High burst volume water-based polyurethane condom and method for its preparation

Abstract

The present invention provides an aqueous polyurethane condom with a high burst volume and a method for preparing the same, comprising the steps of: preparing an aqueous polyurethane; immersing the aqueous polyurethane in the aqueous polyurethane and then drying it; repeating the process of immersing the aqueous polyurethane in the aqueous polyurethane and then drying it N times to obtain an aqueous polyurethane film; rolling up one end of the aqueous polyurethane film and then drying it; immersing the aqueous polyurethane in a releasing agent, followed by drying, demolding, and electrical testing to obtain an aqueous polyurethane condom, where N is equal to 1 to 5; the aqueous polyurethane is an anionic aqueous polyurethane; the aqueous polyurethane has a 100% tensile modulus of 2.0 MPa or less and an elongation at break of 650% or more; and the polyurethane condom prepared by this method has a burst volume of more than 12 L, a burst pressure of more than 1 KPa, and a 100% tensile modulus of 2.0 MPa or less.

Description

[Technical Field]

[0001] The present invention relates to the technical field of aqueous polyurethane applications, in particular to aqueous polyurethane condoms with high burst volumes and methods for preparing same. [Background technology]

[0002] Condoms are currently the most widely used and simplest devices for contraception and prevention of sexually transmitted diseases in the world. Existing products mainly include natural latex condoms and water-based polyurethane condoms. Due to the material properties of natural latex, it is difficult to achieve a thickness of 0.04 mm or less with natural latex rubber condoms, and natural latex contains various proteins, which poses a certain safety risk to people with protein allergies. However, after decades of commercialization, natural latex rubber condoms have found a wide market following, and their soft texture has been well received by consumers. Currently, commercially available polyurethane condoms generally have a high modulus and a burst volume of approximately 7 to 11 L. However, they are insufficiently soft and have a burst volume that is insufficient compared to latex. Therefore, the development of a low modulus, high elongation, water-based polyurethane condom that not only retains the advantages of polyurethane, such as no protein allergies, high strength, high pressure, and high thermal conductivity, but also has softness and a high burst volume close to that of latex products, and further improves the experience of polyurethane condom products, is of great market significance. Summary of the Invention

[0003] In order to solve the technical problems existing in the prior art, the present invention provides a water-based polyurethane condom with high burst volume and a method for preparing the same. First, the present invention provides an aqueous polyurethane condom with a high burst volume and a preparation method thereof, the method comprising at least the steps of: preparing an aqueous polyurethane; immersing the aqueous polyurethane in the aqueous polyurethane and then drying it; repeating the process of immersing the aqueous polyurethane in the aqueous polyurethane and then drying it N times to obtain an aqueous polyurethane film; rolling up one end of the aqueous polyurethane film and then drying it; immersing the aqueous polyurethane in a releasing agent, followed by drying, demolding, and electrical testing to obtain an aqueous polyurethane condom, wherein N is equal to 1 to 5; the aqueous polyurethane is an anionic aqueous polyurethane, and the aqueous polyurethane has a 100% tensile modulus of 2.0 MPa or less and a breaking elongation of 650% or more. In one embodiment, the drying after winding one end of the aqueous polyurethane film is drying for forming, and the drying after immersion in the aqueous polyurethane is drying for fixing, and the duration of the drying for fixing and the duration of the drying for forming are t 形成 =90·Φ-1.8·(N+2)·t 固定 (In the formula, t 形成 is the duration of drying for formation (min), and t 固定 where is the duration of drying for fixation (min), N is the number of repeated immersion, Φ = 2.7 − 0.015 · T, and T is the temperature (°C) of drying for fixation and drying for formation.

[0004] In one embodiment, the duration of drying for fixation is 2 to 10 minutes, the duration of drying for formation is 10 to 65 minutes, and the duration of drying for the releasing agent is 2 to 30 minutes. In one embodiment, the drying temperature is 80 to 140°C. In one embodiment, the water-based polyurethane has a solids content of 15-30%. In one embodiment, among the solid raw material components of the aqueous polyurethane, the polymer polyol accounts for 60 to 85% of the total solid raw material components, and the proportion of the polymer polyol having three or more functional groups is 10 to 40% of the polymer polyol. In one embodiment, the polymeric polyol consists of a difunctional polymeric polyol of molecular mass 500 to 4,000 and a trifunctional polymeric polyol of molecular mass 650 to 6,000 in a weight ratio of 4:(0.2 to 1.5).

[0005] The present invention also provides a water-based polyurethane condom prepared by the above method. In one embodiment, the thickness of the water-based polyurethane condom is 0.02 mm to 0.06 mm. In one embodiment, the water-based polyurethane condom has the following properties: 100% tensile modulus of elasticity of 2.0 MPa or less, Bursting volume of 12L or more, Burst pressure of 1KPa or more, Elongation at break of 650% or more, and Tensile strength of 20 MPa or more It has one or more of the following. As described above, the present invention provides a polyurethane condom with a low modulus and a high burst volume, and a method for preparing the same, which has the following beneficial effects: by using an aqueous polyurethane resin with a low modulus and high elongation, the polyurethane condom with a low modulus and a high burst volume obtained in the present invention through a forming process of multiple dipping and drying can achieve a product thickness of 0.02-0.06 mm, a 100% tensile modulus of ≦2.0 MPa, a burst volume of ≧12 L, and a performance index of ≧1 KPa. [Brief explanation of the drawings]

[0006] [Figure 1] FIG. 1 is a schematic flow chart of the preparation method of the present invention. DETAILED DESCRIPTION OF THE INVENTION

[0007] Embodiments of the present invention are described below with specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the disclosure of this specification. The present invention can also be implemented or applied in other separate specific embodiments, and various modifications or changes can be made to the details of this specification based on different perspectives and applications without departing from the spirit of the present invention. It should be noted that performance tests of the polyurethane resin and condom according to the present invention are carried out with reference to national standards GB / T1040.1-2006 and GB7544-2009, respectively. Unless otherwise specified, "%" and "parts" shown in this specification mean "% by mass" and "parts by mass", respectively.

[0008] Referring to Figure 1, first, the present invention provides a method for preparing an aqueous polyurethane condom having a high burst volume, which can be carried out by repeatedly immersing the condom in an aqueous polyurethane resin, and includes at least steps S1 to S4: S1: preparing a water-based polyurethane; S2: Repeat the process of immersing in aqueous polyurethane, then drying, immersing in aqueous polyurethane, then drying N times to obtain an aqueous polyurethane film; S3: One end of the aqueous polyurethane film is rolled up and then dried; S4: Immersing in a releasing agent, followed by drying, demolding, and electrical testing to obtain a water-based polyurethane condom; Including, The method is provided wherein N is equal to 1 to 5, the aqueous polyurethane is an anionic aqueous polyurethane, and the aqueous polyurethane has a 100% tensile modulus of elasticity of 2.0 MPa or less and an elongation at break of 650% or more.

[0009] In step S1, to prepare an aqueous polyurethane condom, the present invention provides an anionic aqueous polyurethane with excellent tensile modulus and breaking elongation. The 100% tensile modulus of the anionic polyurethane may be 2.0 MPa or less, for example, 1.8 MPa, 1.5 MPa, 1.4 MPa, or 1.3 MPa. The breaking elongation of the anionic aqueous polyurethane may be 650% or more, for example, 720%, 730%, or 750%. The aqueous polyurethane provided by the present invention enables the final aqueous polyurethane condom to have excellent performance, such as a burst volume of more than 12 L. The anionic aqueous polyurethane resin used in the present invention is produced using mature technology and has the advantage of high molecular weight combined with a low modulus. The solid content of the aqueous polyurethane resin may be between 15% and 30%, for example, 20% or 25%. The aqueous polyurethane resin has good leveling within the above solid content range, and the prepared condom has the advantages of little difference in uniformity, a large burst volume, and few defects.

[0010] The aqueous polyurethane of the present invention can be synthesized by a stepwise method. The aqueous polyurethane can be formed by preparing it from a solid raw material and dispersing it in water. The stepwise method may include processes such as polymerization, chain extension, and emulsification. The solid raw material for the aqueous polyurethane may include a soft segment and a hard segment. The soft segment may be a polymeric polyol or a composition of polymeric polyols, and the hard segment may be a polyisocyanate or a composition of polyisocyanates. The polymeric polyol may include a polymeric diol and a polymeric triol, for example, poly(tetramethylene ether glycol) (PTMEG), polypropylene glycol (PPG), and polyoxypropylene triol. In this specification, the molecular weight of the poly(tetramethylene ether glycol) may be 500 to 4,000, the molecular weight of the polypropylene glycol may be 1,000 to 5,000, and the molecular weight of the polyoxypropylene triol may be 650 to 6,000.

[0011] In one embodiment, the aqueous polyurethane comprises the following solid raw material components (parts by mass): 23 to 38 parts of a polymeric diol, 3 to 5 parts of a polymeric triol, 6.5 to 10 parts of a polyisocyanate, 1.3 to 1.6 parts of a hydrophilic chain extender, 0.05 to 0.08 parts of a low molecular weight polyol chain extender, 1 to 1.3 parts of a neutralizing agent, 0.2 to 0.3 parts of a low molecular weight amine post-chain extender, and 0.05 to 0.08 parts of a catalyst. The hydrophilic chain extender may be one or more of dimethylolpropionic acid, dimethylolbutyric acid, and sodium 2-[(2-aminoethyl)amino]ethanesulfonate; the low molecular weight polyol chain extender may include any one or more of trimethylolpropane, glycerol, butanediol, ethylene glycol, and cyclohexanedimethanol; the neutralizing agent may include any one or more of triethylamine and sodium bicarbonate; and the low molecular weight amine post-chain extender may be any one or more of ethylenediamine, hexamethylenediamine, isophoronediamine, toluenediamine, and diaminodicyclohexylmethane. The polyisocyanate may be any one or more of TDI, MDI, IPDI, HDI, and HMDI.

[0012] In one embodiment, the waterborne polyurethane comprises 8 to 13 parts PTMEG, 15 to 25 parts PPG, 3 to 5 parts polyoxypropylene triol, 5.5 to 8 parts IPDI, 1 to 2 parts HDI, 1.3 to 1.6 parts DMPA, and 0.5 to 0.8 parts DEG, 0.05 to 0.08 parts catalyst, 1 to 1.3 parts triethylamine, and 0.2 to 0.3 parts isophorone diamine. In one embodiment, the polymeric polyol comprises a difunctional polymeric polyol having a molecular mass of 500 to 4,000 and a trifunctional polymeric polyol having a molecular mass of 650 to 6000 in a mass ratio of 4:(0.2 to 1.5).Further, the polymeric polyol comprises poly(tetramethylene ether glycol) (PTMEG) having a molecular mass of 500 to 4000, polypropylene glycol (PPG) having a molecular mass of 1000 to 5000, and polyoxypropylene triol having a molecular mass of 650 to 6000 in a mass ratio of 1:3:(0.2 to 1.5). In the aqueous polyurethane resin, the soft segment may account for 60 to 85%, for example 79.5%, of the total solid raw materials, and the crosslinking ratio of the soft segment may be 10 to 40%, for example 25%. The crosslinking ratio of the soft segment may be defined as the mass ratio of the polymer polyol having three or more functional groups to the total polymer polyol.

[0013] In step S2, the preparation of the aqueous polyurethane condom further includes a process of repeatedly dipping and drying to form an aqueous polyurethane film. For example, this may be achieved by dipping a mold into aqueous polyurethane and then drying it, and repeating this process N times, where the number of repetitions (N) may be 1 to 5, for example, 2 or 3. The repeated dipping process allows the condom to have good thickness uniformity, fewer defects, and a large burst volume, which is beneficial for drying without wrinkling or tearing. The aqueous polyurethane of the present invention requires a drying step after each dipping, which may be drying for fixation, and the duration of the drying for fixation may be 2 to 10 minutes. In step S3, the aqueous polyurethane film may be further dried after one end is wound up, and this drying may be drying for forming, and the duration of drying for forming may be 10 to 65 minutes. In steps S2 to S4, the drying temperature may be 80 to 140°C, for example, 120°C or 130°C.

[0014] In the present invention, the tensile strength of a film formed by immersion in polyurethane and drying may be tested after each immersion in polyurethane. For example, when the tensile strength of a film formed by each immersion in polyurethane and drying reaches 60% of a predetermined tensile strength, drying may be stopped and the next immersion may be performed. The predetermined tensile strength may be, for example, 20 MPa or more. In the present invention, drying is performed for a specific time after each immersion. For example, when the tensile strength of a polyurethane film is tested after the first immersion, the time used for drying at this point when the tensile strength of the polyurethane film reaches 60% of the predetermined tensile strength can be used as the duration of drying for fixation in the present invention. The duration of drying for fixation used in the present invention may be equal to or longer than the drying time required for the tensile strength of the polyurethane film formed by the first immersion in aqueous polyurethane to reach 60% of the predetermined tensile strength. The duration of drying for formation is t 形成 =90·Φ-1.8·(N+2)·t 固定 (In the formula, t 形成 is the duration of drying for formation (min), and t 固定 where N is the duration of drying for fixing (minutes), N is the number of repeated dippings, Φ is a temperature influence coefficient, Φ=2.7-0.015·T, and T is the temperature (°C) of drying for fixing and drying for forming. In one embodiment, when the above formula is applied, the temperature of drying for forming is the same as the temperature of drying for fixing. By applying the above formula during the duration of drying for fixing and the duration of drying for forming, it is possible to ensure that the final condom has the best performance and prevent the final product from being too brittle due to a drying duration that is too long, or from having insufficient strength due to a drying duration that is too short.

[0015] In step S4, the duration of drying after immersion in the release agent may be 2 to 30 minutes. The present invention also provides an aqueous polyurethane condom with a low modulus and a high burst volume. The aqueous polyurethane condom may be a thin type, with a thickness between 0.02 mm and 0.06 mm, for example, 0.03 mm. The polyurethane condom has a good tensile modulus and burst volume. The 100% tensile modulus of the polyurethane condom of the present invention may be 2.0 MPa or less, for example, 1.8 MPa, 1.3 MPa, or 1.4 MPa. The burst volume of the polyurethane condom may be greater than 12 L, for example, 15 L, 17 L, 18 L, or 20 L. In one embodiment, the polyurethane condom also has a good breaking elongation. The breaking elongation of the polyurethane condom may be 650% or more, for example, 720% or 750%. The condom's burst pressure may be 1 KPa or more, for example, 1.3 KPa or 1.4 KPa. The tensile strength of the polyurethane condom can be 20 MPa or more, for example, 30 MPa, 31 MPa, 32 MPa, or 33 MPa. As used herein, the polyurethane condom can be a male condom. It should be understood that the polyurethane condom can also be made into a female condom, other specially shaped condoms, etc. The present invention will now be described in more detail with reference to specific examples. [Example]

[0016] Example 1 4.73 kg of PTMEG 3000, 9.47 kg of PPG 3000, and 4.2 kg of polyoxypropylene triol with a molecular weight of 5000 were fed into a reactor. 2.92 kg of IPDI and 0.75 kg of HDI were added, and the mixture was heated to 80-120°C under stirring and maintained at this temperature for 1-3 hours. 0.72 kg of DMPA, 0.31 kg of DEG, 6.5 kg of acetone, and 0.04 kg of catalyst were added, and the mixture was reacted at 70-90°C for 2-6 hours. The temperature was then lowered, and triethylamine was added for neutralization, followed by water for high-speed dispersion and emulsification. 0.15 kg of isophoronediamine was then added for chain extension, and the solvent was removed under vacuum to obtain the desired aqueous polyurethane resin emulsion. The prepared polyurethane resin was measured to have a 100% tensile modulus of 1.69 MPa and an elongation at break of 811%. A glass molding die was cleaned, the surface of the die was heated to 30-40°C, and the die was dipped into the prepared polyurethane resin five times. After each dipping, it was dried at 140°C for 4 minutes to set the mold. One end was wound up, and then it was dried at 140°C for 10.8 minutes to form the mold. The die was then dipped into a release agent, dried at 80°C, and subjected to demolding, electrical testing, and interior and exterior finishing to obtain Sample 1. Sample 1 had a thickness of 0.032 mm, a 100% tensile modulus of 1.7 MPa, a burst volume of 18.9 L, an elongation at break of 805%, a burst pressure of 2.8 KPa, and a tensile strength of 33 MPa.

[0017] Example 2 A glass molding die was cleaned, the surface of the die was heated to 30-40°C, and the die was dipped four times into the polyurethane resin prepared in Example 1. After each dipping, the die was dried at 120°C for 6 minutes to set the mold. One end was wound up, and the die was dried at 120°C for 27 minutes to form the mold. The mold was then dipped in a release agent, dried at 80°C, and subjected to demolding, electrical testing, and interior and exterior packaging to obtain Sample 2. Sample 2 had a thickness of 0.038 mm, a 100% tensile modulus of 1.69 MPa, a burst volume of 19.5 L, an elongation at break of 812%, a burst pressure of 3.7 KPa, and a tensile strength of 32 MPa.

[0018] Example 3 A glass molding die was cleaned, the surface of the die was heated to 30-40°C, and the die was immersed three times in the polyurethane resin prepared in Example 1. After each immersion, the die was dried at 80°C for 10 minutes to set the mold. One end was wound up, and the mold was dried at 80°C for 63 minutes to form the mold. The mold was then immersed in a release agent, dried at 80°C, and subjected to demolding, electrical testing, and interior and exterior finishing to obtain Sample 3. Sample 3 had a thickness of 0.026 mm, a 100% tensile modulus of 1.67 MPa, a burst volume of 18.2 L, a breaking elongation of 801%, a burst pressure of 2.0 KPa, and a tensile strength of 30 MPa.

[0019] (Comparative Example 1) The preparation conditions for Comparative Example 1 were the same as those for Example 2, except that the duration of drying for forming Sample 2 in Example 2 was changed to 37 minutes to obtain Comparative Sample 1. Comparative Sample 1 had a product thickness of 0.038 mm, a 100% tensile modulus of 1.9 MPa, a burst volume of 15.4 L, an elongation at break of 721%, a burst pressure of 2 KPa, and a tensile strength of 25 MPa. (Comparative Example 2) The preparation conditions for Comparative Example 2 were the same as those for Example 2, except that the duration of drying for forming Sample 2 in Example 2 was changed to 32 minutes to obtain Comparative Sample 2. Comparative Sample 2 had a product thickness of 0.038 mm, a 100% tensile modulus of 1.79 MPa, a burst volume of 16.2 L, an elongation at break of 761%, a burst pressure of 2.4 KPa, and a tensile strength of 26.5 MPa.

[0020] (Comparative Example 3) The preparation conditions for Comparative Example 3 were the same as those for Example 2, except that the duration of drying for forming Sample 2 in Example 2 was changed to 22 minutes to obtain Comparative Sample 3. Comparative Sample 3 had a product thickness of 0.038 mm, a 100% tensile modulus of 1.54 MPa, a burst volume of 21.2 L, an elongation at break of 856%, a burst pressure of 2.6 KPa, and a tensile strength of 27.3 MPa. Comparative Example 4 The preparation conditions for Comparative Example 4 were the same as those for Example 2, except that the duration of drying for forming Sample 2 in Example 2 was changed to 17 minutes to obtain Comparative Sample 4. Comparative Sample 4 had a product thickness of 0.038 mm, a 100% tensile modulus of 1.3 MPa, a burst volume of 24 L, an elongation at break of 921%, a burst pressure of 1.6 KPa, and a tensile strength of 23.1 MPa.

[0021] Therefore, the present invention effectively overcomes various drawbacks of the prior art and is highly valuable in industrial applications. The above-described embodiments merely illustrate the principles and effects of the present invention and are not intended to limit the present invention. Those skilled in the art can modify or change the above embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or changes made by those skilled in the art without departing from the spirit and technical concept disclosed in the present invention are intended to be encompassed in the scope of the claims of the present invention. Preferred embodiments of the present invention are as follows. [1] A method for preparing a water-based polyurethane condom having a high burst volume, comprising: providing a water-based polyurethane; Repeating the process of immersing in aqueous polyurethane, then drying, immersing in aqueous polyurethane, then drying N times to obtain an aqueous polyurethane film; rolling up one end of the aqueous polyurethane film and then drying it; immersing in a releasing agent, followed by drying, demolding, and electrical testing to obtain a water-based polyurethane condom; At least N is equal to 1 to 5, the aqueous polyurethane is an anionic aqueous polyurethane, and the aqueous polyurethane has a 100% tensile modulus of elasticity of 2.0 MPa or less and an elongation at break of 650% or more. A method characterized by: [2] The drying after winding one end of the aqueous polyurethane film is drying for forming, and the drying after immersion in the aqueous polyurethane is drying for fixing, and the duration of the drying for fixing and the duration of the drying for forming are t 形成 =90·Φ-1.8·(N+2)·t 固定 (In the formula, t 形成 is the duration of drying for formation (min), and t 固定 is the duration of drying for fixation (minutes), N is the number of times the immersion is repeated, Φ=2.7-0.015·T, and T is the temperature (°C) of drying for fixation and drying for formation. [3] The method according to [2], characterized in that the duration of drying for fixation is 2 to 10 minutes, the duration of drying for formation is 10 to 65 minutes, and the duration of drying of the releasing agent is 2 to 30 minutes. [4] The method according to [2] above, characterized in that the drying temperature is 80 to 140°C. [5] The method according to [1] above, wherein the aqueous polyurethane has a solid content of 15 to 30%. [6] The method according to [1], wherein the polymer polyol accounts for 60 to 85% of the total solid raw material components of the aqueous polyurethane, and the proportion of the polymer polyol having three or more functional groups is 10 to 40% of the polymer polyol. [7] The method according to [6], characterized in that the polymer polyol consists of a bifunctional polymer polyol having a molecular mass of 500 to 4,000 and a trifunctional polymer polyol having a molecular mass of 650 to 6,000 in a mass ratio of 4:(0.2 to 1.5). [8] A water-based polyurethane condom having a high burst volume, prepared by the method according to any one of [1] to [7] above. [9] The aqueous polyurethane condom according to [8], characterized in that the thickness of the aqueous polyurethane condom is 0.02 mm to 0.06 mm.

[10] A water-based polyurethane condom having the following characteristics: 100% tensile modulus of elasticity of 2.0 MPa or less, Bursting volume of 12L or more, Burst pressure of 1KPa or more, Elongation at break of 650% or more, and Tensile strength of 20 MPa or more The aqueous polyurethane condom according to [8], characterized in that it has any one or more of the following:

Claims

1. 1. A method for preparing a water-based polyurethane condom having a high burst volume, comprising: providing a water-based polyurethane; Repeating the process of immersing in aqueous polyurethane, then drying, immersing in aqueous polyurethane, then drying N times to obtain an aqueous polyurethane film; rolling up one end of the aqueous polyurethane film and then drying it; immersing in a releasing agent, followed by drying, demolding, and electrical testing to obtain a water-based polyurethane condom; At least N is equal to 1 to 5, the aqueous polyurethane is an anionic aqueous polyurethane, and the aqueous polyurethane has a 100% tensile modulus of elasticity of 2.0 MPa or less and an elongation at break of 650% or more; drying after winding up one end of the aqueous polyurethane film is drying for forming, drying after immersion in the aqueous polyurethane is drying for fixing, and the duration of the drying for fixing and the duration of the drying for forming satisfy t forming = 90 Φ - 1.8 (N + 2) t fixing (wherein t forming is the duration of the drying for forming (minutes), t fixing is the duration of the drying for fixing (minutes), N is the number of repeated immersion cycles, Φ = 2.7 - 0.015 T, and T is the temperature (°C) of the drying for fixing and the drying for forming). A method characterized by:

2. 2. The method according to claim 1, wherein the duration of drying for fixation is 2 to 10 minutes, the duration of drying for formation is 10 to 65 minutes, and the duration of drying of the releasing agent is 2 to 30 minutes.

3. 2. The method according to claim 1, wherein the drying temperature is 80 to 140°C.

4. 2. The method of claim 1, wherein the aqueous polyurethane has a solids content of 15 to 30%.

5. The method according to claim 1, characterized in that, among the solid raw material components of the aqueous polyurethane, the polymer polyol accounts for 60 to 85% of the total solid raw material components, and the proportion of the polymer polyol having three or more functional groups is 10 to 40% of the polymer polyol.

6. 6. The method of claim 5, wherein the polymeric polyol is composed of a difunctional polymeric polyol having a molecular mass of 500 to 4,000 and a trifunctional polymeric polyol having a molecular mass of 650 to 6,000 in a weight ratio of 4:(0.2 to 1.5).

7. A water-based polyurethane condom having a high burst volume prepared by the method of any one of claims 1 to 6.

8. 8. The water-based polyurethane condom according to claim 7, wherein the thickness of the water-based polyurethane condom is 0.02 mm to 0.06 mm.

9. Water-based polyurethane condoms have the following properties: 100% tensile modulus of elasticity of 2.0 MPa or less, Bursting volume of 12L or more, Burst pressure of 1 KPa or more, Elongation at break of 650% or more, and Tensile strength of 20 MPa or more 8. The water-based polyurethane condom according to claim 7, characterized in that it comprises any one or more of the following:

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