Catalyst component for olefin polymerization, preparation method of catalyst component, catalyst and application of catalyst

By preparing a catalyst component containing components such as magnesium composite, auxiliary precipitation agent, titanium-containing compounds, etc., the problems of insufficient molecular weight, low distribution and poor processing performance of ultra-high molecular weight polyethylene in the prior art are solved, and polyethylene preparation with high molecular weight, low hexane extract content and excellent processing performance are achieved.

CN119899291AActive Publication Date: 2025-04-29CHINA PETROLEUM & CHEMICAL CORP +1
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Patent Information

Application Number
CN202311413496.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-10-27
Publication Date
2025-04-29
Estimated Expiration
2043-10-27

AI Technical Summary

Technical Problem

The prior art is difficult to prepare ultra-high molecular weight polyethylene with sufficient high molecular weight, narrow molecular weight distribution, low hexane extract content, large particles and small fine powder content, and its poor processing performance limits its large-scale application.

Method used

A catalyst component for olefin polymerization includes magnesium composites, co-precipitants, titanium-containing compounds, acetate compounds, organic alcohol compounds, organoaluminum compounds and electron donor compounds. By optimizing the proportions and reaction conditions of these components, a catalyst with high activity and bulk density is prepared.

Benefits of technology

The prepared catalyst can regulate the molecular weight of the polymer, increase the narrowness of the molecular weight distribution, reduce the content of hexane extract, reduce the content of large particles and fine powder, improve the spherical and low tangle properties, thereby improving the processing performance and quality of polyethylene.

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Abstract

The invention provides a catalyst component for olefin polymerization, a preparation method of the catalyst component, a catalyst and application of the catalyst component. The catalyst component is prepared by reacting raw materials including a magnesium compound, a precipitation aid, a titanium-containing compound, an acetate compound, an organic alcohol compound, an organic aluminum compound N and an electron donor compound. The catalyst provided by the invention is used for preparing special / ultra-high molecular weight polyolefin through olefin polymerization reaction, and the prepared polymer has the advantages of controllable molecular weight, narrow molecular weight distribution, low hexane extract content, low large particle and fine powder content, low branching degree, high sphericity and better low entanglement performance.
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