Wavelength conversion device and illumination device

Abstract

To provide a wavelength conversion device that can improve light extraction efficiency while narrowing an angle of fluorescence emitted by nano-antennas, and a lighting unit.SOLUTION: A wavelength conversion device has: a phosphor member that has a first surface on which excitation light is incident, and on the other surface including a phosphor excited by excitation light to emit fluorescence and on an opposite side of the first surface, and has a rugged structure composed of a plurality of projections provided in a first direction along the other surface at a period smaller than a peak wavelength of the phosphor; and a plurality of nano-antennas that is composed of a metal member and arranged on top faces of the plurality of projections.SELECTED DRAWING: Figure 2

Description

Technical Field

[0001] The present invention relates to a wavelength conversion device and a lighting device.

Background Art

[0002] There is disclosed a lighting device that narrows light using a metal antenna made of nano-sized metal particles (hereinafter referred to as a nano-antenna). For example, Patent Document 1 discloses a lighting device having a transparent substrate, a wavelength converter disposed on the transparent substrate, and a plurality of nano-antennas formed on the wavelength converter.

Prior Art Documents

Patent Documents

[0003]

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0004] In a lighting device such as that of Patent Document 1, among the fluorescence generated by excitation of the phosphor in the wavelength converter by excitation light, the component exceeding the critical angle is totally reflected at the interface between the wavelength converter and air. At this time, a part of the totally reflected fluorescence is absorbed by the nano-antenna after repeating multiple reflections in the wavelength converter without being taken out to the outside, and there is a problem that the light extraction efficiency of the entire lighting device is reduced.

[0005] The present invention has been made in view of the above problems, and an object thereof is to provide a wavelength conversion device and a lighting device capable of improving the light extraction efficiency while achieving narrowing of fluorescence by a nano-antenna.

Means for Solving the Problems

[0006] The wavelength conversion device according to the present invention is characterized by comprising: a phosphor member having one surface into which excitation light is incident, containing a phosphor that is excited by the excitation light and emits fluorescence, and having a surface opposite to the one surface having a surface with [Brief explanation of the drawing]

[0007] [Figure 1] This is a top view of the wavelength conversion device according to Example 1. [Figure 2] This is a cross-sectional view of the wavelength conversion device according to Example 1. [Figure 3] This graph shows the transmission intensity as a function of the incident angle in the wavelength conversion device according to Example 1. [Figure 4] This graph shows the transmission intensity as a function of the depth of the recess in the wavelength conversion device according to Example 1. [Figure 5] This graph shows the transmission intensity as a function of the depth of the recess in the wavelength conversion device according to Example 1. [Figure 6] This graph shows the length of evanescent light leakage with respect to the incident angle in the wavelength conversion device according to Example 1. [Figure 7] This is a top view of a wavelength conversion device according to a modified example of Example 1. [Figure 8] This is a cross-sectional view of the wavelength conversion device according to Example 2. [Figure 9] This is a cross-sectional view of the lighting device according to Example 3. [Figure 10] This is a cross-sectional view of the wavelength conversion device according to Example 3. [Modes for carrying out the invention]

[0008] Hereinafter, embodiments of the present invention will be specifically described with reference to the drawings. In the drawings, identical components are denoted by the same reference numerals, and descriptions of redundant components are omitted. [Examples]

[0009] The configuration of the wavelength conversion device 100 according to Example 1 will be described with reference to Figures 1 and 2. Figure 1 is a top view of the wavelength conversion device 100 according to Example 1. Figure 2 is a cross-sectional view of the wavelength conversion device 100 shown in Figure 1 along line 2-2.

[0010] [Mounted circuit board] The mounting substrate 12 is a flat, insulating substrate with a rectangular top surface. The mounting substrate 12 is made of, for example, aluminum nitride (AlN) or alumina (Al2O3). For the sake of simplicity, the XYZ axes are defined as follows: the Z-axis is the direction perpendicular to the top surface of the mounting substrate 12, and the X-axis and Y-axis are the directions along two mutually perpendicular sides of the mounting substrate 12.

[0011] [Light-emitting element] The light-emitting element 13 is mounted on the upper surface of the mounting substrate 12 and is a light-emitting diode (LED) with a rectangular upper surface shape. The light-emitting element 13 is composed of a semiconductor structural layer 14 having a light-emitting layer, a support substrate 15 disposed on the upper surface of the semiconductor structural layer 14, and a p electrode 16 and an n electrode 17 disposed on the lower surface of the semiconductor structural layer 14 and bonded to the mounting substrate 12. In other words, the light-emitting element 13 is flip-chip mounted on the mounting substrate 12.

[0012] The semiconductor structure layer 14 is a semiconductor stack consisting of an n-type semiconductor layer, an emissive layer, and a p-type semiconductor layer (none of which are shown), each primarily made of gallium nitride (GaN). When the light-emitting element 13 is driven, blue light with a peak wavelength of 450 nm is emitted from the emissive layer of the semiconductor structure layer 14.

[0013] The support substrate 15 is a flat substrate with a rectangular top surface. The support substrate 15 is made of a material that is transparent to blue light emitted from the semiconductor structural layer 14, such as single-crystal sapphire (Al2O3). The top surface of the support substrate 15 is the light emission surface from which blue light is emitted from the light-emitting element 13.

[0014] The p - electrode 16 is an electrode electrically connected to the p - type semiconductor layer of the semiconductor structure layer 14. The p - electrode 16 is joined to a p - side wiring (not shown) formed on the upper surface of the mounting substrate 12 via a conductive joining member (not shown).

[0015] The n - electrode 17 is an electrode electrically connected to the n - type semiconductor layer via a through - electrode (not shown) that vertically penetrates the light - emitting layer and the p - type semiconductor layer of the semiconductor structure layer 14 and whose side surfaces are covered with an insulator. In other words, the n - electrode 17 is electrically connected only to the n - type semiconductor layer and is insulated from the light - emitting layer and the p - type semiconductor layer. The n - electrode 17 is joined to an n - side wiring (not shown) formed on the upper surface of the mounting substrate 12 via a conductive joining member (not shown).

[0016] As described above, the light - emitting element 13 has a structure in which a voltage is applied to the p - electrode 16 and the n - electrode 17 via the mounting substrate 12, and blue light generated by a current flowing in the semiconductor structure layer 14 is emitted from the upper surface of the support substrate 15.

[0017] [Phosphor member] The phosphor member 18 is a phosphor plate with a rectangular upper - surface shape having a thickness of 50 - 250 μm, which is adhered to the upper surface of the light - emitting element 13, that is, the upper surface of the support substrate 15 via a light - transmissive joining member (not shown). The phosphor member 18 has the same shape as the support substrate 15 of the light - emitting element 13 in top - view.

[0018] The phosphor member 18 is made of a phosphor that is excited by the blue light emitted from the light - emitting element 13 and emits yellow fluorescence. Specifically, the phosphor member 18 is, for example, a single - phase transparent ceramic phosphor plate made of yttrium aluminum garnet (YAG:Ce) phosphor with cerium (Ce) as an activator.

[0019] When excitation light emitted from the light-emitting surface of the light-emitting element 13 is incident on the phosphor member 18 described above, a portion of the light passes through the phosphor member 18, while the other portion excites the phosphor, causing yellow fluorescence to be emitted from the excited phosphor. The yellow fluorescence generated from the phosphor has a peak wavelength of 520-570 nm and a yellow emission spectrum consisting of a broad peak over 480 nm-700 nm.

[0020] Therefore, from the upper surface of the phosphor member 18, excitation light (blue light) that has passed through the phosphor member 18 without contributing to fluorescence generation, and fluorescence (yellow light) emitted from the phosphor are emitted. As a result, the wavelength conversion device 100 extracts white light, which is a mixture of the blue light and yellow fluorescence emitted from the upper surface of the phosphor member 18.

[0021] Hereafter, as shown in Figure 1, we will refer to the pair of sides of the phosphor member 18 extending in the X direction in the figure as side 18X, and the pair of sides of the phosphor member 18 extending in the Y direction in the figure as side 18Y.

[0022] The upper surface of the phosphor member 18 has an uneven surface structure comprising protrusions 18C arranged in a matrix with periodicity P along the X and Y directions, each having a frustoconical shape, and square grid-like recesses 18G formed between the protrusions 18C.

[0023] The recessed portion 18G of the uneven structure is a structure formed by combining multiple grooves arranged in multiple rows vertically and horizontally, forming a lattice-like structure that individually partitions each of the protruding portions 18C. The period P is a period shorter than the peak wavelength of fluorescence emitted from the phosphor member 18. The period P is preferably 500 nm or less.

[0024] [Nano Antenna] The nanoantennas 21 are a plurality of frustoconical metal members, each formed on the upper surface of each of the protrusions 18C in the uneven structure of the phosphor member 18. Because each nanoantenna 21 is formed on the upper surface of each of the protrusions 18C arranged in a square grid, it is consequently arranged in a square grid with a period P when viewed from above, just like the protrusions 18C.

[0025] Each lower surface of the nanoantenna 21 is the same size as each upper surface of the protrusion 18C of the phosphor member 18. In other words, the lower surfaces of the nanoantenna 21 and the upper surfaces of the protrusions 18C of the phosphor member 18 have the same diameter W, and the protrusions 18C and the nanoantenna 21 formed on the upper surfaces of the protrusions 18C together form a frustoconical shape.

[0026] Each of the nanoantennas 21 has the same height H on the upper surface of each of the protrusions 18C. Furthermore, each of the nanoantennas 21 is composed of a material having a plasma frequency in the visible light region, such as Au (gold), Ag (silver), Cu (copper), Pt (platinum), Pd (palladium), Al (aluminum), and Ni (nickel), as well as an alloy or laminate containing these materials. In particular, it is desirable that each of the nanoantennas 21 be composed of a metal that has low absorption in the visible light region, such as aluminum (Al) or silver (Ag).

[0027] It should be noted that the uneven structure of the phosphor member 18 and the arrangement of the nanoantennas 21 shown in Figures 1 and 2 are merely schematic representations to illustrate the uneven structure and the nanoantennas 21. In reality, the light-emitting element 13 is, for example, 1 mm square, in which case more protrusions 18C and nanoantennas 21 are formed than those shown in Figures 1 and 2.

[0028] Here, we will explain the fluorescence enhancement effect that occurs in the nano-antenna 21.

[0029] When fluorescence reaches the upper surface of the phosphor member 18 at an angle greater than the critical angle, total internal reflection occurs at that upper surface. When this total internal reflection occurs, an evanescent wave is generated that seeps from the upper surface of the phosphor member 18 toward the low refractive index medium. This evanescent wave propagates along the upper surface of the phosphor member 18, in other words, along the interface between the phosphor member 18 and the air.

[0030] When the evanescent wave propagating along the upper surface of the phosphor member 18 reaches the nanoantenna 21, it is emitted in the form of visible light with the same wavelength as the fluorescence in a direction that matches the diffraction conditions determined by the arrangement period of the nanoantenna 21. This phenomenon causes fluorescence to be emitted within a narrow angular range that matches the diffraction conditions, promoting the narrowing of the angle of fluorescence emitted from the upper surface of the phosphor member 18.

[0031] Furthermore, when fluorescence emitted from the phosphor material 18 irradiates the nanoantenna 21, localized surface plasmon resonance occurs on the surface of the nanoantenna 21, increasing the electric field intensity near the nanoantenna 21. In the nanoantenna 21 group, which is arranged with a period P smaller than the peak wavelength of the fluorescence described above, the electric field intensity is further increased in the portion of the surface of each nanoantenna 21 that is close to adjacent nanoantennas 21, in other words, in the portion facing adjacent nanoantennas 21.

[0032] As a result of this electric field enhancement, the highly localized plasmon resonance significantly amplifies fluorescence in the vicinity of the nanoantenna 21, and this amplified fluorescence has a narrow-angle light distribution characteristic (low etendue). In other words, the nanoantenna 21 has the function of enhancing the fluorescence emitted from the phosphor member 18 and narrowing the direction of fluorescence emission.

[0033] [Light-reflecting material] The light-reflecting member 22 is a light-reflecting member that extends continuously to cover the outer surfaces of the semiconductor structural layer 14 and support substrate 15 of the light-emitting element 13 and the phosphor member 18. The light-reflecting member 22 is made of a translucent resin containing light-scattering particles, for example, a resin material containing titanium dioxide (TiO2) particles in a silicone resin.

[0034] The light-reflecting member 22 reflects, for example, excitation light (blue light) emitted from the light-emitting element 13 and reaching the outer surface upward. The light-reflecting member 22 also reflects, for example, fluorescence generated within the phosphor member 18 and reaching the outer surface upward.

[0035] As described above, the multiple irregularities formed on the upper surface of the phosphor member 18 are arranged with a period P smaller than the peak wavelength of fluorescence emitted from the phosphor member 18. In other words, the phosphor member 18 has an irregular structure consisting of multiple protrusions on its upper surface arranged with a period smaller than the peak wavelength of fluorescence.

[0036] According to this embodiment, because the period P in the uneven surface structure of the phosphor member 18 is smaller than the peak wavelength of fluorescence, when the fluorescence reaches the uneven structure, the refractive index of the medium gradually changes in the height direction of the uneven structure portion. Specifically, it behaves similarly to how the refractive index decreases as you go higher, approaching the refractive index of air.

[0037] Therefore, the critical angle of fluorescence at the interface between the phosphor member 18 and the air on the upper surface of the phosphor member 18 is larger compared to the case without an uneven structure, making total internal reflection less likely. Thus, the component of fluorescence in the phosphor member 18 that exceeds the critical angle can be reduced, and the component that is totally reflected at the interface between the phosphor member 18 and the air can be reduced.

[0038] Therefore, according to this embodiment, the proportion of fluorescence extracted from each upper surface of the protrusions 18C of the phosphor member 18 can be increased. In other words, it is possible to improve the light extraction efficiency while achieving narrowing of the fluorescence angle by the nanoantenna 21.

[0039] [Method for preparing phosphor material] The following describes a method for manufacturing a phosphor member 18 having an uneven structure and a nanoantenna 21 formed on the upper surface of the protrusions 18C of the uneven structure.

[0040] First, a metal film made of Al or Ag, which will serve as the substrate for the nanoantenna 21, is deposited on the upper surface of a flat substrate that will become the phosphor member 18, by electron beam deposition or sputtering (Step 1).

[0041] Next, a resist is applied to the metal film formed in step 1, and patterning is performed using a nanoimprint apparatus or ion beam lithography apparatus to form a tetragonal lattice-like surface (step 2).

[0042] Next, using the resist applied to the raised portions of the patterned surface in step 2 as an etching mask, dry etching is performed on the recessed portions (step 3). At this time, etching is performed until the depth of the recess reaches depth D, resulting in a surfaced structure having recesses 18G of depth D.

[0043] Finally, the etching mask (resist) on the convex portions is removed by ashing (step 4). This makes it possible to obtain a phosphor member 18 having an uneven structure on its upper surface, with nanoantennas 21 formed on the upper surface of each of the convex portions 18C of the uneven structure.

[0044] Furthermore, when forming the uneven structure of the phosphor material 18 and the nanoantenna 21 by the etching described above, the type of etching gas can be appropriately selected depending on the object to be etched. For example, when forming the nanoantenna 21 made of Al, etching is performed using chlorine (Cl2) gas and argon (Ar) gas. Also, for example, when forming an uneven structure on a phosphor plate made of YAG:CEe phosphor, etching is performed using sulfur hexafluoride (SF6) gas or methane tetrafluoride (CF4) gas.

[0045] [verification] The verifications performed on the wavelength conversion device 100 of the present invention and the results of those verifications will be described below with reference to Figures 3 to 6. In these verifications, the depth D of the recesses 18G of the uneven structure of the phosphor member 18 was mainly examined.

[0046] The model used in this verification is described below. The phosphor member 18 is a single-crystal ceramic plate of a single-phase YAG:Ce phosphor, and the nanoantenna 21 is made of Al. The uneven structure of the phosphor member 18 has a period P of 350 nm and is arranged in a square lattice pattern. The nanoantenna 21 has a height H of 150 nm and a diameter W of the lower surface (diameter of the upper surface of the protrusion 18C) of 200 nm. The wavelength of the incident light incident on the nanoantenna 21 from the phosphor member 18 is set to 550 nm (peak wavelength of yellow fluorescence).

[0047] Figure 3 is a graph showing the results of calculating the intensity of fluorescence extracted into the air via the nanoantenna 21 (through the formation surface of the nanoantenna 21) when the incident angle of fluorescence on the interface between the phosphor material 18 and air is changed, using the RCWA (Rigorous Coupled Wave Analysis) method.

[0048] Figure 3 shows the fluorescence transmission intensity when the depth D of the recess 18G is 0 nm (no uneven structure), 10 nm, 30 nm, 50 nm, 70 nm, and 100 nm. Also in Figure 3, the critical angle of incidence at the interface between the phosphor member 18 and air when there is no nanoantenna and uneven structure (depth D is 0 nm) is shown by a dashed line. In this embodiment, the critical angle is 34 degrees.

[0049] Figure 3 shows that, in the range of fluorescence incidence angles from 20° to 65°, the transmission intensity when the depth D of the recess 18G is 10 nm, 30 nm, 50 nm, 70 nm, and 100 nm is greater than when there is no recess (D=0 nm). In particular, in the range of fluorescence incidence angles from 20° to the critical angle (single dotted line in the figure) when there is no nanoantenna and uneven structure, it is clearly shown that the transmission intensity is greater when the phosphor member 18 has a recess 18G compared to when there is no recess.

[0050] Furthermore, it can be seen that in the range of fluorescence incidence angles from 20° to 65°, the transmission intensity increases as the depth D of the recess 18G increases. In this way, by providing the phosphor member 18 with multiple irregularities consisting of recesses 18G with a depth D, high light extraction efficiency can be obtained over a wide range of fluorescence incidence angles.

[0051] Figure 4 is a graph showing the transmission intensity calculated using the RCWA method when the depth D of the recess 18G is varied. In Figure 4, the transmission intensity was calculated separately for the case where the incident angle of fluorescence is the entire angular range, the case where it is below the critical angle when there are no nanoantennas and uneven structures, and the case where it is above the critical angle when there are no nanoantennas and uneven structures. In Figure 4, the transmission intensity when there is no recess 18G is shown as 1.0.

[0052] As shown in Figure 4, in the range where the depth D of the recess 18G is 10 to 100 nm, the transmission intensity is increased by approximately 10 to 20% compared to when the recess 18G is not provided, regardless of the incident angle of fluorescence.

[0053] Furthermore, when the nanoantenna and uneven structure are not present, the fluorescence transmission intensity above the critical angle is lower than when the recess 18G is not present when the depth D of the recess 18G exceeds 120 nm. In other words, in order to keep the fluorescence transmission intensity above the critical angle higher than when the recess 18G is not present, it is preferable to set the depth D of the recess 18G to 120 nm or less.

[0054] Figure 5 is a graph showing the transmission intensity of fluorescence across all angular ranges when the depth D of the recess 18G is varied, calculated using the RCWA method. In Figure 5, the change in transmission intensity with and without a nanoantenna was verified using the wavelength conversion device 100 and a wavelength conversion device without a nanoantenna as a comparison. In Figure 5, the transmission intensity when the recess 18G is not provided is shown as 1.0 for both the nanoantenna-equipped and nanoantenna-less models.

[0055] As shown in Figure 5, the transmission intensity in the case of "no nano-antenna" increases as the depth D of the recess 18G increases. In other words, to increase the transmission intensity of fluorescence emitted from the phosphor member 18 having an uneven structure, it is preferable to increase the depth D of the recess 18G.

[0056] However, as described above, when a nanoantenna 21 is formed on the upper surface of the protrusion 18C (with nanoantenna), if the depth D of the recess 18G exceeds 120 nm, the transmission intensity in the range where the incident angle of fluorescence is above the critical angle in the case without a nanoantenna and uneven structure decreases compared to the case without an uneven structure.

[0057] Therefore, in order to improve the light extraction efficiency from the phosphor member 18 while utilizing fluorescence at an incident angle greater than the critical angle in the case without nanoantennas and a surface irregularity structure, it is preferable to set the depth D of the recess 18G to 120 nm or less.

[0058] Figure 6 is a graph showing the seepage length when the evanescent wave seeping from the upper surface of the phosphor member 18 changes from its maximum intensity to a predetermined intensity when the incident angle of fluorescence is changed.

[0059] In Figure 6, the evanescent wave generated on the surface of the phosphor material is 1 / e from the maximum intensity. 2 The stain length required to reach the desired intensity is shown for each fluorescence wavelength (500nm, 550nm, 600nm, 650nm). The stain length d of the evanescent wave can be calculated using the following formula.

[0060]

number

[0061] Here, wavelength λ is the wavelength of fluorescence, refractive index n1 is the refractive index of the phosphor material 18, and refractive index n2 is the refractive index of air. Also, the angle of incidence θ is the angle of incidence of fluorescence to the interface between the phosphor material 18 and the air.

[0062] As shown in Figure 6, the change in the stain length d with respect to the incident angle is large in the range up to 40° of fluorescence, and small in the range from 40° to 89° of fluorescence.

[0063] For example, when the fluorescence wavelength is 550 nm, in order to obtain an evanescent wave with a stain length d of 150 nm, the fluorescence component must have an incident angle θ of less than 40°. In other words, if the incident angle θ of the fluorescence exceeds 40°, it becomes difficult to obtain an evanescent wave with a stain length d of 150 nm.

[0064] In other words, the deeper the depth D of the recess 18G, the more evanescent waves with a staining length d corresponding to that depth are required, which limits the range of incident angles of fluorescence that satisfy that staining length d.

[0065] Therefore, in Figure 5, it is thought that as the depth D of the recess 18G increases, the evanescent wave leakage becomes less likely to reach the nano-antenna 21, and electric field enhancement becomes less likely, resulting in a decrease in fluorescence transmission intensity.

[0066] Therefore, as shown in Figures 3 to 6, in order to improve light extraction efficiency while utilizing a wide range of incident angles of fluorescence, it is preferable to set the depth D of the recesses 18G of the uneven structure of the phosphor member 18 to 120 nm or less. In other words, it is preferable that the height of the protrusions 18C from the bottom surface of the recesses 18G be 120 nm or less.

[0067] [Differentiation] A modified example of the wavelength conversion device 100 according to Example 1 will be described below with reference to Figure 7. Figure 7 is a top view of the modified wavelength conversion device 110. The modified wavelength conversion device 110 differs from Example 1 in the manner in which the uneven structure of the phosphor member 18 is formed, but other aspects, such as the configuration of the light-emitting element 13 and the arrangement period of the nano-antenna 21, are the same as in Example 1.

[0068] In this modified example, the phosphor member 18 has a textured structure consisting of multiple protrusions and recesses that extend in the direction along side 18Y from one side 18X to the other side 18X when viewed from above. That is, the textured structure of the phosphor member 18 forms a striped pattern by arranging multiple protrusions 18C and recesses 18G in the direction along side 18Y.

[0069] In this modified example, each of the nanoantennas 21 is arranged on the upper surface of each of the protrusions 18C with the same period P along the extension direction of the protrusions 18C. That is, in this modified example, the upper surface of the protrusions 18C is exposed in the regions other than the formation regions of each of the nanoantennas 21.

[0070] Even with a wavelength conversion device 110 having such a configuration, the same effects as in Example 1 can be achieved. That is, the component of fluorescence above the critical angle in the phosphor member 18 can be reduced, and the component that is totally reflected at the interface between the phosphor member 18 and air can be reduced.

[0071] Therefore, the proportion of fluorescence extracted from the phosphor material 18 can be increased. Consequently, it is possible to improve the light extraction efficiency while achieving narrowing of the fluorescence angle by the nanoantenna 21. [Examples]

[0072] Next, Example 2 will be described using Figure 8. Figure 8 is a cross-sectional view of the wavelength conversion device 200 according to Example 2. The wavelength conversion device 200 differs from Example 1 in that it includes a light-transmitting member 24, but other aspects, such as the configuration of the light-emitting element 13 and the formation of the uneven structure of the phosphor member 18, are the same as in Example 1.

[0073] As shown in Figure 8, the translucent member 24 is a member that fills the recesses 18G of the phosphor member 18 to a height approximately uniform with the upper surface of the protrusions 18C of the uneven structure. In other words, the translucent member 24 fills the recesses 18G in such a way that the upper surfaces of each of the protrusions 18C of the uneven structure are exposed.

[0074] The light-transmitting member 24 is made of a material that is transparent to the light emitted from the light-emitting element 13 (blue light) and the fluorescence generated in the phosphor member 18 (yellow light), and has a refractive index smaller than that of the phosphor member 18. The light-transmitting member 24 is made of, for example, silicon dioxide (SiO2 (refractive index n=1.46)) or Al2O3 (refractive index n=1.63).

[0075] According to this embodiment, since the recesses 18G of the phosphor member 18 are filled with a translucent member 24 having a lower refractive index than the phosphor member 18, the behavior of the change in refractive index when the fluorescence reaches the uneven structure becomes more gradual.

[0076] In other words, by filling the recess 18G of the phosphor member 18 with the translucent member 24, the critical angle of fluorescence with respect to the interface between the phosphor member 18 and air on the upper surface of the phosphor member 18 becomes larger than in Example 1, making total internal reflection less likely. Therefore, the component of fluorescence above the critical angle in the phosphor member 18 can be reduced compared to Example 1, and the component that undergoes total internal reflection at the interface between the phosphor member 18 and air can be reduced.

[0077] Therefore, according to this embodiment, the proportion of fluorescence extracted from each upper surface of the protrusions 18C of the phosphor member 18 can be increased. In other words, it is possible to improve the light extraction efficiency while achieving narrowing of the fluorescence angle by the nanoantenna 21.

[0078] Furthermore, it is preferable that the translucent member 24 is filled in the recess 18G to a height that does not directly contact the nanoantenna 21. This is because if the translucent member 24 comes into contact with the nanoantenna 21, the sensitivity of the nanoantenna 21 to evanescent waves will decrease, and the effect of enhancing fluorescence will decrease. For this reason, it is preferable that the translucent member 24 is filled in the recess 18G to a predetermined height lower than the upper surface of the convex portion 18C.

[0079] [Method for manufacturing phosphor material] Here, we will describe the method for manufacturing the phosphor member 18 on which the translucent member 24 according to Example 2 is formed. Note that the process up to the step of forming recesses in the phosphor member by etching (step 3) is the same as in Example 1, so the explanation will be omitted.

[0080] First, a transparent dielectric film made of SiO2 or Al2O3 is deposited on the uneven structure of the phosphor member, which has been formed by patterning as in Example 1, by electron beam deposition or sputtering (Step 4A). This forms a light-transmitting member across the upper surface of the phosphor member.

[0081] Next, the translucent material deposited on each etching mask (resist) of the protrusions 18C is lifted off and removed along with the etching mask (step 5). This makes it possible to obtain a phosphor material 18 in which the recesses 18G are filled with translucent material 24.

[0082] Furthermore, the configuration in which the translucent member 24 is filled into the recesses 18G described above may also be applied to the modified configuration described above. That is, the configuration may be such that the translucent member 24 is filled into each of the multiple recesses 18G that are patterned in a striped manner. [Examples]

[0083] Next, Example 3 will be described using Figures 9 and 10. Figure 9 is a schematic cross-sectional view showing the configuration of the lighting device 300 according to Example 3. Figure 10 is a cross-sectional view of the wavelength conversion device 310. Note that hatching has been omitted in Figure 9 for visibility.

[0084] The housing 26 is a box-shaped housing, and each of its two opposing surfaces has openings OP1 and OP2. The housing 26 has a support structure 26A that supports an object at a position between opening OP1 and opening OP2. The support structure 26A has a through hole 26AO that penetrates the support structure 26A at its center.

[0085] The light source 27 is fixed within the aperture OP1 and emits light L1 having a predetermined wavelength toward the aperture OP2. The aperture OP1, the through hole 26AO, and the aperture OP2 are formed on the optical axis OA.

[0086] In this embodiment, the light source 27 is a laser light source having an emissive layer made of an InGaN-based semiconductor. Blue light with a peak wavelength of approximately 450 nm is emitted from the light source 27 as light L1.

[0087] The wavelength converter 310 is supported by the support structure 26A so as to be located on the optical axis OA. Specifically, the wavelength converter 310 is positioned on the upper surface of the support structure 26A such that the central part of the bottom surface through which the optical axis OA passes is exposed through the through hole 26AO of the support structure 26A. In other words, the wavelength converter 310 is supported by the support structure 26A in all areas except the central part of the bottom surface of the wavelength converter 310.

[0088] As shown in Figure 10, the wavelength conversion device 310 has nanoantennas 21 formed on the upper surfaces of the phosphor member 18 and the protrusions 18C of the phosphor member 18, as shown in Figure 2, and light reflecting members 22 formed on the side surface of the phosphor member 18. In other words, the wavelength conversion device 310 has a configuration that is the same as the wavelength conversion device 100 in Example 1, but without the mounting substrate 12 and the light-emitting element 13.

[0089] Similar to Example 1, the wavelength converter 310 is excited by excitation light (blue light) with a peak wavelength of 450 nm and emits fluorescence (yellow light) with a peak wavelength of 550 nm. Therefore, the wavelength converter 310 emits both the excitation light (blue light) that has passed through the phosphor material 18 without contributing to fluorescence generation, and the fluorescence (yellow light) emitted from the phosphor. In Figure 9, the excitation light and fluorescence emitted from the wavelength converter 310 are shown together as light L2.

[0090] Furthermore, a transparent support substrate made of, for example, single-crystal sapphire, which has high thermal conductivity, may be provided between the wavelength conversion device 310 and the support structure 26A. By providing this transparent support substrate, the heat generated by the wavelength conversion device 310 can be efficiently transferred to the support structure 26A.

[0091] Furthermore, a lens for focusing the laser light may be provided between the light source 27 and the incident surface of the light L1 of the wavelength conversion device 310. By providing such a lens, the laser light can be focused and efficiently irradiated onto the wavelength conversion device 310.

[0092] The lens 28 is an optical component fixed within the aperture OP2. That is, the lens 28 is positioned on the optical axis OA. The lens 28 is an optical lens that receives light L2 emitted from the wavelength conversion device 310, shapes the light L2 into a desired light distribution, and generates light L3 as illumination light. For example, a spherical lens or an aspherical lens can be used for the lens 28. The light L3 generated by the lens 28 is taken out to the outside of the housing 26.

[0093] In this embodiment, the space between the light source 27 and the wavelength converter 310 within the housing 26, and the space between the wavelength converter 310 and the lens 28, are filled with air. That is, the light L2 emitted from the wavelength converter 310 passes through the air and is incident on the lens 28.

[0094] The lighting device 300 having the configuration described above can also achieve the same effects as in Example 1. That is, the component of fluorescence above the critical angle in the phosphor member 18 can be reduced, and the component that is totally reflected at the interface between the phosphor member 18 and air can be reduced.

[0095] Therefore, the proportion of fluorescence extracted from the phosphor material 18 can be increased. Consequently, it is possible to improve the light extraction efficiency while achieving narrowing of the fluorescence angle by the nanoantenna 21.

[0096] In the above-described examples and modifications, the case in which the phosphor member 18 is made of a single-crystal YAG:Ce phosphor plate was explained, but the phosphor member 18 is not limited to this configuration as long as it has a structure that does not easily cause light scattering inside it. As a structure that does not easily cause scattering, a single-phase phosphor plate made of a single material is preferred, and in this case, it may be polycrystalline. For example, it may be a plate made of a resin or glass medium containing phosphor particles that emit yellow fluorescence.

[0097] Furthermore, in the embodiments and modifications described above, the case in which each of the protrusions 18C of the uneven structure of the phosphor member 18 is arranged in a square grid on the upper surface of the phosphor member 18 has been described, but the invention is not limited to this. For example, each of the protrusions 18C may have a triangular grid arrangement pattern on the upper surface of the phosphor member 18.

[0098] In the above-described embodiments and modifications, the case in which the nanoantenna 21 has a frustoconical shape was explained, but the shape is not limited to this, as long as the nanoantenna 21 can exert a fluorescence narrowing effect. For example, the nanoantenna 21 may have a columnar shape such as a cylinder or a conical shape such as a cone.

[0099] In the embodiments and modifications described above, the case in which the light-reflecting member 22 is provided has been explained, but depending on the desired light distribution, the light-reflecting member 22 may not be provided. Depending on the desired light distribution, an optical multilayer reflective film or a metallic reflective film may be used instead of the light-reflecting member 22, or a combination thereof may be provided on the side surfaces of the light-emitting element 13 and the phosphor member 18. [Explanation of symbols]

[0100] 100, 110, 200, 310 wavelength conversion device 300 Lighting devices 12 Implemented circuit board 13 Light-emitting element 14 Semiconductor structural layers 15 Support substrate 16p electrode 17 n electrode 18. Phosphor material 21 Nano Antennas 22 Light-reflecting member 24 Translucent member 26 cabinets 27. Light source (laser light source) 28 lenses

Claims

1. A phosphor member having one surface to which excitation light is incident, containing a phosphor that emits fluorescence when excited by the excitation light, and having a surface opposite to the one surface having a surface with a surface structure consisting of multiple protrusions, each provided in a direction along the other surface with a period smaller than the peak wavelength of the fluorescence, Multiple nano-antennas made of metal members arranged on the upper surface of the multiple protrusions, A wavelength conversion device characterized by having the following features.

2. The aforementioned uneven structure forms a square grid or triangular grid arrangement pattern. The wavelength conversion device according to claim 1, characterized in that each of the plurality of nanoantennas is arranged on the upper surface of each of the plurality of protrusions.

3. The aforementioned uneven structure forms a striped pattern arranged in the direction of 1, The wavelength conversion device according to claim 1, characterized in that the plurality of nanoantennas are arranged in a plurality along the extension direction of each of the plurality of protrusions.

4. The wavelength conversion device according to claim 1, characterized in that it has a translucent member that fills the recesses of the uneven structure, has a refractive index smaller than that of the phosphor member, and is translucent to the excitation light and the fluorescence.

5. The phosphor has the property of being excited by the excitation light and emitting fluorescence having the peak wavelength of 520 to 570 nm. The wavelength conversion device according to claim 1, characterized in that each of the plurality of protrusions has a height of 120 nm or less.

6. The wavelength conversion device according to claim 1, characterized in that the phosphor member consists of a single-phase phosphor plate.

7. The wavelength conversion device according to claim 1, characterized in that the plurality of nanoantennas are columnar, conical, or frustum-shaped.

8. The wavelength conversion device according to claim 1, characterized in that the plurality of nanoantennas are made of Al or Ag.

9. A wavelength conversion device according to claim 1, A light source that emits the excitation light toward the first surface of the phosphor member, A lighting device characterized by having the following features.

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