Moisture-crosslinkable compositions based on silylated polymers

Abstract

The present invention provides - at least one polymer (A) containing at least one alkoxysilane group; - at least 25% by weight, relative to the total weight of the composition, of at least one carbonate filler (B); - at least one compound selected from bis(alkoxysilanes) or tri(alkoxysilanes) (C) having a molar mass in the range from 250 to 1000 g / mol; - at least one cross-linking catalyst (D) and a plasticizer content of 1% by weight or less relative to the total weight of the composition.

Description

[Technical Field]

[0001] The present invention relates to moisture crosslinkable compositions based on silylated polymers.

[0002] The present invention also relates to the use of said composition as an adhesive, coating or sealant. [Background technology]

[0003] In the automotive field, adhesive compositions are widely used, whether for the attachment of movable panels such as doors, hoods, etc., or for the attachment of windshields.

[0004] The adhesive used on the windscreen must fulfill several functions: it must not only have sufficient adhesion to the seal / windscreen interface, but also good impermeability to external conditions (water, temperature, humidity, etc.).

[0005] Silane-modified polymers ("SMPs") are widely used in the adhesive field. However, these adhesives can have the drawback of producing adhesive seals that lose their adhesive properties under severe climatic conditions. Summary of the Invention

[0006] Therefore, there is a need for new compositions that produce adhesive seals that exhibit a balance of good adhesion and good aging resistance, especially under severe temperature and humidity conditions. DETAILED DESCRIPTION OF THE INVENTION

[0007] composition The present invention provides - at least one polymer (A) containing at least one alkoxysilane group; - at least 25% by weight, relative to the total weight of the composition, of at least one carbonate filler (B); - at least one compound selected from bis(alkoxysilanes) or tri(alkoxysilanes) (C) having a molar mass in the range from 250 to 1000 g / mol; - at least one cross-linking catalyst (D) and a plasticizer content of 1% by weight or less relative to the total weight of the composition.

[0008] Preferably, the plasticizer content is less than or equal to 0.5%, preferentially less than or equal to 0.1% and even more preferentially the plasticizer content is equal to zero.

[0009] Plasticizers are a class of compounds well known to those skilled in the art, especially in the field of adhesive, coating or sealant compositions. Mention may be made, inter alia, of phthalates such as dibutyl, diisononyl or diisodecyl phthalate; diisononyl 1,2-cyclohexanedicarboxylate (Hexamoll DINCH available from BASF); unsaturated fatty acid esters (e.g., butyl oleate); alkyl sulfonic acid esters (such as Mesamoll from Lanxess); phosphate compounds; trimellitate compounds; hydrocarbon oils; epoxy plasticizers, etc.

[0010] It has been found in practice that the composition that is the subject of the present invention advantageously makes it possible, after crosslinking, to obtain adhesive seals that have good mechanical properties and good resistance to aging, especially under severe temperature and humidity conditions.

[0011] Polymer (A) containing at least one alkoxysilane group According to one embodiment, the polymer (A) comprising at least one alkoxysilane group comprises at least one, preferably at least two groups of formula (I): TIFF0007824874000001.tif10170[In the formula, -R 4 represents a linear or branched alkyl group containing 1 to 4 carbon atoms or an alkoxy group containing 1 to 4 carbon atoms; -R5 is a linear or branched alkyl group containing 1 to 4 carbon atoms or a group -N=C(R i )R j where: -R i is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2 represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R j is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2 represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R i and R j are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, preferably 4 to 8 carbon atoms, said aliphatic ring optionally being substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen atoms, sulfur atoms or nitrogen atoms, said nitrogen atoms then not being bound to a hydrogen atom; - p is an integer equal to 0, 1 or 2. is a polymer comprising:

[0012] Preferably, the groups of formula (1) are located at the ends of the main chain of the polymer, also known as terminal groups.

[0013] Preferably, the polymer (A) comprising at least one alkoxysilane group is chosen from polyurethanes, polyethers and mixtures thereof.

[0014] The polymer (A) containing at least one alkoxysilane group can exhibit a number average molecular weight in the range of 500 to 50,000 g / mol, more preferably in the range of 700 to 20,000 g / mol.

[0015] The number average molecular weight of a polymer can be measured by methods well known to those skilled in the art, for example, by size exclusion chromatography using polyethylene glycol type standards.

[0016] According to one embodiment, the silylated polymer comprising at least one alkoxysilane group is a polymer of formula (II), (III) or (IV) as defined below, and mixtures thereof: TIFF0007824874000002.tif108170[In the formula, -R 1 represents a divalent hydrocarbon-based group containing 5 to 15 carbon atoms, which may be aromatic or aliphatic and linear, branched or cyclic, -R 0 represents a linear or branched divalent alkylene group containing 3 to 6 carbon atoms, -R 3 represents a linear or branched divalent alkylene group containing 1 to 6 carbon atoms, and R 3 preferably represents methylene or n-propylene, -R 2 represents a linear or branched divalent alkylene group containing from 2 to 14 carbon atoms, preferably from 2 to 6 carbon atoms and even more preferentially from 2 to 4 carbon atoms, -R 4 represents a linear or branched alkyl group containing 1 to 4 carbon atoms or an alkoxy group containing 1 to 4 carbon atoms; -R 5 is a linear or branched alkyl group containing 1 to 4 carbon atoms or a group -N=C(R i )R j where: -R i is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2 represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R j is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2 represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R i and R j are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, preferably 4 to 8 carbon atoms, said aliphatic ring optionally being substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen atoms, sulfur atoms or nitrogen atoms, said nitrogen atoms then not being bound to a hydrogen atom; -R 6 is a hydrogen atom, a phenyl group, a linear, branched or cyclic alkyl group containing 1 to 6 carbon atoms, or a group of the formula: TIFF0007824874000003.tif16170 (in the formula, R 7 is a linear or branched alkyl group containing 1 to 6 carbon atoms. represents a 2-succinate group of n is a group of the formula -[OR 2 ] n - is an integer such that the number average molecular weight of the polyether block is in the range of 300 g / mol to 40,000 g / mol, m1 is zero or an integer, n and m1 are such that the number average molecular weight of the polymer of formula (III) ranges from 500 g / mol to 50 000 g / mol, preferably from 700 g / mol to 20 000 g / mol, - m is a non-zero integer, n and m are such that the number average molecular weight of the polymer of formula (IV) ranges from 500 g / mol to 50 000 g / mol, preferably from 700 g / mol to 20 000 g / mol, - p is an integer equal to 0, 1 or 2, and p is preferably 0 or 1. is selected from.

[0017] Preferably, R in formula (II), (III) and (IV) 1 The group is selected from one of the following divalent groups, the formula of which shows two free valences: a) a divalent group derived from isophorone diisocyanate (IPDI): TIFF0007824874000004.tif35170-b) Divalent radicals derived from dicyclohexylmethane-4,4'- and 2,4'-diisocyanate (HMDI): TIFF0007824874000005.tif28170-c) Groups derived from toluene-2,4- and 2,6-diisocyanate (TDI): TIFF0007824874000006.tif40170-d) Groups derived from diphenylmethane-4,4'- and 2,4'-diisocyanate (MDI): TIFF0007824874000007.tif28170-e) Groups derived from m-xylylene diisocyanate (m-XDI): TIFF0007824874000008.tif22170-f) Groups derived from hexamethylene diisocyanate (HDI): TIFF0007824874000009.tif8170-g) A group derived from an HDI allophanate having the following formula (Y): TIFF0007824874000010.tif48170 [wherein p is an integer ranging from 1 to 2, q is an integer ranging from 0 to 9, preferably from 2 to 5, and R c represents a saturated or unsaturated, cyclic or acyclic, linear or branched hydrocarbon chain containing 1 to 20 carbon atoms, preferably 6 to 14 carbon atoms, R d represents a linear or branched divalent alkylene group having 2 to 4 carbon atoms, preferably a divalent propylene group.

[0018] Preferably, R in formula (II), (III) and (IV) 1 The group is a divalent group derived from isophorone diisocyanate or xylylene diisocyanate.

[0019] The polymers of formula (III) can be obtained according to the methods described in documents EP 2336208 and WO 2009 / 106699.

[0020] Among the polymers corresponding to formula (III), mention may be made, for example, of: Geniosil® STP-E10 (available from Wacker): 3 represents a methylene group, a polyether containing two groups (I) of the dimethoxy type having a number average molecular weight of about 8889 g / mol (m is equal to 0, p is equal to 1, R 4 and R 5 represents a methyl group); Geniosil® STP-E30 (available from Wacker): 3represents a methylene group, a polyether containing two groups (I) of the dimethoxy type having a number average molecular weight of about 14493 g / mol (m is equal to 0, p is equal to 1, R 4 and R 5 represents a methyl group); - Spur+® 1050MM (available from Momentive):R 3 represents an n-propylene radical, a polyurethane containing two groups of formula (I) of trimethoxy type, exhibiting a number average molecular weight of approximately 21,000 g / mol (m1 is different from 0, p is equal to 0, R 5 represents a methyl group); - Spur+® Y-19116 (available from Momentive): 3 represents an n-propylene radical, and having a number average molecular weight in the range of 15,000 to 17,000 g / mol, polyurethanes of the trimethoxy type containing two groups of formula (I) (where m1 is other than 0 and R 5 represents a methyl group); Desmoseal® S XP2636 (available from Bayer): 3 represents an n-propylene group, a polyurethane containing two groups of formula (I) of trimethoxy type, exhibiting a number average molecular weight of approximately 15038 g / mol (m1 is different from 0, p is equal to 0, R 5 represents a methyl group).

[0021] As an example of a silylated polymer of formula (III), mention may also be made of the commercial product Geniosil® XB502 available from Wacker, which contains a mixture of two products (B) and (C), in which: (B) is a polymer of formula (III) having a number average molecular weight of approximately 14000 g / mol, where m1 is equal to zero, p is equal to 1, and R 5 and R 4 each represents a methyl group, and R 3 represents a methylene group, and -[OR 2 ] n- group is derived from polypropylene glycol; (C) is a silsesquioxane (A) (CAS 1211908-05-2) terminated with a methoxy group and having a number average molecular weight of approximately 800 g / mol; Products (B) and (C) are present in a (B) / (C) weight ratio of approximately (25-30) / (70-75).

[0022] The polymers of formula (II) can be obtained, for example, by hydrosilylation of polyether diallyl ethers according to the method described in document EP 1 829 928.

[0023] Among the polymers corresponding to formula (II), mention may be made of: MS Polymer™ S303H (available from Kaneka), a polyether containing two groups of formula (I) of the dimethoxy type (p is equal to 1 and R 4 represents a methyl group); MS Polymer™ S227 (available from Kaneka), a polyether containing two groups of formula (I) of the dimethoxy type, with a number-average molecular weight of about 27,000 g / mol and a viscosity of 34 Pa.s at 23° C. (p is equal to 1 and R 5 and R 4 each represents a methyl group).

[0024] The polymer of formula (IV) can be obtained according to the following method: a) To form polyurethane-polyether blocks having at least two -NCO end groups, preferably blocks containing 1.5% to 1.9% by weight of -NCO groups, the following formula: TIFF0007824874000011.tif16170 and a stoichiometric excess of the following formula: NCO-R 1 -NCO diisocyanate, and then b) reacting the block obtained in the preceding step with a stoichiometric amount or a slight excess of the following formula: TIFF0007824874000012.tif10170 is reacted with α-, β- or γ-aminosilane.

[0025] Such methods are described, for example, in WO2013 / 136108.

[0026] Among the polymers corresponding to formula (IV), mention may be made of: Spur+ 1050MM (available from Momentive), a polyurethane polyether containing two groups of formula (I) of the trimethoxy type (p equals 0 and R 5 represents a methyl group); Spur+ 1015LM (available from Momentive), a polyurethane polyether containing two groups of formula (I) of the trimethoxy type (p equals 0 and R 5 represents a methyl group).

[0027] According to one embodiment, the composition according to the invention comprises from 3% to 80% by weight, preferably from 10% to 60% by weight, preferentially from 20% to 60% by weight and advantageously from 30% to 60% by weight of silylated polymer (A) relative to the total weight of said composition.

[0028] According to one preferred embodiment, the silylated polymer has formula (II) as defined above, in particular in which: - p is equal to 1; and / or -R 4 represents methyl.

[0029] Carbonate filler (B) According to one embodiment, the carbonate filler is selected from alkali metal or alkaline earth metal carbonates and mixtures thereof; preferably, the carbonate filler is calcium carbonate.

[0030] Calcium carbonate can be rendered hydrophobic, for example with calcium stearate or analogues, which allows the calcium carbonate particles to be partially or completely hydrophobic. The more or less hydrophobic nature of the calcium carbonate can affect the rheology of the composition. Furthermore, the hydrophobic coating can prevent the calcium carbonate from absorbing and neutralizing the constituents of the composition. The hydrophobic coating of calcium carbonate can account for 0.1% to 3.5% by weight of the total weight of the calcium carbonate.

[0031] The calcium carbonate that can be used in the present invention preferably has a particle size in the range of 0.1 to 400 μm, more preferably 1 to 400 μm, preferentially 10 to 350 μm, more preferably 50 to 300 μm.

[0032] An example of calcium carbonate is Mikhart® 1T (available from La Provencale).

[0033] The composition according to the invention comprises at least 25% by weight, preferably at least 30% by weight and preferentially at least 40% by weight of at least one carbonate filler relative to the total weight of the composition.

[0034] The composition according to the invention preferably comprises from 25% to 70% by weight, preferentially from 40% to 60% by weight, in particular from 45% to 55% by weight, of at least one carbonate filler, such as calcium carbonate, relative to the total weight of the composition.

[0035] The composition may comprise from 0.01 to 20 parts by weight of bis(alkoxysilane) or tri(alkoxysilane) (C) per 100 parts of polymer (A), preferably from 0.1 to 10 parts by weight of bis(alkoxysilane) or tri(alkoxysilane) (C) per 100 parts of polymer (A), and even more preferentially from 1 to 5 parts by weight of bis(alkoxysilane) or tri(alkoxysilane) (C) per 100 parts of polymer (A).

[0036] Bis(alkoxysilane) or tri(alkoxysilane) (C) The bis(alkoxysilane) or tri(alkoxysilane) (C) has the following formula (V): TIFF0007824874000013.tif10170[In the formula, - t represents an integer equal to 0, 1 or 2; - s represents an integer equal to 2 or 3; -R 8 represents an organic group: -R 9 may be the same or different, and each represents a linear or branched C1 to C6 alkyl group, or -OR 11 represents a group, and R 11 represents a linear or branched C1-C4 alkyl group; -R 10 may be the same or different and each represents a linear or branched alkyl group containing 1 to 4 carbon atoms or -N=C(R i )R j represents a group, where -R i is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R j is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2 represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R i and R j are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, preferably 4 to 8 carbon atoms, said aliphatic ring being optionally substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen, sulfur or nitrogen atoms, said nitrogen atom being not bonded to a hydrogen atom in that case. may have:

[0037] According to one preferred embodiment, the bis(alkoxysilane) or tri(alkoxysilane) (C) has a molar mass ranging from 270 to 1000 g / mol, preferably from 270 to 750 g / mol and preferentially from 270 to 600 g / mol.

[0038] According to one embodiment, the bis(alkoxysilane) or tri(alkoxysilane) (C) has the following formula (VA) or (VB): TIFF0007824874000014.tif30170[In the formula, -R 9 , R 10 and t is as defined above; -R 12is an oxygen atom, linear or branched C1-C 12 Alkylene group, C6-C 12 an arylene group or a linear or branched C2-C 12 represents an alkenylene group, said alkylene and alkenylene groups may contain one or more groups selected from -O-, -S-, -NR-, wherein R represents H or an alkyl, -C(=O)-O- or -OC(=O), -C(O)-NR'- or -NR'-C(=O), and R' represents H or an alkyl, -OC(=O)-NH- or -NH-C(=O)-O- or a uretdione group; -R 13 The base: TIFF0007824874000015.tif42170, and q represents an integer in the range of 1 to 10. The device has one of the following:

[0039] The compound of formula (VB) is preferably - q is in the range of 1 to 3; -R 9 may be the same or different, and each represents -OR 11 represents a group, and R 11 represents a linear or branched C1-C4 alkyl group.

[0040] Preferably, the compound of formula (VB) is the following compound: Selected from TIFF0007824874000016.tif120170.

[0041] The compound of formula (VA) is preferably -R 12 represents an oxygen atom, a linear or branched C1-C8 alkylene group, or a C2-C8 alkenylene group, wherein the alkylene and alkenylene groups may contain one or more groups selected from -O-, -S-, and -NR-, wherein R represents H or an alkyl, -C(O)-NR'-, or -NR'-C(=O) group, and R' represents H or an alkyl, -OC(=O)-NH-, or -NH-C(=O)-O-, or a uretdione group; -R 10 may be the same or different and each represents a linear or branched alkyl group containing 1 to 4 carbon atoms or -N=C(R i )R j represents a group, where -R i is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2 are each independently a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R j is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH2-N(G 1 G 2 ) wherein G 1 and G 2 are each independently a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R i and R j are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, preferably 4 to 8 carbon atoms, said aliphatic ring optionally being substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen atoms, sulfur atoms or nitrogen atoms, said nitrogen atoms then not being bonded to a hydrogen atom; -R 9may be the same or different, and each represents a linear or branched C1 to C6 alkyl group, or -OR 11 represents a group, and R 11 represents a linear or branched C1-C4 alkyl group; - t represents a number equal to 0, 1 or 2.

[0042] Even more preferably, the compound of formula (VA) is -R 12 represents an oxygen atom, a linear or branched C1-C8 alkylene group, or a C2-C8 alkenylene group, wherein the alkylene and alkenylene groups may contain one or more groups selected from -O-, -S-, and -NR-, wherein R represents H or an alkyl, -C(O)-NR'-, or -NR'-C(=O) group, and R' represents H or an alkyl, -OC(=O)-NH-, or -NH-C(=O)-O-, or a uretdione group; -R 10 may be the same or different and each represents a linear or branched alkyl group containing 1 to 4 carbon atoms; -R 9 may be the same or different, and each represents a linear or branched C1 to C6 alkyl group, or -OR 11 represents a group, and R 11 represents a linear or branched C1-C4 alkyl group; - t represents a number equal to 0, 1 or 2.

[0043] Preferably, the compound of formula (VA) is TIFF0007824874000017.tif199170 TIFF0007824874000018.tif254170 TIFF0007824874000019.tif251170 TIFF0007824874000020.tif247170 TIFF0007824874000021.tif136170.

[0044] The bis(alkoxysilane) or tri(alkoxysilane) (C) is preferably a compound of formula (VA), in particular 1,2-bis(triethoxysilyl)ethane.

[0045] The composition may comprise a total content of bis(alkoxysilane)s or tri(alkoxysilane)s (C) ranging from 0.1% to 20% by weight, preferably from 0.2% to 10% by weight, preferentially from 0.5% to 5% by weight and even more advantageously from 1% to 3% by weight relative to the total weight of the composition.

[0046] Crosslinking catalyst (D) Catalyst (D) can be any catalyst known to those skilled in the art for the condensation of silanols. Examples of such catalysts include: aminosilanes, such as N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (sold under the name Silquest® A-1120 by Momentive) or 3-aminopropyltrimethoxysilane, organic titanium derivatives, such as titanium acetylacetonate (available commercially under the name Tyzor® AA75 from DuPont de Nemours); aluminum, for example aluminum chelate (available under the name K-KAT® 5218 from King Industries), amines, such as 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) or 1,5-diazabicyclo[4.3.0]non-5-ene (DBN), 2,2'-dimorpholinodiethyl ether (DMDEE) or 1,4-diazabicyclo[2.2.2]octane (DABCO), - tin-based catalysts, such as Neostann® S-1 or TIB-KAT® 216 (available from Kaneka or TIB Chemicals, respectively). These tin-based catalysts are particularly suitable for silylated polymers of formula (II).

[0047] The catalyst (D) preferably represents from 0.01% to 1% by weight, preferentially from 0.05% to 0.6% by weight and advantageously from 0.1% to 0.6% by weight of the total weight of the composition.

[0048] composition According to a preferred embodiment, the composition comprises: - 10% to 60% by weight of a polymer (A) containing at least one alkoxysilane group; - 25% to 70% by weight of carbonate filler (B); - 0.01% to 5% by weight of bis(alkoxysilanes) or tri(alkoxysilanes) (C) having a molar mass in the range from 250 to 1000 g / mol; - 0.01% to 1% by weight of a crosslinking catalyst (D) and the percentages are expressed by weight relative to the total weight of the composition.

[0049] According to one embodiment, the composition also comprises at least one additive selected from the group consisting of solvents, pigments, adhesion promoters, moisture absorbers, UV stabilizers, rheological agents, fillers other than carbonate fillers, and mixtures thereof.

[0050] In the context of the present invention, "fillers other than carbonate fillers" or even "fillers" is understood to mean fillers which are not carbonate fillers.

[0051] The filler may be selected from organic fillers, inorganic fillers and mixtures thereof.

[0052] As organic filler, any organic filler, in particular polymeric fillers, typically used in the field of sealant compositions can be used.

[0053] For example, polyvinyl chloride (PVC), polyolefin, rubber, ethylene / vinyl acetate (EVA) or aramid fibers such as Kevlar® can be used.

[0054] Expandable or non-expandable hollow microspheres made of thermoplastic polymers can also be used, particularly hollow microspheres made of vinylidene chloride / acrylonitrile.

[0055] The average particle size of the fillers that can be used is preferably less than or equal to 10 microns, more preferentially less than or equal to 3 microns, in order to prevent them from settling in the composition according to the invention during storage thereof.

[0056] The average particle size is measured for a volume particle size distribution corresponding to 50% by volume of the sample of particles analyzed. If the particles are spherical, the average particle size corresponds to the median diameter (D50 or Dv50), which corresponds to the diameter below which 50% by volume of the particles have a size smaller than that diameter. In the present application, this value is expressed in micrometers and is determined by laser diffraction on a Malvern-type instrument according to standard NF ISO 13320-1 (1999).

[0057] Preferably, the filler is an inorganic filler.

[0058] The inorganic fillers may be provided in the form of particles of various sizes and shapes, which may be, for example, spherical or fibrous, or may exhibit an irregular shape.

[0059] According to one embodiment, the filler is selected from sand, glass beads, glass, quartz, baryte, alumina, mica or talc. Preferably, the filler is selected from sand and glass beads.

[0060] The sand that can be used in the present invention preferably has a particle size in the range of 0.1 to 400 μm, preferentially 1 to 400 μm, more preferably 10 to 350 μm, more preferably 50 to 300 μm.

[0061] The glass beads that can be used in the present invention preferably have a particle size in the range of 0.1 to 400 μm, preferentially 1 to 400 μm, more preferably 10 to 350 μm, more preferably 50 to 300 μm.

[0062] The composition according to the present invention may comprise at least one rheological agent.

[0063] Examples of rheological agents that can be used include any rheological agent commonly used in the field of sealant compositions.

[0064] Preferably, a thixotropic agent is used, more preferably one or more rheological agents selected from the following: PVC plastisols, corresponding to suspensions of PVC in plasticizers miscible with PVC, obtained in situ by heating to temperatures ranging from 60°C to 80°C. These plastisols may in particular be those described in the publication Polyurethane Sealants, Robert M. Evans, ISBN 087762-998-6. - fumed silica, - urea derivatives obtained by reacting aromatic diisocyanate monomers, such as 4,4'-MDI, with aliphatic amines, such as butylamine, the preparation of which is described in particular in application FR 1 591 172. - Micronized amide waxes, for example Crayvallac SLX sold by Arkema.

[0065] The total content of rheological agents that can be used may vary from 1% to 30% by weight, preferably from 5% to 30% by weight, more preferably from 10% to 25% by weight, relative to the total weight of the composition according to the invention.

[0066] The solvent is preferably a solvent that is volatile at room temperature (a temperature of about 23°C). The volatile solvent can be selected from, for example, alcohols that are volatile at room temperature, such as ethanol or isopropanol. The volatile solvent can, for example, reduce the viscosity of the composition, making it easier to apply. The volatility of the solvent allows the seal obtained after curing the composition to be free of the solvent. Therefore, the solvent does not, for example, adversely affect the hardness of the seal.

[0067] When a solvent, particularly a volatile solvent, is present in the composition, its content is preferably 5% by weight or less, more preferably 3% by weight or less, relative to the total weight of the composition.

[0068] Preferably, the content of the solvent in the composition is between 0% and 5% by weight.

[0069] If a pigment is present in the composition, its content is preferably 3% by weight or less, more preferably 2% by weight or less, based on the total weight of the composition. If present, the pigment may account for, for example, 0.1% by weight to 3% by weight or 0.4% by weight to 2% by weight of the total weight of the composition.

[0070] The pigment may be an organic or inorganic pigment.

[0071] For example, the pigment is TiO2, in particular Kronos® 2059 sold by Kronos.

[0072] If present, the moisture absorber may be selected from vinyltrimethoxysilane (VTMO), vinyltriethoxysilane (VTEO) or alkoxyarylsilanes such as Geniosil® XL70 available from Wacker.

[0073] When a moisture absorbent is present in the composition, its content is preferably 3% by weight or less, more preferably 2% by weight or less, based on the total weight of the composition. When present, the moisture absorbent may, for example, account for 0.5% by weight to 3% by weight or 1% by weight to 2% by weight, based on the total weight of the composition.

[0074] Among the UV stabilizers, mention may be made of benzotriazoles, benzophenones, "hindered" amines such as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate, and mixtures thereof.

[0075] Mention may be made, for example, of the products Tinuvin® 328 or Tinuvin™ 770 sold by BASF.

[0076] The composition according to the invention may be in one-component form, ie all components are packaged in one and the same compartment.

[0077] The composition is preferably ready to use, i.e., the user (individual or professional) can apply the composition directly to create a seal without the need to perform premixing.

[0078] The composition can be prepared by mixing the polymer (A) and fillers (carbonates and other fillers) at a temperature ranging from 5°C to 80°C, preferably under an inert atmosphere. The catalyst can be added simultaneously or in a second step after mixing the polymer and filler. The compound (C) can also be added simultaneously or in a second step after mixing the polymer and filler. Other additives are introduced into the composition according to their usual usage.

[0079] The composition according to the invention comprises a moisture-crosslinkable polymer (A) whose chemical structure has terminal reactive groups of the alkoxysilane type, and a compound (C) containing further reactive groups. The reaction of all these reactive groups with water, originating from the air or from the moisture of the substrate (known as the crosslinking reaction), makes it possible to create a strong three-dimensional polymer network that confers the desired mechanical properties to the adhesive seal thus created, in particular after the introduction of the sealant into the gap between the two substrates to be assembled.

[0080] This reaction, called crosslinking, when complete, results in the formation of an adhesive seal between the two substrates constituted by the polymer and the compound (C), which are crosslinked to give a three-dimensional network formed by polymer chains interconnected through siloxane-type bonds, which ensures in particular the robustness of the assembly of the two substrates thus obtained.

[0081] The compositions according to the invention advantageously exhibit good resistance to ageing after crosslinking, in particular they advantageously exhibit increased resistance to compresses.

[0082] The ageing resistance is tested in particular using a wet cloth test according to the conditions of standard NF EN ISO 9142, Annex E, Procedure E2, of January 2004 (exposure time in chamber A = 14 days). This test makes it possible to verify the reliability of the assembly in particular under adverse climatic conditions.

[0083] use The present invention relates to the use of the composition as defined above as an adhesive, sealant or coating, preferably as an industrial sealant.

[0084] The compositions can be used in particular as adhesives and sealants in the automotive field, for example as metal seals for the attachment of automobile windscreens.

[0085] The present invention also provides - at least one polymer (A) containing at least one alkoxysilane group; - at least 25% by weight of carbonate filler (B) relative to the total weight of the composition The present invention relates to the use of a compound (C) selected from bis(alkoxysilanes) and tri(alkoxysilanes) having a molar mass in the range of 250 to 1000 g / mol in a composition comprising the compound (C), for improving the ageing resistance of the composition after crosslinking.

[0086] The ingredients and properties described above for the composition also apply to the uses described above.

[0087] In the context of the present invention, the terms "between x and y" or "in the range of x and y" mean a range that includes the limits x and y. For example, the range "between 1% and 10%" includes, inter alia, the values ​​1% and 10%.

[0088] The following examples illustrate, but do not limit, the present invention.

[0089] Experimental section The following products were used in the preparation of the sealant composition according to the invention: - MS Polymer® S303 (available from Kaneka) (a silylated polyether polymer with Mn of 21,000-23,000 Daltons; Dynasylan BTSE® (CAS: 16068-37-4) available from Evonik: 1,2-bis(triethoxysilyl)ethane, density 0.95 g / cm 3 ; - Tinuvin™ 770: bis(2,2,6,6-tetramethyl-4-piperidinyl) sebacate type antioxidant, available from BASF; - Dynasylan® VTMO: vinyltrimethoxysilane moisture absorber, available from Evonik; - TiO2 sold by Kronos; - Calofort S, sold by Specialty Minerals; - Ammo A1110 sold by Momentive; - Tibkat226 sold by Tib Chemicals.

[0090] Compositions C1 and C2 were prepared by mixing the following ingredients according to the following procedure: mix the polymer, then add the fillers and pigments, as well as the VTMO, and finally add the other ingredients and catalyst. The whole is mixed at a temperature below 70°C. TIFF0007824874000022.tif77170

[0091] In Table 1, the percentages shown are in parts by weight.

[0092] Properties of the crosslinked composition The properties obtained for compositions C1 and C2 after crosslinking are summarized in Table 2 below: TIFF0007824874000023.tif101170

[0093] Skinning times were measured in a controlled atmosphere at a temperature of 20°C and approximately 60% relative humidity.

[0094] The composition is applied to a glass slide having a length of 76 mm and a width of 26 mm in the form of a thin film having a thickness of approximately 0.5 mm using a wooden spatula. Immediately after applying the film, a stopwatch is started, and every minute, the film is checked by lightly pressing with a finger to see if it is dry or if the composition residue is transferred to the finger. The skinning time is the time at which the composition film is dry and no adhesive residue is transferred to the finger. The results are expressed in minutes.

[0095] Tensile strength and elongation at break measurements by tensile testing were carried out according to the following protocol.

[0096] The measurement principle is that a standard test specimen made of the crosslinked composition is stretched in a tensile testing device whose moving jaw moves at a constant speed equal to 100 mm / min, and the applied tensile stress (in MPa) and also the elongation (in %) of the test specimen are recorded at the moment of specimen breakage. The standard test specimen has a dumbbell shape, as illustrated in International Standard ISO 37. The neck of the dumbbell used has a length of 20 mm, a width of 4 mm and a thickness of 500 μm.

[0097] The 24-hour cure was performed by right-angle peeling on flat strips of the product to be tested, of constant width and increasing thickness. The strips were obtained by filling a graduated trough with a width of 10 mm and a linearly varying depth from 0 to 10 mm. The assemblies were made of PTFE. After 24 hours of application in a climate-controlled chamber at 23°C and 50% RH, the level of adhesion of the product, still pasty (not polymerized throughout its thickness), to the assembly was recorded using the scale.

[0098] The modulus at 100% elongation was measured according to the test described in the 2002 standard ISO 11600, which references the 2005 standard ISO 8339.

[0099] The aging test, commonly called poultice, is a very severe aging test for adhesives; it is very widely used, especially by the automotive industry, to ensure assembly reliability under harsh climatic conditions. The poultice test was carried out according to standard NF EN ISO 9142, January 2004, Annex E, Procedure E2 (exposure time in chamber A = 14 days).

[0100] In addition, composition C2 advantageously produces, after crosslinking, adhesive seals with good mechanical performance, including an elongation at break of 150% or greater.

[0101] The poultice test showed that composition C2 did not lose more than 5% of its initial properties, advantageously demonstrating the good resistance to aging of the composition under severe temperature and humidity conditions.

Claims

1. 1. A moisture crosslinkable composition comprising: at least one polymer (A) comprising at least one alkoxysilane group, said polymer (A) being chosen from polyurethanes, polyethers and mixtures thereof; - at least 25% by weight relative to the total weight of the composition of at least one carbonate filler (B); at least one compound chosen from bis(alkoxysilanes) (C) having a molar mass ranging from 250 to 1000 g / mol; at least one crosslinking catalyst (D); and a plasticizer content of 1% by weight or less relative to the total weight of the composition, The bis(alkoxysilane) (C) is represented by the following formula (VA): [In the formula, t represents an integer equal to 0, 1 or 2; -R ９ may be the same or different, and each is a linear or branched C １ ~C ６ an alkyl group or -OR １１ represents a group, and R １１ is a linear or branched C １ ~C ４ represents an alkyl group; -R １０ may be the same or different and each represents a linear or branched alkyl group containing 1 to 4 carbon atoms or —N═C(R ｉ ) R ｊ represents a group, where -R ｉ is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R ｊ is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R ｉ and R ｊ are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, said aliphatic ring being optionally substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen, sulfur or nitrogen atoms, said nitrogen atom then not being bound to a hydrogen atom; -R １２ represents an oxygen atom, a linear or branched C １ ~C １２ Alkylene group, C ６ ~C １２ an arylene group, or a linear or branched C ２ ~C １２ represents an alkenylene group, and the alkylene and alkenylene groups may contain one or more groups selected from —O—, —S—, and —NR—, where R represents H or an alkyl, —C(═O)—O—, —O—C(═O), —C(O)—NR′—, or —NR′—C(═O), and R′ represents H or an alkyl, —O—C(═O)—NH—, —NH—C(═O)—O—, or a uretdione group.] and The compound of formula (VA) is the following compound: A moisture-crosslinkable composition, characterized in that it is selected from:

2. The polymer (A) containing at least one alkoxysilane group contains at least one group of formula (I): [In the formula, -R ４ represents a linear or branched alkyl group containing 1 to 4 carbon atoms or an alkoxy group containing 1 to 4 carbon atoms; -R ５ is a linear or branched alkyl group containing 1 to 4 carbon atoms or a group -N=C(R ｉ ) R ｊ where: -R ｉ is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R ｊ is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R ｉ and R ｊ are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, said aliphatic ring being optionally substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen, sulfur or nitrogen atoms, said nitrogen atom then not being bonded to a hydrogen atom; p is an integer equal to 0, 1 or 2. The composition of claim 1 , wherein the polymer comprises:

3. The silylated polymer (A) comprising at least one alkoxysilane group is represented by formula (II), (III) or (IV) as defined below: [In the formula, -R １ represents a divalent hydrocarbon-based radical containing 5 to 15 carbon atoms, which may be aromatic or aliphatic and linear, branched or cyclic, -R ０ represents a linear or branched divalent alkylene group containing 3 to 6 carbon atoms, -R ３ represents a linear or branched divalent alkylene group containing 1 to 6 carbon atoms, -R ２ represents a linear or branched divalent alkylene group containing 2 to 14 carbon atoms, -R ４ represents a linear or branched alkyl group containing 1 to 4 carbon atoms or an alkoxy group containing 1 to 4 carbon atoms; -R ５ is a linear or branched alkyl group containing 1 to 4 carbon atoms or a group -N=C(R ｉ ) R ｊ where: -R ｉ is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R ｊ is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R ｉ and R ｊ are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, said aliphatic ring being optionally substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen, sulfur or nitrogen atoms, said nitrogen atom then not being bonded to a hydrogen atom; -R ６ is a hydrogen atom, a phenyl group, a linear, branched or cyclic alkyl group containing 1 to 6 carbon atoms, or a group of the formula: (In the formula, R ７ is a linear or branched alkyl group containing 1 to 6 carbon atoms. represents a 2-succinate group of the formula n is a group of the formula —[OR ２ ] ｎ - is an integer such that the number average molecular weight of the polyether block is in the range of 300 g / mol to 40,000 g / mol, - m １ is zero or an integer, - n and m １ is such that the number average molecular weight of the polymer of formula (III) is in the range of 500 g / mol to 50,000 g / mol, m is an integer other than zero, n and m are such that the number average molecular weight of the polymer of formula (IV) ranges from 500 g / mol to 50,000 g / mol, p is an integer equal to 0, 1 or 2.

3. The composition according to claim 1, wherein the polymer is selected from the group consisting of:

4. Polymer (A) is a polymer of formula (II): [In the formula, -R ０ represents a linear or branched divalent alkylene group containing 3 to 6 carbon atoms, -R ２ represents a linear or branched divalent alkylene group containing 2 to 14 carbon atoms, -R ４ represents a linear or branched alkyl group containing 1 to 4 carbon atoms or an alkoxy group containing 1 to 4 carbon atoms; -R ５ is a linear or branched alkyl group containing 1 to 4 carbon atoms or a group -N=C(R ｉ ) R ｊ where: -R ｉ is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R ｊ is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R ｉ and R ｊ are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, said aliphatic ring being optionally substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen, sulfur or nitrogen atoms, said nitrogen atom then not being bonded to a hydrogen atom; p is an integer equal to 0, 1 or 2. The composition of claim 1 , wherein the composition is selected from the group consisting of:

5. 5. The composition according to claim 1, comprising from 3% to 80% by weight of silylated polymer (A) relative to the total weight of the composition.

6. 6. The composition according to claim 1, wherein the bis(alkoxysilanes) (C) have a total content ranging from 0.1% to 20% by weight relative to the total weight of the composition.

7. - 10% to 60% by weight of a polymer (A) containing at least one alkoxysilane group; - 25% to 70% by weight of carbonate filler (B); - 0.01% to 5% by weight of bis(alkoxysilanes) (C) having a molar mass in the range from 250 to 1000 g / mol; - 0.01% to 1% by weight of a crosslinking catalyst (D); 6. The composition according to claim 1, wherein the percentages are expressed by weight relative to the total weight of the composition.

8. 8. The composition according to claim 1, wherein the bis(alkoxysilane) (C) has a molar mass of 270 to 1000 g / mol.

9. 9. A composition according to any one of claims 1 to 8, characterized in that the carbonate filler is selected from alkali metal or alkaline earth metal carbonates and mixtures thereof.

10. 10. The composition of any one of claims 1 to 9, characterized in that it comprises at least one additive selected from the group consisting of solvents, pigments, adhesion promoters, moisture absorbers, UV stabilizers, rheological agents, fillers other than carbonate fillers, and mixtures thereof.

11. 11. Use of a composition according to any one of claims 1 to 10 as an adhesive, sealant or coating.

12. at least one polymer (A) comprising at least one alkoxysilane group, said polymer (A) being chosen from polyurethanes, polyethers and mixtures thereof; at least 25% by weight of carbonate filler (B) relative to the total weight of the composition Use of a compound (C) selected from bis(alkoxysilanes) having a molar mass ranging from 250 to 1000 g / mol in a composition comprising The bis(alkoxysilane) (C) is represented by the following formula (VA): [In the formula, t represents an integer equal to 0, 1 or 2; -R ９ may be the same or different, and each is a linear or branched C １ ~C ６ an alkyl group or -OR １１ represents a group, and R １１ is a linear or branched C １ ~C ４ represents an alkyl group; -R １０ may be the same or different and each represents a linear or branched alkyl group containing 1 to 4 carbon atoms or —N═C(R ｉ ) R ｊ represents a group, where -R ｉ is a hydrogen atom, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; -R ｊ is a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, a cyclic alkyl group containing 3 to 10 carbon atoms, an aryl group containing 6 to 12 carbon atoms, or a group -CH ２ -N(G １ G ２ ) wherein G １ and G ２ represent, independently of one another, a linear or branched alkyl group containing 1 to 10 carbon atoms, a linear or branched alkenyl group containing 2 to 10 carbon atoms, or a benzyl group; - Or R ｉ and R ｊ are taken together to form an aliphatic ring containing 3 to 14 carbon atoms, said aliphatic ring being optionally substituted with at least one alkyl group containing 1 to 4 carbon atoms, said ring optionally containing one or more heteroatoms selected from oxygen, sulfur or nitrogen atoms, said nitrogen atom then not being bound to a hydrogen atom; -R １２ represents an oxygen atom, a linear or branched C １ ~C １２ Alkylene group, C ６ ~C １２ an arylene group, or a linear or branched C ２ ~C １２ represents an alkenylene group, and the alkylene and alkenylene groups may contain one or more groups selected from —O—, —S—, and —NR—, where R represents H or an alkyl, —C(═O)—O—, —O—C(═O), —C(O)—NR′—, or —NR′—C(═O), and R′ represents H or an alkyl, —O—C(═O)—NH—, —NH—C(═O)—O—, or a uretdione group.] and The compound of formula (VA) is the following compound: Selected from: Use to improve the ageing resistance of the composition after crosslinking.

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