Multi-agent cosmetic composition, and multi-agent hair dyeing or bleaching composition

Abstract

The present invention pertains to a multi-agent cosmetic composition having both physical properties that exhibit good adhesion for preventing dripping during mixing at the time of use or during application to keratin tissue such as skin or hair, and physical properties that exhibit ease of spreading after the application.　Specifically, the present invention pertains to a multi-agent cosmetic composition that contains the following components (A) an ionic surfactant, (B) a cationic polymer, (C) a higher alcohol, and (D) a nonionic surfactant, that contains a plurality of constituent agents including an agent I and an agent II that have different viscosities at least at 30℃, and that is to be used by mixing all of the constituent agents at the time of use. The viscosity ratio (agent II / agent I) of the viscosity of the agent II at 30°C to the viscosity of the agent I at 30°C is 3 or more, and, in a mixture obtained by mixing all the constituent agents, the ratio (shear viscosity a / shear viscosity b) of the shear viscosity a at a shear rate of 0.0037 S-1 to the shear viscosity b at a shear rate of 139 S-1 measured at 25°C by a rheometer when the shear rate is changed from 0.001 S-1 to 1000 S-1 is 5000 or more.

Description

Multi-component cosmetic composition and multi-component hair dyeing or bleaching composition

[0001] The present invention relates to a multi-component cosmetic composition and a multi-component hair dyeing or bleaching composition.

[0002] Cosmetics with a wide variety of formulations and compositions are known to provide various functions and effects to meet the needs of a wide variety of users, and some cosmetics are composed of multiple agents that are mixed together before use. For example, Patent Document 1 discloses a multi-agent cosmetic that includes an oil-based cosmetic and an oil-in-water emulsion cosmetic, each containing specific ingredients, and is mixed together before use and applied to keratinous tissue, and aims to improve the fragrance after mixing. Furthermore, Patent Document 2 discloses a hair bleaching or hair dyeing cosmetic that includes a first agent of a specific viscosity containing an alkaline agent and a second agent of a specific viscosity containing hydrogen peroxide, and the mixture of the first and second agents contains specific ingredients in a specific mass ratio. This cosmetic product attempts to improve adhesion to hair at the initial stage of application and facilitate spreading after a certain period of time has passed.

[0003] (Patent Document 1) JP 2020-200285 A (Patent Document 2) JP 2016-113462 A

[0004] The present invention provides a multi-component cosmetic composition comprising the following components (A) to (D): (A) an ionic surfactant, (B) a cationic polymer, (C) a higher alcohol, and (D) a nonionic surfactant, the composition comprising a plurality of components including an agent I and an agent II having different viscosities at at least 30°C, the composition being prepared by mixing all of the components together at the time of use, wherein the viscosity ratio (agent II / agent I) of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C is 3 or more, and the viscosity of the mixture obtained by mixing all of the components is 0.001 S when measured at 25°C using a rheometer. -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 The present invention provides a multi-component cosmetic composition in which the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5,000 or more.

[0005] The present invention also provides a cosmetic kit comprising a multi-component cosmetic composition and a treatment agent composition which is separate and independent from the other and which contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), wherein the multi-component cosmetic composition contains the following components (A) to (D): (A) an ionic surfactant (B) a cationic polymer (C) a higher alcohol (D) a nonionic surfactant, and comprises a plurality of component parts including component I and component II which have at least different viscosities at 30°C, and all of the component parts are mixed together at the time of use, wherein the viscosity ratio (component II / component I) between the viscosity of component II at 30°C and the viscosity of component I at 30°C is 3 or greater, and the viscosity of the mixture obtained by mixing all of the component parts is 0.001 S when measured at 25°C with a rheometer. -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 The present invention provides a cosmetic kit in which the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5,000 or more.

[0006] Furthermore, the present invention provides a multi-component hair dyeing or bleaching composition comprising a plurality of components including component I' and component II', which are mixed together at the time of use, wherein component I' contains the following components (A'-1) and (B'): (A'-1) an anionic surfactant (B') a cationic polymer, and component II' contains the following components (C') and (D''): (C') a higher alcohol (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A arepresents an alkylene group having 2 to 4 carbon atoms, and r' represents a number of 30 to 200 on average), and the content of component (D'') in a mixture obtained by mixing all of the constituent components is 0.6 mass% or more.

[0007] Incidentally, when applying such multi-component cosmetics to skin, hair, etc., it is highly desirable that the cosmetics exhibit excellent adhesion so that they do not drip unnecessarily from the hands, applicators, the target, etc. when mixing them during use or when applying them to the target, and that once applied, they spread easily and smoothly on the target. However, since improving adhesion to prevent unwanted dripping and achieving easy spreadability depend on mutually contradictory physical properties, it is extremely difficult to fully achieve both of these goals even if simple viscosity control, etc. is implemented in multi-component cosmetics, and there is also the risk that this will be affected by the temperature environment. For this reason, detailed investigation has yet to be conducted on any of the technologies described in the above patent documents, and the goal has yet to be achieved.

[0008] That is, the present invention relates to a multi-component cosmetic composition that combines physical properties that exhibit good adhesion to prevent dripping when mixed during use or when applied to keratinous tissues such as skin or hair, and physical properties that exhibit ease of spreadability after application.The present invention also relates to a multi-component hair dyeing or bleaching composition that, even when the multiple constituent components contained therein are mixed in a high-temperature environment during use, exhibits excellent mixability, maintains the good properties and performance of the resulting mixture, and enables the achievement of a uniform hair color on the target hair.

[0009] Therefore, the present inventors conducted extensive research and found that by forming a multi-component cosmetic composition that contains an ionic surfactant, a cationic polymer, a higher alcohol, and a nonionic surfactant, and that comprises multiple components including at least two components with different viscosities, and that is mixed together at the time of use, when applied to keratinous tissues such as skin and hair, the composition has excellent adhesion, preventing dripping, while being very easy to spread, and also providing a smooth feel to the touch, which led to the completion of the present invention. Furthermore, when hair is the target of application, the present inventors have discovered that a composition in which all of the constituent components are mixed at the time of use, the composition comprising two constituent components, one containing an anionic surfactant and a cationic polymer, and the other containing a higher alcohol and a nonionic surfactant containing a specific polyoxyalkylene alkyl ether, and that the mixture obtained by mixing all of the constituent components contains a specific amount of the nonionic surfactant containing the specific polyoxyalkylene alkyl ether, thereby achieving excellent mixability regardless of the temperature environment when all of the constituent components are mixed at the time of use, and that the resulting mixture appropriately maintains good properties and performance, allowing for highly uniform hair coloring or bleaching, and have thus completed the present invention.

[0010] The multi-component cosmetic composition of the present invention exhibits good adhesion that effectively prevents unwanted dripping when the components are mixed or applied to keratinous tissue during use, and also exhibits excellent spreadability that makes it easy to spread and apply after application to keratinous tissue. This also promotes the penetration of the multi-component cosmetic composition of the present invention into keratinous tissue, allowing the desired effect on keratinous tissue to be fully exerted. Furthermore, by forming a cosmetic kit that includes the multi-component cosmetic composition and a separate, independent treatment composition, the desired effect on keratinous tissue can be more effectively and practically exerted. Furthermore, in the case of the multi-component hair dyeing or bleaching composition of the present invention, which is intended for application to hair, the composition exhibits excellent mixability and effectively suppresses excessive foaming and other problems, even when all of the components are mixed in a high-temperature environment, effectively suppressing unwanted variations in the properties and performance of the resulting mixture, enabling hair dyeing or bleaching to impart a highly uniform hair color from root to tip. Therefore, it is possible to achieve a uniform finish even on hair that has a color difference from the root to the tip. Detailed Description of the Invention

[0011] The present invention will be described in detail below. In the present invention, "adhesion" refers to the property of the composition firmly and tightly adhering to the hand, applicator, or the keratinous tissue to which it is applied, preventing unwanted dripping, when the composition is applied to keratinous tissue. "Spreadability" refers to the property of the composition spreading evenly over the target without being unevenly distributed in a specific area, resulting in a smooth, extensible feel along the application direction. "Penetration" refers to the property of the composition reaching the entire keratinous tissue, particularly when the keratinous tissue is a hair bundle containing hair, and being evenly applied. "Applicability" refers to the property of the composition reaching the entire keratinous tissue, from the surface to the inside, and being evenly applied. "Applicability" refers to the property of the composition exhibiting a balanced combination of the three physical properties of adhesion to keratinous tissue, spreadability, and penetration. "Highly uniform hair color" refers to the property of exhibiting a uniform hair color without unevenness throughout the entire application area, from the roots to the tips. Furthermore, in the mixture obtained by mixing all the constituent ingredients at the time of use, "good properties and performance" means the ability to effectively suppress excessive foaming even when all the constituent ingredients are mixed in a high-temperature environment and maintain the ability to develop a highly uniform hair color, and as will be described later, this can be evaluated by the suppression of foaming of the mixture. Furthermore, "average number of added moles" means the average number of alkylene oxide units bonded to the surfactant molecules, and is a value determined by reverse-phase liquid chromatography or size exclusion chromatography.

[0012] The multi-component cosmetic composition of the present invention is a multi-component composition comprising multiple constituents, including two components, component I and component II, which have different viscosities at at least 30°C, and is a composition in which, at the time of use, all of the constituents, including these two components, are mixed together in advance to form a mixture, which is then applied to keratinous tissue. The keratinous tissue to which the multi-component cosmetic composition of the present invention is applied refers to the keratin-containing layer that protects the outermost layer of the body surface of mammals such as humans, and specific examples include skin, hair, body hair other than hair, toenails, and fingernails. Of the keratinous tissues to which the composition is applied, skin or hair is preferred, and hair is more preferred, from the perspective of fully enjoying the effects of the present invention.

[0013] The multi-component cosmetic composition of the present invention contains at least two components, agent I and agent II, and may contain other components in addition to these two components as constituents of the multi-component cosmetic composition of the present invention. Thus, it may be a two-component cosmetic composition containing agents I and II as constituents, or it may be a three-component cosmetic composition, four-component cosmetic composition, or five-component cosmetic composition that contains one or more constituents in addition to agents I and II, or a cosmetic composition that contains five or more constituents.

[0014] The agents I and II contained in the multi-component cosmetic composition of the present invention have different viscosities at 30°C, and the viscosity ratio of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) is 3 or greater. The multi-component cosmetic composition of the present invention comprises two agents having such a viscosity relationship, and also contains specific components (A) to (D) as described below. When all of the constituent agents are mixed, the resulting mixture can exhibit unique viscosity characteristics. The reason why the composition of the present invention exhibits such effects is unclear, but is presumed to be as follows. The agents I and II contained in the multi-component cosmetic composition of the present invention have different viscosities at 30°C, and the viscosity ratio of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) is 3 or greater, thereby enhancing the permeability of the mixture of agent I and agent II into keratinous tissues. Furthermore, when the mixture is mixed, a coacervate complex is formed, and this complex is the cause of the viscosity of the mixture obtained by mixing all of the constituent agents at a shear rate of 0.0037 S. -1 Shear viscosity a and shear rate at 139S -1Since the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5,000 or more, it is presumed that the adhesion of the mixture is enhanced, and that when the mixture is subjected to shear, the viscosity decreases, resulting in increased extensibility. Furthermore, the three physical properties of the mixture, i.e., penetration into keratinous tissues, adhesion, and extensibility, are well balanced, thereby improving the applicability to keratinous tissues. When used as a hair coloring or bleaching composition, the composition is presumed to instantly penetrate deep into hair strands, easily achieving highly uniform hair coloring or bleaching. Furthermore, in the case of the multi-component hair coloring or bleaching composition of the present invention, which is intended for application to hair, even when all of the components are mixed under high-temperature conditions, the composition exhibits excellent mixability, effectively suppresses excessive foaming, and effectively suppresses unwanted variations in the properties and performance of the resulting mixture, thereby enabling hair coloring or bleaching to impart a highly uniform hair color from root to tip. Therefore, a uniform finish can be achieved even on hair that has color variations from root to tip. The reason why the composition of the present invention exhibits such effects is unclear, but is presumed to be as follows. By selecting a polyoxyalkylene alkyl ether in which the average number of moles of alkyleneoxy groups added is in the range of 30 to 200 as the nonionic surfactant, the structure of the mixture can be maintained by the entanglement of molecules in the alkyleneoxy chain moiety, and it is presumed that the properties and performance of the mixture can be maintained without being destroyed by mixing even when mixed in a high-temperature environment. As a result, it is thought that a uniform finish can be achieved on hair that has color variations from the roots to the tips.

[0015] The viscosity ratio of the viscosity of Agent II at 30°C to the viscosity of Agent I at 30°C (Agent II / Agent I) (the value obtained by dividing the viscosity of Agent II at 30°C by the viscosity of Agent I at 30°C) is, from the viewpoint of exhibiting good penetration into keratinous tissues, 3 or more, preferably 100 or more, more preferably 800 or more, even more preferably 1200 or more, still more preferably 1500 or more, and preferably 6000 or less, more preferably 5000 or less, even more preferably 4000 or less, and still more preferably 3000 or less. The viscosity ratio of the viscosity of Agent II at 30°C to the viscosity of Agent I at 30°C (Agent II / Agent I) is 3 or more, preferably 100 to 6000, more preferably 800 to 5000, even more preferably 1200 to 4000, and still more preferably 1500 to 3000.

[0016] The viscosity of agent I at 30°C may be lower than that of agent II so long as the above viscosity ratio is maintained, but is preferably 5000 mPa s or less, more preferably 3000 mPa s or less, and even more preferably 1 mPa s or more.

[0017] The viscosity of the second agent at 30°C may be higher than that of the first agent so long as the above viscosity ratio is maintained, but is preferably 1000 mPa s or more, more preferably 3000 mPa s or more, even more preferably 5000 mPa s or more, and is preferably 50,000 mPa s or less, more preferably 40,000 mPa s or less, and even more preferably 30,000 mPa s or less.

[0018] The viscosity at 30°C refers to a value measured using a Brookfield viscometer, and specifically, is measured by the method described in the examples.

[0019] When using the multi-component cosmetic composition of the present invention, all of the components, including the two components I and II, are mixed in advance, and the resulting mixture is applied to keratinous tissue. The mixture obtained by mixing all of the components is applied to keratinous tissue at a shear rate of 0.001 S, as measured by a rheometer at 25°C. -1 ~1000S-1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 The ratio of shear viscosity a to shear viscosity b at shear rate a (shear viscosity a / shear viscosity b) is 5000 or more. Here, the rheometer is a rotational rheometer, and for example, an MCR301 manufactured by Anton Paar can be used to examine the shear rate dependency of the shear viscosity of the multi-component cosmetic composition of the present invention as a mixture obtained by mixing all of the constituent ingredients. Note that at a shear rate of 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 Specifically, the ratio of shear viscosity a to shear viscosity b at a shear rate of 0.0037 S (shear viscosity a / shear viscosity b) is measured by the method described in the Examples. -1 The shear viscosity a at a shear rate of 139S -1 The shear viscosity b is calculated by dividing the former by the latter.

[0020] For example, the shear rate is in the low speed range of 0.0037 S -1 Shear viscosity a at 139 S -1 A composition having a small ratio of shear viscosity a to shear viscosity b at a shear rate of 0.0037 (shear viscosity a / shear viscosity b) either has good adhesion but is difficult to spread, or has no adhesion but is easy to spread. On the other hand, when this ratio is very large, the composition has physical properties of having excellent adhesion and also having good ease of spreading. Therefore, the multi-component cosmetic composition of the present invention has a shear rate of 0.0037 when the mixture obtained by mixing all of the constituent ingredients is -1 Shear viscosity a and shear rate at 139S -1 It is believed that when the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5,000 or more, the formed coacervate complex is one of the factors that contribute to the development of both good adhesion and excellent extensibility during use.

[0021] In the mixture, the shear rate is 0.0037 -1 Shear viscosity a and shear rate at 139S -1From the viewpoint of exhibiting both good adhesion and excellent extensibility, the ratio of shear viscosity a to shear viscosity b at a shear rate of 0.0037 (shear viscosity a / shear viscosity b) is 5,000 or more, preferably 6,000 or more, more preferably 7,000 or more, and preferably 20,000 or less, more preferably 18,000 or less, and even more preferably 10,200 or less. -1 Shear viscosity a and shear rate at 139S -1 The ratio of shear viscosity a to shear viscosity b (shear viscosity a / shear viscosity b) is 5,000 or more, preferably 5,000 to 20,000, more preferably 6,000 to 18,000, and even more preferably 7,000 to 10,200.

[0022] The multi-component cosmetic composition of the present invention contains an ionic surfactant as component (A), a cationic polymer as component (B), a higher alcohol as component (C), and a nonionic surfactant as component (D). Unless otherwise specified below, the content of each component contained in the multi-component cosmetic composition of the present invention is indicated as a value relative to the total amount of the multi-component cosmetic composition of the present invention, i.e., the total amount of the mixture obtained by mixing all of the constituent components, which is 100% by mass.

[0023] The multi-component cosmetic composition of the present invention contains an ionic surfactant as component (A). Specifically, component (A) preferably contains one or more surfactants selected from anionic surfactants (A-1) and cationic surfactants (A-2).

[0024] The anionic surfactant of component (A-1) preferably contains an anionic surfactant having a sulfate group. Specifically, it is preferable to contain one or more selected from alkyl sulfates, alkenyl sulfates, polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, and polyoxyalkylene alkylphenyl ether sulfates. The number of carbon atoms in the alkyl or alkenyl group of component (A-1) is preferably 6 to 18, more preferably 12 to 18. More specifically, it is preferable to contain a lauryl or lauroyl group, or a stearyl or stearoyl group as a preferred alkyl or alkenyl group. Of these, it is preferable to contain a polyoxyalkylene alkyl ether sulfate, and the average number of moles of ethylene oxide added in such a polyoxyalkylene alkyl ether sulfate is preferably 1 to 4, more preferably 1 to 2.

[0025] The cationic surfactant of component (A-2) preferably contains a cationic surfactant having a quaternary ammonium group represented by the following formula (1):

[0026]

[0027] (In formula (1), R 1 , R 2 , R 3 and R 4 each independently represents a hydrocarbon group which may have a substituent, and R 1 , R 2 , R 3 and R 4 One or two of X1 have 8 to 36 carbon atoms, and the remainder have 1 to 7 carbon atoms. - indicates an anion.)

[0028] The hydrocarbon group preferably contains a linear or branched alkyl group, a linear or branched alkenyl group, an aryl group, or an aralkyl group, and the substituent preferably contains a hydroxy group, an alkoxy group, an aryloxy group, an epoxy group, an amino group, a mono- or di-alkylamino group, a trialkylammonium group, a fatty acid amide group, or a fatty acid ester group.

[0029] R 1 , R 2 , R 3 and R 4 One or two (preferably one) of R is a linear or branched alkyl group, and the number of carbon atoms therein is preferably 8 to 30, more preferably 10 to 24, and even more preferably 12 to 18. 1 , R 2 , R 3 and R 4 The remainder of the above is an alkyl group, preferably having 1 to 3 carbon atoms, more preferably 1 or 2, and even more preferably 1 carbon atom.

[0030] X - Examples of the cation include chloride ion, bromide ion, iodide ion, methyl sulfate ion, ethyl sulfate ion, acetate ion, phosphate ion, sulfate ion, lactate ion, and saccharin ion. Among these, chloride ion or bromide ion is preferred from the viewpoint of availability.

[0031] Specific examples of such component (A-2) include cetyltrimethylammonium chloride (cetrimonium chloride), stearyltrimethylammonium chloride (steartrimonium chloride), isostearyltrimethylammonium chloride (isostearyltrimonium chloride), lauryltrimethylammonium chloride (lauryltrimonium chloride), behenyltrimethylammonium chloride (behentrimonium chloride), cocoyltrimethylammonium chloride (cocotrimonium chloride), cetyltrimethylammonium bromide (cetrimonium chloride), It is preferable that the ammonium bromide contains one or more selected from the group consisting of stearyltrimethylammonium bromide (steartrimonium bromide), lauryltrimethylammonium bromide (lauryltrimonium bromide), isostearyl lauryl dimethylammonium chloride (isostearyl lauryl dimonium chloride), dicetyl dimethyl ammonium chloride (dicetyldimonium chloride), distearyl dimethyl ammonium chloride (distearyldimonium chloride), and dicocoyl dimethyl ammonium chloride (dicoccodimonium chloride).

[0032] Among these, component (A-2) preferably contains one or more selected from monoalkyltrimethylammonium chloride and monoalkyltrimethylammonium bromide, and more preferably contains one or more selected from stearyltrimethylammonium chloride (steartrimonium chloride), cetyltrimethylammonium chloride (cetrimonium chloride), and lauryltrimethylammonium chloride (lauryltrimonium chloride).

[0033] From the viewpoint of exhibiting good adhesion and excellent extensibility, it is preferable that the mixture contains both an anionic surfactant (A-1) and a cationic surfactant (A-2) as the component (A).

[0034] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (A) in the multi-component cosmetic composition of the present invention is preferably 0.48% by mass or more, more preferably 0.60% by mass or more, even more preferably 0.96% by mass or more, and preferably 1.99% by mass or less, more preferably 1.8% by mass or less, and even more preferably 1.44% by mass or less. The content of component (A) in the multi-component cosmetic composition of the present invention is preferably 0.48 to 1.99% by mass, more preferably 0.60 to 1.8% by mass, and even more preferably 0.96 to 1.44% by mass.

[0035] The multi-component cosmetic composition of the present invention contains a cationic polymer as component (B). The term "cationic polymer" refers to a polymer having a substituent that becomes cationic when dissolved in water.

[0036] Specifically, the component (B) preferably contains one or more selected from the group consisting of a polymer containing a diallyl quaternary ammonium salt as a constituent unit, a cationized polygalactomannan, a cationized hydroxyalkyl cellulose, a copolymer containing methacrylamide propyl trimethyl ammonium chloride, and a crosslinked cationic polymer.

[0037] The polymer containing a diallyl quaternary ammonium salt as a constituent unit preferably contains a polymer represented by the following formula (2) or (3).

[0038]

[0039] (In formula (2) or (3), R 5 and R 6 may be the same or different and represent a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an aryl group (e.g., a phenyl group), a hydroxyalkyl group, an amidoalkyl group, a cyanoalkyl group, an alkoxyalkyl group, or a carboalkoxyalkyl group; R 7 and R 8 may be the same or different and represent a hydrogen atom, an alkyl group having 1 to 3 carbon atoms, or a phenyl group; X2 -represents an anion (chloride ion, bromide ion, iodide ion, sulfate anion, sulfonate anion, methyl sulfate anion, phosphate anion, nitrate anion, etc.).

[0040] From the viewpoint of effectively achieving both good adhesion and excellent extensibility, the polymer containing a diallyl quaternary ammonium salt as a structural unit preferably contains 85 to 100 mol %, more preferably 90 to 100 mol %, and even more preferably 95 to 100 mol % of the structural unit represented by formula (2) or (3) per molecule. The mass average molecular weight is preferably 10,000 or more, more preferably 50,000 or more, even more preferably 100,000 or more, and preferably 3,000,000 or less, more preferably 1,000,000 or less, and even more preferably 200,000 or less.

[0041] The mass average molecular weight refers to a value measured by gel permeation chromatography (GPC) under the following conditions: Mobile phase: 50 mM LiBr, 1% by mass CH3COOH / ethanol:water=3:7 Column: TSK gel α-M (two columns in series) Standard: polyethylene glycol

[0042] More specifically, the cationized polygalactomannan of component (B) preferably contains one or more selected from cationized guar gum, cationized tara gum, and cationized locust bean gum. More specifically, the cationized hydroxyalkyl cellulose of component (B) preferably contains one or two selected from cationized hydroxyethyl cellulose and cationized hydroxypropyl cellulose. The copolymer containing methacrylamidepropyltrimethylammonium chloride of component (B) preferably contains one or more selected from acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer and acrylic acid / acrylamide / methacrylamidopropyltrimethylammonium chloride copolymer. More specifically, the crosslinked cationic polymer of component (B) preferably contains N,N-dimethylaminoethyl diethyl methacrylate sulfate / N,N-dimethylacrylamide / polyethylene glycol dimethacrylate copolymer.

[0043] Among such component (B), component (B) preferably contains a polymer containing a diallyl quaternary ammonium salt as a constituent unit, and more preferably contains one or more selected from a homopolymer of a diallyl quaternary ammonium salt and a copolymer of a diallyl quaternary ammonium salt and acrylic acid. More specifically, component (B) preferably contains one or more selected from polydiallyldimethylammonium chloride, diallyldimethylammonium chloride / acrylic acid copolymer, diallyldimethylammonium chloride / acrylamide copolymer, and diallyldimethylammonium chloride / acrylic acid / acrylamide copolymer.

[0044] From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the charge density of component (B) is preferably 4.0 meq / g or more, more preferably 4.3 meq / g or more, even more preferably 4.6 meq / g or more, still more preferably 4.9 meq / g or more, even more preferably 5.2 meq / g or more, even more preferably 5.5 meq / g or more, and preferably 8.0 meq / g or less, more preferably 7.0 meq / g or less, and even more preferably 6.5 meq / g or less. Note that "charge density" means the number of moles of cationic groups per gram of polymer × 1000 (meq / g).

[0045] Of these components (B), it is preferable that component (B) contains a polymer containing a diallyl quaternary ammonium salt as a structural unit, and more specifically, it is preferable that component (B) contains one or more selected from Merquat 100 (manufactured by Lubrizol Advanced Materials, a homopolymer of diallyl quaternary ammonium), MERQUAT 280NP POLYMER, and Merquat 295 POLYMER (all manufactured by Lubrizol Advanced Materials, a copolymer of diallyl quaternary ammonium salt and acrylic acid).

[0046] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (B) in the multi-component cosmetic composition of the present invention is preferably 0.03% by mass or more, more preferably 0.18% by mass or more, even more preferably 0.29% by mass or more, and preferably 0.59% by mass or less, more preferably 0.55% by mass or less, and even more preferably 0.44% by mass or less. The content of component (B) in the multi-component cosmetic composition of the present invention is preferably 0.03 to 0.59% by mass, more preferably 0.18 to 0.55% by mass, and even more preferably 0.29 to 0.44% by mass.

[0047] The multi-component cosmetic composition of the present invention contains a higher alcohol as component (C). Examples of such component (C) include those represented by the following formula (4).

[0048] R 9 -OH...(4) (In formula (4), R 9 represents a straight or branched chain hydrocarbon group having 6 to 36 carbon atoms.

[0049] R 9 From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the number of carbon atoms in is preferably 10 to 24, more preferably 12 to 22, and even more preferably 14 to 22. R9 is preferably a linear or branched alkyl or alkenyl group, and more preferably a linear alkyl group.

[0050] More specifically, such component (C) may include one or more selected from myristyl alcohol, cetyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, oleyl alcohol, etc. Among these, it is preferable to contain one or more selected from cetyl alcohol, stearyl alcohol, and behenyl alcohol, and it is more preferable to contain two or more of these.

[0051] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (C) in the multi-component cosmetic composition of the present invention is preferably 1.52% by mass or more, more preferably 1.9% by mass or more, even more preferably 3.03% by mass or more, and preferably 6.08% by mass or less, more preferably 5.7% by mass or less, and even more preferably 4.54% by mass or less. The content of component (C) in the multi-component cosmetic composition of the present invention is preferably 1.52 to 6.08% by mass, more preferably 1.9 to 5.7% by mass, and even more preferably 3.03 to 4.54% by mass.

[0052] In the multi-component cosmetic composition of the present invention, the mass ratio of the content of component (C) to the content of component (A) ((C) / (A)) is preferably 2 or more, more preferably 2.5 or more, even more preferably 2.77 or more, still more preferably 3.1 or more, and preferably 5 or less, more preferably 3.75 or less, and even more preferably 3.50 or less, from the viewpoint of effectively achieving good adhesion and excellent spreadability. In the multi-component cosmetic composition of the present invention, the mass ratio of the content of component (C) to the content of component (A) ((C) / (A)) is preferably 2 or more, more preferably 2.5 to 5, even more preferably 2.77 to 3.75, and even more preferably 3.1 to 3.50.

[0053] The multi-component cosmetic composition of the present invention contains a nonionic surfactant as component (D). Specifically, component (D) preferably contains one or more surfactants selected from polyoxyalkylene alkyl ethers, alkyl alkanolamides, polyoxyalkylene alkylamines, alkyl polyglucosides, and alkyl glyceryl ethers. The polyoxyalkylene alkyl ether preferably contains one represented by the following formula (5): 10 -O-(A a O) r -H...(5) (In formula (5), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r represents an average number of 1 to 300.

[0054] R 10 From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the number of carbon atoms in is preferably 10 to 22, more preferably 12 to 20, and even more preferably 12 to 18. A is preferably an ethylene group or a propylene group, and more preferably an ethylene group. r is the so-called average number of moles added, and is preferably 1 to 300, more preferably 2 to 250, even more preferably 30 to 200, and even more preferably 90 to 180.

[0055] Among these polyoxyalkylene alkyl ethers, it is preferable to contain those represented by the following formula (5a) or (5b).

[0056]

[0057] (In formula (5a), the sum of m and n is 9 to 11, and p is a number of 3 to 15.) In formula (5a), p means the so-called average number of moles added.

[0058] R 11 -O-(A b O)q-H...(5b) (In formula (5b), R 11 represents a linear saturated hydrocarbon group having 16 carbon atoms, and A b represents an alkylene group having 2 carbon atoms, and q represents an average number of 20 to 200.) In addition, q in formula (5b) means the so-called average number of moles added.

[0059] Examples of the alkyl alkanolamide of component (D) include those represented by the following formula (6).

[0060]

[0061] (In formula (6), R 12 represents a linear or branched, saturated or unsaturated hydrocarbon group having 5 to 23 carbon atoms; R 13 and R 14 each independently represents a hydrogen atom or an alkanol group having 1 to 4 carbon atoms. 13 and R 14 Except when is also a hydrogen atom.)

[0062] R 12 From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the number of carbon atoms is preferably 8 to 22, more preferably 10 to 20, and even more preferably 12 to 18.

[0063] More specifically, such alkyl alkanolamides include one or more selected from coconut oil fatty acid monoethanolamide, coconut oil fatty acid diethanolamide, lauric acid isopropanolamide, and oleic acid diethanolamide.

[0064] Examples of the polyoxyalkylene alkylamine of component (D) include those represented by the following formula (7).

[0065]

[0066] (In formula (7), R 15 represents a linear or branched, saturated or unsaturated hydrocarbon group having 5 to 23 carbon atoms; A c and A d each independently represents an ethylene group or a propylene group, s and t each represent an average value, and the sum of s and t is 5 to 50.

[0067] R 15 From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the number of carbon atoms in A is preferably 8 to 22, more preferably 10 to 20, and even more preferably 12 to 18. c and A d is preferably an ethylene group. The sum of s and t is preferably 8 to 30, more preferably 10 to 20.

[0068] More specifically, such polyoxyalkylene alkylamines include one or more selected from polyoxyethylene laurylamine, polyoxyethylene cetylamine, polyoxyethylene cocamine, and the like.

[0069] Examples of the alkyl polyglucoside of component (D) include those having an alkyl group of 6 to 22 carbon atoms and a condensation degree of the glucoside unit of 1 to 7. Specific examples include one or more selected from octyl polyglucoside, 2-ethylhexyl polyglucoside, decyl polyglucoside, lauryl polyglucoside, myristyl polyglucoside, palmityl polyglucoside, isostearyl polyglucoside, stearyl lauryl polyglucoside, oleyl polyglucoside, and behenyl polyglucoside. Of these, the alkyl polyglucoside of component (D) preferably contains those having an alkyl group of 8 to 18 carbon atoms and a condensation degree of the glucoside unit of 1 to 7.

[0070] More specifically, such alkyl glyceryl ethers include one or more selected from isostearyl glyceryl ether, isostearyl pentaerythryl glyceryl ether, and the like.

[0071] Among these components (D), from the viewpoint of effectively achieving both good adhesion and excellent extensibility, it is preferable that component (D) contains a polyoxyalkylene alkyl ether, and it is more preferable that the polyoxyalkylene alkyl ether contains at least a polyoxyalkylene alkyl ether represented by the above formula (5a) or (5b).

[0072] From the viewpoint of effectively achieving both good adhesion and excellent spreadability, the content of component (D) in the multi-component cosmetic composition of the present invention is preferably 1.63% by mass or more, more preferably 2.04% by mass or more, even more preferably 3.26% by mass or more, and preferably 6.51% by mass or less, more preferably 6.11% by mass or less, and even more preferably 4.95% by mass or less. The content of component (D) in the multi-component cosmetic composition of the present invention is preferably 1.63 to 6.51% by mass, more preferably 2.04 to 6.11% by mass, and even more preferably 3.26 to 4.95% by mass.

[0073] From the viewpoint of further enhancing the good adhesion and excellent spreadability exhibited during use, the multi-component cosmetic composition of the present invention preferably further contains component (E), which is a chloride of one or two compounds selected from alkali metal salts of organic acids having 6 or fewer carbon atoms, alkaline earth metal salts of organic acids having 6 or fewer carbon atoms, inorganic alkali metal salts, and inorganic alkaline earth metal salts. Examples of organic acids constituting alkali metal salts of organic acids having 6 or fewer carbon atoms and alkaline earth metal salts of organic acids having 6 or fewer carbon atoms include acetic acid, carbonic acid, carboxylic acid, and sulfuric acid. Examples of alkali metals in these alkali metal salts include sodium and potassium, and examples of alkaline earth metals in these alkaline earth metal salts include calcium and magnesium. Specifically, the alkali metal salts of organic acids having 6 or fewer carbon atoms and alkaline earth metal salts of organic acids having 6 or fewer carbon atoms preferably contain one or more compounds selected from potassium acetate, calcium acetate, potassium sulfate, and calcium sulfate.

[0074] Examples of the alkali metal in the inorganic alkali metal salt include sodium and potassium, and examples of the alkaline earth metal in the inorganic alkaline earth metal salt include calcium and magnesium. Specific examples of the inorganic alkali metal salt and inorganic alkaline earth metal salt preferably contain one or more selected from potassium chloride, sodium chloride, calcium chloride, magnesium chloride, etc.

[0075] Among these components (E), it is more preferable to contain one or more selected from sodium chloride, magnesium chloride, and potassium chloride as component (E), from the viewpoint of effectively enhancing good adhesion and excellent extensibility.

[0076] The content of component (E) in the multi-component cosmetic composition of the present invention is preferably 0.01% by mass or more, more preferably 0.02% by mass or more, even more preferably 0.03% by mass or more, and preferably 1.33% by mass or less, more preferably 1.2% by mass or less, and even more preferably 1.0% by mass or less. The content of component (E) in the multi-component cosmetic composition of the present invention is preferably 0.01 to 1.33% by mass, more preferably 0.02 to 1.2% by mass, and even more preferably 0.03 to 1.0% by mass.

[0077] The multi-component cosmetic composition of the present invention preferably contains water, from the viewpoint of ensuring the solubility or dispersibility of each component in the mixture and effectively achieving both good adhesion and excellent spreadability. The water content in the multi-component cosmetic composition of the present invention is preferably 50% by mass or more, more preferably 60% by mass or more, even more preferably 65% ​​by mass or more, and preferably 98% by mass or less, more preferably 95% by mass or less, and even more preferably 90% by mass or less. The water content in the multi-component cosmetic composition of the present invention is preferably 50 to 98% by mass, more preferably 60 to 95% by mass, and even more preferably 65 to 90% by mass.

[0078] The multi-component cosmetic composition of the present invention preferably contains a dye, particularly when it is intended for use on hair, i.e., when it is used as a hair cosmetic composition, preferably a composition for hair coloring or hair bleaching. This allows the composition to instantly penetrate deep into the hair strands due to the good adhesion and excellent spreadability that it exhibits during use, making it easy to achieve highly uniform hair coloring or bleaching. Examples of such dyes include oxidation dye intermediates and direct dyes.

[0079] Examples of oxidation dye intermediates include precursors such as paraphenylenediamine, toluene-2,5-diamine, orthochloroparaphenylenediamine, N-phenylparaphenylenediamine, N,N-bis(hydroxyethyl)paraphenylenediamine, 3-methyl-4-aminophenol, 2-hydroxyethylparaphenylenediamine, paraaminophenol, paramethylaminophenol, 4-amino-metacresol, orthoaminophenol, 1-hydroxyethyl-4,5-diaminopyrazole, 2,4,5,6-tetraaminopyrimidine, 2,5,6-triamino-4-pyrimidinol, 2-methoxymethyl-paraphenylenediamine, and salts thereof; Examples of the coupler include one or more couplers selected from the group consisting of resorcinol, 2-methylresorcinol, 1-naphthol, 1,5-dihydroxynaphthalene, 5-amino-o-cresol, meta-phenylenediamine, meta-aminophenol, 2,4-diaminophenoxyethanol, 2,6-diaminopyridine, 2-methyl-5-hydroxyethylaminophenol, 2-amino-3-hydroxypyridine, 4-chlororesorcinol, and salts thereof.

[0080] The content of the oxidation dye intermediate in the multi-component cosmetic composition of the present invention is preferably 0.003% by mass or more, more preferably 0.03% by mass or more, and preferably 1.6% by mass or less, more preferably 1.5% by mass or less.

[0081] Examples of direct dyes include acid dyes such as Blue No. 1, Purple No. 401, Black No. 401, Orange No. 205, Red No. 227, Red No. 106, Yellow No. 203, and Acid Orange 3; nitro dyes such as 2-nitro-p-phenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-p-hydroxyethylaminophenol, 4-nitro-o-phenylenediamine, 4-amino-3-nitrophenol, 4-hydroxypropylamino-3-nitrophenol, HC Blue 2, HC Orange 1, HC Red 1, HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Red 3, and N,N-bis(2-hydroxyethyl)-2-nitro-p-phenylenediamine; and disperse dyes such as Disperse Purple 1, Disperse Blue 1, and Disperse Black 9. One or more dyes selected from basic dyes such as Basic Blue 99, Basic Brown 16, Basic Brown 17, Basic Red 76, Basic Yellow 76, Basic Orange 31, and Basic Red 51; and other dyes such as picramic acid, Basic Purple 2, Basic Yellow 57, Basic Brown 16, Yellow No. 403, Basic Purple 2, Basic Yellow 87, HC Blue 18, HC Yellow 16, HC Red 16, Basic Blue 124, Yellow No. 4, HC Blue 15, and tetrabromophenol blue.

[0082] The multi-component cosmetic composition of the present invention, particularly when it is intended for use on hair, i.e., when it is a hair cosmetic composition, preferably a composition for hair coloring or hair bleaching, preferably contains a dye and also an alkaline agent and hydrogen peroxide. It is also desirable that the alkaline agent and hydrogen peroxide are contained in different components of the multi-component cosmetic composition of the present invention. Furthermore, the composition may contain granulated products such as persulfates.

[0083] Examples of such alkaline agents include one or more selected from ammonia and salts thereof, such as strong aqueous ammonia and ammonium chloride; alkanolamines and salts thereof, such as monoethanolamine, isopropanolamine, 2-amino-2-methylpropanol, and 2-aminobutanol; alkanediamines and salts thereof, such as 1,3-propanediamine; and carbonates, such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, and potassium hydrogencarbonate.

[0084] From the viewpoint of achieving a sufficient hair dyeing or bleaching effect and preventing excessive damage or irritation to the subject of application, the content of the alkaline agent in the multi-component cosmetic composition of the present invention is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, even more preferably 0.2% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less, even more preferably 10% by mass or less, and still more preferably 5% by mass or less. The content of the alkaline agent in the multi-component cosmetic composition of the present invention is preferably 0.05 to 20% by mass, more preferably 0.1 to 15% by mass, even more preferably 0.2 to 10% by mass, and even more preferably 0.2 to 5% by mass.

[0085] Hydrogen peroxide is contained in a component of the multi-component cosmetic composition of the present invention that is different from the component containing the alkaline agent. The content of hydrogen peroxide in the multi-component cosmetic composition of the present invention is preferably 0.5% by mass or more, more preferably 1% by mass or more, even more preferably 2% by mass or more, and preferably 6% by mass or less, more preferably 5% by mass or less.

[0086] The multi-component cosmetic composition of the present invention may contain an oily component as a component other than the above-mentioned components. Specific examples of such oily components include non-volatile silicones such as dimethylpolysiloxane, methylphenylpolysiloxane, polyether-modified silicone, amino-modified silicone, and aminopolyether-modified silicone; low-boiling-point chain silicones such as hexamethyldisiloxane, octamethyltrisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane, and hexadecamethylheptasiloxane; cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane; hydrocarbon oils such as liquid paraffin, liquid isoparaffin, light liquid isoparaffin, polybutene, hydrogenated polydecene, petrolatum, squalane, and isododecane; Ester oils such as diglyceryl isostearate, triglyceryl isostearate, triglyceryl 2-ethylhexanoate (trioctanoin), tri(caprylic / capric)glycerin, isopropyl myristate, isopropyl palmitate, cetyl 2-ethylhexanoate, diisostearyl maleate, 2-heptylundecyl palmitate, isotridecyl isononanoate, and octyldodecyl myristate; waxes such as beeswax, spermaceti, lanolin, carnauba wax, candelilla wax, hydrogenated jojoba oil, and montan wax; and one or more selected from aliphatic alcohols having 1 to 5 carbon atoms, such as methanol, ethanol, propanol, isopropyl alcohol, and butanol.

[0087] The content of the oily component in the multi-component cosmetic composition of the present invention is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, even more preferably 1% by mass or more, and preferably 15% by mass or less, more preferably 10% by mass or less, and even more preferably 3% by mass or less. The content of the oily component in the multi-component cosmetic composition of the present invention is preferably 0.1 to 15% by mass, more preferably 0.3 to 10% by mass, and even more preferably 1 to 3% by mass.

[0088] In addition to the above-mentioned components, the multi-component cosmetic composition of the present invention may contain other components commonly used as cosmetic raw materials, such as fragrances, moisturizers, preservatives, chelating agents, pH adjusters, stabilizers, antioxidants, disinfectants, protein derivatives, hydrolyzed proteins, amino acids, plant extracts, herbal extracts, vitamins, and ultraviolet absorbers.

[0089] However, from the viewpoint of not inhibiting the development of good adhesion and excellent spreadability during use, the multi-component cosmetic composition of the present invention preferably does not contain salicylic acid or acetaminophen, and more preferably does not contain either of these.

[0090] The forms of the constituent components contained in the multi-component cosmetic composition of the present invention, including agent I and agent II, can be appropriately selected from liquid, gel, paste, cream, foam, mist, etc. Among these, from the viewpoint of imparting the above-mentioned viscosity ratio (agent II / agent I) and from the viewpoint of imparting the above-mentioned ratio of shear viscosity a to shear viscosity b (shear viscosity a / shear viscosity b) in the mixture obtained by mixing all the constituent components, it is preferable that agent I be in the form of a liquid and agent II be in the form of a cream. Furthermore, it is preferable that the form of the mixture obtained by mixing all the constituent components contained in the multi-component cosmetic composition of the present invention be in the form of a gel.

[0091] Furthermore, from the viewpoint of promoting the formation of a coacervate complex in a mixture obtained by mixing all of the constituent components, imparting the above-mentioned ratio of shear viscosity a to shear viscosity b (shear viscosity a / shear viscosity b), and effectively exhibiting good adhesion and excellent extensibility, it is preferred that at least component I contain component (A-1) and component (B), and that at least component II contain component (A-2), component (C), and component (D).

[0092] Furthermore, when the multi-component cosmetic composition of the present invention is to be applied to hair, i.e., when it is used as a hair cosmetic composition, preferably a composition for hair coloring or hair bleaching, it is preferable to include the dye in the above-mentioned Agent I, from the viewpoint of allowing the composition to instantly penetrate deep into the hair strands due to the good adhesion and excellent spreadability that are exhibited during use, and easily achieving highly uniform hair coloring or bleaching.

[0093] When obtaining a mixture of all the components contained in the multi-component cosmetic composition of the present invention, the order of mixing these components is not particularly limited, and they may be mixed all at once or may be mixed sequentially as appropriate. In particular, when agent I is in the form of a liquid and agent II is in the form of a cream, it is preferable to add agent I to at least agent II and mix them, from the viewpoint of achieving uniform mixing and more effectively achieving good adhesion and excellent spreadability.

[0094] The present invention relates to a multi-component hair dye or bleach composition for use on hair, more specifically, the composition comprises a plurality of components including component I' and component II', and all of the components are mixed together at the time of use, wherein component I' contains the following components (A'-1) and (B'): (A'-1) an anionic surfactant (B') a cationic polymer, and component II' contains the following components (C') and (D''): (C') a higher alcohol (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents a number of 30 to 200 on average), and the content of component (D'') in a mixture obtained by mixing all of the constituent components is 0.6 mass% or more.

[0095] That is, the multi-component hair dye or bleaching composition of the present invention, which is intended for application to hair, does not necessarily comprise, as in the above-described multi-component cosmetic composition, two components that have different viscosities at 30°C and a specific viscosity ratio (component II / component I), but rather comprises, as component components, an I' component containing components (A'-1) and (B'), and an II' component containing components (C') and (D"), and the content of component (D") in the mixture obtained by mixing all of the components is 0.6 mass% or more. As a result, the multi-component hair dye or bleaching composition of the present invention effectively suppresses excessive foaming and the like, even when the multiple component components are mixed in a high-temperature environment during use, thereby maintaining the good properties and performance of the resulting mixture and enabling the realization of highly uniform hair dyeing or bleaching from the roots to the tips.

[0096] In the agent I' of the multi-component hair dyeing or bleaching composition of the present invention, the anionic surfactant of component (A'-1) contained therein is one or more anionic surfactants selected from the anionic surfactants of component (A-1) that may be contained in the above-mentioned multi-component cosmetic composition and anionic surfactants having a carboxyl group. Examples of such anionic surfactants having a carboxyl group include N-acylamino acid salts, N-acyl-N-alkylamino acid salts, amide-type N-acylamino acid salts, ether carboxylate salts, fatty acid salts, salts of alkyl succinates, and salts of alkenyl succinates. In particular, from the viewpoint of suppressing dripping after application to hair, the anionic surfactant having a carboxyl group in the multi-component cosmetic composition of the present invention preferably contains one or more N-acylamino acids selected from N-lauroyl glutamic acid, N-myristoyl glutamic acid, and N-cocoyl glutamic acid, and more preferably contains N-cocoyl glutamic acid or its sodium salt. Specific examples of the ether carboxylic acid or its salt include polyglyceryl alkyl ether acetic acid or its salt, or ether acetic acid represented by the following formula (8) or its salt. R １６ -Z-(CH ２ CH ２ O) ｘ -CH２ COOM...(8) (In formula (8), R １２ represents a linear or branched alkyl or alkenyl group having 7 to 19 carbon atoms, Z represents -O- or -CONH-, M represents a hydrogen atom, an alkali metal, triethanolamine or ammonium, and x represents a number from 1 to 20. In the above formula (8), R １６ Preferably, x has 11 to 15 carbon atoms, and x is preferably 3 to 15, more preferably 6 to 12. M is preferably an alkali metal, more preferably potassium. More specific examples include polyoxyethylene lauryl ether acetic acid, polyoxyethylene myristyl ether acetic acid, lauric acid amide polyoxyethylene ether acetic acid, and lauric acid amide polyoxyethylene ether acetic acid. Among these, it is preferable to contain one or more selected from polyoxyethylene lauryl ether acetic acid and polyoxyethylene myristyl ether acetic acid, and it is even more preferable to contain polyoxyethylene lauryl ether acetic acid. The content of component (A'-1) in the total amount of agent I' is preferably 1.2% by mass or more, more preferably 1.5% by mass or more, even more preferably 2% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less, and even more preferably 13% by mass or less. Furthermore, the content of component (A'-1) in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the content of component (A'-1) when the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II' is taken as 100% by mass, is preferably 1% by mass or more, more preferably 2% by mass or more, even more preferably 3% by mass or more, and preferably 10% by mass or less, more preferably 5% by mass or less, and even more preferably 4.5% by mass or less. The content of component (A'-1) in the multi-component cosmetic composition of the present invention is preferably 1 to 10% by mass, more preferably 2 to 5% by mass, and even more preferably 3 to 4.5% by mass.

[0097] The component (B') contained in the agent I' of the multi-component hair dye or bleach composition of the present invention is the same as the component (B) contained in the multi-component cosmetic composition. Among such component (B'), for example, a polymer containing a diallyl quaternary ammonium salt as a structural unit preferably contains 20 to 100 mol %, more preferably 30 to 100 mol %, and even more preferably 50 to 100 mol % of the structural unit represented by formula (2) or (3) per molecule, from the viewpoint of effectively achieving both good adhesion and excellent extensibility. Furthermore, the mass-average molecular weight is preferably 10,000 or more, more preferably 50,000 or more, even more preferably 100,000 or more, and preferably 3,000,000 or less, more preferably 1,000,000 or less, and even more preferably 500,000 or less. Furthermore, from the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the charge density of component (B') is preferably 4.0 meq / g or more, more preferably 4.3 meq / g or more, even more preferably 4.6 meq / g or more, still more preferably 4.9 meq / g or more, and even more preferably 5.5 meq / g or more, and is preferably 8.0 meq / g or less, more preferably 7.0 meq / g or less, and even more preferably 6.5 meq / g or less.

[0098] The content of component (B') in the total amount of Agent I' is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, even more preferably 0.7% by mass or more, and preferably 3% by mass or less, more preferably 2% by mass or less, and even more preferably 1.5% by mass or less. Furthermore, the content of component (B') in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the content of component (B') relative to the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II', is preferably 0.03% by mass or more, more preferably 0.18% by mass or more, even more preferably 0.25% by mass or more, and preferably 0.59% by mass or less, more preferably 0.55% by mass or less, and even more preferably 0.44% by mass or less, from the viewpoint of effectively achieving both good adhesion and excellent spreadability. The content of component (B') in the multi-component cosmetic composition of the present invention is preferably 0.03 to 0.59% by mass, more preferably 0.18 to 0.55% by mass, and even more preferably 0.25 to 0.44% by mass.

[0099] The agent II" contained in the multi-component hair dyeing or bleaching composition of the present invention may contain an ionic surfactant (A'-2) other than the anionic surfactant of component (A'-1). Such component (A'-2) is the same as the ionic surfactant other than component (A-1) among the components (A) contained in the multi-component cosmetic composition; that is, component (A'-2) is preferably the cationic surfactant of component (A-2) that may be contained in the multi-component cosmetic composition. The content of component (A'-2) in the total amount of agent II' is preferably 0.3% by mass or more, more preferably 0.4% by mass or more, even more preferably 0.5% by mass or more, and preferably 5% by mass or less, more preferably 2% by mass or less, and even more preferably 1% by mass or less. Furthermore, the content of component (A'-2) in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the content of component (A'-2) relative to the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II', is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, even more preferably 0.3% by mass or more, and preferably 7% by mass or less, more preferably 3% by mass or less, and even more preferably 1% by mass or less. The content of component (A'-2) in the multi-component cosmetic composition of the present invention is preferably 0.1 to 7% by mass, more preferably 0.2 to 3% by mass, and even more preferably 0.3 to 1% by mass.

[0100] In order to fully exert its highly useful hair dyeing or bleaching effect, Agent I' contained in the multi-component hair dyeing or bleaching composition of the present invention preferably contains the same dye as in the multi-component cosmetic composition, and preferably also contains the same alkaline agent as in the multi-component cosmetic composition. The content of the dye in the total amount of Agent I' is preferably 0.01% by mass or more, more preferably 0.1% by mass or more, and preferably 5% by mass or less, and more preferably 4.5% by mass or less. The content of the alkaline agent in the total amount of Agent I' is preferably 0.15% by mass or more, more preferably 0.3% by mass or more, even more preferably 0.6% by mass or more, and preferably 45% by mass or less, more preferably 30% by mass or less, and even more preferably 15% by mass or less. The dye content and alkaline agent content in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the dye content and alkaline agent content, based on 100% by mass of the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II', are the same as the dye content and alkaline agent content in the total amount of the above-mentioned multi-component cosmetic composition, respectively.

[0101] In addition to components (A'-1) and (B'), as well as component (A'-2), the dye, and the alkaline agent, agent I' contained in the multi-component hair dyeing or bleaching composition of the present invention may contain, as appropriate, the following components, within the scope of the effects of the present invention: a higher alcohol for component (C') similar to that of component (C) in the multi-component cosmetic composition; a nonionic surfactant for component (D') similar to that of component (D) in the multi-component cosmetic composition; a chloride for component (E') similar to that of component (E) in the multi-component cosmetic composition; water; and other components commonly used as cosmetic raw materials. However, with regard to the inclusion of component (C'), in particular, from the viewpoint of effectively enhancing the uniformity of hair color while exhibiting excellent penetration and spreadability in hair, it is preferable that only agent II' described below contain the higher alcohol of component (C'), and agent I' does not contain the higher alcohol of component (C'). Furthermore, the nonionic surfactant of component (D') in agent I' preferably contains a nonionic surfactant other than the above-mentioned component (D'') contained in agent II'. When agent I' contains, for example, a polyoxyalkylene alkyl ether represented by the above formula (5a) as component (D'), the content thereof is preferably 1% by mass or more, more preferably 1.5% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less, of the total amount of agent I'.

[0102] The component (C') contained in the agent II' of the multi-component hair dye or bleaching composition of the present invention is the same as the component (C) contained in the multi-component cosmetic composition. Of these, component (C') is preferably one or more selected from cetyl alcohol, stearyl alcohol, and behenyl alcohol; more preferably, two or more of these are used; and even more preferably, three of cetyl alcohol, stearyl alcohol, and behenyl alcohol are used. The content of component (C') in the total amount of agent II' is preferably 2% by mass or more, more preferably 3% by mass or more, even more preferably 4.5% by mass or more, and preferably 12% by mass or less, more preferably 8% by mass or less, and even more preferably 6.9% by mass or less. The content of component (C') in the total amount of agent II' is preferably 2 to 12% by mass, more preferably 3 to 8% by mass, and even more preferably 4.5 to 6.9% by mass or more. In particular, the content of cetyl alcohol in the total amount of Agent II' is preferably 0.5% by mass or more, more preferably 1% by mass or more, even more preferably 1.5% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less, and even more preferably 5% by mass or less. The content of component (C') in the total amount of the multi-component hair dyeing or bleaching composition, that is, the content of component (C') when the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II' is 100% by mass, is the same as the content of component (C) in the total amount of the above-mentioned multi-component cosmetic composition.

[0103] In the agent II′ of the multi-component hair dye or bleach composition of the present invention, the component (D″) contained therein is a compound represented by the following formula (5′): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A arepresents an alkylene group having 2 to 4 carbon atoms, and r' represents a number of 30 to 200 on average.) It should be noted that component (D') in agent II' may contain the same nonionic surfactant as component (D) contained in the multi-component cosmetic composition as above, other than the polyoxyalkylene alkyl ether of component (D''). That is, among component (D) contained in the multi-component cosmetic composition as above, one or more nonionic surfactants selected from polyoxyalkylene alkyl ethers, alkyl alkanolamides, polyoxyalkylene alkylamines, alkyl polyglucosides, alkyl glyceryl ethers, etc., other than component (D'') in agent II' may be contained as nonionic surfactants (D') other than component (D''). In this way, by containing component (D'), a specific nonionic surfactant, in agent II' of the multi-component hair dyeing or bleaching composition of the present invention, it is possible to obtain a mixture that retains good properties and performance even when all the components are mixed in a high-temperature environment during use, thereby making it possible to sufficiently improve the uniformity of hair color.

[0104] That is, component (D″) is a polyoxyalkylene alkyl ether represented by the following formula (5′): R 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents an average value of 30 to 200. 10 From the viewpoint of effectively promoting the formation of a coacervate complex in the mixture, the number of carbon atoms in A is preferably 10 to 22, more preferably 12 to 20, and even more preferably 12 to 18. a is preferably an ethylene group or a propylene group, more preferably an ethylene group. r' is the so-called average number of moles added, and is preferably 30 to 200, more preferably 60 to 190, and even more preferably 90 to 180.

[0105] Among such polyoxyalkylene alkyl ethers (D″), it is preferable to contain one represented by the following formula (5b′).

[0106] R 11 -O-(A b O) q'-H...(5b') (In formula (5b'), R 11 represents a linear saturated hydrocarbon group having 16 carbon atoms, and A b represents an alkylene group having 2 carbon atoms, and q' represents an average number of 30 to 200.) Note that q' in formula (5b') means the so-called average number of moles added. q' in formula (5b') is preferably 30 to 200, more preferably 60 to 190, and even more preferably 90 to 180.

[0107] Of these, the component (D'') is preferably a polyoxyalkylene alkyl ether represented by the above formula (5b').

[0108] In the multi-component hair dye or bleaching composition of the present invention, the content of component (D") in the total amount of Agent II' is preferably 0.8% by mass or more, more preferably 1.1% by mass or more, even more preferably 1.3% by mass or more, and preferably 5.0% by mass or less, more preferably 3.0% by mass or less, and even more preferably 2.0% by mass or less, from the viewpoint of maintaining good properties and characteristics of the mixture and enhancing uniformity of hair color. The content of component (D") in the total amount of Agent II' is preferably 0.8 to 5.0% by mass, more preferably 1.1 to 3.0% by mass, and even more preferably 1.3 to 2.0% by mass. The content of component (D″) in the total amount of the multi-component hair dyeing or bleaching composition of the present invention, i.e., the total content of component (D″) when the total amount of the mixture obtained by mixing all the constituent components including Agent I′ and Agent II′ is 100% by mass, i.e., the content of component (D″) in the total amount of the mixture obtained by mixing all the constituent components, is 0.6% by mass or more, preferably 0.7% by mass or more, more preferably 0.8% by mass or more, even more preferably 0.9% by mass or more, and preferably 2% by mass or less, more preferably 1.3% by mass or less, and even more preferably 1.1% by mass or less, from the viewpoint of obtaining a mixture that maintains good properties and performance and sufficiently enhancing the uniformity of hair color. In the multi-component hair dyeing or bleaching composition of the present invention, the content of component (D″) in the total amount of the mixture obtained by mixing all of the constituent components is 0.6% by mass or more, preferably 0.6 to 2% by mass, more preferably 0.7 to 2% by mass, even more preferably 0.8 to 1.3% by mass, and still more preferably 0.9 to 1.1% by mass.

[0109] In order to fully exert its highly useful hair dyeing or bleaching effect, it is preferable that Agent II' in the multi-component hair dyeing or bleaching composition of the present invention contain the same hydrogen peroxide as in the above-mentioned multi-component cosmetic composition. The content of hydrogen peroxide in Agent II' is preferably 0.75% by mass or more, more preferably 1.5% by mass or more, preferably 12% by mass or less, more preferably 11% by mass or less, and even more preferably 10% by mass or less. The content of hydrogen peroxide in the total amount of the multi-component hair dyeing or bleaching composition, i.e., the content of hydrogen peroxide when the total amount of the mixture obtained by mixing all the constituent components including Agent I' and Agent II' is 100% by mass, is the same as the content of hydrogen peroxide in the total amount of the above-mentioned multi-component cosmetic composition.

[0110] In addition, in addition to components (C') and (D'') and hydrogen peroxide, Agent II' contained in the multi-component hair dye or bleaching composition of the present invention may contain, as in Agent II', components (A'-1), (A'-2), (B'), (E'), water, and other components commonly used as cosmetic raw materials, as appropriate, to the extent that the effects of the present invention are not impaired. However, with regard to the inclusion of component (B'), in particular, from the viewpoint of effectively enhancing hair color uniformity while exhibiting excellent penetration and spreadability in hair, it is preferable that only Agent I' contains component (B') and Agent II' does not contain component (B'). Furthermore, as an ionic surfactant when contained in Agent II', component (A'-2) is preferred, and it is even more preferable that component (A'-1) is not contained. In this case, the content of component (A'-2) in Agent II' is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and preferably 1% by mass or less, more preferably 0.7% by mass or less.

[0111] The mass ratio ((A'-2) / (D'') of the content of component (A'-2) to the content of component (D'') in the multi-component hair dye or bleaching composition of the present invention is preferably 0.1 or more, more preferably 0.2 or more, even more preferably 0.3 or more, and preferably 0.6 or less, more preferably 0.5 or less, and even more preferably 0.4 or less. The mass ratio ((A'-2) / (D'') of the content of component (A'-2) to the content of component (D'') in the multi-component hair dye or bleaching composition of the present invention is preferably 0.1 to 0.6, more preferably 0.2 to 0.5, and even more preferably 0.3 to 0.4. Similarly to the above-mentioned multi-component cosmetic composition, the multi-component hair dye or bleaching composition of the present invention preferably does not contain salicylic acid or acetaminophen, and more preferably does not contain both, in order to avoid inhibiting the expression of excellent penetration and spreadability in hair.

[0112] Such a multi-component hair dye or bleaching composition of the present invention can effectively suppress the prominence of hair color differences and achieve a highly uniform hair color while exhibiting excellent penetration and spreadability into hair, even without necessarily comprising two components that have different viscosities at 30° C. and a specific viscosity ratio (Agent II / Agent I) as in the above-mentioned multi-component cosmetic composition. For example, the viscosity ratio (Agent II' / Agent I') of the viscosity of Agent II' at 30° C. to the viscosity of Agent I at 30° C. (the value obtained by dividing the viscosity value of Agent II' at 30° C. by the viscosity value of Agent I' at 30° C.) in the multi-component hair dye or bleaching composition of the present invention is preferably 3 or greater, more preferably 100 to 6,000, even more preferably 500 to 5,000, still more preferably 700 to 4,000, still more preferably 800 to 3,000, and even more preferably 2,000 to 2,500. That is, in this case, the agent I included in the multi-component cosmetic composition corresponds to the agent I' included in the multi-component hair dye or bleaching composition, the agent II included in the multi-component cosmetic composition corresponds to the agent II' included in the multi-component hair dye or bleaching composition, and the viscosity ratio of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) corresponds to the viscosity ratio of the viscosity of agent II' at 30°C to the viscosity of agent I' at 30°C (agent II' / agent I'). Similarly, the viscosity of agent I included in the multi-component cosmetic composition at 30°C also corresponds to the viscosity of agent I' included in the multi-component hair dye or bleaching composition at 30°C, and the viscosity of agent II included in the multi-component cosmetic composition at 30°C also corresponds to the viscosity of agent II' included in the multi-component hair dye or bleaching composition at 30°C.

[0113] In the components including Agent I' and Agent II' contained in the multi-component hair dyeing or bleaching composition of the present invention, the form of each component can be appropriately selected from the same forms as the forms of the components contained in the above-mentioned multi-component cosmetic composition. In particular, with regard to the forms of Agent I' and Agent II', from the viewpoint of achieving excellent penetration and spreadability in hair while also achieving a highly uniform hair color, it is preferable that Agent I' be in the form of a liquid and Agent II' be in the form of a cream, and when obtaining a mixture of all the components, it is preferable to add Agent I' to at least Agent II' and mix them.

[0114] As described above, the multi-component hair dyeing or bleaching composition of the present invention exhibits excellent mixability on the target hair, regardless of the temperature environment when all components are mixed during use, and the resulting mixture appropriately maintains good properties and performance, enabling highly uniform hair coloring or bleaching. Therefore, the multi-component hair dyeing or bleaching composition is also highly useful as a hair dyeing method that includes applying the multi-component hair dyeing or bleaching composition to the roots of the hair and then spreading it to the ends. For example, specifically, if the roots to which the multi-component hair dyeing or bleaching composition is applied are those where the hair color difference is prominent, the excellent hair compatibility can be fully realized.

[0115] The multi-component cosmetic composition of the present invention can be used in a cosmetic kit that further comprises, independently of one another, other agent compositions for application to keratinous tissues after application of the multi-component cosmetic composition to keratinous tissues. That is, such a cosmetic kit of the present invention comprises the above-mentioned multi-component cosmetic composition as well as other agent compositions for application separately from the multi-component cosmetic composition. This allows the multi-component cosmetic composition of the present invention to be applied to keratinous tissues to fully exert its effects, and then the other agent compositions can be applied to keratinous tissues to further exert desired effects. Note that, similar to the above-mentioned multi-component cosmetic composition, the multi-component hair dyeing or bleaching composition of the present invention can also be used in a cosmetic kit that further comprises, independently of one another, other agent compositions for application to keratinous tissues. Therefore, hereinafter, in the case of a cosmetic kit that comprises the multi-component hair dyeing or bleaching composition of the present invention as well as other agent compositions, the term "multi-component cosmetic composition of the present invention" will be read as "multi-component hair dyeing or bleaching composition of the present invention."

[0116] Examples of other compositions that may be included in such a cosmetic kit include a moisturizer composition, a beauty serum composition, a coating composition, a sunscreen composition, a rinse composition, a conditioner composition, and a treatment composition. In particular, when the multi-component cosmetic composition of the present invention is a hair cosmetic composition intended for application to hair, preferably a hair bleaching or hair dyeing composition, a treatment composition is preferably included as the other composition to be included in the kit. Thus, by further applying such a treatment composition to hair after applying the multi-component cosmetic composition of the present invention as a hair cosmetic composition, it is possible to effectively suppress hair damage that tends to occur due to repeated application treatments, effectively increase the color density of the hair (also referred to as "deepening"), and also impart a pleasant feel to the hair.

[0117] The treatment composition may be in an embodiment containing one constituent agent, specifically, for example, a rinse-off treatment agent, or a leave-in treatment agent. The treatment composition may also be in an embodiment containing multiple constituent agents, specifically, for example, a rinse-off treatment agent and a leave-in treatment agent, for a total of two constituent agents.

[0118] The treatment composition included in the cosmetic kit of the present invention preferably contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2).

[0119] The amino-modified silicone (x1-1) of component (X1) that may be contained in the treatment composition is a silicone that has an amino group but does not have a polyether structure, and specific examples include one or more selected from amodimethicone, aminopropyl dimethicone, bis(aminopropyl) dimethicone, and bis(cetearyl) amodimethicone. Among these, amodimethicone is preferred from the viewpoint of effectively suppressing hair damage while effectively increasing hair color intensity. Commercially available products of such component (x1-1) include, for example, DOWSIL CF 1046 (manufactured by Dow-Toray Industries, Inc.) and Silicone SF 8457 C (manufactured by Dow-Toray Industries, Inc.).

[0120] The aminopolyether-modified silicone (x1-2) of component (X1) that may be contained in the treatment composition is a silicone having an amino group and a polyether structure, and the polyether structure of component (x1-2) is preferably a polyoxyalkylene group. Of these, from the viewpoint of effectively suppressing hair damage while effectively increasing hair color depth, specifically, for example, an aminopolyether-modified silicone represented by the following formula (9) is preferred.

[0121]

[0122] (In formula (9), d is a number of 2 or more, and preferably a number of 2 or more and 1,000 or less. e is a number of 1 or more, and preferably a number of 1 or more and 50 or less. f is a number of 2 or more and 100 or less, and preferably a number of 4 or more and 50 or less. g is a number of 1 or more, and preferably a number of 1 or more and 100 or less.) Examples of commercially available products of such component (x1-2) that can be used include DOWSIL SS-3588 FLUID ((bisisobutyl PEG-15 / amodimethicone) copolymer), DOWSIL SILSTYLE 104 ((bisisobutyl PEG-14 / amodimethicone) copolymer, manufactured by Dow-Toray Industries, Inc.), and DOWSIL SILSTYLE 201 ((bisisobutyl PEG-14 / amodimethicone) copolymer, manufactured by Dow-Toray Industries, Inc.).

[0123] From the viewpoint of effectively suppressing hair damage while effectively increasing hair color depth, the content of component (X1) is preferably 0.1% by mass or more, more preferably 0.4% by mass or more, and preferably 10% by mass or less, and more preferably 7% by mass or less, based on the total amount of the treatment composition. The content of component (X1) is preferably 0.1 to 10% by mass, more preferably 0.4 to 7% by mass, based on the total amount of the treatment composition. In particular, when the treatment composition contains only one component, a rinse-off treatment agent, the content of component (X1) may be 0.8% by mass or more and 5% by mass or less, based on the total amount of the treatment composition.

[0124] The dimethicone component (X2) contained in the treatment composition is a so-called dimethylpolysiloxane having a silicone skeleton. Commercially available products of component (X2) include Silicone X-52-2162 (manufactured by Shin-Etsu Chemical Co., Ltd.), Silicone KHS-3 (manufactured by Shin-Etsu Chemical Co., Ltd.), Silicone KHS-9 (manufactured by Shin-Etsu Chemical Co., Ltd.), TSE200A (manufactured by Momentive Performance Materials, Inc.), SH200-1,000,000cs (manufactured by Dow Corning Toray Co., Ltd.), and TSF451-100MA (manufactured by Momentive Performance Materials, Inc.).

[0125] From the viewpoint of effectively suppressing hair damage while effectively increasing hair color depth, the content of component (X2) is preferably 0.1% by mass or more, more preferably 1% by mass or more, and preferably 15% by mass or less, and more preferably 12% by mass or less, based on the total amount of the treatment composition. The content of component (X2) is preferably 0.1 to 15% by mass, more preferably 1 to 12% by mass, based on the total amount of the treatment composition. In particular, when the treatment composition contains only one component, a rinse-off treatment agent, the content of component (X1) may be 2% by mass or more and 6% by mass or less, based on the total amount of the treatment composition.

[0126] The treatment composition included in the cosmetic kit of the present invention may contain only component (X1) or only component (X2) of the above-mentioned components (X1) and (X2), but preferably contains both component (X1) and component (X2). When both component (X1) and component (X2) are contained, the total content of these components (X1) and (X2) is preferably 1% by mass or more, more preferably 2% by mass or more, even more preferably 3% by mass or more, still more preferably 5% by mass or more, preferably 15% by mass or less, more preferably 12% by mass or less, even more preferably 10% by mass or less, and still more preferably 8% by mass or less, based on the total amount of the treatment composition. The total content of component (X1) and component (X2) in the treatment composition is preferably 1 to 15 mass%, more preferably 1 to 12 mass%, even more preferably 1 to 10 mass%, still more preferably 2 to 10 mass%, even more preferably 3 to 10 mass%, and still more preferably 5 to 8 mass%.

[0127] Furthermore, when the treatment composition contains both component (X1) and component (X2), from the viewpoint of effectively suppressing hair damage while effectively increasing hair color depth, it is preferred that the treatment composition comprises a total of two components: a rinse-off treatment and a leave-in treatment; it is more preferred that the rinse-off treatment contains component (X1) and component (X2), and that the leave-in treatment contains component (X2) without containing component (X1); and it is even more preferred that the component (X1) contained in the rinse-off treatment is component (x1-1).

[0128] More specifically, when the treatment composition provided in the cosmetic kit of the present invention comprises, as constituents, a rinse-off treatment containing component (X1) and component (X2), and a leave-in treatment containing component (X2) but not component (X1), the content of component (X1) in the rinse-off treatment is, relative to 100% by mass of the rinse-off treatment, preferably 0.5% by mass or more, more preferably 0.8% by mass or more, even more preferably 1.0% by mass or more, and preferably 1.8% by mass or less, more preferably 1.5% by mass or less, and even more preferably 1.2% by mass or less. Furthermore, the content of component (X2) in the rinse-off treatment agent is, relative to 100% by mass of the rinse-off treatment agent, preferably 2% by mass or more, more preferably 3% by mass or more, even more preferably 4% by mass or more, preferably 8% by mass or less, more preferably 7% by mass or less, even more preferably 6% by mass or less, and still more preferably 5% by mass or less. On the other hand, when the treatment agent composition provided in the cosmetic kit of the present invention is in the above-described embodiment, the content of component (X2) in the leave-in treatment agent is, relative to 100% by mass of the leave-in treatment agent, preferably 0.5% by mass or more, more preferably 1% by mass or more, even more preferably 1.5% by mass or more, and preferably 30% by mass or less, more preferably 25% by mass or less, and even more preferably 20% by mass or less.

[0129] Furthermore, the treatment composition provided in the cosmetic kit of the present invention may contain, in addition to the above-mentioned (X1) and (X2), other components appropriately selected from the components (A) to (D) and other components that may be contained in the above-mentioned multi-component cosmetic composition.

[0130] The form of the constituents of the treatment composition included in the cosmetic kit of the present invention can be appropriately selected from liquid (oil), emulsion (milk), gel, paste, cream, foam, mist, etc. In particular, when the treatment composition includes a rinse-off treatment containing component (X1) and component (X2) and a leave-in treatment containing component (X2) but not component (X1) as constituents, the rinse-off treatment is preferably in cream form, and the leave-in treatment is preferably in liquid (oil) or emulsion (milk) form, more preferably emulsion (milk). Note that when the leave-in treatment is in emulsion (milk) form, it is preferable to adjust the pH of the leave-in treatment to a specific range. Specifically, when the leave-in treatment agent is in the form of an emulsion (milk), the pH of the leave-in treatment agent at 25°C is preferably 3 or higher, more preferably 3.5 or higher, and preferably 5 or lower, more preferably 4 or lower.

[0131] In the cosmetic kit of the present invention, a multi-component cosmetic composition is first applied to keratinous tissues, and then a treatment composition is applied to keratinous tissues. For example, in an embodiment in which the treatment composition comprises, as constituents, a rinse-off treatment agent containing component (X1) and component (X2) and a leave-in treatment agent containing component (X2) but not component (X1), the rinse-off treatment agent is applied to the keratinous tissues to which the multi-component cosmetic composition has been applied, and after rinsing, the leave-in treatment agent is applied to the keratinous tissues, and the keratinous tissues are then dried without rinsing. This makes it possible to more effectively suppress hair damage and further effectively increase the color intensity of the hair.

[0132] In relation to the above-described embodiments, the present invention further discloses the following multi-component cosmetic composition, multi-component hair dyeing or bleaching composition, and a cosmetic kit and method of using them. [1] A multi-component cosmetic composition comprising the following components (A) to (D): (A) an ionic surfactant, (B) a cationic polymer, (C) a higher alcohol, and (D) a nonionic surfactant, and comprising multiple components including an agent I and an agent II having different viscosities at at least 30°C, and in which all of the components are mixed together at the time of use, wherein the viscosity ratio of the viscosity of the agent II at 30°C to the viscosity of the agent I at 30°C (agent II / agent I) is 3 or more, and the viscosity of the mixture obtained by mixing all of the components is 0.001 S when measured with a rheometer at 25°C. -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 [2] The multi-component cosmetic composition of [1] above, wherein the viscosity ratio of the viscosity of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) is preferably 100 or more, more preferably 800 or more, even more preferably 1200 or more, still more preferably 1500 or more, and preferably 6000 or less, more preferably 5000 or less, even more preferably 4000 or less, and still more preferably 3000 or less. [3 ... agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) is preferably 100 or more, more preferably 800 or more, even more preferably 1200 or more, still more preferably 1500 or more, and -1 Shear viscosity a and shear rate at 139S -1 The multi-component cosmetic composition of [1] or [2] above, wherein the ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is preferably 6,000 or more, more preferably 7,000 or more, and preferably 20,000 or less, more preferably 18,000 or less, and even more preferably 10,200 or less.

[0133] [4] The multi-component cosmetic composition of any one of [1] to [3] above, wherein component (A) comprises an anionic surfactant (A-1), and wherein component (A-1) is preferably an anionic surfactant having a sulfate group, and more preferably the content of an anionic surfactant having a carboxyl group in the multi-component cosmetic composition of the present invention is preferably 0.45% by mass or less, more preferably 0.35% by mass or less, and even more preferably 0.10% by mass or less, or wherein the multi-component cosmetic composition of the present invention is substantially free of an anionic surfactant having a carboxyl group. [5] The multi-component cosmetic composition of any one of [1] to [4] above, wherein component (A) contains the cationic surfactant of component (A-2), and component (A-2) is preferably monoalkyltrimethylammonium chloride or monoalkyltrimethylammonium bromide, more preferably stearyltrimethylammonium chloride (steartrimonium chloride), cetyltrimethylammonium chloride (cetrimonium chloride), or lauryltrimethylammonium chloride (lauryltrimonium chloride). [6] The multi-component cosmetic composition of any one of [1] to [5] above, wherein component (B) is preferably a polymer containing a diallyl quaternary ammonium salt as a structural unit, more preferably a homopolymer of a diallyl quaternary ammonium salt, or a copolymer of a diallyl quaternary ammonium salt and acrylic acid. [7] The multi-component cosmetic composition of any one of [1] to [6] above, wherein component (C) is one or more alcohols selected from myristyl alcohol, cetyl alcohol, stearyl alcohol, arachyl alcohol, behenyl alcohol, oleyl alcohol, etc., preferably one or more alcohols selected from cetyl alcohol, stearyl alcohol, and behenyl alcohol, and it is more preferable to use two or more of these. [8] The multi-component cosmetic composition of any one of [1] to [7] above, wherein in the multi-component cosmetic composition of the present invention, the mass ratio of the content of component (C) to the content of component (A) ((C) / (A)) is preferably 2 or more, more preferably 2.5 to 5, even more preferably 2.77 to 3.75, and still more preferably 3.1 to 3.50.[9] The multi-component cosmetic composition according to any one of the above [1] to [8], wherein component (D) is a polyoxyalkylene alkyl ether represented by the following formula (5): 10 -O-(A a O) r -H...(5) (In formula (5), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r represents a number from 1 to 300 on average.)

[10] The multi-component cosmetic composition of any one of [1] to [9] above, wherein the content of component (A) in the multi-component cosmetic composition of the present invention is preferably from 0.48% by mass to 1.99% by mass, the content of component (B) is preferably from 0.03% by mass to 0.59% by mass, and the content of component (C) is preferably from 1.52% by mass to 6.08% by mass.

[11] The multi-component cosmetic composition of any one of [1] to

[10] above, further comprising component (E) which is a chloride of one or two selected from alkali metal salts of organic acids having 6 or less carbon atoms, alkaline earth metal salts of organic acids having 6 or less carbon atoms, inorganic alkali metal salts, and inorganic alkaline earth metal salts.

[12] The multi-component cosmetic composition according to any one of [1] to

[11] above, which preferably does not contain salicylic acid or acetaminophen, and more preferably does not contain both of them.

[0134]

[13] A method for using a multi-component cosmetic composition comprising the following components (A) to (D): (A) an ionic surfactant, (B) a cationic polymer, (C) a higher alcohol, and (D) a nonionic surfactant, the composition comprising a plurality of components including an agent I and an agent II having different viscosities at least at 30°C, the method comprising mixing all of the components in advance and then applying the resulting mixture to keratinous tissue, wherein the viscosity ratio of the agent II at 30°C to the viscosity of the agent I at 30°C (agent II / agent I) is 3 or more, and the shear rate of the mixture obtained by mixing all of the components is 0.001 S, as measured at 25°C using a rheometer. -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1a / shear viscosity b) of 5,000 or more.

[0135]

[14] A cosmetic kit comprising a multi-component cosmetic composition and a treatment agent composition which is separate and independent and contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), wherein the multi-component cosmetic composition contains the following components (A) to (D): (A) an ionic surfactant (B) a cationic polymer (C) a higher alcohol (D) a nonionic surfactant, and comprises a plurality of component parts including component I and component II which have different viscosities at at least 30°C, and all of the component parts are mixed at the time of use, wherein the viscosity ratio (component II / component I) of the viscosity of component II at 30°C to the viscosity of component I at 30°C is 3 or more, and the mixture obtained by mixing all of the component parts has a viscosity ratio of 0.001 S at 25°C measured with a rheometer. -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 The cosmetic kit has a ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) of 5000 or more.

[15] A method for using the cosmetic kit of

[14] above, which comprises applying the multi-component cosmetic composition to keratinous tissues, and then applying a treatment composition to the keratinous tissues.

[0136]

[16] A multi-component hair dye or bleach composition comprising a plurality of components including an I' component and an II' component, which are mixed together at the time of use, wherein the I' component contains the following components (A'-1) and (B): (A'-1) an anionic surfactant (B') a cationic polymer, and the II' component contains the following components (C') and (D''): (C') a higher alcohol (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A arepresents an alkylene group having 2 to 4 carbon atoms, and r' represents a number from 30 to 200 on average.) and the content of component (D") in the mixture obtained by mixing all the constituent components is 0.6% by mass or more.

[17] The multi-component hair dyeing or bleaching composition of

[16] above, wherein the content of component (A'-1) in the mixture obtained by mixing all the constituent components is preferably 1 to 10% by mass, more preferably 2 to 5% by mass, and even more preferably 3 to 4.5% by mass.

[18] The multi-component hair dyeing or bleaching composition of

[16] above, wherein the content of component (B') in the mixture obtained by mixing all the constituent components is preferably 0.03 to 0.59% by mass, more preferably 0.18 to 0.55% by mass, and even more preferably 0.25 to 0.44% by mass.

[19] The multi-component hair dyeing or bleaching composition of any one of

[16] to

[18] above, wherein the content of ionic surfactant (A'-2) other than the anionic surfactant of component (A'-1) in the mixture obtained by mixing all the constituent components is preferably 0.1 to 7 mass%, more preferably 0.2 to 3 mass%, and even more preferably 0.3 to 1 mass%.

[20] The multi-component hair dyeing or bleaching composition of any one of

[16] to

[19] above, wherein the content of component (C') in the total amount of Agent II' is preferably 2 to 12 mass%, more preferably 3 to 8 mass%, and even more preferably 4.5 to 6.9 mass% or more.

[21] The multi-component hair dyeing or bleaching composition of any one of

[16] to

[20] above, wherein the content of component (D") in the total amount of Agent II' is preferably 0.8 to 5.0% by mass, more preferably 1.1 to 3.0% by mass, and even more preferably 1.3 to 2.0% by mass.

[22] The multi-component hair dyeing or bleaching composition of any one of

[16] to

[21] above, wherein the content of component (D") in the mixture obtained by mixing all the constituent components is preferably 0.7 to 2% by mass, more preferably 0.8 to 1.3% by mass, and even more preferably 0.9 to 1.1% by mass.

[23] The multi-component hair dyeing or bleaching composition according to any one of the above

[16] to

[22] , wherein the mass ratio ((A'-2) / (D'')) of the content of the ionic surfactant (A'-2) other than component (A'-1) to the content of component (D'') is preferably 0.1 to 0.6, more preferably 0.2 to 0.5, and even more preferably 0.3 to 0.4.

[0137]

[24] The agent I' contains the following components (A'-1) and (B): (A'-1) an anionic surfactant and (B') a cationic polymer, and the agent II' contains the following components (C') and (D''): (C') a higher alcohol and (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents a number of 30 to 200 on average), and in a mixture obtained by mixing all of the constituent components, the content of component (A'-1) is 3 to 4.5% by mass, the content of component (B') is 0.25 to 0.44% by mass, the content of component (C') is 3.03 to 4.54% by mass or less, and the content of component (D'') is 0.9 to 1.1% by mass.

[25] A multi-component hair dyeing or bleaching composition comprising a plurality of components including an I' component and an II' component, which are mixed together at the time of use, wherein the I' component contains the following components (A'-1) and (B): (A'-1) an anionic surfactant (B') a cationic polymer, and the II' component contains the following components (C') and (D''): (C') a higher alcohol (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear saturated hydrocarbon group having 12 to 18 carbon atoms; A arepresents an ethylene group, and r' represents a number from 90 to 180 on average.), and the content of component (D") in a mixture obtained by mixing all of the constituent components is 0.6% by mass or more.

[26] A multi-component hair dyeing or bleaching composition comprising a plurality of constituent components including agent I' and agent II', wherein the viscosity ratio of agent II' at 30°C to the viscosity of agent I' at 30°C (agent II' / agent I') is 3 or more, and all of the constituent components are mixed together before use, wherein agent I' contains the following components (A'-1) and (B): (A'-1) an anionic surfactant (B') a cationic polymer, and agent II' contains the following components (C') and (D"): (C') a higher alcohol (D") a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents a number of 30 to 200 on average), and the content of component (D'') in a mixture obtained by mixing all of the constituent components is 0.6 mass% or more.

[0138]

[27] The multi-component hair dyeing or bleaching composition according to any one of the above

[16] to

[26] , wherein component (D″) in agent II′ contains a compound represented by the following formula (5b′): 11 -O-(A b O) q'-H...(5b') (In formula (5b'), R 11 represents a linear saturated hydrocarbon group having 16 carbon atoms, and A brepresents an alkylene group having 2 carbon atoms, and q' represents an average value of 30 to 200.)

[28] The multi-component hair dyeing or bleaching composition of any one of

[16] to

[27] above, wherein only Agent II' contains component (C'), and Agent I' does not contain component (C').

[29] The multi-component hair dyeing or bleaching composition of any one of

[16] to

[28] above, wherein only Agent I' contains component (B'), and Agent II' does not contain component (B').

[30] A hair dyeing method comprising the steps of applying the multi-component hair dyeing or bleaching composition of any one of

[16] to

[29] above to the roots of the hair and then spreading it to the ends.

[31] The hair dyeing method of

[30] above, wherein the roots of the hair have a noticeable difference in hair color.

[0139]

[32] The following components (A'-1) and (B): (A'-1) an anionic surfactant, (B') an agent I' containing a cationic polymer, and (B') an agent II' containing the following components (C') and (D''): (C') a higher alcohol, and (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents a number from 30 to 200 on average.) A method for using a multi-component hair dyeing or bleaching composition comprising a plurality of component parts, including component II', in which the content of component (D'') in the mixture obtained by mixing all of the component parts is 0.6 mass% or more, the method comprising mixing all of the component parts in advance and then applying the resulting mixture to hair.

[0140]

[33] A cosmetic kit comprising a multi-component hair dyeing or bleaching composition and a treatment composition which is separate and independent from the other and contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), wherein the multi-component hair dyeing or bleaching composition comprises a plurality of components including agent I' and agent II', and all of the components are mixed together when used, wherein agent I' contains the following components (A'-1) and (B): (A'-1) an anionic surfactant (B') a cationic polymer, and agent II' contains the following components (C') and (D''): (C') a higher alcohol (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents a number from 30 to 200 on average.), and the content of component (D") in a mixture obtained by mixing all of the constituent components is 0.6% by mass or more.

[34] A method for using the cosmetic kit of the above

[33] , comprising applying a multi-component hair dyeing or bleaching composition to hair, and then applying a treatment composition to hair.

[35] The multi-component hair dyeing or bleaching composition of any one of the above

[16] to

[29] , wherein the viscosity ratio of the viscosity of Agent II' at 30°C to the viscosity of Agent I at 30°C (Agent II' / Agent I') is preferably 3 or more, more preferably 100 to 6,000, even more preferably 500 to 5,000, still more preferably 700 to 4,000, still more preferably 800 to 3,000, and still more preferably 2,000 to 2,500.

[36] The multi-component hair dyeing or bleaching composition according to any one of the above

[16] to

[29] , wherein the mixture obtained by mixing all of the constituent components of the multi-component cosmetic composition of the present invention is in the form of a gel.

[0141] The present invention will be described in detail below with reference to the following examples. Unless otherwise specified in the tables, the content of each component is expressed in mass %.

[0142] Test Example 1: Examples 1 to 8, Comparative Examples 1 to 7 Agents I and II were prepared according to the formulations shown in Table 1, and then mixed with Agent I in a mass ratio of 1:2 (agent I:agent II). The resulting mixture was used to carry out measurements and evaluations according to the following methods. The results are shown in Table 1.

[0143] <<Measurement of Viscosity of Agent I or Agent II>> Using a Brookfield viscometer (TVB-10, manufactured by Toki Sangyo Co., Ltd.), the viscosity at 30°C was measured under the following measurement conditions, appropriately selected depending on the form of the obtained Agent I or Agent II. Specifically, when the agents were in liquid form, 90 g of each agent was sampled and measured at a temperature of 30°C using rotor No. 1 at a rotation speed of 60 rpm for 1 minute. Note that even if the measured value was below 10 mPa s, that value was adopted. On the other hand, when the agents were in cream form, 45 g of each agent was sampled and measured at a temperature of 30°C using rotor T-C at a rotation speed of 10 rpm for 1 minute. Note that if the measured value was below 20,000 mPa s, the value measured using rotor T-B at 10 rpm for 1 minute was adopted.

[0144] <<Measurement of Shear Viscosity of Mixtures>> The shear viscosity of the mixtures obtained by mixing component I and component II was measured using an Anton Paar MCR301. 4 g of component II was weighed into a 50 mL plastic cup, 2 g of component I was added, and the mixture was stirred with a plastic spatula for 30 seconds to obtain a mixture. The resulting mixture was then placed on the stage of the rheometer and clamped with a jig (approximately 0.7 g of the mixture was placed, and excess mixture was removed with a silicone spatula). Measurements were started 3 minutes after mixing. Specifically, the resulting mixture was clamped between a plate and a jig (PP25, Anton Paar) with a gap of 1 mm, and the shear rate was set to 0.001 s. -1 ~1000S -1 The shear rate was changed to 0.0037 S -1 Shear viscosity a at shear rate 139S -1The shear viscosity b at 1000 kJ / 2000 kJ / min was measured. Next, based on the obtained values ​​of shear viscosity a and shear viscosity b, the ratio between these values ​​(shear viscosity a / shear viscosity b) was calculated.

[0145] (i) Evaluation of Adhesion After mixing the I and II components, the mixture was left to stand for 5 minutes to stabilize the viscosity, and then the adhesion was evaluated. Specifically, 0.5 g of the resulting mixture was placed on a glass plate, which was tilted 20° and left for 1 minute. The distance (mm) that the mixture moved from the placement point was measured, and this was used as an index for evaluating adhesion according to the following criteria. The larger the value obtained, the better the adhesion and the more effectively it can be evaluated as preventing unwanted dripping.

[0146] 5: The distance moved was less than 0.5 cm. 4: The distance moved was 0.5 cm or more but less than 1 cm. 3: The distance moved was 1 cm or more but less than 2 cm. 2: The distance moved was 2 cm or more but less than 3 cm. 1: The distance moved was 3 cm or more.

[0147] (ii) Evaluation of Spreadability (Ease of Spreading) A 20 cm square piece of wool muslin was used as a test piece, and 0.5 g of the mixture obtained was applied to an area within 2 cm from one end of the test piece. The applied mixture was then spread with a finger toward the other end of the test piece, and the distance (cm) from the one end was measured as the spreadable distance, and the spreadability (ease of spreadability) was evaluated according to the following criteria.

[0148] 5: The spreadable distance from one end of the test piece was 12 cm or more. 4: The spreadable distance from one end of the test piece was 10 cm or more but less than 12 cm. 3: The spreadable distance from one end of the test piece was 8 cm or more but less than 10 cm. 2: The spreadable distance from one end of the test piece was 6 cm or more but less than 8 cm. 1: The spreadable distance from one end of the test piece was less than 6 cm.

[0149] (iii) Evaluation of Penetration into Keratinous Tissues: A specialist panelist took approximately 3 g of the resulting mixture and applied it three times, applying a force of approximately 600 g over a distance of approximately 20 cm from the top of the head of a mannequin with medium-length hair, toward the ends. This action was repeated twice. Next, using the tip of a standard ring comb (tail comb) handle, the inside of a hair bundle approximately 5 cm from the top of the head was sliced ​​(a manipulation of parting the hair bundle and opening the inside of the hair bundle), and the state of application of the mixture was visually confirmed. The penetration into keratinous tissues was evaluated according to the following criteria.

[0150] 4: The mixture is evenly applied to the inside of the hair bundle. 3: The mixture is unevenly applied, but about half of the mixture is partially applied. 2: The mixture is unevenly applied, but the mixture is partially applied in places. 1: The mixture is not applied at all to the inside of the hair bundle.

[0151] <<Overall Evaluation of Application Efficiency>> The total value of the evaluation results obtained from the above "(i) Evaluation of adhesion," "(ii) Evaluation of spreadability (ease of application)," and "(iii) Evaluation of penetration into keratinous tissues" was calculated and used as an index for the overall evaluation of application ease.

[0152] <Evaluation of Texture> A specialist panel applied 1 g of the mixture obtained to 1 g of gray hair tress (manufactured by Beaulux Co., Ltd.), and sensory evaluation was performed on the texture (texture) of the mixture to the touch, using the degree of smoothness as an index according to the following criteria.

[0153] 4: Very smooth 3: Smooth 2: Slightly less smooth 1: Less smooth

[0154]

[0155] *1: Emal 227-PH11 (manufactured by Kao Corporation) *2: Nikkor SCS (manufactured by Nikko Chemicals Co., Ltd.) *3: Marquart 295 Polymer (manufactured by Lubrizol Advanced Materials Corporation, charge density: 6.04 meq / g) *4: Softanol 90 ((C12-14)s-Palace-9, manufactured by Nippon Shokubai Co., Ltd.) *5: Kalcol 6098 (manufactured by Kao Corporation) *6: Kalcol 8098 (manufactured by Kao Corporation) *7: Kalcol 220-80 (manufactured by Kao Corporation) *8: Nikkor BC-40TX (manufactured by Nikko Chemicals Co., Ltd.) *9: Nikkor BC-150 (manufactured by Nikko Chemicals Co., Ltd.) *10: Courtamine 86W (manufactured by Kao Corporation)

[0156] [Test 2: Examples 9-10] The mixture obtained by mixing Agents I and II of Example 1, together with Treatment Agent XA (rinse-off type), Treatment Agent XB-1 (leave-in type, emulsion (milky) form) or Treatment Agent XB-2 (leave-in type, liquid (oil) form), each having the formulation shown in Table 2, was applied to the hair bundle for evaluation described below in accordance with the method below to evaluate the color-darkening effect using the kit. The results are shown in Table 2.

[0157] <<Preparation of Hair Bundle for Evaluation>> A bundle of untreated black hair (BS-B-A, manufactured by Bealux, length 30 cm, mass 10 g) was prepared in 7 tones (brightness L * :22.5-25.1, saturation C * : 12.3 to 15.9; colorimetric value measured by a color difference meter (CR-400, manufactured by Konica Minolta)) was prepared as a hair bundle for evaluation.

[0158] <<Darkening Effect>> The hair bundle for evaluation was combed to align the hair in one direction, and then a color difference meter (Konica Minolta, CR-400) was used to measure the color depth in the CIE color system (L * ,a * ,b * ) and lightness (L0 * ) was measured. *Measurements were made at six different points on the hair bundle (two points in the center of each of the three equal areas obtained by dividing the hair bundle lengthwise), and the average value was calculated. Next, 10 g of a mixture obtained by mixing Agents I and II of Example 1 was applied to the hair bundle for evaluation, and after leaving it, it was rinsed with water and shampooed and then rinsed away. Next, 1 g of treatment agent XA having the formulation shown in Table 2 was applied evenly to the hair bundle, and after rinsing with water, the hair was towel-dried. Next, 0.2 g of treatment agent XB-1 or treatment agent XB-2 shown in Table 2 was applied evenly to the hair bundle, and then the hair was dried with cold air for 30 minutes using a hair dryer (Hitachi Ltd. "P2-D250", setting HIGH). The dried hair bundle was combed, and the lightness (L1 * ) was measured, and the difference in brightness (ΔL * ) was calculated. * If ΔL is 1.0 or more, it can be evaluated that there is a deep coloring effect, if it is 2.0 or more, the effect is better, and if it is 3.0 or more, it can be evaluated that the effect is even better. * = L0 * -L1 * L0 * : Lightness of hair bundle before processing L1 * : Brightness of hair strands after processing

[0159]

[0160] [Test 3: Examples 11 to 14, Comparative Example 8] Using Agents I' and II' having the formulations shown in Table 3, the foam suppression of the mixture in a high-temperature environment and the mixability of the agents were evaluated according to the following method. The results are shown in Table 3.

[0161] <<Inhibition of Foaming of Mixtures in High-Temperature Environments>> Agents I' and II' of the formulations shown in Table 3 were immersed in water baths at 20°C and 40°C for at least 30 minutes, respectively. Next, 10 g of Agent I' and 20 g of Agent II' were placed in a standard bottle No. 6 manufactured by Kakuyo Glass Co., Ltd., and the bottle was capped and held by hand. The mixture was mixed 30 times at a rate of twice per second with a swing amplitude of approximately 30 cm. The resulting mixture was filled to the brim in a 9.7 mL volume PP plastic cup No. 5 manufactured by Maruemu Co., Ltd., and the weight of the mixture was measured. Based on the measured values, the expansion ratio (mL / g) was calculated using the following formula:

[0162]

[0163] Using the obtained expansion ratio value as an index, the foaming suppression effect of the mixture in a high-temperature environment was evaluated according to the following criteria. If the expansion ratio is 2.0 (mL / g) or less, the mixture obtained by mixing in a high-temperature environment can be evaluated as having an excellent foaming suppression effect, and if the expansion ratio is 1.5 (mL / g) or less, the effect can be evaluated as being even more excellent. 5: Expansion ratio 1.5 (mL / g) or less 4: Expansion ratio more than 1.5 (mL / g) and less than 2.0 (mL / g) 3: Expansion ratio more than 2.0 (mL / g) and less than 2.5 (mL / g) 2: Expansion ratio more than 2.5 (mL / g) and less than 3.0 (mL / g) 1: Expansion ratio more than 3.0 (mL / g)

[0164] <<Mixability of Agents>> Agent I' and Agent II', each having the formulation shown in Table 3, were immersed in a 20°C water bath for at least 30 minutes. Next, 10 g of Agent I' and 20 g of Agent II' were placed in a standard bottle No. 6 manufactured by Kakuyo Glass, the lid was put on, and the bottle was held in the hand and mixed 30 times at a rate of twice per second with a swing amplitude of approximately 30 cm. The bottom of the standard bottle was visually inspected, and the mixability of the agents was evaluated according to the following criteria: 5: Cleanly mixed except for the edges 4: Some areas are slightly unmixed and white except for the edges 3: Approximately half of the area is unmixed and white except for the edges 2: Most of the area is unmixed and white except for the edges 1: Not completely mixed and white except for the edges

[0165]

[0166] *11: Farmin DM E-80 (manufactured by Kao Corporation) *12: Courtamine 60W (manufactured by Kao Corporation) *13: SILSOFT EM341N EMULSION (manufactured by Momentive Performance Materials Japan LLC) *14: DOWSIL CF 1046 (manufactured by Dow Toray Industries, Inc.) *15: Courtamine 2285E-E (manufactured by Kao Corporation) *16: Emanone CH-40 (manufactured by Kao Corporation) *17: Kalcol 6850 (manufactured by Kao Corporation) *18: DPG-RF (manufactured by ADEKA Corporation) *19: Exepar TGO (manufactured by Kao Corporation) *20: SILKFLO 364 (manufactured by Vantage Specialty Chemicals) *21: NIKKOL Sugar squalane (manufactured by Nippon Surfactant Industries Co., Ltd.) * 22: Pearleem EX (manufactured by NOF Corporation) * 23: Salacos 913 (manufactured by Nisshin Oillio Group Co., Ltd.) * 24: Amisoft CS-22B (manufactured by Ajinomoto Co., Inc.) * 25: MERQUAT 280NP POLYMER (manufactured by Lubrizol Advanced Materials, Inc.) * 26: Crewat S1 (manufactured by Nagase & Co., Ltd.) * 27: Purified anhydrous sodium sulfite (manufactured by Air Water Performance Chemicals Co., Ltd.) * 28: AG-10LK (manufactured by Kao Corporation) * 29: Penetol GE-EH (manufactured by Kao Corporation) * 30: Oxyquinoline sulfate (2) (manufactured by Nippon Rikagaku Yakuhin Co., Ltd.) * 31: Dayquest 2010CS (manufactured by Italmatch Japan Co., Ltd.)

Claims

1. A multi-component hair dye or bleach composition comprising multiple components, including component I' and component II', which are mixed together at the time of use, wherein component I' contains the following components (A'-1) and (B'): (A'-1) an anionic surfactant (B') a cationic polymer, and component II' contains the following components (C') and (D''): (C') a higher alcohol (D'') a polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents a number of 30 to 200 on average), and the content of component (D'') in a mixture obtained by mixing all of the constituent components is 0.6 mass% or more.

2. The multi-component hair dyeing or bleaching composition according to claim 1, further comprising component (E'), which is one or more chlorides selected from alkali metal salts of organic acids having 6 or less carbon atoms, alkaline earth metal salts of organic acids having 6 or less carbon atoms, inorganic alkali metal salts, and inorganic alkaline earth metal salts.

3. A multi-component hair dyeing or bleaching composition according to claim 1 or 2, wherein component (B') contains one or more selected from the group consisting of a polymer containing a diallyl quaternary ammonium salt as a constituent unit, a cationized polygalactomannan, a cationized hydroxyalkyl cellulose, a copolymer containing methacrylamide propyl trimethyl ammonium chloride, and a crosslinked cationic polymer.

4. A multi-component hair dyeing or bleaching composition according to any one of claims 1 to 3, wherein component (C') contains one or more selected from the group consisting of cetanol, stearyl alcohol, and behenyl alcohol.

5. The multi-component hair dyeing or bleaching composition according to any one of claims 1 to 4, further comprising an ionic surfactant (A'-2) other than component (A'-1).

6. The multi-component hair dyeing or bleaching composition according to claim 5, wherein the mass ratio of the content of component (A'-2) to the content of component (D'') ((A'-2) / (D'')) is 0.6 or less.

7. A multi-component hair dyeing or bleaching composition according to any one of claims 1 to 6, wherein the viscosity ratio (Agent II' / Agent I') of the viscosity of Agent II' at 30°C to the viscosity of Agent I' at 30°C is 3 or more.

8. A multi-component hair dyeing or bleaching composition according to any one of claims 1 to 7, wherein the mixture obtained by mixing all of the constituent components is in the form of a gel.

9. A hair dyeing method comprising the steps of applying the multi-component hair dyeing or bleaching composition according to any one of claims 1 to 8 to the roots of the hair and then spreading it to the ends.

10. A multi-component hair dyeing or bleaching kit comprising multiple components including component I' and component II', which are mixed together at the time of use, wherein component I' contains the following components (A'-1) and (B'): (A'-1) anionic surfactant (B') cationic polymer, and component II' contains the following components (C') and (D''): (C') higher alcohol (D'') polyoxyalkylene alkyl ether R represented by the following formula (5'): 10 -O-(A a O) r' -H...(5') (In formula (5'), R 10 represents a linear or branched, saturated or unsaturated hydrocarbon group having 8 to 22 carbon atoms; A a represents an alkylene group having 2 to 4 carbon atoms, and r' represents a number of 30 to 200 on average), and the content of component (D'') in a mixture obtained by mixing all of the constituent components is 0.6 mass% or more.

11. A multi-component cosmetic composition comprising the following components (A) to (D): (A) an ionic surfactant, (B) a cationic polymer, (C) a higher alcohol, and (D) a nonionic surfactant, and comprising multiple components including an agent I and an agent II having different viscosities at least at 30°C, and in which all of the components are mixed together at the time of use, wherein the viscosity ratio of the agent II at 30°C to the viscosity of the agent I at 30°C (agent II / agent I) is 3 or more, and the mixture obtained by mixing all of the components has a viscosity of 0.001 S when measured at 25°C using a rheometer. -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 a ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) of 5,000 or more.

12. The multi-component hair dyeing or bleaching composition according to claim 11, wherein component (A) contains one or two surfactants selected from anionic surfactants and cationic surfactants.

13. The multi-component cosmetic composition according to claim 11 or 12, which does not contain salicylic acid or acetaminophen.

14. A cosmetic kit comprising a multi-component cosmetic composition and a treatment agent composition that is separate and independent and contains one or more modified silicones (X1) selected from amino-modified silicones and aminopolyether-modified silicones, and / or dimethicone (X2), wherein the multi-component cosmetic composition contains the following components (A) to (D): (A) ionic surfactant (B) cationic polymer (C) higher alcohol (D) nonionic surfactant, and comprises multiple components including agent I and agent II that have at least different viscosities at 30°C, and all of the components are mixed together when used, wherein the viscosity ratio of agent II at 30°C to the viscosity of agent I at 30°C (agent II / agent I) is 3 or more, and the mixture obtained by mixing all of the components has a shear rate of 0.001 S when measured with a rheometer at 25°C. -1 ~1000S -1 When the shear rate was changed to 0.0037 S -1 Shear viscosity a and shear rate at 139S -1 The ratio of shear viscosity a to shear viscosity b at shear viscosity a (shear viscosity a / shear viscosity b) is 5000 or more.

Images