HERBICIDE COMPOSITION COMPRISING R-PYRIDYLOXYCARBOXYLIC ACID AND DERIVATIVE AND AN APPLICATION THEREOF

Abstract

The present invention pertains to the technical field of pesticides, and relates in particular to a herbicidal composition comprising R-pyridyloxycarboxylic acid and a derivative thereof, and an application thereof. The composition comprises an active ingredient A and an active ingredient B in an effective herbicidal amount, wherein the active ingredient A is one or more compounds selected from an R-pyridyloxycarboxylic acid represented by formula I and its salt, ester derivative (see Formula), wherein R1, R2 each independently represent halogen, C1-C6 alkyl, C1-C6 haloalkyl, or C3-C6 cycloalkyl; R3 represents hydrogen, halogen, C1-C6 alkyl, or C1-C6 haloalkyl; Q represents C1-C6 alkyl, etc.; and Y represents amino, etc.The active ingredient B is selected from the following compounds: acid, salt, or ester derivatives; ALS inhibitor, ACCase inhibitor, PSII inhibitor, HPPD inhibitor, PDS inhibitor, DOXP inhibitor, PPO inhibitor, synthetic hormone, EPSPS inhibitor, GS inhibitor, PSI inhibitor. The composition is capable of effectively controlling various weeds and has the following advantages: it exhibits a broad spectrum of weed control, is used at a reduced dose, and is capable of producing a synergistic effect and eliminating resistant weeds.

Description

TECHNICAL FIELD - The present invention belongs to the technical field of pesticides, and refers, in particular, to a herbicidal composition comprising R-pyridyloxycarboxylic acid and derivative and an application thereof. BACKGROUND jΊChemical weed control is one of the most economical and effective means of controlling weeds on agricultural land; However, continuous use of a single chemical herbicide or a chemical herbicide with a single functional mechanism at a high dose over a long period of time is likely to cause problems associated with evolved drug resistance and weed tolerance. Complexation or formulation of herbicidal compounds can achieve the following advantages: exhibiting a broad spectrum of weed control, improving weed control effect, and delaying the emergence and development of drug resistance and tolerance of weeds. weeds, making it one of the most effective means to solve the above problems. Therefore, herbicidal compositions that have high safety and a broad spectrum of weed control, and are capable of producing a synergistic effect and eliminating resistant weeds, are considered desirable in production. CONTENT OF THE INVENTION To solve the above problems existing in the prior art, the present invention provides a herbicidal composition comprising R-pyridyloxycarboxylic acid and a derivative and an application thereof. The composition is capable of effectively controlling weeds such as broadleaf or grass type weeds, etc. , and has the following advantages: it exhibits a broad spectrum of weed control when used at a reduced dose, and is capable of producing a synergistic effect and eliminating resistant weeds. or. A herbicidal composition comprising R-pyridyloxycarboxylic acid and its derivative comprising an active ingredient A and an active ingredient B in a herbicidal effective amount, wherein, the active ingredient A is one or more compounds selected from an R-pyridyloxycarboxylic acid represented by formula I and the salt, its ester derivative, Qfronnn / zznz / E / YiAi where, Ri, R2 each independently represent halogen, alkyl C1-C6, C1-C6 haloalkyl or C3-C6 cycloalkyl; R3 represents hydrogen, halogen, C1-C6 alkyl or C1-C6 haloalkyl; Q represents C1-C6 alkyl, halo C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, halogen, cyano, amino, nitro, formyl, C1-C6 alkoxy, C1-C6 alkylthio, ig alkoxycarbonyl C1-C6, hydroxy C1-C6 alkyl, C1-C6 alkoxy C1-C6 alkyl, cyano C1-C6 alkyl, C1-C6 alkylamino 01-06 alkyl; ophenyl, benzyl, naphthyl, furyl, thienyl, thiazolyl, pyrazolyl, pyridyl or pyrimidinyl that is unsubstituted or substituted by at least one group selected from the group consisting of C1-C6 alkyl, cyano, halo C1-C6 alkyl, C1 alkylamino -C6, halogen, C1-C6 alkoxy; Y represents amino, C1-C6 alkylamino, C1-C6 alkylcarbonylamino; or phenylcarbonylamino, benzylamino or furylmethyleneamino that is unsubstituted or substituted by at least one group selected from the group consisting of C1-C6 alkyl, halogen, cyano, C1-C6 alkylamino, C1-C6 alkoxy, C1-C6 haloalkyl; salt is metal salt, ammonium salt NH4+, primary amine salt R”NH2, secondary amine salt (R”)2NH, tertiary amine salt (R”)3N, quaternary amine salt (R”)4N+ , polyamine salt, morpholine salt, N-methylmorpholine salt, piperidine salt, pyridine salt, aminopropylmorpholine salt, Jeffamine D-230 salt, 2,4,6-tri(dimethylaminomethyl)phenol hydroxide salt sodium, C1-C16 alkylsulfonium salt preferably, C1-C6 alkylsulfonium salt), alkylsulfonium salt 01-016 (preferably alkylsulfonium salt 01-06), alkylphosphonium salt 01-016 (preferably alkylphosphonium salt 01-06) or alkanolphosphonium salt of 01-016 (preferably alkanolphosphonium salt 01-06); wherein, R" each independently represents C1-C16 alkyl, 02-012 alkenyl (preferably 02-06 alkenyl), 02-012 alkynyl, (preferably 02-06 alkynyl), 03-012 cycloalkyl; or 01-016 alkyl (preferably 01-06 alkyl) substituted with one or more of the following groups: halogen, hydroxy, 01-06 alkoxy, 01-06 alkylthio, 01-06 hydroxy alkoxy; or phenyl or benzyl which is unsubstituted or substituted with 01-06 alkyl. AND O ester is1-1, where X represents O or S; M represents C1-C18 alkyl, halo C1-C8 alkyl, C3-C6 cycloalkyl which is unsubstituted or substituted with C1-C6 alkyl, C2-C6 alkenyl, halo C2-C6 alkenyl, C2-C6 alkynyl, C1-C6 alkoxy , C1-C6 alkoxycarbonyl, C1-C6 alkylsulfonyl, C1-C6 cyanoalkyl, nitroalkyl OR4n'R5nR'4..0¾ C1-C6, C1-C6 alkoxy C1-C6 alkyl, -(C1-C6 alkyl)-Z,R5 ,R5 , O ; either Qfronnn / zznz / E / YiAi phenyl, ' or tetrahydrofuryl, pyridyl, naphthyl, furyl, thienyl, pyrrolyl, pyrazolyl or imidazolyl which is unsubstituted or substituted with at least one group selected from the group consisting of . C1-C6 alkyl, C1-C6 haloalkyl, cyano, C1-C6 alkylamino, halogen, C1-C6 alkoxy; EITHER ,.ργΟ.^ ,γΟ.Β; Z represents R5 ,R5 ,R5 O ,0 ; or phenyl, Qΰ θ, tetrahydrofuryl, pyridyl, pyrazolyl, thienyl, furyl or naphthyl that is unsubstituted or substituted with at least one group selected from the group consisting of C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylamino, halo alkyl C1-C6, cyano, halogen; R4, Rs, Re each independently represent hydrogen, C1-C6 alkyl, C1-C6 alkoxycarbonyl; or phenyl that is unsubstituted or substituted with at least one group selected from the group consisting of 01-06 alkyl, 01-06 alkoxy, 01-06 alkylamino, halo 01-06 alkyl, cyano, halogen; R? represents 01-06 alkyl, C2-C6 alkenyl or;0); active ingredient B is selected from the following one or more compounds or acid derivatives or salt or ester thereof, (1) ALS inhibitor selected from: for example, penoxsulam (CAS N.s: 219714-96-2), bispyribac sodium ( CAS N.2:125401-92-5), pyrazosulfuron-ethyl (CAS N.2: 93697-74-6), nicosulfuron (CAS N.2: 111991-09-4), florasulam (CAS N.2: 145701 -23-1), rimsulfuron (CAS N.2: 122931-48-0), imazethapyr (CAS N.s: 81335-77-5), imazapic (CAS N.s: 104098-48-8), imazamox (CAS N.e: 114311 -32-9), sulfometuron-methyl (CAS N.e: 74222-97-2), chloransulam-methyl (CAS N.s: 147150-35-4); (2) ACCase inhibitor selected from: for example, cyhalofop-butyl (CAS N.s: 122008-85-9), clodinafop-propargyl (CAS N.2: 105512-06-9), pinoxaden (CAS N.2: 243973 -20-8), clethodim (CAS N.2: 99129-21-2), sethoxydim (CAS N.2: 74051-80-2), quizalofop-P-methyl (CAS N.2: 100646-51-3 ), fluazifop-P-butyl (CAS N.2: 79241-46-6), haloxyfop-P-methyl (CAS N.2: 72619-32-0); ,. (3) PSII inhibitor selected from: for example, atrazine (CAS N.s: 1912-24-9), isoproturon (CAS N.2: 34123-59-6), chlorotoluron (CAS N.2: 15545-48-9 ), diuron (CAS N.2: 330-54-1), bentazone (CAS N.8: 25057-89-0), bromoxynyl (CAS N.s: 1689-84-5), propanyl (CAS N.s: 709-98 -8); (4) HPPD inhibitor selected from: for example, huanbifucaotong (CAS N.s: 1855929-45-1), shuangzuocaotong (CAS N.8: 1622908-18-2), benzuofucaotong (CAS N.s: 1992017-55-6), sanzuohuangcaotong (CAS N.8: 1911613-97-2), tefuryltrione (CAS N.8: 473278-76-1), mesotrione (CAS N.s: 104206-82-8), tembotrione (CAS N.e: 335104-84-2 ), topramezone (CAS N.s: 210631-68-8), isoxaflutole (CAS N.s: 141112-29-0), benzobicilone (CAS N.s: 156963-66-5); (5) PDS inhibitor selected from: for example, diflufenican (CAS N.e: 83164-33-4), flurochloridone (CAS N.s: 61213-25-0); (6) DOXP inhibitor: for example, clomazone (CAS N.8: 81777-89-1); (7) PPO inhibitor selected from: for example, carfentrazone-ethyl (CAS N.8: 128621-72-7), fomesafen (CAS N.s: 72178-02-0), fluoroglycophen (CAS N.8: 77501-60 -1), oxyfluorfen (CAS N.8: 42874-03-3), lactofen (CAS N.8: 77501-63-4), acifluorfen sodium (CAS N.s: 50594-66-6), flumioxazin (CAS N.s: 103361-09-7), sulfentrazone (CAS N.s: 122836-35-5), saflufenacil (CAS N.s: 372137-35-4), oxadiazon (CAS N.e: 19666-30-9), oxadiargil (CAS N.8: 39807-15-3); (8) Synthetic hormone inhibitor selected from: for example, triclopyr (CAS N.8: 55335-06-3), MCPA (CAS N.8: 94-74-6), dicamba (CAS N.8: 1918 -00-9), picloram (CAS N.s: 1918-02-1), aminopyralid (CAS N.8: 150114-71-9), fluroxypyr (CAS N.8: 69377-81-7), florpyrauxifen benzyl (CAS N.s: 1390661-72-9), halauxifen-methyl (CAS N.s: 943831-98-9), quinclorac (CAS N.8: 84087-01-4), clopyralid (CAS N.8: 1702-17-6) ; (9) EPSPS inhibitor: for example, glyphosate (CAS N.8: 1071-83-6); (10) GS inhibitor selected from, for example, glufosinate ammonium (CAS N.8: 77182-82-2); (11) PSI inhibitor selected from, for example, diquat dibromide monohydrate (CAS N.8: 6385-62-2), paraquat dichloride (CAS N.8: 1910-42-5). Preferably, Ri, R2 each independently represent fluorine, chlorine, bromine, iodine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or cyclopropyl; R3 represents hydrogen, fluorine, chlorine, bromine, iodine, methyl or trifluoromethyl; Q represents methyl, ethyl, propyl, isopropyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, cyano, amino, nitro, formyl, methoxy, methylthio, methoxycarbonyl, monochloromethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, 2-chloroethyl, 2, 2,2-trifluoroethyl, hydroxymethyl, απρηηη / 77η7 / Β / γΐΛΐ Qfronnn / zznz / E / YiAi O rr and N-N N-N n-n n-n or T ) which is unsubstituted or substituted by fluorine; R'z(r,z, R'zo R,z) which is unsubstituted or substituted with methyl or fluorine; or phenyl that is unsubstituted or substituted by at least one group selected from the group consisting of methyl, trifluoromethyl, chloro, methoxy; salt is alkali metal salt (such as sodium, lithium, potassium, cesium or rubidium), alkaline earth metal salt (such as calcium, magnesium, barium or strontium) and metal salts such as antimony, bismuth, cadmium, cerium, chromium, cobalt, scandium, titanium, manganese, copper, iron, silver, gold, zinc, aluminum, etc., amine salt such as ammonium salt, tetramethylammonium salt, tetraethylammonium salt, tetrapropylammonium salt, tetrabutylammonium salt, N-hexadecyltrimethylamine salt, N-benzyltrimethylammonium salt, benzyltriethylammonium salt, choline amine salt, monomethylamine salt, dimethylamine salt, trimethylamine salt, monoethylamine salt, diethylamine salt, triethylamine salt, n-salt propylamine, dipropylamine salt, tripropylamine salt, monoisoprolamine salt, diisopropylamine salt, triisopropylamine salt, n-butylamine salt, dibutylamine salt, tributylamine salt, isobutylamine salt, tert-butylamine salt, pentylamine salt, hexylamine salt, heptylamine salt, octylamine salt, dodecylamine salt, tetradecylamine salt, diallylamine salt, cyclohexylamine salt, cyclododecylamine salt, aniline salt, o-toluidine salt, m-toluidine salt, p-toluidine, dianiline salt, benzylamine salt, monoethanolamine salt, N-methyl monoethanolamine salt, Ν,Ν-dimethylethanolamine salt, N-ethyl monoethanolamine salt, N-salt, N-diethylethanolamine, N-salt propyl monoethanolamine, N salt, N-di-n-propylethanolamine, N-butyl monoethanolamine salt, diethanolamine salt, N-methyldiethanolamine salt, N-ethyldiethanolamine salt, N-propyldiethanolamine salt, N-butyldiethanolamine salt, N, N-dibutylethanolamine salt, triethanolamine salt, tripropanolamine salt, triisopropanolamine salt, tri(2-hydroxypropyl)amine salt, diglycolamine salt, polyamine salt (for example hexamethylenetetramine salt, ethylenediamine salt, diethylenetriamine salt, dimethylaminopropylamine salt, 1,2-propyldiamine salt, triethylenediamine salt, triethylenetetramine salt, benzidine salt, Ν,Ν-bis [aminopropyl] methylamine), 2-methylthiopropylamine salt, 2-butoxyethylamine salt, AEPD (oh), tri(methylol)aminomethane salt (oh), morpholine salt, Qfronnn / zznz / E / YiAi N-methylmorpholine, piperidine salt, pyridine salt, aminopropylmorpholine (NH2) salt, Jeffamine D-230 salt , n is 2 or 3), the salt of 2,4,6-tri (dimethylaminomethyl) phenol and sodium hydroxide, sulfonium salt such as alkylsulfonium salt (such as trimethylsulfonium salt, triethylsulfonium salt), salt alkylsulfoxonium, phosphonium salt such as alkylphosphonium salt or alkanolphosphonium salt; in formula 1-1, X represents O or S; M represents methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, isobutyl, tere-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, octadecyl, trifluoromethyl, pentafluoroethyl, 3-chlorobutyl , 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 4,4,4-trifluorobutyl, 2,2,3,3,3-pentafluoropropyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, ayl, 2-propynyl, methoxy, ethoxycarbonyl, methylsulfonyl, ό' ΧΝ, < is unsubstituted or substituted with methyl, dimethylamino, chloro, methoxy, trifluoromethyl or isopropyl; or benzyl which is unsubstituted or substituted with trifluoromethyl, bromo, chloro, fluorine, methoxy, cyano or methyl; R' represents hydrogen, methyl, ethyl or difluoromethyl. More preferably, active ingredient A is one or more compounds selected from: Comp N.s. A Structure 1H NMR A1 nh2 d^J^CI G A OH F N Ο γ 0 1H NMR (500 MHz, DMSO-d6) δ 12.96 (s, 1H), 6.99 (s, 2H), 5.06 (q, J=7.0 Hz , 1H), 1.50 (d, J=7.0 Hz, 3H) A2 nh2 CkÁOI F 0 1H NMR (500 MHz, chloroform-d) δ 5.28 (q, J = 7.0 Hz, 1H), 5.15 (s, 2H), 4.27 - 4.07 (m, 3H), 3.91 - 3.73 (m, 2H), 2.04 - 1.82 (m, 3H), 1.66 (d, J = N.a. of comp. A Structure 1H NMR 7.0 Hz, 3H), 1.59-1.54 (m, 1H). A3 A1 sodium salt A4 A1 potassium salt A5 A1 calcium salt A6 A1 lithium salt A7 A1 aluminum salt A8 A1 barium salt A9 A1 magnesium salt A10 A1 copper salt A11 A1 iron salt A12 A1 ammonium salt A13 A1 monomethylamine salt A14 A1 dimethylamine salt A15 A1 trimethylamine salt A16 A1 monoethylamine salt A17 A1 diethylamine salt A18 A1 triethylamine salt A19 A1 ethylenediamine salt A20 A1 triethylene diamine salt A21 A1 monoethanolamine salt A22 A1 diethanolamine A23 A1 triethanolamine salt A24 A1 N-methyl monoethanolamine salt A25 A1 N-methyldiethanolamine salt A26 A1 N-ethyl monoethanolamine salt A27 A1 N-ethyldiethanolamine salt A28 A1 Ν,Ν-diethyldiethanolamine salt A29 A1 N salt -propyl monoethanolamine A30 A1 N-propyl diethanolamine salt A31 A1 N,N-di-n-propylethanolamine salt A32 A1 N-butyl monoethanolamine salt A33 A1 N-butyl diethanolamine salt οίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A34 A1 Ν,Ν-dibutylethanolamine salt A35 A1 n-propylamine salt A36 A1 dipropylamine salt A37 A1 tripropylamine salt A38 A1 n-butylamine salt A39 A1 dibutylamine salt A40 A1 tributylamine salt A41 A1 salt isobutylamine A42 A1 tert-butylamine salt A43 A1 hexylamine salt A44 A1 octylamine salt A45 A1 aniline salt A46 A1 diphenylamine salt A47 A1 benzidine salt A48 A1 benzylamine salt A49 A1 cyclohexylamine salt A50 A1 monoisopropylamine salt A51 A1 diisopropylamine salt A52 A1 diglycolamine salt A53 A1 hexamethylenetetramine salt A54 A1 tetramethylammonium salt A55 A1 tetraethylammonium salt A56 A1 tetrapropylammonium salt A57 A1 tetrabutylammonium salt A58 A1 choline amine salt A59 A1 N-benzyltrimethylammonium salt A60 A1 salt N-hexadecyltrimethylammonium A61 A1 pyridine salt A62 A1 N-methylmorpholine salt A63 A1 o-toluidine salt A64 A1 m-toluidine salt A65 A1 p-toluidine salt οίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A66 A1 piperidiine salt A67 nh2 CI^AoI Λ , 1H), 3.65 (s, 3H), 1.50 (d, J = 7.0Hz, 3H). A68 nh2 ci.^ X X / ..,0, / F N 0 γ 0 A69 nh2 ci ...,1 X a χΑγι F XnXq^Y° γ^ 0 1 A73 nh2 CI^ / LoI XX F^N OW 0 A74 nh2 a X X X F^ N Ο γ 0 οίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A76 o o ..... °=< O A77 o b° ...... ce Ó O O A78 nh2 Carnation X X F N OÁ / i 0 । A79 nh2 CI''A X Aoi X X F^ N owv γ 0 \ A83 nh2 X N.a. of comp. A Structure 1H NMR A85 nh2 d^A^d X X F N OW^ 0 A86 nh2 d.. A X A87 nh2 d^l X X F N OW '^'·ν 0 A88 nh2 d^ÁOi X d^ / L^d / XX a^oxXXx^ F^N^OW 0 A92 nh2 d^A^I X X / f n owy 0 A93 nh2 d^Á^d X X F^ N ^OW 0 N.a. of comp. A Structure 1H NMR A94 nh2 d, J = 7.0Hz, 3H), 1.21 - 1.31 (m, 2H), 1.12-1.24 (m, 16H), 0.83-0.91 (m, 3H) A95 nh2 ΟΙ,ΛόΙ X X F^N^OW O A96 nh2 c |..,a X A101 nh2 GI^ÁO! XX F^N^OW - F 0 A102 nh2 Ci^A^1 iX^o F^N θΑγ ^Cl 0 οίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A103 nh2 ci...A X X F N ΟΑΛγ Br 0 A104 nh2 IIW „CF, ρζΝ0γ 3 or A106 nh2 CI^ J 11 F N 0 and CF3 0 A107 nh2 CI^A / CI JL .0 / x. ^CF, F N 0^ y 3 0 A108 nh2 CI\<^<CI fAA^°-^c' 0 A109 nh2 ciYYci = ρΑ^Ό^-Αγ01 0 Cl A110 nh2 A 0 ΌΝ f n οΑγ x / 0 A111 nh2 xNOo F / N oA z XV 2 0 N.a. of comp. A Structure 1H NMR A112 nh2 ci^Xoi X X F N OW^ NH2 O A113 nh2 CI. A X X / F^ N OWV N 0 1 A114 nh2 ClxX i π — zX5 o o ..... o <^o o A118 \ o o o _.....c° O o o A119 nh2 Ck A. / CI YX ? 0 A120 nh2 CI\X / CI W Ξ ? ΓΌ Η / 1 q J1 / F^N^O^Y ^cr 0 N.a. of comp. A Structure 1H NMR A121 nh2 0 1 or A122 nh2 Ck 1,CI Υύ Ξ ? F^N 0 Y N 0 1 A123 nh2 ci-X^ci _ I T Ξ II 1 N 0 1 A124 -η — o o ok..... o A125 nh2 CkX n ^^CF3 (I T Ξ H 1 T / k k\ Ak X. k F N 0 V c A126 k “ o=pj o _.....k° o o o A127 nh2 F n <a 0 1 a128 nh2 ρλχο>γΟ^ο.Νχ) 0 1 N.a. of comp. A Structure 1H NMR A129 \ o o _.....A o o -V o A130 z / O _.....A o o *0 or 1H NMR (500 MHz, DMSO-d6) δ 6.79 (s, 2H) , 4.73 (q, J = 7.0 Hz, 1 H), 2.47 (s, 3H), 2.41 (s, 3H), 1.50 (d, J = 7.0 Hz, 3H). A131 nh2 CI.A / CI X X A^o, F N 0 y N Al Y A132 nh2 AA ci^Aoi AA X ! o _.....A o o K> o A134 A o o ..... o / Z 7=\ ¿ A o A135 nh2 cl A / Ci Al Y Ξ O F ^Ν^Ο^γ° γ^ΟΗ O nh2 A136 \ O o O =¿ m )—z oZ _.....A O O o οίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A137 P o ..... o o o A138 nh2 CI.XOI P P F N 0 γ 0 Nyp A139 nh2 οι,,,Λ P i -P / 0\^A F^ N OWY YÚ 0 V-0 A140 -n — o O ..... o A141 nh2 ci^Cci pp p^o^o F N 0 γ 0 1H NMR (500 MHz, DMSO-d6) δ 7.34-7.27 (m, 5H), 7.05 (s, 2H) , 5.20-5.17 (m, 3H), 1.53 (d, J = 7.0 Hz, 3H). A142 _..... O o o A143 nh2 ci^P / ci P ϊ F^ N OWY 0 A144 - o h° .....Y o o -ú o A145 nh2 Gi^ÁO! pX F^ N OWY 0 CFa οίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A 1H NMR Structure A146 nh2 d,. 1 II o F N OW^ CF3 O A147 nh2 d., A ^^CF3 11 F N OW^ 0 A148 nh2 d^L.d 1I a^o^II F N OW 0 F A149 m — Ií o o ¿V..... ° A o A150 LL o o Io .....ÓE O O o A151 nh2 c|.A / c| II o £í F^N^OAb^ 0 Cl A152 nh2 II A^o^£l F^N^ OW>r 0 A153 nh2 d^A^a 11 F N ΟΎ«)γ ' 0 A154 nh2 d^A^ c| 11 F^ N O W Z 0 Br N.a. of comp. A Structure 1H NMR A155 nh2 Cl AA X X F N OW^ 0 A156 nh2 Cl..^ ,^^Br X 0 CN A158 nh2 CI^A^CI 11 1 o í 1 0 A159 nh2 CkA.CI a^cn XX α,οΧΧΧ F N OWr 0 A160 nh2 ci.,A II o IJ F^N οΑγ 0 A161 nh2 ci^A / ci AA F X nXq A| |^°''X h 0 A162 nh2 Cl-.^ T A = r N X X A. o. J^.A F N θΑγ o A163 p o _.....A o o A o 1H NMR (500 MHz, chloroform-d) δ 7.41 (d, J = 2.0 Hz, 1H), 6.41 (d, J = 3.5 Hz, 1H), 6.36 (dd, J = 3.5, 2.0 Hz, 1H), 5.25 (q, J = 7.0 Hz, 1H), 5.20 5.08 (m, 4H), 1.63 (d, J = 7.0 Hz, 3H). αίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A164 nh2 d.,^ J A A ​​0 A165 nh2 Ck A / d YA ? Y / A / Fz N OW^ ' V 0 A166 nh2 d. i JL A A o. AA F N OW O A167 nh2 ; V H : Q / FzVxo>|j 0 A168 nh2 C| Ava rN Λ Λ Λ Y'N- F N 0W>r 0 A169 nh2 IIaoAI fz n oA| 0 A170 o A° .....át O o A o A171 o 1H NMR (500 MHz, d-chloroform) δ 7.61 - 7.63 (m, 2H), 7.38 - 7.45 (m, 3H), 6.13 (s, 1H), 5.18 (s, 2H), 3.73 (s, 3H). A172 nh2 Cl vY^A1 / Λ A F N 0 A< 0 1H NMR (500 MHz, DMSO-d6) δ 7.04 (s, 2H), 5.00-5.03 (m, 1 H), 3.66 (s, 3H), 1.84- 1.94 (m, 2H), 0.96-1.0 (m, 3H). αίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A173 nh2 οι .Λόι X , 3.72 (s, 3H), 1.51 (d, J = 7.0Hz, 3H). A174 NH2 Br^ XX N 0 γ 0 A175 -n — X# O Q X..... °A ω / A176 NH2 Cl..^ X ·' N owy v / \ 0 A178 NH2 CI XX Λ s / F^N ΟΤηΛΤ y 0 I A179 nh2 OÍ^ / Lo! X A181 nh2 d^A^i X X F^ N OWY 0 οίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A182 -n — o Q ..... ω X A183 nh2 F N 0 γ 0 A184 nh2 Cl·.^ X II? s 1 F^'N ^ 0 A186 nh2 CI. A / XX a^s^IX^ / F N OWY 0 A187 'o °1 ω _..... O O o A188 nh2 CK / L.CI ^llT Ξ ? F° A~~J ρ^Ν^οΥητγ 0 A189 nh2 a. / L-c| XX^s^O F N 0 Y 0 A190 nh2 Cl.^% 1 N.a. of comp. A Structure 1H NMR A191 nh2 X <...cf3 XX F / s-XXX F N OW>< ' 0 A196 w o o ..... °F ω A197 LL ω Xo .....CE O o o A198 LL M <z>Xo 11 Ycc ó O o A199 nh2 d.ÁO1 X X FxSvX^X F^ N O W Z 0 Cl N.a. of comp. A Structure 1H NMR A200 nh2 ci ..Λ X X / ^s^CX F N OW^ CI 0 A201 nh2 ck.J Cl X 0 Br A203 nh2 CI X X F^N^O#^ 0 A204 nh2 α^ΛΌ! 1X f s £ n F N O^R)^ 0 A205 nh2 CI^Á / CI II u £í F^N^HEARb^ l 0 CN A206 nh2 ci^ / Loi XX ^ / SXCX F^ N OW>< 0 A207 nh2 Ci ^A / d ^ .CN X X ^ / S^XX F N OW^ 0 A208 ° ω Xo .....ác O O o N.a. of comp. A Structure 1H NMR A209 nh2 CI..X F X S O A210 ω •fe o o 'Q O A211 nh2 ck 6.32-6.30 (m, 1H), 6.13-6.07 (m, 1H), 5.01 (q, J = 6.5 Hz, 1H), 4.74 (s, 2H), 4.46 (s, 2H), 1.72 (d, J = 6.5Hz, 3H). A212 nh2 BcJ / OH N 0 Π 0 1H NMR (500 MHz, d-chloroform) δ 10.25 (s, 1H), 7.74 (s, 1H), 4.54 (q, J = 7.0 Hz, 1H), 3.50 (s, 2H), 1.72 (d, J = 7.0 Hz, 3H). A213 fe or O or 1H NMR (500 MHz, d-chloroform) δ 5.42 (s, 2H), 4.63 (q, J = 7.0 Hz, 1H), 4.43 (s, 2H), 2.33 (s, 3H), 1.65 (d, J = 7.0Hz, 3H). A214 nh2 ci.. / X 3.38 - 3.12 (m, 3H), 3.04 - 2.95 (m, 1H), 1.61 (d, J = 6.5 Hz, 3H), 1.59 -1.15 (m, 4H), 1.03 (t, J = 7.5 Hz, 3H) . A215 nh2 Cl.,^ 1 / X X ^\ / 0 F^N θΧγ 0 A216 nh2 CL^ X <rnf '< 0 1αίτοηηη / ζζηζ / Ε / γίΛΐ N.a. of comp. A Structure 1H NMR A217 Λ o o । i | o A218 .....ce O O o A219 Λ o o ..... rx° A220 nh2 CkÁ.CI ΎΎ N OÍñW 0 0 A221 nh2 Ck X X _..... / O or UU or QbQnnn / zznz / B / YiAi The preparation method of active ingredient A comprises the following steps. A compound of formula III is reacted with a compound of formula II to obtain a compound of formula 1-1-1; The reaction scheme is as follows: Qfronnn / zznz / E / YiAi wherein, W represents hydrogen or an alkali metal, preferably K, Na; Hal represents halogen, preferably Br, Cl; The reaction is carried out in the presence of a catalyst and a solvent. Preferably, the catalyst is TBAB, and the solvent is one or more selected from the group consisting of DCM, DCE, ACN, THF, DMF. The compound of formula 1-1-1 is reacted in the presence of an aqueous solution g of lithium hydroxide and a solvent to obtain a compound of formula I; The reaction scheme is as follows: And And O O 1-1-1 i preferably, the solvent is one or more selected from the group consisting of methanol, ethanol and isopropanol. The compound of formula I is reacted with M-SH to obtain a compound of formula 1-1-2; The reaction scheme is as follows: wherein, the reaction is carried out in the presence of a dehydrant and a solvent, preferably the dehydrant is DCC, and the solvent is one or more selected from the group consisting of dichloromethane, dichloroethane, acetonitrile, Ν,Ν-dimethylformamide , Ν,Ν-dimethylacetamide, dimethyl sulfoxide, tetrahydrofuran, toluene, xylene; or, when Y represents NR1R2 (R1, R2 are not hydrogen at the same time), it is obtained by reacting a compound of formula I-2 Or i -2 a compound of formula 1-1-3 1-1-3 with a corresponding halide; wherein, the halide is, preferably, chloride or bromide; The reaction is carried out in the presence of a base and a solvent, wherein the base is one or more selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate and carbonate of cesium; the solvent is one or more selected from the group consisting of THF, 1,4-dioxane, toluene, 1,2-dichloroethane, ethyl acetate, acetonitrile, 13 DMF, acetone, dichloromethane and chloroform; optionally a catalyst, preferably DMAP, is added during the reaction. The salt is an agrochemically acceptable salt, which is preferably prepared by reacting the R-pyridyloxycarboxylic acid compound of the present invention with a chemically acceptable basic compound. The above-mentioned agrochemically acceptable salt can be easily separated and purified through conventional separation methods such as solvent extraction, dilution, recrystallization, column chromatography and preparative thin layer chromatography. In some embodiments, the weight ratio between active ingredient A and active ingredient B is 1:100 ~ 100:1 or 1:50 ~ 50:1, preferably 1:30 ~ 30:1 or 1 :20 ~ 20:1, 23 most preferably 1:10 ~ 10:1 or 1:8 ~ 8:1, most preferably also 1:5 ~ 5:1 or 1:1 ~ 2:1 or 1:1 ~ 1:2. In some embodiments, active ingredients A and B together represent between 1% and 95%, preferably between 10% and 80% of the total weight of the herbicidal composition. The herbicidal composition may comprise a conventional adjuvant; The conventional adjuvant comprises, for example, a carrier and / or a surfactant. The term carrier in this document refers to an organic or inorganic substance, natural or synthetic, that facilitates the application of the active ingredients. In general, the carrier is inert and must be agriculturally acceptable, especially acceptable for a plant to be treated. The carrier may be a solid, such as clay, a natural or synthetic silicate, silica, a resin, a wax, a solid fertilizer, etc. or, a liquid such as water, an alcohol, a ketone, a petroleum fraction, an aromatic or paraffinic hydrocarbon, a chlorohydrocarbon, liquefied gas, etc. The surfactant, which may be ionic or nonionic, may include an emulsifier, a dispersant or a wetting agent. Among the examples that can be mentioned are 3? a salt of polyacrylic acid, a salt of lignosulfonic acid, a salt of phenolsulfonic acid or naphthalenesulfonic acid, a polymer of ethylene oxide with an aliphatic alcohol or with an aliphatic acid or with an aliphatic amine or with substituted phenol (in particular, an alkylphenol or an arylphenol), a sulfosuccinate, a taurine derivative (especially an alkyl taurate) and a phosphoric ester of an alcohol or a polyhydroxyethylated phenol, an alkyl sulfonate, an alkylaryl sulfonate, an alkyl sulfate, a sulfate of lauryl ether, a fatty alcohol sulfate, a sulfated hexadecanol, heptadecanol and octadecanol and a sulfated fatty alcohol polyglycol ether, and also includes a condensate of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethylene octylphenyl ether, ethoxylated isooctylphenol, octylphenol or nonylphenol, an alkylphenyl ether of polyethylene glycol, a tributylphenyl ether of polyethylene glycol, a triesterail ether of polyethylene glycol, an alkylaryl polyether alcohol, a condensate of alcohol and fatty alcohol / ethylene oxide, ethoxylated castor oil, a polyoxyethylene ether alkyl, an ethoxylated polyoxypropylene, a polyglycol lauryl alcohol acetal ether, a sorbitol ester, a lignin sulfite waste liquid, a protein, a denatured protein, a polysaccharide (e.g., methylcellulose), a modified hydrophobic starch, a polyvinyl alcohol, a polycarboxylate, a polyalkoxylate, a polyvinylamine, a polyvinylpyrrolidone and a copolymer thereof. At least one surfactant may be required to facilitate dispersion of the active ingredient in water and its proper application to a plant. The composition may also comprise various other components, such as a protective colloid, an adhesive, a thickener, a thixotropic agent, a penetrant, a stabilizer, a chelating agent, a dye, a colorant or a polymer. Furthermore, the composition that can be combined with the active compounds are, for example, known active compounds, as described, for example, in the publication World Herbicide New Product Technology Handbook, China Agricultural Science and Farming Techniques Press, 2010.9 and in the bibliography cited therein. For example, the following active compounds may be cited as herbicides (Note: Compounds are referred to either by their common name according to the International Organization for Standardization (ISO) or by chemical names, if applicable, along with a number. usual code): acetochlor, butachlor, alachlor, propisochlor, metolachlor, s-metolachlor, pretilachlor, propachlor, etachlor, napropamide, napropamide R-left handed, propanil, mefenacet, difenamid, diflufenican, etaproclor, beflubutamid, bromobutide, dimetenamid, dimetenamid -P, ethobenzanid, flufenacet, tenylchlor, metazachlor, isoxaben, flamprop-M-methyl, flamprop-M-propyl, allidochlor, petoxamide, chloranocril, ciprazine, mefluidide, monalide, delachlor, prinachlor, terbuchlor, xylchlor, dimetachlor, cisanilide, trimexachlor , clomeprop, propyzamide, pentanochlor, carbetamide, benzoylprop-ethyl, ciprazole, butenaclor, tebutam, benzipram, mogrton, diclofluanid, naproanilide, diethyl-ethyl, naptalam, flufenacet, benzadox, chlortiamid, chlorophthalimide, socarbamide, picolinafen, atrazine, simazine, promethrin, cyanathrin, simetrin, ametrin, propazine, dipropetrin, SSH-108, terbutrin, terbutylazine, triaziflam, ciprazine, proglinazine, trietazine, αποηηη / 77η7 / Β / γΐΛΐ prometon, simetone, aziprothrin, desmethrin, dimetamethrin, procyazine, mesop razine, sebutylazine , Secbumeton, terbumeton, metoprotrine, cyanatrin, iPazine, chlorzine, atraton, pendimetallin, eglinazine, cyanuric acid, inaziflam, chlorsulfuron, metsulfuron-methyl, methyl binsulfuron, chlorimuron-ethyl, tribenuron-methyl, tifensulfuron-methyl, pyrazosulfuron Ilo, mesosulfuron , iodosulfuron-methyl sodium, foramsulfuron, cinosulfuron, triasulfuron, sulfometuron methyl, nicosulfuron, etametsulfuron-methyl, amidosulfuron, ethoxysulfuron, cyclosulfamuron, rimsulfuron, azimsulfuron, flazasulfuron, monosulfuron, monosulfuron ester, flucarbazone sodium, flu pirsulfuron-methyl, halosulfuron-methyl, oxasulfuron, imazosulfuron, primisulfuron, propoxycarbazone, prosulfuron, sulfosulfuron, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron, metsulfuron methyl sodium, flucetosulfuron, HNPC-C, orthosulfamuron, propyrisulfuron, metazosulfuron, acifluorfen, fomesafen, lactofen, fluoroglycofen, oxyfluorfen, chlornitrofen, aclonifen, ethoxyfen-ethyl, bifenox, nitrofluorfen, clomethoxyfen, fluorodifen, fluoronitrofen, furiloxifen, nitrofen, TOPE, DMNP, PPG1013, AKH-7088, halosafen, chlortoluron, isoproturon, linuron, diuron, dimron, fluometuron, benzthiazuron, metabenzthiazuron, cumiluron, etidimuron, isouron, tebutiuron, buturon, chlorbromuron, methyldimron, fenobenzuron, SK-85, methobromuron, metoxuron, afesin, monuron, siduron, fenuron, fluotiuron, neburon, cloroxuron, noruron, isonoruron, 3-cyclooctyl-1, thiazfluron, tebutiuron, difenoxuron, parafluron, tribunyl methylamine, karbutylate, trimeturon, dimefuron, monisouron, anisuron, methiuron, cloreturon, tetrafluron, fenmedifam, fenmedifam-ethyl, desmedifam, asulam, terbucarb, barban, profam, chlorprofam, rowmate, swep, chlorbufam, carboxazol, chlorprocarb, fenasulam 2,4 -D butyl ester, MCPA-Na, 2,4-D isooctyl ester, MCPA isooctyl ester, 2,4-D sodium salt, 2,4-D dimethylamine salt, MCPA-thioethyl, MCPA, 2,4-acid D propionic, high 2,4-D propionic acid, 2,4-D butyric acid, MCPA propionic acid, MCPA propionic acid salt, MCPA butyric acid, 2,4,5-D, 2,4,5-D acid propionic, 2,4,5-D butyric acid, MCPA amine salt, dicamba, erbon, chlorfenac, saison, TBA, chloramben, methoxy-TBA, diclofop-methyl, fluazifop-butyl, fluazifop-p-butyl, haloxyfop-methyl , haloxyfop-P, quizalofop-ethyl, quizalofop-p-ethyl, fenoxaprop-ethyl, fenoxaprop-p-ethyl, propaquizafop, cyhalofop-butyl, metamifop, clodinafop-propargyl, fenthiaprop-ethyl, chloroazifop-propynyl, poppenate-methyl, triphopsime , isoxapyrifop, paraquat, diquat, oryzalin, etalfluralin, isopropalin, nitralin,profluralin, prodinamine, benfluralin, fluchloralin, dinitramine, dipropalin, chlornidine, metalpropalin, dinoprop, glyphosate, anilophos, glufosinate ammonium, amiprofos-methyl, sulfosate, piperophos, bialaphos sodium, bensulide, butamiphos, focarb, 2,4-DEP, H- 9201, zitron, imazapyr, imazetapyr, imazaquin, imazamox, imazamox ammonium salt, imazapic, imazametabenz-methyl, fluroxypyr, fluroxypyr isooctyl ester, clopyralid, picloram, triclopyr, dithiopyr, haloxidine, 3,5,6-trichloro-2- prídinol, thiazopyr, fluridone, aminopyralid, diflufenzopyr, triclopyr-butotil, cliodinate, setoxydim, clethodim, cycloxidim, alloxidim, clefoxidim, butroxidim, tralkoxidim, tepraloxidim, QbQnnn / 7znz / B / YiAi butidazole, metribuzin, hexazinone, metamitron, etiozin, ametridione, amibuzin, bromoxynil, bromoxynil octanoate, ioxynyl octanoate, ioxynil, diclobenyl, dipenatril, pyraclonil, chloroxynil, iodobonil, flumetsulam, florasulam, penoxsulam, metosulam , chloransulam -methyl, diclosulam, piroxsulam, benfuresate, bispyribac sodium, piribenzoxim, pyriftalid, piriminobac-methyl, pyrithiobac sodium, benzobicilon, mesotrione, sulcotrione, tembotrione, tefuryltrione, bicyclopyrone, ketodpyradox, isoxaflutol, clomazone, phenoxasulfone, methio zolin, fluazolate, piraflufen-ethyl , pyrazolinate, difenzoquat, pyrazoxifen, benzofenap, nipiraclofen, pirasulfotol, topramezone, pyroxasulfone, cafenstrol, flupoxam, aminotriazole, amicarbazone, azafenidin, carfentrazone-ethyl, sulfentrazone, bencarbazone, benzphendizone, butafenacil, bromacil, isocil, lenacil, terbacil, flupropacil, cinidon -ethyl, flumiclorac-pentyl, flumioxazin, propyzamide, MK-129, flumezin, pentachlorophenol, dinoseb, dinoterb, dinoterb acetate, dinosam, DNOC, chloronitrofen, medinoterb acetate, dinofenate, oxadiargil, oxadiazon, pentoxazone, Flufenacet, fluthiacet-methyl, fentrazamide , flufenpyr-ethyl, pyrazon, brompirazon, metflurazon, kusakira, dimidazon, oxapyrazon, norflurazon, pyridafol, quinclorac, quinmerac, bentazone, pyridate, oxaziclomefona, benazolin, clomazone, cinmethylin, ZJ0702, pyribambenz-propyl, indanophan, sodium chlorate, dalapon , trichloroacetic acid, monochloroacetic acid, hexachloroacetone, flupropanate, ciperquat, bromofenoxim, epronaz, metazole, flurtamone, benfuresate, etofumesate, thioclorim, chlortal, fluorochloridone, tavron, acrolein, bentranil, tridiphane, chlorfenpropmethyl, tidiarizonaimin, phenisopham, busoxinone, methoxyfenone, saflufenacil , claciphos, chloropon, alorac, dietmquat, etnipromid, iprimidam, ipfencarbazone, thiencarbazone-methyl, pirimisulfan, chlorflurazole, tripropindan, sulglicapin, prosulfalin, cambendichlor, aminocyclopyrachlor, rodetanil, benoxacor, fenclorim, flurazole, fenchlorazol-ethyl, cloquintocet-mexyl, or xabetrinil , MG / 91, cyometrinil, DKA-24, mefenpyr-diethyl, furilazol, fluxofenim, isoxadifen-ethyl, dichlormid, halauxifen-methyl, DOW florpirauxifen, UBH-509, D489, LS 82-556, KPP-300, NC-324 , NC-330, KH-218, DPX-N8189, SC-0744, DOWCO535, DK-8910, V-53482, PP-600, MBH-001, KIH-9201, ET-751, KIH-6127 and KIH-2023 . The herbicidal composition may further comprise one or more protectants, which is one or more compounds selected from, a) Compounds of the dichlorophenylpyrazoline-3-carboxylic acid type (S1), preferably compounds such as ethyl l-(2,4-dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazoline-3carboxylate (SI- 1, mefenpyr-diethyl, PM, pp. 594-595), and related compounds as described, for example, in WO 91 / 07874 and PM (pp. 594-595). b) Derivatives of dichlorophenylpyrazolecarboxylic acid, preferably compounds such as ethyl 1-(2,4-dichlorophenyl)-5-methylpyrazole-3-carboxylate (S1-2), 1-(2,4- ethyl dichlorophenyl)-5-isopropylpyrazole-3-carboxylate (SI-3), ethyl l-(2,4-dichlorophenyl)-5-(l, l-dimethyl-ethyl)pyrazole-3-carboxylate (S1-4 ), ethyl 1-(2,4-dichlorophenyl)-5-phenylprazole-3-carboxylate (S1-5) and related compounds as described in EP-A-333 131 and EP -A-269 QbQnnn / zznz / B / YiAi 806. c) Compounds of the triazolecarboxylic acid type (S1), preferably compounds such as fenchlorazole, i.e. 1-(2,4-dichlorophenyl)-5-trichloromethyl-(1H)-1,2,4-triazole-3-carboxylate ethyl (S1-6) and related compounds (see documents EP-A-174 562 and EP-A-346 620). d) Compounds of the 5-benzyl or 5-phenyl-2-isoxazolin-3-carboxylic acid type or the 5,5-diphenyl-2-soxazoline-3-carboxylic acid type, preferably compounds such as ethyl 5-(2,4-dichlorobenzyl)-2-isoxazoline-3-carboxylate (SI-7) or ethyl 5-fenll-2-isoxazoline-3-carboxylate (SI-8) and related compounds such as described in WO 91 / 08202, or ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate (SI-9, isoxadifen-ethyl) or 5,5-diphenyl-2 -n-propyl isoxazoline-3-carboxylate (SI-10) or ethyl 5-(4-fluorophenyl)-5-phenyl-2isoxazoline-3-carboxylate (SI-11), as described in the patent application (WO-A-95 / 07897). e) Compounds of the 8-quinoline oxyacetic acid type (S2), preferably (5-chloro-8-quinolinoxy¡) 1-methylhex-1-yl acetate (S2-1, cloquintocet-mexyl, e.g. PM (pp. 195-196), (1,3-dimethylbutyl-yl) (5-chloro-8-quinolinoxy¡)acetate (S2-2), 4-allyloxybutyl (5-chloro-8-quinolinoxy¡)acetate (S2-3), 1-allyloxyprop-2-yl (5-chloro-8-quinolinoxy¡)acetate (S2-4), ethyl (5-chloro-8-quinolinoxy)acetate (S2-5), ( methyl 5-chloro-8-quinolinoxy)acetate (S2-6), methyl (5-chloro-8-quinolinoxy)acetate (S2-7), 2-(2-chloro-8-quinolinoxy)acetate -propylideneiminooxy¡)-1-ethyl (S2-8), 2-oxoprop-1-yl (5-chloro-8-quinolinoxy)acetate (S2-9) and related compounds as described in EP-A documents -86750, EP-A-94349 and EP-A-191736 or EP-A-0492366. f) Compounds of the (5-chloro-8-quinolinoxy¡)malonic acid type, preferably compounds such as diethyl (5-chloro-8-quinolinoxy) malonate, (5-chloro-8-quinolinoxy¡) diallyl malonate , methyl ethyl (5-chloro-8-quinolinoxy)-malonate and related compounds such as described in EP-A-0582 198. g) Active compounds of phenoxyacetic acids, phenoxypropionic acids or aromatic carboxylic acids, such as, for example, 2,4-dichlorophenoxyacetic acid (and esters) (2,4-D), 4-chloro-2-methylphenoxyprop esters onics (mecoprop), MCPA or 3,6-dichloro-2-methoxybenzo¡ic acid (and esters) (dicamba). h) Active compounds of the pyrimidine type, such as, for example, fenchlorim (PM, pp. 386-387) (= 4,6-dichloro-2-phenylpyrimidine). i) Active compounds of the dichloroacetamide type, which are frequently used as pre-emergence protectants (protectants that act on the soil), such as, for example, dichloromide (PM, pp. 270-271) (= N, N-diallyl- 2,2-dichloroacetamide), AR-29148 (= 3-dlchloroacetyl-2,2,5-trimethyl-l, 3-oxazolidone from Stauffer), benoxacor (PM, pp. 74-75) (= 4 -dichloroacetyl-3,4-dihydro-3-methyl-2H-l, 4-benzoxazine), APPG-1292 (= N-allyl-N [(I, 3-dioxolan-2-yl) QbQnnn / zznz / B / YiAi -methyl] dichloroacetamide from PPG Industries), ADK-24 (= N-allyl-N - [(allylaminocarbonyl) -methyl] -dichloroacetamide from Sagro-Chem), AAD-67 or AMON 4660 (= 3-dichloroaceryl-l -oxa -3-aza-spiro[4,5]decane from Nirrokemia or Monsanto), diclonon or ABAS145138 or ALAB145138 (= (= 3-dichloroacetyl -2,5,5-trimethyl-l, 3-diazabicyclo[4.3.0]nonane from BASF) and furilazole or AMON 13900 (see PM, 482-483) (= (RS) -3-dichloroacetyl-5- (2-furyl) -2,2- dimethyloxazolidone). j) Active compounds of the type of dichloroacetone derivatives, such as, for example, AMG 191 (CAS N.a: 96420-72-3) (= 2-dichloromethyl-2-methyl-1,3-dioxolane from Nitrokemia). k) Active compounds of the type of oxyimino compounds that are known as seed coating materials such as, for example, oxabetrinyl (PM, p. 689) (= (Z) -I, 3-dioxolan-2-ylmethoxyimino (phenyl ) (acetonitrile), which is known as a protectant in seed treatment to prevent damage by metolachlor, fluxofenim (PM, pp. 467-468) (= I(4-chlorophenyl) -2,2,2-trifluoro-l -ethanone O-(1,3-dioxolan -2-ylmethyl)-oxime, which is known as a protectant in seed coating to prevent metolachlor damage, and cyometrinil or A-CGA-43089 (PM, p. 983) (= (Z)-cyanomethoxyimino (phenyl)acetonitrile), which is known as a protectant in seed coating to prevent metolachlor damage. 1) Active compounds of the thiazolecarboxylic ester type, which are known as seed coating materials, such as, for example, flurazole (PM, pp. 450-451) (= benzyl 2-chloro-4-trifluoromethyl-l, 3-thiazole-5-carboxylate), which is known as a protector in seed coating to prevent damage by alachlor and metolachlor. m) Active compounds of the type of naphthalenedicarboxylic acid derivatives that are known as seed coating agents, such as, for example, naphthalic anhydride (PM, pp. 1009-1010) (= 1,8-naphthalenedicarboxylic anhydride), which is Known as a seed coat protectant for corn to prevent damage from thiocarbamate herbicides. n) Active compounds of the type of chroman acetic acid derivatives, such as, for example, ACL 304415 (CAS N.s: 31541-57-8) American Cyanamid (= 2-84-carboxychroman-4-yl) acetic acid). o) Active compounds that, in addition to a herbicidal action against harmful plants, also have a safer action on crop plants, such as dimepiperate or AMY-93 (PM, pp. 302-303) ( = Sl-methyl- 1-phenylethylpiperidine-1-carbothioate), daimuron or ASK 23 (PM, p. 247) (= 1-(1-methyl-1-phenylethyl)-3-p-tolylurea), cumyluron = AJC-940 (= 3- (2-chlorophenyl methyl) -I- (1-methyl- 1-phenyl-ethyl) urea, see JP-A- 60087254), methoxyphenon or ANK 049 (= 3,3'-dimethyl-4-methoxy -benzophenone), CSB (= l-bromo-4(chloromethylsulfonyl)benzene) (CAS N.s: 54091-06-4 from Kumiai). In a preferred embodiment, the protectant is one or more compounds selected from, for example, isoxadifen-ethyl (CAS N.a: 163520-33-0), cyprosulfamide (CAS N.a: Qfronnn / zznz / E / YiAi 221667-31-8), mefenpyr-diethyl (CAS N.s: 135590-91-9), cloquintocet-mexyl (CAS N.s: 99607-70-2), gibberellic acid (CAS N.2: 77-06-5), furilazole (CAS N.2: 121776-33- 8), metcamifen (CAS N.2: 129531-12-0). In the context of the present specification, if an abbreviation of a generic name of an active compound is used, this includes in each case all customary derivatives, such as esters and salts, as well as isomers, in particular optical isomers, in particular a or more commercially available forms. If the generic name denotes an ester or a salt, it also includes in each case all other conventional derivatives, such as other esters and salts, free acids and neutral compounds, as well as isomers, in particular optical isomers, in particular one or more forms commercially available. The chemical name given to a compound means at least one compound included in the generic name, and generally, the preferred compound. In the case of sulfonamides such as sulfonylurea, salts also include salts formed by the exchange of cations with hydrogen atoms in the sulfonamide group. For example, 2-methyl-4-chloro derivatives include, but are not limited to: 2-methyl-4-chloro sodium salt, potassium salt, dimethylammonium salt, isopropylamine salt, etc., as well as -methyl-4-chloro methyl ester, -ethyl ester, -isooctyl ester, -thioethyl, etc.; 2,4-D derivatives include, but are not limited to: 2,4-D salt such as sodium salt, potassium salt, dimethylammonium salt, triethanolammonium salt, isopropylamine salt, choline, etc., and 2,4-esters -D such as methyl ester, ethyl ester, butyl ester, isooctyl ester, etc. In the context of the present invention, the salts of the compounds are preferably in the form of respective alkali metal salts, alkaline earth metal salts or ammonium salts, preferably in the form of respective alkali metal salts, more preferably in the form of respective sodium or potassium salts, more preferably in the form of the respective sodium salt. The composition of the present invention can be diluted before use or used directly by users. The composition can be prepared through a conventional processing method, that is, the active ingredient(s) are mixed with a liquid solvent or a solid carrier, and then, one or more of the surfactants is added as a dispersant, a stabilizer , a wetting agent, an adhesive is added, or a defoaming agent, etc. The herbicidal composition may be in the form of a formulation selected from: a dispersed oil suspension, an aqueous suspension, a suspension, a wettable powder, an emulsified concentrate, a granule dispersed in water (a dry suspension), an aqueous emulsion. and a microemulsion. In summary, the composition of the present invention can be mixed with solid and liquid additives conventionally used in prior art formulations. As external conditions change, the amount of active ingredients used also differs. External conditions are, for example, temperature, humidity, the nature of the herbicide Qfronnn / zznz / E / YiAi used, etc. It can have a wide range of variation, for example between 0.001 and 1.0 kg / ha, or more active substances, but preferably between 0.005 and 750 g / ha, especially between 0.005 and 500 g / ha. Furthermore, the composition according to the invention can be sprayed on a leaf of a plant to be treated, that is to say that the composition of the invention can be applied to a weed, especially to weeds, and in particular to a surface of the weed from where the weed invades or is likely to invade crops. Furthermore, the present invention also provides the use of the herbicidal composition to control weeds; and provides a method of controlling unwanted plant growth, comprising applying the herbicidal composition to plants, plant parts, plant seeds or plant growing areas; Preferably, the herbicidal composition is used to selectively control a weed in a useful crop; Most preferably, the useful crop is a genetically modified crop or a crop treated by gene editing technology. The compounds of the invention are useful in the treatment of the whole plant and parts of a plant. Plant varieties and cultivars can be obtained by conventional methods of propagation and reproduction or by genetic engineering methods. Genetically modified plants (transgenic plants) are those in which a heterologous gene (transgene) has been stably integrated into the plant genome. A transgene that is defined by its particular location in the plant genome is called a transformation or transgenic event. Genetically modified plant cultivars that can be treated according to the invention include those that are resistant to one or more biotic stresses (pests such as nematodes, insects, mites, fungi, etc.) or abiotic stresses (drought, low temperatures, soil salinity, etc.), or that contain other desirable characteristics. Plants can be genetically modified to exhibit traits of, for example, herbicide tolerance, insect resistance, modified oil profiles or drought tolerance. Useful genetically modified plants containing single gene transformation events or combinations of transformation events are listed in Table 1. Additional information for the genetic modifications listed in Table 1 can be obtained from publicly available update databases. regulations, for example, those published by the US Department of Agriculture. The following abbreviations, T1 to T37, are used in Table 1 or in the traits. A dash (-) means the entry is not available. αποηηη / 77η7 / Β / γΐΛΐ Trait Description Trait Description Trait Description T1 Tolerance to glyphosate T15 Tolerance to cold T27 High in tryptophan T2 Oil with high content of lauric acid T16 Tolerance to herbicide imidazolinone T28 Semi-dwarf with erect leaves T3 Tolerance to glufosinate T17 Modified alpha-amylase T29 Semi-dwarf T4 Phytate degradation T18 Pollination control T30 Low iron tolerance T5 Oxylene tolerance T19 2,4-D tolerance T3I Fatty acid / modified oil T6 Disease resistance T20 Increased lysine T32 HPPD tolerance T7 Insect resistance T21 Drought tolerance T33 High oleosol content T9 Modified flower color T22 Senescence / delayed maturation T34 Tolerance to aryloxyalkanoate T11 Tolerance to herbicide ALS T23 Modified product quality T35 Tolerance to mesotrione T12 Tolerance to dicamba T24 High amount of cellulose T36 Reduced nicotine content T13 Anti-allergy T25 Carboxylate / modified starch T37 Modified product T14 Salt tolerance T26 Insect and disease resistance Table 1 shows genetically modified plants. Qfronnn / zznz / E / YiAi Crop Event name Event code Trait(s) Gene(s) Alfalfa J101 MON-00101-K T1 cp4 epsps (aroA:CP4) Alfalfa J163 MON-OO163-7 T1 cp4 epsps (aroA:CP4) Brassica napus 23-18 -17 (Event 18) CGN-89465-2 T2 Te Brassica napus 23-198 (Event 23) CGN-89465-2 T2 Te Brassica napus 61061 DP-O61061-7 T1 gat4621 Brassica napus 73496 DP-O73496-4 T1 gat4621 Brassica napus GT200 (RT200) MON-89249-2 T1 cp4 epsps (aroA:CP4); goxv247 Brassica napus GT73 (RT73) MON-OOO73-7 T1 cp4 epsps (aroA:CP4); goxv247 Brassica napus HCN10 (Topas 19 / 2) - T3 Bar Brassica napus HCN28 (T45) ACS-BNOO8-2 T3 pat (syn) Brassica napus HCN92 (Topas 19 / 2) ACS-BNOO7-1 T3 Bar Brassica napus MONX8302 MON- 883O2-9 T1 cp4 epsps (aroA:CP4) Brassica napus MPS961 - T4 phyA Brassica napus MPS962 - T4 phyA Brassica napus MPS963 - T4 phyA Brassica napus MPS964 - T4 phyA Brassica napus MPS965 - T4 phyA οίτοηηη / ζζηζ / Ε / γίΛΐ Brassica napus MSI (B91-4) ACS-BNOO4-7 T3 Bar Brassica napus MS8 ACS-BNOO5-8 T3 Bar Brassica napus OXY-235 ACS-BNO11-5 T5 Bxn Brassica napus PHY14 - T3 Bar Brassica napus PHY23 - T3 Bar Brassica napus PHY35 - T3 Bar Brassica napus PHY36 - T3 Bar Brassica napus RF1 (B93-101) ACS-BNOO1-4 T3 Bar Brassica napus RF2 (B94-2) ACS-BNOO2-5 T3 Bar Brassica napus RF3 ACS-BNOO3-6 T3 Bar Beans EMBRAPA5.1 EMB-PV051-1 T6 acl (sense and antisense) Eggplant EE-1 T7 cry lAc Cotton 19-51 a DD-O1951A-7 T11 S4-HrA Cotton 281-24-236 DAS-24236-5 T3 , T7 pat (syn); erylF Cotton 3006-210-23 DAS-21023-5 T3, T7 pat (syn): cry lAc Cotton 31707 - T5, T7 bxn; crylAc Cotton 31803 - T5, T7 bxn; crylAc Cotton 31807 - T5, T7 bxn; crylAc Cotton 31808 - T5, T7 bxn; crylAc Cotton 42317 - T5, T7 bxn; crylAc Cotton BNLA-601 - T7 crylAc Cotton BX N10211 BXN10211-9 T5 bxn; crylAc Cotton BXN 10215 BXN10215-4 T5 bxn; crylAc Cotton BXN10222 BXN10222-2 T5 bxn; crylAc αίτοηηη / ζζηζ / Ε / γίΛΐ Cotton BXN10224 BXN10224-4 T5 bxn; crylAc Cotton COT102 SYN-1R102-7 T7 vtp3A(a) Cotton COT67B SYN-1R67B-1 T7 crylAb Cotton COT202 - T7 vip3A Cotton Event 1 - T7 crylAc Cotton GMFCrylA GTL-GMF3II-7 T7 crytAb-Ac Cotton GHB119 BCS-GH005- 8 T7 Cry2AE Cotton GHB614 BCS-GH002-5 T1 2MEPSPS GK12-T7 CRY1 AB-AC Cotton llcotton25 ACS-GH001-3 T3 T3 BAR Cotton MLS 9124-T7 Crylc cotton mon1076 MON-89924-2 T7 CRYLAC Cotton Mon1445 MON1445 MON-01445- 2 T1 cp4 epsps (aroA:CP2) Cotton MON15985 MON-15985-7 T7 cry lAc; cry2Ab2 Cotton MON1695 MON-89383-1 T7 ep4 epsps (aroA:CP4) Cotton MON531 MON-00531-6 T7 cry lAc Cotton MON757 MON-W757-7 T7 cry lAc Cotton MON88913 MON-88913-8 T1 cp4 epsps (aroA:CP4 ) Cotton Nqwe Chi 6 Bt - T7 - ​​Cotton SKG321 - T7 crylA; CpTI Cotton T303-3 BCS-GH003-6 T3, T7 CrylAb; bar Cotton T304-40 BCS-GH004-7 T3, T7 crylAb; bar Cotton CE43-67B - T7 crylAb Cotton CE46-02A - T7 crylAb Cotton CE44-69D - T7 crylAb Cotton U43-14A - T7 crylAb Cotton 1143-51B - T7 crylAb Cotton T342-142 - T7 crylAb Cotton PV-GHGT07(1445) - T1 cp4 epsps (aroA:CP4) Cotton EE-GH3 - T1 Mepsps Cotton EE-GH5 - T7 CrylAb Cotton MGN88701 MON-88701-3 T3, T12 modified dmo; bar Cotton OsCr11 - T13 Cryj modified Linen FPP67 CDC-FL001-2 T11 Ais αίτοηηη / ζζηζ / Ε / γίΛΐ Lentils RH44 - T16 Ais Corn 3272 SYN-E3272-5 T17 amy 797 E Corn 5307 SYN-05307-1 T7 eciy3.1 Ab Corn 59122 DAS-59122-7 T3, T7 cry34Ab1; cry35Ab1; pat Corn 676 PH-000676-7 T3, T18 pat; dam Corn 678 PH-000678-9 T3, T18 put; dam Corn 680 PH-000680-2 T3, T18 pat; dam Corn 98140 DP-098140-6 T1, T11 gat4621; zm-hra Corn Bt10 - T3, T7 Cry1 Ab; pat Corn Ht176(176) SYN-EV176-9 T3, T7 CrylAb; bar Maize BVLA430101 - T4 phyA2 Maize CBH-351 ACS-ZM004-3 T3, T7 cry9C; bar Corn DAS40278-9 DAS40278-9 T19 aad-1 Corn DBT418 DKB-89614-9 T3, T7 Cry1 Ac; pin11; bar Corn DLL25(B16) DKB-89790-5 T3 bar Corn GA21 MON-00021 -9 T1 mepsps Corn GG25 - T1 mepsps Corn GJ11 - T1 mepsps Corn FH17 - T1 mepsps Corn GAT-ZM1 - T3 pat Corn LY038 REN-00038- 3 T20 cordapA Corn MIR182 SYN-IR162-4 T7 vip3Aa20 Corn MIR604 SYN-IR604-5 T7 Mery3A Corn MON801 (MON80100) MON801 T1, T7 cry1 Ab; cp4 cpsps (aroA:CP4); goxv247 Corn MON802 MON-80200-7 T1,T7 Cry1 Ab; cp4 cpsps (aroA:CP4); goxv247 Corn MON809 PH-MON-809-2 T1, T7 cry1 Ab; cp4 cpsps (aroA:CP4); goxv247 Corn MON810 MON-00810-6 T1, T7 cry1 Ab; cp4 cpsps (amA:CP4); goxv247 Corn MON832 - T1 Cp4 cpsps (aroA:CP4); goxv247 Corn MON863 MON-00863-5 T7 cry3Bb1 Corn MON87427 MON-87427-7 T1 cp4 cpsps (aroA:CP4) οίτοηηη / ζζηζ / Ε / γίΛΐ Corn MON87460 MON-87460-4 T21 espB Corn MON88017 MON-88017-3 T1, T7 cry3Bbl; cp4 cpsps (aroA:CP4) Maize MON89034 MON-89034-3 T7 cry 2Ab2; cry1 A.105 Maize MS3 ACS-ZM001-9 T3, T18 bar; barnase Corn MS6 ACS-ZM005-4 T3, T18 bar; barnase Corn NK603 MON-00603-6 T1 cp4 cpsps (aroA:CP4) Corn T14 ACS-ZM002-1 T3 pat (syn) Corn T25 ACS-ZM003-2 T3 pat (syn) Corn TC1507 DAS-01507-1 T3, T7 cry1 Fa2; pat Corn TC6275 DAS-06275-8 T3, T7 mocry 1F: bar Corn VIP1034 - T3, T7 vip3A; pat Corn 43A47 DP-043A47-3 T3, T7 Cry1 F;cry34Ab1; cxy35Ab1; pat Corn 40416 DP-040416-8 T3, T7 cry1 F; cry 34 Ab1; cry35Ab1; pat Corn 32316 DP-032316-8 T3, T7 cry1 F; cry 34 Ab1; cry35Ab1; pat Corn 4114 DP-004114-3 T3, T7 cry1 F; cry 34 Ab1; cry35Ab1; pat Melon Melon A - T22 sam-k Melon Melon B - T22 Sam-k Papaya 55-1 CUH-CP551-8 T6 prsv cp Papaya 63-1 CUH-CP631-7 T6 prsv cp Papaya Huanong N.s 1 - T6 prsv rep Papaya X17-2 UFL-X17CP-6 T6 PRSV CP CIRTURE C-5 Ars-PLMC5-6 T6 PPV CP Brassica Rapa ZSR500-T1 CP4 CPSPS (Aroa: CP4); goxv247 Brassica rapa ZSR502 - T1 cp4 cpsps (aroA:CP4); goxv247 Brassica rapa ZSR503 - T1 cp4 cpsps (aroA:CP4); goxv247 Rice 7Crp#242-95-7 - T13 7crp Rice 7Crp#10 - T13 7crp οίτοηηη / ζζηζ / Ε / γίΛΐ Rice CÍM Shanyou 63 - T7 CrylAb; cry1 Ac Rice Huahui-1 / TT51-1 - T7 CrylAb; cry1 Ac Rice LLRICE06 ACS-OS001-4 T3 Bar Rice LLRICE601 BCS-OS003-7 T3 Bar Rice LLRICE62 ACS-OS002-5 T3 Bar Rice Tarom molaii + cry1 Ab - T7 cry 1 Ab (truncated) Rice GAT-OS2 - T3 Bar Rice GAT-OS3 - T3 Bar Rice PE-7 - T7 Cry1 Ac Rice 7Crp#10 - T13 7crp Rice KPD627-8 - T27 OASA1D Rice KPD722-4 - T27 OASA1D Rice KA317 - T27 0 AS AID Rice HW5 - T27 0ASA1 D Rice HW1 - T27 0ASA1 D Rice B-4-1-18 - T28 AOsBR11 Rice G-3-3-22 - T29 OSGA2ox1 Rice AD77 - T6 DEF Rice AD51 - T6 DEF Rice AD48 - T6 DEF Rice AD41 - T6 DEF Rice 13pNasNa800725atAprt1 - T30 HvNASI; HvNAAT-A; APRT Rice 13pAprt1 - T30 APRT Rice gHvNAS1-gHvNAAT-1 - T30 HvNASI; HvNAAT-A; HvNAAT-B Rice gHvlDS3-1 - T30 HvlDS3 Rice gHvNAATI - T30 HvNAAT-A; HvNAAT-B Rice gHvNASM - T30 HvNASI Rice NIA-OS006-4 - T6 WRKY45 Rice NIA-OS005-3 - T6 WRKY45 Rice NIA-OS004-2 - T6 WRKY45 Rice NIA-OS003-1 - T6 WRKY45 Rice NIA-OS002-9 - T6 WRKY45 αίτοηηη / ζζηζ / Ε / γίΛΐ Rice NIA-OS001-8 - T6 WRKY45 Rice OsCrl1 - T13 Cry j modified Rice 17053 - T1 cp4 epsps (aroA:CP4) Rice 17314 - T1 cp4 epsps (aroA:CP4) Pink WKS82 / 130-4-1 IFD-52401- 4 T9 5AT; bp40 (f3'5'h) Pink WKS92 / 130-9-1 1FD-52901-9 T9 5AT; bp40(f3'5'h) Soy 260-05 (G94-1,G94-19, G168) - T9 gm-fad2-1 (silencing locus) Soy A2704-12 ACS-GM005-3 T3 Pat Soy A2704-21 ACS-GM004-2 T3 Pat Soy A5547-127 ACS-GM006-4 T3 Pat Soy A5547-35 ACS-GM008-6 T3 Pat Soy CV127 BPS-CV127-9 T16 Csr1-2 Pat Soy DAS68416-4 DAS68416-4 T3 Pat Soy DP305423 DP-305423-1 T11, T31 gm-fad2-1 (silencing locus); gm-hra Soya DP356043 DP-356043-5 T1, T31 gm-fad2-1 (silencing locus); gat4601 Soybean FG72 MST-FG072-3 T32, T1 2mepsps; hppdPF W336 Soy GTS 40-3-2 (40-3-2) MON-04032-6 T1 cp4 epsps (aroA:CP4) Soy GU262 ACS-GM003-1 T3 pat Soy MON87701 MON-87701-2 T7 Cry1 Ac fatb1- A (sense and antisense); fad2- Soybean MON87705 MON-87705-6 T1,T31 1A (sense and antisense); cp4 epsps (aroA:CP4) Soybean MON87708 MON-87708-9 T1, T12 dmo; cp4 epsps (aroA:CP4) Soybean MON87769 MON-87769-7 T1, T31 Pj. D6D; Nc.Fad3; cp4 epsps (aroA:CP4) Soybean MON89788 MON-89788-1 T1 ep4 epsps (aroA:CP4) Soybean W62 ACS-GM002-9 T3 Bar Soybean W98 ACS-GM001-8 T3 Bar Soybean MON87754 MON-87754-1 T33 dgat2A αίτοηηη / ζζηζ / Ε / γίΛΐ Soybean DAS21606 DAS-21606 T34, T3 aad-12 modified; pat Soy DAS44406 DAS-44406-6 T1, T3, T34 add-12 modified; 2mepsps; pat Soy SYHT04R SYN-0004R-8 T35 avhppd modified Soy 9582.814.19.1 - T3, T7 cry1 Ac, cry1 F, PAT Cucurbita CZW3 SEM-OCZW3-2 T6 cmv cp, zymv cp, wmv cp Cucurbita ZW20 SEM-0ZW20-7 T6 zymv cp, wmv cp Sugar beet GTSB77 (T9100152) SY-GTSB77-8 T1 cp4 epsps (aroA:CP4); goxv247 Sugar beet H7-1 KM-000H71-4 T1 cp4 epsps (aroA:CP4) Sugar beet T120-7 ACS-BV001-3 T3 Pat Sugar beet T227-1 - T1 cp4 epsps (aroA:CP4) Sugar cane NXI- 1T - T21 EcbetA Sunflower -7I8OO-3 T1 cp4 epsps (aroA:CP4) QbQnnn / zznz / B / YiAi When the herbicidal composition of the present invention is applied, an unexpected synergistic effect is achieved, and the herbicidal activity is greater than a single or the sum of the predicted activity of each herbicide. The synergistic effect is manifested through a reduced application rate, a broader weed control spectrum and a faster and longer lasting weed killing action, all of which are required for weed control procedures. With respect to the characteristics described, the composition is significantly superior to existing herbicides in the art. It is more environmentally friendly since the composition is used in a smaller quantity than existing herbicides in the art. The synergistic herbicidal composition of the present invention also has the following advantages: (1) The composition of the present invention is environmentally friendly, since it degrades easily in the environment. (2) The herbicidal composition of the invention is low cost and convenient for use, and has great economic and social benefit for the popularization and application thereof. Specific way to put the invention into practice The following examples provided are not intended to limit the invention, but simply to illustrate how the invention is carried out. These examples show particularly significant effectiveness for certain weeds. Examples are presented below. A) Examples Dispersed oil suspension of 10% penoxsulam · A1 (2 + 8) % penoxsulam + 8% A1 +5% calcium dodecyldenzenesulfonate + 7% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether of castor + 5% of 200 # solvent oil + 2.5% of organodentonite + 1.5% of fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 12% penoxsulam A2 (2 + 10) % penoxsulam + 10% A2 + 5% calcium dodecyldenzenesulfonate + 7% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor + 5% solvent oil 200 # + 2.0% organodentonite + 1.5% fumed silica + methyl oleate until the rest is complete. Dispersed oil suspension of 14% penoxsulam · A4 (2 + 12) % penoxsulam + 12% A4 + 5% calcium dodecyldenzenesulfonate + 7% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether of castor + 5% of 200 # solvent oil + 2.0% of organodentonite + 1.5% of fumed silica + methyl oleate until completing the rest. Disperse oil suspension of 10% dispyridac sodium A1 (2 + 8) % dispyridac sodium + 8% A1 +6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4 7o polyoxyethylene ether castor oil + 5 7o of 200 # solvent oil + 2.5 7o of organodentonite + 1.5 7o of fumed silica + methyl oleate until completing the rest. Dispyridac sodium A2 (2 + 10) dispersible oil suspension of 12 7o 7o dispyridac sodium + 10 7o A2 + 6 7o calcium dodecyldenzenesulfonate + 8 7o polyoxyethylene fatty alcohol ether + 4 7o polyoxyethylene ether of castor oil + 5 7o solvent oil 200 # + 2.0 7o organodentonite + 1.5 7o of fumed silica + methyl oleate until completing the rest. Disperse oil suspension of 14 7o dispyridac sodium A4 (2 + 12) % bispyribac sodium + 12% A4 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene ether castor oil + 5% 200# solvent oil + 2.0% organobentonite + 1.5% fumed silica + methyl oleate to complete the rest. Dispersed oil suspension of 10% pyrazosulfuron-ethyl A1 (2 + 8) % pyrazosulfuron-ethyl + 8% A1 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 2.5% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 12% pyrazosulfuron-ethyl A2 (2 + 10) % pyrazosulfuron-ethyl + 10% A2 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 14% pyrazosulfuron-ethyl A3 (2 + 12) % pyrazosulfuron-ethyl + 12% A3 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 12% nicosulfuron A1 (4 + 8) % nicosulfuron + 8% A1 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 2.2% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 14% nicosulfuron · A2 (4 + 10) % nicosulfuron + 10% A2 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 16% nicosulfuron A4 (4 + 12) % nicosulfuron + 12% A4 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% ether of polyoxytylene castor oil + 1.8% organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 8.3% florasulam A1 (0.3 + 8) 0.3% florasulam + 8% A1 +1% urea + 6% calcium dodecyldenzenesulfonate + 8% dehydrated sorbitol fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.5% of organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 10.3% florasulam A2 (0.3 + 10) 0.3% florasulam + 10% A2 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% dehydrated sorbitol fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.2% of organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 12.3% florasulam · A3 (0.3 + 12) 0.3% florasulam + 12% A3 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% dehydrated sorditol fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% of organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 10% rimsulfuron A1 (2 + 8) % rimsulfuron + 8% A1 +1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 2.5% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 12% rimsulfuron A2 (2 + 10) % rimsulfuron + 10% A2 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% ether of polyoxyethylene castor oil + 2.0% organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 14% rimsulfuron A4 (2 + 12) % rimsulfuron + 12% A4 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% ether of polyoxyethylene castor oil + 2.0% organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 14% imazethapyr A1 (6 + 8) % imazethapyr + 8% A1 + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor + 2.0% organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 16% imazethapyr · A2 (6 + 10) % imazethapyr + 10% A2 + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor bean + 2.0% organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 18% imazethapyr · A4 (6 + 12) % imazethapyr + 12% A4 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor bean + 1.8% organobentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 18% imazapic A1 (10 + 8) % imazapic + 8% A1 +6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor + 2.0% organodentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 20% imazapic · A2 (10 + 10) % imazapic + 10% A2 + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor bean + 2.0% organodentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 22% imazapic A4 (10 + 12) % imazapic + 12% A4 + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor + 1.8% organodentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 12% imazamox A1 (4 + 8) % imazamox + 8% A1 + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor + 2.2% organodentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 14% imazamox · A2 (4 + 10) % imazamox + 10% A2 + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor bean + 2.0% organodentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 16% imazamox A4 (4 + 12) % imazamox + 12% A4 + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene oil ether castor + 1.8% organodentonite + 1.5% fumed silica + methyl oleate until completing the rest. Dispersed oil suspension of 18% sulfometuron-methyl A1 (10 + 8) % sulfometuron-methyl + 8% A1 + 1% urea + 6% calcium dodecyldenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 2.0% organodentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 20% sulfometuron-methyl A2 (10 + 10) % sulfometuron-methyl + 10% A2 + 1% urea + 6% calcium dodecyldendenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% αποηηη / 77η7 / Β / γΐΛΐ castor oil polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 22% sulfometuron-methyl A4 (10 + 12) % sulfometuron-methyl + 12% A4 + 1% urea + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + 1.6% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 10% chloransulam-methyl A1 (2 + 8) % chloransulam-methyl + 8% A1 +6% calcium dodecyldenzenesulfonate + 8% dehydrated sorditol fatty acid ester polyoxytylene ether + 4% castor oil polyoxyethylene ether + 2.5% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 12% chloransulam-methyl A2 (2 + 10) % chloransulam-methyl + 10% A2 + 6% calcium dodecyldenzenesulfonate + 8% dehydrated sorditol fatty acid ester polyoxytylene ether + 4% castor oil polyoxyethylene ether + 2.2% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 14% chloransulam-methyl A3 (2 + 12) % chloransulam-methyl + 12% A3 + 6% calcium dodecyldenzenesulfonate + 8% dehydrated sorditol fatty acid ester polyoxytylene ether + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + methyl oleate to complete the remainder. Dispersed oil suspension of 18% cyhalofop-butyl A1 (10 + 8) % cyhalofop-dutyl + 8% A1 + 6% calcium dodecyldenzenesulfonate + 8% dehydrated sorditol fatty acid ester polyoxytylene ether + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 15% 150# solvent oil + methyl oleate to complete the remainder. 20% Cyhalofop-Butyl A2 Aqueous Emulsion (10 + 10) % Cyhalofop-Butyl +10% A2 + 20% Solvent Oil 150# + 3.5% Phenylethylphenol Polyoxyethylene Ether Phosphate Triethanolamine Salt + 5 % castor oil polyoxyethylene ether + 3% ethylene glycol + deionized water to complete the rest. Dispersed oil suspension of 22% cyhalofop-butyl A4 (10 + 12) % cyhalofop-butyl + 12% A4 + 6% calcium dodecylbenzenesulfonate + 8% dehydrated sorbitol fatty acid ester polyoxytylene ether + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 15% 150# solvent oil + methyl oleate to complete the remainder. Dispersed oil suspension of 11% clodinafop-propargyl A1 (3 + 8) % clodinafop-propargyl + 8% A1 + 6% calcium dodecylbenzenesulfonate + 8% dehydrated sorbitol fatty acid ester polyoxytylene ether + 4% castor oil polyoxyethylene ether + 2.5% organobentonite + 2.0% fumed silica + 15% 150# solvent oil + methyl oleate to complete the remainder. Aqueous emulsion of 13% clodinafop-propargyl A2 (3 + 10) % clodinafop-propargyl + 10% A2 + 15% solvent oil 150 # + 5% cyclohexanone + 3.5% ether phosphate triethanolamine salt phenylethylphenol polyoxyethylene + 5% castor oil polyoxyethylene ether + 3% ethylene glycol + deionized water to complete the remainder. Dispersible oil suspension of 15% clodinafop-propargyl A3 (3 + 12) % clodinafop-propargyl + 12% A3 + 6% calcium dodecylbenzenesulfonate + 8% dehydrated sorbitol fatty acid ester polyoxytylene ether + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 1.5% fumed silica + 15% 150# solvent oil + methyl oleate to complete the remainder. Water suspension of 13% pinoxaden A1 (5 + 8) % pinoxaden + 8% A1 +5% polycarboxylate + 2% propylene glycol block polyether + 2% polyoxyethylene fatty alcohol ether + 0.2% xanthan gum + 2.0% magnesium aluminosilicate + 3% ethylene glycol + 0.1% silicone as antifoam agent + deionized water to complete the rest. Emulsifiable concentrate of 15% pinoxaden A2 (5 + 10) % pinoxaden + 10% A2 + 15% tetrahydrofurfuryl alcohol + 1% triphenyl phosphate + 5% calcium dodecylbenzenesulfonate + 3.5% polyoxyethylene phenylethylphenol ether + 5% castor oil polyoxyethylene ether + 150 # solvent oil to complete the rest. Dispersible oil suspension of 17% pinoxaden · A3 (5 + 12) % pinoxaden + 12% A3 + 6% calcium dodecylbenzenesulfonate + 8% polyoxytylene ether of dehydrated sorbitol fatty acid ester + 4% Castor oil polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 10% 150 # solvent oil + methyl oleate to complete the remainder. Dispersible oil suspension of 14% clethodim A1 (6 + 8) % clethodim + 8% A1 +6% calcium dodecylbenzenesulfonate + 8% dehydrated sorbitol fatty acid ester polyoxytylene ether + 4% ether of polyoxyethylene castor oil + 2.0% organobentonite + 1.5% fumed silica + 5% 150# solvent oil + methyl oleate until completing the rest. Emulsifiable concentrate of 16% clethodim A2 (6 + 10) αποηηη / 77η7 / Β / γΐΛΐ % clethodim + 10% A2 + 4% calcium dodecylbenzenesulfonate + 4% polyoxyethylene phenylethylphenol ether + 4% ether polyoxyethylene fatty alcohol + 150 # solvent oil until the rest is completed. Dispersed oil suspension of 18% clethodim A4 (6 + 12) % clethodim + 12% A4 + 6% calcium dodecylbenzenesulfonate + 9% dehydrated sorbitol fatty acid ester polyoxytylene ether + 4% ether of polyoxyethylene castor oil + 1.8% organobentonite + 1.5% fumed silica + 5% 150# solvent oil + methyl oleate until completing the rest. Dispersed oil suspension of 23% sethoxydim · A1 (15 + 8) % sethoxydim + 8% A1 + 6% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 2.2% organobentonite + 1.5% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. Emulsifiable concentrate of 25% sethoxydim · A2 (15 + 10) % sethoxydim + 10% A2 + 4% calcium dodecylbenzenesulfonate + 6% phenylethylphenol polyoxyethylene ether + 3% polyoxyethylene fatty alcohol ether + oil 150 # solvent until the rest is complete. Dispersed oil suspension of 27% sethoxydim A4 (15 + 12) % sethoxydim + 12% A4 + 6% calcium dodecylbenzenesulfonate + 9% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organobentonite + 1.5% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 12% quizalofop-P-methyl A1 (4 + 8) % quizalofop-P-methyl + 8% A1 +6% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% of polyoxyethylene ether of castor oil + 2.4% organodentonite + 1.5% fumed silica + 20% 150# solvent oil + methyl oleate until completing the rest. Aqueous emulsion of 14% quizalofop-P-methyl A2 (4 + 10) % quizalofop-P-methyl + 10% A2 + 6% cyclohexanone + 20% solvent oil 150 # + 3.5% triethanolamine salt polyoxyethylene ether phosphate of phenylethylphenol + 4.5% polyoxyethylene ether of castor oil + 3 7o of ethylene glycol + deionized water to complete the remainder. Dispersed oil suspension of 16 7o quizalofop-P-methyl A4 (4 + 12) 7o quizalofop-P-methyl + 12 7o A4 + 6 7o calcium dodecyldenzenesulfonate + 8 7o cardanol polyoxyethylene ether + 4 7o castor oil polyoxyethylene ether + 2.0 7o organodentonite + 1.5 7o fumed silica + 20 7o of 150# solvent oil + απρηηη / 77η7 / Β / γΐΛΐ methyl oleate until completing the rest. Dispersed oil suspension of 12% fluazifop-P-butyl A1 (4 + 8) % fluazifop-P-butyl + 8% A1 +6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% of polyoxyethylene ether of castor oil + 2.4% organobentonite + 1.5% fumed silica + 5% 150# solvent oil + methyl oleate until completing the rest. Aqueous emulsion of 14% fluazifop-P-butyl A2 (4 + 10) % fluazifop-P-butyl + 10% A2 + 20% solvent oil 150# + 3.5% polyoxyethylene ether phosphate triethanolamine salt of phenylethylphenol + 4.5% polyoxyethylene ether of castor oil + 3% ethylene glycol + deionized water until completing the rest. Dispersible oil suspension of 16% fluazifop-P-butyl A4 (4 + 12) % fluazifop-P-butyl + 12% A4 + 6% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% of polyoxytylene ether of castor oil + 2.0% organobentonite + 1.5% fumed silica + 5% 150# solvent oil + methyl oleate until completing the rest. Dispersible oil suspension of 12% Haloxyfop-P-methyl A1 (4 + 8) % Haloxyfop-P-methyl + 8% A1 +6% Calcium dodecylbenzenesulfonate + 8% Polyoxyethylene cardanol ether + 4% of polyoxytylene ether of castor oil + 2.4% organobentonite + 1.5% fumed silica + 5% 150# solvent oil + methyl oleate until completing the rest. Aqueous emulsion of 14% Haloxyfop-P-methyl A2 (4 + 10) % Haloxyfop-P-methyl + 10% A2 + 20% Solvent oil 150# + 3.5% Polyoxyethylene ether phosphate triethanolamine salt of phenylethylphenol + 4.5% polyoxyethylene ether of castor oil + 3% ethylene glycol + deionized water until completing the rest. Dispersible oil suspension of 16% Haloxyfop-P-methyl A4 (4 + 12) % Haloxyfop-P-methyl + 12% A4 + 6% Calcium dodecylbenzenesulfonate + 8% Polyoxyethylene cardanol ether + 4% of polyoxytylene ether of castor oil + 2.0% organobentonite + 1.5% fumed silica + 5% 150# solvent oil + methyl oleate until completing the rest. Dispersible oil suspension of 29% atrazine A1 (25 + 4) % atrazine + 4% A1 +4% calcium dodecylbenzenesulfonate + 8% dehydrated sorbitol fatty acid ester polyoxytylene ether + 4% ether of polyoxyethylene castor oil + 1.0% organobentonite + 5% solvent oil 150 # + methyl oleate until completing the rest. Dispersible oil suspension of 30% atrazine A2 (25 + 5) % atrazine + 5% A2 + 6% calcium dodecylbenzenesulfonate + 8% Qfronnn / zznz / E / YiAi dehydrated sorbitol fatty acid ester polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.0% organodentonite + 0.5% fumed silica + 5% solvent oil 150# + oleate of methyl until completing the rest. Dispersed oil suspension of 31% atrazine A4 (25 + 6) % atrazine + 6 7o A4 + 6 7o calcium dodecyldenzenesulfonate + 8 7o polyoxytylene ether of dehydrated sorditol fatty acid ester + 4 7o ether of polyoxyethylene castor oil + 0.8 7o of organodentonite + 5 7o of solvent oil 150 # + methyl oleate until completing the rest. Dispersed oil suspension of 29 7o of isoproturon · A1 (25 + 4) 7o of isoproturon + 4 7o of A1 +4 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxytylene ether of fatty acid ester of dehydrated sorditol + 4 7o of polyoxyethylene ether of castor oil + 1.0 7o of organodentonite + 5 7o of solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 30 7o of isoproturon · A2 (25 + 5) 7o of isoproturon + 5 7o of A2 + 6 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxytylene ether of fatty acid ester of dehydrated sorditol + 4 7o of polyoxyethylene ether of castor oil + 1.0 7o of organodentonite + 0.5 7o of Fumed silica + 5 7o of 150 # solvent oil + methyl oleate until completing the rest. Dispersed oil suspension of 31 7o of isoproturon A3 (25 + 6) 7o of isoproturon + 6 7o of A3 + 4 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxytylene ether of fatty acid ester of dehydrated sorditol + 4 7o of polyoxyethylene ether of castor oil + 0.8 7o of organodentonite + 5 7o of solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 29 7o chlorotoluron A1 (25 + 4) 7o of chlorotoluron + 4 7o of A1 +4 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxytylene ether of dehydrated sorditol fatty acid ester + 4 7o of polyoxyethylene ether of castor oil + 1.0 7o of organodentonite + 5 7o of solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 30% chlorotoluron A2 (25 + 5) 7o of chlorotoluron + 5 7o of A2 + 6 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxytylene ether of dehydrated sorditol fatty acid ester + 4 7o of polyoxyethylene ether of castor oil + 1.0 7o of organodentonite + 0.5 7o of Fumed silica + 5 7o of 150 # solvent oil + methyl oleate until completing the rest. Dispersed oil suspension of 31 7o of chlorotoluron A3 (25 + 6) 7o of chlorotoluron + 6 7o of A3 + 4 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxytylene ether of dehydrated sorditol fatty acid ester + 4 7o of polyoxyethylene ether of castor oil + 0.8% of organobentonite + 5% of solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 34% diuron · A1 (30 + 4) % diuron + 4% A1 + 4% calcium dodecylbenzenesulfonate + 8% polyoxytylene ether of dehydrated sorbitol fatty acid ester + 4% castor oil polyoxyethylene ether + 0.6% organobentonite + 5% solvent oil 150 # + methyl oleate to complete the remainder. Dispersed oil suspension of 35% diuron · A2 (30 + 5) % diuron + 5% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxytylene ether of dehydrated sorbitol fatty acid ester + 4% castor oil polyoxyethylene ether + 0.8% organobentonite + 8% solvent oil 150 # + methyl oleate to complete the remainder. Dispersed oil suspension of 36% diuron A4 (30 + 6) % diuron + 6% A4 + 5% calcium dodecylbenzenesulfonate + 7% dehydrated sorbitol fatty acid ester polyoxytylene ether + 4% ether of polyoxyethylene castor oil + 0.4% organobentonite + 8% solvent oil 150 # + methyl oleate until completing the rest. Aqueous solution of 48% bentazone A1 (40 + 8) % bentazone + 8% A1 + 5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water to completion the rest. Dispersed oil suspension of 25% bentazone A2 (20 + 5)% bentazone + 5% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxytylene ether of dehydrated sorbitol fatty acid ester + 4% Castor oil polyoxyethylene ether + 0.8% organobentonite + 0.8% fumed silica + 8% 150 # solvent oil + methyl oleate to complete the remainder. Aqueous solution of 52% bentazone A3 (40 + 12) % bentazone + 12% A3 + 5.5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water to completion the rest. Aqueous solution of 20% bromoxynyl A3 (12 + 8) % bromoxynyl + 8% A1 +4% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water to completion the rest. Emulsifiable concentrate of 22% bromoxynil · A2 (12 + 10) % bromoxynyl + 10% A2 + 10% 1-octylpyrrolidin-2-one + 3% calcium dodecylbenzenesulfonate + 5% polyoxyethylene fatty alcohol ether + 4% polyoxyethylene ether of castor oil + 150% solvent oil until the rest is complete. 24% aqueous solution of bromoxynil A3 (12 + 12) QbQnnn / zznz / B / YiAi % bromoxynyl + 12% A3 + 5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water to complete the remainder. Dispersed oil suspension of 27% propanyl A1 (25 + 2)% propanyl + 2% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 0.6% organobentonite + methyl oleate until the rest is complete. Emulsified concentrate of 27.5 % propanyl A2 (25 + 2.5) % propanyl + 2.5 7o A2 + 10 7o 1 -octylpyrrolidin-2-one + 10 7o N, N-dimethylcapramide + 2 7o calcium dodecyldenzenesulfonate + 10 7o of polyoxyethylene fatty alcohol ether + 4 7o of polyoxyethylene ether of castor oil + 150 7o of solvent oil until completing the rest. Dispersed oil suspension of 28 7o propanyl A4 (25 + 3) 7o of propanyl + 3 7o of A4 + 5 7o of calcium dodecyldenzenesulfonate + 7 7o of polyoxyethylene ether of cardanol + 4 7o of polyoxyethylene ether of castor oil + 0.4 7o of organodentonite + methyl oleate until completing the rest. Huandifucaotong A1 (9 + 8) 17 7o dispersed oil suspension 7o of huandifucaotong + 8 7o of A1 +4 7o of calcium dodecyldenzenesulfonate + 8 7o of cardanol polyoxyethylene ether + 4% of polyoxytylene ether of castor oil + 1.5 7o of organodentonite + 1.5 7o of fumed silica + 10 7o of solvent oil 150 # + methyl oleate to complete the rest. Huandifucaotong A2 (9 + 10) 19 7o dispersed oil suspension 7o of huandifucaotong + 10 7o of A2 + 4 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxyethylene ether of cardanol + 4 7o of polyoxytylene ether of castor oil + 2.0 7o of organodentonite + 2.0 7o of fumed silica + 10 7o of 150# solvent oil + methyl oleate until the rest is complete. Huandifucaotong A3 (9 + 12) 21 7o dispersed oil suspension 7o of huandifucaotong + 12 7o of A3 + 4 7o of calcium dodecyldenzenesulfonate + 8 7o of polyoxyethylene ether of cardanol + 4 7o of polyoxytylene ether of castor oil + 1.2 7o of organodentonite + 1.2 7o of fumed silica + 10 7o of 150# solvent oil + methyl oleate until the rest is complete. 10 7o shuangzuocaotong A1 (2+8) dispersed oil suspension 7o of shuangzuocaotong + 8 7o of A1 + 0.4 7o of citric acid + 4 7o of calcium dodecylbenzenesulfonate + 8 7o of polyoxyethylene ether of cardanol + 4 7o of polyoxyethylene ether of castor oil + 1.5 7o of organodentonite + 1.5 7o of Fumed silica + 8 7o of 150 # solvent oil + methyl oleate until completing the rest. 12 7o shuangzuocaotong A2 (2+10) dispersed oil suspension QbQnnn / zznz / B / YiAi % shuangzuocaotong + 10% A2 + 0.4% citric acid + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.5 % organobentonite + 1.5% fumed silica + 8% solvent oil 150 # + methyl oleate until completing the rest. Dispersed oil suspension of 14% shuangzuocaotong A3 (2 + 12) % shuangzuocaotong + 12% A3 + 0.4% citric acid + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% ether of polyoxyethylene castor oil + 1.2% organobentonite + 1.2% fumed silica + 8% solvent oil 150 # + methyl oleate until completing the rest. Dispersed oil suspension of 17% denzuofucaotong A1 (9 + 8) % denzuofucaotong + 8% A1 +4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.5% organodentonite + 1.5% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 19% denzuofucaotong A2 (9 + 10) % denzuofucaotong + 10% A2 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organodentonite + 2.0% fumed silica + 5% 150# solvent oil + methyl oleate to complete the rest. Dispersed oil suspension of 21% denzuofucaotong A3 (9 + 12) % denzuofucaotong + 12% A3 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organodentonite + 1.2% fumed silica + 5% 150# solvent oil + methyl oleate to complete the rest. Dispersed oil suspension of 20% denzuofucaotong A1 (12 + 8) % sanzuohuangcaotong + 8% A1 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.5% organodentonite + 1.5 7o fumed silica + 5 7o solvent oil 150 # + methyl oleate until completing the rest. sanzuohuangcaotong A2 (12+10) 22 7o dispersed oil suspension 7o of sanzuohuangcaotong + 10 7o of A2 + 4 7o of calcium dodecylbenzenesulfonate + 8 7o of polyoxyethylene ether of cardanol + 4 7o of polyoxytylene ether of castor oil + 2.0 7o of organobentonite + 2.0 7o of fumed silica + 5 7o of solvent oil 150 # + methyl oleate to complete the rest. Sanzuohuangcaotong A4 24 7o dispersed oil suspension (12 + Qfronnn / zznz / E / YiAi 12) % sanzuohuangcaotong + 12% A4 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organobentonite + 1.2% fumed silica + 5 % solvent oil 150 # + methyl oleate until the rest is complete. Dispersed oil suspension of 14% tefuryltrione- A1 (6 + 8) % tefurytrione + 8% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.8% organobentonite + 1.8% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 16% tefuryltrione A2 (6 + 10) % tefuryltrione + 10% A2 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organodentonite + 2.0% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 18% tefuryltrione A4 (6 + 12) % tefuryltrione + 12% A4 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.2% organodentonite + 1.0% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. Dispersed oil suspension of 18% mesotrione · A1 (10 + 8) % mesotrione + 8% A1 + 0.5% citric acid + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 1.8% organodentonite + 1.8% fumed silica + 5% 150 # solvent oil + methyl oleate to complete the remainder. Dispersed oil suspension of 20% mesotrione · A2 (10 + 10) % mesotrione + 10% A12+ 0.5% citric acid + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% ether of polyoxyethylene castor oil + 2.0% organodentonite + 2.0% fumed silica + 5% solvent oil 150 # + methyl oleate until completing the rest. Dispersed oil suspension of 22% mesotrione A3 (10 + 12) % mesotrione + 12% A3 + 0.5% citric acid + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% ether of polyoxyethylene castor oil + 1.2% organodentonite + 1.0% fumed silica + 5% solvent oil 150 # + methyl oleate until completing the rest. Dispersed oil suspension of 14% temdotrione A1 (6 + 8) αποηηη / ζζηζ / Β / γίΛΐ % tembotrione + 8% A1 + 1% citric acid + 4% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether of cardanol + 4% polyoxyethylene ether of castor oil + 1.8% organobentonite + 1.8% fumed silica + 5% solvent oil 150 # + methyl oleate until completing the rest. Dispersed oil suspension of 16% temdotrione A2 (6 + 10) % temdotrione + 10% A2 + 1% citric acid + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% ether of polyoxyethylene castor oil + 2.0% organodentonite + 2.0% fumed silica + 5% solvent oil 150 # + methyl oleate until completing the rest. Dispersed oil suspension of 18% temdotrione A3 (6 + 12) % temdotrione + 12% A3 + 1% citric acid + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% ether of polyoxyethylene castor oil + 1.2% organodentonite + 1.0% fumed silica + 5% solvent oil 150 # + methyl oleate until completing the rest. 100 Dispersed oil suspension of 11% topramezone A1 (3 + 8) % topramezone + 8% A1 + 0.2% citric acid + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% castor oil polyoxyethylene ether + 2.0% organodentonite + 2.0% fumed silica + 5% 150 # solvent oil + methyl oleate to complete the remainder. 101 Dispersed oil suspension of 13% topramezone A2 (3 + 10) % topramezone + 10% A2 + 0.2% citric acid + 4% calcium dodecyldenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% castor oil polyoxyethylene ether + 2.0% organodentonite + 2.0% fumed silica + 5% 150 # solvent oil + methyl oleate to complete the remainder. 102 Dispersed oil suspension of 15% topramezone A3 (3 + 12) % topramezone + 12% A3 + 0.2% citric acid + 4% calcium dodecyldenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% Castor oil polyoxyethylene ether + 1.5% organodentonite + 1.5% fumed silica + 5% 150 # solvent oil + methyl oleate to complete the remainder. 103 Dispersed oil suspension of 14% isoxaflutol A1 (6 + 8) % isoxaflutol + 8% A1 + 0.5% citric acid + 4% calcium dodecyldenzenesulfonate + 8% polyoxyethylene cardanol ether + 4% castor oil polyoxyethylene ether + 1.8% organodentonite + 1.8% fumed silica + 5% 150 # solvent oil + methyl oleate to complete the remainder. 104 Dispersed oil suspension of 16% isoxaflutol A2 (6 + 10) % isoxaflutol + 10% A2 + 0.5% citric acid + 4% αποηηη / 77η7 / Β / γΐΛΐ calcium dodecylbenzenesulfonate + 8% calcium ether Cardanol polyoxyethylene + 4% castor oil polyoxyethylene ether + 2.0% organobentonite + 2.0% fumed silica + 5% 150 # solvent oil + methyl oleate to complete the remainder. 105 Dispersible oil suspension of 18% isoxaflutol A4 (6 + 12) % isoxaflutol + 12% A4 + 0.5% citric acid + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% Castor oil polyoxyethylene ether + 1.2% organobentonite + 1.0% fumed silica + 5% 150 # solvent oil + methyl oleate to complete the remainder. 106 Dispersible oil suspension of 28% benzobicylon A1 (20 + 8) % benzobicylon + 8% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.0% organobentonite + 5% 150# solvent oil + methyl oleate to complete the rest. 107 Dispersible oil suspension of 30% benzobicylon A2 (20 + 10) % benzobicylon + 10% A2 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.2% organobentonite + 1.2% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. 108 Dispersible oil suspension of 32% benzobicylon A4 (20 + 12) % benzobicylon + 12% A4 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 0.5% organobentonite + 5% 150# solvent oil + methyl oleate to complete the rest. 109 Dispersible oil suspension of 18% diflufenican A1 (10 + 8) % diflufenican + 8% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.2% organobentonite + 1.2% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. 110 Dispersible oil suspension of 20% diflufenican · A2 (10 + 10) % diflufenican + 10% A2 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% oil polyoxyethylene ether castor oil + 1.5% organobentonite + 1.5% fumed silica + 5% solvent oil 150 # + methyl oleate until completing the rest. 111 Dispersible oil suspension of 22% diflufenican · A3 (10 + 12) % diflufenican + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% oil polyoxyethylene ether castor oil + 0.8% organobentonite + 5% 150# solvent oil + methyl oleate until completing the rest. 112 Dispersible oil suspension of 29% flurochloridone A1 (25 + 4) αποηηη / 77ηη / Β / γΐΛΐ % flurochloridone + 4% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% of castor oil polyoxytylene ether + 2.0% organobentonite + 2.0% fumed silica + 15% 150 # solvent oil + methyl oleate until completing the rest. 113 Dispersed oil suspension of 60% flurochloridone A2 (50 + 10) % flurochloridone + 10% A2 + 6% calcium dodecylbenzenesulfonate + 8% polyoxyethylene ether or castor oil + 10% cyclopentanone + solvent oil 150 # until completing the rest. 114 Dispersed oil suspension of 31% flurochloridone A3 (25 + 6) % flurochloridone + 6% A3 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.8% organodentonite + 1.8% fumed silica + 15% solvent oil 150 # + methyl oleate to complete the rest. 115 Dispersed oil suspension of 38% clomazone · A1 (30 + 8) % clomazone + 8% A1 +5% calcium dodecyldenzenesulfonate + 6% cardanol polyoxyethylene ether + 4% oil polyoxyethylene ether castor oil + 2.5% organodentonite + 2.5% fumed silica + 5% solvent oil 150 # + methyl oleate until completing the rest. 116 Emulsified concentrate of 40% clomazone A2 (30 + 10) % clomazone + 10% A2 + 6% calcium dodecyldenzenesulfonate + 10% castor oil polyoxyethylene ether + 10% ethanol + solvent oil 150 # up complete the rest. 117 Dispersed oil suspension of 42% clomazone A4 (30 + 12) % clomazone + 12% A4 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 2.2% organodentonite + 1.8% fumed silica + 15% solvent oil 150 # + methyl oleate to complete the rest. 118 Suspoemulsion of 10% carfentrazone-ethyl A1 (2 + 8) % carfentrazone-ethyl + 8% A1 +3% phenylethylphenol polyoxyethylene ether phosphate triethanolamine salt + 4% isooctyl alcohol block polyether + 3% castor oil polyoxytylene ether + 10% 150# solvent oil + 0.25% xanthan gum + 2.0% magnesium aluminum silicate + 2% ethylene glycol + deionized water to complete the rest. 119 Aqueous emulsion of 12% carfentrazone-ethyl A2 (2 + 10) % carfentrazone-ethyl + 10% A2 + 3% phenylethylphenol polyoxyethylene ether phosphate triethanolamine salt + 5% oil polyoxyethylene ether castor oil + 10% απρηηη / 77η7 / Β / γΐΛΐ solvent oil 150 # + 3% ethylene glycol + deionized water to complete the rest. 120 Aqueous emulsion of 14% carfentrazone-ethyl A3 (2 + 12) % carfentrazone-ethyl + 12% A3 + 3% polyoxyethylene ether phosphate triethanolamine salt of phenylethylphenol + 5% polyoxyethylene ether castor oil + 10% 150# solvent oil + 0.25% xanthan gum + 2% ethylene glycol + deionized water to complete the rest. 121 Aqueous solution of 33% fomesafen A1 (25 + 8) % fomesafen + 8% A1 +4% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water to complete the rest. 122 Microemulsion of 35% fomesafen A2 (25 + 10) % fomesafen + 10% A2 + 10% cyclohexanone + 10% ethanol + 6% sodium di-sec-octyl maleate sulfonate + 10% C8 alkyl -10 glucoside + deionized water until the rest is complete. 123 Aqueous solution of 37% fomesafen A3 (25 + 12) % fomesafen + 12% A3 + 4.5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + deionized water to complete the rest. 124 Dispersed oil suspension of 9% fluoroglycofen A1 (1 + 8) % fluoroglycene + 8% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 2.0% organobentonite + 2.0% fumed silica + 10% solvent oil 150 # + methyl oleate to complete the rest. 125 Aqueous emulsion of 11% fluoroglycene A2 (1 +10) % fluoroglycene + 10% A2 + 3% triethanolamine salt of polyoxyethylene ether phosphate of phenylethylphenol + 4% polyoxyethylene ether of castor oil + 10 % solvent oil 150 # + 0.1% xanthan gum + 2% ethylene glycol + deionized water to complete the rest. 126 Dispersed oil suspension of 13% fluoroglycofen A3 (1 +12) % fluoroglycene + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 2.0% organobentonite + 1.5% fumed silica + 10% solvent oil 150 # + methyl oleate to complete the rest. 127 Dispersed oil suspension of 20% oxyfluorfen · A2 (12 + 8) % oxyfluorfen + 8% A1 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% oil polyoxyethylene ether castor bean + 5% oil-soluble polycardoxylate + 1.4% organobentonite + 10% soybean oil + methyl oleate until completing the rest. 128 Emulsifiable concentrate of 22% oxyfluorofen · A2 (12 + 10) % oxyfluorofen + 10% A2 + 10% cyclopentanone + 3% calcium dodecyldenzenesulfonate + 4% polyoxyethylene fatty alcohol ether + 4% ether of polyoxyethylene castor oil + 150% solvent oil until the rest is complete. 129 Dispersed oil suspension of 24% oxyfluorophen A3 (12 + 12) % oxyfluorophen + 12% A3 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor oil + 5% oil-soluble polycardoxylate + 1.4% organobentonite + 10% soybean oil + methyl oleate to complete the rest. 130 Dispersed oil suspension of 16% lactofen A1 (8 + 8) % lactofen + 8% A1 +4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.8% organodentonite + 1.8% fumed silica + 5% solvent oil 150 # + methyl oleate to complete the rest. 131 Emulsified concentrate of 18% lactofen A2 (8 + 10) % lactofen + 10% A2 + 3% calcium dodecyldenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 4% castor oil polyoxyethylene ether + solvent oil 150 # until completing the rest. 132 Dispersed oil suspension of 20% lactofen A3 (8 + 12) % lactofen + 12% A3 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.6% organodentonite + 1.6% fumed silica + 10% solvent oil 150 # + methyl oleate to complete the rest. 133 Aqueous solution of 38% acifluorfen sodium A1 (30 + 8) % acifluorfen sodium + 8% A1 + 4.5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + water deionized until the rest is complete. 134 Dispersed oil suspension of 20% acifluorfen sodium A2 (15 + 5) % acifluorfen sodium + 5% A2 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor oil + 1.6% organodentonite + 1.6% fumed silica + 10% 150# solvent oil + methyl oleate to complete the rest. 135 Aqueous solution of 42% acifluorfen sodium A3 (30 + 12) % acifluorfen sodium + 12% A3 + 5% NaOH + 5% polyoxyethylene fatty alcohol ether + 15% C8-10 alkyl glucoside + water deionized until the rest is complete. αποηηη / 77η7 / Β / γΐΛΐ 136 Dispersed oil suspension of 14% flumioxazine · A1 (6 + 8) % flumioxazine + 8% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% oil polyoxyethylene ether castor oil + 1.6% organobentonite + 10% soybean oil + methyl oleate until completing the rest. 137 Emulsifiable concentrate of 16% flumioxazine A2 (6 + 10) % flumioxazine + 10% A2 + 15% cyclopentanone + 3% calcium dodecylbenzenesulfonate + 4% polyoxyethylene fatty alcohol ether + 4% ether castor oil polyoxyethylene + solvent oil 150 # until completing the rest. 138 Dispersed oil suspension of 18% flumioxazine A3 (6 + 12) % flumioxazine + 12% A3 + 4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.4% organobentonite + 10% soybean oil + methyl oleate until the rest is complete. 139 Dispersed oil suspension of 32% sulfentrazone A1 (24 + 8) % sulfentrazone + 8% A1 +4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.3% organodentonite + 10% solvent oil 150 # + methyl oleate to complete the rest. 140 Suspoemulsion of 34% sulfentrazone A2 (24 + 10) % sulfentrazone + 10% A2 + 8% solvent oil 150 # + 4% polyoxyethylene ether phosphate triethanolamine salt of phenylethylphenol + 4% polyether propylene glycol block + 4% castor oil polyoxyethylene ether + 0.15% xanthan gum + 2% ethylene glycol + deionized water to complete the rest. 141 Water suspension of 36% sulfentrazone A1 (24 + 12) % sulfentrazone + 12% A4 + 4% phenylethylphenol polyoxyethylene ether phosphate triethanolamine salt + 3% naphthalenesulfonate as dispersant + 2% ether of polyoxyethylene fatty alcohol + 0.15% xanthan gum + 1% magnesium aluminosilicate + 3% ethylene glycol + deionized water to complete the rest. 142 Dispersed oil suspension of 32% saflufenacil · A2 (24 + 8) % saflufenacil + 8% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% oil polyoxyethylene ether castor oil + 1.2% organobentonite + 1.0% fumed silica + 10% solvent oil 150 # + methyl oleate until completing the rest. 143 Suspoemulsion of 34% saflufenacil A2 (24 + 10) % saflufenacil + 10% A2 + 8% solvent oil 150 # + 4% polyoxyethylene ether phosphate triethanolamine salt of phenylethylphenol + 4% polyether propylene glycol block + 4% castor oil polyoxyethylene ether + 0.12% xanthan gum + 2% ethylene glycol + deionized water to complete the rest. αποηηη / 77η7 / Β / γΐΛΐ 144 Water suspension of 36% saflufenacil · A3 (24 + 12) % saflufenacil + 12% A3 + 4% triethanolamine salt of polyoxyethylene ether phosphate of phenylethylphenol + 3% naphthalenesulfonate as dispersant + 2% polyoxyethylene fatty alcohol ether + 0.15% xanthan gum + 1.2% magnesium aluminosilicate + 3% ethylene glycol + deionized water to complete the rest. 145 Dispersed oil suspension of 24% oxadiazon A1 (20 + 4) % oxadiazon + 4% A1 +4% calcium dodecylbenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.2% organobentonite + 1.0% fumed silica + 10% solvent oil 150 # + methyl oleate to complete the rest. 146 Dispersed oil suspension of 25% oxadiazon A2 (20 + 5) % oxadiazon + 5% A2 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.0% organodentonite + 10% solvent oil 150 # + methyl oleate to complete the rest. 147 Dispersed oil suspension of 26% oxadiazon · A4 (20 + 6) % oxadiazon + 6% A4 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% oil polyoxyethylene ether of castor + 1.2% of organodentonite + 10% of solvent oil 150 # + methyl oleate until completing the rest. 148 Dispersed oil suspension of 14% oxadiargyl A1 (6 + 8) % oxadiargyl + 8% A1 +4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.6% organodentonite + 1.5% fumed silica + 10% solvent oil 150 # + methyl oleate to complete the rest. 149 Dispersed oil suspension of 16% oxadiargyl A2 (6 + 10) % oxadiargyl + 10% A2 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.5% organodentonite + 1.5% fumed silica + 10% solvent oil 150 # + methyl oleate to complete the rest. 150 Dispersed oil suspension of 18% oxadiargyl A4 (6 + 12) % oxadiargyl + 12% A4 + 4% calcium dodecyldenzenesulfonate + 8% cardanol polyoxyethylene ether + 4% cardanol polyoxyethylene ether castor + 1.4% organodentonite + 1.2% fumed silica + 10% solvent oil 150 # + methyl oleate to complete the rest. 151 Dispersible oil suspension of A172 + glyphosate (20 + 30) % A172 + 30% glyphosate + 6% calcium dodecyldenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 6% castor oil polyoxyethylene ether + 0.5 αποηηη / 77η7 / Β / γΐΛΐ % organobentonite + 15% 100# solvent oil + methyl oleate to complete the remainder. 152 Dispersible oil suspension of A67 + glyphosate (10 + 30) % A67 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 5% castor oil polyoxyethylene ether + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. 153 Dispersible oil suspension of A1 + glyphosate (9 + 30) % A1 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 5% castor oil polyoxyethylene ether + 0.5% organobentonite + 15% 100 # solvent oil + methyl oleate to complete the rest. 154 Dispersible oil suspension of A4 + glyphosate (12 + 30) % A4 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 5% castor oil polyoxyethylene ether + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. 155 Dispersible oil suspension of A171 + glyphosate (20 + 30) % A171 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 6% castor oil polyoxyethylene ether + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. 156 Dispersible oil suspension of A211 + glyphosate (10 + 30) % A211 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 6% castor oil polyoxyethylene ether + 0.5% organobentonite + 15% 100# solvent oil + methyl oleate to complete the rest. 157 Dispersible oil suspension of A94 + glyphosate (20 + 30) % A94 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 6% castor oil polyoxyethylene ether + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. 158 Dispersible oil suspension of A173 + glyphosate (10 + 30) % A173 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 6% castor oil polyoxyethylene ether + 0.5% organobentonite + 15% 100# solvent oil + methyl oleate to complete the rest. 159 Dispersible oil suspension of A212 + glyphosate (20 + 30) % A212 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 6% castor oil polyoxyethylene ether + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. 160 Dispersible oil suspension of A141 + glyphosate (10 + 30) % A141 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 6% polyoxyethylene fatty alcohol ether + 6% castor oil polyoxyethylene ether + 0.5 αποηηη / 77η7 / Β / γΐΛΐ % organobentonite + 15% 100# solvent oil + methyl oleate to complete the remainder. 161 Dispersed oil suspension of A163 + glyphosate (10 + 30) % A163 + 30% glyphosate + 5% calcium dodecylbenzenesulfonate + 8% polyoxyethylene fatty alcohol ether + 5% polyoxyethylene castor oil ether + 0.5% organobentonite + 15% 100# solvent oil + methyl oleate to complete the rest. 162 Dispersed oil suspension of A130 + glyphosate (10 + 30) % A130 + 30% glyphosate + 5% calcium dodecyldenzenesulfonate + 7% polyoxyethylene fatty alcohol ether + 5% polyoxyethylene castor oil ether + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. 163 Dispersed oil suspension of A213 + glyphosate (10 + 30) % A213 + 30% glyphosate + 5% calcium dodecyldenzenesulfonate + 7% polyoxyethylene fatty alcohol ether + 5% polyoxyethylene castor oil ether + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. 164 Dispersed oil suspension of A214 + glyphosate (10 + 30) % A214 + 30% glyphosate + 5% calcium dodecyldenzenesulfonate + 7% polyoxyethylene fatty alcohol ether + 5% polyoxyethylene castor oil ether + 0.5% organobentonite + 15% 100# solvent oil + methyl oleate to complete the rest. 165 Dispersible oil suspension of A2 + glyphosate (10 + 30) % A2 + 30% glyphosate + 5% calcium dodecyldenzenesulfonate + 7% polyoxyethylene fatty alcohol ether + 5% polyoxyethylene ether of castor oil + 0.5% organobentonite +15% 100# solvent oil + methyl oleate until the rest is complete. The equipment for processing the above dispersed oil suspensions are: a mixing tank, a colloid mill, a sand mill and a cutting machine, etc. The procedure for processing the above dispersed oil suspensions is as follows: all the materials were introduced into the mixing tank and mixed with stirring, introduced into the colloidal mill, then subjected to grinding at grade 3 in the sand mill and finally, they were cut evenly on the cutter and transferred to the storage tank after passing inspection. The equipment to process the above aqueous suspensions are: a mixing tank, a colloid mill, a sand mill, a cutter, etc. The procedure for processing the above aqueous suspensions is as follows: all the materials were introduced into the mixing tank and mixed with stirring, introduced into the colloidal mill, then subjected to grinding at grade 3 in the mill. sand and finally cut them evenly on the cutter, and transferred them to the storage tank after passing inspection. The equipment to process the previous suspoemulsions are: a tank of QbQnnn / zznz / B / YiAi mixing, a colloid mill, a sand mill, a cutting machine, etc. The procedure for processing the above suspoemulsions is as follows: some of the materials and additives were placed in the mixing tank and mixed with stirring, introduced into the colloidal mill, then subjected to grinding to grade 3 in the sand mill. and then transferred to the intermediate tank as aqueous phase; then the rest of the materials and the cosolvent were introduced into the loading tank and dissolved by stirring until they were completely transparent, and then stirred to the oil phase; and finally he cut it with the cutter; The oil phase was dripped slowly into the aqueous phase; After all the material finished dripping, cutting continued for 1 hour and was transferred to the storage tank after passing inspection. The equipment for processing the above aqueous emulsions is as follows: a vacuum pump, a dosing tank, a storage tank and a cutting tank. The procedure for processing the above aqueous emulsions is as follows: the technical materials and solvent were placed in the dosing tank, stirred and dissolved until they became completely transparent; and the emulsifier was added, and then stirred until even as oil phase; After that, the glycol, antifoam and deionized water were added by pumping into the cutting tank; and finally in the cutting state, the oil phase was slowly pumped into the cutting tank; After all materials were pumped out, cutting continued for 1 hour and was transferred to storage tank after passing inspection. The equipment to process the above microemulsions is as follows: a vacuum pump, a dosing tank and a storage tank. The procedure for processing the above microemulsions is as follows: the technical materials and the solvent were introduced into the dosing tank, stirred and dissolved until they became completely transparent; and the emulsifier was added, and then stirred until uniformity was achieved; and the deionized water was added, and then stirred until it was completely clear; and transferred to the storage tank after passing inspection. The equipment to process the above emulsifiable concentrates is as follows: a vacuum pump, a dosing tank and a storage tank. The procedure for processing the above emulsifiable concentrates is as follows: the technical materials and the solvent were introduced into the dosing tank, stirred and dissolved until they became completely transparent; and the emulsifier was added, and then stirred until it was completely transparent; and transferred to the storage tank after passing inspection. αποηηη / ζζηζ / Β / γίΛΐ The equipment to process the above aqueous solutions is as follows: a vacuum pump, a dosing tank and a storage tank. The procedure for processing the above aqueous solutions is as follows: the technical materials and deionized water were introduced into the dosing tank, stirred and dissolved until they became completely transparent; and the emulsifier was added, and then stirred until it was completely transparent; and transferred to the storage tank after passing inspection. B) Efficacy trials Post-emergence treatment by spraying foliage 1) Experimental conditions 1.1) Tested objectives Tables 1-48, 51-98, 101-148: Echinochloa crusgalli var. zelayensis, Eclipta prostrate, Galium aparine L·, Alopecuros aequalis, Alopecurus japonícus, Lindernia procumbens, Veronica persica 1, Malachium aquaticum, Beckmannia syzigachne, Stellaria media in Huai'an of Jiangsu Province; Commelina communis, Sonchus arvensis, Setaria glauca, Chloris virgata, Setaria faberi, Sonchus oleraceus L., Echinochloa oryzoides, Cirsium setosum, Xanthium strumarium were collected in Qiqiha’er of Heilongjiang province; Sinapis arvensis, Veronica persica2 was collected in Zhumadian of Henan Province; Ludwigia prostrate, Ammannia arenaria was collected in Zhuji of Zhejiang province; Amaranthus retroflexus, Descurainia sophia, Digitaria sanguinalis, Setaria viridis, Conyza Canadensis, Capsella bursa-pastoris, Eleusine indica, Ipomoea purpurea, Abutilon theophrasti, Chenopodium album, Acalypha australis, Solanum nigrum were collected in Qingdao of Shandong province; Echinochloa caudate was collected in Pingluo of Ningxia Province. Tables 151-206: Digitaria sanguinalis, Amaranthus retroflexus, Conyza Canadensis, Capsella bursa-pastoris, Eleusine indica were collected in Huangdao of Shandong Province, Sinapis arvensis was collected in Sixian of Anhui Province, Alopecurus japonicus was collected in Tianchang of Anhui province, Veronica didyma was collected in Siyang of Jiangsu province. The above weeds were grown using a pot culture method. A 180 mm x 140 mm plastic nutrient container containing 4 / 5 of the top layer of soil was placed in a glazed container, in which the soil had been air dried and initial humidity of 20%. Complete and uniform weed seeds were selected, soaked in warm water at 25°C for 6 hours, and germinated in a 28°C biochemical incubator (in the dark). The newly germinated weed seeds were placed evenly on the soil surface and then covered Qfronnn / zznz / E / YiAi with between 0.5 cm and 1 cm of soil according to the size of the seeds. 1.2) Growing conditions The cultivation was carried out in a greenhouse with controllable sunlight at a Qfronnn / zznz / E / YiAi temperature between 20SC and 30SC, with natural light and a relative humidity between 57% and 72%. The soil was loam with an organic matter content of 1.63%, a pH value of 7.1, a hydrolyzable alkaline nitrogen of 84.3 mg / kg, a rapidly available phosphorus of 38.5 mg / kg and a rapidly available potassium of 82.1 mg / kg. . 1.3) Equipment and devices Type 3WP-2000 traveling spray tower (Nanjing Agricultural Machinery Institute, Ministry of Agriculture); electronic scale of ten thousandths of type GA10 (Germany); ZDR2000 type intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); and SPX type intelligent biochemical incubator (Ningbo Jiangnan Instrument Factory). 2) Experiment designs 2.1) Reagents The desired active ingredient A is prepared based on patent CN201911321469.4. Examples of representative compounds are as follows, synthetic methods of other compounds are similar and will not be described in detail herein. (1) Synthesis of compound A67 and A1 Compound a (0.5 g, 2.13 mmol), compound b (313 mg, 2.55 mmol), a catalytic amount of TBAB (10 mg) and DMF (10 ml) were added to a round-bottom flask and stirred at temperature 15eC environment for 24 hours. When a small amount of starting materials remained as detected by LC-MS, further treatment was performed. The reaction solution was poured into 50 ml of water and extracted with methyl tert-butyl ether twice (50 ml x 2). The organic phase was dried, concentrated and separated by column chromatography to obtain compound A67 (300 mg, 50% yield) as a white solid. Compound A67 (0.3g, 1.06 mmol), methanol (20 ml) was added to a 100 ml capacity single neck flask, lithium hydroxide (44.5 mg, 1.06 mmol) was dissolved in 2 ml of water and added slowly dropwise to the single-neck flask at room temperature, followed by stirring at room temperature for 12 hours. After completing the reaction of the starting materials according to the detection by LC-MS, the reaction solution was adjusted with Diluted 0.5 M HCl to pH = 5-6, concentrated and then extracted with water and ethyl acetate. The organic phase was dried and concentrated to obtain compound A1 (200 mg - 70% yield) as a white solid. Qfronnn / zznz / E / YiAi (2) Synthesis of compound A2 Compound A1 (200 mg, 0.74 mmol), compound c (75 mg, 0.74 mmol), DCC (152 mg, 0.74 mmol), and anhydrous DCM (20 ml) were added to a 100 ml round bottom flask. and were reacted at room temperature for 12 hours. After completing the reaction of the starting materials according to LC-MS detection, the reaction solution was concentrated and separated by column chromatography to obtain compound A2 (200 mg, 77% yield) as a solid white. (3) Synthesis of compound A211 Compound A1 (200 mg, 0.74 mmol), compound c (85 mg, 0.74 mmol), DCC (152 mg, 0.74 mmol) and anhydrous DCM (20 ml) were added to a 100 ml capacity round bottom flask and They were reacted at room temperature for 12 hours. After completing the reaction of the starting materials according to LC-MS detection, the reaction solution was concentrated and separated by column chromatography to obtain compound A211 (200 mg, 73% yield) as a solid white. (4) Synthesis of compound A173 Compound d (2 g, 18.16 mmol), compound b (3.64 g, 21.80 mmol), a catalytic amount of TBAB (10 mg) and DMF (10 ml) were added to a round-bottom flask and stirred at temperature 15SC environment for 24 hours. When a small amount of starting materials remained as detected by LC-MS, further treatment was performed. The reaction solution was poured into 50 ml of water and extracted with methyl tert-butyl ether twice (100 ml χ 2). The organic phase was dried, concentrated and separated by column chromatography to obtain compound e (1.5 mg, 42% yield) as a white solid. db Qfronnn / zznz / E / YiAi Compound e (0.5 g, 2.55 mmol) was dissolved in acetonitrile (20 ml) and placed in a 100 ml capacity single-neck flask. NCS (850.7 mg, 6.37 mmol) and a catalytic amount of BPO (10 mg) were added at room temperature, and the temperature was increased to 70 °C and the reaction continued for 2 h. After completing the reaction of starting materials according to LC-MS detection, the reaction solution was concentrated and separated by column chromatography to obtain compound A173 (300 mg, 44% yield), as a colored solid. white. BPO NCS ---► MeCN O A173 (5) Synthesis of compound A174 and A212 Compound e (0.5 g, 2.55 mmol) was dissolved in acetonitrile (20 ml) and placed in a 100 ml capacity single-neck flask. NBS (1.13 mg, 6.37 mmol) and a catalytic amount of BPO (10 mg) were added at room temperature, and the temperature was increased to 70 °C and the reaction continued for 2 h. After completing the reaction of starting materials according to LC-MS detection, the reaction solution was concentrated and separated by column chromatography to obtain compound A174 (500 mg, 54% yield), as a solid of White color. The compound A174 (0.5 g, 1.41 mmol) and methanol (20 ml) were added to a 100 ml capacity single-neck flask, lithium hydroxide (59.3 mg, 1.41 mmol) was dissolved in 2 ml of water and added slowly dropwise to the single-neck flask at room temperature, followed by stirring at room temperature for 12 hours. After completing the reaction of starting materials according to LC-MS detection, the reaction solution was adjusted with 0.5 M dilute HCl to pH = 5-6, concentrated, and then extracted with water and ethyl acetate. . The organic phase was dried and concentrated to obtain compound A212 (350 mg, 73% yield) as a white solid. Qfronnn / zznz / E / YiAi A174 A212 Active ingredient B, for example, huanbifucaotong, shuangzuocaotong, benzuofucaotong and sanzuohuangcaotong, was produced by our company, and the others were purchased from reagent manufacturers. All technical materials were dissolved in acetone and ig diluted with an aqueous solution containing 0.1% Tween-80 emulsifier. Dilution is carried out as necessary. 2.2) Experimental treatments 2.2.1) Determination of dosage The ratio between active ingredient A and active ingredient B and the amounts thereof in each group depends on the characteristics and toxicity of the two agents, as well as the main purpose of application of a corresponding formulation. Based on previous tests in this study, the tables show the doses of active ingredient Ay and active ingredient B applied alone and in combination. Water containing the solvent and the emulsifier was used with the previous groups but free of agents as a control control. 2.2.2) Repetition of experiments Tables 1-48, 51-98, 101-148, 151-206: 3 pots were treated with 20 weed seeds per pot in a treatment with 4 repetitions per treatment, that is, a total of 60 weeds were treated in one treatment. . Tables 207-216: 10 pots were treated with 10 weed seeds per pot in a treatment with 4 repetitions per treatment, and then, 3 weeds were maintained per pot. 2.3) Treatment method 2.3.1) Time and frequency of treatment Tables 1-48, 51-98, 101-148: Agents were used only once in the experiment. At the 3-4 leaf weed stage, weeds were thinned to maintain 15 39 weeds per pot and 45 weeds for each treatment, then continued cultivation until the 5-6 leaf stage of grass-type weeds, the 6-leaf stage. - 7 leaves of broadleaf weeds, and they were subjected to treatment. Tables 151 -206: The agents were used only once in the experiment. At the 3-4 leaf weed stage, weeds were thinned to maintain 15 weeds per pot and 45 35 weeds for each treatment, then continued cultivation until the 4-5 leaf stage of grass-type weeds, the 5-leaf stage. ~ 6 leaves of broadleaf weeds, and they were subjected to the treatment. Tables 207-216: Agents were used only once in the experiment. At the weed stage with 6-8 leaves, the weeds were thinned to maintain 3 weeds per pot and 30 weeds for each treatment, then continued to be grown in Conyza Canadensis with a height of 10 cm and subjected to the treatment. 2.3.2) Equipment and methods for the application of agents The well-grown weeds were evenly placed on a platform with an area of ​​0.5 m2, and agent solution was sprayed on their stems and leaves by the 3WP-2000 type traveling spray tower with a dosage of 450 kg / ha. and under a spray pressure of 0.3 MPa. After all the solution was sprayed, the valve was closed. After 30 seconds, the spray tower door was opened and the nutrient container was removed. Then, the valve was opened and the spray tube was cleaned by spraying 50 ml of water. 3) Experimental methods A pot growing method was used. For weed cultivation, please refer to section 1.1) and "Pesticide guidelines for laboratory bioactivity tests - herbicides". For a method of applying the agents, please refer to section 2.3.2, that is, regarding the foliage treatment that was used. After the treatment, the weeds were usually grown in a greenhouse. 4) Data research and statistical analysis 4.1) Research methods A method was used to investigate the absolute number, in which whole seedlings of survival weeds were cut with a knife along the soil surface, and fresh weeds were weighed with an analytical balance. Regarding the dead weeds, their fresh weight was zero. 4.2) Time and frequency of research Tables 1-48, 51-98, 101-148, 207-216: The investigation was conducted after 24 days of one-time treatment. Tables 151-206: The investigation was conducted after 20 days of one-time treatment. 4.3) Statistical analysis of the data The theoretical inhibition rate of the fresh weight of a combination of two active ingredients in each group was calculated using Gowing's method (E0 = X + Y - X * Y / 100), and then compared with an inhibition rate (E) actually measured, so the effect of the combination was evaluated (hereinafter referred to as effect Qfronnn / zznz / E / YiAi combined) on weeds: the value of E-EO, which was greater than 10%, corresponded to a synergistic effect, the value of E-EO, which was less than -10%, corresponded to an antagonistic effect, and the E-EO value, which was between -10% and 10%, corresponded to an additional effect. An optimal ratio of the two active ingredients was determined through the actual control effect, the characteristics of the herbicides and the balance of a corresponding formula. In the formula, X represents the fresh weight inhibition rate of active ingredient A at a dose of P, and Y represents the fresh weight inhibition rate of active ingredient B at a dose of Q. Floor sealing treatment: 1) Experimental conditions 1.1) Objectives tested Echinochloa crusgalli var. zelayensis in Huai’an of Jiangsu Province; Echinochloa caudate was collected in Pingluo of Ningxia Province; Echinochloa oryzoides was collected in Qiqihaer of Heilongjiang Province. 1.2) Growing conditions Cultivation was carried out in a greenhouse with controllable sunlight at a temperature between 20SC and 30SC, with natural light and a relative humidity between 57% and 72%. The soil was loam with an organic matter content of 1.63%, a pH value of 7.1, a hydrolyzable alkaline nitrogen of 84.3 mg / kg, a rapidly available phosphorus of 38.5 mg / kg and a rapidly available potassium of 82.1 mg / kg. . The test soil was quantitatively placed in 3 / 4 of the pots and then watered from the bottom of the pots to completely moisten the soil until saturation. The pretreated test weed seeds were sown evenly on the surface, then covered with 0.5 cm to 2 cm of soil according to the size of the seed, and were ready for use 24 hours after sowing. . 1.3) Equipment and devices Electronic scale of ten thousandths of type GA10 (Germany); ZDR2000 type intelligent data recorder (Hangzhou Zeda Instrument Co., Ltd.); SPX (Ningbo Jiangnan Instrument Factory) type intelligent biochemical incubator and pipette, etc. 2) Experiment designs 2.1) Reagents All technical materials were dissolved in acetone and diluted with an aqueous solution containing 0.1% T-80 emulsifier. Dilution is carried out as necessary. 2.2) Experimental treatments 2.2.1) Determination of dosage A relationship between A and the active ingredient B and the amounts thereof in each Qfronnn / zznz / E / YiAi group depends on the characteristics and toxicity of the two agents, as well as the main purpose of the application of a corresponding formulation. Based on previous trials in this study, the tables show the doses of A and active ingredient B applied alone and in combination. Water containing the solvent and the emulsifier was used with the previous groups but free of agents as a control control. 2.2.2) Repetition of experiments 3 pots were treated with 30 weed seeds per pot in a treatment with 4 repetitions per treatment. 3) Experimental methods The pots were planted and mulched evenly on a platform with an area of ​​0.5 m2, and a solution of agents was sprayed on the soil surface by the traveling spray tower type 3WP-2000 at a dose of 675 kg / ha and at a spray pressure of 0.3 MPa. After all the solution was sprayed, the valve was closed. After 30 seconds, the spray tower door was opened and the nutrient container was removed. Then, the valve was opened and the spray tube was cleaned by spraying 50 ml of water. 4) Data research and statistical analysis This section was the same as section 4) in the post-emergence treatment by spraying the foliage, and was not repeated here. The statistical results are shown in tables 1-216 below. In addition to those marked as soil sealing treatments, there are other post-emergence treatments by spraying the foliage. Qfronnn / zznz / E / YiAi Table 1 Control effects of A2 or penoxsulam alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 12.3 75+15 5 :1 54.2 70.1 99.7 86.3 13.4 Table 2 Control effects of A2 or bispyribac sodium alone and a combination thereof on Echinochloa crusgalli var. zelayensis αποηηη / ζζηζ / Β / γίΛΐ Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 12.1 75+15 5 :1 54.2 62.9 95.2 83.0 12.2 Table 3 Control effects of A2 or pyrazosulfuron-ethyl alone and a combination thereof on Eclipta postrate Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 13.6 75+15 5 :1 32.3 76.1 96.2 83.8 12.4 Table 4 Control effects of A2 or nicosulfuron alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 75+30 5 :2 54.2 58.7 94.0 81.1 12.9 Table 5 Control effects of A2 or florasulam alone and a combination thereof on Galium aparine L. αποηηη / ζζηζ / Β / γίΛΐ Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). .9 7.5+3.0 5 :2 34.8 76.2 98.2 84.5 13.7 Table 6 Control effects of A2 or rimsulfuron alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 14.6 75+15 5 :1 54.2 67.7 97.9 85.2 12.7 Table 7 Control effects of A2 or imazethapyr alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 5+60 5 :4 54.2 59.2 93.7 81.3 12.4 Qfronnn / zznz / E / YiAi Table 8 Control effects of A2 or imazapic alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 15.7 75+75 1 :1 54.2 57.0 92.4 80.3 12.1 Table 9 Control effects of A2 or imazamox alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 4 75+30 5 :2 54.2 54.8 91.1 79.3 11.8 Table 10 Control effects of A2 or sulfometuron-methyl alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (% ). 13.7 75+75 1 :1 54.2 54.8 91.8 79.3 12.5 Table 11 Control effects of A2 or chloransulam-methyl alone and a combination thereof on Commelina communis Qfronnn / zznz / E / YiAi Dose of A+B g a.i. / ha A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (7o ), E E0 (%) E-EO (7th) 60+1.875 32:1 67.8 4.7 81.2 69.3 11.9 60+3.75 16:1 67.8 15.2 86.9 72.7 14.2 30+7.5 4:1 32.3 53.5 82.3 68.5 1 3.8 30+15 2 :1 32.3 71.8 93.4 80.9 12.5 Table 12 Control effects of A2 or cyhalofop-butyl alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+9.375 16:1 75.3 1.6 86.7 75.7 11.0 150+18.75 8:1 75.3 17.4 89.8 79.6 10.2 75+37.5 2:1 54.2 31.0 81. 3 68.4 12.9 75+ 75 1:1 54.2 70.3 98.6 86.4 12.2 Table 13 Control effects of A2 or clodinafop-propargyl alone and a combination thereof on Alopecurus aequalis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+3.75 40:1 45.5 6.1 61.1 48.8 12.3 150+7.5 20:1 45.5 16.3 68.2 54.4 13.8 75+15 5:1 23.8 59.3 83.4 69 .0 14.4 75+ 30 5:2 23.8 81.1 98.3 85.6 12.7 Qfronnn / zznz / E / YiAi Table 14 Control effects of A2 or pinoxaden alone and a combination thereof on Alopecuros aequalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 3 75+ 30 5:2 23.8 72.4 92.1 79.0 13.1 Table 15 Control effects of A2 or clethodim alone and a combination of the same in Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+ B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 75.3 8.5 87.9 77.4 10.5 150+15 10:1 75.3 23.9 93.1 81.2 11.9 75+30 5:2 54.2 44.3 87.6 74.5 13. 1 75 +60 5:4 54.2 68.8 98.4 85.7 12.7 Table 16 Control effects of A2 or sethoxydim alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+15 10:1 75.3 6.5 88.1 76.9 11.2 150+30 5:1 75.3 22.3 93.4 80.8 12.6 75+60 5:4 54.2 42.4 87.9 73.6 14.3 75 + 120 5:8 54.2 62.4 97.2 82.8 14.4 Table 17 Control effects of A2 or quizalofop-P-methyl alone and a combination thereof on Echinochloa crusgalli var. zelayensis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 5 75+ 30 5:2 54.2 71.0 99.4 86.7 12.7 Table 18 Control effects of A2 or fluazifop-P-butyl alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 75.3 2.0 88.6 75.8 12.8 150+7.5 20:1 75.3 18.2 92.8 79.8 13.0 75+15 5:1 54.2 37.3 87.1 71.3 15 .8 75+ 30 5:2 54.2 73.1 98.1 87.7 10.4 Table 19 Control effects of A2 or haloxyfop-P-methyl alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 1 75+ 30 5:2 54.2 74.5 99.8 88.3 11.5 Table 20 Control effects of A2 or atrazine alone and a combination thereof on Echinochloa crusgalli var. zelayensis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 75.3 4.5 89.4 76.4 13.0 150+150 1:1 75.3 15.4 90.2 79.1 11.1 75+300 1:4 54.2 26.9 78.8 66.5 12.3 7 5+ 600 1:8 54.2 65.5 94.7 84.2 10.5 Table 21 Control effects of A2 or isoproturon alone and a combination thereof on Alopecurus aequalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 150+75 2:1 45.5 2.6 59.4 46.9 12.5 150+150 1:1 45.5 11.9 64.7 52.0 12.7 75+300 1:4 23.8 57.2 81.9 67.4 14.5 75+ 600 1:8 23.8 76.5 95.3 82.1 13.2 Table 22 Control effects of A2 or chlorotoluron alone and a combination thereof on Alopecurus aequalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 45.5 1.7 56.5 46.4 10.1 150+150 1:1 45.5 12.8 63.9 52.5 11.4 75+300 1:4 23.8 40.6 68.5 54.7 13.8 7 5+ 600 1:8 23.8 71.9 91.2 78.6 12.6 Table 23 Control effects of A2 or diuron alone and a combination thereof on Echinochloa crusgalli var. zelayensis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 75.3 2.0 86.6 75.8 10.8 150+150 1:1 75.3 13.0 91.3 78.5 12.8 75+300 1:4 54.2 29.3 79.1 67.6 11.5 7 5+ 600 1:8 54.2 55.0 91.5 79.4 12.1 Table 24 Control effects of A2 or bentazone alone and a combination thereof on Lindernia procumbens Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 15+18.75 4:5 78.9 4.3 91.2 79.8 11.4 15+37.5 2:5 78.9 10.0 93.2 81.0 12.2 7.5+75 1:10 42.3 45.4 82.3 68.5 13 .8 7.5+ 150 1:20 42.3 76.1 98.7 86.2 12.5 Table 25 Control effects of A2 or bromoxynil alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+18.75 8:1 52.4 3.2 64.2 53.9 10.3 150+37.5 4:1 52.4 9.2 68.1 56.8 11.3 75+75 1:1 22.9 57.8 81.2 67.5 13.7 75+ 150 1:2 22.9 83.7 99.6 87.4 12.2 Qfronnn / zznz / E / YiAi Table 26 Control effects of A2 or propanil alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (7th) E-EO (%) 150+75 2:1 75.3 6.1 88.9 76.8 12.1 150+150 1:1 75.3 18.6 93.4 79.9 13.5 75+300 1:4 54.2 35.2 82.1 70.3 11.8 75+ 600 1:8 54.2 52.6 90.2 78.3 11.9 Table 27 Control effects of A2 or huanbifucaotong alone and a combination of the same in Alopecurus aequalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Effect of A+B control (%), E E0 (7th) E-EO (7th) 150+18.75 8:1 45.5 4.6 60.2 48.0 12.2 150+37.5 4:1 45.5 10.1 64.7 51.0 13.7 75+75 1:1 23.8 55.9 79.3 66.4 12.9 75+150 1:2 23.8 81.8 97.6 86.1 11.5 Table 28 Control effects of A2 or shuangzuocaotong alone and a combination thereof on Descurainia sophia Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 30+1.875 16:1 74.2 4.3 86.5 75.3 11.2 30+3.75 8:1 74.2 19.0 92.7 79.1 13.6 15+7.5 2:1 35.7 48.7 80.2 67 .0 13.2 15+ 15 1:1 35.7 82.9 99.3 89.0 10.3 Table 29 Control effects of A2 or benzuofucaotong alone and a combination thereof on Digitaria sanguinalis αποηηη / ζζηζ / Β / γίΛΐ Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 6 75+ 60 5:4 22.4 79.6 95.4 84.2 11.2 Table 30 Control effects of A2 or sanzuohuangcaotong alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+18.75 8:1 75.3 6.9 88.2 77.0 11.2 150+37.5 4:1 75.3 16.2 94.5 79.3 15.2 75+75 1:1 54.2 42.8 87.9 73 .8 14.1 75+ 150 1:2 54.2 74.5 98.9 88.3 10.6 Table 31 Control effects of A2 or tefuryltrione alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+7.5 20:1 75.3 6.9 89.2 77.0 12.2 150+15 10:1 75.3 17.0 91.6 79.5 12.1 75+30 5:2 54.2 44.3 86.8 74.5 12.3 75+ 60 5:4 54.2 68.3 97.6 85.5 12.1 Table 32 Control effects of A2 or mesotrione alone and a combination thereof on Digitaría sanguinalis αποηηη / ζζηζ / Β / γίΛΐ Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (7th) 150+15 10:1 48.9 6.3 62.6 52.1 10.5 150+30 5:1 48.9 13.3 69.2 55.7 13.5 75+60 5:4 22.4 38.5 64.7 52.3 12.4 75+ 120 5:8 22.4 75.6 93.2 81.1 12.1 Table 33 Control effects of A2 or tembotrione alone and a combination thereof on Digitaría sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+3.75 40:1 48.9 3.7 61.5 50.8 10.7 150+7.5 20:1 48.9 12.1 69.9 55.1 14.8 75+15 5:1 22.4 41.2 68.6 54 .4 14.2 75+ 30 5:2 22.4 73.8 91.2 79.7 11.5 Table 34 Control effects of A2 or topramezone alone and a combination thereof on Setaria viridis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 60+1.875 32:1 56.3 2.3 69.5 57.3 12.2 60+3.75 16:1 56.3 11.0 74.7 61.1 13.6 30+7.5 4:1 32.7 37.0 72.1 5 7.6 14.5 30+ 15 2:1 32.7 76.1 95.3 83.9 11.4 Table 35 Control effects of A2 or isoxaflutole alone and a combination thereof on Echinochloa crusgalli var. zelayensis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 5 75+ 60 5:4 54.2 64.4 94.5 83.7 10.8 Table 36 Control effects of A2 or benzobicylon alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+37.5 4:1 75.3 7.3 90.2 77.1 13.1 150+75 2:1 75.3 16.2 91.8 79.3 12.5 75+150 1:2 54.2 44.9 86.5 74.8 11.7 75+ 300 1:4 54.2 55.9 91.3 79.8 11.5 Table 37 Control effects of A2 or diflufenican alone and a combination thereof on Persian Veronica1 Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+15 10:1 38.4 2.1 51.2 39.7 11.5 150+30 5:1 38.4 14.4 61.8 47.3 14.5 75+60 5:4 18.2 41.3 65.8 52.0 1 3.8 75+ 120 5:8 18.2 76.7 93.3 80.9 12.4 Table 38 Control effects of A2 or flurochloridone alone and a combination thereof on Persian Veronica1 Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 38.4 4.9 53.7 41.4 12.3 150+150 1:1 38.4 13.1 59.9 46.5 13.4 75+300 1:4 18.2 45.5 71.2 55.4 15.8 75+ 600 1:8 18.2 80.0 97.2 83.6 13.6 Table 39 Control effects of A2 or clomazone alone and a combination thereof on Echinochloa crusgalli var. zelayensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+45 10:3 75.3 5.7 89.4 76.7 12.7 150+90 5:3 75.3 10.1 90.2 77.8 12.4 75+180 5:12 54.2 48.8 88.9 76.6 12.3 75+ 360 5:24 54.2 70.7 99.7 86.6 13.1 Table 40 Control effects of A2 or carfentrazone-ethyl alone and a combination thereof on Veronica persica1 Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+1.875 80:1 38.4 2.4 51.8 39.9 11.9 150+3.75 40:1 38.4 11.5 58.3 45.5 12.8 75+7.5 10:1 18.2 37.3 62. 4 48.7 13.7 75+ 15 5:1 18.2 68.7 87.1 74.4 12.7 Table 41 Control effects of A2 or fomesafen alone and a combination thereof on Amaranthus retroflexus Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+22.5 20:3 52.4 5.0 64.9 54.8 10.1 150+45 10:3 52.4 11.3 71.2 57.8 13.4 75+90 5:6 22.9 45.5 72.6 58.0 14.6 75+ 180 5:12 22.9 82.0 98.5 86.1 12.4 Table 42 Control effects of A2 or fluoroglycene alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 150+0.9375 160:1 52.4 2.5 65.4 53.6 11.8 150+1.875 80:1 52.4 14.5 71.3 59.3 12.0 75+3.75 20:1 22.9 40.1 67.6 53.8 13.8 75+ 7.5 10:1 22.9 70.7 89.9 77.4 12.5 Table 43 Control effects of A2 or oxyfluorfen alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 52.4 3.2 64.1 53.9 10.2 150+15 10:1 52.4 11.1 68.4 57.7 10.7 75+30 5:2 22.9 30.9 59.8 46.7 13.1 75+ 60 5:4 22.9 68.1 87.3 75.4 11.9 Qfronnn / zznz / E / YiAi Table 44 Control effects of A2 or lactofen alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 52.4 1.3 63.5 53.0 10.5 150+15 10:1 52.4 12.2 71.2 58.2 13.0 75+30 5:2 22.9 39.8 65.8 53.6 12.2 75+ 60 5:4 22.9 65.5 84.2 73.4 10.8 Table 45 Control effects of A2 or acifluorfen sodium alone and of a combination of the same in Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Effect of A+B control (%), E E0 (%) E-E0 (%) 150+37.5 4:1 52.4 4.4 65.7 54.5 11.2 150+75 2:1 52.4 10.3 67.6 57.3 10.3 75+150 1:2 22.9 45.1 70.8 57.7 13.1 75+300 1:4 22.9 85.0 98.7 88.4 10.3 Table 46 Control effects of A2 or flumioxazine alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 150+7.5 20:1 52.4 5.5 67.5 55.0 12.5 150+15 10:1 52.4 12.4 71.3 58.3 13.0 75+30 5:2 22.9 37.4 63.9 51.7 12.2 75+ 60 5:4 22.9 78.9 94.5 83.7 10.8 Table 47 Control effects of A2 or sulfentrazone alone and a combination thereof on Echinochloa crusgalli var. zelayensis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+1.875 80:1 75.3 2.8 87.1 76.0 11.1 150+3.75 40:1 75.3 15.4 92.4 79.1 13.3 75+7.5 10:1 54.2 26.9 78.8 66.5 12.3 75+ 15 5:1 54.2 54.1 90.2 79.0 11.2 Table 48 Control effects of A2 or saflufenacil alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (7th) E-EO (7th) 150+3.75 40:1 57.2 3.0 70.8 58.5 12.3 150+7.5 20:1 57.2 11.9 75.5 62.3 13.2 75+15 5:1 36.7 39.2 75.7 61.5 14.2 75+ 30 5:2 36.7 76.5 98.3 85.1 13.2 Table 49 Control effects of A2 or oxadiazon alone and a combination thereof on Echinochloa crusgalli var. zelayensis (soil sealing treatment) Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+37.5 4:1 45.2 4.2 59.1 47.5 11.6 150+75 2:1 45.2 25.4 71.2 59.1 12.1 75+150 1:2 21.4 41.5 66.3 54.0 12.3 75+ 300 1:4 21.4 64.2 85.2 71.9 13.3 Qfronnn / zznz / E / YiAi Table 50 Control effects of A2 or oxadiargyl alone and a combination thereof on Echinochloa crusgalli var. zelayensis (soil sealing treatment) Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 45.2 1.6 56.5 46.1 10.4 150+15 10:1 45.2 10.4 61.2 50.9 10.3 75+30 5:2 21.4 38.8 64.2 51.9 12.3 75+ 60 5:4 21.4 63.5 82.7 71.3 11.4 Table 51 Control effects of A1 or penoxsulam alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 1 12.8 75+ 15 5:1 55.2 69.4 99.7 86.3 13.4 Table 52 Control effects of A1 or bispyribac sodium alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+1.875 80:1 76.3 5.5 88.9 77.6 11.3 150+3.75 40:1 76.3 16.0 92.8 80.1 12.7 75+7.5 10:1 55.2 44.9 87.2 75.3 11.9 75+ 15 5:1 55.2 62.1 95.6 83.0 12.6 Qfronnn / zznz / E / YiAi Table 53 Control effects of A1 or pyrazosulfuron-ethyl alone and a combination thereof on Ludwigia prostate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+1.875 80:1 72.4 7.6 86.8 74.5 12.3 150+3.75 40:1 72.4 13.0 89.1 76.0 13.1 75+7.5 10:1 34.3 52.2 81.2 68.6 12.6 75+ 15 5:1 34.3 75.3 95.9 83.8 12.1 Table 54 Control effects of A1 or nicosulfuron alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 150+3.75 40:1 76.3 3.8 88.4 77.2 11.2 150+7.5 20:1 76.3 14.3 91.6 79.7 11.9 75+15 5:1 55.2 40.2 87.5 73.2 14 .3 75+ 30 5:2 55.2 58.5 94.3 81.4 12.9 Table 55 Control effects of A1 or florasulam alone and a combination thereof on Malachium aquaticum Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 15+0.375 40:1 69.6 3.6 80.9 70.7 10.2 15+0.75 20:1 69.6 17.4 86.2 74.9 11.3 7.5+1.5 5:1 35.8 56.4 85.9 72.0 1 3.9 7.5+ 3.0 5:2 35.8 77.6 98.2 85.6 12.6 Table 56 Control effects of A1 or rimsulfuron alone and a combination thereof on Echinochloa caudate Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Control effect of A+B ( %), E E0 (%) E-EO (%) 150+1.875 80:1 76.3 5.5 87.8 77.6 10.2 150+3.75 40:1 76.3 25.3 94.6 82.3 12.3 75+7.5 10:1 55.2 37.9 87.8 72.2 15.6 75+15 5:1 55.2 65.8 97.6 84.7 12.9 Table 57 Control effects of A1 or imazethapyr alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 76.3 4.2 87.8 77.3 10.5 150+15 10:1 76.3 18.1 94.3 80.6 13.7 75+30 5:2 55.2 34.8 85.6 70.8 14.8 75+ 60 5:4 55.2 55.6 93.7 80.1 13.6 Table 58 Control effects of A1 or imazapic alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+9.375 16:1 76.3 6.8 89.9 77.9 12.0 150+18.75 8:1 76.3 21.5 92.8 81.4 11.4 75+37.5 2:1 55.2 28.6 81.2 68.0 13.2 75+ 75 1:1 55.2 55.6 93.4 80.1 13.3 Table 59 Control effects of A1 or imazamox alone and a combination thereof on Echinochloa caudate Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 5 75+ 30 5:2 55.2 53.8 92.1 79.3 12.8 Table 60 Control effects of A1 or sulfometuron-methyl alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+9.375 16:1 76.3 3.8 87.3 77.2 10.1 150+18.75 8:1 76.3 13.9 95.5 79.6 15.9 75+37.5 2:1 55.2 24.6 79.6 66.2 13.4 75+ 75 1:1 55.2 52.7 91.6 78.8 12.8 Table 61 Control effects of A1 or chloransulam-methyl alone and a combination thereof on Sonchus arvensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 60+1.875 32:1 70.7 6.5 84.1 72.6 11.5 60+3.75 16:1 70.7 15.0 89.6 75.1 14.5 30+7.5 4:1 33.3 52.8 82.2 68.5 13 .7 30+ 15 2:1 33.3 72.9 93.8 81.9 11.9 Table 62 Control effects of A1 or cyhalofop-butyl alone and a combination thereof on Echinochloa caudate Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E EO (%) E-EO (%) 150+9.375 16:1 76.3 5.9 87.9 77.7 10.2 150+18.75 8:1 76.3 11.4 89.6 79.0 10.6 75+37.5 2:1 55.2 29.9 81.4 68.6 12.8 75+ 75 1:1 55.2 69.6 97.6 86.4 11.2 Table 63 Control effects of A1 or clodinafop-propargyl alone and a combination thereof on Alopecuros japonicus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 2 75+ 30 5:2 25.6 79.9 98.8 85.1 13.8 Table 64 Control effects of A1 or pinoxaden alone and a combination thereof on Alopecuros japonicus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 1 75+ 30 5:2 25.6 71.8 92.5 79.0 13.5 Qfronnn / zznz / E / YiAi Table 65 Control effects of A1 or clethodim alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 76.3 3.4 87.3 77.1 10.2 150+15 10:1 76.3 27.0 93.6 82.7 10.9 75+30 5:2 55.2 43.8 87.4 74.8 12.6 75+ 60 5:4 55.2 67.4 98.1 85.4 12.7 Table 66 Control effects of A1 or sethoxydim alone and of a combination of the same in Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Control effect of A+B (%), E E0 (%) E-EO (%) 150+15 10:1 76.3 5.1 88.6 77.5 11.1 150+30 5:1 76.3 21.5 93.8 81.4 12.4 75+60 5:4 55.2 42.6 88.2 74.3 13.9 75+120 5:8 55.2 61.6 97.2 82.8 14.4 Table 67 Control effects of A1 or quizalofop-P-methyl alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 7 75+ 30 5:2 55.2 72.1 99.6 87.5 12.1 Table 68 Control effects of A1 or fluazifop-P-butyl alone and a combination thereof on Echinochloa caudate αίτοηηη / ζζηζ / Ε / γίΛΐ Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 8 75+ 30 5:2 55.2 74.1 98.6 88.4 10.2 Table 69 Control effects of A1 or haloxyfop-P-methyl alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 0 75+ 30 5:2 55.2 73.4 98.8 88.1 10.7 Table 70 Control effects of A1 or atrazine alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 76.3 3.8 89.5 77.2 12.3 150+150 1:1 76.3 13.5 90.4 79.5 10.9 75+300 1:4 55.2 24.8 78.6 66.3 12.3 7 5+ 600 1:8 55.2 66.5 95.7 85.0 10.7 100 Table 71 Control effects of A1 or isoproturon alone and a combination thereof on Alopecurus japonicus Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 48.1 2.5 62.3 49.4 12.9 150+150 1:1 48.1 11.4 67.2 54.0 13.2 75+300 1:4 25.6 56.5 82.2 67.6 14.6 7 5+ 600 1:8 25.6 75.9 96.1 82.1 14.0 Table 72 Control effects of A1 or chlorotoluron alone and a combination thereof on Alopecurus japonicus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 48.1 2.9 60.5 49.6 10.9 150+150 1:1 48.1 13.1 66.7 54.9 11.8 75+300 1:4 25.6 39.8 69.6 55.2 14.3 7 5+ 600 1:8 25.6 71.9 91.9 79.1 12.7 Table 73 Control effects of A1 or diuron alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 76.3 3.0 87.9 77.0 10.9 150+150 1:1 76.3 16.5 93.3 80.2 13.1 75+300 1:4 55.2 28.6 79.2 68.0 11.2 7 5+ 600 1:8 55.2 52.2 90.9 78.6 12.3 Table 74 Control effects of A1 or bentazone alone and a combination thereof on Abutilon theophrasti Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 6 7.5+ 150 1:20 44.3 69.1 94.7 82.8 11.9 Table 75 Control effects of A1 or bromoxynil alone and a combination thereof on Chenopodium album Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+18.75 8:1 55.6 3.1 67.5 57.0 10.5 150+37.5 4:1 55.6 10.8 72.1 60.4 11.7 75+75 1:1 23.1 57.7 81.5 67 .5 14.0 75+ 150 1:2 23.1 83.6 99.7 87.4 12.3 Table 76 Control effects of A1 or propanil alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 76.3 3.8 88.8 77.2 11.6 150+150 1:1 76.3 21.1 94.4 81.3 13.1 75+300 1:4 55.2 36.4 82.3 71.5 10.8 75+ 600 1:8 55.2 52.5 90.4 78.7 11.7 102 Table 77 Control effects of A1 or huanbifucaotong alone and a combination thereof on Alopecuros japonicus Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 3 75+ 150 1:2 25.6 81.3 98.1 86.1 12.0 Table 78 Control effects of A1 or shuangzuocaotong alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 6 15+ 15 1:1 36.2 80.3 98.1 87.4 10.7 Table 79 Control effects of A1 or benzuofucaotong alone and a combination thereof on Eleusine indica Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 52.2 2.9 64.6 53.6 11.0 150+15 10:1 52.2 10.9 73.6 57.4 16.2 75+30 5:2 24.4 38.6 67.5 53.6 13.9 75+ 60 5:4 24.4 79.1 95.6 84.2 11.4 αποηηη / ζζηζ / Β / γίΛΐ 103 Table 80 Control effects of A1 or sanzuohuangcaotong alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 9 75+ 150 1:2 55.2 74.3 98.6 88.5 10.1 Table 81 Control effects of A1 or tefuryltrione alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 76.3 6.8 89.7 77.9 11.8 150+15 10:1 76.3 13.1 91.4 79.4 12.0 75+30 5:2 55.2 41.3 86.8 73.7 13.1 75+ 60 5:4 55.2 65.4 96.6 84.5 12.1 Table 82 Control effects of A1 or mesotrione alone and a combination thereof on Eleusine indica Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+15 10:1 52.2 4.0 64.8 54.1 10.7 150+30 5:1 52.2 10.9 71.1 57.4 13.7 75+60 5:4 24.4 36.9 65.0 52.3 12.7 75 + 120 5:8 24.4 75.0 93.5 81.1 12.4 104 Table 83 Control effects of A1 or tembotrione alone and a combination thereof on Eleusine indica Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 4 75+ 30 5:2 24.4 73.1 91.5 79.7 11.8 Table 84 Control effects of A1 or topramezone alone and a combination thereof on Setaria glauca Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 60+1.875 32:1 57.6 7.3 72.5 60.7 11.8 60+3.75 16:1 57.6 10.6 76.3 62.1 14.2 30+7.5 4:1 34.7 35.8 71.1 58.1 13 .0 30+ 15 2:1 34.7 72.3 94.3 81.9 12.4 Table 85 Control effects of A1 or isoxaflutole alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 76.3 2.1 89.8 76.8 13.0 150+15 10:1 76.3 14.3 94.7 79.7 15.0 75+30 5:2 55.2 47.9 89.4 76.7 12.7 75+ 60 5:4 55.2 63.6 94.7 83.7 11.0 105 Table 86 Control effects of A1 or benzobicylon alone and a combination thereof on Echinochloa caudate Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+37.5 4:1 76.3 2.1 90.5 76.8 13.7 150+75 2:1 76.3 11.7 92.0 79.1 12.9 75+150 1:2 55.2 43.3 86.6 74.6 12.0 75+ 300 1:4 55.2 54.4 91.5 79.6 12.0 Table 87 Control effects of A1 or diflufenican alone and a combination thereof on Persian Veronica2 Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+15 10:1 42.4 2.3 55.7 43.7 12.0 150+30 5:1 42.4 10.2 63.3 48.3 15.0 75+60 5:4 19.6 40.3 66.3 52.0 14.3 75 + 120 5:8 19.6 76.2 93.8 80.9 12.9 Table 88 Control effects of A1 or flurochloridone alone and a combination thereof on Persian Veronica2 Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 42.4 2.1 56.4 43.6 12.8 150+150 1:1 42.4 12.3 63.4 49.5 13.9 75+300 1:4 19.6 44.5 71.7 55.4 16.3 7 5+ 600 1:8 19.6 79.6 97.7 83.6 14.1 106 Table 89 Control effects of A1 or clomazone alone and a combination thereof on Echinochloa caudate Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+45 10:3 76.3 8.6 89.6 78.3 11.3 150+90 5:3 76.3 19.0 93.5 80.8 12.7 75+180 5:12 55.2 47.7 89.1 76.6 12.5 75+ 360 5:24 55.2 70.1 99.8 86.6 13.2 Table 90 Control effects of A1 or carfentrazone-ethyl alone and a combination thereof on Veronica persica2 Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+1.875 80:1 42.4 2.6 56.3 43.9 12.4 150+3.75 40:1 42.4 11.6 62.4 49.1 13.3 75+7.5 10:1 19.6 36.2 62. 9 48.7 14.2 75+ 15 5:1 19.6 68.2 87.6 74.4 13.2 Table 91 Control effects of A1 or fomesafen alone and a combination thereof on Chenopodium album Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+22.5 20:3 55.6 2.7 67.0 56.8 10.2 150+45 10:3 55.6 18.6 77.5 63.9 13.6 75+90 5:6 23.1 45.4 73.0 58. 0 15.0 75+ 180 5:12 23.1 81.9 98.8 86.1 12.7 107 Table 92 Control effects of A1 or fluoroglycene alone and a combination thereof on Chenopodium album Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+0.9375 160:1 55.6 2.3 68.7 56.6 12.1 150+1.875 80:1 55.6 12.8 73.4 61.3 12.1 75+3.75 20:1 23.1 40.0 67.9 53.9 14.0 75+ 7.5 10:1 23.1 70.6 90.3 77.4 12.9 Table 93 Control effects of A1 or oxyfluorfen alone and a combination thereof on Chenopodium album Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 55.6 3.6 67.8 57.2 10.6 150+15 10:1 55.6 11.9 71.9 60.9 11.0 75+30 5:2 23.1 30.7 59.9 46.7 13.2 75+ 60 5:4 23.1 68.1 87.6 75.5 12.1 Table 94 Control effects of A1 or lactofen alone and a combination thereof on Chenopodium album Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 55.6 3.3 67.8 57.1 10.7 150+15 10:1 55.6 10.4 73.6 60.2 13.4 75+30 5:2 23.1 39.7 66.1 53.6 12.5 75+ 60 5:4 23.1 65.4 84.3 73.4 10.9 108 Qfronnn / zznz / E / YiAi Table 95 Control effects of A1 or acifluorfen sodium alone and a combination thereof on Chenopodium album Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+37.5 4:1 55.6 2.0 67.8 56.5 11.3 150+75 2:1 55.6 13.7 72.2 61.7 10.5 75+150 1:2 23.1 45.0 71.2 57.7 13.5 75+ 300 1:4 23.1 81.0 96.0 85.4 10.6 Table 96 Control effects of A1 or flumioxazine alone and a combination thereof on Chenopodium album Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 55.6 3.4 69.9 57.1 12.8 150+15 10:1 55.6 12.8 74.4 61.3 13.1 75+30 5:2 23.1 37.3 64.2 51.8 12.4 75+ 60 5:4 23.1 78.8 94.9 83.7 11.2 Table 97 Control effects of A1 or sulfentrazone alone and a combination thereof on Echinochloa caudate Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+1.875 80:1 76.3 6.6 89.2 77.9 11.4 150+3.75 40:1 76.3 10.8 92.6 78.9 13.8 75+7.5 10:1 55.2 24.5 79.1 66.2 12.9 75+ 15 5:1 55.2 52.6 90.4 78.8 11.6 109 Qfronnn / zznz / E / YiAi Table 98 Control effects of A1 or saflufenacil alone and a combination thereof on Ipomoea purpurea Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 5 75+ 30 5:2 37.7 75.9 97.8 85.0 12.8 Table 99 Control effects of A1 or oxadiazon alone and a combination thereof on Echinochloa caudate (soil sealing treatment) Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+37.5 4:1 47.2 6.0 62.2 50.4 11.9 150+75 2:1 47.2 22.1 71.4 58.9 12.6 75+150 1:2 23.4 39.5 66.6 53.7 12.9 75+ 300 1:4 23.4 63.0 85.4 71.7 13.7 Table 100 Control effects of A1 or oxadiargyl alone and a combination thereof on Echinochloa caudate (soil sealing treatment) Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 47.2 1.7 58.7 48.1 10.6 150+15 10:1 47.2 10.8 63.3 52.9 10.4 75+30 5:2 23.4 37.2 64.4 51.9 12.5 75+ 60 5:4 23.4 62.5 83.0 71.3 11.7 110 Table 101 Control effects of A4 or penoxsulam alone and a combination thereof on Echinochloa oryzoides Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 3 12.5 75+ 15 5:1 52.6 68.4 98.7 85.0 13.7 Table 102 Control effects of A4 or bispyribac sodium alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 5 11.7 75+ 15 5:1 52.6 62.0 94.3 82.0 12.3 Table 103 Control effects of A3 or pyrazosulfuron-ethyl alone and a combination thereof on Ammannia arenaria Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-E0 (%) 150+1.875 80:1 66.2 16.3 82.7 71.7 11.0 150+3.75 40:1 66.2 26.1 86.4 75.0 11.4 75+7.5 10:1 30.4 52.8 79.6 67 .1 12.5 75+ 15 5:1 30.4 77.2 95.4 84.1 11.3 Table 104 Control effects of A4 or nicosulfuron alone and a combination thereof on Echinochloa oryzoides Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 4 75+ 30 5:2 52.6 62.4 94.3 82.2 12.1 Table 105 Control effects of A3 or florasulam alone and a combination thereof on Stellaria media Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 15+0.375 40:1 67.9 6.8 82.3 70.1 12.3 15+0.75 20:1 67.9 22.3 87.9 75.1 12.9 7.5+1.5 5:1 34.1 56.9 86.1 71.6 1 4.6 7.5+ 3.0 5:2 34.1 76.6 97.9 84.6 13.4 Table 106 Control effects of A4 or rimsulfuron alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 3 14.7 75+ 15 5:1 52.6 69.6 98.1 85.6 12.5 112 Table 107 Control effects of A4 or imazethapyr alone and a combination thereof on Echinochloa oryzoides Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 74.7 6.7 86.8 76.4 10.4 150+15 10:1 74.7 17.8 92.7 79.2 13.5 75+30 5:2 52.6 34.6 83.1 69.0 14.1 75+ 60 5:4 52.6 58.2 93.0 80.2 12.8 Table 108 Control effects of A4 or imazapic alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+9.375 16:1 74.7 4.0 87.0 75.7 11.3 150+18.75 8:1 74.7 21.3 92.1 80.1 12.0 75+37.5 2:1 52.6 30.4 82.4 67.0 15.4 75+ 75 1:1 52.6 59.7 93.4 80.9 12.5 Table 109 Control effects of A4 or imazamox alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 4 75+ 30 5:2 52.6 54.4 91.2 78.4 12.8 Table 110 Control effects of A4 or sulfometuron-methyl alone and a combination thereof on Echinochloa oryzoides αποηηη / ζζηζ / Β / γίΛΐ Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+9.375 16:1 74.7 3.2 85.9 75.5 10.4 150+18.75 8:1 74.7 12.6 92.7 77.9 14.8 75+37.5 2:1 52.6 38.0 84.1 70.6 13.5 75+ 75 1:1 52.6 53.8 90.8 78.1 12.7 Table 111 Control effects of A3 or chloransulam-methyl alone and a combination thereof on Cirsium setosum Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 60+1.875 32:1 64.3 13.6 80.8 69.1 11.6 60+3.75 16:1 64.3 23.1 86.5 72.5 13.9 30+7.5 4:1 31.5 53.8 81.9 68.3 1 3.5 30+ 15 2:1 31.5 71.9 93.0 80.7 12.2 Table 112 Control effects of A4 or cyhalofop-butyl alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+9.375 16:1 74.7 5.5 87.5 76.1 11.4 150+18.75 8:1 74.7 15.0 89.7 78.5 11.2 75+37.5 2:1 52.6 32.1 81.5 67.8 13.7 75+ 75 1:1 52.6 63.5 97.9 82.7 15.2 αποηηη / ζζηζ / Β / γίΛΐ Table 113 Control effects of A3 or clodinafop-propargyl alone and a combination thereof on Beckmannia syzigachne Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+3.75 40:1 42.8 10.3 60.7 48.7 12.0 150+7.5 20:1 42.8 20.1 67.8 54.3 13.5 75+15 5:1 23.0 59.6 83.0 68.9 14 .1 75+ 30 5:2 23.0 81.2 97.9 85.5 12.4 Table 114 Control effects of A3 or pinoxaden alone and a combination thereof on Beckmannia syzigachne Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 0 75+ 30 5:2 23.0 72.6 91.7 78.9 12.8 Table 115 Control effects of A4 or clethodim alone and a combination thereof on Eychinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 74.7 6.7 88.0 76.4 11.6 150+15 10:1 74.7 19.0 92.4 79.5 12.9 75+30 5:2 52.6 37.8 85.6 70.5 15.1 75+ 60 5:4 52.6 62.7 96.0 82.3 13.7 αποηηη / ζζηζ / Β / γίΛΐ Table 116 Control effects of A4 or sethoxydim alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (7th) 150+15 10:1 74.7 5.5 87.8 76.1 11.7 150+30 5:1 74.7 13.8 93.0 78.2 14.8 75+60 5:4 52.6 35.4 87.7 69.4 18.3 75+ 120 5:8 52.6 68.4 97.4 85.0 12.4 Table 117 Control effects of A4 or quizalofop-P-methyl alone and a combination of the same in Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding dose Control effect (7o) of B applied only at the corresponding dose Effect control of A+B (7th), E EO (7th) E-EO (7th) 150+3.75 40:1 74.7 5.9 86.3 76.2 10.1 150+7.5 20:1 74.7 14.6 88.7 78.4 10.3 75+15 5:1 52.6 38.6 86.2 70.9 15.3 75+30 5:2 52.6 63.3 95.4 82.6 12.8 Table 118 Control effects of A4 or fIuazifop-P-butyl Io alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+3.75 40:1 74.7 5.5 87.6 76.1 11.5 150+7.5 20:1 74.7 14.2 90.3 78.3 12.0 75+15 5:1 52.6 32.9 85.0 68 .2 16.8 75+ 30 5:2 52.6 71.5 97.1 86.5 10.6 Table 119 Control effects of A4 or haloxyfop-P-methyl alone and a combination thereof on Echinochloa oryzoides Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (7th) 150+3.75 40:1 74.7 7.9 88.0 76.7 11.3 150+7.5 20:1 74.7 19.0 92.0 79.5 12.5 75+15 5:1 52.6 30.4 86.1 67.0 1 9.1 75+ 30 5:2 52.6 66.9 97.8 84.3 13.5 Table 120 Control effects of A4 or atrazine alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 74.7 6.7 87.4 76.4 11.0 150+150 1:1 74.7 21.7 91.3 80.2 11.1 75+300 1:4 52.6 26.4 75.4 65.1 10.3 75+ 600 1:8 52.6 61.8 92.7 81.9 10.8 Table 121 Control effects of A3 or isoproturon alone and a combination thereof on Beckmannia syzigachne Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 42.8 7.0 59.0 46.8 12.2 150+150 1:1 42.8 15.9 64.3 51.9 12.4 75+300 1:4 23.0 57.6 81.5 67.3 14.2 75+ 600 1:8 23.0 76.6 94.9 82.0 12.9 117 Table 122 Control effects of A3 or chlorotoluron alone and a combination thereof on Beckmannia syzigachne Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 42.8 5.5 56.1 45.9 10.2 150+150 1:1 42.8 16.8 63.5 52.4 11.1 75+300 1:4 23.0 41.1 68.1 54.6 13.5 7 5+ 600 1:8 23.0 72.1 90.8 78.5 12.3 Table 123 Control effects of A4 or diuron alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 74.7 4.1 86.3 75.7 10.6 150+150 1:1 74.7 14.0 90.8 78.2 12.6 75+300 1:4 52.6 31.3 78.7 67.4 11.3 7 5+ 600 1:8 52.6 56.2 91.1 79.2 11.9 Table 124 Control effects of A3 or bentazone alone and a combination thereof on Xanthium strumarium Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 15+18.75 4:5 77.2 10.9 91.4 79.7 11.7 15+37.5 2:5 77.2 16.1 93.4 80.9 12.5 7.5+75 01:10 a.m. 40.8 46.6 82.5 68.4 14.1 7.5+150 01:20 a.m. 40.8 76.5 98.9 86.1 12.8 118 Qfronnn / zznz / E / YiAi Table 125 Control effects of A3 or bromoxynil alone and a combination thereof on Acalypha australis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 0 75+ 150 1:2 20.7 84.0 99.9 87.3 12.5 Table 126 Control effects of A4 or propanil alone and a combination of the same in Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 74.7 7.6 88.5 76.6 11.9 150+150 1:1 74.7 19.9 93.0 79.7 13.3 75+300 1:4 52.6 37.0 81.7 70.1 11.6 75+600 1:8 52.6 53.9 89.8 78.1 11.7 Table 127 Control effects of A3 or huanbifucaotong alone and a combination thereof on Beckmannia syzigachne Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 6 75+ 150 1:2 23.0 81.8 97.2 86.0 11.2 Table 128 Control effects of A3 or shuangzuocaotong alone and a combination of these on Sinapis arvensis αίτοηηη / ζζηζ / Ε / γίΛΐ Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 6 15+ 15 1:1 33.2 83.7 99.8 89.1 10.7 Table 129 Control effects of A3 or benzuofucaotong alone and a combination thereof on Chloris virgata Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 48.3 5.5 62.2 51.2 11.0 150+15 10:1 48.3 14.8 72.1 56.0 16.1 75+30 5:2 22.0 39.9 67.0 53.2 13.8 75+ 60 5:4 22.0 79.2 95.2 83.8 11.4 Table 130 Control effects of A4 or sanzuohuangcaotong alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 9 75+ 150 1:2 52.6 75.2 98.6 88.3 10.4 120 Table 131 Control effects of A4 or tefuryltrione alone and a combination thereof on Echinochloa oryzoides Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 74.7 8.9 88.9 77.0 12.0 150+15 10:1 74.7 18.8 91.3 79.5 11.9 75+30 5:2 52.6 46.1 86.5 74.5 12.1 75+ 60 5:4 52.6 69.3 97.3 85.5 11.9 Table 132 Control effects of A3 or mesotrione alone and a combination thereof on Chloris virgata Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+15 10:1 48.3 6.5 62.4 51.7 10.7 150+30 5:1 48.3 13.4 69.0 55.3 13.7 75+60 5:4 22.0 38.3 64.5 51.9 12.6 75 + 120 5:8 22.0 75.2 93.0 80.7 12.3 Table 133 Control effects of A3 or tembotrione alone and a combination thereof on Chloris virgata Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 4 75+ 30 5:2 22.0 73.4 91.0 79.3 11.7 Table 134 Control effects of A3 or topramezone alone and a combination thereof on Setaria faberi Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 60+1.875 32:1 55.4 3.2 69.2 56.8 12.4 60+3.75 16:1 55.4 11.7 74.4 60.6 13.8 30+7.5 4:1 32.5 36.5 71.8 57.1 14 .7 30+ 15 2:1 32.5 75.4 95.0 83.4 11.6 Table 135 Control effects of A4 or isoxaflutole alone and a combination thereof on Eyinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 74.7 8.1 89.3 76.8 12.6 150+15 10:1 74.7 19.6 94.2 79.7 14.6 75+30 5:2 52.6 50.6 88.9 76.6 12.3 75+ 60 5:4 52.6 65.5 94.2 83.7 10.6 Table 136 Control effects of A4 or benzobicylon alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+37.5 4:1 74.7 9.3 89.9 77.1 12.9 150+75 2:1 74.7 18.0 91.5 79.3 12.3 75+150 1:2 52.6 46.6 86.2 74.7 11.5 75+ 300 1:4 52.6 57.3 91.0 79.8 11.3 122 Table 137 Control effects of A3 or diflufenican alone and a combination thereof on Solanum nigrum Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+15 10:1 37.5 6.0 52.9 41.3 11.6 150+30 5:1 37.5 15.0 61.5 46.9 14.6 75+60 5:4 16.9 41.7 65.5 51.6 13.9 75 + 120 5:8 16.9 76.5 93.0 80.5 12.5 Table 138 Control effects of A3 or flurochloridone alone and a combination thereof on Solanum nigrum Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 37.5 5.5 53.4 41.0 12.4 150+150 1:1 37.5 13.7 59.6 46.1 13.5 75+300 1:4 16.9 45.8 70.9 55.0 15.9 7 5+ 600 1:8 16.9 79.7 96.9 83.2 13.7 Table 139 Control effects of A4 or clomazone alone and a combination thereof on Echinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+45 10:3 74.7 8.6 89.1 76.9 12.3 150+90 5:3 74.7 12.9 89.9 78.0 12.0 75+180 5:12 52.6 50.9 88.6 76.7 11.9 75+ 360 05:24 a.m. 52.6 72.1 99.4 86.8 12.7 123 Qfronnn / zznz / E / YiAi Table 140 Control effects of A3 or carfentrazone-ethyl alone and a combination thereof on Solanum nigrum Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+1.875 80:1 37.5 6.3 53.5 41.5 12.0 150+3.75 40:1 37.5 12.1 58.0 45.1 12.9 75+7.5 10:1 16.9 38.0 62.1 48.5 13.6 75+ 15 5:1 16.9 68.7 86.8 74.0 12.8 Table 141 Control effects of A3 or fomesafen alone and a combination thereof on Acalypha australis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+22.5 20:3 51.6 6.4 65.2 54.7 10.4 150+45 10:3 51.6 12.6 71.5 57.7 13.7 75+90 5:6 20.7 46.9 72.9 57.9 14.9 75+ 180 5:12 20.7 82.4 98.8 86.0 12.7 Table 142 Control effects of A3 or fluoroglycene alone and a combination thereof on Acalypha australis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+0.9375 160:1 51.6 4.0 65.7 53.5 12.1 150+1.875 80:1 51.6 15.7 71.6 59.2 12.3 75+3.75 20:1 20.7 41.6 67.9 53.7 14.1 75+ 7.5 10:1 20.7 71.4 90.2 77.3 12.8 124 Table 143 Control effects of A3 or oxyfluorfen alone and a combination of the same in Acalypha australis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 51.6 4.6 64.4 53.8 10.5 150+15 10:1 51.6 12.4 68.7 57.6 11.0 75+30 5:2 20.7 32.7 60.1 46.6 13.4 75+60 5:4 20.7 68.9 87.6 75.3 12.2 Qfronnn / zznz / E / YiAi Table 144 Control effects of A3 or lactofen alone and a combination of the same in Acalypha australis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 51.6 2.7 63.8 52.9 10.8 150+15 10:1 51.6 13.5 71.5 58.1 13.3 75+30 5:2 20.7 41.4 66.1 53.5 12.5 75+60 5:4 20.7 66.4 84.5 73.3 11.1 Table 145 Control effects of A3 or acifluorfen sodium alone and a combination thereof on Acalypha australis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+37.5 4:1 51.6 5.8 66.0 54.4 11.5 150+75 2:1 51.6 11.6 67.9 57.2 10.6 75+150 1:2 20.7 46.6 71.1 57.6 13.4 75+ 300 1:4 20.7 85.3 99.0 88.3 10.6 125 Table 146 Control effects of A3 or flumioxazine alone and a combination thereof on Acalypha australis αποηηη / ζζηζ / Β / γίΛΐ Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 5 75+ 60 5:4 20.7 79.3 94.8 83.6 11.1 Table 147 Control effects of A4 or sulfentrazone alone and a combination thereof on Eychinochloa oryzoides Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+1.875 80:1 74.7 5.8 86.8 76.2 10.7 150+3.75 40:1 74.7 18.1 92.1 79.3 12.9 75+7.5 10:1 52.6 29.7 78. 5 66.7 11.9 75+ 15 5:1 52.6 56.1 89.9 79.2 10.8 Table 148 Control effects of A3 or saflufenacil alone and a combination thereof on Sonchus oleraceas L. Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+3.75 40:1 55.5 5.4 70.6 57.9 12.7 150+7.5 20:1 55.5 13.9 75.3 61.7 13.6 75+15 5:1 33.8 40.9 75.5 60 .9 14.6 75+ 30 5:2 33.8 76.6 98.1 84.5 13.6 126 Qfronnn / zznz / E / YiAi Table 149 Control effects of A4 or oxadiazon alone and a combination thereof on Echinochloa oryzoides (soil sealing treatment) Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+37.5 4:1 42.5 5.1 56.8 45.4 11.4 150+75 2:1 42.5 10.3 60.3 48.4 11.9 75+150 1:2 18.9 39.7 63.2 51.1 12.1 75+ 300 1:4 18.9 50.8 73.2 60.1 13.1 Table 150 Control effects of A4 or oxadiargyl alone and a combination thereof on Echinochloa oryzoides (soil sealing treatment) Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+7.5 20:1 42.5 2.6 54.2 44.0 10.2 150+15 10:1 42.5 12.7 59.9 49.8 10.1 75+30 5:2 18.9 41.6 64.7 52.6 12.1 75+ 60 5:4 18.9 63.3 81.4 70.2 11.2 Table 151 Control effects of A172 or glyphosate alone and a combination thereof on Digitada sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 38.9 12.3 62.1 46.4 15.7 150+150 1:1 38.9 24.6 73.9 53.9 20.0 75+300 1:4 21.2 43.5 78.1 55.5 22.7 75+ 600 1:8 21.2 76.4 93.1 81.4 11.7 127 Qfronnn / zznz / E / YiAi Table 152 Control effects of A172 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 47.9 2.1 65.2 49.0 16.2 150+150 1:1 47.9 8.7 72.3 52.4 19.9 75+300 1:4 22.4 15.3 53.7 34.3 19.4 75 + 600 1:8 22.4 34.5 74.2 49.2 25.0 Table 153 Control effects of A67 or glyphosate alone and a combination thereof on Digitaria sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 62.2 12.3 82.4 66.8 15.6 150+150 1:1 62.2 24.6 93.3 71.5 21.8 75+300 1:4 23.4 43.5 78.1 56.7 21.4 75+ 600 1:8 23.4 76.4 95.9 81.9 14.0 Table 154 Control effects of A67 or glyphosate alone and a combination thereof on Eleusine indica Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 75.3 6.9 88.7 77.0 11.7 150+150 1:1 75.3 13.6 92.3 78.7 13.6 75+300 1:4 42.5 21.3 71.4 54.7 16.7 7 5+ 600 1:8 42.5 68.9 93.9 82.1 11.8 128 Qfronnn / zznz / E / YiAi Table 155 Control effects of A67 or glyphosate alone and a combination thereof on Sinapis arvensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 72.8 2.5 86.2 73.5 12.7 150+150 1:1 72.8 9.4 90.9 75.4 15.5 75+300 1:4 45.7 19.8 73.6 56.5 17.1 75 + 600 1:8 45.7 37.2 85.2 65.9 19.3 Table 156 Control effects of A67 or glyphosate alone and a combination thereof on Alopecurus japonicus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 52.4 7.6 71.3 56.0 15.3 150+150 1:1 52.4 19.5 75.4 61.7 13.7 75+300 1:4 28.7 30.8 65.5 50.7 14.8 7 5+ 600 1:8 28.7 66.9 89.4 76.4 13.0 Table 157 Control effects of A67 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 75.6 2.1 87.4 76.1 11.3 150+150 1:1 75.6 8.7 91.6 77.7 13.9 75+300 1:4 51.4 15.3 83.2 58.8 24.4 75 + 600 1:8 51.4 34.5 90.3 68.2 22.1 129 Qfronnn / zznz / E / YiAi Table 158 Control effects of A67 or glufosinate ammonium alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 63.9 10.2 82.6 67.6 15.0 150+150 1:1 63.9 19.6 89.4 71.0 18.4 75+300 1:4 31.7 28.6 83.7 51.2 32.5 75+ 600 1:8 31.7 54.1 92.3 68.7 23.6 Table 159 Control effects of A67 or paraquat dichloride alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 65.6 3.2 78.4 66.7 11.7 150+150 1:1 65.6 17.2 85.1 71.5 13.6 75+300 1:4 45.9 47.9 84.9 71.8 13.1 7 5+ 600 1:8 45.9 75.2 97.6 86.6 11.0 Table 160 Control effects of A67 or diquat dibromide monohydrate alone and a combination thereof on Veronica didyma Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 43.1 5.5 57.7 46.2 11.5 150+150 1:1 43.1 12.6 73.8 50.3 23.5 75+300 1:4 23.2 41.3 78.3 54.9 23.4 7 5+ 600 1:8 23.2 80.4 95.8 84.9 10.9 130 Table 161 Control effects of A1 or glyphosate alone and a combination thereof on Digitada sanguinalis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 69.1 12.3 85.3 72.9 12.4 150+150 1:1 69.1 24.6 94.6 76.7 17.9 75+300 1:4 25.9 43.5 75.4 58.1 17.3 75+ 600 1:8 25.9 76.4 96.1 82.5 13.6 Table 162 Control effects of A1 or glyphosate alone and a combination thereof on Eleusine indica ggg A:B Control effect (%) of A applied only at the corresponding dose Control effect (%) of B applied only at the corresponding dose Control effect of A+B (%), E E0 (%) E- E0 (%). 8 46.9 68.9 97.9 83.5 14.4 Table 163 Control effects of A1 or glyphosate alone and a combination thereof on Sinapis arvensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 79.9 2.5 93.1 80.4 12.7 150+150 1:1 79.9 9.4 97.3 81.8 15.5 75+300 1:4 50.4 19.8 79.8 60.2 19.6 75 + 600 1:8 50.4 37.2 87.4 68.9 18.5 131 Table 164 Control effects of A1 or glyphosate alone and a combination thereof on Alopecurus japonicus Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 57.6 7.6 79.7 60.8 18.9 150+150 1:1 57.6 19.5 83.8 65.9 17.9 75+300 1:4 31.3 30.8 75.2 52.5 22.7 7 5+ 600 1:8 31.3 66.9 95.1 77.3 17.8 Table 165 Control effects of A1 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 82.4 2.1 95.8 82.8 13.0 150+150 1:1 82.4 8.7 98.7 83.9 14.8 75+300 1:4 56.5 15.3 82.5 63.2 19.3 75 + 600 1:8 56.5 34.5 90.5 71.5 19.0 Table 166 Control effects of A1 or glufosinate ammonium alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 71.7 10.2 91.4 74.6 16.8 150+150 1:1 71.7 19.6 97.2 77.2 20.0 75+300 1:4 35.4 28.6 76.7 53.9 22.8 75+ 600 1:8 35.4 54.1 90.2 70.3 19.9 132 Table 167 Control effects of A4 or glyphosate alone and a combination thereof on Digitaría sanguinalis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 8 75+ 600 1:8 22.2 76.4 94.4 81.6 12.8 Table 168 Control effects of A4 or glyphosate alone and a combination thereof on Eleusine indica Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (7th) E-EO (7th) 150+75 2:1 69.2 6.9 84.1 71.3 12.8 150+150 1:1 69.2 13.6 89.2 73.4 15.8 75+300 1:4 38.5 21.3 69.8 51.6 18 .2 75+ 600 1:8 38.5 68.9 94.9 80.9 14.0 Table 169 Control effects of A4 or glyphosate alone and a combination thereof on Sinapis arvensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 65.9 2.5 82.1 66.8 15.3 150+150 1:1 65.9 9.4 89.3 69.1 20.2 75+300 1:4 41.1 19.8 71.2 52.8 1 8.4 75+ 600 1:8 41.1 37.2 81.2 63.0 18.2 133 Table 170 Control effects of A4 or glyphosate alone and a combination thereof on Alopecurus japonicus Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (7th) E-EO (%) 150+75 2:1 47.2 7.6 67.1 51.2 15.9 150+150 1:1 47.2 19.5 72.3 57.5 14.8 75+300 1:4 24.9 30.8 63.4 48.0 15.4 75+ 600 1:8 24.9 66.9 87.2 75.1 12.1 Table 171 Control effects of A4 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 5 75+ 600 1:8 44.2 34.5 79.2 63.5 15.7 Table 172 Control effects of A4 or glufosinate ammonium alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 57.2 10.2 72.5 61.6 10.9 150+150 1:1 57.2 19.6 82.6 65.6 17.0 75+300 1:4 26.7 28.6 71.4 47.7 23.7 75+ 600 1:8 26.7 54.1 84.7 66.4 18.3 134 Qfronnn / zznz / E / YiAi Table 173 Control effects of A171 or glyphosate alone and a combination thereof on Digitaría sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 31.9 12.3 52.3 40.3 12.0 150+150 1:1 31.9 24.6 64.2 48.7 15.5 75+300 1:4 19.2 43.5 69.2 54.3 14.9 75+ 600 1:8 19.2 76.4 92.3 80.9 11.4 Table 174 Control effects of A171 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 28.9 2.1 42.2 30.4 11.8 150+150 1:1 28.9 8.7 53.2 35.1 18.1 75+300 1:4 12.2 15.3 46.2 25.6 20.6 75 + 600 1:8 12.2 34.5 61.3 42.5 18.8 Table 175 Control effects of A211 or glyphosate alone and a combination thereof on Digitaría sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 68.3 12.3 83.2 72.2 11.0 150+150 1:1 68.3 24.6 90.9 76.1 14.8 75+300 1:4 31.3 43.5 85.2 61.2 24.0 75+ 600 1:8 31.3 76.4 98.7 83.8 14.9 135 Qfronnn / zznz / E / YiAi Table 176 Control effects of A211 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B In 600 1:8 5.8 34.5 61.3 38.3 23.0 Table 177 Control effects of A94 or glyphosate alone and a combination thereof on Digitaria sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 51.7 12.3 72.3 57.6 14.7 150+150 1:1 51.7 24.6 82.5 63.6 18.9 75+300 1:4 23.4 43.5 79.5 56.7 22.8 75+ 600 1:8 23.4 76.4 95.3 81.9 13.4 Table 178 Control effects of A94 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B In 600 1:8 6.2 34.5 52.8 38.6 14.2 136 Qfronnn / zznz / E / YiAi Table 179 Control effects of A173 or glyphosate alone and a combination thereof on Digitaría sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%). 2 75+ 600 1:8 38.2 76.4 95.9 85.4 10.5 Table 180 Control effects of A173 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 52.4 2.1 66.9 53.4 13.5 150+150 1:1 52.4 8.7 76.8 56.5 20.3 75+300 1:4 24.8 15.3 52.5 36.3 1 6.2 75+ 600 1:8 24.8 34.5 67.3 50.7 16.6 Table 181 Control effects of A212 or glyphosate alone and a combination thereof on Digitaría sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 150+75 2:1 24.6 12.3 51.4 33.9 17.5 150+150 1:1 24.6 24.6 62.1 43.1 19.0 75+300 1:4 11.5 43.5 70.4 50.0 20.4 75+ 600 1:8 11.5 76.4 95.3 79.1 16.2 137 αίτοηηη / ζζηζ / Ε / γίΛΐ Table 182 Control effects of A212 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B In 600 1:8 8.6 34.5 61.2 40.1 21.1 Table 183 Control effects of A141 or glyphosate alone and a combination thereof on Digitaria sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 55.8 12.3 76.4 61.2 15.2 150+150 1:1 55.8 24.6 83.1 66.7 16.4 75+300 1:4 27.7 43.5 73.2 59.2 14.0 75+ 600 1:8 27.7 76.4 95.1 82.9 12.2 Table 184 Control effects of A141 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B In 600 1:8 7.8 34.5 54.8 39.6 15.2 138 Qfronnn / zznz / E / YiAi Table 185 Control effects of A163 or glyphosate alone and a combination thereof on Digitaría sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 45.4 12.3 71.2 52.2 19.0 150+150 1:1 45.4 24.6 81.6 58.9 22.7 75+300 1:4 16.6 43.5 74.9 52.9 22.0 75+ 600 1:8 16.6 76.4 95.8 80.3 15.5 Table 186 Control effects of A163 or glyphosate alone and a combination thereof on Eleusine indica Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 56.0 6.9 73.7 59.0 14.7 150+150 1:1 56.0 13.6 86.1 62.0 24.1 75+300 1:4 31.7 21.3 65.0 46.2 18.8 7 5+ 600 1:8 31.7 68.9 91.7 78.8 12.9 Table 187 Control effects of A163 or glyphosate alone and a combination thereof on Sinapis arvensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 47.2 2.5 69.7 48.5 21.2 150+150 1:1 47.2 9.4 77.3 52.1 25.2 75+300 1:4 29.6 19.8 70.4 43.6 26.8 75 + 600 1:8 29.6 37.2 81.1 55.8 25.3 139 αποηηη / ζζηζ / Β / γίΛΐ Table 188 Control effects of A163 or glyphosate alone and a combination thereof on Alopecuros japonicus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 44.0 7.6 61.8 48.3 13.5 150+150 1:1 44.0 19.5 71.8 54.9 16.9 75+300 1:4 24.1 30.8 62.3 47.5 14.8 7 5+ 600 1:8 24.1 66.9 89.3 74.9 14.4 Table 189 Control effects of A163 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 60.5 2.1 73.9 61.3 12.6 150+150 1:1 60.5 8.7 88.0 63.9 24.1 75+300 1:4 41.1 15.3 74.3 50.1 24.2 75 + 600 1:8 41.1 34.5 86.2 61.4 24.8 Table 190 Control effects of A163 or glufosinate ammonium alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 53.7 10.2 70.1 58.4 11.7 150+150 1:1 53.7 19.6 85.8 62.8 23.0 75+300 1:4 26.6 28.6 70.5 47.6 22.9 75+ 600 1:8 26.6 54.1 88.5 66.3 22.2 140 Qfronnn / zznz / E / YiAi Table 191 Control effects of A163 or paraquat dichloride alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 55.8 3.2 75.9 57.2 18.7 150+150 1:1 55.8 17.2 81.5 63.4 18.1 75+300 1:4 39.0 47.9 81.7 68.2 13.5 7 5+ 600 1:8 39.0 75.2 97.5 84.9 12.6 Table 192 Control effects of A163 or diquat dibromide monohydrate alone and a combination thereof on Veronica didyma Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 34.5 5.5 55.2 38.1 17.1 150+150 1:1 34.5 12.6 70.2 42.7 27.5 75+300 1:4 18.6 41.3 75.1 52.2 22.9 7 5+ 600 1:8 18.6 80.4 97.7 84.0 13.7 Table 193 Control effects of A130 or glyphosate alone and a combination thereof on Digitada sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 36.8 12.3 66.3 44.6 21.7 150+150 1:1 36.8 24.6 75.5 52.3 23.2 75+300 1:4 16.7 43.5 72.7 52.9 19.8 75+ 600 1:8 16.7 76.4 93.9 80.3 13.6 141 Qfronnn / zznz / E / YiAi Table 194 Control effects of A130 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B In 600 1:8 5.4 34.5 56.2 38.0 18.2 Table 195 Control effects of A213 or glyphosate alone and a combination thereof on Digitaria sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 31.2 12.3 53.9 39.7 14.2 150+150 1:1 31.2 24.6 67.9 48.1 19.8 75+300 1:4 14.9 43.5 68.2 51.9 16.3 75+ 600 1:8 14.9 76.4 91.3 79.9 11.4 Table 196 Control effects of A213 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 26.8 2.1 43.9 28.3 15.6 150+150 1:1 26.8 8.7 52.8 33.2 19.6 75+300 1:4 14.6 15.3 48.7 27.7 21.0 75 + 600 1:8 14.6 34.5 61.2 44.1 17.1 142 Table 197 Control effects of A214 or glyphosate alone and a combination thereof on Digitaría sanguinalis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 44.6 12.3 63.9 51.4 12.5 150+150 1:1 44.6 24.6 74.7 58.2 16.5 75+300 1:4 21.9 43.5 74.6 55.9 18.7 75+ 600 1:8 21.9 76.4 95.6 81.6 14.0 Table 198 Control effects of A214 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 46.2 2.1 65.8 47.3 18.5 150+150 1:1 46.2 8.7 73.8 50.9 22.9 75+300 1:4 24.8 15.3 68.8 36.3 32.5 75 + 600 1:8 24.8 34.5 72.3 50.7 21.6 Table 199 Control effects of A2 or glyphosate alone and a combination thereof on Digitaría sanguinalis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 51.6 12.3 73.8 57.6 16.2 150+150 1:1 51.6 24.6 87.2 63.5 23.7 75+300 1:4 19.4 43.5 74.7 54.5 20.2 75+ 600 1:8 19.4 76.4 94.5 81.0 13.5 143 Qfronnn / zznz / E / YiAi Table 200 Control effects of A2 or glyphosate alone and a combination thereof on Eleusine indica Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 63.3 6.9 83.2 65.8 17.4 150+150 1:1 63.3 13.6 88.7 68.2 20.5 75+300 1:4 35.7 21.3 68.2 49.4 18.8 7 5+ 600 1:8 35.7 68.9 91.8 80.0 11.8 Table 201 Control effects of A2 or glyphosate alone and a combination thereof on Sinapis an / ensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 60.4 2.5 81.1 61.4 19.7 150+150 1:1 60.4 9.4 88.2 64.1 24.1 75+300 1:4 37.9 19.8 72.5 50.2 22.3 75 + 600 1:8 37.9 37.2 83.3 61.0 22.3 Table 202 Control effects of A2 or glyphosate alone and a combination thereof on Alopecurus japonicus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 44.5 7.6 65.4 48.8 16.6 150+150 1:1 44.5 19.5 73.9 55.4 18.5 75+300 1:4 24.4 30.8 63.6 47.7 15.9 7 5+ 600 1:8 24.4 66.9 89.8 75.0 14.8 144 Qfronnn / zznz / E / YiAi Table 203 Control effects of A2 or glufosinate ammonium alone and a combination thereof on Capsella bursa-pastoris Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 65.0 2.1 79.3 65.8 13.5 150+150 1:1 65.0 8.7 85.9 68.1 17.8 75+300 1:4 44.2 15.3 76.3 52.7 23.6 75 + 600 1:8 44.2 34.5 84.1 63.5 20.6 Table 204 Control effects of A2 or glufosinate ammonium alone and a combination thereof on Amaranthus retroflexus Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 51.8 10.2 69.7 56.7 13.0 150+150 1:1 51.8 19.6 82.5 61.2 21.3 75+300 1:4 25.7 28.6 72.4 46.9 25.5 75+ 600 1:8 25.7 54.1 83.5 65.9 17.6 Table 205 Control effects of A2 or paraquat dichloride alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 54.4 3.2 67.2 55.9 11.3 150+150 1:1 54.4 17.2 78.9 62.3 16.6 75+300 1:4 38.1 47.9 82.2 67.7 14.5 7 5+ 600 1:8 38.1 75.2 98.4 84.6 13.8 Qfronnn / zznz / E / YiAi 145 Table 206 Control effects of A2 or diquat dibromide monohydrate alone and a combination thereof on Veronica didyma Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 150+75 2:1 36.6 5.5 61.7 40.1 21.6 150+150 1:1 36.6 12.6 75.3 44.6 30.7 75+300 1:4 19.7 41.3 79.0 52.9 26.1 7 5+ 600 1:8 19.7 80.4 97.3 84.3 13.0 Table 207 Control effects of A2 or triclopyr alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 60+300 1:5 22.6 78.4 95.1 83.3 11.8 Table 208 Control effects of A2 or MCPA alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 120+75 1.6:1 47.9 18.8 71.3 57.7 13.6 Table 209 Control effects of A2 or dicamba alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E E0 (7th) E-EO (7th) 60+150 1:2.5 22.6 58.7 81.4 68.0 13.4 146 Table 210 Control effects of A2 or picloram alone and a combination thereof on Conyza Canadensis Qfronnn / zznz / E / YiAi Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 120+7.5 16:1 47.9 5.0 60.8 50.5 10.3 60+60 1:1 22.6 69.4 88.4 76.3 12.1 Table 211 Control effects of A2 or aminopyralid alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 120+15 8:1 47.9 19.0 71.2 57.8 13.4 60+30 2:1 22.6 40.7 65.8 54.1 11.7 Table 212 Control effects of A2 or fluroxypyr alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 120+37.5 3.2:1 47.9 5.8 63.4 50.9 12.5 Table 213 Control effects of A2 or florpyrauxifen benzyl alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 120+1.875 64:1 47.9 3.5 59.8 49.7 10.1 60+7.5 8:1 22.6 47.4 73.2 59.3 13.9 147 Qfronnn / zznz / E / YiAi Table 214 Control effects of A2 or halauxifen-methyl alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (%) of B applied only at the corresponding rate Control effect of A+B (%), E E0 (%) E-EO (%) 120+3.75 32:1 47.9 20.5 72.4 58.6 13.8 60+15 4:1 22.6 81.5 99.3 85.7 13.6 ig Table 215 Control effects of A2 or quinclorac alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (%) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 120+30 4:1 47.9 11.7 72.5 54.0 18.5 120+60 2:1 47.9 28.8 82.2 62.9 19.3 60+120 1:2 22.6 53.7 87.4 64.2 23.2 60+ 240 1:4 22.6 76.2 94.7 81.6 13.1 Table 216 Control effects of A2 or clopyralid alone and a combination thereof on Conyza Canadensis Dose of A+B (g a.i. / ha) A:B Control effect (7o) of A applied only at the corresponding rate Control effect (7o) of B applied only at the corresponding rate Control effect of A+B (7th), E EO (7th) E-EO (7th) 120+15 8:1 47.9 6.1 78.3 51.1 27.2 120+30 4:1 47.9 29.8 85.5 63.4 22.1 60+60 1:1 22.6 53.5 86.7 64.0 22 .7 60+ 120 1:2 22.6 82.8 98.6 86.7 11.9 C) Pilot sites Tests in which the herbicidal compositions prepared in the Examples 1) to 150) to control weeds in fields. 148 In 2018, a demonstration popularization trial was carried out at the pilot sites in Qingdao City, Shandong Province. Weeds in the fields mainly included: Digitaría sanguinalis, Eleusine indica, Echinochloa crus-galli, Setaria viridis, Panicum miliaceum L., Amaranthus retroflexus, Acalypha australis, Equisetum arvense, Mollugo pentaphylla L., Juncellus serotinus, etc. Experimental methods: Foliage treatment: At the 3-5 leaf stage of weeds, the agent was sprayed evenly on the stems and leaves through a hand-held sprayer, in which the amount of water added was 30 kg / 667 m2. The specific agents tested and their dosage are shown in Table 217. The pilot site area was 50 square meters, and each treatment was repeated 4 times. The efficiency of weed control after 45 days of application is shown in Table 217. Weed control effect expressed in fresh weight (%) = (fresh weight of control weed - fresh weight of treated weed) / fresh weight of control weed x 100 Table 217 Control effects of the claimed compositions in pilot sites z m IO Dosage (g a.i. / ha) Control effect expressed in fresh weight (%) 1 150 97.8 2 180 95.6 3 210 93.8 4 150 98.3 5 180 95.2 6 210 94.6 7 150 97.5 8 180 96.7 9 210 94 .9 10 180 96.6 11 210 96.7 12 240 94.1 13 124.5 97.1 14 154.5 96.3 15 184.5 94.9 149 z m ΙΟ Dosage (g a.i. / ha) Control effect expressed in fresh weight (%) 16 150 96.3 17 180 97.8 18 210 95.2 19 210 95.4 20 240 97.8 21 270 94.4 22 270 95.9 23 300 97 .4 24 330 95.2 25 180 95.1 26 210 98.9 27 240 95.5 28 270 94.2 29 300 98.9 30 330 94.7 31 150 94.7 32 180 98.5 33 210 95.5 34 270 93.9 35 300 98.3 3 6 330 95.8 37 165 97.5 38 195 95.1 39 225 93.6 40 195 97.6 41 225 94.9 42 255 94.1 43 210 97.3 44 240 95.8 45 270 94.6 46 345 96.1 47 375 96.5 αίτοηηη / ζζηζ / Ε / γίΛΐ 150 z m ΙΟ Dosage (g a.i. / ha) Control effect expressed in fresh weight (%) 48 405 93.4 49 180 96.8 50 210 95.8 51 240 94.7 52 180 95.6 53 210 97.5 54 240 94.7 55 180 95 .1 56 210 97.3 57 240 94.2 58 870 95.2 59 900 97.1 60 930 94.7 61 870 94.9 62 900 97.8 63 930 95.2 64 870 93.7 65 900 98.7 66 930 93.5 67 1020 94.4 68 1050 97.7 69 1080 95.3 70 720 93.2 71 750 97.5 72 780 95.3 73 300 92.7 74 330 96.5 75 360 95.3 76 1620 94.5 77 1650 94.9 78 1680 97.2 79 255 94.1 αίτοηηη / ζζηζ / Ε / γίΛΐ 151 ζ m ΙΟ Dosage (g a.i. / ha) Control effect expressed in fresh weight (%) 80 285 94.8 81 315 96.3 82 150 93.5 83 180 94.5 84 210 96.8 85 255 94.2 86 285 94.7 87 315 ​​96.2 88 300 94.9 89 330 93.2 90 360 98.5 91 210 92.3 92 240 94.1 93 270 96.9 94 270 95.1 95 300 92.5 96 330 96.7 97 210 94.8 98 240 92.2 99 270 9 6.3 100 165 94.2 101 195 93.8 102 225 94.4 103 210 97.9 104 240 95.7 105 270 94.5 106 420 97.1 107 450 93.3 108 480 93.8 109 270 97.2 110 300 93.7 111 330 94.2 αίτοηηη / ζζηζ / Ε / γίΛΐ 152 ζ m ΙΟ Dosage (g a.i. / ha) Control effect expressed in fresh weight (%) 112 870 96.5 113 900 93.8 114 930 92.9 115 570 99.8 116 600 92.6 117 630 92.9 118 150 96.6 119 180 94.3 120 210 92.3 121 495 97.9 122 525 94.6 123 555 96.8 124 135 95.4 125 165 95.8 126 195 97.4 127 300 92.1 128 330 93.5 129 360 96.4 130 240 93.5 131 270 95.4 132 300 96.3 133 570 93.1 134 600 93.2 135 630 99.3 136 210 92.1 137 240 92.7 138 270 95.5 139 480 95.1 140 510 93.6 141 540 98.2 142 480 93.4 143 510 97.9 αίτοηηη / ζζηζ / Ε / γίΛΐ 153 z m IO Dosage (g a.i. / ha) Control effect expressed in fresh weight (%) 144 540 94.6 145 720 91.5 146 750 96.7 147 780 94.9 148 210 93.7 149 240 95.8 150 270 96.3 Qfronnn / zznz / E / YiAi D) Internal evaluation tests The indoor evaluation test was carried out using the herbicide composition produced by A) Example 151-165, and the specific test method was the same as the corresponding part of B) Efficacy Tests. Test weeds: Echinochloa crus-galli, Digitaría sanguinalis, Eleusine indica, Setaria viridis, Panicum miliaceum L., Amaranthus retroflexus, Abutilón theophrasti, Acalypha australis. Test crop (containing glyphosate, 2,4-D resistance trait): SmartStaxTMPro x EnlistTM corn (Event Name MON87427 x MON89034 x TC1507 x MON87411 29 x 59122 x DAS40278), Conkesta Enlist E3TM soybeans (Event Name DAS81419 x ) (DAS44406) . Leaf age in stem and leaf treatments: weeds at the 3-5 leaf stage, corn at the 3-5 leaf stage with one leaf not fully expanded, and soybean at the second to third trilobar stage. The specific test agents, doses, and results of the 20-day post-application studies are shown in Table 218. Weed control effect expressed in fresh weight (%) = (fresh weight of control weed - fresh weight of treated weed) / fresh weight of blank control weed x 100 Table 218: Application of the compound compositions in crops with '0 traits resistant to transgenic herbicides 154 Agents Dosage (g a.i. / ha) Weed control effect expressed in fresh weight (%) Safety of corn Safety of soybeans 151 1125 93.1 safety safety 152 900 96.4 safety safety 153 877.5 97.2 safety safety 154 945 95.2 safety safety 155 1125 94.9 security security 156 900 92.3 security security 157 1125 91.7 security security 158 900 93.9 security security 159 1125 94.6 security security 160 900 92.0 security security 161 900 95.5 security security 162 900 94.2 security security 163 900 91.6 security security 164 900 93.2 security security 165 900 96.0 security security Qfronnn / zznz / E / YiAi After doing extensive experimentation and exploration, the inventors herein have unexpectedly discovered that after using the claimed compositions to control broadleaf weeds such as Ammannia arenaria, Amaranthus retroflexus, Acalypha australis, Solanum nigrum, Eclipta prostrate, Galium aparine L. , Convolvulus arvensis, Conyza Canadensis, Capsella bursa-pastoris, Abutiion theophrasti, Persian speedwell, Malachium aquaticum, Stellaria media, Sinapis arvensis, Ludwigia prostrate, Lindernia procumbens, Sonchus arvensis, Sonchus oleraceus L., Cirsium setosum, Xanthium strumarium, Descunaria sophia, Chenopodíum album, Commelina communis, Ipomoea purpurea, etc.; grass-type weeds such as Alopecurus aequalis, Alopecurus japonicus, Chloris virgata, Echinochloa crus-galli, Echinochloa crusgalli var. zelayensis, Echinochloa oryzoides, Echinochloa caudate, Setaria faberi, Setaria viridis, Setaria glauca, Digitaría sanguinalis, Eleusine indica, Beckmannia syzigachne, Eriochloa villosa, Panicum miliaceum, etc.; and equitecean weeds such as Equisetum arvense, etc., surprising and unexpected synergistic effects are achieved, and the synergistic effects are particularly significant at low doses, thus reducing the application dose as well as environmental pollution, and the rational formulation of compounds leads to reduced agricultural costs and highly effective control of weeds resistant to ALS and ACCase inhibitors. The claimed compositions have a good application prospect. At the same time, it 155 demonstrated through experiments that the claimed compositions exhibit good selectivity and excellent synergistic effects in fields such as wheat fields, corn and rice fields, as well as for crops such as peanuts, sugar cane, sorghum, millet, potatoes, rapeseed. , soybean, cotton, vegetables, Poa annua, tall fescue and Zoysia japonica, and can be grown in herbicidal mixtures that have wide market values.

Claims

1. A herbicidal composition comprising R-pyridyloxycarboxylic acid and derivative, comprising an active ingredient A and an active ingredient B in an effective herbicidal amount, characterized in that the active ingredient A is one or more compounds selected from an R-pyridyloxycarboxylic acid represented by formula I and the salt, its ester derivative, YITX or Rs^NHO 19 1 wherein, Ri, R2 each independently represent halogen, C1-C6 alkyl, C1-C6 haloalkyl or C3-C6 cycloalkyl; R3 represents hydrogen, halogen, C1-C6 alkyl or C1-C6 haloalkyl; Q represents C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, halogen, cyano, amino, nitro, formyl, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkoxycarbonyl, C1-C6 hydroxyalkyl, C1-C6 alkoxy, C1-C6 alkyl, C1-C6 cyanoalkyl, C1-C6 alkylamino, C1-C6 alkyl;phenyl, benzyl, naphthyl, furyl, thienyl, thiazolyl, pyrazolyl, pyridyl or pyrimidinyl that is not substituted or is substituted by at least one group selected from the group consisting of C1-C6 alkyl, cyano, C1-C6 haloalkyl, C1-C6 alkylamino, halogen, C1-C6 alkoxy; AND represents amino, C1-C6 alkylamino, C1-C6 alkylcarbonylamino; or phenylcarbonylamino, benzylamino or furylmethyleneamino that is not substituted or is substituted by at least one group selected from the group consisting of C1-C6 alkyl, halogen, cyano, C1-C6 alkylamino, C1-C6 alkoxy, C1-C6 haloalkyl;25 salt is metal salt, ammonium salt NH4+, primary amine salt RNH2, secondary amine salt (R)2NH, tertiary amine salt (R)sN, quaternary amine salt (R)4N+, polyamine salt, morpholine salt, N-methyl morpholine salt, piperidine salt, pyridine salt, aminopropyl morpholine salt, Jeffamine salt D-230, the salt of 2,4,6-tri(dimethylaminomethyl)phenol and sodium hydroxide, alkylsulfonium salt 01-06, alkylsulfoxonium salt 01-06, alkylphosphonium salt 3 3 01 -06 or alkanolphosphonium salt C1 -06; where, R” represents each independently C1-C16 alkyl that is either unsubstituted or substituted with one or more of the following groups: halogen, hydroxy, alkoxy O1-O6, alkylthio O1-O6, hydroxyalkoxy O1-O6; alkenyl O2-O12, alkynyl O2-O12, cycloalkyl O3-O12; or phenyl or benzyl that is either unsubstituted or substituted with alkyl O1-O6; Qfronnn / zznz / E / YiAi 157 Y Qfronnn / zznz / E / YiAi O the ester is 1 1 , where X represents O or S;5 M represents C1-C18 alkyl, C1-C8 halo alkyl, C3-C6 cycloalkyl that is unsubstituted or substituted with C1-C6 alkyl, C2-C6 alkenyl, C2-C6 halo alkenyl, O2-O6 alkynyl, C1-C6 alkoxy, C1-C6 alkoxycarbonyl, C1-C6 alkylsulfonyl, C1-C6 cyanoalkyl, nitroalkyl O R4NRs •n R4 aa ,.crg 13 C1-C6, C1-C6 alkoxy C1-C6 alkyl, -(C1-C6 alkyl)-Z, R5 , R5 , O ; or phenyl, tetrahydrofuryl, pyridyl, naphthyl, furyl, thienyl, pyrrolyl, pyrazolyl or midazolyl that is unsubstituted or substituted with at least one group selected from the group consisting of C1-C6 alkyl, C1-C6 haloalkyl, cyano, C1-C6 alkylamino, halogen, C1-C6 alkoxy; RxV4 λΑν-r, yr< ¿>y%7 , / y%7 Z represents Rs , Rs , Rs O ,0 ; or phenyl, °x L O , tetrahydrofuryl, pyridyl, pyrazolyl, thienyl, furyl or naphthyl that is unsubstituted or substituted with at least one group selected from the group consisting of C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylamino, C1-C6 haloalkyl, cyano, halogen;FU, Rs, Re each independently represent hydrogen, C1-C6 alkyl, C1-C6 alkoxycarbonyl; or phenyl that is either unsubstituted or substituted with at least one group selected from the group consisting of O1-O6 alkyl, O1-O6 alkoxy, O1-O6 alkylamino, O1-O6 haloalkyl, cyano, halogen; R? represents C1-C6 alkyl, C2-C6 alkenyl or 'n; active ingredient B is selected from the following compounds or acid derivatives or salts or esters thereof, 33 (1) ALS inhibitor selected from: penoxsulam, bispiribac sodium, pyrazosulfuron-ethyl, nicosulfuron, florasulam, rimsulfuron, imazethapyr, imazapic, imazamox, sulfometuron-methyl and chloransulam-methyl; (2) ACCase inhibitor selected from: cyhalofop-butyl, clodinafop-propargyl, pinoxaden, clethodim, sethoxydim, quizalofop-P-methyl, fluazifop-P-butyl and haloxyfop-P-methyl; 35 (3) PSII inhibitor selected from: atrazine, isoproturon, chlorotoluron, diuron, 158 bentazone, bromoxynil and propanil; (4) HPPD inhibitor selected from: huanbifucaotong, shuangzuocaotong, benzuofucaotong, sanzuohuangcaotong, tefuryltrione, mesotrione, tembotrione, topramezone, isoxaflutol and benzobicylon; (5) PDS inhibitor selected from: diflufenican and flurochloridone; (6) DOXP inhibitor: clomazone; (7) PPO inhibitor selected from: carfentrazone-ethyl, fomesafen, fluoroglycophene, oxyfluorfen, lactofen, acifluorfen sodium, flumioxazine, sulfentrazone, saflufenacil, oxadiazone, and oxadiargil; (8) Synthetic hormone inhibitor selected from: triclopyr, MCPA, dicamba, picloram, aminopyralid, fluroxypyr, florpyrauxifen benzyl, halauxifen-methyl, quinclorac and clopyralid; (9) EPSPS inhibitor: glyphosate; (10) GS inhibitor selected from glufosinate ammonium; (11) PSI inhibitor selected from diquat dibromide monohydrate and paraquat dichloride.

2. The herbicidal composition comprising R-pyridyloxycarboxylic acid and derivative according to claim 1, characterized in that: Ri, R2 each independently represent fluorine, chlorine, bromine, iodine, methyl, ethyl, propyl, isopropyl, trifluoromethyl or cyclopropyl; R3 represents hydrogen, fluorine, chlorine, bromine, iodine, methyl or trifluoromethyl; Q represents methyl, ethyl, propyl, isopropyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, cyano, amino, nitro, formyl, methoxy, methylthio, methoxycarbonyl, monochloromethyl, monofluoromethyl, difluoromethyl, trifluoromethyl, 2-chloroethyl, 2,2,2-trifluoroethyl, hydroxymethyl, vFK IO .·\ / ¿YX .... N ' , v O , | , NC \ benzyl, naphthyl, furyl, pyridyl, pyrimidinyl; thiazolyl that is not substituted or is substituted with chlorine; thienyl that is not substituted or is substituted with fluorine; R,z that is not substituted oris substituted with methyl or fluorine; or phenyl that is not substituted or is substituted by at least one group selected from the group consisting of methyl, trifluoromethyl, chlorine, methoxy; 159 salt is sodium salt, lithium salt, potassium salt, cesium salt, rubidium salt, calcium salt, magnesium salt, barium salt, strontium salt, antimony salt, bismuth salt, cadmium salt, cerium salt, chromium salt, cobalt salt, scandium salt, titanium salt, manganese salt, copper salt, iron salt, silver salt, gold salt, salt zinc, aluminum salt, ammonium salt, tetramethylammonium salt, tetraethylammonium salt, tetrapropylammonium salt, tetrabutylammonium salt, N-hexadecyltrimethylamine salt, N-benzyltrimethylammonium salt, benzyltriethylammonium salt, choline amine salt, monomethylamine salt, dimethylamine salt, trimethylamine salt, monoethylamine salt, diethylamine salt, triethylamine salt, salt n-propylamine, salt dipropylamine, tripropylamine salt, salt ofmonoisopropylamine, diisopropylamine sal, triisopropylamine sal, n-butylamine sal, dibutylamine sal, tributylamine sal, isobutylamine sal, tert-butylamine sal, pentylamine sal, hexylamine sal, heptylamine sal, octylamine sal, dodecylamine sal, tetradecylamine sal, dialilamine sal, cyclohexylamine sal, cyclododecylamine sal, aniline sal, o-toluidine sal, m-toluidine sal, p-toluidine sal, dianiline sal, bencylamine sal, monoethanolamine sal, N-methylmonoethanolamine sal, N,N-dimethylethanolamine sal, N-ethylmonoethanolamine sal, N,N-diethylethanolamine sal, N-propyl monoethanolamine, sal de N,N-di-n-propylethanolamine, sal de N-butyl monoethanolamine, sal de diethanolamine, sal de N-methyldiethanolamine, sal de N-ethyldiethanolamine, sal de N-propyldiethanolamine, sal de N-butyldiethanolamine, sal de Ν,Ν-dibutylethanolamine, sal de triethanolamine, sal de tripropanolamina, sal de triisopropanolamina, sal de tri(2-hydroxypropyl)amine, diglycolamine sal, hexamethylenetetramine sal, ethylenediamine sal, diethylenetriamine sal, dimethylaminopropylamine sal, 1,2-propyldiamine sal, triethylenediamine sal, triethylenetetramine sal, bencidine sal, N, N-bis [aminopropyl]methylamine sal, 2-methylthiopropylamine sal, 2-butoxyethylamine sal, AEPD sal, tri(methylol)aminomethane sal, morpholine sal, N-methylmorpholine sal, piperidine sal, pyridine sal, aminopropylmorpholine sal, Jeffamina D-230 sal, 2,4,6-tri(dimethylaminomethyl)phenol e hidróxido de sodio sal, trimethylsulfonio sal or triethylsulfonium; in the formula 1-1, X represents O or S; M represents methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, ¡sobutyl, tere-butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, octadecyl, trifluoromethyl, pentafluoroethyl, 3-chlorobutyl, 2-fluoroethyl, 2-chloroethyl, 2-bromoethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl,4,4,4-trifluorobutyl, 2,2,3,3,3-pentafluoropropyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, allyl, 2-propynyl, methoxy, ethoxycarbonyl, methylsulfonyl, / Qfronnn / zznz / E / YiAi 160 , tetrahydrofuryl, tetrahydrofurylmethylene, pyridyl, pyridylmethylene, naphthyl, naphthylmethylene, furyl, furylmethylene, thienyl, thienylmethylene, is substituted or is substituted with methyl; phenyl that is not substituted or is substituted with methyl, dimethylamino, chloro, methoxy, trifluoromethyl or isopropyl; or benzyl that is not substituted or is substituted with trifluoromethyl, bromo, chloro, fluor, methoxy, cyano or methyl; R' represents hydrogen, methyl, ethyl or difluoromethyl.

3. The herbicidal composition comprising R-pyridyloxycarboxylic acid and derivative according to claim 1 or 2, characterized in that the active ingredient A is one or more compounds selected from, N.s of component A Structure A1 nh2 εκΛγι Jt k A ΌΗ F^N 0 161 N.s of component A Structure A2 nh2 CkA / CI Π F 0 A3A1 sodium salt A4 A1 potassium salt A5 A1 calcium salt A6 A1 lithium salt A7 A1 aluminum salt A8 A1 barium salt A9 A1 magnesium salt A10 A1 copper salt A11 A1 iron salt A12 A1 ammonium salt A13 A1 monomethylamine salt A1 A1 A14 A14 amine salt trimethylamine A16 A1 monoethylamine salt A17 A1 diethylamine salt A18 A1 triethylamine salt A19 A1 ethylenediamine salt A20 A1 triethylene diamine salt A21 A1 monoethanolamine salt A22 A1 diethanolamine salt A23 A1 triethanolamine salt A23 A14 A14 N N-methyldiethanolamine salt A26 A1 N-ethyl monoethanolamine salt A27 A1 N-ethyldiethanolamine salt A28 A1 Ν,Ν-diethyldiethanolamine salt A29 A1 N-propyl monoethanolamine salt A30 A1 N-propyl diethanolamine salt A31 A1 αίτοηηη / ζζηζ / Ε / γίΛΐ 162 N.sde component A Structure A32 A1 salt of N-butyl monoethanolamine A33 A1 salt of N-butyl diethanolamine A34 A1 salt of Ν,Ν-dibutyl ethanol A1 salt A1n-propylamine A36 A1 dipropylamine salt A37 A1 tripropylamine salt A38 A1 n-butylamine salt A39 A1 dibutylamine salt A40 A1 tributylamine salt A41 A1 isobutylamine salt A42 A1 tert-butylamine salt A43 A1 hexylamine salt A14 Aylamine octyl salt A14 aniline salt A46 A1 diphenylamine salt A47 A1 benzidine salt A48 A1 benzylamine salt A49 A1 cyclohexylamine salt A50 A1 monoisopropylamine salt A51 A1 diisopropylamine salt A52 A1 diglycolamine salt A53 A1 hexamethyl salt A55 A1 tetraethylammonium salt A56 A1 tetrapropylammonium salt A57 A1 tetrabutylammonium salt A58 A1 choline amine salt A59 A1 N-benzyltrimethylammonium salt A60 A1 N-hexadecyltrimethylammonium salt A61 A1 pyridine salt A6 A12 Amorphous salt of o-toluidine οίτοηηη / ζζηζ / Ε / γίΛΐ 163 N.sde component A Structure A64 A1 m-toluidine salt A65 A1 p-toluidine salt A66 A1 piperidine salt A67 nh 20 x 20 x N ^ N γ nh2 ci^AoiXXFNOY 0 A69 nh2 ογ λ XXRN ο γ 0 A70 nh2 CI^AoI XXFN 0 YY 0 A71 nh2 CL^ XXFN ο γ 0 A72 nh2 ci.AFX nX0^° X 0 1 A73 nh2 XX FN OW 0 A74 nh2 α,Λγ:1 XX f^n owy 0 A75 nh2 ci\^Xci FX nXo^0^^-^ 0 οίτονην / ζηζ / Ε / γίΛΐ 164 N.sde componente A Estructura A76 nh2 ci ...4 XXFN OWY y 0 1 A77 nh2 οιΑγι XXF^ N οΥγ 0 A78 O Xo 11 · ác ω O o A79 nh2 CI^AoI XXF^N θΥγ η 0 A80 nh2 ΟΙ^ΑόΙ XX ^v.'0 FN Οιγ< 0 A81 nh2 gl^t XXF^N OWY 0 A82 nh2 c|.Aoi XX Ά / °ν F^ N ΟΥΒγ Y 0 A83 nh2 c|^A / Ci XXFN ΟΥ«γ O A84 nh2 CI\vAvCI F Ν^Ο^γ°γ 0 . 165 N.sde componente A Estructura A85 nh2 CI.AFXN^'OO A86 nh2 CI..XFN OW^ 0 I A87 nh2 d., J^ FXNO^ / |^ O A88 nh2 d^Áxii x XF' N OWY 0 A89 nh2 d^X, d XX FN 'OW 0 A90 nh2 CF. JXX 0 A91 nh2 d^ÁOI / XX A^°xXXx^ F^ N XOW 0 A92 nh2 d^ÁOI XXFN OWY O A93 nh2 d^ / Lud XX F^ N OWY 0 166 N.sde componente A Estructura A94 nh2 ci..AFN OW^ 0 A95 nh2 CI^A / C| XXFNO# / O A97 nh2 CI^ A XI^o^ FN 0 y 0 A98 nh2 ci^Aoi F 0 v A99nh2 CI^AoI XXFN OWY 'Y o AJ A100 nh2 Gi^AjD! XX Á / °\XXN OWX A / o AA A101 nh2 G^Ao! XXFN OWy FO A102 nh2 ^^Xa31 11 o F^N^oA / γ '^^'Cl 0 167 N.sde component A Structure A103 nh2 ci .A^CI XXFN OWY Fr 0 n A104 nh2 XX^o A10 Ϊ Ci^zL / Ci JL zX AA AFo FNC^ 3 O A106 nh2 Cl AA / C xx FN 0 γ CF3 0 A107 nh2 CI^A^CI JL yL A. .0 ^CF, FN O-^ γ nVh02 0 A108 / ci\V090 CI\90 yAci = pAA-yaA-0 0 Cl A110 nh2 Ci^JyOi A 0 ΌΝ fn οΑγ 0 A111 nh2 Z' J. / , A ,NOo F^ N OWY 2 0 168 N.sde component A Structure AHX3No AY1 ci X1 NH2 ci XX / F^ N ^OW N 0 1 A114 nh2 ci-AA' i X o ρΛΝΑ(Αγ 0 A115 nh2 CI.. AA ,0 / \ FN 0 γ 0 ° \ 0 A116 oo o4..... O xo A1.1..... c A oo o4. A119 nh2 YX ?f'n'OZ''|OA'O O A120 nh2 CkX / CI Aife Ξ ? nh2 ci-^Vci º Y, IT Ξ II 1 HO A124 γ-Ο where A125 nh2 c|·^ n ^^CF3 11 T Ξ η Γ ιΓ YY.YY Y. γ FN 0 YV ó A126 XY o _.....A ooo A127 nh2 o^Y / 01 O . A128 z \ O o _.....Y oo OJ \-----( >-< o αίτοηηη / ζζηζ / Ε / γίΛΐ 170 N.sde component A Structure A129 _.....roo (M — X \--<-- =4….. o / zr A131 / o _…..^oooo A132 Λ oo oí….. o / A133 -Π θ oo o4….. o / Z ,----< y__ / \ o A134 ιCKfy \ 1 / ^=7 zo _.5 / θ - n ooo A1 FN^O^y°X^OH O nh2 A136 o O m )—~z Q _.....Γ oo fO O 171 N.sde component A Structure A137 AO o A..... od A138 i: O _.....Y ooo A139 nh2 AXFN Ao A1 o Q_.... o AA. ..... A142 _.....A ω o A o A143 nh2 ci\P^ci x X Αχ,οχΧΑΧ F^ N OW>< 0 A144 nh2 CÍ^Ao XX ^ / 0 γζΧ FN n 0W^ O A145 nh2 o CFa 172 N.sde component A Structure A146 nh2 CI^Aoi AA XX o FN ΟΑγ AA cf3 O A147 nh2 CI^ACI ^^CF3 XXA^o^ / XX FN θΑγ Ά <A 0 A148 nh2 Cl Λ / 1 AA X X aaXj F N 0W vAAA 0 F A149 nh2 caJ IJ ¡ o £ 1 F^A'O^ '·Α<Α'τ 0 A150 nh2 cia£^ci XX -Áv°xXX F N OWA '- A^ 0 A151 nh2 ClaA^IN AA 1 T ? o £ ϊ f^nAdAy '^ γ 0 Cl A152 nh2 Cl aaCci aa XX a^o^ / XX F^ N OW \AAA^C| 0 A153 nh2 Cl xx Α^οχζχ FN 0Α)γ '-A ÍA o A154 nh2 Cl a£aci AA XX á^o^Cj F^N OWA \AAA 0 Br αίτοηηηηη / γΐ 173 N.sde component A Structure A155 nh2 CI^JXXFN OW^ O A156 nh2 ci^ XX / '. / °.X 0 A157 nh2 XXA / °XxX FN OW 0 CN A158 nh2 X. 11 ¡h / O^91 F^] Oh^ / Lo! XX ^^°xXX FN OW>r 0 A160 tfí o Q ¿SÍ..... h A161 nh2 GI. / L / CI FX ΝΧοίΑύ^θ^ΧΧ 0 A162 nh2 cl^rcl ΓΝ 0 A.....3 oo αίτοηηη / ζζηζ / Ε / γίΛΐ 174 N.sde component A Structure A164 oo A..... °A ob A165 nh2 Ck Á ,CI W i JA ., / . o / A / F^ N owy 0 A166 nh2 ci XXFN OWA 0 A167 -n — hX oo A..... o X A168 nh2 dyA / 01 rN 11a o^X / 'n- FN oA / 0 A169 nh2 GÍ1^Aoí / AX7]N]Ok'C| .....ár Ó OA o A171 oo A172 nh2 Cl AXX Fx N 0 yx 0 175 N.sde component A Structure A173 nh2 ci , Λ / ι XX / , / °. N 0 γ \ 0 A174 nh2 Br,4 XX / , / 0.., NOY / 0 A175 -n — Xí oo X '' 11 / 75 A176 NH2 XXFN ox y 0 A177 NH2Oí^ / Lo1 XX / / 's, / / .. FN OWY ''^ / ^ 0 A178 NH2 Cl IX fs ρ^^^οAγ A179 nh2 Oí^ / LoI XX F^ N OWY X / XW 0 A180 nh2 ciwX^ci XXF N OWY Y / O 1 A181 nh2 ciwX^ci XXF^N OWY 0 176 N.sde componente A Estructura A182 y- ω Io .....¿ce Ó O 1C· o A183 nh2 ck..JFN 0 γ 0 A184 nh2 Cl TI s F' N' OW A185 nh2 C|^ / C| 11 1 s 1 F' NWÚY 0 A186 nh2 CI^Á / CI 11 FN OWY 0 A187 T °í ω _.....Γ OO o A188 nh2 Ck Á XCI IΙT Ξ ? ΓΟ F^N^cwy 0 A189 nh2 ci ^T^ci iI^s^OFN 0 Y 'V -v 0 A190 nh2 Cl Ilx s 1J F^N OWY αίτονην / ζηζ / Ε / γίΛΐ 177 N.sde componente A Estructura A191 nh2 ci,AXXFN θΑγ O A192 nh2 CI^ AXX / ^θ^ΧΧ FN θΑγ 0 A193 nh2 XX AA-. XFN OWY 0 cf3 A194 nh2 CI^Aoi 1 X 1 s £ 1 fA o# / 0 A195 nh2 0|^Α^,α ^ .cf3 XX A^s^xxr FN οΑγ 0 A196 nh2 Cl 1 T ? s £ ϊ fx n oA) |^ ''^ A 0 F A197 nh2 gi^A^gi XX FN οΑγ 0 A198 nh2 c|^A / Ci XXA^s^Cj FN οΑγ o A199 nh2 XX á^s^xXí F^ N ΟύΑ< 0 Cl αίτονην / ζηζ / Ε / γίΛΐ 178 N.sde componente A Estructura A200 nh2 Cl \^ / Cl ^X, XXFN OW^ O A201 nh2 Cl x^L / CI / A / Cl XX ^^s^XoX AN OW^ - x 0 A202 nh2 Cl .Jx.^ XXA / s^Cj FN OW 0 Br A203 nh2 CI^ A / / 12 ¡ s £ 1 F^ N OÍRl^ 0 A204 nh2 Gí^ / Lo! XX a^ / sXXX FNO# / 0 A205 nh2 Cl 1 T ? s £ ϊ F^ NO^ I^ ''^ γ 0 CN A206 nh2 gi^ / Loi XX x^S^CX F^ N OW>< xx^x^CN 0 A207 nh2 Gi^Á / C! / .CN XX / V / sXX^ Fz N cwy / o A208 nh2 XX a^ / sXx 1 F^ N OW>< N 0 αίτοηηη / ζζηζ / Ε / γίΛΐ 179 N.sdeW0 A20 componente AX9 A E - ω Xo .....¿ce OO o A211 - ω .....4o obo A212 nh2 BrJ^vn 0 T 0 A213 nh2 f ci^F^ci f^X / XX -F°XXX FN OWV —γΈ 0 F A214^ nh2 G XXFN 0 y 0 A215 nh2 gi^ / Fgi | / XX F^ N WK 0 A216 Xí oo Y..... °F A217 nh2 CI^Ao! XX f^ n embb γγ o. F αίτοηηη / ζζηζ / Ε / γίΛΐ 180 N.sde component A Structure A218 cX-^ Xo 11 · GE ó o fQ O A219 nh2 CI^XCI XX OO1 A220 A2 F2N oγ^2 Xo .....ÓX ω oo A222 NX Ci.^ XX Á / °\ FNOO A223 / O _.....Γ / O o O Qfronnn / zznz / E / YiAiClaims 1 to 3, characterized in that the weight ratio between ingredient A and ingredient B is 1:100 ~ 100:1 or 1:50 ~ 50:1, preferably 1:30 ~ 30:1 or 1:20 ~ 20:1, more preferably 1:10 ~ 10:1 or 1:8 ~ 8:1, more preferably also 1:5 ~ 5:1, 1:1 ~ 2:1 or 1:1 ~ 1:

2.

5. The herbicide composition comprising R-pyridyloxycarboxylic acid and derivative according to any one of claims 1 to 4, characterized in that ingredients A and B together represent 1-95% of the total weight of the herbicide composition, preferably 10-80%.

6. The herbicide composition comprising R-pyridyloxycarboxylic acid and a derivative according to any one of claims 1 to 4, characterized in that the herbicide composition further comprises a conventional auxiliary, preferably comprising a carrier and / or a surfactant.

7. The herbicide composition comprising R-pyridyloxycarboxylic acid and a derivative according towith any one of claims 1 to 4, characterized in that the herbicide composition further comprises one or more protectants, preferably said protectant being one or more compounds selected from: isoxadiphen-ethyl, cyprosulfamide, mefenpyr-diethyl, cloquintocet-mexyl, gibberellic acid, furylazole, and methcamyphen.

8. The herbicide composition comprising R-pyridyloxycarboxylic acid and a derivative according to any one of claims 1 to 7, characterized in that the herbicide composition is presented in the form of a formulation selected from: a dispersible oil suspension, a water suspension, a suspoemulsion, a wetting powder, an emulsifiable concentrate, a water-dispersible granule, an aqueous emulsion, and a microemulsion.

9. Use of the herbicide composition comprising R-pyridyloxycarboxylic acid and a derivative according to any one of claims 1 to 7 for controlling a weed; Ideally, the compositionA herbicide is used to selectively control a weed in a useful crop; more preferably, the useful crop is a genetically modified crop or a crop treated by gene-editing technology.

10. A method for controlling unwanted plant growth, comprising applying a herbicide composition comprising R-pyridyloxycardoxylic acid and a derivative according to any one of claims 1 to 7 to plants, parts of plants, plant seeds, or areas of plant cultivation; preferably, the herbicide composition is used to selectively control a weed in a useful crop; more preferably, the useful crop is a genetically modified crop or a crop treated by gene-editing technology.