Method and device for separating particles made of different plastics

Abstract

The aim of the invention is to separate particles (6) made of different plastics. This is achieved in that the particles (6) are suspended in a first liquid (10) with a first density and are separated into first light particles (11) with a lower density and first heavy particles (12) which have at least the first density. The first heavy particles (12) are dried and are then separated at least into a first fraction (21) and a second fraction (22) by means of a first electrostatic separation (19) on the basis of the dielectric properties of the particles. The particles of the second fraction (22) can be electrostatically charged, and the particles of the first fraction (21), on the basis of the dielectric properties thereof, are not charged or are charged differently than the electrostatically chargeable particles of the second fraction (22). The particles of the second fraction (22) are then suspended in a second liquid (25) with a higher second density and are divided into second light particles (27) with a lower density and second heavy particles (28) which have at least the second density. The second light particles (27) are dried and are then separated into at least two other fractions (34, 35) by means of a second electrostatic separation (32) on the basis of the dielectric properties of the particles.

Description

[0001] METHOD AND DEVICE FOR SEPARATION OF PARTICLES FROM DIFFERENT PLASTICS

[0002] TECHNICAL FIELD OF THE INVENTION

[0003] The invention relates to a method and a device for separating particles from different plastics. In particular, the invention relates to a method having the features of the preamble of independent patent claim 1 and a device having the features of the preamble of independent patent claim 14.

[0004] Recycling plastics into high-quality products requires separating the plastics into pure fractions. This separation proves challenging even when composite materials made of different plastics are not present, or when such composite materials can be separated into particles consisting of only one plastic by crushing.

[0005] STATE OF THE ART

[0006] A method for separating particles from different plastics with the features of the preamble of independent patent claim 1 and a corresponding device with the features of the preamble of independent patent claim 14 are disclosed in DE 202021 000353 U1. In order to produce a polyvinyl chloride (PVC) recyclate containing a maximum of one percent by weight of polyolefins from cable recyclate, the float / sink process is first used at a separation density of 1.00 to 1.23 g / cm 3A sinking fraction is separated. This sinking fraction is dried mechanically using a centrifuge and additionally thermally. PVC is then separated from the sinking fraction using electrostatic separation. Considerable effort is required to mechanically pre-dry the sinking fraction to a high degree of drying of a maximum of 0.4% residual moisture by weight. Electrostatic separation is known to be only feasible at a maximum residual moisture content of 0.2% by weight, which must be achieved during the subsequent thermal drying. The sink / float process not only separates a light fraction from the cable recyclate, but also removes fractions that prevent the PVC from specifically charging during electrostatic separation.However, after separation of the light fraction and subsequent mechanical and thermal drying, PVC, due to its position in the electrostatic series, should be able to be charged in such a way that the rubber, fluoroelastomer, and silicone elastomer components present as foreign material can be electrostatically separated, thus achieving the required purity and desired material properties of the PVC. Furthermore, in the known process, non-ferrous metals are separated between drying and electrostatic separation using an eddy current separator. It turns out that the known process is only suitable for separating PVC particles from particles of other plastics.

[0007] GB 2 465 839 A discloses a process for recycling plastics. Plastic waste is reduced to an average particle size of 100 to 500 mm. Contaminants are removed using a rotary screen, a ferrous metal separator, and / or manually. The plastic waste is then reduced to an average particle size of 50 to 150 mm. In a second contaminant removal step, a non-ferrous metal separator and / or a plastic film separator are used. The plastic material is then granulated to an average particle size of 10 mm to 50 mm. The granulated plastic material is divided into a sinking stream and a floating stream of plastic material in a flotation tank. The plastic material in the sinking stream and / or floating stream is dried. An initial optical separation is preferably carried out using near-infrared technology.After the first optical separation, the plastic material is granulated to an average particle size of 2 to 10 mm. The granulated plastic material is then passed through a second flotation tank. The plastic material is then dried and a second optical separation is performed. An electrostatic separation can be performed downstream of each optical separation.

[0008] EP 2 484 506 A1 discloses a method for sorting and separating plastic waste. The plastic waste is shredded. The resulting fragments are steam-cleaned. Liquids of different densities separate the fragments in two density separators. The density-separated fragments are further electrostatically separated in electrostatic separators.

[0009] OBJECT OF THE INVENTION

[0010] The invention is based on the object of demonstrating a method and a device for separating particles from different plastics, with which further high-quality, pure fractions of the particles can be obtained.

[0011] SOLUTION

[0012] The object of the invention is achieved by a method having the features of independent patent claim 1 and a device having the features of independent patent claim 14. The dependent patent claims relate to preferred embodiments of the method and device according to the invention.

[0013] DESCRIPTION OF THE INVENTION

[0014] In a method according to the invention for separating particles of different plastics, the particles are suspended in a first liquid having a first density and separated into first light particles having a density lower than the first density and first heavy particles having a density at least equal to the first density. At least the first light particles or the first heavy particles are dried to form first dried particles. The first dried particles are separated by a first electrostatic separation based on their dielectric properties into at least a first fraction and a second fraction, wherein the particles of the second fraction are electrostatically chargeable.During the first electrostatic separation, the particles of the first fraction are not electrostatically charged or are charged differently than the electrostatically chargeable particles of the second fraction due to their dielectric properties, so that the particles of the first and second fractions can be separated during the first electrostatic separation. The electrostatically chargeable particles of the second fraction are suspended in a second liquid with a second density and separated into second light particles with a lower density than the second density and second heavy particles with a density of at least the second density. At least the second light particles or the second heavy particles are dried to form second dried particles. The second dried particles are separated into at least two further fractions by a second electrostatic separation due to their dielectric properties.By repeating the density separation using a second liquid whose second density differs from the first density of the first liquid by typically at least 0.10 g / cm. 3 differs, the electrostatically chargeable particles of the second fraction are further divided, whereby further pure fractions can be obtained, so that it is actually worthwhile to undertake the additional effort, especially for the renewed drying of the particles after their second density separation with the aid of the second liquid.

[0015] The process according to the invention does not achieve the additional pure particle fractions by a perhaps obvious density separation of the particles directly one after the other using different liquids of different densities. Rather, after the first density separation, a first drying and a first electrostatic separation take place, and only one of the fractions obtained, whose particles are electrostatically chargeable, is subjected to the second density separation and then to a renewed drying and a further electrostatic separation. The advantage of additional pure particle fractions is surprising; and the additional pure particle fractions are only obtained if the associated, already mentioned, high additional drying effort is accepted.

[0016] It proves particularly advantageous if at least the liquid with the greater density, which is used in one of the density separations of the process according to the invention, is based on a solution of sodium phosphinate in water, i.e. the density is adjusted by adding sodium phosphinate to water, whereby the liquid can contain further additives to a limited extent of not more than 20 wt.% and generally not more than 10 or 5 wt.%. These additives can be, for example, surface-active agents, which facilitate complete wetting of the particles with the respective liquid and prevent the inclusion of air bubbles. Both are measures that improve the quality of the density separation. Sodium phosphinate is highly soluble in water to achieve a desired increased density liquid.Above all, sodium phosphinate can be easily removed mechanically from the particles with the liquid, and any sodium phosphinate residues remaining after drying do not impede the electrostatic separation of the particles in the process according to the invention. If surface-active agents are added to the first and / or second liquid in the process according to the invention, care must be taken to ensure that these do not impair the at least one subsequent electrostatic separation. Such an impairment can be associated with the use of antistatic agents, which, while helpful for density separation, can be very detrimental to subsequent electrostatic separation, since they can prevent electrostatic charging even of particles that are inherently chargeable.Ethanol has proven to be a very suitable surfactant that can be added to the first liquid and / or the second liquid without compromising the at least one subsequent electrostatic separation. Specifically, the first liquid and / or the second liquid can contain 5 to 10 wt.% ethanol. A concomitant reduction in the density of the respective liquid can be compensated by adding sodium phosphinate. The addition of ethanol to water does not limit the solubility of sodium phosphinate in water to any extent relevant to the present invention.

[0017] The first density of the first liquid can be 1 .00 g / cm 3 + / - 0.03 g / cm 3 and preferably 1.00 g / cm 3 + / - 0.01 g / cm 3Specifically, the first liquid can consist at least predominantly of water. At this first density, the first heavy particles, which have at least the first density, are preferably dried to form the first dried particles. In other words, the first density separation with the first liquid produces a light fraction with a density of less than 1.00 g / cm 3 separated. This light fraction can consist at least predominantly of low-density polyethylene (PE) and ethylene propylene diene monomer (EPDM). Here and elsewhere in this description and the appended claims, the term "predominantly" is to be understood literally, meaning that the substance of which the respective particles predominantly consist constitutes more than 50% by weight of the particles.

[0018] During the first electrostatic separation, the first dried particles can be separated into a first fraction, a second fraction, and a third fraction. The first fraction can contain particles without a pronounced electrostatic charge, the second fraction can contain particles with a positive electrostatic charge, and the third fraction can contain particles with a negative electrostatic charge. The electrostatic charges that occur during the first electrostatic separation and the second electrostatic separation can be caused independently of one another, particularly by friction and / or electrical discharges. The charges of the individual particles after their electrostatic charging depend on their relative specific capacities in the dimension of charge per area. The particles with the medium capacity are neutral and form the first fraction.The particles with larger capacities become positively charged and form the second fraction; the particles with smaller capacities become negatively charged and form the third of the three fractions.

[0019] Specifically, the particles of the first fraction may consist predominantly of PVC-w, while the particles of the third fraction may consist at least predominantly of filler-containing EPDM and other high-density ethylene propylene diene monomer (EPDM), i.e. EPDM with a density greater than 1.00 g / cm 3 consist.

[0020] The second density of the second liquid, with the help of which the second density separation is carried out, can be 1 .23 g / cm 3 + / - 0.03 g / cm 3 and is preferably 1.23 g / cm 3 + / - 0.01 g / cm 3. If the second light particles are then dried to form the second dried particles, wherein the drying, like the drying to form the first dried particles, preferably takes place first mechanically and then thermally, the second light particles can consist at least predominantly of polyamide (PA) and polyurethane (PU). By means of the second electrostatic separation, the second light particles can then be separated into a further fraction consisting at least predominantly of PA and another further fraction consisting at least predominantly of PU. The second heavy particles consist at least predominantly of fluoroelastomer, silicone elastomer, polyethylene terephthalate (PET) and / or cellulose acetate (CA).

[0021] In the process according to the invention, electrically conductive particles can be separated, for example, by eddy current separation. The eddy current separation can be performed anywhere upstream of the first electrostatic separation in order to separate the electrically conductive particles beforehand. Otherwise, the electrically conductive particles end up in the above-mentioned first fraction of particles without electrostatic charge. However, eddy current separation is not suitable for separating all electrically conductive particles. For example, ferromagnetic particles cannot be separated by eddy current separation. In addition to particles made of non-ferromagnetic metals, particles made of electrically conductive plastics can also be separated by eddy current separation. Furthermore, ferromagnetic particles can be separated using the process according to the invention. This is achieved in particular by magnetic separation using an electromagnet.Magnetic separation also preferably takes place upstream of the first electrostatic separation. It also separates ferromagnetic, electrically conductive particles that cannot be separated by eddy current separation. Magnetic separation can also remove particles from plastics that exhibit ferromagnetic properties due to the presence of appropriate metallic additives.

[0022] Furthermore, electrically polarizable particles can be separated using the method according to the invention. This can be achieved, for example, by separation using a strong electric field gradient, which results in forces of varying magnitude on the particles in the direction of the electric field gradient, depending on their electrical polarizability.

[0023] In the process according to the invention, it proves to be advantageous if a particle size of the particles is set at the beginning of their separation to 1 mm to 6 mm and preferably 2 mm to 6 mm, for example by grinding and sieving, and particularly preferably with an accuracy of at least + / - 1.5 mm and even more preferably with an accuracy of at least + / - 1.0 mm. A size of all particles that is as uniform as possible eliminates influences of the particle size, which can fundamentally occur in a density separation with the aid of a liquid, in an electrostatic separation, in an eddy current separation, in a magnetic separation or in an E-field gradient separation.Particularly for density separation and electrostatic separation, it has proven advantageous to set the particle size not only as accurately as possible, but precisely within the range of 1 mm to 6 mm, with as many particles as possible falling within this range, so that the average particle size is between 2.5 and 4.5 mm or between 2 and 5 mm, depending on the accuracy.

[0024] A device according to the invention for separating particles from different plastics comprises a first density separator designed to separate the particles suspended in a first liquid having a first density into first light particles having a density lower than the first density and into first heavy particles having a density at least equal to the first density. The device further comprises a first dryer designed and arranged to dry the first light particles or preferably the first heavy particles into first dried particles, and a first electrostatic separator designed and arranged to separate the first dried particles by a first electrostatic separation based on their dielectric properties into at least a first fraction and a second fraction, wherein the particles of the second fraction are electrostatically chargeable.The device further comprises a second density separator designed to separate the electrostatically chargeable particles of the second fraction suspended in a second liquid having a second density into second light particles having a density lower than the second density and second heavy particles having a density at least equal to the second density. A second dryer of the device is designed and arranged to dry the second heavy particles, or preferably the second light particles, into second dried particles. The device then comprises a second electrostatic separator designed and arranged to separate the second dried particles into at least two further fractions by a second electrostatic separation based on their dielectric properties.

[0025] Preferably, the electrostatic separator is configured to separate the first dried particles into the first fraction, the second fraction, and a third fraction, wherein the first fraction comprises particles without a pronounced electrostatic charge, and wherein the second fraction comprises positively electrostatically charged particles and the third fraction comprises negatively electrostatically charged particles.

[0026] As already indicated, the dryers can each comprise mechanical and thermal components, for example, a centrifuge and an infrared oven. Furthermore, the device can additionally comprise, particularly upstream of the first electrostatic separator, an eddy current separator and / or a magnetic separator and / or an e-field gradient separator.

[0027] Commercially available industrial electrostatic separators with electrostatic charging through friction and / or electrical discharges can be used as electrostatic separators.

[0028] Advantageous developments of the invention will become apparent from the patent claims, the description, and the drawings. The advantages of features and combinations of features mentioned in the description are merely exemplary and may be effective alternatively or cumulatively, without necessarily achieving the advantages of embodiments according to the invention.

[0029] With regard to the disclosure content – ​​not the scope of protection – of the original application documents and the patent, the following applies: Further features can be found in the drawings – in particular the illustrated geometries and the relative dimensions of several components to one another, as well as their relative arrangement and operative connection. The combination of features of different embodiments of the invention or features of different patent claims is also possible, deviating from the chosen references of the patent claims, and is hereby encouraged. This also applies to features that are illustrated in separate drawings or mentioned in their description. These features can also be combined with features of different patent claims.Likewise, features listed in the patent claims may be omitted for further embodiments of the invention, but this does not apply to the independent patent claims of the granted patent.

[0030] The number of features mentioned in the patent claims and the description is to be understood as meaning that exactly this number or a greater number than the stated number is present, without the need for the explicit use of the adverb "at least." Thus, for example, if reference is made to a first dryer, this is to be understood as meaning that exactly one first dryer, two first dryers, or more first dryers are present. The features mentioned in the patent claims may be supplemented by further features or may be the only features present in the subject matter of the respective patent claim.

[0031] The reference symbols contained in the patent claims do not represent a limitation of the scope of the subject matter protected by the patent claims. They serve solely to make the patent claims easier to understand. BRIEF DESCRIPTION OF THE FIGURES

[0032] In the following, the invention is further explained and described with reference to preferred embodiments shown in the figures.

[0033] Fig. 1 is a flow diagram of a method according to the invention and at the same time a block diagram of an apparatus according to the invention for separating particles from different plastics.

[0034] FIGURE DESCRIPTION

[0035] Fig. 1 explains the sequence of a method according to the invention and at the same time the structure of a device 1 according to the invention. Starting material 2 can be so-called cable recyclate 3, the essential components of which can be polyvinyl chloride with plasticizer (PVC-w), polyethylene (PE), polyamide (PA), polyurethane (PU), fluoroelastomer, silicone elastomer, ethylene-propylene-diene rubber (EPDM), polyethylene terephthalate (PET), cellulose acetate (CA), copper (Cu) and / or aluminum (AI). By grinding and sieving 4 in a particle size adjustment device 5, particles 6 with an average particle size in the range of 1 to 6 mm are obtained. In the process, a fine fraction 7, i.e. so-called fines, is separated from the particles 6.

[0036] In a subsequent first density separation 8 in a density separator 9, the particles 6 are suspended in a first liquid 10 with a first density of 1.00 g / cm 3suspended and then into floating first light particles 11 with a density of less than 1 ,00 g / cm 3 and sinking first heavy particles 12 with a density of at least 1 .00 g / cm 3 separated. The first light particles 11 are at least predominantly particles of low-density PE and EPDM.

[0037] The first heavy particles 12 are subjected to a first drying step 13 in a first dryer 14. The first drying step 11 results in first dried particles 15. During an eddy current separation 16 in an eddy current separator 17, electrically conductive particles 18 that are not ferromagnetic are separated. The electrically conductive particles 18 consist at least predominantly of aluminum, copper, and electrically conductive EPDM.

[0038] The remaining first dried particles 15 are subjected to a first electrostatic separation 19 in a first electrostatic separator 20. The first dried particles 15 are separated into a first fraction 21, a second fraction 22, and a third fraction 23. The third fraction 23 comprises negatively electrostatically charged particles and consists at least predominantly of the higher-density EPDM not yet separated. The first fraction 21 comprises neutral, i.e., weakly electrostatically charged particles and at least predominantly of PVC-w. The second fraction 22 comprises the positively electrostatically charged first dried particles 15.

[0039] The second fraction 22 is subjected to a second density separation 24 using a second liquid 25 with a density of 1.22 g / cm 3in a second density separator 26 and thereby into second light particles 27 with a density of less than 1.22 g / cm 3 and second heavy particles 28 with a density of at least 1.22 g / cm 3 separated. The second light particles 27 are dried in a second drying process 29 in a second dryer 30 to form second dried particles 31. The second dried particles 31 are subjected to a second electrostatic separation 32 in a second electrostatic separator 33.

[0040] The second electrostatic separation 32 divides the second dried particles 31 into two further fractions 34 and 35 consisting of particles with different electrostatic charges. One fraction 34 comprises the negatively or less strongly positively charged particles, which consist at least predominantly of PA, while the other fraction 35 comprises the more positively charged particles, which consist at least predominantly of PU.

[0041] The heavy second particles 28 comprise particles of fluoroelastomer, silicone elastomer, PET and CA and can also be dried and subjected to further electrostatic separation, which is not shown here.

[0042] The process according to the invention utilizes both differences in the density of the plastics contained in the starting material 2, i.e., the cable recyclate 3, as well as different electrostatic charge capacities, as listed in the following table. The capacity in microcoulombs per square meter indicates the area-specific electrostatic charge to which the (non-conductive) particles of the respective plastic can be electrostatically charged under the same conditions.

[0043] Electrostatic separation does not separate directly based on capacitance, i.e. the strength of the chargeability. For electrostatic separation to occur, a difference in capacitance must exist. In a mixture of three plastics, the plastic with a medium capacitance behaves neutrally when electro-optically charged, for example through friction, i.e. the corresponding particles do not become significantly electrostatically charged. The particles from plastics with high capacity are positively charged; those with low capacity are negatively charged. This applies even though all of the plastics mentioned have positive values ​​for their capacitance. For example, PVC-w behaves neutrally, while PA, PU, ​​PET, CA, silicone and fluoroelastomer are positively charged, and PE and EPDM rubber are negatively charged.

[0044] LIST OF REFERENCE SYMBOLS

[0045] device

[0046] Source material

[0047] Recycled cable

[0048] Grinding and sieving

[0049] Particle size adjustment device

[0050] particles

[0051] Fine fraction

[0052] First density separation

[0053] First density separator

[0054] First liquid

[0055] First light particles

[0056] First heavy particle

[0057] First drying

[0058] First dryer

[0059] First dried particles

[0060] Eddy current separation

[0061] We use current se pa rato r

[0062] Non-ferromagnetic electrically conductive particles

[0063] First electrostatic separation

[0064] First electrostatic separator

[0065] First Group

[0066] Second Group

[0067] Third Group

[0068] Second density separation

[0069] Second liquid

[0070] Second density separator

[0071] Second light particles

[0072] Second heavy particles

[0073] Second drying

[0074] Other faction

[0075] Second dried particles

[0076] Second electrostatic separation Second electrostatic separator Further fraction Further fraction

Claims

PATENT CLAIMS 1. A method for separating particles (6) made of different plastics, wherein the particles (6) are suspended in a first liquid (10) having a first density and are separated into first light particles (11) having a density lower than the first density and into first heavy particles (12) having a density at least equal to the first density, wherein at least the first light particles (11) or the first heavy particles (12) are dried to form first dried particles (15), and wherein the first dried particles (15) are separated by a first electrostatic separation (19) based on their dielectric properties into at least a first fraction (21) and a second fraction (22),wherein the particles of the second fraction (22) are electrostatically chargeable and wherein the particles of the first fraction (21) are not electrostatically charged or are charged differently than the electrostatically chargeable particles of the second fraction (22) due to their dielectric properties, characterized in that the electrostatically chargeable particles of the second fraction (22) are suspended in a second liquid (25) with a second density different from the first density and are separated into second light particles (27) with a lower density than the second density and into second heavy particles (28) with a density at least equal to the second density,wherein at least the second light particles (27) or the second heavy particles (28) are dried to form second dried particles (31), and wherein the second dried particles (31) are separated into at least two further fractions (34, 35) by a second electrostatic separation (32) based on their dielectric properties.

2. The method according to claim 1, wherein at least the first liquid (10) or the second liquid (25) having the greater of the first density and the second density is based on a solution of sodium phosphinate in water.

3. The method according to claim 1 or 2, wherein at least the first liquid (10) or the second liquid (25) comprises 5 to 10 weight percent ethanol.

4. A method according to any one of the preceding claims, wherein the first density is 1.00 g / cm 3 + / - 0.03 g / cm 3 and preferably 1.00 g / cm 3 + / - 0.01 g / cm 3and wherein the first heavy particles (12) are dried, preferably mechanically and thermally, to form the first dried particles (15).

5. The method according to claim 4, wherein the first lightweight particles (11) consist at least predominantly of low density polyethylene (PE) and / or ethylene propylene diene monomer (EPDM).

6. The method according to any one of the preceding claims, wherein the first dried particles (15) are separated into the first fraction (21), the second fraction (22) and a third fraction (23), optionally wherein the first fraction (21) comprises particles without electrostatic charge, the second fraction (22) comprises particles with a positive electrostatic charge and the third fraction (23) comprises particles with a negative electrostatic charge.

7. The method according to claim 6 as dependent on claim 4 or 5, wherein the first fraction (21) consists at least predominantly of polyvinyl chloride with plasticizer (PVC-w) and the third fraction (23) consists at least predominantly of ethylene propylene diene monomer (EPDM) of higher density.

8. A method according to any one of the preceding claims, wherein the second density is 1.23 g / cm 3 + / - 0.03 g / cm 3 and preferably 1.23 g / cm 3 + / - 0.01 g / cm 3 and wherein the second light particles (27) are dried, preferably mechanically and thermally, to form the second dried particles (31).

9. The method according to claim 8, wherein the second dried particles (31) consist at least predominantly of polyamide (PA) and polyurethane (PU) and are separated by the second electrostatic separation (32) into a further fraction (34) at least predominantly of PA and another further fraction (35) at least predominantly of PU and wherein the second heavy particles (28) consist at least predominantly of fluoroelastomer, silicone elastomer, polyethylene terephthalate (PET) and / or cellulose acetate (CA).

10. Method according to one of the preceding claims, wherein electrically conductive particles (18) are separated, optionally by eddy current separation.

11. A method according to any one of the preceding claims, wherein ferromagnetic particles are separated, optionally by magnetic separation.

12. A method according to any one of the preceding claims, wherein electrically polarizable particles are separated, optionally by E-field gradient separation.

13. The method according to any one of the preceding claims, wherein a particle size of the particles (6) is adjusted so that all particles fall within a range of 1 mm to 6 mm, optionally by grinding and sieving (4).

14. The method according to claim 13, wherein the particle size of the particles (6) is adjusted to a value with an accuracy of + / - 1.5 mm and preferably of + / - 1.0 mm.

15. A device (1) for separating particles (6) made of different plastics, comprising a first density separator (9) designed to separate the particles (6) suspended in a first liquid (10) having a first density into first light particles (11) having a density lower than the first density and into first heavy particles (12) having a density at least equal to the first density, a first dryer (14) designed and arranged to dry the first light particles (11) or the first heavy particles (12) into first dried particles (15), and a first electrostatic separator (20) designed and arranged to separate the first dried particles (15) by a first electrostatic separation (19) based on their dielectric properties at least into a first fraction (21) and a second fraction (22),wherein the particles of the second fraction (22) are electrostatically chargeable and wherein the particles of the first fraction (21) are not electrostatically charged or are charged differently than the electrostatically chargeable particles of the second fraction (22) due to their dielectric properties, characterized by a second density separator (26) which is designed to separate the electrostatically chargeable particles of the second fraction (22) suspended in a second liquid (25) with a second density into second light particles (27) with a lower density than the second, Density and into second heavy particles (28) with a density at least of the second density, a second dryer (30) which is designed and arranged to dry the second light particles (27) or the second heavy particles (28) to second dried particles (31), and a second electrostatic separator (33) which is designed and arranged to separate the second dried particles (31) by a second electrostatic separation (32) into at least two further fractions (34, 35) on the basis of their dielectric properties.

16. The apparatus of claim 15, wherein the first dryer (14) is arranged to dry the first heavy particles (12) to the first dried particles (15).

17. Apparatus according to claim 15 or 16, wherein the first electrostatic separator (20) is configured to separate the first dried particles (15) into the first fraction (21), the second fraction (22) and a third fraction (21), wherein optionally the first fraction (21) comprises particles without electrostatic charge, the second fraction (22) comprises particles with a positive electrostatic charge and the third fraction (23) comprises particles with a negative electrostatic charge.

18. Apparatus according to claim 15, 16 or 17, wherein the second dryer (30) is arranged to dry the second light particles (27) to the second dried particles (31).

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