Toner for electrostatic image development, electrostatic image developer, toner cartridge, process cartridge, image forming apparatus, and image forming method

Abstract

To provide an electrostatic image development toner capable of forming images with superior bending resistance, separability, and high reflectance.SOLUTION: An electrostatic image development toner comprising toner particles containing an organic colorant and a binder resin is provided, the organic colorant containing a non-fluorescent organic pigment and a fluorescent organic pigment. Total content of the organic colorant with respect to an entire mass of a toner particle is in a range of 5 to 20 mass%, inclusive. Specific gravity D1 of the non-fluorescent organic pigment and specific gravity D2 of the fluorescent organic pigment satisfy the following expressions (1) and (2): D1≥2.0 ...(1), D1-D2≥0.6 ...(2).SELECTED DRAWING: Figure 1

Description

Technical Field

[0001] The present disclosure relates to an electrostatic charge image developing toner, an electrostatic charge image developer, a toner cartridge, a process cartridge, an image forming apparatus, and an image forming method.

Background Art

[0002] Patent Document 1 discloses a magenta toner for electrostatic charge image development comprising magenta toner particles containing a binder resin and a colorant, wherein the colorant contains at least one type of visible light-excitable nitride phosphor, the visible light-excitable nitride phosphor contains a matrix crystal and an activator, and has an average dispersed particle diameter of 50 nm or more and 500 nm or less.

[0003] Patent Document 2 discloses a white toner for electrostatic charge image development containing a binder resin, a first white pigment, and a second white pigment, wherein the specific gravity D1 of the first white pigment satisfies the relationship 3.5 < D1 < 6.0, and the specific gravity D2 of the second white pigment satisfies the relationship 0.3 < D2 < 1.2.

Prior Art Documents

Patent Documents

[0004]

Patent Document 1

Patent Document 2

Summary of the Invention

Problems to be Solved by the Invention

[0005] The present disclosure aims to provide a toner for developing electrostatic images that exhibits superior bending resistance and peelability in the resulting image, and has high reflectivity, compared to a case in which the organic colorant comprises toner particles containing an organic colorant and a binder resin, the organic colorant comprises a non-fluorescent organic pigment and a fluorescent organic pigment, the total content of the organic colorant is less than 5% by mass or more than 20% by mass of the total mass of the toner particles, or the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy either of the following formulas (1) and (2). [Means for solving the problem]

[0006] The following embodiments are included as specific means for solving the aforementioned problems. <1> A toner for developing electrostatic images, comprising toner particles containing an organic colorant and a binder resin, wherein the organic colorant comprises a non-fluorescent organic pigment and a fluorescent organic pigment, the total content of the organic colorant is 5% by mass or more and 20% by mass or less of the total mass of the toner particles, and the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy both of the following formulas (1) and (2). D1≧2.0 Formula (1) D1-D2≧0.6 Formula (2) <2> The volume-average particle size D50v of the fluorescent organic pigment is between 30 nm and 800 nm. <1> Toner for developing electrostatic images as described above. <3> The volume-average particle size D50v of the fluorescent organic pigment is between 100 nm and 500 nm. <2> Toner for developing electrostatic images as described above. <4> The volume-average particle size of the non-fluorescent organic pigment is less than or equal to the volume-average particle size of the fluorescent organic pigment. <1> ~ <3> A toner for developing electrostatic images, as described in one of the following. <5> The specific gravity D1 of the non-fluorescent organic pigment satisfies the following formula (1A). <1> ~ <4> A toner for developing electrostatic images, as described in one of the following. D1≧2.5 Formula (1A) <6> The specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy the following formula (2A). <1> ~ <5> A toner for developing electrostatic images, as described in one of the following. D1-D2≧0.75 Formula (2A) <7> The specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy the following formula (2B). <6> Toner for developing electrostatic images as described above. D1-D2≧1.0 Formula (2B) <8> The non-fluorescent organic pigment has a halogen atom. <1> ~ <7> A toner for developing electrostatic images, as described in one of the following. <9> The halogen atom is at least one selected from the group consisting of chlorine atoms and bromine atoms. <8> Toner for developing electrostatic images as described above. <10> <1> ~ <9> A electrostatic image developer containing an electrostatic image developing toner as described in any one of the following. <11> <1> ~ <9> A toner cartridge that contains the electrostatic image developing toner described in any one of the above, and is attached to and detached from an image forming apparatus. <12> <10> A process cartridge that contains the electrostatic image developer described above, and includes a developing means for developing an electrostatic image formed on the surface of an image holder as a toner image using the electrostatic image developer, and is attached to and detached from an image forming apparatus. <13> An image holder, a charging means for charging the surface of the image holder, and a static charge image forming means for forming a static charge image on the charged surface of the image holder, <10> An image forming apparatus comprising: a developing means for containing the electrostatic image developer described in [reference] and developing an electrostatic image formed on the surface of the image holder as a toner image using the electrostatic image developer; a transfer means for transferring the toner image formed on the surface of the image holder to the surface of a recording medium; and a fixing means for fixing the toner image transferred to the surface of the recording medium. <14> A charging step of charging the surface of the image holder, and a static charge image forming step of forming a static charge image on the charged surface of the image holder, <10> An image forming method comprising: a developing step of developing an electrostatic image formed on the surface of an image holder as a toner image using the electrostatic image developer described in [reference]; a transfer step of transferring the toner image formed on the surface of the image holder to the surface of a recording medium; and a fixing step of fixing the toner image transferred to the surface of the recording medium. <15> The system comprises first to sixth image forming units of an electrophotographic method that form images of pink, yellow, magenta, cyan, black, and green, and the image forming unit that forms the green image is <10> An image forming apparatus containing the electrostatic image developer described above. <16> The system has first to sixth image forming steps in an electrophotographic method for forming images of pink, yellow, magenta, cyan, black, and green, and the image forming step for forming the green image is <10> An image formation method using the electrostatic image developer described above. [Effects of the Invention]

[0007] <1> According to the invention, a toner for developing electrostatic images is provided that contains toner particles containing an organic colorant and a binder resin, wherein the organic colorant comprises a non-fluorescent organic pigment and a fluorescent organic pigment, and the total content of the organic colorant is less than 5% by mass or more than 20% by mass of the total mass of the toner particles, or the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy either of the following formulas (1) and (2). Compared to this, the toner provides superior bending resistance and peelability in the resulting image, and the resulting image has high reflectivity. <2> According to the invention, a toner for developing electrostatic images is provided that exhibits superior bending resistance and peelability in the resulting image compared to cases where the volume average particle size D50v of the fluorescent organic pigment is less than 30 nm or greater than 800 nm. <3> According to the invention, a toner for developing electrostatic images is provided that exhibits superior bending resistance and peelability in the resulting image compared to cases where the volume average particle size D50v of the fluorescent organic pigment is less than 100 nm or greater than 500 nm. <4> According to the invention, a toner for developing electrostatic images is provided that has superior bending resistance and peelability in the resulting image compared to the case where the volume-average particle size of the non-fluorescent organic pigment is larger than the volume-average particle size of the fluorescent organic pigment. According to the invention according to <5>, when the specific gravity D1 of the non-fluorescent organic pigment does not satisfy the formula (1A), the toner for electrostatic charge image development has more excellent bending resistance in the obtained image, and the obtained image has a higher reflectance. According to the invention according to <6>, when the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy the formula (2A), the toner for electrostatic charge image development has more excellent bending resistance in the obtained image, and the obtained image has a higher reflectance. According to the invention according to <7>, when the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy the formula (2B), the toner for electrostatic charge image development has more excellent bending resistance in the obtained image, and the obtained image has a higher reflectance. According to the invention according to <8>, when the non-fluorescent organic pigment does not have a halogen atom, the toner for electrostatic charge image development has more excellent bending resistance in the obtained image, and the obtained image has a higher reflectance. According to the invention according to <9>, when the halogen atom is only a fluorine atom or an iodine atom, the toner for electrostatic charge image development has more excellent bending resistance in the obtained image, and the obtained image has a higher reflectance. According to the invention according to <10>, <11>, <12>, <13>, <14>, <15> or <16>, the toner for electrostatic charge image development includes toner particles containing an organic colorant and a binder resin. The organic colorant includes a non-fluorescent organic pigment and a fluorescent organic pigment. The total content of the organic colorant is less than 5% by mass or more than 20% by mass with respect to the total mass of the toner, or when the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy any of the formulas (1) and (2), the toner for electrostatic charge image development has excellent bending resistance and peelability in the obtained image, and the obtained image has a high reflectance. An electrostatic charge image developer, a toner cartridge, a process cartridge, an image forming apparatus or an image forming method is provided.

Brief Description of the Drawings

[0008] [Figure 1] It is a schematic configuration diagram showing an example of an image forming apparatus according to the present embodiment. [Figure 2] It is a schematic configuration diagram showing an example of a process cartridge that is attached to and detached from the image forming apparatus according to the present embodiment.

Mode for Carrying Out the Invention

[0009] Embodiments of the present disclosure will be described below. These descriptions and examples are illustrative of the embodiments and do not limit the scope of the embodiments.

[0010] In the present disclosure, a numerical range indicated using "~" indicates a range including the numerical values described before and after "~" as the minimum value and the maximum value, respectively. In the numerical ranges described step by step in the present disclosure, the upper limit value or the lower limit value described in one numerical range may be replaced with the upper limit value or the lower limit value of another numerically described range. Also, in the numerical ranges described in the present disclosure, the upper limit value or the lower limit value of the numerical range may be replaced with the value shown in the examples.

[0011] In the present disclosure, the term "step" includes not only an independent step but also cases where it cannot be clearly distinguished from other steps, as long as the purpose of the step is achieved.

[0012] When an embodiment is described in the present disclosure with reference to the drawings, the configuration of the embodiment is not limited to the configuration shown in the drawings. Also, the sizes of the members in each figure are conceptual, and the relative relationships of the sizes between the members are not limited to this.

[0013] In the present disclosure, each component may contain a plurality of corresponding substances. When referring to the amount of each component in the composition, when there are a plurality of substances corresponding to each component in the composition, unless otherwise specified, it means the total amount of the plurality of substances present in the composition. In this disclosure, each component may contain multiple types of particles. If multiple types of particles corresponding to each component are present in the composition, the particle size of each component refers to the value for a mixture of such multiple types of particles present in the composition, unless otherwise specified.

[0014] In this disclosure, "(meth)acrylic" is a term that includes both acrylic and methacrylic, and "(meth)acrylate" is a term that includes both acrylate and methacrylate.

[0015] In this disclosure, "electrostatic image developing toner" is also referred to as "toner," "fluorescent green toner" is also referred to as "green toner," "electrostatic image developer" is also referred to as "developer," and "electrostatic image developing carrier" is also referred to as "carrier."

[0016] <Toner for developing electrostatic images> The electrostatic image developing toner according to this embodiment comprises toner particles containing an organic colorant and a binder resin, wherein the organic colorant comprises a non-fluorescent organic pigment and a fluorescent organic pigment, the total content of the organic colorant is 5% by mass or more and 20% by mass or less of the total mass of the toner particles, and the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy both of the following formulas (1) and (2). D1≧2.0 Formula (1) D1-D2≧0.6 Formula (2)

[0017] Furthermore, the electrostatic image developing toner according to this embodiment is preferably a fluorescent toner, more preferably a fluorescent green toner, fluorescent pink toner, fluorescent red toner, fluorescent orange toner, fluorescent yellow toner, or fluorescent purple toner, even more preferably a fluorescent green toner, fluorescent red toner, or fluorescent orange toner, and particularly preferably a fluorescent green toner. Furthermore, the electrostatic image developing toner according to this embodiment is preferably a toner having a core-shell structure.

[0018] Conventional toners containing fluorescent colorants often resulted in a higher-than-usual colorant content due to the combination of a fluorescent colorant for achieving fluorescence intensity and a non-fluorescent colorant for color matching, leading to a decrease in image bending strength. Furthermore, while using dyes as fluorescent colorants allows for a reduction in colorant content to normal levels and improved bending strength, the molecularly dispersed dye in the toner lowers the Tg of the binder resin, worsening release properties. In the electrostatic image developing toner according to this embodiment, the organic colorant contains a non-fluorescent organic pigment and a fluorescent organic pigment, and the total content of the organic colorant in the toner is 5% by mass or more and 20% by mass or less of the total mass of the toner, and the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy both formulas (1) and (2), so it is estimated that the resulting image will have excellent bending resistance and peelability, and the resulting image will have high reflectivity, as shown below. Non-fluorescent organic pigments used for color mixing absorb light containing the excitation wavelength of fluorescent organic pigments. However, high-density non-fluorescent organic pigments have a high electron density, so they absorb and scatter a large amount of light at the same time. Therefore, the amount of excitation wavelength light that the fluorescent organic pigment can absorb in the image does not decrease, and the fluorescence intensity of the toner is maintained at a high level. Consequently, when the specific gravity of the non-fluorescent organic pigment is 2.0 or less, less light is scattered, the amount of excitation wavelength light decreases, and the fluorescence intensity decreases. Furthermore, in areas where non-fluorescent organic pigments and fluorescent organic pigments are in close proximity, the greater the difference in specific gravity between the non-fluorescent and fluorescent organic pigments (≧0.6), the greater the difference in electron density. As a result, light is strongly scattered at the boundary between the non-fluorescent and fluorescent organic pigments, allowing light to reach the fluorescent organic pigment and increasing its fluorescence intensity. Therefore, by using high-density (2.0 or higher) organic pigments for color matching, and by having a large difference in specific gravity between the fluorescent and non-fluorescent pigments (0.6 or higher), the fluorescence intensity increases. This allows the colorant content to be reduced to the same level as normal toner, resulting in a high reflectivity and improved bending strength of the resulting image, as well as excellent peelability due to the appropriate presence of pigment in the image. Furthermore, due to the high reflectivity of the resulting images, it excels at reproducing highly saturated and bright colors.

[0019] In this embodiment, a fluorescent organic pigment refers to an organic pigment that emits light in response to external light energy, and a non-fluorescent organic pigment refers to an organic pigment that does not emit light in response to external light energy. Generally, fluorescent organic pigments exhibit color through both reflected and emitted light, while non-fluorescent organic pigments exhibit color through reflected light only.

[0020] The configuration of the electrostatic image developing toner according to this embodiment will be described in detail below.

[0021] [Toner particles] The toner particles are composed of an organic colorant containing a non-fluorescent organic pigment and a fluorescent organic pigment, and a binder resin, and optionally contain a release agent and other additives.

[0022] In the electrostatic image developing toner according to this embodiment, the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy formula (1), and from the viewpoint of bending resistance and reflectance in the resulting image, it is preferable that they satisfy the following formula (1Z), more preferably that they satisfy the following formula (1A), even more preferably that they satisfy the following formula (1B), and particularly preferably that they satisfy the following formula (1C). D1≧2.1 Formula (1Z) D1≧2.5 Formula (1A) 3.5≧D1≧2.5 Formula (1B) 3.0≧D1≧2.5 Formula (1C)

[0023] In the electrostatic image developing toner according to this embodiment, the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy formula (2), and from the viewpoint of bending resistance and reflectance in the resulting image, it is preferable that the following formula (2A) is satisfied, more preferably that formula (2B) is satisfied, even more preferably that formula (2C) is satisfied, and particularly preferably that formula (2D) is satisfied. D1-D2≧0.75 Formula (2A) D1-D2≧1.0 Formula (2B) 2.0≧D1-D2≧1.0 Formula (2C) 1.6≧D1-D2≧1.0 Formula (2D)

[0024] In this embodiment, the specific gravity of the pigment shall be measured by the following method. Using a Le Chatelier specific gravity bottle, the specific gravity is measured in accordance with JIS K 0061 (2001) 5-2-1 using the following procedure. (1) Pour 250 ml of ethyl alcohol into a Le Chatelier specific gravity bottle and adjust so that the meniscus is at the marked position. (2) Immerse the specific gravity bottle in a constant temperature water bath, and when the liquid temperature reaches 20.0℃ ± 0.2℃, accurately read the position of the meniscus using the scale on the specific gravity bottle (accuracy 0.0025 ml). (3) Weigh out 100g of the sample. (4) Place the measured sample in a specific gravity bottle and remove any bubbles. (5) Immerse the specific gravity bottle in a constant temperature bath, and when the liquid temperature reaches 20.0°C ± 0.2°C, accurately read the position of the meniscus using the scale on the specific gravity bottle (accuracy 0.0025 ml). (6) The specific gravity is calculated using the following formula. Formula: D = W / (L2 - L1) ·Formula: S=D / 0.9982 In the formula, D is the density of the sample (g / cm³). 3 (at 20°C), S is the specific gravity of the sample (at 20°C), W is the apparent mass of the sample (g), L1 is the meniscus reading before the sample is placed in the specific gravity bottle (ml, 20°C), L2 is the meniscus reading after the sample is placed in the specific gravity bottle (ml, 20°C), and 0.9982 is the density of water at 20°C (g / cm³). 3 )

[0025] -Organic colorants- The toner particles contain an organic colorant, the organic colorant contains a non-fluorescent organic pigment and a fluorescent organic pigment, and the total content of the organic colorant is 5% by mass or more and 20% by mass or less of the total mass of the toner particles.

[0026] The total content of the organic colorant is 5% by mass or more and 20% by mass or less relative to the total mass of the toner particles, and is preferably 6% by mass or more and 18% by mass or less, and more preferably 8% by mass or more and 17% by mass or less, from the viewpoint of bending resistance and peelability in the resulting image.

[0027] From the viewpoint of bending resistance and reflectivity in the resulting image, it is preferable that the content of the fluorescent organic pigment is greater than the content of the non-fluorescent organic pigment. Furthermore, the mass-based ratio M2 / M1 of the content M1 of the fluorescent organic pigment and the content M2 of the non-fluorescent organic pigment in the toner particles is preferably 0.05 or more and 1.5 or less, from the viewpoint of bending resistance and reflectance in the resulting image. Furthermore, from the viewpoint of bending resistance and reflectivity in the resulting image, the ratio M2 / M1 is 0.05 or higher, preferably 0.1 or higher, and more preferably 0.3 or higher. Furthermore, from the viewpoint of bending resistance and reflectivity in the resulting image, the ratio M2 / M1 is 1.5 or less, preferably 1.0 or less, more preferably less than 1.0, and even more preferably 0.8 or less.

[0028] <<Fluorescent Organic Pigments>> The toner particles contain fluorescent organic pigments. The aforementioned fluorescent organic pigment is not limited in color or other characteristics as long as it is an organic pigment that has fluorescence, and examples include fluorescent yellow organic pigment, fluorescent pink organic pigment, fluorescent red organic pigment, fluorescent orange organic pigment, fluorescent green organic pigment, and fluorescent purple organic pigment. In particular, when the non-fluorescent organic pigment is a non-fluorescent green organic pigment or a non-fluorescent red organic pigment, a fluorescent yellow organic pigment is preferred from the viewpoint of bending resistance and reflectivity in the resulting image.

[0029] Examples of fluorescent organic pigments include azomethine compounds, isoindolinone compounds, xanthene compounds (including rhodamine compounds, fluorescein compounds, and eosin compounds), naphthalene compounds, and triarylmethane compounds. In particular, the fluorescent organic pigment is preferably an azomethine compound, and more preferably a bizuazomethine compound, from the viewpoint of bending resistance and reflectivity in the resulting image. Azomethine compounds include -R 1 C=N-(R 1 Examples include compounds having an azomethine structure represented by a hydrogen atom or a monovalent substituent. As for bisazometine compounds, -R 1 C=NN=CR 2 -(R 1 and R 2 Examples include compounds having a bisazomethine structure in their molecular structure, each independently represented by a hydrogen atom or a monovalent substituent.

[0030] The fluorescent organic pigment preferably has a hydrophilic group. Examples of hydrophilic groups in the aforementioned fluorescent organic pigments include hydroxyl groups, primary to tertiary amino groups, carboxyl groups, sulfo groups, and phosphate groups. In particular, the fluorescent organic pigment is preferably characterized by having a hydroxyl group as the hydrophilic group, from the viewpoint of bending resistance and reflectivity in the resulting image.

[0031] Examples of fluorescent organic pigments include the following azomethine compounds (1) to (3).

[0032] [ka]

[0033] The emission peak wavelength of azomethine compound (1) is 520 nm. The emission peak wavelength of azomethine compound (2) is 510 nm. The emission peak wavelength of azomethine compound (3) is 520 nm.

[0034] Furthermore, derivatives of azomethine compounds are also preferred examples of fluorescent organic pigments, and boron difluoride derivatives of azomethine compounds are more preferred examples. Examples of boron difluoride derivatives of azomethine compounds include the following compounds.

[0035] [ka]

[0036] The fluorescent organic pigment is preferably at least one selected from the group consisting of azomethine compound (1), azomethine compound (2), azomethine compound (3), and boron difluoride derivatives thereof.

[0037] Furthermore, as the fluorescent organic pigment, CI Pigment Yellow 101 or a boron difluoride derivative of CI Pigment Yellow 101 is preferred, and CI Pigment Yellow 101 is more preferred. CI Pigment Yellow 101 is an azomethine compound (1).

[0038] The volume-average particle size D50v of the fluorescent organic pigment is preferably 30 nm to 800 nm, more preferably 100 nm to 500 nm, and even more preferably 200 nm to 400 nm, from the viewpoint of achieving a good balance of bending resistance and peelability in the resulting image, as well as dispersibility in toner particles, color development on the recording medium, and fixation to the recording medium. The volume-average particle size of a pigment is measured by dispersing the pigment in an aqueous solution of a surfactant and using a laser diffraction particle size distribution analyzer (e.g., LA-700 from Horiba, Ltd.). The volume-based particle size distribution is plotted from the smallest particle size side, and the particle size at which the cumulative total reaches 50% is defined as the volume-average particle size.

[0039] The fluorescent organic pigment may be contained as a single type or as two or more types, but from the viewpoint of the brightness and saturation of the resulting image, it is preferable to contain only one type. Regarding the content of the fluorescent organic pigment, from the viewpoint of bending resistance and peelability in the resulting image, it is preferably 1% to 19.9% ​​by mass, more preferably 0.3% to 18% by mass, and particularly preferably 5% to 15% by mass, relative to the total mass of the toner particles.

[0040] -Non-fluorescent organic pigments- The toner particles contain a non-fluorescent organic pigment. The aforementioned non-fluorescent organic pigment is not limited in color or other characteristics as long as it is an organic pigment that does not have fluorescence. Examples include non-fluorescent green organic pigment, non-fluorescent red organic pigment, non-fluorescent yellow organic pigment, non-fluorescent pink organic pigment, non-fluorescent orange organic pigment, and non-fluorescent purple organic pigment. Among these, a non-fluorescent green pigment or a non-fluorescent red pigment is preferred, and a non-fluorescent green pigment is more preferred.

[0041] The non-fluorescent organic pigment preferably contains halogen atoms, from the viewpoint of bending resistance and reflectivity in the resulting image. Examples of halogen atoms in the aforementioned non-fluorescent organic pigments include fluorine atoms, chlorine atoms, bromine atoms, and iodine atoms. In particular, the non-fluorescent organic pigment preferably has at least one halogen atom selected from the group consisting of chlorine atoms and bromine atoms, more preferably has a bromine atom, and especially preferably has both chlorine atoms and bromine atoms, from the viewpoint of bending resistance and reflectance in the resulting image. Furthermore, the non-fluorescent organic pigment preferably has two or more halogen atoms, more preferably four or more halogen atoms, even more preferably two or more halogen atoms, and particularly preferably eight to 32 halogen atoms, from the viewpoint of bending resistance and reflectance in the resulting image.

[0042] Examples of the non-fluorescent organic pigments include lake pigments of halogenated phthalocyanine compounds and halogenated triphenylmethane dyes. As the non-fluorescent organic pigment, halogenated phthalocyanine compounds are preferred, and at least one selected from the group consisting of copper phthalocyanine halide and zinc phthalocyanine halide is preferred, with copper phthalocyanine halide being more preferred. Examples of copper phthalocyanine halides include CI Pigment Green 7 (specific gravity 2.1, reflection peak wavelength 500 nm, containing 16 chlorine atoms) and CI Pigment Green 36 (specific gravity 2.9, reflection peak wavelength 510 nm, containing 10 chlorine atoms and 6 bromine atoms).

[0043] Examples of non-fluorescent organic pigments include anthraquinone compounds. Examples of anthraquinone compounds include CI Pigment Red 168 (specific gravity 2.1, containing 2 bromine atoms) and CI Pigment Red 216 (specific gravity 2.8, containing 3 bromine atoms).

[0044] The non-fluorescent organic pigment is preferably at least one selected from the group consisting of CI Pigment Green 7, CI Pigment Green 36, CI Pigment Red 168, and CI Pigment Red 216, and more preferably at least one selected from the group consisting of CI Pigment Green 36 and CI Pigment Red 216.

[0045] The volume-average particle size D50v of the non-fluorescent organic pigment is preferably 50 nm to 500 nm, more preferably 80 nm to 400 nm, even more preferably 100 nm to 300 nm, and particularly preferably 120 nm to 200 nm, from the viewpoint of achieving a good balance of reflectivity in the resulting image, dispersibility in toner particles, color development on the recording medium, and fixability on the recording medium.

[0046] Non-fluorescent organic pigments may be included individually or in combination of two or more types. As for the content of the non-fluorescent organic pigment, from the viewpoint of bending resistance and peelability in the resulting image, it is preferably 0.1% to 19.9% ​​by mass, more preferably 0.5% to 15% by mass, even more preferably 1% to 10% by mass, and particularly preferably 2% to 8% by mass, relative to the total toner particles.

[0047] The ratio D1 / D2 of the volume-average particle size D1 of the fluorescent organic pigment to the volume-average particle size D2 of the non-fluorescent organic pigment is preferably 1 to 3, more preferably 1.2 to 2.5, and even more preferably 1.5 to 2, from the viewpoint of bending resistance and peelability in the resulting image.

[0048] The toner particles may contain other colorants besides the fluorescent organic pigment and the non-fluorescent organic pigment. The total amount of the fluorescent organic pigment and the non-fluorescent organic pigment in the total colorant contained in the toner particles is preferably 90% by mass or more, more preferably 95% by mass or more, and even more preferably 100% by mass.

[0049] -Binding resin- Examples of binder resins include vinyl resins consisting of monomer homopolymers of styrenes (e.g., styrene, parachlorostyrene, α-methylstyrene, etc.), (meth)acrylic acid esters (e.g., methyl acrylate, ethyl acrylate, n-propyl acrylate, n-butyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, lauryl methacrylate, 2-ethylhexyl methacrylate, etc.), ethylenically unsaturated nitriles (e.g., acrylonitrile, methacrylonitrile, etc.), vinyl ethers (e.g., vinyl methyl ether, vinyl isobutyl ether, etc.), vinyl ketones (e.g., vinyl methyl ketone, vinyl ethyl ketone, vinyl isopropenyl ketone, etc.), olefins (e.g., ethylene, propylene, butadiene, etc.), etc., or copolymers of two or more of these monomers. Examples of binder resins include non-vinyl resins such as epoxy resins, polyester resins, polyurethane resins, polyamide resins, cellulose resins, polyether resins, and modified rosin; mixtures of these with the aforementioned vinyl resins; and graft polymers obtained by polymerizing vinyl monomers in the presence of these. These binding resins may be used individually or in combination of two or more types.

[0050] Polyester resin is preferred as the binder resin. Examples of polyester resins include well-known polyester resins.

[0051] Examples of polyester resins include condensation polymers of polycarboxylic acids and polyhydric alcohols. Commercially available polyester resins may be used, or synthetically produced ones may be used.

[0052] Examples of polycarboxylic acids include aliphatic dicarboxylic acids (e.g., oxalic acid, malonic acid, maleic acid, fumaric acid, citraconic acid, itaconic acid, glutaconic acid, succinic acid, alkenylsuccinic acid, adipic acid, sebacic acid, etc.), alicyclic dicarboxylic acids (e.g., cyclohexanedicarboxylic acid, etc.), aromatic dicarboxylic acids (e.g., terephthalic acid, isophthalic acid, phthalic acid, naphthalenedicarboxylic acid, etc.), their anhydrides, or their lower alkyl esters (e.g., with 1 to 5 carbon atoms). Among these, aromatic dicarboxylic acids are preferred as polycarboxylic acids. As the polycarboxylic acid, a trivalent or higher carboxylic acid with a crosslinked or branched structure may be used in combination with the dicarboxylic acid. Examples of trivalent or higher carboxylic acids include trimellitic acid, pyromellitic acid, their anhydrides, or their lower alkyl esters (e.g., having 1 to 5 carbon atoms). Polycarboxylic acids may be used individually or in combination of two or more.

[0053] Examples of polyhydric alcohols include aliphatic diols (e.g., ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, butanediol, hexanediol, neopentyl glycol, etc.), alicyclic diols (e.g., cyclohexanediol, cyclohexanedimethanol, hydrogenated bisphenol A, etc.), and aromatic diols (e.g., ethylene oxide adducts of bisphenol A, propylene oxide adducts of bisphenol A, etc.). Among these, aromatic diols and alicyclic diols are preferred as polyhydric alcohols, and aromatic diols are more preferred. As for the polyhydric alcohol, a trihydric or higher polyhydric alcohol with a cross-linked or branched structure may be used in combination with the diol. Examples of trihydric or higher polyhydric alcohols include glycerin, trimethylolpropane, and pentaerythritol. Polyhydric alcohols may be used individually or in combination of two or more types.

[0054] The glass transition temperature (Tg) of the polyester resin is preferably 50°C to 80°C, and more preferably 50°C to 65°C. The glass transition temperature is determined from the DSC curve obtained by differential scanning calorimetry (DSC), and more specifically, from the "extracorporeal glass transition onset temperature" described in the method for determining the glass transition temperature in JIS K7121-1987 "Method for Measuring the Transition Temperature of Plastics".

[0055] The weight-average molecular weight (Mw) of the polyester resin is preferably 5,000 to 1,000,000, and more preferably 7,000 to 500,000. The number-average molecular weight (Mn) of the polyester resin is preferably between 2,000 and 100,000. The molecular weight distribution (Mw / Mn) of the polyester resin is preferably 1.5 to 100, and more preferably 2 to 60. Weight-average molecular weight and number-average molecular weight are measured by gel permeation chromatography (GPC). GPC molecular weight measurement is performed using a Tosoh GPC-HLC-8120GPC analyzer, a Tosoh TSKgel SuperHM-M (15cm) column, and THF solvent. The weight-average molecular weight and number-average molecular weight are calculated from these measurement results using a molecular weight calibration curve prepared with monodisperse polystyrene standard samples.

[0056] Polyester resins can be obtained by known manufacturing methods. Specifically, for example, they can be obtained by a method in which the polymerization temperature is set to 180°C or higher and 230°C or lower, and the reaction system is subjected to reduced pressure as needed, while removing water and alcohol generated during condensation. If the monomers of the raw materials do not dissolve or miscible at the reaction temperature, a high-boiling point solvent may be added as a solubilizer to dissolve them. In this case, the polycondensation reaction should be carried out while distilling off the solubilizer. If there are monomers with poor miscibility, it is advisable to condense the poorly miscible monomers with the acid or alcohol to be polycondensed with them beforehand, and then polycondense them with the main component.

[0057] The binder resin content is preferably 40% to 95% by mass, more preferably 50% to 90% by mass, and even more preferably 60% to 85% by mass, relative to the total toner particles.

[0058] -Release agent- Examples of release agents include hydrocarbon waxes; natural waxes such as carnauba wax, rice wax, and candelilla wax; synthetic or mineral / petroleum-based waxes such as montan wax; and ester waxes such as fatty acid esters and montanic acid esters. However, the release agents are not limited to these.

[0059] The melting temperature of the release agent is preferably 50°C to 110°C, and more preferably 60°C to 100°C. The melting temperature is determined from the DSC curve obtained by differential scanning calorimetry (DSC) using the "melting peak temperature" described in JIS K7121-1987 "Method for determining the transition temperature of plastics".

[0060] The release agent content is preferably 1% by mass or more and 20% by mass or less, and more preferably 5% by mass or more and 15% by mass or less, relative to the total toner particles.

[0061] -Other additives- Other known additives include, for example, magnetic materials, charge control agents, and inorganic powders. These additives are included in the toner particles as internal additives.

[0062] -Characteristics of toner particles, etc.- The toner particles may be single-layer toner particles, or they may be toner particles with a so-called core-shell structure, consisting of a core (core particle) and a coating layer (shell layer) that covers the core. The core-shell structure of the toner particles may consist of, for example, a core made up of a binder resin and, if necessary, other additives such as a colorant and a release agent, and a coating layer made up of a binder resin.

[0063] The volume-average particle size (D50v) of the toner particles is preferably 2 μm or more and 10 μm or less, and more preferably 4 μm or more and 8 μm or less.

[0064] The average particle size and particle size distribution indices of toner particles are measured using the Coulter Multisizer II (manufactured by Beckman Coulter), and the electrolyte is measured using the ISOTON-II (manufactured by Beckman Coulter). For measurement, 0.5 mg to 50 mg of the sample to be measured is added to 2 ml of a 5% aqueous solution of a surfactant (preferably sodium alkylbenzenesulfonate) as a dispersant. This is then added to 100 ml to 150 ml of electrolyte. The electrolyte in which the sample is suspended is dispersed for 1 minute using an ultrasonic disperser, and the particle size distribution of particles with a particle size ranging from 2 μm to 60 μm is measured using a Coulter Multisizer II with an aperture diameter of 100 μm. The number of particles to be sampled is 50,000. Based on the measured particle size distribution, cumulative distributions of volume and number are plotted for the particle size ranges (channels) divided, and the particle size at which the cumulative value becomes 16% is defined as the volume particle size D16v, the number particle size D16p, the particle size at which the cumulative value becomes 50% is defined as the volume average particle size D50v, the cumulative number average particle size D50p, and the particle size at which the cumulative value becomes 84% is defined as the volume particle size D84v and the number particle size D84p. Using these, the volume particle size distribution index (GSDv) is (D84v / D16v) 1 / 2 and the number particle size distribution index (GSDp) is (D84p / D16p) 1 / 2 and is calculated as such.

[0065] The average circularity of the toner particles is preferably 0.94 or more and 1.00 or less, and more preferably 0.95 or more and 0.98 or less.

[0066] The average circularity of the toner particles is obtained by (circumference equivalent to a circle) / (circumference) [(circumference of a circle having the same projected area as the particle image) / (circumference of the particle projection image)]. Specifically, it is a value measured by the following method. First, the toner particles to be measured are aspirated and collected, a flat flow is formed, and a stroboscopic light emission is instantaneously performed to capture the particle image as a still image, and it is obtained by a flow-type particle image analyzer (FPIA-3000 manufactured by Sysmex Corporation) that analyzes the particle image. The number of samplings when obtaining the average circularity is 3,500. When the toner has an external additive, after dispersing the toner (developer) to be measured in water containing a surfactant, ultrasonic treatment is performed to obtain toner particles from which the external additive has been removed.

[0067] [External additive] Examples of external additives include inorganic particles. These include SiO2, TiO2, Al2O3, CuO, ZnO, SnO2, CeO2, Fe2O3, MgO, BaO, CaO, K2O, Na2O, ZrO2, CaO·SiO2, and K2O·(TiO2). n Examples include Al2O3·2SiO2, CaCO3, MgCO3, BaSO4, and MgSO4.

[0068] The surface of the inorganic particles used as an external additive should preferably be hydrophobic. Hydrophobic treatment is carried out, for example, by immersing the inorganic particles in a hydrophobic agent. The hydrophobic agent is not particularly limited, but examples include silane-based coupling agents, silicone oil, titanate-based coupling agents, and aluminum-based coupling agents. These may be used individually or in combination of two or more. The amount of hydrophobic treatment agent is typically, for example, 1 to 10 parts by mass per 100 parts by mass of inorganic particles.

[0069] Examples of external additives include resin particles (such as polystyrene, polymethyl methacrylate, and melamine resin) and cleaning activators (for example, metal salts of higher fatty acids represented by zinc stearate, and fluorine-based high molecular weight particles).

[0070] The amount of external additive added is preferably 0.01% by mass or more and 5% by mass or less relative to the toner particles, and more preferably 0.01% by mass or more and 2.0% by mass or less.

[0071] In this embodiment, the toner for developing electrostatic images preferably has a reflectance of 70% or more in the reflectance peak of the spectral reflectance spectrum for a solid image formed on coated paper.

[0072] -Manufacturing method for toner for electrostatic image development- The electrostatic image developing toner according to this embodiment is obtained by manufacturing toner particles and then adding an external additive to the toner particles.

[0073] Toner particles may be manufactured by either a dry process (e.g., kneading and grinding) or a wet process (e.g., agglomeration, suspension polymerization, dissolution and suspension). There are no particular restrictions on these methods, and known methods can be used. Among these, obtaining toner particles by agglomeration is preferable.

[0074] When manufacturing toner particles by an aggregation and coalescence method, the following manufacturing method is preferred. The process involves preparing a resin particle dispersion in which resin particles that will serve as the binder are dispersed (resin particle dispersion preparation process); The process involves preparing a fluorescent organic pigment dispersion in which fluorescent organic pigments are dispersed (fluorescent organic pigment dispersion preparation process); The process involves preparing a non-fluorescent organic pigment dispersion in which non-fluorescent organic pigments are dispersed (non-fluorescent organic pigment dispersion preparation process); The process involves a step of agglomerating the mixed particles in a mixed dispersion obtained by mixing a resin particle dispersion, a fluorescent organic pigment dispersion, and a non-fluorescent organic pigment dispersion to form aggregated particles (aggregated particle formation step); A manufacturing method comprising the steps of: heating a dispersion of aggregated particles containing dispersed aggregated particles to fuse and combine the aggregated particles to form toner particles (fusion and combination step);

[0075] The details of each step are explained below.

[0076] -Resin particle dispersion preparation process- A resin particle dispersion is prepared, for example, by dispersing resin particles in a dispersion medium using a surfactant.

[0077] Examples of dispersion media used in resin particle dispersions include aqueous media. Examples of aqueous media include water such as distilled water and deionized water, and alcohols. These may be used individually or in combination of two or more.

[0078] Examples of surfactants include anionic surfactants such as sulfate esters, sulfonates, phosphates, and soaps; cationic surfactants such as amine salts and quaternary ammonium salts; and nonionic surfactants such as polyethylene glycol, alkylphenol ethylene oxide adducts, and polyhydric alcohols. Among these, anionic surfactants and cationic surfactants are particularly noteworthy. Nonionic surfactants may be used in combination with anionic or cationic surfactants. Surfactants may be used individually or in combination of two or more types.

[0079] In resin particle dispersions, common dispersion methods for dispersing resin particles in a dispersion medium include, for example, rotary shear homogenizers, ball mills with media, sand mills, and dyno mills. Depending on the type of resin particles, the resin particles may also be dispersed in the dispersion medium by phase inversion emulsification. Phase inversion emulsification is a method in which the resin to be dispersed is dissolved in a hydrophobic organic solvent in which the resin is soluble, a base is added to neutralize the organic continuous phase (O phase), and then an aqueous medium (W phase) is added to perform a phase inversion from W / O to O / W, thereby dispersing the resin in particulate form in the aqueous medium.

[0080] The volume-average particle size of the resin particles dispersed in the resin particle dispersion is preferably 0.01 μm to 1 μm, more preferably 0.08 μm to 0.8 μm, and even more preferably 0.1 μm to 0.6 μm. The volume-average particle size of the resin particles is measured using a laser diffraction particle size distribution analyzer (e.g., LA-700 manufactured by Horiba, Ltd.). The cumulative distribution is subtracted from the smallest particle size side for each divided particle size range (channel), and the particle size that accounts for 50% of the total particle size is measured as the volume-average particle size D50v. The volume-average particle size of particles in other dispersions is measured in the same manner.

[0081] The resin particle content in the resin particle dispersion is preferably 5% by mass or more and 50% by mass or less, and more preferably 10% by mass or more and 40% by mass or less.

[0082] The method for preparing the release agent particle dispersion is the same as for the resin particle dispersion. The release agent particle content in the release agent particle dispersion is preferably 5% by mass or more and 50% by mass or less, and more preferably 10% by mass or more and 40% by mass or less.

[0083] -Preparation process for fluorescent organic pigment dispersion- A fluorescent organic pigment dispersion can be prepared, for example, by dispersing a fluorescent organic pigment in a dispersion medium using a surfactant.

[0084] Examples of dispersion media used in fluorescent organic pigment dispersions include aqueous media. Examples of aqueous media include water such as distilled water and deionized water, and alcohols. These may be used individually or in combination of two or more.

[0085] Examples of surfactants include anionic surfactants such as sulfate esters, sulfonates, phosphates, and soaps; cationic surfactants such as amine salts and quaternary ammonium salts; and nonionic surfactants such as polyethylene glycol, alkylphenol ethylene oxide adducts, and polyhydric alcohols. Among these, anionic surfactants and cationic surfactants are particularly noteworthy. Nonionic surfactants may be used in combination with anionic or cationic surfactants. Surfactants may be used individually or in combination of two or more types.

[0086] Methods for dispersing fluorescent organic pigments in a dispersion medium include, for example, dispersion methods using a rotary shear homogenizer, a ball mill with media, a sand mill, a dyno mill, a key mill, etc.

[0087] The volume-average particle size of the fluorescent organic pigment dispersed in the fluorescent organic pigment dispersion is preferably 50 nm to 800 nm, more preferably 150 nm to 600 nm, and even more preferably 250 nm to 400 nm. The particle size of the fluorescent organic pigment can be adjusted, for example, by the dispersion method and time.

[0088] The fluorescent organic pigment content in the fluorescent organic pigment dispersion is preferably 5% by mass or more and 50% by mass or less, and more preferably 10% by mass or more and 40% by mass or less.

[0089] -Preparation process for non-fluorescent organic pigment dispersion- A non-fluorescent organic pigment dispersion can be prepared, for example, by dispersing a non-fluorescent organic pigment in a dispersion medium using a surfactant.

[0090] Examples of dispersion media used in non-fluorescent organic pigment dispersions include aqueous media. Examples of aqueous media include water such as distilled water and deionized water, and alcohols. These may be used individually or in combination of two or more.

[0091] Examples of surfactants include anionic surfactants such as sulfate esters, sulfonates, phosphates, and soaps; cationic surfactants such as amine salts and quaternary ammonium salts; and nonionic surfactants such as polyethylene glycol, alkylphenol ethylene oxide adducts, and polyhydric alcohols. Among these, anionic surfactants and cationic surfactants are particularly noteworthy. Nonionic surfactants may be used in combination with anionic or cationic surfactants. Surfactants may be used individually or in combination of two or more types.

[0092] Methods for dispersing non-fluorescent organic pigments in a dispersion medium include, for example, dispersion methods using a rotary shear homogenizer, a ball mill with media, a sand mill, a dyno mill, a key mill, etc.

[0093] The volume-average particle size of the non-fluorescent organic pigment dispersed in the non-fluorescent organic pigment dispersion is preferably 50 nm to 300 nm, more preferably 100 nm to 250 nm, and even more preferably 120 nm to 200 nm. The particle size of the non-fluorescent organic pigment can be adjusted, for example, by the dispersion method and time.

[0094] The content of non-fluorescent organic pigment in the non-fluorescent organic pigment dispersion is preferably 5% by mass or more and 50% by mass or less, and more preferably 10% by mass or more and 40% by mass or less.

[0095] -Agglomerated particle formation process- A dispersion of resin particles, a dispersion of fluorescent organic pigment, a dispersion of non-fluorescent organic pigment, and a dispersion of release agent particles are mixed. Then, in the mixed dispersion, the resin particles, fluorescent organic pigment, non-fluorescent organic pigment, and release agent particles are heteroaggregated to form aggregated particles containing the resin particles, fluorescent organic pigment, non-fluorescent organic pigment, and release agent particles, which have a diameter close to the diameter of the target toner particles.

[0096] Specifically, for example, a coagulant is added to a mixed dispersion, the pH of the mixed dispersion is adjusted to be acidic (for example, pH 2 to 5), a dispersion stabilizer is added as needed, and then the mixture is heated to a temperature close to the glass transition temperature of the resin particles (specifically, for example, above -30°C or below -10°C), causing the particles dispersed in the mixed dispersion to coagulate and form coagulated particles. In the agglomerated particle formation process, for example, the mixed dispersion may be stirred in a rotary shear homogenizer, a flocculant may be added at room temperature (e.g., 25°C), the pH of the mixed dispersion may be adjusted to acidic (e.g., pH 2 to 5), a dispersion stabilizer may be added as needed, and then heating may be performed.

[0097] Examples of flocculants include surfactants with opposite polarity to the surfactant contained in the mixed dispersion, inorganic metal salts, and metal complexes with a valency of 2 or higher. When a metal complex is used as a flocculant, the amount of surfactant used is reduced and the electrostatic properties are improved. Along with the flocculant, an additive that forms a complex or similar bond with the metal ions of the flocculant may be used as needed. A chelating agent is preferably used as this additive.

[0098] Examples of inorganic metal salts include metal salts such as calcium chloride, calcium nitrate, barium chloride, magnesium chloride, zinc chloride, aluminum chloride, and aluminum sulfate; and inorganic metal salt polymers such as polyaluminum chloride, polyaluminum hydroxide, and calcium polysulfide. As a chelating agent, a water-soluble chelating agent may be used. Examples of chelating agents include oxycarboxylic acids such as tartaric acid, citric acid, and gluconic acid; and aminocarboxylic acids such as iminodiacid acetic acid (IDA), nitrilotriacetic acid (NTA), and ethylenediaminetetraacetic acid (EDTA). The amount of chelating agent added is preferably 0.01 parts by mass or more and 5.0 parts by mass or less per 100 parts by mass of resin particles, and more preferably 0.1 parts by mass or more and less than 3.0 parts by mass.

[0099] -Fusion / unification process- Next, the dispersion of aggregated particles is heated to a temperature above the glass transition temperature of the resin particles (for example, 10°C to 30°C higher than the glass transition temperature of the resin particles) to fuse and combine the aggregated particles and form toner particles.

[0100] Toner particles are obtained through the above process. Toner particles may be manufactured by first obtaining an aggregate particle dispersion in which aggregate particles are dispersed, then further mixing the aggregate particle dispersion with a resin particle dispersion in which resin particles are dispersed, and agglomerating the aggregate particles so that the resin particles adhere to the surface of the aggregate particles to form second aggregate particles, and then heating the second aggregate particle dispersion in which the second aggregate particles are dispersed to fuse and combine the second aggregate particles to form toner particles with a core-shell structure.

[0101] After the fusion and combination process is completed, the toner particles in the dispersion are subjected to known washing, solid-liquid separation, and drying processes to obtain dried toner particles. From the viewpoint of electrostatic properties, the washing process should be performed thoroughly by displacement washing with ion-exchanged water. From the viewpoint of productivity, the solid-liquid separation process should be performed by suction filtration, pressure filtration, etc. From the viewpoint of productivity, the drying process should be performed by freeze-drying, air-flow drying, fluidized bed drying, vibratory fluidized bed drying, etc.

[0102] The toner according to this embodiment is manufactured, for example, by adding an external additive to the obtained dried toner particles and mixing them. Mixing is preferably carried out using a V-blender, Henschel mixer, Lödige mixer, etc. Furthermore, if necessary, coarse particles of the toner may be removed using a vibrating screen separator, a wind screen separator, etc.

[0103] <Electrostatic Image Developer> The electrostatic image developer according to this embodiment includes at least the green toner according to this embodiment. The electrostatic image developer according to this embodiment may be a one-component developer containing only the electrostatic image developing toner according to this embodiment, or it may be a two-component developer in which the electrostatic image developing toner and a carrier are mixed.

[0104] There are no particular restrictions on the carriers, and known carriers can be used. Examples of carriers include coated carriers in which a resin is coated on the surface of a core material made of magnetic powder; magnetic powder dispersed carriers in which magnetic powder is dispersed in a matrix resin; and resin-impregnated carriers in which resin is impregnated into porous magnetic powder. Magnetic powder dispersion carriers and resin-impregnated carriers may be carriers in which the constituent particles of the carrier are used as a core material and the surface thereof is coated with resin.

[0105] Examples of magnetic powders include magnetic metals such as iron, nickel, and cobalt; and magnetic oxides such as ferrite and magnetite.

[0106] Examples of coating resins and matrix resins include polyethylene, polypropylene, polystyrene, polyvinyl acetate, polyvinyl alcohol, polyvinyl butyral, polyvinyl chloride, polyvinyl ether, polyvinyl ketone, vinyl chloride-vinyl acetate copolymer, styrene acrylic acid ester copolymer, straight silicone resin or modified thereof containing organosiloxane bonds, fluororesin, polyester, polycarbonate, phenolic resin, epoxy resin, etc. The coating resin and matrix resin may also contain conductive particles and other additives. Examples of conductive particles include metals such as gold, silver, and copper, carbon black, titanium dioxide, zinc oxide, tin oxide, barium sulfate, aluminum borate, potassium titanate, etc.

[0107] To coat the surface of the core material with resin, one method is to coat it with a coating layer-forming solution prepared by dissolving the coating resin and various additives (used as needed) in a suitable solvent. The solvent is not particularly limited and should be selected considering the type of resin used and its suitability for coating. Specific resin coating methods include the immersion method, in which the core material is immersed in a coating layer forming solution; the spray method, in which the coating layer forming solution is sprayed onto the surface of the core material; the fluidized bed method, in which the coating layer forming solution is sprayed onto the core material while it is suspended by fluidized air; and the kneader coater method, in which the carrier core material and the coating layer forming solution are mixed in a kneader coater, and then the solvent is removed.

[0108] In a two-component developer, the mixing ratio (mass ratio) of green toner and carrier is preferably green toner:carrier = 1:100 to 30:100, and more preferably 3:100 to 20:100.

[0109] <Image forming device, image forming method> The image forming apparatus and image forming method according to this embodiment will be described below. The image forming apparatus according to this embodiment comprises an image holder, a charging means for charging the surface of the image holder, an electrostatic image forming means for forming an electrostatic image on the charged surface of the image holder, a developing means for containing an electrostatic image developer and developing the electrostatic image formed on the surface of the image holder as a toner image using the electrostatic image developer, a transfer means for transferring the toner image formed on the surface of the image holder to the surface of a recording medium, and a fixing means for fixing the toner image transferred to the surface of the recording medium. The electrostatic image developer according to this embodiment is applied as the electrostatic image developer.

[0110] The image forming apparatus according to this embodiment implements an image forming method (image forming method according to this embodiment) comprising: a charging step of charging the surface of an image holder; an electrostatic image forming step of forming an electrostatic image on the charged surface of the image holder; a developing step of developing the electrostatic image formed on the surface of the image holder as a toner image using an electrostatic image developer according to this embodiment; a transfer step of transferring the toner image formed on the surface of the image holder to the surface of a recording medium; and a fixing step of fixing the toner image transferred to the surface of the recording medium.

[0111] The image forming apparatus according to this embodiment may be any known image forming apparatus such as: a direct transfer apparatus that directly transfers a toner image formed on the surface of an image holder to a recording medium; an intermediate transfer apparatus that first transfers a toner image formed on the surface of an intermediate transfer body to the surface of an intermediate transfer body, and then secondarily transfers the toner image transferred to the surface of the intermediate transfer body to the surface of a recording medium; an apparatus equipped with cleaning means for cleaning the surface of the image holder before charging after the transfer of the toner image; or an apparatus equipped with static elimination means for irradiating the surface of the image holder with static elimination light before charging after the transfer of the toner image. In the case of an image forming apparatus of the present embodiment, if the image forming apparatus is an intermediate transfer type apparatus, the transfer means may include, for example, an intermediate transfer body on which a toner image is transferred; a primary transfer means for primaryly transferring the toner image formed on the surface of the image holder to the surface of the intermediate transfer body; and a secondary transfer means for secondary transferring the toner image transferred to the surface of the intermediate transfer body to the surface of the recording medium.

[0112] In the image forming apparatus according to this embodiment, for example, the part including the developing means may be a cartridge structure (process cartridge) that can be attached to and detached from the image forming apparatus. As the process cartridge, for example, a process cartridge containing the electrostatic image developer according to this embodiment and equipped with a developing means is preferably used.

[0113] The following describes an example of an image forming apparatus according to this embodiment, but is not limited to this example. In the following description, only the main parts shown in the figures will be described, and other parts will be omitted.

[0114] In the following description, a six-unit tandem image forming apparatus, in which six image forming units are arranged in a row, will be described as an example of an image forming apparatus according to this embodiment. The tandem image forming apparatus is not limited to this, and may also be a five-unit tandem image forming apparatus, a four-unit tandem image forming apparatus, a four-unit tandem image forming apparatus, and so on.

[0115] Figure 1 is a schematic diagram showing an image forming apparatus according to this embodiment, and is a diagram showing an image forming apparatus with a 6-series tandem system and an intermediate transfer system. The image forming apparatus shown in Figure 1 includes first to sixth image forming units 10P, 10Y, 10M, 10C, 10K, and 10G, which are electrophotographic image forming means that output images of pink (P), yellow (Y), magenta (M), cyan (C), black (K), and green (G) based on color-separated image data. These image forming units (hereinafter sometimes simply referred to as "units") 10P, 10Y, 10M, 10C, 10K, and 10G are arranged side by side at predetermined distances from each other in the horizontal direction. These units 10P, 10Y, 10M, 10C, 10K, and 10G may also be process cartridges that can be attached to and detached from the image forming apparatus. Furthermore, an embodiment in which orange (O) is used instead of pink (P) or green (G) is also preferred.

[0116] An intermediate transfer belt (an example of an intermediate transfer body) 20 extends from below each unit 10P, 10Y, 10M, 10C, 10K, and 10G through each unit. The intermediate transfer belt 20 is wound around a drive roll 22, a support roll 23, and an opposing roll 24 that are in contact with the inner surface of the intermediate transfer belt 20, and is configured to travel in the direction from the first unit 10P to the sixth unit 10G. An intermediate transfer body cleaning device 21 is provided on the image holding surface side of the intermediate transfer belt 20, opposite the drive roll 22.

[0117] Each of the developing devices (examples of developing means) for each unit 10P, 10Y, 10M, 10C, 10K, and 10G, specifically 4P, 4Y, 4M, 4C, 4K, and 4G, is supplied with pink, yellow, magenta, cyan, black, and green toners contained in toner cartridges 8P, 8Y, 8M, 8C, 8K, and 8G.

[0118] Since the first to sixth units 10P, 10Y, 10M, 10C, 10K, and 10G have equivalent configurations and operations, the sixth unit 10G, which forms the green image, will be described as representative here.

[0119] The sixth unit 10G has a photoreceptor 1G that acts as an image holder. Around the photoreceptor 1G are, in order, a charging roll (an example of a charging means) 2G that charges the surface of the photoreceptor 1G to a predetermined potential, an exposure device (an example of a charge image forming means) 3G that exposes the charged surface with a laser beam based on a color-separated image signal to form a charge image, a developing device (an example of a developing means) 4G that supplies toner to the charge image to develop the charge image, a primary transfer roll (an example of a primary transfer means) 5G that transfers the developed toner image onto an intermediate transfer belt 20, and a photoreceptor cleaning device (an example of a cleaning means) 6G that removes toner remaining on the surface of the photoreceptor 1G after primary transfer.

[0120] The primary transfer roll 5G is positioned inside the intermediate transfer belt 20, facing the photoreceptor 1G. Each primary transfer roll 5Y, 5P, 5M, 5C, 5G, and 5K of each unit is connected to a bias power supply (not shown) that applies the primary transfer bias. Each bias power supply changes the value of the transfer bias applied to each primary transfer roll through control by a control unit (not shown).

[0121] The following describes the process of forming a green image in the 6th unit 10G. First, prior to operation, the surface of the photoreceptor 1G is charged to a potential of -600V to -800V by the charging roll 2G. Photoreceptor 1G is conductive (e.g., volume resistivity of 1 × 10 at 20°C). -6 The photosensitive layer is formed by laminating a photosensitive layer on a substrate (less than Ωcm). This photosensitive layer normally has high resistance (resistance of general resin), but when irradiated with a laser beam, the resistivity of the irradiated area changes. Therefore, a laser beam is irradiated from the exposure device 3G onto the surface of the charged photoreceptor 1G according to green image data sent from a control unit (not shown). As a result, an electrostatic image of the green image pattern is formed on the surface of the photoreceptor 1G.

[0122] An electrostatic image is an image formed on the surface of the photoreceptor 1G due to electrostatic charge. It is a so-called negative latent image formed when the resistivity of the irradiated portion of the photoreceptor decreases due to the laser beam from the exposure device 3G, causing the charged material on the surface of the photoreceptor 1G to flow, while the charge remains in the portion not irradiated by the laser beam. The electrostatic charge image formed on the photoreceptor 1G rotates to a predetermined development position as the photoreceptor 1G moves. At this development position, the electrostatic charge image on the photoreceptor 1G is developed as a toner image by the developing device 4G and made visible.

[0123] The developing device 4G contains, for example, an electrostatic image developer including at least green toner and a carrier. The green toner is triboelectrically charged by being agitated inside the developing device 4G and is held on the developer roll (an example of a developer holder) with a charge of the same polarity (negative polarity) as the static charge on the photoreceptor 1G. As the surface of the photoreceptor 1G passes through the developing device 4G, the green toner electrostatically adheres to the discharged latent image on the surface of the photoreceptor 1G, and the latent image is developed by the green toner. The photoreceptor 1G, on which the green toner image has been formed, continues to move at a predetermined speed, and the toner image developed on the photoreceptor 1G is transported to a predetermined primary transfer position.

[0124] When the green toner image on the photoreceptor 1G is transported to the primary transfer position, a primary transfer bias is applied to the primary transfer roll 5G, and an electrostatic force acts on the toner image from the photoreceptor 1G to the primary transfer roll 5G, transferring the toner image on the photoreceptor 1G onto the intermediate transfer belt 20. The transfer bias applied at this time has a polarity opposite to the toner's polarity (-) (+), and in the first unit 10G, it is controlled by a control unit (not shown) to, for example, +10 μA.

[0125] After transferring the toner image to the intermediate transfer belt 20, the photoreceptor 1G continues to rotate and comes into contact with the cleaning blades of the photoreceptor cleaning device 6G. Any toner remaining on the photoreceptor 1G is removed and collected by the photoreceptor cleaning device 6G.

[0126] The intermediate transfer belt 20 is sequentially transported through the first to sixth image forming units 10P, 10Y, 10M, 10C, 10K, and 10G, and the toner images of each color are superimposed and transferred in multiple layers.

[0127] The intermediate transfer belt 20, on which six toner images have been multiple-transferred through the first to sixth units, proceeds to a secondary transfer section consisting of the intermediate transfer belt 20, a counter roll 24 in contact with the inner surface of the intermediate transfer belt, and a secondary transfer roll (an example of a secondary transfer means) 26 positioned on the image-holding surface side of the intermediate transfer belt 20. Meanwhile, recording paper (an example of a recording medium) P is fed via a supply mechanism into the gap between the secondary transfer roll 26 and the intermediate transfer belt 20 at a predetermined timing, and a secondary transfer bias is applied to the counter roll 24. The transfer bias applied at this time has the same polarity (-) as the toner's polarity (-), and an electrostatic force from the intermediate transfer belt 20 toward the recording paper P acts on the toner image, transferring the toner image on the intermediate transfer belt 20 onto the recording paper P. The secondary transfer bias at this time is determined according to the resistance detected by a resistance detection means (not shown) that detects the resistance of the secondary transfer section, and is voltage-controlled.

[0128] After transferring the toner image to the recording paper P, the intermediate transfer belt 20 continues to move and comes into contact with the cleaning blades of the intermediate transfer body cleaning device 21. Any toner remaining on the intermediate transfer belt 20 is removed and collected by the intermediate transfer body cleaning device 21.

[0129] The recording paper P onto which the toner image has been transferred is fed to the contact area (nip area) of a pair of fixing rolls in a fixing device (an example of a fixing means) 28, where the toner image is fixed onto the recording paper P, and a fixed image is formed.

[0130] Examples of recording paper P used to transfer toner images include plain paper used in electrophotographic photocopiers and printers. Other recording media besides recording paper P include OHP sheets. To further improve the smoothness of the image surface after fixing, it is preferable that the surface of the recording paper P is also smooth. For example, coated paper, which is plain paper coated with resin or the like, or art paper for printing are preferably used.

[0131] Once the color image has been fixed onto the recording paper P, it is discharged towards the output section, and the series of color image formation operations is completed.

[0132] <Processor cartridges, toner cartridges> The process cartridge according to this embodiment will be described. The process cartridge according to this embodiment contains the electrostatic image developer according to this embodiment and includes a developing means for developing the electrostatic image formed on the surface of the image holder as a toner image using the electrostatic image developer, and is a process cartridge that can be attached to and detached from an image forming apparatus.

[0133] The process cartridge according to this embodiment is not limited to the above configuration, and may also include a developing means and, as necessary, at least one other means selected from, for example, an image holder, a charging means, an electrostatic image forming means, and a transfer means.

[0134] An example of a process cartridge according to this embodiment is shown below, but it is not limited to this example. In the following description, only the main parts shown in the figure will be described, and other parts will be omitted from the description.

[0135] Figure 2 is a schematic diagram showing the process cartridge according to this embodiment. The process cartridge 200 shown in Figure 2 is constructed by integrally holding a photoreceptor 107 (an example of an image holder), a charging roll 108 (an example of a charging means) provided around the photoreceptor 107, a developing device 111 (an example of a developing means), and a photoreceptor cleaning device 113 (an example of a cleaning means) within a housing 117 equipped with a mounting rail 116 and an opening 118 for exposure, and is then formed into a cartridge. In Figure 2, 109 is an exposure apparatus (an example of electrostatic image formation means), 112 is a transfer apparatus (an example of a transfer means), 115 is a fixing apparatus (an example of a fixing means), and 300 is recording paper (an example of a recording medium).

[0136] Next, the toner cartridge according to this embodiment will be described. The toner cartridge according to this embodiment is a toner cartridge that contains the electrostatic image developing toner according to this embodiment and is attached to and detached from an image forming apparatus. The toner cartridge contains replenishment toner for supply to the developing means provided in the image forming apparatus.

[0137] The image forming apparatus shown in Figure 1 is configured to allow the attachment and detachment of toner cartridges 8Y, 8P, 8M, 8C, 8G, and 8K. The developing units 4Y, 4P, 4M, 4C, 4G, and 4K are connected to toner cartridges corresponding to their respective colors by toner supply pipes (not shown). When the toner contained in a toner cartridge becomes low, the toner cartridge is replaced. An example of a toner cartridge according to this embodiment is toner cartridge 8G, which contains the electrostatic image developing toner according to this embodiment. Toner cartridges 8P, 8Y, 8M, 8C, and 8K contain pink, yellow, magenta, cyan, and black toners, respectively. [Examples]

[0138] The embodiments of the invention will be described in detail below with reference to examples, but the embodiments of the invention are not limited to these examples. In the following explanation, unless otherwise specified, "parts" and "%" refer to mass. Synthesis, processing, and manufacturing were carried out at room temperature (25°C ± 3°C) unless otherwise specified.

[0139] <Preparation of colorant particle dispersion (1)> • Fluorescent yellow pigment (CI Pigment Yellow 101 (Radiant Color, Radglo VSF-0-01, emission peak wavelength 520nm)): 70 parts • Anionic surfactant (manufactured by Daiichi Kogyo Seiyaku Co., Ltd., Neogen RK): 30 parts (solid content concentration 20%) • Ion-exchanged water: 200 bottles The above components were mixed and ground to 0.5 μm using a continuous key mill (KMC-3), and the solid content was adjusted to 20% by mass to obtain a coloring agent particle dispersion (1).

[0140] <Preparation of colorant particle dispersion (2)> • Non-fluorescent green pigment (CI Pigment Green 36 (manufactured by Toyo Color Co., Ltd., LIONOL GREEN 8624, reflectance peak wavelength 510nm)): 70 parts • Anionic surfactant (manufactured by Daiichi Kogyo Seiyaku Co., Ltd., Neogen RK): 30 parts (solid content concentration 20%) • Ion-exchanged water: 200 bottles The above components were mixed and ground to 0.2 μm using a continuous key mill (KMC-3), and the solid content was adjusted to 20% by mass to obtain a coloring agent particle dispersion (2).

[0141] <Preparation of resin particle dispersion (1)> Terephthalic acid: 30 moles Fumaric acid: 70 moles • Bisphenol A ethylene oxide adduct: 5 moles • Bisphenol A propylene oxide adduct: 95 moles The above materials were placed in a flask equipped with a stirrer, nitrogen inlet tube, temperature sensor, and rectification column, and the temperature was raised to 220°C over 1 hour. One part titanium tetraethoxide was added for every 100 parts of the above materials. The temperature was raised to 230°C over 30 minutes while distilling off the generated water, and the dehydration condensation reaction was continued at this temperature for 1 hour. After that, the reactants were cooled. In this way, a polyester resin with a weight-average molecular weight of 18,000 and a glass transition temperature of 60°C was obtained. In a container equipped with temperature control and nitrogen purging means, 40 parts of ethyl acetate and 25 parts of 2-butanol were added to form a mixed solvent. Then, 100 parts of polyester resin were gradually added and dissolved. A 10% by mass aqueous ammonia solution (equivalent to 3 times the molar ratio of the acid value of the resin) was added and stirred for 30 minutes. Next, the container was purged with dry nitrogen, and the temperature was maintained at 40°C. While stirring the mixture, 400 parts of deionized water were added dropwise at a rate of 2 parts / minute. After the dropwise addition was complete, the mixture was returned to room temperature (20°C to 25°C), and while stirring, it was bubbled with dry nitrogen for 48 hours to obtain a resin particle dispersion in which the ethyl acetate and 2-butanol were reduced to 1,000 ppm or less. Deionized water was added to the resin particle dispersion to adjust the solid content to 20% by mass to obtain resin particle dispersion (1).

[0142] <Preparation of mold release agent particle dispersion (1)> • Paraffin wax (manufactured by Nippon Seiro Co., Ltd., HNP-9): 100 units • Anionic surfactant (manufactured by Daiichi Kogyo Seiyaku Co., Ltd., Neogen RK): 1 part • Ion-exchanged water: 350 units The above materials were mixed and heated to 100°C, dispersed using a homogenizer (IKA Corporation, product name Ultra-Turrax T50), and then dispersed again using a Manton-Gorin high-pressure homogenizer (Gorin Corporation) to obtain a release agent particle dispersion (1) (solid content 20% by mass) containing release agent particles with a volume average particle size of 200 nm.

[0143] <Preparation of toner particles (1)> ·Resin particle dispersion (1): 400 parts • Coloring agent particle dispersion (1): 50 parts • Coloring agent particle dispersion (2): 25 parts • Release agent particle dispersion (1): 25 parts Anionic surfactant (Daiichi Kogyo Seiyaku Co., Ltd.: Neogen RK, 20%): 10 parts The above materials were placed in a round stainless steel flask, and 0.1 N (= mol / L) nitric acid was added to adjust the pH to 3.5. Then, 30 parts of a 10% by mass nitric acid aqueous solution containing aluminum chloride were added. Next, the mixture was dispersed at a liquid temperature of 30°C using a homogenizer (IKA Corporation, product name Ultra-Turrax T50), and then heated to 45°C in a heating oil bath and held for 30 minutes. After that, 50 parts of the resin particle dispersion (1) were added and held for 1 hour, and then a 0.1 N sodium hydroxide aqueous solution was added to adjust the pH to 8.5. After that, it was heated to 84°C and held for 2.5 hours. Next, it was cooled to 20°C at a rate of 20°C / min, the solid components were filtered off, thoroughly washed with deionized water, and dried to obtain toner particles (1). The volume-average particle size of the toner particles (1) was 5.8 μm.

[0144] <Creating Carrier 1> • Ferrite particles (average particle size 35 μm): 100 parts • Toluene: 14 parts • Polymethyl methacrylate (MMA, weight-average molecular weight 75,000): 5 parts • Carbon black: 0.2 parts (VXC-72, manufactured by Cabot, volume resistivity: 100 Ωcm or less) The above materials, excluding the ferrite particles, were dispersed in a sand mill to prepare a dispersion. This dispersion was then placed together with the ferrite particles in a vacuum-degassed kneader and dried under reduced pressure while stirring to obtain carrier 1.

[0145] <Toner production> To 100 parts by mass of the obtained toner particles (1), 1.5 parts by mass of hydrophobic silica (manufactured by Nippon Aerosil Co., Ltd., RY50) and 1.0 part by mass of hydrophobic titanium oxide (manufactured by Nippon Aerosil Co., Ltd., T805) were mixed and blended using a sample mill at 10,000 rpm (revolutions per minute) for 30 seconds. Subsequently, the mixture was sieved using a vibrating sieve with a mesh size of 45 μm to prepare toner 1 (toner for electrostatic image development). The volume-average particle size of the obtained toner 1 was 5.8 μm.

[0146] <Preparation of electrostatic image developer> Eight parts toner and ninety-two parts carrier were mixed in a V-blender to prepare developer 1 (electrostatic image developer).

[0147] [Measurement of spectral reflectance] The spectral reflectance of the toner image was measured using the following method. In a room with a temperature of 25°C and a humidity of 60%RH, the main unit, developer unit, and toner cartridge of a Fujifilm Business Innovation Co., Ltd. DocuCentre Color 400 CP were thoroughly cleaned, removing all previously installed developer and toner, before being loaded into the toner cartridge. Next, the amount of toner used for developing a 100% single-color image on OS coated paper manufactured by Fujifilm Business Innovation Co., Ltd. is 4.0 g / m². 2 The image was adjusted to create a 5cm x 5cm image consisting only of toner. Using an X-Rite939 (manufactured by X-Rite, with a 4mm aperture), the spectral reflectance in the visible light region was measured at 10 random locations within the image plane. The spectral reflectance of the reflection peaks was then averaged to calculate the value. The evaluation criteria are as follows: A: Spectral reflectance at peak wavelength is 80% or higher B: Spectral reflectance at peak wavelength is 70% or more but less than 80% C: Spectral reflectance at peak wavelength is less than 70%

[0148] [Image bending resistance] In each example and comparative example, the toner-fixed image prepared during the spectral reflectance measurement was folded, and a 3kg weight was rubbed back and forth five times along the fold. After that, the paper was unfolded, and the image loss at the fold was visually evaluated. The evaluation criteria were as follows. A: There are no image defects, and the images remain in good condition; there are no problems. B: Some toner image defects are visible with line widths of 0.2mm or less, but this does not affect practical use. C: Toner images with line widths exceeding 0.2mm show missing parts, which poses a problem for practical use.

[0149] [Removability] With the DocuCentre Color 400 manufactured by Fujifilm Business Innovation Co., Ltd., the toner load is 4.5 g / m². 2 The unfixed image was output after adjustments were made to achieve the desired result. Film-based synthetic paper (Yupo paper, manufactured by Yupo Corporation) was used as the recording medium. The output image was a 50mm x 50mm solid image with 100% image density. For the fixation evaluation device, a modified ApeosPortIV C3370 manufactured by Fujifilm Business Innovation Co., Ltd. was used, with the fuser removed and the fixing temperature adjustable. The nip width of the fixation evaluation device was 6mm, and the nip thickness was 1.6kgf / cm². 2 The process speed was 175 mm / sec. Unfixed images were fixed at fixing temperatures from 160°C to 220°C in 5°C intervals, and the presence or absence of hot offset was visually checked. The lowest temperature at which hot offset occurred was evaluated as the hot offset occurrence temperature. The evaluation criteria are as follows. A: Hot offset occurs at temperatures above 200°C. B: Hot offset occurs at temperatures between 170°C and 200°C. C: Hot offset occurs at a temperature of less than 170°C

[0150] <Examples 2 to 18, and Comparative Examples 1 to 8> Except for changing the type and content of non-fluorescent organic pigments and fluorescent organic pigments as shown in Table 1 or Table 2, toners were prepared in the same manner as in Example 1, and then a developer was obtained and evaluated in the same manner.

[0151] [Table 1]

[0152] [Table 2]

[0153] The content of non-fluorescent organic pigments, fluorescent organic pigments, and total organic colorants in Tables 1 and 2 are all expressed as the content relative to the total mass of toner particles.

[0154] Details of the abbreviations in Tables 1 and 2 are shown below. PG36: CI Pigment Green 36 (manufactured by Toyo Color Co., Ltd., LIONOL GREEN 8624, specific gravity 2.9), a copper phthalocyanine non-fluorescent organic pigment containing chlorine and bromine atoms. • PG7: CI Pigment Green 7 (manufactured by Toyo Color Co., Ltd., LIONOL GREEN 8390, specific gravity 2.1), a copper phthalocyanine non-fluorescent organic pigment containing chlorine atoms. • PB15:3:CI Pigment Blue 15:3 (manufactured by Toyo Color Co., Ltd., LIONOL BLUE FG-7330, specific gravity 1.6), a non-fluorescent organic pigment containing copper phthalocyanine and no halogen atoms. PR216: CI Pigment Red 216 (BASF, Paliogen Red L3530, specific gravity 2.8), the following compound, anthraquinone-based non-fluorescent organic pigment PR168: CI Pigment Red 168 (Clariant, Hostaperm Scarlet GO, specific gravity 2.1), the following compound, anthraquinone-based non-fluorescent organic pigment PR3: CI Pigment Red 3 (Hansa Scarlet RNC, manufactured by Clariant, specific gravity 1.4), the following compound, azo-based non-fluorescent organic pigment. • PY101: CI Pigment Yellow 101 (Radiant Color, Radglo VSF-0-01, emission peak wavelength 520nm), azomethine-based fluorescent organic pigment • VSF-0-05: The following compound (Radiant Color, Radglo VSF-0-05, emission peak wavelength 519 nm), isoindolinone-based fluorescent organic pigment. PY101-BF2: A boron difluoride derivative of CI Pigment Yellow 101 (emission peak wavelength 570nm), the following compound, an azomethine-based fluorescent organic pigment.

[0155] [ka]

[0156] (Example 101) <Image formation using actual equipment> A six-tandem electrophotographic and intermediate transfer image forming apparatus was prepared. Each of the six developing units was filled with a pink developer, a yellow developer, a magenta developer, a cyan developer, a black developer, and a green developer (the developer from Example 1). Then, based on the image data obtained by color-separating RGB data into the six colors described above, an image was formed on A4-sized coated paper. An image with good color reproduction close to the original RGB data was obtained.

[0157] (((1))) A toner for developing electrostatic images comprising toner particles containing an organic colorant and a binder resin, wherein the organic colorant comprises a non-fluorescent organic pigment and a fluorescent organic pigment, the total content of the organic colorant is 5% by mass or more and 20% by mass or less of the total mass of the toner particles, and the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy both of the following formulas (1) and (2). D1≧2.0 Formula (1) D1-D2≧0.6 Formula (2) (((2))) The toner for developing electrostatic images according to (((1))), wherein the volume average particle size D50v of the fluorescent organic pigment is 30 nm or more and 800 nm or less. (((3))) The toner for developing electrostatic images according to (((2))), wherein the volume average particle size D50v of the fluorescent organic pigment is 100 nm or more and 500 nm or less. (((4))) The toner for developing electrostatic images according to any one of (((1))) to (((3))), wherein the volume average particle size of the non-fluorescent organic pigment is less than or equal to the volume average particle size of the fluorescent organic pigment. (((5))) The toner for developing electrostatic images according to any one of (((1))) to (((4))) wherein the specific gravity D1 of the non-fluorescent organic pigment satisfies the following formula (1A). D1≧2.5 Formula (1A) (((6))) A toner for developing electrostatic images according to any one of (((1))) to (((5))) wherein the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy the following formula (2A). D1-D2≧0.75 Formula (2A) (((7))) The toner for developing electrostatic images according to (((6))), wherein the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy the following formula (2B). D1-D2≧1.0 Formula (2B) (((8))) The nonfluorescent organic pigment having a halogen atom is the electrostatic image developing toner according to any one of (((1))) to (((7))). (((9))) The toner for developing electrostatic images according to (((8))), wherein the halogen atom is at least one selected from the group consisting of chlorine atoms and bromine atoms. A electrostatic image developer containing the toner for developing electrostatic images described in any one of (((10))) (((1))) to (((9))). A toner cartridge that contains the electrostatic image developing toner described in any one of (((11))) (((1))) to (((9))) and is attached to and detached from an image forming apparatus. A process cartridge that contains the electrostatic image developer described in (((12))) (((10))) and includes a developing means for developing an electrostatic image formed on the surface of an image holder as a toner image using the electrostatic image developer, and is detachable from an image forming apparatus. (((13))) An image forming apparatus comprising: an image holder; charging means for charging the surface of the image holder; electrostatic image forming means for forming an electrostatic image on the charged surface of the image holder; developing means for containing the electrostatic image developer described in (((10))) and developing the electrostatic image formed on the surface of the image holder as a toner image using the electrostatic image developer; transfer means for transferring the toner image formed on the surface of the image holder to the surface of a recording medium; and fixing means for fixing the toner image transferred to the surface of the recording medium. (((14))) An image forming method comprising: a charging step of charging the surface of an image holder; a static charge image forming step of forming a static charge image on the charged surface of the image holder; a developing step of developing the static charge image formed on the surface of the image holder as a toner image using the static charge image developer described in (((10))); a transfer step of transferring the toner image formed on the surface of the image holder to the surface of a recording medium; and a fixing step of fixing the toner image transferred to the surface of the recording medium. (((15))) An image forming apparatus comprising first to sixth electrophotographic image forming units that form images of pink, yellow, magenta, cyan, black, and green, wherein the image forming unit that forms the green image contains the electrostatic image developer described in (((10))). (((16))) An image forming method comprising first to sixth electrophotographic image forming steps for forming images of pink, yellow, magenta, cyan, black, and green, wherein the image forming step for forming the green image uses the electrostatic image developer described in (((10))).

[0158] According to the invention of (((1))), a toner for developing electrostatic images is provided that includes toner particles containing an organic colorant and a binder resin, wherein the organic colorant includes a non-fluorescent organic pigment and a fluorescent organic pigment, and the total content of the organic colorant is less than 5% by mass or more than 20% by mass of the total mass of the toner particles, or the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy either of the following formulas (1) and (2). According to the invention of (((2))), a toner for developing electrostatic images is provided that has superior bending resistance and peelability in the resulting image compared to cases where the volume average particle size D50v of the fluorescent organic pigment is less than 30 nm or greater than 800 nm. According to the invention of (((3))), a toner for developing electrostatic images is provided that has superior bending resistance and peelability in the resulting image compared to cases where the volume average particle size D50v of the fluorescent organic pigment is less than 100 nm or greater than 500 nm. According to the invention of (((4))), a toner for developing electrostatic images is provided that is superior in terms of bending resistance and peelability in the resulting image compared to the case where the volume average particle size of the non-fluorescent organic pigment is larger than the volume average particle size of the fluorescent organic pigment. According to the invention of (((5))), a toner for developing electrostatic images is provided in which the resulting image has better bending resistance and higher reflectivity compared to the case in which the specific gravity D1 of the non-fluorescent organic pigment does not satisfy formula (1A). According to the invention of (((6))), compared to the case where the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy formula (2A), a toner for developing electrostatic images is provided which has superior bending resistance in the resulting image and a higher reflectivity in the resulting image. According to the invention of (((7))), a toner for developing electrostatic images is provided in which the resulting image has superior bending resistance and higher reflectivity compared to the case where the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy formula (2B). According to the invention of ((8)), a toner for developing electrostatic images is provided which has superior bending resistance in the resulting image and a higher reflectivity in the resulting image compared to when the non-fluorescent organic pigment does not have halogen atoms. According to the invention of (((9))), a toner for developing electrostatic images is provided that has superior bending resistance in the resulting image and a higher reflectivity in the resulting image compared to the case where the halogen atoms consist only of fluorine atoms or iodine atoms. According to the inventions of (((10))), (((11))), (((12))), (((13))), (((14))), (((15))), or (((16))), the electrostatic image developing toner contains toner particles containing an organic colorant and a binder resin, the organic colorant contains a non-fluorescent organic pigment and a fluorescent organic pigment, the total content of the organic colorant is less than 5% by mass or more than 20% by mass of the total mass of the toner, or the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment do not satisfy either formula (1) or formula (2), compared to the case in which the resulting image has superior bending resistance and peelability, and the resulting image has high reflectivity, an electrostatic image developing agent, toner cartridge, process cartridge, image forming apparatus, or image forming method is provided. [Explanation of symbols]

[0159] 1P, 1Y, 1M, 1C, 1K, 1G Photoreceptor (an example of an image retainer) 2P, 2Y, 2M, 2C, 2K, 2G Charging Rolls (Example of Charging Method) 3P, 3Y, 3M, 3C, 3K, 3G exposure equipment (an example of electrostatic image forming means) 4P, 4Y, 4M, 4C, 4K, 4G developing device (an example of a developing method) 5P, 5Y, 5M, 5C, 5K, 5G Primary transfer rolls (an example of a primary transfer method) 6P, 6Y, 6M, 6C, 6K, 6G Photoconductor Cleaning Device (Example of Cleaning Method) 8P, 8Y, 8M, 8C, 8K, 8G Toner Cartridges 10P, 10Y, 10M, 10C, 10K, 10G Image Forming Units 20. Intermediate transfer belt (an example of an intermediate transfer material) 21 Intermediate Transfer Body Cleaning Apparatus 22 Drive Roll 23 Support Roll 24 Opposing Roll 26. Secondary transfer roll (an example of a secondary transfer means) 28 Fixing device (an example of a fixing means) P Recording paper (an example of a recording medium)

[0160] 107 Photoreceptor (an example of an image-retaining element) 108 Charging Roll (Example of Charging Method) 109 Exposure apparatus (an example of a means for forming electrostatic images) 111 Developing apparatus (an example of a developing means) 112 Transfer device (an example of a transfer means) 113 Photoreceptor cleaning device (an example of a cleaning method) 115 Fixing device (an example of a fixing means) 116 Mounting Rail 117 cabinets 118 Aperture for exposure 200 Process Cartridges 300 Recording paper (an example of a recording medium)

Claims

1. Contains toner particles containing organic colorants and binder resins, The aforementioned organic colorant comprises a non-fluorescent organic pigment and a fluorescent organic pigment. The total content of the organic colorant is 5% by mass or more and 20% by mass or less, relative to the total mass of the toner particles. The volume-average particle size D50v of the fluorescent organic pigment is 30 nm or more and 800 nm or less. The specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy both formulas (1) and (2) below. Toner for developing electrostatic images. D1≧2.0 Formula (1) D1-D2≧0.6 Formula (2)

2. The toner for developing electrostatic images according to claim 1, wherein the fluorescent organic pigment is an azomethine compound.

3. The toner for developing electrostatic images according to claim 1, wherein the volume-average particle size D50v of the fluorescent organic pigment is 100 nm or more and 500 nm or less.

4. The toner for developing electrostatic images according to claim 1, wherein the volume-average particle size of the non-fluorescent organic pigment is less than or equal to the volume-average particle size of the fluorescent organic pigment.

5. The toner for developing electrostatic images according to claim 1, wherein the specific gravity D1 of the non-fluorescent organic pigment satisfies the following formula (1A). D1≧2.5 Formula (1A)

6. The toner for developing electrostatic images according to claim 1, wherein the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy the following formula (2A). D1-D2≧0.75 Formula (2A)

7. The toner for developing electrostatic images according to claim 6, wherein the specific gravity D1 of the non-fluorescent organic pigment and the specific gravity D2 of the fluorescent organic pigment satisfy the following formula (2B). D1-D2≧1.0 Formula (2B)

8. The toner for developing electrostatic images according to claim 1, wherein the non-fluorescent organic pigment has a halogen atom.

9. The toner for developing electrostatic images according to claim 8, wherein the halogen atom is at least one selected from the group consisting of chlorine atoms and bromine atoms.

10. A electrostatic image developer comprising the electrostatic image developing toner according to any one of claims 1 to 9.

11. A toner cartridge for containing the electrostatic image developing toner described in any one of claims 1 to 9, and which can be attached to and detached from an image forming apparatus.

12. A process cartridge that contains the electrostatic image developer described in claim 10, and comprises a developing means for developing an electrostatic image formed on the surface of an image holder as a toner image using the electrostatic image developer, and is detachable from an image forming apparatus.

13. Image holder and, A charging means for charging the surface of the image holder, A means for forming an electrostatic image on the surface of the charged image holder, A developing means comprising: containing the electrostatic image developer described in claim 10; and developing the electrostatic image formed on the surface of the image holder as a toner image using the electrostatic image developer; A transfer means for transferring a toner image formed on the surface of the image holder to the surface of a recording medium, Fixing means for fixing the toner image transferred to the surface of the recording medium, An image forming apparatus equipped with the following features.

14. A charging step in which the surface of the image holder is charged, A step of forming an electrostatic image on the surface of the charged image holder, A developing step of developing the electrostatic image formed on the surface of the image holder as a toner image using the electrostatic image developer described in claim 10, A transfer step of transferring the toner image formed on the surface of the image holder to the surface of the recording medium, A fixing step for fixing the toner image transferred to the surface of the recording medium, An image forming method having the following characteristics.

15. It comprises first to sixth image forming units of an electrophotographic method that form images of pink, yellow, magenta, cyan, black, and green, The image forming unit that forms the green image contains the electrostatic image developer described in claim 10. Image forming apparatus.

16. The system has first to sixth image forming steps using an electrophotographic method to form images of pink, yellow, magenta, cyan, black, and green. The image forming step for forming the aforementioned green image uses the electrostatic image developer described in claim 10. Image forming method.

Images