Secondary batteries

Abstract

A secondary battery 1 comprises a plurality of current collectors 50 that are electrically connected to a plurality of electrodes, and a terminal joined to the plurality of current collectors 50, wherein: an outer surface of the terminal in a joint portion J between the plurality of current collectors 50 and the terminal has a first undulating region R1 having an undulating shape; the first undulating region R1 includes a first undulating pattern P1 having a plurality of first recessed portions U1, and two second undulating patterns P2 having a plurality of second recessed portions U2 having an area, in a plan view of the outer surface of the terminal, that is larger than that of the first recessed portions U1; and the first undulating pattern P1 is located between the two second undulating patterns P2 in a plan view.

Description

Technical Field

[0001] The present disclosure relates to secondary batteries.

Background Art

[0002] Patent Document 1 discloses an ultrasonic bonding device including an anvil and a horn disposed opposite to the anvil. The ultrasonic bonding device of Patent Document 1 ultrasonically bonds a plurality of workpieces stacked on the anvil by pressurizing and vibrating the workpieces with the horn.

[0003] In the ultrasonic bonding device of Patent Document 1, the height of the outermost protrusion among a plurality of protrusions provided on at least one of the anvil and the horn is set to be smaller than the height of the inner protrusions. Thereby, in the workpiece, generation of cracks at the boundary between the gripping region sandwiched by the anvil and the horn and the non-gripping region not sandwiched by the anvil and the horn is suppressed. Therefore, the strength of the joint portion of the workpiece is improved, and the joint state of the joint portion can be stabilized.

Prior Art Documents

Patent Documents

[0004]

Patent Document 1

Summary of the Invention

Problems to be Solved by the Invention

[0005] However, in the ultrasonic bonding apparatus of Patent Document 1, if the height of the outermost protrusion is smaller than the height of the inner protrusion, the inner protrusion will wear out earlier than the outermost protrusion. As a result, when the difference between the height of the inner protrusion and the height of the outermost protrusion becomes small, cracks may occur at the boundary between the gripping area and the non-gripping area, reducing the strength of the bond and potentially causing variability in the bonding state of the bond. This is also true when the objects to be bonded are multiple current collectors and terminals of a secondary battery.

[0006] This disclosure has been made in view of the above, and aims to stabilize the connection state between multiple current collectors and terminals in a secondary battery. [Means for solving the problem]

[0007] The secondary battery of this disclosure comprises a laminate in which a plurality of electrodes are stacked, a plurality of current collectors electrically connected to the plurality of electrodes, and a terminal joined to the plurality of current collectors, wherein the outer surface of the terminal at the joint between the plurality of current collectors and the terminal has a first uneven region, the first uneven region having a first uneven pattern having a plurality of first recesses, and two second uneven patterns having a plurality of second recesses whose area in plan view of the outer surface of the terminal is larger than that of the first recess, and the first uneven pattern is located between the two second uneven patterns in plan view. [Effects of the Invention]

[0008] The secondary battery of this disclosure makes it possible to stabilize the connection state between multiple current collectors and terminals. [Brief explanation of the drawing]

[0009] [Figure 1] Figure 1 is a plan view of a secondary battery according to an embodiment of the present disclosure. [Figure 2] Figure 2 is a cross-sectional view of a secondary battery along the line II-II shown in Figure 1. [Figure 3]Figure 3 is a schematic diagram showing the process of joining the positive terminal to multiple current collectors. [Figure 4] Figure 4 is a plan view of the support surface of the anvil. [Figure 5] Figure 5 is a view of the anvil as indicated by arrow V shown in Figure 4. [Figure 6] Figure 6 is a plan view of the horn's pressing surface. [Figure 7] Figure 7 is a side view of the horn. [Figure 8] Figure 8 is a cross-sectional view of the horn along the line VIII-VIII shown in Figure 6. [Figure 9] Figure 9 is a cross-sectional view of the horn along the IX-IX line shown in Figure 6. [Figure 10] Figure 10 shows the amount of wear on the support surface of the anvil according to the embodiment of this disclosure shown in Figure 4, and the amount of wear on the support surface of the anvil in a comparative example. [Figure 11] Figure 11 is a plan view from the positive terminal side of the junction between multiple current collectors and the positive terminal. [Figure 12] Figure 12 is a magnified view of a portion of the first uneven region showing the first uneven pattern shown in Figure 11. [Figure 13] Figure 13 is a cross-sectional view of the joint. [Figure 14] Figure 14 is a magnified view of the first uneven region showing the first uneven pattern, the second uneven pattern, and the third uneven pattern shown in Figure 11. [Figure 15] Figure 15 is a plan view from the current collector side at the junction between multiple current collectors and the positive terminal. [Figure 16] Figure 16 is an enlarged view of the second uneven region shown in Figure 15. [Figure 17] Figure 17 is a cross-sectional view of the joint along the line XVII-XVII shown in Figure 16. [Figure 18] Figure 18 is a cross-sectional view of the joint along the line XVIII-XVIII shown in Figure 16. [Figure 19] Figure 19 is a plan view of an anvil used in a joining process according to a first modified example of the embodiment of this disclosure. [Figure 20] Figure 20 is an arrow view of the anvil by the arrow XX shown in Figure 19. [Figure 21] Figure 21 is a plan view of the anvil used in the bonding process according to the second modification of the embodiment of the present disclosure. [Figure 22] Figure 22 is a plan view of the anvil used in the bonding process according to the third modification of the embodiment of the present disclosure. [Figure 23] Figure 23 is a plan view of the anvil used in the bonding process according to the fourth modification of the embodiment of the present disclosure. [Figure 24] Figure 24 is a plan view of the anvil used in the bonding process according to the fifth modification of the embodiment of the present disclosure. [Figure 25] Figure 25 is a plan view of the anvil used in the bonding process according to the sixth modification of the embodiment of the present disclosure. [Figure 26] Figure 26 is a side view of the anvil and the horn according to the sixth modification of the embodiment of the present disclosure. [Figure 27] Figure 27 is a plan view of the anvil used in the bonding process according to the seventh modification of the embodiment of the present disclosure. [Figure 28] Figure 28 is a plan view of the anvil used in the bonding process according to the eighth modification of the embodiment of the present disclosure.

Mode for Carrying Out the Invention

[0010] Hereinafter, embodiments will be described in detail based on the drawings. Note that the present disclosure is not limited by this embodiment. Each embodiment is an example, and it is needless to say that partial substitution or combination of the configurations shown in different embodiments is possible.

[0011] Figure 1 is a plan view of the secondary battery 1 according to the embodiment of the present disclosure. Figure 2 is a cross-sectional view of the secondary battery 1 taken along the line II-II shown in Figure 1.

[0012] The secondary battery 1 is, for example, a lithium-ion battery. As shown in Figure 1, the secondary battery 1 comprises a laminate 10, a positive electrode terminal 20, a negative electrode terminal 30, an outer casing 40, and a current collector 50.

[0013] The laminate 10 is housed in the outer casing 40. As shown in Figure 2, the laminate 10 has a laminated structure and has multiple sheet-like positive electrodes 11 and negative electrodes 12, with multiple positive electrodes 11 and multiple negative electrodes 12 being alternately stacked via separators 13.

[0014] The positive terminal 20 is a plate-like shape with an L-shaped cross-section having a bent surface 21, with one end including the bent surface 21 located inside the outer casing 40. The other end of the positive terminal 20 is located outside the outer casing 40. The positive terminal 20 may also be an unbent plate-like shape.

[0015] The positive terminal 20 is electrically connected to each of the multiple positive electrodes 11 via multiple current collectors 50. The current collectors 50 are metal foils. The positive terminal 20 and the current collectors 50 connected to the positive terminal 20 are made of the same metal (e.g., aluminum). The joint J is formed when the positive terminal 20 and the multiple current collectors 50 are electrically joined (details will be described later).

[0016] The negative electrode terminal 30, like the positive electrode terminal 20, has an L-shaped cross-section with a bent surface, and one end including the bent surface is located inside the outer casing 40. The other end of the negative electrode terminal 30 is located outside the outer casing 40. The negative electrode terminal 30 is electrically connected to each of the multiple negative electrodes 12 via a plurality of current collectors 50. The negative electrode terminal 30 and the current collectors 50 connected to the negative electrode terminal 30 are each made of the same metal (for example, copper). The joint J is formed by the electrical connection between the negative electrode terminal 30 and the plurality of current collectors 50 (details will be described later). Note that the negative electrode terminal 30 and the current collectors 50 connected to the negative electrode terminal 30 may be made of different metals. For example, the material of the negative electrode terminal 30 may be copper, and the material of the current collectors 50 connected to the negative electrode terminal 30 may be nickel, nickel-plated copper, nickel-clad copper, etc.

[0017] As shown in Figure 1, the outer casing 40 has a housing section 41 for housing the laminate 10 and a flange section 42 around the housing section 41. The housing section 41 houses an electrolyte (for example, a non-aqueous electrolyte).

[0018] The outer casing 40 is formed by folding a single film. A portion of the film is formed into a convex shape, for example by press processing, to form a housing portion 41. The overlapping portions of the film around the housing portion 41 are joined together to form a flange portion 42, which prevents leakage of the electrolyte.

[0019] Next, the joint J between the positive terminal 20 and the multiple current collectors 50 will be described in detail. Figure 3 is a schematic diagram showing the process of joining the positive terminal 20 and the multiple current collectors 50.

[0020] The positive electrode terminal 20 and the multiple current collectors 50 are joined using an ultrasonic bonding machine 2. The ultrasonic bonding machine 2 includes an anvil 3 having a support surface 3a for supporting the workpiece, a horn 4 having a pressing surface 4a for pressing the workpiece, and an ultrasonic vibration generator 5 for applying ultrasonic vibrations to the horn 4. The horn 4 presses the positive electrode terminal 20 and the multiple current collectors 50 along a pressing direction D1 that is aligned with the thickness direction of the positive electrode terminal 20. The horn 4 also vibrates along a vibration direction D2 that is perpendicular to the pressing direction D1.

[0021] Figure 4 is a plan view of the support surface 3a of anvil 3. Figure 5 is a view of anvil 3 taken along the arrow V shown in Figure 4. Arrow V follows the third straight line L3, which will be described later.

[0022] As shown in Figure 4, the support surface 3a of the anvil 3 is rectangular in shape and extends along a first straight line L1 that is perpendicular to the vibration direction D2 of the horn 4 in a plan view. Note that the plan view of the support surface 3a is when the support surface 3a is viewed along the pressing direction D1. Furthermore, multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3 are arranged on the support surface 3a such that the support surface 3a is symmetrical with respect to the first straight line L1 as the axis of symmetry.

[0023] The first protrusion T1, the second protrusion T2, and the third protrusion T3 are each frustoconical in shape. That is, the upper and lower surfaces of the first protrusion T1, the second protrusion T2, and the third protrusion T3 are planar. The first protrusion T1, the second protrusion T2, and the third protrusion T3 that overlap with the periphery of the support surface 3a in plan view are shaped as if they have been cut off by the periphery of the support surface 3a in plan view. The shapes of the first protrusion T1, the second protrusion T2, and the third protrusion T3 will be described below in the state where they are not cut off by the periphery of the support surface 3a2.

[0024] As shown in Figure 5, the lower surfaces of each of the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3 are located on a first plane S1 perpendicular to the pressing direction D1. Furthermore, the upper surfaces of each of the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3 are located on a second plane S2 parallel to the first plane S1 (i.e., on the same plane). In other words, the heights of each of the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3 are equal to each other.

[0025] As shown in Figure 4, the first range A1 in which the multiple first protrusions T1 are arranged is located in the center of the support surface 3a in a direction along the first straight line L1 in a plan view. The lower and upper surfaces of the first protrusions T1 are square in shape in a plan view. Furthermore, the multiple first protrusions T1 are arranged adjacent to each other with their diagonals parallel to the first straight line L1. As a result, the multiple first protrusions T1 are arranged in a matrix along the second straight line L2 and the third straight line L3 that intersect the first straight line L1 in a plan view.

[0026] In plan view, the second line L2 and the third line L3 are perpendicular to each other, and the angles that the second line L2 and the third line L3 make with the first line L1 are equal to 45°. The side of the lower surface of the first projection T1 is parallel to either the second line L2 or the third line L3.

[0027] Furthermore, the edges of the lower surfaces of two adjacent first protrusions T1 are in contact with each other. In other words, the cross-section between two adjacent first protrusions T1 is V-shaped.

[0028] The second range A2, in which multiple second protrusions T2 are arranged, is located adjacent to the first range A1 on both sides of the first range A1 in the direction along the first straight line L1. Furthermore, the second range A2 is located outside the ranges extending from the first range A1 along the second straight line L2 and the third straight line L3, respectively.

[0029] The lower and upper surfaces of the second protrusion T2 are square in shape when viewed from above. In a plan view, the length of the sides on the lower surface of the second protrusion T2 is longer than the length of the sides on the lower surface of the first protrusion T1 (specifically, twice as long). That is, in a plan view, the area of ​​the lower surface of the second protrusion T2 is larger than the area of ​​the lower surface of the first protrusion T1 (specifically, four times as large). Also, in a plan view, the area of ​​the upper surface of the second protrusion T2 is larger than the area of ​​the upper surface of the first protrusion T1.

[0030] Furthermore, the multiple second protrusions T2 are arranged adjacent to each other such that the diagonals of their lower surfaces are parallel to the first straight line L1. As a result, the multiple second protrusions T2 are arranged in a matrix along the second straight line L2 and the third straight line L3 in a plan view. The edges of the lower surfaces of the second protrusions T2 are parallel to either the second straight line L2 or the third straight line L3.

[0031] Furthermore, the edges of the lower surfaces of two adjacent second protrusions T2 are in contact. In other words, the cross-section between two adjacent second protrusions T2 is V-shaped. And, the vertices of the lower surfaces of two adjacent second protrusions T2 and first protrusion T1 are in contact. In other words, the cross-section between two adjacent second protrusions T2 and first protrusion T1 is V-shaped.

[0032] The third range A3, where multiple third protrusions T3 are located, is situated in the range extending from the first range A1 along the second straight line L2 and the third straight line L3, respectively. The multiple third ranges A3 are located between the first range A1 and the second range A2 in the direction along the first straight line L1. The third ranges A3 are adjacent to the first range A1 in the direction along either the second straight line L2 or the third straight line L3. Furthermore, the multiple third ranges A3 are adjacent to the second range A2 in the direction along either the second straight line L2 or the third straight line L3.

[0033] The lower and upper surfaces of the third projection T3 are rectangular in shape when viewed from above. In plan view, the area of ​​the upper surface of the third projection T3 is larger than the area of ​​the upper surface of the first projection T1, and smaller than the area of ​​the upper surface of the second projection T2.

[0034] Furthermore, on the lower surface of the third projection T3, the length of the longer side is equal to the length of one side of the lower surface of the second projection T2, and the length of the shorter side is equal to the length of one side of the lower surface of the first projection T1. The multiple third projections T3 are arranged in a matrix along the second line L2 and the third line L3 in a plan view. The sides of the lower surface of the third projection T3 are parallel to either the second line L2 or the third line L3.

[0035] Furthermore, the lower edges of two adjacent third protrusions T3 are in contact with each other. In other words, the cross-section between two adjacent third protrusions T3 is V-shaped.

[0036] Furthermore, the adjacent third protrusion T3 and first protrusion T1 are adjacent to each other in a direction along either the second straight line L2 or the third straight line L3, and the lower edges of the adjacent third protrusion T3 and first protrusion T1 are in contact with each other. In other words, the cross-section between the adjacent third protrusion T3 and first protrusion T1 is V-shaped.

[0037] Furthermore, the adjacent third protrusion T3 and second protrusion T2 are adjacent to each other in a direction along either the second straight line L2 or the third straight line L3, and the lower edges of the adjacent third protrusion T3 and second protrusion T2 are in contact with each other. In other words, the cross-section between the adjacent third protrusion T3 and second protrusion T2 is V-shaped.

[0038] Furthermore, the inclination angles of the sides of the first protrusion T1, the second protrusion T2, and the third protrusion T3 are equal to each other. In a support surface 3a having such a shape, the manufacturing process can be simplified. Specifically, the multiple V-shaped grooves located between the first protrusion T1, the second protrusion T2, and the third protrusion T3, and formed by the sides of the first protrusion T1, the second protrusion T2, and the third protrusion T3, are continuous from one side to the other of the support surface 3a in a direction along one of the second straight line L2 and the third straight line L3. Therefore, by grinding the support surface 3a with a grinding wheel having a V-shaped corner in a direction along the second straight line L2 and the third straight line L3 from one side to the other of the support surface 3a, the multiple first protrusions T1, the multiple second protrusions T2, and the multiple third protrusions T3 can be easily formed.

[0039] Figure 6 is a plan view of the pressing surface 4a of the horn 4. Figure 7 is a side view of the horn 4. Figure 8 is a cross-sectional view of the horn 4 along the line VIII-VIII shown in Figure 6. Figure 9 is a cross-sectional view of the horn 4 along the line IX-IX shown in Figure 6.

[0040] The pressing surface 4a of the horn 4 is rectangular in shape and extends along the fourth straight line L4, which is perpendicular to the vibration direction D2 in a plan view. Note that the plan view of the pressing surface 4a is when viewed along the pressing direction D1. In the plan view, the corners of the pressing surface 4a are chamfered. In the plan view, the area of ​​the pressing surface 4a is smaller than the area of ​​the support surface 3a.

[0041] Multiple sixth protrusions T6 are arranged on the pressing surface 4a such that the pressing surface 4a has a line-symmetric shape with respect to the fourth line L4 as the axis of symmetry. The multiple sixth protrusions T6 are arranged in a matrix along the fifth line L5 and the sixth line L6, which intersect the fourth line L4 in a plan view.

[0042] In plan view, the fifth line L5 and the sixth line L6 are perpendicular to each other, and the angles that the fifth line L5 and the sixth line L6 make with the fourth line L4 are equal to 45°. The side of the lower surface of the sixth projection T6 is parallel to either the fifth line L5 or the sixth line L6.

[0043] The sixth projection T6 has a square-shaped lower surface, with its width decreasing towards the projection end. Two adjacent sixth projections T6 have their lower surfaces touching each other. Also, as shown in Figures 7, 8, and 9, the multiple sixth projections T6 are located on a third plane S3 perpendicular to the pressing direction D1, with their respective lower surfaces facing each other.

[0044] Furthermore, as shown in Figure 6, the multiple sixth protrusions T6 are arranged such that, in a plan view, the diagonals of their lower surfaces are parallel to the fourth straight line L4. Hereinafter, among the multiple sixth protrusions T6, the sixth protrusion T6 whose upper surface coincides with the fourth straight line L4 in a plan view will be referred to as the seventh protrusion T7, and the sixth protrusions T6 located on both sides of the seventh protrusion T7 in the vibration direction D2 will be referred to as the eighth protrusion T8.

[0045] As shown in Figure 7, the pressing surface 4a has a convex arc C in a side view perpendicular to the vibration direction D2 that passes through the periphery of the pressing surface 4a in the vibration direction D2 and extends outward from the horn 4. The seventh projection T7 does not overlap with the arc C in a side view. The seventh projection T7 is a frustoconical shape with a rectangular (specifically square) top and bottom surface. As shown in Figures 7 and 8, the top and side surfaces of the seventh projection T7 are straight in cross-sectional view.

[0046] On the other hand, the eighth projection T8 is arc-shaped in a side view, following the arc C. In other words, as shown in Figures 8 and 9, the top and side surfaces of the eighth projection T8 follow the arc C in a cross-sectional view. Specifically, the eighth projection T8 is shaped like the seventh projection T7, with the top side cut off by a curved surface that is arc C in a side view. As a result, the heights H2a and H2b of the eighth projection T8 are lower than the height H1 of the seventh projection T7.

[0047] Furthermore, among the multiple eighth protrusions T8, the closer the eighth protrusion T8 is to the periphery of the pressing surface 4a in the vibration direction D2 (in other words, the further it is from the center in the vibration direction D2), the lower its height. Specifically, the eighth protrusion T8 shown in Figure 8 is closer to the periphery of the pressing surface 4a in the vibration direction D2 than the eighth protrusion T8 shown in Figure 9, and the height H2b of the eighth protrusion T8 shown in Figure 8 is lower than the height H2a of the eighth protrusion T8 shown in Figure 9.

[0048] Furthermore, the height H1 of the seventh projection T7 is higher than the heights of the first projection T1, the second projection T2, and the third projection T3 of the anvil 3 (i.e., the distance between the first plane S1 and the second plane S2).

[0049] Next, the process of joining the positive terminal 20 and the multiple current collectors 50 (hereinafter referred to as the joining process) will be described. As shown in Figure 3, the positive terminal 20 is placed on the support surface 3a of the anvil 3 with the opposite side of the bent surface 21 of the positive terminal 20 in contact with it. Furthermore, the multiple current collectors 50 are arranged on top of the bent surface 21 of the positive terminal 20.

[0050] Furthermore, in a plan view along the pressing direction D1, the support surface 3a and the pressing surface 4a face each other in an overlapping state. At this time, in a plan view along the pressing direction D1, the first range A1, second range A2, and third range A3 of the support surface 3a each overlap with the multiple sixth protrusions T6 of the pressing surface 4a.

[0051] Next, the multiple current collectors 50 are pressed by the pressing surface 4a of the horn 4 along the pressing direction D1, and as the horn 4 vibrates along the vibration direction D2, the positive electrode terminal 20 and the multiple current collectors 50 are welded together and integrated, forming a joint J. The negative electrode terminal 30 and the multiple current collectors 50 are similarly joined using the ultrasonic bonding machine 2, forming a joint J.

[0052] As described above, the horn 4 extends along a fourth straight line L4 perpendicular to the vibration direction D2. As a result, on both sides of the horn 4 in the direction along the fourth straight line L4, vibrations of the horn 4 during the joining process occur not only along the vibration direction D2 but also along the pressing direction D1. Therefore, on the support surface 3a of the anvil 3, the load acting on the support surface 3a during the joining process is greater on both sides of the support surface 3a in the direction along the first straight line L1 than on the central part of the support surface 3a in the direction along the first straight line L1 perpendicular to the vibration direction D2, which may lead to greater wear on the support surface 3a.

[0053] To address the issue of wear on the support surface 3a, as described above, multiple first protrusions T1 are located in the center of the support surface 3a in the direction along the first straight line L1, and multiple second protrusions T2 are located at both ends of the support surface 3a in the direction along the first straight line L1. Furthermore, in a plan view, the area of ​​the upper surface of the second protrusions T2 is larger than the area of ​​the upper surface of the first protrusions T1. Therefore, the concentration of load acting on the support surface 3a during the joining process is suppressed at both ends of the support surface 3a in the direction along the first straight line L1, thereby suppressing wear on the support surface 3a.

[0054] Furthermore, as described above, the heights of the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3 are equal to each other. Therefore, it is possible to suppress the concentration of load acting on the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3. Consequently, it is possible to equalize the amount of wear on the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3.

[0055] In this way, wear of the support surface 3a can be suppressed at both ends of the support surface 3a in the direction along the first straight line L1, and the amount of wear of the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3 can be made uniform. Therefore, the connection state between the multiple current collectors 50 and the positive electrode terminal 20 at the joint J can be stabilized.

[0056] Figure 10 shows the amount of wear on the support surface 3a of the anvil 3 according to the embodiment of the present disclosure shown in Figure 4, and the amount of wear on the support surface of the anvil 6 of the comparative example. The vertical axis of Figure 10 shows the average amount of wear on each protrusion T1, T2, T3, and the horizontal axis of Figure 10 shows the number of connections (so-called shots) between the current collector 50 and the positive electrode terminal 20.

[0057] The comparative example anvil 6 differs from the anvil 3 of the above embodiment in that the entire support surface is formed by the first projection T1. In other words, the first projection T1 is arranged throughout the entire support surface of the comparative example anvil 6.

[0058] As shown in Figure 10, the average wear amount of the support surface 3a in the anvil 3 of this embodiment is less than the average wear amount of the support surface in the comparative example anvil 6. Furthermore, the difference between the average wear amount of the support surface 3a in the anvil 3 of this embodiment and the average wear amount of the support surface in the comparative example anvil 6 increases as the number of joining cycles increases. In other words, Figure 10 shows that the average wear amount of the support surface 3a in the anvil 3 of this embodiment is suppressed by suppressing wear of the support surface 3a at both ends of the support surface 3a in the direction along the first straight line L1 as described above, and by making the wear amount of the multiple first protrusions T1, multiple second protrusions T2, and multiple third protrusions T3 uniform.

[0059] Next, the condition of the outer surface of the joint J between the positive terminal 20 and the multiple current collectors 50 will be described in detail.

[0060] Figure 11 is a plan view of the joint J between the multiple current collectors 50 and the positive terminal 20, as seen from the positive terminal 20 side. The plan view of the joint J shown in Figure 11 is a plan view of the joint J as seen from the positive terminal 20 side along the thickness direction of the positive terminal 20. A plan view of the joint J means viewing the joint J along the thickness direction of the positive terminal 20.

[0061] The outer surface of the positive terminal 20 at the joint J has a first uneven region R1 with multiple depressions that are recessed in the thickness direction of the positive terminal 20. The dashed line shown in Figure 11 indicates the periphery of the first uneven region R1. The first uneven region R1 is formed when the current collector 50 is pressed by the horn 4 along the pressing direction D1 while the positive terminal 20 is supported on the support surface 3a of the anvil 3.

[0062] The first uneven region R1 extends along the first direction W1. When the joint J is supported by the anvil 3 during joining, the first direction W1 is approximately perpendicular to the pressing direction D1 and the vibration direction D2, respectively. The first uneven region R1 has a first uneven pattern P1, two second uneven patterns P2, and four third uneven patterns P3. The seventh line L7, eighth line L8, ninth line L9, and tenth line L10 shown in Figure 11 indicate the boundaries of the first uneven pattern P1, the second uneven pattern P2, and the third uneven pattern P3 (details will be described later).

[0063] The first uneven pattern P1 is located in the center of the first uneven region R1 in the first direction W1. In a plan view, the first uneven pattern P1 is located between two second uneven patterns P2. Specifically, in the first direction W1, the first uneven pattern P1 is located between two second uneven patterns P2. The first uneven pattern P1 has multiple first recesses U1.

[0064] Furthermore, regarding the first recess U1, and the second and third recesses U2 and U3 described later, the first recess U1, second recess U2 and third recess U3 that overlap with the periphery of the first uneven region R1 in a plan view have a shape that is cut off by the periphery of the first uneven region R1 in a plan view. Below, the shapes of the first recess U1, second recess U2 and third recess U3 will be described as those that are not cut off by the periphery of the first uneven region R1.

[0065] Multiple first recesses U1 are arranged in a matrix along second and third directions W2 and W3, which intersect each other in a plan view. In this embodiment, the second and third directions W2 and W3 are orthogonal to each other in a plan view. The second and third directions W2 and W3 each intersect with the first direction W1.

[0066] Figure 12 is a magnified view of a portion of the first uneven region R1 showing the first uneven pattern P1 shown in Figure 11. Figure 12 is a magnified view of the area indicated by the rectangular frame XI shown in Figure 11. The bottom B1 of the first recess U1 corresponds to the shape of the upper surface of the first projection T1 of the support surface 3a. Specifically, the bottom B1 of the first recess U1 is planar and square in plan view. In this specification, planar means a range having a predetermined surface roughness that is sufficiently small compared to the step between the periphery of the bottom B1 of the first recess U1 and the bottom B1 in the pressing direction D1. The sufficiently small predetermined surface roughness is 1 / 10 or less of the step between the periphery of the bottom B1 of the first recess U1 and the bottom B1 in the pressing direction D1. Surface roughness can be measured by measuring and analyzing the three-dimensional shape of the surface of the bottom B1 using a non-contact surface roughness measuring instrument such as a laser microscope. The non-contact surface roughness measuring instrument is set to a magnification of 200x, and a measurement range of 0.05 mm in diameter is set near the center of the bottom B1 of the first recess D1 to obtain the surface roughness. For example, when the measured roughness Ry (μm) is 20 (μm) or less, it can be determined that the bottom B1 is planar. Note that the roughness Ry is the maximum height specified in JIS B 0601 (1994) and JIS B 0031 (1994). In the second direction W2 and the third direction W3, the distance between the bottom B1s of two adjacent first recesses U1 (specifically, the distance between the center points of the bottom B1s of the first recesses U1 in a plan view) is equal to each other.

[0067] Figure 13 is a cross-sectional view of the joint J. As described above, the upper surfaces of the multiple first protrusions T1 are located on the same plane, so the bottoms B1 of the multiple first recesses U1 are located on the fourth plane S4 (i.e., on the same plane).

[0068] As shown in Figure 11, the second uneven pattern P2 is located adjacent to the first uneven pattern P1 on both outer sides in the first direction W1. Furthermore, in a plan view, the second uneven pattern P2 is located outside the range extending from the first uneven pattern P1 along the second direction W2 and the third direction W3. The second uneven pattern P2 has multiple second recesses U2.

[0069] The multiple second recesses U2 are arranged in a plan view along either the second direction W2 or the third direction W3. In this embodiment, the multiple second recesses U2 are arranged in a matrix along the second direction W2 and the third direction W3 in a plan view. In a plan view, the area of ​​the second recesses U2 is greater than the area of ​​the first recess U1.

[0070] Figure 14 is a magnified view of the first uneven region R1 showing the first uneven pattern P1, the second uneven pattern P2, and the third uneven pattern P3 shown in Figure 11. Figure 14 is a magnified view of the area indicated by the rectangular frame XIV shown in Figure 11. The bottom B2 of the second recess U2 corresponds to the shape of the upper surface of the second projection T2 of the support surface 3a. Specifically, the bottom B2 of the second recess U2 is planar and square in plan view. Also, the area of ​​the bottom B2 of the second recess U2 is larger than the area of ​​the bottom B1 of the first recess U1. Furthermore, in the first direction W1, the length of the bottom B2 of the second recess U2 is longer than the length of the bottom B1 of the first recess U1.

[0071] In both the second direction W2 and the third direction W3, the distance between the bottoms B2 of two adjacent second recesses U2 (specifically, the distance between the center points of the bottoms B2 of the second recesses U2 in a plan view) is equal. Also, in both the second direction W2 and the third direction W3, the distance between the bottoms B2 of two adjacent second recesses U2 is greater than the distance between the bottoms B1 of two adjacent first recesses U1.

[0072] As shown in Figure 13, the bottoms B2 of the multiple second recesses U2 are located on the fourth plane S4 (i.e., on the same plane), similar to the bottoms B1 of the multiple first recesses U1. As described above, the upper surfaces of the multiple first protrusions T1 and the upper surfaces of the multiple second protrusions T2 are located on the same plane, so the bottoms B1 of the multiple first recesses U1 and the bottoms B2 of the multiple second recesses U2 are located on the same plane.

[0073] As shown in Figure 11, the third uneven pattern P3 is located in the range extending from the first uneven pattern P1 along the second direction W2 and the third direction W3, respectively. The third uneven pattern P3 is located between the first uneven pattern P1 and the second uneven pattern P2 in the first direction W1. The third uneven pattern P3 is adjacent to the first uneven pattern P1 in either the second direction W2 or the third direction W3. Also, the third uneven pattern P3 is adjacent to the second uneven pattern P2 in either the second direction W2 or the third direction W3. The third uneven pattern P3 has multiple third recesses U3.

[0074] The multiple third recesses U3 are aligned in a plan view along at least one of the second direction W2 and the third direction W3. In a plan view, the area of ​​the third recesses U3 is greater than the area of ​​the first recess U1 and less than the area of ​​the second recess U2.

[0075] The bottom B3 of the third recess U3 shown in Figure 14 corresponds to the shape of the upper surface of the third projection T3 of the support surface 3a. Specifically, the bottom B3 of the third recess U3 is planar and rectangular in plan view. Furthermore, the area of ​​the bottom B3 of the third recess U3 is larger than the area of ​​the bottom B1 of the first recess U1 and smaller than the area of ​​the bottom B2 of the second recess U2.

[0076] The distance between the bottom B3 of two adjacent third recesses U3 in the second direction W2 (specifically, the distance between the center points of the bottom B3 of the third recesses U3 in a plan view) is different from the distance between the bottom B3 of two adjacent third recesses U3 in the third direction W3.

[0077] Specifically, for a third uneven pattern P3 adjacent to a first uneven pattern P1 in the second direction W2, the distance between the bottoms B3 of two adjacent third recesses U3 in the second direction W2 is equal to the distance between the bottoms B2 of two adjacent second recesses U2 in the second direction W2 and the third direction W3, and the distance between the bottoms B3 of two adjacent third recesses U3 in the third direction W3 is equal to the distance between the bottoms B1 of two adjacent first recesses U1 in the second direction W2 and the third direction W3.

[0078] Furthermore, for a third uneven pattern P3 adjacent to a first uneven pattern P1 in the third direction W3, the distance between the bottom B3 of two adjacent third recesses U3 in the second direction W2 is equal to the distance between the bottom B1 of two adjacent first recesses U1 in the second direction W2 and the third direction W3, and the distance between the bottom B3 of two adjacent third recesses U3 in the third direction W3 is equal to the distance between the bottom B1 of two adjacent first recesses U1 in the second direction W2 and the third direction W3.

[0079] As shown in Figure 13, the bottoms B3 of the multiple third recesses U3 are located on the fourth plane S4 (i.e., on the same plane), similar to the bottoms B1 of the multiple first recesses U1 and the bottoms B2 of the multiple second recesses U2. As described above, the top surfaces of the multiple first protrusions T1, the multiple second protrusions T2, and the multiple third protrusions T3 are located on the same plane, so the bottoms B1 of the multiple first recesses U1, the bottoms B2 of the multiple second recesses U2, and the bottoms B3 of the multiple third recesses U3 are located on the same plane.

[0080] Furthermore, the seventh line L7 and the ninth line L9 are parallel to the second direction W2. Also, the seventh line L7 and the ninth line L9 pass between the first recess U1 and the third recess U3, and between the third recess U3 and the second recess U2, which are adjacent to each other in the third direction W3. And the eighth line L8 and the tenth line L10 are parallel to the third direction W3. Also, the eighth line L8 and the tenth line L10 pass between the first recess U1 and the third recess U3, and between the third recess U3 and the second recess U2, which are adjacent to each other in the second direction W2. In other words, the seventh line L7, the eighth line L8, the ninth line L9, and the tenth line L10 correspond to the edges between the adjacent first unevenness patterns P1, P2, and P3.

[0081] Furthermore, the ranges of the first unevenness pattern P1, the second unevenness pattern P2, and the third unevenness pattern P3 can be defined by drawing the periphery of the first unevenness region R1, the seventh straight line L7, the eighth straight line L8, the ninth straight line L9, and the tenth straight line L10 on an image of the outer surface of the joint J magnified to, for example, 100 times. In addition, the distance between the center points of the bottom B1 of the first recess U1, the distance between the center points of the bottom B2 of the second recess U2, the distance between the center points of the bottom B3 of the third recess U3, the area of ​​the first recess U1, the area of ​​the second recess U2, the area of ​​the third recess U3, the area of ​​the bottom B1 of the first recess U1, the area of ​​the bottom B2 of the second recess U2, and the area of ​​the bottom B3 of the third recess U3 can also be measured using an image of the outer surface of the joint J magnified to, for example, 100 times.

[0082] As described above, in the joining process, on both sides of the horn 4 in the first direction W1, which is perpendicular to the vibration direction D2, vibrations of the horn 4 during the joining process occur not only along the vibration direction D2 but also along the pressing direction D1. Therefore, the load acting on the first uneven region R1 during the joining process is greater on both sides of the first uneven region R1 in the first direction W1 than in the center of the first uneven region R1 in the first direction W1, which may cause cracks to form in the joint J.

[0083] To address the issue of cracking in the joint J, as described above, multiple first recesses U1 are located in the center of the first uneven region R1 in the first direction W1, and multiple second recesses U2 are located at both ends of the first uneven region R1 in the first direction W1. Furthermore, in a plan view, the area of ​​the second recesses U2 is larger than the area of ​​the first recesses U1. Therefore, the concentration of load acting on the joint J during the joining process is suppressed at both ends of the first uneven region R1 in the first direction W1.

[0084] Furthermore, when multiple second recesses U2 are located at both ends of the first uneven region R1 in the first direction W1, the area of ​​the second recesses U2 is larger than the area of ​​the first recess U1, which suppresses local compression of the joint J at both ends of the first uneven region R1. Therefore, it is possible to suppress the occurrence of cracks in the joint J and stabilize the joint state between the multiple current collectors 50 and the positive electrode terminals 20 at the joint J.

[0085] Furthermore, as described above, the bottoms B1 of the multiple first recesses U1, B2 of the multiple second recesses U2, and B3 of the multiple third recesses U3 are located on the same plane. Therefore, compared to the case where the bottoms B1 of the multiple first recesses U1, B2 of the multiple second recesses U2, and B3 of the multiple third recesses U3 are located on different planes, local compression of the joint J is suppressed. Consequently, the occurrence of cracks in the joint J can be suppressed, and the joint state between the multiple current collectors 50 and the positive electrode terminals 20 at the joint J can be stabilized.

[0086] Figure 15 is a plan view of the joint J between the multiple current collectors 50 and the positive terminal 20, as seen from the current collector 50 side. In other words, the plan view of the joint J shown in Figure 15 is a plan view of the joint J as seen from the current collector 50 side along the thickness direction of the positive terminal 20.

[0087] The outer surface of the current collector 50 at the joint J has a second uneven region R2 with multiple recesses that are recessed in the thickness direction of the positive terminal 20. The second uneven region R2 is formed when the current collector 50 is pressed by the horn 4 along the pressing direction D1 while the positive terminal 20 is supported on the support surface 3a of the anvil 3. The second uneven region R2 extends along the first direction W1. The second uneven region R2 has multiple sixth recesses U6.

[0088] Figure 16 is an enlarged view of the second uneven region R2 shown in Figure 15. Figure 17 is a cross-sectional view of the joint J along the line XVII-XVII shown in Figure 16. Figure 18 is a cross-sectional view of the joint J along the line XVIII-XVIII shown in Figure 16.

[0089] The multiple sixth recesses U6 correspond to the shapes of the sixth protrusions T6 (seventh protrusions T7 and eighth protrusions T8: see Figures 7, 8, and 9) of the pressing surface 4a. Specifically, the sixth recess U6 located in the center of the second uneven region R2 in the vibration direction D2 corresponds to the shape of the seventh protrusion T7 of the horn 4. Also, the sixth recesses U6 located on both sides of the second uneven region R2 in the vibration direction D2 correspond to the shapes of the eighth protrusion T8. As shown in Figure 16, the multiple sixth recesses U6 are arranged in a matrix along the second direction W2 and the third direction W3.

[0090] As described above, the height of the eighth protrusion T8 of the horn 4 is lower than the height of the seventh protrusion T7. Also, the depth of the sixth recess U6 becomes shallower as it approaches the periphery of the second uneven region R2 in the vibration direction D2. Therefore, as shown in Figures 17 and 18, when the seventh straight line L7 connecting the peripheries E of the second uneven region R2 on both sides in the vibration direction D2 is used as a reference, the bottom B6a of the sixth recess U6 located in the center of the vibration direction D2 is the deepest among the multiple sixth recesses U6. Furthermore, the depth of the bottom of the sixth recess U6 becomes shallower as it approaches the periphery E of the second uneven region R2 in the vibration direction D2.

[0091] Specifically, in the multiple sixth recesses U6 shown in Figures 17 and 18, the bottom B6a of the sixth recess U6 located in the center of the vibration direction D2 shown in Figure 17, the bottom B6b of the sixth recess U6 located outside the center in the vibration direction D2 shown in Figure 18, and the bottom B6c of the sixth recess U6 located outside the center in the vibration direction D2 shown in Figure 17 are, in this order, closer to the periphery E of the second uneven region R2 in the vibration direction D2. Furthermore, the depth of bottom B6a, the depth of bottom B6b, and the depth of bottom B6c become shallower in this order.

[0092] As a result, in the vibration direction D2, the compressibility of the joint J at the bottom of the sixth recess U6 decreases as it approaches the periphery E of the second uneven region R2. In other words, damage to the current collector 50 at the periphery of the second uneven region R2 in the vibration direction D2 is suppressed during the joining process. Therefore, the joining state between multiple current collectors 50 and the positive electrode terminal 20 can be stabilized.

[0093] Furthermore, as described above, the eighth projection T8 of the horn 4 is arc-shaped in cross-sectional view, following the arc C that passes through the periphery of the pressing surface 4a in the vibration direction D2. Therefore, as shown in Figures 17 and 18, in the sixth recess U6, which is located outside the center in the vibration direction D2 and extends to the periphery E of the second uneven region R2, the outer surface connecting the periphery E of the second uneven region R2 and the bottom is arc-shaped in cross-section, almost following the arc C.

[0094] As a result, in the sixth recess U6 that extends to the periphery of the second uneven region R2 in the vibration direction D2, the compressibility of the joint J decreases from the bottom toward the periphery E of the second uneven region R2. In other words, damage to the current collector 50 at the periphery of the second uneven region R2 in the vibration direction D2 is suppressed during the joining process. Therefore, the joining state between multiple current collectors 50 and the positive electrode terminal 20 can be stabilized.

[0095] Furthermore, as described above, the top surface of the seventh projection T7 of the horn 4 is flat. Therefore, the bottom B6a of the sixth recess U6 located in the center of the vibration direction D2 shown in Figure 16 is flat.

[0096] As a result, in the central part of the vibration direction D2, the high compressibility of the joint J is suppressed because it is compressed in a planar manner, preventing damage to the current collector 50. Therefore, the connection state between multiple current collectors 50 and the positive electrode terminal 20 can be stabilized.

[0097] Furthermore, as described above, the height H1 of the seventh protrusion T7 corresponding to the second uneven region R2 is higher than the heights of the first protrusion T1, second protrusion T2, and third protrusion T3 corresponding to the first uneven region R1. As a result, as shown in Figure 13, the depth De1 corresponding to the depth of the first recess U1, the depth of the second recess U2, and the depth of the third recess U3 in the first uneven region R1 is shallower than the depth De2 corresponding to the deepest part (i.e., bottom B6a) of the sixth recess U6 in the second uneven region R2. In other words, the depth of the first uneven region R1 is shallower than the depth of the second uneven region R2. As a result, the compression ratio of the joint J on the positive terminal 20 side is lower than that of the joint J on the current collector 50 side. Therefore, it is possible to suppress the occurrence of cracks in the joint J on the positive terminal 20 side and stabilize the joint state between the multiple current collectors 50 and the positive terminal 20 at the joint J.

[0098] Furthermore, the connection between the multiple current collectors 50 and the negative terminal 30 is carried out in the same manner as the connection between the multiple current collectors 50 and the positive terminal 20. In other words, the connection portion J between the multiple current collectors 50 and the negative terminal 30 has a first uneven region R1 and a second uneven region R2 formed thereon, similar to the connection portion J between the multiple current collectors 50 and the positive terminal 20. Therefore, the connection portion J between the multiple current collectors 50 and the negative terminal 30 can stabilize the connection state between the multiple current collectors 50 and the negative terminal 30, similar to the connection portion J between the multiple current collectors 50 and the positive terminal 20 described above.

[0099] Next, the joint J according to the first modified example of the embodiment of this disclosure will be described, primarily in terms of its differences from the joint J according to the above embodiment.

[0100] Figure 19 is a plan view of an anvil 3 used in a joining process according to a first modified embodiment of the present disclosure. Figure 20 is a view of the anvil 3 along the arrow XX shown in Figure 19. Arrow XX is along the third direction W3.

[0101] In the support surface 3a1 of the anvil 3 according to this first modification, the multiple first projections T1 are pyramidal in shape. The multiple third projections T3 have a triangular cross-section with a square lower surface. The multiple second projections T2 are truncated square pyramidal in shape, similar to the second projections T2 in the above embodiment.

[0102] When the joining process is performed using such anvil 3, the bottom B1 of the first recess U1, the bottom B2 of the second recess U2, and the bottom B3 of the third recess U3 in the first uneven region R1 of the joint J will have the following shapes. That is, the bottom B1 of the first recess U1 corresponding to the shape of the first protrusion T1 has a V-shaped cross-section. The bottom B3 of the third recess U3 corresponding to the shape of the third protrusion T3 has a V-shaped cross-section. The bottom B2 of the second recess U2 corresponding to the shape of the second protrusion T2 is planar, similar to the bottom B2 of the second recess U2 in the above embodiment, and is square in plan view.

[0103] Next, the differences between the joint J in the second modified example of the embodiment of this disclosure and the joint J in the first modified example of the embodiment described above will be explained. Figure 21 is a plan view of the anvil 3 used in the joining process in the second modified example of the embodiment of this disclosure.

[0104] The support surface 3a2 of the anvil 3 in this second modified example further comprises a plurality of first protrusions T1, a plurality of second protrusions T2, and a plurality of third protrusions T3, as well as a plurality of fourth protrusions T4 and a plurality of fifth protrusions T5. The fourth protrusions T4 and fifth protrusions T5, which overlap with the periphery of the support surface 3a2 in plan view, are shaped as if they have been cut off by the periphery of the support surface 3a2 in plan view. The shapes of the fourth protrusions T4 and fifth protrusions T5 will be described below in a state where they are not cut off by the periphery of the support surface 3a2.

[0105] The fourth range A4, where multiple fourth protrusions T4 are located, is positioned adjacent to the second range A2 on both sides of the two second ranges A2 in the direction along the first straight line L1. Furthermore, the fourth range A4 is located off-center from the directions extending from the second range A2 along the second straight line L2 and the third straight line L3, respectively.

[0106] The multiple fourth protrusions T4 are frustum-shaped. That is, the top and bottom surfaces of the fourth protrusions T4 are planar. The bottom and top surfaces of the multiple fourth protrusions T4 are square in plan view. In plan view, the length of the sides on the bottom surface of the fourth protrusion T4 is longer than the length of the sides on the bottom surface of the second protrusion T2 (specifically, twice as long). That is, in plan view, the area of ​​the bottom surface of the fourth protrusion T4 is larger than the area of ​​the bottom surface of the second protrusion T2 (specifically, four times as large). Also, in plan view, the area of ​​the top surface of the fourth protrusion T4 is larger than the area of ​​the top surface of the second protrusion T2.

[0107] Furthermore, the multiple fourth protrusions T4 are arranged adjacent to each other such that the diagonals of their lower surfaces are parallel to the first straight line L1. As a result, the multiple fourth protrusions T4 are arranged in a matrix along the second straight line L2 and the third straight line L3 in a plan view. The edges of the lower surfaces of the multiple fourth protrusions T4 are parallel to either the second straight line L2 or the third straight line L3.

[0108] Furthermore, the edges of the lower surfaces of the two adjacent fourth protrusions T4 are in contact. In other words, the cross-section between the two adjacent second protrusions T2 is V-shaped. And, the vertices of the lower surfaces of the adjacent fourth protrusions T4 and second protrusions T2 are in contact. In other words, the cross-section between the adjacent fourth protrusions T4 and second protrusions T2 is V-shaped.

[0109] The fifth range A5, where multiple fifth protrusions T5 are located, is adjacent to the second range A2 in the direction along the second line L2 and the third line L3, respectively. Furthermore, the fifth range A5 is adjacent to the fourth range A4 in the direction along the second line L2 and the third line L3, respectively.

[0110] The multiple fifth protrusions T5 have a triangular cross-section with a square-shaped lower surface. The lower and upper surfaces of the fifth protrusions T5 are rectangular in plan view. In plan view, the area of ​​the upper surface of the fifth protrusion T5 is larger than the area of ​​the upper surface of the second protrusion T2, and smaller than the area of ​​the upper surface of the fourth protrusion T4.

[0111] Furthermore, on the lower surface of the fifth projection T5, the length of the longer side is equal to the length of one side of the lower surface of the fourth projection T4, and the length of the shorter side is equal to the length of one side of the lower surface of the second projection T2. ​​The multiple fifth projections T5 are arranged along one of the second line L2 and the third line L3 in a plan view. The sides of the lower surface of the multiple third projections T3 are parallel to one of the second line L2 and the third line L3. Note that the multiple fifth projections T5 may be arranged in a matrix along the second line L2 and the third line L3 in a plan view.

[0112] Furthermore, the lower edges of two adjacent fifth protrusions T5 are in contact with each other. In other words, the cross-section between two adjacent fifth protrusions T5 is V-shaped.

[0113] Furthermore, the adjacent fifth protrusions T5 and fifth protrusions T5 are adjacent to each other in a direction along either the second straight line L2 or the third straight line L3, and the lower edges of the adjacent fifth protrusions T5 and fifth protrusions T5 are in contact with each other. In other words, the cross-section between the adjacent fifth protrusions T5 and fifth protrusions T5 is V-shaped.

[0114] Furthermore, the adjacent fifth protrusion T5 and fourth protrusion T4 are adjacent to each other in a direction along either the second straight line L2 or the third straight line L3, and the lower edges of the adjacent fifth protrusion T5 and fourth protrusion T4 are in contact with each other. In other words, the cross-section between the adjacent fifth protrusion T5 and fourth protrusion T4 is V-shaped.

[0115] Furthermore, the inclination angles of the sides of the first protrusion T1, second protrusion T2, third protrusion T3, fourth protrusion T4, and fifth protrusion T5 are equal to each other. Therefore, the manufacturing process can be simplified in a support surface 3a2 having such a shape. Specifically, the V-shaped grooves between the first protrusion T1, second protrusion T2, third protrusion T3, fourth protrusion T4, and fifth protrusion T5 are continuous from one side to the other of the support surface 3a2 in the direction along the second straight line L2 and the third straight line L3. Therefore, by moving a grinding wheel having a V-shaped cross-section corner along the second straight line L2 and the third straight line L3 from one side to the other side of the support surface 3a2 and grinding the support surface 3a2, the above-mentioned number of first protrusions T1, multiple second protrusions T2, multiple third protrusions T3, multiple fourth protrusions T4, and multiple fifth protrusions T5 can be easily formed.

[0116] By performing the joining process using such an anvil 3, the first uneven region R1 of the joint J in this second modified example further has two fourth uneven patterns (not shown) and four fifth uneven patterns (not shown), in addition to the first uneven pattern P1, second uneven pattern P2, and third uneven pattern P3 described above.

[0117] The fourth uneven pattern is located adjacent to the first uneven pattern P1 on both outer sides of the two second uneven patterns P2 in the first direction W1. In other words, the two second uneven patterns P2 are located between the two fourth uneven patterns in the first direction W1. Furthermore, the fourth uneven pattern is located outside the range extending from the second uneven pattern P2 along the second direction W2 and the third direction W3 in a plan view. The fourth uneven pattern has multiple fourth recesses (not shown).

[0118] The multiple fourth recesses are arranged along either the second direction W2 or the third direction W3 in a plan view. Alternatively, the multiple fourth recesses may be arranged in a matrix along the second direction W2 and the third direction W3 in a plan view. In a plan view, the area of ​​the fourth recesses is greater than the area of ​​the second recess U2.

[0119] Furthermore, the bottom of the fourth recess corresponds to the shape of the upper surface of the fourth projection T4 of the support surface 3a2. Specifically, the bottom of the fourth recess is planar and square in plan view. Also, the area of ​​the bottom of the fourth recess is larger than the area of ​​the bottom of the fourth recess.

[0120] In both the second direction W2 and the third direction W3, the distance between the bottoms of two adjacent fourth recesses (specifically, the distance between the center points of the bottoms of the fourth recesses in a plan view) is equal to that of each other. Also, in both the second direction W2 and the third direction W3, the distance between the bottoms of two adjacent fourth recesses is greater than the distance between the bottoms B2 of two adjacent second recesses U2.

[0121] The bottoms of the multiple fourth recesses lie on the fourth plane S4 (see Figure 13). Therefore, the bottoms B1 of the multiple first recesses U1, the bottoms B2 of the multiple second recesses U2, the bottoms B3 of the multiple third recesses U3, and the bottoms of the multiple fourth recesses lie on the same plane.

[0122] The fifth uneven pattern is located in the range extending from the second uneven pattern P2 along the second direction W2 and the third direction W3, respectively. In the first direction W1, the fifth uneven pattern is located between the second uneven pattern P2 and the fourth uneven pattern. The fifth uneven pattern is adjacent to the second uneven pattern P2 in either the second direction W2 or the third direction W3. Also, the fifth uneven pattern is adjacent to the fourth uneven pattern in either the second direction W2 or the third direction W3. The fifth uneven pattern has multiple fifth recesses (not shown).

[0123] The multiple fifth recesses are aligned in a plan view along at least one of the second direction W2 and the third direction W3. In a plan view, the area of ​​the fifth recess is greater than the area of ​​the second recess U2 and less than the area of ​​the fourth recess.

[0124] The bottom of the fifth recess corresponds to the shape of the upper surface of the fifth projection T5 of the support surface 3a. Specifically, the bottom of the fifth recess is planar and rectangular in plan view. Furthermore, the area of ​​the bottom of the fifth recess is larger than the area of ​​the bottom B2 of the second recess U2 and smaller than the area of ​​the bottom of the fourth recess.

[0125] The distance between the bottoms of two adjacent fifth recesses in the second direction W2 (specifically, the distance between the center points of the bottoms of the fifth recesses in a plan view) is different from the distance between the bottoms of two adjacent fifth recesses in the third direction W3.

[0126] Specifically, for a fifth uneven pattern adjacent to a second uneven pattern P2 in the second direction W2, the distance between the bottoms of two adjacent fifth recesses in the second direction W2 is equal to the distance between the bottoms of two adjacent fourth recesses in the second direction W2 and the third direction W3, and the distance between the bottoms of two adjacent fifth recesses in the third direction W3 is equal to the distance between the bottoms B2 of two adjacent second recesses U2 in the second direction W2 and the third direction W3.

[0127] Furthermore, for a fifth uneven pattern adjacent to a second uneven pattern P2 in the third direction W3, the distance between the bottoms of two adjacent fifth recesses in the third direction W3 is equal to the distance between the bottoms of two adjacent fourth recesses in the second direction W2 and the third direction W3, and the distance between the bottoms of two adjacent fifth recesses in the second direction W2 is equal to the distance between the bottoms B2 of two adjacent second recesses U2 in the second direction W2 and the third direction W3.

[0128] The bottoms B3 of the multiple third recesses U3 are located on the fourth plane S4 (see Figure 13). Therefore, the bottoms B1 of the multiple first recesses U1, the bottoms B2 of the multiple second recesses U2, the bottoms B3 of the multiple third recesses U3, the bottoms of the multiple fourth recesses, and the bottoms of the multiple fifth recesses are located on the same plane.

[0129] Next, the differences between the joint J according to the third modified embodiment of the present disclosure and the joint J according to the above embodiment will be explained. Figure 22 is a plan view of the anvil 3 used in the joining process according to the third modified embodiment of the present disclosure.

[0130] In the support surface 3a3 of the anvil 3 according to this third modification, the first projection T1, the second projection T2, and the third projection T3 are frustoconical in shape, with the lower and upper surfaces being rectangular, respectively. Furthermore, because the lower surface of the first projection T1 is rectangular, the shape of the third projection T3 located in the third range A3 adjacent to the first range A1 in the second direction W2 is different from the shape of the third projection T3 located in the third range A3 adjacent to the first range A1 in the third direction W3.

[0131] When the joining process is carried out using such anvil 3, the bottom B1 of the first recess U1, the bottom B2 of the second recess U2, and the bottom B3 of the third recess U3 in the first uneven region R1 of the joint J will have the following shapes. That is, the bottom B1 of the first recess U1 corresponding to the shape of the first protrusion T1, the bottom B2 of the second recess U2 corresponding to the shape of the second protrusion T2, and the bottom B3 of the third recess U3 corresponding to the shape of the third protrusion T3 are all planar and rectangular in plan view.

[0132] Next, the differences between the joint J according to the fourth modified embodiment of the present disclosure and the joint J according to the above embodiment will be explained. Figure 23 is a plan view of the anvil 3 used in the joining process according to the fourth modified embodiment of the present disclosure.

[0133] In the support surface 3a4 of the anvil 3 according to this fourth modification, the second line L2 and the third line L3 intersect but are not perpendicular to each other in a plan view. The angle between the second line L2 and the first line L1 and the angle between the third line L3 and the first line L1 are equal to each other, for example, 60°. As a result, the first projection T1 and the second projection T2 have a frustoconical shape with a rhombic bottom and top surface, respectively. The third projection T3 has a frustoconical shape with a parallelogram bottom and top surface.

[0134] When the joining process is carried out using such anvil 3, the second direction W2 and the third direction W3 intersect but are not orthogonal to each other in a plan view.

[0135] Furthermore, the bottom B1 of the first recess U1, the bottom B2 of the second recess U2, and the bottom B3 of the third recess U3, which are located in the first uneven region R1 of the joint J, have the following shapes. Specifically, the bottom B1 of the first recess U1 corresponding to the shape of the first protrusion T1, and the bottom B2 of the second recess U2 corresponding to the shape of the second protrusion T2, are both planar and rhombic in plan view. Also, the bottom B3 of the third recess U3 corresponding to the shape of the third protrusion T3 are both planar and parallelogram in plan view.

[0136] Next, the joint J according to the fifth modified example of the embodiment of this disclosure will be described, mainly in terms of its differences from the joint J according to the above embodiment. Figure 24 is a plan view of the anvil 3 used in the joining process according to the fifth modified example of the embodiment of this disclosure.

[0137] In the support surface 3a5 of the anvil 3 according to this fifth modified example, the second line L2 and the third line L3 intersect but are not perpendicular to each other in a plan view. Also, the angle between the second line L2 and the first line L1 and the angle between the third line L3 and the first line L1 are different. The angle between the second line L2 and the first line L1 is, for example, 45°, and the angle between the third line L3 and the first line L1 is, for example, 60°. As a result, the first projection T1, the second projection T2, and the third projection T3 are truncated square pyramids with parallelogram shapes on their lower and upper surfaces, respectively.

[0138] Furthermore, because the lengths of two adjacent sides on the lower surface of the first protrusion T1 are different, the shape of the third protrusion T3 located in the third range A3 adjacent to the first range A1 in the second direction W2 is different from the shape of the third protrusion T3 located in the third range A3 adjacent to the first range A1 in the third direction W3.

[0139] When the joining process is carried out using such anvil 3, the second direction W2 and the third direction W3 intersect but are not orthogonal to each other in a plan view. Also, the angle between the second direction W2 and the first direction W1 and the angle between the third direction W3 and the first direction W1 are different from each other.

[0140] Furthermore, the bottom B1 of the first recess U1, the bottom B2 of the second recess U2, and the bottom B3 of the third recess U3, which are located in the first uneven region R1 of the joint J, have the following shapes. That is, the bottom B1 of the first recess U1 corresponding to the shape of the first protrusion T1, the bottom B2 of the second recess U2 corresponding to the shape of the second protrusion T2, and the bottom B3 of the third recess U3 corresponding to the shape of the third protrusion T3 are all planar and have a parallelogram shape in plan view.

[0141] Next, the joint J according to the sixth modified example of the embodiment of this disclosure will be described, mainly in terms of its differences from the joint J according to the first modified example of the embodiment described above. Figure 25 is a plan view of the anvil 3 used in the joining process according to the sixth modified example of the embodiment of this disclosure.

[0142] The support surface 3a6 of the anvil 3 in this sixth modified example has two first ranges A1, three second ranges A2, and eight third ranges A3.

[0143] The two first ranges A1 are positioned apart from each other in the direction along the first straight line L1. The three second ranges A2 are positioned between the two first ranges A1 in the direction along the first straight line L1, and on both sides of the two first ranges A1 in the direction along the first straight line L1. The third range A3 is located between the first range A1 and the second range A2 in the direction along the first straight line L1. The third range A3 is adjacent to the first range A1 in the direction along either the second straight line L2 or the third straight line L3. Also, the third range A3 is adjacent to the second range A2 in the direction along either the second straight line L2 or the third straight line L3.

[0144] Figure 26 is a side view of an anvil 3 and a horn 4 according to a sixth modified example of an embodiment of the present disclosure. The horn 4 of this sixth modified example has two pressing surfaces 4a. In the joining process, the two pressing surfaces 4a overlap in plan view with one first range A1, two second ranges A2 adjacent to the first range A1, and four third ranges A3 adjacent to each other with the first range A1, respectively.

[0145] As the joining process is carried out using the anvil 3 and horn 4, two first uneven regions R1 shown in Figure 11 are formed on the outer surface of the positive terminal 20 at the joint J, and two second uneven regions R2 are formed on the outer surface of the current collector 50 at the joint J.

[0146] Next, the joint J according to the seventh modified example of the embodiment of this disclosure will be described, mainly in terms of its differences from the joint J according to the above embodiment. Figure 27 is a plan view of the anvil 3 used in the joining process according to the seventh modified example of the embodiment of this disclosure.

[0147] The support surface 3a7 of the anvil 3 in this seventh modified example does not have a third range A3. The second range A2 is located adjacent to the first range A1 on both outer sides in the direction along the first straight line L1.

[0148] In this seventh modified example, the multiple V-shaped grooves between the first protrusion T1 and the second protrusion T2 include grooves G1 (shown as dashed lines in Figure 27) that are not continuous from one side to the other of the support surface 3a in the direction along the second straight line L2 and the third straight line L3. In this case, even if a grinding wheel having a V-shaped corner is moved from one side to the other of the support surface 3a in the direction along the second straight line L2 and the third straight line L3, grooves G1 cannot be formed, and the machining process for the support surface 3a is increased compared to the above embodiment.

[0149] When the joining process is performed using such anvil 3, the first uneven region R1 does not have a third uneven pattern P3. The second uneven pattern P2 is located adjacent to the first uneven pattern P1 on both outer sides of the first uneven pattern P1 in the first direction W1.

[0150] Next, the differences between the joint J in the eighth modified example of the embodiment of this disclosure and the joint J in the seventh modified example of the above embodiment will be explained. Figure 28 is a plan view of the anvil 3 used in the joining process in the eighth modified example of the embodiment of this disclosure.

[0151] In this eighth modified example, the support surface 3a8 of the anvil 3 is such that the first straight line L1 and the second straight line L2 overlap in a plan view. The second range A2 is located adjacent to the first range A1 on both outer sides in the direction along the first straight line L1, similar to the seventh modified example described above.

[0152] In this eighth modified example, the multiple V-shaped grooves between the first protrusion T1 and the second protrusion T2 include a groove G2 (shown as a dashed line in Figure 28) that lies inward from the periphery of the support surface 3a in the direction along the second straight line L2. In this case, it is difficult to form the groove G2 with a grinding wheel having V-shaped corners, and the machining direction of the support surface 3a becomes more complex compared to the above embodiment. The groove is formed, for example, by electrical discharge machining.

[0153] When the joining process is performed using such anvil 3, the first uneven region R1 does not have the third uneven pattern P3. Also, the second direction W2 is the same direction as the first direction W1. In the first direction W1, it is located adjacent to the first uneven pattern P1 on both outer sides of the first uneven pattern P1.

[0154] The joint J in each of the above modified examples can stabilize the connection between the multiple current collectors 50 and the positive terminal 20, and stabilize the connection between the multiple current collectors 50 and the negative terminal 30, similar to the joint J in the above embodiment.

[0155] The embodiments described above are provided to facilitate understanding of this disclosure and are not intended to limit its interpretation. This disclosure may be modified or improved without departing from its intent, and equivalents thereof are included.

[0156] For example, the laminate 10 may be of the winding type. Alternatively, the laminate 10 may constitute an all-solid-state battery. In this case, the laminate 10 has a positive electrode and a negative electrode, and a solid electrolyte is housed in the housing 41.

[0157] Furthermore, it goes without saying that the support surface 3a is not limited to a rectangular shape in plan view; for example, it may be square or circular in plan view.

[0158] Furthermore, the multiple first protrusions T1, multiple second protrusions T2, multiple third protrusions T3, multiple fourth protrusions T4, and multiple fifth protrusions T5 may be arranged so that their lower surfaces are separated from each other.

[0159] Furthermore, the multiple sixth protrusions T6 of the pressing surface 4a may not have an eighth protrusion T8, but may be composed of seventh protrusions T7. In this case, the bottoms of the multiple sixth recesses U6 of the second uneven region R2 each correspond to the shape of the seventh protrusion T7 and are located on the same plane.

[0160] Furthermore, the first uneven region R1 and the second uneven region R2 do not extend along the first direction W1, and the lengths of the two directions that are orthogonal to each other in a plan view may be equal, for example, they may be square and circular. In this case, the pressing surface 4a of the horn 4 may be square and circular in a plan view, for example.

[0161] Furthermore, this disclosure may also be a combination of the following configurations.

[0162] (1) A laminate in which multiple electrodes are stacked, Multiple current collectors electrically connected to multiple electrodes, The terminals are connected to a plurality of the aforementioned current collectors, The outer surface of the terminal at the joint between the multiple current collectors and the terminal has a first uneven region, The first uneven region is, A first uneven pattern having multiple first recesses, The terminal has two second recess patterns, each having a plurality of second recesses whose area in plan view of the outer surface is larger than that of the first recess, The first uneven pattern is located between the two second uneven patterns in the plan view. Secondary battery.

[0163] (2) The first uneven region extends along the first direction in the plan view, The first uneven pattern is located between the two second uneven patterns in the first direction. (1) The secondary battery described above.

[0164] (3) The plurality of first recesses are arranged in a matrix along the second and third directions that intersect each other in the plan view. (1) or (2) the secondary battery described above.

[0165] (4) The plurality of the second recesses are arranged in the plan view along one of the second direction and the third direction. (3) The secondary battery described above.

[0166] (5) The first uneven region further has a third uneven pattern having a plurality of third recesses whose area in plan view is larger than the first recess and smaller than the second recess, The third uneven pattern is adjacent to the first uneven pattern in one of the second and third directions, The second uneven pattern is located outside the range extending from the first uneven pattern in the second and third directions in the plan view. (3) or (4) The secondary battery described above.

[0167] (6) The outer surface of the current collector at the joint has a second uneven region, The depth of the first uneven region is shallower than the depth of the second uneven region. A secondary battery as described in any one of (1) through (5).

[0168] (7) The plurality of electrodes have a positive electrode and a negative electrode, The laminate has a laminated structure in which the positive electrode and the negative electrode are laminated with a separator in between. A secondary battery as described in any one of (1) through (6). [Explanation of Symbols]

[0169] 1 Secondary battery 10 Laminate 11 Positive electrode 12. Negative electrode 13 Separator 20 Positive terminal (terminal) 30 Negative terminal (terminal) 50 Current collector B1 Bottom of the first recess B2 Bottom of the second recess B3 Bottom of the third recess J joint P1 First uneven pattern P2 Second uneven pattern P3 Third uneven pattern R1 1st uneven area R2 2nd uneven area T1 1st protrusion U1 First recess U2 Second recess U3 Third recess W1 1st direction W2 Second direction W3 Third Direction

Claims

1. A laminate in which multiple electrodes are stacked, Multiple current collectors electrically connected to multiple electrodes, The terminals are connected to a plurality of the aforementioned current collectors, The outer surface of the terminal at the joint between the multiple current collectors and the terminal has a first uneven region, The first uneven region is, A first uneven pattern having multiple first recesses, The joint portion has two second recesses, each having a plurality of second recesses, the area of ​​which, when viewed from above, is larger than the area of ​​the outer surface of the terminal than the area of ​​the first recess. The first uneven pattern is located between the two second uneven patterns in the plan view. Secondary battery.

2. The first uneven region extends along the first direction in the plan view, The first uneven pattern is located between the two second uneven patterns in the first direction. The secondary battery according to claim 1.

3. The plurality of first recesses are arranged in a matrix along the second and third directions that intersect each other in the plan view. The secondary battery according to claim 1 or 2.

4. The plurality of the second recesses are arranged in the plan view along one of the second direction and the third direction. The secondary battery according to claim 3.

5. The first uneven region further has a third uneven pattern having a plurality of third recesses whose area in plan view is larger than the first recess and smaller than the second recess. The third uneven pattern is adjacent to the first uneven pattern in one of the second and third directions, The second uneven pattern is located outside the range extending from the first uneven pattern in the second and third directions in the plan view. The secondary battery according to claim 3.

6. The outer surface of the current collector at the joint has a second uneven region, The depth of the first uneven region is shallower than the depth of the second uneven region. The secondary battery according to claim 1 or 2.

7. The plurality of electrodes have a positive electrode and a negative electrode, The laminate has a laminated structure in which the positive electrode and the negative electrode are laminated with a separator in between. The secondary battery according to claim 1 or 2.

Images