Preparation method of high-adhesion carbon paper for fuel cell and application thereof

CN117661374BActive Publication Date: 2026-08-28湖南隆深氢能科技有限公司
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Patent Information

Application Number
CN202311814188.9
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-12-27
Publication Date
2026-08-28
Estimated Expiration
2043-12-27

AI Technical Summary

Technical Problem

[0005]基于此,为了解决现有的燃料电池用高粘结碳纸存在的密度高导致的导热性差和导电性差的问题,本发明提供了一种燃料电池用高粘结碳纸的制备方法及其应用,具体技术方案如下:

Benefits of technology

[0030]上述技术方案提供的制备方法由于同时采用了聚氨酯和碳纳米管对碳纤维进行改性、聚乙炔对碳纤维原纸进行改性和乙烯基三氯硅烷对酚醛树脂进行改性,其制备得到的燃料电池用高粘结碳纸在高密度的情况下,导热性能和导电性能优异;具体地,碳纤维经过聚氨酯和碳纳米管的改性,得到的改性碳纤维的导电性能和粘性显著增强,从而使得制备的碳纤维原纸的导电性能和粘性显著增强;将碳纤维原纸进行苯乙炔改性能进一步形成高密度高导电网络,同时扩展导热面,从而提升导热性能;将得到的碳纤维纸浸渍于乙烯基三氯硅烷改性的酚醛树脂可以提高密度粘性的同时保证导电性能,从而使得最终得到的燃料电池用高粘结碳纸在高密度的情况下,导热性能和导电性能优异。

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Abstract

The application discloses a preparation method of high-adhesion carbon paper for fuel cells and relates to the technical field of fuel cells.The method comprises the following steps: performing cleaning treatment on carbon fibers to obtain carbon fiber precursors; performing modification treatment on the carbon fiber precursors to obtain modified carbon fibers; performing wet forming treatment on the modified carbon fibers to obtain carbon fiber base paper; placing the carbon fiber base paper in phenylacetylene to obtain carbon fiber paper precursors; performing heat preservation on the carbon fiber paper precursors to obtain carbon fiber paper; performing impregnation on the carbon fiber paper, and then performing solidification treatment and carbonization treatment to obtain the high-adhesion carbon paper for fuel cells.The preparation method simultaneously adopts polyurethane and carbon nanotubes to modify the carbon fibers, polyacetylene to modify the carbon fiber base paper and vinyltrichlorosilane to modify phenolic resin, and the high-adhesion carbon paper for fuel cells prepared by the method has high density and excellent heat conduction performance and electric conduction performance.
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Citation Information

Patent Citations

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    CN115233498A

  • Preparation method of polyphenylacetylene triggered by tri-(trimethylsilyl) silicane

    CN106749813A

  • Gas diffusion layer and preparation method

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  • Gradient carbon paper and preparation method thereof

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