Lithium secondary battery

By using a lithium nickel-cobalt-manganese-based positive electrode active material and a silicon-based negative electrode active material with a high nickel content in lithium secondary batteries, and using a high concentration of specific lithium salts in a non-aqueous electrolyte solution, the performance deterioration of lithium secondary batteries when combining high nickel and silicon-based materials is solved, and excellent electrochemical characteristics, stability and life characteristics are achieved.

CN119812310APending Publication Date: 2025-04-11LG ENERGY SOLUTION LTD
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Patent Information

Application Number
CN202510232885.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2018-05-11
Filing Date
2019-05-10
Publication Date
2025-04-11

AI Technical Summary

Technical Problem

When the existing lithium secondary batteries combine the positive electrode active material with a high nickel content and the silicon-based negative electrode active material, there are problems such as sharp deterioration of battery performance, structural instability and negative electrode deterioration.

Method used

A high nickel content of lithium nickel cobalt manganese-based positive electrode active material and silicon-based negative electrode active material were used, and a high concentration of LiPF6 and bis(fluorosulfonyl)imide lithium were used in the non-aqueous electrolyte solution to form a stable SEI film to inhibit the dissolution of metal ions and the expansion of the negative electrode.

Benefits of technology

The excellent electrochemical characteristics, stability and life characteristics of lithium secondary batteries are achieved, while the capacity characteristics and thermal stability are improved, and the structural instability of high-nickel electrodes is reduced.

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Abstract

The present invention relates to a lithium secondary battery comprising: a positive electrode containing a lithium nickel cobalt manganese-based positive electrode active material in which the nickel content is at least 80 mol% with respect to the total amount of transition metals; a negative electrode containing a silicon-based negative electrode active material and a carbon-based negative electrode active material in a weight ratio of 1: 99 to 50: 50; a diaphragm; and a non-aqueous electrolyte solution containing a non-aqueous organic solvent and a lithium salt, in which the concentration of the lithium salt is 1.8 M to 5 M, and the lithium salt contains LiPF6 and lithium bis (fluorosulfonyl) imide.
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