A coating for improving the efficiency of photovoltaic panels

By crosslinking modified nano-ZnO/TiO2/SiO2 composite powder with modified polyaniline and fluorosilane-modified hydrogen-containing silicone oil to form a thermally conductive network, the problem of poor self-cleaning effect of photovoltaic panel coating is solved, and the power generation efficiency of photovoltaic panels is improved.

CN119331512BActive Publication Date: 2026-08-25JIANGSU AOJINGJIA ENVIRONMENTAL PROTECTION TECH CO LTD
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Patent Information

Application Number
CN202411432357.7
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-10-14
Publication Date
2026-08-25
Estimated Expiration
2044-10-14

AI Technical Summary

Technical Problem

The poor photocatalytic properties of nano-TiO2 in existing photovoltaic panel coatings result in poor self-cleaning effects, which affects power generation efficiency.

Method used

Modified nano-ZnO/TiO2/SiO2 composite powder is crosslinked with modified polyaniline and fluorosilane-modified hydrogen-containing silicone oil to form a thermally conductive network, thereby enhancing the photocatalytic performance and adhesion of the coating.

Benefits of technology

It significantly improves the photocatalytic and thermal conductivity of photovoltaic panels, and enhances the self-cleaning effect and power generation efficiency of the coating.

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Abstract

The application discloses a coating for improving the power generation efficiency of a photovoltaic panel and belongs to the technical field of the coating of the photovoltaic panel. The coating for improving the power generation efficiency of the photovoltaic panel prepared by the application comprises the following raw materials in parts by weight: modified nano ZnO / TiO2 / SiO2 composite powder 30-50 parts, modified polyaniline 10-30 parts, fluorosilane modified hydrogen-containing silicone oil 80-100 parts and chloroplatinic acid 1-5 parts. The application prepares the nano ZnO / TiO2 / SiO2 composite powder, combines the nano ZnO with the nano TiO2, improves the insufficient photocatalytic performance of the nano TiO2, utilizes the good heat conduction performance of the nano zinc oxide, improves the heat conduction performance of the prepared coating for improving the power generation efficiency of the photovoltaic panel, and further forms a heat conduction network through the grafting of the silicone on the polyaniline, so that the heat conduction performance and the self-cleaning performance of the prepared coating for improving the power generation efficiency of the photovoltaic panel are greatly improved.
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Description

Technical Field

[0001] This invention belongs to the field of photovoltaic panel coating technology, and specifically relates to a coating that improves the power generation efficiency of photovoltaic panels. Background Technology

[0002] The photoelectric efficiency of solar photovoltaic panels is very low in actual operation, usually less than 20%. At present, the main research on how to improve their output efficiency is to optimize the installation method, optimize the supporting hardware facilities, develop new panel materials and improve the self-cleaning of panel coatings.

[0003] For solar photovoltaic (PV) panels, the absorption of light with wavelengths between 350nm and 1200nm is particularly important. Maintaining high light transmittance and minimizing reflection is crucial. One solution is surface roughening, but this method also leads to the adhesion of dust and organic impurities. Existing methods such as manual cleaning, robotic cleaning, and high-pressure water cleaning can quickly damage the light-transmitting coating on the surface of solar PV panels. To address these issues, applying a dust-proof and self-cleaning coating to the surface of PV panels has become the preferred method for preventing contamination.

[0004] Patent CN114231177A discloses a self-cleaning coating for solar photovoltaic panels and its preparation method. This photovoltaic panel coating is prepared by preparing nano-TiO2 / SiO2, grafting it with siloxane, and then cross-linking and curing it with fluorosilane-modified hydrogen-containing silicone oil to obtain a self-cleaning coating that achieves good hydrophobic and oleophobic properties and self-cleaning function. However, the nano-TiO2 in the prepared nano-TiO2 / SiO2 has very weak photocatalytic properties, resulting in poor self-cleaning effect of the coating. Summary of the Invention

[0005] The purpose of this invention is to provide a coating that improves the power generation efficiency of photovoltaic panels, thereby solving the problem in the background art where the poor photocatalytic properties of nano-TiO2 in the actual use of photovoltaic panels lead to poor self-cleaning effect of the coating, which in turn affects the power generation efficiency of the photovoltaic panels.

[0006] The objective of this invention can be achieved through the following technical solutions:

[0007] A coating for improving the power generation efficiency of photovoltaic panels comprises the following raw materials in parts by weight:

[0008] 30-50 parts of modified nano ZnO / TiO2 / SiO2 composite powder, 10-30 parts of modified polyaniline, 80-100 parts of fluorosilane-modified hydrogen-containing silicone oil, and 1-5 parts of chloroplatinic acid.

[0009] The modified nano-ZnO / TiO2 / SiO2 composite powder includes the following preparation steps:

[0010] Step (1): Tetraethyl orthosilicate and isopropyl titanate were added to an ethanol aqueous solution, stirred, and the pH value was adjusted to 3. After stirring, the mixture was allowed to stand and age to obtain a silica-titanium dioxide composite sol. The obtained composite sol was dried, then calcined, and ground to obtain nano-TiO2 / SiO2 composite powder.

[0011] Step (2): Add nano TiO2 / SiO2 composite powder and zinc nitrate hexahydrate to deionized water, stir, add NaOH aqueous solution dropwise, continue stirring, sonicate and place in a sealed container for hydrothermal reaction, cool to room temperature, centrifuge, wash and dry to obtain nano ZnO / TiO2 / SiO2 composite powder;

[0012] Step (3): Disperse the nano ZnO / TiO2 / SiO2 composite powder in an ethanol aqueous solution, then add vinyltrimethoxysilane, stir, filter, and dry to obtain modified nano ZnO / TiO2 / SiO2 composite powder.

[0013] Further, the ratio of tetraethyl orthosilicate, isopropyl titanate, and aqueous ethanol solution used in step (1) is 10g:0.5g:50mL.

[0014] Further, the volume fraction of the ethanol aqueous solution in step (1) is 80-85%.

[0015] Furthermore, the aging time in step (1) is 8-10 hours.

[0016] Furthermore, the calcination conditions described in step (1) are calcination at 530°C for 2-4 hours.

[0017] Further, in step (2), the ratio of the amount of nano-TiO2 / SiO2 composite powder, zinc nitrate hexahydrate, deionized water and sodium hydroxide aqueous solution is 1.5g:0.75g:30mL:25mL.

[0018] Furthermore, the concentration of the sodium hydroxide aqueous solution in step (2) is 0.1 mol / L.

[0019] Furthermore, the hydrothermal reaction in step (2) is carried out at 100°C for 12 hours.

[0020] Further, in step (3), the ratio of the nano ZnO / TiO2 / SiO2 composite powder, the ethanol aqueous solution, and the vinyltrimethoxysilane is 10g:50mL:0.3g.

[0021] Furthermore, the volume fraction of the ethanol aqueous solution in step (3) is 70%.

[0022] Furthermore, the modified polyaniline includes the following preparation steps:

[0023] KH-570 was added to an aqueous ethanol solution to obtain a silane treatment solution. Polyaniline powder was then immersed in the silane treatment solution, sealed, and stirred periodically. After settling, the powder was washed, centrifuged, and the supernatant was poured off to obtain modified polyaniline.

[0024] Furthermore, the ratio of KH-570 to the aqueous ethanol solution is 2g:100mL.

[0025] Furthermore, the volume fraction of the ethanol-water solution is 75%.

[0026] Furthermore, the ratio of the polyaniline powder to the silane treatment solution is 20g:100mL.

[0027] Furthermore, the soaking is performed at room temperature for 3 hours.

[0028] Furthermore, the timed stirring is performed once every 30 minutes.

[0029] Furthermore, the washing process involves using an ultrasonic cleaner for 30 minutes.

[0030] Furthermore, the fluorosilane-modified hydrogen-containing silicone oil includes the following preparation steps:

[0031] Hydroxysilicone oil, dimethoxymethylsilane, and heptadecafluorodecyltriethoxysilane were added to a reactor, and then tetramethylammonium hydroxide was added. The mixture was stirred at 85-90℃ for 6 hours and then kept at 130-140℃ for 2 hours to obtain fluorosilane-modified hydrogen-containing silicone oil.

[0032] Furthermore, the mass ratio of the hydroxyl silicone oil, dimethoxymethylsilane, heptadecafluorodecyltriethoxysilane, and tetramethylammonium hydroxide is 100g:15g:6g:0.035g.

[0033] Furthermore, the viscosity of the hydroxyl silicone oil is 50-2000 cSt at 25°C.

[0034] Furthermore, the coating for improving the power generation efficiency of the photovoltaic panel includes the following preparation steps:

[0035] Modified nano-ZnO / TiO2 / SiO2 composite powder, modified polyaniline, fluorosilane-modified hydrogen-containing silicone oil, and chloroplatinic acid are mixed and then coated onto the surface of a solar photovoltaic panel. After cross-linking and curing, a coating that improves the power generation efficiency of the photovoltaic panel is obtained.

[0036] Furthermore, the mass ratio of the modified nano-ZnO / TiO2 / SiO2 composite powder, modified polyaniline, fluorosilane-modified hydrogen-containing silicone oil, and chloroplatinic acid is 30-50:10-30:80-100:1-5.

[0037] Furthermore, the cross-linking curing temperature is 45-80℃, and the cross-linking curing time is 12h.

[0038] The beneficial effects of this invention are:

[0039] 1. This invention prepares nano-ZnO / TiO2 / SiO2 composite powder. Combining nano-ZnO with nano-TiO2 can reduce the recombination of photogenerated electrons and holes in nano-TiO2, increase light utilization, greatly improve photocatalytic performance, effectively remove pollutants with different characteristics, and is suitable for different application environments.

[0040] 2. The nano-ZnO in the nano-ZnO / TiO2 / SiO2 composite powder prepared by this invention has good thermal conductivity. When the nano-ZnO / TiO2 / SiO2 composite powder undergoes surface cross-linking activity modification, the nano-ZnO will be uniformly dispersed in the middle of the coating, thereby improving the thermal conductivity of the coating. In addition, the presence of modified polyaniline can further improve the thermal conductivity of the coating. The two form a thermally conductive network in the coating, enabling the photovoltaic panel to achieve rapid cooling, thereby improving the power generation efficiency of the photovoltaic panel.

[0041] 3. This invention modifies the surface of nano-ZnO / TiO2 / SiO2 composite powder by preparing modified nano-ZnO / TiO2 / SiO2 composite powder, and then highly crosslinks it with fluorosilane-modified hydrogen-containing silicone oil to form a rigid fluorosilane-modified hydrogen-containing silicone oil network structure, which significantly enhances its adhesion to the surface of solar photovoltaic panels and significantly enhances the coating strength. Detailed Implementation

[0042] The technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. Obviously, the described embodiments are only some embodiments of the present invention, and not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative effort are within the scope of protection of the present invention.

[0043] Example 1

[0044] This embodiment provides a nano-ZnO / TiO2 / SiO2 composite powder, and the specific synthesis steps are as follows:

[0045] Step (1): Add 10g of tetraethyl orthosilicate and 0.5g of isopropyl titanate to 50mL of 80% ethanol aqueous solution, stir, adjust the pH to 3, continue stirring for 2h, and then let stand for 8h to obtain silica-titanium dioxide composite sol; dry the obtained composite sol under vacuum at 120℃ for 12h, then calcine at 530℃ for 2h, and grind until it can pass through a 600-mesh sieve to obtain nano TiO2 / SiO2 composite powder.

[0046] Step (2): Add 1.5g of nano TiO2 / SiO2 composite powder and 0.75g of zinc nitrate hexahydrate to 30mL of deionized water, stir for 15min, add 25mL of 0.1mol / L NaOH aqueous solution, continue stirring for 60min, sonicate for 10min, place in a sealed container, hydrothermally react at 100℃ for 12h, cool to room temperature, centrifuge at 8000r / min, wash with deionized water and ethanol in sequence, and dry in a 60℃ forced-air drying oven for 12h to obtain nano ZnO / TiO2 / SiO2 composite powder.

[0047] Step (3): Disperse 10g of nano ZnO / TiO2 / SiO2 composite powder in 50mL of 70% ethanol aqueous solution, then add 0.3g of vinyltrimethoxysilane, stir for 30min, filter, and dry in a vacuum drying oven at 60℃ for 12h to obtain modified nano ZnO / TiO2 / SiO2 composite powder.

[0048] Example 2

[0049] This embodiment provides a nano-ZnO / TiO2 / SiO2 composite powder, and the specific synthesis steps are as follows:

[0050] Step (1): Add 20g of tetraethyl orthosilicate and 1g of isopropyl titanate to 100mL of 85% ethanol aqueous solution, stir, adjust the pH to 3, continue stirring and react for 2h, and then let stand and age for 10h to obtain silica-titanium dioxide composite sol; dry the obtained composite sol under vacuum at 120℃ for 12h, then calcine at 530℃ for 4h, and grind until it can pass through a 600-mesh sieve to obtain nano TiO2 / SiO2 composite powder.

[0051] Step (2): Add 3g of nano TiO2 / SiO2 composite powder and 1.5g of zinc nitrate hexahydrate to 60mL of deionized water, stir for 15min, add 50mL of 0.1mol / L NaOH aqueous solution, continue stirring for 60min, sonicate for 10min, place in a sealed container, hydrothermally react at 100℃ for 12h, cool to room temperature, centrifuge at 8000r / min, wash with deionized water and ethanol in sequence, and dry in a 60℃ forced-air drying oven for 12h to obtain nano ZnO / TiO2 / SiO2 composite powder.

[0052] Step (3): Disperse 20g of nano ZnO / TiO2 / SiO2 composite powder in 100mL of 70% ethanol aqueous solution, then add 0.6g of vinyltrimethoxysilane, stir for 30min, filter, and dry in a vacuum drying oven at 60℃ for 12h to obtain modified nano ZnO / TiO2 / SiO2 composite powder.

[0053] Comparative Example 1

[0054] This example provides a modified nano-TiO2 / SiO2 composite powder, and the specific synthesis steps are as follows:

[0055] Compared with Example 1, based on Example 1, the 10g nano ZnO / TiO2 / SiO2 composite powder in step (3) of Example 1 is replaced with the 10g nano TiO2 / SiO2 composite powder in step (1) of Example 1, and the other raw materials and preparation steps are the same as in Example 1.

[0056] Example 3

[0057] This embodiment provides a modified polyaniline, and the specific synthesis steps are as follows:

[0058] Add 2g of KH-570 to 100mL of 75% ethanol to obtain a silane treatment solution. Immerse 20g of polyaniline powder in 100mL of the silane treatment solution, seal and soak for 3 hours, stirring every 30 minutes during this period. After settling, wash with an ultrasonic cleaner for 30 minutes and centrifuge at 4000rpm / min for 25 minutes. Pour off the supernatant to obtain modified polyaniline.

[0059] Example 4

[0060] This embodiment provides a modified polyaniline, and the specific synthesis steps are as follows:

[0061] Add 4g of KH-570 to 200mL of 75% ethanol to obtain a silane treatment solution. Immerse 40g of polyaniline powder in 200mL of the silane treatment solution, seal and soak for 3 hours, stirring every 30 minutes during this period. After settling, wash with an ultrasonic cleaner for 30 minutes and centrifuge at 4000rpm / min for 25 minutes. Pour off the supernatant to obtain modified polyaniline.

[0062] Example 5

[0063] This embodiment provides a coating to improve the power generation efficiency of photovoltaic panels. The specific synthesis steps are as follows:

[0064] 100g of hydroxyl silicone oil (Dow Corning (DOW) linear silicone oil PMX-0156, viscosity 50cSt), 15g of dimethoxymethylsilane and 6g of heptadecafluorodecyltriethoxysilane were added to a reactor, heated to 85℃, and then 0.035g of tetramethylammonium hydroxide was added and stirred for 4h. The temperature was then raised to 130℃ and maintained for 2h to obtain fluorosilane-modified hydrogen-containing silicone oil.

[0065] 30g of the modified nano-ZnO / TiO2 / SiO2 composite powder prepared in Example 1, 10g of the modified polyaniline prepared in Example 3, 80g of the obtained fluorosilane-modified hydrogen-containing silicone oil, and 1g of chloroplatinic acid were mixed evenly and then coated onto the surface of a solar photovoltaic panel. The mixture was then crosslinked and cured at 45°C for 12 hours to obtain a coating that improves the power generation efficiency of the photovoltaic panel.

[0066] Example 6

[0067] This embodiment provides a coating to improve the power generation efficiency of photovoltaic panels. The specific synthesis steps are as follows:

[0068] 200g of hydroxyl silicone oil (Dow Corning (DOW) linear silicone oil PMX-0156, viscosity 1000cSt), 30g of dimethoxymethylsilane and 12g of heptadecafluorodecyltriethoxysilane were added to a reactor, heated to 87℃, and then 0.07g of tetramethylammonium hydroxide was added and stirred for 4h. The temperature was then raised to 135℃ and maintained for 2h to obtain fluorosilane-modified hydrogen-containing silicone oil.

[0069] 40g of the modified nano-ZnO / TiO2 / SiO2 composite powder prepared in Example 2, 20g of the modified polyaniline prepared in Example 4, 90g of the obtained fluorosilane-modified hydrogen-containing silicone oil, and 3g of chloroplatinic acid were mixed evenly and then coated onto the surface of a solar photovoltaic panel. The mixture was then crosslinked and cured at 60°C for 12 hours to obtain a coating that improves the power generation efficiency of the photovoltaic panel.

[0070] Example 7

[0071] This embodiment provides a coating to improve the power generation efficiency of photovoltaic panels. The specific synthesis steps are as follows:

[0072] 300g of hydroxyl silicone oil (Dow Corning (DOW) linear silicone oil PMX-0156, viscosity 2000cSt), 45g of dimethoxymethylsilane and 18g of heptadecafluorodecyltriethoxysilane were added to a reactor, heated to 90℃, and then 0.105g of tetramethylammonium hydroxide was added and stirred for 4h. The temperature was then raised to 140℃ and maintained for 2h to obtain fluorosilane-modified hydrogen-containing silicone oil.

[0073] 50g of the modified nano-ZnO / TiO2 / SiO2 composite powder prepared in Example 1, 30g of the modified polyaniline prepared in Example 3, 100g of the obtained fluorosilane-modified hydrogen-containing silicone oil, and 5g of chloroplatinic acid were mixed evenly and then coated onto the surface of a solar photovoltaic panel. The mixture was then crosslinked and cured at 80°C for 12 hours to obtain a coating that improves the power generation efficiency of the photovoltaic panel.

[0074] Comparative Example 2

[0075] This embodiment provides a coating to improve the power generation efficiency of photovoltaic panels. The specific synthesis steps are as follows:

[0076] Compared with Example 5, the modified nano-ZnO / TiO2 / SiO2 composite powder prepared in Example 1 was replaced with the modified nano-TiO2 / SiO2 composite powder prepared in Comparative Example 1, while the other raw materials and preparation steps were the same as in Example 5.

[0077] Comparative Example 3

[0078] This embodiment provides a coating to improve the power generation efficiency of photovoltaic panels. The specific synthesis steps are as follows:

[0079] Compared with Example 5, based on Example 5, 10g of the modified polyaniline prepared in Example 3 was replaced with 10g of polyaniline, and the remaining raw materials and preparation steps were the same as in Example 5.

[0080] Comparative Example 4

[0081] This embodiment provides a coating to improve the power generation efficiency of photovoltaic panels. The specific synthesis steps are as follows:

[0082] Compared with Example 5, based on Example 5, 10g of the nano ZnO / TiO2 / SiO2 composite powder prepared in Example 1 was replaced with 10g of the nano TiO2 / SiO2 composite powder prepared in Comparative Example 1; 10g of the modified polyaniline prepared in Example 3 was replaced with 10g of polyaniline, and the remaining raw materials and preparation steps were the same as in Example 5.

[0083] The photocatalytic performance and thermal conductivity of the coatings for improving photovoltaic power generation efficiency obtained in Examples 5-7 and Comparative Examples 2-4 were tested.

[0084] The photocatalytic performance was tested by adding a 0.10% methyl orange aqueous solution to three different areas on the surface of the self-cleaning coating. The solution was then irradiated with a visible light source for 12 hours for photodegradation. The test droplets were then diluted and detected by a UV-Vis spectrophotometer. The photocatalytic degradation rate of methyl orange was calculated and the average value was taken.

[0085] The thermal conductivity of the coating was tested using a DRL-Ⅲ thermal conductivity meter manufactured by Xiangtan Xiangyi Instrument Co., Ltd., via the steady-state heat flow method. The results are shown in Table 1.

[0086] Table 1

[0087] Degradation rate (%) 90.5 90.6 90.8 85.3 90.5 85.1 Thermal conductivity (W / mK) 1.04 1.06 1.11 0.72 0.73 0.41

[0088] As can be seen from Table 1, the degradation rates of Examples 5-7 are all higher than 90.5%. Observing Comparative Examples 2-4, it can be seen that the combination of nano zinc oxide and nano titanium dioxide in the modified nano ZnO / TiO2 / SiO2 composite powder greatly improves the degradation rate of organic matter by the coating.

[0089] The thermal conductivity data from Examples 5-7 show that the cross-linked thermally conductive network formed by nano-zinc oxide and modified polyaniline in the modified nano-ZnO / TiO2 / SiO2 composite powder significantly improves the thermal conductivity of the coating. Comparative Example 2 reveals that when only modified nano-TiO2 / SiO2 composite powder is present, the lack of the thermally conductive portion of nano-ZnO results in poor thermal conductivity, leading to a decrease in the coating's thermal conductivity. Comparative Example 3 shows that adding polyaniline to improve thermal conductivity, instead of using cross-linkable modified polyaniline, also leads to a decrease in the coating's thermal conductivity. Comparative Example 4 shows that the coating prepared using the combination of modified nano-TiO2 / SiO2 composite powder and polyaniline has the worst thermal conductivity.

[0090] It should be noted that, in this document, relational terms such as "first" and "second" are used only to distinguish one entity or operation from another, and do not necessarily require or imply any such actual relationship or order between these entities or operations. Furthermore, the terms "comprising," "including," or any other variations thereof are intended to cover non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements includes not only those elements but also other elements not expressly listed, or elements inherent to such process, method, article, or apparatus.

[0091] Although embodiments of the invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made to these embodiments without departing from the principles and spirit of the invention, the scope of which is defined by the appended claims and their equivalents.

Claims

1. A coating for improving the power generation efficiency of photovoltaic panels, characterized in that, Including the following parts by weight of raw materials: 30-50 parts of modified nano ZnO / TiO2 / SiO2 composite powder, 10-30 parts of modified polyaniline, 80-100 parts of fluorosilane-modified hydrogen-containing silicone oil, and 1-5 parts of chloroplatinic acid. The modified nano-ZnO / TiO2 / SiO2 composite powder comprises the following preparation steps: The nano ZnO / TiO2 / SiO2 composite powder was dispersed in an ethanol aqueous solution, then vinyltrimethoxysilane was added, stirred, filtered, and dried to obtain the modified nano ZnO / TiO2 / SiO2 composite powder. The nano-ZnO / TiO2 / SiO2 composite powder includes the following preparation steps: Step (1): Add tetraethyl orthosilicate and isopropyl titanate to an ethanol aqueous solution, stir, adjust the pH value to 3, stir, let stand for aging, dry, then calcine, grind, and obtain nano TiO2 / SiO2 composite powder. Step (2): Add nano TiO2 / SiO2 composite powder and zinc nitrate hexahydrate to deionized water, stir, add NaOH aqueous solution dropwise, continue stirring, sonicate, place in a sealed container, hydrothermal reaction, cool, centrifuge, wash, dry, to obtain nano ZnO / TiO2 / SiO2 composite powder; The modified polyaniline includes the following preparation steps: KH-570 was added to an aqueous ethanol solution to obtain a silane treatment solution. Polyaniline powder was then immersed in the silane treatment solution, sealed, and soaked for 3 hours with periodic stirring. After settling, the powder was washed, centrifuged, and the supernatant was poured off to obtain modified polyaniline.

2. The coating for improving the power generation efficiency of photovoltaic panels according to claim 1, characterized in that, In the preparation steps of modified nano ZnO / TiO2 / SiO2 composite powder: The ratio of nano ZnO / TiO2 / SiO2 composite powder, ethanol aqueous solution and vinyltrimethoxysilane is 10g:50mL:0.3g; the volume fraction of ethanol aqueous solution is 70%.

3. The coating for improving the power generation efficiency of photovoltaic panels according to claim 1, characterized in that, In the preparation steps of nano ZnO / TiO2 / SiO2 composite powder, the ratio of tetraethyl orthosilicate, isopropyl titanate, and ethanol aqueous solution is 10g:0.5g:50mL.

4. The coating for improving the power generation efficiency of photovoltaic panels according to claim 1, characterized in that, In the preparation steps of nano-ZnO / TiO2 / SiO2 composite powder, the ratio of nano-TiO2 / SiO2 composite powder, zinc nitrate hexahydrate, deionized water and NaOH aqueous solution is 1.5g:0.75g:30mL:25mL; the hydrothermal reaction conditions are 100℃ for 12h.

5. The coating for improving the power generation efficiency of photovoltaic panels according to claim 1, characterized in that, In the preparation of modified polyaniline, the ratio of KH-570 to ethanol aqueous solution is 2g:100mL; the ratio of polyaniline powder to silane treatment solution is 20g:100mL.

6. The coating for improving the power generation efficiency of a photovoltaic panel according to claim 1, characterized in that, The preparation steps include the following: Modified nano-ZnO / TiO2 / SiO2 composite powder, modified polyaniline, fluorosilane-modified hydrogen-containing silicone oil, and chloroplatinic acid are mixed and then coated onto the surface of a solar photovoltaic panel. After cross-linking and curing, a coating that improves the power generation efficiency of the photovoltaic panel is obtained.

7. The coating for improving the power generation efficiency of a photovoltaic panel according to claim 6, characterized in that, The cross-linking curing temperature is 45-80℃, and the cross-linking curing time is 12h.

Citation Information

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