234 results about "O-dichlorobenzene" patented technology

This invention provides a solid titanium catalyst component which comprises magnesium, titanium, halogen and an electron donor, is free from elimination of titanium when washed with hexane at room temperature, and has a titanium content decrease ratio of less than 15 % by weight when washed with o-dichlorobenzene at 90° C. The catalyst component can be prepared by a process wherein solid titanium (i) which is free from elimination of titanium when washed with hexane at room temperature is contacted with a polar compound having a dipole moment of 0.50 to 4.00 Debye to decrease the titanium content by at least 25 % by weight, whereby a solid titanium catalyst component having a weight ratio of an electron donor to titanium of at least 6 is prepared. Olefin polymerization catalyst containing the solid titanium catalyst component can be used for (co)polymerization of olefins with high activity to obtain a polyolefin of high stereoregularity in decreased quantities of a low stereoregular polyolefin.

In a toner having toner particles having at least a binder resin and a colorant, the binder resin in the toner contains at least i) a vinyl resin formed of a vinyl resin having at least a carboxyl group and a vinyl resin having at least an epoxy group, and having a cross-linked structure formed by the reaction of the carboxyl group of the former with the epoxy group of the latter, and ii) a copolymer having an aliphatic conjugated diene compound as a monomer component; and the binder resin in the toner has a THF-insoluble matter in a content of from 0.1% by weight to 60% by weight, and the copolymer having an aliphatic conjugated diene compound as a monomer component is incorporated in an o-dichlorobenzene-soluble matter of the THF-insoluble matter. This toner has superior developing stability and running performance in high-speed machines, and can keep fixing separation claws from contamination.

The present invention relates to an organic semiconductor thin film suitably employed in electronics, photonics, bioelectronics, or the like, and a method for forming the same. The present invention further relates to a solution for an organic semiconductor used to form the organic semiconductor thin film and an organic semiconductor device using the organic semiconductor thin film.

The transistor of the present invention is manufactured by forming sequentially a gate electrode (2), an insulator layer (3), a source electrode and drain electrode (4, 4) on a glass substrate (5), applying thereto a 0.05% (by mass) solution of pentacene in o-dichlorobenzene and drying the solution to form an organic semiconductor thin film (1).

The present invention provides a transistor with superior electronic characteristics because the organic semiconductor thin film (1), which can be formed easily at low cost, is almost free of defects.

The invention provides a chloration method for phenoxyacetic acid and derivatives thereof, which comprises the following steps that: raw materials of the phenoxyacetic acid or the derivatives of the phenoxyacetic acid and chlorinating agents take reaction at a certain temperature in organic solvents under the effect of catalysts, wherein the chlorinating agents can be chlorine gas, sodium hypochlorite, calcium hypochlorite and sulfuryl chloride, the catalysts can be lewis acid and sulfurated substances, and solvents can be dichloromethane, dichloroethane, trichloromethane, carbon tetrachloride, formic acid, ethyl acetate, benzene, toluene, dimethylbenzene, chlorobenzene and o-dichlorobenzene. The method has the advantages that the operation can be carried out under the waterless condition, the generation of a large amount of industrial waste water is avoided, the used catalysts are safe and are easy to obtain, the solvents can be cyclically used, and the industrialization is easy.

The present disclosure provides for improved soluble carbon nanotube (“CNT”) composites at least partially coated with a metal material, and improved methods for the synthesis, generation or formation of substantially soluble carbon nanotube composites via heating conditions (e.g., microwave reactions). For example, the present disclosure provides for methods for the rapid, controllable, environmentally-friendly formation of substantially soluble carbon nanotube composites via in-situ microwave-assisted reactions, wherein the carbon nanotube composites are at least partially coated with nanometal particles (e.g., nanoplatinum particles), and wherein the nanocomposites are substantially soluble in water and/or in organic solvents (e.g., o-dichlorobenzene (ODCB), chloroform, tetrahydrofuran (THF), ethanol, toluene, hexane and DMF).

The invention provides a method for modifying a covalent organic framework material. The method comprises the following steps: (1) mixing 1,3,5-tris-(4-aminophenyl)benzene with 2,5-dioxymethyl-terephthalaldehyde, adding o-dichlorobenzene/n-butanol and an acetic acid catalyst, carrying out freezing-exhausting-unfreezing circulation for several times, carrying out flame sealing, heating, centrifugally collecting precipitates, washing, carrying out Soxhlet extraction, drying, and collecting powder, so as to obtain TPB-DMTA-COF; (2) adding 2-methyl-2-butene, a sodium chlorite water solution and glacial acetic acid into dioxane suspension liquid of the TPB-DMTA-COF powder, and stirring in a dark environment, so as to obtain purple solids; and (3) re-oxidizing the purple solids by virtue of thesodium chlorite water solution, and carrying out filtration separation, washing, drying, so as to obtain purple powder. The preparation method is simple, the synthesis conditions are easily controlled, and prepared O-TPB-DMTA-COF powder has a good glycopeptides enriching effect.

The invention relates to the field of methods for preparing medicinal intermediates, in particular to the field of methods for preparing key intermediates of quinolone medicines, and develops a method for coproducing the key intermediates of the quinolone medicines by using o-dichlorobenzene as a raw material. The method comprises the following steps of: nitrifying the o-dichlorobenzene serving as the raw material, and performing distillation, purification and stepwise crystallization to obtain 2,3-dichloronitrobenzene and 3,4-dichloronitrobenzene; performing fluoridation on the 2,3-dichloronitrobenzene to obtain 3-chloro-2-fluoronitrobenzene, performing chlorination to obtain 2,6-dichlorofluorobenzene, performing nitration to obtain 1,3-dichloro-2-fluoro-4-nitrobenzene, and finally performing fluoridation to obtain 2,3,4-trifluoronitrobenzene; and performing fluoridation on the 2,3,4-trifluoronitrobenzene to obtain 3-chloro-4-fluoronitrobenzene, performing chlorination to obtain 1,3-dichloro-4-fluorobenzene, and finally performing acylation reaction on the 1,3-dichloro-4-fluorobenzene and acetylchloride to obtain 2,4-dichloro-5-fluoroacetophenone.

The invention specifically relates to production equipment for refining hexamethylene diisocyanate and a method thereof. A stirrer is respectively arranged in the middle of the bottom of both a distillation column and a rectifying tower which are provided with a stirring device, and stirring wings are a frame type. The method for refining hexamethylene diisocyanate comprises the following steps: (1) letting an synthesized HDI solution enter a distillation column through a heat exchanger, starting a first vacuum pump, and starting a first stirrer in the column bottom while the agitation speed is less than or equal to 60rpm/min; Starting a first condenser on the tower top, evaporating all o-dichlorobenzene, continuously discharging by the distillation column and entering a mixing tank; and (ii) adding a DEIP solvent into the mixing tank, uniformly mixing crude HDI and the DEIP solvent according to the HDI-DEIP ratio of 1:1-1.5, sending the mixture into the rectifying tower to firstly evaporate mono-isocyanate chloride and continuously evaporate the HDI, drawing forth the DEIP for recycling, stirring high polymer residue in a heating vessel and discharging regularly, and carrying out burning treatment. The device and method provided by the invention can be applied in distillation separation and purification production technology which is easy to generate auto-agglutination phenomenon under the distillation condition.

The invention relates to a preparation method of bromoamine acid, which comprises the following steps: (1) sulfonation reaction: by using 1-aminoanthraquinone as a raw material, dropwisely adding chlorosulfonic acid into an orthodichlorobenzene solvent to carry out sulfonation reaction so as to obtain the sulfonated material containing sulfonated product, wherein the weight ratio of the 1-aminoanthraquinone to the orthodichlorobenzene is 1:(5-7), and the temperature of the sulfonation reaction is 115-150 DEG C; (2) stratification by adding dilute sulfuric acid: after the sulfonation reaction reaches to the end, directly adding 55-60 wt% dilute sulfuric acid into the reaction system until the sulfonated material stratifies, wherein the upper stratum is an orthodichlorobenzene organic phase which can be used repeatedly, and the understratum is a sulfuric acid solution of 1-aminoanthraquinone-2-sulfonic acid; and (3) bromination reaction: adding water into the understratum material obtained in the step (2) until the acidity reaches to 8-10%, and directly dropwisely adding bromine to carry out bromination reaction, thereby obtaining the bromoamine acid crude product. The invention greatly lowers the energy consumption; and the quality and yield of the bromoamine acid product are obviously enhanced.

Bis(halophthalimides) are prepared in mixture in an organic liquid such as ortho-dichlorobenzene or anisole, by a reaction at a temperatire of at least 150° C. between at least one diamine compound and at least one halophthalic anhydride in the presence of imidization catalyst. The reaction mixture is maintained at about 15% by weight solids content and rich in the halophthalic anhydride by constantly monitoring the reaction mixture using analytical methods such as high performance liquid chromatography. The product mixture may be directly employed in the direct preparation of polyetherimides, and similar slurries may be employed to prepare other polyether polymers.

The invention discloses a synthetic method of m-dichlorobenzene which is obtained by transposition in the presence of a catalyst by taking o-dichlorobenzene and/or p-dichlorobenzene as raw materials. The catalyst is a composite catalyst comprising a solid phase catalyst and a gas phase catalyst, wherein the solid phase catalyst is aluminum trichloride or halide of transition metal, and the gas phase catalyst is anhydrous hydrogen chloride or other anhydrous halogen acids. The raw materials have no limitation of water, have arbitrary ortho-para proportion and react under normal pressure; the solid catalyst has long service life, and the gas catalyst can be recycled after gas-liquid separation and has high conversion ratio; and the synthetic method can be used for large-scale industrial production. The process realizes the automatic control easily and has energy saving, safety, environment protection and low cost.

The invention discloses a preparation method of a conjugated three-dimensional porphyrin-based covalent organic framework material. The preparation method comprises the following steps: taking 3,3', 5,5'-tetra (4-formylphenyl) hexamethylbiphenyl (TFBM) and a series of porphyrin derivatives as raw materials, o-dichlorobenzene and n-butanol as solvents and acetic acid as a catalyst, and carrying outsolvothermal reaction for several days; after the reaction is finished, sequentially using DMF and THF for suction filtration and washing, carrying out soxhlet extraction for 24 hours, and carrying out vacuum drying to obtain purple black powder, namely the target product. For the first time, tetrahedral tetraaldehyde based on steric hindrance effect is used as a building block, so that the material has a fully conjugated three-dimensional skeleton structure, good thermal stability and chemical stability, and porphyrin units facing three-dimensional pore channels are used as single active catalytic sites, so that the material shows good application prospects in the field of bionic catalysis.

The invention discloses a complex function resin and process for preparation, and a method used for dealing with phthalate ester water body pollution. The process for preparation comprises the following procedures: swelling chlorine ball in the organic solvent; sulfonating in the mixing condition; getting the sulfonated chlorine ball after reacting; charging nitrobenzene or o-dichlorobenzene in order to swell in the air-tight condition after drying the sulfonated chorine ball; charging the accelerant in order to react; filtering the resin; washing the resin sequentially with distilled water, alcohol and chlorhydric acid 2%-5%; washing the resin with the distilled water until the washed water is neutral; getting the complex function resin. The specific surface area of the complex function resin is 900-1500m2/g, the exchange capacity of corrosive acid is 2.1-5.5mmol/g, and the sulfonic group is distributed in the micropore section, the mesopore section and the big pore section of the resin. The complex function resin is applied to deal with water body polluted by phthalate ester. The invention solves the problem that the corrosive acid of the prior complex function resin is concentrated in the mescopore and the big pore of the resin and is distributed less in the micropore, which enhances the absorption effect of the resin for phthalate ester, and enhances the acid hydrolysis catalytic activity of the resin.

The invention mainly discloses a synthetic method of p-hydroxyacetophenone. According to the synthetic method, phenol and acetic anhydride are taken as raw materials so prepare phenylacetate; under catalytic action of aluminium trichloride, o-dichlorobenzene is added for reaction, steam distillation is carried out, active carbon filtration is carried out, and crystallization is carried out so as to obtain p-hydroxyacetophenone; and then p-hydroxyacetophenone is also prepared via two times of circular reaction of o-dichlorobenzene layer and phenylacetate, wherein the o-dichlorobenzene layer contains o-hydroxyacetophenone and is obtained via layering of a product of the former reaction. Compared with the prior art, the synthetic method possesses following advantages: side product suppression assistant circulating method (three times of continuous operation, and two times of circulation) is adopted, o-dichlorobenzene containing o-hydroxyacetophenone is used in circulation process, generation of o-hydroxyacetophenone in subsequent process is reduced effectively, p-hydroxyacetophenone yield is increased by 10% at least, and HPLC detection purity is 99.7% or higher. The synthetic method is capable of increasing p-hydroxyacetophenone yield, realizing reasonable cyclic utilization of side product, and reducing production cost, and is suitable for industrialized production.

One object of the present invention is to provide a polyethylene-base resin laminate having excellent properties in the transparency, blocking resistance, flexibility and the like, exhibiting heat resistance high enough to withstand a sterilization at 121° C., and being greatly improved in the impact strength of seal part as compared with conventional laminates; in order to achieve the object, the present invention provide a laminate having at least an inner layer, an intermediate layer and an outer layer, wherein said inner layer comprises a resin material (A) containing a high-density polyethylene, said intermediate layer comprises a resin material (B) mainly comprising Polyethylene-Base Resin I which is an ethylene.alpha-olefin copolymer obtained by copolymerizing ethylene with an alpha-olefin having from 3 to 20 carbon atoms and which has the following physical properties (a) to (d), and said outer layer comprises a resin material (c) containing a high-density polyethylene: (a) the density is less than 0.920 g/cm<3>, (b) the MFR is from 0.1 to 50 g/10 min, (c) the amount X (% by mass) of o-dichlorobenzene-soluble portion at 25° C., the density d (g/cm<3>) and the MFR (g/10 min) satisfy the following relationship: X<9.8X10<3>x(0.9300-d+0.008 logMFR)<2>+2.0 (d) the parameter Cb of the composition distribution is from 1.08 to 2.00.

The invention discloses a method for reducing COD (chemical oxygen demand) of permanent violet process wastewater and an application of the method and belongs to the technical field of pigment wastewater treatment. The method comprises the following steps: firstly, process wastewater is collected and treated in a classified manner according to specific pollutants of the wastewater: a nekal-bx-containing nitride washing wastewater is subjected to alkali regulating treatment, a flocculating agent is added for coagulating sedimentation, and an anionic surfactant is removed; layered wastewater produced through solvent o-dichlorobenzene recovery is subjected to alkaline hydrolysis and stripping; high-concentration wastewater containing triethylamine hydrochloride at a front section is separated from finished washing wastewater and subjected to alkali regulation and distillation, and triethylamine is recovered; secondly, the three parts of treated wastewater are mixed with other acidic wastewater for iron-carbon micro-electrolysis and Fenton oxidation coupled reinforced treatment. Classified collection and quality-divided treatment are performed according to features of the wastewater pollutants, the treatment process is safe and environment-friendly, wastewater treatment is targeted, refractory organics are removed to a greater extent, and the COD and total nitrogen content of the wastewater are reduced.

The invention discloses distillation equipment and method for separating dichlorobenzene isomers. The distillation equipment comprises a dividing wall tower, a tower kettle reboiler and a tower top condenser, wherein the dividing wall tower comprises a middle tower region, a tower top distillation section arranged above the middle tower region and used for performing distillation and separation on m-dichlorobenzene and p-dichlorobenzene, and a tower kettle stripping section arranged below the middle tower region and used for stripping and separating m-dichlorobenzene and o-dichlorobenzene; the middle tower region is divided into a pre-separation tower region and a finished product separation tower region by a baffle plate arranged in a longitudinal direction; the pre-separation tower region is parallel to the finished product separation tower region; the pre-separation tower region comprises an upper feeding distillation section and a lower feeding stripping section; the finished product separation tower comprises an upper m-dichlorobenzene/p-dichlorobenzene stripping section and a lower p-dichlorobenzene/o-dichlorobenzene distillation section. According to the distillation equipment, the dichlorobenzene isomers, namely the m-dichlorobenzene, the p-dichlorobenzene and o-dichlorobenzene can be separated in a distillation tower through the dividing wall tower, so that the energy consumption, the equipment investment and the occupied area are reduced.

The invention discloses a synthesizing method for an amide compound shown in formula (III). The synthesizing method comprises the following steps: adopting replacing acetonitrile shown in formula (I) and amines compound shown in formula (II) as raw materials in air atmosphere; adopting Ru/C as a catalyst; conducting reaction in solvent to generate the amide compound shown in formula (III); the solvent is one selected from ethyl alcohol, furanidine, methyl sulfoxide and o-dichlorobenzene. The synthesizing method being novel synthesizing route is simple to operate, convenient in post-treatment, high in product yield, and good in product purity; particularly, the catalyst and the solvent can be used repeatedly; air is taken as oxidant; not only production cost is reduced, but also the method is environmental-friendly, and very suitable for large-scale industrialization production.

The invention relates to a method for recovering o-dichlorobenzene through a sulfonation process of bromamine acid produced by a solvent method, which comprises the following steps of: after 1-amino-anthraquinone is sulfonated by the chlorosulfonic acid in an o-dichlorobenzene solvent, adding 93-96 percent of sulfuric acid to extract 1-amino-anthraquinone-2-sulfonic acid from an o-dichlorobenzene layer; and carrying out distilling under reduced pressure on sulfuric acid solution to recover the o-dichlorobenzene. The sulfuric acid solution recovering the o-dichlorobenzene can be directly bromized. The method has the beneficial effects that the recovery rate of the o-dichlorobenzene reaches above 98 percent, the recovery rate of the solvent o-dichlorobenzene is greatly improved, the emission of an organic solvent is reduced, the environment is protected, and meanwhile, the energy consumption is low.