Electrode assembly, manufacturing method and apparatus thereof, cylindrical battery including electrode assembly, battery pack including same, and automobile
The tab-less cylindrical battery design with ultrasonic cutting and bending techniques addresses high resistance and heat issues by forming a uniform folding surface, enhancing energy density and safety for electric vehicle applications.
Patent Information
- Application Number
- JP2023542620
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Priority Date
- 2022-08-26
- Filing Date
- 2022-11-24
- Publication Date
- 2026-01-16
- Estimated Expiration
- 2042-11-24
AI Technical Summary
Conventional cylindrical batteries experience high resistance and excessive heat generation due to current concentration at strip-shaped electrode tabs, posing a fire risk, especially when scaled for use in electric vehicles.
A tab-less cylindrical battery design with uncoated areas at the top and bottom of the jelly-roll type electrode assembly, where current collector plates are welded to these areas, and a method involving ultrasonic cutting and bending to form a uniform, flat folding surface, reducing resistance and improving electrolyte impregnation.
The solution enhances energy density, reduces resistance, and improves safety by minimizing irregular deformations, allowing for high-capacity battery packs suitable for vehicles with efficient energy use and fast charging.
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Abstract
Description
[Technical Field]
[0001] The present invention relates to an electrode assembly, a method and apparatus for manufacturing the same, a cylindrical battery including the electrode assembly, and a battery pack and automobile including the same.
[0002] This application claims priority based on Korean Patent Application No. 10-2021-0163807 filed on November 24, 2021, and Korean Patent Application No. 10-2022-0107707 filed on August 26, 2022, and the contents disclosed in the specifications and drawings of those applications are incorporated herein in their entirety. [Background technology]
[0003] Secondary batteries, which have high applicability to each product group and electrical properties such as high energy density, are widely used not only in portable devices but also in electric vehicles (EVs) and hybrid electric vehicles (HEVs) that are driven by electrical sources.
[0004] These secondary batteries not only have the primary advantage of dramatically reducing the use of fossil fuels, but are also environmentally friendly as they do not produce any by-products from energy use, and are attracting attention as a new energy source for improving energy efficiency.
[0005] Currently, secondary batteries such as lithium-ion batteries, lithium polymer batteries, nickel-cadmium batteries, nickel-metal hydride batteries, and nickel-zinc batteries are widely used. The operating voltage of such unit secondary batteries, i.e., unit batteries, is approximately 2.5V to 4.5V. Therefore, if a higher output voltage is required, a battery pack is constructed by connecting multiple batteries in series. Alternatively, a battery pack may be constructed by connecting multiple batteries in parallel depending on the required charge / discharge capacity of the battery pack. Therefore, the number of batteries included in the battery pack and the electrical connection configuration can be variously set depending on the required output voltage and / or charge / discharge capacity.
[0006] Meanwhile, known types of unit secondary batteries include cylindrical, prismatic, and pouch-type batteries. In cylindrical batteries, a separator, which is an insulator, is interposed between a positive electrode and a negative electrode, and the separator is wound up to form a jelly-roll-type electrode assembly. This assembly is then inserted into a battery housing to complete the battery. Strip-shaped electrode tabs are connected to the uncoated portions of the positive and negative electrodes, respectively, and the electrode tabs electrically connect the electrode assembly to the exposed electrode terminals. For reference, the positive electrode terminal is a sealing cap that seals the opening of the battery housing, and the negative electrode terminal is the battery housing. However, conventional cylindrical batteries with this structure suffer from problems such as high resistance, excessive heat generation, and poor current collection efficiency due to current concentration at the strip-shaped electrode tabs connected to the positive electrode uncoated portion and / or negative electrode uncoated portion.
[0007] Resistance and heat generation are not a major issue for small cylindrical batteries with form factors such as 1865 and 2170. However, when the form factor of a cylindrical battery is increased to be used in an electric vehicle, a large amount of heat is generated around the electrode tabs during the fast charging process, which can cause the cylindrical battery to catch fire.
[0008] To solve this problem, a cylindrical battery (so-called tab-less cylindrical battery) has been proposed, which has a structure in which positive and negative electrode uncoated areas are located at the top and bottom of a jelly-roll type electrode assembly, respectively, and current collector plates are welded to these uncoated areas to improve current collection efficiency.
[0009] Figures 1 to 3 show the manufacturing process of a tabless cylindrical battery. Figure 1 shows the structure of the electrode, Figure 2 shows the electrode winding process, and Figure 3 shows the process of welding a current collector plate to the bent surface of the uncoated portion.
[0010] 1 to 3, the positive electrode 10 and the negative electrode 11 have a structure in which an active material 21 is coated on a sheet-shaped current collector 20, and include a plain portion 22 on one long side along the winding direction X.
[0011] 2, the electrode assembly A is fabricated by sequentially stacking a positive electrode 10 and a negative electrode 11 together with two separators 12 and then winding them in one direction (X-axis direction). In this case, the uncoated portion of the positive electrode 10 and the uncoated portion of the negative electrode 11 are arranged in opposite directions based on the short side direction of the separator 12. The positions of the positive electrode 10 and the negative electrode 11 may be reversed from those shown in the figure.
[0012] After the winding process, the uncoated portion 10a of the positive electrode 10 and the uncoated portion 11a of the negative electrode 11 are bent toward the core. Thereafter, the current collector plates 30 and 31 are welded to the uncoated portions 10a and 11a, respectively.
[0013] No separate electrode tabs are attached to the positive electrode uncoated region 10a and the negative electrode uncoated region 11a, and current collector plates 30 and 31 are connected to external electrode terminals, forming a current path with a large cross-sectional area along the winding axis direction of electrode assembly A (see arrow), which has the advantage of reducing battery resistance, since resistance is inversely proportional to the cross-sectional area of the path through which current flows.
[0014] In a tabless cylindrical battery, in order to improve the welding characteristics between the uncoated portions 10a, 11a and the current collector plates 30, 31, strong pressure must be applied to the welding points of the uncoated portions 10a, 11a to bend the uncoated portions 10a, 11a as flat as possible.
[0015] When bending the uncoated portions 10a and 11a, a jig for pressing the uncoated portions 10a and 11a toward the core of the electrode assembly A is used.
[0016] Figure 4 is a magnified photograph of the bent shape of uncoated portions 10a and 11a, taken by cutting a portion of the bent portion in the longitudinal direction of electrode assembly A when uncoated portions 10a and 11b are bent radially toward the core using a jig.
[0017] 4, it can be seen that the uncoated portions 10a, 11a are not uniformly bent, and that the uncoated portions 10a, 11b are irregularly deformed during bending. In particular, the degree of deformation of the uncoated portions 10a, 11a increases toward the core of the electrode assembly A. This is because the uncoated portions 10a, 11a located closer to the core of the electrode assembly A are subjected to greater stress from the jig.
[0018] If the uncoated portions 10a, 11a are bent irregularly, the folded surface will not be flat, making it difficult to weld the current collector plates 30, 31. Furthermore, if the uncoated portions 10a, 11a are deformed irregularly below the folded surface, the stress caused by the irregular deformation of the uncoated portions 10a, 11a may affect the nearby separator, causing the separator to rupture or the active material layer to crack, potentially resulting in an internal short circuit. If an internal short circuit occurs, an overcurrent will flow, causing the cylindrical battery to rapidly increase in temperature, potentially resulting in a fire or explosion. Summary of the Invention [Problem to be solved by the invention]
[0019] The present invention has been made in light of the background of the prior art as described above, and aims to provide a method and apparatus for manufacturing an electrode assembly that can uniformly bend the non-coating portion of a tab-less cylindrical battery, and an electrode assembly manufactured by the method and apparatus.
[0020] Another object of the present invention is to provide a cylindrical battery including an electrode assembly manufactured by the improved method.
[0021] It is yet another object of the present invention to provide an electrode assembly having improved energy density, reduced resistance, and improved electrolyte impregnation.
[0022] It is yet another object of the present invention to provide a cylindrical battery including an electrode assembly of an improved structure, a battery pack including the same, and a vehicle including the battery pack.
[0023] The technical problems that the present invention aims to solve are not limited to the above-mentioned problems, and other problems will be clearly understood by those skilled in the art from the following description of the invention. [Means for solving the problem]
[0024] To achieve the above object, according to one aspect of the present invention, an electrode assembly includes a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode, wound around a single axis to define a core and an outer circumferential surface, wherein at least one of the positive electrode and the negative electrode includes an uncoated portion at a long side end that is exposed to the outside of the separator along an axial direction of the electrode assembly, and a wound turn portion of the uncoated portion is provided at one side end of the electrode assembly, the wound turn portion including cut portions and bent portions alternately arranged along a circumferential direction, the axial height of the cut portions being lower than the axial height of the bent portions, and the bent portion includes a plurality of uncoated portion flags arranged along a radial direction of the electrode assembly, and the plurality of uncoated portion flags overlap along the axial direction to form a folded surface region along the radial direction of the electrode assembly.
[0025] The cutting portion may include a first cutting surface that is substantially perpendicular to the axial direction, and the first cutting surface may be an ultrasonic cutting surface.
[0026] An insulating coating layer may be provided on a base end of the uncoated portion flag, an axial end of the insulating coating layer may be extended and exposed outside the axial end of the separator, and the first cut surface may be spaced apart from the axial end of the insulating coating layer.
[0027] When viewed in the axial direction, an axial end of the insulating coating layer and an axial end of the active material layer included in the positive electrode or the negative electrode may be exposed through the first cut surface.
[0028] The plurality of uncoated flags may protrude from the first cut surface along the axial direction.
[0029] The plurality of uncoated portion flags may be bent toward a core of the electrode assembly along a bend line spaced apart from the first cut surface to form a bent surface region.
[0030] The bend length of the uncoated flag closest to the core of the electrode assembly may be shorter than or equal to the distance from the position of the uncoated flag to the core.
[0031] The first cutting surface may be spaced apart from the folding surface region.
[0032] The folded portion may include a second cut surface extending along a side edge of the plurality of plain flags, and the second cut surface may be an ultrasonic cut surface.
[0033] The second cutting plane may be parallel to the axial direction.
[0034] The first cutting plane and the second cutting plane may intersect perpendicularly.
[0035] The second cut surface may be a flat surface.
[0036] The second cut surface may be a curved surface.
[0037] The eccentricity of the circular arc where the curved surface intersects with an imaginary plane perpendicular to the axial direction may be approximately 1.
[0038] The center of an imaginary circle including the arc and the core center of the electrode assembly may face each other with respect to the arc.
[0039] The arc may be substantially symmetrical with respect to a line connecting the center of an imaginary circle including the arc and the center of the core of the electrode assembly.
[0040] The plurality of uncoated flags may have substantially the same circumferential width from the core side to the outer circumferential surface side of the electrode assembly.
[0041] The width of the plurality of uncoated flags in the circumferential direction may gradually increase or decrease from the core side to the outer circumferential surface side of the electrode assembly.
[0042] The cut portions may include first to n-th cut portions, where n is a natural number from 2 to 9, and the first to n-th cut portions may extend radially from a core center of the electrode assembly.
[0043] The first to nth cut portions may be arranged rotationally symmetrically with respect to a core center of the electrode assembly.
[0044] The bent portions may include first to n-th bent portions, where n is a natural number from 2 to 9, and the first to n-th bent portions may extend radially from a core center of the electrode assembly.
[0045] The first to nth bent portions may be arranged rotationally symmetrically with respect to the core center of the electrode assembly.
[0046] The folded surface region may include a region in which three or more plain flags overlap along the axial direction.
[0047] To achieve the above object, a method for manufacturing an electrode assembly according to another aspect of the present invention includes the steps of: (a) preparing sheet-shaped positive and negative electrodes each having an uncoated portion at a long edge; (b) stacking the positive and negative electrodes at least once so that a separator is interposed between the positive and negative electrodes, thereby forming an electrode-separator laminate in which the uncoated portion of the positive electrode and the uncoated portion of the negative electrode are exposed on opposite sides of the short edge of the separator; and (c) winding the electrode-separator laminate around one axis to separate the wound turn portion of the uncoated portion of the positive electrode and the uncoated portion of the negative electrode. (d) forming an electrode assembly so that the wound turn portion of the uncoated portion of the positive electrode and the wound turn portion of the uncoated portion of the negative electrode are exposed on opposite sides in the axial direction; (d) cutting at least one of the wound turn portion of the uncoated portion of the positive electrode and the wound turn portion of the uncoated portion of the negative electrode, leaving at least one folding target area in a shape that protrudes along the axial direction, thereby forming a plurality of uncoated flags within the folding target area; and (e) bending the plurality of uncoated flags included in the folding target area along the radial direction of the electrode assembly to form a folding surface area.
[0048] Step (d) may include a first cutting step of cutting an edge of the bending target area along the axial direction of the electrode assembly, and a second cutting step of cutting a peripheral area of the bending target area perpendicular to the axial direction so that the bending target area remains in a protruding shape along the axial direction.
[0049] In the first cutting step, an edge of the bending target region may be cut using a vertical cutter that ultrasonically vibrates in an axial direction of the electrode assembly.
[0050] There are multiple cutting lines for the edge of the bending target area, and when viewed in the axial direction of the electrode assembly, the multiple cutting lines may extend radially from the core center of the electrode assembly, forming pairs of two.
[0051] The cutting lines for the edge of the bending target area may be multiple, and when viewed in the axial direction of the electrode assembly, each of the multiple cutting lines may be an arc curved toward the core center of the electrode assembly.
[0052] In the second cutting step, a horizontal cutter that ultrasonically vibrates perpendicular to the axial direction of the electrode assembly may be used to cut the peripheral area of the bending target area perpendicular to the axial direction so that the bending target area remains in a protruding shape along the axial direction.
[0053] In the second cutting step, a horizontal cutter rotating in a plane perpendicular to the axial direction of the electrode assembly may be used to cut the peripheral area of the bending target area perpendicular to the axial direction so that the bending target area remains in a shape that protrudes along the axial direction.
[0054] In the second cutting step, a horizontal cutter that rotates in a plane perpendicular to the axial direction of the electrode assembly and ultrasonically vibrates along the plane may be used to cut the peripheral area of the bending target area perpendicular to the axial direction so that the bending target area remains in a shape that protrudes along the axial direction.
[0055] In step (e), the plurality of plain flags may be folded along the axial direction so that an area where at least three plain flags overlap is included in the folded surface area.
[0056] In order to achieve the above object, according to yet another aspect of the present invention, an ultrasonic cutting device is an ultrasonic cutting device for cutting a wound turn portion of an uncoated portion exposed at one end of an electrode assembly in which a positive electrode and a negative electrode each having an uncoated portion at a long side end and a separator interposed between the positive electrode and the negative electrode are wound around a single axis, and may include: a vertical cutter that ultrasonically cuts edges of a plurality of folding target areas arranged along a circumferential direction of the electrode assembly in an axial direction to form a plurality of uncoated portion flags within the folding target areas; and a horizontal cutter that ultrasonically cuts peripheral areas of the plurality of folding target areas perpendicular to the axial direction to cause the plurality of uncoated portion flags to protrude from an ultrasonically cut surface along the axial direction.
[0057] The vertical cutter may include a cutter body and a plurality of cutter knives coupled to the cutter body, and the plurality of cutter knives may be arranged to correspond to the edges of the plurality of folding target areas.
[0058] The horizontal cutter includes a cutter body and a cutter knife coupled to the cutter body, the cutter knife being coupled to the cutter body so as to be positioned on a cutting plane perpendicular to the axial direction, and may have a shape corresponding to a winding turn region between adjacent bending target regions in the circumferential direction.
[0059] The winding turn region between adjacent folded surface regions in the circumferential direction includes a portion curved toward the core of the electrode assembly, and the cutter knife may be a disk-shaped rotary knife having a radius of curvature substantially the same as the radius of curvature of the curved portion.
[0060] To achieve the above object, according to yet another aspect of the present invention, there is provided a cylindrical battery comprising: (a) an electrode assembly in which a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode are wound around one axis to define a core and an outer circumferential surface, wherein at least one of the positive electrode and the negative electrode includes an uncoated portion at a long side end thereof that is exposed to the outside of the separator along the axial direction of the electrode assembly, and a wound turn portion of the uncoated portion at one side end of the electrode assembly, the wound turn portion including cut portions and bent portions alternately arranged along the circumferential direction, the axial height of the cut portions being lower than the axial height of the bent portions, and the bent portions being formed in a half of the electrode assembly; (b) an electrode assembly including a plurality of uncoated flags arranged in a radial direction, the plurality of uncoated flags overlapping in an axial direction to form a folded surface region along the radial direction of the electrode assembly; (b) a battery housing including an open end and a closed portion opposite the open end, the electrode assembly being housed through the open end and being electrically connected to the negative electrode; (c) a sealing body sealing the open end of the battery housing; (d) a terminal electrically connected to the positive electrode and having a surface exposed to the outside; and (e) a current collector plate welded to the folded surface region and electrically connected to either the battery housing or the terminal.
[0061] The terminal may be a rivet terminal inserted through a through hole formed in the closing portion of the battery housing, and an insulating gasket may be interposed between the rivet terminal and the through hole.
[0062] The rivet terminal may be welded to the current collector plate.
[0063] The current collecting plate may include a support portion having a hole, at least one leg portion extending radially from the support portion and welded to the bent surface region, a connection portion provided inside the hole, and a bridge portion connecting the support portion and the connection portion.
[0064] The cylindrical battery may further include a crimping portion formed by bending the open end of the battery housing toward the core, and the sealing body may include a cap covering the open end of the battery housing and a sealing gasket interposed between the cap and the open end, and the crimping portion may press the sealing gasket toward a periphery of the cap.
[0065] The cylindrical battery may further include a beading portion in a region adjacent to the open end of the battery housing, and at least a portion of a periphery of the current collector plate may be interposed between an inner surface of the beading portion and the sealing gasket and coupled to the inner surface of the beading portion.
[0066] At least a portion of the periphery of the current collector plate may be welded to the inner surface of the beading portion.
[0067] The current collecting plate may include a support portion, at least one leg portion extending radially from the support portion and welded to the bent surface region, and a housing connection portion extending from the support portion or the leg portion toward the beading portion and coupled to an inner surface of the beading portion.
[0068] The cap corresponds to the terminal, and the current collecting plate may include a support portion, at least one leg portion extending outward from the support portion and welded to the bent surface region, and a lead portion extending from the support portion or the leg portion and coupled to the cap.
[0069] The above object can also be achieved by a battery pack including a plurality of the above-described cylindrical batteries, and a vehicle including the battery pack. [Effects of the Invention]
[0070] According to one aspect of the present invention, a folding target region of the plain portion having a shape that protrudes in the axial direction of the electrode assembly is formed in a pattern that extends along the folding direction, and by folding the flag of the plain portion of the folding target region, the flatness of the plain portion relative to the folding surface can be improved and the phenomenon of the plain portion being folded irregularly below the folding surface can be mitigated.
[0071] According to one aspect of the present invention, by cutting a substantial portion of the wound turn portion of the uncoated portion in the peripheral region of the bending target region at the axial end of the electrode assembly, a path through which the electrolyte can quickly penetrate into the active material layer can be provided, thereby improving electrolyte impregnation.
[0072] In addition, according to one aspect of the present invention, the axial height of the electrode assembly can be reduced by cutting and bending the wound turn portion of the uncoated portion, thereby increasing the energy density of the cylindrical battery.
[0073] According to another aspect of the present invention, in the process of cutting the wound turn portion of the uncoated portion, a plurality of uncoated portion flags formed within the bending target area are bent along the radial direction of the electrode assembly to form a folded surface area where the uncoated portion flags are overlapped, and then a current collector plate is welded to the corresponding area, thereby reducing the resistance of the cylindrical battery.
[0074] In addition, according to one aspect of the present invention, an ultrasonic cutting device including a vertical cutter and a horizontal cutter is provided, which makes it possible to easily cut the winding turn portion of the uncoated portion so that the bending target area remains protruding in the axial direction of the electrode assembly.
[0075] In addition, according to one aspect of the present invention, a method is provided that allows the wound turn portion of the uncoated portion to be easily cut so that the bending target region remains protruding in the axial direction of the electrode assembly, thereby improving the productivity of the electrode assembly and reducing manufacturing costs.
[0076] In addition, according to one aspect of the present invention, a large-capacity battery pack manufactured using a cylindrical battery with high energy density and low resistance and a vehicle including the same are provided, thereby improving the safety of fast charging and the efficiency of energy use.
[0077] The present invention also provides various other effects, which will be described later with reference to the embodiments, but explanations of effects that can be easily inferred by ordinary skilled artisans will be omitted.
[0078] The following drawings attached to this specification illustrate preferred embodiments of the present invention and, together with the detailed description of the invention, serve to further understand the technical concepts of the present invention. Therefore, the present invention should not be interpreted as being limited to the matters described in the drawings. [Brief explanation of the drawings]
[0079] [Figure 1] 1 is a plan view showing the structure of an electrode used in manufacturing a conventional tabless cylindrical battery. [Figure 2] 1 is a diagram showing the electrode winding process of a conventional tabless cylindrical battery. [Figure 3] 10A and 10B are diagrams illustrating a process of welding a current collector plate to a bent surface of a non-coating portion in a conventional tabless cylindrical battery. [Figure 4] 1 is a photograph showing an enlarged view of a folded structure of a non-coating portion in a cross section of an electrode assembly according to a conventional technique; [Figure 5] FIG. 2 is a plan view showing the structure of an electrode according to an embodiment of the present invention. [Figure 6a] 1 is a cross-sectional view of a jelly-roll type electrode assembly in which electrodes according to an embodiment of the present invention are applied to positive and negative electrodes, taken along an axial direction (Y-axis). [Figure 6b] 1 is a partial perspective view showing an upper structure of an electrode assembly according to an embodiment of the present invention; [Figure 6c] 3 is a partial cross-sectional view of a bending target region of an electrode assembly according to an embodiment of the present invention, taken along an axial direction (Y-axis). [Figure 6d] 10 is a top view showing a cutting structure of a winding turn portion provided on an upper portion of an electrode assembly according to another embodiment of the present invention; FIG. [Figure 7] FIG. 10 is a plan view of a vertical cutter used to cut a wound turn portion along the axial direction (Y-axis) according to an embodiment of the present invention. [Figure 8] FIG. 10 is a cross-sectional view of a vertical cutter used to cut a wound turn portion along the axial direction (Y-axis) according to an embodiment of the present invention. [Figure 9] 1 is a diagram illustrating a configuration of an ultrasonic cutting device according to an embodiment of the present invention; [Figure 10] 10A-10C are plan views of vertical cutters according to various variations of the present invention. [Figure 11] 10A-10C are plan views of vertical cutters according to various variations of the present invention. [Figure 12] 10A-10C are plan views of vertical cutters according to various variations of the present invention. [Figure 13] FIG. 10 is a plan view of a horizontal cutter used to cut a wound turn portion perpendicular to the axial direction (Y-axis) according to an embodiment of the present invention. [Figure 14] FIG. 10 is a cross-sectional view of a horizontal cutter used to cut a wound turn portion perpendicular to the axial direction (Y-axis) according to an embodiment of the present invention. [Figure 15] FIG. 10 is a plan view of a horizontal cutter including a rotary knife according to another embodiment of the present invention. [Figure 16] 10 is a cross-sectional view of a horizontal cutter including a rotary knife according to another embodiment of the present invention. [Figure 17] 10 is a plan view illustrating a state after a cutting line is formed in a winding turn portion of an electrode assembly using a vertical cutter according to an embodiment of the present invention. FIG. [Figure 18] 10A and 10B are views illustrating a process of cutting a winding turn portion in a plane (XZ plane) perpendicular to the axial direction (Y axis) of an electrode assembly using a horizontal cutter according to an embodiment of the present invention. [Figure 19]10 is a plan view illustrating a state after a cutting line is formed in a winding turn portion of an electrode assembly using a vertical cutter according to another embodiment of the present invention. FIG. [Figure 20] 10A and 10B are views illustrating a process of cutting a winding turn portion in a plane (XZ plane) perpendicular to the axial direction (Y axis) of an electrode assembly using a horizontal cutter including a rotary knife according to an embodiment of the present invention. [Figure 21] 10 is a top view illustrating the layout of the folding target area after the winding turn portion is cut according to an embodiment of the present invention. FIG. [Figure 22] 10 is a top view illustrating the layout of the folding target area after the winding turn portion is cut according to an embodiment of the present invention. FIG. [Figure 23] 10 is a top view illustrating the layout of the folding target area after the winding turn portion is cut according to an embodiment of the present invention. FIG. [Figure 24] 10 is a top view illustrating the layout of the folding target area after the winding turn portion is cut according to an embodiment of the present invention. FIG. [Figure 25a] 1 is a cross-sectional view of a cylindrical battery according to an embodiment of the present invention taken along the axial direction (Y-axis). [Figure 25b] FIG. 2 is a plan view showing the structure of a first current collector plate according to an embodiment of the present invention. [Figure 25c] FIG. 4 is a plan view showing the structure of a second current collecting plate according to one embodiment of the present invention. [Figure 26a] 4 is a cross-sectional view of a cylindrical battery according to another embodiment of the present invention, taken along the axial direction (Y-axis). FIG. [Figure 26b] FIG. 10 is a plan view showing the structure of a first current collecting plate according to another embodiment of the present invention. [Figure 26c] FIG. 10 is a perspective view showing the structure of a second current collecting plate according to another embodiment of the present invention. [Figure 27] 1 is a diagram illustrating a schematic configuration of a battery pack according to an embodiment of the present invention; [Figure 28] 1 is a schematic diagram of a vehicle including a battery pack according to an embodiment of the present invention; DETAILED DESCRIPTION OF THE INVENTION
[0080] Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. Prior to this, the terms and words used in the specification and claims should not be construed as being limited to their ordinary and dictionary meanings, but should be construed as having meanings and concepts corresponding to the technical ideas of the present invention, in accordance with the principle that the inventors themselves can appropriately define the concepts of terms in order to best explain the invention.
[0081] Therefore, it should be understood that the embodiments described in this specification and the configurations shown in the drawings are merely the most desirable embodiments of the present invention and do not represent the entire technical idea of the present invention, and that there may be various equivalents and modifications that can be substituted therefor at the time of this application.
[0082] In addition, to facilitate understanding of the invention, the accompanying drawings may not be drawn to scale, and the dimensions of some components may be exaggerated. In addition, the same reference numerals may be used to refer to the same components in different embodiments.
[0083] Furthermore, although terms such as "first" and "second" are used to indicate various components, these terms are not intended to limit the components. These terms are used merely to distinguish one component from another, and unless otherwise specified, the first component can also be the second component.
[0084] Throughout the specification, unless otherwise stated, each element may be singular or plural.
[0085] Hereinafter, when an arbitrary configuration is placed "on (or under)" a component or "above (or below)" a component, it means not only that the arbitrary configuration is placed in contact with the upper surface (or lower surface) of the component, but also that other configurations may be interposed between the component and the arbitrary configuration placed above (or below) the component.
[0086] Furthermore, when a component is said to be "coupled," "coupled," or "connected" to another component, it does not only mean that the components are directly coupled or connected to each other, but also that other components are "intervening" between the components, or that each component is "coupled," "coupled," or "connected" through other components.
[0087] Furthermore, as used herein, singular expressions include plural expressions unless the context clearly indicates otherwise. In this application, terms such as "comprise" or "include" are not necessarily interpreted as including all of the components or steps described in the specification, and may mean that some of the components or steps may not be included, and that additional components or steps may also be included.
[0088] Throughout the specification, unless otherwise specified, "A and / or B" means A, B, or A and B, and "C to D" means C or more and D or less, unless otherwise specified.
[0089] For ease of explanation, in this specification, the direction along the longitudinal direction of the winding shaft of the electrode assembly wound into a jelly roll is referred to as the axial direction (Y-axis direction). The direction surrounding the winding shaft is referred to as the circumferential direction or outer circumferential direction (X-axis direction). The direction approaching or moving away from the winding shaft is referred to as the radial direction or radial direction (Z-axis direction). Of these, the direction approaching the winding shaft is particularly referred to as the centripetal direction, and the direction moving away from the winding shaft is particularly referred to as the centrifugal direction.
[0090] First, an electrode assembly according to an embodiment of the present invention will be described. The electrode assembly is a jelly-roll type electrode assembly having a structure in which a sheet-shaped positive electrode, a sheet-shaped negative electrode, and a separator interposed therebetween are wound in one direction.
[0091] Preferably, at least one of the positive electrode and the negative electrode includes a non-coated portion on a long edge in the winding direction where the active material is not coated, and at least a portion of the non-coated portion itself is used as an electrode tab.
[0092] FIG. 5 is a plan view showing the structure of an electrode 40 according to an embodiment of the present invention.
[0093] Referring to FIG. 5 , the electrode 40 includes a current collector 41 made of metal foil and an active material layer 42. The metal foil is made of a conductive metal. The metal foil may be aluminum or copper, and is appropriately selected depending on the polarity of the electrode 40. The active material layer 42 is formed on at least one surface of the current collector 41 and includes a plain portion 43 at the end of the long side in the winding direction X. The plain portion 43 is an area where no active material is coated. An insulating coating layer 44 may be formed at the boundary between the active material layer 42 and the plain portion 43. The insulating coating layer 44 is formed so that at least a portion of the insulating coating layer 44 overlaps the boundary between the active material layer 42 and the plain portion 43. The insulating coating layer 44 includes a polymer resin and may include an inorganic filler such as SiO2 or Al2O3. The polymer resin may have a porous structure. The polymer resin is not particularly limited as long as it is an insulating material. The polymer resin may be polyolefin, polyimide, polyethylene terephthalate, polybutylene fluoride, etc., but the present invention is not limited thereto.
[0094] Preferably, a portion of the uncoated portion 43 adjacent to the core side may be cut off through a notching process. In this case, even when the uncoated portion 43 is bent toward the core side, the core of the electrode assembly is not blocked by the bent portion of the uncoated portion 43. For reference, the core has a cavity created when the bobbin used in winding the electrode assembly is removed. The cavity can be used as a passage for injecting electrolyte or for inserting a welding jig. In the drawings, the dashed line indicates the lowest position at which the uncoated portion 43 can be bent. The uncoated portion 43 is bent at or above the dashed line.
[0095] When the electrode 40 is wound, the cut portion B of the uncoated portion 43 forms a plurality of winding turns in the radial direction. The plurality of winding turns have a predetermined width in the radial direction. Preferably, the width d of the cut portion B and the folding length h of the uncoated portion 43 can be adjusted so that the predetermined width is equal to or greater than the folding length h of the uncoated portion 43. This prevents the core of the electrode assembly from being blocked even when the uncoated portion 43 is folded.
[0096] When forming the cut portion B of the uncoated portion 43, it is preferable to provide a gap G between the cutting line and the insulating coating layer 44 to prevent damage to the active material layer 42 and / or the insulating coating layer 44. The gap G is preferably 0.2 mm to 4 mm. If the gap G is adjusted to fall within the above numerical range, it is possible to prevent damage to the active material layer 42 and / or the insulating coating layer 44 due to cutting tolerances when the uncoated portion 43 is cut.
[0097] In a specific example, when the electrode 40 is used to manufacture an electrode assembly for a cylindrical battery with a form factor of 4680, the width d of the cut portion B of the uncoated portion may be set to 180 mm to 350 mm depending on the diameter of the core of the electrode assembly.
[0098] On the other hand, when the core of the electrode assembly is not used in the electrolyte injection process, welding process, or the like, the cut portion B of the non-coating portion 43 does not need to be formed.
[0099] The electrode 40 of the above-described embodiment may be applied to the positive electrode and / or negative electrode included in a jelly roll-type electrode assembly. Furthermore, when the electrode structure of the embodiment is applied to either the positive electrode or the negative electrode, a conventional electrode structure (FIG. 1) may be applied to the other. Furthermore, the electrode structures applied to the positive electrode and the negative electrode do not have to be the same, and may be different.
[0100] In the present invention, the positive electrode active material coated on the positive electrode and the negative electrode active material coated on the negative electrode may be any active material known in the art without any limitation.
[0101] As an example, the positive electrode active material has the general chemical formula A[A x M y ]O 2+z (A includes at least one element of Li, Na, and K; M includes at least one element selected from Ni, Co, Mn, Ca, Mg, Al, Ti, Si, Fe, Mo, V, Zr, Zn, Cu, Al, Mo, Sc, Zr, Ru, and Cr; x≧0, 1≦x+y≦2, −0.1≦z≦2; and the stoichiometric coefficients x, y, and z are selected to maintain electroneutrality of the compound).
[0102] As another example, the positive electrode active material may be an alkali metal compound xLiM disclosed in U.S. Pat. No. 6,677,082, U.S. Pat. No. 6,680,143, etc. 1 O2-(1-x)Li2M 2 O3(M 1 contains at least one element having an average oxidation state of 3; M 2 contains at least one element having an average oxidation state of 4; 0≦x≦1).
[0103] In yet another example, the positive electrode active material may be a compound represented by the general chemical formula Li a M 1 x Fe 1-x M 2 y P 1-y M 3 z O 4-z (M 1 contains at least one element selected from Ti, Si, Mn, Co, Fe, V, Cr, Mo, Ni, Nd, Al, Mg and Al; M 2 contains at least one element selected from Ti, Si, Mn, Co, Fe, V, Cr, Mo, Ni, Nd, Al, Mg, Al, As, Sb, Si, Ge, V and S; M 3contains a halogen group element selectively containing F; 0 < a ≤ 2, 0 ≤ x ≤ 1, 0 ≤ y < 1, 0 ≤ z < 1; the stoichiometric coefficients a, x, y, and z are selected so that the compound maintains electrical neutrality), or can be a lithium metal phosphate represented by Li3M2(PO4)3 [M contains at least one element selected from Ti, Si, Mn, Fe, Co, V, Cr, Mo, Ni, Al, Mg, and Al].
[0104] Preferably, the positive electrode active material may contain primary particles and / or secondary particles formed by aggregation of primary particles.
[0105] As an example, as the negative electrode active material, a carbon material, a lithium metal or a lithium metal compound, silicon or a silicon compound, tin or a tin compound, etc. can be used. Metal oxides such as TiO2 and SnO2 with a potential of less than 2V can also be used as the negative electrode active material. As the carbon material, both low-crystalline carbon and high-crystalline carbon can be used.
[0106] As the separation membrane, a porous polymer film, for example, a porous polymer film made of a polyolefin-based polymer such as a polyethylene homopolymer, a polypropylene homopolymer, an ethylene / butene copolymer, an ethylene / hexene copolymer, an ethylene / methacrylate copolymer, etc., can be used alone or by laminating these. As another example, the separation membrane can use a normal porous non-woven fabric, for example, a non-woven fabric made of high-melting-point glass fibers, polyethylene terephthalate fibers, etc.
[0107] At least one surface of the separation membrane may include a coating layer of inorganic particles. Also, the separation membrane itself may consist of a coating layer of inorganic particles. The particles constituting the coating layer may have a structure bonded to a binder so that an interstitial volume exists between adjacent particles.
[0108] The inorganic particles can be made of an inorganic substance with a dielectric constant of 5 or more. As a non-limiting example, the inorganic particles are Pb(Zr,Ti)O3 (PZT), Pb1-x La x Zr 1-y Ti y O3(PLZT), PB(Mg3Nb 2 / 3 )O3-PbTiO3 (PMN-PT), BaTiO3, hafnia (HfO2), SrTiO3, TiO2, Al2O3, ZrO2, SnO2, CeO2, MgO, CaO, ZnO, and Y2O3.
[0109] The electrode 40 according to the embodiment of the present invention can be applied to the positive and negative electrodes of a jelly roll type electrode assembly.
[0110] FIG. 6a is a cross-sectional view of a jelly-roll type electrode assembly 50 in which an electrode 40 according to an embodiment of the present invention is applied to a positive electrode and a negative electrode, cut along the axial direction (Y-axis), FIG. 6b is a partial perspective view showing the upper structure of the electrode assembly 50, and FIG. 6c is a partial cross-sectional view of the axial direction (Y-axis) showing a state in which a plurality of plain portion flags 48c included in the folding target area of the electrode assembly 50 are folded along the radial direction (Z-axis).
[0111] Referring to Figure 6a, an electrode assembly 50 may be manufactured using the winding method described with reference to Figure 2. The uncoated portion 41 protruding upward from the electrode assembly 50 extends from the positive electrode 43. The uncoated portion 42 protruding downward from the electrode assembly 50 extends from the negative electrode 44.
[0112] The electrode assembly 50 has an upper portion provided with a wound turn portion 48 formed by bending the uncoated portion 41 of the positive electrode 43. Similarly, the electrode assembly 50 has a lower portion provided with a wound turn portion 49 formed by bending the uncoated portion 42 of the negative electrode 44. The wound turn portions 48 and 49 are exposed to the outside of the separator 45 along the axial direction (Y-axis).
[0113] The separator 45 is interposed between the positive electrode 43 and the negative electrode 44. The length of the active material coating region of the positive electrode 43 in the Y-axis direction may be shorter than the length of the active material coating region of the negative electrode 44 in the Y-axis direction. Therefore, the active material coating region of the negative electrode 44 may extend longer in the Y-axis direction than the active material coating region of the positive electrode 43.
[0114] Preferably, the insulating coating layer 47 formed at the boundary between the active material region and the uncoated portion of each of the positive electrode 43 and the negative electrode 44 may extend to or be exposed to the edge of the separator 45. When the insulating coating layer 47 is exposed to the outside of the separator 45, it can serve to support the bending points when the uncoated portions 41 and 42 are bent. Supporting the bending points reduces stress applied to the active material layer and the separator 45 when the uncoated portions 41 and 42 are bent. In addition, the insulating coating layer 47 can prevent the positive electrode 43 and the negative electrode 44 from coming into contact with each other, causing a short circuit.
[0115] The positive electrode 43 includes a current collector and an active material coating layer formed on at least one surface thereof, and the current collector (uncoated portion 41) may have a thickness of 180 μm to 220 μm. The negative electrode 44 includes a current collector and an active material coating layer formed on at least one surface thereof, and the current collector (uncoated portion 42) may have a thickness of 140 μm to 180 μm. The separator 45 is interposed between the positive electrode 43 and the negative electrode 44, and may have a thickness of 8 μm to 18 μm.
[0116] In the wound structure of the positive electrode 43, the spacing between uncoated portions 41 located on adjacent wound turns in the radial direction may be 350 μm to 380 μm. In the wound structure of the negative electrode 44, the spacing between uncoated portions 42 located on adjacent wound turns in the radial direction may be 350 μm to 380 μm.
[0117] In the electrode assembly 50, the number of winding turns of the positive electrode 43 varies depending on the form factor of the cylindrical battery, but may be 48 to 56. The number of winding turns of the negative electrode 44 also varies depending on the form factor of the cylindrical battery, but may be 48 to 56.
[0118] The uncoated portions 41 and 42 are longer than the uncoated portions applied to the design of a small cylindrical battery. Desirably, the uncoated portions 41 and 42 may be 6 mm or more, optionally 7 mm or more, optionally 8 mm or more, optionally 9 mm or more, optionally 10 mm or more, optionally 11 mm or more, or optionally 12 mm or more.
[0119] 6b, the wound turn portion 48 of the positive electrode 43 includes cut portions 48a and bent portions 48b arranged alternately along the circumferential direction (X-axis). The height of the cut portions 48a in the axial direction (Y-axis) is lower than the height of the bent portions 48b in the axial direction (Y-axis). The region near the core C of the electrode assembly 50 does not include the bent portions 48b. This is because the uncoated portion on the core side of the positive electrode 43 is low in height (see FIG. 5).
[0120] The bent portion 48b includes a plurality of uncoated flags 48c arranged along the radial direction (Z-axis) of the electrode assembly 50. The uncoated flags 48c have substantially the same circumferential width from the core side to the outer circumferential surface side of the electrode assembly 50. Alternatively, the uncoated flags 48c may have a circumferential width that gradually increases from the core side to the outer circumferential surface side of the electrode assembly 50. In this case, the bent portion 48b may have a substantially fan shape when viewed in the axial direction (Y-axis).
[0121] The cut portion 48a may include a first cut portion to an nth cut portion. The first cut portion to the nth cut portion may be arranged rotationally symmetrically with respect to the center of the core C of the electrode assembly 50. Similarly, the bent portion 48b may include a first bent portion to an nth bent portion. Furthermore, the first bent portion to the nth bent portion may be arranged rotationally symmetrically with respect to the center of the core C of the electrode assembly 50. Rotational symmetry refers to symmetry in which the structures match when the electrode assembly 50 is rotated by a predetermined angle along the winding direction.
[0122] In this embodiment, since the number of cut portions 48a and bent portions 48b is four, n is 4. In addition, the four cut portions 48a and the four bent portions 48b are each rotationally symmetrical by 90° with respect to the center of the core C of the electrode assembly 50.
[0123] Meanwhile, n can decrease or increase to 2, 3, 5, 6, 9, etc. Thus, the angle of rotational symmetry can be changed to 180°, 120°, 75°, 60°, 40°, etc. depending on the value of n.
[0124] Referring to FIG. 6c, multiple plain flags 48c can be folded along the radial direction (Z-axis) of the electrode assembly 50 while overlapping along the axial direction (Y-axis) to form a flat folded surface area F.
[0125] Even when the plurality of uncoated flags 48c are bent, they do not block the core C of the electrode assembly 50. Therefore, the bend length of the uncoated flag 48c that is closest to the core C may be shorter than or equal to the distance from the point where the uncoated flag 48c is located to the core C.
[0126] The folded surface region F can be used as a welding region for the current collector plate. The folded surface region F includes a region where the plain portion flags 48c are overlapped multiple times along the axial direction (Y axis) to achieve sufficient welding strength.
[0127] 6a and 6b, the cut portion 48a may include a first cut surface 51 that is substantially perpendicular to the axial direction (Y-axis). The first cut surface 51 may be an ultrasonic cut surface formed when the wound turn portion 48 provided on the upper part of the electrode assembly 50 is cut perpendicular to the axial direction (Y-axis) using an ultrasonic cutting device.
[0128] An insulating coating layer 47 is provided on the base end of each of the plurality of uncoated portion flags 48c, and an axial (Y-axis) end of the insulating coating layer 47 may extend and be exposed outside the axial (Y-axis) end of the separator 45. The first cut surface 51 may be spaced apart from the axial (Y-axis) end of the insulating coating layer 47 by a cutting tolerance. The axial (Y-axis) end of the insulating coating layer 47 and the axial end of the active material layer included in the anode 44 may be exposed through the first cut surface 51 when viewed from the axial (Y-axis) direction. Therefore, the electrolyte directly contacts the axial end of the active material layer included in the anode 44 and the axial (Y-axis) end of the insulating coating layer 47 through the first cut surface 51, thereby significantly improving impregnation (speed and uniformity).
[0129] 6c, the plurality of uncoated portion flags 48c may protrude upward along the axial direction (Y-axis) from the first cut surface 51. The plurality of uncoated portion flags 48c included in the bent portion 48b are bent toward the core C of the electrode assembly 50 along a bend line spaced apart from the first cut surface 51 to form a bent surface region F. The first cut surface 51 may be spaced apart from the bent surface region F in the axial direction (Y-axis) depending on the position of the bend line.
[0130] 6b, the bent portion 48b includes a second cut surface 52 extending along the side of each of the plurality of plain portion flags 48c. The second cut surface 52 may be an ultrasonic cut surface formed when the wound turn portion 48 provided on the upper portion of the electrode assembly 50 is cut in the axial direction using an ultrasonic cutting device. Therefore, the second cut surface 52 is parallel to the axial direction (Y-axis). The second cut surface 52 is also flat and perpendicular to the first cut surface 51.
[0131] In the present invention, the cutting structure of the wound turn portion 48 provided on the upper part of the electrode assembly 50 can be modified in various ways.
[0132] FIG. 6d is a top view showing another cutting structure of the winding turn portion 48 provided on the upper part of the electrode assembly 50. As shown in FIG.
[0133] 6d, the second cut surface 52 perpendicularly intersects with the first cut surface 51 and may have a curved shape. The configuration of an ultrasonic cutting device for forming the curved second cut surface 52 will be described later.
[0134] The arc R where the second cross section 52 intersects with an imaginary plane perpendicular to the axial direction (Y axis) arc The eccentricity of the arc R can be approximately 1. arc The core center O1 of the electrode assembly 50 and the center O2 of the imaginary circle R correspond to the arc of the imaginary circle R. arc In addition, the electrode assembly 50 may be opposed to the center O2 of the imaginary circle R by using a straight line connecting the core center O1 of the electrode assembly 50 and the center O2 of the imaginary circle R as a reference. arc may be approximately symmetrical.
[0135] When the second cut surface 52 is a curved surface, the circumferential width of the uncoated portion flag 48c gradually decreases from the core side toward the outer periphery of the electrode assembly 50. In this case, the expanded bent surface area F has the advantage of ensuring a wider welding area for the current collecting plate.
[0136] 6a to 6d can be applied in substantially the same manner to the winding turn portion 49 of the uncoated portion of the negative electrode 44 exposed at the bottom of the electrode assembly 50. Therefore, a description of the winding turn portion 49 of the uncoated portion of the negative electrode 44 will be omitted.
[0137] The structure of the wound turn portions 48, 49 provided at the upper and lower portions of the electrode assembly 50 may be formed by cutting the wound turn portions 48, 49 along the axial direction (Y-axis) of the electrode assembly 50 and then cutting them along the direction perpendicular to the axial direction (Y-axis) (Z-axis). Of course, the cutting order may be reversed.
[0138] Hereinafter, a cut in the axial direction (Y axis) will be referred to as a "vertical cut," and a cut in the axial direction (Y axis) and perpendicular direction (Z axis) will be referred to as a "horizontal cut."
[0139] 7 and 8 are diagrams showing the structure of a vertical cutter 60 used to vertically cut the winding turn portions 48 and 49 according to an embodiment of the present invention, where FIG. 7 is a plan view of the vertical cutter 60 and FIG. 8 is a cross-sectional view of the vertical cutter 60 taken along line A-A' in FIG.
[0140] 7 and 8, the vertical cutter 60 includes a cutter body 61 and a plurality of cutter knives 62. The cutter body 61 may have a plurality of grooves into which the cutter knives 62 are inserted and fixed. Preferably, the cutter body 61 may be coupled to a horn 64 of an ultrasonic cutting device. The ultrasonic cutting device will be described later.
[0141] Preferably, the cutter body 61 is made of a metal material such as an aluminum alloy, a titanium alloy, a carbon steel, etc. The cutter knife 62 is made of a metal material such as a carbon steel, an alloy iron, a high-speed steel, a cast alloy, a cermet, a cubic boron nitride, a ceramic, a diamond, etc.
[0142] The lower ends of the plurality of cutter knives 62 may be embedded in the cutter body 61. Alternatively, the lower ends of the cutter knives 62 may be inserted into grooves formed in the cutter body 61 and then welded to the cutter body 61.
[0143] Each of the cutter knives 62 extends outward from the center of the cutter body 61 and has a strip shape that stands vertically with respect to the surface of the cutter body 61 .
[0144] The plurality of cutter knives 62 can be arranged to correspond to the edges of the plurality of folding target areas (folding portions).
[0145] Preferably, the cutter knives 62 are arranged in pairs and extend in parallel from the center of the cutter body 61 outward. The area between the two cutter knives 62 extending in parallel corresponds to the folding target area (folded portion) of the winding turn portion.
[0146] The cutter knives 62 are arranged in pairs of two and extend radially from the center of the cutter body 61, and the angles between the pairs of cutter knives 62 may be substantially the same.
[0147] For example, the number of cutter knives 62 may be eight in total. In this case, pairs of radially extending cutter knives 62 form a 90° angle with each other. As will be described later, the manner in which pairs of cutter knives 62 extend radially may be modified in various ways.
[0148] The vertical cutter 60 ultrasonically cuts the edges of the plurality of circumferentially arranged folding target areas (folding portions) along the axial direction (Y-axis), thereby forming second cutting surfaces 52 parallel to the axial direction (Y-axis) along the edges of the plurality of folding target areas (folding portions), as shown in Fig. 6b, and thus defining a plurality of plain flags 48c within the folding target areas (folding portions).
[0149] The vertical cutter 60 may be included in an ultrasonic cutting device.
[0150] FIG. 9 is a diagram showing a schematic configuration of an ultrasonic cutting device 70 according to an embodiment of the present invention.
[0151] Referring to FIG. 9, an ultrasonic cutting device 70 according to an embodiment may include a converter 71, a booster 72, a horn 73, and a cutter 74.
[0152] The converter 71 generates ultrasonic vibrations. The converter 71 may include a ceramic vibrator for generating ultrasonic waves. The booster 72 amplifies the ultrasonic waves generated by the converter 71 and transmits them to the horn 73. The horn 73 transmits the ultrasonic vibrations amplified by the booster 72 to the cutter 74. Preferably, the cutter 74 may be the vertical cutter 60 described above. In this case, the lower part of the cutter body 61 of the vertical cutter 60 may be connected to the horn 73 by bolt / nut fastening, riveting, welding, or the like. When the horn 73 connected to the cutter 74 is moved in the axial direction (Y-axis) while in contact with the wound turn portions 48 and 49, the wound turn portions 48 and 49 are cut in the axial direction (Y-axis) by the ultrasonically vibrating cutter 74.
[0153] Although not shown, the ultrasonic cutting device 70 may further include a mechanical and / or electronic mechanism for linearly and / or rotationally moving the horn 73, a station where a workpiece is fixed, and / or a servo motor, a linear motor, and / or an air cylinder that supports the linearly and / or rotationally moving the horn 73; and / or a drive source thereof; and / or an electronic control device thereof.
[0154] The configuration of the converter 71, booster 72, and horn 73 of the ultrasonic cutting device 70 is well known in the art. It will be apparent to those skilled in the art that various components necessary for linear and / or rotational movement of the horn 73 may be further coupled to the ultrasonic cutting device 70.
[0155] Those skilled in the art will also appreciate that the structure of the vertical cutter 60 can be modified in a variety of ways.
[0156] 10-12 are plan views of vertical cutters 60a, 60b, 60c according to various variations of the present invention.
[0157] 10 to 12, the vertical cutter 60a may have a structure in which a pair of cutter knives 62 extend radially at an angle of 120° to each other, and the vertical cutter 60b may have a structure in which a pair of cutter knives 62 extend radially at an angle of 180° to each other.
[0158] In another modified embodiment, the vertical cutter 60c may include an arc-shaped cutter knife 62 concave toward the center of the cutter body 61. The arc-shaped cutter knife 62 corresponds to the arc of a circle with an eccentricity of 1. The arc-shaped cutter knife 62 may be point-symmetric, left-right symmetric, or up-down symmetric with respect to the center of the cutter body 61. Although the cutter knife 62 has an arc-shaped configuration, it has a structure that extends radially from the center of the cutter body 61. The number of arc-shaped cutter knives 62 is not limited to four and can be adjusted to two or three. In this case, it is desirable that the cutter knives 62 be arranged at equal intervals in the circumferential direction of the cutter body 61.
[0159] The cross-sectional structure of the cutter knife 62 included in the vertical cutters 60a, 60b, and 60c of various embodiments is substantially the same as that shown in Fig. 8 and can be used as the cutter 74 of the ultrasonic cutting device 70. In this case, the cutter body 61 can be coupled to the horn 73 of the ultrasonic cutting device 70.
[0160] Meanwhile, according to an embodiment of the present invention, the winding turn portions 48 and 49 provided at the upper and lower portions of the electrode assembly 50, respectively, are cut in the axial direction (Y-axis) by vertical cutters 60, 60a, 60b, and 60c, and then the peripheral area of the bending target area (bending portion) can be cut perpendicular to the axial direction (Y-axis) so that the bending target area (bending portion) remains in a shape protruding in the axial direction (Y-axis).
[0161] Desirably, the peripheral area of the folding target area may be cut by a horizontal cutter 80 .
[0162] FIG. 13 is a plan view showing an example of a horizontal cutter 80 according to an embodiment of the present invention, and FIG. 14 is a cross-sectional view taken along line BB' in FIG.
[0163] 13 and 14, the horizontal cutter 80 may include a cutter knife 81 and a cutter body 82. The horizontal cutter 80 may ultrasonically cut peripheral regions of a plurality of circumferentially spaced folding target regions perpendicular to the axial direction (Y-axis). When the peripheral regions are ultrasonically cut by the horizontal cutter 80, a plurality of plain portion flags 48c protrude from the first cutting surface 51 along the axial direction (Y-axis), as shown in FIG.
[0164] The cutter knife 81 may have a polygonal shape. Preferably, the polygonal shape may correspond to the pattern of the area where cutting is to be performed. That is, the cutter knife 81 may be coupled to the cutter body 82 so as to be positioned on a cutting plane perpendicular to the axial direction (Y-axis) of the electrode assembly 50, and may have a shape corresponding to the winding turn portion area between adjacent folding target areas (folded portions) in the circumferential direction.
[0165] As one example, if the pattern of the area where cutting is to be performed is a right triangle, the cutter knife 81 has a right triangle shape. As another example, if the pattern of the area where cutting is to be performed is an isosceles triangle in which the interior angle of the vertex opposite the hypotenuse is greater than 90° (e.g., 120°), the cutter knife 81 also has an obtuse isosceles triangle shape. As yet another example, if the pattern of the area where cutting is to be performed is an isosceles triangle in which the interior angle of the vertex opposite the hypotenuse is less than 90° (e.g., 60°), the cutter knife 81 also has an acute isosceles triangle shape. The lower part of the cutter knife 81 may be embedded in or welded to the cutter body 82, similar to the cutter knife 62 of the vertical cutter 60.
[0166] The cutter knife 81 of the horizontal cutter 80 can form a first cutting surface 51 that intersects perpendicularly with a flat second cutting surface 52 as shown in FIG. 6b.
[0167] FIG. 15 is a plan view showing an example of a horizontal cutter 90 according to another embodiment of the present invention, and FIG. 16 is a cross-sectional view taken along line CC' in FIG.
[0168] 15 and 16, the horizontal cutter 90 includes a disk-shaped rotary knife 91 and a cutter body 92. The rotary knife 91 is attached to a rotation mechanism 93 so as to be rotatable in one direction. The rotation shaft of the rotary knife 91 may be fastened to a bearing 94 of the rotation mechanism 93. The rotation mechanism 93 is coupled to a motor (not shown) to rotate the rotary knife 91.
[0169] The radius of the rotary knife 91 may be approximately the same as the radius of the imaginary circle R shown in Fig. 6d. Referring to Fig. 6d, the rotary knife 91 may form a first cutting surface 51 that intersects perpendicularly with a curved second cutting surface 52.
[0170] The horizontal cutters 80, 90 may be coupled to the horn 73 as the cutter 74 of the ultrasonic cutting device 70. The manner in which the horizontal cutters 80, 90 are coupled to the horn 73 is substantially the same as the manner in which the vertical cutter 60 is coupled to the horn 73.
[0171] The horizontal cutters 80, 90 approach the winding turn portions 48, 49 formed by the uncoated portions on a plane perpendicular to the axial direction (Y-axis) of the electrode assembly 50 and cut the winding turn portions 48, 49 using the shape of the cutter knife. The rotary knife 91 of the horizontal cutter 90 can be rotated at high speed to cut the winding turn portions 48, 49. Preferably, if the horizontal cutters 80, 90 are used as the cutter 74 of the ultrasonic cutting device 70, the winding turn portions 48, 49 can be cut by the ultrasonically vibrating cutter knives 81, 91.
[0172] The process of cutting the wound turn portions 48 and 49 by the vertical cutter (60 in FIG. 7) and the horizontal cutter (80 in FIG. 13) will now be described in detail.
[0173] FIG. 17 is a diagram illustrating a state after cutting lines 100 are formed on the wound turn portions 48, 49 of the electrode assembly 50 using a vertical cutter 60 according to an embodiment of the present invention.
[0174] Referring to Figure 17, first, while ultrasonically vibrating the vertical cutter 60, the cutter knife 62 is placed opposite the upper surface of the electrode assembly 50, and the vertical cutter 60 is moved along the axial direction (Y-axis) to cut the upper parts of the winding turn portions 48, 49 to a predetermined depth, thereby forming a cutting line 100 on the edge of the bending target area D.
[0175] The bending target area D corresponds to the area where the uncoated flag is bent along the radial direction of the electrode assembly 50 for welding to the current collector plate. The cutting line 100 corresponds to the area where the upper portions of the wound turn portions 48 and 49 are cut in the form of a score line.
[0176] Preferably, the cutting depth may be 2 mm to 10 mm. Taking into consideration cutting tolerance, the lowest point where the vertical cutting using the vertical cutter 60 ends may be located higher (as indicated by the arrow) than the end of the insulating coating layer 47 exposed to the outside of the separator 45, as shown in FIG. 6a.
[0177] FIG. 18 is a diagram illustrating a process of cutting the winding turn portions 48, 49 in a plane (XZ plane) perpendicular to the axial direction (Y axis) of the electrode assembly 50 using a horizontal cutter 80 according to an embodiment of the present invention.
[0178] Referring to Figure 18, after forming a cutting line 100 on the edge of the bending target area D, the horizontal cutter 80 is ultrasonically vibrated while the cutter knife 81 is moved toward the core of the electrode assembly 50 in the axial direction (Y axis) and vertical plane (XZ) of the electrode assembly 50, thereby cutting the winding turn portion located between adjacent bending target areas D in the circumferential direction.
[0179] Preferably, the position where the horizontal cut is made may be the lowest point where the vertical cut ended (the point indicated by the arrow in FIG. 6a) or a point above it. As the horizontal cutter 80 moves toward the center of the core C of the electrode assembly 50, the area overlapping with the cutter knife 81 (the hatched area) is cut, and as the cutter knife 81 moves to the edge of the folding target area D, all of the winding turn portions 48, 49 around the folding target area D are cut and removed. As a result, the folding target area D remains (remains) protruding above the first cutting surface 51 in the axial direction (Y-axis) of the electrode assembly 50.
[0180] Preferably, the bending target regions D may extend radially along the radial direction when viewed from the axial direction (Y-axis) of the electrode assembly 50 and be arranged at the same angle along the circumferential direction.
[0181] Preferably, the bending target area D may have a cross shape extending outward from the core center of the electrode assembly 50 when viewed in the axial direction (Y-axis) of the electrode assembly 50 .
[0182] Next, a process of cutting the winding turn portions 48 and 49 provided at the top and bottom of the electrode assembly 50 by the vertical cutter (60c in FIG. 12) and the horizontal cutter (90 in FIG. 15), respectively, will be described in detail.
[0183] FIG. 19 is a diagram illustrating a state after cutting lines 100 are formed on the wound turn portions 48, 49 of the electrode assembly 50 using a vertical cutter 60c according to an embodiment of the present invention.
[0184] 19, first, while ultrasonically vibrating the vertical cutter 60c, the cutter knife 62 is brought into opposition to the upper surface of the electrode assembly 50, and the vertical cutter 60c is moved in the axial direction (Y-axis) to cut the winding turn portions 48, 49 to a predetermined depth, thereby forming a cutting line 100 on the edge of the bending target region D. The cutting line 100 is an arc-shaped recessed toward the core center of the electrode assembly 50. The arc corresponds to the arc of a circle with an eccentricity of 1. The bending target region D is cross-shaped, but the edge is arc-shaped.
[0185] The bending target region D corresponds to a region where the uncoated flag is bent along the radial direction of the electrode assembly 50 for welding to the current collector plate. The cutting line 100 corresponds to a region where the wound turn portions 48, 49 are removed along the axial direction (Y-axis) of the electrode assembly 50. The cutting depth may preferably be 2 mm to 10 mm.
[0186] As shown in FIG. 6a, it is desirable that the lowest point where the vertical cutting using the vertical cutter 60c ends be located higher (as indicated by the arrow) than the end of the insulating coating layer 47 exposed to the outside of the separator 45, taking into account cutting tolerances.
[0187] FIG. 20 is a diagram showing a process of cutting the winding turn portion around the bent surface area (D) in a plane (XZ plane) perpendicular to the axial direction (Y axis) of the electrode assembly 50 using a horizontal cutter 90 including a rotary knife 91 according to an embodiment of the present invention.
[0188] 20, after forming an arc-shaped cutting line 100 at the edge of the bending target area D, the rotary knife 91 of the horizontal cutter 90 is ultrasonically vibrated while moving the rotary knife 91 toward the core of the electrode assembly 50 on a plane (XZ) perpendicular to the axial direction (Y axis) of the electrode assembly 50, thereby cutting the winding turn portion area outside the arc-shaped cutting line 100. In some cases, the rotary knife 91 of the horizontal cutter 90 may not be ultrasonically vibrated, but the winding turn portion may be cut by rotating the rotary knife 91 alone.
[0189] Preferably, the position where the horizontal cut is made may be the lowest point where the vertical cut ended (the point indicated by the arrow in FIG. 6a) or a point above it. As the horizontal cutter 90 moves toward the center of the core of the electrode assembly 50, the area overlapping with the rotary knife 91 (the hatched area) is cut, and when the rotary knife 91 moves to the edge of the folding target area D, all of the winding turns except for the folding target area D are cut and removed. As a result, the folding target area D remains protruding above the first cutting surface 51 in the axial direction (Y-axis) of the electrode assembly 50.
[0190] Desirably, the radius of curvature of the rotary knife 91 of the horizontal cutter 90 is approximately the same as or less than the radius of curvature of the cutting line 100. In the latter case, the rotary knife 91 may be moved linearly and rotationally in combination to cut the wound turn region outside the cutting line 100.
[0191] 21 to 24 are top views showing the arrangement of the folding target area D after the winding turn portions 48 and 49 are cut according to the embodiment of the present invention.
[0192] In the drawing, the bending target region D protrudes upward from the electrode assembly 50 from a first cut surface 51 perpendicular to the axial direction (Y-axis).
[0193] In each drawing, the cutter structure is shown on the cross-sectional structure of the electrode assembly 50. The bending target area D shown in Figures 21 to 23 can be formed by sequentially using a vertical cutter 60 and a horizontal cutter 80. And the bending target area D shown in Figure 24 can be formed by sequentially using a vertical cutter 60c and a horizontal cutter 90 including a rotary knife 91.
[0194] 5, the height of the uncoated portion near the core of the electrode assembly 50 is preferably lower than the height of the uncoated portion in other portions, so that the bending target region D may not be formed near the core.
[0195] According to another embodiment of the present invention, the folding target region D formed by cutting the wound turn portions 48, 49 of the electrode assembly 50 includes a plurality of uncoated flags 48c along the radial direction. The plurality of uncoated flags 48c can be folded in the radial direction of the electrode assembly 50, preferably from the outer periphery toward the core.
[0196] Preferably, the axial (Y-axis) height of the plain portion flags 48c can be adjusted within a range of 2 mm to 10 mm so that when the plain portion flags 48c are bent along the radial direction, at least three, at least four, at least five, at least six, at least seven, at least eight, at least nine, or at least ten flags can be stacked in the axial (Y-axis) direction of the electrode assembly 50, as shown in FIG. 6c.
[0197] The bending target region D protrudes from the first cut surface 51 in the axial direction (Y-axis) of the electrode assembly 50 and extends radially along the bending direction. The uncoated portion flags 48c included in the bending target region D have a narrow circumferential width. Therefore, when the uncoated portion flags 48c included in the bending target region D are bent radially along the electrode assembly 50, they are bent uniformly. Furthermore, as the uncoated portion flags 48c are stacked in multiple layers along the axial direction (Y-axis), the flatness of the bending surface region (F in FIG. 6c) is improved. Furthermore, welding a current collector plate to the flattened bending surface region F can increase the welding power, thereby significantly increasing the welding strength and improving the resistance characteristics of the welding interface.
[0198] The electrode assembly 50 according to the embodiment of the present invention is applicable to a jelly-roll type cylindrical battery.
[0199] Desirably, the cylindrical battery may be, for example, a cylindrical battery having a form factor ratio (defined as the diameter of a cylindrical battery divided by its height, i.e., the ratio of height (H) to diameter (Φ)) greater than about 0.4.
[0200] Here, form factor refers to a value indicating the diameter and height of a cylindrical battery. A cylindrical battery according to an embodiment of the present invention may be, for example, a 46110 battery, a 4875 battery, a 48110 battery, a 4880 battery, or a 4680 battery. In the form factor number, the first two digits indicate the cell diameter, and the remaining digits indicate the battery height.
[0201] When an electrode assembly having a tabless structure is applied to a cylindrical battery with a form factor ratio exceeding 0.4, the uncoated portion is susceptible to tearing due to the large radial stress applied when the uncoated portion is bent. Furthermore, when welding a current collector plate to the bent surface area of the uncoated portion, the number of overlapping layers of the uncoated portion must be increased to ensure sufficient weld strength and reduce resistance. These requirements can be met by the electrode and electrode assembly according to an embodiment (variant) of the present invention.
[0202] A battery according to one embodiment of the present invention may be a generally cylindrical battery having a diameter of about 46 mm, a height of about 110 mm, and a form factor ratio of 0.418.
[0203] Another embodiment of the battery may be a generally cylindrical battery having a diameter of about 48 mm, a height of about 75 mm, and a form factor ratio of 0.640.
[0204] In yet another embodiment, the battery may be a generally cylindrical battery having a diameter of about 48 mm, a height of about 110 mm, and a form factor ratio of 0.436.
[0205] In yet another embodiment, the battery may be a generally cylindrical battery having a diameter of about 48 mm, a height of about 80 mm, and a form factor ratio of 0.600.
[0206] In yet another embodiment, the battery may be a generally cylindrical battery having a diameter of about 46 mm, a height of about 80 mm, and a form factor ratio of 0.575.
[0207] Conventionally, batteries with a form factor ratio of approximately 0.4 or less have been used. For example, 1865 batteries and 2170 batteries have been used. 1865 batteries have a diameter of approximately 18 mm and a height of approximately 65 mm, resulting in a form factor ratio of 0.277. 2170 batteries have a diameter of approximately 21 mm and a height of approximately 70 mm, resulting in a form factor ratio of 0.300.
[0208] Hereinafter, a cylindrical battery according to an embodiment of the present invention will be described in detail.
[0209] FIG. 25a is a cross-sectional view of a cylindrical battery 190 according to one embodiment of the present invention cut along the axial direction (Y-axis).
[0210] 25a, a cylindrical battery 190 according to one embodiment of the present invention includes an electrode assembly 110 including a positive electrode, a separator, and a negative electrode, wound into a jelly roll shape, a battery housing 142 that houses the electrode assembly 110, and a seal 143 that seals the open end of the battery housing 142. The electrode assembly 110 has the structure of the above-described embodiment.
[0211] The battery housing 142 is a cylindrical container with an opening at the top. The battery housing 142 is made of a conductive metal material such as aluminum, steel, or stainless steel. The battery housing 142 accommodates the electrode assembly 10 in the internal space through the opening at the top, along with the electrolyte. A Ni coating layer may be formed on the outer and / or inner surfaces of the battery housing 142.
[0212] The electrolyte is A + B - where A +Li + , Na + , K. + or a combination thereof. - is F - , Cl - , Br - , I - , NO3 - , N(CN)2 - , BF4 - , ClO4 - , AlO4 - , AlCl4 - , PF6 - , SbF6 - , AsF6 - , BF2C2O4 - , BC4O8 - , (CF3)2PF4 - , (CF3)3PF3 - , (CF3)4PF2 - , (CF3)5PF - , (CF3)6P - , CF3SO3 - , C4F9SO3 - , CF3CF2SO3 - , (CF3SO2)2N - , (FSO2)2N - , CF3CF2(CF3)2CO - , (CF3SO2)2CH - , (SF5)3C - , (CF3SO2)3C - , CF3(CF2)7SO3 - , CF3CO2 - , CH3CO2 - , SCN - and (CF3CF2SO2)2N - The anion comprises one or more anions selected from the group consisting of:
[0213] The electrolyte may be dissolved in an organic solvent such as propylene carbonate (PC), ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), dipropyl carbonate (DPC), dimethyl sulfoxide, acetonitrile, dimethoxyethane, diethoxyethane, tetrahydrofuran, N-methyl-2-pyrrolidone (NMP), ethyl methyl carbonate (EMC), γ-butyrolactone, or a mixture thereof.
[0214] The electrode assembly 110 may have a jelly roll structure. As shown in FIG. 2, the electrode assembly 110 may be manufactured by winding an electrode-separator stack formed by sequentially stacking a lower separator, a positive electrode, an upper separator, and a negative electrode at least once around a winding center C.
[0215] A positive electrode uncoated portion 146a and a negative electrode uncoated portion 146b protrude from the top and bottom of the electrode assembly 110, respectively. The positive electrode uncoated portion 146a forms a wound turn portion 48 at the top of the electrode assembly 110, and the negative electrode uncoated portion 146b forms a wound turn portion 49 at the bottom of the electrode assembly 110. The wound turn portions 48, 49 include bent portions and cut portions that are alternately arranged along the circumferential direction. Embodiments of the bent portions and cut portions are as described above with reference to Figures 6b and 6d.
[0216] The sealing body 143 may include a cap 143a, an insulating sealing gasket 143b that provides airtightness between the cap 143a and the battery housing 142, and a connecting plate 143c that is electrically and mechanically coupled to the cap 143a.
[0217] The cap 143a is a part made of a conductive metal material and covers the upper opening of the battery housing 142. The cap 143a is electrically connected to the bent portion 48b of the positive electrode wound turn portion 48 and is electrically insulated from the battery housing 142 via a sealing gasket 143b. Therefore, the cap 143a can function as the positive electrode terminal of the cylindrical battery.
[0218] The cap 143a is placed on a beading portion 147 formed on the battery housing 142 and fixed by a crimping portion 148. A sealing gasket 143b may be interposed between the cap 143a and the crimping portion 148 to ensure airtightness of the battery housing 142 and to provide electrical insulation between the battery housing 142 and the cap 143a. The cap 143a may have a protrusion 143d formed to protrude upward from the center thereof.
[0219] The battery housing 142 is electrically connected to the bent portion of the negative electrode wound turn portion 49. Therefore, the battery housing 142 has the same polarity as the negative electrode.
[0220] The battery housing 142 has a beading portion 147 and a crimping portion 148 at its upper end. The beading portion 147 is formed by pressing in around the outer periphery of the battery housing 142. The beading portion 147 prevents the electrode assembly 110 housed inside the battery housing 142 from slipping out of the upper opening of the battery housing 142, and can also function as a support portion on which the sealing body 143 is placed.
[0221] The crimping portion 148 is formed on the upper portion of the beading portion 147. The crimping portion 148 is extended and bent to enclose the outer circumferential surface of the cap 143a disposed on the beading portion 147 and a part of the upper surface of the cap 143a.
[0222] The cylindrical battery 190 may further include a first current collector 144 and / or a second current collector 145 and / or an insulator 146 .
[0223] 25b and 25c are top views showing the structures of the first current collector plate 144 and the second current collector plate 145, respectively.
[0224] 25b and 25c, the first current collecting plate 144 is coupled to the upper part of the electrode assembly 110. The first current collecting plate 144 is made of a conductive metal material such as aluminum, copper, or nickel.
[0225] The first current collector plate 144 is welded to a welding target area of a bent surface area (F in FIG. 6c) formed by bending a plain flag included in the bent portion of the positive electrode winding turn portion 48.
[0226] Preferably, the welding target area may have an average stacked number of uncoated flags of 5 or more in the axial direction (Y-axis) of the electrode assembly 110. Also, the welding target area may have an average stacked thickness of uncoated flags of 50 μm or more.
[0227] The first current collector 144 may include a support 144a, a plurality of legs 144b extending outward from the support 144a, and a lead 149 extending outward from the support 144a between adjacent legs 144b. Unlike the illustration, the lead 149 may extend from any one of the legs 144b.
[0228] The support portion 144a is placed near the core of the electrode assembly 110, and the legs 144b can be welded to the welding target area of the bent surface region while being placed on the bent surface region.
[0229] A hole H1 is formed in the center of the support portion 144a. Electrolyte can be injected through the hole H1. The diameter of the hole H1 is at least 0.5 times the diameter of the cavity in the core of the electrode assembly 110. If the diameter of the hole H1 is smaller than the diameter of the cavity in the core, it is possible to prevent the electrodes and separator from being extruded through the cavity in the core when venting occurs in the cylindrical battery 190. Furthermore, if the diameter of the hole H1 is the same as or larger than the diameter of the cavity in the core, it is easy to insert a welding jig during the process of welding the second current collector plate 145 to the bottom of the battery housing 142, and electrolyte can be injected smoothly.
[0230] The lead portion 149 may extend above the electrode assembly 110 and be connected to the connection plate 143c or may be directly connected to the lower surface of the cap 143a. The connection plate 143c may be connected to the lower surface of the cap 143a. The connection of the lead portion 149 to other components may be performed by welding.
[0231] The folded surface area formed by folding the plain flag may be bonded to the first current collecting plate 144 by laser welding, which may be replaced by resistance welding, ultrasonic welding, or the like.
[0232] Referring to FIGS. 25a and 25c, a plate-shaped second current collector 145 may be coupled to the lower surface of the electrode assembly 110.
[0233] The second current collecting plate 145 may include a support portion 145a having a hole H2 formed therein, a plurality of legs 145b extending outward from the support portion 145a, a connection portion 145c provided inside the hole H2 and coupled to the bottom surface of the battery housing 142, and a bridge portion 145d connecting the connection portion 145c and the support portion 145a.
[0234] The second current collector 145 is made of a conductive metal material such as aluminum, copper, or nickel. The support 145a is placed near the core on the lower surface of the electrode assembly 110. The legs 145b are welded to welding target areas on the bent surface formed by bending the plain flag of the negative electrode winding turn portion 49. The connection portion 145c can be welded to the inner bottom surface of the battery housing 142.
[0235] The diameter of the connection portion 145c is larger than the diameter of the cavity in the core of the electrode assembly 110. The bridge portion 145d connects the inner surface of the hole H2 to the outer surface of the connection portion 145c. The bridge portion 145d acts to buffer vibrations and stresses when they are applied to the second current collecting plate 145. The width and thickness of the bridge portion 145d may be partially reduced. As a result, when an overcurrent flows through the bridge portion 145d, the bridge portion 145d melts and breaks, thereby interrupting the overcurrent.
[0236] Preferably, the welding target area may have an average stacked number of uncoated flags of 5 or more in the axial direction (Y-axis) of the electrode assembly 110. Also, the welding target area may have an average stacked thickness of uncoated flags of 50 μm or more.
[0237] 25b and 25c, the weld pattern W1 formed on the leg portion 144b of the first current collector plate 144 and the weld pattern W2 formed on the leg portion 145b of the second current collector plate 145 may extend radially from points spaced approximately the same distance from the core center of the electrode assembly 110. The radial length of the weld pattern W1 may be the same as or different from the radial length of the weld pattern W2. The weld patterns W1 and W2 may be continuous weld beads or discontinuous weld bead arrangements.
[0238] 25a, an insulator 146 may cover the first current collector 144. By covering the upper surface of the first current collector 144, the insulator 146 can prevent direct contact between the first current collector 144 and the inner peripheral surface of the battery housing 142.
[0239] The insulator 146 has a lead hole 151 through which the lead portion 149 extending upward from the first current collecting plate 144 is drawn out. The lead portion 149 is drawn out upward through the lead hole 151 and coupled to the lower surface of the connecting plate 143c or the lower surface of the cap 143a.
[0240] The peripheral region of the insulator 146 is interposed between the first current collecting plate 144 and the beading portion 147 to fix the combination of the electrode assembly 110 and the first current collecting plate 144. This limits the movement of the combination of the electrode assembly 110 and the first current collecting plate 144 in the axial direction (Y-axis), thereby improving the assembly stability of the cylindrical battery 190.
[0241] The insulator 146 may be made of an insulating polymer resin. As an example, the insulator 146 may be made of polyethylene, polypropylene, polyimide, or polybutylene terephthalate.
[0242] The battery housing 142 may further include a vent 152 formed on its bottom surface. The vent 152 corresponds to a region on the bottom surface of the battery housing 142 that is thinner than the surrounding region. The vent 152 is structurally weaker than the surrounding region. Therefore, if an abnormality occurs in the cylindrical battery 190 and the internal pressure increases above a certain level, the vent 152 may burst, causing gas generated inside the battery housing 142 to be released to the outside.
[0243] The vents 152 may be formed continuously or discontinuously in a circular pattern on the underside of the battery housing 142. In a variant, the vents 152 may be formed in a linear pattern or other patterns.
[0244] Since the diameter of the connection portion 145c of the second current collector plate 145 is larger than the diameter of the cavity in the core of the electrode assembly 110, when the venting portion 152 bursts and gas generated inside the battery housing 142 is discharged to the outside, it is possible to prevent the electrodes and separator near the core from being pushed out.
[0245] FIG. 26a is a cross-sectional view of a cylindrical battery 200 according to another embodiment of the present invention, taken along the axial direction (Y-axis).
[0246] Referring to FIG. 26a, a cylindrical battery 200 differs from the cylindrical battery 190 shown in FIG. 25a in that the structure of the electrode assembly is substantially the same, but other structures except for the electrode assembly have been changed.
[0247] Specifically, the cylindrical battery 200 includes a battery housing 171 having a terminal 172 extending therethrough. The terminal 172 may be a rivet terminal having the periphery of one end riveted to the inner surface of the closed portion of the battery housing 171. The terminal 172 is provided on the closed portion of the battery housing 171 (the upper surface in the drawing). The terminal 172 is riveted into a through-hole in the battery housing 171 with an insulating gasket 173 interposed therebetween. The terminal 172 is exposed to the outside in the direction opposite to the direction of gravity.
[0248] The terminal 172 includes a terminal exposure portion 172a and a terminal insertion portion 172b. The terminal exposure portion 172a is exposed to the outside of the closed portion of the battery housing 171. The terminal exposure portion 172a may be located approximately at the center of the closed portion of the battery housing 171. The maximum diameter of the terminal exposure portion 172a may be larger than the maximum diameter of the through-hole formed in the battery housing 171. The terminal insertion portion 172b may penetrate approximately the center of the closed portion of the battery housing 171 and be electrically connected to the bent portion of the positive electrode wound turn portion 48. The electrically connected portion is a bent surface area formed by bending the plain flag of the positive electrode wound turn portion 48. The terminal insertion portion 172b may be riveted to the inner surface of the closed portion of the battery housing 171. That is, the peripheral edge of the end of the terminal insertion portion 172b may be bent toward the inner surface of the battery housing 171 by being pressed by a caulking tool. The maximum diameter of the end of the terminal insertion portion 172b can be larger than the maximum diameter of the through hole of the battery housing 171.
[0249] The lower end surface of the terminal insertion portion 172b is substantially flat and can be welded to the first current collector plate 144' connected to the bent portion of the winding turn portion 48 of the positive electrode.
[0250] FIG. 26b is a top view showing the structure of a first current collector plate 144'. Referring to FIG. 26b, the first current collector plate 144' has substantially the same structure as the current collector plate 145 shown in FIG. 25c. That is, the first current collector plate 144' may include a support portion 144a' having a hole H3, a plurality of legs 144b' extending radially from the support portion 144a', a connection portion 144c' provided inside the hole H3, and a bridge portion 144d' connecting the support portion 144a' and the connection portion 144c'. The connection portion 144c' of the first current collector plate 144' may be welded to the flat lower end of the terminal insertion portion 172b of the terminal 172. The plurality of legs 144b' may be welded to a welding target area defined in a bent surface area of the winding turn portion 48 of the positive electrode.
[0251] 26a, an insulator 174 made of an insulating material may be interposed between the first current collecting plate 144' and the inner surface of the battery housing 171. The insulator 174 covers the upper portion of the first current collecting plate 144' and the upper peripheral edge portion of the electrode assembly 110. This prevents the first current collecting plate 144' from coming into contact with the inner surface of the battery housing 171 of the opposite polarity, causing a short circuit. Preferably, the terminal insertion portion 172b of the terminal 172 may penetrate the insulator 174 and be welded to the first current collecting plate 144'. The insulator 174 is made of an insulating polymer resin.
[0252] The insulating gasket 173 is interposed between the battery housing 171 and the terminal 172 to prevent electrical contact between the battery housing 171 and the terminal 172, which have opposite polarities. This allows the upper surface of the battery housing 171, which has a substantially flat shape, to function as the negative terminal of the cylindrical battery 200.
[0253] The insulating gasket 173 includes a gasket exposing portion 173a and a gasket inserting portion 173b. The gasket exposing portion 173a is interposed between the terminal exposing portion 172a of the terminal 172 and the battery housing 171. The gasket inserting portion 173b is interposed between the terminal inserting portion 172b of the terminal 172 and the battery housing 171. The gasket inserting portion 173b may be deformed when the terminal inserting portion 172b is riveted, thereby adhering closely to the inner surface of the battery housing 171. The insulating gasket 173 may be made of, for example, an insulating polymer resin.
[0254] The gasket exposing portion 173a of the insulating gasket 173 may be extended to cover the outer peripheral surface of the terminal exposing portion 172a of the terminal 172. When the insulating gasket 173 covers the outer peripheral surface of the terminal 172, it is possible to prevent a short circuit from occurring during the process of connecting an electrical connection part, such as a bus bar, to the upper surface of the battery housing 171 and / or the terminal 172. Although not shown, the gasket exposing portion 173a may be extended to cover not only the outer peripheral surface of the terminal exposing portion 172a but also a portion of the upper surface.
[0255] When the insulating gasket 173 is made of a polymer resin, the insulating gasket 173 may be joined to the battery housing 171 and the terminal 172 by heat sealing. In this case, the airtightness at the joining interface between the insulating gasket 173 and the terminal 172 and at the joining interface between the insulating gasket 173 and the battery housing 171 is strengthened. Meanwhile, when the gasket exposed portion 173a of the insulating gasket 173 extends to the upper surface of the terminal exposed portion 172a, the terminal 172 may be joined integrally with the insulating gasket 173 by insert injection.
[0256] On the upper surface of the battery housing 171 , a region 175 other than the region occupied by the terminal 172 and the insulating gasket 173 corresponds to an electrode terminal having a polarity opposite to that of the terminal 172 .
[0257] Figure 26c is a perspective view showing the structure of the second current collector 176. Referring to Figures 26a and 26c, the second current collector 176 is coupled to the lower part of the electrode assembly 110. The second current collector 176 is made of a conductive metal material such as aluminum, steel, copper, or nickel. The second current collector 176 may be coupled to a welding target area of a bent surface area formed on the winding turn portion 49 of the negative electrode by welding.
[0258] The second current collector 176 includes a support portion 176a and multiple legs 176b extending radially from the support portion 176a and welded to the welding target area. The support portion 176a includes a hole H4 in the center. Electrolyte can be injected through the hole H4. The diameter of the hole H4 is 0.5 times or more the diameter of the cavity in the core of the electrode assembly 110. The function of the hole H4 is substantially the same as the function of the hole H1 described above.
[0259] Preferably, at least a portion of the second current collector 176 may be electrically connected to the battery housing 171. As an example, at least a portion of the peripheral edge of the second current collector 176 may be fixed between the inner surface of the battery housing 171 and the sealing gasket 178b. To this end, the second current collector 176 includes a housing connection portion 176c. The housing connection portion 176c includes a connecting portion 176c2 that extends obliquely from the end of the leg portion 176b toward the lower surface of the beading portion 180, and a contact portion 176c1 that is disposed on the lower surface of the beading portion 180. Unlike the illustration, the connecting portion 176c2 may extend from the support portion 176a region between the leg portions 176b. The contact portion 176c1 may extend in an arc shape along the circumferential direction of the beading portion 180 to increase the contact area with the beading portion 180.
[0260] At least a portion of the peripheral edge of the second current collector 176, for example, the contact portion 176c1, can be fixed to the beading portion 180 by welding while being supported on the lower end surface of the beading portion 180 formed at the lower end of the battery housing 171. In a modified embodiment, at least a portion of the peripheral edge of the second current collector 176 can be directly welded to the inner wall surface of the battery housing 171.
[0261] Preferably, the second current collector 176 and a welding target area included in the folded surface area of the negative electrode winding turn portion 49 may be joined by laser welding. In this case, welding is performed in an area of the folded surface area where the average number of plain flags stacked in the axial direction (Y-axis) is 5 or more or the average thickness of the plain flags stacked is 25 μm or more. Laser welding may be substituted by resistance welding, ultrasonic welding, spot welding, etc.
[0262] Meanwhile, the weld pattern W1 formed on the leg 144b' of the first current collector 144' and the weld pattern W2 formed on the leg 176b of the second current collector 176 may extend radially from points spaced approximately the same distance from the core center of the electrode assembly 110. The radial length of the weld pattern W1 may be the same as or different from the radial length of the weld pattern W2. For example, the radial length of the weld pattern W1 is longer than the radial length of the weld pattern W2. This is because the second current collector 176 includes the connecting portion 176c2, and the leg 176b of the second current collector 176 is shorter than the leg 144b' of the first current collector 144'. At least one weld pattern W3 is also formed on the contact portion 176c1 of the second current collector 176. The weld pattern W3 may be linear or arc-shaped. The weld patterns W1, W2, W3 can be a continuous weld bead or an arrangement of discontinuous weld beads.
[0263] The sealing body 178 that seals the lower open end of the battery housing 171 includes a cap 178a and a sealing gasket 178b. The sealing gasket 178b electrically isolates the cap 178a from the battery housing 171. A crimping portion 181 secures the periphery of the cap 178a and the sealing gasket 178b together. The cap 178a is provided with a venting portion 179. The configuration of the venting portion 179 is substantially the same as in the above-described embodiment.
[0264] Preferably, the cap 178a is made of a conductive metal material. However, since a sealing gasket 178b is interposed between the cap 178a and the battery housing 171, the cap 178a does not have electrical polarity. The seal 178 seals the lower open end of the battery housing 171 and functions to release gas when the internal pressure of the battery 200 exceeds a critical value. The cap 178a may have a vent 179 in the peripheral region of the flat portion. The configuration of the vent 179 is substantially the same as in the above-described embodiment.
[0265] Preferably, the terminal 172 electrically connected to the bent portion of the positive electrode winding turn portion 48 through the first current collector 144' is used as the first electrode terminal. Furthermore, a portion 175 of the upper surface of the battery housing 171, excluding the terminal 172, electrically connected to the bent portion of the negative electrode winding turn portion 49 through the second current collector 176 is used as the second electrode terminal of opposite polarity to the first electrode terminal. When two electrode terminals are located on the upper portion of the cylindrical battery 200, electrical connection components such as bus bars can be disposed on only one side of the cylindrical battery 200. This simplifies the battery pack structure and improves energy density. Furthermore, the portion 175 used as the second electrode terminal has a substantially flat shape, ensuring a sufficient contact area for connecting electrical connection components such as bus bars. This allows the cylindrical battery 200 to reduce resistance at the contact points of electrical connection components to a desired level.
[0266] In the present invention, as shown in Figure 5, the height of the uncoated portion constituting the winding turn near the core is low. Therefore, even if the uncoated portion flag of the bending target area D is bent toward the center of the core C of the electrode assembly 110, the cavity 112 of the core C is not blocked but can be opened upward.
[0267] If the cavity 112 is not blocked, the electrolyte injection process can be performed without any problems, improving the efficiency of the electrolyte injection. In addition, a welding jig can be inserted through the cavity 112 to easily weld the current collector 145 to the bottom of the battery housing 142 or the current collector 144' to the terminal 172.
[0268] The cylindrical battery according to the above-described embodiment (variant) can be used to manufacture a battery pack.
[0269] FIG. 27 is a diagram schematically illustrating the configuration of a battery pack according to one embodiment of the present invention.
[0270] 27, a battery pack 300 according to one embodiment of the present invention includes an assembly of electrically connected cylindrical batteries 301 and a pack housing 302 that accommodates the assembly. The cylindrical batteries 301 may be any one of the batteries according to the above-described embodiments (variants). For convenience of illustration, components such as bus bars for electrical connection of the cylindrical batteries 301, a cooling unit, and external terminals are not shown.
[0271] The battery pack 300 may be installed in a vehicle. The vehicle may be, for example, an electric vehicle, a hybrid vehicle, or a plug-in hybrid vehicle. The vehicle may be a four-wheeled vehicle or a two-wheeled vehicle.
[0272] FIG. 28 is a diagram illustrating a vehicle including the battery pack 300 of FIG.
[0273] 28, an automobile V according to an embodiment of the present invention includes a battery pack 300 according to an embodiment of the present invention. The automobile V operates by receiving a supply of power from the battery pack 300 according to an embodiment of the present invention.
[0274] According to one aspect of the present invention, a folding target region of the plain portion having a shape that protrudes in the axial direction of the electrode assembly is formed in a pattern that extends along the folding direction, and by folding the flag of the plain portion of the folding target region, the flatness of the plain portion relative to the folding surface can be improved and the phenomenon of the plain portion being folded irregularly below the folding surface can be mitigated.
[0275] According to one aspect of the present invention, by cutting a substantial portion of the wound turn portion of the uncoated portion in the peripheral region of the bending target region at the axial end of the electrode assembly, a path through which the electrolyte can quickly penetrate into the active material layer can be provided, thereby improving electrolyte impregnation.
[0276] In addition, according to one aspect of the present invention, the axial height of the electrode assembly can be reduced by cutting and bending the wound turn portion of the uncoated portion, thereby increasing the energy density of the cylindrical battery.
[0277] According to another aspect of the present invention, in the process of cutting the wound turn portion of the uncoated portion, a plurality of uncoated portion flags formed within the bending target area are bent along the radial direction of the electrode assembly to form a folded surface area where the uncoated portion flags are overlapped, and then a current collector plate is welded to the corresponding area, thereby reducing the resistance of the cylindrical battery.
[0278] In addition, according to one aspect of the present invention, an ultrasonic cutting device including a vertical cutter and a horizontal cutter is provided, which makes it possible to easily cut the winding turn portion of the uncoated portion so that the bending target area remains protruding in the axial direction of the electrode assembly.
[0279] In addition, according to one aspect of the present invention, a method is provided that allows the wound turn portion of the uncoated portion to be easily cut so that the bending target region remains protruding in the axial direction of the electrode assembly, thereby improving the productivity of the electrode assembly and reducing manufacturing costs.
[0280] In addition, according to one aspect of the present invention, a large-capacity battery pack manufactured using a cylindrical battery with high energy density and low resistance and a vehicle including the same are provided, thereby improving the safety of fast charging and the efficiency of energy use.
[0281] As described above, the present invention has been described using limited embodiments and drawings, but the present invention is not limited thereto, and it goes without saying that various modifications and variations can be made by a person having ordinary knowledge in the technical field to which the present invention pertains within the technical spirit of the present invention and the equivalent scope of the claims. [Explanation of symbols]
[0282] 10 Electrode assembly, positive electrode 11 Negative electrode 12 Separation membrane 20 Current collector 21 Active material 22 Plain area 30 Current collector plate 31 Current collector plate 40 electrodes 41 Current collector, plain part 42 Plain area, active material layer 43 Plain area 43 Positive electrode 44 Negative electrode, insulating coating layer 45 Separation membrane 47 Insulation coating layer 48 Winding turn section 49 Winding turn section 50 electrode assembly 51 1st cutting plane 52 2nd cutting plane 60 Vertical cutter 61 Cutter body 62 Cutter knife 64 Horn 70 Ultrasonic cutting device 71 Converter 72 Booster 73 Horn 74 Cutter 80 Horizontal cutter 81 Cutter knife 82 Cutter body 90 Horizontal cutter 91 Rotating Knife 91 Cutter knife 92 Cutter body 93 Rotation mechanism 94 bearings 100 Arc cutting line 110 Electrode assembly 112 Cavity 142 Battery Housing 143 Sealed body 144 First current collector plate 145 Second current collector plate 146 Insulators 147 Beading section 148 Crimping section 149 Lead section 151 Lead hole 152 Venting section 171 Battery housing 172 terminals 173 Insulating gasket 174 Insulators 176 Second current collector 178 Sealed body 179 Venting Section 180 Beading section 181 Crimping section 190 Cylindrical Battery 200 Cylindrical Battery 300 battery pack 301 Cylindrical Battery 302 Pack Housing 4680 form factor
Claims
1. An electrode assembly in which a positive electrode, a negative electrode, and a separator interposed between the positive electrode and the negative electrode are wound around a single axis to define a core and an outer circumferential surface, At least one of the positive electrode and the negative electrode includes a non-coating portion at a long side end portion thereof, the non-coating portion being exposed to the outside of the separator along the axial direction of the electrode assembly; a winding turn portion of the non-coating portion is provided at one end of the electrode assembly; the winding turn portion includes a plurality of cut portions and a plurality of bent portions alternately arranged along a circumferential direction in an outer peripheral region of the electrode assembly, an axial height of the plurality of cut portions being lower than an axial height of the plurality of bent portions; Each of the plurality of bent portions includes a plurality of uncoated flags arranged along a radial direction of the electrode assembly, The plurality of uncoated flags overlap each other in an axial direction to form a folded surface region in a radial direction of the electrode assembly, The plurality of bent portions have the same polarity. an electrode assembly; a battery housing including an open end and a closed portion opposite the open end, the electrode assembly being housed through the open end and electrically connected to the negative electrode; a seal sealing the open end of the battery housing; a terminal electrically connected to the positive electrode, riveted to the through-hole of the closing portion, and having an exposed surface; an insulating gasket interposed between the terminal and the through hole; a current collecting plate welded to a lower end of the terminal exposed to the electrode assembly side through the closing portion; Including, a portion of the current collecting plate corresponding to the bent surface area is welded to the bent surface area; a portion of the uncoated portion forming the winding turn portion near the core is shorter in height than the uncoated portion flags forming the plurality of folds so that the core is opened.
2. The cylindrical battery according to claim 1 , wherein the cut portion includes a first cut surface that is substantially perpendicular to the axial direction.
3. The base end of the plain flag is provided with an insulating coating layer, an axial end portion of the insulating coating layer is extended and exposed outside the axial end portion of the separator; The cylindrical battery according to claim 2 , wherein the first cut surface is spaced apart from an axial end of the insulating coating layer.
4. 4. The cylindrical battery according to claim 3, wherein, when viewed in the axial direction, an axial end of the insulating coating layer and an axial end of the active material layer included in the positive electrode or the negative electrode are exposed through the first cut surface.
5. The cylindrical battery according to claim 2 , wherein the plurality of plain flags protrude from the first cut surface along the axial direction.
6. 6. The cylindrical battery according to claim 5, wherein the plurality of uncoated flags are bent toward the core of the electrode assembly along a bend line spaced apart from the first cut surface to form a bent surface region.
7. The cylindrical battery according to claim 6, wherein a bent length of the uncoated flag closest to the core of the electrode assembly is shorter than or equal to a distance from the position of the uncoated flag to the core.
8. The cylindrical battery according to claim 6 , wherein the first cut surface is spaced apart from the folded surface region.
9. The cylindrical battery according to any one of claims 2 to 8, wherein the bent portion includes a second cut surface extending along a side edge of the plurality of plain flags.
10. The cylindrical battery according to claim 9 , wherein the second cutting plane is parallel to the axial direction.
11. The cylindrical battery according to claim 9 , wherein the first cut surface and the second cut surface intersect perpendicularly with each other.
12. The cylindrical battery of claim 9 , wherein the second cut surface is a plane.
13. The cylindrical battery according to claim 9 , wherein the second cut surface is a curved surface.
14. 14. The cylindrical battery according to claim 13, wherein the center of an imaginary circle including an arc where an imaginary plane perpendicular to the axial direction and the curved surface intersect is opposite to the core center of the electrode assembly with respect to the arc.
15. 14. The cylindrical battery according to claim 13, wherein the arc is substantially symmetrical with respect to a line connecting a center of an imaginary circle including an arc where an imaginary plane perpendicular to the axial direction and the curved surface intersect with each other and a core center of the electrode assembly.
16. The cylindrical battery according to claim 1 , wherein the plurality of uncoated flags have substantially the same circumferential width from the core side to the outer circumferential surface side of the electrode assembly.
17. The cylindrical battery according to claim 1 , wherein the width of the plurality of uncoated flags in the circumferential direction gradually increases or decreases from a core side to an outer circumferential side of the electrode assembly.
18. the cut portions include a first cut portion to an n-th cut portion, where n is a natural number from 2 to 9; The cylindrical battery of claim 1, wherein the first to nth cut portions extend radially from a core center of the electrode assembly.
19. The cylindrical battery of claim 18, wherein the first to nth cut portions are arranged rotationally symmetrically with respect to the core center of the electrode assembly.
20. The bent portions include a first bent portion to an nth bent portion, where n is a natural number from 2 to 9; The cylindrical battery of claim 1, wherein the first to nth bent portions extend radially from a core center of the electrode assembly.
21. The cylindrical battery of claim 20, wherein the first to nth bent portions are arranged rotationally symmetrically with respect to the center of the core of the electrode assembly.
22. The cylindrical battery according to claim 1 , wherein the folded surface region includes a region where three or more plain flags overlap along the axial direction.
23. (a) preparing sheet-like positive and negative electrodes each having a plain portion on a long edge; (b) stacking the positive electrode, the negative electrode, and the separator at least once so that a separator is interposed between the positive electrode and the negative electrode, and forming an electrode-separator laminate so that an uncoated portion of the positive electrode and an uncoated portion of the negative electrode are exposed on opposite sides of the separator in a short side direction; (c) winding the electrode-separator laminate around one axis to form an electrode assembly such that the wound turn portion of the uncoated portion of the positive electrode and the wound turn portion of the uncoated portion of the negative electrode are exposed on opposite sides in the axial direction; (d) cutting at least one of the wound turn portion of the uncoated portion of the positive electrode and the wound turn portion of the uncoated portion of the negative electrode, and arranging a plurality of cut portions and a plurality of bent portions alternately in a circumferential direction in an outer peripheral region of the electrode assembly, thereby forming a plurality of uncoated portion flags in each of the bent portions; (e) bending the plurality of uncoated portion flags included in each of the plurality of bent portions along a radial direction of the electrode assembly to form a bent surface region; (f) placing a current collector plate on the bent surface area and welding a portion of the current collector plate corresponding to the bent surface area to the bent surface area; (g) providing a battery housing including an open end and a closure portion opposite said open end; (h) forming a through hole in the closing portion, and riveting a terminal into the through hole with an insulating gasket interposed therebetween; (i) inserting an electrode assembly into the battery housing through the open end of the battery housing so that the current collector plate faces the terminal; (j) welding the current collecting plate to the lower end of the terminal exposed on the electrode assembly side; Including, a portion of the uncoated region of the positive electrode or the uncoated region of the negative electrode that forms the wound turn portion near the core of the electrode assembly in step (b) is lower in height than other portions of the uncoated region that form the plurality of bent portions so that the core is opened; and in step (i), the current collecting plate is welded to a lower end of the terminal through the core.
24. In the step (e), 24. The method for manufacturing a cylindrical battery according to claim 23, wherein the plurality of plain flags are folded so that an area where at least three plain flags overlap along the axial direction is included in the folded surface area.
25. A battery pack comprising the cylindrical battery of claim 1.
26. 26. A motor vehicle comprising the battery pack of claim 25.
Citation Information
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