Method for manufacturing high specific surface area anode string and ECO reactor

Abstract

Disclosed in the present invention are a method for manufacturing a high specific surface area anode string, and an ECO reactor, relating to the technical field of ECO reactors, comprising a string body and cleaning assemblies, a limiting wheel being disposed at an outer middle part of the rope body, and the cleaning assemblies being disposed at left and right ends of the string body. The present invention utilizes an anode string to replace the traditional anode plate, and due to the fluffy three-dimensional structure of the anode rope providing a relatively high specific surface area for the loading of an anodic catalytic coating, in a cross-section of the same width, the fluffy three-dimensional structure of the anode rope has a larger effective reaction surface area than a conventional anode plate, thereby achieving the purposes of improving reaction catalysis efficiency and reducing the cost of the ECO reactor. An original descaling apparatus can periodically clean the surface of the anode rope, achieving the purpose of increasing anodic reaction sites, promoting reaction catalysis efficiency, and extending the service life of the electrocatalytic oxidation reactor.

Description

A method for manufacturing anode rope with large specific surface area and ECO reactor Technical Field

[0001] The present invention relates to the technical field of ECO reactors, in particular to a method for manufacturing an anode rope with a large specific surface area and an ECO reactor. Background Art

[0002] A large amount of organic wastewater is generated during industrial production. With the acceleration of the industrialization process, the types of industrial wastewater emissions are gradually increasing. The organic wastewater generated by the petrochemical, printing and dyeing, papermaking, pharmaceutical and other industries has the characteristics of being difficult to biodegrade, having high chemical oxygen demand and strong toxicity. It is difficult to degrade it quickly and thoroughly using traditional water treatment methods. Electrocatalysis is a green, secondary pollution-free, easy-to-control and efficient water treatment technology. Under the action of an external electric field, organic pollutants undergo direct or indirect redox reactions on the electrode surface or in the water body, realizing the decomposition of organic pollutants and achieving the purpose of water purification.

[0003] In recent years, the development of high-performance anode materials and three-dimensional anode structures has been a hot topic in electrocatalytic oxidation technology research and development. Furthermore, plate scaling, which causes plate aging and short plate lifespan, contributes to high investment and maintenance costs for electrocatalytic reactors, severely limiting the large-scale application of electrocatalytic oxidation technology in wastewater treatment.

[0004] In view of this, to solve the problem of plate aging and insufficient plate life caused by plate scaling, a method for manufacturing anode ropes with large specific surface area and an ECO reactor are proposed. Summary of the Invention

[0005] The present invention aims to provide a method for manufacturing anode ropes with large specific surface areas and an ECO reactor. By replacing traditional anode plates with limited specific surface area with anode ropes with fluffy three-dimensional structures, the goal is to improve reaction catalytic efficiency and reduce the cost of the ECO reactor. A unique descaling device regularly cleans the surface of the anode ropes, increasing the number of anode reaction sites, promoting reaction catalytic efficiency, and extending the service life of the electrocatalytic oxidation reactor. The reciprocating motion of the anode ropes also cleans the cathode plates, effectively removing organic scale from the surface.

[0006] To achieve the above object, the present invention provides the following technical solution: a method for manufacturing an anode rope with a large specific surface area, comprising the following steps:

[0007] S1: After alkali washing and degreasing, a 0.2 mm titanium wire is placed in the acidified carbon gel and soaked for 1 hour, then taken out and dried for later use;

[0008] S2: Soak the anode wire in 15% H2O2 solution, add 4% melamine solution and 5% cyanuric acid solution, heat the solution to 80℃, soak for 12 hours, then take out and dry;

[0009] S3: Place the anode wire in a solution of NiSO4·6H2O:CoSO4·7H2O:MnSO4*7H2O (mass ratio) = 10:5:2, add 5%~10% volume fraction of additives, stir evenly and immerse for 1 hour, place in a drying oven to isolate from air and dry until the surface is completely dry, heat treat at 900~1200℃ for 15 minutes under nitrogen protection, and repeat the immersion, drying and heat treatment 8~10 times.

[0010] S4: The glass fiber rope and the anode wire are braided into a fluffy three-dimensional anode rope with a diameter of 2 cm.

[0011] Furthermore, it includes a rope body and a cleaning component, a limiting wheel is provided on the outer middle part of the rope body, and the cleaning component is provided at the left and right ends of the rope body, and the cleaning component includes a cleaning frame, a cleaning motor, a drive shaft, a take-up wheel, a guide wheel, a brush plate, a waste frame and a filter frame, a cleaning motor is placed on the upper end of one side of the cleaning frame, and one end of the cleaning motor is connected to the drive shaft, and the take-up wheel is sleeved on the outer middle part of the drive shaft, a guide wheel is symmetrically provided at the center of the interior of the cleaning frame, and a brush plate is placed at the lower end of the interior of the cleaning frame, and the brush plate is slidably connected to the rope body, a waste frame is provided at the lower end of one side of the cleaning frame, and a filter frame is placed inside the waste frame.

[0012] Furthermore, a tensioning assembly is disposed inside the take-up wheel, and the tensioning assembly includes a guide rod, a slider, a buffer spring, a rubber ring and a pressure sensor. A guide rod is fixed inside the take-up wheel, and the guide rod is arc-shaped. A slider is sleeved on the outer side of the middle part of the guide rod, and the slider is fixedly connected to the drive shaft. Buffer springs are connected on both sides of the slider, and a rubber ring is disposed inside the slider. A pressure sensor is connected to one side of the buffer spring, and the pressure sensor is fixedly connected to the take-up wheel.

[0013] Furthermore, a debris removal component is provided on the top of the cleaning frame, and the debris removal component includes a cam, a pulley and a telescopic cylinder. One end of the drive shaft is connected to the cam, and one side of the cam is connected to the pulley, and one end of the pulley is provided with a telescopic cylinder.

[0014] Furthermore, the impurity removal component also includes a reset spring, a one-way valve and a connecting pipe. A reset spring is sleeved on the outside of one end of the telescopic cylinder, and a one-way valve is provided on the lower side of the telescopic cylinder. A connecting pipe is placed on one end of the one-way valve, and the connecting pipe is connected to the interior of the waste frame.

[0015] Furthermore, the impurity removal component also includes a one-way valve 2, a diverter pipe and a nozzle. The lower end of the telescopic cylinder is provided with a one-way valve 2, and the end of the one-way valve 2 is connected to the diverter pipe, and a nozzle is provided on one side of the diverter pipe.

[0016] Furthermore, a cooling assembly is provided in the middle of the connecting pipe, and the cooling assembly includes a cooling box, a rotating seat 1, a cooling pipe and a rotating seat 2. The interior of the cooling box is provided with a rotating seat 1, and the interior of the rotating seat 1 is hollow. One side of the rotating seat 1 is connected to the cooling pipe, and a rotating seat 2 is provided at one end of the cooling pipe, and the rotating seat 2 is rotatably connected to the cooling box.

[0017] Furthermore, the cooling assembly also includes a semiconductor refrigeration plate, a heat-conducting fin, a dual-axis motor and fan blades. A semiconductor refrigeration plate is placed inside one side of the cooling box, and heat-conducting fins are provided on both sides of the semiconductor refrigeration plate. A dual-axis motor is placed on one side of the cooling box, and a fan blade is provided at one end of the dual-axis motor.

[0018] Furthermore, the cooling assembly also includes a driving gear, a driven gear and a driving gear. The other end of the dual-axis motor is fixed with a driving gear, and one side of the driving gear is engaged with a driven gear. The diameter of the driving gear is smaller than the diameter of the driven gear, and one side of the driven gear is engaged with a driving gear. The driving gear is fixedly connected to the rotating seat 2.

[0019] Furthermore, a reactor shell is provided on one side of the cleaning frame, and a water inlet is provided at the upper left end of the reactor shell, a drain outlet is provided at the upper right end of the reactor shell, cathode plates are provided on both sides of the middle part of the rope body, and the spacing between the two cathode plates is 2 cm.

[0020] The present invention provides a method for manufacturing an anode rope with a large specific surface area and an ECO reactor, which have the following beneficial effects:

[0021] 1. The present invention uses anode ropes to replace traditional anode plates. Since the cross-section of the anode rope is a fluffy three-dimensional structure, in a cross-section of the same width, the anode rope with a fluffy three-dimensional structure on the outside will have a larger surface area than the traditional anode plate, thereby increasing the contact area between the reactor and the wastewater, allowing for sufficient contact during the reaction, which is beneficial to improving the reaction efficiency and reducing the use of precious metals, thereby reducing the investment in the plates and saving the production cost of the ECO reactor.

[0022] 2. When the anode rope is cleaned, the cleaning motor drives the take-up wheel to rotate through the drive shaft, so that part of the rope body can be moved from one take-up wheel to another. At this time, the brush plate can brush and clean the surface of the rope body when it moves, so that the anode rope can be cleaned and maintained without stopping the machine, thereby improving the efficiency of the ECO reactor treatment. In addition, the guide wheel can also limit the rope body to prevent it from deflecting inside the brush plate and affecting its cleaning effect.

[0023] 3. In the present invention, when the two take-up wheels rotate synchronously, the rope may be too tight or too loose due to uneven distribution of the anode rope on the take-up wheels or asynchronous rotation speeds of the two cleaning motors. At this time, a slider and a guide rod can provide a buffer distance at one end between the drive shaft and the take-up wheel, and a buffer spring is used to tighten the slider and the guide rod. When the anode rope is too tight, the buffer spring can be compressed to prevent the anode rope from being damaged due to excessive tension. At the same time, a certain damping force can be applied between the slider and the guide rod by the rubber ring to suppress the vibration of the buffer spring, thereby enhancing the stability during winding or unwinding. The elastic force of the buffer spring on one side is monitored by a pressure sensor, thereby facilitating the observation of the tension state of the rope body and correcting the rotation speed of the cleaning motor. The anode rope is located between two cathode plates with a spacing of 2 cm. The back and forth movement of the anode rope can also clean the cathode plates, effectively removing organic scale on the surface of the cathode plates.

[0024] 4. In the present invention, when the drive shaft rotates, the pulley can reduce the friction loss between the cam and the telescopic cylinder, so that the telescopic cylinder can be squeezed when the cam rotates. At this time, the air inside the telescopic cylinder can be ejected from the nozzle on the diversion pipe through the second one-way valve to clean the front end of the brush plate, avoiding excessive accumulation of impurities at the front end of the brush plate and affecting the cleaning effect. When the cam continues to rotate, the return spring can push the telescopic cylinder to extend it. At this time, once the one-way valve is opened, the waste frame can be evacuated through the connecting pipe, and the air inside the telescopic cylinder can be filled with air filtered by the filter frame, so that it can be used reciprocatingly.

[0025] 5. In the present invention, when the connecting pipe draws air from the waste frame, the air can enter the cooling pipe through the rotating seat 1. At this time, the semiconductor refrigeration plate can cool the coolant inside the cooling box, so that the coolant can cool the air in the cooling pipe, so that the air with lower temperature flows toward the rope body, thereby cooling the anode rope. When the dual-axis motor drives the fan blades to rotate to dissipate heat from the hot end of the semiconductor refrigeration plate, the rotating seat 2 can be driven to rotate by the active gear, the driven gear and the drive gear, so that the cooling pipe can be stirred in the cooling box, which can not only make the internal coolant temperature evenly distributed, but also evenly cool down each cooling pipe to improve the efficiency of heat exchange. BRIEF DESCRIPTION OF THE DRAWINGS

[0026] FIG1 is a schematic diagram of the overall front cross-sectional structure of the present invention;

[0027] FIG2 is a schematic diagram of the three-dimensional structure of the brush plate of the present invention;

[0028] FIG3 is a schematic diagram of a left side cross-sectional structure of a tensioning assembly according to the present invention;

[0029] FIG4 is a schematic diagram of the cam structure from the left side of the present invention;

[0030] FIG5 is a schematic diagram of a top view of the cooling assembly of the present invention;

[0031] FIG6 is an enlarged structural diagram of point A in FIG5 of the present invention;

[0032] FIG7 is a schematic diagram of the structure of the anode rope after braiding of the present invention.

[0033] Figure: 1. Rope body; 2. Limiting wheel; 3. Cleaning assembly; 301. Cleaning frame; 302. Cleaning motor; 303. Drive shaft; 304. Take-up wheel; 305. Guide wheel; 306. Brush plate; 307. Waste frame; 308. Filter frame; 4. Tensioning assembly; 401. Guide rod; 402. Slider; 403. Buffer spring; 404. Rubber ring; 405. Pressure sensor; 5. De-duster assembly; 501. Cam; 502. Pulley; 503. Telescopic cylinder; 504. Return spring ; 505, one-way valve one; 506, connecting pipe; 507, one-way valve two; 508, diverter pipe; 509, nozzle; 6, cooling assembly; 601, cooling box; 602, rotating seat one; 603, cooling pipe; 604, rotating seat two; 605, semiconductor refrigeration plate; 606, thermal fin; 607, dual-axis motor; 608, fan blade; 609, driving gear; 610, driven gear; 611, driving gear; 7, reactor shell; 8, water inlet; 9, drain outlet; 10, cathode plate. DETAILED DESCRIPTION

[0034] A method for manufacturing an anode rope with a large specific surface area comprises the following steps:

[0035] S1: After alkali washing and degreasing, a 0.2 mm titanium wire is placed in the acidified carbon gel and soaked for 1 hour, then taken out and dried for later use;

[0036] S2: Soak the anode wire in 15% H2O2 solution, add 4% melamine solution and 5% cyanuric acid solution, heat the solution to 80℃, soak for 12 hours, then take out and dry;

[0037] S3: Place the anode wire in a solution of NiSO4·6H2O:CoSO4·7H2O:MnSO4*7H2O (mass ratio) = 10:5:2, add 5%~10% volume fraction of additives, stir evenly and immerse for 1 hour, place in a drying oven to isolate from air and dry until the surface is completely dry, heat treat at 900~1200℃ for 15 minutes under nitrogen protection, and repeat the immersion, drying and heat treatment 8~10 times.

[0038] S4: The glass fiber rope and the anode wire are braided into a fluffy three-dimensional anode rope with a diameter of 2 cm.

[0039] Please refer to Figures 1 to 7, which include a rope body 1 and a cleaning component 3. A limiting wheel 2 is provided on the outer middle part of the rope body 1. The cleaning component 3 is provided at the left and right ends of the rope body 1. The cleaning component 3 includes a cleaning frame 301, a cleaning motor 302, a drive shaft 303, a take-up wheel 304, a guide wheel 305, a brush plate 306, a waste frame 307 and a filter frame 308. A cleaning motor 302 is placed on the upper end of one side of the cleaning frame 301, and one end of the cleaning motor 302 is connected to the drive shaft 303, and the take-up wheel 304 is sleeved on the outer middle part of the drive shaft 303. The inner center of the cleaning frame 301 is symmetrically provided with The guide wheel 305 is provided, and the lower end of the interior of the cleaning frame 301 is provided with a brush plate 306, and the brush plate 306 is slidably connected to the rope body 1, a waste frame 307 is provided at the lower end of one side of the cleaning frame 301, and a filter frame 308 is provided inside the waste frame 307, and a tensioning assembly 4 is provided inside the take-up wheel 304, and the tensioning assembly 4 includes a guide rod 401, a slider 402, a buffer spring 403, a rubber ring 404 and a pressure sensor 405, and a guide rod 401 is fixed inside the take-up wheel 304, and the guide rod 401 is arc-shaped, and a slider 402 is sleeved on the outer side of the middle part of the guide rod 401, and the slider 402 is sleeved on the outer side of the middle part of the guide rod 401. The block 402 is fixedly connected to the driving shaft 303, and buffer springs 403 are connected to both sides of the slider 402, and a rubber ring 404 is placed inside the slider 402, and a pressure sensor 405 is connected to one side of the buffer spring 403, and the pressure sensor 405 is fixedly connected to the take-up wheel 304. A debris removal component 5 is provided on the top of the cleaning frame 301, and the debris removal component 5 includes a cam 501, a pulley 502 and a telescopic cylinder 503. One end of the driving shaft 303 is connected to the cam 501, and one side of the cam 501 is connected to the pulley 502, and a telescopic cylinder 503 is provided at one end of the pulley 502. 5 also includes a return spring 504, a one-way valve 505 and a connecting pipe 506. The return spring 504 is sleeved on the outside of one end of the telescopic cylinder 503, and the one-way valve 505 is provided on one side of the lower part of the telescopic cylinder 503. One end of the one-way valve 505 is provided with a connecting pipe 506, and the connecting pipe 506 is connected to the interior of the waste frame 307. The impurity removal component 5 also includes a second one-way valve 507, a diverter pipe 508 and a nozzle 509. The second one-way valve 507 is provided on the lower end of the telescopic cylinder 503, and the end of the second one-way valve 507 is connected to the diverter pipe 508, and a nozzle 509 is provided on one side of the diverter pipe 508.

[0040] The specific operation is as follows: after the wastewater enters the reactor shell 7, the rope body 1 is distributed in a serpentine shape under the action of the limiting wheel 2, which can extend its surface area inside the reactor shell 7. When cleaning impurities attached to the anode rope, the cleaning motor 302 drives the take-up wheel 304 to rotate through the drive shaft 303, the slider 402 and the buffer spring 403, so that part of the rope body 1 can be moved from one take-up wheel 304 to another take-up wheel 304. At this time, the brush plate 306 can brush and clean the surface of the rope body 1 when it moves, so that the anode rope can be cleaned and maintained without stopping the machine, thereby improving EC O reactor processing efficiency, and the guide wheel 305 can also limit the rope body 1 to prevent it from deflecting inside the brush plate 306 and affecting its cleaning effect, and when the two take-up wheels 304 rotate synchronously, the rope body 1 may be unevenly distributed on the take-up wheel 304 or the speed of the two cleaning motors 302 is not synchronized, resulting in the rope body 1 being too tight or too loose. At this time, the slider 402 and the guide rod 401 can provide a buffer distance at one end between the drive shaft 303 and the take-up wheel 304, and the buffer spring 403 is used to tighten the slider 402 and the guide rod 401, so that When the anode rope is too tight, the buffer spring 403 can be compressed to prevent the anode rope from being damaged due to excessive tension. At the same time, the rubber ring 404 can give a certain damping force between the slider 402 and the guide rod 401 to suppress the vibration of the buffer spring 403, thereby enhancing the stability when winding or releasing the line. The elastic force of the buffer spring 403 on one side is monitored by the pressure sensor 405, so as to facilitate the observation of the tensioning state of the rope body 1, so as to correct the speed of the cleaning motor 302. At the same time, when the driving shaft 303 rotates, it can also drive the cam 501 to rotate synchronously, and The telescopic cylinder 503 is squeezed by the pulley 502, and the air inside it can be sprayed out from the nozzle 509 on the diversion pipe 508 through the one-way valve 2 507 to clean the front end of the brush plate 306 with air, so as to avoid excessive accumulation of impurities at the front end of the brush plate 306 and affect the cleaning effect. When the cam 501 continues to rotate, the return spring 504 can push the telescopic cylinder 503 to extend it. At this time, the one-way valve 1 505 is opened, and the waste frame 307 can be evacuated through the connecting pipe 506, and the air inside the telescopic cylinder 503 can be filled with the air filtered by the filter frame 308.

[0041] Please refer to Figures 5 and 6. A cooling component 6 is provided in the middle of the connecting pipe 506. The cooling component 6 includes a cooling box 601, a rotating seat 1 602, a cooling pipe 603 and a rotating seat 2 604. The interior of the cooling box 601 is provided with a rotating seat 1 602, and the interior of the rotating seat 1 602 is hollow. One side of the rotating seat 1 602 is connected to the cooling pipe 603, and one end of the cooling pipe 603 is provided with a rotating seat 2 604, and the rotating seat 2 604 is rotatably connected to the cooling box 601. The cooling component 6 also includes a semiconductor refrigeration sheet 605, a heat-conducting fin 606, a dual-axis motor 607 and a fan blade 608. A semiconductor refrigeration sheet 605 is provided inside one side of the cooling box 601, and heat-conducting fins 606 are provided on both sides of the semiconductor refrigeration sheet 605. A dual-axis motor 607 is provided on one side of the cooling box 601, and a fan blade is provided at one end of the dual-axis motor 607. Blade 608, the cooling assembly 6 also includes a driving gear 609, a driven gear 610 and a driving gear 611. The other end of the dual-axis motor 607 is fixed with a driving gear 609, and one side of the driving gear 609 is meshed with a driven gear 610. The diameter of the driving gear 609 is smaller than the diameter of the driven gear 610, and one side of the driven gear 610 is meshed with a driving gear 611. The driving gear 611 is fixedly connected to the rotating seat 2 604. A reactor shell 7 is provided on one side of the cleaning frame 301, and a water inlet 8 is provided at the upper left end of the reactor shell 7, and a drain outlet 9 is provided at the upper right end of the reactor shell 7. Cathode plates 10 are provided on both sides of the middle of the rope body 1, and the distance between the two cathode plates 10 is 2 cm. Since both sides of the middle of the rope body 1 are in contact with the cathode plate 10 made of titanium plate material, the cathode plate 10 is automatically cleaned during the back and forth movement of the anode rope;

[0042] The specific operation is as follows: when the connecting pipe 506 draws air from the waste frame 307, the air will enter the cooling tube 603 through the rotating seat 1 602. At this time, the semiconductor refrigeration plate 605 can cool the coolant inside the cooling box 601, so that the coolant can cool the air in the cooling tube 603, so that the air with lower temperature is sprayed toward the rope body 1, thereby cooling the anode rope. At the same time, since the cooling tube 603 is spiral, the overall heat exchange time can be extended, thereby improving the cooling effect. When the dual-axis motor 607 drives the fan blade 608 to rotate to dissipate heat from the hot end of the semiconductor refrigeration plate 605, the rotating seat 2 604 can be driven to rotate through the active gear 609, the driven gear 610 and the drive gear 611, so that the cooling tube 603 can be stirred in the cooling box 601, which can not only make the internal coolant temperature evenly distributed, but also evenly cool down each cooling tube 603 to improve the efficiency of heat exchange.

[0043] In summary, the method for manufacturing a large specific surface area anode rope and the ECO reactor, when in use, first, after the wastewater enters the reactor shell 7 through the water inlet 8, since one end of the rope body 1 and the cathode plate 10 are electrically connected to the power supply, discharge can be carried out between the rope body 1 and the cathode plate 10 to electrocatalytically oxidize the wastewater. At this time, the rope body 1 is distributed in a serpentine shape under the action of the limiting wheel 2, which can extend its surface area inside the reactor shell 7. Then, when cleaning the impurities attached to the anode rope, the cleaning motor 302 drives the take-up wheel 304 to rotate through the drive shaft 303, the slider 402 and the buffer spring 403, so that part of the rope body 1 can be moved from one take-up wheel 304 to another. The guide wheel 305 can also limit the rope body 1. Secondly, when the two take-up wheels 304 rotate synchronously, the slider 402 and the guide rod 401 can provide a buffer distance at one end between the drive shaft 303 and the take-up wheel 304, and the buffer spring 403 is used to tighten the slider 402 and the guide rod 401, so that when the anode rope is too tight, the buffer spring 403 can be compressed to avoid damage to the anode rope due to excessive tension. At the same time, the rubber ring 404 can give a certain damping force between the slider 402 and the guide rod 401 to suppress the vibration of the buffer spring 403, and by pressing The force sensor 405 monitors the elastic force of the buffer spring 403 on one side so as to correct the speed of the cleaning motor 302. Then, when the driving shaft 303 rotates, it can also drive the cam 501 to rotate synchronously and squeeze the telescopic cylinder 503 through the pulley 502. At this time, the air inside it can be ejected from the nozzle 509 on the shunt pipe 508 through the one-way valve 2 507 to jet the front end of the brush plate 306 for cleaning. When the cam 501 continues to rotate, the return spring 504 can push the telescopic cylinder 503 to extend it. At this time, the one-way valve 1 505 is opened, and the waste frame 307 can be evacuated through the connecting pipe 506 to fill the air inside the telescopic cylinder 503. Finally, when the connecting pipe 506 is opened, the air inside the telescopic cylinder 503 can be filled. When the pipe 506 draws air from the waste frame 307, the air can enter the cooling tube 603 through the rotating seat 1 602. At this time, the semiconductor refrigeration plate 605 can cool the coolant inside the cooling box 601, so that the coolant can cool the air in the cooling tube 603, so that the air with lower temperature can be directed to the rope body 1, thereby cooling the anode rope. When the dual-axis motor 607 drives the fan blade 608 to rotate to dissipate heat from the hot end of the semiconductor refrigeration plate 605, the rotating seat 2 604 can be driven to rotate by the driving gear 609, the driven gear 610 and the driving gear 611, so that the cooling tube 603 can be stirred in the cooling box 601 to improve the efficiency of heat exchange.

[0044] The embodiments of the present invention are presented for purposes of illustration and description and are not intended to be exhaustive or to limit the invention to the disclosed forms. Many modifications and variations will be apparent to those skilled in the art. The embodiments are chosen and described in order to better illustrate the principles of the invention and its practical application and to enable those skilled in the art to understand the invention and design various embodiments with various modifications as suited for specific applications.

Claims

1. A method for making an anode rope with a large specific surface area, characterized in that: The following steps are involved: S1: After alkali washing and degreasing of 0.2 mm titanium wire, soak it in the acidified carbon gel for 1 hour, then take it out and dry it for later use; S2: Soak the anode wire in 15% H2O2 solution, add 4% melamine solution and 5% cyanuric acid solution, heat the solution to 80°C, soak for 12 hours and then take out and dry; S3: Place the anode wire in a solution of NiSO4·6H2O:CoSO4·7H2O:MnSO4*7H2O (mass ratio) = 10:5:2, add 5%~10% of the volume fraction of the additive, stir evenly and immerse for 1 hour, place in a drying oven to isolate the air and dry until the surface is completely dry, heat treat at 900~1200℃ for 15min under nitrogen protection, and repeat the immersion, drying and heat treatment 8~10 times; S4: The glass fiber rope and the anode wire are woven into a fluffy three-dimensional anode rope with a diameter of 2 cm.

2. An ECO reactor for an anode rope with a large specific surface area, applied to the method for making an anode rope with a large specific surface area according to claim 1, wherein the ECO reactor for an anode rope with a large specific surface area is characterized in that: The invention comprises a rope body (1) and a cleaning assembly (3), wherein a limit wheel (2) is arranged on the outer side of the middle part of the rope body (1), and the cleaning assembly (3) is arranged at the left and right ends of the rope body (1). The cleaning assembly (3) comprises a cleaning frame (301), a cleaning motor (302), a driving shaft (303), a take-up wheel (304), a guide wheel (305), a brush plate (306), a waste frame (307) and a filter frame (308). The cleaning motor (302) is arranged on the upper end of one side of the cleaning frame (301), and the cleaning motor (302) is arranged on the upper end of the cleaning frame (301). One end of the motor (302) is connected to a driving shaft (303), and a take-up wheel (304) is sleeved on the outer side of the middle part of the driving shaft (303); a guide wheel (305) is symmetrically arranged at the center of the cleaning frame (301); a brush plate (306) is arranged at the lower end of the cleaning frame (301); and the brush plate (306) is slidably connected to the rope body (1); a waste frame (307) is arranged at the lower end of one side of the cleaning frame (301), and a filter frame (308) is arranged inside the waste frame (307).

3. The ECO reactor of the anode rope with large specific surface area according to claim 2, characterized in that: A tensioning assembly (4) is arranged inside the take-up wheel (304), and the tensioning assembly (4) comprises a guide rod (401), a slider (402), a buffer spring (403), a rubber ring (404) and a pressure sensor (405); a guide rod (401) is fixed inside the take-up wheel (304), and the guide rod (401) is arc-shaped; a slider (402) is sleeved on the outer side of the middle part of the guide rod (401), and the slider (402) is fixedly connected to the driving shaft (303); buffer springs (403) are connected to both sides of the slider (402), and a rubber ring (404) is arranged inside the slider (402); a pressure sensor (405) is connected to one side of the buffer spring (403), and the pressure sensor (405) is fixedly connected to the take-up wheel (304).

4. The ECO reactor of the anode rope with large specific surface area according to claim 2, characterized in that: A debris removal component (5) is arranged on the top of the cleaning frame (301), and the debris removal component (5) comprises a cam (501), a pulley (502) and a telescopic cylinder (503); one end of the driving shaft (303) is connected to the cam (501), one side of the cam (501) is connected to the pulley (502), and one end of the pulley (502) is arranged with the telescopic cylinder (503).

5. The ECO reactor of the anode rope with large specific surface area according to claim 4, characterized in that: The impurity removal component (5) further comprises a return spring (504), a one-way valve (505) and a connecting pipe (506); the return spring (504) is sleeved on the outside of one end of the telescopic cylinder (503), and a one-way valve (505) is arranged on one side of the lower part of the telescopic cylinder (503); a connecting pipe (506) is arranged on one end of the one-way valve (505), and the connecting pipe (506) is communicated with the interior of the waste frame (307).

6. The ECO reactor of the anode rope with large specific surface area according to claim 5, characterized in that: The impurity removal component (5) further comprises a second one-way valve (507), a diverter pipe (508) and a nozzle (509); the second one-way valve (507) is arranged at the lower end of the telescopic cylinder (503); the end of the second one-way valve (507) is connected to the diverter pipe (508); and the nozzle (509) is arranged on one side of the diverter pipe (508).

7. The ECO reactor of the anode rope with large specific surface area according to claim 6, characterized in that: A cooling assembly (6) is arranged in the middle of the connecting pipe (506), and the cooling assembly (6) comprises a cooling box (601), a rotating seat one (602), a cooling pipe (603) and a rotating seat two (604); a rotating seat one (602) is arranged inside the cooling box (601), and the interior of the rotating seat one (602) is hollow; one side of the rotating seat one (602) is connected to the cooling pipe (603), and a rotating seat two (604) is arranged at one end of the cooling pipe (603), and the rotating seat two (604) is rotatably connected to the cooling box (601).

8. The ECO reactor of the anode rope with large specific surface area according to claim 7, characterized in that: The cooling assembly (6) further comprises a semiconductor cooling sheet (605), heat-conducting fins (606), a dual-axis motor (607) and a fan blade (608); the semiconductor cooling sheet (605) is arranged inside one side of the cooling box (601), and heat-conducting fins (606) are arranged on both sides of the semiconductor cooling sheet (605); the dual-axis motor (607) is arranged on one side of the cooling box (601), and a fan blade (608) is arranged at one end of the dual-axis motor (607).

9. The ECO reactor of the anode rope with large specific surface area according to claim 8, characterized in that: The cooling assembly (6) further comprises a driving gear (609), a driven gear (610) and a drive gear (611); the other end of the dual-axis motor (607) is fixed with the driving gear (609), and one side of the driving gear (609) is meshed with the driven gear (610); the diameter of the driving gear (609) is smaller than the diameter of the driven gear (610), and one side of the driven gear (610) is meshed with the drive gear (611); the drive gear (611) is fixedly connected to the second rotating seat (604).

10. The ECO reactor of the anode rope with large specific surface area according to claim 2, characterized in that: A reactor shell (7) is provided on one side of the cleaning frame (301), and a water inlet (8) is provided at the upper left end of the reactor shell (7), and a drain outlet (9) is provided at the upper right end of the reactor shell (7). Cathode plates (10) are provided on both sides of the middle of the rope body (1), and the spacing between the two cathode plates (10) is 2 cm.

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