6 results about "O-dichlorobenzene" patented technology

The application belongs to the technical field of organic synthesis, and particularly relates to a method for catalytically synthesizing N-substituted-3-methyl indole compounds by using aza carbene oxazoline ring palladium compound. The application aims to provide a new synthesis method for N-substituted-3-methyl indole compounds, specifically, a high-catalytic-activity aza carbene oxazoline ring palladium compound is used as a catalyst to catalyze a direct coupling cyclization reaction of o-dichlorobenzene or o-bromochlorobenzene compounds and allyl arylamine, so as to obtain N-substituted-3-methyl indole compounds. The catalyst used in the application has high catalytic activity, the reaction has good product and functional group compatibility, in addition, the catalyst itself is easy to synthesize, and aryl chlorides used in the synthesis route are cheap and easy to obtain. Therefore, the synthesis route provided in the application has great competitive advantages and industrial production utilization value.

The present application belongs to the technical field of rectification separation, and provides a rectification separation and purification method for preparing high-purity o-dichlorobenzene. The present application adopts the design of loading surface-modified structured packing in the rectification section of the rectification tower. The structured packing is composed of an alumina ceramic matrix and a cross-linked copolymer layer. The cross-linked copolymer layer contains structural units formed by N-vinyl-2-pyrrolidone, 2-hydroxyethyl methacrylate and ethylene glycol dimethacrylate, and is prepared through a silanization and graft cross-linking polymerization process. The rectification tower is operated under the conditions of a tower top absolute pressure of 0.5-20 kPa and a reflux ratio of 2-6. The present application realizes the efficient separation of o-dichlorobenzene products with a purity of not less than 99.9 wt% from dichlorobenzene isomer mixtures, solves the problem that the structured packing in a low-pressure rectification system cannot simultaneously achieve low pressure drop, large flux and high separation efficiency, and the stability of the surface modification layer in a high-temperature organic vapor environment is insufficient, and has wide industrial application value.

The application discloses a kind of solid-state luminescent Schiff base two-dimensional covalent organic framework material and its preparation method and application, belong to material field.The preparation method of the solid-state luminescent Schiff base two-dimensional covalent organic framework material of the present application includes the following steps: the amine with C2 symmetry, DAD, solvent and acetic acid aqueous solution are mixed, and solvent thermal reaction is carried out, to obtain the solid-state luminescent Schiff base two-dimensional covalent organic framework material;The solvent is o-dichlorobenzene and n-butanol.The COFs material prepared in the application has high crystallinity and porosity, and the solid-state absolute luminescence quantum yield is as high as 39%.

A lithium-mediated electrochemical method for ammonia synthesis, relating to the field of ammonia synthesis technology, solves the technical problems of severe side reactions, limited nitrogen mass transfer, and poor interfacial stability in existing lithium-mediated ammonia synthesis systems. Tetra(4-formylphenyl)porphyrin iron and an amino-containing multifunctional organic ligand are added to a mixed solvent of n-butanol and o-dichlorobenzene. An acid catalyst is added, and after stirring until homogeneous, the mixture is degassed and sealed for reaction. The solid product is collected by centrifugation, washed, and dried to obtain COF powder. This powder is then added to an ethanol-water solution, followed by ultrasonic dispersion with Nafion solution. The powder is then drop-coated / sprayed onto the surface of a carbon paper current collector and dried. This powder is used as the working electrode, with a platinum mesh as the counter electrode, a platinum wire as the quasi-reference electrode, and a LiBF4 tetrahydrofuran solution as the electrolyte. Ethanol is used as the proton donor, and electrolysis is performed under a nitrogen atmosphere using a constant current. This invention can be applied to the field of ammonia synthesis technology.

A toner, comprising a toner particle comprising a binder resin, wherein the binder resin comprises an amorphous polyester and a crystalline polyester; (i) a weight-average molecular weight of a soluble matter of the crystalline polyester in o-dichlorobenzene at 100° C. is 1500 to 4900; (ii) the crystalline polyester comprises a modified crystalline polyester having at least one terminal-modified structure selected from among a structure in which a hydroxy group at a main chain terminal of the crystalline polyester is terminal-modified with a C16 to C31 aliphatic monocarboxylic acid, and a structure in which a carboxy group at a main chain terminal of the crystalline polyester is terminal-modified with a C15 to C30 aliphatic monoalcohol; and (iii) a content ratio of the terminal-modified structure in the crystalline polyester is 80.0 mol % or higher.

The present application belongs to the field of chemical analysis and detection and rectification control, and provides a detection method and preparation method of high-purity o-dichlorobenzene, the present application determines through closed sampling, different polarity capillary column double-column gas chromatography, target impurity fingerprint, water content and acidic component combination, and feeds back the determination result to the light removal, main rectification, heavy removal and reprocessing path according to the corresponding relationship between abnormal index and preparation parameter, forms a detection-preparation feedback closed loop, realizes stable 1,2-dichlorobenzene purity, accurate impurity attribution and timely working condition adjustment, solves the problem that purity stability and processing efficiency, feedback timeliness and attribution accuracy are difficult to be considered, and is suitable for high-purity o-dichlorobenzene continuous or batch production quality control.