Vacuum insulation material

Abstract

The present invention provides a vacuum insulation material that reduces equipment and manufacturing costs, lowers thermal conductivity, maintains its insulating effect even when laid in a tile-like pattern, and allows for greater flexibility in planar shape. [Solution] A vacuum insulation material comprising an exterior body having an upper surface, a lower surface and an outer peripheral side surface, being flattened in the vertical direction and having an internal space, a film-like metal member, and a spacer, wherein the exterior body is composed of two outer plates made of resin flat plates facing each other in the vertical direction, two metal plates laminated on the opposing inner surfaces of the two outer plates, and a resin peripheral member arranged to encircle the periphery of the two metal plates and sealing the internal space together with the two metal plates, the spacer is attached to the exterior body so as to be sandwiched between the two metal plates in the internal space, and the film-like metal member is attached to the exterior body so as to cover at least one of the outer peripheral side surface and the inner surface of the peripheral member, and the internal space is sealed in a high vacuum state.

Description

Technical Field

[0001] The present invention relates to a vacuum insulation material.

Background Art

[0002] Conventional vacuum insulation materials are members that use heat insulation materials such as silica or glass wool as a core material and seal the periphery of the core material in a vacuum state. More specifically, the core material is disposed in a bag-shaped outer package made of an aluminum laminate film whose inside is maintained in a vacuum state. In the vacuum insulation material, the region where the core material is disposed is formed in a rectangular flat plate shape, and the periphery of the flat plate-shaped region serves as a seal portion for sealing the bag-shaped outer package. This vacuum insulation material has extremely little heat conduction due to the internal vacuum state and the low heat conductivity core material, has no heat transfer by convection because there are extremely few gas molecules in the vacuum state, and the outer package of the aluminum laminate film also greatly reduces heat transfer by radiation. Therefore, while achieving a thinner thickness, it has the same heat insulation effect as a conventional thick heat insulation material using the core material as it is.

[0003] And, from the viewpoints of energy saving and space saving, the vacuum insulation material is widely used for various heat insulation applications, for example, the walls of buildings, the casings of refrigerators and coolers. That is, due to its thin rectangular flat plate shape, the vacuum insulation material can obtain a higher heat insulation effect while maintaining the outer dimensions and volume by laminating in the thickness direction. Alternatively, the volume can be increased while maintaining the outer dimensions and the heat insulation effect. Furthermore, the amount of the core material in the vacuum insulation material may be the minimum amount necessary to secure a space in the outer package made of a flexible and easily deformable aluminum laminate film. Therefore, the vacuum insulation material is also useful from the viewpoint of resource saving.

[0004] In addition to conventional vacuum insulation materials that use aluminum laminate film for the outer casing, vacuum insulation materials that use stainless steel foil for the outer casing have recently appeared, and their commercialization in the fields of cold chain transportation and building materials is being considered, with some examples of their introduction being reported. Vacuum insulation materials are described, for example, in the following Patent Document 1 and Non-Patent Document 1. [Prior art documents] [Patent Documents]

[0005] [Patent Document 1] Japanese Patent Publication No. 2010-173700 [Non-patent literature]

[0006] [Non-Patent Document 1] Panasonic Holdings Corporation, "Development of High-Performance Vacuum Insulation Material and its Application to Refrigerators," [online], [Accessed May 16, 2024], Internet<URL:https: / / holdings.panasonic / jp / corporate / technology / technology-journal / pdf / v6002 / p0110.pdf> [Overview of the project] [Problems that the invention aims to solve]

[0007] As mentioned above, conventional vacuum insulation materials have a structure in which a core material with low thermal conductivity is placed inside a thin, flexible outer casing made of aluminum laminate film. Therefore, when vacuum insulation materials are installed for building material applications, there is a problem that holes are easily formed in the outer casing. In addition, when vacuum insulation materials are installed in large areas such as the walls of buildings, multiple vacuum insulation materials are laid out in a tile-like pattern, but with conventional vacuum insulation materials, it is difficult to lay multiple vacuum insulation materials without gaps due to the seal formed around the outer casing of the laminate film, and heat leaks from between adjacent vacuum insulation materials, reducing the insulation effect. It is possible to increase the area of ​​each vacuum insulation material, but this would require creating a high vacuum of 10⁻² Pa or less inside the large outer casing, which would increase manufacturing costs.

[0008] Furthermore, the degree of thermal insulation effect of a flat vacuum insulation material is judged comprehensively, not just in the front-to-back direction (thickness direction). For example, conventional vacuum insulation materials use an aluminum laminate film as the outer casing. As is well known, aluminum is a material with high thermal conductivity. And, in conventional vacuum insulation materials, the front and back surfaces of the outer casing are in direct contact at the seal, so the heat that transfers from the front to the back surface due to thermal conduction on the surface of the outer casing cannot be ignored.

[0009] Furthermore, conventional vacuum insulation materials use an outer casing made by welding the edges of an aluminum laminate film to form a bag, which limits the flexibility of the planar shape of the area that provides insulation. For example, if the planar shape of a wall or floor is complex, there will be areas where vacuum insulation material cannot be placed. If a wide variety of vacuum insulation materials with different planar shapes are prepared to accommodate complex shapes, a wide variety of welding equipment for aluminum laminate films will be required to accommodate the wide variety of outer casings with different shapes, increasing the cost of manufacturing equipment and overall production costs.

[0010] Vacuum insulation materials that use stainless steel foil instead of aluminum laminate film for the outer casing have the same challenges as conventional vacuum insulation materials. However, a key feature is that the amount of heat that moves from the surface to the back is expected to be significantly reduced due to heat conduction on the surface of the outer casing. On the other hand, dealing with heat passing perpendicularly from the surface of the seal portion that protrudes from the side may be a challenge.

[0011] Therefore, the present invention aims to provide a vacuum insulation material that does not increase the cost of manufacturing equipment or production costs, can lower the overall thermal conductivity, does not reduce the insulation effect even when laid out in a tile-like manner over a large area, and allows for a high degree of freedom in planar shape. Furthermore, it also aims to be applied to areas that conventional vacuum insulation materials have not addressed, such as large refrigerated containers with large wall surfaces and areas that are subjected to impact during loading, unloading, and transportation. [Means for solving the problem]

[0012] A vacuum insulation material for solving the above problem comprises an outer casing having a top surface, a bottom surface and an outer peripheral side surface, being flattened in the vertical direction and having an internal space, a film-like metal member attached to the outer casing, and a spacer attached to the outer casing, wherein the outer casing is a flattened box-shaped vacuum insulation material with a constant thickness in the vertical direction, comprising: two outer plates made of resin flat plates facing each other in the vertical direction, two metal plates laminated on the opposing inner surfaces of the two outer plates so as to cover the inner surfaces, and a resin peripheral member arranged to encircle the periphery of the two metal plates and to seal the internal space together with the two metal plates, the spacer is attached to the outer casing so as to be sandwiched between the two metal plates in the internal space sealed by the two metal plates and the peripheral member, and the film-like metal member is attached to the outer casing so as to cover at least one of the outer peripheral side surface and the inner surface of the peripheral member facing the internal space. One of the two outer panels and the metal plate laminated to that outer panel have holes for discharging air from the internal space that penetrate the outer panel in a shape that decreases in diameter from the outer panel toward the metal plate, and the holes are sealed using a spherical sealant and adhesive. The internal space is sealed in a high vacuum state. [Effects of the Invention]

[0013] According to the present invention, a vacuum insulation material is provided that does not increase the cost of manufacturing equipment or production costs, does not reduce the heat insulation effect even when laid out in a tile-like pattern over a large area, and allows for a high degree of freedom in planar shape. Other effects will be clarified in the following description. [Brief explanation of the drawing]

[0014] [Figure 1] This figure shows the common appearance of the vacuum insulation material according to the examples. [Figure 2] This is an enlarged view of the cross-section of the vacuum insulation material according to the example. [Figure 3] This figure shows the arrangement of the side plates that constitute the outer casing of the vacuum insulation material according to the embodiment. [Figure 4] This figure shows a modified example of the vacuum insulation material according to the example. [Figure 5] This figure shows the manufacturing procedure for vacuum insulation material according to the example. [Figure 6] This diagram shows the cross-section and heat transfer of a conventional vacuum insulation material. [Modes for carrying out the invention]

[0015] Embodiments of the present invention will be described below with reference to the accompanying drawings. In the drawings used in the following description, the same or similar parts may be denoted by the same reference numerals, and redundant explanations may be omitted. In some drawings, unnecessary reference numerals may be omitted for explanation. ===maker=== An example of a vacuum insulation material 10 according to an embodiment of the present invention is given. Figure 1 shows the external appearance of the vacuum insulation material 10 according to the embodiment. As shown in Figure 1, the vacuum insulation material 10 according to the embodiment has a flat box-like appearance. In this flat box-shaped vacuum insulation material 10, if the thickness direction is the vertical direction, the vacuum insulation material 10 is square when viewed from the vertical direction. Both the upper and lower surfaces are the surfaces of a rectangular flat outer plate 2 made of resin material, and the sides are covered with a metal foil 3 such as stainless steel foil.

[0016] FIG. 2 is a view showing the structure of the vacuum heat insulating material 10 according to the embodiment. Note that FIG. 2 is a cross-sectional view taken along the line a-a in FIG. 1 and is an enlarged view of the dotted circular region 100 in FIG. 1. As shown in FIG. 2, the vacuum heat insulating material 10 according to the embodiment includes two resin outer plates 2 facing each other in the vertical direction, and two metal plates 4 made of stainless steel or the like that are fixed in a laminated state on the inner surfaces of the respective outer plates 2 so as to cover the facing inner surfaces of these two outer plates 2. Among the facing inner surfaces of the two metal plates 4, a resin prismatic member (hereinafter sometimes referred to as "side plate 5") sandwiched between the two metal plates 4 in the peripheral region of the two metal plates 4, a resin spacer 6 disposed between the two metal plates 4 facing each other in the vertical direction, and the above-mentioned metal foil 3.

[0017] FIG. 3 shows the arrangement of the side plates 5 when viewed from the vertical direction. As shown in this FIG. 3, the four side plates 5 are formed as a frame-shaped member (hereinafter sometimes referred to as "peripheral side member 30") that circulates around the peripheries of the outer plate 2 and the metal plate 4 laminated thereon. And the outer package 20 of the vacuum heat insulating material 10 is formed by the outer plate 2, the metal plate 4, and the peripheral side member 30. Further, an internal space of the outer package 20 is formed so as to be surrounded by the two metal plates 4 and the peripheral side member 30. This internal space is sealed and is in a high-vacuum state. Note that hereinafter, in the internal space of the outer package 20, the vacuum space excluding the region of the spacer 6 will be referred to as the vacuum portion 7.

[0018] Thus, the outer package 20 has an upper surface, a lower surface, and an outer peripheral side surface, is flat in the vertical direction and has an internal space, and the upper surface and the lower surface are constituted by the two outer plates 2. Further, the outer peripheral side surface of the outer package 20 is constituted by the two outer plates 2, the two metal plates 4, and the side plates 5 (peripheral side member 30). Also, the outer package 20 has an internal space sealed by the two metal plates 4 and the side plates 5 (peripheral side member 30).

[0019] The outer panel 2, side panels 5, and spacers 6 are all made of a resin material commonly referred to as "hard plastic" (hereinafter sometimes referred to as "plastic"), such as polycarbonate (PC) or polyvinyl chloride (PVC). These resins all have a Young's modulus of 2 GPa or higher, an elongation of 50% or less, and a Shore hardness of 70 or higher. Of course, these values ​​are not limited as long as the shape of the exterior body 20 can be maintained.

[0020] Here, referring to Figures 1 to 3, the specifications of the vacuum insulation material 10 will be explained. The vacuum insulation material 10 has a square planar shape with a side length L1 = 600 mm and a flattened box shape with a top-to-bottom height H1 = 6 mm. The outer panel 2 that constitutes the exterior body 20 has a square planar shape with a side length L1 = 600 mm and is made of plastic with a thickness of t1 = 0.8 mm. Each side panel 5 that constitutes the peripheral member 30 is made of the same material as the outer panel 2, and has a top-to-bottom height H2 and a width w1 of H2 = 4 mm and w1 = 2 mm, respectively, and is a slender rectangular prism shape with a length L2 = 598 mm. The metal foil 3 is stainless steel foil with a thickness of t2 = 0.01 mm, and its width in the top-to-bottom direction is 6 mm, the same as the height H1 of the outer shape of the vacuum insulation material 10.

[0021] The metal plate 4 is a flat plate made of stainless steel, with a square planar shape having the same side length L1 = 600 mm as the outer plate 2, and a thickness t3 = 0.2 mm. Inside the outer casing 20, an internal space with a planar shape of 596 mm × 596 mm and a height H2 = 4 mm is formed, and within this space, numerous spacers 6 made of the same material as the outer plate 2 are arranged at equal intervals in the plane when viewed from above. In this embodiment, 900 spacers 6 are arranged, and each spacer 6 has a cylindrical shape with a diameter of 2 mm and a height of 4 mm. The metal foil 3 is a stainless steel foil with a vertical height H1 = 6 mm and a thickness t2 = 0.01 mm, and is fixed in close contact with the outer edge surfaces of the outer plate 2 and the metal plate 4 and the outer surface of the peripheral member 30. The outer plate 2, metal plate 4, side plate 5, spacer 6, and metal foil 3 are each bonded to each other at the surfaces that are in contact with each other by an adhesive (e.g., acrylic adhesive, epoxy adhesive, etc.).

[0022] According to the vacuum insulation material 10 with the above configuration, the outer casing 20 uses resin and metal materials with much lower thermal conductivity than the aluminum laminate film used for the outer casing of conventional vacuum insulation materials, thereby reducing heat transfer across the outer surface. Inside the vacuum insulation material 10, metal plates 4 are fixed to the upper and lower outer panels 2 in a laminated state, suppressing thermal expansion and contraction of the resin outer panels 2. In other words, deformation of the outer panels 2 does not generate unnecessary stress in the adhesive sealing area, and the sealed state of the outer casing 20 is maintained more reliably. The metal plates 4 also serve to improve gas barrier properties.

[0023] Furthermore, in the vacuum insulation material 10 according to the embodiment, although the outer plate 2 and side plates 5 constituting the exterior body 20 are bonded together with adhesive, and the inside of the exterior body 20 is reliably sealed, there is still a possibility that gaps may form at the bonding points between the side plates 5 and the bonding points between the side plates 5 and the metal plate 4 due to external stress, etc., which could become pathways for air to enter the interior of the exterior body 20. Therefore, in the vacuum insulation material 10 according to the embodiment, a metal foil 3 with excellent gas barrier properties is bonded to the outer surface of the exterior body 20, thereby more reliably blocking the intrusion of air from the outside and more reliably maintaining the vacuum state of the internal space. In addition to the intrusion of air from the outside, gas generation from spacers 6, etc., can also be considered as a factor that reduces the vacuum state of the internal space, so it is preferable to install a getter agent (not shown) inside the vacuum section 7.

[0024] Furthermore, the metal plates 4 laminated on the outer panel 2 and the metal foil 3 bonded to the outer periphery of the exterior body 20 also serve the function of reflecting radiant heat from the outside. Specifically, the metal plates 4 reflect heat radiation from above and below, and the metal foil 3 reflects heat radiation from the sides outwards. As a result, the vacuum insulation material 10 also suppresses the transfer of heat into the interior of the exterior body 20 by radiation.

[0025] In this embodiment, stainless steel is used for the metal plate 4 and metal foil 3, but the metal used for the metal plate 4 and metal foil 3 can be appropriately selected according to the specifications of the intended use of the vacuum insulation material 10.

[0026] Furthermore, the vacuum insulation material 10 according to the embodiment is flat and box-shaped, and unlike conventional vacuum insulation materials, there is no laminate film sealing area around the perimeter. Therefore, if multiple vacuum insulation materials 10 are arranged in a tile-like manner on the walls or floors of a building, the sides of adjacent vacuum insulation materials 10 will be in contact with each other without any gaps, thus suppressing heat leakage from between adjacent vacuum insulation materials 10.

[0027] Furthermore, in the vacuum insulation material 10 according to the embodiment, the outer plate 2 and metal plate 4 can be made into any planar shape simply by cutting a resin plate or a thin metal plate. For example, as shown in the modified example of the vacuum insulation material 10 in Figure 4, the planar shape of the vacuum insulation material 10 when viewed from above or below can be made into a polygon. In the side plates 5, at positions corresponding to each corner of the outer plate 2, as shown in the enlarged view of the inside of the circular region 102 in Figure 4, the tips of the two side plates 5 that abut each other at each corner of the polygon are cut diagonally at an angle that matches the corner. Each side plate 5 constituting the vacuum insulation material 10 shown in Figure 4 can be made, for example, by cutting a long rectangular prism-shaped resin member at an angle corresponding to each corner of the polygon. Of course, if the side plates 5 are formed in a curved shape, it can also accommodate planar shapes that include curves. Thus, the vacuum insulation material 10 according to the embodiment also has the effect of improving the degree of freedom in the planar shape of the exterior body 20 by using resin outer plates 2 and side plates 5 that are easy to machine, and thin metal plates 4. <Procedure for manufacturing vacuum insulation material> Figure 5 shows an example of the manufacturing procedure for a vacuum insulation material 10 according to an embodiment. Note that in Figure 5, the scale of each component has been changed to make the manufacturing procedure easier to understand. First, the components that make up the vacuum insulation material 10 are prepared: two outer plates 2, two metal plates 4, four side plates 5, 900 spacers 6, and four strip-shaped metal foils 3 (s1). Here, the outer plates 2 and the metal plates 4 are prepared as components that have been bonded together in a laminated state beforehand (hereinafter sometimes referred to as "laminated components (21, 22)"). In addition, a hole 23 that penetrates in the thickness direction is formed in one of the two laminated components (21, 22), 22. Note that this hole 23 is formed in a tapered shape that narrows in diameter toward the metal plate 4 in the outer plate 2 portion.

[0028] Next, the four side plates 5 are bonded together so that they form a rectangular frame-shaped peripheral member 30, and the rectangular frame-shaped peripheral member 30 is bonded to the surface of the metal plate 4 on one of the laminated members 21. This forms a box-shaped member 11 that is open at the top (s2). Furthermore, a spacer 6 is bonded to the inner bottom surface (metal plate 4) of this box-shaped member 11, and the opening of the box-shaped member 11 is covered with the other laminated member 22, while the contact surfaces of each member are bonded together (s3). In this way, a flat, box-shaped exterior body 20 is completed, which has a void inside where the spacer 6 is placed, and is sealed in all parts except for the holes 23 that connect the inside and outside. Next, metal foil 3 is bonded to each of the four sides (outer peripheral sides) of this exterior body 20. This completes the assembly of the vacuum insulation material 10 (hereinafter sometimes referred to as the "insulation structure 12") as a structure, although air is present inside (s4).

[0029] Next, the insulating structure 12 having the holes 23 connecting the inside and outside is placed in a vacuum chamber (not shown), and the pressure inside the vacuum chamber is reduced to create a vacuum in the internal space of the insulating structure 12, forming a vacuum section 7 (s5). Furthermore, a sealing material 24 made of an iron ball or the like is dropped into the tapered holes 23 using a manipulator or the like inside the vacuum chamber (s6), closing the holes 23. Then, adhesive 25 is dropped into the holes 23 using a dispenser or the like, allowing the adhesive to penetrate the interface between the sealing material 24 and the holes 23, and the adhesive 25 is cured to complete the vacuum insulating material 10 (s7). Thermosetting or ultraviolet curing adhesives 25 can be used. Of course, if sufficient gas barrier properties can be ensured, the holes 23 may be sealed with adhesive 25 alone. Also, the above-described procedure (s5) to (s7) can be carried out, for example, using a well-known vacuum sealing device. ===Thermal insulation effect=== <Conditions for manufacturing vacuum insulation material> The thermal insulation effect of the vacuum insulation material 10 according to the example was roughly determined and evaluated. Table 1 below shows the conditions of each component for calculating the thermal conductivity of the vacuum insulation material 10 according to the example. Since each component constituting the vacuum insulation material 10 is in the form of a plate or foil, in Table 1, the planar size when viewed from the top and bottom is denoted as L and W, and the size in the vertical direction is denoted as H.

[0030] [Table 1] <Confirmation of the insulation effect> Next, the results of determining the thermal conductivity of the vacuum insulation material 10 according to the embodiment are shown. Possible methods for determining thermal conductivity include calculation methods for each heat transfer path, measurement methods using measuring instruments, and simulation methods. However, the method using measuring instruments does not have an established method for measuring thermal conductivity. Furthermore, when determining the thermal conductivity of the vacuum insulation material 10 by calculation methods for each heat transfer path, it is necessary to set several conditions that greatly affect the thermal conductivity, which may result in obtaining an uncertain thermal conductivity.

[0031] Therefore, in this embodiment, the thermal conductivity was determined by simulation. By using software for thermal conduction analysis, the thermal conductivity that can be used as a reference for determining the practicality of the vacuum insulation material 10 can be determined. In this embodiment, the thermal conductivity was determined using "Cradle FCD scFLOW 2024.2", software supplied by MSC Software Corporation, which has a proven track record of use.

[0032] Table 2 shows the physical properties set for the simulation.

[0033] [Table 2] Analysis conditions: Transient heat transfer analysis (3,600 seconds in 1-second increments) Initial conditions: Set the entire area to 0°C. Boundary conditions: The upper surface (high temperature side) was given an external temperature of 100°C, the lower surface (low temperature side) was given an external temperature of 0°C, and the contact heat transfer coefficient was set to 5 W / m²·K, which is a typical value for natural convection of air.

[0034] Vacuum section: No physical properties were applied, and the heat transfer boundary conditions were adiabatic.

[0035] Structure: A 1 / 4 scale model of 600×600×6mm full scale, similar to Figures 1, 2, and 3, was used, with 300×300×6mm geometrically symmetrical boundary conditions, divided in half along the (xy) orthogonal central axes. The number of mesh elements was 591,124.

[0036] As a result of the simulation conducted under these conditions, the average temperature of the bottom surface after 3,600 seconds reached 17.13°C, indicating a near-steady state, and the equivalent thermal conductivity in the thickness direction of the vacuum insulation material 10 was found to be 0.0063 W / m·K. Note that equivalent thermal conductivity is the thermal conductivity given when a component composed of multiple materials, such as this vacuum insulation material 10, is treated as a single block.

[0037] Based on the result of a thermal conductivity of 0.0063 W / mK, it can be said that the vacuum insulation material 10 according to the example has practical, high-performance insulation capabilities.

[0038] Furthermore, the vacuum insulation material 10 according to the embodiment has superior characteristics compared to conventional vacuum insulation materials that are widely used, as described below.

[0039] The following explanation will first describe the significant challenges regarding the heat conduction of conventional vacuum insulation materials, and then explain the superiority of the vacuum insulation material 10 according to this embodiment. This can be considered one of the features of the vacuum insulation material 10 according to this embodiment.

[0040] First, the challenges in determining the thermal conductivity of conventional vacuum insulation materials will be explained with reference to Figure 6. Conventional vacuum insulation materials, as mentioned above, consist of a core material placed inside an outer shell which is a bag-shaped outer shell made of aluminum laminate film that is maintained in a vacuum state on the inside. The area where the core material is placed is formed in the shape of a rectangular plate. For the sake of explanation, the temperature of the air in contact with the upper and lower plate-shaped surfaces, which are also the outer shells of this type of vacuum insulation material, will be referred to as the high-temperature side for the upper shell and the low-temperature side for the lower shell. In a vacuum insulation material under such environmental conditions, the path by which heat received from the high-temperature air region moves from the upper shell to the lower shell can be divided into two paths: one that moves vertically from the upper shell through the core material to the lower shell, and another that moves laterally towards the high-temperature end P10 (hereinafter sometimes referred to as the "top") of the upper shell, and then moves via the side of the vacuum insulation material to the low-temperature end P11 (hereinafter sometimes referred to as the "bottom") of the lower shell; in other words, the path of heat wrapping around.

[0041] In the former path, heat moves through the core material, which has low thermal conductivity, so the amount of heat transferred is extremely small. In contrast, in the path that wraps around the sides, heat moves through the outer skin, which is made of aluminum and has high thermal conductivity, so it has high heat transfer performance. However, if the amount of heat supplied from the area of ​​air surrounding the top P10 to the bottom P11 is insufficient to match the heat transfer performance, the temperature near the top P10 will decrease. Along with this decrease, lateral heat transfer towards the top P10 begins in the upper outer skin. Thus, heat wrap-around occurs. This phenomenon is called a thermal bridge, and the amount of heat transferred is generally larger than the amount of heat that moves vertically through the core material, becoming a major problem that reduces the insulation performance. In the lower outer skin, the opposite occurs to the upper outer skin: a temperature increase and lateral heat transfer towards the center of the outer skin.

[0042] Thus, a major problem with conventional vacuum insulation materials is the large amount of heat that can wrap around the sides.

[0043] Therefore, regarding the amount of heat that wraps around the side, Table 3 shows the results obtained by setting conditions for the degree of heat conduction performance of the peripheral members constituting the side in the case of conventional vacuum insulation material and the vacuum insulation material 10 according to the embodiment. The peripheral members of the conventional vacuum insulation material are aluminum foil, and the peripheral members of the vacuum insulation material 10 are a side plate 5 made of resin and a metal foil 3 made of stainless steel, and the height of the aluminum foil is 6 mm out of the height H of each peripheral member, and the height of the side plate 5 and the metal foil 3 is 4 mm as shown in Figure 2 (H2), and the temperature difference between the upper and lower ends of each peripheral member is the same t. To illustrate this with the conventional vacuum insulation material, the height from the top P10 to the bottom P11 in Figure 6 is 6 mm, and the temperature difference between the temperature T10 at the top P10 and the temperature T11 at the bottom P11 is t, for convenience t is set to 100°C. Furthermore, the cross-sectional area A of the peripheral member when viewed from the top and bottom is 6 mm² when the thickness of the aluminum in the conventional vacuum insulation material is 0.01 mm and the length of one side of the peripheral member is 600 mm. For the vacuum insulation material 10, if the peripheral member is considered as a composite material composed of a side plate 2 and a metal foil 3, its cross-sectional area A is 1,206 mm² when the combined thickness of the side plate 2 (2 mm) and the metal foil 3 (0.01 mm) is 2.01 mm and the length of one side of the peripheral member is 600 mm. Incidentally, if the peripheral member of the vacuum insulation material 10 is considered as a composite material and its thermal conductivity λ in the top and bottom direction is calculated to be 0.328 W / m·K ((= 0.01 mm × 16 W / m·K + 2 mm × 0.25 W / m·K) / 2.01 mm).

[0044] [Table 3] Table 3 shows the heat conduction performance of the peripheral member, which is a key component in the heat transfer path, calculated in terms of heat quantity by setting conditions to understand the degree of performance of the vacuum insulation material 10 in the example compared to a conventional vacuum insulation material. As can be seen from Table 3, the heat transfer of the vacuum insulation material 10 is approximately 42% of that of the conventional vacuum insulation material, indicating less heat transfer. In other words, while the large amount of heat transfer is a major problem with conventional vacuum insulation materials, the vacuum insulation material 10 has the characteristic of being able to significantly improve this problem. ===Other Examples=== Although the vacuum insulation material 10 according to the embodiment has been described above, it goes without saying that the present invention is not limited to the above embodiment and can be modified in various ways without departing from the spirit of the invention. Furthermore, the above embodiment has been described in detail in order to explain the present invention in an easy-to-understand manner and is not necessarily limited to having all the configurations described. In addition, it is possible to add, delete, or replace some of the configurations of the above embodiment with other configurations.

[0045] For example, in the embodiment, the metal foil 3 arranged on the outer peripheral side surface of the exterior body 20 was individually bonded to each side of the square outer plate 2 when viewed from above or below, but a single long strip of metal foil 3 may be bonded so as to encircle the outer peripheral side surface of the exterior body 20.

[0046] In the vacuum insulation material 10 according to the embodiment, the peripheral member 30 of the outer casing 20 is formed in a frame shape by bonding the respective ends of the strip-shaped side plates 5 together, but it may also be integrally formed in a frame shape.

[0047] The function of the spacers 6 in the vacuum insulation material 10 according to the embodiment is to prevent the outer casing 20 from being deformed and crushed vertically due to the pressure difference between the inside and outside of the outer casing 20. In the vacuum insulation material 10 according to the embodiment, 900 spacers 6 were placed inside the outer casing 20 because it was necessary to reliably evaluate the insulation effect. However, in the vacuum insulation material 10 according to the embodiment, a metal plate 4 having sufficient strength to the resin is laminated onto the resin outer plate 2, so it is considered that there would be no problem even if the number of spacers 6 were further reduced.

[0048] In this embodiment, since the peripheral member 30 of the exterior body 20 is composed of a rectangular prism-shaped side plate 5, this rectangular prism-shaped side plate 5 may also serve as a spacer 6. In any case, the spacer 6 should be a member that is sandwiched between metal plates 4 facing each other in the vertical direction to maintain the spatial shape inside the exterior body 20.

[0049] In the vacuum insulation material 10 according to the embodiment, the metal foil 3 arranged on the outer surface of the outer casing 20 may be replaced with a laminate film (such as an aluminum laminate film) in which a metal layer and a resin layer are laminated. Alternatively, a large sheet of laminate film may be cut into strips and heat-pressed to the outer surface of the outer casing 20. This simplifies the process of arranging the metal foil 3 on the outer surface of the outer casing 20. In any case, it is sufficient that the thin metal member adheres closely to the outer surface of the outer casing 20 and covers it. As is well known, laminate films include those in which a thin metal film formed by vapor deposition or the like is laminated on a resin film, or those in which a resin coating is applied to the surface of a metal foil.

[0050] In the embodiment, the exterior body 20 had a component constituting the periphery member 30 arranged between the upper and lower metal plates 4. However, a laminate of the outer plate 2 and the metal plate 4 may be arranged inside the frame-shaped periphery member 30. In such a case, the inner circumferential surface of the frame-shaped periphery member 30 is bonded to the outer circumferential edge surfaces of the outer plate 2 and the metal plate 4. In such a case, the metal foil 3 should be arranged to cover from the outer circumferential side surface of the exterior body 20 to the bonding area between the outer circumferential edge surface of the outer plate 2 and the inner circumferential surface of the periphery member 30.

[0051] In the above embodiment, the metal foil 3 was attached to the outer peripheral side surface of the outer casing 20, but it may also be attached to the inner side of the peripheral member 30, that is, to the side of the internal space sealed by the peripheral member 30 and the metal plate 4. [Explanation of Symbols]

[0052] 2. Outer panel 3 Metal foil 4 metal plate 5 Side panels 6 Spacers 7 Vacuum section 10 Vacuum insulation material 20 Exterior 30 Peripheral side member

Claims

1. A vacuum insulation material comprising an outer casing having a top surface, a bottom surface and outer peripheral sides, being flattened in the vertical direction and having an internal space, a film-like metal member attached to the outer casing, and a spacer attached to the outer casing, wherein the material is a flattened box-shaped vacuum insulation material with a constant thickness in the vertical direction, The exterior body is composed of two outer plates made of resin flat plates facing each other in the vertical direction, two metal plates laminated on the opposing inner surfaces of the two outer plates so as to cover the inner surfaces, and a resin peripheral member arranged to encircle the periphery of the two metal plates and to seal the internal space together with the two metal plates. The spacer is attached to the exterior body so as to be sandwiched between the two metal plates in the internal space sealed by the two metal plates and the peripheral member. The film-like metal member is attached to the exterior body so as to cover at least one of the outer peripheral surface and the inner surface of the peripheral member facing the internal space. One of the two outer panels and the metal plate laminated to it have holes for discharging air from the internal space that penetrate the outer panel in a shape that decreases in diameter from the outer panel toward the metal plate, and these holes are sealed using a spherical sealant and adhesive. The aforementioned internal space is sealed in a high vacuum state. Vacuum insulation material.

2. The vacuum insulation material according to claim 1, wherein the peripheral member is sandwiched between the two metal plates in a region along the periphery of the two metal plates among the opposing inner surfaces of the two metal plates, and is arranged together with the two outer plates and the two metal plates to form the outer peripheral surface of the exterior body.

3. The vacuum insulation material according to claim 1, wherein the film-like metal member is a metal foil.

4. The vacuum insulation material according to claim 1, wherein the film-like metal member is a laminate film formed by laminating a metal layer and a resin layer, and the resin layer is in close contact with the outer peripheral surface of the exterior body.

5. The vacuum insulation material according to any one of claims 1 to 4, wherein the metal constituting the film-like metal member and the metal plate is stainless steel.

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