Dimethylamine gas catalytic luminescence sensing material, sensor, preparation and application

By preparing metastable tetragonal phase zirconium dioxide particles as catalytic luminescent sensing materials, the problems of low sensitivity and poor anti-interference ability in detecting amine gases are solved, and high sensitivity and selective detection of dimethylamine gases are achieved.

CN119306252BActive Publication Date: 2025-03-07CRINM (GUANGDONG) INST FOR ADVANCED MATERIALS & TECH
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Patent Information

Application Number
CN202411860814.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-12-17
Publication Date
2025-03-07
Estimated Expiration
2044-12-17

AI Technical Summary

Technical Problem

The prior art has problems such as low sensitivity, high background interference, and susceptible to environmental temperature when detecting amine gases, making it difficult to effectively monitor dimethylamine gases.

Method used

Metastable tetragonal phase zirconium dioxide is used as a catalytic luminescence sensing material. Specific preparation methods include dissolving zirconium chlorine hydrate, adding chelating agents and polyhydroxy alcohols, heating and calcining in three stages, and zirconium dioxide particles with small particle size, large specific surface area and stable existence are prepared for building a catalytic luminescence sensor.

Benefits of technology

It realizes detection of high sensitivity, good selectivity and strong anti-interference ability of dimethylamine gas, and has the advantages of fast response speed, high accuracy and long service life.

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Abstract

The invention discloses a dimethylamine gas catalytic luminescence sensing material, a sensor, and preparation and application thereof, and belongs to the field of gas catalytic luminescence sensors. The material preparation steps include dissolving zirconium oxychloride hydrate in water, adding a chelating agent and a polyhydroxy alcohol, evaporating after dissolution, calcining at a specific temperature, and then cooling naturally. The invention can quickly prepare a metastable tetragonal zirconium dioxide sensing material, with a particle size of about 10 nm, a relatively uniform particle size distribution, no agglomeration, a large specific surface area, and the ability to exist stably at room temperature, and has the potential to quickly detect dimethylamine gas. The catalytic luminescence sensor has high sensitivity, good cycle performance, and exhibits good consistency when continuously and repeatedly detecting amine VOCs. It can highly selectively determine dimethylamine gas without being interfered by other gases, has good reproducibility and stability, and can be used for long-term monitoring of dimethylamine gas, with fast response speed, high accuracy, and long service life.
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Citation Information

Patent Citations

  • Method for synthesizing cerium-doped stable tetragonal-phase zirconia nanopowder by sol-gel method

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