An internal heating type continuous semi-carbon method carbon disulfide reaction furnace without harmful gas emission

Abstract

The present application relates to the technical fields of reaction furnace, in particular to a kind of inner heating type continuous semi-coke method carbon disulfide reaction furnace without harmful gas emission, including shell, the inner chamber of the shell is equipped with reaction kettle, the outer surface wall of the reaction kettle is connected with sulphur pipe that penetrates the lateral wall of shell, the bottom of the reaction kettle is connected with discharge pipe, the discharge pipe is directly below being provided with discharge bin, the top side of the discharge bin is connected with the discharge pipe between anti-leakage outer frame, the side of the discharge bin is equipped with driving motor, the one end of the driving motor is equipped with threaded transmission rod that penetrates the lateral wall of discharge bin inner chamber;The present application utilizes the waste heat of exhaust gas, heats neutralizing liquid, so that atomization effect is better, improves work efficiency, reduces the production cost of user, simultaneously can also adjust the volume of first discharge bin and second discharge bin, further adjusts the adding amount according to different granularity semi-coke, and makes the inactivated activated carbon plate revive, improves the versatility and durability of device.

Description

TECHNICAL FIELD

[0001] The present application relates to the technical field of reaction furnace, in particular to an internal heating type continuous semi-coke method carbon disulfide reaction furnace without harmful gas emission. BACKGROUND

[0002] Carbon disulfide is an inorganic substance, chemical formula is CS2, common solvent, colorless liquid, pure carbon disulfide used in the laboratory has a sweet aroma similar to chloroform, but the industrial product is usually impure and yellowish because of the presence of other sulfides, and has an unpleasant taste of rotten beets, it can dissolve sulfur, carbon disulfide is used to make rayon, pesticides, accelerators, etc., and also used as a solvent, according to the characteristics of carbon disulfide, it is suitable for continuous semi-coke method carbon disulfide reaction furnace, carbon disulfide reaction furnace produces harmful gas to human body when reacting, which cannot be directly discharged and needs to be treated to meet the standard before being discharged.

[0003] Chinese invention patent CN2016107200296 discloses a carbon disulfide reaction furnace, which comprises a furnace body, a feeding port, a discharging port and a slag outlet, the furnace body is divided into at least upper and lower two sections, the lower section is provided with a movable inner container, the inner container separates the space in the furnace body into a reaction chamber and a sulfur gasification chamber, the lower part of the inner container is provided with an inclined air hole, the air hole is higher at one end of the sulfur gasification chamber than at one end of the reaction chamber, and at least one sulfur adding port is arranged on the furnace body constituting the sulfur gasification chamber, but the carbon disulfide reaction furnace usually filters and discharges through an external treatment device, which occupies a very large space and increases the use cost, and the heat contained in the discharged waste gas cannot be effectively applied to help waste gas treatment, resulting in waste of energy, so a continuous semi-coke method carbon disulfide reaction furnace without harmful gas emission is needed.

[0004] Chinese invention patent CN021476780 discloses a process for producing carbon disulfide by semi-coke-sulfur method, semi-coke is added into the reaction furnace according to different particle size ratio, and chemical reaction is carried out with gaseous sulfur in the furnace at a temperature of 850-1000 DEG C to generate carbon disulfide gas, the carbon disulfide gas is discharged from the gas outlet at the top of the reaction furnace and enters the condensing system; during production, semi-flow bed feeding method is adopted, the cleaning interval of the slag generated after reaction is 48-72 hours, and the semi-coke is added in time after cleaning of the slag to ensure continuous reaction, therefore, the particle size of the semi-coke added into the reaction furnace should be controlled within 10-30 mm, the particle size ratio is 25-35% of 10 mm, 25-35% of 20 mm and 35-45% of 30 mm, but the existing device cannot accurately control and adjust the amount of semi-coke with different particle sizes during actual production, thereby causing low quality of the output and failing to meet normal production requirements.

[0005] At the same time, the activated carbon is prone to internal blockage during long-term use, thereby reducing the filtering and cleaning effect on carbon disulfide, and because the activated carbon is deactivated, the discharge path of the output carbon disulfide is blocked, further reducing the yield and concentration thereof. When discharging, the discharge pipe is blocked due to poor discharge of waste and sundries in the reaction furnace, which affects subsequent production. In addition, uneven stirring of the semicoke inside during the reaction affects the subsequent reaction and reduces the quality of the reaction product. SUMMARY

[0006] The purpose of the present application is to provide an internal heating type continuous semicoke method carbon disulfide reaction furnace without harmful gas emission, which solves the problem that the carbon disulfide reaction furnace on the market in the prior art is usually filtered and discharged by external treatment devices, occupies a very large space, and increases the use cost. The heat contained in the discharged waste gas cannot be effectively used to help waste gas treatment, resulting in waste of energy, and the control of the addition amount of semicoke of different particle sizes and the deactivation of activated carbon plates.

[0007] In order to achieve the above-mentioned purpose, the present application adopts the following technical scheme: an internal heating type continuous semicoke method carbon disulfide reaction furnace without harmful gas emission, comprising an outer shell, an inner cavity of the outer shell is provided with a reaction kettle, an outer surface wall of the reaction kettle is communicated with a sulfur adding pipe penetrating through the side wall of the outer shell, the bottom of the reaction kettle is communicated with a slag outlet pipe, the directly below of the slag outlet pipe is provided with a discharge bin, a leakage-proof frame is arranged between the top of the discharge bin and the slag outlet pipe, the other side of the discharge bin is provided with a driving motor, one end of the driving motor is provided with a threaded transmission rod penetrating through the side wall of the inner cavity of the discharge bin, and the end of the threaded transmission rod away from the slag outlet pipe is provided with a fan blade.

[0008] A top cover is arranged at the top of the reaction kettle, the top cover is communicated with a gas outlet pipe penetrating through the top cover, the other end of the gas outlet pipe is communicated with a liquid storage box, the other end of the liquid storage box is communicated with a treatment bin, the top of the treatment bin is communicated with an exhaust pipe, and a plurality of detachable activated carbon plates are arranged in the inner cavity of the exhaust pipe and along the vertical direction of the exhaust pipe.

[0009] A first discharge bin is arranged on one side of the top cover through a second electromagnetic valve, a first bellow is arranged on the side wall of the heat conducting pipe through a first flow valve, a first baffle is arranged at the other end of the first bellow, the first baffle is in sliding connection with the first discharge bin, a second discharge bin is arranged at the other end of the top cover through a third electromagnetic valve, a second bellow is arranged on the other side wall of the heat conducting pipe through a second flow valve, a second baffle is arranged at the other end of the second bellow, and the second baffle is in sliding connection with the second discharge bin.

[0010] The driving motor drives the fan blade to rotate, the first electromagnetic valve is opened, when the opening degree of the first flow valve is larger, the volume change amount of the first bellow is larger, the moving distance of the first baffle in the first discharge bin is larger, and the volume of the first discharge bin is smaller; when the activated carbon plate is deactivated, the first electromagnetic valve is opened, the high-temperature sulfur carbide gas in the air outlet pipe enters the heat conduction pipe and passes through heat conduction to reactivate the activated carbon plate.

[0011] The present application has at least the following advantages:

[0012] 1. The present application adds raw materials to the inside of the reaction kettle through the setting of the sulfurizing pipe, helps to carry out the reaction, and the carbon residue generated in the reaction is discharged to the discharge bin through the slag outlet pipe, and the exhaust gas generated in the reaction is transmitted to the inside of the treatment bin through the exhaust pipe, because the exhaust gas contains heat, which will cause the surface of the exhaust pipe to heat up, the liquid storage box is penetrated through the exhaust pipe to heat the neutralizing liquid inside the liquid storage box, the neutralizing liquid inside the liquid storage box is transmitted to the atomizing head inside the treatment bin through the hose, and the exhaust gas is atomized and treated, the treated gas is discharged through the exhaust pipe, is affected by the activated carbon plate, and is subjected to secondary purification and filtration, and finally is discharged outward through the connecting ring, solves the problem of large space occupation of the treatment device, and utilizes the waste heat of the exhaust gas to help heat the neutralizing liquid, so that the atomization effect is better, the work efficiency is improved, and the production cost of the user is reduced.

[0013] 2. The present application is convenient for personnel to disassemble and replace the activated carbon plate through the setting of the limiting block and the limiting groove, the flow direction of the treated exhaust gas is limited through the setting of the connecting ring, foreign matters or dust in the outside is prevented from entering the inside of the exhaust pipe through the setting of the dustproof sheet, the personnel is convenient to add the neutralizing liquid to the inside of the liquid storage box through the setting of the adding pipe, and the exhaust gas is subjected to the effect of secondary purification and filtration through the setting of the activated carbon plate.

[0014] 3. The application solves the problems of different adding amounts of semi-coke of different particle sizes and the deactivation of activated carbon in the reaction process through the mutual cooperation of the first feeding bin, the second feeding bin, the heat conducting pipe, the first bellow, the first baffle, the second bellow and the second baffle. In actual use, the motor drives the fan blade to rotate, the fan blade pumps air to the reaction kettle and the discharge bin. The greater the opening degree of the first flow valve is controlled, the greater the volume change of the first bellow is, the greater the moving distance of the first baffle in the first feeding bin is, and the smaller the volume of the first feeding bin is. Then, the size of the first feeding bin and the second feeding bin can be controlled by controlling the opening size of the first flow valve and the second flow valve, further meeting the control of the adding amount of semi-coke of different particle sizes in actual use. When the activated carbon plate is deactivated, only the first electromagnetic valve needs to be opened. The high-temperature sulfur carbide gas reaches the heat conducting pipe along the air outlet pipe and reaches the outer surface of the processing bin along the heat conducting pipe. The temperature of the activated carbon plate can be increased by heat conduction of the high-temperature gas, so that the activated carbon plate is revived and reused. The device can effectively control the adding amount of semi-coke of different particle sizes, further meet the actual demand, improve the adaptability, and can also recycle and process impurities in the reaction kettle when adjusting the adding amount of semi-coke, improve the multi-functionality of the device, save time, and improve the reaction efficiency. At the same time, in the case that the activated carbon plate is deactivated after long-term use, the deactivated activated carbon plate is revived at high temperature by the high-temperature sulfur carbide gas produced by the reaction, so that it regains the required filtering effect, improves the durability of the device, reduces the reaction consumption, and ensures the reaction effect. BRIEF DESCRIPTION OF DRAWINGS

[0015] In order to more clearly illustrate the technical solutions of the embodiments of the present application, the following will briefly introduce the drawings needed in the embodiment description. Obviously, the drawings in the following description are some embodiments of the present application, and other drawings can also be obtained by those skilled in the art without creative labor.

[0016] Figure 1 It is a schematic diagram of the overall structure of the present application.

[0017] Figure 2 It is a schematic diagram of the overall structure of another embodiment of the present application.

[0018] Figure 3 It is a schematic diagram of the top cover structure of the present application.

[0019] Figure 4 It is a schematic diagram of the internal structure of the processing bin of the present application.

[0020] Figure 5 It is an explosion view of the air outlet pipe of the present application.

[0021] Figure 6 It is a top view of the top cover of the present application.

[0022] In the figure: 1, shell; 2, support leg; 3, connecting plate; 4, leakage-proof outer frame; 5, reaction kettle; 6, slag outlet pipe; 7, sulfur adding pipe; 8, top cover; 9, gas outlet pipe; 10, liquid storage box; 11, adding pipe; 12, hose; 13, processing bin; 14, exhaust pipe; 15, dustproof sheet; 16, atomizing head; 17, limiting groove; 18, activated carbon plate; 19, limiting block; 20, air permeation hole; 21, connecting ring; 22, discharge bin; 23, driving motor; 24, cooling water tank; 25, first discharging bin; 26, second discharging bin; 27, heat conducting pipe; 28, first bellow; 29, first baffle; 30, second bellow; 31, second baffle. DETAILED DESCRIPTION

[0023] In order to make the objects, technical solutions and advantages of the present application clearer, the present application will be further described in detail below with reference to the accompanying drawings and examples. It should be understood that the specific examples described herein are only used to explain the present application and do not limit the present application. EXAMPLE

[0024] REFERENCE Figures 1-6The utility model provides a kind of carbon disulfide reaction furnace of continuous semi-coke method without harmful gas escape, including shell 1, the inner chamber of shell 1 is equipped with reaction kettle 5, and the inner side wall of shell 1 is equipped with several electric furnace wire heating blocks, and the outer wall of reaction kettle 5 is attached with electric furnace wire heating block, the outer surface wall of reaction kettle 5 is communicated with the sulfurization pipe 7 that penetrates the lateral wall of shell 1, and the bottom of reaction kettle 5 is communicated with the discharge pipe 6, and the discharge pipe 6 is provided with discharge bin 22 directly below, and the top side of discharge bin 22 is communicated with the discharge pipe 6 between the outer frame 4 of leakage prevention and is equipped with the threaded transmission rod that penetrates the lateral wall of the inner chamber of discharge bin 22 in one end of driving motor 23, and the bottom side of discharge bin 22 is communicated with cooling tank 24, the lower surface of shell 1 is equipped with connecting plate 3, and the four corners of the bottom of connecting plate 3 are all equipped with support leg 2, the top of reaction kettle 5 is equipped with top cover 8, and the other side of top cover 8 is communicated with gas outlet pipe 9, the other end of gas outlet pipe 9 is communicated with liquid storage box 10, the other end of liquid storage box 10 is communicated with processing bin 13, the two sides of the outer wall of liquid storage box 10 close to processing bin 13 are all communicated with hose 12, the end of hose 12 away from liquid storage box 10 is communicated with atomizing head 16 that is installed in the lateral wall of processing bin 13 and penetrates the lateral wall of processing bin 13, the top of processing bin 13 is communicated with exhaust pipe 14, the inner chamber of exhaust pipe 14 and along exhaust pipe 14 vertical direction are provided with several detachable connection activated carbon plate 18, and the top of activated carbon plate 18 is provided with several air holes 20, specifically, when personnel uses, semi-coke is added in reaction kettle 5, the physical contact of electric furnace wire heating piece inside shell 1 and reaction kettle 5 makes reaction kettle 5 warm, raw material sulfur is added to the inside of reaction kettle 5 through sulfurization pipe 7, to help reaction, carbon residue produced in reaction is discharged to discharge bin 22 through discharge pipe 6, carbon residue is transmitted to cooling tank 24 by driving motor 23 to drive threaded transmission rod to rotate, exhaust gas produced in reaction is transmitted to the inside of processing bin 13 through gas outlet pipe 9, because exhaust gas contains heat, will cause the surface of gas outlet pipe 9 to warm, neutralizing liquid in the inside of liquid storage box 10 is heated by liquid storage box 10 that penetrates gas outlet pipe 9, neutralizing liquid in the inside of liquid storage box 10 is transmitted to atomizing head 16 in the inside of processing bin 13 through hose 12 and atomizes, exhaust gas is treated by neutralization, after treatment, gas is affected by activated carbon plate 18, and secondary purification filtering is carried out, finally, it is discharged outwardly via connecting ring 21, solve the problem that processing device space occupies big, and utilize the waste heat of exhaust gas, help neutralizing liquid to heat, so that atomization effect is better, improve work efficiency, reduce the production cost of user.

[0025] The active carbon plate 18 is provided with a limiting block 19 on both sides, and the limiting block 19 is in sliding connection with a limiting groove 17 opened in the inner cavity of the exhaust pipe 14. Specifically, through the setting of the limiting block 19 and the limiting groove 17, the personnel can conveniently disassemble and replace the active carbon plate 18.

[0026] The upper surface of the exhaust pipe 14 is provided with a connecting ring 21. Specifically, through the setting of the connecting ring 21, the flow direction of the treated exhaust gas is limited.

[0027] The upper surface of the connecting ring 21 is provided with a dustproof sheet 15. Specifically, through the setting of the dustproof sheet 15, the foreign matters or dust from the outside is prevented from entering the inside of the exhaust pipe 14.

[0028] The side outer wall of the liquid storage box 10 is communicated with an adding pipe 11. Specifically, through the setting of the adding pipe 11, the personnel can conveniently add the neutralizing liquid into the inside of the liquid storage box 10.

[0029] The top of the active carbon plate 18 is provided with a plurality of gas permeable holes 20 distributed in a circumferential array. The top of the gas permeable hole 20 is communicated with a sulfur dioxide gas recovery box. Specifically, through the setting of the active carbon plate 18, the exhaust gas is subjected to the effect of secondary purification and filtration, and the product is directly recovered to the sulfur dioxide gas recovery box through the gas permeable hole 20.

[0030] In personnel use, the reaction kettle 5 is heated by physical contact of the heating sheet inside the shell 1 with the electric furnace wire, raw material liquid sulfur is added to the inside of the reaction kettle 5 through the sulfur adding pipe 7 to help the reaction, the carbon residue generated in the reaction is discharged to the discharge bin 22 through the slag discharge pipe 6, the carbon residue is conveyed to the cooling tank 24 by rotating the threaded conveying rod driven by the driving motor 23, the exhaust gas generated in the reaction is transmitted to the inside of the treatment bin 13 through the exhaust pipe 9, because the exhaust gas contains heat, which will cause the surface of the exhaust pipe 9 to heat up, the neutralizing liquid inside the liquid storage box 10 is heated through the liquid storage box 10 penetrating the liquid storage box 10, the neutralizing liquid inside the liquid storage box 10 is transmitted to the atomizing head 16 inside the treatment bin 13 through the hose 12 to atomize and neutralize the exhaust gas, the treated gas is subjected to secondary purification and filtration by the activated carbon plate 18, and finally discharged outward through the connecting ring 21 and recovered to the sulfur gas recovery tank through the air hole 20. By the setting of the limiting block 19 and the limiting groove 17, the personnel can conveniently disassemble and replace the activated carbon plate 18. By the setting of the connecting ring 21, the flow direction of the treated exhaust gas is limited. By the setting of the dustproof sheet 15, foreign matter or dust from the outside is prevented from entering the inside of the exhaust pipe 14. By the setting of the adding pipe 11, the personnel can conveniently add neutralizing liquid to the inside of the liquid storage box 10. By the setting of the activated carbon plate 18, the exhaust gas is subjected to the effect of secondary purification and filtration, the problem of large space occupation of the treatment device is solved, and the waste heat of the exhaust gas is utilized to help heat the neutralizing liquid, so that the atomization effect is better, the work efficiency is improved, and the production cost of the user is reduced. Embodiment

[0031] Based on the first embodiment, a continuous semi-coke carbon disulfide reaction furnace without harmful gas emission is provided. In actual use, raw material semi-coke needs to be added to the reaction kettle 5. The main component of semi-coke is the product of low-temperature dry distillation of lignite, which is a carbon material with high carbon content, easy to burn, and has high chemical activity, which is beneficial to the chemical diffusion of sulfur vapor. However, due to the large pore size of semi-coke, the adsorption of sulfur is poorer than that of charcoal, and it is not easy to form ash after reaction, which affects the carbon supplement space. In order to solve this problem, when semi-coke is selected, it is necessary to use semi-coke with different particle sizes, so the particle size ratio of semi-coke used is 10mm for 25-35%, 20mm for 25-35%, and 30mm for 35-45%. By using this ratio, the amount of semi-coke added can be increased, the gas resistance can be increased, and the time of sulfur staying in the reaction furnace can be prolonged, which can promote the smooth progress of the chemical reaction. Therefore, when adding semi-coke, the addition ratio needs to be adjusted according to different particle sizes to obtain the best reaction effect.

[0032] Meanwhile, after the device is used for a long time, the activated carbon plate 18 will gradually be deactivated due to clogging. The deactivated activated carbon plate 18 not only loses the adsorption capacity for impurities of the product carbon disulfide, but also affects the subsequent normal discharge of carbon disulfide, hinders the subsequent reaction, and thus reduces the yield. In order to solve the above problems, the self-adaptive adjusting device adjusts the matching ratio of different particle sizes of semi-coke, and also revives the deactivated activated carbon plate 18 and improves the cleaning capacity of the device for the inside of the reaction kettle 5. The internal heat type continuous semi-coke carbon disulfide reaction furnace without harmful gas emission also comprises: a threaded transmission rod, one end of the threaded transmission rod away from the slag discharge pipe 6 is provided with a fan blade, so that the rotation of the driving motor 23 not only drives the threaded transmission rod to rotate and convey the waste discharged from the slag discharge pipe 6 into the cooling water tank 24 for recycling, but also drives the fan blade to rotate when the driving motor 23 rotates, thereby pumping air inside the whole discharge bin 22 and the reaction kettle 5, and cooperating with the rotation of the threaded transmission rod to clean the inside of the reaction kettle 5 thoroughly and effectively. The discharge bin 22 away from the fan blade is provided with an air outlet, which is mainly used for discharging the gas inside when pumping air. The other end of the air outlet is communicated with a recovery gas bag, which is convenient for recycling waste gas and avoiding environmental pollution.

[0033] One side of the air outlet pipe 9 is communicated with a heat pipe 27 through a first electromagnetic valve. The other end of the heat pipe 27 bypasses the treatment bin 13 and is communicated with the other side of the air outlet pipe 9. When the first electromagnetic valve is opened, the heat pipe 27 can guide the high-temperature carbon disulfide gas discharged along the air outlet pipe 9. The heat pipe 27 is in contact with the treatment bin 13, so that the high-temperature carbon disulfide gas entering the heat pipe 27 will conduct heat with the treatment bin 13. Therefore, the heat can be transmitted to the activated carbon plate 18 through heat conduction, and the deactivated activated carbon plate 18 can be revived again in a high-temperature environment. When the first electromagnetic valve is closed, the heat pipe 27 is no longer supplied with high-temperature carbon disulfide gas, and the activated carbon plate 18 returns to normal and continues to work.

[0034] The input end of the heat pipe 27 is located at the front end of the air outlet pipe 9, and the output end of the heat pipe 27 is located at the tail end of the air outlet pipe 9. In this way, when the first electromagnetic valve is opened, the high-temperature carbon disulfide gas discharged from the air outlet pipe 9 can enter the front end of the heat pipe 27, flow through the heat pipe 27 to the rear end, and then re-enter the air outlet pipe 9, thereby reviving the activated carbon plate 18 by virtue of the high-temperature characteristics of the high-temperature carbon disulfide gas, while not causing excessive waste of the product carbon disulfide gas.

[0035] One side of the top cover 8 is provided with a first discharge bin 25 through a second electromagnetic valve, one side of the heat pipe 27 is provided with a first bellows pipe 28 through a first flow valve, the other end of the first bellows pipe 28 is provided with a first baffle 29, the first baffle 29 is slidably connected with the first discharge bin 25, the gas content entering the first bellows pipe 28 along the heat pipe 27 can be controlled through the first flow valve, thereby controlling the deformation amount of the first bellows pipe 28, further controlling the moving distance of the first baffle 29 in the first discharge bin 25, and the volume of the first discharge bin 25 will also change accordingly. The same particle size of semi-coke is placed in the first discharge bin 25, when the first discharge bin 25 is filled, the second electromagnetic valve is opened to pour it into the reaction kettle 5 for subsequent reaction.

[0036] The other end of the top cover 8 is provided with a second discharge bin 26 through a third electromagnetic valve, the other side of the heat pipe 27 is provided with a second bellows pipe 30 through a second flow valve, the other end of the second bellows pipe 30 is provided with a second baffle 31, the second baffle 31 is slidably connected with the second discharge bin 26, and the same as the first discharge bin 25, the amount of gas entering the second bellows pipe 30 can be effectively controlled by controlling the opening degree of the second flow valve, thereby controlling the deformation amount of the second bellows pipe 30, further controlling the moving distance of the second baffle 31 in the second discharge bin 26, and the volume of the second discharge bin 26 will also change. Among them, the volumes of the first discharge bin 25 and the second discharge bin 26 are mainly compared, thereby controlling the content ratio of the semi-coke of the same particle size in the first discharge bin 25 and the semi-coke of different particle sizes in the second discharge bin 26, and further improving the effect of sulfur dioxide reaction.

[0037] Among them, displacement sensors are arranged in the first discharge bin 25 and the second discharge bin 26, the heights of the first discharge bin 25 and the second discharge bin 26 are the same, the greater the transverse displacement ratio of the first baffle 29 and the second baffle 31 in the first discharge bin 25 and the second discharge bin 26, the smaller the volume of the first discharge bin 25 and the second discharge bin 26, so the displacement amount of the first baffle 29 and the second baffle 31 can be detected through the displacement sensor, and the height values of the first discharge bin 25 and the second discharge bin 26 are the same, thereby quickly and efficiently calculating the content of the semi-coke in the first discharge bin 25 and the second discharge bin 26, and controlling the appropriate proportion of adding, thereby improving the subsequent reaction effect.

[0038] In use, first, the impurities in the reaction kettle 5 need to be cleaned, at this time the driving motor 23 is started, the driving motor 23 drives the fan blade to rotate, the fan blade rotates to exhaust the inside of the discharge bin 22 and the reaction kettle 5, so that the impurities and gas in the reaction kettle 5 enter the inside of the discharge bin 22 along the slag outlet pipe 6, at the same time, the rotation of the driving motor 23 drives the threaded transmission rod to rotate, the rotation of the threaded transmission rod transmits and feeds the impurities in the discharge bin 22 to make them quickly fall into the cooling water tank 24.

[0039] When the fan blade rotates to pump the reaction kettle 5, the outside air will enter the treatment bin 13 along the exhaust pipe 14, and the outside air can impact the reaction in the activated carbon plate 18, so that the impurities clamped in the activated carbon plate 18 are removed, thereby ensuring to improve the durability of the activated carbon plate 18.

[0040] At the same time, the outside air enters the exhaust pipe 9 along the treatment bin 13, the first electromagnetic valve is opened, and the gas enters the heat conducting pipe 27 inside along the exhaust pipe 9. At this time, the gas circulates along the heat conducting pipe 27 and then reaches the exhaust pipe 9 and enters the reaction kettle 5. In order to control the amount of semi-coke added to the reaction kettle 5, the amount of semi-coke with different particle sizes is different, so that the first flow valve in the first bellows pipe 28 is opened, and the second flow valve in the second bellows pipe 30 is opened. At the same time, the opening degree of the first flow valve and the second flow valve is controlled to be different, and due to the pumping effect of the fan blade, the moving distance of the first bellows pipe 28 and the second bellows pipe 30 is different, so that the moving distance of the first baffle 29 in the first discharge bin 25 is different from the moving distance of the second baffle 31 in the second discharge bin 26, and both of them cause the volume of the first discharge bin 25 and the second discharge bin 26 to decrease, and the displacement sensor detects different displacement values. The distance value detected in the first discharge bin 25 is the distance value between the first baffle 29 and the inner wall of the first discharge bin 25, and the distance value detected in the second discharge bin 26 is the distance value between the second baffle 31 and the inner wall of the second discharge bin 26. Since the height of the first discharge bin 25 and the second discharge bin 26 is the same, the volume ratio of the first discharge bin 25 and the second discharge bin 26 is related to the displacement amount of the first baffle 29 and the second baffle 31. The greater the moving distance of the first baffle 29, the smaller the distance between the first baffle 29 and the inner wall of the first discharge bin 25, and the smaller the volume of the first discharge bin 25, and the smaller the proportion of the particle size content of the semi-coke in the first discharge bin 25.

[0041] Therefore, by controlling the size of the first flow valve and the second flow valve, the volume of the first discharge bin 25 and the second discharge bin 26 can be effectively controlled, and the content of the semi-coke with different particle sizes can be further controlled to meet the required proportion requirement, thereby improving the effect of subsequent reaction.

[0042] When the semi-coke raw materials with different particle sizes are added to the corresponding first discharge bin 25 and second discharge bin 26 and filled, the driving motor 23 stops working, the second electromagnetic valve and the third electromagnetic valve are opened, and the semi-coke raw materials in the first discharge bin 25 and the second discharge bin 26 are directly discharged into the reaction kettle 5 for subsequent reaction.

[0043] Therefore, when more groups of particle size semi-coke need to be put in, the number of the feeding bins can be increased according to the above method, and the corresponding number of the feeding bins can be increased by connecting the bellows and the baffle through the flow valve inside the corresponding feeding bin, thereby realizing the one-time proportional feeding of more different particle size semi-coke raw materials, and further improving the adaptability of the device.

[0044] After the feeding is completed, liquid sulfur is added into the reaction kettle 5 along the sulfur adding pipe 7 to react with the semi-coke in the reaction kettle 5. During the reaction process, the generated sulfur gas enters the gas outlet pipe 9 from the reaction kettle 5. At this time, the first electromagnetic valve is closed, and the sulfur gas in the gas outlet pipe 9 reaches the inside of the liquid storage box 10. The liquid in the liquid storage box 10 is heated by the heat conduction of the high-temperature gas outlet pipe 9, and the high-temperature liquid in the liquid storage box 10 enters the treatment bin 13 along the hose 12 at this time. The gas in the gas outlet pipe 9 enters the treatment bin 13, and the entering liquid cools, removes and neutralizes the sulfur gas. At the same time, the treated sulfur gas rises to the activated carbon plate 18 along the treatment bin 13, and is further removed and treated by the adsorption of the activated carbon plate 18, and is then discharged through the gas hole 20 at the top and collected by the sulfur gas recovery box.

[0045] The activated carbon plate 18 is easily clogged and deactivated after long-term use, and hinders the discharge of the subsequent product. When the amount of sulfur gas discharged through the gas hole 20 decreases, the first electromagnetic valve is opened, the high-temperature sulfur gas in the gas outlet pipe 9 enters the heat conduction pipe 27, and the first flow valve and the second flow valve are both closed. The high-temperature sulfur gas in the heat conduction pipe 27 reaches the treatment bin 13, and the heat conduction effect of the high-temperature gas can transfer the heat of the heat conduction pipe 27 to the activated carbon plate 18 in the treatment bin 13, so that the activated carbon plate 18 is revived in the high-temperature environment and regains the filtering performance. The high-temperature sulfur gas in the heat conduction pipe 27 continues to move to the rear end along the heat conduction pipe 27 and returns to the gas outlet pipe 9 to continue the subsequent removal effect. Through the flow direction control of the high-temperature sulfur gas in the gas outlet pipe 9, the deactivated activated carbon plate 18 can be effectively revived, further improving the durability of the device, and without affecting the subsequent reaction and collection.

[0046] When the reaction is completed, the sulfur gas collection box is removed, and only the switch of the slag outlet pipe 6 is opened. The driving motor 23 is started to drive the threaded transmission rod and the fan blade to rotate. The impurities and gas in the reaction kettle 5 are sucked into the discharge bin 22 by the fan blade, and are cooled and recovered in the cooling tank 24 by the threaded transmission rod. The impurity gas reaches the recovery gas bag through the gas hole for recovery treatment.

[0047] When the impurities in the reaction kettle 5 are recovered, and subsequent reaction is needed, only the above operation needs to be repeated, the opening size of the first flow valve and the second flow valve is controlled, and then the volume of the first discharging bin 25 and the second discharging bin 26 is adjusted, so that the subsequent feeding and reaction process is completed.

[0048] The device can effectively control the addition amount of semi-coke with different particle sizes, thereby meeting the actual demand, improving the adaptability, and recycling the impurities in the reaction kettle 5 when adjusting the addition amount of semi-coke, improving the multi-functionality of the device, saving time, improving the reaction efficiency, and in the case that the activated carbon plate 18 is deactivated due to long-time work, the deactivated activated carbon plate 18 is high-temperature revived by the high-temperature sulfur gas as the reaction product, so that the activated carbon plate 18 regains the required filtering effect, improving the durability of the device, reducing the reaction consumption, and ensuring the reaction effect.

[0049] The basic principle, main features and advantages of the present application are shown and described above. It should be understood by those skilled in the art that the present application is not limited by the above examples, and the above examples and descriptions in the specification are only the principles of the present application. Without departing from the spirit and scope of the present application, various changes and improvements can be made to the present application, and these changes and improvements all fall within the scope of the claimed present application. The scope of protection required by the present application is defined by the appended claims and their equivalents.

Claims

1. A continuous internal heat type semi-carbon method carbon disulfide reaction furnace without harmful gas emission, comprising a shell, characterized in that, The inner cavity of the shell is provided with a reaction kettle, the outer surface wall of the reaction kettle is communicated with a vulcanization pipe penetrating through the side wall of the shell, the bottom of the reaction kettle is communicated with a slag discharge pipe, the directly below of the slag discharge pipe is provided with a discharge bin, the top side of the discharge bin is communicated with the anti-leakage outer frame between the discharge bin and the slag discharge pipe, the other side of the discharge bin is provided with a driving motor, one end of the driving motor is provided with a threaded transmission rod penetrating through the side wall of the inner cavity of the discharge bin, and the end of the threaded transmission rod away from the slag discharge pipe is provided with a fan blade. The top of the reaction kettle is provided with a top cover, the top of the reaction kettle is communicated with a gas outlet pipe penetrating through the top cover, the other end of the gas outlet pipe is communicated with a liquid storage box, the other end of the liquid storage box is communicated with a treatment bin, the top of the treatment bin is communicated with an exhaust pipe, and a plurality of detachably connected activated carbon plates are arranged in the inner cavity of the exhaust pipe and along the vertical direction of the exhaust pipe. One side of the top cover is provided with a first discharge bin through a second electromagnetic valve, the side wall of the heat conduction pipe is provided with a first bellows through a first flow valve, the other end of the first bellows is provided with a first baffle, the first baffle is in sliding connection with the first discharge bin, the other end of the top cover is provided with a second discharge bin through a third electromagnetic valve, the other side wall of the heat conduction pipe is provided with a second bellows through a second flow valve, the other end of the second bellows is provided with a second baffle, and the second baffle is in sliding connection with the second discharge bin. A plurality of electric furnace wire heating blocks are arranged between the inner side wall of the shell and the reaction kettle, and the lower surface of the shell is provided with a connecting plate. The liquid storage box is communicated with a hose on both sides, and the end of the hose away from the liquid storage box is communicated with an atomizing head penetrating through the side wall of the treatment bin. The first discharge bin and the second discharge bin are both provided with displacement sensors, the heights of the first discharge bin and the second discharge bin are the same, the greater the transverse displacement ratio of the first baffle in the first discharge bin is, the larger the volume of the first discharge bin is.

2. The endothermic continuous semi-coking process carbon disulfide reaction furnace according to claim 1, wherein, The two sides of the activated carbon plate are both provided with limit blocks in sliding connection with limit grooves arranged in the inner cavity of the exhaust pipe.

3. The endothermic continuous semi-coking process carbon disulfide reaction furnace according to claim 1, characterized in that, The upper surface of the connecting ring is provided with a dustproof sheet.

4. The endothermic continuous semi-coking process carbon disulfide reaction furnace according to claim 1, characterized in that, The input end of the heat conduction pipe is located at the front end of the gas outlet pipe, and the output end of the heat conduction pipe is located at the tail end of the gas outlet pipe.

5. The endothermic continuous semi-coking process carbon disulfide reaction furnace according to claim 1, characterized in that, The side away from the fan blade of the discharge bin is provided with an air outlet, and the other end of the air outlet is communicated with a recovery gas bag.

6. The endothermic continuous semi-coking process carbon disulfide reaction furnace according to claim 1, wherein The outer wall of one side of the liquid storage box is communicated with an adding pipe, the top of the activated carbon plate is provided with a plurality of gas permeable holes arranged in a circumferential array, and the top of the gas permeable hole is communicated with a sulfur dichloride gas recovery box.

7. The said inner heated continuous semi-carbon process carbon disulfide reaction furnace without harmful gas emission according to claim 1, characterized in that, The bottom side of the discharge bin is communicated with a cooling water tank.

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