sheet material and the casting device, and sucks air to create a decompressed space, The decompression chamber comprises: Exhaust nozzles for sucking air from the decompression chamber are arranged outside both ends of the sheet material in the width direction so that their openings face each other; the die, the casting device, and the exhaust nozzle are arranged so that Y1 / H≦0.13 and 0.25≦Y2 / H≦0.75, where H is the shortest distance from the discharge port of the die to the outer peripheral surface of the casting device, Y1 is the shortest distance from the upper end side of the opening of the exhaust nozzle to the end of the sheet material, and Y2 is the shortest distance from the lower end side of the opening of the exhaust nozzle to the end of the sheet material; Microporous polyolefin resin sheet manufacturing equipment.

7. 7. The apparatus for producing a microporous polyolefin resin sheet according to claim 6, wherein the exhaust nozzle is positioned so that the suction width L1, which is the horizontal distance from the end of the sheet material 3 at the upper end of the opening of the exhaust nozzle to the upstream end in the sheet conveying direction when observed from the outside in the sheet width direction, satisfies L1 / H≦0.

38.

8. 8. The microporous polyolefin resin sheet manufacturing apparatus according to claim 6 or 7, further comprising a sealing material that physically seals a seal gap, which is a gap located directly below the opening of the exhaust nozzle, between the side wall of the decompression chamber perpendicular to the sheet width direction and the casting device.

9. The apparatus for producing a microporous polyolefin resin sheet according to claim 8, wherein the sealing material is an elastic material and is pressed against the casting device.

10. The apparatus for producing a microporous polyolefin resin sheet according to claim 9, further comprising a pressing member for pressing and fixing the sealing material against the decompression chamber.

11. the side walls are movable across the width of the sheet material; The apparatus for producing a microporous polyolefin resin sheet according to any one of claims 8 to 10.

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